WO2022037178A1 - Semiconductor device and method for forming same - Google Patents

Semiconductor device and method for forming same Download PDF

Info

Publication number
WO2022037178A1
WO2022037178A1 PCT/CN2021/097506 CN2021097506W WO2022037178A1 WO 2022037178 A1 WO2022037178 A1 WO 2022037178A1 CN 2021097506 W CN2021097506 W CN 2021097506W WO 2022037178 A1 WO2022037178 A1 WO 2022037178A1
Authority
WO
WIPO (PCT)
Prior art keywords
conductive contact
layer
substrate
capacitor
capacitor array
Prior art date
Application number
PCT/CN2021/097506
Other languages
French (fr)
Chinese (zh)
Inventor
赵亮
Original Assignee
长鑫存储技术有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 长鑫存储技术有限公司 filed Critical 长鑫存储技术有限公司
Priority to EP21773277.5A priority Critical patent/EP3985724B1/en
Priority to US17/391,181 priority patent/US11937419B2/en
Publication of WO2022037178A1 publication Critical patent/WO2022037178A1/en

Links

Images

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/01Manufacture or treatment
    • H10B12/02Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
    • H10B12/03Making the capacitor or connections thereto
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/01Manufacture or treatment
    • H10B12/09Manufacture or treatment with simultaneous manufacture of the peripheral circuit region and memory cells

