WO2022101662A1 - Analog stack for debugging sofc system - Google Patents

Analog stack for debugging sofc system Download PDF

Info

Publication number
WO2022101662A1
WO2022101662A1 PCT/IB2020/060670 IB2020060670W WO2022101662A1 WO 2022101662 A1 WO2022101662 A1 WO 2022101662A1 IB 2020060670 W IB2020060670 W IB 2020060670W WO 2022101662 A1 WO2022101662 A1 WO 2022101662A1
Authority
WO
WIPO (PCT)
Prior art keywords
stack
combustion
debugging
analog
supporting gas
Prior art date
Application number
PCT/IB2020/060670
Other languages
French (fr)
Inventor
Youpeng CHEN
Changming HU
Tianqin KANG
Zuofeng WANG
Original Assignee
Ceres Intellectual Property Company Limited
Weichai Power Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ceres Intellectual Property Company Limited, Weichai Power Co., Ltd. filed Critical Ceres Intellectual Property Company Limited
Priority to PCT/IB2020/060670 priority Critical patent/WO2022101662A1/en
Publication of WO2022101662A1 publication Critical patent/WO2022101662A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/247Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • H01M8/2475Enclosures, casings or containers of fuel cell stacks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the present invention relates to the technical field of solid oxide fuel cells, particularly to an analog stack for debugging an SOFC system.
  • a solid oxide fuel cell (SOFC) system is a high-temperature operating system, so after all components are assembled, the operation and control strategy of the overall system needs to be debugged. Throughout the process, various extreme conditions need to be verified and frequent start, shutdown, disassembly, and installation are needed. Because the SOFC known stacks (real stack) are mostly made of a ceramic material, and the number of thermal cycles is limited, and the cost is high, if a real stack is used for simulation, damage to the real stack will be inevitable.
  • An object of the present invention is to provide an analog stack for debugging an SOFC system.
  • the analog stack is similar to a real stack and can better simulate the operating conditions of the real stack.
  • the present invention provides an analog stack for debugging an SOFC system.
  • the analog stack comprises a casing in a shape and size the same as those of a casing of a real stack; a gas pipe, mounted in the casing and forming a gas inlet and a gas outlet; a combustion-supporting gas pipe, mounted in the casing and forming a combustion-supporting gas inlet and a combustion-supporting gas outlet; and a counter weight, mounted in the casing so that the weight of the analog stack is equal to the weight of the real stack.
  • a gas pipe and a combustion-supporting gas pipe are arranged inside the analog stack and are used for simulating connection to a combustor, a preheater, and other peripheral components.
  • the shape and size of the casing are the same as those of a casing of the real stack and can verify whether the installation space is sufficient and whether the installation process is feasible.
  • a counterweight is mounted in the casing, so by using different counter weights, the weight of the analog stack can be changed so that the analog stack and the real stack have the same weight. Thereby it can be determined whether the stack bracket can provide a reliable support and the mass balance of the SOFC system can be verified.
  • the analog stack provided by the present invention is more similar to a real stack and can better simulate the operating conditions of the real stack and verify more parameters to debug the SOFC system in a more comprehensive manner.
  • the casing comprises a top plate, a bottom plate and a perimeter plate.
  • the gas inlet, the gas outlet, and the combustion-supporting gas inlet and the combustion-supporting gas outlet are arranged on the top plate and/or the bottom plate.
  • Two ends of the gas pipe are mounted in the gas inlet and the gas outlet respectively, and two ends of the combustion-supporting gas pipe are mounted in the combustion-supporting gas inlet and the combustion-supporting gas outlet respectively.
  • the gas pipe and the combustion-supporting gas pipe each comprise at least one section of corrugated pipe.
  • At least one of the gas inlet and the gas outlet is provided with a necking ring, and at least one of the combustion-supporting gas inlet and the combustion-supporting gas outlet is provided with a necking ring.
  • the material of the bottom plate is the same as the material of the fixing plate of the gas pipe and the combustion-supporting gas pipe in the real stack.
  • the top plate is mounted with a collecting terminal, which is electrically insulated from the top plate.
  • the top plate is provided with a through hole.
  • the upper end and lower end of the through hole are each provided with a mounting groove extending outwards in a radial direction, and insulation spacers are arranged inside the mounting grooves.
  • the collecting terminal comprises a terminal portion and a threaded rod portion.
  • the threaded rod portion can pass through the insulation spacer on the upper side, the through hole and the insulation spacer on the lower side and is fixed with a nut.
  • the terminal portion presses against the insulation spacer on the upper side, the nut presses against the insulation spacer on the lower side, and the threaded rod portion is in clearance fit with the through hole.
  • the insulation spacers are mica spacers
  • the top plate is further provided with lifting holes and stack fixing holes.
  • the perimeter plate is a split structure.
  • the counterweight is mounted on the top plate and/or the bottom plate in a detachable manner.
  • Fig. l is a structural schematic view of a specific implementation manner of an analog stack for debugging an SOFC system.
  • Fig. 2 is a structural view of the connection between a gas pipe or a combustion-supporting gas pipe and a bottom plate.
  • Fig. 3 is a structural view of the connection between a collecting terminal and a top plate.
  • Fig. 4 is a structural view of the connection between a counterweight and a bottom plate.
