WO2022070755A1 - Cartouche de parfum - Google Patents

Cartouche de parfum Download PDF

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Publication number
WO2022070755A1
WO2022070755A1 PCT/JP2021/032367 JP2021032367W WO2022070755A1 WO 2022070755 A1 WO2022070755 A1 WO 2022070755A1 JP 2021032367 W JP2021032367 W JP 2021032367W WO 2022070755 A1 WO2022070755 A1 WO 2022070755A1
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WO
WIPO (PCT)
Prior art keywords
aromatic
fragrance
base material
wasabi extract
isothiocyanate
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PCT/JP2021/032367
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English (en)
Japanese (ja)
Inventor
龍志 渡邊
Original Assignee
Ｆｕｔｕｒｅ Ｔｅｃｈｎｏｌｏｇｙ株式会社
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Priority claimed from JP2021081468A external-priority patent/JP2022060140A/ja
Application filed by Ｆｕｔｕｒｅ Ｔｅｃｈｎｏｌｏｇｙ株式会社 filed Critical Ｆｕｔｕｒｅ Ｔｅｃｈｎｏｌｏｇｙ株式会社
Publication of WO2022070755A1 publication Critical patent/WO2022070755A1/fr

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    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10—Chemical features of tobacco products or tobacco substitutes
    • A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18—Treatment of tobacco products or tobacco substitutes
    • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/20—Devices using solid inhalable precursors

Definitions

  • the present invention relates to an aromatic cartridge that is attached to a suction device having an electric heating means and can generate an aerosol containing an aromatic component by being heated by the electric heating means.
  • wasabi has a unique flavor that comes out of the nose when the user eats it. For this reason, wasabi is widely used as a spice.
  • Patent Document 1 describes that horseradish (wasabi) is used as a flavor material for oral tobacco.
  • Patent Document 2 discloses a dressing-type seasoning composition containing microcapsules containing a wasabi aroma component.
  • the present invention has been made in view of the above problems, and an object of the present invention is to provide an aromatic cartridge having a good flavor derived from wasabi and useful for health.
  • the fragrance cartridge of the present invention is attached to a suction device having an electric heating means, and is housed in a tubular cover and the cover in an fragrance cartridge that generates an aerosol by being heated by the electric heating means. It contains an aromatic substrate that generates an aerosol containing an aromatic component when heated, a filter housed in the cover, and a wasabi extract, and the wasabi extract is in the form of a liquid or solid. Alternatively, it is encapsulated and contained in any one or more of the above-mentioned aromatic cartridges.
  • the wasabi extract is in the form of a liquid or solid, or is encapsulated, and is contained in one or more of the above-mentioned aromatic cartridges, so that the aerosol generated from the aromatic substrate contains wasabi. It is possible to contain an extract. As a result, the user can aspirate the aromatic component and the vaporized wasabi extract generated from the aromatic substrate together with the aerosol.
  • the wasabi extract has a good flavor derived from wasabi and is useful for health.
  • the wasabi extract preferably contains allyl isothiocyanate.
  • the user can aspirate the aromatic component generated from the aromatic substrate and the vaporized allyl isothiocyanate together with the aerosol. Allyl isothiocyanate can deepen the flavor of aromatic components that can be perceived by the user. Therefore, it is possible to impart a deep flavor to the aroma cartridge.
  • the allyl isothiocyanate is contained in an amount of 1 to 50 mg per fragrance cartridge.
  • the wasabi extract preferably contains 6-methylsulfinylhexyl isothiocyanate.
  • the user can aspirate the aromatic component generated from the aromatic substrate and the vaporized 6-methylsulfinylhexyl isothiocyanate together with the aerosol.
  • 6-Methylsulfinylhexyl isothiocyanate can exert effects such as antioxidant action and anti-inflammatory action in the user's body, for example.
  • the aromatic cartridge of the present invention preferably contains the above-mentioned 6-methylsulfinylhexyl isothiocyanate in an amount of 0.1 to 5 mg per aromatic cartridge.
  • the wasabi extract is preferably contained by being dissolved in a solvent selected from fats and oils and alcohol-based solvents.
  • the wasabi extract can be easily mixed, impregnated or encapsulated in, for example, an aromatic base material or a filter by dissolving and containing the wasabi extract in a solvent selected from fats and oils and alcohol-based solvents. can.
  • the fragrance base material contains a pulverized dried plant, an aerosol former, and a sorbent for sorbing the wasabi extract on the fragrance base material, and the wasabi extract. It is preferable that the substance is mixed and contained in the raw material of the aromatic base material.
  • the wasabi extract is mixed and contained in the raw material of the aromatic base material, so that when the aromatic base material is heated, the aromatic component generated from the aromatic base material and the vaporized wasabi The components of the extract are released with the aerosol. Therefore, the user can effectively inhale the wasabi extract while enjoying the scent of the aromatic component.
  • the fragrance substrate includes the fragrance substrate and a support member arranged between the filters, and the wasabi extract is encapsulated in (a) the fragrance substrate, (b). ) Placed at least one selected from between the aromatic base material and the support member, (c) in the support member, (d) between the support member and the filter, and (e) in the filter. It is preferable that it is.
  • the wasabi extract is encapsulated and arranged, the coating of the capsule is melted by heating, the coating is destroyed by the electric heating means, or the user presses the capsule when smoking. By breaking the coating, wasabi extract flows out. Therefore, the user can aspirate a high concentration of wasabi extract and can expect a higher flavor of aroma components. Further, by encapsulating the wasabi extract in the capsule, it is possible to prevent the wasabi extract from volatilizing.
  • the capsule is formed by coating the wasabi extract with a paste solution containing a gelling agent selected from alginate and pectin, and the paste solution is coagulated by calcium ions. Is preferable.
  • the aroma cartridge of the present invention in addition to the wasabi extract, it is preferable that at least one selected from a refreshing agent, a flavoring agent, and a fragrance is contained as the aroma component.
  • the wasabi extract in addition to the wasabi extract, at least one selected from a refreshing agent, a flavoring agent, and a fragrance is contained as the aroma component, so that the wasabi extract has a refreshing flavor and the like. Can be improved to provide a deeper flavor.
  • the capsule contains the wasabi extract and the fragrance component.
  • the wasabi extract and the aromatic component are released to the outside of the capsule. That is, the user can include more wasabi extract and aromatic components in the aerosol when using the aromatic cartridge.
  • the wasabi extract is contained in any one or more of the fragrance cartridges, the user can ingest the wasabi extract by smoking. That is, the user can taste the good flavor derived from wasabi, and can obtain health-useful effects such as antioxidant action and anti-inflammatory action.
  • FIG. 1 It is a perspective view of the fragrance cartridge which concerns on one Embodiment of this invention. It is a developed perspective view of the fragrance cartridge. It is an enlarged cross-sectional view along the line AA of FIG. It is a perspective view of the fragrance cartridge. It is a flow chart which shows the manufacturing process of the aromatic base material of FIG. It is a flow chart which shows the raw material (A2) manufacturing process of FIG. It is a flow chart which shows the other manufacturing process of the aromatic base material of FIG. It is a perspective view of the fragrance cartridge which concerns on Embodiment 2. FIG. It is a perspective view of the fragrance cartridge which concerns on Embodiment 3. FIG. It is a perspective view of the fragrance cartridge which concerns on Embodiment 4. FIG.
  • FIG. 1 It is a perspective view of the fragrance cartridge which concerns on Embodiment 5. It is a perspective view of the fragrance cartridge which concerns on Embodiment 6. It is a perspective view of the fragrance cartridge which concerns on Embodiment 7. It is a perspective view of the fragrance cartridge which concerns on Embodiment 8. It is a perspective view of the fragrance cartridge which concerns on Embodiment 9. FIG. It is a perspective view of the fragrance cartridge which concerns on Embodiment 9 which shows the form of another capsule.
  • FIG. 1 is a perspective view of an fragrance cartridge according to the present embodiment.
  • FIG. 2 is a developed perspective view of the fragrance cartridge.
  • FIG. 3 is an enlarged cross-sectional view taken along the line AA of FIG.
  • FIG. 4 is a perspective view of the fragrance cartridge according to the present embodiment.
  • the fragrance cartridge 100 can be used for a heat-not-burn tobacco cartridge.
  • the fragrance cartridge 100 is a cartridge used for a heated cigarette, which is a suction device having an electric heating means, will be described.
  • the fragrance cartridge 100 includes a tubular cover 10, an fragrance base material 20 housed on one end side of the cover 10, a filter 30 housed on the other end side of the cover 10, and an fragrance group housed in the cover 10.
  • a support member 40 arranged between the material 20 and the filter 30 is provided.
  • the aromatic base material 20, the support member 40, and the filter 30 are arranged along the axial direction from one end side to the other end side of the cover 10.
  • the cover 10 further includes a wrapping paper 11 that covers the fragrance base material 20, a base material 12 that covers the fragrance base material 20, the support member 40, and the filter 30 from the outside of the wrapping paper 11, and an outer peripheral portion of the filter 30 from the outside of the base material 12. It is composed of a covering chip paper 13.
  • the base material 12 is bonded to the wrapping paper 11 and the chip paper 13 by means such as adhesion and heat fusion.
  • the wrapping paper 11, the base material 12, and the chip paper 13 can be made of, for example, paper, a synthetic resin film, a metal foil, or the like, and may be a composite sheet in which these are laminated. Further, a layer that can be adhered or fused, such as an adhesive layer or a hot melt layer, may be formed on the inner surfaces of the wrapping paper 11, the base material 12, and the chip paper 13.