Definitions

  • the present disclosure relates to the field of semiconductor technology, and in particular, to a semiconductor device and a method for forming the same.
  • DRAM Dynamic Random Access Memory
  • the purpose of the present disclosure is to overcome the above-mentioned deficiencies of the prior art, and to provide a semiconductor device and a method for forming the same, which can laterally support the outside of the capacitor array, avoid short circuits, and increase the capacitance.
  • a semiconductor device including:
  • a substrate on which a plurality of conductive contact plugs arranged at intervals are formed;
  • a capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is in contact with the conductive contact plug ;
  • the support structure is formed on the substrate at the edge of the capacitor array and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are on any cross section parallel to the substrate The spacing is greater than the diameter of the capacitor hole on the cross section of any one of the column capacitors.
  • the conductive contact plug includes a first conductive contact plug and a second conductive contact plug, the first conductive contact plug is in contact with the lower electrode layer of the column capacitor, the A second conductive contact plug is in contact with the bottom of the support structure.
  • At least an insulating dielectric layer is formed on the substrate, and the capacitor array and the support structure are formed in the insulating dielectric layer.
  • an orthographic projection of the support structure on the second conductive contact plug coincides with a boundary of the second conductive contact plug.
  • the substrate includes a cell region and a peripheral region
  • the capacitor array is formed in the cell region
  • the conductive contact plug further includes a peripheral conductive contact plug
  • the peripheral conductive Contact plugs are formed in the peripheral region
  • the semiconductor device further includes an interconnect structure connected to the peripheral conductive contact plug, the interconnect structure formed in the insulating dielectric layer.
  • the insulating dielectric layer includes a first insulating dielectric layer and a second insulating dielectric layer spaced along a direction perpendicular to the substrate, the capacitor array and the A support structure is formed in the first insulating dielectric layer and the second insulating dielectric layer.
  • a method of forming a semiconductor device comprising:
  • a capacitor array is formed, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is in contact with the conductive contact plug connect;
  • a support structure is formed, the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are in any cross-section parallel to the substrate The distance between the capacitor holes is larger than the diameter of the capacitor holes on the cross section of any one of the column capacitors.
  • the substrate has a unit area, a plurality of conductive contact plugs arranged at intervals are formed on the unit area, and the conductive contact plugs are located at the edge of the unit area
  • the width of the conductive contact plug is greater than the width of the non-edge conductive contact plug in the unit area
  • the forming the capacitor array and the supporting structure includes:
  • a sacrificial layer and an insulating dielectric layer are sequentially formed on the substrate, the conductive contact plug is used as an etch stop layer, the sacrificial layer and the insulating dielectric layer in the unit area are etched, and multiple layers are formed in the unit area.
  • Columnar void structures are arranged at intervals, and the etching window is controlled so that the cross-sectional spacing of the columnar void structures located at the periphery of the cell region in the direction parallel to the substrate is greater than that of the non-periphery columnar void structures in the cell region the cross-sectional spacing;
  • a capacitor dielectric layer and an upper electrode layer are sequentially formed on the lower electrode layer of the non-peripheral columnar void structure in the unit area to form a capacitor array.
  • the substrate further has a peripheral region, and before etching the sacrificial layer and the insulating dielectric layer in the unit region, the forming method further includes:
  • An interconnect structure is formed in the peripheral region.
  • forming the interconnect structure includes:
  • a first interconnect structure is formed in the first via.
  • the forming method further includes:
  • the insulating dielectric layer and the second sacrificial layer are sequentially formed on the first sacrificial layer in the peripheral region, and the insulating dielectric layer and the second sacrificial layer are etched using the first interconnect structure as an etch stop layer. , to form a second via;
  • a second interconnect structure is formed in the second via.
  • the support structure surrounds the outside of the capacitor array, the outside of the capacitor array can be laterally supported, thereby increasing the lateral stability of the capacitor array, preventing lateral deformation of the capacitors in the capacitor array, and avoiding short circuits.
  • the distance between the inner wall and the outer wall of the support structure on any cross section parallel to the substrate is larger than the aperture of any capacitor hole in the capacitor array on the cross section, the support strength of the support structure can be guaranteed.
  • the capacitor array includes multiple capacitors, the multiple capacitors can be charged and discharged at the same time during use, thereby increasing the capacitance.
  • FIG. 1 is a schematic structural diagram of a semiconductor device according to an embodiment of the disclosure.
  • FIG. 2 is a schematic structural diagram of a capacitor hole and an annular ring according to an embodiment of the present disclosure.
  • FIG. 3 is a schematic structural diagram of a lower electrode layer according to an embodiment of the disclosure.
  • FIG. 4 is a schematic structural diagram of a support structure according to an embodiment of the present disclosure.
  • FIG. 5 is a schematic structural diagram of a semiconductor layer according to an embodiment of the disclosure.
  • FIG. 6 is a schematic structural diagram of an insulating dielectric layer according to an embodiment of the disclosure.
  • FIG. 7 is a schematic structural diagram of a first via hole according to an embodiment of the present disclosure.
  • FIG. 8 is a schematic structural diagram of a connection layer according to an embodiment of the present disclosure.
  • FIG. 9 is a flowchart of a method of forming a semiconductor device according to an embodiment of the disclosure.
  • FIG. 10 is a flow chart of forming a capacitor array and a support structure in an embodiment of the disclosure.
  • FIG. 11 is a schematic structural diagram of an insulating dielectric layer and a sacrificial layer according to an embodiment of the disclosure.
  • FIG. 12 is a schematic structural diagram of forming a photoresist on an insulating dielectric layer according to an embodiment of the present disclosure.
  • FIG. 13 is a schematic structural diagram of a lower electrode layer covering a capacitor hole and its top surface in an embodiment of the disclosure.
  • FIG. 14 is a schematic structural diagram of a cover layer according to an embodiment of the disclosure.
  • FIG. 15 is a schematic diagram of a structure after forming a photoresist on the cover layer according to an embodiment of the present disclosure.
  • FIG. 16 is a schematic structural diagram of an opening formed in a cover layer according to an embodiment of the present disclosure.
  • FIG. 17 is a schematic structural diagram of an embodiment of the present disclosure after removing the top sacrificial layer.
  • FIG. 18 is a schematic structural diagram of a cover layer after planarization processing is performed according to an embodiment of the present disclosure.
  • FIG. 19 is a flowchart corresponding to step S160 in FIG. 9 .
  • Example embodiments will now be described more fully with reference to the accompanying drawings.
  • Example embodiments can be embodied in various forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of example embodiments to those skilled in the art.
  • the same reference numerals in the drawings denote the same or similar structures, and thus their detailed descriptions will be omitted.
  • the drawings are merely schematic illustrations of the present disclosure and are not necessarily drawn to scale.
  • the semiconductor device may include a substrate 1 , a capacitor array 3 and a support structure 4 , wherein:
  • a plurality of conductive contact plugs 2 arranged at intervals are formed on the substrate 1;
  • the capacitor array 3 includes a plurality of column capacitors arranged at intervals, each column capacitor is formed on each conductive contact plug 2, and the lower electrode layer 33 of the column capacitor is in contact with the conductive contact plug 2;
  • the support structure 4 is formed on the substrate 1 at the edge of the capacitor array 3 and surrounds the capacitor array 3, and the distance between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the capacitance of any column capacitor The diameter of the hole in the cross section.
  • the support structure 4 surrounds the outside of the capacitor array 3, the outside of the capacitor array 3 can be laterally supported, thereby increasing the lateral stability of the capacitor array 3, preventing lateral deformation of the capacitors in the capacitor array 3, and avoiding At the same time, since the distance between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the aperture of any capacitor hole in the capacitor array 3 on the cross section, the support strength of the support structure 4 can be guaranteed. .
  • the capacitor array 3 includes a plurality of capacitors, in use, the plurality of capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
  • the substrate 1 can have a flat plate structure, which can be rectangular, circular, elliptical, polygonal or irregular, and its material can be silicon or other semiconductor materials. Materials are subject to special restrictions.
  • a plurality of conductive contact plugs 2 can be formed on the substrate 1 at intervals.
  • the conductive contact plugs 2 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition.
  • the conductive contact plugs 2 can be formed on the substrate 1.
  • the conductive contact plugs 2 may also be formed in other ways, which will not be listed one by one here.
  • the conductive contact plug 2 may include a first conductive contact plug 21 and a second conductive contact plug 22, and the second conductive contact plug 22 may be an annular structure, which may be a circular ring or a rectangular ring;
  • the second conductive contact plug 22 may be made of conductor or semiconductor material, for example, the material may be tungsten, copper or polysilicon.
  • There can be a plurality of first conductive contact plugs 21 the plurality of first conductive contact plugs 21 can be located in the annular shape of the second conductive contact plugs 22 , and can be distributed in an array, and the material of the first conductive contact plugs 21 can be the same as that of the second conductive contact plugs 21 .
  • the material of the conductive contact plugs 22 is the same.
  • the substrate 1 may include a unit area 11 and a peripheral area 12 arranged side by side, a capacitor array 3 may be formed on the substrate 1 and may be located on the unit area 11, and the capacitor array 3 may include a plurality of spaced rows
  • each column capacitor can be formed on each conductive contact plug 2 respectively, and specifically, each column capacitor can be formed on each first conductive contact plug 21 respectively.
  • multiple capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
  • the capacitor array 3 may include an insulating layer 31 , an insulating medium layer 32 , a lower electrode layer 33 , a capacitor medium layer 34 and an upper electrode layer 35 .
  • the insulating layer 31 is distributed between the first conductive contact plugs 21 and can be used to separate the first conductive contact plugs 21 ;
  • the lower electrode layer 33 can be in the shape of a strip, which can be formed on the first conductive contact plug 21 away from the substrate 1 .
  • one side and can be in contact with the first conductive contact plug 21, and can extend to the side of the first conductive contact plug 21 away from the substrate 1 along the direction perpendicular to the contact direction of the first conductive contact plug 21, so as to form a columnar capacitor .
  • the capacitor dielectric layer 34 is located between the lower electrode layer 33 and the upper electrode layer 35 to form a double-sided capacitor, so as to improve the capacitance.
  • the insulating medium layer 32 can cover the outer periphery of the lower electrode layer 33 , can support the lower electrode layer 33 laterally, increase the stability of the lower electrode layer 33 in the lateral direction, and prevent the lower electrode layer 33 from being deformed laterally.
  • the insulating layer 31 can be formed on the substrate 1.
  • the insulating layer 31 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition.
  • the insulating layer 31 can also be formed by other methods. Layer 31 will not be listed one by one here.
  • the shape of the insulating layer 31 may be the same as that of the substrate 1 , and the material thereof may be silicon nitride, silicon oxide, etc., and the material thereof is not limited herein.
  • the insulating layer 31 can be provided with an annular hole and a plurality of openings arranged in an array inside the annular hole.
  • the annular hole and each opening can be a through hole, and the annular hole can be a circular ring or a rectangular ring.
  • the shape of the annular hole and each opening is not particularly limited here.
  • the second conductive contact plugs 22 may be formed in the annular holes, and at the same time, the first conductive contact plugs 21 may be formed in each opening, and the second conductive contact plugs 22 and a plurality of first conductive contact plugs 21 may be formed simultaneously in one process, For example, the second conductive contact plugs 22 and the plurality of first conductive contact plugs 21 may be simultaneously formed through a chemical vapor deposition process.
  • the second conductive contact plugs 22 can be in contact with the substrate 1 through the annular hole, and at the same time, each of the first conductive contact plugs 21 can be in contact with the substrate 1 through each opening.
  • At least an insulating dielectric layer 32 is formed on the substrate 1 .
  • an insulating dielectric layer 32 can be formed on the side of the insulating layer 31 away from the substrate 1 , and the insulating dielectric layer 32 can cover both the cell region 11 and the peripheral region 12 .
  • Both the capacitor array 3 and the supporting structure 4 can be formed in the insulating dielectric layer 32 opposite to the unit region 11 , that is, the insulating dielectric layer 32 can be used to support the capacitors.
  • the insulating dielectric layer 32 may have a plurality of through holes exposing the first conductive contact plugs 21 respectively.
  • the through holes may be capacitor holes 37 , which may be used to form capacitors.
  • Each capacitor hole 37 may be perpendicular to the insulating medium.
  • the direction of the layer 32 runs through the insulating dielectric layer 32 , and the cross-sectional shape of the layer 32 may be a circle, a rectangle, etc., or an irregular shape, and the shape of the capacitor hole 37 is not particularly limited herein.
  • the through hole can also include an annular ring 41, which can be used to form the support structure 4, which can be a circular ring or a rectangular ring, which is not limited herein.
  • the insulating medium layer 32 may include a first insulating medium layer 322 and a second insulating medium layer 324 spaced along a direction perpendicular to the substrate 1, which may be deposited by vacuum evaporation, magnetron sputtering or chemical vapor deposition
  • the first insulating dielectric layer 322 and the second insulating dielectric layer 324 can be formed in the same manner.
  • the insulating dielectric layer 32 can also be formed by other processes, which are not limited herein.
  • Both the capacitor array 3 and the support structure 4 can be formed in the first insulating dielectric layer 322 and the second insulating dielectric layer 324 , and the capacitors inside the capacitor array 3 can be adjusted through the first insulating dielectric layer 322 and the second insulating dielectric layer 324 . At the same time, the edge of the capacitor array 3 can be supported by the support structure 4 .
  • a lower electrode layer 33 can be formed in the capacitor hole 37 to conform to the bottom and the sidewall surface of the capacitor hole 37 , and the lower electrode layer 33 can be in contact with the first conductive contact plug 21 through the capacitor hole 37 connected to input the electricity stored in the lower electrode layer 33 to the first conductive contact plug 21 to realize capacitance storage.
  • the chemical vapor deposition process can be used to form the lower electrode layer 33 in the capacitor hole 37 , and of course, the lower electrode layer 33 can also be formed by other processes, which is not limited herein.
  • the material of the lower electrode layer 33 may be titanium nitride, and its thickness may be 4 nm to 10 nm, for example, it may be 4 nm, 6 nm, 8 nm or 10 nm.
  • the lower electrode layer 33 may also be made of other materials or other thicknesses. I will not list them one by one here.
  • the capacitor dielectric layer 34 may be a thin film formed on the outer surface and the inner surface of the structure composed of the lower electrode layer 33 and the insulating dielectric layer 32, and may be formed by vacuum evaporation or magnetron sputtering. Of course, the capacitive dielectric layer 34 can also be formed by other processes, which will not be listed here.
  • the capacitor dielectric layer 34 may be a single-layer film structure composed of the same material, or may be a mixed film layer structure composed of film layers of different materials.
  • it may include a material with a higher dielectric constant, for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
  • a material with a higher dielectric constant for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
  • the upper electrode layer 35 may be formed on the outer surface of the capacitor dielectric layer 34 by a chemical vapor deposition process. Of course, the upper electrode layer 35 may also be formed by other processes, which are not limited herein.
  • the material of the upper electrode layer 35 can be titanium nitride, and its thickness can be 2nm-8nm, for example, it can be 2nm, 4nm, 6nm or 8nm, of course, the upper electrode layer 35 can also be other materials or other thicknesses, I will not list them one by one here.
  • the support structure 4 may be formed on the substrate 1, which may be located at the edge of the capacitor array 3, and may surround the periphery of the capacitor array 3. For example, as shown in FIG. 4, the support structure 4 may be formed on the second conductive contact The plug 22 faces away from the surface of the substrate 1 , the bottom of which can be in contact with the second conductive contact plug 22 .
  • the support structure 4 may be formed on the surface of the second conductive contact plug 22 facing away from the substrate 1 by means of vacuum evaporation, magnetron sputtering or chemical vapor deposition.
  • the support structure 4 may be of the same material as the insulating dielectric layer 32, for example, it may be silicon nitride.
  • the support structure 4 can be in contact with the capacitor array 3, for example, it can be in contact with the insulating dielectric layer 32 in the capacitor array 3, so as to support the capacitors located at the edge of the capacitor array 3 all around, increasing the capacitor array 3
  • the stability in the lateral direction prevents the lateral deformation of the capacitors located at the edge of the capacitor array 3 and avoids short circuits.
  • the spacing between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the aperture of the capacitor hole 37 of any column capacitor in the capacitor array 3 on the cross section, which can ensure that the support structure 4 is positioned opposite to the capacitor array.
  • the support strength of the capacitor at the edge part may be at least twice the diameter of any capacitor hole 37 in the capacitor array 3 on the cross section.
  • the minimum value of the distance between the inner wall and the outer wall of the support structure 4 may also be greater than the maximum value of the diameter of any capacitor hole 37 .
  • the distance between the inner wall and the outer wall of the support structure 4 can be increased sequentially from the side close to the substrate 1 to the side away from the substrate 1 .
  • the distance between the inner wall and the outer wall can also be equal, and the size between the inner wall and the outer wall of the support structure 4 is not particularly limited here.
  • the orthographic projection of the support structure 4 on the second conductive contact plug 22 can be coincident with the boundary of the second conductive contact plug 22, that is, the support structure 4 can be a continuous whole, which can be continuously wrapped around the second conductive contact plug 22. Outside the capacitor array 3, so as to continuously support the edge portion of the capacitor array 3.
  • the supporting structure 4 may be a discontinuous segment, which may include a plurality of supporting regions distributed at intervals and a one-to-one corresponding supporting column formed on each supporting region, and the thickness of each supporting column may be equal. , and can be encircled in a ring shape, and each support column can be respectively contacted and connected with the insulating medium layer 32 of the capacitor array 3 , so as to support the capacitor array 3 in sections.
  • the thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of each capacitor in the capacitor array 3 in the direction perpendicular to the substrate 1, which can support the capacitor array 3 in the lateral direction, and can also The capacitor array 3 is supported in the longitudinal direction to improve the stability of the device.
  • the thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of the lower electrode layer 33 in the direction perpendicular to the substrate 1, and the capacitors located at the edge of the capacitor array 3 can be adjusted by the support structure 4.
  • the lower electrode layer 33 of the capacitor array 3 is supported laterally and vertically to prevent the lower electrode layer 33 of the capacitor located at the edge of the capacitor array 3 from deforming outward.
  • the semiconductor device of the present disclosure may further include a semiconductor layer 5 , which may cover the surface of the capacitor array 3 and may be filled with capacitor holes 37 and capacitors. The gap between two adjacent capacitors in array 3,
  • the semiconductor layer 5 covering the capacitor array 3 can be formed on the surface of the upper electrode layer 35 by a vacuum evaporation process, so that the electric charges can be fully contacted with the second electrode, which helps to improve the charging efficiency of the capacitor. As shown in FIG. 5, the semiconductor layer 5 can cover the surface of the capacitor array 3, and can fill the capacitor hole 37 and the gap between two adjacent capacitors in the capacitor array 3, which can improve the electrical conductivity of the device and strengthen the capacitor array. The stability of each capacitor in 3.
  • the semiconductor layer 5 may be composed of silicon material, metal material or metal compound, for example, it may be silicon, silicon germanium, tungsten, titanium silicide, titanium oxide or tungsten oxide, etc., which is not limited herein.
  • the conductive contact plugs 2 may further include peripheral conductive contact plugs 23, which may be formed in the peripheral region 12 of the substrate 1, and the semiconductor device of the present disclosure may further include an interconnect structure that The interconnection structure can be formed in the insulating medium layer 32 corresponding to the peripheral region 12 , and can be in contact with the peripheral conductive contact plug 23 so as to electrically lead out the capacitor array 3 .
  • the peripheral conductive contact plugs 23 can be made of the same material as the first conductive contact plugs 21 and the second conductive contact plugs 22 and have the same thickness, and the peripheral conductive contact plugs can be formed at the same time as the first conductive contact plugs 21 and the second conductive contact plugs 22 are formed twenty three.
  • the first interconnect structure 6 can be formed in the first via hole 61 by a chemical vapor deposition process, and the first interconnect structure 6 can be communicated with the semiconductor layer 5 through the first via hole 61 , In order to lead out the capacitor array 3 electrically.
  • the first interconnection structure 6 may include a connection layer 62 and an extraction layer 63.
  • the connection layer 62 may be attached to the hole wall and bottom surface of the first via hole 61, and may communicate with the top of the semiconductor layer 5.
  • the extraction layer 63 may be connected to the top of the semiconductor layer 5. It is located on the connection layer 62 and can fill the first via hole 61 .
  • Both the connection layer 62 and the extraction layer 63 can be made of conductive materials, for example, the connection layer 62 can be made of titanium nitride, and the extraction layer 63 can be made of tungsten.
  • Embodiments of the present disclosure also provide a method for forming a semiconductor device. As shown in FIG. 9 , the forming method may include:
  • Step S110 providing a substrate
  • Step S120 forming a plurality of conductive contact plugs arranged at intervals on the substrate;
  • Step S130 forming a capacitor array, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is connected to the conductive contact plug. contact plug contact connection;
  • Step S140 forming a support structure, the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are in any position parallel to the substrate.
  • the spacing on a cross section is larger than the diameter of the capacitor hole of any one of the column capacitors on the cross section.
  • the support structure 4 surrounds the outside of the capacitor array 3, the outside of the capacitor array 3 can be laterally supported, thereby increasing the lateral stability of the capacitor array 3 and preventing the capacitors in the capacitor array 3 from generating lateral deformation to avoid short circuit; at the same time, since the spacing between the inner wall and the outer wall of the support structure 4 on any cross-section parallel to the substrate 1 is greater than the aperture of any capacitor hole 37 in the capacitor array 3 on the cross-section, the support structure can be guaranteed. 4. Support strength.
  • the capacitor array 3 includes a plurality of capacitors, in use, the plurality of capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
  • step S110 a substrate is provided.
  • the substrate 1 may have a flat plate structure, which may be rectangular, circular, elliptical, polygonal or irregular, and its material may be silicon or other semiconductor materials.
  • the shape and material of the substrate 1 are not particularly limited herein.
  • step S120 a plurality of spaced conductive contact plugs are formed on the substrate.
  • a plurality of conductive contact plugs 2 can be formed on the substrate 1 at intervals.
  • the conductive contact plugs 2 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition.
  • the conductive contact plugs 2 can be formed on the substrate 1.
  • the conductive contact plugs 2 may also be formed in other ways, which will not be listed one by one here.
  • the conductive contact plug 2 may include a first conductive contact plug 21 and a second conductive contact plug 22, and the second conductive contact plug 22 may be an annular structure, which may be a circular ring or a rectangular ring;
  • the second conductive contact plug 22 may be made of conductor or semiconductor material, for example, the material may be tungsten, copper or polysilicon.
  • There can be a plurality of first conductive contact plugs 21 the plurality of first conductive contact plugs 21 can be located in the annular shape of the second conductive contact plugs 22 , and can be distributed in an array, and the material of the first conductive contact plugs 21 can be the same as that of the second conductive contact plugs 21 .
  • the material of the conductive contact plugs 22 is the same.
  • the substrate 1 may include a cell region 11 and a peripheral region 12 arranged side by side, and the first conductive contact plugs 21 and the second conductive contact plugs 22 are formed in the cell region 11 .
  • a capacitor array is formed, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is respectively formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is connected to all the column capacitors.
  • the conductive contact plugs make contact connections.
  • the capacitor array 3 can be formed on the substrate 1 and can be located on the unit area 11.
  • the capacitor array 3 can include a plurality of column capacitors arranged at intervals, and each column capacitor can be formed on each conductive contact plug. Specifically, Each column capacitor may be formed on each first conductive contact plug 21 , respectively. When in use, multiple capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
  • the capacitor array 3 may include an insulating layer 31 , an insulating medium layer 32 , a lower electrode layer 33 , a capacitor medium layer 34 and an upper electrode layer 35 .
  • the insulating layer 31 is distributed between the first conductive contact plugs 21 and can be used to separate the first conductive contact plugs 21 ;
  • the lower electrode layer 33 can be in the shape of a strip, which can be formed on the first conductive contact plug 21 away from the substrate 1 .
  • one side and can be in contact with the first conductive contact plug 21, and can extend to the side of the first conductive contact plug 21 away from the substrate 1 along the direction perpendicular to the contact direction of the first conductive contact plug 21, so as to form a columnar capacitor .
  • the capacitor dielectric layer 34 is located between the lower electrode layer 33 and the upper electrode layer 35 to form a double-sided capacitor, so as to improve the capacitance.
  • the insulating medium layer 32 can cover the outer periphery of the lower electrode layer 33 , can support the lower electrode layer 33 laterally, increase the stability of the lower electrode layer 33 in the lateral direction, and prevent the lower electrode layer 33 from being deformed laterally.
  • the insulating layer 31 can be formed on the substrate 1.
  • the insulating layer 31 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition.
  • the insulating layer 31 can also be formed by other methods. Layer 31 will not be listed one by one here.
  • the shape of the insulating layer 31 may be the same as that of the substrate 1 , and the material thereof may be silicon nitride, silicon oxide, etc., and the material thereof is not limited herein.
  • the insulating layer 31 can be provided with an annular hole and a plurality of openings arranged in an array inside the annular hole.
  • the annular hole and each opening can be a through hole, and the annular hole can be a circular ring or a rectangular ring.
  • the shape of the annular hole and each opening is not particularly limited here.
  • the second conductive contact plugs 22 may be formed in the annular holes, and at the same time, the first conductive contact plugs 21 may be formed in each opening, and the second conductive contact plugs 22 and a plurality of first conductive contact plugs 21 may be formed simultaneously in one process, For example, the second conductive contact plugs 22 and the plurality of first conductive contact plugs 21 may be simultaneously formed through a chemical vapor deposition process.
  • the second conductive contact plugs 22 can be in contact with the substrate 1 through the annular hole, and at the same time, each of the first conductive contact plugs 21 can be in contact with the substrate 1 through each opening.
  • At least an insulating dielectric layer 32 is formed on the substrate 1 .
  • an insulating dielectric layer 32 can be formed on the side of the insulating layer 31 away from the substrate 1 , and the insulating dielectric layer 32 can cover both the cell region 11 and the peripheral region 12 .
  • Both the capacitor array 3 and the supporting structure 4 can be formed in the insulating dielectric layer 32 opposite to the unit region 11 , that is, the insulating dielectric layer 32 can be used to support the capacitors.
  • the insulating dielectric layer 32 may have a plurality of through holes exposing the first conductive contact plugs 21 respectively.
  • the through holes may be capacitor holes 37 , which may be used to form capacitors.
  • Each capacitor hole 37 may be perpendicular to the insulating medium.
  • the direction of the layer 32 runs through the insulating dielectric layer 32 , and the cross-sectional shape of the layer 32 may be a circle, a rectangle, etc., or an irregular shape, and the shape of the capacitor hole 37 is not particularly limited herein.
  • the through hole can also include an annular ring 41, which can be used to form the support structure 4, which can be a circular ring or a rectangular ring, which is not limited herein.
  • the insulating medium layer 32 may include a first insulating medium layer 322 and a second insulating medium layer 324 spaced along a direction perpendicular to the substrate 1, which may be deposited by vacuum evaporation, magnetron sputtering or chemical vapor deposition
  • the first insulating dielectric layer 322 and the second insulating dielectric layer 324 can be formed in the same manner.
  • the insulating dielectric layer 32 can also be formed by other processes, which are not limited herein.
  • Both the capacitor array 3 and the support structure 4 can be formed in the first insulating dielectric layer 322 and the second insulating dielectric layer 324 , and the capacitors inside the capacitor array 3 can be processed through the first insulating dielectric layer 322 and the second insulating dielectric layer 324 . At the same time, the edge of the capacitor array 3 can be supported by the support structure 4 .
  • a lower electrode layer 33 can be formed in the capacitor hole 37 to conform to the bottom and the sidewall surface of the capacitor hole 37 , and the lower electrode layer 33 can be in contact with the first conductive contact plug 21 through the capacitor hole 37 connected to input the electricity stored in the lower electrode layer 33 to the first conductive contact plug 21 to realize capacitance storage.
  • the chemical vapor deposition process can be used to form the lower electrode layer 33 in the capacitor hole 37 , and of course, the lower electrode layer 33 can also be formed by other processes, which is not limited herein.
  • the material of the lower electrode layer 33 may be titanium nitride, and its thickness may be 4 nm to 10 nm, for example, it may be 4 nm, 6 nm, 8 nm or 10 nm.
  • the lower electrode layer 33 may also be made of other materials or other thicknesses. I will not list them one by one here.
  • the capacitor dielectric layer 34 may be a thin film formed on the outer surface and the inner surface of the structure composed of the lower electrode layer 33 and the insulating dielectric layer 32, and may be formed by vacuum evaporation or magnetron sputtering. Of course, the capacitive dielectric layer 34 can also be formed by other processes, which will not be listed here.
  • the capacitor dielectric layer 34 may be a single-layer film structure composed of the same material, or may be a mixed film layer structure composed of film layers of different materials.
  • it may include a material with a higher dielectric constant, for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
  • a material with a higher dielectric constant for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
  • the upper electrode layer 35 may be formed on the outer surface of the capacitor dielectric layer 34 by a chemical vapor deposition process. Of course, the upper electrode layer 35 may also be formed by other processes, which are not limited herein.
  • the material of the upper electrode layer 35 can be titanium nitride, and its thickness can be 2nm-8nm, for example, it can be 2nm, 4nm, 6nm or 8nm, of course, the upper electrode layer 35 can also be other materials or other thicknesses, I will not list them one by one here.
  • step S140 a support structure is formed, the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are parallel to the substrate
  • the spacing on any cross-section is greater than the diameter of the capacitor hole of any of the column capacitors on the cross-section.
  • the support structure 4 may be formed on the substrate 1, which may be located at the edge of the capacitor array 3, and may surround the periphery of the capacitor array 3. For example, as shown in FIG. 4, the support structure 4 may be formed on the second conductive contact The plug 22 faces away from the surface of the substrate 1 , the bottom of which can be in contact with the second conductive contact plug 22 .
  • the support structure 4 may be formed on the surface of the second conductive contact plug 22 facing away from the substrate 1 by means of vacuum evaporation, magnetron sputtering or chemical vapor deposition.
  • the support structure 4 may be of the same material as the insulating dielectric layer 32, for example, it may be silicon nitride.
  • the support structure 4 can be in contact with the capacitor array 3, for example, it can be in contact with the insulating dielectric layer 32 in the capacitor array 3, so as to support the capacitors located at the edge of the capacitor array 3 all around, increasing the capacitor array 3
  • the stability in the lateral direction prevents the lateral deformation of the capacitors located at the edge of the capacitor array 3 and avoids short circuits.
  • the spacing between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the aperture of the capacitor hole 37 of any column capacitor in the capacitor array 3 on the cross section, which can ensure that the support structure 4 is positioned opposite to the capacitor array.
  • the support strength of the capacitor at the edge part may be at least twice the diameter of any capacitor hole 37 in the capacitor array 3 on the cross section.
  • the minimum value of the distance between the inner wall and the outer wall of the support structure 4 may also be greater than the maximum value of the diameter of any capacitor hole 37 .
  • the distance between the inner wall and the outer wall of the support structure 4 can be increased sequentially from the side close to the substrate 1 to the side away from the substrate 1 .
  • the distance between the inner wall and the outer wall can also be equal, and the size between the inner wall and the outer wall of the support structure 4 is not particularly limited here.
  • the orthographic projection of the support structure 4 on the second conductive contact plug 22 can be coincident with the boundary of the second conductive contact plug 22, that is, the support structure 4 can be a continuous whole, which can be continuously wrapped around the second conductive contact plug 22. Outside the capacitor array 3, so as to continuously support the edge portion of the capacitor array 3.
  • the supporting structure 4 may be a discontinuous segment, which may include a plurality of supporting regions distributed at intervals and a one-to-one corresponding supporting column formed on each supporting region, and the thickness of each supporting column may be equal. , and can be encircled in a ring shape, and each support column can be respectively contacted and connected with the insulating medium layer 32 of the capacitor array 3 , so as to support the capacitor array 3 in sections.
  • the thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of each capacitor in the capacitor array 3 in the direction perpendicular to the substrate 1, which can support the capacitor array 3 in the lateral direction, and can also The capacitor array 3 is supported in the longitudinal direction to improve the stability of the device.
  • the thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of the lower electrode layer 33 in the direction perpendicular to the substrate 1, and the capacitors located at the edge of the capacitor array 3 can be adjusted by the support structure 4.
  • the lower electrode layer 33 of the capacitor array 3 is supported laterally and vertically to prevent the lower electrode layer 33 of the capacitor located at the edge of the capacitor array 3 from deforming outward.
  • forming the capacitor array 3 and the supporting structure 4 on the substrate 1 may include steps S210 to S250, as shown in FIG. 10 , wherein:
  • Step S210 forming a sacrificial layer and an insulating dielectric layer on the substrate in sequence, using the conductive contact plug as an etch stop layer, etching the sacrificial layer and the insulating dielectric layer in the unit area, and etching the sacrificial layer and the insulating dielectric layer in the unit area.
  • the area forms a plurality of columnar void structures arranged at intervals, and the etching window is controlled so that the cross-sectional spacing of the columnar void structures located at the periphery of the unit area in the direction parallel to the substrate is greater than that of the non-periphery in the unit area.
  • the cross-sectional spacing of the columnar void structures is controlled so that the cross-sectional spacing of the columnar void structures located at the periphery of the unit area in the direction parallel to the substrate is greater than that of the non-periphery in the unit area.
  • the insulating layer 31 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition, etc. Of course, the insulating layer 31 can also be formed by other methods, which will not be listed here.
  • the shape of the insulating layer 31 may be the same as that of the substrate 1 , and the material thereof may be silicon nitride, silicon oxide, etc., and the material thereof is not limited herein.
  • the pattern in the mask can be transferred to the insulating layer 31 by a photolithography process.
  • the mask can be grid-shaped, and the pattern on it can be the same as the pattern required for the annular hole and each opening, so that the insulating layer 31 can be formed.
  • An annular hole and a plurality of openings arranged in an array are formed inside the annular hole, the annular hole and each opening can be a through hole, the annular hole can be a circular ring or a rectangular ring, and each opening can be circular, It can also be rectangular or irregular, and the shape of the annular hole and each opening is not limited here.
  • An overlapping sacrificial layer and an insulating dielectric layer 32 may be sequentially formed on the surface of the structure formed by each of the first conductive contact plugs 21 , the second conductive contact plugs 22 and the substrate 1 by chemical vapor deposition or physical vapor deposition. As shown in FIG. 11 , it may include a first sacrificial layer 321 , a first insulating dielectric layer 322 , a second sacrificial layer 323 and a second insulating dielectric layer 324 , which are stacked in sequence, which can be formed by vacuum evaporation or magnetron sputtering.
  • the first sacrificial layer 321, the first insulating dielectric layer 322, the second sacrificial layer 323, and the second insulating dielectric layer 324 are formed in other ways.
  • the dielectric layer 322 , the second sacrificial layer 323 and the second insulating dielectric layer 324 are not particularly limited herein.
  • the first sacrificial layer 321 can be formed on the surface of the structure formed by the first conductive contact plugs 21, the second conductive contact plugs 22 and the substrate 1, and its material can be SiO2; the first insulating dielectric layer 322 can be formed on the surface of the structure.
  • a thin film on the side of the sacrificial layer 321 away from the substrate 1 can be made of silicon nitride or SiCN; the second sacrificial layer 323 can be formed on the side of the first insulating dielectric layer 322 away from the first sacrificial layer 321, and can be The material and thickness of the first sacrificial layer 321 are the same, and the top surfaces of the first sacrificial layer 321 and the second sacrificial layer 323 may be polished by a chemical polishing process, so that the first sacrificial layer 321 and the second sacrificial layer 323 The thickness of each part is uniform; the second insulating dielectric layer 324 can be formed on the side of the second sacrificial layer 323 away from the first insulating dielectric layer 322, and can be made of the same material as the first insulating dielectric layer 322. It should be noted that , the thickness of each insulating dielectric layer 32 may be the same or different, which is not particularly limited here.
  • a photoresist layer 3341 may be formed on the second insulating medium layer 324 by spin coating or other methods, and the material of the photoresist layer 3341 may be positive photoresist or negative photoresist, which is not limited herein.
  • the shape of the surface of the photoresist layer 3341 away from the second insulating medium layer 324 may be the same as the shape of the surface of the second insulating medium layer 324 .
  • the photoresist layer 3341 can be exposed using a mask, the pattern of which can be matched to the desired pattern of the annular ring 41 and each capacitor hole 37 . Subsequently, the exposed photoresist layer 3341 can be developed to form a developed area, as shown in FIG.
  • the second insulating medium layer 324 can be exposed in the developed area, and the pattern of the developed area can be matched with the annular ring 41 and the respective The required pattern of the capacitor holes 37 is the same, and the size of the developing area can be the same as the required size of the annular ring 41 and each capacitor hole 37 .
  • the first sacrificial layer 321, the first insulating dielectric layer 322, the second sacrificial layer 323 and the second insulating dielectric layer 324 can be etched in the developing area by dry etching, and the conductive contact plug 2 is used as the etching stop layer, A plurality of columnar void structures arranged at intervals are formed in the unit region 11 , and the columnar void structures can expose the second conductive contact plug 22 and each of the first conductive contact plugs 21 .
  • the opening size of the columnar void structure can be controlled so that The cross-sectional spacing of the columnar void structures located at the periphery of the cell region 11 in the direction parallel to the substrate 1 is greater than the cross-sectional spacing of the non-peripheral columnar void structures in the cell region 11 .
  • the columnar pore structure corresponding to the first conductive contact plug 21 may be used as the capacitor hole 37
  • the columnar pore structure corresponding to the second conductive contact plug 22 may be used as the annular ring 41.
  • each capacitor hole 37 can be sequentially increased from the side close to the substrate 1 to the side away from the substrate 1.
  • each capacitor hole 37 can also be a straight hole.
  • the size is specially limited.
  • the distance between the inner wall and the outer wall of the annular ring 41 can be increased sequentially from the side close to the substrate 1 to the side away from the substrate 1 .
  • the distance between the inner wall and the outer wall can also be equal, and the size between the inner wall and the outer wall of the annular ring 41 is not particularly limited here.
  • Step S220 depositing a lower electrode material, and forming a lower electrode layer on the sidewall of the columnar void structure.
  • the lower electrode layer 33 can be formed on the sidewall of the columnar void structure. Specifically, the lower electrode layer 33 can be formed in the capacitor hole 37 to conform to the bottom of the capacitor hole 37 and the surface of the sidewall, as shown in FIG. 13 . For the convenience of the process, the lower electrode layer 33 can be formed in the capacitor hole 37 and its top surface at the same time, and then the lower electrode layer 33 on the top surface of the capacitor hole 37 can be removed, and only the bottom electrode layer 33 on the bottom and sidewalls of the capacitor hole 37 can be left, and finally The formed lower electrode layer 33 is shown in FIG. 3 . In addition, the lower electrode layer 33 can be in contact with the first conductive contact plug 21 through the capacitor hole 37 to input the electricity stored in the lower electrode layer 33 to the storage dielectric contact plug, thereby realizing capacitance storage.
  • the chemical vapor deposition process can be used to form the lower electrode layer 33 in the capacitor hole 37 , and of course, the lower electrode layer 33 can also be formed by other processes, which is not limited herein.
  • the material of the lower electrode layer 33 may be titanium nitride, and its thickness may be 4 nm to 10 nm, for example, it may be 4 nm, 6 nm, 8 nm or 10 nm.
  • the lower electrode layer 33 may also be made of other materials or other thicknesses. I will not list them one by one here.
  • the lower electrode layer 33 may also be formed in the annular ring 41 at the same time.
  • Step S230 depositing a dielectric material, the dielectric material filling the columnar void structures at the periphery of the cell region to form the support structure, and the non-periphery columnar void structures in the cell region are not filled.
  • a chemical vapor deposition process can be used to deposit a dielectric material on the surface of the second insulating dielectric layer 324 facing away from the second sacrificial layer 323 and in the annular ring 41 to form a cover layer 7, as shown in FIG. 14, the cover layer 7 can fill the cell
  • the columnar void structure at the periphery of the area 11 is filled with the annular ring 41 to form the support structure 4 .
  • the columnar void structure at the non-periphery of the cell area 11 is not filled, that is, the capacitor hole 37 is not filled.
  • a mask material layer can be formed on the side of the insulating dielectric layer 32 farthest from the substrate 1 away from the substrate 1 by chemical vapor deposition or other methods, and the mask material layer can cover the capacitor hole 37 away from the first conductive contact. one side of the plug 21.
  • the material of the mask material layer may be at least one of silicon oxide, oxynitride or carbon, and of course, may also be other materials, which will not be listed here.
  • the mask material layer may be a single-layer structure or a multi-layer structure, which is not particularly limited here.
  • the photoresist layer 3341 may be formed on the mask material layer by spin coating or other methods, and the material of the photoresist layer 3341 may be positive photoresist or negative photoresist, which is not limited herein.
  • the photoresist layer 3341 can be exposed using a mask, and the pattern of the mask can match the desired pattern of the opening on the insulating medium layer 32 farthest from the substrate 1 , as shown in FIG. 16 .
  • the orthographic projection of the opening 71 on the substrate 1 may cover the area between two adjacent capacitor holes 37 .
  • the exposed photoresist layer 3341 may be developed to form a development area, which may expose the mask material layer.
  • FIG. 17 the mask material layer and the insulating medium layer 32 farthest from the substrate 1 are etched in the developing area to form an opening 71 through which the sacrificial layer adjacent to the insulating medium layer 32 can be exposed. .
  • Step S240 removing the sacrificial layer in the unit region and leaving the insulating dielectric layer.
  • the sacrificial layers in the unit region 11 can be removed, and the insulating dielectric layers 32 can be retained, which can not only increase the capacitance storage density, but also support the lower electrode layer 33 and prevent the lower electrode layer 33 from being deformed. , reduce the risk of short circuit.
  • the surface of the cover layer 7 can also be planarized to remove the cover layer 7 located at the top of the outer ring 41 , so that the surface of the cover layer 7 in the ring ring 41 is insulated from the second The surface of the dielectric layer 324 on the side facing away from the substrate 1 is flush to form the support structure 4 .
  • step S250 a capacitor dielectric layer and an upper electrode layer are sequentially formed on the lower electrode layer of the non-peripheral columnar void structure in the unit region to form a capacitor array.
  • the capacitor dielectric layer 34 can be formed on the lower electrode layer 33 in the capacitor hole 37 of the unit region 11.
  • the capacitor dielectric layer 34 can be a thin film formed on the surface of the lower electrode layer 33, which can be formed by vacuum evaporation or magnetic
  • the capacitive dielectric layer 34 may be formed by processes such as controlled sputtering. Of course, the capacitive dielectric layer 34 may also be formed by other processes, which will not be listed here.
  • the capacitor dielectric layer 34 may be a single-layer film structure composed of the same material, or may be a mixed film layer structure composed of film layers of different materials.
  • it may include a material with a higher dielectric constant, for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
  • a material with a higher dielectric constant for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
  • the upper electrode layer 35 may be formed on the outer surface of the capacitor dielectric layer 34 by a chemical vapor deposition process. Of course, the upper electrode layer 35 may also be formed by other processes, which are not limited herein.
  • the material of the upper electrode layer 35 can be titanium nitride, and its thickness can be 2nm-8nm, for example, it can be 2nm, 4nm, 6nm or 8nm, of course, the upper electrode layer 35 can also be other materials or other thicknesses, I will not list them one by one here.
  • the forming method of the present disclosure may further include the steps: as shown in FIG. 9 , wherein:
  • Step S150 forming a semiconductor layer covering the surface of the capacitor array, the semiconductor layer filling the capacitor hole and the gap between two adjacent capacitors in the capacitor array.
  • the semiconductor layer 5 covering the capacitor array 3 can be formed on the surface of the upper electrode layer 35 by a vacuum evaporation process, so that the electric charges can be fully contacted with the second electrode, which helps to improve the charging efficiency of the capacitor.
  • the semiconductor layer 5 can cover the surface of the capacitor array 3 and can fill the capacitor hole 37 and the gap between two adjacent capacitors in the capacitor array 3 , which can improve the electrical conductivity of the device and enhance the stability of each capacitor in the capacitor array 3 sex.
  • the semiconductor layer 5 may be composed of silicon material, metal material or metal compound, for example, it may be silicon, silicon germanium, tungsten, titanium silicide, titanium oxide or tungsten oxide, etc., which is not limited herein.
  • the formation method of the present disclosure may further include:
  • Step S160 forming an interconnection structure in the peripheral region.
  • the interconnection structure can be formed in the insulating dielectric layer 32 corresponding to the peripheral region 12 , and can be in contact with the peripheral conductive contact plugs 23 , so as to electrically lead out the capacitor array 3 .
  • the peripheral conductive contact plugs 23 can be made of the same material as the first conductive contact plugs 21 and the second conductive contact plugs 22 and have the same thickness, and the peripheral conductive contact plugs can be formed at the same time as the first conductive contact plugs 21 and the second conductive contact plugs 22 are formed twenty three.
  • forming the interconnect structure may include:
  • Step S1601 the conductive contact plugs are formed in the peripheral region while the conductive contact plugs are formed on the unit region of the substrate.
  • the first conductive contact plugs 21 , the second conductive contact plugs 22 and the peripheral conductive contact plugs 23 located in the peripheral area 12 of the cell region 11 may be simultaneously formed in one process.
  • the first conductive contact plugs 21 , the second conductive contact plugs 22 and the peripheral conductive contact plugs 23 can be formed simultaneously by a chemical vapor deposition process and a dry etching process.
  • the first conductive contact plugs 21 can also be formed simultaneously by means of , the second conductive contact plug 22 and the peripheral conductive contact plug 23 , which will not be listed one by one here.
  • Step S1602 forming a first sacrificial layer in the peripheral region.
  • the first sacrificial layer 321 can be formed by vacuum evaporation, magnetron sputtering, atomic layer deposition, or the like.
  • Step S1603 using the conductive contact plug in the peripheral region as an etch stop layer, etching the first sacrificial layer to form a first via hole.
  • the first via hole 61 may be formed by a photolithography process, and the first via hole 61 may be formed in the first sacrificial layer 321 and may expose the peripheral conductive contact plugs 23 .
  • Step S1604 forming a first interconnect structure in the first via hole.
  • the first interconnect structure 6 can be formed in the first via hole 61 by a chemical vapor deposition process, and the first interconnect structure 6 can be communicated with the semiconductor layer 5 through the first via hole 61 so as to electrically lead out the capacitor array 3 .
  • the first interconnection structure 6 may include a connection layer 62 and an extraction layer 63.
  • the connection layer 62 may be attached to the hole wall and bottom surface of the first via hole 61, and may communicate with the top of the semiconductor layer 5.
  • the extraction layer 63 may be connected to the top of the semiconductor layer 5. It is located on the connection layer 62 and can fill the first via hole 61 .
  • Both the connection layer 62 and the extraction layer 63 can be made of conductive materials, for example, the connection layer 62 can be made of titanium nitride, and the extraction layer 63 can be made of tungsten.
  • the forming method of the present disclosure may further include:
  • step S1605 the insulating dielectric layer and the second sacrificial layer are sequentially formed on the first sacrificial layer in the peripheral region, and the first interconnection structure is used as an etch stop layer to etch the insulating dielectric layer and the second sacrificial layer.
  • two sacrificial layers to form second vias are sequentially formed on the first sacrificial layer in the peripheral region.
  • the insulating dielectric layer 32 and the second sacrificial layer 323 can be sequentially formed on the first sacrificial layer 321 in the peripheral region 12 by vacuum evaporation, magnetron sputtering, atomic layer deposition, etc., and the second via hole can be formed by a photolithography process , the second via hole can be formed in the second sacrificial layer 323 and can be in contact with the first interconnect structure 6 .
  • Step S1606 forming a second interconnection structure in the second via hole.
  • the second interconnection structure can be formed in the second via hole by a chemical vapor deposition process, and the second interconnection structure can be communicated with the first interconnection structure 6 through the second via hole, so as to electrically lead out the capacitor array 3 .
  • the second interconnection structure may be the same in structure and material as the first interconnection structure 6 , the second interconnection structure may also include a connection layer and a lead-out layer, and the connection layer may be attached to the hole wall of the second via hole 91 according to the pattern and the bottom surface, and can communicate with the top of the first interconnection structure 6 , the lead-out layer can be located on the connection layer, and the second via hole 91 can be filled.
  • the semiconductor device of the present disclosure can be a memory chip, for example, it can be a DRAM (Dynamic Random Access Memory, dynamic random access memory), of course, can also be other semiconductor devices, which will not be listed one by one here.
  • DRAM Dynamic Random Access Memory, dynamic random access memory

