WO2022062912A1 - Bulk acoustic wave resonator having acoustic resistance layer, and assembly thereof and manufacturing method therefor, filter, and electronic device - Google Patents

Bulk acoustic wave resonator having acoustic resistance layer, and assembly thereof and manufacturing method therefor, filter, and electronic device Download PDF

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WO2022062912A1
WO2022062912A1 PCT/CN2021/117485 CN2021117485W WO2022062912A1 WO 2022062912 A1 WO2022062912 A1 WO 2022062912A1 CN 2021117485 W CN2021117485 W CN 2021117485W WO 2022062912 A1 WO2022062912 A1 WO 2022062912A1
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layer
resonator
acoustic resistance
acoustic
top electrode
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PCT/CN2021/117485
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French (fr)
Chinese (zh)
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庞慰
班圣光
徐洋
杨清瑞
张孟伦
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诺思(天津)微系统有限责任公司
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    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/02Details
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/15Constructional features of resonators consisting of piezoelectric or electrostrictive material
    • H03H9/17Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator

Definitions

  • Embodiments of the present disclosure relate to the field of semiconductors, and in particular, to a bulk acoustic wave resonator and components thereof, a method of manufacturing a bulk acoustic wave resonator, a filter, and an electronic device.
  • the requirements for data transmission rate are getting higher and higher.
  • the high utilization rate of spectrum resources and the complexity of spectrum is the high utilization rate of spectrum resources and the complexity of spectrum.
  • the complexity of the communication protocol puts forward strict requirements for various performances of the radio frequency system.
  • the radio frequency filter plays a crucial role, which can filter out out-of-band interference and noise to meet the requirements of the radio frequency system and the Communication protocol requirements for signal-to-noise ratio.
  • FBAR thin film bulk acoustic resonator
  • the series resonators and parallel resonators of the prior art filters work together to form the filter passband characteristics.
  • the roll-off characteristic on the right side of the passband of the filter can be effectively improved. It is easy to achieve good roll-off characteristics by applying a small Kt 2 resonator to the filter, but once the design indicators (bandwidth, insertion loss, out-of-band rejection, etc.) are determined, the Kt 2 of the resonator is basically determined, so that the filter bandwidth and filter The good roll-off characteristics of the resonator are contradictory.
  • the structural main body of the thin film bulk acoustic wave resonator is a "sandwich" structure composed of electrode-piezoelectric film-electrode, that is, a piezoelectric material is sandwiched between two metal electrode layers.
  • the FBAR uses the inverse piezoelectric effect to convert the input electrical signal into mechanical resonance, and then uses the piezoelectric effect to convert the mechanical resonance into an electrical signal output.
  • the film bulk acoustic wave resonator mainly uses the longitudinal piezoelectric coefficient of the piezoelectric film to generate the piezoelectric effect, so its main working mode is the longitudinal wave mode in the thickness direction, that is, the sound wave of the bulk acoustic wave resonator is mainly in the film body of the resonator, and the main working mode is the longitudinal wave mode in the thickness direction.
  • the vibration direction is in the vertical direction.
  • the lateral Lamb wave will leak out from the lateral direction of the piezoelectric film layer, resulting in acoustic loss, thus making the Q value of the resonator. decrease.
  • the present disclosure is made to alleviate or solve at least one aspect of the above-mentioned problems in the prior art.
  • a bulk acoustic wave resonator comprising:
  • the overlapping area of the top electrode, the piezoelectric layer and the bottom electrode in the thickness direction of the resonator constitutes an effective area of the resonator
  • the piezoelectric layer includes a first layer and a second layer, an acoustic resistance layer is arranged between the first layer and the second layer, the second layer is above the first layer, and the inner edge of the acoustic resistance layer is in the horizontal direction On the inner side of the boundary of the acoustic mirror, the acoustic resistance of the acoustic resistance layer is different from the acoustic resistance of the piezoelectric layer;
  • the resonator also includes a channel or opening that communicates the acoustically resistive layer to the outside.
  • Embodiments of the present disclosure also relate to a bulk acoustic wave resonator assembly, comprising at least two bulk acoustic wave resonators, wherein at least one bulk acoustic wave resonator is the above-mentioned resonator.
  • Embodiments of the present disclosure also relate to a method of manufacturing a bulk acoustic wave resonator
  • the resonator includes a substrate, an acoustic mirror, a bottom electrode, a piezoelectric layer and a top electrode, the piezoelectric layer includes a first layer and a second layer, and a non-electrode connection end of the top electrode is arranged between the first layer and the second layer A voided layer, the method comprising the steps of:
  • the method further includes the steps of: at the non-electrode connection end of the top electrode, removing the second layer by etching to expose the outer end of the sacrificial layer; and releasing the sacrificial layer to form the void layer; or
  • the method further includes the steps of: forming a release channel in the second layer penetrating the second layer in the thickness direction of the second layer outside the non-electrode connection end of the top electrode; and releasing the sacrificial layer via the release channel to form the void layer.
  • Embodiments of the present disclosure also relate to a filter comprising the resonator or assembly described above.
  • Embodiments of the present disclosure also relate to an electronic device comprising the above-mentioned filter or the above-mentioned resonator or the above-mentioned assembly.
  • FIG. 1 is a schematic top view of a bulk acoustic wave resonator according to an exemplary embodiment of the present disclosure
  • FIG. 2-4 are schematic cross-sectional views of a bulk acoustic wave resonator along the MOM' line in FIG. 1 according to various exemplary embodiments of the present disclosure
  • FIG. 5 exemplarily shows the relationship between the width of the AW structure and the electromechanical coupling coefficient
  • FIG. 6 exemplarily shows the width of the AW structure and the parallel resonance impedance of the bulk acoustic wave resonator in the case where the AW structure is provided in the piezoelectric layer and in the case where the AW structure is provided between the top electrode and the piezoelectric layer, respectively
  • FIG. 7 exemplarily shows the case where the AW structure is provided in the piezoelectric layer and the upper piezoelectric layer is removed and the case where the AW is provided in the piezoelectric layer and the upper piezoelectric layer is not removed, respectively,
  • FIG. 8-10 are schematic cross-sectional views of a bulk acoustic wave resonator along the MOM' line in FIG. 1 according to various exemplary embodiments of the present disclosure
  • FIG. 11 is a schematic top view of a bulk acoustic wave resonator according to another exemplary embodiment of the present disclosure.
  • FIG. 12 is a schematic cross-sectional view of a bulk acoustic wave resonator along the MOM' line in FIG. 11 according to an exemplary embodiment of the present disclosure
  • FIG. 13 is a schematic top view of a bulk acoustic wave resonator according to yet another exemplary embodiment of the present disclosure.
  • FIG. 14 is a schematic top view of a bulk acoustic wave resonator according to still another exemplary embodiment of the present disclosure.
  • FIG. 15 is a schematic cross-sectional view of a bulk acoustic wave resonator along the MOM' line in FIG. 14 according to an exemplary embodiment of the present disclosure
  • 16A-16G exemplarily show cross-sectional schematic diagrams of the manufacturing process of the bulk acoustic wave resonator in FIG. 15;
  • 17 is a schematic cross-sectional view exemplarily showing that the acoustic resistance layer is provided in the middle of the piezoelectric layer and the piezoelectric layer on the upper side is not removed.
  • Substrate, optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
  • Acoustic mirror which can be a cavity, or a Bragg reflector and other equivalent forms.
  • the embodiment of the present disclosure adopts the form of a cavity.
  • a release channel which communicates the release hole 90 with the cavity of the acoustic mirror.
  • the sacrificial layer 21 Sacrificial layer, when the acoustic mirror is in the form of a cavity, it is set in the cavity during the process of preparing the resonator, and is released in the subsequent process to form the cavity of the acoustic mirror.
  • the sacrificial layer 21 can be optionally two. Silicon oxide, doped silicon dioxide, polysilicon, amorphous silicon and other materials.
  • Bottom electrode (including bottom electrode pins), the material can be selected from molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or a composite of the above metals or their alloys.
  • the first piezoelectric layer which can be a single crystal piezoelectric material, optional, such as: single crystal aluminum nitride, single crystal gallium nitride, single crystal lithium niobate, single crystal lead zirconate titanate (PZT), Materials such as single crystal potassium niobate, single crystal quartz film, or single crystal lithium tantalate can also be polycrystalline piezoelectric materials (corresponding to single crystals, non-single crystal materials), optional, such as polycrystalline nitridation
  • Aluminum, zinc oxide, PZT, etc. can also be a rare earth element doped material containing a certain atomic ratio of the above materials, for example, can be doped aluminum nitride, and doped aluminum nitride contains at least one rare earth element, such as scandium (Sc) , Yttrium (Y), Magnesium (Mg), Titanium (Ti), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neody
  • the second piezoelectric layer the material of which can be a single crystal piezoelectric material, optional, such as: single crystal aluminum nitride, single crystal gallium nitride, single crystal lithium niobate, single crystal lead zirconate titanate (PZT ), single crystal potassium niobate, single crystal quartz film, or single crystal lithium tantalate, etc., or polycrystalline piezoelectric material (corresponding to single crystal, non-single crystal material), optional, such as polycrystalline Aluminum nitride, zinc oxide, PZT, etc., can also be a rare earth element doped material containing a certain atomic ratio of the above materials, for example, can be doped aluminum nitride, and doped aluminum nitride contains at least one rare earth element, such as scandium ( Sc), Yttrium (Y), Magnesium (Mg), Titanium (Ti), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodym
  • Top electrode (including top electrode pins), the material can be selected from molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or a composite of the above metals or their alloys.
  • Passivation layer or process layer which can be aluminum nitride, silicon nitride or silicon dioxide, etc.
  • Acoustic resistance layer the acoustic resistance of which is different from the acoustic resistance of the first piezoelectric layer 41 and the second piezoelectric layer 42, in the embodiment illustrated in the present disclosure, in the form of an air gap (ie AW), but also It may be in the form of a solid dielectric layer, such as silicon dioxide or its dopants, or silicon nitride or its dopants.
  • the acoustic resistance of the acoustic resistance layer may also be greater than the acoustic resistance of the first piezoelectric layer and the second piezoelectric layer.
  • a sacrificial layer which is set at the position corresponding to the air gap during the process of preparing the resonator, and is released in the subsequent process to form the air gap.
  • the sacrificial layer 81 can be selected from silicon dioxide, doped silicon dioxide, and polysilicon , amorphous silicon and other materials.
  • a release hole for releasing the sacrificial layer material in the cavity of the acoustic mirror a release hole for releasing the sacrificial layer material in the cavity of the acoustic mirror.
  • a release channel for releasing the sacrificial layer material in the void layer.
  • FIG. 1 is a schematic top view of a bulk acoustic wave resonator according to an exemplary embodiment of the present disclosure
  • FIG. 2 is a schematic cross-sectional view of the bulk acoustic wave resonator along the MOM' line in FIG. 1 according to an exemplary embodiment of the present disclosure .
  • the BAW resonator includes a substrate 10, an acoustic mirror cavity 20 disposed in the substrate 10, a bottom electrode 30, a top electrode 50, and a piezoelectric layer including a first piezoelectric layer 41 and a piezoelectric layer.
  • the second piezoelectric layer 42 The second piezoelectric layer 42 .
  • An acoustic resistance layer 80 in the form of an air gap is provided between the first piezoelectric layer and the second piezoelectric layer.
  • Passivation layer 70 is also shown in FIGS. 1-2.
  • FIG. 7 exemplarily shows the case in which the AW structure is provided in the piezoelectric layer and the upper piezoelectric layer is removed (in FIG. 7 , corresponding to the solid line, for example, see FIGS. 2-4 , 8 -10) and in the case where the AW is arranged in the piezoelectric layer and the upper piezoelectric layer is not removed (in Fig. 7, corresponding to the dotted line, for example, see Fig. 17 for an embodiment), the width of the AW structure is related to the bulk acoustic wave Graph of the relationship between the parallel resonant impedances of the resonators.
  • the AW structure is placed between two piezoelectric layers and the second piezoelectric layer 42 is etched or removed along the boundary of the non-electrode connection end of the top electrode.
  • the performance is significantly better than the device performance when the second piezoelectric layer is not etched or removed under the same conditions.
  • the portion of the first piezoelectric layer 41 outside the AW structure 80 is not etched, that is, at the non-electrode connection end of the top electrode, the portion of the first layer outside the outer edge of the acoustic resistance layer is not etched.
  • the thickness is equal to the thickness of the portion located inside the outer edge of the acoustically resistive layer.
  • the second piezoelectric layer 42 is etched together, so that the second piezoelectric layer 42, the top electrode and the passivation layer form the same etching surface. .
  • the first piezoelectric layer 41 under the AW structure 80 is not etched in the inactive area of the resonator, but the second piezoelectric layer 42 is etched, so at the non-electrode connection end of the top electrode of the resonator, resonance There is no second piezoelectric layer in the inactive region of the device.
  • the AW structure 80 at the non-electrode connection end, the second piezoelectric layer 41 , the non-electrode connection end of the top electrode, and the passivation layer 70 form the same etching surface. It should be noted that it is not required that the end surfaces of the passivation layer 70 and the non-electrode connection end of the top electrode are flush.
  • FIG. 3 is a schematic cross-sectional view of a bulk acoustic wave resonator similar to the MOM' line in FIG. 1 according to an exemplary embodiment of the present disclosure.
  • the difference between FIG. 3 and FIG. 2 is that, in FIG. 3 , the first piezoelectric The portion of the layer 41 on the outside of the AW structure 80 is partially etched, while in FIG. 2 the corresponding portion of the first piezoelectric layer 41 is not etched. That is, in FIG. 3 , at the non-electrode connection end of the top electrode, the thickness of the portion of the first layer outside the outer edge of the acoustic resistance layer is smaller than the thickness of the portion inside the outer edge of the acoustic resistance layer.
  • the first piezoelectric layer 41 may be etched to a certain extent in the process of etching the second piezoelectric layer 42 , thereby obtaining the structure shown in FIG. 3 . In this case, the first piezoelectric layer 41 is partially etched.
  • FIG. 4 is a schematic cross-sectional view of a bulk acoustic wave resonator similar to the MOM' line in FIG. 1 according to an exemplary embodiment of the present disclosure.
  • the difference between FIG. 4 and FIG. 2 is that, in FIG. 4 , the first piezoelectric The portions of the layer 41 outside the AW structure 80 are all etched away, while in FIG. 2 , the corresponding portions of the first piezoelectric layer are not etched. That is, in FIG. 4, at the non-electrode connection end of the top electrode, the portion of the first layer that is outside the outer edge of the acoustic resistance layer is removed. That is, in the process of etching the second piezoelectric layer 42 , the first piezoelectric layer 41 may be etched away together, thereby obtaining the structure of FIG. 4 .
  • the end face of the second piezoelectric layer 42 is a vertical end face and is flush with the end face of the non-electrode connection end of the top electrode, but the present disclosure is not limited thereto.
  • FIG. 8-10 are schematic cross-sectional views of a bulk acoustic wave resonator along the MOM' line in FIG. 1 according to various exemplary embodiments of the present disclosure.
  • the end face of the second piezoelectric layer 42 is still a vertical end face, the end face of the non-electrode connection end of the top electrode is located outside the end face of the second piezoelectric layer 42 in the horizontal direction, and the two end faces are in the horizontal direction. There is a distance ⁇ d in the horizontal direction.
  • the end face of the second piezoelectric layer 42 is still a vertical end face, the end face of the non-electrode connection end of the top electrode is located inside the end face of the second piezoelectric layer 42 in the horizontal direction, and the two end faces are in the horizontal direction. There is a distance ⁇ d in the horizontal direction.
  • the end face of the second piezoelectric layer 42 is inclined outward, and the end face of the non-electrode connection end of the top electrode is located inside the end face of the second piezoelectric layer 42 in the horizontal direction, and the two end faces are horizontal There is a distance ⁇ d in the direction, and in FIG.
  • the inclination angle of the slope of the second piezoelectric layer 42 is ⁇ .
  • ⁇ d is between 0.25-5 ⁇ m.
  • the above-mentioned outwardly inclined inclined surface may also be an inwardly inclined inclined surface.