  • Fig. 5 is a structural view of the connection of an analog stack to a combustor and a preheater.
  • Fig. 1 to Fig. 5 The reference numerals used in Fig. 1 to Fig. 5 are as follows: 1 casing, 11 top plate, 111 through hole, 12 bottom plate, 121 gas inlet, 122 gas outlet, 123 combustion-supporting gas inlet, 124 combustion-supporting gas outlet, 125 necking ring, 13 perimeter plate, 2 gas pipe, 21 corrugated pipe, 3 combustion-supporting gas pipe, 4 counterweight, 41 connecting piece, 5 collecting terminal, 51 terminal portion, 52 threaded rod portion, 6 insulation spacer, 7 nut, 8 combustor, 9 preheater.
  • the present invention provides an analog stack for debugging an SOFC system.
  • the analog stack comprises a casing 1 in a shape and size the same as those of a casing of a real stack.
  • a gas pipe 2 is mounted in the casing 1, forming a gas inlet 121 and a gas outlet 122.
  • a combustion-supporting gas pipe 3 is mounted in the casing 1, forming a combustion-supporting gas inlet 123 and a combustion-supporting gas outlet 124.
  • a counterweight 4 is mounted in the casing 1 so that the weight of the analog stack is equal to the weight of the real stack.
  • a gas pipe 2 and a combustion-supporting gas pipe 3 are arranged inside the analog stack provided by the present invention and are used for simulating connection to a combustor 8, a preheater 9 and other peripheral components.
  • the shape and size of the casing 1 are the same as those of a casing of the real stack and can verify whether the installation space is sufficient and whether the installation process is feasible.
  • a counterweight 4 is mounted in the casing 1. By using different counterweights 4, the weight of the analog stack can be changed so that the analog stack and the real stack have the same weight. Thereby it can be determined whether the stack bracket can provide a reliable support and the mass balance of the SOFC system can be verified.
  • the analog stack provided by the present invention is more similar to a real stack and can better simulate the operating conditions of the real stack and verify more parameters to debug the SOFC system in a more comprehensive manner.
  • gas input to the foregoing gas pipe 2 can be hydrogen (H2), methane (CH4), city coal gas, or other combustible gases
  • combustion-supporting gas input to the combustion-supporting gas pipe 3 can be oxygen, air, etc.
  • gas and combustion-supporting gas can be input to the stack after heating and temperature rise in the preheater 9 in order to undergo reactions and generate power.
  • the gas and combustion-supporting gas that are not fully reacted can be input to the combustor 8 for combustion.
  • the heat obtained from the combustion can be input to the preheater 9 to heat gas and combustion-supporting gas to form a gas circulation.
  • the analog stack provided by the present invention does not need to be used to generate power, and the provision of the gas pipe 2 and the combustion-supporting gas pipe 3 is principally used for diverting gas and combustion-supporting gas, and may also be used for verifying heat expansibility, etc. (see below for details).
  • the casing 1 may comprise a top plate 11, a bottom plate 12 and a perimeter plate 13.
  • the gas inlet 121, gas outlet 122, combustion-supporting gas inlet 123, and combustion-supporting gas outlet 124 can be arranged on the top plate 11 and/or the bottom plate 12.
  • Two ends of the gas pipe 2 can be mounted in the gas inlet 121 and the gas outlet 122 respectively, and two ends of the combustion-supporting gas pipe 3 can be mounted in the combustion-supporting gas inlet 123 and the combustion-supporting gas outlet 124 respectively.
  • the gas pipe can be designed to be a U pipe. If the gas inlet and outlet are arranged on the top plate 11 and the bottom plate 12 respectively, then the gas pipe can be designed to be a straight pipe. In the embodiments shown in the drawings, the gas inlet 121, the gas outlet 122, the combustion-supporting gas inlet 123, and the combustion-supporting gas outlet 124 are all arranged on the bottom plate 12, so the gas pipe 2 and the combustion-supporting gas pipe 3 can both be U pipes.
  • the upper end of the gas inlet 121 can be provided with a first slot extending outwards in a radial direction.
  • An end of the gas pipe 2 can be inserted into the first slot and then the gas pipe 2 can be fixed by means such as welding.
  • This solution of first insertion and positioning and then fixing by welding can simplify the welding operation and is more favorable for ensuring the reliability of welding.
  • the structures for connecting the gas outlet 122, the combustion-supporting gas inlet 123, and the combustion-supporting gas outlet 124 to the ends of corresponding gas pipes are similar to the above-mentioned structure, so they are not described again here.
  • the gas pipe 2 and the combustion-supporting gas pipe 3 can each comprise at least one section of corrugated pipe 21.
  • the corrugated pipe 21 can better ease the pipeline deformation caused by thermal expansion at high temperatures to lengthen the service life of the gas pipe 2 and the combustion-supporting gas pipe 3.
  • the embodiments of the present invention do not limit the number of corrugated pipe sections 21 arranged in each gas pipe, which can be one or more, and which can be selected according to actual needs.
  • At least one of the gas inlet 121 and the gas outlet 122, and at least one of the combustion-supporting gas inlet 123 and the combustion-supporting gas outlet 124 can be provided with a necking ring 125.
  • necking rings 125 By changing necking rings 125 in different inner diameters, the gas flow resistance of the gas line and the combustion-supporting gas line can be adjusted to achieve the purpose of adjusting pressure loss of the analog stack, so that the pressure loss of the analog stack is the same as that of the real stack, thereby better simulating the operating conditions of the real stack.
  • the foregoing necking rings 125 may directly adopt a press-fitting solution.
  • the lower end of the gas inlet 121 may also be provided with a second slot extending outwards in a radial direction, and the outer diameter of the necking ring 125 can be slightly greater than the inner diameter of the second slot.