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Semiconductor Memories (AREA)
  • Semiconductor Integrated Circuits (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

The present disclosure relates to the technical field of semiconductors, and provides a semiconductor device and a method for forming same. The semiconductor device of the present disclosure comprises a substrate, a capacitor array, and a support structure; a plurality of conductive contact plugs arranged at intervals are formed on the substrate; the capacitor array comprises a plurality of columnar capacitors arranged at intervals, the columnar capacitors are respectively formed on the conductive contact plugs, and a lower electrode of each columnar capacitor is in contact connection with the corresponding conductive contact plug; the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array; the distance between the inner wall and the outer wall of the support structure in any cross section parallel to the substrate is greater than the aperture of a capacitor hole of any columnar capacitor in the cross section. The semiconductor device of the present disclosure can perform lateral support on the outside of the capacitor array, thereby avoiding short circuit and increasing capacitance.

Description

半导体器件及其形成方法Semiconductor device and method of forming the same
交叉引用cross reference
本公开要求于2020年8月21日提交的申请号为202010849895.1,名称为“半导体器件及其形成方法。”的中国专利申请的优先权,该中国专利申请的全部内容通过引用全部并入本文。This disclosure claims priority to the Chinese Patent Application No. 202010849895.1, entitled "Semiconductor Device and Method for Forming the Same," filed on August 21, 2020, the entire contents of which are incorporated herein by reference in their entirety.
技术领域technical field
本公开涉及半导体技术领域,具体而言,涉及一种半导体器件及其形成方法。The present disclosure relates to the field of semiconductor technology, and in particular, to a semiconductor device and a method for forming the same.
背景技术Background technique
随着移动设备的不断发展,手机、平板电脑、可穿戴设备等带有电池供电的移动设备被越来越多地应用于生活中,存储器作为移动设备中必不可少的元件,人们对存储器的小体积、集成化提出了巨大的需求。With the continuous development of mobile devices, battery-powered mobile devices such as mobile phones, tablet computers, and wearable devices are more and more used in life. Small size and integration have put forward huge demands.
目前,动态随机存储器(Dynamic Random Access Memory,DRAM)以其快速的传输速度被广泛应用于移动设备中。但是,随着体积的不断微缩,动态随机存储器中的柱状存储电容的尺寸也在不断缩小,密度也越来越大,电容结构的稳定性也随之降低。At present, Dynamic Random Access Memory (DRAM) is widely used in mobile devices due to its fast transmission speed. However, with the continuous shrinking of the volume, the size of the columnar storage capacitor in the dynamic random access memory is also shrinking, the density is also increasing, and the stability of the capacitor structure is also reduced.
需要说明的是,在上述背景技术部分公开的信息仅用于加强对本公开的背景的理解,因此可以包括不构成对本领域普通技术人员已知的现有技术的信息。It should be noted that the information disclosed in the above Background section is only for enhancement of understanding of the background of the present disclosure, and therefore may contain information that does not form the prior art that is already known to a person of ordinary skill in the art.
公开内容public content
本公开的目的在于克服上述现有技术的不足,提供一种半导体器件及其形成方法,可对电容阵列外部进行横向支撑,避免短路,提高电容量。The purpose of the present disclosure is to overcome the above-mentioned deficiencies of the prior art, and to provide a semiconductor device and a method for forming the same, which can laterally support the outside of the capacitor array, avoid short circuits, and increase the capacitance.
根据本公开的一个方面,提供一种半导体器件,包括:According to one aspect of the present disclosure, there is provided a semiconductor device including:
衬底,所述衬底上形成有多个间隔排布的导电接触塞;a substrate, on which a plurality of conductive contact plugs arranged at intervals are formed;
电容阵列,所述电容阵列包括多个间隔排布的柱状电容,各所述柱状电容分别形成在各所述导电接触塞上,且所述柱状电容的下电极层与所述导电接触塞接触连接;A capacitor array, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is in contact with the conductive contact plug ;
支撑结构,所述支撑结构形成于所述电容阵列边缘的所述衬底上,并环绕所述电容阵列,且所述支撑结构的内壁与外壁在平行于所述衬底的任一横截面上的间距大于任一所述柱状电容的电容孔在所述横截面上的孔径。a support structure, the support structure is formed on the substrate at the edge of the capacitor array and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are on any cross section parallel to the substrate The spacing is greater than the diameter of the capacitor hole on the cross section of any one of the column capacitors.
在本公开的一种示例性实施例中,所述导电接触塞包括第一导电接触塞和第二导电接触塞,所述第一导电接触塞与所述柱状电容的下电极层接触,所述第二导电 接触塞与所述支撑结构的底部接触。In an exemplary embodiment of the present disclosure, the conductive contact plug includes a first conductive contact plug and a second conductive contact plug, the first conductive contact plug is in contact with the lower electrode layer of the column capacitor, the A second conductive contact plug is in contact with the bottom of the support structure.
在本公开的一种示例性实施例中,所述衬底上至少形成有绝缘介质层,所述电容阵列和所述支撑结构形成于所述绝缘介质层中。In an exemplary embodiment of the present disclosure, at least an insulating dielectric layer is formed on the substrate, and the capacitor array and the support structure are formed in the insulating dielectric layer.
在本公开的一种示例性实施例中,所述支撑结构在所述第二导电接触塞上的正投影与所述第二导电接触塞的边界重合。In an exemplary embodiment of the present disclosure, an orthographic projection of the support structure on the second conductive contact plug coincides with a boundary of the second conductive contact plug.
在本公开的一种示例性实施例中,所述衬底包括单元区域和外围区域,所述电容阵列形成在所述单元区域,所述导电接触塞还包括外围导电接触塞,所述外围导电接触塞形成在所述外围区域,所述半导体器件还包括与所述外围导电接触塞连接的互连结构,所述互连结构形成在所述绝缘介质层中。In an exemplary embodiment of the present disclosure, the substrate includes a cell region and a peripheral region, the capacitor array is formed in the cell region, the conductive contact plug further includes a peripheral conductive contact plug, the peripheral conductive Contact plugs are formed in the peripheral region, and the semiconductor device further includes an interconnect structure connected to the peripheral conductive contact plug, the interconnect structure formed in the insulating dielectric layer.
在本公开的一种示例性实施例中,所述绝缘介质层包括沿垂直于所述衬底的方向间隔排布的第一绝缘介质层和第二绝缘介质层,所述电容阵列和所述支撑结构形成在所述第一绝缘介质层和所述第二绝缘介质层中。In an exemplary embodiment of the present disclosure, the insulating dielectric layer includes a first insulating dielectric layer and a second insulating dielectric layer spaced along a direction perpendicular to the substrate, the capacitor array and the A support structure is formed in the first insulating dielectric layer and the second insulating dielectric layer.
根据本公开的一个方面,提供一种半导体器件的形成方法,所述形成方法包括:According to one aspect of the present disclosure, there is provided a method of forming a semiconductor device, the forming method comprising:
提供衬底;provide a substrate;
在所述衬底上形成多个间隔排布的导电接触塞;forming a plurality of spaced-apart conductive contact plugs on the substrate;
形成电容阵列,所述电容阵列包括多个间隔排布的柱状电容,各所述柱状电容分别形成在各所述导电接触塞上,且所述柱状电容的下电极层与所述导电接触塞接触连接;A capacitor array is formed, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is in contact with the conductive contact plug connect;
形成支撑结构,所述支撑结构形成于所述电容阵列边缘的所述衬底上,并环绕所述电容阵列,且所述支撑结构的内壁与外壁在平行于所述衬底的任一横截面上的间距大于任一所述柱状电容的电容孔在所述横截面上的孔径。A support structure is formed, the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are in any cross-section parallel to the substrate The distance between the capacitor holes is larger than the diameter of the capacitor holes on the cross section of any one of the column capacitors.
在本公开的一种示例性实施例中,所述衬底具有单元区域,所述单元区域上形成有多个间隔排布的导电接触塞,且位于所述单元区域边缘的所述导电接触塞的宽度大于所述单元区域中非边缘的所述导电接触塞的宽度,所述形成电容阵列和支撑结构包括:In an exemplary embodiment of the present disclosure, the substrate has a unit area, a plurality of conductive contact plugs arranged at intervals are formed on the unit area, and the conductive contact plugs are located at the edge of the unit area The width of the conductive contact plug is greater than the width of the non-edge conductive contact plug in the unit area, and the forming the capacitor array and the supporting structure includes:
在所述衬底上依次形成牺牲层和绝缘介质层,以所述导电接触塞为蚀刻停止层,蚀刻所述单元区域的所述牺牲层和所述绝缘介质层,在所述单元区域形成多个间隔排布的柱状空隙结构,并控制蚀刻窗口,使得位于所述单元区域外围的柱状空隙结构在平行于所述衬底方向上的横截面间距大于所述单元区域中非外围的柱状空隙结构的横截面间距;A sacrificial layer and an insulating dielectric layer are sequentially formed on the substrate, the conductive contact plug is used as an etch stop layer, the sacrificial layer and the insulating dielectric layer in the unit area are etched, and multiple layers are formed in the unit area. Columnar void structures are arranged at intervals, and the etching window is controlled so that the cross-sectional spacing of the columnar void structures located at the periphery of the cell region in the direction parallel to the substrate is greater than that of the non-periphery columnar void structures in the cell region the cross-sectional spacing;
沉积下电极材料,在所述柱状空隙结构的侧壁形成下电极层;depositing a lower electrode material to form a lower electrode layer on the sidewall of the columnar void structure;
沉积电介质材料,所述电介质材料填满所述单元区域外围的所述柱状空隙结构,以形成所述支撑结构,且在所述单元区域的非外围柱状空隙结构未被填充;depositing a dielectric material, the dielectric material filling the columnar void structures at the periphery of the cell region to form the support structure, and the non-peripheral columnar void structures in the cell region being unfilled;
去除所述单元区域内的所述牺牲层,保留所述绝缘介质层;removing the sacrificial layer in the unit region, leaving the insulating dielectric layer;
在所述单元区域的非外围柱状空隙结构的下电极层上依次形成电容介质层和上 电极层,以形成电容阵列。A capacitor dielectric layer and an upper electrode layer are sequentially formed on the lower electrode layer of the non-peripheral columnar void structure in the unit area to form a capacitor array.
在本公开的一种示例性实施例中,所述衬底还具有外围区域,在蚀刻所述单元区域的所述牺牲层和所述绝缘介质层之前,所述形成方法还包括:In an exemplary embodiment of the present disclosure, the substrate further has a peripheral region, and before etching the sacrificial layer and the insulating dielectric layer in the unit region, the forming method further includes:
在所述外围区域形成互连结构。An interconnect structure is formed in the peripheral region.
在本公开的一种示例性实施例中,形成所述互连结构包括:In an exemplary embodiment of the present disclosure, forming the interconnect structure includes:
在所述衬底的单元区域上形成所述导电接触塞的同时在所述外围区域形成所述导电接触塞;forming the conductive contact plugs in the peripheral region while forming the conductive contact plugs on the cell region of the substrate;
在所述外围区域形成第一牺牲层;forming a first sacrificial layer in the peripheral region;
以所述外围区域的所述导电接触塞为蚀刻停止层,蚀刻所述第一牺牲层,以形成第一过孔;Using the conductive contact plug in the peripheral region as an etch stop layer, etching the first sacrificial layer to form a first via hole;
在所述第一过孔中形成第一互连结构。A first interconnect structure is formed in the first via.
在本公开的一种示例性实施例中,在形成所述第一互连结构后,所述形成方法还包括:In an exemplary embodiment of the present disclosure, after forming the first interconnect structure, the forming method further includes:
在所述外围区域的第一牺牲层上依次形成所述绝缘介质层和第二牺牲层,以所述第一互连结构为蚀刻停止层,蚀刻所述绝缘介质层和所述第二牺牲层,以形成第二过孔;The insulating dielectric layer and the second sacrificial layer are sequentially formed on the first sacrificial layer in the peripheral region, and the insulating dielectric layer and the second sacrificial layer are etched using the first interconnect structure as an etch stop layer. , to form a second via;
在所述第二过孔中形成第二互连结构。A second interconnect structure is formed in the second via.
本公开的半导体器件及其形成方法,由于支撑结构环绕于电容阵列外侧,可对电容阵列外部进行横向支撑,增加电容阵列在横向上的稳定性,防止电容阵列中的电容产生横向形变,避免短路;同时,由于支撑结构的内壁与外壁在平行于衬底的任一横截面上的间距大于电容阵列中任一电容孔在横截面上的孔径,可保证支撑结构的支撑强度。此外,由于电容阵列中包含多个电容,在使用时,多个电容可同时充放电,可提高电容量。In the semiconductor device and its forming method of the present disclosure, since the support structure surrounds the outside of the capacitor array, the outside of the capacitor array can be laterally supported, thereby increasing the lateral stability of the capacitor array, preventing lateral deformation of the capacitors in the capacitor array, and avoiding short circuits. At the same time, since the distance between the inner wall and the outer wall of the support structure on any cross section parallel to the substrate is larger than the aperture of any capacitor hole in the capacitor array on the cross section, the support strength of the support structure can be guaranteed. In addition, since the capacitor array includes multiple capacitors, the multiple capacitors can be charged and discharged at the same time during use, thereby increasing the capacitance.
应当理解的是,以上的一般描述和后文的细节描述仅是示例性和解释性的,并不能限制本公开。It is to be understood that the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the present disclosure.
附图说明Description of drawings
此处的附图被并入说明书中并构成本说明书的一部分,示出了符合本公开的实施例,并与说明书一起用于解释本公开的原理。显而易见地,下面描述中的附图仅仅是本公开的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the disclosure and together with the description serve to explain the principles of the disclosure. Obviously, the drawings in the following description are only some embodiments of the present disclosure, and for those of ordinary skill in the art, other drawings can also be obtained from these drawings without creative effort.
图1为本公开实施方式半导体器件的结构示意图。FIG. 1 is a schematic structural diagram of a semiconductor device according to an embodiment of the disclosure.
图2为本公开实施方式电容孔和环形圈的结构示意图。FIG. 2 is a schematic structural diagram of a capacitor hole and an annular ring according to an embodiment of the present disclosure.
图3为本公开实施方式下电极层的结构示意图。FIG. 3 is a schematic structural diagram of a lower electrode layer according to an embodiment of the disclosure.
图4为本公开实施方式支撑结构的结构示意图。FIG. 4 is a schematic structural diagram of a support structure according to an embodiment of the present disclosure.
图5为本公开实施方式半导体层的结构示意图。FIG. 5 is a schematic structural diagram of a semiconductor layer according to an embodiment of the disclosure.
图6为本公开实施方式绝缘介质层的结构示意图。FIG. 6 is a schematic structural diagram of an insulating dielectric layer according to an embodiment of the disclosure.
图7为本公开实施方式第一过孔的结构示意图。FIG. 7 is a schematic structural diagram of a first via hole according to an embodiment of the present disclosure.
图8为本公开实施方式连接层的结构示意图。FIG. 8 is a schematic structural diagram of a connection layer according to an embodiment of the present disclosure.
图9为本公开实施方式半导体器件的形成方法的流程图。9 is a flowchart of a method of forming a semiconductor device according to an embodiment of the disclosure.
图10为本公开实施方式中形成电容阵列及支撑结构的流程图。FIG. 10 is a flow chart of forming a capacitor array and a support structure in an embodiment of the disclosure.
图11为本公开实施方式绝缘介质层和牺牲层的结构示意图。FIG. 11 is a schematic structural diagram of an insulating dielectric layer and a sacrificial layer according to an embodiment of the disclosure.
图12为本公开实施方式在绝缘介质层上形成光刻胶后的结构示意图。FIG. 12 is a schematic structural diagram of forming a photoresist on an insulating dielectric layer according to an embodiment of the present disclosure.
图13为本公开实施方式中覆盖电容孔及其顶表面的下电极层的结构示意图。13 is a schematic structural diagram of a lower electrode layer covering a capacitor hole and its top surface in an embodiment of the disclosure.
图14为本公开实施方式覆盖层的结构示意图。FIG. 14 is a schematic structural diagram of a cover layer according to an embodiment of the disclosure.
图15为本公开实施方式在覆盖层上形成光刻胶后的结构示意图。FIG. 15 is a schematic diagram of a structure after forming a photoresist on the cover layer according to an embodiment of the present disclosure.
图16为本公开实施方式在覆盖层上形成的开口的结构示意图。FIG. 16 is a schematic structural diagram of an opening formed in a cover layer according to an embodiment of the present disclosure.
图17为本公开实施方式去除顶部牺牲层后的结构示意图。FIG. 17 is a schematic structural diagram of an embodiment of the present disclosure after removing the top sacrificial layer.
图18为本公开实施方式对覆盖层进行平坦化处理后的结构示意图。FIG. 18 is a schematic structural diagram of a cover layer after planarization processing is performed according to an embodiment of the present disclosure.
图19为对应于图9中步骤S160的流程图。FIG. 19 is a flowchart corresponding to step S160 in FIG. 9 .
图中:1、衬底;11、单元区域;12、外围区域;2、导电接触塞;21、第一导电接触塞;22、第二导电接触塞;23、外围导电接触塞;3、电容阵列;31、绝缘层;32、绝缘介质层;321、第一牺牲层;322、第一绝缘介质层;323、第二牺牲层;324、第二绝缘介质层;3341、光刻胶层;33、下电极层;34、电容介质层;35、上电极层;37、电容孔;4、支撑结构;41、环形圈;5、半导体层;6、第一互连结构;61、第一过孔;62、连接层;63、引出层;7、覆盖层;71、开口。In the figure: 1, substrate; 11, unit area; 12, peripheral area; 2, conductive contact plug; 21, first conductive contact plug; 22, second conductive contact plug; 23, peripheral conductive contact plug; 3, capacitor Array; 31, insulating layer; 32, insulating medium layer; 321, first sacrificial layer; 322, first insulating medium layer; 323, second sacrificial layer; 324, second insulating medium layer; 3341, photoresist layer; 33, lower electrode layer; 34, capacitor dielectric layer; 35, upper electrode layer; 37, capacitor hole; 4, support structure; 41, annular ring; 5, semiconductor layer; 6, first interconnect structure; 61, first 62, connection layer; 63, lead-out layer; 7, cover layer; 71, opening.
具体实施方式detailed description
现在将参考附图更全面地描述示例实施方式。然而,示例实施方式能够以多种形式实施,且不应被理解为限于在此阐述的实施方式;相反,提供这些实施方式使得本公开将全面和完整,并将示例实施方式的构思全面地传达给本领域的技术人员。图中相同的附图标记表示相同或类似的结构,因而将省略它们的详细描述。此外,附图仅为本公开的示意性图解,并非一定是按比例绘制。Example embodiments will now be described more fully with reference to the accompanying drawings. Example embodiments, however, can be embodied in various forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of example embodiments to those skilled in the art. The same reference numerals in the drawings denote the same or similar structures, and thus their detailed descriptions will be omitted. Furthermore, the drawings are merely schematic illustrations of the present disclosure and are not necessarily drawn to scale.
虽然本说明书中使用相对性的用语,例如“上”“下”来描述图标的一个组件对于另一组件的相对关系,但是这些术语用于本说明书中仅出于方便,例如根据附图中所述的示例的方向。能理解的是,如果将图标的装置翻转使其上下颠倒,则所叙述在“上”的组件将会成为在“下”的组件。当某结构在其它结构“上”时,有可能是指某结构一体形成于其它结构上,或指某结构“直接”设置在其它结构上,或指某结构通过另一结构“间接”设置在其它结构上。Although relative terms such as "upper" and "lower" are used in this specification to describe the relative relationship of one component of an icon to another component, these terms are used in this specification only for convenience, such as according to the direction of the example described. It will be appreciated that if the device of the icon is turned upside down, the components described as "on" will become the components on "bottom". When a certain structure is "on" other structures, it may mean that a certain structure is integrally formed on other structures, or that a certain structure is "directly" arranged on other structures, or that a certain structure is "indirectly" arranged on another structure through another structure. other structures.
用语“一个”、“一”、“该”和“所述”用以表示存在一个或多个要素/组成部分/等; 用语“包括”和“具有”用以表示开放式的包括在内的意思并且是指除了列出的要素/组成部分/等之外还可存在另外的要素/组成部分/等。用语“第一”和“第二”仅作为标记使用,不是对其对象的数量限制。The terms "a", "an", "the" and "said" are used to indicate the presence of one or more elements/components/etc; the terms "including" and "having" are used to indicate open-ended inclusive means and means that additional elements/components/etc may be present in addition to the listed elements/components/etc. The terms "first" and "second" are used only as labels and are not intended to limit the number of their objects.
本公开实施方式提供了一种半导体器件,如图1所示,该半导体器件可以包括衬底1、电容阵列3及支撑结构4,其中:Embodiments of the present disclosure provide a semiconductor device. As shown in FIG. 1 , the semiconductor device may include a substrate 1 , a capacitor array 3 and a support structure 4 , wherein:
衬底1上形成有多个间隔排布的导电接触塞2;A plurality of conductive contact plugs 2 arranged at intervals are formed on the substrate 1;
电容阵列3包括多个间隔排布的柱状电容,各柱状电容分别形成在各导电接触塞2上,且柱状电容的下电极层33与导电接触塞2接触连接;The capacitor array 3 includes a plurality of column capacitors arranged at intervals, each column capacitor is formed on each conductive contact plug 2, and the lower electrode layer 33 of the column capacitor is in contact with the conductive contact plug 2;
支撑结构4形成于电容阵列3边缘的衬底1上,并环绕电容阵列3,且支撑结构4的内壁与外壁在平行于衬底1的任一横截面上的间距大于任一柱状电容的电容孔在横截面上的孔径。The support structure 4 is formed on the substrate 1 at the edge of the capacitor array 3 and surrounds the capacitor array 3, and the distance between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the capacitance of any column capacitor The diameter of the hole in the cross section.
本公开的半导体器件,由于支撑结构4环绕于电容阵列3外侧,可对电容阵列3外部进行横向支撑,增加电容阵列3在横向上的稳定性,防止电容阵列3中的电容产生横向形变,避免短路;同时,由于支撑结构4的内壁与外壁在平行于衬底1的任一横截面上的间距大于电容阵列3中任一电容孔在横截面上的孔径,可保证支撑结构4的支撑强度。此外,由于电容阵列3中包含多个电容,在使用时,多个电容可同时充放电,可提高电容量。In the semiconductor device of the present disclosure, since the support structure 4 surrounds the outside of the capacitor array 3, the outside of the capacitor array 3 can be laterally supported, thereby increasing the lateral stability of the capacitor array 3, preventing lateral deformation of the capacitors in the capacitor array 3, and avoiding At the same time, since the distance between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the aperture of any capacitor hole in the capacitor array 3 on the cross section, the support strength of the support structure 4 can be guaranteed. . In addition, since the capacitor array 3 includes a plurality of capacitors, in use, the plurality of capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
下面对本公开实施方式半导体器件的各部分进行详细说明:Each part of the semiconductor device according to the embodiment of the present disclosure will be described in detail below:
如图1所示,衬底1可呈平板结构,其可为矩形、圆形、椭圆形、多边形或不规则图形,其材料可以是硅或其他半导体材料,在此不对衬底1的形状及材料做特殊限定。As shown in FIG. 1 , the substrate 1 can have a flat plate structure, which can be rectangular, circular, elliptical, polygonal or irregular, and its material can be silicon or other semiconductor materials. Materials are subject to special restrictions.
可在衬底1上形成多个间隔排布的导电接触塞2,举例而言,可通过真空蒸镀、磁控溅射或化学气相沉积等方式在衬底1上形成导电接触塞2,当然,还可以通过其他方式形成导电接触塞2,在此不再一一列举。A plurality of conductive contact plugs 2 can be formed on the substrate 1 at intervals. For example, the conductive contact plugs 2 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition. Of course, the conductive contact plugs 2 can be formed on the substrate 1. , the conductive contact plugs 2 may also be formed in other ways, which will not be listed one by one here.
