WO2022077366A1 - Fuel system components - Google Patents

Fuel system components Download PDF

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Publication number
WO2022077366A1
WO2022077366A1 PCT/CN2020/121228 CN2020121228W WO2022077366A1 WO 2022077366 A1 WO2022077366 A1 WO 2022077366A1 CN 2020121228 W CN2020121228 W CN 2020121228W WO 2022077366 A1 WO2022077366 A1 WO 2022077366A1
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WO
WIPO (PCT)
Prior art keywords
fuel
component
fuel system
steel alloy
phosphorous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2020/121228
Other languages
French (fr)
Inventor
Yang Su
Xiaoli Huang
Steven E. FERDON
Ross A. PHILLIPS
Manoj M. THETE
Brian J. Wright
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cummins Inc
Original Assignee
Cummins Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cummins Inc filed Critical Cummins Inc
Priority to CN202080106263.4A priority Critical patent/CN117157423A/en
Priority to PCT/CN2020/121228 priority patent/WO2022077366A1/en
Priority to DE112020007531.1T priority patent/DE112020007531T5/en
Publication of WO2022077366A1 publication Critical patent/WO2022077366A1/en
Priority to US18/299,934 priority patent/US11873547B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M61/00Fuel-injectors not provided for in groups F02M39/00 - F02M57/00 or F02M67/00
    • F02M61/16Details not provided for in, or of interest apart from, the apparatus of groups F02M61/02 - F02M61/14
    • F02M61/166Selection of particular materials
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24Nitriding
    • C23C8/26Nitriding of ferrous surfaces

