WO2022087966A1 - 一种生物毒性预警监测系统及其方法 - Google Patents

一种生物毒性预警监测系统及其方法 Download PDF

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WO2022087966A1
WO2022087966A1 PCT/CN2020/124843 CN2020124843W WO2022087966A1 WO 2022087966 A1 WO2022087966 A1 WO 2022087966A1 CN 2020124843 W CN2020124843 W CN 2020124843W WO 2022087966 A1 WO2022087966 A1 WO 2022087966A1
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sewage
early warning
biological toxicity
monitoring system
detection unit
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PCT/CN2020/124843
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English (en)
French (fr)
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蔡健明
梁鹏
周碧波
郭承元
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中清信益环境(南京)有限公司
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment

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  • the invention relates to the field of sewage treatment detection, in particular to a biological toxicity early warning monitoring system and a method thereof.
  • the water quality early warning system can pre-evaluate the toxicity of the pollution accident, make a preliminary determination of the main pollutant types, and quickly take emergency measures to ensure the stable operation of the sewage treatment plant.
  • Traditional water quality monitoring methods mainly rely on physical and chemical analysis methods, and physical and chemical analysis methods relying on complex and large-scale instruments and equipment are not suitable for the development of online water quality early warning systems.
  • the measured pollutant concentration is the total concentration in the water body, which cannot reflect the actual exposure concentration of living organisms and their biological reactions, requiring tedious sample pretreatment processes and professional operations.
  • Bio early warning technology uses biosensors to monitor changes in biological indicators of test organisms at different levels to characterize changes in water quality to achieve early warning.
  • toxic substances flow in, the activity of electricity-generating microorganisms decreases, resulting in a decrease in electricity production; when nutrient substances flow in, the activity of electricity-generating microorganisms increases, resulting in an increase in electricity production.
  • the comprehensive toxicity level of the sample to be tested is expressed by continuously testing the toxicity of the sample. . Automatically control the whole process of water sample import to result calculation, and realize online monitoring of comprehensive toxicity of water quality.
  • the present invention provides a biological toxicity early warning monitoring system and a method thereof.
  • the incoming sewage is pretreated through a pretreatment unit to remove coarse impurities in the sewage, and then the sewage enters the detection unit, and the sewage is contained in the sewage.
  • the presence or absence of biological toxicity will have a certain impact on the power generation amount of the power generation microorganisms in the detection unit. According to the difference of the power generation amount, it can be detected whether the sewage contains biological toxicity; high sensitivity.
  • the present invention achieves the above technical purpose through the following technical means.
  • a biological toxicity early warning monitoring system comprising a pretreatment unit, a detection unit and a control unit; the pretreatment unit is used for rough filtering the incoming sewage; the detection unit is used to detect the sewage treated by the pretreatment unit Whether it has biological toxicity; the control unit controls the opening and closing of the valve by collecting and displaying the relevant data in the detection unit, thereby controlling whether the sewage enters the sewage treatment system.
  • the pretreatment unit sequentially includes a grid room and a sand settling area; wherein, the grid room is used to intercept larger floating objects and impurities in the sewage; the sand settling area is used to remove inorganic particles with a relatively high density.
  • the sewage passes through the coarse grid, the fine grid and the supporting facilities in sequence.
  • the detection unit includes a power-generating microbial carrier, and the power-generating microbial carrier is a device for converting chemical energy into electrical energy.
  • control unit includes a data processing module, a display recording module, a data storage module and an execution module; the data processing module sets different limits according to different water quality backgrounds, and saves the different limits in the data storage module;
  • the display and recording module is connected with an ammeter or a voltmeter to display the current generation of microorganism carriers in the detection unit;
  • the execution module is used to control the opening and closing of the valve on the water inlet pipeline of the detection unit.
  • the voltage or current generated by the microbial carrier is relatively small, which can be easily measured by adding a voltage amplifier or a current amplifier to amplify the voltage or current.
  • the power-generating microbial carrier is an electroactive organism, and the electroactive organism is made into a biological toxicity early warning chip by adopting the method of immobilizing microorganisms.