在一实施方式中,导电接触塞2可以包括第一导电接触塞21和第二导电接触塞22,第二导电接触塞22可为环形结构,其可以是圆形环,也可以是矩形环;第二导电接触塞22可由导体或半导体材料构成,举例而言,其材料可以是钨、铜或聚硅等。第一导电接触塞21可以有多个,多个第一导电接触塞21可位于第二导电接触塞22的环形内,并可呈阵列分布,且第一导电接触塞21的材料可与第二导电接触塞22的材料相同。In one embodiment, the conductive contact plug 2 may include a first conductive contact plug 21 and a second conductive contact plug 22, and the second conductive contact plug 22 may be an annular structure, which may be a circular ring or a rectangular ring; The second conductive contact plug 22 may be made of conductor or semiconductor material, for example, the material may be tungsten, copper or polysilicon. There can be a plurality of first conductive contact plugs 21 , the plurality of first conductive contact plugs 21 can be located in the annular shape of the second conductive contact plugs 22 , and can be distributed in an array, and the material of the first conductive contact plugs 21 can be the same as that of the second conductive contact plugs 21 . The material of the conductive contact plugs 22 is the same.
如图2所示,衬底1可包括并排设置的单元区域11和外围区域12,电容阵列3可形成于衬底1上,并可位于单元区域11上,电容阵列3可包括多个间隔排布的柱状电容,各柱状电容可分别形成在各导电接触塞2上,具体而言,各柱状电容可分别形成在各第一导电接触塞21上。在使用时,多个电容可同时充放电,从而提高电容量。As shown in FIG. 2, the substrate 1 may include a unit area 11 and a peripheral area 12 arranged side by side, a capacitor array 3 may be formed on the substrate 1 and may be located on the unit area 11, and the capacitor array 3 may include a plurality of spaced rows As for the cloth column capacitors, each column capacitor can be formed on each conductive contact plug 2 respectively, and specifically, each column capacitor can be formed on each first conductive contact plug 21 respectively. When in use, multiple capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
在本开的一种实施方式中,电容阵列3可以包括绝缘层31、绝缘介质层32、下电极层33、电容介质层34及上电极层35。绝缘层31分布于各第一导电接触塞21之间,可用于分隔各第一导电接触塞21;下电极层33可呈条状,其可形成于第一导电接触塞21背离衬底1的一侧,并可与第一导电接触塞21接触连接,且其可沿垂直于第一导电接触塞21接触的方向向第一导电接触塞21背离衬底1的一侧延伸,以便形成柱状电容。电容介质层34位于下电极层33和上电极层35之间可形成双面电容,以便于提高电容量。绝缘介质层32可包覆于下电极层33的外周,可对下电极层33进行横向支撑,增加下电极层33在横向上的稳定性,防止下电极层33产生横向形变。In an embodiment of the present disclosure, the capacitor array 3 may include an insulating layer 31 , an insulating medium layer 32 , a lower electrode layer 33 , a capacitor medium layer 34 and an upper electrode layer 35 . The insulating layer 31 is distributed between the first conductive contact plugs 21 and can be used to separate the first conductive contact plugs 21 ; the lower electrode layer 33 can be in the shape of a strip, which can be formed on the first conductive contact plug 21 away from the substrate 1 . one side, and can be in contact with the first conductive contact plug 21, and can extend to the side of the first conductive contact plug 21 away from the substrate 1 along the direction perpendicular to the contact direction of the first conductive contact plug 21, so as to form a columnar capacitor . The capacitor dielectric layer 34 is located between the lower electrode layer 33 and the upper electrode layer 35 to form a double-sided capacitor, so as to improve the capacitance. The insulating medium layer 32 can cover the outer periphery of the lower electrode layer 33 , can support the lower electrode layer 33 laterally, increase the stability of the lower electrode layer 33 in the lateral direction, and prevent the lower electrode layer 33 from being deformed laterally.
举例而言,绝缘层31可形成于衬底1上,可通过真空蒸镀、磁控溅射或化学气相沉积等方式在衬底1上形成绝缘层31,当然,还可以通过其他方式形成绝缘层31,在此不再一一列举。绝缘层31可与衬底1的形状相同,其材料可以是氮化硅、氧化硅等,在此不对其材料做特殊限定。For example, the insulating layer 31 can be formed on the substrate 1. The insulating layer 31 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition. Of course, the insulating layer 31 can also be formed by other methods. Layer 31 will not be listed one by one here. The shape of the insulating layer 31 may be the same as that of the substrate 1 , and the material thereof may be silicon nitride, silicon oxide, etc., and the material thereof is not limited herein.
绝缘层31上可设有环形孔以及位于环形孔内部的多个呈阵列分布的开口,环形孔和各开口均可为通孔,环形孔可为圆形环,也可为矩形环,各开口可呈圆形,也可呈矩形或不规则图形,在此不对环形孔和各开口的形状做特殊限定。The insulating layer 31 can be provided with an annular hole and a plurality of openings arranged in an array inside the annular hole. The annular hole and each opening can be a through hole, and the annular hole can be a circular ring or a rectangular ring. The shape of the annular hole and each opening is not particularly limited here.
可在环形孔内形成第二导电接触塞22,同时,可在各开口内形成第一导电接触塞21,可通过一次工艺同时形成第二导电接触塞22和多个第一导电接触塞21,举例而言,可通过化学气相沉积工艺同时形成第二导电接触塞22和多个第一导电接触塞21。在一实施方式中,第二导电接触塞22可通过环形孔与衬底1接触,同时,各第一导电接触塞21可通过各开口与衬底1相接触。The second conductive contact plugs 22 may be formed in the annular holes, and at the same time, the first conductive contact plugs 21 may be formed in each opening, and the second conductive contact plugs 22 and a plurality of first conductive contact plugs 21 may be formed simultaneously in one process, For example, the second conductive contact plugs 22 and the plurality of first conductive contact plugs 21 may be simultaneously formed through a chemical vapor deposition process. In one embodiment, the second conductive contact plugs 22 can be in contact with the substrate 1 through the annular hole, and at the same time, each of the first conductive contact plugs 21 can be in contact with the substrate 1 through each opening.
衬底1上至少形成有绝缘介质层32,例如,可在绝缘层31背离衬底1的一侧形成绝缘介质层32,该绝缘介质层32可同时覆盖于单元区域11和外围区域12。电容阵列3和支撑结构4均可形成于与单元区域11正对的绝缘介质层32中,即:绝缘介质层32可用于支撑电容。At least an insulating dielectric layer 32 is formed on the substrate 1 . For example, an insulating dielectric layer 32 can be formed on the side of the insulating layer 31 away from the substrate 1 , and the insulating dielectric layer 32 can cover both the cell region 11 and the peripheral region 12 . Both the capacitor array 3 and the supporting structure 4 can be formed in the insulating dielectric layer 32 opposite to the unit region 11 , that is, the insulating dielectric layer 32 can be used to support the capacitors.
如图2所示,绝缘介质层32可具有分别露出各第一导电接触塞21的多个通孔,通孔可为电容孔37,可用于形成电容,各电容孔37可在垂直于绝缘介质层32的方向上贯穿绝缘介质层32,其横截面的形状可以是圆形,矩形等,还可以是不规则形状,在此不对电容孔37的形状做特殊限定。通孔还可以包括环形圈41,可用于形成支撑结构4,其可以是圆形环,也可以是矩形环,在此不做特殊限定。As shown in FIG. 2 , the insulating dielectric layer 32 may have a plurality of through holes exposing the first conductive contact plugs 21 respectively. The through holes may be capacitor holes 37 , which may be used to form capacitors. Each capacitor hole 37 may be perpendicular to the insulating medium. The direction of the layer 32 runs through the insulating dielectric layer 32 , and the cross-sectional shape of the layer 32 may be a circle, a rectangle, etc., or an irregular shape, and the shape of the capacitor hole 37 is not particularly limited herein. The through hole can also include an annular ring 41, which can be used to form the support structure 4, which can be a circular ring or a rectangular ring, which is not limited herein.
举例而言,绝缘介质层32可包括沿垂直于衬底1的方向间隔排布的第一绝缘介质层322和第二绝缘介质层324,可通过真空蒸镀、磁控溅射或化学气相沉积等方式形成第一绝缘介质层322和第二绝缘介质层324,当然,还可通过其他工艺形成绝缘介质层32,在此不做特殊限定。For example, the insulating medium layer 32 may include a first insulating medium layer 322 and a second insulating medium layer 324 spaced along a direction perpendicular to the substrate 1, which may be deposited by vacuum evaporation, magnetron sputtering or chemical vapor deposition The first insulating dielectric layer 322 and the second insulating dielectric layer 324 can be formed in the same manner. Of course, the insulating dielectric layer 32 can also be formed by other processes, which are not limited herein.
电容阵列3和支撑结构4均可形成于第一绝缘介质层322和第二绝缘介质层324 中,可通过第一绝缘介质层322和第二绝缘介质层324对电容阵列3内部的各电容进行支撑,同时可通过支撑结构4对电容阵列3的边缘进行支撑。Both the capacitor array 3 and the support structure 4 can be formed in the first insulating dielectric layer 322 and the second insulating dielectric layer 324 , and the capacitors inside the capacitor array 3 can be adjusted through the first insulating dielectric layer 322 and the second insulating dielectric layer 324 . At the same time, the edge of the capacitor array 3 can be supported by the support structure 4 .
如图3所示,可在电容孔37内形成随形贴合于电容孔37底部及侧壁表面的下电极层33,且下电极层33可通过电容孔37与第一导电接触塞21接触连接,以将下电极层33存储的电量输入至第一导电接触塞21,从而实现电容存储。举例而言,可采用化学气相沉积工艺在电容孔37中形成下电极层33,当然,还可通过其他工艺形成下电极层33,在此不做特殊限定。下电极层33的材料可以是氮化钛,其厚度可以是4nm~10nm,举例而言,其可以是4nm、6nm、8nm或10nm,当然,下电极层33还可以是其他材料或其他厚度,在此不再一一列举。As shown in FIG. 3 , a lower electrode layer 33 can be formed in the capacitor hole 37 to conform to the bottom and the sidewall surface of the capacitor hole 37 , and the lower electrode layer 33 can be in contact with the first conductive contact plug 21 through the capacitor hole 37 connected to input the electricity stored in the lower electrode layer 33 to the first conductive contact plug 21 to realize capacitance storage. For example, the chemical vapor deposition process can be used to form the lower electrode layer 33 in the capacitor hole 37 , and of course, the lower electrode layer 33 can also be formed by other processes, which is not limited herein. The material of the lower electrode layer 33 may be titanium nitride, and its thickness may be 4 nm to 10 nm, for example, it may be 4 nm, 6 nm, 8 nm or 10 nm. Of course, the lower electrode layer 33 may also be made of other materials or other thicknesses. I will not list them one by one here.
如图1所示,电容介质层34可以是形成于下电极层33和绝缘介质层32共同构成的结构的外表面和内表面上的薄膜,可通过真空蒸镀或磁控溅射等工艺形成电容介质层34,当然,还可以通过其他工艺形成电容介质层34,在此不再一一列举。电容介质层34可以是由同一种材料构成的单层膜结构,也可以是由不同材质的膜层构成的混合膜层结构。举例而言,其可包括具有较高介电常数的材料,例如,其可以是氧化铝、氧化铪、氧化镧、氧化钛、氧化锆、氧化钽、氧化铌、氧化锶或其混合物,当然,还可以是其他材料,在此不再一一列举。As shown in FIG. 1 , the capacitor dielectric layer 34 may be a thin film formed on the outer surface and the inner surface of the structure composed of the lower electrode layer 33 and the insulating dielectric layer 32, and may be formed by vacuum evaporation or magnetron sputtering. Of course, the capacitive dielectric layer 34 can also be formed by other processes, which will not be listed here. The capacitor dielectric layer 34 may be a single-layer film structure composed of the same material, or may be a mixed film layer structure composed of film layers of different materials. For example, it may include a material with a higher dielectric constant, for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
可采用化学气相沉积工艺在电容介质层34的外表面形成上电极层35,当然,还可通过其他工艺形成上电极层35,在此不做特殊限定。上电极层35的材料可以是氮化钛,其厚度可以是2nm~8nm,举例而言,其可以是2nm、4nm、6nm或8nm,当然,上电极层35还可以是其他材料或其他厚度,在此不再一一列举。The upper electrode layer 35 may be formed on the outer surface of the capacitor dielectric layer 34 by a chemical vapor deposition process. Of course, the upper electrode layer 35 may also be formed by other processes, which are not limited herein. The material of the upper electrode layer 35 can be titanium nitride, and its thickness can be 2nm-8nm, for example, it can be 2nm, 4nm, 6nm or 8nm, of course, the upper electrode layer 35 can also be other materials or other thicknesses, I will not list them one by one here.
支撑结构4可形成于衬底1上,其可位于电容阵列3的边缘,并可环绕于电容阵列3的外周,举例而言,如图4所示,支撑结构4可形成于第二导电接触塞22背离衬底1的表面,其底部可与第二导电接触塞22接触。可通过真空蒸镀、磁控溅射或化学气相沉积等方式在第二导电接触塞22背离衬底1的表面形成支撑结构4。支撑结构4可与绝缘介质层32的材料相同,举例而言,其可以是氮化硅。The support structure 4 may be formed on the substrate 1, which may be located at the edge of the capacitor array 3, and may surround the periphery of the capacitor array 3. For example, as shown in FIG. 4, the support structure 4 may be formed on the second conductive contact The plug 22 faces away from the surface of the substrate 1 , the bottom of which can be in contact with the second conductive contact plug 22 . The support structure 4 may be formed on the surface of the second conductive contact plug 22 facing away from the substrate 1 by means of vacuum evaporation, magnetron sputtering or chemical vapor deposition. The support structure 4 may be of the same material as the insulating dielectric layer 32, for example, it may be silicon nitride.
支撑结构4可与电容阵列3接触连接,举例而言,其可与电容阵列3中的绝缘介质层32接触连接,以便对位于电容阵列3边缘部分的电容的四周均进行支撑,增加电容阵列3在横向上的稳定性,防止位于电容阵列3边缘部分的电容产生横向形变,避免短路。The support structure 4 can be in contact with the capacitor array 3, for example, it can be in contact with the insulating dielectric layer 32 in the capacitor array 3, so as to support the capacitors located at the edge of the capacitor array 3 all around, increasing the capacitor array 3 The stability in the lateral direction prevents the lateral deformation of the capacitors located at the edge of the capacitor array 3 and avoids short circuits.
支撑结构4的内壁与外壁在平行于衬底1的任一横截面上的间距大于电容阵列3中任一柱状电容的电容孔37在横截面上的孔径,可保证支撑结构4对位于电容阵列3边缘部分的电容的支撑强度。举例而言,支撑结构4的内壁与外壁在平行于衬底1的任一横截面上的间距可至少为电容阵列3中任一电容孔37在该横截面上的孔径的两倍。当然,支撑结构4的内壁与外壁之间的间距的最小值也可大于任一电容孔37的孔径的最大值。The spacing between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the aperture of the capacitor hole 37 of any column capacitor in the capacitor array 3 on the cross section, which can ensure that the support structure 4 is positioned opposite to the capacitor array. 3 The support strength of the capacitor at the edge part. For example, the distance between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 may be at least twice the diameter of any capacitor hole 37 in the capacitor array 3 on the cross section. Of course, the minimum value of the distance between the inner wall and the outer wall of the support structure 4 may also be greater than the maximum value of the diameter of any capacitor hole 37 .
同时,为了保证对电容顶部的支撑强度,支撑结构4的内壁与外壁之间的间距可由靠近衬底1一侧向远离衬底1的一侧依次增大,当然,在平行于衬底1的所有横截面上,其内壁与外壁之间的间距也均可相等,在此不对支撑结构4的内壁与外壁之间的尺寸做特殊限定。At the same time, in order to ensure the support strength for the top of the capacitor, the distance between the inner wall and the outer wall of the support structure 4 can be increased sequentially from the side close to the substrate 1 to the side away from the substrate 1 . In all cross sections, the distance between the inner wall and the outer wall can also be equal, and the size between the inner wall and the outer wall of the support structure 4 is not particularly limited here.
在一实施方式中,支撑结构4在第二导电接触塞22上的正投影可与第二导电接触塞22的边界重合,即:支撑结构4可为连续的整体,其可连续的包覆于电容阵列3外部,以便对电容阵列3边缘部分进行连续支撑。在另一实施方式中,支撑结构4可为非连续的片段,其可包括多个间隔分布的支撑区域及一一对应的形成于各支撑区域上的支撑柱,各支撑柱的厚度均可相等,并可围成环形,且各支撑柱可分别与电容阵列3的绝缘介质层32接触连接,以便对电容阵列3进行分段支撑。In one embodiment, the orthographic projection of the support structure 4 on the second conductive contact plug 22 can be coincident with the boundary of the second conductive contact plug 22, that is, the support structure 4 can be a continuous whole, which can be continuously wrapped around the second conductive contact plug 22. Outside the capacitor array 3, so as to continuously support the edge portion of the capacitor array 3. In another embodiment, the supporting structure 4 may be a discontinuous segment, which may include a plurality of supporting regions distributed at intervals and a one-to-one corresponding supporting column formed on each supporting region, and the thickness of each supporting column may be equal. , and can be encircled in a ring shape, and each support column can be respectively contacted and connected with the insulating medium layer 32 of the capacitor array 3 , so as to support the capacitor array 3 in sections.
支撑结构4在垂直于衬底1的方向上的厚度可与电容阵列3中的各电容在垂直于衬底1的方向上的高度相等,既可在横向上对电容阵列3进行支撑,又可在纵向上对电容阵列3进行支撑,提高器件稳定性。举例而言,支撑结构4在垂直于衬底1的方向上的厚度可与下电极层33在垂直于衬底1的方向上的高度相等,可通过支撑结构4对位于电容阵列3边缘的电容的下电极层33进行横向和纵向支撑,防止位于电容阵列3边缘的电容的下电极层33向外发生形变。The thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of each capacitor in the capacitor array 3 in the direction perpendicular to the substrate 1, which can support the capacitor array 3 in the lateral direction, and can also The capacitor array 3 is supported in the longitudinal direction to improve the stability of the device. For example, the thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of the lower electrode layer 33 in the direction perpendicular to the substrate 1, and the capacitors located at the edge of the capacitor array 3 can be adjusted by the support structure 4. The lower electrode layer 33 of the capacitor array 3 is supported laterally and vertically to prevent the lower electrode layer 33 of the capacitor located at the edge of the capacitor array 3 from deforming outward.
在一实施方式中,如图1、图5及图6所示,本公开的半导体器件还可包括半导体层5,半导体层5可覆盖于电容阵列3的表面,且可充满电容孔37及电容阵列3中相邻两个电容之间的间隙,In one embodiment, as shown in FIG. 1 , FIG. 5 and FIG. 6 , the semiconductor device of the present disclosure may further include a semiconductor layer 5 , which may cover the surface of the capacitor array 3 and may be filled with capacitor holes 37 and capacitors. The gap between two adjacent capacitors in array 3,
可通过真空蒸镀工艺在上电极层35的表面形成覆盖电容阵列3的半导体层5,以使电荷与第二电极充分接触,有助于提高电容充电效率。如图5所示,该半导体层5可覆盖于电容阵列3的表面,且可充满电容孔37及电容阵列3中相邻两个电容之间的间隙,可提高器件的导电性能,加强电容阵列3中各电容的稳定性。半导体层5可由硅材料、金属材料或金属化合物构成,举例而言,其可以是硅、锗硅、钨、硅化钛、氧化钛或氧化钨等,在此不做特殊限定。The semiconductor layer 5 covering the capacitor array 3 can be formed on the surface of the upper electrode layer 35 by a vacuum evaporation process, so that the electric charges can be fully contacted with the second electrode, which helps to improve the charging efficiency of the capacitor. As shown in FIG. 5, the semiconductor layer 5 can cover the surface of the capacitor array 3, and can fill the capacitor hole 37 and the gap between two adjacent capacitors in the capacitor array 3, which can improve the electrical conductivity of the device and strengthen the capacitor array. The stability of each capacitor in 3. The semiconductor layer 5 may be composed of silicon material, metal material or metal compound, for example, it may be silicon, silicon germanium, tungsten, titanium silicide, titanium oxide or tungsten oxide, etc., which is not limited herein.
在一实施方式中,导电接触塞2还可以包括外围导电接触塞23,该外围导电接触塞23可形成于衬底1的外围区域12中,本公开的半导体器件还可以包括互连结构,该互连结构可形成于外围区域12对应的绝缘介质层32中,并可与外围导电接触塞23接触连接,以便将电容阵列3电学引出。外围导电接触塞23可与第一导电接触塞21以及第二导电接触塞22的材料相同,厚度相等,可在形成第一导电接触塞21以及第二导电接触塞22的同时形成外围导电接触塞23。In one embodiment, the conductive contact plugs 2 may further include peripheral conductive contact plugs 23, which may be formed in the peripheral region 12 of the substrate 1, and the semiconductor device of the present disclosure may further include an interconnect structure that The interconnection structure can be formed in the insulating medium layer 32 corresponding to the peripheral region 12 , and can be in contact with the peripheral conductive contact plug 23 so as to electrically lead out the capacitor array 3 . The peripheral conductive contact plugs 23 can be made of the same material as the first conductive contact plugs 21 and the second conductive contact plugs 22 and have the same thickness, and the peripheral conductive contact plugs can be formed at the same time as the first conductive contact plugs 21 and the second conductive contact plugs 22 are formed twenty three.
如图7-图8所示,可通过化学气相沉积工艺在第一过孔61内形成第一互连结构6,该第一互连结构6可通过第一过孔61与半导体层5连通,以便将电容阵列3电学引出。As shown in FIGS. 7-8 , the first interconnect structure 6 can be formed in the first via hole 61 by a chemical vapor deposition process, and the first interconnect structure 6 can be communicated with the semiconductor layer 5 through the first via hole 61 , In order to lead out the capacitor array 3 electrically.
第一互连结构6可以包括连接层62和引出层63,连接层62可随型贴附于第一 过孔61的孔壁和底面,并可与半导体层5的顶部连通,引出层63可位于连接层62上,且可填满第一过孔61。连接层62和引出层63的材料均可为导电材料,例如,连接层62的材料可为氮化钛,引出层63的材料可为钨。The first interconnection structure 6 may include a connection layer 62 and an extraction layer 63. The connection layer 62 may be attached to the hole wall and bottom surface of the first via hole 61, and may communicate with the top of the semiconductor layer 5. The extraction layer 63 may be connected to the top of the semiconductor layer 5. It is located on the connection layer 62 and can fill the first via hole 61 . Both the connection layer 62 and the extraction layer 63 can be made of conductive materials, for example, the connection layer 62 can be made of titanium nitride, and the extraction layer 63 can be made of tungsten.
本公开实施方式还提供一种半导体器件的形成方法,如图9所示,该形成方法可以包括:Embodiments of the present disclosure also provide a method for forming a semiconductor device. As shown in FIG. 9 , the forming method may include:
步骤S110,提供衬底;Step S110, providing a substrate;
步骤S120,在所述衬底上形成多个间隔排布的导电接触塞;Step S120, forming a plurality of conductive contact plugs arranged at intervals on the substrate;
步骤S130,形成电容阵列,所述电容阵列包括多个间隔排布的柱状电容,各所述柱状电容分别形成在各所述导电接触塞上,且所述柱状电容的下电极层与所述导电接触塞接触连接;Step S130, forming a capacitor array, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is connected to the conductive contact plug. contact plug contact connection;
步骤S140,形成支撑结构,所述支撑结构形成于所述电容阵列边缘的所述衬底上,并环绕所述电容阵列,且所述支撑结构的内壁与外壁在平行于所述衬底的任一横截面上的间距大于任一所述柱状电容的电容孔在所述横截面上的孔径。Step S140, forming a support structure, the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are in any position parallel to the substrate. The spacing on a cross section is larger than the diameter of the capacitor hole of any one of the column capacitors on the cross section.
本公开的半导体器件的形成方法,由于支撑结构4环绕于电容阵列3外侧,可对电容阵列3外部进行横向支撑,增加电容阵列3在横向上的稳定性,防止电容阵列3中的电容产生横向形变,避免短路;同时,由于支撑结构4的内壁与外壁在平行于衬底1的任一横截面上的间距大于电容阵列3中任一电容孔37在横截面上的孔径,可保证支撑结构4的支撑强度。此外,由于电容阵列3中包含多个电容,在使用时,多个电容可同时充放电,可提高电容量。In the method for forming a semiconductor device of the present disclosure, since the support structure 4 surrounds the outside of the capacitor array 3, the outside of the capacitor array 3 can be laterally supported, thereby increasing the lateral stability of the capacitor array 3 and preventing the capacitors in the capacitor array 3 from generating lateral deformation to avoid short circuit; at the same time, since the spacing between the inner wall and the outer wall of the support structure 4 on any cross-section parallel to the substrate 1 is greater than the aperture of any capacitor hole 37 in the capacitor array 3 on the cross-section, the support structure can be guaranteed. 4. Support strength. In addition, since the capacitor array 3 includes a plurality of capacitors, in use, the plurality of capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
下面对本公开实施方式形成方法的各步骤进行详细说明:Each step of the method for forming the embodiment of the present disclosure will be described in detail below:
在步骤S110中,提供衬底。In step S110, a substrate is provided.
衬底1可呈平板结构,其可为矩形、圆形、椭圆形、多边形或不规则图形,其材料可以是硅或其他半导体材料,在此不对衬底1的形状及材料做特殊限定。The substrate 1 may have a flat plate structure, which may be rectangular, circular, elliptical, polygonal or irregular, and its material may be silicon or other semiconductor materials. The shape and material of the substrate 1 are not particularly limited herein.
