WO2022046237A1 - Multiferroic-assisted voltage controlled magnetic anisotropy memory device and methods of manufacturing the same - Google Patents

Abstract

A magnetic memory device includes a first electrode, a second electrode, and a layer stack located between the first electrode and the second electrode. The layer stack includes a reference layer, a tunnel barrier layer, a free layer, and a magnetoelectric multiferroic layer including at least one crystalline grain. The magnetization of the magnetoelectric multiferroic layer may be axial, canted, or in-plane. For axial or canted magnetization of the magnetoelectric multiferroic layer, a deterministic switching of the free layer may be achieved through coupling with the axial component of magnetization of the magnetoelectric multiferroic layer. Alternatively, the in-plane magnetization of the magnetoelectric multiferroic layer may be employed to induce precession of the magnetization angle of the free layer.

Description

MULTIFERROIC-ASSISTED VOLTAGE CONTROLLED MAGNETIC ANISOTROPY MEMORY DEVICE AND METHODS OF MANUFACTURING THE SAME

RELATED APPLICATIONS

[0001] This application claims the benefit of priority from U.S. Non-Provisional Application No. 17/004,534, filed August 27, 2020; and from U.S. Non-Provisional Application No. 17/004,690, filed August 27, 2020; the entire contents of which is herein incorporated by reference.

FIELD

[0002] The present disclosure relates generally to the field of magnetic (e.g., spintronic) memory devices, and specifically to a magnetoresistive random access memory (“MRAM”) device including a multiferroic layer and methods of manufacturing the same.

BACKGROUND

[0003] A magnetoresistive memory device can store information employing the difference in electrical resistance of a first configuration in which a ferromagnetic free layer has a magnetization direction that is parallel to the magnetization of a ferromagnetic reference layer and a second configuration in which the free layer has a magnetization direction that is antiparallel to the magnetization of the reference layer. Programming of the magnetoresistive memory device requires flipping of the direction of the magnetization of the free layer employing various external power sources, which may be magnetic in nature or may employ a spin transfer mechanism.

[0004] Voltage controlled magnetic anisotropy (VCMA) refers to an effect in which the perpendicular magnetic anisotropy of the free layer has a first-order dependence on the externally applied voltage across the free layer located in a magnetic tunnel junction which includes a dielectric tunnel barrier layer between the free layer and a ferromagnetic reference layer. The thickness of the dielectric tunnel barrier layer may be at least 1 nm, which reduces tunneling current flow through the dielectric tunnel barrier layer below a critical current required to switch the magnetization direction of the free layer during programming. Therefore, an applied voltage is used to switch the magnetization direction of the free layer. The applied voltage lowers the energy perpendicular magnetic anisotropy in one bias direction and raises it for the other bias direction. However, the VCMA programming is non deterministic and requires precise control of the timing of the applied voltage pulses to obtain a desired magnetization direction of the free layer.

SUMMARY

[0005] According to an aspect of the present disclosure, a magnetic memory device is provided, which comprises: a first electrode; a second electrode; and a layer stack located between the first electrode and the second electrode and comprising, from one side to another, a reference layer, a tunnel barrier layer, a free layer, and a magnetoelectric multiferroic layer including at least one crystalline grain having an easy axis of magnetization along an axial direction or along a first tilted direction having a first tilt angle less than 90 degrees relative to the axial direction, the axial direction being perpendicular to an interface between the free layer and the tunnel barrier layer.

[0006] According to another aspect of the present disclosure a method of programming the magnetic memory device includes applying a first programming voltage pattern comprising a first positive voltage having a magnitude greater than a coercive voltage sufficient to switch a magnetization direction of the magnetoelectric multiferroic layer, and applying a second programming voltage pattern comprising a negative voltage having a magnitude greater than the coercive voltage followed by a second positive voltage having a magnitude less than the coercive voltage.

[0007] In one embodiment, the first positive voltage deterministically programs the magnetization direction of the magnetoelectric multiferroic layer to be parallel to a magnetization direction of the reference layer, and the first positive voltage has a sufficient magnitude to lower a perpendicular magnetic anisotropy of the free layer that allows the free layer to switch its magnetization direction to be parallel to the magnetization direction of the reference layer. The negative voltage deterministically programs the magnetization direction of the magnetoelectric multiferroic layer to be antiparallel to the magnetization direction of the reference layer, and the negative voltage increases the perpendicular magnetic anisotropy of the free layer such that the free layer cannot switch its magnetization direction. The second positive voltage does not have a sufficient magnitude to switch the magnetization direction of the magnetoelectric multiferroic layer, and the second positive voltage has a sufficient magnitude to lower the perpendicular magnetic anisotropy of free layer that allows the free layer to deterministically switch its magnetization direction to be antiparallel to magnetization direction of the reference layer.

[0008] According to yet another aspect of the present disclosure, a magnetic memory device comprises a first electrode, a second electrode, and a layer stack located between the first electrode and the second electrode and comprising, from one side to another, a reference layer, a tunnel barrier layer, a free layer, and a voltage controlled magnetic anisotropy (VCMA) assist structure having an in-plane magnetization direction. BRIEF DESCRIPTION OF THE DRAWINGS

[0009] FIG. 1 is a schematic diagram of a random access array of magnetic tunnel junction devices according to an embodiment of the present disclosure.

[0010] FIG. 2A is a vertical cross-sectional view of a first exemplary structure after formation according to a first embodiment of the present disclosure.

[0011] FIG. 2B is a vertical cross-sectional view of an alternative embodiment of the first exemplary structure according to the first embodiment of the present disclosure.

[0012] FIG. 3A is a perspective view of a unit cell of Bi FeO with ferroelectric polarization and magnetic moment

[0013] FIG. 3B illustrates the relative spatial orientation between the ferroelectric polarization and the magnetic moment directions of the unit cell of Bi FeOa of FIG. 3 A.

[0014] FIG. 4A is a vertical cross-sectional view of the first exemplary structure in a first programmed state according to the first embodiment of the present disclosure.

[0015] FIG. 4B is a vertical cross-sectional view of the first exemplary structure in a second programmed state according to the first embodiment of the present disclosure.

[0016] FIG. 5 is a diagram illustrating changes in the axial ferroelectric polarization of the magnetoelectric multiferroic layer according to the first embodiment of the present disclosure.

[0017] FIG. 6A is a diagram illustrating a first voltage pulse pattern for programming the magnetic memory cell of the first exemplary structure into a first magnetic state according to an aspect of the present disclosure.

[0018] FIG. 6B is a diagram illustrating a second voltage pulse pattern for programming the magnetic memory cell of the first exemplary structure into a second magnetic state according to an aspect of the present disclosure. [0019] FIG. 7A is a vertical cross-sectional view of a second exemplary structure after formation according to a first embodiment of the present disclosure.

[0020] FIG. 7B is a vertical cross-sectional view of an alternative embodiment of the second exemplary structure according to the first embodiment of the present disclosure.

[0021] FIG. 8 is a vertical cross-sectional view of another alternative embodiment of the second exemplary structure according to the second embodiment of the present disclosure.

[0022] FIG. 9A is a vertical cross-sectional view of a second exemplary structure in a first magnetic state according to a second embodiment of the present disclosure.

[0023] FIG. 9B is a vertical cross-sectional view of the second exemplary structure in a second magnetic state according to the second embodiment of the present disclosure.

[0024] FIG. 10A is a diagram of a sensing voltage pattern for sensing a magnetic state of the magnetic memory device of the second exemplary structure according to the second embodiment of the present disclosure.

[0025] FIG. 10B is a diagram of a programming voltage pattern for programming a magnetic state of the magnetic memory device of the second exemplary structure according to the second embodiment of the present disclosure.

DETAILED DESCRIPTION

[0026] Embodiments of the present disclosure are directed to a voltage controlled magnetic anisotropy memory device containing a magnetoelectric multiferroic layer and methods of operating the same, the various aspects of which are described in detail herebelow. The magnetoelectric multiferroic layer provides a deterministic VCMA programming mechanism (e.g., where the magnetization direction of the free layer is not dependent on the duration of the programming voltage pulse), and/or provides a precisely controlled, in-plane assist magnetic field that is determined by the crystalline characteristics of the magnetoelectric multiferroic layer.