  • the rolling paper 11 serves to form the aromatic base material 20 together in a columnar shape.
  • the base material 12 serves to connect the aromatic base material 20, the support member 40, and the filter 30.
  • the chip paper 13 serves to reinforce a portion (mouthpiece) in which the user holds the fragrance cartridge 100 in his / her mouth.
  • the cover 10 is not limited to the one in which the wrapping paper 11, the base material 12, and the chip paper 13 are individually configured.
  • the cover 10 is a single sheet in which the wrapping paper 11, the base material 12, and the chip paper 13 are integrated. It may be composed of the sheets of.
  • the aromatic base material 20, the support member 40, and the filter 30 are arranged along the axial direction from one end side to the other end side of the cover 10. ing.
  • the aromatic base material 20 is, for example, an aggregate of rod-shaped, strip-shaped, powder-shaped, granule-shaped, pellet-shaped, strip-shaped, sheet-shaped, fibrous, porous or block-shaped components.
  • the aromatic base material 20 is formed into a cylindrical shape as a whole by the strip-shaped components.
  • the aromatic base material 20 can generate an aerosol by being heated by an electric heating means of a heating type smoking tool.
  • the aromatic base material 20 is not limited to tobacco plants, but is a crushed dried product of a plant made from a non-tobacco plant, an aerosol former capable of generating an aerosol, and a heat-meltable substance that melts by heating. Those containing and are preferably used. The configuration of the aromatic base material 20 will be described later.
  • the filter 30 has a certain air permeability to the mainstream smoke or aerosol generated from the aromatic base material 20, and has a function of capturing solid particles contained in the mainstream smoke or aerosol and adsorbing harmful components and the like. Those having the above are preferably used.
  • the shape of the filter 30 is not particularly limited, and may be any shape as long as it can be wrapped by the cover 10.
  • the filter 30 has, for example, an acetate filter using acetate fibers, a charcoal filter containing activated carbon in the acetate filter, and a plurality of grooves formed recessed from the outer peripheral surface of the filter 30 along the axial direction of the cover 10.
  • AFT Advanced Filter Technology
  • the filter 30 is fixed to the inner peripheral surface of the base material 12 of the cover 10 by fixing means such as adhesion and welding.
  • the support member 40 is located between the aromatic base material 20 and the filter 30, and is arranged adjacent to each other.
  • the support member 40 may have a shape having an outer peripheral surface corresponding to the shape of the inner peripheral surface of the cover 10.
  • the support member 40 is formed in a cylindrical shape as a whole.
  • the support member 40 is fixed to the cover 10 by fixing means such as adhesion and welding, and in the present embodiment, is fixed to the inner peripheral surface of the base material 12.
  • the shape of the support member 40 is not limited as long as it has a structure that allows ventilation from one end side to the other end side and has a function of restricting the movement of the aromatic base material 20 to the other end side.
  • the support member 40 has one or a plurality of ventilation passages 41 penetrating in the axial direction thereof.
  • the ventilation passage 41 is defined by four concave grooves formed at equal intervals in the circumferential direction and along the axial direction on the outer peripheral surface of the support member 20 and the inner peripheral surface of the cover 10. There is.
  • the ventilation passage 41 may be composed of one or a plurality of through holes formed so as to penetrate in the axial direction from one end surface to the other end surface of the support member 40, for example.
  • the ventilation passage 41 is arranged side by side in the circumferential direction so as to surround the central ventilation passage formed along the axial center of the support member 40 and the central ventilation passage, and also penetrates in the axial direction. It may be composed of a plurality of air passages formed in.
  • the support member 40 may be composed of a honeycomb structure or the like having a hexagonal end face shape of the partition wall and having a plurality of air passages penetrating in the axial direction. Further, the support member 40 may be made of, for example, a porous body in which open cells are formed.
  • the fragrance base 20 is used.
  • the cover 10 has a shape capable of restricting the movement of the cover 10 in the axial direction.
  • the shape that can regulate the movement of the cover 10 of the fragrance base material 20 in the axial direction may be, for example, a shape that can regulate the movement of the material of the fragrance base material 20 to the extent that it does not hinder practical use. ..
  • the support member 40 is formed in this way, when the electric heating means for heating the aromatic base material 20 of the heating type smoking device is inserted from one end side of the aromatic cartridge 100, the support member 40 has an aromatic group. The movement of the material 20 to the other end side is restricted. In other words, the support member 40 can support the aromatic base material 20.
  • the support member 40 can cool the high-temperature aerosol when the aerosol containing the aromatic component generated from the aromatic base material 20 passes through. Therefore, the support member 40 is formed of a member having heat resistance according to the combustion temperature or the heating temperature of the fragrance cartridge 100.
  • the support member may be formed of a member having a heat resistance of about 200 to 350 ° C.
  • Examples of such a member include paper, resin, rubber, wood, metal, ceramic, and the like, but a resin that can be molded into various shapes is more preferable.
  • the resin may be either a thermoplastic resin or a thermosetting resin, and for example, a polyolefin resin, a polyester resin, a polystyrene resin, a nylon resin, an acrylic resin, a silicon resin, a fluororesin, and a polyurethane.
  • a polyolefin resin for example, a polyolefin resin, a polyester resin, a polystyrene resin, a nylon resin, an acrylic resin, a silicon resin, a fluororesin, and a polyurethane.
  • examples thereof include based resins, ethylene-vinyl acetate (EVA) based resins, phenolic resins, amino resins, ABS resins, biodegradable plastics and the like.
  • EVA ethylene-vinyl acetate
  • biodegradable plastic is preferable from the viewpoint of protecting the natural environment because the aromatic cartridge 100 becomes waste after being used.
  • biodegradable plastic examples include poly (3-hydroxybutyrate) (PHB), poly ( ⁇ -caprolactone) (PCL), poly (butylene succinate) (PBS), polylactic acid (PLA) and the like. Can be mentioned.
  • the fragrance base material 20 of the fragrance cartridge 100 is heated to a heating target temperature of 200 ° C. or higher from room temperature or outside air temperature by an electric heating means of a suction device (not shown). Therefore, the aromatic base material 20 undergoes a heating process from room temperature or outside air temperature to the heating target temperature. The user can suck the aerosol emitted from the fragrance cartridge 100 immediately after the end of the temperature raising process.
  • the aromatic base material 20 includes a pulverized dried product of a plant that generates an aroma when heated, an aerosol former that generates an aerosol by heating, and a wasabi extract. Therefore, the aromatic base material 20 can generate an aerosol containing an aromatic component by being heated.
  • the aromatic base material 20 preferably contains a heat-meltable substance that melts when heated, crosslinked polyvinylpyrrolidone and / or polyvinylpyrrolidone, and at least one of fragrances.
  • the aromatic component is a substance contained in the aerosol and capable of stimulating the user's sense of smell.
  • the aroma component include a volatile component of a pulverized and dried plant contained in the aroma base material 20, and an aroma agent capable of assisting the aroma of the volatile component.
  • the aromatic base material 20 also contributes to binding and integrating, for example, a molding agent capable of improving the moldability of the aromatic base material 20, an aerosol former, and a pulverized and dried plant product. It may contain an agent, an aerosol capable of retaining the aerosol on the aerosol base 20 and a preservative capable of improving the storage stability of the aerosol base 20.
  • the aromatic base material 20 has a two-layer structure composed of a first base material 21 containing no wasabi extract and a second base material 22 containing wasabi extract. Is formed.
  • the first base material 21 is arranged on the tip side.
  • the second base material 22 is arranged on the base end side.
  • the second base material 22 can be formed, for example, by impregnating with a liquid wasabi extract.
  • the arrangement of the first base material 21 and the second base material 22 is not limited to such an example, and for example, the second base material 22 is arranged on the tip side and the first base material 21 is arranged. May be arranged on the base end side. Further, a plurality of the first base material 21 and the second base material 22 may be arranged. For example, the first base material 21 and the second base material 22 may be arranged alternately along the axial direction of the fragrance cartridge 100.
  • crushed dried plant examples include leaves, stems, flowers, seeds, fruits, bark, roots and the like of a non-cigarette plant, in addition to tobacco leaves and stems.
  • Peppermint and dried plants are especially those of Chinese tea, tea, roses, mint family mint, lavender, saffron flowers, mint, eshalot, garlic, onion, mint stalk, karin, mint family mint.
  • Plants (Daidai, Unshuumikan, Natsudaidai, Peppermint, Hassaku, Iyokan, Echan Lemon, Karatachi, Orange, Mandarin Orange, Kabos, Kishuumikan, Kinotte, Grapefruit, Koji, Sanboukan, Citron, Jabara, Sudachi, Tachibana, Tangor, Natsumikan Peppermint, Peppermint, Peppermint, Buntan (Zabon), Yuzu, Lime, Lemon, Kobumikan, etc.), Peppermint genus Peppermint, Apple, Pineapple, Mango, Kinkan, Melon, Pomegranate, Ume, Ann , Rose family Dutch strawberry genus plants, raspberries, bananas, and grape fruits, mint family mint peppermint plants (peppermint, Japanese mint
  • the crushed and dried plant has a fragrance defined as a scent drifting from the fragrance cartridge 100 itself, an aroma defined as a scent floating in the space when the fragrance cartridge 100 is heated, and when the fragrance cartridge 100 is heated and sucked together with an aerosol. It is preferable to combine the three elements of flavor, which is defined as the scent that floats in the mouth.