在步骤S120中,在所述衬底上形成多个间隔排布的导电接触塞。In step S120, a plurality of spaced conductive contact plugs are formed on the substrate.
可在衬底1上形成多个间隔排布的导电接触塞2,举例而言,可通过真空蒸镀、磁控溅射或化学气相沉积等方式在衬底1上形成导电接触塞2,当然,还可以通过其他方式形成导电接触塞2,在此不再一一列举。A plurality of conductive contact plugs 2 can be formed on the substrate 1 at intervals. For example, the conductive contact plugs 2 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition. Of course, the conductive contact plugs 2 can be formed on the substrate 1. , the conductive contact plugs 2 may also be formed in other ways, which will not be listed one by one here.
在一实施方式中,导电接触塞2可以包括第一导电接触塞21和第二导电接触塞22,第二导电接触塞22可为环形结构,其可以是圆形环,也可以是矩形环;第二导电接触塞22可由导体或半导体材料构成,举例而言,其材料可以是钨、铜或聚硅等。第一导电接触塞21可以有多个,多个第一导电接触塞21可位于第二导电接触塞22的环形内,并可呈阵列分布,且第一导电接触塞21的材料可与第二导电接触塞22的材料相同。衬底1可包括并排设置的单元区域11和外围区域12,第一导电接触塞21和第二导电接触塞22形成于单元区域11内。In one embodiment, the conductive contact plug 2 may include a first conductive contact plug 21 and a second conductive contact plug 22, and the second conductive contact plug 22 may be an annular structure, which may be a circular ring or a rectangular ring; The second conductive contact plug 22 may be made of conductor or semiconductor material, for example, the material may be tungsten, copper or polysilicon. There can be a plurality of first conductive contact plugs 21 , the plurality of first conductive contact plugs 21 can be located in the annular shape of the second conductive contact plugs 22 , and can be distributed in an array, and the material of the first conductive contact plugs 21 can be the same as that of the second conductive contact plugs 21 . The material of the conductive contact plugs 22 is the same. The substrate 1 may include a cell region 11 and a peripheral region 12 arranged side by side, and the first conductive contact plugs 21 and the second conductive contact plugs 22 are formed in the cell region 11 .
在步骤S130中,形成电容阵列,所述电容阵列包括多个间隔排布的柱状电容, 各所述柱状电容分别形成在各所述导电接触塞上,且所述柱状电容的下电极层与所述导电接触塞接触连接。In step S130, a capacitor array is formed, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is respectively formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is connected to all the column capacitors. The conductive contact plugs make contact connections.
电容阵列3可形成于衬底1上,并可位于单元区域11上,电容阵列3可包括多个间隔排布的柱状电容,各柱状电容可分别形成在各导电接触塞上,具体而言,各柱状电容可分别形成在各第一导电接触塞21上。在使用时,多个电容可同时充放电,从而提高电容量。The capacitor array 3 can be formed on the substrate 1 and can be located on the unit area 11. The capacitor array 3 can include a plurality of column capacitors arranged at intervals, and each column capacitor can be formed on each conductive contact plug. Specifically, Each column capacitor may be formed on each first conductive contact plug 21 , respectively. When in use, multiple capacitors can be charged and discharged at the same time, thereby increasing the capacitance.
在本开的一种实施方式中,电容阵列3可以包括绝缘层31、绝缘介质层32、下电极层33、电容介质层34及上电极层35。绝缘层31分布于各第一导电接触塞21之间,可用于分隔各第一导电接触塞21;下电极层33可呈条状,其可形成于第一导电接触塞21背离衬底1的一侧,并可与第一导电接触塞21接触连接,且其可沿垂直于第一导电接触塞21接触的方向向第一导电接触塞21背离衬底1的一侧延伸,以便形成柱状电容。电容介质层34位于下电极层33和上电极层35之间可形成双面电容,以便于提高电容量。绝缘介质层32可包覆于下电极层33的外周,可对下电极层33进行横向支撑,增加下电极层33在横向上的稳定性,防止下电极层33产生横向形变。In an embodiment of the present disclosure, the capacitor array 3 may include an insulating layer 31 , an insulating medium layer 32 , a lower electrode layer 33 , a capacitor medium layer 34 and an upper electrode layer 35 . The insulating layer 31 is distributed between the first conductive contact plugs 21 and can be used to separate the first conductive contact plugs 21 ; the lower electrode layer 33 can be in the shape of a strip, which can be formed on the first conductive contact plug 21 away from the substrate 1 . one side, and can be in contact with the first conductive contact plug 21, and can extend to the side of the first conductive contact plug 21 away from the substrate 1 along the direction perpendicular to the contact direction of the first conductive contact plug 21, so as to form a columnar capacitor . The capacitor dielectric layer 34 is located between the lower electrode layer 33 and the upper electrode layer 35 to form a double-sided capacitor, so as to improve the capacitance. The insulating medium layer 32 can cover the outer periphery of the lower electrode layer 33 , can support the lower electrode layer 33 laterally, increase the stability of the lower electrode layer 33 in the lateral direction, and prevent the lower electrode layer 33 from being deformed laterally.
举例而言,绝缘层31可形成于衬底1上,可通过真空蒸镀、磁控溅射或化学气相沉积等方式在衬底1上形成绝缘层31,当然,还可以通过其他方式形成绝缘层31,在此不再一一列举。绝缘层31可与衬底1的形状相同,其材料可以是氮化硅、氧化硅等,在此不对其材料做特殊限定。For example, the insulating layer 31 can be formed on the substrate 1. The insulating layer 31 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition. Of course, the insulating layer 31 can also be formed by other methods. Layer 31 will not be listed one by one here. The shape of the insulating layer 31 may be the same as that of the substrate 1 , and the material thereof may be silicon nitride, silicon oxide, etc., and the material thereof is not limited herein.
绝缘层31上可设有环形孔以及位于环形孔内部的多个呈阵列分布的开口,环形孔和各开口均可为通孔,环形孔可为圆形环,也可为矩形环,各开口可呈圆形,也可呈矩形或不规则图形,在此不对环形孔和各开口的形状做特殊限定。The insulating layer 31 can be provided with an annular hole and a plurality of openings arranged in an array inside the annular hole. The annular hole and each opening can be a through hole, and the annular hole can be a circular ring or a rectangular ring. The shape of the annular hole and each opening is not particularly limited here.
可在环形孔内形成第二导电接触塞22,同时,可在各开口内形成第一导电接触塞21,可通过一次工艺同时形成第二导电接触塞22和多个第一导电接触塞21,举例而言,可通过化学气相沉积工艺同时形成第二导电接触塞22和多个第一导电接触塞21。在一实施方式中,第二导电接触塞22可通过环形孔与衬底1接触,同时,各第一导电接触塞21可通过各开口与衬底1相接触。The second conductive contact plugs 22 may be formed in the annular holes, and at the same time, the first conductive contact plugs 21 may be formed in each opening, and the second conductive contact plugs 22 and a plurality of first conductive contact plugs 21 may be formed simultaneously in one process, For example, the second conductive contact plugs 22 and the plurality of first conductive contact plugs 21 may be simultaneously formed through a chemical vapor deposition process. In one embodiment, the second conductive contact plugs 22 can be in contact with the substrate 1 through the annular hole, and at the same time, each of the first conductive contact plugs 21 can be in contact with the substrate 1 through each opening.
衬底1上至少形成有绝缘介质层32,例如,可在绝缘层31背离衬底1的一侧形成绝缘介质层32,该绝缘介质层32可同时覆盖于单元区域11和外围区域12。电容阵列3和支撑结构4均可形成于与单元区域11正对的绝缘介质层32中,即:绝缘介质层32可用于支撑电容。At least an insulating dielectric layer 32 is formed on the substrate 1 . For example, an insulating dielectric layer 32 can be formed on the side of the insulating layer 31 away from the substrate 1 , and the insulating dielectric layer 32 can cover both the cell region 11 and the peripheral region 12 . Both the capacitor array 3 and the supporting structure 4 can be formed in the insulating dielectric layer 32 opposite to the unit region 11 , that is, the insulating dielectric layer 32 can be used to support the capacitors.
如图2所示,绝缘介质层32可具有分别露出各第一导电接触塞21的多个通孔,通孔可为电容孔37,可用于形成电容,各电容孔37可在垂直于绝缘介质层32的方向上贯穿绝缘介质层32,其横截面的形状可以是圆形,矩形等,还可以是不规则形状,在此不对电容孔37的形状做特殊限定。通孔还可以包括环形圈41,可用于形 成支撑结构4,其可以是圆形环,也可以是矩形环,在此不做特殊限定。As shown in FIG. 2 , the insulating dielectric layer 32 may have a plurality of through holes exposing the first conductive contact plugs 21 respectively. The through holes may be capacitor holes 37 , which may be used to form capacitors. Each capacitor hole 37 may be perpendicular to the insulating medium. The direction of the layer 32 runs through the insulating dielectric layer 32 , and the cross-sectional shape of the layer 32 may be a circle, a rectangle, etc., or an irregular shape, and the shape of the capacitor hole 37 is not particularly limited herein. The through hole can also include an annular ring 41, which can be used to form the support structure 4, which can be a circular ring or a rectangular ring, which is not limited herein.
举例而言,绝缘介质层32可包括沿垂直于衬底1的方向间隔排布的第一绝缘介质层322和第二绝缘介质层324,可通过真空蒸镀、磁控溅射或化学气相沉积等方式形成第一绝缘介质层322和第二绝缘介质层324,当然,还可通过其他工艺形成绝缘介质层32,在此不做特殊限定。For example, the insulating medium layer 32 may include a first insulating medium layer 322 and a second insulating medium layer 324 spaced along a direction perpendicular to the substrate 1, which may be deposited by vacuum evaporation, magnetron sputtering or chemical vapor deposition The first insulating dielectric layer 322 and the second insulating dielectric layer 324 can be formed in the same manner. Of course, the insulating dielectric layer 32 can also be formed by other processes, which are not limited herein.
电容阵列3和支撑结构4均可形成于第一绝缘介质层322和第二绝缘介质层324中,可通过第一绝缘介质层322和第二绝缘介质层324对电容阵列3内部的各电容进行支撑,同时可通过支撑结构4对电容阵列3的边缘进行支撑。Both the capacitor array 3 and the support structure 4 can be formed in the first insulating dielectric layer 322 and the second insulating dielectric layer 324 , and the capacitors inside the capacitor array 3 can be processed through the first insulating dielectric layer 322 and the second insulating dielectric layer 324 . At the same time, the edge of the capacitor array 3 can be supported by the support structure 4 .
如图3所示,可在电容孔37内形成随形贴合于电容孔37底部及侧壁表面的下电极层33,且下电极层33可通过电容孔37与第一导电接触塞21接触连接,以将下电极层33存储的电量输入至第一导电接触塞21,从而实现电容存储。举例而言,可采用化学气相沉积工艺在电容孔37中形成下电极层33,当然,还可通过其他工艺形成下电极层33,在此不做特殊限定。下电极层33的材料可以是氮化钛,其厚度可以是4nm~10nm,举例而言,其可以是4nm、6nm、8nm或10nm,当然,下电极层33还可以是其他材料或其他厚度,在此不再一一列举。As shown in FIG. 3 , a lower electrode layer 33 can be formed in the capacitor hole 37 to conform to the bottom and the sidewall surface of the capacitor hole 37 , and the lower electrode layer 33 can be in contact with the first conductive contact plug 21 through the capacitor hole 37 connected to input the electricity stored in the lower electrode layer 33 to the first conductive contact plug 21 to realize capacitance storage. For example, the chemical vapor deposition process can be used to form the lower electrode layer 33 in the capacitor hole 37 , and of course, the lower electrode layer 33 can also be formed by other processes, which is not limited herein. The material of the lower electrode layer 33 may be titanium nitride, and its thickness may be 4 nm to 10 nm, for example, it may be 4 nm, 6 nm, 8 nm or 10 nm. Of course, the lower electrode layer 33 may also be made of other materials or other thicknesses. I will not list them one by one here.
如图1所示,电容介质层34可以是形成于下电极层33和绝缘介质层32共同构成的结构的外表面和内表面上的薄膜,可通过真空蒸镀或磁控溅射等工艺形成电容介质层34,当然,还可以通过其他工艺形成电容介质层34,在此不再一一列举。电容介质层34可以是由同一种材料构成的单层膜结构,也可以是由不同材质的膜层构成的混合膜层结构。举例而言,其可包括具有较高介电常数的材料,例如,其可以是氧化铝、氧化铪、氧化镧、氧化钛、氧化锆、氧化钽、氧化铌、氧化锶或其混合物,当然,还可以是其他材料,在此不再一一列举。As shown in FIG. 1 , the capacitor dielectric layer 34 may be a thin film formed on the outer surface and the inner surface of the structure composed of the lower electrode layer 33 and the insulating dielectric layer 32, and may be formed by vacuum evaporation or magnetron sputtering. Of course, the capacitive dielectric layer 34 can also be formed by other processes, which will not be listed here. The capacitor dielectric layer 34 may be a single-layer film structure composed of the same material, or may be a mixed film layer structure composed of film layers of different materials. For example, it may include a material with a higher dielectric constant, for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
可采用化学气相沉积工艺在电容介质层34的外表面形成上电极层35,当然,还可通过其他工艺形成上电极层35,在此不做特殊限定。上电极层35的材料可以是氮化钛,其厚度可以是2nm~8nm,举例而言,其可以是2nm、4nm、6nm或8nm,当然,上电极层35还可以是其他材料或其他厚度,在此不再一一列举。The upper electrode layer 35 may be formed on the outer surface of the capacitor dielectric layer 34 by a chemical vapor deposition process. Of course, the upper electrode layer 35 may also be formed by other processes, which are not limited herein. The material of the upper electrode layer 35 can be titanium nitride, and its thickness can be 2nm-8nm, for example, it can be 2nm, 4nm, 6nm or 8nm, of course, the upper electrode layer 35 can also be other materials or other thicknesses, I will not list them one by one here.
在步骤S140中,形成支撑结构,所述支撑结构形成于所述电容阵列边缘的所述衬底上,并环绕所述电容阵列,且所述支撑结构的内壁与外壁在平行于所述衬底的任一横截面上的间距大于任一所述柱状电容的电容孔在所述横截面上的孔径。In step S140, a support structure is formed, the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are parallel to the substrate The spacing on any cross-section is greater than the diameter of the capacitor hole of any of the column capacitors on the cross-section.
支撑结构4可形成于衬底1上,其可位于电容阵列3的边缘,并可环绕于电容阵列3的外周,举例而言,如图4所示,支撑结构4可形成于第二导电接触塞22背离衬底1的表面,其底部可与第二导电接触塞22接触。可通过真空蒸镀、磁控溅射或化学气相沉积等方式在第二导电接触塞22背离衬底1的表面形成支撑结构4。支撑结构4可与绝缘介质层32的材料相同,举例而言,其可以是氮化硅。The support structure 4 may be formed on the substrate 1, which may be located at the edge of the capacitor array 3, and may surround the periphery of the capacitor array 3. For example, as shown in FIG. 4, the support structure 4 may be formed on the second conductive contact The plug 22 faces away from the surface of the substrate 1 , the bottom of which can be in contact with the second conductive contact plug 22 . The support structure 4 may be formed on the surface of the second conductive contact plug 22 facing away from the substrate 1 by means of vacuum evaporation, magnetron sputtering or chemical vapor deposition. The support structure 4 may be of the same material as the insulating dielectric layer 32, for example, it may be silicon nitride.
支撑结构4可与电容阵列3接触连接,举例而言,其可与电容阵列3中的绝缘 介质层32接触连接,以便对位于电容阵列3边缘部分的电容的四周均进行支撑,增加电容阵列3在横向上的稳定性,防止位于电容阵列3边缘部分的电容产生横向形变,避免短路。The support structure 4 can be in contact with the capacitor array 3, for example, it can be in contact with the insulating dielectric layer 32 in the capacitor array 3, so as to support the capacitors located at the edge of the capacitor array 3 all around, increasing the capacitor array 3 The stability in the lateral direction prevents the lateral deformation of the capacitors located at the edge of the capacitor array 3 and avoids short circuits.
支撑结构4的内壁与外壁在平行于衬底1的任一横截面上的间距大于电容阵列3中任一柱状电容的电容孔37在横截面上的孔径,可保证支撑结构4对位于电容阵列3边缘部分的电容的支撑强度。举例而言,支撑结构4的内壁与外壁在平行于衬底1的任一横截面上的间距可至少为电容阵列3中任一电容孔37在该横截面上的孔径的两倍。当然,支撑结构4的内壁与外壁之间的间距的最小值也可大于任一电容孔37的孔径的最大值。The spacing between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 is greater than the aperture of the capacitor hole 37 of any column capacitor in the capacitor array 3 on the cross section, which can ensure that the support structure 4 is positioned opposite to the capacitor array. 3 The support strength of the capacitor at the edge part. For example, the distance between the inner wall and the outer wall of the support structure 4 on any cross section parallel to the substrate 1 may be at least twice the diameter of any capacitor hole 37 in the capacitor array 3 on the cross section. Of course, the minimum value of the distance between the inner wall and the outer wall of the support structure 4 may also be greater than the maximum value of the diameter of any capacitor hole 37 .
同时,为了保证对电容顶部的支撑强度,支撑结构4的内壁与外壁之间的间距可由靠近衬底1一侧向远离衬底1的一侧依次增大,当然,在平行于衬底1的所有横截面上,其内壁与外壁之间的间距也均可相等,在此不对支撑结构4的内壁与外壁之间的尺寸做特殊限定。At the same time, in order to ensure the support strength for the top of the capacitor, the distance between the inner wall and the outer wall of the support structure 4 can be increased sequentially from the side close to the substrate 1 to the side away from the substrate 1 . In all cross sections, the distance between the inner wall and the outer wall can also be equal, and the size between the inner wall and the outer wall of the support structure 4 is not particularly limited here.
在一实施方式中,支撑结构4在第二导电接触塞22上的正投影可与第二导电接触塞22的边界重合,即:支撑结构4可为连续的整体,其可连续的包覆于电容阵列3外部,以便对电容阵列3边缘部分进行连续支撑。在另一实施方式中,支撑结构4可为非连续的片段,其可包括多个间隔分布的支撑区域及一一对应的形成于各支撑区域上的支撑柱,各支撑柱的厚度均可相等,并可围成环形,且各支撑柱可分别与电容阵列3的绝缘介质层32接触连接,以便对电容阵列3进行分段支撑。In one embodiment, the orthographic projection of the support structure 4 on the second conductive contact plug 22 can be coincident with the boundary of the second conductive contact plug 22, that is, the support structure 4 can be a continuous whole, which can be continuously wrapped around the second conductive contact plug 22. Outside the capacitor array 3, so as to continuously support the edge portion of the capacitor array 3. In another embodiment, the supporting structure 4 may be a discontinuous segment, which may include a plurality of supporting regions distributed at intervals and a one-to-one corresponding supporting column formed on each supporting region, and the thickness of each supporting column may be equal. , and can be encircled in a ring shape, and each support column can be respectively contacted and connected with the insulating medium layer 32 of the capacitor array 3 , so as to support the capacitor array 3 in sections.
支撑结构4在垂直于衬底1的方向上的厚度可与电容阵列3中的各电容在垂直于衬底1的方向上的高度相等,既可在横向上对电容阵列3进行支撑,又可在纵向上对电容阵列3进行支撑,提高器件稳定性。举例而言,支撑结构4在垂直于衬底1的方向上的厚度可与下电极层33在垂直于衬底1的方向上的高度相等,可通过支撑结构4对位于电容阵列3边缘的电容的下电极层33进行横向和纵向支撑,防止位于电容阵列3边缘的电容的下电极层33向外发生形变。The thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of each capacitor in the capacitor array 3 in the direction perpendicular to the substrate 1, which can support the capacitor array 3 in the lateral direction, and can also The capacitor array 3 is supported in the longitudinal direction to improve the stability of the device. For example, the thickness of the support structure 4 in the direction perpendicular to the substrate 1 can be equal to the height of the lower electrode layer 33 in the direction perpendicular to the substrate 1, and the capacitors located at the edge of the capacitor array 3 can be adjusted by the support structure 4. The lower electrode layer 33 of the capacitor array 3 is supported laterally and vertically to prevent the lower electrode layer 33 of the capacitor located at the edge of the capacitor array 3 from deforming outward.
在一实施方式中,在衬底1上形成电容阵列3及支撑结构4可以包括步骤S210-步骤S250,如图10所示,其中:In one embodiment, forming the capacitor array 3 and the supporting structure 4 on the substrate 1 may include steps S210 to S250, as shown in FIG. 10 , wherein:
步骤S210,在所述衬底上依次形成牺牲层和绝缘介质层,以所述导电接触塞为蚀刻停止层,蚀刻所述单元区域的所述牺牲层和所述绝缘介质层,在所述单元区域形成多个间隔排布的柱状空隙结构,并控制蚀刻窗口,使得位于所述单元区域外围的柱状空隙结构在平行于所述衬底方向上的横截面间距大于所述单元区域中非外围的柱状空隙结构的横截面间距。Step S210, forming a sacrificial layer and an insulating dielectric layer on the substrate in sequence, using the conductive contact plug as an etch stop layer, etching the sacrificial layer and the insulating dielectric layer in the unit area, and etching the sacrificial layer and the insulating dielectric layer in the unit area. The area forms a plurality of columnar void structures arranged at intervals, and the etching window is controlled so that the cross-sectional spacing of the columnar void structures located at the periphery of the unit area in the direction parallel to the substrate is greater than that of the non-periphery in the unit area. The cross-sectional spacing of the columnar void structures.
可通过真空蒸镀、磁控溅射或化学气相沉积等方式在衬底1上形成绝缘层31,当然,还可以通过其他方式形成绝缘层31,在此不再一一列举。绝缘层31可与衬底1的形状相同,其材料可以是氮化硅、氧化硅等,在此不对其材料做特殊限定。The insulating layer 31 can be formed on the substrate 1 by vacuum evaporation, magnetron sputtering or chemical vapor deposition, etc. Of course, the insulating layer 31 can also be formed by other methods, which will not be listed here. The shape of the insulating layer 31 may be the same as that of the substrate 1 , and the material thereof may be silicon nitride, silicon oxide, etc., and the material thereof is not limited herein.
可通过光刻工艺将掩膜版中的图案转移至绝缘层31上,掩膜版可为网格状,其上的图案可与环形孔及各开口所需的图案相同,以便在绝缘层31上形成环形孔以及位于环形孔内部的多个呈阵列分布的开口,环形孔和各开口均可为通孔,环形孔可为圆形环,也可为矩形环,各开口可呈圆形,也可呈矩形或不规则图形,在此不对环形孔和各开口的形状做特殊限定。The pattern in the mask can be transferred to the insulating layer 31 by a photolithography process. The mask can be grid-shaped, and the pattern on it can be the same as the pattern required for the annular hole and each opening, so that the insulating layer 31 can be formed. An annular hole and a plurality of openings arranged in an array are formed inside the annular hole, the annular hole and each opening can be a through hole, the annular hole can be a circular ring or a rectangular ring, and each opening can be circular, It can also be rectangular or irregular, and the shape of the annular hole and each opening is not limited here.
可通过化学气相沉积或物理气相沉积的方式在各第一导电接触塞21、第二导电接触塞22及衬底1共同构成的结构的表面依次形成交叠设置的牺牲层和绝缘介质层32。如图11所示,其可以包括依次叠层设置的第一牺牲层321、第一绝缘介质层322、第二牺牲层323和第二绝缘介质层324,可通过真空蒸镀或磁控溅射等方式形成第一牺牲层321、第一绝缘介质层322、第二牺牲层323和第二绝缘介质层324,当然,也可通过其他方式形成叠层设置的第一牺牲层321、第一绝缘介质层322、第二牺牲层323和第二绝缘介质层324,在此不做特殊限定。An overlapping sacrificial layer and an insulating dielectric layer 32 may be sequentially formed on the surface of the structure formed by each of the first conductive contact plugs 21 , the second conductive contact plugs 22 and the substrate 1 by chemical vapor deposition or physical vapor deposition. As shown in FIG. 11 , it may include a first sacrificial layer 321 , a first insulating dielectric layer 322 , a second sacrificial layer 323 and a second insulating dielectric layer 324 , which are stacked in sequence, which can be formed by vacuum evaporation or magnetron sputtering. The first sacrificial layer 321, the first insulating dielectric layer 322, the second sacrificial layer 323, and the second insulating dielectric layer 324 are formed in other ways. The dielectric layer 322 , the second sacrificial layer 323 and the second insulating dielectric layer 324 are not particularly limited herein.