  • the inclination angle ⁇ of the inclined plane is in the range of 10-80 degrees.
  • a portion of the second piezoelectric layer 42 is removed (eg, cut by etching) at the non-electrode connection end of the top electrode, thereby directly exposing the AW structure or the acoustic resistance layer or air gap.
  • the air reflective surface formed after cutting can prevent energy or lateral Lamb waves from leaking through the second piezoelectric layer outside the AW structure, as shown in FIG. 7 , thereby improving the performance of the resonator.
  • the transverse Lamb wave forms a strong reflection at the air reflection surface, thereby reducing the lateral
  • the Lamb wave leakage increases the Q of the resonator. If only the AW structure is provided and the second piezoelectric layer 42 is not etched, the second piezoelectric layer 42 is a continuous interface, and the lateral Lamb waves can leak out of the effective area through the second piezoelectric layer 42, thereby reducing the the Q value of the resonator.
  • the second piezoelectric layer 42 can effectively reflect the transverse wave whose 1/4 of the transverse wavelength is L1
  • the top electrode can effectively reflect the transverse wave whose 1/4 of the transverse wavelength is L1+ ⁇ d.
  • the structure can only effectively reflect the transverse wave with a wavelength L1 of 1/4 of the transverse wavelength.
  • the second piezoelectric layer 42 can effectively reflect the transverse wave whose wavelength is between L2 and L3, which is 1/4 of the transverse wavelength. Therefore, more waves can be reflected, so the Q value will be higher.
  • the second piezoelectric layer 42 is removed at the non-electrode connection end of the top electrode to expose the AW structure or the acoustic resistance layer or the air gap, but this disclosure does not limited to this.
  • FIG. 11 is a schematic top view of a bulk acoustic wave resonator according to another exemplary embodiment of the present disclosure
  • FIG. 12 is a cross-section of the bulk acoustic wave resonator along the MOM' line in FIG. 11 according to an exemplary embodiment of the present disclosure Schematic.
  • the second piezoelectric layer 42 is provided with a channel 91 on the outside of the non-electrode connection end of the top electrode to communicate with the AW structure or void layer 80 .
  • the void layer 80 is continuously arranged along the circumferential direction of the effective area at least at the non-electrode connection end of the top electrode, and correspondingly, the channel 91 is a continuous channel arranged along the circumferential direction of the effective area.
  • the channel 91 By arranging the channel 91, it can be used to release the sacrificial layer material in the void layer 80 to form the void layer. At this time, the channel 91 is the release channel. Cut-off or partial cut-off processing, which can also prevent or reduce energy leakage during the operation of the resonator. The effect of preventing or reducing energy leakage can be seen, for example, in FIG. 7 .
  • the channel 91 may also only serve to prevent or reduce energy leakage during the operation of the resonator.
  • the acoustic resistance layer 80 is not in the form of a void layer, but in the form of a solid medium layer.
  • the acoustic resistive layers 80 are in the form of a continuous arrangement, but the present disclosure is not limited thereto.
  • 13 is a schematic top view of a bulk acoustic wave resonator according to still another exemplary embodiment of the present disclosure, and a cross-sectional view taken along the MOM' line in FIG. 13 is similar to FIG. 12 .
  • the acoustically resistive layer 80 includes a plurality of acoustically resistive portions that are spaced apart in the circumferential direction along the effective area of the resonator.
  • the channel 91 may include a plurality of holes communicating with the plurality of acoustic resistance parts respectively (corresponding to the case of partial cutting process), or may be arranged along the circumferential direction of the effective area and communicate with each acoustic resistance part.
  • FIG. 6 exemplarily shows the width of the AW structure and the parallel resonance impedance of the bulk acoustic wave resonator in the case where the AW structure is provided in the piezoelectric layer and in the case where the AW structure is provided between the top electrode and the piezoelectric layer, respectively diagram of the relationship between them.
  • the abscissa is the width of the AW structure (unit is ⁇ m)
  • the ordinate is the parallel resonance impedance Rp of the resonator (unit is ohm).
  • the broken line represents the case where the AW structure is provided between the top electrode and the piezoelectric layer
  • the solid line represents the case where the AW structure is provided in the piezoelectric layer.
  • the value of the parallel resonance impedance when the AW structure is in the piezoelectric layer is significantly higher than the value of the parallel resonance impedance when the AW structure is between the piezoelectric layer and the top electrode. It can be seen that by disposing the acoustic resistance layer 80 between the first piezoelectric layer 41 and the second piezoelectric layer 42 , the performance of the resonator can be effectively improved compared to disposing the acoustic resistance layer between the top electrode and the piezoelectric layer.
  • the value of the electromechanical coupling coefficient of the resonator can also be adjusted. Since the first piezoelectric layer 41 and the second piezoelectric layer 42 are prepared separately, the two piezoelectric layers can be prepared as different materials, so that the electromechanical coupling coefficient of the resonator can be freely adjusted.
  • the first piezoelectric layer 41 is a piezoelectric layer of a certain material (for example, a piezoelectric layer of a material selected from aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate).
  • the second piezoelectric layer 42 is a doped layer doped with at least one rare earth element as mentioned above in the same material layer as the material of the first piezoelectric layer 41
  • the first piezoelectric layer 41 and the second piezoelectric layer 42 are both piezoelectric materials based on aluminum nitride, but one layer of the piezoelectric material is a piezoelectric material without any doping, and the other layer is a doping element scandium piezoelectric material.
  • the first piezoelectric layer and the second piezoelectric layer are both doped layers of the same material, but the doping concentration of the first piezoelectric layer is different from the doping concentration of the second piezoelectric layer.
  • the first piezoelectric layer 41 and the second piezoelectric layer 42 are both piezoelectric materials based on aluminum nitride doped with rare earth element scandium, but the doping concentration of the first piezoelectric layer and the second piezoelectric layer is different. .
  • the material of the first piezoelectric layer 41 is one of aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate
  • the second piezoelectric layer 42 It is a material different from the material of the first piezoelectric layer among aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate.
  • the first piezoelectric The layer is aluminum nitride and the second piezoelectric layer is zinc oxide.
  • the above arrangement of the piezoelectric layers 41 and 42 with different doping can adjust the electromechanical coupling coefficient of the resonator to a relatively large extent.
  • the electromechanical coupling coefficient of the resonator in the transmit filter Tx and the electromechanical coupling coefficient of the resonator in the receive filter Rx need to be quite different (greater than 1%), but in Inside the transmitting filter Tx or the receiving filter Rx, the electromechanical coupling coefficient between different resonators needs to have a small difference (less than 1%).
  • the width of the AW structure in the effective area of the resonator can be adjusted, and The electromechanical coupling coefficient of the resonator inside the filter is adjusted by adjusting the width L1 of the AW structure in FIG. 2 .
  • L1 is the width of the AW structure at the non-electrode connection end of the top electrode, which is the horizontal distance between the non-electrode connection end of the top electrode and the inner edge of the AW structure.
  • the acoustic resistance layer can also be further disposed on the electrode connection end of the top electrode, and FIGS. 14-15 show such an embodiment.
  • 14 is a schematic top view of a bulk acoustic wave resonator according to still another exemplary embodiment of the present disclosure
  • FIG. 15 is a cross-section of the bulk acoustic wave resonator along the MOM' line in FIG. 14 according to an exemplary embodiment of the present disclosure Schematic.
  • the width of the AW structure in the effective area of the resonator can be adjusted, that is, the electromechanical coupling coefficient of the resonator inside the filter can be adjusted by adjusting the widths L1 and L2 of the AW structure in FIG. 15 .
  • L1 is the width of the AW structure at the non-electrode connection end of the top electrode, which is the distance between the non-electrode connection end of the top electrode and the inner edge of the AW structure in the horizontal direction; as shown in Figure 15, L2 is the width of the AW structure at the electrode connection end of the top electrode, which is the distance in the horizontal direction between the boundary of the acoustic mirror and the inner edge of the AW structure at the connection end of the top electrode.
  • FIG. 5 exemplarily shows the relationship between the width of the AW structure or the air gap and the electromechanical coupling coefficient.
  • the abscissa is the width of the AW structure (unit is ⁇ m)
  • the ordinate is the electromechanical coupling coefficient.
  • Figure 5 shows the influence of the width of the AW structure of the resonator on the electromechanical coupling coefficient when the width of the AW structure on each side of the effective area of the resonator is the same.
  • the electromechanical coupling coefficient increases with the increase of the AW width. slowing shrieking. It can be seen that the electromechanical coupling coefficient of the resonator can be adjusted by adjusting the width of the AW structure.
  • the width of the AW structure on each side can be the same or different.
  • the AW structure or the acoustic resistance layer or the air gap can only be arranged at the non-electrode connection end of the top electrode, as shown in Figures 2-4 and 8-13; it can also be arranged at the non-electrode connection end and the electrode connection end of the top electrode at the same time, As shown in Figure 14-15.
  • an AW structure or an acoustic resistance layer or an air gap is provided at the non-electrode connection end of the top electrode.
  • the effective area of the resonator is a polygon, it can be It includes the case where it is provided only on one side or a plurality of sides of the non-electrode connection end, and may also include the case where it is provided on all sides of the non-electrode connection end.
  • an AW structure or an acoustic resistive layer or an air gap is provided at the electrode connection end of the top electrode, and in the case where the effective area of the resonator is a polygon, it is indicated at the electrode connection end of the top electrode
  • the side where it is located is provided with an AW structure or an acoustic resistance layer or an air gap.
  • An AW structure or an acoustically resistive layer or an air gap can also be provided around the entire active area of the resonator.
  • the electromechanical properties of the resonator will be a definite value.
  • the design freedom of the electromechanical coupling coefficient of the resonator can be increased.
  • the first piezoelectric layer 41 is made of undoped aluminum nitride material
  • the second piezoelectric layer 42 is made of scandium-doped aluminum nitride material.
  • the electromechanical coupling coefficient is 6% when the piezoelectric layer only uses undoped aluminum nitride piezoelectric layer, and the electromechanical coupling coefficient is 10% when the piezoelectric layer only uses doped aluminum nitride. . Therefore, when the thickness of the piezoelectric layer is constant, by controlling the doping concentration of the first piezoelectric layer 41 and the second piezoelectric layer 42, the electromechanical coupling coefficient of the resonator can be freely changed between 6% and 10%.
  • the electromechanical coupling coefficients of different resonators in the filter can be fine-tuned by controlling the change of the width of the AW structure, so this scheme can maximize the increase in the efficiency of the filter.
  • the materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 may be different.
  • a certain electromechanical coupling of the resonator The required electromechanical coupling coefficient can be achieved by changing the material of the piezoelectric layer.
  • the electromechanical coupling coefficient of the resonator can be further adjusted by changing the width L1 in FIG. 2 .
  • the materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 may be different, and when the thicknesses of the first piezoelectric layer 41 and the second piezoelectric layer 42 are fixed, a certain electromechanical coupling of the resonator
  • the required electromechanical coupling coefficient can be achieved by changing the material of the piezoelectric layer. After the doping or materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 are determined, the electromechanical coupling coefficient of the resonator can be further adjusted by changing the widths L1 and L2 in FIG. 15 .
  • the thicknesses of the first piezoelectric layer 41 and the second piezoelectric layer 42 are H1 and H2, respectively.
  • the ratio of two different piezoelectric materials can be adjusted by adjusting the ratio of H1 and H2, thereby adjusting the electromechanical coupling coefficient of the resonator.
  • H2 and H1 are determined, similarly, the electromechanical coupling coefficient of the resonator can be further adjusted by changing the widths of the widths L1 and L2 in FIG. 2 .
  • the position of the AW structure sandwiched between the first piezoelectric layer 41 and the second piezoelectric layer 42 is not fixed.
  • the distance between the lower surface of the AW structure and the lower surface of the first piezoelectric layer 41 is greater than
  • the distance between the upper surface of the AW structure and the second piezoelectric layer 42 is also greater than
  • the range of thickness of the AW structure is
  • FIGS. 14-15 The fabrication process of the bulk acoustic wave resonator in FIGS. 14-15 is exemplarily described below with reference to FIGS. 16A-16G . It should be pointed out that this manufacturing process can also be used in the case where the acoustic resistance layer is only provided on the non-electrode connection end of the top electrode. At this time, different from the following steps, the sacrifice corresponding to the acoustic resistance layer is no longer provided. layer and release of the sacrificial layer.
  • a cavity as the acoustic mirror 20 is formed on the upper surface of the substrate 10, and then a sacrificial material is provided on the upper surface of the substrate 10, the sacrificial material fills the cavity, and then, by CMP (Chemical Mechanical Polishing) ) process removes the sacrificial material on the upper surface of the substrate 10 and makes the upper surface of the sacrificial material in the cavity flush with the upper surface of the substrate 10 to form the sacrificial layer 21 .
  • CMP Chemical Mechanical Polishing
  • a layer of electrode material is deposited and patterned on the structure of FIG. 16A to form bottom electrode 30 .
  • a first piezoelectric layer 41 is deposited on the structure of FIG. 16B , which may be, for example, an undoped piezoelectric layer.
  • a sacrificial material is deposited and patterned on the upper surface of the first piezoelectric layer 41 of FIG. 16C to form a sacrificial layer 81 .
  • the sacrificial layer 81 will be released for forming the AW structure 80 at a later stage.
  • a sacrificial layer 81 for electrode connection terminals and non-connection terminals of the top electrode is provided.
  • a second piezoelectric layer 42 is deposited on the upper surface of the structure of FIG. 16D , which may be, for example, a doped piezoelectric layer.
  • a top electrode 50 and a protective layer or passivation layer 70 are prepared on the upper surface of the structure of FIG. 16E.
  • the passivation layer 70, the top electrode 50 and the second piezoelectric layer 42 are etched to expose the sacrificial layer 81 at the non-electrode connection end of the top electrode.
  • the sacrificial layer 21 and the sacrificial layer 81 are released to form the acoustic mirror 20 and the AW structure 80, respectively, as shown in FIG. 16G.
  • the second piezoelectric layer can be prepared and etched first, followed by the preparation of the top electrode and passivation layer.
  • each numerical range except that it is explicitly stated that it does not include the endpoint value, may be the endpoint value, but also the middle value of each numerical range, and these are all within the protection scope of the present disclosure. .
  • upper and lower are relative to the bottom surface of the substrate, and for a component, the side close to the bottom surface is the lower side, and the side away from the bottom surface is the upper side.
  • inner and outer are in the lateral direction or radial direction relative to the center of the effective area of the resonator (the overlapping area of the piezoelectric layer, the top electrode, the bottom electrode and the acoustic mirror in the thickness direction of the resonator constitutes the effective area).
  • the side or end of a component close to the center of the active area is the inner or inner end
  • the side or end of the component away from the center of the active area is the outer or outer end.
  • being located inside the position means between the position and the center of the effective area in the lateral or radial direction
  • being located outside of the position means more laterally or radially than the position away from the center of the active area.
  • bulk acoustic wave resonators may be used to form filters or other semiconductor devices.
  • a bulk acoustic wave resonator comprising:
  • the overlapping area of the top electrode, the piezoelectric layer and the bottom electrode in the thickness direction of the resonator constitutes an effective area of the resonator
  • the piezoelectric layer includes a first layer and a second layer, an acoustic resistance layer is arranged between the first layer and the second layer, the second layer is above the first layer, and the inner edge of the acoustic resistance layer is in the horizontal direction On the inner side of the boundary of the acoustic mirror, the acoustic resistance of the acoustic resistance layer is different from the acoustic resistance of the piezoelectric layer;
  • the resonator also includes a channel or opening that communicates the acoustically resistive layer to the outside.
  • the outer edge of the acoustic resistance layer is flush with the end of the second layer, and the outer edge of the acoustic resistance layer forms or is in the opening;
  • the non-electrode connection end of the top electrode forms a cantilever structure.
  • the end face of the end portion of the second layer is a vertical plane or an inclined plane.
  • the thickness of the portion of the first layer on the outside of the outer edge of the acoustically resistive layer is equal to the thickness of the portion on the inside of the outer edge of the acoustically resistive layer;
  • the thickness of the portion of the first layer on the outside of the outer edge of the acoustically resistive layer is less than the thickness of the portion on the inside of the outer edge of the acoustically resistive layer;
  • the portion of the first layer outside the outer edge of the acoustically resistive layer is removed.