[0027] The drawings are not drawn to scale. Multiple instances of an element may be duplicated where a single instance of the element is illustrated, unless absence of duplication of elements is expressly described or clearly indicated otherwise. Ordinals such as “first,” “second,” and “third” are employed merely to identify similar elements, and different ordinals may be employed across the specification and the claims of the instant disclosure. The term “at least one” element refers to all possibilities including the possibility of a single element and the possibility of multiple elements. The same reference numerals refer to the same element or similar element. Unless otherwise indicated, elements having the same reference numerals are presumed to have the same composition and the same function. Unless otherwise indicated, a “contact” between elements refers to a direct contact between elements that provides an edge or a surface shared by the elements. If two or more elements are not in direct contact with each other or among one another, the two elements are “disjoined from” each other or “disjoined among” one another. As used herein, a first element located “on” a second element can be located on the exterior side of a surface of the second element or on the interior side of the second element. As used herein, a first element is located “directly on” a second element if there exist a physical contact between a surface of the first element and a surface of the second element. As used herein, a first element is “electrically connected to” a second element if there exists a conductive path consisting of at least one conductive material between the first element and the second element. As used herein, a “prototype” structure or an “in-process” structure refers to a transient structure that is subsequently modified in the shape or composition of at least one component therein. [0028] As used herein, a “layer” refers to a material portion including a region having a thickness. A layer may extend over the entirety of an underlying or overlying structure, or may have an extent less than the extent of an underlying or overlying structure. Further, a layer may be a region of a homogeneous or inhomogeneous continuous structure that has a thickness less than the thickness of the continuous structure. For example, a layer may be located between any pair of horizontal planes between, or at, a top surface and a bottom surface of the continuous structure. A layer may extend horizontally, vertically, and/or along a tapered surface. A substrate may be a layer, may include one or more layers therein, or may have one or more layer thereupon, thereabove, and/or therebelow. As used herein, a “layer stack” refers to a stack of layers. As used herein, a “line” or a “line structure” refers to a layer that has a predominant direction of extension, i.e., having a direction along which the layer extends the most. As used herein, a “ferroelectric material” refers to any material that exhibits spontaneous ferroelectric polarization that can be reversed by the application of an external electric field (e.g., exhibits ferroelectricity). As used herein, a “multiferroic” material refers to a material that exhibits at least two ferroic orders, such as magnetic (ferromagnetism, antiferromagnetism, or ferrimagnetism) and ferroelectric. As used herein, a “magnetoelectric multiferroic” refers to a material that exhibits a ferromagnetic-type order and ferroelectricity. A change in total magnetization is coupled to a change in total ferroelectric polarization in a magnetoelectric multiferroic material, and thus, a change in a magnetic moment direction of the material can be coupled to a change in the ferroelectric polarization direction and vice versa.

[0029] FIG. 1 is a schematic diagram of a random access memory device 501 of magnetic tunnel junction devices 180 according to an embodiment of the present disclosure. As used herein, a “random access memory device” refers to a memory device including memory cells that allow random access, i.e., access to any selected memory cell upon a command for reading the contents of the selected memory cell. [0030] The random access memory device 501 of the embodiments of the present disclosure may comprise an MRAM device, such as a multistate STT-type MRAM device containing multiferroic portions. The device 501 includes a memory array region 550 containing an array of the respective magnetic devices, such as magnetic tunnel junction devices (e.g., magnetoresistive memory cells) 180 located at intersections of word lines (which may comprise first electrically conductive lines 30 as illustrated or as second electrically conductive lines 90 in an alternate configuration) and bit lines (which may comprise second electrically conductive lines 90 as illustrated or as first electrically conductive lines 30 in an alternate configuration). For example, the first electrically conductive lines 30 may be electrically connected to, and/or may comprise, bottom electrodes of a respective row of magnetic tunnel junction devices 180 in the memory array region 550, while the second electrically conductive lines 90 may be electrically connected to, and/or may comprise, top electrodes of a respective column of magnetic tunnel junction devices 180 in the memory array region 550.

[0031] The random access memory device 501 may also contain a row decoder 560 connected to the word lines, a sensing and programming circuit 570 (which may include sense amplifiers, programming transistors, and control circuits) connected to the bit lines, a column decoder 580 connected to the bit lines, and a data buffer 590 connected to the sense circuitry. The magnetic tunnel junction devices 180 are provided in an array configuration that forms the random access memory device 501. In one embodiment, the magnetic tunnel junction devices 180 may be provided as a rectangular array. As such, each of the magnetic tunnel junction devices 180 can be a two-terminal device including a respective first electrode and a respective second electrode. It should be noted that the location and interconnection of elements are schematic, and the elements may be arranged in a different configuration. Further, a magnetic tunnel junction device 180 may be manufactured as a discrete device, i.e., a single isolated device.

[0032] The random access configuration illustrated in the random access memory device 501 is only exemplary, and the magnetic tunnel junction devices 180 of the embodiments of the present disclosure can be connected in different interconnection configurations.

[0033] Referring to FIGS. 2 A and 2B, exemplary configurations of a magnetic tunnel junction device 180 are illustrated in first exemplary structures. The configuration of FIG. 2A and the configuration of FIG. 2B are alternative configurations that may be derived from each other by reversing the order of material deposition during formation of a magnetic tunnel junction device 180, which is a magnetic memory device.

[0034] The first exemplary structure includes an optional insulating material layer 110 that includes an insulating material such as undoped silicate glass, a doped silicate glass, organosilicate glass, silicon nitride, a dielectric metal oxide, or a combination thereof. In one embodiment, the insulating material layer 110 comprises an insulating substrate, such as a ceramic or a glass substrate. In another embodiment, the insulating material layer 110 can be provided over a semiconductor substrate (not shown) with semiconductor devices (not shown) such as field effect transistors thereupon. In this case, the insulating material layer 110 may include a plurality of interconnect- level dielectric material layers embedding metal interconnect structures therein. The metal interconnect structure can provide electrical connection between the semiconductor devices and to the first electrically conductive lines 30 and the second electrically conductive lines 90 that are formed above the insulating material layer 110. In this case, structural elements that are formed above the insulating material layer 110 may be embedded within a dielectric matrix (not expressly shown) that embeds the first electrically conductive lines 30 and the second electrically conductive lines. [0035] First electrically conductive lines 30 can be formed over the insulating material layer 110. The first electrically conductive lines 30 may be formed over the top surface of the insulating material layer 110 by depositing and patterning at least one metallic layer and patterning the at least one metallic layer into line- shaped structures that laterally extend along a first horizontal direction. In one embodiment, the at least one metallic layer may include a stack of a metallic barrier layer including a conductive metallic nitride and a high-electrical- conductivity metal layer such a copper layer or a tungsten layer. Alternatively, line cavities may be formed in an upper portion of the insulating material layer 110, and the first electrically conductive lines 30 may be formed by a damascene method in which at least one metallic material is deposited in the line cavities, and excess portions of the at least one metallic material is removed from above the horizontal plane including the top surface of the insulating material layer 110. Each portion of a first electrically conductive line 30 that contacts an overlying magnetic tunnel junction device 180 comprises a first electrode of the magnetic tunnel junction device 180, which is a magnetic memory device.

[0036] A continuous layer stack can be deposited over the first electrically conductive lines 30. The continuous layer stack includes, from bottom to top or from top to bottom, an optional continuous synthetic antiferromagnetic (SAF) structure, a continuous ferromagnetic reference layer, a continuous tunnel barrier layer, a continuous ferromagnetic free layer, a continuous magnetoelectric multiferroic layer, and an optional continuous nonmagnetic capping layer.