  • the crushed dried products of the plants that make up the fragrance include Chinese tea, tea, roses, plants of the genus Oleaceae, lavender, saffron flowers, and plants of the genus Tobacco of the Solanaceae family. It is preferable to contain at least one selected from the above-ground foliage.
  • the crushed dried product (hereinafter, also referred to as aroma material) of the plant constituting the aroma is selected from the rhizomes of scallions, shallots, garlic, onions, konjac, and the above-ground foliage of plants of the Solanaceae tobacco species. It is preferable to include at least one of them.
  • the crushed dried products of the plants that make up the flavor include karin and plants of the genus Peppermint (Daidai, Satsuma mandarin, Natsudaidai, Peppermint, Hassaku, Iyokan, Echan, Lemon, Karatachi, Orange, Mandarin).
  • Orange Kabos, Kishuumikan, Kinotte, Grapefruit, Koji, Sanboukan, Citron, Jabara, Sudachi, Tachibana, Tangoru, Natsumikan, Hanayuzu, Hyuganats, Hirami Lemon (Shikuwasa), Buntan (Zabon), Yuzu, Lime, Lemon, Kobumikan, etc.
  • Rose family peach peach species plant apple, pineapple, mango, mandarin, melon, pomegranate, sea urchin, apricot, blueberry, rose family Dutch strawberry genus plant, raspberry, banana, grape fruit, mint family peppermint Peppermint, Japanese mint, apple mint, water mint, corsica mint, penny royal mint, etc. It preferably contains at least one selected from the above-ground foliage of plants of (lemon balm), mint mint (savory), mint mint (hisop), and mint species of the mint family.
  • the aerosol former is added to generate an aerosol when the aromatic substrate 20 is heated.
  • the aerosolformer include glycerin, propylene glycol, sorbitol, triethylene glycol, lactic acid, diacetin (glycerin diacetate), triacetin (glycerin triacetate), triethylene glycol diacetate, triethyl citrate, and isopropyl myristate.
  • Methyl stearate, dimethyl dodecandionate, dimethyl tetradecanesandioate and the like can be used, but glycerin and propylene glycol are particularly preferably used.
  • the wasabi extract preferably contains at least one of allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate.
  • Allyl isothiocyanate has been reported to have antibacterial effects against pathogenic bacteria, molds, yeasts, etc. (Naohide Kinae, Shuichi Masuda: “Functionality of Sawa Wasabi", Journal of Japan Food Materials Research Association, Vol. 11, pp.64-74 (2008)). Allyl isothiocyanate is contained in Brassicaceae plants such as wasabi, mustard, cabbage, horseradish and radish, as well as nastaltium. As the allyl isothiocyanate-containing substance, the above-mentioned plant extract can also be used. In particular, it is preferable to use an extract of wasabi or mustard.
  • the above plant extract contains various aromatic components in addition to allyl isothiocyanate.
  • the extract of Sawa wasabi is methylisothiocyanate, isopropylisothiocyanate, n-butylisothiocyanate, isobutylisothiocyanate, 1-methylpropylisothiocyanate, 3-butenyl isothiocyanate, allyl isothiocyanate, n-amyl isothiocyanate, isoamyl isothiocyanate, 4-pentenyl isothiocyanate, 5-hexenyl isothiocyanate, 3-methylthiopropyl isothiocyanate, n-hexyl isothiocyanate, ⁇ -phenylethyl Isothiocyanate, 6-heptenyl isothiocyanate, 4-methylthiobutyl isothiocyanate, 5-methylthioamyl isothiocyanate, 6-methylthiohexyl isothiothiocyanate, 4-methylthiohexyl isothiocyan
  • Extraction methods include a method using a non-volatile solvent or a volatile solvent, a method for producing an extract that removes the solvent after extraction with a solvent, and an aromatic tincture containing alcohol as a diluting solvent in a natural alcohol extract.
  • the extraction method is not limited to this, and any extraction method may be used as long as it is an extraction method used for foods and the like.
  • isothiocyanates can be extracted from the above-mentioned dried plant using an extraction solvent.
  • an extraction solvent a solvent other than water can be used, but ethanol having a purity of 99% or more is particularly desirable. Ethanol with low purity is not preferable because it elutes components other than isothiocyanates in the raw material.
  • Cooking oil can also be used as an extraction solvent other than alcohol.
  • Edible oils include rapeseed oil, corn oil, soybean oil, sesame oil, rice oil, camellia oil, benibana oil, palm oil, cottonseed oil, sunflower oil, sesame oil, olive oil, peanut oil, almond oil, avocado oil, hazelnut oil, walnut oil, Grape seed oil, fish oil, etc. can be used.
  • Extraction conditions can be arbitrarily set in light of known techniques, depending on the type of plant species, isothiocyanates, and the like. For example, in the case of this wasabi, 4 to 10 times the amount of solvent can be added to the raw material, and extraction can be performed at room temperature for about 2 hours while stirring.
  • a separation operation is performed to separate the solvent containing isothiocyanates from the solid content.
  • a method such as filtration with filter paper, membrane filtration, or centrifugation can be selected and used.
  • the extract thus obtained (extraction solvent containing isothiocyanates) can be used as it is, or after being concentrated or powdered.
  • allyl isothiocyanate purified to a higher purity can be used, or synthetic allyl isothiocyanate can be used.
  • allyl isothiocyanate is preferably contained in an amount of 1 to 50 mg, more preferably 3 to 40 mg, and most preferably 5 to 30 mg per aromatic cartridge. If the content of allyl isothiocyanate per fragrance cartridge 100 is less than 1 mg, the effects such as enhancing the flavor may not be sufficiently obtained, and if it exceeds 50 mg, the pungent taste is too strong and unsuitable for smoking. there is a possibility.
  • the content of allyl isothiocyanate can be measured by gas chromatography.
  • the wasabi extract can be dissolved in a heat-melting substance described later, an aerosol former, or the like and contained in the aromatic base material 20.
  • the wasabi extract can be encapsulated and contained in any one or more of the aromatic cartridges.
  • 6-Methylsulfinylhexyl isothiocyanate 6-Methylsulfinylhexyl isothiocyanate is included in the wasabi extract. Therefore, by adding wasabi extract to the aromatic cartridge, 6-methylsulfinylhexyl isothiocyanate can be contained together with allyl isothiocyanate. In addition, 6-methylsulfinylhexyl isothiocyanate can be added separately.
  • the 6-methylsulfinylhexyl isothiocyanate can be obtained by a chemical synthesis method, but may be extracted and purified from a plant.
  • Such plants include Batisaceae, Brassicaceae, Bretschneideraceae, Capparaceae, Caricaceae, and Ephaceae. (Gyrostemonaceae), Limnanthaceae, Moringaceae, Pentadiplandraceae, Phytolaccaceae, Phytolaccaceae, Pitelaceae) Plants of the family (Tovariaceae), Tropaeolaceae (Tropaeolaceae), and the like can be mentioned.
  • wasabi (Wasabi japonica) [alias: book wasabi], horseradish (Armorasia rusticana) [alias: mountain wasabi], Batis maritima (Japanese name unknown), watercress (Brassica juncea), broccoli.
  • oleracea var.italica Arabidopsis (Arabidopsis thaliana), shepherd's purse (Capsella bursa-pastoris), watercress (Nasturtium officinale), Bretschneidera sinensis (Japanese name unknown), capers (Capparis spinosa), papaya (Carica papaya), Drypetes roxburghii (sum Name unknown); Putranjiva roxburghii (Japanese name unknown), Tersonia brevipes (Japanese name unknown), Limnanthes douglasii (Japanese name unknown), Wasabi noki (Moringa oleifera), Pentadai pran Bursaris spinosa var.
  • Examples include incana (Japanese name unknown), Nasturtium (Reseda alba), Salvadora persica (Japanese name unknown), Tovalia pendula (Japanese name unknown), Nasturtium (Tropaeolum majus) and the like.
  • the 6-methylsulfinylhexyl isothiocyanate is not limited to that obtained from the above plants, and all natural resources containing 6-methylsulfinylhexyl isothiocyanate can be used as a raw material.
  • 6-Methylsulfinylhexyl isothiocyanate can be obtained, for example, by the following chemical synthesis method.
  • 6-Chlorohexanol is refluxed with CH 3 -SNa to give 6-methylthiohexanol.
  • Thionyl chloride (SOCl 2 ) is allowed to act on this to obtain 6-chlorohexylmethyl sulfide.
  • an amino group is introduced with a phthalimide potassium salt to produce N- (6-methylthiohexyl) -phthalimide.
  • Hydrazine hydrate is added to this and refluxed to obtain 6-methylthiohexylamine, and then thiocarbonyl chloride is allowed to act to obtain 6-methylthiohexyl isothiocyanate.
  • 6-methylthiohexyl isothiocyanate is oxidized with m-chloroperbenzoic acid to obtain a 6-methylsulfinylhexyl isothiocyanate (Morimitsu et. Al., J. Biol. Chem., 277, 3456). , 2002).
  • the 6-methylsulfinylhexyl isothiocyanate thus obtained can be used as it is, or after being concentrated or powdered.
  • 6-methylsulfinylhexyl isothiocyanate is preferably contained in an amount of 0.1 to 5 mg, more preferably 0.3 to 4 mg, and most preferably 0.5 to 3 mg per aromatic cartridge. .. If the content of 6-methylsulfinylhexyl isothiocyanate per aromatic cartridge 100 is less than 0.1 mg, sufficient effects such as antioxidant action and anti-inflammatory effect may not be obtained, and if it exceeds 5 mg, it may not be possible to obtain sufficient effects. The manufacturing cost tends to increase, and the flavor of the aerosol generated from the aromatic cartridge 100 tends to be lightened.
