Classifications

• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
  • A24B15/10—Chemical features of tobacco products or tobacco substitutes
  • A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B13/00—Tobacco for pipes, for cigars, e.g. cigar inserts, or for cigarettes; Chewing tobacco; Snuff
  • A24B13/02—Flakes or shreds of tobacco
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
  • A24B15/10—Chemical features of tobacco products or tobacco substitutes
  • A24B15/12—Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
  • A24B15/10—Chemical features of tobacco products or tobacco substitutes
  • A24B15/12—Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco
  • A24B15/14—Chemical features of tobacco products or tobacco substitutes of reconstituted tobacco made of tobacco and a binding agent not derived from tobacco
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
  • A24B15/18—Treatment of tobacco products or tobacco substitutes
  • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
  • A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
  • A24B15/18—Treatment of tobacco products or tobacco substitutes
  • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
  • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
  • A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
  • A24B15/18—Treatment of tobacco products or tobacco substitutes
  • A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
  • A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
  • A24B15/32—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by acyclic compounds
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
  • A24B3/00—Preparing tobacco in the factory
  • A24B3/14—Forming reconstituted tobacco products, e.g. wrapper materials, sheets, imitation leaves, rods, cakes; Forms of such products
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
  • A24D1/00—Cigars; Cigarettes
  • A24D1/20—Cigarettes specially adapted for simulated smoking devices
• • A—HUMAN NECESSITIES
  • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
  • A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
  • A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
  • A24F40/20—Devices using solid inhalable precursors

Definitions

• the present invention relates to aerosol generation.
• Smoking articles such as cigarettes, cigars and the like burn tobacco during use to create tobacco smoke.
• Alternatives to these types of articles release an inhalable aerosol or vapour by releasing compounds from a substrate material by heating without burning. These may be referred to as non-combustible smoking articles or aerosol generating assemblies.
• a heating device which release compounds by heating, but not burning, a solid aerosol-generating composition.
• This solid aerosolgenerating composition may, in some cases, contain a tobacco material.
• the heating volatilises at least one component of the material, typically forming an inhalable aerosol.
• These products may be referred to as heat-not-burn devices, tobacco heating devices or tobacco heating products.
• Various different arrangements for volatilising at least one component of the solid aerosol-generating composition are known.
• e-cigarette I tobacco heating product hybrid devices also known as electronic tobacco hybrid devices.
• These hybrid devices contain a liquid source (which may or may not contain nicotine) which is vaporised by heating to produce an inhalable vapour or aerosol.
• the device additionally contains a solid aerosol-generating composition (which may or may not contain a tobacco material) and components of this material are entrained in the inhalable vapour or aerosol to produce the inhaled medium.
• an aerosol-generating composition comprising an amorphous solid, the amorphous solid comprising:
• filler in an amount of at least about 15 wt% of the amorphous solid; wherein the amount of gelling agent and filler taken together is from about 20 to about 75 wt% of the amorphous solid, these weights being calculated on a dry weight basis.
• an aerosol-generating composition comprising an aerosol-generating material, the aerosol generating material comprising:
• filler in an amount of at least about 15 wt% of the amorphous solid; wherein the amount of gelling agent and filler taken together is from about 20 to 75 wt% of the aerosol-generating material, these weights being calculated on a dry weight basis.
• an aerosol-generating composition comprising:
• the aerosol-generating composition has an aerosol generating agent content of from about 5 to about 30wt% of the aerosol-generating composition, these weights being calculated on a dry weight basis.
• an article for use with a noncombustible aerosol provision device comprising an aerosol-generating composition as described herein.
• a non-combustible aerosol provision system comprising an article as described herein and a non-combustible aerosol provision device, wherein the non-combustible aerosol provision device is configured to generate aerosol from the article when the article is used with the non-combustible aerosol provision device.
• Another aspect provides a method of generating an aerosol using the non- combustible aerosol provision system, the method comprising heating the aerosolgenerating composition to a temperature of less than 350 °C.
• Another aspect provides use of the aerosol-generating composition, the article, or the non-combustible aerosol provision system to generate an aerosol.
• an aerosolgenerating composition comprising an amorphous solid, the method comprising:
• a method of making an aerosol-generating composition comprising: providing an amorphous solid as defined herein; providing tobacco material; and combining the amorphous solid and tobacco material to provide the aerosolgenerating composition, the aerosol-generating composition having an aerosol generating agent content of from about 5 to 30 wt% of the aerosol-generating composition, weights being calculated on a dry weight basis.
• a further aspect provides a method of making an amorphous solid as defined in the first aspect or an aerosol-generating material as defined in the second aspect, the method comprising making the amorphous solid or the aerosol-generating material using a paper-making process, such as an air-laid paper-making process.
• Figure 1 shows a section view of an example of an aerosol-generating article.
• Figure 2 shows a perspective view of the article of Figure 1.
• Figure 3 shows a sectional elevation of an example of an aerosol-generating article.
• Figure 4 shows a perspective view of the article of Figure 3.
• Figure 5 shows a perspective view of an example of an aerosol generating assembly.
• Figure 6 shows a section view of an example of an aerosol generating assembly.
• Figure 7 shows a perspective view of an example of an aerosol generating assembly.
• Aerosol-generating compositions described herein are compositions that are capable of generating aerosol, for example when heated, irradiated or energized in any other way. Aerosol-generating compositions may, for example, include features in the form of a solid, liquid or gel.
• the aerosol-generating compositions comprise an “amorphous solid”, which may alternatively be referred to as a “monolithic solid” (i.e. non-fibrous).
• the amorphous solid may be a dried gel.
• the amorphous solid is a solid material that may retain some fluid, such as liquid, within it.
• the aerosol-generating composition comprises an aerosol-generating material.
• the aerosol-generating material may alternatively be referred to as a “monolithic solid”.
• the aerosol-generating material may be non-fibrous or fibrous.
• the aerosol-generating material may be a dried gel.
• the aerosol-generating material may be a solid material that may retain some fluid, such as liquid, within it.
• the aerosol-generating material is a film.
• an aerosol-generating composition is suitable to be comprised in an article for use with a non-combustible aerosol provision device.
• the aerosol-generating composition comprises an amorphous solid and, optionally, tobacco material.
• an aerosol-generating material such as an amorphous solid
• an area density of about 80 to about 120 g/m 2 , such as about 100 g/m 2 , so that mixtures of the aerosol-generating material and tobacco (such as cut rag tobacco) do not readily separate.
• an aerosol-generating material to have sufficient tensile strength for the aerosol-generating material to be wound (e.g. in sheet form) onto a bobbin and unwound without breakages.
• Amorphous solids as defined herein can possess such favourable area densities and sufficient tensile strength to be wound onto and unwound from a bobbin (such as greater than or equal to about 250 N/m).
• the amorphous solid comprises:
• the amorphous solid comprises:
• filler in an amount of at least about 15 wt% of the amorphous solid; and wherein the amount of gelling agent and filler taken together is from about 20 to 65 wt% of the amorphous solid.
• the amorphous solid comprises gelling agent and filler, taken together, in an amount of from about 20 wt%, 25 wt%, 30 wt%, 35 wt%, 40 wt% or 45 wt% to about 75 wt%, 70 wt% 65 wt%, 60 wt%, or 55 wt% of the amorphous solid.
• the amorphous solid comprises gelling agent and filler, taken together, in an amount of about 20-65 wt%, 20-60 wt%, 25-55 wt%, 30-70 wt%, 35-65 wt%, 40-60 wt%, or 45-55 wt% of the amorphous solid.
• the amount of the gelling agent and filler, taken together, in the amorphous solid is from about 45 to about 55 or is about 50 wt%.
• the amorphous solid may comprise gelling agent (i.e. without taking into account the amount of filler) in an amount of from about 5 wt%, 10 wt%, 15 wt%, 17 wt% or 20 wt% to about 50 wt%, 45 wt%, 40 wt%, 35 wt%, 30 wt% or 25 wt% of the amorphous solid.
• the amorphous solid comprises gelling agent (i.e.
• the amount of filler in an amount of about 5 to 50 wt%, 10 to 50 wt%, 10 to 40 wt%, 15 to 30 wt%, 15 to 25 wt%, or 17 to 25 wt% of the amorphous solid.
• the amount of gelling agent in the amorphous solid is from about 15 to about 25 wt%.
• the amorphous solid comprises a gelling agent selected from methyl cellulose and/or guar gum.
• amorphous solids comprising guar gum or methyl cellulose exhibit good tensile strength and acceptable area densities. These gelling agents are also cheaper than alginic materials and may be more sustainable.
• guar gum is comprised in the gelling agent in an amount of from about 3 to 40 wt% of the amorphous solid. That is, the amorphous solid comprises guar gum in an amount of from about 3 to 40 wt% by dry weight of the amorphous solid. In some examples, the amorphous solid comprises guar gum in an amount of from about 3 wt%, 5 wt%, 7 wt%, 10 wt%, 15 wt%, 17 wt% or 20 wt% to about 40 wt%, 35 wt%, 30 wt% or 25 wt% of the amorphous solid.
• the amorphous solid comprises guar gum in an amount of from about 5 to 10 wt% of the amorphous solid. In some examples, the amorphous solid comprises guar gum in an amount of from about 15 to 40 wt% of the amorphous solid, or from about 20 to 40 wt%, or from about 15 to 35 wt%. In some particular examples, the amorphous solid comprises guar gum in an amount of about 7-40 wt %, 10-30 wt%, 15-30 wt %, 15-25 wt% or 17-25 wt% of the amorphous solid.
• the amorphous solid does not contain any alginate or pectin.
• Alginate and pectin gelling agents may be set by adding a setting agent (such as a calcium source) during formation of the amorphous solid.
• the amorphous solid may then comprise a calcium-crosslinked alginate and/or a calcium-crosslinked pectin.
• any calcium salts present in solvents used during preparation of the amorphous solid can cause premature crosslinking, which may complicate the preparation process.
• alginate or pectin gelling agents distilled water may be used as a solvent to assist in avoiding premature crosslinking.