Definitions

  • the present disclosure relates to fuel system components formed of a steel alloy and a method of making the same.
  • Fuel system components made from steel are often exposed to fuel with high acidity and/or sulfates that corrode the components, and lead to various issues such as cup flow issues and sealing issues, among others.
  • fuel with high acidity and/or sulfates that passes through an injector nozzle has been known to corrode the surface of the nozzle spray hole (s) enlarging the spray hole, and increasing the cup flow.
  • s nozzle spray hole
  • a fuel system comprising at least one fuel component formed of a steel alloy comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum, wherein the at least one fuel component is configured to come in contact with fuel when fuel is passed through the fuel system.
  • a method of manufacturing a component of a fuel system comprising rough machining an annealed steel alloy mass comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum to form the component, hardening a core of the component, nitriding the component after hardening the core of the component, and finish machining the component.
  • FIG. 1 shows a perspective view of a fuel pump of the present disclosure
  • FIG. 2 shows a cut-away view of the fuel pump of FIG. 1;
  • FIG. 3 shows a cross-sectional view of a portion of a fuel injector of the present disclosure
  • FIG. 4 shows a perspective view of an injector control valve seat of the fuel injector of FIG. 3;
  • FIG. 5 shows a perspective view of an injector needle seal of the fuel injector of FIG. 3;
  • FIG. 6 shows a perspective view of an injector needle of the fuel injector of FIG. 3;
  • FIG. 7 shows a perspective view of an injector nozzle of the fuel injector of FIG. 3;
  • FIG. 8A shows a perspective view of a first embodiment of a pump tappet barrel of the fuel pump of FIG. 1;
  • FIG. 8B shows a cross-sectional view of the pump tappet barrel of FIG. 8A
  • FIG. 9A shows a perspective view of a second embodiment of a pump tappet barrel of the fuel pump of FIG. 1;
  • FIG. 9B shows a cross-sectional view of the pump tappet barrel of FIG. 9A
  • FIG. 10 shows a method of forming a fuel system component of the present disclosure
  • FIG. 11A shows a detailed cross-section view of a fuel system component of the present disclosure after core hardening
  • FIG. 11B shows a detailed cross-section view of the fuel system component of FIG. 10A after gas nitriding
  • FIG. 12 shows a graph detailing nozzle cup flow versus time of a prior art nozzle as compared to that of a nozzle of the present disclosure.
  • a fuel system for an internal combustion engine includes a fuel pump 2 (FIGS. 1 and 2) and one or more fuel injectors 4 (FIG. 3) .
  • the fuel system may also include a fuel accumulator, valves, and other elements (not shown) which are fluidly coupled to fuel injector (s) 4 and/or fuel pump 2.
  • Fuel pump 2 is configured to provide pressurized fuel to fuel injector (s) 4, and each fuel injector 4 is configured to inject metered quantities of fuel into a combustion chamber of the internal combustion engine in timed relation to the reciprocation of an engine piston (not shown) .
  • fuel injector 4 includes an injector body 8 which houses an injector control valve seat 10 (FIG. 4) , an injector needle seal 12 (FIG. 5) , an injector needle 14 (FIG. 7) , and an injector nozzle 16 (FIG. 6) .
  • injector body 8 which houses an injector control valve seat 10 (FIG. 4) , an injector needle seal 12 (FIG. 5) , an injector needle 14 (FIG. 7) , and an injector nozzle 16 (FIG. 6) .
  • the structural and functional details of fuel injector 2 may be similar to those disclosed in U.S. Patent Nos. 5,676,114 and 7,156,368, the complete disclosures of which are expressly incorporated by reference herein.
  • fuel pump 4 includes at least one pump tappet barrel or pump compression cylinder 6, 6’ , illustratively two pump tappet barrels.
  • Pump tappet barrel 6, 6’ includes a plurality of channels 18 through which fuel may flow when fuel is passed through the fuel system.
  • Each of pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and injector nozzle 16 are fuel system components that are configured to contact fuel when fuel is passed through the fuel system.
  • exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 of the present disclosure are fabricated from an annealed steel alloy bar comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt.
  • exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 are fabricated from an annealed steel alloy bar, blank, or rough forged mass comprising 0.01-0.12 wt.
  • %carbon 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-5.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 – 0.100 wt. %vanadium, and 2.000-2.400 wt.
  • exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 are fabricated from an annealed steel alloy bar comprising 0.16-0.20 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt.
  • exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 are fabricated from an annealed steel alloy bar comprising 0.25-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
  • a method 20 for forming the exemplary fuel components is provided.
  • injector control valve seat 10 injector needle seal 12, injector needle 14, and/or injector nozzle 16
  • the annealed steel alloy bar, blank, or rough forged mass is rough machined into the shape and form of the specific fuel component in a first step 22.
  • the fuel component is then hardened in second step 24.
  • the fuel component is quenched, tempered, and/or age hardened to harden a core 25 of the fuel component (see FIG. 11A for a microstructure of the fuel component after core hardening) .
  • the hardness range of the fuel component after the core is hardened is approximately 50-62 HRC (Rockwell C) or approximately 505-790 HV.
  • the fuel component may be further hardened by subsequently gas nitriding the fuel component, as shown in step 26.
  • the gas nitriding of the fuel component results in a compound layer 27 comprising iron nitrides being formed on the surface of the fuel component (see FIG. 11B) .
  • the hardness range of the fuel component after gas nitriding is approximately 900-1100 HK500gf (Knoop Hardness) or approximately 905-1340 HV.
  • Finish machining may include creating spray holes among other machining via grinding, electrical discharge machining (EDM) , abrasive flow machining (AFM) , laser drilling, and/or marking.
  • a graph of the nozzle cup flow in pounds per hour (pph) versus time in hours of a currently used or currently produced nozzle as compared to that of a nozzle of the present disclosure is provided.
  • the currently used nozzle has a composition of 0.35-0.45 wt. %carbon, 0.80-1.20 wt. %silicon, 0.2-0.5 wt. %manganese, 0.0 -0.030 wt. %phosphorous, 0.005-0.017 wt. %sulfur, 4.75-5.50 wt. %chromium, 0.00-0.35 wt. %nickel, 1.1-1.75 wt.
  • the graph of FIG. 12 shows data for three runs 100, 101, and 102 of the currently used or currently produced nozzle, an average 103 of those three runs, two runs 104 and 105 of a nozzle of the present disclosure, and an average 106 of those two runs.
  • the nozzle of the present disclosure had an increase of nozzle cup flow from approximately 220 pph to approximately 240 pph after approximately 110 hours or a change in nozzle cup flow of approximately 20 pph, while the currently used nozzle had an increase of nozzle cup flow from 220 pph to approximately 250 pph after approximately 110 hours or a change in nozzle cup flow of approximately 30 pph.
  • the nozzle of the present disclosure has a better resistance to corrosion and thus a reduced increase in the cup flow as compared to the currently used or currently produced nozzle.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
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Abstract