  • biotoxicity early warning chip can be produced in a standardized manner, and can be directly replaced with a new chip after an alarm.
  • the detection method of the biological toxicity early warning monitoring system includes the following steps: the pretreatment unit performs rough filtration on the incoming sewage; the microbial carrier in the detection unit performs biological toxicity detection on the pretreated sewage; the control unit is used for early warning and alarm and control the sewage Closure of the inlet valve on the inlet water treatment system.
  • the sewage entering the biological toxicity early warning monitoring system is a part of the sewage in the sewage influent water treatment system.
  • the water inlet valve of the sewage treatment system is closed; Sewage is a branch branch of the sewage main road.
  • the control system controls the closing of the water inlet valve on the sewage main road.
  • the incoming sewage is pretreated by the pretreatment unit to remove the coarse impurities in the sewage, and then the sewage enters the detection unit. Whether there is biological toxicity in the sewage will have a certain impact on the power generation microbial power generation in the detection unit. According to the power generation Different amounts of sewage can be detected to detect whether biological toxicity is contained in sewage; the invention is mainly applied in the front section of sewage treatment, and has high detection sensitivity to sewage with high biological toxicity.
  • the sewage passes through the coarse grid, the fine grid and the supporting facilities in turn, so as to intercept the larger floating objects and impurities in the sewage, which is used in the sand settling area. Inorganic particles with high density are removed. After the above-mentioned pretreatment of sewage, floating objects, impurities and inorganic particles are removed, so that the quality of sewage entering the detection unit can be improved, and the convenience and rapidity of biological toxicity detection can be improved.
  • the biotoxicity is detected by the power generation microbial battery, and the size of the biotoxicity is reflected by the reading size of the ammeter or the voltmeter, which is convenient and intuitive, and has good operability and flexibility.
  • the data processing module in the control unit sets different limits according to different water quality backgrounds, and saves the different limits in the data storage module; the display and record module is connected with an ammeter or a voltmeter to display the power generation of the microbial carrier in the current detection unit
  • the execution module is used to control the opening and closing of the valve on the water inlet pipeline of the detection unit; through the division of labor and cooperation of the above modules, the accuracy of the detection of biological toxicity and the completeness of the records are ensured. Controls so that when biological toxicity is detected, it can feed back and protect the wastewater treatment system.
  • the power generation microbial carrier is an electroactive organism.
  • the electroactive organism is made of an immobilized microorganism to make a biotoxicity early warning chip.
  • the biotoxicity early warning chip can be produced and replaced in a standardized manner, thereby reducing the production cost and improving the biotoxicity early warning chip. Convenience and operability for testing biological toxicity.
  • the current or voltage of the microbial fuel cell can be measured conveniently and accurately.
  • FIG. 1 is a schematic diagram of a related biological toxicity early warning monitoring system according to an embodiment of the present invention
  • FIG. 2 is a schematic diagram of the biological toxicity monitoring method of the present invention.
  • the terms “installed”, “connected”, “connected”, “fixed” and other terms should be understood in a broad sense, for example, it may be a fixed connection or a detachable connection , or integrally connected; it can be a mechanical connection or an electrical connection; it can be a direct connection, or an indirect connection through an intermediate medium, or the internal communication between the two components.
  • installed e.g., it may be a fixed connection or a detachable connection , or integrally connected; it can be a mechanical connection or an electrical connection; it can be a direct connection, or an indirect connection through an intermediate medium, or the internal communication between the two components.
  • the monitoring system uses microbial fuel cells to detect biological toxicity.
  • the specific principle is: the use of electricity-generating microorganisms to oxidize and decompose organic matter in water, and the generated electrons are transferred along the electrodes to generate current.
  • toxic substances flow in
  • the activity of electricity-generating microorganisms decreases, resulting in a decrease in electricity production.
  • nutrient substances flow in
  • the activity of electricity-generating microorganisms increases, resulting in an increase in electricity production.