• Amorphous solids which do not comprise any alginate or pectin as the gelling agent may not require use of a setting agent and/or may not be at risk of premature crosslinking during preparation.
• the gelling agent (b) may be methyl cellulose.
• the amount of the methyl cellulose may be about 7-40 wt% of the amorphous solid, such as 10-30 wt%, 15-30 wt%, 15- 25 wt%, or 17-25 wt%.
• the amorphous solid further comprises xanthan gum.
• the gelling agent (b) is methyl cellulose and the amorphous solid further comprises xanthan gum.
• Xanthan gum is a gelling agent.
• the amorphous solid may comprise the xanthan gum in an amount of about 0.5- 15 wt%, such as 1-10 wt% or 2-5 wt% of the amorphous solid.
• the amount of methyl cellulose is from about 5-30 wt%, such as about 10-25 wt or about 15-20 wt% of the amorphous solid and the amount of xanthan gum is 0.5-15 wt% such as 1-10 wt% or 2-5 wt% of the amorphous solid.
• the amorphous solid further comprises chitosan.
• Chitosan is a gelling agent which may improve the retention rate of certain effective compounds in the amorphous solid/aerosol-generating material.
• the use of chitosan may aid retention of glycerol within the amorphous solid/aerosol-generating material. This may help to reduce the tackiness of the surface of the amorphous solid, such as when it contains high concentrations of aerosol generating agent, and so may facilitate processing and/or handling of the amorphous solid/aerosol-generating material (during its manufacture and/or subsequent processing).
• chitosan may also improve the tensile strength of the amorphous solid/aerosol-generating material.
• Chitosan is a copolymer of D-glucosamine and /V-acetyl-D-glucosamine. Typically, chitosan is produced by /V-deacetylation of chitin through alkaline hydrolysis.
• the aerosol-generating material comprises chitosan in an amount of from about 0.01 wt%, 0.025 wt%, 0.05 wt% or 0.1 wt% to about 10 wt%, 5 wt%, 4 wt%, 3 wt% 2 wt %, 1 wt% or 0.7 wt% of the aerosol-generating material on a dry weight basis.
• the aerosol-generating material may comprise chitosan in an amount of about 0.01-10 wt%, such as 0.025-5 wt%, 0.05-2 wt %, 0.1-1 wt% or 0.1 -0.7 wt%.
• the amorphous solid further comprises hydroxypropyl starch and/or carboxymethyl starch sodium.
• Hydroxypropyl starch and carboxymethyl starch sodium are gelling agents.
• these may be used combination with guar gum.
• the gelling agent (b) is guar gum and the amorphous solid further comprises hydroxypropyl starch or carboxymethyl starch sodium.
• the amorphous solid comprises filler.
• the amorphous solid comprises filler in an amount of from 15 wt% of the amorphous solid, such as about 15 to 40 wt%.
• the amorphous solid comprises filler in an amount of about 20 to 40 wt%, or about 25 to 35 wt%.
• the filler may comprise one or more inorganic filler materials, such as calcium carbonate, perlite, vermiculite, diatomaceous earth, colloidal silica, magnesium oxide, magnesium sulphate, magnesium carbonate, and suitable inorganic sorbents, such as molecular sieves.
• inorganic filler materials such as calcium carbonate, perlite, vermiculite, diatomaceous earth, colloidal silica, magnesium oxide, magnesium sulphate, magnesium carbonate, and suitable inorganic sorbents, such as molecular sieves.
• the filler may comprise one or more organic filler materials such as wood pulp, tobacco pulp; hemp fibre; cellulose and cellulose derivatives, such as microcrystalline cellulose and/or nanocrystalline cellulose.
• microcrystalline cellulose may be formed by depolymerising cellulose by a chemical process (e.g. using an acid or enzyme).
• a chemical process e.g. using an acid or enzyme.
• One exemplary method for forming microcrystalline cellulose involves acid hydrolysis of cellulose, using an acid such as HCI.
• the cellulose produced after this treatment is crystalline (i.e. no amorphous regions remain). Suitable methods and conditions for forming microcrystalline cellulose are well-known in the art.
• the amorphous solid comprises no calcium carbonate such as chalk.
• the aerosol-generating composition comprises no calcium carbonate such as chalk.
• the filler is fibrous.
• the filler may be a fibrous organic filler material such as wood pulp, hemp fibre, cellulose or cellulose derivatives.
• fibrous filler in an amorphous solid may increase the tensile strength of the material. This may be particularly advantageous in examples wherein the amorphous solid is provided as a sheet, such as when an amorphous solid sheet circumscribes a rod of tobacco material.
• the filler is wood pulp.
• tackiness may arise when higher wt% levels of aerosol generating agents such as glycerol are used in the amorphous solid. Excessive tackiness may be undesirable as it can cause problems with handleability when processing the amorphous solid or the aerosol-generating composition. For example, it may be more difficult to shred a sheet of a tacky amorphous solid.
• the amorphous solid does not comprise tobacco fibres.
• the amorphous solid does not comprise tobacco material.
• Aerosol generating agent Aerosol generating agent
• the amorphous solid comprises aerosol generating agent in an amount of about 25 wt% to about 80 wt% of the amorphous solid. In some cases, the amorphous solid comprises aerosol generating agent in an amount of about 35-80 wt%, about 35-65 wt%, about 40-60 wt%, about 45-60 wt%, or about 45-55 wt%, such as about 50 wt%.
• the aerosol generating agent typically comprises one or more of glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1 ,3-butylene glycol, erythritol, meso-Erythritol, ethyl vanillate, ethyl laurate, a diethyl suberate, triethyl citrate, triacetin, a diacetin mixture, benzyl benzoate, benzyl phenyl acetate, tributyrin, lauryl acetate, lauric acid, myristic acid, and propylene carbonate.
• the aerosol generating agent comprises glycerol, optionally in combination with propylene glycol.
• the amorphous solid may have any suitable water content, such as from 1 wt % to 15 wt%.
• the water content of the amorphous solid is from about 5 wt%, 7 wt% or 9 wt% to about 15 wt%, 13 wt% or 11 wt% (WWB), for example from about 5 wt% to about 15 wt%, from about 7 wt% to about 13 wt% or from about 9 wt% to about 11 wt%.
• the water content of the amorphous solid may, for example, be determined by Karl-Fischer-titration or Gas Chromatography with Thermal Conductivity Detector (GC-TCD).
• the amorphous solid consists essentially of, or consists of, gelling agent, aerosol generating agent, filler, and water.
• the amorphous solid comprises, consists essentially of, or consists of guar gum, wood pulp, glycerol and water.
• the amorphous solid comprises, consists essentially of, or consists of methyl cellulose, wood pulp, glycerol and water.
• the aerosol-generating composition or amorphous solid may comprise one or more active substances.
• the amorphous solid comprises one or more active substances, e.g. up to about 50 wt%, or 40 wt %, or 30 wt%, or 20 wt% of the amorphous solid.
• the amorphous solid comprises active substance in an amount of from about 1 wt%, 5 wt%, 10 wt%, or 15 wt% to about 50 wt%, 40 wt%, 30 wt%, 20 wt%, 15 wt%, 10 wt% or 5wt% of the amorphous solid.
• the amorphous solid comprises about 20 wt% or less of active substances.
• the amorphous solid does not comprise an active substance. In particular examples, the amorphous solid does not comprise any tobacco or tobacco extract.
• the active substance may comprise a physiologically and/or olfactory active substance which is included in the amorphous solid or aerosol-generating composition in order to achieve a physiological and/or olfactory response.
• the active substance may for example be selected from nutraceuticals, nootropics, and psychoactives.
• the active substance may be naturally occurring or synthetically obtained.
• the active substance may comprise for example nicotine, caffeine, taurine, theine, a vitamin such as B6 or B12 or C, melatonin, a cannabinoid, or a constituent, derivative, or combinations thereof.
• the active substance comprises nicotine.
• the active substance comprises caffeine, melatonin or vitamin B12.
• the active substance may comprise a constituent, derivative or extract of tobacco or of another botanical such as cannabis, such as a cannabinoid or terpene.
• the active substance is a physiologically active substance and may be selected from nicotine, nicotine salts (e.g. nicotine ditartrate/nicotine bitartrate), nicotine-free tobacco substitutes, other alkaloids such as caffeine, cannabinoids, or mixtures thereof.
• Cannabinoids are a class of natural or synthetic chemical compounds which act on cannabinoid receptors (i.e., CB1 and CB2) in cells that repress neurotransmitter release in the brain.
• Cannabinoids Two of the most important cannabinoids are tetrahydrocannabinol (THC) and cannabidiol (CBD).
• Cannabinoids may be naturally occurring (Phytocannabinoids) from plants such as cannabis, (endocannabinoids) from animals, or artificially manufactured (Synthetic cannabinoids).
• Cannabinoids are cyclic molecules exhibiting particular properties such as the ability to easily cross the bloodbrain barrier, weak toxicity, and few side effects.
• Cannabis species express at least 85 different phytocannabinoids, and are divided into subclasses, including cannabigerols, cannabichromenes, cannabidiols, tetrahydrocannabinols, cannabinols and cannabinodiols, and other cannabinoids.
• Cannabinoids found in cannabis include, without limitation: cannabigerol (CBG), cannabichromene (CBC), cannabidiol (CBD), tetrahydrocannabinol (THC), cannabinol (CBN) and cannabinodiol (CBDL), cannabicyclol (CBL), cannabivarin (CBV), tetrahydrocannabivarin (THCV), cannabidivarin (CBDV), cannabichromevarin (CBCV), cannabigerovarin (CBGV), cannabigerol monomethyl ether (CBGM), cannabinerolic acid, cannabidiolic acid (CBDA), Cannabinol propyl variant (CBNV), cannabitriol (CBO), tetrahydrocannabmolic acid (THCA), and tetrahydrocannabivarinic acid (THCV A).