  • the non-electrode connection end of the top electrode is staggered from the end of the second layer in the horizontal direction.
  • the acoustic resistance layer includes a plurality of acoustic resistance portions, the plurality of acoustic resistance portions are spaced apart in the circumferential direction along the effective area of the resonator, and outer edges of the plurality of acoustic resistance portions constitute a circumference along the effective area. a plurality of said openings spaced in the direction; or
  • the acoustic resistance layer is continuously arranged in the circumferential direction along the effective area of the resonator, and the outer edge of the acoustic resistance layer constitutes the openings continuously arranged in the circumferential direction of the effective area.
  • the acoustic resistance layer is a void layer or a solid medium layer.
  • the channel passes through the second layer in the thickness direction of the second layer, the channel is outside the non-electrode connection end of the top electrode in the horizontal direction, and the channel is connected to the second layer.
  • the acoustic resistance layers are communicated or connected to each other.
  • the acoustic resistance layer is continuously arranged along the circumferential direction of the effective area at least at the non-electrode connection end of the top electrode, and the channel is a continuous channel arranged along the circumference of the effective area and communicated with or connected to the acoustic resistance layer , or the channel includes a plurality of holes spaced circumferentially along the effective area; or
  • the acoustic resistance layer includes a plurality of acoustic resistance parts, the plurality of acoustic resistance parts are arranged spaced apart in the circumferential direction along the effective area of the resonator, and the channel comprises a plurality of acoustic resistance parts respectively communicating with or in phase with the plurality of acoustic resistance parts;
  • a plurality of holes connected to each other, or the channel is a continuous channel arranged along the circumference of the effective area and communicated with or connected to the plurality of acoustic resistance parts.
  • the acoustic resistance layer is a void layer, and the channel is a release channel communicated with the void layer.
  • the piezoelectric material of the first layer is different from the piezoelectric material of the second layer.
  • One of the first layer and the second layer is a doped layer of the other;
  • the first layer and the second layer are both doped layers of the same material, and the doping concentration of the first layer is different from the doping concentration of the second layer; or
  • the material of the first layer is one of aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, lithium tantalate
  • the second layer is aluminum nitride, zinc oxide, zirconium A material different from the first layer material among lead titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate.
  • the acoustic resistance layer includes a non-connecting end acoustic resistance layer at the non-electrode connection end of the top electrode, and the inner edge of the non-connecting end acoustic resistance layer is located inside the non-electrode connection end of the top electrode in the horizontal direction.
  • the non-electrode connection end of the top electrode is in the inner side of the boundary of the acoustic mirror in the horizontal direction or is flush with the boundary of the acoustic mirror;
  • the first distance is in the range of 0.25-10 ⁇ m.
  • the acoustic resistance layer further includes a connection end acoustic resistance layer at the electrode connection end of the top electrode.
  • the thickness of the first layer is different from the thickness of the second layer.
  • a bulk acoustic wave resonator assembly comprising:
  • At least two BAW resonators wherein at least one BAW resonator is the resonator according to any one of 1-17.
  • the at least two bulk acoustic wave resonators include a first resonator and a second resonator;
  • Both the first resonator and the second resonator are resonators according to any one of 1-17.
  • the first resonator and the second resonator are the resonators according to 12.
  • the difference between the electromechanical coupling coefficient of the first resonator and the electromechanical coupling coefficient of the second resonator is in the range of 0%-10%.
  • said first and second resonators are both resonators according to 14 or 16;
  • the widths of the acoustic resistance layer of the first resonator and the corresponding acoustic resistance layer of the second resonator are different from each other.
  • a method of manufacturing a bulk acoustic wave resonator comprising a substrate, an acoustic mirror, a bottom electrode, a piezoelectric layer and a top electrode, the piezoelectric layer comprising a first layer and a second layer, the first layer and the second layer A void layer is arranged between the layers at the non-electrode connection end of the top electrode, and the method includes the steps:
  • the method further includes the steps of: at the non-electrode connection end of the top electrode, removing the second layer by etching to expose the outer end of the sacrificial layer; and releasing the sacrificial layer to form the void layer; or
  • the method further includes the steps of: forming a release channel in the second layer penetrating the second layer in the thickness direction of the second layer outside the non-electrode connection end of the top electrode; and releasing the sacrificial layer via the release channel to form the the void layer.
  • a filter comprising the BAW resonator of any one of 1-17, or the BAW resonator assembly of any one of 18-22.
  • An electronic device comprising the filter according to 24, or the BAW resonator according to any one of 1-17, or the BAW resonator assembly according to any one of 18-22 .
  • the electronic equipment here includes but is not limited to intermediate products such as RF front-end, filter and amplifier modules, and terminal products such as mobile phones, WIFI, and drones.

Abstract

The present disclosure relates to a bulk acoustic wave resonator, comprising: a substrate; an acoustic mirror; a bottom electrode; a piezoelectric layer; and a top electrode. The overlapping region of the top electrode, the piezoelectric layer, and the bottom electrode in the thickness direction of the resonator constitutes an effective region of the resonator; the piezoelectric layer comprises a first layer and a second layer; an acoustic resistance layer is provided between the first layer and the second layer; the second layer is located above the first layer; the inner edge of the acoustic resistance layer is located at the inner side of the boundary of the acoustic mirror in a horizontal direction; the acoustic resistance of the acoustic resistance layer is different from the acoustic resistance of the piezoelectric layer; and the resonator further comprises a channel or an opening for communicating the acoustic resistance layer with the outside. The present disclosure further relates to a bulk acoustic wave resonator assembly, a method for manufacturing a bulk acoustic wave resonator, a filter, and an electronic device.

Description

具有声阻层的体声波谐振器及其组件和制造方法、滤波器和电子设备Bulk acoustic wave resonator with acoustic resistance layer and its assembly and manufacturing method, filter and electronic device 技术领域technical field
本公开的实施例涉及半导体领域,尤其涉及一种体声波谐振器及其组件,一种制造体声波谐振器的方法,以及一种滤波器和一种电子设备。Embodiments of the present disclosure relate to the field of semiconductors, and in particular, to a bulk acoustic wave resonator and components thereof, a method of manufacturing a bulk acoustic wave resonator, a filter, and an electronic device.
背景技术Background technique
随着5G通信技术的日益发展,对数据传输速率的要求越来越高。与数据传输速率相对应的是频谱资源的高利用率和频谱的复杂化。通信协议的复杂化对于射频系统的各种性能提出了严格的要求,在射频前端模块,射频滤波器起着至关重要的作用,它可以将带外干扰和噪声滤除掉以满足射频系统和通信协议对于信噪比的要求。With the increasing development of 5G communication technology, the requirements for data transmission rate are getting higher and higher. Corresponding to the data transmission rate is the high utilization rate of spectrum resources and the complexity of spectrum. The complexity of the communication protocol puts forward strict requirements for various performances of the radio frequency system. In the radio frequency front-end module, the radio frequency filter plays a crucial role, which can filter out out-of-band interference and noise to meet the requirements of the radio frequency system and the Communication protocol requirements for signal-to-noise ratio.
传统的射频滤波器受结构和性能的限制,不能满足高频通信的要求。薄膜体声波谐振器(FBAR)作为一种新型的MEMS器件,具有体积小、质量轻、插入损耗低、频带宽以及品质因子高等优点,很好地适应了无线通信系统的更新换代,使FBAR技术成为通信领域的研究热点之一。Traditional RF filters are limited by structure and performance and cannot meet the requirements of high-frequency communication. As a new type of MEMS device, thin film bulk acoustic resonator (FBAR) has the advantages of small size, light weight, low insertion loss, high frequency bandwidth and high quality factor. It has become one of the research hotspots in the field of communication.
已有技术中的滤波器的串联谐振器和并联谐振器共同作用形成滤波器通带特性。通过设置串联谐振器的串联谐振频率彼此不同以及串联谐振器的机电耦合系数Kt 2的变化,可以有效改善滤波器通带右侧的滚降特性。滤波器应用小Kt 2谐振器容易实现良好的滚降特性,但是一旦设计指标(带宽、插损、带外抑制等)确定,谐振器的Kt 2也就基本确定了,这样滤波器带宽和滤波器良好的滚降特性是相互矛盾的,常规架构下宽带宽滤波器设计很难实现良好的滚降特性,且对于普通滤波器中的谐振器叠层已确定的条件下,通过对谐振器结构的改变,50Ohm谐振器的Kt 2变化只有±0.5%左右,对滤波器滚降特性的改善有限。所以放开各个谐振器间的Kt 2的自由度的限制,有利于提升整个滤波器的滚降性能。 The series resonators and parallel resonators of the prior art filters work together to form the filter passband characteristics. By setting the series resonance frequencies of the series resonators to be different from each other and the variation of the electromechanical coupling coefficient Kt 2 of the series resonators, the roll-off characteristic on the right side of the passband of the filter can be effectively improved. It is easy to achieve good roll-off characteristics by applying a small Kt 2 resonator to the filter, but once the design indicators (bandwidth, insertion loss, out-of-band rejection, etc.) are determined, the Kt 2 of the resonator is basically determined, so that the filter bandwidth and filter The good roll-off characteristics of the resonator are contradictory. It is difficult to achieve good roll-off characteristics in the design of wide-bandwidth filters under the conventional architecture. The change of Kt2 of the 50Ohm resonator is only about ±0.5%, and the improvement of the filter roll-off characteristic is limited. Therefore, releasing the restriction of the degree of freedom of Kt 2 between each resonator is beneficial to improve the roll-off performance of the entire filter.
此外,薄膜体声波谐振器的结构主体为由电极-压电薄膜-电极组成的“三明治”结构,即两层金属电极层之间夹一层压电材料。通过在两电极间输入正弦信号,FBAR利用逆压电效应将输入电信号转换为机械谐振,并且再利用压电效应将机械谐振转换为电信号输出。薄膜体声波谐振器主 要利用压电薄膜的纵向压电系数产生压电效应,所以其主要工作模式为厚度方向上的纵波模式,即体声波谐振器的声波主要在谐振器的薄膜体内,而且主要的震动方向在纵向。但是由于存在边界,在边界处会存在不垂直于压电膜层的兰姆波,这时横向的兰姆波会从压电膜层的横向漏出,导致声学损失,从而使得谐振器的Q值减小。现有技术中还存在进一步降低横向的兰姆波泄露的需要。In addition, the structural main body of the thin film bulk acoustic wave resonator is a "sandwich" structure composed of electrode-piezoelectric film-electrode, that is, a piezoelectric material is sandwiched between two metal electrode layers. By inputting a sinusoidal signal between two electrodes, the FBAR uses the inverse piezoelectric effect to convert the input electrical signal into mechanical resonance, and then uses the piezoelectric effect to convert the mechanical resonance into an electrical signal output. The film bulk acoustic wave resonator mainly uses the longitudinal piezoelectric coefficient of the piezoelectric film to generate the piezoelectric effect, so its main working mode is the longitudinal wave mode in the thickness direction, that is, the sound wave of the bulk acoustic wave resonator is mainly in the film body of the resonator, and the main working mode is the longitudinal wave mode in the thickness direction. The vibration direction is in the vertical direction. However, due to the existence of a boundary, there will be Lamb waves that are not perpendicular to the piezoelectric film layer at the boundary. At this time, the lateral Lamb wave will leak out from the lateral direction of the piezoelectric film layer, resulting in acoustic loss, thus making the Q value of the resonator. decrease. There is also a need in the prior art to further reduce lateral Lamb wave leakage.
发明内容SUMMARY OF THE INVENTION
为缓解或解决现有技术中的上述问题的至少一个方面,提出本公开。The present disclosure is made to alleviate or solve at least one aspect of the above-mentioned problems in the prior art.
根据本公开的实施例的一个方面,提出了一种体声波谐振器,包括:According to an aspect of the embodiments of the present disclosure, a bulk acoustic wave resonator is proposed, comprising:
基底;base;
声学镜;acoustic mirror;
底电极;bottom electrode;
压电层;和piezoelectric layer; and
顶电极,top electrode,
其中:in:
顶电极、压电层、底电极在谐振器的厚度方向上的重叠区域构成谐振器的有效区域;The overlapping area of the top electrode, the piezoelectric layer and the bottom electrode in the thickness direction of the resonator constitutes an effective area of the resonator;
所述压电层包括第一层和第二层,第一层与第二层之间设置有声阻层,第二层在第一层的上方,所述声阻层的内边缘在水平方向上处于声学镜边界的内侧,所述声阻层的声阻不同于所述压电层的声阻;The piezoelectric layer includes a first layer and a second layer, an acoustic resistance layer is arranged between the first layer and the second layer, the second layer is above the first layer, and the inner edge of the acoustic resistance layer is in the horizontal direction On the inner side of the boundary of the acoustic mirror, the acoustic resistance of the acoustic resistance layer is different from the acoustic resistance of the piezoelectric layer;
所述谐振器还包括将所述声阻层与外部相通的通道或开口。The resonator also includes a channel or opening that communicates the acoustically resistive layer to the outside.
本公开的实施例还涉及一种体声波谐振器组件,包括至少两个体声波谐振器,其中至少一个体声波谐振器为上述的谐振器。Embodiments of the present disclosure also relate to a bulk acoustic wave resonator assembly, comprising at least two bulk acoustic wave resonators, wherein at least one bulk acoustic wave resonator is the above-mentioned resonator.
本公开的实施例也涉及一种制造体声波谐振器的方法,Embodiments of the present disclosure also relate to a method of manufacturing a bulk acoustic wave resonator,
所述谐振器包括基底、声学镜、底电极、压电层和顶电极,压电层包括第一层和第二层,第一层与第二层之间在顶电极的非电极连接端设置有空隙层,所述方法包括步骤:The resonator includes a substrate, an acoustic mirror, a bottom electrode, a piezoelectric layer and a top electrode, the piezoelectric layer includes a first layer and a second layer, and a non-electrode connection end of the top electrode is arranged between the first layer and the second layer A voided layer, the method comprising the steps of:
在第一层上形成和图形化牺牲层;和forming and patterning a sacrificial layer on the first layer; and
利用第二层覆盖第一层以及其上的牺牲层,Cover the first layer and the sacrificial layer thereon with the second layer,
其中:in:
所述方法还包括步骤:在顶电极的非电极连接端,以刻蚀的方式移除第二层以露出牺牲层的外端;和释放牺牲层,以形成所述空隙层;或者The method further includes the steps of: at the non-electrode connection end of the top electrode, removing the second layer by etching to expose the outer end of the sacrificial layer; and releasing the sacrificial layer to form the void layer; or
所述方法还包括步骤:在顶电极的非电极连接端的外侧,在第二层形成在第二层的厚度方向上贯穿第二层的释放通道;和经由所述释放通道释放牺牲层,以形成所述空隙层。The method further includes the steps of: forming a release channel in the second layer penetrating the second layer in the thickness direction of the second layer outside the non-electrode connection end of the top electrode; and releasing the sacrificial layer via the release channel to form the void layer.
本公开的实施例还涉及一种滤波器,包括上述的谐振器或组件。Embodiments of the present disclosure also relate to a filter comprising the resonator or assembly described above.
本公开的实施例也涉及一种电子设备,包括上述的滤波器或者上述的谐振器或上述的组件。Embodiments of the present disclosure also relate to an electronic device comprising the above-mentioned filter or the above-mentioned resonator or the above-mentioned assembly.