[0037] The optional SAF structure may include a superlattice structure including an alternating sequence of ferromagnetic material layers and conductive nonmagnetic material layers. In an illustrative example, the superlattice structure may include [X/Q]_n, in which X represents a ferromagnetic material layer, such as Co, CoFe, Fe, or CoFeB layer, Q represents a nonmagnetic material layer, such as Pt or Pd layer, and n represents the total number of repetitions of a bilayer stack of the ferromagnetic material layer and the nonmagnetic material layer. The total number n of repetitions may be in a range from 2 to 20, such as from 3 to 8, although a greater number may also be employed.

[0038] The continuous reference layer includes a ferromagnetic material having perpendicular magnetic anisotropy. The continuous reference layer includes a ferromagnetic material such as CoFe or CoFeB. The continuous reference layer may be deposited, for example, by physical vapor deposition, and may have a thickness in a range from 1 nm to 3 nm, although lesser and greater thicknesses may also be employed.

[0039] The continuous tunnel barrier layer includes a tunneling dielectric material such as MgO. The continuous tunnel barrier layer may be deposited, for example, by physical vapor deposition. The thickness of the continuous tunnel barrier layer may be in a range from 1 nm to 2 nm, such as 1.5 nm to 2 nm, although lesser and greater thicknesses may also be employed.

[0040] The continuous free layer includes a ferromagnetic material having perpendicular magnetic anisotropy. The continuous free layer includes a ferromagnetic material such as CoFe or CoFeB. The continuous free layer may be deposited, for example, by physical vapor deposition, and may have a thickness in a range from 0.6 nm to 2 nm, although lesser and greater thicknesses may also be employed.

[0041] The continuous magnetoelectric multiferroic layer comprises a magnetoelectric multiferroic material. As used herein, a “multiferroic” refers to a material that exhibits at least two ferroic orders (such as ferromagnetism and ferroelectricity) As used herein, a “magnetoelectric multiferroic” refers to a material that exhibits a ferromagnetic-type order and ferroelectricity. A change in total magnetization is coupled to a change in total electric polarization in a magnetoelectric multiferroic, and thus, a magnetic transition can be coupled to a change in the ferroelectric polarization and vice versa.

[0042] The continuous magnetoelectric multiferroic layer may comprise any polycrystalline multiferroic material or a single crystalline multiferroic material that can generate a non- zero net magnetization either as deposited, or upon application of an initializing magnetic field or an initializing electric field. In an illustrative example, the continuous magnetoelectric multiferroic layer may comprise a material selected from BiFeO , h-YMnCh, BaNiF4, PbVO₃, BiMnO₃, LuFe2O4, HoMmOa, h-HoMnO₃, h-ScMnO₃, h- ErMnO₃, h-TmMnCh, h-YbMnCh, h-LuMnO₃, K₂SeO₄, Cs₂CdI₄, TbMnO₃, Ni₃V₂O₈, MnWCh, CuO, ZnCr₂Se4, LiCu₂O₂, and Ni₃B70i₃I. The continuous magnetoelectric multiferroic layer may be deposited by a suitable deposition method, such as physical vapor deposition. The thickness of the continuous magnetoelectric multiferroic layer can be 1 nm or less, such as in a range from 0.3 nm to 1 nm, such as from 0.5 nm to 0.8 nm, although lesser and greater thicknesses can also be employed.

[0043] In one embodiment, the polarization and magnetization directions of the continuous magnetoelectric multiferroic layer are orthogonal to each other. The continuous magnetoelectric multiferroic layer includes at least one crystalline grain having an easy axis of magnetization along an axial direction or along a first tilted (i.e., canted) direction having a first tilt angle less than 90 degrees relative to the axial direction. The axial direction is perpendicular to the interface between the continuous free layer and the continuous tunnel barrier layer. In one embodiment, the continuous magnetoelectric multiferroic layer includes a plurality of crystalline grains having an easy axis of magnetization along the axial direction or along a respective first tilted direction having a respective first tilt angle less than 90 degrees relative to the axial direction. [0044] Generally, the magnetization direction in the crystalline grains of the continuous magnetoelectric multiferroic layer may depend on the preferred grain orientation and/or impurity doping within the magnetoelectric multiferroic layer. If the magnetoelectric multiferroic material comprises BiFeCL, then a polycrystalline BiFeOa layer having a preferred grain orientation along the (110) plane can provide a predominantly axial magnetization direction, i.e., more than 50 % all crystalline grains can have a respective magnetization direction (e.g., spin orientation) that is perpendicular to the interface between the continuous tunnel barrier layer and the continuous free layer. A polycrystalline Bi FeO layer having a preferred grain orientation along the (100) plane can provide a predominantly canted magnetization direction along the <111> direction, i.e., more than 50 % all crystalline grains can have a respective magnetization direction (e.g., spin orientation) that is not perpendicular to, and not parallel to, the interface between the continuous tunnel barrier layer and the continuous free layer. In contrast, a poly crystalline Bi FeO layer having the preferred grain orientation along the (100) plane but which is doped with La on the Bi lattice sites can provide a predominantly axial magnetization direction, i.e., more than 50 % all crystalline grains can have a respective magnetization direction (e.g., spin orientation) that is perpendicular to the interface between the continuous tunnel barrier layer and the continuous free layer. A polycrystalline Bi FeCL layer having a preferred grain orientation along the (111) plane can provide predominantly in-plane magnetization direction, i.e., more than 50 % all crystalline grains can have a respective magnetization direction (e.g., spin orientation) that is parallel to the interface between the continuous tunnel barrier layer and the continuous free layer.

[0045] The optional continuous nonmagnetic capping layer includes a nonmagnetic metal that is resistant to oxidation and/or diffusion. In one embodiment, the continuous nonmagnetic capping layer may include a metal having a melting point higher than 1,500 degrees Celsius. For example, the metal of the continuous nonmagnetic capping layer may include ruthenium, tantalum, platinum or gold. The continuous nonmagnetic capping layer may be deposited by a physical vapor deposition. The thickness of the continuous nonmagnetic capping layer may be in a range from 0.5 nm to 2 nm, although lesser and greater thicknesses may also be employed.

[0046] The continuous layer stack can be patterned into a two-dimensional array of pillar structures. The patterning can be performed using ion beam milling and/or photolithography and etching. Each of the pillar structures may include a magnetic tunnel junction device 180, which is a magnetic memory device (e.g., an MRAM cell).

[0047] In each pillar structure (e.g., in each magnetic tunnel junction device 180 which comprises an MRAM cell), each patterned portion of the continuous SAF structure comprises a SAF structure 120. Each patterned portion of the continuous reference layer comprises a reference layer 132. If the SAF structure 120 includes the superlattice, then the reference layer 132 may contact the nonmagnetic layer of the SAF structure superlattice. Each patterned portion of the continuous tunnel barrier layer comprises a tunnel barrier layer (i.e., tunneling dielectric layer) 134. Each patterned portion of the continuous free layer comprises a free layer 136. Each patterned portion of the continuous magnetoelectric multiferroic layer comprises a magnetoelectric multiferroic layer 140.

[0048] A dielectric matrix layer 190 may be deposited over and around the array of magnetic tunnel junction devices 180 (i.e., around the pillar structures). The dielectric matrix layer 190 includes a dielectric material such as silicon nitride, silicon oxide, organosilicate glass, and/or a dielectric metal oxide. In one embodiment, the dielectric matrix layer 190 may include a dielectric diffusion liner (such as a silicon nitride liner) and a dielectric fill material (such as silicon oxide). The dielectric matrix layer 190 may be planarized to provide a horizontal top surface above a horizontal plane including the top surfaces of the magnetic tunnel junction devices 180. For example, chemical mechanical planarization (CMP) may be employed to planarize the top surface of the dielectric matrix layer 190.