• CBD cannabigerol
• the active substance comprises one or more cannabinoid compounds selected from the group consisting of: cannabidiol (CBD), tetrahydrocannabinol (THC), tetrahydrocannabinolic acid (THCA), cannabidiolic acid (CBDA), cannabinol (CBN), cannabigerol (CBG), cannabichromene (CBC), cannabicyclol (CBL), cannabivarin (CBV), tetrahydrocannabivarin (THCV), cannabidivarin (CBDV), cannabichromevarin (CBCV), cannabigerovarin (CBGV), cannabigerol monomethyl ether (CBGM) and cannabielsoin (CBE), cannabicitran (CBT).
• CBD cannabidiol
• THC tetrahydrocannabinol
• THCA tetrahydrocannabinolic acid
• CBDA
• the active substance may comprise one or more cannabinoid compounds selected from the group consisting of cannabidiol (CBD) and THC (tetrahydrocannabinol).
• CBD cannabidiol
• THC tetrahydrocannabinol
• the active substance may comprise cannabidiol (CBD).
• the active substance may comprise nicotine and cannabidiol (CBD).
• CBD cannabidiol
• the active substance may comprise nicotine, cannabidiol (CBD), and THC (tetrahydrocannabinol).
• the active substance is an olfactory active substance and may be selected from a "flavour” and/or "flavourant” which, where local regulations permit, may be used to create a desired taste, aroma or other somatosensorial sensation in a product for adult consumers.
• a "flavour” and/or "flavourant” which, where local regulations permit, may be used to create a desired taste, aroma or other somatosensorial sensation in a product for adult consumers.
• such constituents may be referred to as flavours, flavourants, cooling agents, heating agents, or sweetening agents.
• flavour materials may include naturally occurring flavour materials, botanicals, extracts of botanicals, synthetically obtained materials, or combinations thereof (e.g., tobacco, cannabis, licorice (liquorice), hydrangea, eugenol, Japanese white bark magnolia leaf, chamomile, fenugreek, clove, maple, matcha, menthol, Japanese mint, aniseed (anise), cinnamon, turmeric, Indian spices, Asian spices, herb, Wintergreen, cherry, berry, red berry, cranberry, peach, apple, orange, mango, clementine, lemon, lime, tropical fruit, papaya, rhubarb, grape, durian, dragon fruit, cucumber, blueberry, mulberry, citrus fruits, Drambuie, bourbon, scotch, whiskey, gin, tequila, rum, spearmint, peppermint, lavender, aloe vera, cardamom, celery, cascarilla, nutmeg, sandalwood, bergamot,
• the flavour may be imitation, synthetic or natural ingredients or blends thereof. They may be in any suitable form, for example, liquid such as an oil, solid such as a powder, or gas.
• the flavour comprises menthol, spearmint and/or peppermint.
• the flavour comprises flavour components of cucumber, blueberry, citrus fruits and/or redberry.
• the flavour comprises eugenol.
• the flavour comprises flavour components extracted from tobacco.
• the flavour comprises flavour components extracted from cannabis.
• the flavour may comprise a sensate, which is intended to achieve a somatosensorial sensation which are usually chemically induced and perceived by the stimulation of the fifth cranial nerve (trigeminal nerve), in addition to or in place of aroma or taste nerves, and these may include agents providing heating, cooling, tingling, numbing effect.
• a suitable heat effect agent may be, but is not limited to, vanillyl ethyl ether and a suitable cooling agent may be, but not limited to eucalyptol, or WS-3 (/ ⁇ /-ethyl-2-isopropyl-5- methylcyclohexanecarboxamide).
• the amorphous solid does not comprise a flavour.
• botanical includes any material derived from plants including, but not limited to, extracts, leaves, bark, fibres, stems, roots, seeds, flowers, fruits, pollen, husk, shells or the like.
• the material may comprise an active compound naturally existing in a botanical, obtained synthetically.
• the material may be in the form of liquid, gas, solid, powder, dust, crushed particles, granules, pellets, shreds, strips, sheets, or the like.
• Examples of botanicals are tobacco, eucalyptus, star anise, hemp, cocoa, cannabis, fennel, lemongrass, peppermint, spearmint, rooibos, chamomile, flax, ginger, ginkgo biloba, hazel, hibiscus, laurel, licorice (liquorice), matcha, mate, orange skin, papaya, rose, sage, tea such as green tea or black tea, thyme, clove, cinnamon, coffee, aniseed (anise), basil, bay leaves, cardamom, coriander, cumin, nutmeg, oregano, paprika, rosemary, saffron, lavender, lemon peel, mint, juniper, elderflower, vanilla, Wintergreen, beefsteak plant, curcuma, turmeric, sandalwood, cilantro, bergamot, orange blossom, myrtle, cassis, valerian, pimento, mace, damien, marjoram, olive,
• the mint may be chosen from the following mint varieties: Mentha arvensis, Mentha c.v., Mentha niliaca, Mentha piperita, Mentha piperita citrata c.v., Mentha piperita c.v., Mentha spicata crispa, Mentha cordifolia, Mentha longifolia, Mentha suaveolens variegata, Mentha pulegium, Mentha spicata c.v. and Mentha suaveolens.
• the botanical is selected from eucalyptus, star anise, cocoa and hemp, particularly eucalyptus or star anise
• the botanical is selected from rooibos and fennel.
• the amorphous solid does not contain any botanical.
• the amorphous solid or aerosol-generating composition may further comprise one or more other functional materials.
• the one or more other functional materials may comprise one or more of pH regulators, colouring agents, preservatives, stabilizers, and/or antioxidants.
• the aerosol-generating composition or the amorphous solid may comprise an acid.
• the acid may be an organic acid.
• the acid may be at least one of a monoprotic acid, a diprotic acid and a triprotic acid.
• the acid may contain at least one carboxyl functional group.
• the acid may be at least one of an alpha-hydroxy acid, carboxylic acid, dicarboxylic acid, tricarboxylic acid and keto acid.
• the acid may be an alpha-keto acid.
• the acid may be at least one of succinic acid, lactic acid, benzoic acid, citric acid, tartaric acid, fumaric acid, levulinic acid, acetic acid, malic acid, formic acid, sorbic acid, benzoic acid, propanoic and pyruvic acid.
• the acid is lactic acid.
• the acid is benzoic acid.
• the acid may be an inorganic acid.
• the acid may be a mineral acid.
• the acid may be at least one of sulphuric acid, hydrochloric acid, boric acid and phosphoric acid.
• the acid is levulinic acid.
• an acid is particularly preferred in embodiments in which the aerosol-generating composition or the amorphous solid comprises nicotine.
• the presence of an acid may stabilise dissolved species in the slurry from which the aerosol-generating composition or the amorphous solid is formed.
• the presence of the acid may reduce or substantially prevent evaporation of nicotine during drying of the slurry, thereby reducing loss of nicotine during manufacturing.
• the amorphous solid may comprise a colourant.
• the addition of a colourant may alter the visual appearance of the amorphous solid.
• the presence of colourant in the amorphous solid may enhance the visual appearance of the amorphous solid and the aerosol-generating composition.
• the amorphous solid may be colour-matched to other components of the aerosolgenerating composition or to other components of an article comprising the amorphous solid.
• colourants may be used depending on the desired colour of the amorphous solid.
• the colour of amorphous solid may be, for example, white, green, red, purple, blue, brown or black. Other colours are also envisaged.
• Natural or synthetic colourants such as natural or synthetic dyes, food-grade colourants and pharmaceutical-grade colourants may be used.
• the colourant is caramel, which may confer the amorphous solid with a brown appearance.
• the colour of the amorphous solid may be similar to the colour of other components (such as tobacco material) in an aerosol-generating composition comprising the amorphous solid.
• the addition of a colourant to the amorphous solid renders it visually indistinguishable from other components in the aerosol-generating composition.
• the colourant may be incorporated during the formation of the amorphous solid (e.g. when forming a slurry comprising the materials that form the amorphous solid) or it may be applied to the amorphous solid after its formation (e.g. by spraying it onto the amorphous solid).
• One aspect of the invention provides an aerosol-generating composition comprising an amorphous solid as defined herein.
• the aerosol-generating composition comprises tobacco material in addition to the amorphous solid as described herein, and the aerosol-generating composition has an aerosol generating agent content of from about 5 to about 30 wt% of the aerosol-generating composition, these weights being calculated on a dry weight basis.
• the tobacco material does not form part of the amorphous solid, that is it is present in the aerosol-generating composition separately to the amorphous solid.
• tobacco material refers to any material comprising tobacco or derivatives therefore.
• tobacco material may include one or more of tobacco, tobacco derivatives, expanded tobacco, reconstituted tobacco or tobacco substitutes.
• the tobacco material may comprise one or more of ground tobacco, tobacco fibre, cut tobacco, extruded tobacco, tobacco stem, reconstituted tobacco and/or tobacco extract.
• the tobacco used to produce tobacco material may be any suitable tobacco, such as single grades or blends, cut rag or whole leaf, including Virginia and/or Burley and/or Oriental. It may also be tobacco particle ‘fines’ or dust, expanded tobacco, stems, expanded stems, and other processed stem materials, such as cut rolled stems.
• the tobacco material may be a ground tobacco or a reconstituted tobacco material.
• the reconstituted tobacco material may comprise tobacco fibres, and may be formed by casting, a Fourdrinier-based paper making-type approach with back addition of tobacco extract, or by extrusion.
• the aerosol-generating composition of these embodiments comprises aerosol generating agent in an amount of from about 10 to about 20 wt%, or about 13 to about 17 wt%. In examples, the aerosol-generating composition comprises aerosol generating agent in an amount of about 15 wt%. This amount includes any aerosol generating agent present in the aerosol-generating composition, such as aerosol generating agent provided in the amorphous solid and any aerosol generating agent loaded on to the tobacco material.
• a cut rag tobacco blend which might typically be used alone in a conventional combustible smoking article such as a cigarette has been found to be unsuitable for use in a non-combustible aerosol provision device. Without wishing to be bound be theory, it is believed that a cut rag tobacco blend for use in a cigarette typically cannot be loaded with sufficient aerosol generating agent to provide a desirable inhalable aerosol when heated by a non-combustible aerosol provision device.