  • the necking ring 125 can be press-fitted in the second slot, and against the bottom of the second slot to complete the mounting and fixation of the necking ring 125.
  • the necking ring 125 is taken out directly from the gas inlet 121 and then a new necking ring 125 is mounted.
  • the material of the bottom plate 12 is the same as the material of the fixing plate of the gas pipe and the combustion-supporting gas pipe in the real stack. In this way, it can be ensured that the bottom plate 12, and the fixing plates in the real stack produce the same thermal expansion in the heating process to verify whether the connecting methods of the gas pipe 2 and the combustion-supporting gas pipe 3 to the bottom plate 12 are reliable.
  • the structures and mounting and fixing methods of the gas pipe 2 and the combustion-supporting gas pipe 3 are illustrated by assuming that two ends of the gas pipe 2 and two ends of the combustion-supporting gas pipe 3 are all fixed to the bottom plate 12.
  • the two ends of the gas pipe 2 and the two ends of the combustion-supporting gas pipe 3 may also be mounted on different plate bodies respectively as long as their mounting positions are the same as the mounting positions of the gas pipe 2 and the combustion-supporting gas pipe 3 of the real stack in the SOFC system that is to be debugged.
  • the mounting positions and mounting methods of the gas pipe 2 and the combustion-supporting gas pipe 3 in the analog stack provided by the present invention need to be the same as the conditions in the real stack.
  • the structures and mounting positions of the gas pipe 2 and the combustion-supporting gas pipe 3 in the analog stack provided by the present invention can be adjusted in an adaptable manner.
  • gas inlet 121, gas outlet 122, combustion-supporting gas inlet 123 and combustion-supporting gas outlet 124 may also be formed by ends of the gas pipe 2 and the combustion-supporting gas pipe 3.
  • the necking rings 125 can be directly mounted inside the ends of corresponding gas pipes.
  • the top plate 11 can be mounted with a collecting terminal 5.
  • a collecting terminal 5 In general, there are two collecting terminals 5.
  • the two collecting terminals 5 can be connected to an anode and a cathode respectively and are used for exporting current of the real stack, while in the analog stack provided by the present invention, the provision of the collecting terminal 5 is principally for testing the circuit connection outside the stack.
  • the collecting terminal 5 should be electrically insulated from the top plate 11 so as to test whether the electrical connection is normal and reliable
  • the top plate 11 can be provided with a through hole 111, and both the upper end and lower end of the through hole 111 can be provided with a mounting groove extending outwards in a radial direction. Insulation spacers 6 can be arranged inside the mounting grooves.
  • the collecting terminal 5 may comprise a terminal portion 51 and a threaded rod portion 52, the terminal portion 51 can be used for connecting an external circuit, and the threaded rod portion 52 can be located under the terminal portion 51.
  • the threaded rod portion 52 can pass through the insulation spacer 6 on the upper side, the through hole 111 and the insulation spacer 6 on the lower side and is fixed with a nut 7.
  • the terminal portion 51 can press against the insulation spacer 6 on the upper side
  • the nut 7 can press against the insulation spacer 6 on the lower side.
  • the threaded rod portion 52 can be in clearance fit with the through hole 111 In other words, there may be a clearance between the outer wall of the threaded rod portion 52 and the inner wall of the through hole 11 to ensure electrical insulation between the collecting terminal 5 and the top plate 11.
  • insulation spacers 6 specifically can be mica spacers, rubber spacers, etc. and the top plate 11 can be further provided with lifting holes and stack fixing holes to facilitate the lifting, mounting and fixing of the analog stack provided by the present invention.
  • the perimeter plate 13 can be an integral structure, or a split structure. In the embodiments of the present invention, a split structure is preferred to make for processing.
  • the perimeter plate 13 may comprise a plurality of sub-plates, and the structure of the sub-plates is associated with the number of the sub-plates. In the embodiment shown in Fig. 1, there may be two sub-plates, and in this case, both of the sub-plates can be U-shaped plates. Of course, it is also acceptable that one sub-plate is a U-shaped plate and the other is a flat plate. In another embodiment, there may be four sub-plates, and in this case, all of the sub-plates are flat plates. Alternatively, there may be more than two sub-plates, with a single U-shaped plate and two or more flat plates. During specific mounting, the sub-plates can be fixed with the top plate 11 and the bottom plate 12 by means of welding or detachable connection.
  • the counterweight 4 specifically can be in a block shape and can be mounted on the top plate 11 and/or the bottom plate 12 in a manner of detachable connection to facilitate replacement of the counterweight 4.
  • a connecting piece 41 in the forms of a screw can be provided to fix the counterweight 4 to the connecting piece 41.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses an analog stack for debugging an SOFC (Solid Oxide Fuel Cell) system. The analog stack comprises a casing in a shape and size the same as those of a casing of a real stack; a gas pipe, mounted in the casing and forming a gas inlet and a gas outlet; a combustion-supporting gas pipe, mounted in the casing and forming a combustion-supporting gas inlet and a combustion-supporting gas outlet; and a counter weight, mounted in the casing so that the weight of the analog stack is equal to the weight of the real stack. The analog stack for debugging an SOFC system provided by the invention is more similar to a real stack and can better simulate the operating conditions of the real stack.