  • the toxicity of the sample to be tested is measured to indicate its comprehensive toxicity level.
  • a biological toxicity early warning monitoring system comprising a pretreatment unit, a detection unit and a control unit; the pretreatment unit is used for rough filtering the incoming sewage; the detection unit is used to detect the sewage treated by the pretreatment unit Whether it has biological toxicity; the control unit controls the opening and closing of the valve by collecting and displaying the relevant data in the detection unit, thereby controlling whether the sewage enters the sewage treatment system.
  • the purpose of setting up the preprocessing unit in front of the detection unit is to remove impurities in the sewage that affect the effect of the subsequent detection unit through slag removal between the grids and sand removal in the sedimentation area, so that the sensitivity and accuracy of the detection unit are higher.
  • the pretreatment unit sequentially includes a grid room and a sand settling area; wherein, the grid room is used to intercept larger floating objects and impurities in the sewage; the sand settling area is used to remove the inorganic particles with high density; , the sewage passes through the coarse grid, the fine grid and the supporting facilities in turn.
  • the detection unit includes a power-generating microbial carrier, which is a device for converting chemical energy into electrical energy.
  • the control unit includes a data processing module, a display recording module, a data storage module and an execution module; the data processing module sets different limits according to different water quality backgrounds, and saves the different limits in the data storage module; the display and recording module An ammeter or a voltmeter is connected to display the electricity generation situation of the microbial carrier in the current detection unit; the execution module is used to control the opening and closing of the valve on the water inlet pipeline of the detection unit.
  • control unit satisfies in the present invention.
  • the limit value can be set according to different water quality backgrounds, with abnormal information recording and feedback functions, such as: insufficient water sample, insufficient nutrient solution, etc.;
  • the system can automatically reset to the state of restarting the measurement
  • the data processing system shall have the functions of data and operation log collection, storage, processing, display and output, and shall be able to store the original data and operation logs for at least 12 months.
  • the biological toxicity degree can be obtained, that is, under the specified conditions, the percentage of the electricity production of the microorganisms after the sewage to be tested enters the detection unit is reduced or increased relative to that before the introduction.
  • the voltage or current generated by the microbial carrier is relatively small, which can be easily measured by adding a voltage amplifier or a current amplifier to amplify the voltage or current.
  • the power-generating microbial carrier is an electroactive organism, and the electroactive organism is made of an immobilized microorganism to make a biotoxicity early warning chip; the biotoxicity early warning chip can be produced and replaced in a standardized manner.
  • the sewage in the sewage inflow treatment system in the sewage treatment plant is divided into several branches.
  • the valve on the main road of the sewage system will automatically close under the control of the control system, so that the sewage will no longer enter the sewage branch.
  • the biological toxicity early warning monitoring system monitors the biological toxicity. After toxicity, the biological toxicity early warning chip in the detection unit in the biological toxicity early warning monitoring system needs to be replaced.
  • the detection method of the biological toxicity early warning monitoring system includes the following steps: the pretreatment unit performs rough filtration on the incoming sewage; the microbial carrier in the detection unit performs biological toxicity detection on the pretreated sewage; the control unit is used for early warning and alarm and control the sewage Closure of the inlet valve on the inlet water treatment system.
  • the sewage entering the biological toxicity early warning monitoring system is a part of the sewage in the sewage influent water treatment system.
  • the biological toxicity early warning monitoring system detects biological toxicity
  • the water inlet valve of the sewage treatment system is closed; specifically: the sewage entering the pretreatment unit It is a branch branch of the sewage main road.
  • the control system controls the closing of the water inlet valve on the sewage main road.