  • the 6-methylsulfinylhexyl isothiocyanate can be quantified by using known means such as gas chromatography and liquid chromatography (HPLC).
  • 6-methylsulfinylhexyl isothiocyanate can be dissolved in a heat-melting substance described later, an aerosol former, or the like and contained in the aromatic base material 20.
  • 6-methylsulfinylhexyl isothiocyanate can be encapsulated and contained in any one or more of the aromatic cartridges.
  • the heat-meltable substance is added to dissolve at a relatively low temperature to dissolve and vaporize the aromatic component generated from the aromatic substrate 20 so that it can be easily released together with the aerosol former.
  • the heat-meltable substance also serves to fix the crushed and dried plant and / or the fragrance at room temperature.
  • the heat-melting substance has a melting point in the range of 50 to 100 ° C, preferably in the range of 50 to 80 ° C, and more preferably in the range of 60 to 67 ° C. If the melting point of the heat-meltable substance is less than 50 ° C., the heat-meltable substance may be melted in a high temperature period such as summer, and stickiness may occur. Further, when the melting point of the heat-meltable material exceeds 100 ° C., the heat-meltable material is not sufficiently melted at the initial stage of the temperature raising process of the aromatic substrate, and immediately after the heating process of the heated smoking device is completed. There is a tendency for the aroma of the aerosol to be insufficient.
  • the melting point of the heat-melting substance can be measured, for example, in accordance with the method for measuring the melting point of paraffin wax specified in JIS K2235. That is, using a predetermined melting point tester, put the melted sample into the examiner, read the reading of the melting point measuring thermometer every 15 seconds, and the temperature drop is within a certain range (difference within 0.1 ° C). The temperature at which it is at 5 times) can be measured as the melting point.
  • the heat-melting substance is preferably in the form of powder.
  • the average particle size of the heat-melting substance is preferably 125 to 355 ⁇ m, more preferably 150 to 300 ⁇ m, and even more preferably 180 to 250 ⁇ m.
  • the average particle size can be measured by, for example, a laser diffraction type particle size distribution measuring device or the like.
  • the average particle size in the present invention means the median diameter.
  • the average particle size of the heat-melting substance is too large, the total surface area of the heat-melting substance will be small, and the chance of contact with the heat source will decrease. As a result, the heat-melting substance is not sufficiently melted, and the concentration of the aromatic component in the aerosol immediately after the end of the temperature raising process tends to decrease.
  • the heat-meltable substance is preferably contained in the aromatic base material 20 in an amount of 2 to 20% by mass, preferably 3 to 15% by mass, and more preferably 5 to 15% by mass.
  • the blending amounts of the ground dry matter, aerosol former and heat-melting substance of the plant were 55 to 75% by mass, 20 to 40% by mass, and 2 to 2, respectively, in order to balance the volatile amounts of the smoke component and the aromatic component. It is preferably 15% by mass, more preferably 60 to 70% by mass, 25 to 35% by mass, and 3 to 10% by mass.
  • the heat-melting substance is not particularly limited as long as it is an "organic compound that exhibits a melting point or a softening point when heated and becomes a non-Newtonian fluid".
  • organic compounds generally called wax and wax are preferable, and petroleum-based natural wax, synthetic wax, vegetable-based natural wax and animal-based natural wax, which are typical waxes and waxes, can be used. ..
  • various tack fires to which rosin, which is also used as wax and wax, belong can be used. These can be used alone or as a mixture containing at least one selected from them.
  • plant-based natural wax and animal-based natural wax are preferably used from the viewpoint of having a preferable melting point and imparting flavor.
  • plant-based natural wax for example, goby wax, sumac wax, carnauba wax, sugar cane wax, palm wax, candelilla wax and the like can be used.
  • animal-based natural wax beeswax, spermaceti, Ibota wax, wool wax, shellac and the like can be used. These are easy to obtain those having a melting point in the range of 50 to 100 ° C. specified in the present invention, and have a preferable flavor by themselves, so that the aroma of the aerosol can be enhanced.
  • carnauba wax, beeswax, petrolatum, and paraffin wax are particularly preferable, and beeswax having a melting point of 62 to 65 ° C. and rich in aromatic components is most preferable.
  • Plant-based natural wax and animal-based natural wax are mainly composed of esters of fatty acids and fatty alcohols.
  • the plant-based natural wax and the animal-based natural wax are mixtures of fatty acids having various carbon atoms and esters of fatty alcohols, and also contain free fatty acids, free fatty alcohols, hydrocarbons, and the like. Therefore, plant-based natural wax and animal-based natural wax are characterized by having a wide molecular weight distribution, a wide melting point temperature range, and high viscosity at the time of melting.
  • petroleum-based natural wax is a hydrocarbon compound, it has the advantage that it has little interaction with aromatic components and aerosol formers and does not adversely affect the flavor.
  • the petroleum-based natural wax for example, petrolatum, paraffin wax, microcrystalline wax and the like can be preferably used.
  • Vaseline is a mixture of branched hydrocarbons and alicyclic hydrocarbons, and has a wide melting point temperature range of 36 to 60 ° C.
  • Paraffin wax is mainly composed of linear hydrocarbons, has high crystallinity, and most of them have a melting point of 40 to 70 ° C., and the temperature range of the melting point is narrow.
  • Microcrystalline wax is a mixture of branched hydrocarbons and saturated cyclic hydrocarbons. It has a low crystallinity but a high molecular weight, and has the highest melting point of 60 to 90 ° C., and the width of the melting point temperature range. Is also the second largest after Vaseline.
  • Paraffin wax and microcrystalline wax have low melt viscosity and surface energy during thermal melting, and have little interaction with aromatic components and aerosol formers.
  • paraffin wax examples include Paraffin Wax-115, 120, 125, 130, 135, 140, 145, 150, 155, which are standard products manufactured by Nippon Seiro Co., Ltd., and any of them is preferably used. ..
  • special paraffin wax for example, HNP series products, which are high-purity refined paraffin wax, which is a special product manufactured by Nippon Seiro Co., Ltd., SP series products for specific applications, and isoparaffin manufactured by a special manufacturing method are the main components. EMW series products of the above are also preferably used.
  • microcrystalline wax for example, any of the Hi-Mic series manufactured by Nippon Seiro Co., Ltd. is preferably used.
  • Examples of synthetic waxes include Fischer-Tropsch wax, polyethylene (PE) wax, modified PE wax, polypropylene (PP) wax, modified PP wax, fatty acid amide, fatty acid, fatty alcohol, and polyoxyalkylene glycol.
  • Polyoxyethylene alkyl ether, polyoxyethylene alkylamine and the like can be preferably used.
  • Fischer-Tropschwax is a linear hydrocarbon-based organic compound, its melt viscosity and surface energy during heat melting are low, and its interaction with aerosol formers and aromatic components is also small.
  • a medium melting point product C80 or the like melting point: about 85 to 88 ° C.
  • PE wax and modified PE wax, and PP wax and modified PP wax are also hydrocarbon compounds and can be preferably used.
  • “High Wax (registered trademark)” manufactured by Mitsui Chemicals, Inc., “Sun Wax” and “Viscol” manufactured by Sanyo Chemical Industries, Ltd., and “CERAFAK (registered trademark)” 929, 950, 913,914 manufactured by BYK. , 915 ”and the like can be preferably used.
  • the metallocene-catalyzed polyolefin wax has a narrow molecular weight distribution and is more preferable.
  • "Excelex (registered trademark)” manufactured by Mitsui Kagaku Co., Ltd. which is a metallocene-catalyzed PE wax, has a melting point of 89 to 128 ° C. due to its narrow molecular weight distribution and composition distribution, but its melt viscosity during thermal melting is low. , It is very excellent as such a polyolefin wax.
  • fatty acid amides fatty acids, aliphatic alcohols and the like can also be used as the heat-melting substance.
  • fatty acid amide monoamide and bisamide are suitable.
  • monoamide stearic acid monoamide, oleic acid monoamide, and erucic acid monoamide are preferable because they have a melting point of about 72 to 105 ° C.
  • the fragrance cartridge 100 of the present invention contains an fragrance agent as an fragrance component in addition to the volatile component of the pulverized and dried plant.
  • the fragrance include a refreshing agent such as menthol, a flavoring agent such as an ingredient extracted from coffee, and a flavoring agent.
  • a refreshing agent such as menthol
  • a flavoring agent such as an ingredient extracted from coffee
  • a flavoring agent such as an ingredient extracted from coffee
  • a flavoring agent such as an ingredient extracted from coffee
  • the refreshing agent examples include menthol, menthol derivative, menthol, menthone derivative, mentancarboxylic acid amide, 2,3-dimethyl-2- (2-propyl) -butyric acid derivative, menthol, mentan derivative, L-carboxylic acid and xylitol.
  • Eucalyptus essential oil, peppermint oil, spearmint essential oil, spiranthol, etc. can be used.
  • the refreshing agent is preferably adopted because it can improve the refreshing sensation by interacting with allyl isothiocyanate.
  • flavoring agent examples include ingredients extracted from coffee.
  • the components extracted from coffee include, for example, coffee aromatic components such as caffeine, pyridine, methylpyrazine, acetic acid, furfuryl alcohol, cycloten, 1H-pyrrolecarbaldehyde, hydroxypyridine, hydroxyacetone, furfural, methylfurfural, and maltor. It is preferable to include it.