• Paper reconstituted tobacco can typically contain a greater proportion of aerosol generating agent.
• a tobacco blend which comprises a high proportion of paper reconstituted tobacco may have undesirable sensory characteristics when heated by a non-combustible aerosol provision device.
• the tobacco material comprises or consists of lamina tobacco (such as cut rag tobacco), which provides desirable sensory characteristics.
• the tobacco material comprises reconstituted tobacco in an amount less than about 50 wt%, 30 wt%, 10 wt%, 5 wt%, or 1 wt% by dry weight of the tobacco material.
• the tobacco material substantially does not comprise reconstituted tobacco.
• the tobacco material is typically present in the aerosol-generating composition in an amount of about 50 to 95 wt%, or about 60 to 95 wt%, or about 60 to 90 wt%, or about 70 to 90 wt%, or about 75 to 85 wt% or about 80 to 90 wt%.
• the tobacco material may be present in any format, but is typically fine-cut (e.g. cut into narrow shreds). Fine-cut tobacco material may advantageously be blended with the amorphous solid to provide an aerosol-generating composition which has an even dispersion of tobacco material and amorphous solid throughout the aerosolgenerating composition.
• the tobacco material comprises one or more of ground tobacco, tobacco fibre, cut tobacco, extruded tobacco, tobacco stem, reconstituted tobacco and/or tobacco extract. It is possible to use a relatively large amount of lamina tobacco in the aerosol-generating composition and still provide an acceptable aerosol when heated by a non-combustible aerosol provision system. Lamina tobacco typically provides superior sensory characteristics.
• the tobacco material comprises lamina tobacco in an amount of at least about 50 wt%, 60 wt%, 70 wt%, 80 wt%, 85 wt%, 90 wt%, or 95 wt% of the tobacco material.
• the tobacco material comprises cut tobacco in an amount of at least about 50 wt%, 60 wt%, 70 wt%, 80 wt%, 85 wt%, 90 wt%, or 95 wt% of the tobacco material.
• the tobacco used to produce tobacco material may be any suitable tobacco, such as single grades or blends, cut rag or whole leaf, including Virginia and/or Burley and/or Oriental.
• the amorphous solid is present in the aerosol-generating composition in any amount such that the overall aerosol generating agent content of the aerosol-generating composition is from about 5 to 30 wt% of the aerosol-generating composition.
• the amorphous solid is comprised in the aerosol-generating composition in an amount of from about 5 to 40 wt%, 10 to 30 wt%, 15 to 25 wt%, or 17 to 23 wt%.
• the aerosol-generating composition comprises amorphous solid in an amount of about 20 wt% of the aerosol-generating composition.
• the amorphous solid is present in the aerosol-generating composition in an amount of about 5 to 40 wt%, 5 to 30 wt%, 5 to 25 wt%, or 10 to 25 wt% or 10 to 20 wt%.
• a relatively small amount of amorphous solid e.g. around 10 to 20 wt% can be employed in the aerosol-generating composition while still achieving a desirable aerosol in use with a non-combustible aerosol provision system.
• the tobacco material itself comprises aerosol generating agent, such as an aerosol generating agent as described above.
• the tobacco material comprises tobacco which is fine-cut, and aerosol generating agent is loaded onto the shreds of tobacco.
• the tobacco material comprises aerosol generating agent in an amount of from about 1 to 10 wt% of the tobacco material, such as about 3 to 6 wt%.
• the aerosol generating agents defined above in relation to the amorphous solid are also suitable for use in the tobacco material.
• the amorphous solid is present in the aerosol-generating composition in any suitable form.
• the amorphous solid is present in sheet form.
• the amorphous solid is present as a shredded sheet (e.g. the aerosol-generating composition comprises shreds of amorphous solid).
• the amorphous solid is present as a shredded sheet and is blended with tobacco material which is fine-cut and/or shredded, e.g. the amorphous solid and tobacco material are in a similar form.
• providing both the amorphous solid and tobacco material as shreds I fine-cut portions allows for an aerosol-generating composition blend which has an even dispersion of amorphous solid and tobacco material throughout the aerosol-generating composition.
• the amorphous solid may be present on or in a support to form a substrate.
• the support functions as a support on which the amorphous solid layer forms, easing manufacture.
• the support may provide rigidity to the amorphous solid layer, easing handling.
• the support may be any suitable material which can be used to support an amorphous solid.
• the support may be formed from materials selected from metal foil, paper, carbon paper, greaseproof paper, ceramic, carbon allotropes such as graphite and graphene, plastic, cardboard, wood or combinations thereof.
• the support may comprise or consist of a tobacco material, such as a sheet of reconstituted tobacco.
• the support may be formed from materials selected from metal foil, paper, cardboard, wood or combinations thereof.
• the support comprises paper.
• the support itself be a laminate structure comprising layers of materials selected from the preceding lists.
• the support may also function as a flavour support.
• the support may be impregnated with a flavourant or with tobacco extract.
• the thickness of any support layer may be in the range of about 10pm, 15pm, 17pm, 20pm, 23pm, 25pm, 50pm, 75pm or 0.1mm to about 2.5mm, 2.0mm, 1.5mm, 1.0mm or 0.5mm.
• the support may comprise more than one layer, and the thickness described herein refers to the aggregate thickness of those layers.
• the support may have a thickness of between about 0.017mm and about 2.0mm, suitably from about 0.02mm, 0.05mm or 0.1 mm to about 1.5mm, 1.0mm, or 0.5mm.
• the surface of the support that abuts the amorphous solid may be porous.
• the support comprises paper. It has been found that a porous support such as paper is particularly suitable: the porous (e.g. paper) layer abuts the amorphous solid layer and forms a strong bond.
• the amorphous solid may be formed by drying a slurry and, without being limited by theory, it is thought that the slurry partially impregnates the porous support (e.g. paper) so that the support is partially bound into the amorphous solid. This provides a strong binding between the amorphous solid and the support.
• surface roughness may contribute to the strength of bond between the amorphous material and the support.
• Paper roughness (for the surface abutting the support) may suitably be in the range of 50-1000 Bekk seconds, suitably 50-150 Bekk seconds, suitably 100 Bekk seconds (measured over an air pressure interval of 50.66-48.00 kPa).
• a Bekk smoothness tester is an instrument used to determine the smoothness of a paper surface, in which air at a specified pressure is leaked between a smooth glass surface and a paper sample, and the time (in seconds) for a fixed volume of air to seep between these surfaces is the "Bekk smoothness”.
• the support is formed from or comprises metal foil, such as aluminium foil.
• a metallic support may allow for better conduction of thermal energy to the amorphous solid.
• a metal foil may function as a susceptor in an induction heating system.
• the amorphous solid may have any suitable area density (mass per unit area), such as from 30 g/m 2 to 120 g/m 2 .
• the amorphous solid has an area density of from about 80 to 120 g/m 2 , or from about 70 to 110 g/m 2 , or particularly from about 90 to 110 g/m 2 , or suitably about 100 g/m 2 (so that it will not readily separate when mixed with tobacco, such as cut rag tobacco).
• Such area densities may be particularly suitable where the amorphous solid is included in an aerosol-generating article/assembly in sheet form, or as a shredded sheet (described further herein below).
• the amorphous solid has an area density which is from about 90 to 110% of the area density of any tobacco material in the aerosol-generating composition. That is, the amorphous solid and the tobacco material have similar area densities. Configuring the amorphous solid and tobacco material to have similar area densities allows for better blending of the amorphous solid and tobacco material, typically when provided as shredded sheet. For example, shredded amorphous solid sheet and cut rag tobacco which have similar area densities can be blended to provide a more homogenous aerosol-generating composition (e.g. better distribution of each component throughout the aerosol-generating composition).
• Fine cut tobacco (such as cut rag tobacco) has a cut width, typically represented as CPI (cuts per inch), and refers to the width of a shred of tobacco.
• Amorphous solid which is provided as a solid sheet has a cut width.
• the cut width of the amorphous solid is from about 90 to 110% of the cut width of the cut rag tobacco. That is, the amorphous solid and the tobacco material have cut widths, or shred widths. Configuring the amorphous solid and tobacco material to have similar cut widths allows for better blending of the amorphous solid and tobacco material.
• shredded amorphous solid sheet and cut rag tobacco which have similar cut widths can be blended to provide a more homogenous aerosol-generating composition (e.g. better distribution of each component throughout the aerosol-generating composition).
• the tobacco material may have a length of 1-4 cm.
• the amorphous solid in sheet form may have sufficient tensile strength such that it can be wound onto, or unwound from, a bobbin without breakages. In some examples, the amorphous solid in sheet form has a tensile strength of greater than or equal to about 250 N/m.
• Another aspect of the invention provides a method of making an aerosolgenerating composition described herein.
• a first method of making an aerosol-generating composition comprising an amorphous solid, the method comprising:
• a second method of making an aerosol-generating composition comprising: providing an amorphous solid comprising:
• filler in an amount of at least about 15 wt% of the amorphous solid, wherein the amount of gelling agent and filler taken together is from about 20 to 75 wt% of the amorphous solid;
• any optional further components of the amorphous solid providing tobacco material; and combining the amorphous solid and tobacco material to provide the aerosolgenerating composition, the aerosol-generating composition having an aerosol generating agent content of from about 5 to 30 wt% of the aerosol-generating composition, weights being calculated on a dry weight basis.
• the amorphous solid is provided as a shredded sheet.
• the providing the amorphous solid comprises shredding a sheet of the amorphous solid to provide the amorphous solid as a shredded sheet.
• the tobacco material is fine-cut, and the combining the amorphous solid and tobacco material comprises blending the shredded sheet of amorphous solid with the fine-cut tobacco material.
• the providing the amorphous solid comprises (i) forming a slurry comprising components of the amorphous solid or precursors thereof, (ii) forming a layer of the slurry, and (iii) drying the slurry to form an amorphous solid.