[0049] Line cavities that laterally extend along a second horizontal direction can be formed in an upper portion of the dielectric matrix layer 190. The second horizontal direction is different from the first horizontal direction, and may be perpendicular to the first horizontal direction. At least one conductive material can be deposited in the line cavities, and excess portions of the at least one conductive material can be removed from above the horizontal plane including the top surface of the dielectric matrix layer 190. Each remaining portion of the at least one conductive material filling the line cavities comprises a second electrically conductive line 90. Each second electrically conductive line 90 can comprise at least one second electrode of the two-dimensional array of magnetic tunnel junction devices 180. Alternatively, the second electrically conductive lines 90 may be formed on each of the pillar structures followed by forming the dielectric matrix layer 190 over the second electrically conductive lines 90.

[0050] In one embodiment, each first electrically conductive line 30 can contact a respective row of magnetic tunnel junction devices 180, and each second electrically conductive line 90 can contact a respective column of magnetic tunnel junction devices 180. In this case, each first electrically conductive line 30 can comprise a row of first electrodes, and each second electrically conductive line 90 can comprise a column of second electrodes. [0051] In one embodiment, a predominant subset in volume of the crystalline grains (i.e., a set of crystalline grains that occupy more than 50 % of the entire volume of each magnetoelectric multiferroic layer 140) within the magnetoelectric multiferroic layers 140 can have an easy axis of magnetization along an axial direction or along a first tilted direction having a first tilt angle less than 90 degrees relative to the axial direction (such as the <111> direction). The axial direction is perpendicular to each interface between the free layer 136 and the tunnel barrier layer 134 within each magnetic tunnel junction device 180. In one embodiment, each magnetoelectric multiferroic layer 140 can have a respective easy axis of ferroelectric polarization along the axial direction or along a second tilted direction having a second tilt angle less than 90 degrees relative to the axial direction. The second direction of each crystalline grain may, or may not, be parallel or antiparallel to the first direction of the respective crystalline grain. Each magnetoelectric multiferroic layer 140 may be either single crystalline or polycrystalline, i.e., may contain a plurality of crystalline grains that are adjoined at grain boundaries at which crystal structures of the magnetoelectric multiferroic material are discontinuous.

[0052] According to an embodiment of the present disclosure, a net axial magnetization can be induced within each magnetoelectric multiferroic layer 140 within the array of magnetic tunnel junction devices 180 by application of an axial initialization magnetic field or electric field. The electric field can switch the ferroelectric polarization and corresponding magnetization due to the magnetoelectric coupling. The axial initialization magnetic field or electric field can be applied along a vertical direction that is perpendicular to the interface between each free layer 136 and the tunnel barrier layer 134. The axial initialization magnetic field or electric field can align the vertical component of the magnetization of each crystalline grain in each magnetoelectric multiferroic layer 140 along the direction of the axial initialization magnetic field or electric field. Thus, each magnetoelectric multiferroic layer 140 can have a net non- zero axial magnetization. In this case, each magnetoelectric multiferroic layer 140 can have a net non- zero ferroelectric polarization that is associated with the net non-zero axial magnetization.

[0053] According to another embodiment of the present disclosure, a net axial ferroelectric polarization can be induced within each magnetoelectric multiferroic layer 140 within the array of magnetic tunnel junction devices 180 by application of an axial initialization electric field. The axial initialization electric field can be applied along a vertical direction that is perpendicular to the interface between each free layer 136 and the tunnel barrier layer 134. The axial initialization electric field can align the vertical component of the ferroelectric polarization of each crystalline grain in each magnetoelectric multiferroic layer 140 along the direction of the axial initialization electric field. Thus, each magnetoelectric multiferroic layer 140 can have a net non-zero axial ferroelectric polarization. In this case, each magnetoelectric multiferroic layer 140 can have a net nonzero magnetization that is associated with the net non-zero axial ferroelectric polarization. [0054] According to an aspect of the present disclosure, a magnetic memory device is provided, which comprises: a first electrode (comprising a portion of a first electrically conductive line 30); a second electrode (comprising a portion of a second electrically conductive line 90); and a layer stack (120, 132, 134, 136, 140, 170) located between the first electrode and the second electrode and comprising, from one side to another, a reference layer 132, a tunnel barrier layer 134, a free layer 136, and a magnetoelectric multiferroic layer 140 including at least one crystalline grain having an easy axis of magnetization along an axial direction or along a first tilted direction having a first tilt angle less than 90 degrees relative to the axial direction, the axial direction being perpendicular to an interface between the free layer 136 and the tunnel barrier layer 134.

[0055] In one embodiment, the layer stack (120, 132, 134, 136, 140, 170) also comprises a nonmagnetic capping layer 170 including a nonmagnetic metal and contacting the magnetoelectric multiferroic layer 140 and one of the first electrode and the second electrode.

In one embodiment, the magnetoelectric multiferroic layer 140 comprises, and/or consist essentially of, at least one material selected from BiFeO , h-YMnOa, BaNiF4, PbVOa, BiMnOa, LuFe2O4, HoMnaOa, h-HoMnOa, h-ScMnOa, h-ErMnOa, h-TmMnOa, h-YbMnOa, h-LuMnO₃, K2SeO₄, Cs₂Cdl4, TbMnO₃, Ni₃V₂O₈, MnW0₄, CuO, ZnCr₂Se₄, LiCu₂O₂, or Ni₃B70i₃I.

[0056] In one embodiment, a two-dimensional array of instances of the magnetic memory device of FIG. 2A or FIG. 2B can be provided. The magnetic memory array can comprise: first electrically conductive lines 30 that are parallel to each other and extend along a first direction, and second electrically conductive lines 90 that are parallel to each other and extend along a second direction that is perpendicular to the first direction. Each of the first electrically conductive lines 30 comprises first electrodes of a respective row of the instances of the magnetic memory device in the magnetic memory array. Each of the second electrically conductive lines 90 comprises second electrodes of a respective column of the instances of the magnetic memory device in the magnetic memory array.

[0057] In one embodiment, the magnetoelectric multiferroic layer 140 can have a net non- zero axial magnetization. The net in-plane ferromagnetic moment of the magnetoelectric multiferroic layer 140 may be zero (for axial multiferroic material) or not zero (for canted multiferroic material). Thus, the net in-plane magnetization of the magnetoelectric multiferroic layer 140 may be zero (for axial multiferroic material) or not zero (for canted multiferroic material).

[0058] FIG. 3A illustrates a cubic unit cell of BiFeO₃ with a direction of ferroelectric polarization P along one of the <111> family directions (e.g., the [111] direction) and a canted magnetic moment direction Me within the (111) plane. FIG. 3B illustrates the in plane (100) and out of plane (001) components of the magnetic moment direction Me in the

(111) plane. The relative spatial orientation (e.g., 90 degree angle) between the magnetic moment direction Me and the polarization direction P is the same for each magnetoelectric multiferroic unit cell. The out of plane (001) component of the canted magnetic moment direction Me of each multiferroic portion is magnetically coupled to the magnetization direction of corresponding free layer via exchange bias or coupling (e.g., ferromagnetic or antiferromagnetic coupling) at their interface.

[0059] In one embodiment, the easy axis of magnetization of polycrystalline grains of the magnetoelectric multiferroic layer 140 may be along the axial direction. In another embodiment, the easy axis of magnetization of polycrystalline grains of the magnetoelectric multiferroic layer 140 may be along a respective first tilted (i.e., canted) direction, such as one of the <111> directions.