Description

Analog Stack for Debugging SOFC System
TECHNICAL FIELD
The present invention relates to the technical field of solid oxide fuel cells, particularly to an analog stack for debugging an SOFC system.
BACKGROUND ART
A solid oxide fuel cell (SOFC) system is a high-temperature operating system, so after all components are assembled, the operation and control strategy of the overall system needs to be debugged. Throughout the process, various extreme conditions need to be verified and frequent start, shutdown, disassembly, and installation are needed. Because the SOFC known stacks (real stack) are mostly made of a ceramic material, and the number of thermal cycles is limited, and the cost is high, if a real stack is used for simulation, damage to the real stack will be inevitable.
To address this problem, a popular solution at present is to use a pipe to short-circuit the gas inlet and outlet of the system. Although this solution is simple, it cannot fully simulate the operating conditions of the real stack, for example whether the installation space is suitable and whether the stack bracket can provide an effective support.
Therefore, how to provide a solution to better simulate the operating conditions of a real stack is still a problem.
SUMMARY OF THE INVENTION
An object of the present invention is to provide an analog stack for debugging an SOFC system. The analog stack is similar to a real stack and can better simulate the operating conditions of the real stack.
The present invention provides an analog stack for debugging an SOFC system. The analog stack comprises a casing in a shape and size the same as those of a casing of a real stack; a gas pipe, mounted in the casing and forming a gas inlet and a gas outlet; a combustion-supporting gas pipe, mounted in the casing and forming a combustion-supporting gas inlet and a combustion-supporting gas outlet; and a counter weight, mounted in the casing so that the weight of the analog stack is equal to the weight of the real stack.
A gas pipe and a combustion-supporting gas pipe are arranged inside the analog stack and are used for simulating connection to a combustor, a preheater, and other peripheral components. The shape and size of the casing are the same as those of a casing of the real stack and can verify whether the installation space is sufficient and whether the installation process is feasible. At the same time, a counterweight is mounted in the casing, so by using different counter weights, the weight of the analog stack can be changed so that the analog stack and the real stack have the same weight. Thereby it can be determined whether the stack bracket can provide a reliable support and the mass balance of the SOFC system can be verified.
Compared with the pipe short-circuit solution in the prior art, the analog stack provided by the present invention is more similar to a real stack and can better simulate the operating conditions of the real stack and verify more parameters to debug the SOFC system in a more comprehensive manner.
Optionally, the casing comprises a top plate, a bottom plate and a perimeter plate. The gas inlet, the gas outlet, and the combustion-supporting gas inlet and the combustion-supporting gas outlet are arranged on the top plate and/or the bottom plate. Two ends of the gas pipe are mounted in the gas inlet and the gas outlet respectively, and two ends of the combustion-supporting gas pipe are mounted in the combustion-supporting gas inlet and the combustion-supporting gas outlet respectively.
Optionally, the gas pipe and the combustion-supporting gas pipe each comprise at least one section of corrugated pipe.
Optionally, at least one of the gas inlet and the gas outlet is provided with a necking ring, and at least one of the combustion-supporting gas inlet and the combustion-supporting gas outlet is provided with a necking ring.
Optionally, the material of the bottom plate is the same as the material of the fixing plate of the gas pipe and the combustion-supporting gas pipe in the real stack.
Optionally, the top plate is mounted with a collecting terminal, which is electrically insulated from the top plate.
Optionally, the top plate is provided with a through hole. The upper end and lower end of the through hole are each provided with a mounting groove extending outwards in a radial direction, and insulation spacers are arranged inside the mounting grooves. The collecting terminal comprises a terminal portion and a threaded rod portion. The threaded rod portion can pass through the insulation spacer on the upper side, the through hole and the insulation spacer on the lower side and is fixed with a nut. The terminal portion presses against the insulation spacer on the upper side, the nut presses against the insulation spacer on the lower side, and the threaded rod portion is in clearance fit with the through hole.
Optionally, the insulation spacers are mica spacers, and the top plate is further provided with lifting holes and stack fixing holes.
Optionally, the perimeter plate is a split structure.
Optionally, the counterweight is mounted on the top plate and/or the bottom plate in a detachable manner.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. l is a structural schematic view of a specific implementation manner of an analog stack for debugging an SOFC system.
Fig. 2 is a structural view of the connection between a gas pipe or a combustion-supporting gas pipe and a bottom plate.
Fig. 3 is a structural view of the connection between a collecting terminal and a top plate.
Fig. 4 is a structural view of the connection between a counterweight and a bottom plate.
Fig. 5 is a structural view of the connection of an analog stack to a combustor and a preheater.
The reference numerals used in Fig. 1 to Fig. 5 are as follows: 1 casing, 11 top plate, 111 through hole, 12 bottom plate, 121 gas inlet, 122 gas outlet, 123 combustion-supporting gas inlet, 124 combustion-supporting gas outlet, 125 necking ring, 13 perimeter plate, 2 gas pipe, 21 corrugated pipe, 3 combustion-supporting gas pipe, 4 counterweight, 41 connecting piece, 5 collecting terminal, 51 terminal portion, 52 threaded rod portion, 6 insulation spacer, 7 nut, 8 combustor, 9 preheater.