第一牺牲层321可形成于各第一导电接触塞21、第二导电接触塞22及衬底1共同构成的结构的表面,其材料可以是SiO2;第一绝缘介质层322可以是形成于第一牺牲层321背离衬底1的一侧的薄膜,其材料可以是氮化硅或SiCN;第二牺牲层323可形成于第一绝缘介质层322背离第一牺牲层321的一侧,并可与第一牺牲层321的材料相同,厚度相等,可采用化学抛光工艺对第一牺牲层321和第二牺牲层323的顶表面进行抛光处理,以使第一牺牲层321和第二牺牲层323各部分的厚度均匀一致;第二绝缘介质层324可形成于第二牺牲层323层背离第一绝缘介质层322的一侧,其可与第一绝缘介质层322的材料相同,需要说明的是,各绝缘介质层32的厚度可以相同,也可以不同,在此不做特殊限定。The first sacrificial layer 321 can be formed on the surface of the structure formed by the first conductive contact plugs 21, the second conductive contact plugs 22 and the substrate 1, and its material can be SiO2; the first insulating dielectric layer 322 can be formed on the surface of the structure. A thin film on the side of the sacrificial layer 321 away from the substrate 1 can be made of silicon nitride or SiCN; the second sacrificial layer 323 can be formed on the side of the first insulating dielectric layer 322 away from the first sacrificial layer 321, and can be The material and thickness of the first sacrificial layer 321 are the same, and the top surfaces of the first sacrificial layer 321 and the second sacrificial layer 323 may be polished by a chemical polishing process, so that the first sacrificial layer 321 and the second sacrificial layer 323 The thickness of each part is uniform; the second insulating dielectric layer 324 can be formed on the side of the second sacrificial layer 323 away from the first insulating dielectric layer 322, and can be made of the same material as the first insulating dielectric layer 322. It should be noted that , the thickness of each insulating dielectric layer 32 may be the same or different, which is not particularly limited here.
可通过旋涂或其他方式在第二绝缘介质层324上形成光刻胶层3341,光刻胶层3341的材料可以是正性光刻胶或负性光刻胶,在此不做特殊限定。光刻胶层3341远离第二绝缘介质层324的表面的形状可与第二绝缘介质层324表面的形状相同。可采用掩膜版对光刻胶层3341进行曝光,该掩膜版的图案可与环形圈41和各电容孔37所需的图案匹配。随后,可对曝光后的光刻胶层3341进行显影,从而形成显影区,如图12所示,该显影区可露出第二绝缘介质层324,且显影区的图案可与环形圈41和各电容孔37所需的图案相同,显影区的尺寸可与所需环形圈41和各电容孔37的尺寸相同。A photoresist layer 3341 may be formed on the second insulating medium layer 324 by spin coating or other methods, and the material of the photoresist layer 3341 may be positive photoresist or negative photoresist, which is not limited herein. The shape of the surface of the photoresist layer 3341 away from the second insulating medium layer 324 may be the same as the shape of the surface of the second insulating medium layer 324 . The photoresist layer 3341 can be exposed using a mask, the pattern of which can be matched to the desired pattern of the annular ring 41 and each capacitor hole 37 . Subsequently, the exposed photoresist layer 3341 can be developed to form a developed area, as shown in FIG. 12 , the second insulating medium layer 324 can be exposed in the developed area, and the pattern of the developed area can be matched with the annular ring 41 and the respective The required pattern of the capacitor holes 37 is the same, and the size of the developing area can be the same as the required size of the annular ring 41 and each capacitor hole 37 .
可通过干法刻蚀在显影区对第一牺牲层321、第一绝缘介质层322、第二牺牲层323和第二绝缘介质层324进行刻蚀,并以导电接触塞2为蚀刻停止层,在单元区域11形成多个间隔排布的柱状空隙结构,该柱状孔隙结构可露出第二导电接触塞22和各第一导电接触塞21,同时,可对柱状孔隙结构的开口尺寸进行控制,使得位于单元区域11外围的柱状空隙结构在平行于衬底1方向上的横截面间距大于单元区域11中非外围的柱状空隙结构的横截面间距。为了便于区分,可将与第一导 电接触塞21对应的柱状孔隙结构作为电容孔37,将与第二导电接触塞22对应的柱状孔隙结构作为环形圈41。The first sacrificial layer 321, the first insulating dielectric layer 322, the second sacrificial layer 323 and the second insulating dielectric layer 324 can be etched in the developing area by dry etching, and the conductive contact plug 2 is used as the etching stop layer, A plurality of columnar void structures arranged at intervals are formed in the unit region 11 , and the columnar void structures can expose the second conductive contact plug 22 and each of the first conductive contact plugs 21 . At the same time, the opening size of the columnar void structure can be controlled so that The cross-sectional spacing of the columnar void structures located at the periphery of the cell region 11 in the direction parallel to the substrate 1 is greater than the cross-sectional spacing of the non-peripheral columnar void structures in the cell region 11 . In order to facilitate the distinction, the columnar pore structure corresponding to the first conductive contact plug 21 may be used as the capacitor hole 37, and the columnar pore structure corresponding to the second conductive contact plug 22 may be used as the annular ring 41.
为了提高电容储量,各电容孔37的尺寸可由靠近衬底1一侧向远离衬底1的一侧依次增大,当然,各电容孔37也可均为直孔,在此不对各电容孔37的尺寸做特殊限定。同时,为了保证对电容顶部的支撑强度,环形圈41的内壁与外壁之间的间距可由靠近衬底1一侧向远离衬底1的一侧依次增大,当然,在平行于衬底1的所有横截面上,其内壁与外壁之间的间距也均可相等,在此不对环形圈41的内壁与外壁之间的尺寸做特殊限定。In order to increase the capacity of the capacitor, the size of each capacitor hole 37 can be sequentially increased from the side close to the substrate 1 to the side away from the substrate 1. Of course, each capacitor hole 37 can also be a straight hole. The size is specially limited. At the same time, in order to ensure the support strength for the top of the capacitor, the distance between the inner wall and the outer wall of the annular ring 41 can be increased sequentially from the side close to the substrate 1 to the side away from the substrate 1 . In all cross sections, the distance between the inner wall and the outer wall can also be equal, and the size between the inner wall and the outer wall of the annular ring 41 is not particularly limited here.
步骤S220,沉积下电极材料,在所述柱状空隙结构的侧壁形成下电极层。Step S220, depositing a lower electrode material, and forming a lower electrode layer on the sidewall of the columnar void structure.
可在柱状空隙结构的侧壁形成下电极层33,具体而言,可在电容孔37内形成随形贴合于电容孔37底部及侧壁表面的下电极层33,如图13所示,为了工艺方便,可在电容孔37内和其顶表面同时形成下电极层33,随后可去除电容孔37顶表面的下电极层33,只保留其底部及侧壁上的下电极层33,最终形成的下电极层33,如图3所示。且下电极层33可通过电容孔37与第一导电接触塞21接触连接,以将下电极层33存储的电量输入至存储介电接触塞,从而实现电容存储。The lower electrode layer 33 can be formed on the sidewall of the columnar void structure. Specifically, the lower electrode layer 33 can be formed in the capacitor hole 37 to conform to the bottom of the capacitor hole 37 and the surface of the sidewall, as shown in FIG. 13 . For the convenience of the process, the lower electrode layer 33 can be formed in the capacitor hole 37 and its top surface at the same time, and then the lower electrode layer 33 on the top surface of the capacitor hole 37 can be removed, and only the bottom electrode layer 33 on the bottom and sidewalls of the capacitor hole 37 can be left, and finally The formed lower electrode layer 33 is shown in FIG. 3 . In addition, the lower electrode layer 33 can be in contact with the first conductive contact plug 21 through the capacitor hole 37 to input the electricity stored in the lower electrode layer 33 to the storage dielectric contact plug, thereby realizing capacitance storage.
举例而言,可采用化学气相沉积工艺在电容孔37中形成下电极层33,当然,还可通过其他工艺形成下电极层33,在此不做特殊限定。下电极层33的材料可以是氮化钛,其厚度可以是4nm~10nm,举例而言,其可以是4nm、6nm、8nm或10nm,当然,下电极层33还可以是其他材料或其他厚度,在此不再一一列举。此外,为了工艺方便,也可同时在环形圈41内形成下电极层33。For example, the chemical vapor deposition process can be used to form the lower electrode layer 33 in the capacitor hole 37 , and of course, the lower electrode layer 33 can also be formed by other processes, which is not limited herein. The material of the lower electrode layer 33 may be titanium nitride, and its thickness may be 4 nm to 10 nm, for example, it may be 4 nm, 6 nm, 8 nm or 10 nm. Of course, the lower electrode layer 33 may also be made of other materials or other thicknesses. I will not list them one by one here. In addition, for the convenience of the process, the lower electrode layer 33 may also be formed in the annular ring 41 at the same time.
步骤S230,沉积电介质材料,所述电介质材料填满所述单元区域外围的所述柱状空隙结构,以形成所述支撑结构,且在所述单元区域的非外围柱状空隙结构未被填充。Step S230 , depositing a dielectric material, the dielectric material filling the columnar void structures at the periphery of the cell region to form the support structure, and the non-periphery columnar void structures in the cell region are not filled.
可采用化学气相沉积工艺在第二绝缘介质层324背离第二牺牲层323的表面及环形圈41内沉积电介质材料,以形成覆盖层7,如图14所示,该覆盖层7能够填满单元区域11外围的柱状空隙结构,即填满环形圈41,以形成支撑结构4,此时,位于单元区域11的非外围的柱状空隙结构未被填充,即电容孔37未被填充。同时,可通过化学气相沉积或其它方式在距离衬底1最远的绝缘介质层32背离衬底1的一侧形成掩膜材料层,该掩膜材料层可覆盖电容孔37远离第一导电接触塞21的一侧。掩膜材料层的材料可以是氧化硅、氮氧化物或碳中至少一种,当然,也可以是其它材料,在此不再一一列举。掩膜材料层可以是单层结构也可以是多层结构在此不做特殊限定。A chemical vapor deposition process can be used to deposit a dielectric material on the surface of the second insulating dielectric layer 324 facing away from the second sacrificial layer 323 and in the annular ring 41 to form a cover layer 7, as shown in FIG. 14, the cover layer 7 can fill the cell The columnar void structure at the periphery of the area 11 is filled with the annular ring 41 to form the support structure 4 . At this time, the columnar void structure at the non-periphery of the cell area 11 is not filled, that is, the capacitor hole 37 is not filled. At the same time, a mask material layer can be formed on the side of the insulating dielectric layer 32 farthest from the substrate 1 away from the substrate 1 by chemical vapor deposition or other methods, and the mask material layer can cover the capacitor hole 37 away from the first conductive contact. one side of the plug 21. The material of the mask material layer may be at least one of silicon oxide, oxynitride or carbon, and of course, may also be other materials, which will not be listed here. The mask material layer may be a single-layer structure or a multi-layer structure, which is not particularly limited here.
可通过旋涂或其它方式在掩膜材料层上形成光刻胶层3341,光刻胶层3341材料可以是正性光刻胶或负性光刻胶,在此不做特殊限定。如图15所示,可采用掩膜版对光刻胶层3341进行曝光,掩膜版的图案可与距离衬底1最远的绝缘介质层 32上的开口所需的图案匹配,如图16所示,开口71在衬底1上的正投影可覆盖于相邻两个电容孔37之间的区域。随后,可对曝光后的光刻胶层3341进行显影,从而形成显影区,该显影区可露出掩膜材料层。如图17所示,在显影区对掩膜材料层及距离衬底1最远的绝缘介质层32进行刻蚀,以形成开口71,可通过该开口71露出与绝缘介质层32邻接的牺牲层。The photoresist layer 3341 may be formed on the mask material layer by spin coating or other methods, and the material of the photoresist layer 3341 may be positive photoresist or negative photoresist, which is not limited herein. As shown in FIG. 15 , the photoresist layer 3341 can be exposed using a mask, and the pattern of the mask can match the desired pattern of the opening on the insulating medium layer 32 farthest from the substrate 1 , as shown in FIG. 16 . As shown, the orthographic projection of the opening 71 on the substrate 1 may cover the area between two adjacent capacitor holes 37 . Subsequently, the exposed photoresist layer 3341 may be developed to form a development area, which may expose the mask material layer. As shown in FIG. 17 , the mask material layer and the insulating medium layer 32 farthest from the substrate 1 are etched in the developing area to form an opening 71 through which the sacrificial layer adjacent to the insulating medium layer 32 can be exposed. .
步骤S240,去除所述单元区域内的所述牺牲层,保留所述绝缘介质层。Step S240 , removing the sacrificial layer in the unit region and leaving the insulating dielectric layer.
在形成下电极层33后可去除单元区域11内各牺牲层,而保留各绝缘介质层32,既可增大电容存储密度,又可对下电极层33进行支撑,避免下电极层33发生形变,降低短路风险。After the lower electrode layer 33 is formed, the sacrificial layers in the unit region 11 can be removed, and the insulating dielectric layers 32 can be retained, which can not only increase the capacitance storage density, but also support the lower electrode layer 33 and prevent the lower electrode layer 33 from being deformed. , reduce the risk of short circuit.
此外,如图18所示,还可对覆盖层7的表面进行平坦化处理,以去除位于环形圈41外部的顶部的覆盖层7,使环形圈41中的覆盖层7的表面与第二绝缘介质层324背离衬底1一侧的表面平齐,从而成支撑结构4。In addition, as shown in FIG. 18 , the surface of the cover layer 7 can also be planarized to remove the cover layer 7 located at the top of the outer ring 41 , so that the surface of the cover layer 7 in the ring ring 41 is insulated from the second The surface of the dielectric layer 324 on the side facing away from the substrate 1 is flush to form the support structure 4 .
步骤S250,在所述单元区域的非外围柱状空隙结构的下电极层上依次形成电容介质层和上电极层,以形成电容阵列。In step S250, a capacitor dielectric layer and an upper electrode layer are sequentially formed on the lower electrode layer of the non-peripheral columnar void structure in the unit region to form a capacitor array.
可在单元区域11的电容孔37内的下电极层33上形成电容介质层34,举例而言,电容介质层34可以是形成于下电极层33表面上的薄膜,可通过真空蒸镀或磁控溅射等工艺形成电容介质层34,当然,还可以通过其他工艺形成电容介质层34,在此不再一一列举。电容介质层34可以是由同一种材料构成的单层膜结构,也可以是由不同材质的膜层构成的混合膜层结构。举例而言,其可包括具有较高介电常数的材料,例如,其可以是氧化铝、氧化铪、氧化镧、氧化钛、氧化锆、氧化钽、氧化铌、氧化锶或其混合物,当然,还可以是其他材料,在此不再一一列举。The capacitor dielectric layer 34 can be formed on the lower electrode layer 33 in the capacitor hole 37 of the unit region 11. For example, the capacitor dielectric layer 34 can be a thin film formed on the surface of the lower electrode layer 33, which can be formed by vacuum evaporation or magnetic The capacitive dielectric layer 34 may be formed by processes such as controlled sputtering. Of course, the capacitive dielectric layer 34 may also be formed by other processes, which will not be listed here. The capacitor dielectric layer 34 may be a single-layer film structure composed of the same material, or may be a mixed film layer structure composed of film layers of different materials. For example, it may include a material with a higher dielectric constant, for example, it may be aluminum oxide, hafnium oxide, lanthanum oxide, titanium oxide, zirconium oxide, tantalum oxide, niobium oxide, strontium oxide, or mixtures thereof, of course, It can also be other materials, which will not be listed one by one here.
可采用化学气相沉积工艺在电容介质层34的外表面形成上电极层35,当然,还可通过其他工艺形成上电极层35,在此不做特殊限定。上电极层35的材料可以是氮化钛,其厚度可以是2nm~8nm,举例而言,其可以是2nm、4nm、6nm或8nm,当然,上电极层35还可以是其他材料或其他厚度,在此不再一一列举。The upper electrode layer 35 may be formed on the outer surface of the capacitor dielectric layer 34 by a chemical vapor deposition process. Of course, the upper electrode layer 35 may also be formed by other processes, which are not limited herein. The material of the upper electrode layer 35 can be titanium nitride, and its thickness can be 2nm-8nm, for example, it can be 2nm, 4nm, 6nm or 8nm, of course, the upper electrode layer 35 can also be other materials or other thicknesses, I will not list them one by one here.
在一实施方式中,本公开的形成方法还可包括步骤:如图9所示,其中:In one embodiment, the forming method of the present disclosure may further include the steps: as shown in FIG. 9 , wherein:
步骤S150,形成覆盖所述电容阵列的表面的半导体层,所述半导体层充满所述电容孔及所述电容阵列中相邻两个电容之间的间隙。Step S150, forming a semiconductor layer covering the surface of the capacitor array, the semiconductor layer filling the capacitor hole and the gap between two adjacent capacitors in the capacitor array.
可通过真空蒸镀工艺在上电极层35的表面形成覆盖电容阵列3的半导体层5,以使电荷与第二电极充分接触,有助于提高电容充电效率。该半导体层5可覆盖于电容阵列3的表面,且可充满电容孔37及电容阵列3中相邻两个电容之间的间隙,可提高器件的导电性能,加强电容阵列3中各电容的稳定性。半导体层5可由硅材料、金属材料或金属化合物构成,举例而言,其可以是硅、锗硅、钨、硅化钛、氧化钛或氧化钨等,在此不做特殊限定。The semiconductor layer 5 covering the capacitor array 3 can be formed on the surface of the upper electrode layer 35 by a vacuum evaporation process, so that the electric charges can be fully contacted with the second electrode, which helps to improve the charging efficiency of the capacitor. The semiconductor layer 5 can cover the surface of the capacitor array 3 and can fill the capacitor hole 37 and the gap between two adjacent capacitors in the capacitor array 3 , which can improve the electrical conductivity of the device and enhance the stability of each capacitor in the capacitor array 3 sex. The semiconductor layer 5 may be composed of silicon material, metal material or metal compound, for example, it may be silicon, silicon germanium, tungsten, titanium silicide, titanium oxide or tungsten oxide, etc., which is not limited herein.
在一实施方式中,在蚀刻单元区域11的牺牲层和绝缘介质层32之前,本公开 的形成方法还可以包括:In one embodiment, before etching the sacrificial layer and the insulating dielectric layer 32 of the cell region 11, the formation method of the present disclosure may further include:
步骤S160,在所述外围区域形成互连结构。Step S160, forming an interconnection structure in the peripheral region.
该互连结构可形成于外围区域12对应的绝缘介质层32中,并可与外围导电接触塞23接触连接,以便将电容阵列3电学引出。外围导电接触塞23可与第一导电接触塞21以及第二导电接触塞22的材料相同,厚度相等,可在形成第一导电接触塞21以及第二导电接触塞22的同时形成外围导电接触塞23。The interconnection structure can be formed in the insulating dielectric layer 32 corresponding to the peripheral region 12 , and can be in contact with the peripheral conductive contact plugs 23 , so as to electrically lead out the capacitor array 3 . The peripheral conductive contact plugs 23 can be made of the same material as the first conductive contact plugs 21 and the second conductive contact plugs 22 and have the same thickness, and the peripheral conductive contact plugs can be formed at the same time as the first conductive contact plugs 21 and the second conductive contact plugs 22 are formed twenty three.
在一实施方式中,如图19所示,形成互连结构可以包括:In one embodiment, as shown in FIG. 19, forming the interconnect structure may include:
步骤S1601,在所述衬底的单元区域上形成所述导电接触塞的同时在所述外围区域形成所述导电接触塞。Step S1601, the conductive contact plugs are formed in the peripheral region while the conductive contact plugs are formed on the unit region of the substrate.
可过一次工艺同时形成单元区域11的第一导电接触塞21、第二导电接触塞22和位于外围区域12的外围导电接触塞23。例如,可通过化学气相沉积工艺及干法刻蚀工艺同时形成第一导电接触塞21、第二导电接触塞22和外围导电接触塞23,当然,也可以通过方式同时形成第一导电接触塞21、第二导电接触塞22和外围导电接触塞23,在此不再一一列举。The first conductive contact plugs 21 , the second conductive contact plugs 22 and the peripheral conductive contact plugs 23 located in the peripheral area 12 of the cell region 11 may be simultaneously formed in one process. For example, the first conductive contact plugs 21 , the second conductive contact plugs 22 and the peripheral conductive contact plugs 23 can be formed simultaneously by a chemical vapor deposition process and a dry etching process. Of course, the first conductive contact plugs 21 can also be formed simultaneously by means of , the second conductive contact plug 22 and the peripheral conductive contact plug 23 , which will not be listed one by one here.
步骤S1602,在所述外围区域形成第一牺牲层。Step S1602, forming a first sacrificial layer in the peripheral region.
可通过真空蒸镀、磁控溅射、原子层沉积等方式形成第一牺牲层321。The first sacrificial layer 321 can be formed by vacuum evaporation, magnetron sputtering, atomic layer deposition, or the like.
步骤S1603,以所述外围区域的所述导电接触塞为蚀刻停止层,蚀刻所述第一牺牲层,以形成第一过孔。Step S1603, using the conductive contact plug in the peripheral region as an etch stop layer, etching the first sacrificial layer to form a first via hole.
可通过光刻工艺形成第一过孔61,第一过孔61可形成于第一牺牲层321内,且可露出外围导电接触塞23。The first via hole 61 may be formed by a photolithography process, and the first via hole 61 may be formed in the first sacrificial layer 321 and may expose the peripheral conductive contact plugs 23 .
步骤S1604,在所述第一过孔中形成第一互连结构。Step S1604, forming a first interconnect structure in the first via hole.
可通过化学气相沉积工艺在第一过孔61内形成第一互连结构6,该第一互连结构6可通过第一过孔61与半导体层5连通,以便将电容阵列3电学引出。The first interconnect structure 6 can be formed in the first via hole 61 by a chemical vapor deposition process, and the first interconnect structure 6 can be communicated with the semiconductor layer 5 through the first via hole 61 so as to electrically lead out the capacitor array 3 .
第一互连结构6可以包括连接层62和引出层63,连接层62可随型贴附于第一过孔61的孔壁和底面,并可与半导体层5的顶部连通,引出层63可位于连接层62上,且可填满第一过孔61。连接层62和引出层63的材料均可为导电材料,例如,连接层62的材料可为氮化钛,引出层63的材料可为钨。The first interconnection structure 6 may include a connection layer 62 and an extraction layer 63. The connection layer 62 may be attached to the hole wall and bottom surface of the first via hole 61, and may communicate with the top of the semiconductor layer 5. The extraction layer 63 may be connected to the top of the semiconductor layer 5. It is located on the connection layer 62 and can fill the first via hole 61 . Both the connection layer 62 and the extraction layer 63 can be made of conductive materials, for example, the connection layer 62 can be made of titanium nitride, and the extraction layer 63 can be made of tungsten.
如图19所示,在形成第一互连结构6后,本公开的形成方法还可包括:As shown in FIG. 19, after forming the first interconnect structure 6, the forming method of the present disclosure may further include:
步骤S1605,在所述外围区域的第一牺牲层上依次形成所述绝缘介质层和第二牺牲层,以所述第一互连结构为蚀刻停止层,蚀刻所述绝缘介质层和所述第二牺牲层,以形成第二过孔。In step S1605, the insulating dielectric layer and the second sacrificial layer are sequentially formed on the first sacrificial layer in the peripheral region, and the first interconnection structure is used as an etch stop layer to etch the insulating dielectric layer and the second sacrificial layer. two sacrificial layers to form second vias.
可通过真空蒸镀、磁控溅射、原子层沉积等方式在外围区域12的第一牺牲层321上依次形成绝缘介质层32和第二牺牲层323,可通过光刻工艺形成第二过孔,第二过孔可形成于第二牺牲层323内,且可与第一互连结构6接触连接。The insulating dielectric layer 32 and the second sacrificial layer 323 can be sequentially formed on the first sacrificial layer 321 in the peripheral region 12 by vacuum evaporation, magnetron sputtering, atomic layer deposition, etc., and the second via hole can be formed by a photolithography process , the second via hole can be formed in the second sacrificial layer 323 and can be in contact with the first interconnect structure 6 .
步骤S1606,在所述第二过孔中形成第二互连结构。Step S1606, forming a second interconnection structure in the second via hole.
可通过化学气相沉积工艺在第二过孔内形成第二互连结构,该第二互连结构可通过第二过孔与第一互连结构6连通,以便将电容阵列3电学引出。The second interconnection structure can be formed in the second via hole by a chemical vapor deposition process, and the second interconnection structure can be communicated with the first interconnection structure 6 through the second via hole, so as to electrically lead out the capacitor array 3 .
第二互连结构可与第一互连结构6的结构和材料均相同,第二互连结构也可包括连接层和引出层,连接层可随型贴附于第二过孔91的孔壁和底面,并可第一互连结构6的顶部连通,引出层可位于连接层上,且可填满第二过孔91。The second interconnection structure may be the same in structure and material as the first interconnection structure 6 , the second interconnection structure may also include a connection layer and a lead-out layer, and the connection layer may be attached to the hole wall of the second via hole 91 according to the pattern and the bottom surface, and can communicate with the top of the first interconnection structure 6 , the lead-out layer can be located on the connection layer, and the second via hole 91 can be filled.
本公开的半导体器件可以是存储芯片,例如,其可以是DRAM(Dynamic Random Access Memory,动态随机存取存储器),当然,还可以是其它半导体器件,在此不再一一列举。The semiconductor device of the present disclosure can be a memory chip, for example, it can be a DRAM (Dynamic Random Access Memory, dynamic random access memory), of course, can also be other semiconductor devices, which will not be listed one by one here.
本领域技术人员在考虑说明书及实践这里公开的发明后,将容易想到本公开的其它实施方案。本申请旨在涵盖本公开的任何变型、用途或者适应性变化,这些变型、用途或者适应性变化遵循本公开的一般性原理并包括本公开未公开的本技术领域中的公知常识或惯用技术手段。说明书和实施例仅被视为示例性的,本公开的真正范围和精神由所附的权利要求指出。Other embodiments of the present disclosure will readily occur to those skilled in the art upon consideration of the specification and practice of the invention disclosed herein. This application is intended to cover any variations, uses, or adaptations of the present disclosure that follow the general principles of the present disclosure and include common knowledge or techniques in the technical field not disclosed by the present disclosure . The specification and examples are to be regarded as exemplary only, with the true scope and spirit of the disclosure being indicated by the appended claims.