  • the component extracted from coffee for example, coffee bean powder, coffee extract, coffee flavor, raw coffee extract and the like can be used.
  • the component extracted from coffee may contain 0.3 to 60 mg, preferably 1.5 to 30 mg, and more preferably 3 to 15 mg in the aromatic base material 20 of one aromatic cartridge 100.
  • the component extracted from coffee may contain 0.1 to 20% by mass, preferably 0.5 to 10% by mass, and more preferably 1 to 5% by mass with respect to the aromatic base material 20.
  • fragrance As the fragrance, any of natural fragrance, synthetic fragrance and compounded fragrance can be used. It can also be used in flavors (food additives) and fragrances (cosmetic fragrances).
  • fragrances include citrus, floral, fruit, milk, chypre, oriental, (preference) food and drink, ready-made (preference) smoking equipment, vanilla, mint, and sweetener. , Spices, nuts, and alcoholic beverages.
  • citrus-based, fruit-based, mint-based and other refreshing flavors chocolate, milk, coffee and other (preference) food and drink-based and relaxing flavors
  • vanilla-based, floral-based, sweetener-based and other sweetnesses are preferable.
  • the fragrance cartridge 100 of the present invention may contain a physiologically active substance having effects such as arousal effect and sedative effect.
  • a physiologically active substance include catechin, caffeine, theanine and the like.
  • the catechin preferably contains epicatechin, catechin, epigalocatechin, epicatechin gallate, catechin gallate, epigalocatechin gallate, and gallocatechin gallate, and among these catechins, epicatechin and epigallocatechin are particularly contained. Is preferable.
  • purified catechins containing these catechins with high purity can be used, but an extract extracted from a plant containing catechins using an appropriate solvent, or a catechin content from the extract can be used. It is also possible to use a crudely refined product that has been crudely refined so as to be enhanced.
  • catechin As the plant containing catechin, for example, tea leaves selected from sencha, roasted tea, kabusecha, gyokuro and the like can be used. Catechin can be obtained from these tea leaves by extracting them with water, alcohols such as ethanol and methanol, and solvents such as acetone, and further fractionating them if necessary. For example, the extract obtained by extracting tea leaves with hot water is fractionated with an organic solvent such as ethyl acetate and dried to obtain epigallocatechin gallate, gallocatechin gallate, epicatechin gallate, catechin gallate, epigallocatechin gallate. A powder containing 30 to 98% by mass of catechins such as catechin, gallocatechin, epicatechin, and (+) catechin can be obtained.
  • the powder containing catechin preferably contains 0.03% by mass or more of catechin, more preferably 0.1 to 5% by mass, and even more preferably 1 to 4% by mass.
  • Catechin powder containing a high concentration of catechin is commercially available from various companies, and these commercially available products can also be used.
  • the content of catechin can be quantified by, for example, the iron tartrate method (tea industry research report 71 (1990) 43-74), high performance liquid chromatography (HPLC), or the like.
  • Caffeine is the most characteristic ingredient of coffee and is also abundant in foods such as tea, cocoa and cola. Caffeine is widely known for its excitatory effects such as drowsiness and diuretic effects that promote the excretion of urine. Various effects such as “making” and “improving athletic ability” have been clarified. By including caffeine, it is possible to refresh the feelings of the user who inhaled the aerosol, to awaken drowsiness, and to impart an antipyretic analgesic effect.
  • One fragrance cartridge 100 preferably contains 1 to 50 mg of caffeine, more preferably 5 to 30 mg, and even more preferably 10 to 20 mg.
  • Caffeine can also be added as one component contained in the components extracted from coffee as a flavoring agent described later.
  • Theanine can be contained in the aromatic base material 20 by using, for example, an extract obtained by extracting tea leaves with hot water, a powder of green tea leaves, an extract of green tea leaves, a fragrance of green tea leaves, or the like. Since the aromatic base material 20 contains theanine, the action of the sympathetic nerve of the user who inhaled the aerosol can be suppressed and relaxed.
  • Theanine may be contained in the aromatic base material 20 of one aromatic cartridge 100 in an amount of 10 to 100 mg, preferably 20 to 80 mg, and preferably 30 to 60 mg in order for a user with a low anxiety tendency to obtain a relaxing effect. More preferred.
  • a user with a high tendency to anxiety may contain 20 to 120 mg, preferably 30 to 100 mg, and more preferably 40 to 80 mg in order to obtain a relaxing effect.
  • theanine may be contained in an amount of 3.3 to 33% by mass, preferably 6.6 to 26% by mass, preferably 10 to 26% by mass, so that a user having a low tendency to anxiety can obtain a relaxing effect with respect to the aromatic base material 20. It is more preferable to contain 24% by mass. In order for a user with a high anxiety tendency to obtain a relaxing effect, it is preferable to contain 6.6 to 10% by mass, preferably 10 to 33.3% by mass, and 13.3 to 26. It is more preferable to contain 6% by mass.
  • theanine may be encapsulated in the above-mentioned capsule and contained in the aromatic cartridge 100.
  • the sorbent can be used to prevent the wasabi extract and fragrances such as refreshing agents and fragrances from volatilizing before being used in suction devices. By using the sorbent, the user can enjoy a sufficient fragrance even in the fragrance cartridge 100 that has been stored for a long period of time.
  • the volatile component of the pulverized and dried plant, the wasabi extract, and the fragrance such as the refreshing agent and the fragrance can be retained on the fragrance base 20.
  • the sorbent it is preferable to use an sorbent that adsorbs a volatile component of a pulverized and dried plant, a wasabi extract and an fragrance to retain the fragrance-generating base material 20.
  • the fragrance is menthol
  • the menthol has a phenolic hydroxyl group. Therefore, as the sorbent, it is preferable to use a hydrophilic crosslinked polymer capable of adsorbing a phenolic hydroxyl group, for example, crosslinked polyvinylpyrrolidone (PVPP: Polyvinylpolypyrrolidone) or polyvinylpyrrolidone (PVP: Polyvinylpyrrolidone).
  • PVPP Polyvinylpolypyrrolidone
  • PVP Polyvinylpyrrolidone
  • examples of the components to be deposited on the aromatic base material 20 by the sorbent include volatile components of crushed and dried plants, refreshing agents, flavoring agents, fragrances and the like.
  • volatile components of crushed and dried plants For example, nicotine, a volatile component of ground and dried plants, has a nitrogen-containing 5-membered heterocyclic compound. Therefore, as the sorbent, a crosslinked PVP that is considered to interact with a 5-membered heterocyclic compound containing nitrogen can be used.
  • the sorbent When cross-linked PVP and / or PVP is used as the sorbent, the sorbent is often contained in an amount of 4 to 25% by mass based on 100% by mass of the total amount of pulverized dried plant, aerosol former and heat-melting substance. More preferably, it is contained in an amount of 5 to 20% by mass.
  • bleaching agent one capable of forming an inclusion compound is preferable.
  • a sorbent include cyclodextrin.
  • Cyclodextrin is known to form an inclusion compound with a chemical substance having a hydroxyl group or a carboxyl group of various sizes, and any of ⁇ , ⁇ , and ⁇ -cyclodextrin can be used.
  • ⁇ -cyclodextrin forms an inclusion compound with a refreshing agent such as menthol, and is most suitable as a sorbent for menthol.
  • the sorbent When cyclodextrin is used as the sorbent, the sorbent is often contained in an amount of 0.1 to 1.2% by mass based on 100% by mass of the total amount of crushed dried plant, aerosol former and heat-melting substance. , 0.2 to 1.0% by mass is more preferable.
  • the sorbent also plays a role of adsorbing and retaining physiologically active substances such as wasabi extract, catechin, caffeine, and theanine. It is more preferable that the sorbent contains both PVPP and cyclodextrin.
  • the molding agent is used to reinforce the physical strength of the aromatic substrate 20.
  • the molding agent for example, cellulose fibers, microcrystalline cellulose and the like can be used.
  • cellulose fiber for example, cellulose fiber such as sugar cane, bamboo, wheat, rice, esparto, jute, hemp, and wood is preferably used.
  • the fiber diameter of these cellulose fibers is preferably 5 to 25 ⁇ m, and the fiber length is preferably 0.25 to 6 mm.
  • the microcrystalline cellulose preferably has an average particle size of 70 to 120 ⁇ m. If the average particle size of the microcrystalline cellulose is less than 70 ⁇ m, it tends to be difficult to suppress the shrinkage of the aromatic base material 20 and prevent the adhesion between the aromatic base material 20 and the molding machine. When the average particle size of the microcrystalline cellulose exceeds 120 ⁇ m, the aromatic base material 20 tends to break easily.
  • the average particle size of the microcrystalline cellulose can be measured by a laser diffraction type particle size distribution measuring device.
  • the average particle size in the present invention means the median diameter.
  • the mass average molecular weight (Mw) of the microcrystalline cellulose is preferably 20,000 to 60,000.
  • Mw mass average molecular weight
  • the mass average molecular weight (Mw) of the microcrystalline cellulose is less than 20,000, the effect of suppressing the shrinkage of the aromatic substrate 20 tends to be poor.
  • the mass average molecular weight (Mw) of the microcrystalline cellulose exceeds 60,000, the aromatic base material 20 tends to break easily.
  • the molding agent is preferably contained in an amount of 2 to 25% by mass, preferably 3 to 20% by mass, based on 100% by mass of the total amount of the pulverized and dried plant, the aerosol former and the heat-melting substance.