[0060] Referring to FIGS. 4 A and 4B, magnetic states (which correspond to magnetoresistance states) of a magnetic tunnel junction device 180 in the first exemplary structure are illustrated. FIG. 4A illustrates a first magnetic state of the magnetic tunnel junction device 180, and FIG. 4B illustrates a second magnetic state of the magnetic tunnel junction device 180. The magnetization direction Mm of the magnetoelectric multiferroic layer 140 is magnetically coupled to the magnetization direction Mf of the free layer 136. Thus, in each of the first magnetic state and the second magnetic state of the magnetic tunnel junction device 180, the magnetization direction Mm of the magnetoelectric multiferroic layer 140 can be aligned to the magnetization direction Mf of the free layer 136. In FIG. 4 A, the magnetization direction Mf of the free layer 136 is parallel to the magnetization direction Mr of the reference layer 132. Thus, the magnetic tunnel junction device 180 (e.g., MRAM cell) is in the lower resistance state. In FIG. 4B, the magnetization direction Mf of the free layer 136 is antiparallel to the magnetization direction Mr of the reference layer 132. Thus, the magnetic tunnel junction device 180 (e.g., MRAM cell) is in the higher resistance state. [0061] Referring to FIG. 5, the programming mechanism for the magnetic memory device illustrated in FIGS. 4A and 4B is schematically illustrated. FIG. 5 illustrates the hysteresis curve for the axial electrical polarization of the magnetoelectric multiferroic layer 140 as a function of an external voltage applied across the second electrode and the first electrode, i.e., the external voltage as applied to the second electrode with respect to the first electrode. The direction of magnetization Mm of the magnetoelectric multiferroic layer 140 can be switched upon application of an electric voltage across the magnetoelectric multiferroic layer 140 that exceeds the magnitude of the coercive voltage (which may be VC+ or Vc- depending on the polarity) of the magnetoelectric multiferroic material of the magnetoelectric multiferroic layer 140. The positive coercive voltage VC+ and the negative coercive voltage Vc- may have equal magnitudes, and may differ from each other by the polarity.

[0062] FIG. 6A illustrates a first programming voltage pattern Pl that can be employed to program the magnetic tunnel junction device 180 into the lower resistance state in the configuration shown in FIG. 4A. FIG. 6B illustrates a second programming voltage pattern P2 that can be employed to program magnetic tunnel junction device 180 into the higher resistance state shown in FIG. 4B.

[0063] Referring to FIGS. 5 and 6A, the first programming voltage pattern Pl includes a first polarity voltage having a magnitude greater than the coercive voltage which is applied to magnetic tunnel junction device 180 between the first and second electrodes. In the embodiment of FIGS. 5 and 6 A, the first polarity voltage is a positive voltage VP1 having a magnitude greater than the coercive voltage (Vc+) which is applied to magnetic tunnel junction device 180 between the first and second electrodes. However, it should be understood that in an alternative embodiment, the first polarity voltage can be a negative voltage having a magnitude greater than the coercive voltage. The positive voltage deterministically programs the magnetization direction Mm of the magnetoelectric multiferroic layer 140 to be parallel to magnetization direction Mr of the reference layer 132. Furthermore, the positive voltage has a sufficient magnitude to lower the perpendicular magnetic anisotropy (“PMA”) and magnetic anisotropy barrier height at the interface between the tunnel barrier layer 134 and the free layer 136 to allow the free layer 136 to deterministically switch its magnetization direction Mf. Since the magnetization direction Mf of the free layer 136 is coupled to the magnetization direction Mm of the magnetoelectric multiferroic layer 140, the magnetization direction Mf of the free layer 136 is aligned to the direction of the magnetization of the Mm of the magnetoelectric multiferroic layer 140. Therefore, the magnetization direction Mf of the free layer 136 is deterministically programmed to be parallel to magnetization direction Mr of the reference layer 132, as shown in FIG. 4A. Thus, the magnetic tunnel junction device 180 is deterministically programmed into the lower resistance state.

[0064] Referring to FIGS. 5 and 6B, the second programming voltage pattern P2 includes a second polarity voltage opposite to the first polarity voltage having a magnitude greater than the coercive voltage which is applied to magnetic tunnel junction device 180 between the first and second electrodes. In the embodiment of FIGS. 5 and 6B, the second polarity voltage is a negative voltage VP2 having a magnitude greater than the coercive voltage (Vc-) which is applied to magnetic tunnel junction device 180 between the first and second electrodes. However, it should be understood that in an alternative embodiment, the second polarity voltage can be a positive voltage having a magnitude greater than the coercive voltage. The negative voltage deterministically programs the magnetization direction Mm of the magnetoelectric multiferroic layer 140 to be antiparallel to magnetization direction Mr of the reference layer 132. However, the negative voltage increases the perpendicular magnetic anisotropy (“PMA”) and magnetic anisotropy barrier height at the interface between the tunnel barrier layer 134 and the free layer 136 such that the free layer 136 cannot switch its magnetization direction Mf.

[0065] Therefore, the second programming voltage pattern P2 also includes a first polarity voltage having a magnitude less than the coercive voltage which is applied to magnetic tunnel junction device 180 between the first and second electrodes. In the embodiment of FIGS. 5 and 6B, the first polarity voltage is a positive voltage VP3 having a magnitude less than the coercive voltage (Vc+) which is applied to magnetic tunnel junction device 180 between the first and second electrodes. However, it should be understood that in an alternative embodiment, the first polarity voltage can be a negative voltage having a magnitude less than the coercive voltage.

The positive voltage VP3 does not have a sufficient magnitude to switch the magnetization direction Mm of the magnetoelectric multiferroic layer 140. However, the positive voltage VP3 does have a sufficient magnitude to lower the perpendicular magnetic anisotropy (“PMA”) and magnetic anisotropy barrier height at the interface between the tunnel barrier layer 134 and the free layer 136 to allow the free layer 136 to deterministically switch its magnetization direction Mf. Since the magnetization direction Mf of the free layer 136 is coupled to the magnetization direction Mm of the magnetoelectric multiferroic layer 140, the magnetization direction Mf of the free layer 136 is aligned to the direction of the magnetization of the Mm of the magnetoelectric multiferroic layer 140. Therefore, the magnetization direction Mf of the free layer 136 is deterministically programmed to be antiparallel to magnetization direction Mr of the reference layer 132, as shown in FIG. 4B. Thus, the magnetic tunnel junction device 180 is deterministically programmed into the higher resistance state when the negative voltage pulse VP2 is followed by the smaller positive voltage pulse VP3.

[0066] Referring to FIGS. 5, 6 A and 6B, the positive voltage pulse VP1 may have a magnitude between 0.5 V and 2 V, the negative voltage pulse VP2 may have a magnitude between -0.5 V and -2 V, and the third positive voltage pulse VP3 may have a magnitude between 0.3 V and 1 V, and which has an absolute value which is less than an absolute value of the negative voltage pulse VP2.

[0067] Generally, the magnetic memory device of the embodiments present disclosure can comprise a programming circuit, such as a component of the sensing and programming circuit 570 of the random access memory device 501 of FIG. 1 which applies the avoid voltages. Alternatively, each magnetic tunnel junction device 180 may be individually connected to a respective programming circuit configured to program a single magnetic tunnel junction device 180.

[0068] Referring to FIGS. 7 A and 7B, configurations of a second exemplary structure according to a second embodiment of the present disclosure are illustrated. The configurations of the second exemplary structure may be derived from the configurations of the first exemplary structure illustrated in FIGS. 2A and 2B by replacing the magnetoelectric multiferroic layer 140 with a VCMA assist structure 200 having an in-plane magnetization direction. In the configuration of FIGS. 7 A and 7B, the VCMA assist structure 200 comprises a magnetoelectric multiferroic layer 140’ having an in-plane magnetization direction Mm. The in-plane magnetization provides an in-plane magnetic dipolar magnetic field for VCMA processional switching. Layer 140’ may comprise a polycrystalline BiFeCL layer having a preferred grain orientation along the (111) plane can provide predominantly in-plane magnetization direction, i.e., more than 50 % all crystalline grains can have a respective magnetization direction (e.g., spin orientation) that is parallel to the interface between the tunnel barrier layer 134 and the free layer 136.

[0069] A net in-plane magnetization of the magnetoelectric multiferroic layer 140’ can be induced by application of an in-plane magnetic field or by application of an out-of-plane external electric field. Thus, a predominant portion (i.e., more than 50 % in volume) of the crystalline grains of the magnetoelectric multiferroic layer 140’ can have a net non-zero inplane magnetization. In this case, each magnetoelectric multiferroic layer 140’ can have a net non-zero ferroelectric polarization that is associated with the net non-zero in-plane magnetization. In other words, the net in-plane magnetization of each magnetoelectric multiferroic layer 140’ can be induced by applying external magnetic field along an in-plane direction that is parallel to the interface between the free layer 136 and the tunnel barrier layer 134. A net in-plane ferroelectric polarization of the magnetoelectric multiferroic layer 140’ and the net in-plane magnetization of the magnetoelectric multiferroic layer 140’ can be simultaneously induced by the external magnetic field.