Abstract

一种生物毒性预警监测系统及其方法,属于污水处理监测领域,包括预处理单元、检测单元和控制单元;预处理单元用来对进入的污水进行粗滤;检测单元用来对经过预处理单元处理后的污水检测是否具有生物毒性;控制单元通过对检测单元中相关数据的采集和显示,从而控制阀门的启闭,进而控制污水是否进入污水处理后续单元。预处理单元对进入的污水进行预处理,除去污水的粗粒杂质,然后污水进入检测单元,污水中是否存在生物毒性对检测单元内的发电微生物发电量会有一定的影响,根据发电量的不同从而检测出污水中是否含有生物毒性。主要应用在污水处理前段,对高的生物毒性污水检测灵敏度高。

Description

一种生物毒性预警监测系统及其方法 技术领域
本发明涉及污水处理检测领域,尤其涉及到一种生物毒性预警监测系统及其方法。
背景技术
目前,工业和生活用水量很大,水污染问题制约着社会经济的发展。污水处理技术已从传统单纯去除污染物的高能耗、资源浪费型向污水资源化处理过渡,并开发了多种新型水处理技术。以活性污泥工艺为主要代表的污水处理工艺已经得到了广泛的应用,随着排放标准的逐渐提高,对污水处理厂的稳定运行和水质达标均提出了很高的要求。对污水处理厂进水水质的监测一般仅包含常规指标,例如常规五项、COD、氨氮、总氮和总磷等。但对于进水有毒有害物质的监测尚处于探索阶段,特别是对影响污水处理厂活性污泥的性能,造成生产事故的有毒有害物质,是污水处理厂稳定运行和水质达标需要关注并做好防范的重点之一。
水质预警系统可在污染事故发生时,对其毒性做出预先评价,对其主要污染物类型进行初步判定,并迅速采取应急措施,从而保障污水处理厂稳定运行。传统的水质监测手段主要依赖于物化分析方法,依赖复杂大型仪器设备的物化分析方法并不适用于在线水质预警系统的开发。例如,所测得的污染物浓度是水体中的总浓度,不能反映活体生物的实际暴露浓度及其生物反应,需要繁琐的样品前处理过程和专业人员操作。
生物预警技术通过生物传感器监测受试生物在不同水平上的生物学指标变化来表征水质变化实现预警。当毒性物质流入时,产电微生物活性降低,从而导致产电量下降;营养型物质流入时,产电微生物活性增加,从而导致产电量上升,通过连续测试待测样品毒性度来表示其综合毒性水平。自动控制水样导入至结果计算的全过程,实现水质综合毒性的在线监测。
发明内容
针对现有技术中存在不足,本发明提供了一种生物毒性预警监测系统及其方法,通过预处理单元对进入的污水进行预处理,去除污水的粗粒杂质,然后污水进入检测单元,污水中是否存在生物毒性对检测单元内的发电微生物发电量会有一定的影响,根据发电量的不同从而检测出污水中是否含有生物毒性;本发明主要应用在污水处理前段,对高的生物毒性污水检测灵敏度高。
本发明是通过以下技术手段实现上述技术目的的。
一种生物毒性预警监测系统,包括预处理单元、检测单元和控制单元;所述预处理单元用来对进入的污水进行粗滤;所述检测单元用来对经过预处理单元处理后的污水检测是否具 有生物毒性;所述控制单元通过对检测单元中相关数据的采集和显示,从而控制阀门的开闭,进而控制污水是否进入污水处理系统。
进一步的,所述预处理单元依次包括格栅间和沉砂区;其中,格栅间用来拦截污水中较大的漂浮物及杂质;沉砂区用来去除密度较大的无机颗粒。
进一步的,格栅间中,污水依次通过粗格栅、细格栅及配套设施。
进一步的,所述检测单元包括发电微生物载体,发电微生物载体为将化学能转化为电能的装置。
进一步的,所述控制单元包括数据处理模块、显示记录模块、数据储存模块和执行模块;所述数据处理模块根据不同水质背景设置不同限值,并将不同的限值保存到数据储存模块内;所述显示记录模块连接有电流表或者电压表用来显示当前检测单元中微生物载体发电情况;所述执行模块用来控制检测单元进水管路上阀门开闭。
进一步的,微生物载体的发电的电压或者电流比较小,通过增加电压放大器或者电流放大器放大电压或者电流可方便测得。
进一步的,发电微生物载体为电活性生物,将电活性生物采用固定化微生物方式,制成生物毒性预警芯片。
进一步的,所述生物毒性预警芯片可标准化生产,当报警后,可用新的芯片直接替换。