• the (ii) forming a layer of the slurry typically comprises spraying, casting or extruding the slurry.
• the slurry layer is formed by electrospraying the slurry.
• the slurry layer is formed by casting the slurry.
• the slurry is applied to a support.
• the layer may be formed on a support.
• the slurry comprises gelling agent, aerosol generating agent, and filler.
• the slurry may comprise these components in any of the proportions given herein in relation to the composition of the amorphous solid.
• the slurry may comprise (on a dry weight basis): gelling agent and filler, wherein the amount of gelling agent and filler taken together is about 20 to 75 wt% of the slurry; and aerosol generating agent in an amount of about 25 to 80 wt% of the slurry;
• the drying (iii) removes from about 50 wt%, 60 wt%, 70 wt%, 80 wt% or 90 wt% to about 80 wt%, 90 wt% or 95 wt% (wet weight basis, WWB) of water in the slurry.
• the drying (iii) reduces the cast material thickness by at least 80%, suitably 85% or 87%. For instance, if the slurry is cast at a thickness of 2 mm, the resulting dried amorphous solid material may have a thickness of 0.2 mm.
• the dried amorphous solid material forms a sheet or layer with a thickness of about 0.015 mm to about 1 .0 mm.
• the thickness may be in the range of about 0.05 mm, 0.1 mm or 0.15 mm to about 0.5 mm or 0.3 mm, for example 0.05-0.3 or 0.15-0.3 mm.
• a material having a thickness of 0.2 mm may be particularly suitable.
• the slurry solvent consists essentially of or consists of water.
• the slurry comprises from about 50 wt%, 60 wt%, 70 wt%, 80 wt% or 90 wt% of solvent (WWB).
• a further aspect provides a method for making an amorphous solid or aerosolgenerating material as described herein using a paper-making process.
• the paper-making process is an air-laid paper-making process.
• Use of an air-laid paper-making process reduces water consumption.
• a suitable air-laid paper-making process is discussed in US9901112B2, the disclosure of which is incorporated herein by reference.
• An aspect also provides a method for making an aerosol-generating composition comprising an amorphous solid or aerosol-generating material as described herein, the method comprising making the amorphous solid or the aerosol-generating material using a paper-making process, such as an air-laid paper-making process.
• the air-laid process comprises:
• the spraying step (c) and the drying step (d) are repeated, for example 2 or 3 times.
• An aspect of the present invention relates to an article for use with a noncombustible aerosol provision system.
• the article comprises the aerosol-generating composition described herein.
• a consumable is an article, part or all of which is intended to be consumed during use by a user.
• a consumable may comprise or consist of aerosol-generating composition.
• a consumable may comprise one or more other elements, such as a filter or an aerosol modifying substance.
• a consumable may comprise a heating element that emits heat to cause the aerosol-generating composition to generate aerosol in use.
• the heating element may, for example, comprise combustible material, or may comprise a susceptor that is heatable by penetration with a varying magnetic field.
• a susceptor is material that is heatable by penetration with a varying magnetic field, such as an alternating magnetic field.
• the heating material may be an electrical ly-conductive material, so that penetration thereof with a varying magnetic field causes induction heating of the heating material.
• the heating material may be magnetic material, so that penetration thereof with a varying magnetic field causes magnetic hysteresis heating of the heating material.
• the heating material may be both electrically-conductive and magnetic, so that the heating material is heatable by both heating mechanisms.
• Induction heating is a process in which an electrically-conductive object is heated by penetrating the object with a varying magnetic field.
• An induction heater may comprise an electromagnet and a device for passing a varying electrical current, such as an alternating current, through the electromagnet.
• a varying electrical current such as an alternating current
• the electromagnet and the object to be heated are suitably relatively positioned so that the resultant varying magnetic field produced by the electromagnet penetrates the object, one or more eddy currents are generated inside the object.
• the object has a resistance to the flow of electrical currents. Therefore, when such eddy currents are generated in the object, their flow against the electrical resistance of the object causes the object to be heated. This process is called Joule, ohmic, or resistive heating.
• the susceptor is in the form of a closed circuit. It has been found that, when the susceptor is in the form of a closed circuit, magnetic coupling between the susceptor and the electromagnet in use is enhanced, which results in greater or improved Joule heating.
• Magnetic hysteresis heating is a process in which an object made of a magnetic material is heated by penetrating the object with a varying magnetic field.
• a magnetic material can be considered to comprise many atomic-scale magnets, or magnetic dipoles. When a magnetic field penetrates such material, the magnetic dipoles align with the magnetic field. Therefore, when a varying magnetic field, such as an alternating magnetic field, for example as produced by an electromagnet, penetrates the magnetic material, the orientation of the magnetic dipoles changes with the varying applied magnetic field. Such magnetic dipole reorientation causes heat to be generated in the magnetic material.
• Articles of the present invention may be provided in any suitable shape.
• the article is provided as a rod (e.g. substantially cylindrical).
• the aerosol-generating composition includes the amorphous solid as a shredded sheet, optionally blended with the tobacco material (e.g. cut tobacco).
• the tobacco material e.g. cut tobacco.
• an article having a substantially cylindrical shape comprising aerosol-generating composition which includes amorphous solid as a shredded sheet blended with tobacco material.
• the article provided as a rod may include the amorphous solid as a sheet, such as a sheet circumscribing a rod of tobacco material.
• An aspect provides a non-combustible aerosol provision system comprising an article as described herein and a non-combustible aerosol provision device, wherein the non-combustible aerosol provision device is configured to generate aerosol from the article when the article is used with the non-combustible aerosol provision device.
• An aspect of the invention provides non-combustible aerosol provision system comprising an article as described herein and non-combustible aerosol provision device comprising a heater which is configured to heat not burn the aerosol-generating article.
• a non-combustible aerosol provision system may also be referred to as an aerosol generating assembly.
• a non-combustible aerosol provision device may be referred to as an aerosol generating apparatus.
• the heater may heat, without burning, the aerosolgenerating composition to a temperature equal to or less than 350 °C, such as between 120°C and 350 °C. In some cases, the heater may heat, without burning, the aerosolgenerating composition to between 140 °C and 250 °C in use, or between 220 °C and 280 °C.
• the heater is configured to heat not burn the aerosol-generating article, and thus the aerosol-generating composition.
• the heater may be, in some cases, a thin film, electrically resistive heater. In other cases, the heater may comprise an induction heater or the like.
• the heater may be a combustible heat source or a chemical heat source which undergoes an exothermic reaction to product heat in use.
• the aerosol generating assembly may comprise a plurality of heaters. The heater(s) may be powered by a battery.
• the aerosol-generating article may additionally comprise a cooling element and/or a filter.
• the cooling element if present, may act or function to cool gaseous or aerosol components. In some cases, it may act to cool gaseous components such that they condense to form an aerosol. It may also act to space the very hot parts of the non-combustible aerosol provision device from the user.
• the filter if present, may comprise any suitable filter known in the art such as a cellulose acetate plug.
• the non-combustible aerosol provision system may be a heat- not-burn system. That is, it may contain a solid material (and no liquid aerosolgenerating material).
• a heat-not-burn device is disclosed in WO 2015/062983 A2, which is incorporated by reference in its entirety.
• the aerosol-generating article (which may be referred to herein as an article, a cartridge or a consumable) may be adapted for use in a THP, an electronic tobacco hybrid device or another aerosol generating device.
• the article may additionally comprise a filter and/or cooling element (which have been described above).
• the aerosol-generating article may be circumscribed by a wrapping material such as paper.
• the article is adapted for use with a tobacco heating product.
• the aerosol-generating article may additionally comprise ventilation apertures. These may be provided in the sidewall of the article. In some cases, the ventilation apertures may be provided in the filter and/or cooling element. These apertures may allow cool air to be drawn into the article during use, which can mix with the heated volatilised components thereby cooling the aerosol.
• the ventilation enhances the generation of visible heated volatilised components from the article when it is heated in use.
• the heated volatilised components are made visible by the process of cooling the heated volatilised components such that supersaturation of the heated volatilised components occurs.
• the heated volatilised components then undergo droplet formation, otherwise known as nucleation, and eventually the size of the aerosol particles of the heated volatilised components increases by further condensation of the heated volatilised components and by coagulation of newly formed droplets from the heated volatilised components.
• the ratio of the cool air to the sum of the heated volatilised components and the cool air is at least 15%.
• a ventilation ratio of 15% enables the heated volatilised components to be made visible by the method described above. The visibility of the heated volatilised components enables the user to identify that the volatilised components have been generated and adds to the sensory experience of the smoking experience.
• the ventilation ratio is between 50% and 85% to provide additional cooling to the heated volatilised components. In some cases, the ventilation ratio may be at least 60% or 65%.
• the aerosol-generating composition and/or the amorphous solid may be included in the article/assembly in sheet form. In some cases, the aerosolgenerating composition and/or amorphous solid may be included as a planar sheet. In some cases, the aerosol-generating composition and/or amorphous solid may be included as a planar sheet, as a bunched or gathered sheet, as a crimped sheet, or as a rolled sheet (i.e. in the form of a tube). In some such cases, the amorphous solid of these embodiments may be included in an aerosol-generating article/assembly as a sheet, such as a sheet circumscribing a rod of tobacco material. In some other cases, the amorphous solid may be formed as a sheet and then shredded and incorporated into the article. In some cases, the shredded sheet may be mixed with cut rag tobacco and incorporated into the article.
• the aerosol generating assembly may comprise an integrated aerosolgenerating article and heater, or may comprise a heater device into which the article is inserted in use.
• FIG. 1 and 2 there are shown a partially cut-away section view and a perspective view of an example of an aerosol-generating article 101.
• the article 101 is adapted for use with a device having a power source and a heater.
• the article 101 of this embodiment is particularly suitable for use with the device 51 shown in Figures 5 to 7, described below.
• the article 101 may be removably inserted into the device shown in Figure 5 at an insertion point 20 of the device 51 .