[0070] According to another embodiment of the present disclosure, a net in-plane ferroelectric polarization can be induced within each magnetoelectric multiferroic layer 140’ within the array of magnetic tunnel junction devices 180 by application of an in-plane or out- of plane initialization electric field. The in-plane initialization electric field can be applied along a horizontal direction that is parallel to the interface between each free layer 136 and the tunnel barrier layer 134. The in-plane initialization electric field can align the in-plane component of the ferroelectric polarization of each crystalline grain in each magnetoelectric multiferroic layer 140’ along the direction of the in-plane initialization electric field. Thus, each magnetoelectric multiferroic layer 140’ can have a net non- zero in-plane ferroelectric polarization. In this case, each magnetoelectric multiferroic layer 140’ can have a net nonzero in-plane magnetization that is associated with the net non- zero in-plane ferroelectric polarization. In other words, the net in-plane magnetization of each magnetoelectric multiferroic layer 140’ can be induced by applying external electric field along an in-plane direction that is parallel to the interface between the free layer 136 and the tunnel barrier layer 134. A net in-plane ferroelectric polarization of each magnetoelectric multiferroic layer 140’ and the net in-plane magnetization of each magnetoelectric multiferroic layer 140’ can be simultaneously induced by the external electric field.

[0071] Generally, the magnitude of the net in-plane magnetization of each magnetoelectric multiferroic layer 140’ can be greater than the magnitude of any net axial magnetization of the respective magnetoelectric multiferroic layer 140’ by at least one order of magnitude, i.e., by a factor greater than 10 such as by a factor greater than 30 or 100.

[0072] Referring to FIG. 8, an alternative configuration of the second exemplary structure is illustrated, which can be derived from the configurations of the second exemplary structure illustrated in FIGS. 7A and 7B by using a VCMA assist structure 200 which comprises a ferromagnetic or ferrimagnetic layer 240 having an in-plane magnetization direction and an electrically conductive nonmagnetic spacer layer 138 located between the free layer 136 and the ferromagnetic or ferrimagnetic layer 240. The ferromagnetic or ferrimagnetic layer 240 may comprise a CoFe or CoFeB ferromagnetic layer or a Fe3O4 ferrimagnetic layer. The electrically conductive nonmagnetic spacer layer 138 may comprise any suitable nonmagnetic metal layer, such as Pt, Ta, Ru, W, etc. The thickness of each of layers 238 and 240 may be between 1 nm and 2 nm, although lesser and greater thicknesses may also be employed

[0073] Referring collectively to FIGS. 7A, 7B, and 8, a magnetic memory device is provided, which comprises: a first electrode (comprising portion of a first electrically conductive line 30); a second electrode (comprising portion of a second electrically conductive line 90); and a layer stack (optional 120, 132, 134, 136, 200, optional 170) located between the first electrode and the second electrode and comprising, from one side to another, a reference layer 132 having a fixed axial magnetization direction, a tunnel barrier layer 134, a free layer 136 having an easy axis of magnetization that is parallel or antiparallel to the fixed axial magnetization direction, and a VCMA assist structure 200 having an inplane magnetization direction.

[0074] In one embodiment, the VCMA assist structure comprises a magnetoelectric multiferroic layer 140’ including at least one crystalline grain which has an easy axis of magnetization that is parallel to an interface between the free layer 136 and the tunnel barrier layer 134, and a net in-plane magnetization of the magnetoelectric multiferroic layer 140’ is non-zero.

[0075] In one embodiment, the magnetoelectric multiferroic layer 140’ has a net ferroelectric polarization that is parallel to the interface between the free layer 136 and the tunnel barrier layer 134. In one embodiment, the magnetoelectric multiferroic layer 140’ can be poly crystalline, and a predominant subset in volume of crystalline grains i.e., a set of crystalline grains that occupy more than 50 % of the entire volume of the magnetoelectric multiferroic layer 140) within the magnetoelectric multiferroic layer 140’ can have a respective magnetization direction that is aligned, or has an angle less than 145 degrees from, a direction of the net in-plane magnetization of the magnetoelectric multiferroic layer 140’. In one embodiment, the net in-plane magnetization of the magnetoelectric multiferroic layer 140’ can be parallel to, or is antiparallel to, the direction of the net in-plane magnetization of the magnetoelectric multiferroic layer 140’.

[0076] In one embodiment, the magnetoelectric multiferroic layer 140’ comprises a material selected from BiFeO , h-YMnOa, BaNiF4, PbVOa, BiMnOa, LuFe2O4, HoMmOa, h- HoMnO₃, h-ScMnO₃, h-ErMnO₃, h-TmMnO₃, h-YbMnO₃, h-LuMnO₃, K2SeO₄, Cs₂CdI₄, TbMnO₃, Ni₃V20s, MnWCh, CuO, ZnCr₂Se4, LiCu2O2, and Ni₃B70i₃I. For example, the magnetoelectric multiferroic layer 140’ comprises a BiFeO₃ layer having a (111) preferred grain orientation and a thickness of 1 nm or less.

[0077] In one embodiment, the layer stack also includes the SAF structure 120. In one embodiment, the layer stack (optional 120, 132, 134, 136, 200, optional 170) comprises a nonmagnetic capping layer 170 including a nonmagnetic metal contacting the magnetoelectric multiferroic layer 140’ and one of the electrode and the second electrode. [0078] In another embodiment illustrated in FIG. 8, the VCMA assist structure 200 comprises a ferromagnetic or ferrimagnetic layer 240 having an in-plane magnetization direction and an electrically conductive nonmagnetic spacer layer 138 located between the free layer 136 and the ferromagnetic or ferrimagnetic layer 240.

[0079] Referring to FIGS. 9A and 9B, a first programmed state and a second programmed state of a second exemplary structure is illustrated. FIG. 9A illustrates the first programmed state, and FIG. 9B illustrates the second programmed state. The first programmed state (e.g., the lower resistance state) has a parallel alignment between the magnetization Mf of the free layer 136 and the magnetization Mr of the reference layer 132. The second programmed state (e.g., the higher resistance state) has an antiparallel alignment between the magnetization Mf of the free layer 136 and the magnetization Mr of the reference layer 132. The first programmed state of FIG. 9A and the second programmed state of FIG. 9B have different tunneling magnetoresistance values. Thus, the magnetic state of the magnetic tunnel junction device 180 in the second exemplary structure can be determined by applying a low voltage sensing bias voltage across the second electrode and the first electrode, and measuring the magnitude of the tunneling current through the magnetic tunnel junction device 180.

[0080] Referring to FIG. 10A, the second exemplary structure can include a sensing circuit (which may be a component of the sensing and programming circuit 570 illustrated in FIG. 1 or may be a stand-alone sensing circuit) configured to determine tunneling magnetoresistance of the layer stack (optional 120, 132, 134, 136, 200, optional 170) between the first electrode and the second electrode. The sensing circuit can be configured to determine whether the memory state of the magnetic memory device (i.e., the magnetic tunnel junction device 180) is in a target state or not by comparing a measured value of the tunneling magnetoresistance of the layer stack to a target value, which may be the target value for the parallel state illustrated in FIG. 9A or the target value for the antiparallel state illustrated in FIG. 9B.

[0081] The sensing circuit can be configured to apply a sensing pulse Vs of a first polarity. The first polarity can be selected such that the sensing pulse Vs increases perpendicular magnetic anisotropy of the free layer 136. In other words, the magnetization of the free layer 136 is less likely to make a transition between a parallel state and an antiparallel state. Thus, the sensing operation does not disturb the magnetic state of the magnetic tunnel junction device 180 of the second exemplary structure. For example, the sensing pulse may comprise a negative voltage pulse. In one embodiment, the absolute magnitude of the voltage of the sensing pulse Vs may be in a range from 0.05 V to 0.5 V such as from 0.1 V to 0.2 V, although lesser and greater voltages may also be employed. [0082] In case the sensing operation determines that the measured magnetic state of the magnetic tunnel junction device 180 is the same as the target magnetic state for the magnetic tunnel junction device 180, no further action is necessary.