A fuel system comprises at least one fuel component formed of a steel alloy comprising 0.01-0.31 wt. % carbon, 0.0-0.20 wt. % silicon, 0.15-0.50 wt. % manganese, 0.0 -0.015 wt. % phosphorous, 0.0-0.001 wt. % sulfur, 4.80-5.20 wt. % chromium, 4.80-6.20 wt. % nickel, 0.60-0.80 wt. % molybdenum, 0.0–0.550 wt. % vanadium, and 2.000-2.400 wt. % aluminum, wherein the at least one fuel component is configured to come in contact with fuel when fuel is running through the fuel system.

Description

FUEL SYSTEM COMPONENTS TECHNICAL FIELD
The present disclosure relates to fuel system components formed of a steel alloy and a method of making the same.
BACKGROUND
Fuel system components made from steel are often exposed to fuel with high acidity and/or sulfates that corrode the components, and lead to various issues such as cup flow issues and sealing issues, among others. For instance, fuel with high acidity and/or sulfates that passes through an injector nozzle has been known to corrode the surface of the nozzle spray hole (s) enlarging the spray hole, and increasing the cup flow. Thus, a need exists for improved fuel system components that better resist corrosion.
SUMMARY
In one embodiment of the present disclosure, a fuel system comprising at least one fuel component formed of a steel alloy comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum, wherein the at least one fuel component is configured to come in contact with fuel when fuel is passed through the fuel system.
In another embodiment of the present disclosure, a method of manufacturing a component of a fuel system comprising rough machining an annealed steel alloy mass comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum to form the component, hardening a core of the component, nitriding the component after hardening the core of the component, and finish machining the component.
Advantages and features of the embodiments of this disclosure will become more apparent from the following detailed description of exemplary embodiments when viewed in  conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows a perspective view of a fuel pump of the present disclosure;
FIG. 2 shows a cut-away view of the fuel pump of FIG. 1;
FIG. 3 shows a cross-sectional view of a portion of a fuel injector of the present disclosure;
FIG. 4 shows a perspective view of an injector control valve seat of the fuel injector of FIG. 3;
FIG. 5 shows a perspective view of an injector needle seal of the fuel injector of FIG. 3;
FIG. 6 shows a perspective view of an injector needle of the fuel injector of FIG. 3;
FIG. 7 shows a perspective view of an injector nozzle of the fuel injector of FIG. 3;
FIG. 8A shows a perspective view of a first embodiment of a pump tappet barrel of the fuel pump of FIG. 1;
FIG. 8B shows a cross-sectional view of the pump tappet barrel of FIG. 8A;
FIG. 9A shows a perspective view of a second embodiment of a pump tappet barrel of the fuel pump of FIG. 1;
FIG. 9B shows a cross-sectional view of the pump tappet barrel of FIG. 9A;
FIG. 10 shows a method of forming a fuel system component of the present disclosure;
FIG. 11A shows a detailed cross-section view of a fuel system component of the present disclosure after core hardening;
FIG. 11B shows a detailed cross-section view of the fuel system component of FIG. 10A after gas nitriding; and
FIG. 12 shows a graph detailing nozzle cup flow versus time of a prior art nozzle as compared to that of a nozzle of the present disclosure.
DETAILED DESCRIPTION OF THE DRAWINGS
Referring to FIGS. 1-3, a fuel system for an internal combustion engine (not shown) includes a fuel pump 2 (FIGS. 1 and 2) and one or more fuel injectors 4 (FIG. 3) . The fuel system may also include a fuel accumulator, valves, and other elements (not shown) which are fluidly coupled to fuel injector (s) 4 and/or fuel pump 2. Fuel pump 2 is configured to provide pressurized fuel to fuel injector (s) 4, and each fuel injector 4 is configured to inject metered quantities of fuel into a combustion chamber of the internal combustion engine in timed relation to the reciprocation of an engine piston (not shown) .
With reference to FIGS. 3-7, fuel injector 4 includes an injector body 8 which houses an injector control valve seat 10 (FIG. 4) , an injector needle seal 12 (FIG. 5) , an injector needle 14 (FIG. 7) , and an injector nozzle 16 (FIG. 6) . The structural and functional details of fuel injector 2 may be similar to those disclosed in U.S. Patent Nos. 5,676,114 and 7,156,368, the complete disclosures of which are expressly incorporated by reference herein.
Referring to FIGS. 2 and 8A-9B, fuel pump 4 includes at least one pump tappet barrel or pump compression cylinder 6, 6’ , illustratively two pump tappet barrels. Pump tappet barrel 6, 6’ includes a plurality of channels 18 through which fuel may flow when fuel is passed through the fuel system.