DETAILED DESCRIPTION
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
As shown in Fig. 1, the present invention provides an analog stack for debugging an SOFC system. The analog stack comprises a casing 1 in a shape and size the same as those of a casing of a real stack. A gas pipe 2 is mounted in the casing 1, forming a gas inlet 121 and a gas outlet 122. A combustion-supporting gas pipe 3 is mounted in the casing 1, forming a combustion-supporting gas inlet 123 and a combustion-supporting gas outlet 124. A counterweight 4 is mounted in the casing 1 so that the weight of the analog stack is equal to the weight of the real stack.
A gas pipe 2 and a combustion-supporting gas pipe 3 are arranged inside the analog stack provided by the present invention and are used for simulating connection to a combustor 8, a preheater 9 and other peripheral components. The shape and size of the casing 1 are the same as those of a casing of the real stack and can verify whether the installation space is sufficient and whether the installation process is feasible. At the same time, a counterweight 4 is mounted in the casing 1. By using different counterweights 4, the weight of the analog stack can be changed so that the analog stack and the real stack have the same weight. Thereby it can be determined whether the stack bracket can provide a reliable support and the mass balance of the SOFC system can be verified.
Compared with the pipe short-circuit solution in the prior art, the analog stack provided by the present invention is more similar to a real stack and can better simulate the operating conditions of the real stack and verify more parameters to debug the SOFC system in a more comprehensive manner.
The term “Same” used in this description means being essentially the same, not that the two are identical. Variation is acceptable as long as simulation can be essentially performed on whether the installation space of the real stack is sufficient and whether the stack bracket can provide a support.
Further, the gas input to the foregoing gas pipe 2 can be hydrogen (H2), methane (CH4), city coal gas, or other combustible gases, and the combustion-supporting gas input to the combustion-supporting gas pipe 3 can be oxygen, air, etc. As shown in Fig. 5, for the SOFC system, gas and combustion-supporting gas can be input to the stack after heating and temperature rise in the preheater 9 in order to undergo reactions and generate power. The gas and combustion-supporting gas that are not fully reacted can be input to the combustor 8 for combustion. The heat obtained from the combustion can be input to the preheater 9 to heat gas and combustion-supporting gas to form a gas circulation. Compared with a real stack, the analog stack provided by the present invention does not need to be used to generate power, and the provision of the gas pipe 2 and the combustion-supporting gas pipe 3 is principally used for diverting gas and combustion-supporting gas, and may also be used for verifying heat expansibility, etc. (see below for details).
In a specific solution, the casing 1 may comprise a top plate 11, a bottom plate 12 and a perimeter plate 13. The gas inlet 121, gas outlet 122, combustion-supporting gas inlet 123, and combustion-supporting gas outlet 124 can be arranged on the top plate 11 and/or the bottom plate 12. Two ends of the gas pipe 2 can be mounted in the gas inlet 121 and the gas outlet 122 respectively, and two ends of the combustion-supporting gas pipe 3 can be mounted in the combustion-supporting gas inlet 123 and the combustion-supporting gas outlet 124 respectively.
If the gas inlet and outlet are arranged on the same plate body, then the gas pipe can be designed to be a U pipe. If the gas inlet and outlet are arranged on the top plate 11 and the bottom plate 12 respectively, then the gas pipe can be designed to be a straight pipe. In the embodiments shown in the drawings, the gas inlet 121, the gas outlet 122, the combustion-supporting gas inlet 123, and the combustion-supporting gas outlet 124 are all arranged on the bottom plate 12, so the gas pipe 2 and the combustion-supporting gas pipe 3 can both be U pipes.
Taking the structure for the connection between the gas inlet 121 and the gas pipe 2 for example, as shown in Fig. 2, the upper end of the gas inlet 121 can be provided with a first slot extending outwards in a radial direction. An end of the gas pipe 2 can be inserted into the first slot and then the gas pipe 2 can be fixed by means such as welding. This solution of first insertion and positioning and then fixing by welding can simplify the welding operation and is more favorable for ensuring the reliability of welding. The structures for connecting the gas outlet 122, the combustion-supporting gas inlet 123, and the combustion-supporting gas outlet 124 to the ends of corresponding gas pipes are similar to the above-mentioned structure, so they are not described again here.
The gas pipe 2 and the combustion-supporting gas pipe 3 can each comprise at least one section of corrugated pipe 21. The corrugated pipe 21 can better ease the pipeline deformation caused by thermal expansion at high temperatures to lengthen the service life of the gas pipe 2 and the combustion-supporting gas pipe 3. Here, the embodiments of the present invention do not limit the number of corrugated pipe sections 21 arranged in each gas pipe, which can be one or more, and which can be selected according to actual needs.
At least one of the gas inlet 121 and the gas outlet 122, and at least one of the combustion-supporting gas inlet 123 and the combustion-supporting gas outlet 124 can be provided with a necking ring 125. By changing necking rings 125 in different inner diameters, the gas flow resistance of the gas line and the combustion-supporting gas line can be adjusted to achieve the purpose of adjusting pressure loss of the analog stack, so that the pressure loss of the analog stack is the same as that of the real stack, thereby better simulating the operating conditions of the real stack.