[0083] Referring to FIG. 10B, in case the sensing operation determines that the measured magnetic state of the magnetic tunnel junction device 180 is the opposite of the target magnetic state of the magnetic tunnel junction device 180, a programming circuit may be employed to program the magnetic tunnel junction device 180 into the target magnetic state. The programming circuit may be a component of the sensing and programming circuit 570 illustrated in FIG. 1, or may be a discrete circuit configured to program a single magnetic tunnel junction device 180. The programming circuit can be configured to apply a VCMA programming voltage pulse Vp that induces precession of an angle between the magnetization direction of the free layer 136 and an axial direction that is perpendicular to the interface between the free layer 136 and the tunnel barrier layer 134 if, the magnetic memory device is not in the target state, and can be configured not to apply any programming voltage pulse if the magnetic memory device is in the target state.

[0084] The VCMA programming voltage pulse Vp non-deterministically programs the magnetic memory device without applying an external magnetic field. The VCMA programming voltage pulse Vp can have a second polarity that is an opposite of the first polarity. The programming voltage pulse Vp reduces the perpendicular magnetic anisotropy of the free layer 136. Thus, the programming voltage pulse Vp enables movement of the direction of the magnetization of the free layer 136. For example, the programming voltage Vp can be a 0.3 V to 1 V positive voltage pulse which has a greater absolute magnitude than the sensing pulse Vs.

[0085] The various embodiments of the present disclosure can be employed to provide a voltage controlled magnetic anisotropy (VCMA) tunnel magnetoresistance (TMR) memory device. The VCMA TMR device may have a deterministic switching mechanism as in the case of the first exemplary structure, or may have a pulse duration-controlled switching mechanism as in the case of the second exemplary structure. The outcome of programming is independent of the variations in the pulse magnitude or pulse duration in the case of the first exemplary structure due to the deterministic nature of the programming mechanism. The VCMA assist structure of the second exemplary structure provides a predictable and well controlled stray magnetic field (residual magnetic field) that determines the precession frequency of the angle between the magnetization of the free layer 136 and the vertical axis, thereby improving the accuracy and reliability of VCMA programming that switches the magnetic states. Furthermore, when the VCMA assist structure includes the in-plane multiferroic layer 140’, such multiferroic layer can provide additional PMA to free layer due to the hybridization of oxygen orbitals and metal 3d orbital.

[0086] Furthermore, the multiferroic layer, such as BiFeO , has a smaller resistivity than the typical tunnel barrier material (e.g., MgO). Since the multiferroic layer has similar thickness as the tunnel barrier layer, the multiferroic layer does not significantly increase the resistance of the memory device (i.e., does not add a significant parasitic resistance). Therefore, a relatively small sense voltage may be used to read the memory device without disturbing the written magnetic state similar to conventional VCMA MRAMs which lack a multiferroic layer.

[0087] Although the foregoing refers to particular preferred embodiments, it will be understood that the disclosure is not so limited. It will occur to those of ordinary skill in the art that various modifications may be made to the disclosed embodiments and that such modifications are intended to be within the scope of the disclosure. Where an embodiment employing a particular structure and/or configuration is illustrated in the present disclosure, it is understood that the present disclosure may be practiced with any other compatible structures and/or configurations that are functionally equivalent provided that such substitutions are not explicitly forbidden or otherwise known to be impossible to one of ordinary skill in the art. All of the publications, patent applications and patents cited herein are incorporated herein by reference in their entirety.

Claims

WHAT IS CLAIMED IS:

1. A magnetic memory device, comprising: a first electrode; a second electrode; and a layer stack located between the first electrode and the second electrode and comprising, from one side to another, a reference layer, a tunnel barrier layer, a free layer, and a magnetoelectric multiferroic layer including at least one crystalline grain having an easy axis of magnetization along an axial direction or along a first tilted direction having a first tilt angle less than 90 degrees relative to the axial direction, the axial direction being perpendicular to an interface between the free layer and the tunnel barrier layer.

2. The magnetic memory device of Claim 1, wherein the at least one crystalline grain of the magnetoelectric multiferroic layer has an easy axis of ferroelectric polarization along the axial direction or along a second tilted direction having a second tilt angle less than 90 degrees relative to the axial direction.

3. The magnetic memory device of Claim 1, further comprising a programming circuit configured to apply programming voltage patterns between the first electrode and the second electrode, wherein the programming voltage patterns comprise: a first programming voltage pattern comprising a first voltage having a first polarity and having a magnitude greater than a coercive voltage sufficient to switch a magnetization direction of the magnetoelectric multiferroic layer; and a second programming voltage pattern comprising a second voltage having a second

-32- polarity opposite to the first polarity and having a magnitude greater than the coercive voltage followed by a third voltage having the first polarity and having a magnitude less than the coercive voltage.

4. The magnetic memory device of Claim 3, wherein: the first voltage comprises a first positive voltage deterministically programs the magnetization direction of the magnetoelectric multiferroic layer to be parallel to a magnetization direction of the reference layer; and the first positive voltage has a sufficient magnitude to lower a perpendicular magnetic anisotropy of the free layer that allows the free layer to deterministically switch its magnetization direction to be parallel to the magnetization direction of the reference layer.

5. The magnetic memory device of Claim 4, wherein: the second voltage comprises a negative voltage which deterministically programs the magnetization direction of the magnetoelectric multiferroic layer to be antiparallel to the magnetization direction of the reference layer; and the negative voltage increases the perpendicular magnetic anisotropy of the free layer such that the free layer cannot switch its magnetization direction.

6. The magnetic memory device of Claim 5, wherein: the third voltage comprises a second positive voltage which does not have a sufficient magnitude to switch the magnetization direction of the magnetoelectric multiferroic layer; and the second positive voltage has a sufficient magnitude to lower the perpendicular

-33- magnetic anisotropy at the interface between the tunnel barrier layer and the free layer to allow the free layer to deterministically switch its magnetization direction to be antiparallel to magnetization direction of the reference layer.

7. The magnetic memory device of Claim 6, wherein: the first positive voltage pulse has a magnitude between 0.5 V and 2 V; the negative voltage pulse has a magnitude between -0.5 V and -2 V; and the second positive voltage pulse has a magnitude between 0.3 V and 1 V, and has an absolute value which is less than an absolute value of the negative voltage pulse.

8. The magnetic memory device of Claim 6, wherein the magnetization direction of the free layer is coupled to the magnetization direction of the magnetoelectric multiferroic layer.

9. The magnetic memory device of Claim 6, wherein: the magnetic memory device is programmed into a lower resistance state by the first programming voltage pattern; and the magnetic memory device is programmed into a higher resistance state by the second programming voltage pattern.

10. The magnetic memory device of Claim 1, wherein the easy axis of magnetization of the at least one crystalline grain of the magnetoelectric multiferroic layer is along the axial direction.

11. The magnetic memory device of Claim 1, wherein the easy axis of magnetization of the at least one crystalline grain of the magnetoelectric multiferroic layer is along the first tilted direction.

12. The magnetic memory device of Claim 1, wherein the layer stack further comprises a SAF structure located adjacent to the reference layer.

13. The magnetic memory device of Claim 1, wherein the layer stack further comprises a nonmagnetic electrically conductive capping layer contacting the magnetoelectric multiferroic layer and one of the electrode and the second electrode.