• the article 101 of one example is in the form of a substantially cylindrical rod that includes a body of aerosol-generating composition 103 and a filter assembly 105 in the form of a rod.
• the aerosol-generating composition comprises the amorphous solid material described herein. In some embodiments, it may be included in sheet form. In some embodiments it may be included in the form of a shredded sheet. In some embodiments, the amorphous solid described herein may be incorporated in sheet form and in shredded form.
• the filter assembly 105 includes three segments, a cooling segment 107, a filter segment 109 and a mouth end segment 111.
• the article 101 has a first end 113, also known as a mouth end or a proximal end and a second end 115, also known as a distal end.
• the body of aerosol-generating composition 103 is located towards the distal end 115 of the article 101.
• the cooling segment 107 is located adjacent the body of aerosol-generating composition 103 between the body of aerosolgenerating composition 103 and the filter segment 109, such that the cooling segment 107 is in an abutting relationship with the aerosol-generating composition 103 and the filter segment 103.
• the filter segment 109 is located in between the cooling segment 107 and the mouth end segment 111.
• the mouth end segment 111 is located towards the proximal end 113 of the article 101 , adjacent the filter segment 109.
• the filter segment 109 is in an abutting relationship with the mouth end segment 111.
• the total length of the filter assembly 105 is between 37mm and 45mm, more preferably, the total length of the filter assembly 105 is 41 mm.
• the rod of aerosol-generating composition 103 is between 34mm and 50mm in length, suitably between 38mm and 46mm in length, suitably 42mm in length.
• the total length of the article 101 is between 71mm and 95mm, suitably between 79mm and 87mm, suitably 83mm.
• An axial end of the body of aerosol-generating composition 103 is visible at the distal end 115 of the article 101.
• the distal end 115 of the article 101 may comprise an end member (not shown) covering the axial end of the body of aerosol-generating composition 103.
• the body of aerosol-generating composition 103 is joined to the filter assembly 105 by annular tipping paper (not shown), which is located substantially around the circumference of the filter assembly 105 to surround the filter assembly 105 and extends partially along the length of the body of aerosol-generating composition 103.
• the tipping paper is made of 58GSM standard tipping base paper.
• the tipping paper has a length of between 42mm and 50mm, suitably of 46mm.
• the cooling segment 107 is an annular tube and is located around and defines an air gap within the cooling segment.
• the air gap provides a chamber for heated volatilised components generated from the body of aerosolgenerating composition 103 to flow.
• the cooling segment 107 is hollow to provide a chamber for aerosol accumulation yet rigid enough to withstand axial compressive forces and bending moments that might arise during manufacture and whilst the article 101 is in use during insertion into the device 51.
• the thickness of the wall of the cooling segment 107 is approximately 0.29mm.
• the cooling segment 107 provides a physical displacement between the aerosol-generating composition 103 and the filter segment 109.
• the physical displacement provided by the cooling segment 107 will provide a thermal gradient across the length of the cooling segment 107.
• the cooling segment 107 is configured to provide a temperature differential of at least 40 degrees Celsius between a heated volatilised component entering a first end of the cooling segment 107 and a heated volatilised component exiting a second end of the cooling segment 107.
• the cooling segment 107 is configured to provide a temperature differential of at least 60 degrees Celsius between a heated volatilised component entering a first end of the cooling segment 107 and a heated volatilised component exiting a second end of the cooling segment 107.
• This temperature differential across the length of the cooling element 107 protects the temperature sensitive filter segment 109 from the high temperatures of the aerosol-generating composition 103 when it is heated by the device 51 . If the physical displacement was not provided between the filter segment 109 and the body of aerosol-generating composition 103 and the heating elements of the device 51 , then the temperature sensitive filter segment 109 may become damaged in use, so it would not perform its required functions as effectively.
• the length of the cooling segment 107 is at least 15mm. In one example, the length of the cooling segment 107 is between 20mm and 30mm, more particularly 23mm to 27mm, more particularly 25mm to 27mm, suitably 25mm.
• the cooling segment 107 is made of paper, which means that it is comprised of a material that does not generate compounds of concern, for example, toxic compounds when in use adjacent to the heater of the device 51.
• the cooling segment 107 is manufactured from a spirally wound paper tube which provides a hollow internal chamber yet maintains mechanical rigidity. Spirally wound paper tubes are able to meet the tight dimensional accuracy requirements of high-speed manufacturing processes with respect to tube length, outer diameter, roundness and straightness.
• the cooling segment 107 is a recess created from stiff plug wrap or tipping paper.
• the stiff plug wrap or tipping paper is manufactured to have a rigidity that is sufficient to withstand the axial compressive forces and bending moments that might arise during manufacture and whilst the article 101 is in use during insertion into the device 51.
• the filter segment 109 may be formed of any filter material sufficient to remove one or more volatilised compounds from heated volatilised components from the aerosol-generating composition.
• the filter segment 109 is made of a mono-acetate material, such as cellulose acetate.
• the filter segment 109 provides cooling and irritation-reduction from the heated volatilised components without depleting the quantity of the heated volatilised components to an unsatisfactory level for a user.
• a capsule (not illustrated) may be provided in filter segment 109. It may be disposed substantially centrally in the filter segment 109, both across the filter segment 109 diameter and along the filter segment 109 length. In other cases, it may be offset in one or more dimension.
• the capsule may in some cases, where present, contain a volatile component such as a flavourant or aerosol generating agent.
• the density of the cellulose acetate tow material of the filter segment 109 controls the pressure drop across the filter segment 109, which in turn controls the draw resistance of the article 101. Therefore the selection of the material of the filter segment 109 is important in controlling the resistance to draw of the article 101. In addition, the filter segment performs a filtration function in the article 101.
• the filter segment 109 is made of a 8Y15 grade of filter tow material, which provides a filtration effect on the heated volatilised material, whilst also reducing the size of condensed aerosol droplets which result from the heated volatilised material.
• the presence of the filter segment 109 provides an insulating effect by providing further cooling to the heated volatilised components that exit the cooling segment 107. This further cooling effect reduces the contact temperature of the user’s lips on the surface of the filter segment 109.
• the filter segment 109 is between 6mm to 10mm in length, suitably 8mm.
• the mouth end segment 111 is an annular tube and is located around and defines an air gap within the mouth end segment 111.
• the air gap provides a chamber for heated volatilised components that flow from the filter segment 109.
• the mouth end segment 111 is hollow to provide a chamber for aerosol accumulation yet rigid enough to withstand axial compressive forces and bending moments that might arise during manufacture and whilst the article is in use during insertion into the device 51.
• the thickness of the wall of the mouth end segment 111 is approximately 0.29mm.
• the length of the mouth end segment 111 is between 6mm to 10mm, suitably 8mm.
• the mouth end segment 111 may be manufactured from a spirally wound paper tube which provides a hollow internal chamber yet maintains critical mechanical rigidity. Spirally wound paper tubes are able to meet the tight dimensional accuracy requirements of high-speed manufacturing processes with respect to tube length, outer diameter, roundness and straightness.
• the mouth end segment 111 provides the function of preventing any liquid condensate that accumulates at the exit of the filter segment 109 from coming into direct contact with a user.
• the mouth end segment 111 and the cooling segment 107 may be formed of a single tube and the filter segment 109 is located within that tube separating the mouth end segment 111 and the cooling segment 107.
• FIGS 3 and 4 there are shown a partially cut-away section and perspective views of an example of an article 301.
• the reference signs shown in Figures 3 and 4 are equivalent to the reference signs shown in Figures 1 and 2, but with an increment of 200.
• a ventilation region 317 is provided in the article 301 to enable air to flow into the interior of the article 301 from the exterior of the article 301.
• the ventilation region 317 takes the form of one or more ventilation holes 317 formed through the outer layer of the article 301.
• the ventilation holes may be located in the cooling segment 307 to aid with the cooling of the article 301.
• the ventilation region 317 comprises one or more rows of holes, and preferably, each row of holes is arranged circumferentially around the article 301 in a cross-section that is substantially perpendicular to a longitudinal axis of the article 301 .
• each row of ventilation holes may have between 12 to 36 ventilation holes 317.
• the ventilation holes 317 may, for example, be between 100 to 500pm in diameter. I n one example, an axial separation between rows of ventilation holes 317 is between 0.25mm and 0.75mm, suitably 0.5mm. In one example, the ventilation holes 317 are of uniform size. In another example, the ventilation holes 317 vary in size.
• the ventilation holes can be made using any suitable technique, for example, one or more of the following techniques: laser technology, mechanical perforation of the cooling segment 307 or pre-perforation of the cooling segment 307 before it is formed into the article 301 .
• the ventilation holes 317 are positioned so as to provide effective cooling to the article 301.
• the rows of ventilation holes 317 are located at least 11 mm from the proximal end 313 of the article, suitably between 17mm and 20mm from the proximal end 313 of the article 301.
• the location of the ventilation holes 317 is positioned such that user does not block the ventilation holes 317 when the article 301 is in use.
• Providing the rows of ventilation holes between 17mm and 20mm from the proximal end 313 of the article 301 enables the ventilation holes 317 to be located outside of the device 51 , when the article 301 is fully inserted in the device 51 , as can be seen in Figures 6 and 7.
• By locating the ventilation holes outside of the device non-heated air is able to enter the article 301 through the ventilation holes from outside the device 51 to aid with the cooling of the article 301.
• the length of the cooling segment 307 is such that the cooling segment 307 will be partially inserted into the device 51 , when the article 301 is fully inserted into the device 51.
• the length of the cooling segment 307 provides a first function of providing a physical gap between the heater arrangement of the device 51 and the heat sensitive filter arrangement 309, and a second function of enabling the ventilation holes 317 to be located in the cooling segment, whilst also being located outside of the device 51 , when the article 301 is fully inserted into the device 51 .
• the majority of the cooling element 307 is located within the device 51. However, there is a portion of the cooling element 307 that extends out of the device 51. It is in this portion of the cooling element 307 that extends out of the device 51 in which the ventilation holes 317 are located.