Each of pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and injector nozzle 16 are fuel system components that are configured to contact fuel when fuel is passed through the fuel system. To reduce corrosion, exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 of the present disclosure are fabricated from an annealed steel alloy bar comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum, and having a hardness of 240-350 HV (Vickers Pyramid Number) and a density of approximately 7500-7600 kg/m 3, and more particularly, approximately 7582 kg/m 3. More particularly, in a first embodiment, exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 are fabricated from an annealed steel alloy bar, blank, or rough forged mass comprising 0.01-0.12 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-5.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 – 0.100 wt. %vanadium, and 2.000-2.400 wt. %aluminum, while in a second embodiment, exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 are fabricated from an annealed steel alloy bar comprising 0.16-0.20 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum. In a third embodiment, exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16 are fabricated from an annealed steel alloy bar comprising 0.25-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
With reference to FIGS. 10-11B, a method 20 for forming the exemplary fuel components is provided. To begin the formation of the exemplary pump tappet barrel 6, injector control valve seat 10, injector needle seal 12, injector needle 14, and/or injector nozzle 16, the annealed steel alloy bar, blank, or rough forged mass is rough machined into the shape and form of the specific fuel component in a first step 22. The fuel component is then hardened in second step 24. To harden the fuel component, the fuel component is quenched, tempered, and/or age hardened to harden a core 25 of the fuel component (see FIG. 11A for a microstructure of the fuel component after core hardening) . The hardness range of the fuel component after the core is hardened is approximately 50-62 HRC (Rockwell C) or approximately 505-790 HV. In various embodiments, the fuel component may be further hardened by subsequently gas nitriding the fuel component, as shown in step 26. The gas nitriding of the fuel component results in a compound layer 27 comprising iron nitrides being formed on the surface of the fuel component (see FIG. 11B) . The hardness range of the fuel component after gas nitriding is approximately 900-1100 HK500gf (Knoop Hardness) or approximately 905-1340 HV. Once hardened, the fuel component can then be finish machined. Finish machining may include creating spray holes among other machining via grinding, electrical discharge machining (EDM) , abrasive flow machining (AFM) , laser drilling, and/or marking.
Referring to FIG. 12, a graph of the nozzle cup flow in pounds per hour (pph) versus time in hours of a currently used or currently produced nozzle as compared to that of a  nozzle of the present disclosure is provided. The currently used nozzle has a composition of 0.35-0.45 wt. %carbon, 0.80-1.20 wt. %silicon, 0.2-0.5 wt. %manganese, 0.0 -0.030 wt. %phosphorous, 0.005-0.017 wt. %sulfur, 4.75-5.50 wt. %chromium, 0.00-0.35 wt. %nickel, 1.1-1.75 wt. %molybdenum, 0.8 –1.2 wt. %vanadium, and 0.0-0.8 wt. %aluminum. The graph of FIG. 12 shows data for three  runs  100, 101, and 102 of the currently used or currently produced nozzle, an average 103 of those three runs, two  runs  104 and 105 of a nozzle of the present disclosure, and an average 106 of those two runs. As shown in the graph, the nozzle of the present disclosure had an increase of nozzle cup flow from approximately 220 pph to approximately 240 pph after approximately 110 hours or a change in nozzle cup flow of approximately 20 pph, while the currently used nozzle had an increase of nozzle cup flow from 220 pph to approximately 250 pph after approximately 110 hours or a change in nozzle cup flow of approximately 30 pph. Thus, the nozzle of the present disclosure has a better resistance to corrosion and thus a reduced increase in the cup flow as compared to the currently used or currently produced nozzle.
While various embodiments of the disclosure have been shown and described, it is understood that these embodiments are not limited thereto. The embodiments may be changed, modified and further applied by those skilled in the art. Therefore, these embodiments are not limited to the detail shown and described previously, but also include all such changes and modifications.