14. The magnetic memory device of Claim 1, wherein: the tunnel barrier layer comprises a dielectric layer having a thickness of 1 nm to 2 nm; and the magnetoelectric multiferroic layer comprises a material selected from BiFeO , h- YMnO₃, BaNiF4, PbVO₃, BiMnO₃, LuFe2O4, HoMmOa, h-HoMnO₃, h-ScMnO₃, h-ErMnO₃, h-TmMnO₃, h-YbMnCh, h-LuMnCh, K2SeO₄, Cs₂CdI₄, TbMnO₃, Ni₃V₂O₈, MnW0₄, CuO, ZnCr₂Se4, LiCu₂O₂, or Ni₃B70i₃I.

15. The magnetic memory device of Claim 14, wherein the magnetoelectric multiferroic layer comprises a BiFeO₃ layer having a thickness of 1 nm or less.

16. A method of programming the magnetic memory device of Claim 1, comprising: applying a first programming voltage pattern comprising a first voltage having a first polarity and having a magnitude greater than a coercive voltage sufficient to switch a magnetization direction of the magnetoelectric multiferroic layer; and applying a second programming voltage pattern comprising a second voltage having a second polarity opposite to the first polarity and having a magnitude greater than the coercive voltage followed by a third voltage having the first polarity and having a magnitude less than the coercive voltage.

17. The method of Claim 16, wherein: the first voltage comprises a first positive voltage which deterministically programs the magnetization direction of the magnetoelectric multiferroic layer to be parallel to a magnetization direction of the reference layer; and the first positive voltage has a sufficient magnitude to lower a perpendicular magnetic anisotropy at an interface between the tunnel barrier layer and the free layer to allow the free layer to deterministically switch its magnetization direction to be parallel to the magnetization direction of the reference layer.

18. The method of Claim 17, wherein: the second voltage comprises a negative voltage which deterministically programs the magnetization direction of the magnetoelectric multiferroic layer to be antiparallel to the magnetization direction of the reference layer; the negative voltage increases the perpendicular magnetic anisotropy of the free layer such that the free layer cannot switch its magnetization direction; the third voltage comprises a second positive voltage which does not have a sufficient magnitude to switch the magnetization direction of the magnetoelectric multiferroic layer; and

-36- the second positive voltage has a sufficient magnitude to lower the perpendicular magnetic anisotropy at the interface between the tunnel barrier layer and the free layer to allow the free layer to deterministically switch its magnetization direction to be antiparallel to magnetization direction of the reference layer.

19. The method of Claim 18, wherein: the first positive voltage pulse has a magnitude between 0.5 V and 2 V; the negative voltage pulse has a magnitude between -0.5 V and -2 V; and the second positive voltage pulse has a magnitude between 0.3 V and 1 V, and has an absolute value which is less than an absolute value of the negative voltage pulse.

20. The method of claim 18, wherein: the magnetization direction of the free layer is coupled to the magnetization direction of the magnetoelectric multiferroic layer; the magnetic memory device is deterministically programmed into a lower resistance state by the first programming voltage pattern; and the magnetic memory device is deterministically programmed into a higher resistance state by the second programming voltage pattern.

21. A magnetic memory device, comprising: a first electrode; a second electrode; and a layer stack located between the first electrode and the second electrode and comprising, from one side to another, a reference layer, a tunnel barrier layer, a free layer,

-37- and a voltage controlled magnetic anisotropy (VCMA) assist structure having an in-plane magnetization direction.

22. The magnetic memory device of Claim 21, wherein the VCMA assist structure comprises a magnetoelectric multiferroic layer including at least one crystalline grain having an easy axis of magnetization that is parallel to an interface between the free layer and the tunnel barrier layer, and a net in-plane magnetization of the magnetoelectric multiferroic layer is non-zero.

23. The magnetic memory device of Claim 22, wherein the magnetoelectric multiferroic layer has a net ferroelectric polarization that is parallel to the interface between the free layer and the tunnel barrier layer.

24. The magnetic memory device of Claim 22, wherein the magnetoelectric multiferroic layer is polycrystalline, wherein a predominant subset in volume of crystalline grains within the magnetoelectric multiferroic layer has a respective magnetization direction that is aligned to, or has an angle less than 145 degrees from a direction of the net in-plane magnetization of the magnetoelectric multiferroic layer.

25. The magnetic memory device of Claim 24, wherein the net in-plane magnetization of the magnetoelectric multiferroic layer is parallel to or is antiparallel to the direction of the net inplane magnetization of the magnetoelectric multiferroic layer.

26. The magnetic memory device of Claim 21, wherein the magnetoelectric multiferroic layer

-38- comprises a material selected from BiFeO , h-YMnOa, BaNiF4, PbVOa, BiMnOa, LuFe2C>4, HoM C , h-HoMnCh, h-ScMnCh, h-ErMnCh, h-TmMnCh, h-YbMnCh, h-LuMnCh, K2SeC>4, Cs₂Cdl4, TbMnO₃, Ni₃V₂O8, MnW0₄, CuO, ZnCr₂Se₄, LiCu₂O₂, and Ni₃B₇0i₃I.

27. The magnetic memory device of Claim 26, wherein the magnetoelectric multiferroic layer comprises a BiFeO₃ layer having a (111) preferred grain orientation and a thickness of 1 nm or less.

28. The magnetic memory device of Claim 21, wherein the VCMA assist structure comprises a ferromagnetic layer having an in-plane magnetization direction and an electrically conductive nonmagnetic spacer layer located between the free layer and the ferromagnetic layer.

29. The magnetic memory device of Claim 21, wherein the VCMA assist structure comprises a ferrimagnetic layer having an in-plane magnetization direction and an electrically conductive nonmagnetic spacer layer located between the free layer and the ferrimagnetic layer.

30. The magnetic memory device of Claim 21, wherein the layer stack further comprises a nonmagnetic capping layer including a nonmagnetic metal contacting the magnetoelectric multiferroic layer and one of the electrode and the second electrode.

31. The magnetic memory device of Claim 21, wherein the layer stack further comprises a

SAF structure contacting the reference layer.

-39-

32. The magnetic memory device of Claim 21, wherein the tunnel barrier layer comprises a dielectric layer having a thickness of 1 nm to 2 nm.

33. The magnetic memory device of Claim 21, further comprising a sensing circuit configured to determine tunneling magnetoresistance of the layer stack between the first electrode and the second electrode.

34. The magnetic memory device of Claim 33, further comprising programming circuit connected to the first electrode and the second electrode and configured to non- deterministically program the magnetic memory device using non-deterministic VCMA programming.

35. The magnetic memory device of Claim 34, wherein the programming circuit is configured to: to determine whether a memory state of the magnetic memory device is in a target state or not by comparing a measured value of the tunneling magnetoresistance of the layer stack to a target value; and to apply a programming voltage pulse that induces precession of an angle between a magnetization direction of the free layer and an axial direction that is perpendicular to the interface between the free layer and the tunnel barrier layer if the magnetic memory device is not in the target state, and not to apply any programming voltage pulse if the magnetic memory device is in the target state.

36. The magnetic memory device of Claim 35, wherein the in-plane magnetization of the

-40- VCMA assist structure induces precession of the angle between the magnetization direction of the free layer and the axial direction between 0 degree and 180 degrees upon application of the programming voltage pulse without applying an external magnetic field.

37. A method of operating the magnetic memory device of Claim 21, comprising determining tunneling magnetoresistance of the layer stack.

38. The method of Claim 37, further comprising non-deterministically programming the magnetic memory device without applying an external magnetic field by applying a VCMA programming voltage pulse between the first electrode and the second electrode.

39. The method of Claim 38, further comprising: determining whether a memory state of the magnetic memory device is in a target state or not by comparing a measured value of the tunneling magnetoresistance of the layer stack to a target value; and applying the VCMA programming voltage pulse that induces a precession of an angle between a magnetization direction of the free layer and an axial direction that is perpendicular to the interface between the free layer and the tunnel barrier layer if the magnetic memory device is not in the target state, and not applying any programming voltage pulse if the magnetic memory device is in the target state.

40. The method of Claim 39, wherein a duration of the programming voltage pulse is selected such that the angle between the magnetization direction and the axial direction changes by more than 135 degrees at an end of the programming voltage pulse.

-41-