附图说明Description of drawings
以下描述与附图可以更好地帮助理解本公开所公布的各种实施例中的这些和其他特点、优点,图中相同的附图标记始终表示相同的部件,其中:These and other features and advantages of the various embodiments disclosed in this disclosure may be better understood by the following description and accompanying drawings, wherein like reference numerals refer to like parts throughout, wherein:
图1为根据本公开的一个示例性实施例的体声波谐振器的俯视示意图;1 is a schematic top view of a bulk acoustic wave resonator according to an exemplary embodiment of the present disclosure;
图2-4为根据本公开的不同示例性实施例的沿图1中的MOM’线的体声波谐振器的截面示意图;2-4 are schematic cross-sectional views of a bulk acoustic wave resonator along the MOM' line in FIG. 1 according to various exemplary embodiments of the present disclosure;
图5示例性示出了AW结构的宽度与机电耦合系数之间的关系图;FIG. 5 exemplarily shows the relationship between the width of the AW structure and the electromechanical coupling coefficient;
图6示例性分别示出了在AW结构设置在压电层中的情况下与在AW设置在顶电极与压电层之间的情况下,AW结构的宽度与体声波谐振器的并联谐振阻抗之间的关系图;FIG. 6 exemplarily shows the width of the AW structure and the parallel resonance impedance of the bulk acoustic wave resonator in the case where the AW structure is provided in the piezoelectric layer and in the case where the AW structure is provided between the top electrode and the piezoelectric layer, respectively The relationship diagram between;
图7示例性分别示出了在AW结构设置在压电层中且上压电层被移除的情况下与在AW设置在压电层中且上压电层没有被移除的情况下,AW结构的宽度与体声波谐振器的并联谐振阻抗之间的关系图;FIG. 7 exemplarily shows the case where the AW structure is provided in the piezoelectric layer and the upper piezoelectric layer is removed and the case where the AW is provided in the piezoelectric layer and the upper piezoelectric layer is not removed, respectively, The relationship between the width of the AW structure and the parallel resonance impedance of the bulk acoustic wave resonator;
图8-10为根据本公开的不同示例性实施例的沿图1中的MOM’线的体声波谐振器的截面示意图;8-10 are schematic cross-sectional views of a bulk acoustic wave resonator along the MOM' line in FIG. 1 according to various exemplary embodiments of the present disclosure;
图11为根据本公开的另一个示例性实施例的体声波谐振器的俯视示意图;11 is a schematic top view of a bulk acoustic wave resonator according to another exemplary embodiment of the present disclosure;
图12为根据本公开的一个示例性实施例的沿图11中的MOM’线的体声波谐振器的截面示意图;12 is a schematic cross-sectional view of a bulk acoustic wave resonator along the MOM' line in FIG. 11 according to an exemplary embodiment of the present disclosure;
图13为根据本公开的再一个示例性实施例的体声波谐振器的俯视示 意图;13 is a schematic top view of a bulk acoustic wave resonator according to yet another exemplary embodiment of the present disclosure;
图14为根据本公开的还一个示例性实施例的体声波谐振器的俯视示意图;14 is a schematic top view of a bulk acoustic wave resonator according to still another exemplary embodiment of the present disclosure;
图15为根据本公开的一个示例性实施例的沿图14中的MOM’线的体声波谐振器的截面示意图;15 is a schematic cross-sectional view of a bulk acoustic wave resonator along the MOM' line in FIG. 14 according to an exemplary embodiment of the present disclosure;
图16A-16G示例性示出了图15中的体声波谐振器的制作过程的截面示意图;16A-16G exemplarily show cross-sectional schematic diagrams of the manufacturing process of the bulk acoustic wave resonator in FIG. 15;
图17为示例性示出声阻层设置在压电层的中间且上侧的压电层没有被移除的示意性截面图。17 is a schematic cross-sectional view exemplarily showing that the acoustic resistance layer is provided in the middle of the piezoelectric layer and the piezoelectric layer on the upper side is not removed.
具体实施方式detailed description
下面通过实施例,并结合附图,对本公开的技术方案作进一步具体的说明。下述参照附图对本公开实施方式的说明旨在对本公开的总体公开构思进行解释,而不应当理解为对本公开的一种限制。The technical solutions of the present disclosure will be further specifically described below through the embodiments and in conjunction with the accompanying drawings. The following description of the embodiments of the present disclosure with reference to the accompanying drawings is intended to explain the general disclosed concept of the present disclosure, and should not be construed as a limitation of the present disclosure.
首先,本公开的附图中的附图标记说明如下:First of all, the reference numerals in the drawings of the present disclosure are explained as follows:
10:基底,可选材料为单晶硅、氮化镓、砷化镓、蓝宝石、石英、碳化硅、金刚石等。10: Substrate, optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
20:声学镜,可为空腔,也可采用布拉格反射层及其他等效形式。本公开的实施例中采用的是空腔的形式。20: Acoustic mirror, which can be a cavity, or a Bragg reflector and other equivalent forms. The embodiment of the present disclosure adopts the form of a cavity.
20A:释放通道,将释放孔90与声学镜空腔相通。20A: a release channel, which communicates the release hole 90 with the cavity of the acoustic mirror.
21:牺牲层,在声学镜为空腔形式的情况下,在制备谐振器的过程中设置在该空腔中,在之后的工艺中被释放以形成声学镜空腔,牺牲层21可选二氧化硅、掺杂二氧化硅、多晶硅、非晶硅等材料。21: Sacrificial layer, when the acoustic mirror is in the form of a cavity, it is set in the cavity during the process of preparing the resonator, and is released in the subsequent process to form the cavity of the acoustic mirror. The sacrificial layer 21 can be optionally two. Silicon oxide, doped silicon dioxide, polysilicon, amorphous silicon and other materials.
30:底电极(包括底电极引脚),材料可选钼、钌、金、铝、镁、钨、铜,钛、铱、锇、铬或以上金属的复合或其合金等。30: Bottom electrode (including bottom electrode pins), the material can be selected from molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or a composite of the above metals or their alloys.
41:第一压电层,可以为单晶压电材料,可选的,如:单晶氮化铝、单晶氮化镓、单晶铌酸锂、单晶锆钛酸铅(PZT)、单晶铌酸钾、单晶石英薄膜、或者单晶钽酸锂等材料,也可以为多晶压电材料(与单晶相对应,非单晶材料),可选的,如多晶氮化铝、氧化锌、PZT等,还可是包含上述材料的一定原子比的稀土元素掺杂材料,例如可以是掺杂氮化铝,掺杂氮化铝至少含一种稀土元素,如钪(Sc)、钇(Y)、镁(Mg)、钛(Ti)、镧 (La)、铈(Ce)、镨(Pr)、钕(Nd)、钷(Pm)、钐(Sm)、铕(Eu)、钆(Gd)、铽(Tb)、镝(Dy)、钬(Ho)、铒(Er)、铥(Tm)、镱(Yb)、镥(Lu)等。41: The first piezoelectric layer, which can be a single crystal piezoelectric material, optional, such as: single crystal aluminum nitride, single crystal gallium nitride, single crystal lithium niobate, single crystal lead zirconate titanate (PZT), Materials such as single crystal potassium niobate, single crystal quartz film, or single crystal lithium tantalate can also be polycrystalline piezoelectric materials (corresponding to single crystals, non-single crystal materials), optional, such as polycrystalline nitridation Aluminum, zinc oxide, PZT, etc., can also be a rare earth element doped material containing a certain atomic ratio of the above materials, for example, can be doped aluminum nitride, and doped aluminum nitride contains at least one rare earth element, such as scandium (Sc) , Yttrium (Y), Magnesium (Mg), Titanium (Ti), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu) , gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), etc.
42:第二压电层,其材料可以为单晶压电材料,可选的,如:单晶氮化铝、单晶氮化镓、单晶铌酸锂、单晶锆钛酸铅(PZT)、单晶铌酸钾、单晶石英薄膜、或者单晶钽酸锂等材料,也可以为多晶压电材料(与单晶相对应,非单晶材料),可选的,如多晶氮化铝、氧化锌、PZT等,还可是包含上述材料的一定原子比的稀土元素掺杂材料,例如可以是掺杂氮化铝,掺杂氮化铝至少含一种稀土元素,如钪(Sc)、钇(Y)、镁(Mg)、钛(Ti)、镧(La)、铈(Ce)、镨(Pr)、钕(Nd)、钷(Pm)、钐(Sm)、铕(Eu)、钆(Gd)、铽(Tb)、镝(Dy)、钬(Ho)、铒(Er)、铥(Tm)、镱(Yb)、镥(Lu)等。42: The second piezoelectric layer, the material of which can be a single crystal piezoelectric material, optional, such as: single crystal aluminum nitride, single crystal gallium nitride, single crystal lithium niobate, single crystal lead zirconate titanate (PZT ), single crystal potassium niobate, single crystal quartz film, or single crystal lithium tantalate, etc., or polycrystalline piezoelectric material (corresponding to single crystal, non-single crystal material), optional, such as polycrystalline Aluminum nitride, zinc oxide, PZT, etc., can also be a rare earth element doped material containing a certain atomic ratio of the above materials, for example, can be doped aluminum nitride, and doped aluminum nitride contains at least one rare earth element, such as scandium ( Sc), Yttrium (Y), Magnesium (Mg), Titanium (Ti), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium ( Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) and the like.
50:顶电极(包括顶电极引脚),材料可选钼、钌、金、铝、镁、钨、铜,钛、铱、锇、铬或以上金属的复合或其合金等。50: Top electrode (including top electrode pins), the material can be selected from molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or a composite of the above metals or their alloys.
70:钝化层或工艺层,其可以是氮化铝、氮化硅或二氧化硅等。70: Passivation layer or process layer, which can be aluminum nitride, silicon nitride or silicon dioxide, etc.
80:声阻层,其声阻不同于第一压电层41和第二压电层42的声阻,在本公开图示的实施例中,为空气隙(即AW)的形式,但是也可以为固态介质层的形式,例如二氧化硅或其掺杂物,或氮化硅或其掺杂物。如能够理解的,声阻层的声阻也可以大于第一压电层和第二压电层的声阻。80: Acoustic resistance layer, the acoustic resistance of which is different from the acoustic resistance of the first piezoelectric layer 41 and the second piezoelectric layer 42, in the embodiment illustrated in the present disclosure, in the form of an air gap (ie AW), but also It may be in the form of a solid dielectric layer, such as silicon dioxide or its dopants, or silicon nitride or its dopants. As can be appreciated, the acoustic resistance of the acoustic resistance layer may also be greater than the acoustic resistance of the first piezoelectric layer and the second piezoelectric layer.
81:牺牲层,在制备谐振器的过程中设置在该空气隙对应的位置,在后续的工艺中被释放以形成该空气隙,牺牲层81可选二氧化硅、掺杂二氧化硅、多晶硅、非晶硅等材料。81: A sacrificial layer, which is set at the position corresponding to the air gap during the process of preparing the resonator, and is released in the subsequent process to form the air gap. The sacrificial layer 81 can be selected from silicon dioxide, doped silicon dioxide, and polysilicon , amorphous silicon and other materials.
90:释放孔,用于释放声学镜空腔内的牺牲层材料。90: a release hole for releasing the sacrificial layer material in the cavity of the acoustic mirror.
91:释放通道,用于释放空隙层内的牺牲层材料。91: a release channel for releasing the sacrificial layer material in the void layer.
图1为根据本公开的一个示例性实施例的体声波谐振器的俯视示意图,图2为根据本公开的一个示例性实施例的沿图1中的MOM’线的体声波谐振器的截面示意图。1 is a schematic top view of a bulk acoustic wave resonator according to an exemplary embodiment of the present disclosure, and FIG. 2 is a schematic cross-sectional view of the bulk acoustic wave resonator along the MOM' line in FIG. 1 according to an exemplary embodiment of the present disclosure .
在图1-2中,体声波谐振器包括基底10,设置在基底10中的声学镜空腔20,底电极30,顶电极50和压电层,压电层包括第一压电层41和第二压电层42。在第一压电层与第二压电层之间设置有声阻层80,其为 空气隙的形式。图1-2中还示出了钝化层70。1-2, the BAW resonator includes a substrate 10, an acoustic mirror cavity 20 disposed in the substrate 10, a bottom electrode 30, a top electrode 50, and a piezoelectric layer including a first piezoelectric layer 41 and a piezoelectric layer. The second piezoelectric layer 42 . An acoustic resistance layer 80 in the form of an air gap is provided between the first piezoelectric layer and the second piezoelectric layer. Passivation layer 70 is also shown in FIGS. 1-2.
图7示例性分别示出了在AW结构设置在压电层中且上压电层被移除的情况下(在图7中,对应于实线,实施例则例如参见图2-4,8-10)与在AW设置在压电层中且上压电层没有被移除的情况下(在图7中,对应于虚线,实施例则例如参见图17),AW结构的宽度与体声波谐振器的并联谐振阻抗之间的关系图。FIG. 7 exemplarily shows the case in which the AW structure is provided in the piezoelectric layer and the upper piezoelectric layer is removed (in FIG. 7 , corresponding to the solid line, for example, see FIGS. 2-4 , 8 -10) and in the case where the AW is arranged in the piezoelectric layer and the upper piezoelectric layer is not removed (in Fig. 7, corresponding to the dotted line, for example, see Fig. 17 for an embodiment), the width of the AW structure is related to the bulk acoustic wave Graph of the relationship between the parallel resonant impedances of the resonators.
由图7可知,在绝大多数情况下,将AW结构放置在两层压电层之间并且将第二压电层42沿顶电极的非电极连接端的边界进行刻蚀或移除的谐振器性能明显优于同等条件下第二压电层不刻蚀或移除时的器件性能。As can be seen from FIG. 7, in most cases, the AW structure is placed between two piezoelectric layers and the second piezoelectric layer 42 is etched or removed along the boundary of the non-electrode connection end of the top electrode. The performance is significantly better than the device performance when the second piezoelectric layer is not etched or removed under the same conditions.
在图2中,第一压电层41的处于AW结构80外侧的部分未被刻蚀,即在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分的厚度等于处于声阻层的外边缘的内侧的部分的厚度。对应于图2所示的结构,在进行顶电极的刻蚀时,将第二压电层42一并进行刻蚀,使得第二压电层42、顶电极和钝化层形成同一刻蚀面。AW结构80下方的第一压电层41在谐振器的非有效区并不进行刻蚀,而对第二压电层42进行刻蚀,因此在谐振器的顶电极的非电极连接端,谐振器的非有效区无第二压电层。此种情况下,在非电极连接端的AW结构80、第二压电层41、顶电极的非电极连接端和钝化层70形成同一刻蚀面。需要指出的是,并不要求钝化层70、顶电极的非电极连接端的端面齐平。In FIG. 2, the portion of the first piezoelectric layer 41 outside the AW structure 80 is not etched, that is, at the non-electrode connection end of the top electrode, the portion of the first layer outside the outer edge of the acoustic resistance layer is not etched. The thickness is equal to the thickness of the portion located inside the outer edge of the acoustically resistive layer. Corresponding to the structure shown in FIG. 2, when the top electrode is etched, the second piezoelectric layer 42 is etched together, so that the second piezoelectric layer 42, the top electrode and the passivation layer form the same etching surface. . The first piezoelectric layer 41 under the AW structure 80 is not etched in the inactive area of the resonator, but the second piezoelectric layer 42 is etched, so at the non-electrode connection end of the top electrode of the resonator, resonance There is no second piezoelectric layer in the inactive region of the device. In this case, the AW structure 80 at the non-electrode connection end, the second piezoelectric layer 41 , the non-electrode connection end of the top electrode, and the passivation layer 70 form the same etching surface. It should be noted that it is not required that the end surfaces of the passivation layer 70 and the non-electrode connection end of the top electrode are flush.
图3为根据本公开的一个示例性实施例的类似于沿图1中的MOM’线的体声波谐振器的截面示意图,图3与图2的区别在于,在图3中,第一压电层41在AW结构80的外侧的部分被部分刻蚀,而在图2中,第一压电层41的对应部分未被刻蚀。即,在图3中,在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分的厚度小于处于声阻层的外边缘的内侧的部分的厚度。在实际的制备过程中,在刻蚀第二压电层42时因为需要一定的过刻量,并且因为第一压电层41和第二压电层42的材料刻蚀选择比较小或者因为相同材料而具有相同的刻蚀速率,在刻蚀第二压电层42的过程可能会对第一压电层41有一定的刻蚀,从而得到如图3所示的结构。在此种情况下,第一压电层41被部分刻蚀。3 is a schematic cross-sectional view of a bulk acoustic wave resonator similar to the MOM' line in FIG. 1 according to an exemplary embodiment of the present disclosure. The difference between FIG. 3 and FIG. 2 is that, in FIG. 3 , the first piezoelectric The portion of the layer 41 on the outside of the AW structure 80 is partially etched, while in FIG. 2 the corresponding portion of the first piezoelectric layer 41 is not etched. That is, in FIG. 3 , at the non-electrode connection end of the top electrode, the thickness of the portion of the first layer outside the outer edge of the acoustic resistance layer is smaller than the thickness of the portion inside the outer edge of the acoustic resistance layer. In the actual preparation process, when etching the second piezoelectric layer 42, a certain amount of overetching is required, and because the etching selection of the materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 is relatively small or because the same Although the materials have the same etching rate, the first piezoelectric layer 41 may be etched to a certain extent in the process of etching the second piezoelectric layer 42 , thereby obtaining the structure shown in FIG. 3 . In this case, the first piezoelectric layer 41 is partially etched.