• FIG. 5 there is shown an example of a device 51 arranged to heat aerosol-generating composition to volatilise at least one component of said aerosol-generating composition, typically to form an aerosol which can be inhaled.
• the device 51 is a heating device which releases compounds by heating, but not burning, the aerosol-generating composition.
• a first end 53 is sometimes referred to herein as the mouth or proximal end 53 of the device 51 and a second end 55 is sometimes referred to herein as the distal end 55 of the device 51 .
• the device 51 has an on/off button 57 to allow the device 51 as a whole to be switched on and off as desired by a user.
• the device 51 comprises a housing 59 for locating and protecting various internal components of the device 51.
• the housing 59 comprises a uni-body sleeve 11 that encompasses the perimeter of the device 51 , capped with a top panel 17 which defines generally the ‘top’ of the device 51 and a bottom panel 19 which defines generally the ‘bottom’ of the device 51.
• the housing comprises a front panel, a rear panel and a pair of opposite side panels in addition to the top panel 17 and the bottom panel 19.
• the top panel 17 and/or the bottom panel 19 may be removably fixed to the uni-body sleeve 11 , to permit easy access to the interior of the device 51 , or may be “permanently” fixed to the uni-body sleeve 11 , for example to deter a user from accessing the interior of the device 51.
• the panels 17 and 19 are made of a plastics material, including for example glass-filled nylon formed by injection moulding, and the uni-body sleeve 11 is made of aluminium, though other materials and other manufacturing processes may be used.
• the top panel 17 of the device 51 has an opening 20 at the mouth end 53 of the device 51 through which, in use, the article 101 , 301 including the aerosolgenerating composition may be inserted into the device 51 and removed from the device 51 by a user.
• the housing 59 has located or fixed therein a heater arrangement 23, control circuitry 25 and a power source 27.
• the heater arrangement 23, the control circuitry 25 and the power source 27 are laterally adjacent (that is, adjacent when viewed from an end), with the control circuitry 25 being located generally between the heater arrangement 23 and the power source 27, though other locations are possible.
• the control circuitry 25 may include a controller, such as a microprocessor arrangement, configured and arranged to control the heating of the aerosol-generating composition in the article 101 , 301 as discussed further below.
• a controller such as a microprocessor arrangement
• the power source 27 may be for example a battery, which may be a rechargeable battery or a non-rechargeable battery.
• suitable batteries include for example a lithium-ion battery, a nickel battery (such as a nickel-cadmium battery), an alkaline battery and/ or the like.
• the battery 27 is electrically coupled to the heater arrangement 23 to supply electrical power when required and under control of the control circuitry 25 to heat the aerosol-generating composition in the article (as discussed, to volatilise the aerosol-generating composition without causing the aerosol-generating composition to burn).
• An advantage of locating the power source 27 laterally adjacent to the heater arrangement 23 is that a physically large power source 25 may be used without causing the device 51 as a whole to be unduly lengthy.
• a physically large power source 25 has a higher capacity (that is, the total electrical energy that can be supplied, often measured in Amp-hours or the like) and thus the battery life for the device 51 can be longer.
• the heater arrangement 23 is generally in the form of a hollow cylindrical tube, having a hollow interior heating chamber 29 into which the article 101 , 301 comprising the aerosol-generating composition is inserted for heating in use.
• the heater arrangement 23 may comprise a single heating element or may be formed of plural heating elements aligned along the longitudinal axis of the heater arrangement 23.
• the or each heating element may be annular or tubular, or at least part-annular or part-tubular around its circumference.
• the or each heating element may be a thin film heater.
• the or each heating element may be made of a ceramics material.
• suitable ceramics materials include alumina and aluminium nitride and silicon nitride ceramics, which may be laminated and sintered.
• Other heating arrangements are possible, including for example inductive heating, infrared heater elements, which heat by emitting infrared radiation, or resistive heating elements formed by for example a resistive electrical winding.
• the heater arrangement 23 is supported by a stainless steel support tube and comprises a polyimide heating element.
• the heater arrangement 23 is dimensioned so that substantially the whole of the body of aerosolgenerating composition 103, 303 of the article 101 , 301 is inserted into the heater arrangement 23 when the article 101 , 301 is inserted into the device 51.
• the or each heating element may be arranged so that selected zones of the aerosol-generating composition can be independently heated, for example in turn (over time, as discussed above) or together (simultaneously) as desired.
• the heater arrangement 23 in this example is surrounded along at least part of its length by a thermal insulator 31 .
• the insulator 31 helps to reduce heat passing from the heater arrangement 23 to the exterior of the device 51. This helps to keep down the power requirements for the heater arrangement 23 as it reduces heat losses generally.
• the insulator 31 also helps to keep the exterior of the device 51 cool during operation of the heater arrangement 23.
• the insulator 31 may be a double-walled sleeve which provides a low pressure region between the two walls of the sleeve. That is, the insulator 31 may be for example a “vacuum” tube, i.e. a tube that has been at least partially evacuated so as to minimise heat transfer by conduction and/or convection.
• Other arrangements for the insulator 31 are possible, including using heat insulating materials, including for example a suitable foam-type material, in addition to or instead of a double-walled sleeve.
• the housing 59 may further comprises various internal support structures 37 for supporting all internal components, as well as the heating arrangement 23.
• the device 51 further comprises a collar 33 which extends around and projects from the opening 20 into the interior of the housing 59 and a generally tubular chamber 35 which is located between the collar 33 and one end of the vacuum sleeve 31.
• the chamber 35 further comprises a cooling structure 35f, which in this example, comprises a plurality of cooling fins 35f spaced apart along the outer surface of the chamber 35, and each arranged circumferentially around outer surface of the chamber 35.
• the air gap 36 is around all of the circumference of the article 101 , 301 over at least part of the cooling segment 307.
• the collar 33 comprises a plurality of ridges 60 arranged circumferentially around the periphery of the opening 20 and which project into the opening 20.
• the ridges 60 take up space within the opening 20 such that the open span of the opening 20 at the locations of the ridges 60 is less than the open span of the opening 20 at the locations without the ridges 60.
• the ridges 60 are configured to engage with an article 101 , 301 inserted into the device to assist in securing it within the device 51.
• Open spaces (not shown in the Figures) defined by adjacent pairs of ridges 60 and the article 101 , 301 form ventilation paths around the exterior of the article 101 , 301. These ventilation paths allow hot vapours that have escaped from the article 101 , 301 to exit the device 51 and allow cooling air to flow into the device 51 around the article 101 , 301 in the air gap 36.
• the article 101 , 301 is removably inserted into an insertion point 20 of the device 51 , as shown in Figures 5 to 7.
• the body of aerosol-generating composition 103, 303 which is located towards the distal end 115, 315 of the article 101 , 301 , is entirely received within the heater arrangement 23 of the device 51.
• the proximal end 113, 313 of the article 101 , 301 extends from the device 51 and acts as a mouthpiece assembly for a user.
• the heater arrangement 23 will heat the article 101 , 301 to volatilise at least one component of the aerosol-generating composition from the body of aerosol-generating composition 103, 303.
• the primary flow path for the heated volatilised components from the body of aerosol-generating composition 103, 303 is axially through the article 101 , 301 , through the chamber inside the cooling segment 107, 307, through the filter segment 109, 309, through the mouth end segment 111 , 313 to the user.
• the temperature of the heated volatilised components that are generated from the body of aerosol-generating composition is between 60°C and 250°C, which may be above the acceptable inhalation temperature for a user. As the heated volatilised component travels through the cooling segment 107, 307, it will cool and some volatilised components will condense on the inner surface of the cooling segment 107, 307.
• cool air will be able to enter the cooling segment 307 via the ventilation holes 317 formed in the cooling segment 307. This cool air will mix with the heated volatilised components to provide additional cooling to the heated volatilised components.
• the method comprises heating the aerosol-generating composition to a temperature of less than or equal to 350 °C.
• the method typically comprises heating the aerosol-generating composition to a temperature of from about 220 °C to about 280 °C.
• the method comprises heating at least a portion of the aerosol-generating composition to a temperature of from about 220 °C to about 280 °C over a session of use.
• “Session of use” as used herein refers to a single period of use of the noncombustible aerosol provision system by a user.
• the session of use begins at the point at which power is first supplied to at least one heating unit present in the heating assembly.
• the device will be ready for use after a period of time has elapsed from the start of the session of use.
• the session of use ends at the point at which no power is supplied to any of the heating elements in the aerosol-generating device.
• the end of the session of use may coincide with the point at which the smoking article is depleted (the point at which the total particulate matter yield (mg) in each puff would be deemed unacceptably low by a user).
• the session will have a duration of a plurality of puffs.
• Said session may have a duration less than 7 minutes, or 6 minutes, or 5 minutes, or 4 minutes and 30 seconds, or 4 minutes, or 3 minutes and 30 seconds.
• the session of use may have a duration of from 2 to 5 minutes, or from 3 to 4.5 minutes, or 3.5 to 4.5 minutes, or suitably 4 minutes.
• a session may be initiated by the user actuating a button or switch on the device, causing at least one heating element to begin rising in temperature.
• use of the aerosolgenerating composition, the article or the non-combustible aerosol provision system as described herein to generate an aerosol may comprise interacting with the non-combustible aerosol provision device (e.g. activating an actuator) to initiate a smoking session.
• the non-combustible aerosol provision device e.g. activating an actuator
• the aerosol-generating composition as defined in claim 1 wherein the amorphous solid comprises aerosol generating agent in an amount of about 35-80 wt% of the amorphous solid.
• Embodiment 2 The aerosol-generating composition of Embodiment 1 , wherein the amorphous solid comprises aerosol generating agent in an amount of about 35-65 wt% of the amorphous solid.
• Embodiment 3 The aerosol-generating composition of Embodiment 2, wherein the amorphous solid comprises aerosol generating agent in an amount of about 40-60 wt% of the amorphous solid.