Claims (11)

  1. 一种半导体器件,其中,包括:A semiconductor device, comprising:
    衬底,所述衬底上形成有多个间隔排布的导电接触塞;a substrate, on which a plurality of conductive contact plugs arranged at intervals are formed;
    电容阵列,所述电容阵列包括多个间隔排布的柱状电容,各所述柱状电容分别形成在各所述导电接触塞上,且所述柱状电容的下电极层与所述导电接触塞接触连接;A capacitor array, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is in contact with the conductive contact plug ;
    支撑结构,所述支撑结构形成于所述电容阵列边缘的所述衬底上,并环绕所述电容阵列,且所述支撑结构的内壁与外壁在平行于所述衬底的任一横截面上的间距大于任一所述柱状电容的电容孔在所述横截面上的孔径。a support structure, the support structure is formed on the substrate at the edge of the capacitor array and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are on any cross section parallel to the substrate The spacing is greater than the diameter of the capacitor hole on the cross section of any one of the column capacitors.
  2. 根据权利要求1所述的半导体器件,其中,所述导电接触塞包括第一导电接触塞和第二导电接触塞,所述第一导电接触塞与所述柱状电容的下电极层接触,所述第二导电接触塞与所述支撑结构的底部接触。The semiconductor device of claim 1, wherein the conductive contact plug comprises a first conductive contact plug and a second conductive contact plug, the first conductive contact plug is in contact with a lower electrode layer of the column capacitor, the A second conductive contact plug is in contact with the bottom of the support structure.
  3. 根据权利要求1所述的半导体器件,其中,所述衬底上至少形成有绝缘介质层,所述电容阵列和所述支撑结构形成于所述绝缘介质层中。The semiconductor device of claim 1, wherein at least an insulating dielectric layer is formed on the substrate, and the capacitor array and the support structure are formed in the insulating dielectric layer.
  4. 根据权利要求2所述的半导体器件,其中,所述支撑结构在所述第二导电接触塞上的正投影与所述第二导电接触塞的边界重合。3. The semiconductor device of claim 2, wherein an orthographic projection of the support structure on the second conductive contact plug coincides with a boundary of the second conductive contact plug.
  5. 根据权利要求3所述的半导体器件,其中,所述衬底包括单元区域和外围区域,所述电容阵列形成在所述单元区域,所述导电接触塞还包括外围导电接触塞,所述外围导电接触塞形成在所述外围区域,所述半导体器件还包括与所述外围导电接触塞连接的互连结构,所述互连结构形成在所述绝缘介质层中。The semiconductor device of claim 3, wherein the substrate includes a cell region and a peripheral region, the capacitor array is formed in the cell region, the conductive contact plug further includes a peripheral conductive contact plug, the peripheral conductive Contact plugs are formed in the peripheral region, and the semiconductor device further includes an interconnect structure connected to the peripheral conductive contact plug, the interconnect structure formed in the insulating dielectric layer.
  6. 根据权利要求3所述的半导体器件,其中,所述绝缘介质层包括沿垂直于所述衬底的方向间隔排布的第一绝缘介质层和第二绝缘介质层,所述电容阵列和所述支撑结构形成在所述第一绝缘介质层和所述第二绝缘介质层中。3. The semiconductor device of claim 3, wherein the insulating dielectric layer comprises a first insulating dielectric layer and a second insulating dielectric layer spaced along a direction perpendicular to the substrate, the capacitor array and the A support structure is formed in the first insulating dielectric layer and the second insulating dielectric layer.
  7. 一种半导体器件的形成方法,其中,所述形成方法包括:A method of forming a semiconductor device, wherein the forming method comprises:
    提供衬底;provide a substrate;
    在所述衬底上形成多个间隔排布的导电接触塞;forming a plurality of spaced-apart conductive contact plugs on the substrate;
    形成电容阵列,所述电容阵列包括多个间隔排布的柱状电容,各所述柱状电容分别形成在各所述导电接触塞上,且所述柱状电容的下电极层与所述导电接触塞接触连接;A capacitor array is formed, the capacitor array includes a plurality of column capacitors arranged at intervals, each of the column capacitors is formed on each of the conductive contact plugs, and the lower electrode layer of the column capacitor is in contact with the conductive contact plug connect;
    形成支撑结构,所述支撑结构形成于所述电容阵列边缘的所述衬底上,并环绕所述电容阵列,且所述支撑结构的内壁与外壁在平行于所述衬底的任一横截面上的间距大于任一所述柱状电容的电容孔在所述横截面上的孔径。A support structure is formed, the support structure is formed on the substrate at the edge of the capacitor array, and surrounds the capacitor array, and the inner wall and the outer wall of the support structure are in any cross-section parallel to the substrate The distance between the capacitor holes is larger than the diameter of the capacitor holes on the cross section of any one of the column capacitors.
  8. 根据权利要求7所述的形成方法,其中,所述衬底具有单元区域,所述单元区域上形成有多个间隔排布的导电接触塞,且位于所述单元区域边缘的所述导电接触塞的宽度大于所述单元区域中非边缘的所述导电接触塞的宽度,所述形成电容阵 列和支撑结构包括:The forming method according to claim 7, wherein the substrate has a unit area, a plurality of conductive contact plugs arranged at intervals are formed on the unit area, and the conductive contact plugs are located at the edge of the unit area The width of the conductive contact plug is greater than the width of the non-edge conductive contact plug in the unit area, and the forming the capacitor array and the supporting structure includes:
    在所述衬底上依次形成牺牲层和绝缘介质层,以所述导电接触塞为蚀刻停止层,蚀刻所述单元区域的所述牺牲层和所述绝缘介质层,在所述单元区域形成多个间隔排布的柱状空隙结构,并控制蚀刻窗口,使得位于所述单元区域外围的柱状空隙结构在平行于所述衬底方向上的横截面间距大于所述单元区域中非外围的柱状空隙结构的横截面间距;A sacrificial layer and an insulating dielectric layer are sequentially formed on the substrate, the conductive contact plug is used as an etch stop layer, the sacrificial layer and the insulating dielectric layer in the unit area are etched, and multiple layers are formed in the unit area. Columnar void structures are arranged at intervals, and the etching window is controlled so that the cross-sectional spacing of the columnar void structures located at the periphery of the cell region in the direction parallel to the substrate is greater than that of the non-periphery columnar void structures in the cell region the cross-sectional spacing;
    沉积下电极材料,在所述柱状空隙结构的侧壁形成下电极层;depositing a lower electrode material to form a lower electrode layer on the sidewall of the columnar void structure;
    沉积电介质材料,所述电介质材料填满所述单元区域外围的所述柱状空隙结构,以形成所述支撑结构,且在所述单元区域的非外围柱状空隙结构未被填充;depositing a dielectric material, the dielectric material filling the columnar void structures at the periphery of the cell region to form the support structure, and the non-peripheral columnar void structures in the cell region being unfilled;
    去除所述单元区域内的所述牺牲层,保留所述绝缘介质层;removing the sacrificial layer in the unit region, leaving the insulating dielectric layer;
    在所述单元区域的非外围柱状空隙结构的下电极层上依次形成电容介质层和上电极层,以形成电容阵列。A capacitor dielectric layer and an upper electrode layer are sequentially formed on the lower electrode layer of the non-peripheral columnar void structure in the unit region to form a capacitor array.
  9. 根据权利要求8所述的形成方法,其中,所述衬底还具有外围区域,在蚀刻所述单元区域的所述牺牲层和所述绝缘介质层之前,所述形成方法还包括:The forming method according to claim 8, wherein the substrate further has a peripheral area, and before etching the sacrificial layer and the insulating dielectric layer of the unit area, the forming method further comprises:
    在所述外围区域形成互连结构。An interconnect structure is formed in the peripheral region.
  10. 根据权利要求9所述的形成方法,其中,形成所述互连结构包括:9. The forming method of claim 9, wherein forming the interconnect structure comprises:
    在所述衬底的单元区域上形成所述导电接触塞的同时在所述外围区域形成所述导电接触塞;forming the conductive contact plugs in the peripheral region while forming the conductive contact plugs on the cell region of the substrate;
    在所述外围区域形成第一牺牲层;forming a first sacrificial layer in the peripheral region;
    以所述外围区域的所述导电接触塞为蚀刻停止层,蚀刻所述第一牺牲层,以形成第一过孔;Using the conductive contact plug in the peripheral region as an etch stop layer, etching the first sacrificial layer to form a first via hole;
    在所述第一过孔中形成第一互连结构。A first interconnect structure is formed in the first via.
  11. 根据权利要求10所述的形成方法,其中,在形成所述第一互连结构后,所述形成方法还包括:The forming method of claim 10, wherein after forming the first interconnect structure, the forming method further comprises:
    在所述外围区域的第一牺牲层上依次形成所述绝缘介质层和第二牺牲层,以所述第一互连结构为蚀刻停止层,蚀刻所述绝缘介质层和所述第二牺牲层,以形成第二过孔;The insulating dielectric layer and the second sacrificial layer are sequentially formed on the first sacrificial layer in the peripheral region, and the insulating dielectric layer and the second sacrificial layer are etched using the first interconnect structure as an etch stop layer. , to form a second via;
    在所述第二过孔中形成第二互连结构。A second interconnect structure is formed in the second via.
PCT/CN2021/097506 2020-08-21 2021-05-31 Semiconductor device and method for forming same WO2022037178A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP21773277.5A EP3985724B1 (en) 2020-08-21 2021-05-31 Semiconductor device and method for forming same
US17/391,181 US11937419B2 (en) 2020-08-21 2021-08-02 Semiconductor device and forming method thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202010849895.1 2020-08-21
CN202010849895.1A CN114078855A (en) 2020-08-21 2020-08-21 Semiconductor device and method of forming the same