The foregoing necking rings 125 may directly adopt a press-fitting solution. Taking the necking ring 125 in the gas inlet 121 for example, as shown in Fig. 2, the lower end of the gas inlet 121 may also be provided with a second slot extending outwards in a radial direction, and the outer diameter of the necking ring 125 can be slightly greater than the inner diameter of the second slot. In an assembly state, the necking ring 125 can be press-fitted in the second slot, and against the bottom of the second slot to complete the mounting and fixation of the necking ring 125. When replacement is needed, the necking ring 125 is taken out directly from the gas inlet 121 and then a new necking ring 125 is mounted.
Further, the material of the bottom plate 12 is the same as the material of the fixing plate of the gas pipe and the combustion-supporting gas pipe in the real stack. In this way, it can be ensured that the bottom plate 12, and the fixing plates in the real stack produce the same thermal expansion in the heating process to verify whether the connecting methods of the gas pipe 2 and the combustion-supporting gas pipe 3 to the bottom plate 12 are reliable.
In the foregoing solutions, the structures and mounting and fixing methods of the gas pipe 2 and the combustion-supporting gas pipe 3 are illustrated by assuming that two ends of the gas pipe 2 and two ends of the combustion-supporting gas pipe 3 are all fixed to the bottom plate 12. As a matter of fact, the two ends of the gas pipe 2 and the two ends of the combustion-supporting gas pipe 3 may also be mounted on different plate bodies respectively as long as their mounting positions are the same as the mounting positions of the gas pipe 2 and the combustion-supporting gas pipe 3 of the real stack in the SOFC system that is to be debugged.
In other words, the mounting positions and mounting methods of the gas pipe 2 and the combustion-supporting gas pipe 3 in the analog stack provided by the present invention need to be the same as the conditions in the real stack. For different forms of real stacks, the structures and mounting positions of the gas pipe 2 and the combustion-supporting gas pipe 3 in the analog stack provided by the present invention can be adjusted in an adaptable manner.
Further, the foregoing gas inlet 121, gas outlet 122, combustion-supporting gas inlet 123 and combustion-supporting gas outlet 124 may also be formed by ends of the gas pipe 2 and the combustion-supporting gas pipe 3. Now, the necking rings 125 can be directly mounted inside the ends of corresponding gas pipes.
The top plate 11 can be mounted with a collecting terminal 5. In general, there are two collecting terminals 5. In the real stack, the two collecting terminals 5 can be connected to an anode and a cathode respectively and are used for exporting current of the real stack, while in the analog stack provided by the present invention, the provision of the collecting terminal 5 is principally for testing the circuit connection outside the stack. The collecting terminal 5 should be electrically insulated from the top plate 11 so as to test whether the electrical connection is normal and reliable
As shown in Fig. 3, the top plate 11 can be provided with a through hole 111, and both the upper end and lower end of the through hole 111 can be provided with a mounting groove extending outwards in a radial direction. Insulation spacers 6 can be arranged inside the mounting grooves. The collecting terminal 5 may comprise a terminal portion 51 and a threaded rod portion 52, the terminal portion 51 can be used for connecting an external circuit, and the threaded rod portion 52 can be located under the terminal portion 51.
In an assembled state, the threaded rod portion 52 can pass through the insulation spacer 6 on the upper side, the through hole 111 and the insulation spacer 6 on the lower side and is fixed with a nut 7. The terminal portion 51 can press against the insulation spacer 6 on the upper side, the nut 7 can press against the insulation spacer 6 on the lower side. The threaded rod portion 52 can be in clearance fit with the through hole 111 In other words, there may be a clearance between the outer wall of the threaded rod portion 52 and the inner wall of the through hole 11 to ensure electrical insulation between the collecting terminal 5 and the top plate 11.
The foregoing insulation spacers 6 specifically can be mica spacers, rubber spacers, etc. and the top plate 11 can be further provided with lifting holes and stack fixing holes to facilitate the lifting, mounting and fixing of the analog stack provided by the present invention.
The perimeter plate 13 can be an integral structure, or a split structure. In the embodiments of the present invention, a split structure is preferred to make for processing. In detail, the perimeter plate 13 may comprise a plurality of sub-plates, and the structure of the sub-plates is associated with the number of the sub-plates. In the embodiment shown in Fig. 1, there may be two sub-plates, and in this case, both of the sub-plates can be U-shaped plates. Of course, it is also acceptable that one sub-plate is a U-shaped plate and the other is a flat plate. In another embodiment, there may be four sub-plates, and in this case, all of the sub-plates are flat plates. Alternatively, there may be more than two sub-plates, with a single U-shaped plate and two or more flat plates. During specific mounting, the sub-plates can be fixed with the top plate 11 and the bottom plate 12 by means of welding or detachable connection.
The counterweight 4 specifically can be in a block shape and can be mounted on the top plate 11 and/or the bottom plate 12 in a manner of detachable connection to facilitate replacement of the counterweight 4. Specifically, as shown in Fig. 4, a connecting piece 41 in the forms of a screw can be provided to fix the counterweight 4 to the connecting piece 41.
The above are only preferred implementation manners of the present invention. Various improvements and modifications can be made without departing from the principle of the present invention, and these improvements and modifications should also be considered within the scope of protection of the present invention.