生物毒性预警监测系统的检测方法,包括如下步骤:预处理单元对进入的污水进行粗滤;检测单元中的微生物载体对预处理后的污水进行生物毒性检测;控制单元用来预警报警并控制污水进水处理系统上的进水管阀门的关闭。
进一步的,进入生物毒性预警监测系统的污水是污水进水处理系统中污水的一部分,当生物毒性预警监测系统检测出生物毒性后,关闭污水处理系统进水阀门;具体的:进入预处理单元的污水是污水干路分出的一个支路,检测单元检测到生物毒性后,控制系统控制污水干路上的进水阀门的关闭。
有益效果:
1.通过预处理单元对进入的污水进行预处理,除去污水的粗粒杂质,然后污水进入检测单元,污水中是否存在生物毒性对检测单元内的发电微生物发电量会有一定的影响,根据发电量的不同从而检测出污水中是否含有生物毒性;本发明主要应用在污水处理前段,对高的生物毒性污水检测灵敏度高。
2.在预处理单元中,在格栅间中,污水依次通过粗格栅、细格栅及配套设施,从而起到拦截污水中较大的漂浮物及杂质的作用,在沉砂区用来去除密度较大的无机颗粒,污水经过上述预处理,漂浮物及杂质和无机颗粒被除去,从而可以提高进入检测单元污水的质量,提 高了生物毒性检测的方便性和快速性。
3.检测单元中通过发电微生物电池对生物毒性进行检测,并通过电流表或者电压表来的读数大小来反应生物毒性的大小,方便且直观,具有很好的操作性和灵活性。
4.控制单元中数据处理模块根据不同水质背景设置不同限值,并将不同的限值保存到数据储存模块内;显示记录模块连接有电流表或者电压表用来显示当前检测单元中微生物载体发电情况;执行模块用来控制检测单元进水管路上阀门开闭;通过上述各个模块的分工合作,确保了生物毒性的检测准确性及记录的完备性,通过执行模块对检测单元进水管路上阀门开闭的控制,使得当生物毒性一旦被检测出来,就能反馈并保护污水处理系统。
5.发电微生物载体为电活性生物,将电活性生物采用固定化微生物方式,制成生物毒性预警芯片,该生物毒性预警芯片可标准化生产和替换,从而降低了生产成本,提高了生物毒性预警芯片检测生物毒性的方便性和可操作性。
6.通过增加电压放大器或者电流放大器,可对微生物燃料电池的电流或者电压方便准确的测得。
附图说明
图1为根据本发明实施例的涉及到的生物毒性预警监测系统原理图;
图2为本发明生物毒性监测方法的原理图。
具体实施方式
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,旨在用于解释本发明,而不能理解为对本发明的限制。
在本发明中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。
下面首先结合附图具体描述根据本发明实施例的
本监测系统利用微生物燃料电池对生物毒性进行检测,具体的原理为:利用产电微生物将水中的有机物氧化分解,产生的电子沿着电极转移而产生电流。当毒性物质流入时,产电微生物活性降低,从而导致产电量下降,营养型物质流入时,产电微生物活性增加,从而导致产电量上升,通过测试待测样品毒性度来表示其综合毒性水平。
一种生物毒性预警监测系统,包括预处理单元、检测单元和控制单元;所述预处理单元用来对进入的污水进行粗滤;所述检测单元用来对经过预处理单元处理后的污水检测是否具有生物毒性;所述控制单元通过对检测单元中相关数据的采集和显示,从而控制阀门的开闭,进而控制污水是否进入污水处理系统。
在检测单元前设置预处理单元的目的在于:通过格栅间除渣和沉沙区除砂去除污水中影响后续检测单元效果的杂质,使得检测单元的灵敏度和准确性更高。
所述预处理单元依次包括格栅间和沉砂区;其中,格栅间用来拦截污水中较大的漂浮物及杂质;沉砂区用来去除密度较大的无机颗粒;格栅间中,污水依次通过粗格栅、细格栅及配套设施。
所述检测单元包括发电微生物载体,发电微生物载体为将化学能转化为电能的装置。
控制单元包括数据处理模块、显示记录模块、数据储存模块和执行模块;所述数据处理模块根据不同水质背景设置不同限值,并将不同的限值保存到数据储存模块内;所述显示记录模块连接有电流表或者电压表用来显示当前检测单元中微生物载体发电情况;所述执行模块用来控制检测单元进水管路上阀门开闭。