  • the molding agent fulfills the above-mentioned functions and prevents the molding agent from being harmful to the generation of pulverized dried plants and aerosol former volatile substances. Can be done.
  • the binder is used to bind raw materials such as pulverized and dried plants, aerosol formers, and heat-meltable substances constituting the aromatic base material.
  • a polysaccharide-based polymer, a cellulosic polymer, calcium carbonate or the like can be used.
  • the polysaccharide-based polymer for example, konjac mannan (glucomannan), guar gum, pectin, carrageenan, tamarin seed gum, arabic rubber, soybean polysaccharide, locust bean gum, karaya gum, xanthan gum, agar and the like can be used.
  • the polysaccharide-based polymer is preferably glucomannan, guar gum, pectin, carrageenan, tamarin seed gum, locust bean gum, karaya gum, and xanthan gum, and the neutral polysaccharide glucomannan, from the viewpoint of strength and moldability. Guar gum, polysaccharide seed gum, and locust bean gum are more preferred.
  • Examples of the cellulose-based polymer include carboxymethyl cellulose (CMC), carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, CMC sodium salt, CMC potassium salt, CMC calcium salt, carboxyethyl cellulose sodium salt, and carboxy.
  • a potassium salt of ethyl cellulose, a calcium salt of carboxyethyl cellulose, or the like can be used.
  • a sodium salt of CMC, a potassium salt of CMC, a sodium salt of carboxyethyl cellulose, and a potassium salt of carboxyethyl cellulose are preferable from the viewpoint of the strength of the aromatic base material 20 and the moldability.
  • the binder it is preferable to use a polysaccharide polymer and a cellulosic polymer in combination.
  • glucomannan it is preferable to use glucomannan, guar gum, tamarin seed gum, and locust bean gum as the polysaccharide polymer.
  • the cellulose-based polymer it is preferable to use a sodium salt of CMC, a potassium salt of CMC, a sodium salt of carboxyethyl cellulose, and a potassium salt of carboxyethyl cellulose.
  • the strength and molding processability of the aromatic base material 20 can be improved.
  • the binder is preferably contained in an amount of 5 to 30% by mass, preferably 8 to 28% by mass, based on 100% by mass of the total amount of the pulverized dried plant, the aerosol former, and the heat-melting substance. More preferred.
  • the binder in the aromatic base material 20 at such a content, the strength and molding processability of the aromatic base material 20 can be improved, and the pulverized dried plant and the volatile matter of the aerosol former can be improved. It is possible to avoid adverse effects on the occurrence and the like.
  • the aromatic base material 20 of the present invention contains both a binder and a molding agent.
  • the compounding ratio of the binder and the molding agent is preferably 1: 1 to 1:25 in terms of mass ratio in terms of the binding effect.
  • Preservatives may be used for long-term storage of aromatic cartridges.
  • the preservative for example, potassium sorbate and / or sodium benzoate can be used.
  • the preservative is preferably contained in an amount of 0.005 to 0.04% by mass based on 100% by mass of the total amount of the pulverized dried plant, the aerosol former, and the heat-melting substance.
  • FIG. 5 shows an embodiment of the manufacturing process of the second base material 22 of the aromatic base material 20.
  • a mixing step of mixing the raw material (B) including the aroma material which is a product is performed.
  • the mixing step is carried out below the melting point of the heat-melting material.
  • the mixing step can be performed using, for example, a known mixer.
  • the raw material (A) contains a raw material (A1) containing a fragrance material which is a crushed dried product of a plant constituting the fragrance, a flavor material which is a crushed dried product of a plant constituting the flavor, a wasabi extract and a heat-melting substance.
  • Raw material (A2), raw material (A3) containing alcohol aqueous solution of microcrystalline cellulose, alcohol aqueous solution of binder and alcohol aqueous solution of sorbent, and raw material (A4) containing aerosol former, fragrance and molding agent are mixed. And it is obtained by aging.
  • the raw material (A1) to the raw material (A4) are mixed at a temperature lower than the melting point of the heat-melting substance. Further, this mixing step can be performed using, for example, a known mixer.
  • the raw material (A1) is obtained by sterilizing the fragrance material and then crushing it.
  • the raw material (A2) is obtained by sterilizing a mixture of a flavor material, wasabi extract and a heat-melting substance and then pulverizing the mixture. Specifically, as shown in FIG. 6, the flavor material is sterilized and then crushed to a predetermined size. Further, the powdered heat-melting substance and the wasabi extract are heated and mixed at a temperature equal to or higher than the melting point of the heat-melting substance, cooled, and then pulverized to a predetermined size. It is advisable to compress and shear mix the crushed product and the powdery flavor material, cool the crushed material, and then crush the crushed material to prepare a raw material (A2).
  • the raw material (A3) is obtained by mixing an aqueous alcohol solution of microcrystalline cellulose, an aqueous alcohol solution of a binder, and an aqueous alcohol solution of a sorbent (crosslinked polyvinylpyrrolidone and / or polyvinylpyrrolidone).
  • the alcohol aqueous solution is a mixed solution of pure water and ethanol.
  • the raw material (A4) is obtained by mixing an aerosol former, an aromatic agent and a molding agent.
  • Aging is preferably carried out for 3 to 14 days under temperature conditions of, for example, 15 to 30 ° C. From the viewpoint of retaining aroma components, aging is more preferably carried out for 4 to 7 days under a temperature condition of 20 ⁇ 2 ° C. When the temperature exceeds 30 ° C. or the aging period exceeds 14 days, the possibility of mold growth and rot tends to increase.
  • the raw material (B) is obtained by mixing a raw material (B1) containing an aroma material, which is a pulverized and dried product of a plant constituting the aroma, and a raw material (B2) containing a preservative.
  • the raw materials (B1) and (B2) can be mixed using, for example, a known mixer.
  • the raw material (B1) is obtained by sterilizing the aroma material and then pulverizing it.
  • the raw material (B2) is obtained by dissolving a preservative in pure water.
  • the mixture obtained in the mixing step is compressed and sheared to form a sheet.
  • the compression / shearing process can be performed using, for example, three rolls. By performing compression / shearing with three rolls, it is possible to embrace air and form a sheet while evaporating water.
  • the sheet thus obtained has a porous structure containing air inside. As a result, it becomes possible to obtain an aromatic base material 20 having a low density. Further, since the roll of the three rolls has an extremely flat surface, the surface of the sheet is formed flat.
  • the aromatic base material 20 has a low density because it has a porous structure containing air inside, and its surface is formed flat without unevenness.
  • the mixture formed into a sheet by compression / shearing is cut into a predetermined shape and size, and the cutting process is performed.
  • the sheet-like mixture is processed into strips, for example.
  • the first base material 21 can be prepared by the above-mentioned production method by removing the wasabi extract from the raw materials of the second base material 22.
  • the aromatic base material 20 including the first base material 21 and the second base material 22 thus produced is placed on the cover 10 together with the filter 30 and the support member 40.
  • the cover 10 is rolled so as to wrap them, and the ends of the cover 10 are fixed to each other, whereby the fragrance cartridge 100 is manufactured.
  • the heat-melting substance When the heat-melting substance is dispersed and arranged in an island shape on the aromatic base material 20 than when it is impregnated in the crushed and dried plant, it becomes easier to flow when it is melted, and the crushed and dried plant is dried. Aroma components generated from substances are likely to be contained. Further, the flowing heat-melting substance can come into contact with the aerosol former, and the aromatic component can be easily volatilized together with the aerosol former as an aerosol.
  • the wasabi extract may be added to the raw material (B).
  • FIG. 7 shows another embodiment of the manufacturing process of the aromatic base material 20. As shown in FIG. 7, when the wasabi extract is added to the raw material (B), it may be added to the raw material (B1), for example. In this case, the embodiment shown in FIG. 7, that is, the flavor material may be replaced with an aroma material to prepare the raw material (B1).
  • the wasabi extract is in the form of a liquid or solid, or is encapsulated and contained in any one of the aromatic cartridges 100.
  • the aerosol generated from the base material 20 can contain allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate.
  • the user can aspirate the aromatic components and vaporized allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate generated from the aromatic substrate 20 together with the aerosol. Therefore, the user can enjoy a deep flavor while feeling the scent of the aromatic component.
  • the fragrance cartridge 100 of the second embodiment is different from the fragrance cartridge 100 of the first embodiment in that the wasabi extract is encapsulated and contained.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 8 shows the fragrance cartridge 100 according to the second embodiment.
  • the capsule 50 containing the wasabi extract is encapsulated in the aromatic base material 20. More specifically, the capsule 50 is arranged in the aromatic base material 20 in the middle of the aromatic cartridge 100 in the axial direction.
  • the aromatic base material 20 may be appropriately adjusted according to the shape and size of the capsule 50.
  • the aromatic base material 20 is preferably formed in the form of granules, powder, paste or the like. By constructing the aromatic base material 20 in this way, it is possible to easily enclose the capsule 50.
  • the capsule 50 is, for example, a seamless capsule.
  • the capsule 50 releases the liquid wasabi extract encapsulated therein when it is crushed by the user when it receives an external force during smoking or when it is heated by the electric heating means of the suction device.
  • the capsule 50 is broken by the user pressing the cover 10 containing the capsule 50, and the liquid wasabi extract enclosed in the capsule 50 is released.
  • the capsule coating is broken and the liquid wasabi extract enclosed in the capsule 50 is released.