Claims (18)

  1. A fuel system, comprising:
    at least one fuel component formed of a steel alloy comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt.%sulfur, 4.80-5.20 wt. %chromium, 4.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum, wherein the at least one fuel component is configured to come in contact with fuel when fuel is passed through the fuel system.
  2. The fuel system of claim 1, wherein the at least one fuel component has a hardness of approximately 900-1100 HK500gf (Knoop Hardness) .
  3. The fuel system of claim 1, wherein the steel alloy comprises 0.01-0.12 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-5.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.100 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
  4. The fuel system of claim 1, wherein the steel alloy comprises 0.16-0.20 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
  5. The fuel system of claim 1, wherein the steel alloy comprises 0.25-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
  6. The fuel system of claim 1, wherein the at least one fuel component has a surface layer comprised of a nitride compound layer.
  7. The fuel system of claim 1, wherein the at least one fuel component includes at least one of an injector control valve seat, an injector needle seal, an injector needle, an injector nozzle and  a pump tappet barrel.
  8. A method of manufacturing a component of a fuel system, comprising:
    rough machining an annealed steel alloy mass comprising 0.01-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum to form the component;
    hardening a core of the component;
    nitriding the component after hardening the core of the component; and
    finish machining the component.
  9. The method of claim 8, wherein the step of finish machining the component includes at least one of grinding, electrical discharge machining, abrasive flow machining, laser drilling, and marking.
  10. The method of claim 8, wherein the annealed steel alloy has a density of 7,500-7,600 kg/m 3.
  11. The fuel system of claim 10, wherein the density is 7,582 kg/m 3.
  12. The method of claim 8, wherein a hardness of the annealed steel alloy mass is approximately 240-350 HV.
  13. The method of claim 8, wherein a hardness of the component after hardening the core is approximately 505-790 HV.
  14. The method of claim 8, wherein a hardness of the component after nitriding the component is approximately 905-1340 HV.
  15. The method of claim 8, wherein the step of hardening the core includes at least one of quenching, tempering, and age hardening of the component.
  16. The method of claim 8, wherein the annealed steel alloy mass comprises 0.01-0.12 wt. %carbon, 0.0-0.20 wt. %silicon, 0.15-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 4.80-5.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.0 –0.100 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
  17. The method of claim 8, wherein the annealed steel alloy mass comprises 0.16-0.20 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
  18. The method of claim 8, wherein the steel alloy comprises 0.25-0.31 wt. %carbon, 0.0-0.20 wt. %silicon, 0.20-0.50 wt. %manganese, 0.0 -0.015 wt. %phosphorous, 0.0-0.001 wt. %sulfur, 4.80-5.20 wt. %chromium, 5.80-6.20 wt. %nickel, 0.60-0.80 wt. %molybdenum, 0.450 –0.550 wt. %vanadium, and 2.000-2.400 wt. %aluminum.
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