图4为根据本公开的一个示例性实施例的类似于沿图1中的MOM’线 的体声波谐振器的截面示意图,图4与图2的区别在于,在图4中,第一压电层41处于AW结构80外侧的部分均被刻蚀掉,而在图2中,第一压电层的对应部分未被刻蚀。即在图4中,在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分被移除。即在刻蚀第二压电层42的过程中,可以将第一压电层41一起刻蚀掉,从而得到图4的结构。4 is a schematic cross-sectional view of a bulk acoustic wave resonator similar to the MOM' line in FIG. 1 according to an exemplary embodiment of the present disclosure. The difference between FIG. 4 and FIG. 2 is that, in FIG. 4 , the first piezoelectric The portions of the layer 41 outside the AW structure 80 are all etched away, while in FIG. 2 , the corresponding portions of the first piezoelectric layer are not etched. That is, in FIG. 4, at the non-electrode connection end of the top electrode, the portion of the first layer that is outside the outer edge of the acoustic resistance layer is removed. That is, in the process of etching the second piezoelectric layer 42 , the first piezoelectric layer 41 may be etched away together, thereby obtaining the structure of FIG. 4 .
在图2-4中,被刻蚀或移除后,第二压电层42的端面为竖直端面,且与顶电极的非电极连接端的端面齐平,但是本公开不限于此。In FIGS. 2-4 , after being etched or removed, the end face of the second piezoelectric layer 42 is a vertical end face and is flush with the end face of the non-electrode connection end of the top electrode, but the present disclosure is not limited thereto.
图8-10为根据本公开的不同示例性实施例的沿图1中的MOM’线的体声波谐振器的截面示意图。在图8中,虽然第二压电层42的端面仍为竖直端面,但是顶电极的非电极连接端的端面在水平方向上处于第二压电层42的端面的外侧,且两个端面在水平方向上存在一个距离△d。在图9中,虽然第二压电层42的端面仍为竖直端面,但是顶电极的非电极连接端的端面在水平方向上处于第二压电层42的端面的内侧,且两个端面在水平方向上存在一个距离△d。在图10中,第二压电层42的端面为倾斜向外的斜面,顶电极的非电极连接端的端面在水平方向上处于第二压电层42的端面的内侧,且两个端面在水平方向上存在一个距离△d,在图10中,第二压电层42的斜面的斜角为α。在本公开的实施例中,Δd在0.25-5μm之间。如本领域技术人员能够理解的,上述倾斜向外的斜面也可以为倾斜向内的斜面。在本公开的实施例中,斜面的斜角α在10-80度的范围内。8-10 are schematic cross-sectional views of a bulk acoustic wave resonator along the MOM' line in FIG. 1 according to various exemplary embodiments of the present disclosure. In FIG. 8 , although the end face of the second piezoelectric layer 42 is still a vertical end face, the end face of the non-electrode connection end of the top electrode is located outside the end face of the second piezoelectric layer 42 in the horizontal direction, and the two end faces are in the horizontal direction. There is a distance Δd in the horizontal direction. In FIG. 9 , although the end face of the second piezoelectric layer 42 is still a vertical end face, the end face of the non-electrode connection end of the top electrode is located inside the end face of the second piezoelectric layer 42 in the horizontal direction, and the two end faces are in the horizontal direction. There is a distance Δd in the horizontal direction. In FIG. 10 , the end face of the second piezoelectric layer 42 is inclined outward, and the end face of the non-electrode connection end of the top electrode is located inside the end face of the second piezoelectric layer 42 in the horizontal direction, and the two end faces are horizontal There is a distance Δd in the direction, and in FIG. 10 , the inclination angle of the slope of the second piezoelectric layer 42 is α. In embodiments of the present disclosure, Δd is between 0.25-5 μm. As can be understood by those skilled in the art, the above-mentioned outwardly inclined inclined surface may also be an inwardly inclined inclined surface. In the embodiment of the present disclosure, the inclination angle α of the inclined plane is in the range of 10-80 degrees.
在图2-4和8-10的实施例中,第二压电层42在顶电极的非电极连接端被移除一部分(例如通过刻蚀切割),从而直接露出AW结构或者声阻层或者空气隙。如此,切割后形成的空气反射面可以防止能量或横向的兰姆波经由在AW结构外侧的第二压电层泄露,如图7所示,从而提高谐振器的性能。更具体的,由于在第二压电层42对应的非电极连接端处形成有空气反射面(阻抗不匹配界面),使得横向的兰姆波在该空气反射面处形成强反射,从而减少横向的兰姆波泄露,提高谐振器的Q值。如果只是设置AW结构而不对第二压电层42进行刻蚀,则第二压电层42是一个连续界面,横向的兰姆波可以通过第二压电层42泄露到有效区以外,从而降低了谐振器的Q值。In the embodiments of FIGS. 2-4 and 8-10, a portion of the second piezoelectric layer 42 is removed (eg, cut by etching) at the non-electrode connection end of the top electrode, thereby directly exposing the AW structure or the acoustic resistance layer or air gap. In this way, the air reflective surface formed after cutting can prevent energy or lateral Lamb waves from leaking through the second piezoelectric layer outside the AW structure, as shown in FIG. 7 , thereby improving the performance of the resonator. More specifically, since an air reflection surface (impedance mismatch interface) is formed at the non-electrode connection end corresponding to the second piezoelectric layer 42, the transverse Lamb wave forms a strong reflection at the air reflection surface, thereby reducing the lateral The Lamb wave leakage increases the Q of the resonator. If only the AW structure is provided and the second piezoelectric layer 42 is not etched, the second piezoelectric layer 42 is a continuous interface, and the lateral Lamb waves can leak out of the effective area through the second piezoelectric layer 42, thereby reducing the the Q value of the resonator.
此外,第二压电层42的刻蚀界面和顶电极的非电极连接端的端面不在同一界面时可以相对二者在同一界面时反射更多的横向的兰姆波。以图8为例,第二压电层42可以对横向波长的1/4波长为L1的横波进行有效反射,而顶电极可以对横向波长的1/4波长为L1+Δd的横波进行有效反射。然而当第二压电层42的刻蚀界面和顶电极的非电极连接端的端面平齐时,则此结构只会对横向波长的1/4波长为L1的横波进行有效反射。另外,如图10所示,当第二压电层42端面为斜面时,第二压电层存在两个距离,L2为AW结构内边缘到上表面外边缘的距离,L3为AW结构内边缘到下表面外边缘的距离。因此第二压电层42可以对横向波长的1/4波长为L2到L3之间的横波进行有效反射,因此可以反射的波更多,因此Q值会更高。In addition, when the etched interface of the second piezoelectric layer 42 and the end face of the non-electrode connection end of the top electrode are not at the same interface, more lateral Lamb waves can be reflected than when the two are at the same interface. Taking FIG. 8 as an example, the second piezoelectric layer 42 can effectively reflect the transverse wave whose 1/4 of the transverse wavelength is L1, and the top electrode can effectively reflect the transverse wave whose 1/4 of the transverse wavelength is L1+Δd. . However, when the etched interface of the second piezoelectric layer 42 is flush with the end face of the non-electrode connecting end of the top electrode, the structure can only effectively reflect the transverse wave with a wavelength L1 of 1/4 of the transverse wavelength. In addition, as shown in FIG. 10 , when the end face of the second piezoelectric layer 42 is inclined, there are two distances between the second piezoelectric layer, L2 is the distance from the inner edge of the AW structure to the outer edge of the upper surface, and L3 is the inner edge of the AW structure Distance to the outer edge of the lower surface. Therefore, the second piezoelectric layer 42 can effectively reflect the transverse wave whose wavelength is between L2 and L3, which is 1/4 of the transverse wavelength. Therefore, more waves can be reflected, so the Q value will be higher.
在图2-4和8-10所示的实施例中,第二压电层42在顶电极的非电极连接端被移除,以露出AW结构或者声阻层或者空气隙,但是本公开不限于此。In the embodiments shown in FIGS. 2-4 and 8-10, the second piezoelectric layer 42 is removed at the non-electrode connection end of the top electrode to expose the AW structure or the acoustic resistance layer or the air gap, but this disclosure does not limited to this.
图11为根据本公开的另一个示例性实施例的体声波谐振器的俯视示意图,图12为根据本公开的一个示例性实施例的沿图11中的MOM’线的体声波谐振器的截面示意图。在图11-12中,第二压电层42在顶电极的非电极连接端的外侧设置有通道91与AW结构或空隙层80相通。11 is a schematic top view of a bulk acoustic wave resonator according to another exemplary embodiment of the present disclosure, and FIG. 12 is a cross-section of the bulk acoustic wave resonator along the MOM' line in FIG. 11 according to an exemplary embodiment of the present disclosure Schematic. In FIGS. 11-12 , the second piezoelectric layer 42 is provided with a channel 91 on the outside of the non-electrode connection end of the top electrode to communicate with the AW structure or void layer 80 .
如图11所示,空隙层80至少在顶电极的非电极连接端沿有效区域周向方向连续设置,相应的,通道91为沿有效区域周向设置的连续通道。As shown in FIG. 11 , the void layer 80 is continuously arranged along the circumferential direction of the effective area at least at the non-electrode connection end of the top electrode, and correspondingly, the channel 91 is a continuous channel arranged along the circumferential direction of the effective area.
通过设置通道91,可以用于释放空隙层80内的牺牲层材料从而形成空隙层,此时通道91为释放通道,此外,还可以对第二压电层42在顶电极的非电极连接端进行切断或部分切断处理,这同样可以防止或减少谐振器工作过程中的能量泄露。防止或减少能量泄露的效果可以例如参见图7。By arranging the channel 91, it can be used to release the sacrificial layer material in the void layer 80 to form the void layer. At this time, the channel 91 is the release channel. Cut-off or partial cut-off processing, which can also prevent or reduce energy leakage during the operation of the resonator. The effect of preventing or reducing energy leakage can be seen, for example, in FIG. 7 .
通道91也可以仅仅起到防止或减少谐振器工作过程中的能量泄露的作用。此时,声阻层80并非是空隙层的形式,而是固态介质层的形式。The channel 91 may also only serve to prevent or reduce energy leakage during the operation of the resonator. At this time, the acoustic resistance layer 80 is not in the form of a void layer, but in the form of a solid medium layer.
在图2-4和8-12所示的图中,声阻层80为连续布置的形式,但是本公开不限于此。图13为根据本公开的再一个示例性实施例的体声波谐振器的俯视示意图,沿图13中的MOM’线截得的截面图类似于图12。在图13中,可以看到,声阻层80包括多个声阻部,所述多个声阻部沿谐振 器的有效区域在周向方向上间隔开布置。相应的,通道91可以是包括分别与所述多个声阻部相通的多个孔(此时对应于部分切断处理的情形),也可以是沿有效区域的周向方向设置且与各个声阻部相通的连续通道(此时对应于切断的情形)。In the diagrams shown in FIGS. 2-4 and 8-12, the acoustic resistive layers 80 are in the form of a continuous arrangement, but the present disclosure is not limited thereto. 13 is a schematic top view of a bulk acoustic wave resonator according to still another exemplary embodiment of the present disclosure, and a cross-sectional view taken along the MOM' line in FIG. 13 is similar to FIG. 12 . In Figure 13, it can be seen that the acoustically resistive layer 80 includes a plurality of acoustically resistive portions that are spaced apart in the circumferential direction along the effective area of the resonator. Correspondingly, the channel 91 may include a plurality of holes communicating with the plurality of acoustic resistance parts respectively (corresponding to the case of partial cutting process), or may be arranged along the circumferential direction of the effective area and communicate with each acoustic resistance part. A continuous channel that is connected to each other (corresponding to a cut-off situation at this time).
图6示例性分别示出了在AW结构设置在压电层中的情况下与在AW设置在顶电极与压电层之间的情况下,AW结构的宽度与体声波谐振器的并联谐振阻抗之间的关系图。在图6中,横坐标为AW结构的宽度(单位为μm),纵坐标为谐振器的并联谐振阻抗Rp(单位为欧姆)。在图6中,虚线表示AW结构设置在顶电极与压电层之间的情况,而实线表示AW结构设置在压电层中的情况。如图6所示,AW结构在压电层中时并联谐振阻抗的值明显高于AW结构在压电层与顶电极之间时并联谐振阻抗的值。可见,通过在第一压电层41与第二压电层42之间设置声阻层80,相对于将声阻层设置在顶电极与压电层之间,可以有效提升谐振器的性能。FIG. 6 exemplarily shows the width of the AW structure and the parallel resonance impedance of the bulk acoustic wave resonator in the case where the AW structure is provided in the piezoelectric layer and in the case where the AW structure is provided between the top electrode and the piezoelectric layer, respectively diagram of the relationship between them. In FIG. 6 , the abscissa is the width of the AW structure (unit is μm), and the ordinate is the parallel resonance impedance Rp of the resonator (unit is ohm). In FIG. 6 , the broken line represents the case where the AW structure is provided between the top electrode and the piezoelectric layer, and the solid line represents the case where the AW structure is provided in the piezoelectric layer. As shown in Fig. 6, the value of the parallel resonance impedance when the AW structure is in the piezoelectric layer is significantly higher than the value of the parallel resonance impedance when the AW structure is between the piezoelectric layer and the top electrode. It can be seen that by disposing the acoustic resistance layer 80 between the first piezoelectric layer 41 and the second piezoelectric layer 42 , the performance of the resonator can be effectively improved compared to disposing the acoustic resistance layer between the top electrode and the piezoelectric layer.
通过在第一压电层41与第二压电层42之间设置声阻层80,还可以调节谐振器的机电耦合系数的值。因为第一压电层41和第二压电层42分开制备,因此可以将这两压电层制备为不同的材料,进而可以自由调节谐振器的机电耦合系数。例如,第一压电层41为某种材料的压电层(例如氮化铝、氧化锌、锆钛酸铅、铌酸锂、石英、铌酸钾、钽酸锂中的一种材料的压电层),而第二压电层42则为与第一压电层41的材料相同的材料层中掺杂如上提及的至少一种稀土元素的掺杂层,在一个具体的实施例中,第一压电层41和第二压电层42都是基于氮化铝的压电材料,但是其中一层压电材料是没有任何掺杂的压电材料,另外一层是掺杂元素钪的压电材料。再如,第一压电层与第二压电层均为同一材料的掺杂层,只是第一压电层的掺杂浓度不同于第二压电层的掺杂浓度,在一个具体的实施例中,第一压电层41和第二压电层42都是基于掺杂了稀土元素钪的氮化铝的压电材料,只是第一压电层与第二压电层掺杂浓度不同。又如,第一压电层41的材料为氮化铝、氧化锌、锆钛酸铅、铌酸锂、石英、铌酸钾、钽酸锂中的一种材料,而第二压电层42为氮化铝、氧化锌、锆钛酸铅、铌酸锂、石英、铌酸钾、钽酸锂中不同于第一压电层材料的材料,在一个具体的实施例中,第一压电层为氮化铝,第二压电层为氧化锌。By providing the acoustic resistance layer 80 between the first piezoelectric layer 41 and the second piezoelectric layer 42, the value of the electromechanical coupling coefficient of the resonator can also be adjusted. Since the first piezoelectric layer 41 and the second piezoelectric layer 42 are prepared separately, the two piezoelectric layers can be prepared as different materials, so that the electromechanical coupling coefficient of the resonator can be freely adjusted. For example, the first piezoelectric layer 41 is a piezoelectric layer of a certain material (for example, a piezoelectric layer of a material selected from aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate). electric layer), and the second piezoelectric layer 42 is a doped layer doped with at least one rare earth element as mentioned above in the same material layer as the material of the first piezoelectric layer 41, in a specific embodiment , the first piezoelectric layer 41 and the second piezoelectric layer 42 are both piezoelectric materials based on aluminum nitride, but one layer of the piezoelectric material is a piezoelectric material without any doping, and the other layer is a doping element scandium piezoelectric material. For another example, the first piezoelectric layer and the second piezoelectric layer are both doped layers of the same material, but the doping concentration of the first piezoelectric layer is different from the doping concentration of the second piezoelectric layer. In the example, the first piezoelectric layer 41 and the second piezoelectric layer 42 are both piezoelectric materials based on aluminum nitride doped with rare earth element scandium, but the doping concentration of the first piezoelectric layer and the second piezoelectric layer is different. . For another example, the material of the first piezoelectric layer 41 is one of aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate, and the second piezoelectric layer 42 It is a material different from the material of the first piezoelectric layer among aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate. In a specific embodiment, the first piezoelectric The layer is aluminum nitride and the second piezoelectric layer is zinc oxide.