Claims

1. An analog stack for debugging an SOFC system, comprising: a casing (1) having a shape and size the same as those of a casing (1) of a known stack; a gas pipe (2), mounted in the casing (1) and forming a gas inlet (121) and a gas outlet (122); a combustion-supporting gas pipe (3), mounted in the casing (1) and forming a combustion-supporting gas inlet (123) and a combustion-supporting gas outlet (124); and a counterweight (4) mounted in the casing (1) so that the weight of the analog stack is equal to the weight of the known stack.
2. The analog stack for debugging an SOFC system according to claim 1, wherein: the casing (1) comprises a top plate (11), a bottom plate (12), and a perimeter plate (13), and the gas inlet (121), the gas outlet (122), the combustion-supporting gas inlet (123), and the combustion-supporting gas outlet (124) are arranged on the top plate (11) and/or the bottom plate (12); and two ends of the gas pipe (2) are mounted in the gas inlet (121) and the gas outlet (122) respectively, and two ends of the combustion-supporting gas pipe (3) are mounted in the combustion-supporting gas inlet (123) and the combustion-supporting gas outlet (124) respectively.
3. The analog stack for debugging an SOFC system according to claim 2, wherein the gas pipe (2) and the combustion-supporting gas pipe (3) each comprise at least one section of corrugated pipe (21).
4. The analog stack for debugging an SOFC system according to claim 2 or 3, wherein the gas inlet (121) and/or the gas outlet (122) is provided with a necking ring (125), and the combustion-supporting gas inlet (123) and/or the combustion-supporting gas outlet (124) is provided with a necking ring (125).
5. The analog stack for debugging an SOFC system according to any of claims 2 to 4, wherein the material of the bottom plate (12) is the same as the material of the fixing plate of the gas pipe and the combustion-supporting gas pipe in the known stack.
6. The analog stack for debugging an SOFC system according to any one of claims 2 to 5, wherein the top plate (11) is provided with a collecting terminal (5), which is electrically insulated from the top plate (11).
7. The analog stack for debugging an SOFC system according to claim 6, wherein: the top plate (11) is provided with a through hole (111), the upper end and lower end of the through hole (111) are both provided with a mounting groove extending outwards in a radial direction, and insulation spacers (6) are arranged inside the mounting grooves; the collecting terminal (5) comprises a terminal portion (51) and a threaded rod portion (52), wherein the threaded rod portion (52) is configured to pass through the insulation spacer (6) on the upper side, the through hole (111), and the insulation spacer (6) on the lower side, and is fixed with a nut (7), such that the terminal portion (51) presses against the insulation spacer (6) on the upper side, the nut (7) presses against the insulation spacer (6) on the lower side, and the threaded rod portion (52) is in a clearance fit with the through hole (111).
8. The analog stack for debugging an SOFC system according to claim 7, wherein the insulation spacers (6) are mica spacers and the top plate (11) is further provided with lifting holes and stack fixing holes.
9. The analog stack for debugging an SOFC system according to claim 6, 7, or 8, wherein the perimeter plate (13) is a split structure.
10. The analog stack for debugging an SOFC according to claim 9, wherein the split structure comprises more than two sub-plates, with a single U-shaped plate and two or more flat plates.
11. The analog stack for debugging an SOFC system according to any of claims 6 to 10, wherein the counterweight (4) is mounted on the top plate (11) and/or the bottom plate (12) in a detachable manner.
PCT/IB2020/060670 2020-11-12 2020-11-12 Analog stack for debugging sofc system WO2022101662A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/IB2020/060670 WO2022101662A1 (en) 2020-11-12 2020-11-12 Analog stack for debugging sofc system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2020/060670 WO2022101662A1 (en) 2020-11-12 2020-11-12 Analog stack for debugging sofc system