本发明中控制单元满足的条件为:
应具有预警报警功能,可根据不同水质背景设置限值,有异常信息记录、反馈功能,如:水样不足、营养液不足等;
应具有仪器运行状态记录功能,如机箱温度、预警报警记录、仪器检测步骤等;
仪器意外断电再度通电后,系统能自动复位到重新开始测量的状态;
数据处理系统应具有数据和运行日志采集、存储、处理、显示和输出等功能,应能存储至少12个月的原始数据和运行日志。
本发明中根据电流表或者电压表的示数,可以得出生物毒性度,即在规定条件下,待测污水进入检测单元后微生物的产电量相对导入前所降低或者提高的百分比。
一般的,微生物载体的发电的电压或者电流比较小,通过增加电压放大器或者电流放大器放大电压或者电流可方便测得。
发电微生物载体为电活性生物,将电活性生物采用固定化微生物方式,制成生物毒性预警芯片;所述生物毒性预警芯片可标准化生产和替换。
结合附图2,从图2中可以看出,污水厂中的污水进水处理系统中的污水分为数个支路,在其中的支路一中安装生物毒性预警监测系统,对支路一中的污水进行生物毒性监测,当监测到生物毒性后,污水系统干路上的阀门在控制系统控制下会自行关闭,从而使得污水不再进入污水支路中,另外,生物毒性预警监测系统监测到生物毒性后,生物毒性预警监测系统 中的检测单元中的生物毒性预警芯片需要更换掉。
生物毒性预警监测系统的检测方法,包括如下步骤:预处理单元对进入的污水进行粗滤;检测单元中的微生物载体对预处理后的污水进行生物毒性检测;控制单元用来预警报警并控制污水进水处理系统上的进水管阀门的关闭。
其中,进入生物毒性预警监测系统的污水是污水进水处理系统中污水的一部分,当生物毒性预警监测系统检测出生物毒性后,关闭污水处理系统进水阀门;具体的:进入预处理单元的污水是污水干路分出的一个支路,检测单元检测到生物毒性后,控制系统控制污水干路上的进水阀门的关闭。
在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。
尽管上面已经示出和描述了本发明的实施例,可以理解的是,上述实施例是示例性的,不能理解为对本发明的限制,本领域的普通技术人员在不脱离本发明的原理和宗旨的情况下在本发明的范围内可以对上述实施例进行变化、修改、替换和变型。

Claims (10)

  1. 一种生物毒性预警监测系统,其特征在于,包括预处理单元、检测单元和控制单元;所述预处理单元用来对进入的污水进行粗滤;所述检测单元用来对经过预处理单元处理后的污水检测是否具有生物毒性;所述控制单元通过对检测单元中相关数据的采集和显示,从而控制阀门的开闭,进而控制污水是否进入污水处理系统。
  2. 根据权利要求1所述的生物毒性预警监测系统,其特征在于,所述预处理单元依次包括格栅间和沉砂区;其中,格栅间用来拦截污水中较大的漂浮物及杂质;沉砂区用来去除密度较大的无机颗粒。
  3. 根据权利要求2所述的生物毒性预警监测系统,其特征在于,格栅间中,污水依次通过粗格栅、细格栅及配套设施。
  4. 根据权利要求1所述的生物毒性预警监测系统,其特征在于,所述检测单元包括发电微生物载体,发电微生物载体为将化学能转化为电能的装置。
  5. 根据权利要求1所述的生物毒性预警监测系统,其特征在于,所述控制单元包括数据处理模块、显示记录模块、数据储存模块和执行模块;所述数据处理模块根据不同水质背景设置不同限值,并将不同的限值保存到数据储存模块内;所述显示记录模块连接有电流表或者电压表用来显示当前检测单元中微生物载体发电情况;所述执行模块用来控制检测单元进水管路上阀门开闭。
  6. 根据权利要求5所述的生物毒性预警监测系统,其特征在于,微生物载体的发电的电压或者电流比较小,通过增加电压放大器或者电流放大器放大电压或者电流可方便测得。
  7. 根据权利要求4所述的生物毒性预警监测系统,其特征在于,发电微生物载体为电活性生物,将电活性生物采用固定化微生物方式,制成生物毒性预警芯片。
  8. 根据权利要求7所述的生物毒性预警监测系统,其特征在于,所述生物毒性预警芯片可标准化生产。
  9. 根据权利要求1至8任一项所述的生物毒性预警监测系统的检测方法,其特征在于,包括如下步骤:
    预处理单元对进入的污水进行粗滤;
    检测单元中的微生物载体对预处理后的污水进行生物毒性检测;
    控制单元用来预警报警并控制污水进水处理系统上的进水管阀门的关闭。
  10. 根据权利要求9所述的生物毒性预警监测系统的检测方法,其特征在于,进入生物毒性预警监测系统的污水是污水进水处理系统中污水的一部分,当生物毒性预警监测系统检测出生物毒性后,关闭污水处理系统进水阀门;具体的:进入预处理单元的污水是污水干路分出的一个支路,检测单元检测到生物毒性后,控制系统控制污水干路上的进水阀门的关闭。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114965617A (zh) * 2022-06-06 2022-08-30 北京航空航天大学 一种识别电子受体导致的电化学活性微生物检测毒害污染物假阳性的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101477056A (zh) * 2009-01-22 2009-07-08 浙江清华长三角研究院 多通道发光细菌在线水质毒性监测装置及监测方法
CN102980983A (zh) * 2012-11-28 2013-03-20 广州中国科学院沈阳自动化研究所分所 一种污水生物毒性在线监测分析仪及监测系统
CN109856121A (zh) * 2019-02-19 2019-06-07 廊坊市慧璟科技有限公司 一种水质生物毒性在线检测的装置
US20190210897A1 (en) * 2018-01-08 2019-07-11 A. O. Smith Corporation Electrochemical analysis device for reagentless detection
CN210367341U (zh) * 2019-07-03 2020-04-21 上海泾泓环境科技有限公司 一种污水处理系统
CN111392970A (zh) * 2020-04-01 2020-07-10 北京鼎勝投资管理有限公司 一种污臭水处理装置和方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101477056A (zh) * 2009-01-22 2009-07-08 浙江清华长三角研究院 多通道发光细菌在线水质毒性监测装置及监测方法
CN102980983A (zh) * 2012-11-28 2013-03-20 广州中国科学院沈阳自动化研究所分所 一种污水生物毒性在线监测分析仪及监测系统
US20190210897A1 (en) * 2018-01-08 2019-07-11 A. O. Smith Corporation Electrochemical analysis device for reagentless detection
CN109856121A (zh) * 2019-02-19 2019-06-07 廊坊市慧璟科技有限公司 一种水质生物毒性在线检测的装置
CN210367341U (zh) * 2019-07-03 2020-04-21 上海泾泓环境科技有限公司 一种污水处理系统
CN111392970A (zh) * 2020-04-01 2020-07-10 北京鼎勝投资管理有限公司 一种污臭水处理装置和方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114965617A (zh) * 2022-06-06 2022-08-30 北京航空航天大学 一种识别电子受体导致的电化学活性微生物检测毒害污染物假阳性的方法
CN114965617B (zh) * 2022-06-06 2023-11-07 北京航空航天大学 一种识别电子受体导致的电化学活性微生物检测毒害污染物假阳性的方法

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