• the aerosol generating agent comprises (or is) one or more of glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1 ,3-butylene glycol, erythritol, meso-Erythritol, ethyl vanillate, ethyl laurate, a diethyl suberate, triethyl citrate, triacetin, a diacetin mixture, benzyl benzoate, benzyl phenyl acetate, tributyrin, lauryl acetate, lauric acid, myristic acid, and propylene carbonate.
• the aerosol generating agent comprises (or is) one or more of glycerol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1 ,3-butylene glycol, erythritol, meso-Erythritol,
• aerosol-generating composition of of claim 1 or any preceding Embodiment wherein the aerosol generating agent comprises (or is) glycerol, optionally in combination with propylene glycol.
• amorphous solid comprises gelling agent and filler, taken together, in an amount of about 20-65 wt% of the amorphous solid.
• Embodiment 8 wherein the amorphous solid comprises gelling agent and filler, taken together, in an amount of about 20- 60 wt% of the amorphous solid.
• amorphous solid comprises gelling agent and filler, taken together, in an amount of about 30-70 wt% of the amorphous solid.
• amorphous solid comprises gelling agent and filler, taken together, in an amount of about 40-60 wt% of the amorphous solid.
• amorphous solid comprises gelling agent and filler, taken together, in an amount of about 45-55 wt% of the amorphous solid.
• amorphous solid comprises gelling agent in an amount of about 5-50 wt% of the amorphous solid.
• the aerosol-generating composition of Embodiment 15 wherein the amorphous solid comprises gelling agent in an amount of about 10-50 wt% of the amorphous solid. 17.
• Embodiment 17 wherein the amorphous solid comprises gelling agent in an amount of about 15-30 wt% of the amorphous solid.
• Embodiment 19 The aerosol-generating composition of Embodiment 18, wherein the amorphous solid comprises gelling agent in an amount of about 15-25 wt% of the amorphous solid.
• Embodiment 20 The aerosol-generating composition of Embodiment 19, wherein the amorphous solid comprises gelling agent in an amount of about 17-25 wt% of the amorphous solid.
• Embodiment 23 The aerosol-generating composition of Embodiment 22, wherein the amorphous solid comprises guar gum in an amount of about 7-40 wt % of the amorphous solid.
• Embodiment 27 The aerosol-generating composition of Embodiment 26, wherein the amorphous solid comprises guar gum in an amount of about 15-30 wt % of the amorphous solid.
• Embodiment 31 The aerosol-generating composition of Embodiment 30, wherein the amorphous solid comprises methyl cellulose in an amount of about 7-40 wt% of the amorphous solid.
• Embodiment 32 The aerosol-generating composition of Embodiment 31 , wherein the amorphous solid comprises methyl cellulose in an amount of about 10-30 wt% of the amorphous solid.
• Embodiment 33 The aerosol-generating composition of Embodiment 32, wherein the amorphous solid comprises methyl cellulose in an amount of about 15-30 wt % of the amorphous solid.
• Embodiment 34 The aerosol-generating composition of Embodiment 33, wherein the amorphous solid comprises methyl cellulose in an amount of about 15-25 wt% of the amorphous solid.
• Embodiment 35 The aerosol-generating composition of Embodiment 34, wherein the amorphous solid comprises methyl cellulose in an amount of about 17-25 wt% of the amorphous solid.
• Embodiment 37 The aerosol-generating composition of Embodiment 36, wherein the amorphous solid comprises the methyl cellulose in an amount of about 5-30 wt% of the amorphous solid.
• Embodiment 38 The aerosol-generating composition of Embodiment 37, wherein the amorphous solid comprises the methyl cellulose in an amount of about 10-25 wt of the amorphous solid.
• Embodiment 39 The aerosol-generating composition of Embodiment 38, wherein the amorphous solid comprises the methyl cellulose in an amount of about 15-20 wt% of the amorphous solid.
• Embodiment 42 The aerosol-generating composition of Embodiment 41 , wherein the amorphous solid comprises the xanthan gum in an amount of about 2-5 wt% of the amorphous solid.
• Embodiment 44 The aerosol-generating composition of Embodiment 43, wherein the amorphous solid comprise chitosan in an amount of about 0.01-10 wt% of the amorphous solid.
• Embodiment 45 The aerosol-generating composition of Embodiment 44, wherein the amorphous solid comprise chitosan in an amount of about 0.025-5 wt% of the amorphous solid.
• Embodiment 46 The aerosol-generating composition of Embodiment 45, wherein the amorphous solid comprise chitosan in an amount of about 0.05-2 wt % of the amorphous solid.
• Embodiment 47 The aerosol-generating composition of Embodiment 46, wherein the amorphous solid comprise chitosan in an amount of about 0.1-1 wt% of the amorphous solid.
• Embodiment 48 The aerosol-generating composition of Embodiment 47, wherein the amorphous solid comprise chitosan in an amount of about 0.1 -0.7 wt% of the amorphous solid.
• amorphous solid comprises filler in an amount of about 15-40 wt% of the amorphous solid.
• the aerosol-generating composition of Embodiment 49 wherein the amorphous solid comprises filler in an amount of about 20-40 wt% of the amorphous solid.
• the aerosol-generating composition of Embodiment 50 wherein the amorphous solid comprises filler in an amount of about 25-35 wt% of the amorphous solid.
• the organic filler materials are selected from wood pulp, cellulose and cellulose derivatives, such as microcrystalline cellulose.
• Embodiment 61 The aerosol-generating composition of Embodiment 61 , wherein the water content of the amorphous solid is about 7-13 wt% (WWB) of the amorphous solid.
• Embodiment 63 The aerosol-generating composition of Embodiment 62, wherein the water content of the amorphous solid is about 9-11 wt % (WWB) of the amorphous solid.
• An aerosol-generating composition comprising an amorphous solid as defined in claim 1 or any preceding Embodiment and further comprising tobacco material, wherein the aerosol-generating composition has an aerosol generating agent content of from about 5 to about 30 wt% of the aerosol-generating composition.
• the aerosol-generating composition Embodiment 64 wherein the aerosolgenerating composition has an aerosol generating agent content of about 10-20 wt%.
• the aerosol-generating composition of Embodiment 65 wherein the aerosolgenerating composition has an aerosol generating agent content of about 13-17 wt%.
• Embodiment 67 The aerosol-generating composition of Embodiment 67, wherein the aerosolgenerating composition comprises the amorphous solid in an amount of about 5 to 30 wt%.
• the aerosol-generating composition of Embodiment 70 wherein the aerosolgenerating composition comprises the amorphous solid in an amount of about 10 to 25 wt%.
• Embodiment 72 The aerosol-generating composition of Embodiment 71 , wherein the aerosolgenerating composition comprises the amorphous solid in an amount of about 15 to 25 wt%.
• Embodiment 72 The aerosol-generating composition of Embodiment 72, wherein the aerosolgenerating composition comprises the amorphous solid in an amount of about 17 to 23 wt%.
• the aerosol-generating composition of Embodiment 71 wherein the aerosolgenerating composition comprises the amorphous solid in an amount of about 10 to 20 wt%.
• aerosol-generating composition of any of Embodiments 64-74, wherein aerosol-generating composition comprises the tobacco material in an amount of about 50 to 95 wt%.
• aerosol-generating composition of Embodiment 75 wherein aerosolgenerating composition comprises the tobacco material in an amount of about 60 to 95 wt%.
• aerosol-generating composition of Embodiment 76 wherein aerosolgenerating composition comprises the tobacco material in an amount of about 60 to 90 wt%
• aerosol-generating composition of Embodiment 77 wherein aerosolgenerating composition comprises the tobacco material in an amount of about 70 to 90 wt%.
• aerosol-generating composition of Embodiment 78 wherein aerosolgenerating composition comprises the tobacco material in an amount of about 75 to 85 wt%
• aerosol-generating composition of Embodiment 78, wherein aerosolgenerating composition comprises the tobacco material in an amount of about 80 to 90 wt%.
• the aerosol-generating composition according to any one of Embodiments 64-81 wherein the tobacco material comprises lamina tobacco
• the tobacco material comprises cut rag tobacco.
• the aerosol-generating composition according to Embodiment 83 wherein the cut rag tobacco is present in an amount of at least 90 wt% of the tobacco material.
• the aerosol-generating composition according to any one of Embodiments 64-84 wherein the tobacco material comprises aerosol generating agent in an amount of from 1 to 10 wt% of the tobacco material
• the aerosol-generating composition according to any one of Embodiments 64-85 wherein the amorphous solid is a shredded sheet blended with the tobacco material.
• the aerosol-generating composition according to any one of Embodiments 64-86 wherein the tobacco material comprises cut rag tobacco having a cut width, and the amorphous solid shredded sheet has a cut width, the cut width of the amorphous solid being from about 90 to 110% of the cut width of the cut rag tobacco.
• the aerosol-generating composition according to any one of Embodiments 64-87 wherein the tobacco material has an area density, and the amorphous solid has an area density, the area density of the amorphous solid being from about 90 to 110% of the area density of the tobacco material.
• the amorphous solid may be made from a slurry.
• the above Embodiments defining features of the amorphous solid in the aerosol-generating compositions of the invention apply equally to the slurry of the invention.
• Embodiments apply equally to the articles, systems, methods of making the aerosol-generating composition, methods of forming the aerosolgenerating material and uses of the invention.
• Amorphous solids having the following constituents were produced using an air-laid paper-making process. Percentage amounts are quoted on a dry weight basis unless specified otherwise. Thicknesses, area densities, tensile strengths and water contents of the amorphous solids were measured.
• Thicknesses were measured using a L&W Micrometre (A-2 version) with the settings in the following table. Conditions during the measurement were 22 ⁇ 2°C of temperature and 60 ⁇ 5 % of Relative Humidity.
• Area densities were determined by cutting a 100 cm 2 sample of aerosol generating material using a 100 cm 2 cutter and then weighing the cut sample on an analytical balance (resolution 0.01 g). Conditions during the measurement were 22 ⁇ 2°C of temperature and 60 ⁇ 5 % of Relative Humidity.

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