因此,在本公开中,通过在压电层中设置AW结构来提升谐振器性能的同时,还可以在AW结构上下两侧制备不同的压电层来实现对谐振器的机电耦合系数的自由设置。Therefore, in the present disclosure, while improving the performance of the resonator by arranging the AW structure in the piezoelectric layer, it is also possible to prepare different piezoelectric layers on the upper and lower sides of the AW structure to realize the free setting of the electromechanical coupling coefficient of the resonator .
上述设置不同掺杂的压电层41和42可以较大幅度的调节谐振器的机电耦合系数。比如在同一个Die内制作双工器,需要发射滤波器Tx中的谐振器的机电耦合系数和接收滤波器Rx中的谐振器的机电耦合系数有较大的差异(大于1%),但是在发射滤波器Tx或者接收滤波器Rx内部,需要不同的谐振器之间的机电耦合系数有较小差异(小于1%),此时,可以调整AW结构在谐振器的有效区域内的宽度,也就是通过调节图2中的AW结构的宽度L1来调节滤波器内部的谐振器的机电耦合系数。如图2所示,L1为在顶电极的非电极连接端的AW结构的宽度,其为顶电极的非电极连接端与AW结构的内边缘在水平方向上的距离。The above arrangement of the piezoelectric layers 41 and 42 with different doping can adjust the electromechanical coupling coefficient of the resonator to a relatively large extent. For example, to make a duplexer in the same Die, the electromechanical coupling coefficient of the resonator in the transmit filter Tx and the electromechanical coupling coefficient of the resonator in the receive filter Rx need to be quite different (greater than 1%), but in Inside the transmitting filter Tx or the receiving filter Rx, the electromechanical coupling coefficient between different resonators needs to have a small difference (less than 1%). At this time, the width of the AW structure in the effective area of the resonator can be adjusted, and The electromechanical coupling coefficient of the resonator inside the filter is adjusted by adjusting the width L1 of the AW structure in FIG. 2 . As shown in FIG. 2 , L1 is the width of the AW structure at the non-electrode connection end of the top electrode, which is the horizontal distance between the non-electrode connection end of the top electrode and the inner edge of the AW structure.
声阻层也可以进一步设置在顶电极的电极连接端,图14-15示出了这样的实施例。图14为根据本公开的还一个示例性实施例的体声波谐振器的俯视示意图,图15为根据本公开的一个示例性实施例的沿图14中的MOM’线的体声波谐振器的截面示意图。此时,可以调整AW结构在谐振器的有效区域内的宽度,也就是通过调节图15中的AW结构的宽度L1和L2来调节滤波器内部的谐振器的机电耦合系数。如图15所示,L1为在顶电极的非电极连接端的AW结构的宽度,其为顶电极的非电极连接端与AW结构的内边缘在水平方向上的距离;如图15所示,L2为在顶电极的电极连接端的AW结构的宽度,其为在顶电极的连接端,声学镜边界与AW结构的内边缘在水平方向上的距离。The acoustic resistance layer can also be further disposed on the electrode connection end of the top electrode, and FIGS. 14-15 show such an embodiment. 14 is a schematic top view of a bulk acoustic wave resonator according to still another exemplary embodiment of the present disclosure, and FIG. 15 is a cross-section of the bulk acoustic wave resonator along the MOM' line in FIG. 14 according to an exemplary embodiment of the present disclosure Schematic. At this time, the width of the AW structure in the effective area of the resonator can be adjusted, that is, the electromechanical coupling coefficient of the resonator inside the filter can be adjusted by adjusting the widths L1 and L2 of the AW structure in FIG. 15 . As shown in Figure 15, L1 is the width of the AW structure at the non-electrode connection end of the top electrode, which is the distance between the non-electrode connection end of the top electrode and the inner edge of the AW structure in the horizontal direction; as shown in Figure 15, L2 is the width of the AW structure at the electrode connection end of the top electrode, which is the distance in the horizontal direction between the boundary of the acoustic mirror and the inner edge of the AW structure at the connection end of the top electrode.
图5示例性示出了AW结构或空气隙的宽度与机电耦合系数之间的关系图。在图5中,横坐标为AW结构的宽度(单位为μm),纵坐标为机电耦合系数。图5表示当谐振器的有效区域的每个边的AW结构的宽度相同时,谐振器的AW结构的宽度对机电耦合系数的影响,如图5所示,机电耦合系数随AW宽度的增加而逐渐减小。可见,可以通过调节AW结构的宽度来调节谐振器的机电耦合系数。FIG. 5 exemplarily shows the relationship between the width of the AW structure or the air gap and the electromechanical coupling coefficient. In FIG. 5 , the abscissa is the width of the AW structure (unit is μm), and the ordinate is the electromechanical coupling coefficient. Figure 5 shows the influence of the width of the AW structure of the resonator on the electromechanical coupling coefficient when the width of the AW structure on each side of the effective area of the resonator is the same. As shown in Figure 5, the electromechanical coupling coefficient increases with the increase of the AW width. slowing shrieking. It can be seen that the electromechanical coupling coefficient of the resonator can be adjusted by adjusting the width of the AW structure.
对于有效区域为多边形的谐振器来说,每个边的AW结构的宽度可以是相同的,也可以是不同的。For a resonator whose active area is a polygon, the width of the AW structure on each side can be the same or different.
AW结构或者声阻层或者空气隙可以仅设置在顶电极的非电极连接端,如图2-4和8-13所示;也可以同时设置在顶电极的非电极连接端和电极连接端,如图14-15所示。The AW structure or the acoustic resistance layer or the air gap can only be arranged at the non-electrode connection end of the top electrode, as shown in Figures 2-4 and 8-13; it can also be arranged at the non-electrode connection end and the electrode connection end of the top electrode at the same time, As shown in Figure 14-15.
在本公开中,例如参见图2-4和8-13所示,AW结构或者声阻层或者空气隙设置在顶电极的非电极连接端,在谐振器的有效区域为多边形的情况下,可以包括仅在非电极连接端的一条边或多条边设置的情况,也可以包括在非电极连接端的所有边设置的情况。In the present disclosure, for example, as shown in FIGS. 2-4 and 8-13, an AW structure or an acoustic resistance layer or an air gap is provided at the non-electrode connection end of the top electrode. In the case where the effective area of the resonator is a polygon, it can be It includes the case where it is provided only on one side or a plurality of sides of the non-electrode connection end, and may also include the case where it is provided on all sides of the non-electrode connection end.
在本公开中,例如参见图14-15,AW结构或者声阻层或者空气隙设置在顶电极的电极连接端,在谐振器的有效区域为多边形的情况下,表示在顶电极的电极连接端所在的边设置有AW结构或者声阻层或者空气隙。In the present disclosure, see, for example, FIGS. 14-15 , an AW structure or an acoustic resistive layer or an air gap is provided at the electrode connection end of the top electrode, and in the case where the effective area of the resonator is a polygon, it is indicated at the electrode connection end of the top electrode The side where it is located is provided with an AW structure or an acoustic resistance layer or an air gap.
AW结构或者声阻层或者空气隙也可以围绕谐振器的整个有效区域设置。An AW structure or an acoustically resistive layer or an air gap can also be provided around the entire active area of the resonator.
在压电层的厚度一定时,当采用在AW结构的上下两侧采用同一种压电材料时,则无论AW结构设置在压电层内的任一位置,在同等条件下,谐振器的机电耦合系数是一个确定的值。但是当AW结构的上下两侧采用不同的压电层材料时,可以增加谐振器的机电耦合系数的设计自由度。例如,第一压电层41采用不掺杂氮化铝材料,第二压电层42采用掺杂钪的氮化铝材料。当压电层厚度固定时,压电层只采用不掺杂氮化铝压电层时其机电耦合系数为6%,而压电层只采用掺杂氮化铝时其机电耦合系数为10%。因此,在压电层厚度不变时,通过控制第一压电层41和第二压电层42的掺杂浓度使得谐振器的机电耦合系数在6%-10%之间自由变化。当两层压电层的厚度分别确定后,接着可以通过控制AW结构的宽度的变化,对滤波器内不同的谐振器的机电耦合系数进行微调,所以该方案能够最大限度的提升滤波器内的谐振器的机电耦合系数的设计自由度。When the thickness of the piezoelectric layer is constant, when the same piezoelectric material is used on the upper and lower sides of the AW structure, no matter where the AW structure is located in the piezoelectric layer, under the same conditions, the electromechanical properties of the resonator will The coupling coefficient is a definite value. However, when different piezoelectric layer materials are used on the upper and lower sides of the AW structure, the design freedom of the electromechanical coupling coefficient of the resonator can be increased. For example, the first piezoelectric layer 41 is made of undoped aluminum nitride material, and the second piezoelectric layer 42 is made of scandium-doped aluminum nitride material. When the thickness of the piezoelectric layer is fixed, the electromechanical coupling coefficient is 6% when the piezoelectric layer only uses undoped aluminum nitride piezoelectric layer, and the electromechanical coupling coefficient is 10% when the piezoelectric layer only uses doped aluminum nitride. . Therefore, when the thickness of the piezoelectric layer is constant, by controlling the doping concentration of the first piezoelectric layer 41 and the second piezoelectric layer 42, the electromechanical coupling coefficient of the resonator can be freely changed between 6% and 10%. After the thicknesses of the two piezoelectric layers are determined respectively, then the electromechanical coupling coefficients of different resonators in the filter can be fine-tuned by controlling the change of the width of the AW structure, so this scheme can maximize the increase in the efficiency of the filter. Design freedom for the electromechanical coupling coefficient of the resonator.
在图2中,第一压电层41与第二压电层42的材料可不同,在第一压电层41和第二压电层42的厚度固定时,对于谐振器的某一机电耦合系数,可以通过改变压电层的材料即可达到需要的机电耦合系数。在第一压电层41和第二压电层42的掺杂或者材料确定后,可以通过改变图2中的宽度L1对谐振器的机电耦合系数做进一步的调整。In FIG. 2, the materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 may be different. When the thicknesses of the first piezoelectric layer 41 and the second piezoelectric layer 42 are fixed, a certain electromechanical coupling of the resonator The required electromechanical coupling coefficient can be achieved by changing the material of the piezoelectric layer. After the doping or materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 are determined, the electromechanical coupling coefficient of the resonator can be further adjusted by changing the width L1 in FIG. 2 .
在图15中,第一压电层41与第二压电层42的材料可不同,在第一 压电层41和第二压电层42的厚度固定时,对于谐振器的某一机电耦合系数,可以通过改变压电层的材料即可达到需要的机电耦合系数。在第一压电层41和第二压电层42的掺杂或者材料确定后,可以通过改变图15中的宽度L1和L2对谐振器的机电耦合系数做进一步的调整。In FIG. 15, the materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 may be different, and when the thicknesses of the first piezoelectric layer 41 and the second piezoelectric layer 42 are fixed, a certain electromechanical coupling of the resonator The required electromechanical coupling coefficient can be achieved by changing the material of the piezoelectric layer. After the doping or materials of the first piezoelectric layer 41 and the second piezoelectric layer 42 are determined, the electromechanical coupling coefficient of the resonator can be further adjusted by changing the widths L1 and L2 in FIG. 15 .
图2中还示出了第一压电层41和第二压电层42的厚度,其分别为H1和H2。可以通过调节H1和H2的比例来调整两种不同压电材料的占比,从而调节谐振器的机电耦合系数。当H2和H1确定后,类似的,可以通过改变图2中的宽度L1和L2的宽度对谐振器的机电耦合系数做进一步的调整。Also shown in FIG. 2 are the thicknesses of the first piezoelectric layer 41 and the second piezoelectric layer 42, which are H1 and H2, respectively. The ratio of two different piezoelectric materials can be adjusted by adjusting the ratio of H1 and H2, thereby adjusting the electromechanical coupling coefficient of the resonator. When H2 and H1 are determined, similarly, the electromechanical coupling coefficient of the resonator can be further adjusted by changing the widths of the widths L1 and L2 in FIG. 2 .
如图2所示,AW结构夹在第一压电层41和第二压电层42的位置不是固定的。在本公开的一个实施例中,AW结构的下表面距离第一压电层41下表面的距离要大于
Figure PCTCN2021117485-appb-000001
AW结构的上表面距离第二压电层42的距离也要大于
Figure PCTCN2021117485-appb-000002
AW结构的厚度的范围是
Figure PCTCN2021117485-appb-000003
As shown in FIG. 2 , the position of the AW structure sandwiched between the first piezoelectric layer 41 and the second piezoelectric layer 42 is not fixed. In one embodiment of the present disclosure, the distance between the lower surface of the AW structure and the lower surface of the first piezoelectric layer 41 is greater than
Figure PCTCN2021117485-appb-000001
The distance between the upper surface of the AW structure and the second piezoelectric layer 42 is also greater than
Figure PCTCN2021117485-appb-000002
The range of thickness of the AW structure is
Figure PCTCN2021117485-appb-000003
下面参照图16A-16G示例性说明图14-15中的体声波谐振器的制作过程。需要指出的是,该制作过程也可以用于仅仅在顶电极的非电极连接端设置有声阻层的情况,此时,与下面的步骤不同的是,不再设置与该声阻层对应的牺牲层以及对该牺牲层的释放。The fabrication process of the bulk acoustic wave resonator in FIGS. 14-15 is exemplarily described below with reference to FIGS. 16A-16G . It should be pointed out that this manufacturing process can also be used in the case where the acoustic resistance layer is only provided on the non-electrode connection end of the top electrode. At this time, different from the following steps, the sacrifice corresponding to the acoustic resistance layer is no longer provided. layer and release of the sacrificial layer.
第一,如图16A所示,在基底10上表面形成作为声学镜20的空腔,接着在基底10的上表面设置牺牲材料,该牺牲材料填充该空腔,然后,通过CMP(化学机械研磨)工艺移除基底10上表面的牺牲材料并且使得空腔内的牺牲材料的上表面与基底10的上表面齐平从而形成牺牲层21。First, as shown in FIG. 16A , a cavity as the acoustic mirror 20 is formed on the upper surface of the substrate 10, and then a sacrificial material is provided on the upper surface of the substrate 10, the sacrificial material fills the cavity, and then, by CMP (Chemical Mechanical Polishing) ) process removes the sacrificial material on the upper surface of the substrate 10 and makes the upper surface of the sacrificial material in the cavity flush with the upper surface of the substrate 10 to form the sacrificial layer 21 .
第二,如图16B所示,在图16A的结构上沉积和图形化电极材料层,以形成底电极30。Second, as shown in FIG. 16B , a layer of electrode material is deposited and patterned on the structure of FIG. 16A to form bottom electrode 30 .
第三,如图16C所示,在图16B的结构上沉积第一压电层41,其例如可以为未掺杂压电层。Third, as shown in FIG. 16C , a first piezoelectric layer 41 is deposited on the structure of FIG. 16B , which may be, for example, an undoped piezoelectric layer.