Publications (1)

Publication Number Publication Date
WO2022101662A1 true WO2022101662A1 (en) 2022-05-19

Family

ID=73854845

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2020/060670 WO2022101662A1 (en) 2020-11-12 2020-11-12 Analog stack for debugging sofc system

Country Status (1)

Country Link
WO (1) WO2022101662A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116259795A (en) * 2023-05-09 2023-06-13 武汉海亿新能源科技有限公司 Simulated galvanic pile device for ejector test and control method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060083975A1 (en) * 2004-10-15 2006-04-20 Hyundai Mobis Co., Ltd. Fuel cell stack mock-up and pressure measuring instrument of fuel cell balance of plant using fuel cell stack mock-up
US20110129754A1 (en) * 2009-12-02 2011-06-02 Haltiner Jr Karl J Structure for Forming a Solid Oxide Fuel Cell Stack
CN209896186U (en) * 2019-06-03 2020-01-03 潍柴动力股份有限公司 Simulation galvanic pile for SOFC system debugging

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060083975A1 (en) * 2004-10-15 2006-04-20 Hyundai Mobis Co., Ltd. Fuel cell stack mock-up and pressure measuring instrument of fuel cell balance of plant using fuel cell stack mock-up
US20110129754A1 (en) * 2009-12-02 2011-06-02 Haltiner Jr Karl J Structure for Forming a Solid Oxide Fuel Cell Stack
CN209896186U (en) * 2019-06-03 2020-01-03 潍柴动力股份有限公司 Simulation galvanic pile for SOFC system debugging

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116259795A (en) * 2023-05-09 2023-06-13 武汉海亿新能源科技有限公司 Simulated galvanic pile device for ejector test and control method thereof
CN116259795B (en) * 2023-05-09 2023-07-25 武汉海亿新能源科技有限公司 Simulated galvanic pile device for ejector test and control method thereof

Similar Documents

Publication Publication Date Title
JP3580455B2 (en) Molten carbonate fuel cell and power generator using the same
EP1825546B1 (en) Solid oxide fuel cell system
US20060204821A1 (en) Fuel cell end unit with integrated heat exchanger
CN111457585B (en) High-temperature pure air heater
RU2459764C1 (en) Apparatus for producing hydrogen and fuel cell system equipped with said apparatus
CN101682071A (en) Solid state oxide fuel cell
WO2022101662A1 (en) Analog stack for debugging sofc system
JP2017076609A (en) Fuel cell module including heat exchanger and method for actuating such module
CN209896186U (en) Simulation galvanic pile for SOFC system debugging
US4824742A (en) Manifold, bus support and coupling arrangement for solid oxide fuel cells
Hosoi et al. Status of national project for SOFC development in Japan
CN116413602A (en) Device, method and application for testing performance of solid oxide cell and connector
JP3898647B2 (en) Cell stack and fuel cell
CN115295852A (en) SOFC (solid oxide Fuel cell) galvanic pile module and operation method thereof
CN214409059U (en) Test fixture of bipolar plate
CN116893352B (en) Solid oxide fuel cell test platform and test method
US20110033770A1 (en) Fuel cell stack having single body support
US8263288B2 (en) Rapid start-up, auxiliary power, and air preheating device of high temperature fuel cell systems
JP3764693B2 (en) Fuel cell
CN220894477U (en) Testing arrangement of SOFC monocell
TWI384678B (en) Rapid set-up, double chamber detecting device of solid oxide fuel cell positive-electrolyte-negative (pen) plate
CN113764704B (en) Stacking system of fuel cell stack and short circuit detection method thereof
CN113632270B (en) Electrochemical cell, electrochemical cell stack, method for producing an electrochemical cell, and method for producing an electrochemical cell stack
CN221041179U (en) Testing device for solid oxide fuel cell stack
KR102244133B1 (en) Connection type fuel cell system

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20825232

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20825232

Country of ref document: EP

Kind code of ref document: A1