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US17/391,181 Continuation US11937419B2 (en) 2020-08-21 2021-08-02 Semiconductor device and forming method thereof

Publications (1)

Publication Number Publication Date
WO2022037178A1 true WO2022037178A1 (en) 2022-02-24

Family

ID=79316869

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2021/097506 WO2022037178A1 (en) 2020-08-21 2021-05-31 Semiconductor device and method for forming same

Country Status (2)

Country Link
CN (1) CN114078855A (en)
WO (1) WO2022037178A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116209257A (en) * 2023-05-05 2023-06-02 长鑫存储技术有限公司 Semiconductor device and method for manufacturing the same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI814309B (en) * 2022-03-28 2023-09-01 華邦電子股份有限公司 Semiconductor structure and manufacturing method therefore
CN114420678B (en) * 2022-03-29 2022-06-07 威海嘉瑞光电科技股份有限公司 Capacitor structure and manufacturing method thereof
TWI822048B (en) * 2022-05-19 2023-11-11 華邦電子股份有限公司 Semiconductor device and method of manufacturing the same
CN116489993B (en) * 2023-06-21 2023-11-14 长鑫存储技术有限公司 Semiconductor structure and forming method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000196038A (en) * 1998-12-28 2000-07-14 Fujitsu Ltd Semiconductor device and manufacture thereof
US20060014344A1 (en) * 2004-07-19 2006-01-19 Manning H M Methods of forming semiconductor structures and capacitor devices
US20110165756A1 (en) * 2010-01-07 2011-07-07 Elpida Memory, Inc Method for manufacturing semiconductor device
US20130168812A1 (en) * 2012-01-04 2013-07-04 Inotera Memories, Inc. Memory capacitor having a robust moat and manufacturing method thereof
US20170025416A1 (en) * 2015-07-22 2017-01-26 Samsung Electronics Co., Ltd. Capacitor structures and methods of forming the same, and semiconductor devices including the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000196038A (en) * 1998-12-28 2000-07-14 Fujitsu Ltd Semiconductor device and manufacture thereof
US20060014344A1 (en) * 2004-07-19 2006-01-19 Manning H M Methods of forming semiconductor structures and capacitor devices
US20110165756A1 (en) * 2010-01-07 2011-07-07 Elpida Memory, Inc Method for manufacturing semiconductor device
US20130168812A1 (en) * 2012-01-04 2013-07-04 Inotera Memories, Inc. Memory capacitor having a robust moat and manufacturing method thereof
US20170025416A1 (en) * 2015-07-22 2017-01-26 Samsung Electronics Co., Ltd. Capacitor structures and methods of forming the same, and semiconductor devices including the same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3985724A4 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116209257A (en) * 2023-05-05 2023-06-02 长鑫存储技术有限公司 Semiconductor device and method for manufacturing the same

Also Published As

Publication number Publication date
CN114078855A (en) 2022-02-22

Similar Documents

Publication Publication Date Title
WO2022037178A1 (en) Semiconductor device and method for forming same
JP3577197B2 (en) Method for manufacturing semiconductor device
KR102076060B1 (en) Semiconductor device including capacitors and method for manufacturing the same
TWI538226B (en) Manufacturing method of stacked capacitor having high structural strength
WO2022247013A1 (en) Memory manufacturing method, and memory
CN113161356B (en) Memory device, semiconductor structure and forming method thereof
US8482046B2 (en) Concentric or nested container capacitor structure for integrated circuits
CN115241372A (en) Memory device, semiconductor structure and forming method thereof
EP3985724B1 (en) Semiconductor device and method for forming same
WO2022052545A1 (en) Semiconductor device and manufacturing method therefor
WO2023231067A1 (en) Memory, semiconductor structure and forming method therefor
WO2022142346A1 (en) Memory device, semiconductor structure and forming method therefor
WO2021254030A1 (en) Semiconductor component, capacitor device, and manufacturing method for capacitor device
JP2004311918A (en) Semiconductor device with capacitor and its manufacturing method
CN115206885A (en) Semiconductor structure and manufacturing method thereof
US20220085021A1 (en) Semiconductor device and method for manufacturing the same
WO2022057410A1 (en) Semiconductor device, semiconductor structure and manufacturing method therefor
CN116489993B (en) Semiconductor structure and forming method thereof
WO2021233269A1 (en) Semiconductor device holes, semiconductor device preparation method, and semiconductor device
CN117279365A (en) Semiconductor structure, forming method thereof and memory
WO2022088781A1 (en) Semiconductor structure and forming method therefor
US20240008247A1 (en) Semiconductor structure, method for forming semiconductor structure, and memory
WO2023173482A1 (en) Memory, semiconductor structure and preparation method therefor
WO2021203915A1 (en) Capacitor array structure and manufacturing method therefor, and semiconductor storage device
WO2022166216A1 (en) Semiconductor structure and method for forming same

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2021773277

Country of ref document: EP

Effective date: 20210929

NENP Non-entry into the national phase

Ref country code: DE