  • the aromatic base material 20 is heated by the electric heating means of the suction device, the shell of the capsule 50 is melted or destroyed, and the liquid wasabi extract enclosed in the capsule 50 is released.
  • various materials can be used for the shell (outer shell) in which the wasabi extract is enclosed.
  • shells commonly used in the pharmaceutical industry can be used, such shells may be, for example, gelatin-based or formed of a polymeric material such as modified cellulose. good.
  • the capsule 50 can be manufactured, for example, as follows. First, an extract obtained from a plant containing allyl isothiocyanate and 6-methylsulfinyl hexyl isothiocyanate, purified allyl isothiocyanate, 6-methylsulfinyl hexyl isothiocyanate and the like are dissolved in an alcohol solvent or an oil or fat. Next, this solution is granulated so as to be wrapped in a paste solution containing a gelling agent such as sodium alginate (alginate) and pectin, and then dropped into a calcium chloride aqueous solution containing calcium ions to gel the gelling agent. It can be manufactured by allowing it to be produced.
  • a gelling agent such as sodium alginate (alginate) and pectin
  • the capsule 50 can be granulated, for example, by simultaneously extruding a paste liquid containing a wasabi extract from the inside of the discharge port of a double pipe and a gelling agent from the outside and dropping a predetermined amount into a calcium chloride aqueous solution. can.
  • Polysaccharides and proteins with a polymer structure can also be used to assist in the formation and stabilization of particles.
  • carrageenan, locust bean gum, guar gum, gellan gum, gelatin, xanthan gum, farcerelan and the like can be used as particle formation and stabilization aids.
  • the moisture content of the particles can be adjusted by adjusting the charged water at the time of producing the particles, such as cold air drying.
  • a liquid one in which allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate are dissolved in the above-mentioned fat and oil or alcohol solvent can be used.
  • allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate are dissolved in an alcohol-based solvent. It is good to use the one that has been used.
  • the electrical heating means is heated, the alcoholic solvent volatilizes, allowing the user to more effectively ingest allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate.
  • allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate are dissolved in the oil and fat solvent. It is good to use one. The user will be able to ingest allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate along with the scent of fats and oils.
  • the user can destroy the capsule 50 immediately before using the aroma cartridge 100 to obtain allyl isothiocyanate and 6-methylsulfinylhexyl. Isothiocyanate can be inhaled. Therefore, the user can enjoy a deep flavor while enjoying the aroma of the aromatic component enhanced by allyl isothiocyanate. Further, by filling and holding the wasabi extract in a capsule, it is possible to easily prevent volatilization of allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate and denaturation of components during storage.
  • the fragrance cartridge 100 of the third embodiment is different from the fragrance cartridge 100 of the second embodiment in the position where the capsule 50 containing the wasabi extract is arranged.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 9 shows the fragrance cartridge 100 according to the third embodiment.
  • the capsule 50 containing the wasabi extract is encapsulated in the aromatic base material 20. More specifically, the capsule 50 is arranged in the vicinity of the support member 40 in the aromatic base material 20.
  • the allyl isothiocyanate and 6-methylsulfinylhexylisothiocyanate released from the capsule 50 are easily mixed with the fragrance component that is heated and volatilized by the aromatic base material 20, and allyl isothiocyanate and 6-methylsulfinylhexyliso are easily mixed.
  • the isothiocyanate can be facilitated to be inhaled together with the aromatic component.
  • volatilized allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate are generated in the flow path of the aerosol, so that the user can ingest high concentrations of allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate.
  • the fragrance cartridge 100 of the fourth embodiment is different from the fragrance cartridge 100 of the second embodiment in the aspect of the capsule 50 in which the wasabi extract is encapsulated.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 10 shows the fragrance cartridge 100 according to the fourth embodiment.
  • the plurality of capsules 50 in which the wasabi extract is encapsulated are encapsulated in the aromatic base material 20. More specifically, six capsules 50 are dispersed and arranged in the aromatic base material 20.
  • the capsule 50 may have a wasabi extract encapsulated in at least one of the plurality of capsules.
  • the capsule 50 may contain the above-mentioned refreshing agent, fragrance and the like.
  • the wasabi extract flows out from each of the plurality of capsules 60, so that the wasabi extract can be uniformly flowed out into the aromatic base material 20.
  • the fragrance cartridge 100 of the fifth embodiment is different from the fragrance cartridge 100 of the second embodiment in the position where the capsule 50 containing the wasabi extract is arranged.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 11 shows the fragrance cartridge 100 according to the fifth embodiment.
  • the capsule 50 containing the wasabi extract is arranged between the aromatic base material 20 and the support member 40 in the axial direction of the aromatic cartridge 100. More specifically, in this embodiment, the capsule 50 is formed into an ellipsoid. A gap for accommodating the capsule 50 is formed between the aromatic base material 20 and the support member 40.
  • the wasabi extract flowing out of the capsule comes into contact with the aerosol and aromatic components generated from the aromatic base material 20, and the allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate are contained in a high concentration in the aerosol. Allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate can be effectively inhaled because of the facilitation.
  • the fragrance cartridge 100 of the sixth embodiment is different from the fragrance cartridge 100 of the fifth embodiment in that the capsule 50 in which the wasabi extract is encapsulated is arranged.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 12 shows the fragrance cartridge 100 according to the sixth embodiment.
  • a gap is provided between the fragrance base material 20 and the support member 40 in the axial direction of the fragrance cartridge 100, and the plurality of capsules 50 in which the wasabi extract is sealed and the mixed sphere 60 are in the gap. It is arranged in. More specifically, in the present embodiment, two capsules 50 formed on a sphere and one mixed sphere 60 are arranged.
  • the capsule 50 may contain wasabi extract in at least one of the two capsules.
  • the capsule 50 may contain the above-mentioned refreshing agent, fragrance and other fragrances.
  • the mixed sphere 60 has the same size as the capsule 50 and is formed of a material harder than the capsule 50, for example, a resin.
  • the capsule 50 and the mixed sphere 60 collide with each other in the void. Capsules 50 are destroyed by collision with mixed spheres 60 and release wasabi extract.
  • the fragrance cartridge 100 of the seventh embodiment is different from the fragrance cartridge 100 of the fifth embodiment in the position where the capsule 50 containing the wasabi extract is arranged.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 13 shows the fragrance cartridge 100 according to the seventh embodiment. As shown in FIG. 13, a gap is formed between the support member 40 and the filter 30 in the axial direction of the fragrance cartridge 100.
  • the capsule 50 containing the wasabi extract is arranged in the above void. In this embodiment, the capsule 50 is formed into an ellipsoid.
  • the capsule 50 By arranging the capsule 50 between the support member 40 and the filter 30 in this way, when the capsule 50 is broken, the wasabi extract is easily impregnated into the filter 30 and the concentration is high through the filter 30.
  • Wasabi extract can be aspirated. That is, since the capsule 50 is arranged near the filter 30 on the mouthpiece side, the user can ingest higher concentrations of allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate.
  • the fragrance cartridge 100 of the eighth embodiment is different from the fragrance cartridge 100 of the first embodiment in that the wasabi extract is contained.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 14 shows the fragrance cartridge 100 according to the eighth embodiment. As shown in FIG. 14, the wasabi extract is contained in the filter 30.
  • the filter 30 can be made, for example, by impregnating the filter 30 with a liquid wasabi extract and then drying it.
  • the filter 30 is not limited to such an embodiment, and can be prepared, for example, by dispersing a powdered wasabi extract in the filter 30.
  • the filter 30 As described above, by containing the wasabi extract in the filter 30, the influence of the heat of the aromatic base material 20 heated to a high temperature is avoided as much as possible, and the allyl isothiocyanate and 6-methylsulfinylhexyliso generated from the wasabi extract are avoided.
  • the thiocyanate can be inhaled.
  • the wasabi extract may be provided on the cover 10 that covers the outer peripheral portion of the filter 30.
  • the wasabi extract is preferably provided on the chip paper 13 of the cover 10.
  • the wasabi extract is provided on the chip paper 13, it is preferable to impregnate the chip paper 13 with the above-mentioned liquid wasabi extract and dry it.
  • the lips touch the chip paper 13 impregnated with the wasabi extract.
  • the wasabi extract is ingested from the lips into the user's body.
  • the aroma component enhanced by allyl isothiocyanate can be felt.
  • the filter 30 impregnated with the wasabi extract.
  • the user can ingest allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate contained in mainstream smoke, and also from the lips, allyl isothiocyanate and 6-. Methylsulfinylhexyl isothiocyanate can be taken.
  • allyl isothiocyanate and 6-methylsulfinyl hexyl isothiocyanate volatilized from the filter 30 soak into the chip paper 13, so that the concentration of allyl isothiocyanate and 6-methylsulfinyl hexyl isothiocyanate in the chip paper 13 increases, and the concentration from the skin increases. It is possible to promote the intake of allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate.
  • the fragrance cartridge 100 of the ninth embodiment is different from the fragrance cartridge 100 of the eighth embodiment in that the wasabi extract is contained.
  • the same reference numerals are given to the same parts, and the description thereof will be omitted.
  • FIG. 15 shows the fragrance cartridge 100 according to the eighth embodiment.
  • the capsule 50 containing the wasabi extract is contained in the filter 30. More specifically, the capsule 50 is arranged in the filter 30 in the middle of the aromatic cartridge 100 in the axial direction.