第四,如图16D所示,在图16C的第一压电层41的上表面沉积和图形化牺牲材料,以形成牺牲层81。该牺牲层81在后期将被释放以用于形成AW结构80。如图16D所示,设置了用于顶电极的电极连接端和非连接端的牺牲层81。Fourth, as shown in FIG. 16D , a sacrificial material is deposited and patterned on the upper surface of the first piezoelectric layer 41 of FIG. 16C to form a sacrificial layer 81 . The sacrificial layer 81 will be released for forming the AW structure 80 at a later stage. As shown in FIG. 16D, a sacrificial layer 81 for electrode connection terminals and non-connection terminals of the top electrode is provided.
第五,如图16E所示,在图16D的结构的上表面沉积第二压电层42, 其例如可以为掺杂压电层。Fifth, as shown in FIG. 16E , a second piezoelectric layer 42 is deposited on the upper surface of the structure of FIG. 16D , which may be, for example, a doped piezoelectric layer.
第六,如图16F所示,在图16E的结构的上表面制备顶电极50和保护层或钝化层70。Sixth, as shown in FIG. 16F, a top electrode 50 and a protective layer or passivation layer 70 are prepared on the upper surface of the structure of FIG. 16E.
第七,在顶电极的非电极连接端,刻蚀钝化层70、顶电极50和第二压电层42以露出在顶电极的非电极连接端的牺牲层81。Seventh, at the non-electrode connection end of the top electrode, the passivation layer 70, the top electrode 50 and the second piezoelectric layer 42 are etched to expose the sacrificial layer 81 at the non-electrode connection end of the top electrode.
第八,释放牺牲层21和牺牲层81,以分别形成声学镜20和AW结构80,如图16G所示。Eighth, the sacrificial layer 21 and the sacrificial layer 81 are released to form the acoustic mirror 20 and the AW structure 80, respectively, as shown in FIG. 16G.
需要指出的是,以上的方法步骤仅仅是示例性的,本领域技术人员也可以对上述步骤进行调整和变更。例如,可以先制备和刻蚀第二压电层,在制备顶电极和钝化层。It should be pointed out that the above method steps are only exemplary, and those skilled in the art can also adjust and change the above steps. For example, the second piezoelectric layer can be prepared and etched first, followed by the preparation of the top electrode and passivation layer.
需要指出的是,在本公开中,各个数值范围,除了明确指出不包含端点值之外,除了可以为端点值,还可以为各个数值范围的中值,这些均在本公开的保护范围之内。It should be pointed out that, in the present disclosure, each numerical range, except that it is explicitly stated that it does not include the endpoint value, may be the endpoint value, but also the middle value of each numerical range, and these are all within the protection scope of the present disclosure. .
在本公开中,上和下是相对于基底的底面而言的,对于一个部件,其靠近该底面的一侧为下侧,远离该底面的一侧为上侧。In the present disclosure, upper and lower are relative to the bottom surface of the substrate, and for a component, the side close to the bottom surface is the lower side, and the side away from the bottom surface is the upper side.
在本公开中,内和外是相对于谐振器的有效区域(压电层、顶电极、底电极和声学镜在谐振器的厚度方向上的重叠区域构成有效区域)的中心在横向方向或者径向方向上而言的,一个部件的靠近有效区域的中心的一侧或一端为内侧或内端,而该部件的远离有效区域的中心的一侧或一端为外侧或外端。对于一个参照位置而言,位于该位置的内侧表示在横向方向或径向方向上处于该位置与有效区域的中心之间,位于该位置的外侧表示在横向方向或径向方向上比该位置更远离该有效区域的中心。In the present disclosure, inner and outer are in the lateral direction or radial direction relative to the center of the effective area of the resonator (the overlapping area of the piezoelectric layer, the top electrode, the bottom electrode and the acoustic mirror in the thickness direction of the resonator constitutes the effective area). Directionally, the side or end of a component close to the center of the active area is the inner or inner end, and the side or end of the component away from the center of the active area is the outer or outer end. For a reference position, being located inside the position means between the position and the center of the effective area in the lateral or radial direction, and being located outside of the position means more laterally or radially than the position away from the center of the active area.
如本领域技术人员能够理解的,体声波谐振器可以用于形成滤波器或其他半导体器件。As can be appreciated by those skilled in the art, bulk acoustic wave resonators may be used to form filters or other semiconductor devices.
基于以上,本公开提出了如下技术方案:Based on the above, the present disclosure proposes the following technical solutions:
1、一种体声波谐振器,包括:1. A bulk acoustic wave resonator, comprising:
基底;base;
声学镜;acoustic mirror;
底电极;bottom electrode;
压电层;和piezoelectric layer; and
顶电极,top electrode,
其中:in:
顶电极、压电层、底电极在谐振器的厚度方向上的重叠区域构成谐振器的有效区域;The overlapping area of the top electrode, the piezoelectric layer and the bottom electrode in the thickness direction of the resonator constitutes an effective area of the resonator;
所述压电层包括第一层和第二层,第一层与第二层之间设置有声阻层,第二层在第一层的上方,所述声阻层的内边缘在水平方向上处于声学镜边界的内侧,所述声阻层的声阻不同于所述压电层的声阻;The piezoelectric layer includes a first layer and a second layer, an acoustic resistance layer is arranged between the first layer and the second layer, the second layer is above the first layer, and the inner edge of the acoustic resistance layer is in the horizontal direction On the inner side of the boundary of the acoustic mirror, the acoustic resistance of the acoustic resistance layer is different from the acoustic resistance of the piezoelectric layer;
所述谐振器还包括将所述声阻层与外部相通的通道或开口。The resonator also includes a channel or opening that communicates the acoustically resistive layer to the outside.
2、根据1所述的谐振器,其中:2. The resonator according to 1, wherein:
在顶电极的非电极连接端,所述声阻层的外边缘与第二层的端部齐平,所述声阻层的外边缘构成或处于所述开口;或者At the non-electrode connection end of the top electrode, the outer edge of the acoustic resistance layer is flush with the end of the second layer, and the outer edge of the acoustic resistance layer forms or is in the opening; or
基于所述声阻层,顶电极的非电极连接端形成悬翼结构。Based on the acoustic resistance layer, the non-electrode connection end of the top electrode forms a cantilever structure.
3、根据2所述的谐振器,其中:3. The resonator according to 2, wherein:
在顶电极的非电极连接端,所述第二层的端部的端面为竖直面或斜面。At the non-electrode connection end of the top electrode, the end face of the end portion of the second layer is a vertical plane or an inclined plane.
4、根据2所述的谐振器,其中:4. The resonator according to 2, wherein:
在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分的厚度等于处于声阻层的外边缘的内侧的部分的厚度;或者At the non-electrode connection end of the top electrode, the thickness of the portion of the first layer on the outside of the outer edge of the acoustically resistive layer is equal to the thickness of the portion on the inside of the outer edge of the acoustically resistive layer; or
在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分的厚度小于处于声阻层的外边缘的内侧的部分的厚度;或者At the non-electrode connection end of the top electrode, the thickness of the portion of the first layer on the outside of the outer edge of the acoustically resistive layer is less than the thickness of the portion on the inside of the outer edge of the acoustically resistive layer; or
在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分被移除。At the non-electrode connection end of the top electrode, the portion of the first layer outside the outer edge of the acoustically resistive layer is removed.
5、根据2所述的谐振器,其中:5. The resonator according to 2, wherein:
顶电极的非电极连接端在水平方向上与所述第二层的端部错开。The non-electrode connection end of the top electrode is staggered from the end of the second layer in the horizontal direction.
6、根据1所述的谐振器,其中:6. The resonator according to 1, wherein:
所述声阻层包括多个声阻部,所述多个声阻部沿谐振器的有效区域在周向方向上间隔开布置,所述多个声阻部的外边缘构成沿有效区域的周向方向间隔布置的多个所述开口;或者The acoustic resistance layer includes a plurality of acoustic resistance portions, the plurality of acoustic resistance portions are spaced apart in the circumferential direction along the effective area of the resonator, and outer edges of the plurality of acoustic resistance portions constitute a circumference along the effective area. a plurality of said openings spaced in the direction; or
所述声阻层沿谐振器的有效区域在周向方向上连续布置,所述声阻层的外边缘构成沿有效区域的周向方向连续布置的所述开口。The acoustic resistance layer is continuously arranged in the circumferential direction along the effective area of the resonator, and the outer edge of the acoustic resistance layer constitutes the openings continuously arranged in the circumferential direction of the effective area.
7、根据2-6中任一项所述的谐振器,其中:7. The resonator according to any one of 2-6, wherein:
所述声阻层为空隙层或者固态介质层。The acoustic resistance layer is a void layer or a solid medium layer.
8、根据1所述的谐振器,其中:8. The resonator according to 1, wherein:
在顶电极的非电极连接端,所述通道在第二层的厚度方向上穿过第二层,所述通道在水平方向上处于所述顶电极的非电极连接端的外侧,所述通道与所述声阻层相通或相接。At the non-electrode connection end of the top electrode, the channel passes through the second layer in the thickness direction of the second layer, the channel is outside the non-electrode connection end of the top electrode in the horizontal direction, and the channel is connected to the second layer. The acoustic resistance layers are communicated or connected to each other.
9、根据8所述的谐振器,其中:9. The resonator of 8, wherein:
所述声阻层至少在所述顶电极的非电极连接端沿有效区域周向方向连续设置,且所述通道为沿有效区域周向设置且与所述声阻层相通或相接的连续通道,或者所述通道包括沿有效区域周向间隔开设置的多个孔;或者The acoustic resistance layer is continuously arranged along the circumferential direction of the effective area at least at the non-electrode connection end of the top electrode, and the channel is a continuous channel arranged along the circumference of the effective area and communicated with or connected to the acoustic resistance layer , or the channel includes a plurality of holes spaced circumferentially along the effective area; or
所述声阻层包括多个声阻部,所述多个声阻部沿谐振器的有效区域在周向方向上间隔开布置,所述通道包括分别与所述多个声阻部相通或相接的多个孔,或者所述通道为沿有效区域周向设置且与所述多个声阻部相通或相接的连续通道。The acoustic resistance layer includes a plurality of acoustic resistance parts, the plurality of acoustic resistance parts are arranged spaced apart in the circumferential direction along the effective area of the resonator, and the channel comprises a plurality of acoustic resistance parts respectively communicating with or in phase with the plurality of acoustic resistance parts; A plurality of holes connected to each other, or the channel is a continuous channel arranged along the circumference of the effective area and communicated with or connected to the plurality of acoustic resistance parts.
10、根据8或9所述的谐振器,其中:10. The resonator according to 8 or 9, wherein:
所述声阻层为空隙层,所述通道为与所述空隙层相通的释放通道。The acoustic resistance layer is a void layer, and the channel is a release channel communicated with the void layer.
11、根据1-10中任一项所述的谐振器,其中:11. The resonator of any of 1-10, wherein:
第一层的压电材料不同于第二层的压电材料。The piezoelectric material of the first layer is different from the piezoelectric material of the second layer.
12、根据11所述的谐振器,其中:12. The resonator of 11, wherein:
第一层与第二层中的一层为另一层的掺杂层;或者One of the first layer and the second layer is a doped layer of the other; or
第一层与第二层均为同一材料的掺杂层,第一层的掺杂浓度不同于第二层的掺杂浓度;或者The first layer and the second layer are both doped layers of the same material, and the doping concentration of the first layer is different from the doping concentration of the second layer; or
第一层的材料为氮化铝、氧化锌、锆钛酸铅、铌酸锂、石英、铌酸钾、钽酸锂中的一种材料,而第二层为氮化铝、氧化锌、锆钛酸铅、铌酸锂、石英、铌酸钾、钽酸锂中不同于第一层材料的材料。The material of the first layer is one of aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, lithium tantalate, and the second layer is aluminum nitride, zinc oxide, zirconium A material different from the first layer material among lead titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate.
13、根据1-12中任一项所述的谐振器,其中:13. The resonator of any of 1-12, wherein:
所述声阻层包括在顶电极的非电极连接端的非连接端声阻层,所述非连接端声阻层的内边缘在水平方向上处于顶电极的非电极连接端的内侧。The acoustic resistance layer includes a non-connecting end acoustic resistance layer at the non-electrode connection end of the top electrode, and the inner edge of the non-connecting end acoustic resistance layer is located inside the non-electrode connection end of the top electrode in the horizontal direction.
14、根据13所述的谐振器,其中:14. The resonator of 13, wherein:
顶电极的非电极连接端在水平方向上处于声学镜边界的内侧或与声 学镜边界齐平;The non-electrode connection end of the top electrode is in the inner side of the boundary of the acoustic mirror in the horizontal direction or is flush with the boundary of the acoustic mirror;
在水平方向上,所述顶电极的非电极连接端与非连接端声阻层的内边缘之间存在第一距离,第一距离在0.25-10μm的范围内。In the horizontal direction, there is a first distance between the non-electrode connecting end of the top electrode and the inner edge of the non-connecting end acoustic resistance layer, and the first distance is in the range of 0.25-10 μm.
15、根据13所述的谐振器,其中:15. The resonator of 13, wherein:
所述声阻层还包括在顶电极的电极连接端的连接端声阻层。The acoustic resistance layer further includes a connection end acoustic resistance layer at the electrode connection end of the top electrode.
16、根据15所述的谐振器,其中:16. The resonator of 15, wherein:
在水平方向上,所述声学镜的边界与连接端声阻层的内边缘存在第二距离,第二距离在0.25-10μm的范围内。In the horizontal direction, there is a second distance between the boundary of the acoustic mirror and the inner edge of the acoustic resistance layer at the connection end, and the second distance is in the range of 0.25-10 μm.
17、根据1所述的谐振器,其中:17. The resonator of 1, wherein:
第一层的厚度不同于第二层的厚度。The thickness of the first layer is different from the thickness of the second layer.
18、一种体声波谐振器组件,包括:18. A bulk acoustic wave resonator assembly comprising:
至少两个体声波谐振器,其中至少一个体声波谐振器为根据1-17中任一项所述的谐振器。At least two BAW resonators, wherein at least one BAW resonator is the resonator according to any one of 1-17.
19、根据18所述的组件,其中:19. The assembly of 18, wherein:
所述至少两个体声波谐振器包括第一谐振器和第二谐振器;the at least two bulk acoustic wave resonators include a first resonator and a second resonator;
第一谐振器和第二谐振器均为根据1-17中任一项所述的谐振器。Both the first resonator and the second resonator are resonators according to any one of 1-17.
20、根据19所述的组件,其中:20. The assembly of 19, wherein:
第一谐振器和第二谐振器为根据12所述的谐振器。The first resonator and the second resonator are the resonators according to 12.
21、根据20所述的组件,其中:21. The assembly of 20, wherein:
第一谐振器的机电耦合系数与第二谐振器的机电耦合系数的差值在0%-10%的范围内。The difference between the electromechanical coupling coefficient of the first resonator and the electromechanical coupling coefficient of the second resonator is in the range of 0%-10%.
22、根据18-21中任一项所述的组件,其中:22. The assembly of any of 18-21, wherein:
所述第一谐振器和第二谐振器均为根据14或16的谐振器;said first and second resonators are both resonators according to 14 or 16;
第一谐振器的声阻层与第二谐振器的对应声阻层的宽度彼此不同。The widths of the acoustic resistance layer of the first resonator and the corresponding acoustic resistance layer of the second resonator are different from each other.
23、一种制造体声波谐振器的方法,所述谐振器包括基底、声学镜、底电极、压电层和顶电极,压电层包括第一层和第二层,第一层与第二层之间在顶电极的非电极连接端设置有空隙层,所述方法包括步骤:23. A method of manufacturing a bulk acoustic wave resonator, the resonator comprising a substrate, an acoustic mirror, a bottom electrode, a piezoelectric layer and a top electrode, the piezoelectric layer comprising a first layer and a second layer, the first layer and the second layer A void layer is arranged between the layers at the non-electrode connection end of the top electrode, and the method includes the steps:
在第一层上形成和图形化牺牲层;和forming and patterning a sacrificial layer on the first layer; and
利用第二层覆盖第一层以及其上的牺牲层,Cover the first layer and the sacrificial layer thereon with the second layer,
其中:in:
所述方法还包括步骤:在顶电极的非电极连接端,以刻蚀的方式移除第二层以露出牺牲层的外端;和释放牺牲层以形成所述空隙层;或者The method further includes the steps of: at the non-electrode connection end of the top electrode, removing the second layer by etching to expose the outer end of the sacrificial layer; and releasing the sacrificial layer to form the void layer; or
所述方法还包括步骤:在顶电极的非电极连接端的外侧,在第二层形成在第二层的厚度方向上贯穿第二层的释放通道;和经由所述释放通道释放牺牲层以形成所述空隙层。The method further includes the steps of: forming a release channel in the second layer penetrating the second layer in the thickness direction of the second layer outside the non-electrode connection end of the top electrode; and releasing the sacrificial layer via the release channel to form the the void layer.
24、一种滤波器,包括根据1-17中任一项所述的体声波谐振器,或根据18-22中任一项所述的体声波谐振器组件。24. A filter comprising the BAW resonator of any one of 1-17, or the BAW resonator assembly of any one of 18-22.
25、一种电子设备,包括根据24所述的滤波器,或根据1-17中任一项所述的体声波谐振器,或根据18-22中任一项所述的体声波谐振器组件。25. An electronic device comprising the filter according to 24, or the BAW resonator according to any one of 1-17, or the BAW resonator assembly according to any one of 18-22 .
这里的电子设备,包括但不限于射频前端、滤波放大模块等中间产品,以及手机、WIFI、无人机等终端产品。The electronic equipment here includes but is not limited to intermediate products such as RF front-end, filter and amplifier modules, and terminal products such as mobile phones, WIFI, and drones.
尽管已经示出和描述了本公开的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本公开的原理和精神的情况下可以对这些实施例进行变化,本公开的范围由所附权利要求及其等同物限定。Although embodiments of the present disclosure have been shown and described, it will be understood by those skilled in the art that changes may be made to these embodiments without departing from the principles and spirit of the present disclosure, the scope of which is determined by It is defined by the appended claims and their equivalents.

Claims (25)

  1. 一种体声波谐振器,包括:A bulk acoustic wave resonator, comprising:
    基底;base;
    声学镜;acoustic mirror;
    底电极;bottom electrode;
    压电层;和piezoelectric layer; and
    顶电极,top electrode,
    其中:in:
    顶电极、压电层、底电极在谐振器的厚度方向上的重叠区域构成谐振器的有效区域;The overlapping area of the top electrode, the piezoelectric layer and the bottom electrode in the thickness direction of the resonator constitutes an effective area of the resonator;
    所述压电层包括第一层和第二层,第一层与第二层之间设置有声阻层,第二层在第一层的上方,所述声阻层的内边缘在水平方向上处于声学镜边界的内侧,所述声阻层的声阻不同于所述压电层的声阻;The piezoelectric layer includes a first layer and a second layer, an acoustic resistance layer is arranged between the first layer and the second layer, the second layer is above the first layer, and the inner edge of the acoustic resistance layer is in the horizontal direction On the inner side of the boundary of the acoustic mirror, the acoustic resistance of the acoustic resistance layer is different from the acoustic resistance of the piezoelectric layer;
    所述谐振器还包括将所述声阻层与外部相通的通道或开口。The resonator also includes a channel or opening that communicates the acoustically resistive layer to the outside.
  2. 根据权利要求1所述的谐振器,其中:The resonator of claim 1, wherein:
    在顶电极的非电极连接端,所述声阻层的外边缘与第二层的端部齐平,所述声阻层的外边缘构成或处于所述开口;或者At the non-electrode connection end of the top electrode, the outer edge of the acoustic resistance layer is flush with the end of the second layer, and the outer edge of the acoustic resistance layer forms or is in the opening; or
    基于所述声阻层,顶电极的非电极连接端形成悬翼结构。Based on the acoustic resistance layer, the non-electrode connection end of the top electrode forms a cantilever structure.
  3. 根据权利要求2所述的谐振器,其中:The resonator of claim 2, wherein:
    在顶电极的非电极连接端,所述第二层的端部的端面为竖直面或斜面。At the non-electrode connection end of the top electrode, the end face of the end portion of the second layer is a vertical plane or an inclined plane.
  4. 根据权利要求2所述的谐振器,其中:The resonator of claim 2, wherein:
    在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分的厚度等于处于声阻层的外边缘的内侧的部分的厚度;或者At the non-electrode connection end of the top electrode, the thickness of the portion of the first layer on the outside of the outer edge of the acoustically resistive layer is equal to the thickness of the portion on the inside of the outer edge of the acoustically resistive layer; or
    在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分的厚度小于处于声阻层的外边缘的内侧的部分的厚度;或者At the non-electrode connection end of the top electrode, the thickness of the portion of the first layer on the outside of the outer edge of the acoustically resistive layer is less than the thickness of the portion on the inside of the outer edge of the acoustically resistive layer; or
    在顶电极的非电极连接端,第一层的处于声阻层的外边缘的外侧的部分被移除。At the non-electrode connection end of the top electrode, the portion of the first layer outside the outer edge of the acoustically resistive layer is removed.
  5. 根据权利要求2所述的谐振器,其中:The resonator of claim 2, wherein:
    顶电极的非电极连接端在水平方向上与所述第二层的端部错开。The non-electrode connection end of the top electrode is staggered from the end of the second layer in the horizontal direction.
  6. 根据权利要求1所述的谐振器,其中:The resonator of claim 1, wherein:
    所述声阻层包括多个声阻部,所述多个声阻部沿谐振器的有效区域在周向方向上间隔开布置,所述多个声阻部的外边缘构成沿有效区域的周向方向间隔布置的多个所述开口;或者The acoustic resistance layer includes a plurality of acoustic resistance portions, the plurality of acoustic resistance portions are spaced apart in the circumferential direction along the effective area of the resonator, and outer edges of the plurality of acoustic resistance portions constitute a circumference along the effective area. a plurality of said openings spaced in the direction; or
    所述声阻层沿谐振器的有效区域在周向方向上连续布置,所述声阻层的外边缘构成沿有效区域的周向方向连续布置的所述开口。The acoustic resistance layer is continuously arranged in the circumferential direction along the effective area of the resonator, and the outer edge of the acoustic resistance layer constitutes the openings continuously arranged in the circumferential direction of the effective area.
  7. 根据权利要求2-6中任一项所述的谐振器,其中:The resonator of any of claims 2-6, wherein:
    所述声阻层为空隙层或者固态介质层。The acoustic resistance layer is a void layer or a solid medium layer.
  8. 根据权利要求1所述的谐振器,其中:The resonator of claim 1, wherein:
    在顶电极的非电极连接端,所述通道在第二层的厚度方向上穿过第二层,所述通道在水平方向上处于所述顶电极的非电极连接端的外侧,所述通道与所述声阻层相通或相接。At the non-electrode connection end of the top electrode, the channel passes through the second layer in the thickness direction of the second layer, the channel is outside the non-electrode connection end of the top electrode in the horizontal direction, and the channel is connected to the second layer. The acoustic resistance layers are communicated or connected to each other.
  9. 根据权利要求8所述的谐振器,其中:The resonator of claim 8, wherein:
    所述声阻层至少在所述顶电极的非电极连接端沿有效区域周向方向连续设置,且所述通道为沿有效区域周向设置且与所述声阻层相通或相接的连续通道,或者所述通道包括沿有效区域周向间隔开设置的多个孔;或者The acoustic resistance layer is continuously arranged along the circumferential direction of the effective area at least at the non-electrode connection end of the top electrode, and the channel is a continuous channel arranged along the circumference of the effective area and communicated with or connected to the acoustic resistance layer , or the channel includes a plurality of holes spaced circumferentially along the effective area; or
    所述声阻层包括多个声阻部,所述多个声阻部沿谐振器的有效区域在周向方向上间隔开布置,所述通道包括分别与所述多个声阻部相通或相接的多个孔,或者所述通道为沿有效区域周向设置且与所述多个声阻部相通或相接的连续通道。The acoustic resistance layer includes a plurality of acoustic resistance parts, the plurality of acoustic resistance parts are arranged spaced apart in the circumferential direction along the effective area of the resonator, and the channel comprises a plurality of acoustic resistance parts respectively communicating with or in phase with the plurality of acoustic resistance parts; A plurality of holes connected to each other, or the channel is a continuous channel arranged along the circumference of the effective area and communicated with or connected to the plurality of acoustic resistance parts.
  10. 根据权利要求8或9所述的谐振器,其中:A resonator according to claim 8 or 9, wherein:
    所述声阻层为空隙层,所述通道为与所述空隙层相通的释放通道。The acoustic resistance layer is a void layer, and the channel is a release channel communicated with the void layer.
  11. 根据权利要求1-10中任一项所述的谐振器,其中:The resonator of any of claims 1-10, wherein:
    第一层的压电材料不同于第二层的压电材料。The piezoelectric material of the first layer is different from the piezoelectric material of the second layer.
  12. 根据权利要求11所述的谐振器,其中:The resonator of claim 11, wherein:
    第一层与第二层中的一层为另一层的掺杂层;或者One of the first layer and the second layer is a doped layer of the other; or
    第一层与第二层均为同一材料的掺杂层,第一层的掺杂浓度不同于第二层的掺杂浓度;或者The first layer and the second layer are both doped layers of the same material, and the doping concentration of the first layer is different from the doping concentration of the second layer; or
    第一层的材料为氮化铝、氧化锌、锆钛酸铅、铌酸锂、石英、铌酸钾、 钽酸锂中的一种材料,而第二层为氮化铝、氧化锌、锆钛酸铅、铌酸锂、石英、铌酸钾、钽酸锂中不同于第一层材料的材料。The material of the first layer is one of aluminum nitride, zinc oxide, lead zirconate titanate, lithium niobate, quartz, potassium niobate, lithium tantalate, and the second layer is aluminum nitride, zinc oxide, zirconium A material different from the first layer material among lead titanate, lithium niobate, quartz, potassium niobate, and lithium tantalate.
  13. 根据权利要求1-12中任一项所述的谐振器,其中:The resonator of any of claims 1-12, wherein:
    所述声阻层包括在顶电极的非电极连接端的非连接端声阻层,所述非连接端声阻层的内边缘在水平方向上处于顶电极的非电极连接端的内侧。The acoustic resistance layer includes a non-connecting end acoustic resistance layer at the non-electrode connection end of the top electrode, and the inner edge of the non-connecting end acoustic resistance layer is located inside the non-electrode connection end of the top electrode in the horizontal direction.
  14. 根据权利要求13所述的谐振器,其中:The resonator of claim 13, wherein:
    顶电极的非电极连接端在水平方向上处于声学镜边界的内侧或与声学镜边界齐平;The non-electrode connection end of the top electrode is in the inner side of the boundary of the acoustic mirror in the horizontal direction or is flush with the boundary of the acoustic mirror;
    在水平方向上,所述顶电极的非电极连接端与非连接端声阻层的内边缘之间存在第一距离,第一距离在0.25-10μm的范围内。In the horizontal direction, there is a first distance between the non-electrode connecting end of the top electrode and the inner edge of the non-connecting end acoustic resistance layer, and the first distance is in the range of 0.25-10 μm.
  15. 根据权利要求13所述的谐振器,其中:The resonator of claim 13, wherein:
    所述声阻层还包括在顶电极的电极连接端的连接端声阻层。The acoustic resistance layer further includes a connection end acoustic resistance layer at the electrode connection end of the top electrode.
  16. 根据权利要求15所述的谐振器,其中:The resonator of claim 15, wherein:
    在水平方向上,所述声学镜的边界与连接端声阻层的内边缘存在第二距离,第二距离在0.25-10μm的范围内。In the horizontal direction, there is a second distance between the boundary of the acoustic mirror and the inner edge of the acoustic resistance layer at the connection end, and the second distance is in the range of 0.25-10 μm.
  17. 根据权利要求1所述的谐振器,其中:The resonator of claim 1, wherein:
    第一层的厚度不同于第二层的厚度。The thickness of the first layer is different from the thickness of the second layer.
  18. 一种体声波谐振器组件,包括:A bulk acoustic wave resonator assembly, comprising:
    至少两个体声波谐振器,其中至少一个体声波谐振器为根据权利要求1-17中任一项所述的谐振器。At least two bulk acoustic wave resonators, wherein at least one bulk acoustic wave resonator is a resonator according to any one of claims 1-17.
  19. 根据权利要求18所述的组件,其中:The assembly of claim 18, wherein:
    所述至少两个体声波谐振器包括第一谐振器和第二谐振器;the at least two bulk acoustic wave resonators include a first resonator and a second resonator;
    第一谐振器和第二谐振器均为根据权利要求1-17中任一项所述的谐振器。Both the first resonator and the second resonator are resonators according to any one of claims 1-17.
  20. 根据权利要求19所述的组件,其中:The assembly of claim 19, wherein:
    第一谐振器和第二谐振器为根据权利要求12所述的谐振器。The first resonator and the second resonator are resonators according to claim 12 .
  21. 根据权利要求20所述的组件,其中:The assembly of claim 20, wherein:
    第一谐振器的机电耦合系数与第二谐振器的机电耦合系数的差值在0%-10%的范围内。The difference between the electromechanical coupling coefficient of the first resonator and the electromechanical coupling coefficient of the second resonator is in the range of 0%-10%.
  22. 根据权利要求18-21中任一项所述的组件,其中:The assembly of any of claims 18-21, wherein:
    所述第一谐振器和第二谐振器均为根据权利要求14或16的谐振器;Both the first resonator and the second resonator are resonators according to claim 14 or 16;
    第一谐振器的声阻层与第二谐振器的对应声阻层的宽度彼此不同。The widths of the acoustic resistance layer of the first resonator and the corresponding acoustic resistance layer of the second resonator are different from each other.
  23. 一种体声波谐振器的制造方法,所述谐振器包括基底、声学镜、底电极、压电层和顶电极,压电层包括第一层和第二层,第一层与第二层之间在顶电极的非电极连接端设置有空隙层,所述方法包括步骤:A method for manufacturing a bulk acoustic wave resonator, the resonator includes a substrate, an acoustic mirror, a bottom electrode, a piezoelectric layer and a top electrode, the piezoelectric layer includes a first layer and a second layer, and the first layer and the second layer are between the first layer and the second layer. A void layer is arranged between the non-electrode connection ends of the top electrode, and the method includes the steps:
    在第一层上形成和图形化牺牲层;和forming and patterning a sacrificial layer on the first layer; and
    利用第二层覆盖第一层以及其上的牺牲层,Covering the first layer and the sacrificial layer thereon with the second layer,
    其中:in:
    所述方法还包括步骤:在顶电极的非电极连接端,以刻蚀的方式移除第二层以露出牺牲层的外端;和释放牺牲层以形成所述空隙层;或者The method further includes the steps of: at the non-electrode connection end of the top electrode, removing the second layer by etching to expose the outer end of the sacrificial layer; and releasing the sacrificial layer to form the void layer; or
    所述方法还包括步骤:在顶电极的非电极连接端的外侧,在第二层形成在第二层的厚度方向上贯穿第二层的释放通道;和经由所述释放通道释放牺牲层以形成所述空隙层。The method further includes the steps of: forming a release channel in the second layer penetrating the second layer in the thickness direction of the second layer outside the non-electrode connection end of the top electrode; and releasing the sacrificial layer via the release channel to form the the void layer.
  24. 一种滤波器,包括根据权利要求1-17中任一项所述的体声波谐振器,或根据权利要求18-22中任一项所述的体声波谐振器组件。A filter comprising a bulk acoustic wave resonator according to any one of claims 1-17, or a bulk acoustic wave resonator assembly according to any one of claims 18-22.
  25. 一种电子设备,包括根据权利要求24所述的滤波器,或根据权利要求1-17中任一项所述的体声波谐振器,或根据权利要求18-22中任一项所述的体声波谐振器组件。An electronic device comprising a filter according to claim 24, or a bulk acoustic wave resonator according to any one of claims 1-17, or a bulk acoustic wave resonator according to any one of claims 18-22 Acoustic resonator assembly.
PCT/CN2021/117485 2020-09-22 2021-09-09 Bulk acoustic wave resonator having acoustic resistance layer, and assembly thereof and manufacturing method therefor, filter, and electronic device WO2022062912A1 (en)

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