  • the size of the capsule 50 arranged on the filter 30 is not particularly limited, but it can be installed in a larger size than the capsule of the above-described embodiment. That is, when the size of the capsule 50 arranged on the aromatic base material 20 is increased, the amount of the aromatic base material 20 decreases. Further, when the capsule 50 is arranged in the above-mentioned gap, when the capsule is enlarged, the gap is also formed wide accordingly, so that the axial length of the fragrance cartridge 100 becomes long. However, when the capsule 50 is arranged in the filter 30, such a problem does not occur, so that a capsule larger than the capsule arranged in another position can be arranged.
  • the filter 30 can be pinched to facilitate the destruction of the capsule 50, and the wasabi extract discharged when the capsule 50 is destroyed can be effectively impregnated into the filter 30. Can be made to.
  • the shape of the capsule 50 is not limited to a spherical shape, and may be formed in an ellipsoidal shape as shown in FIG. 16, for example. By making the shape of the capsule 50 an ellipsoid, more wasabi extract can be encapsulated in the capsule 50. Further, since the length of the capsule 50 becomes long, the capsule 50 can be easily ruptured when pressed with a finger.
  • the wasabi extract may be contained in a material other than the capsule.
  • a sponge material such as polyurethane or a porous material such as pumice stone may be impregnated with a liquid wasabi extract before use.
  • the aromatic cartridge 100 can be easily produced as compared with the case where the wasabi extract is contained in the capsule 50.
  • Example 1 (Sensory evaluation of flavor) An aromatic base material containing wasabi extract and crosslinked polyvinylpyrrolidone was prepared as an example, and an aromatic base material containing at least one of wasabi extract and crosslinked polyvinylpyrrolidone was prepared as a comparative example, and the flavors of both aerosols were evaluated. bottom.
  • the wasabi extract the wasabi extract obtained in the following manner was used. That is, the rhizome of wasabi grated at low temperature was added to ethanol and stirred. Centrifugation was performed on this ethanol solution to obtain a supernatant.
  • Cooking oil was added to this supernatant, and ethanol was evaporated with an evaporator to transfer the extract components of Sawa wasabi contained in ethanol into the cooking oil to obtain an extract.
  • the extract contains allyl isothiocyanate and 6-methylsulfinylhexyl isothiocyanate in a content ratio of 14.2: 1.
  • Example 1 The fragrance cartridge 100 of Example 1 was prepared with the formulations shown in Table 1. Specifically, a compound of crushed dried plant (aromatic material, fragrance material and flavor material), wasabi extract (including allyl isothiocyanate-containing substance and 6-methylsulfinylhexyl isothiocyanate), aerosol former and heat-melting substance. was used as the basic composition. In Example 1, the basic formulation was 65% by mass of ground dried plant and wasabi extract (including allyl isothiocyanate-containing substance and 6-methylsulfinylhexyl isothiocyanate), 25% by mass of aerosol former, and heat-melting substance. Was 10% by mass.
  • the fragrance cartridge 100 of Example 1 was prepared. Although pure water is added for the molding process, it is removed from the aromatic substrate by being dried after the molding process.
  • konjac flour was used as the aroma material of the raw material (B1)
  • black tea and sweet osmanthus flowers were used as the fragrance material of the raw material (A1)
  • Jiaogulan was used as the flavor material of the raw material (A3).
  • Glycerin and propylene glycol were used as the aerosol former of the raw material (A4).
  • Beeswax was used as the heat-melting substance of the raw material (A2).
  • Mentha oil and menthol were used as the fragrance as the raw material (A4).
  • As the binder of the raw material (A3) CMC sodium salt and sugar cane fiber were used.
  • Cross-linked polyvinylpyrrolidone and ⁇ -cyclodextrin were used as the sorbent of the raw material (A3). Potassium sorbate and sodium benzoate were used as preservatives for the raw material (B2).
  • the raw materials (A1) and (A2) were prepared in the manner shown in FIG. Specifically, the raw material (A1) was obtained by sterilizing the fragrance material and then pulverizing it into powder.
  • the raw material (A2) a flavor material, wasabi extract (including allyl isothiocyanate-containing substance and 6-methylsulfinylhexyl isothiocyanate) and a heat-melting substance are roughly mixed with a Henshell mixer, then compressed and sheared to be mixed. It was prepared by pulverizing after cooling to 0 ° C. or lower. Further, as the raw materials (A1) and (A2), those selected by an 80 mesh sieve having an average particle size of about 250 ⁇ m were used.
  • the fragrance cartridge 100 was produced using the raw materials (A) and (B). Specifically, a mixing step of mixing the raw materials (A) and (B) with a kneader was performed.
  • a compression / shearing step of forming the mixture into a sheet using three rolls was performed.
  • the compression / shearing step it was formed into a sheet so that the thickness was 0.28 ⁇ 0.02 mm.
  • the compression / shearing steps were performed below the melting point of beeswax.
  • a cutting process of cutting the sheet was performed. In the cutting step, the sheet was cut so as to have a width of 1.5 ⁇ 0.1 mm and a length of about 240 mm.
  • the aromatic base material thus obtained was wrapped in paper so as to have a filling rate of a predetermined amount.
  • the aromatic substrate wrapped in paper was cut to a length of 11.5 to 12.0 mm and then dried to produce an aromatic cartridge 100.
  • Comparative Example 1 The fragrance cartridge 100 of Comparative Example 1 was prepared with the formulations shown in Table 4. Comparative Example 1 is different from Example 1 in that it does not contain the wasabi extract of the raw material (A2) (containing the allyl isothiocyanate-containing substance and 6-methylsulfinylhexyl isothiocyanate). Others are the same as in Examples 1 to 3, so the description of the raw material and the manufacturing method will be omitted.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Fats And Perfumes (AREA)

Abstract

L'invention concerne une cartouche de parfum qui a un bon arôme dérivé du wasabi et qui est bénéfique pour la santé. La cartouche de parfum est montée sur un inhalateur ayant un moyen de chauffage électrique, et est chauffée par le moyen de chauffage électrique pour générer un aérosol. La cartouche de parfum comprend : un couvercle cylindrique ; une substance de base de parfum qui est stockée dans le couvercle et est chauffée pour générer un aérosol contenant un composant de parfum ; un filtre stocké dans le couvercle ; et un extrait de wasabi. L'extrait de wasabi est liquide ou solide ou est encapsulé, et est inclus dans une ou plusieurs parties de la cartouche de parfum.
PCT/JP2021/032367 2020-10-02 2021-09-02 Cartouche de parfum WO2022070755A1 (fr)

Applications Claiming Priority (4)

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JP2020167766 2020-10-02
JP2020-167766 2020-10-02
JP2021081468A JP2022060140A (ja) 2020-10-02 2021-05-13 芳香カートリッジ
JP2021-081468 2021-05-13

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012525138A (ja) * 2009-04-29 2012-10-22 ブリティッシュ アメリカン タバコ （インヴェストメンツ） リミテッド 処理されたタバコ
WO2015002279A1 (fr) * 2013-07-03 2015-01-08 味の素株式会社 Composition favorisant la production de glutathion
JP2015509702A (ja) * 2011-12-14 2015-04-02 センティエンズ，エルエルシー 喫煙の化学受容を刺激するためのデバイス及び方法
WO2019111536A1 (fr) * 2017-12-05 2019-06-13 日本たばこ産業株式会社 Charge pour article à fumer
JP2019523631A (ja) * 2016-05-20 2019-08-29 ブリティッシュ アメリカン タバコ （インヴェストメンツ） リミテッドＢｒｉｔｉｓｈ Ａｍｅｒｉｃａｎ Ｔｏｂａｃｃｏ （Ｉｎｖｅｓｔｍｅｎｔｓ） Ｌｉｍｉｔｅｄ エアロゾル生成装置のためのフィルタ
WO2019163146A1 (fr) * 2018-02-23 2019-08-29 株式会社 東亜産業 Charge pour cigarette électronique et cartouche de cigarette électronique l'utilisant
WO2020012633A1 (fr) * 2018-07-13 2020-01-16 株式会社ダイセル Ruban pour bout de cigarette électronique, pointe de cigarette électronique, et procédé de production de ruban pour bout de cigarette électronique

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012525138A (ja) * 2009-04-29 2012-10-22 ブリティッシュ アメリカン タバコ （インヴェストメンツ） リミテッド 処理されたタバコ
JP2015509702A (ja) * 2011-12-14 2015-04-02 センティエンズ，エルエルシー 喫煙の化学受容を刺激するためのデバイス及び方法
WO2015002279A1 (fr) * 2013-07-03 2015-01-08 味の素株式会社 Composition favorisant la production de glutathion
JP2019523631A (ja) * 2016-05-20 2019-08-29 ブリティッシュ アメリカン タバコ （インヴェストメンツ） リミテッドＢｒｉｔｉｓｈ Ａｍｅｒｉｃａｎ Ｔｏｂａｃｃｏ （Ｉｎｖｅｓｔｍｅｎｔｓ） Ｌｉｍｉｔｅｄ エアロゾル生成装置のためのフィルタ
WO2019111536A1 (fr) * 2017-12-05 2019-06-13 日本たばこ産業株式会社 Charge pour article à fumer
WO2019163146A1 (fr) * 2018-02-23 2019-08-29 株式会社 東亜産業 Charge pour cigarette électronique et cartouche de cigarette électronique l'utilisant
WO2020012633A1 (fr) * 2018-07-13 2020-01-16 株式会社ダイセル Ruban pour bout de cigarette électronique, pointe de cigarette électronique, et procédé de production de ruban pour bout de cigarette électronique

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