WO2022011663A1 - Procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone - Google Patents

Procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone Download PDF

Info

Publication number
WO2022011663A1
WO2022011663A1 PCT/CN2020/102579 CN2020102579W WO2022011663A1 WO 2022011663 A1 WO2022011663 A1 WO 2022011663A1 CN 2020102579 W CN2020102579 W CN 2020102579W WO 2022011663 A1 WO2022011663 A1 WO 2022011663A1
Authority
WO
WIPO (PCT)
Prior art keywords
carbon steel
resistant coating
low
wear
powder
Prior art date
Application number
PCT/CN2020/102579
Other languages
English (en)
Chinese (zh)
Inventor
孟君晟
于利民
史晓萍
王永东
金国
王铀
Original Assignee
山东交通学院
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 山东交通学院 filed Critical 山东交通学院
Priority to JP2023503178A priority Critical patent/JP7457427B2/ja
Priority to PCT/CN2020/102579 priority patent/WO2022011663A1/fr
Priority to CN202080006607.4A priority patent/CN113166918B/zh
Publication of WO2022011663A1 publication Critical patent/WO2022011663A1/fr
Priority to ZA2022/03916A priority patent/ZA202203916B/en

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/131—Wire arc spraying
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06—Metallic material
    • C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18—After-treatment

Definitions

  • the invention relates to the technical field of metal surface coating, in particular to a preparation method of a compact wear-resistant coating on the surface of low carbon steel.
  • Wear and corrosion are the main forms of failure of metal materials, especially machine parts under working conditions, such as gears, cylinder liners, and crankshafts of various engines.
  • the performance of high temperature oxidation resistance is an important factor in determining the length of the machine's service life. Therefore, the use of advanced surface strengthening technology to prepare the required wear-resistant coating on the surface of ordinary materials is an effective method to prevent the surface wear of metal materials. This method can significantly improve the service life of parts and save energy materials and energy.
  • Thermal spraying technology is one of the common surface repair and protection technologies at present. It has the advantages of high production efficiency, simple operation, good economic benefits, and high material utilization rate.
  • thermal spraying technologies among which supersonic arc spraying is one of the typical technologies of thermal spraying, although supersonic spraying coatings can obtain higher wear resistance.
  • defects such as pores, cracks, small coating thickness, and poor bonding with the substrate in the spray coating, resulting in poor compactness of the spray coating, and cracking may occur in harsh environments (such as high stress, high temperature and cyclic fatigue). or peeling, limiting its application range.
  • the purpose of the present invention is to provide a preparation method of a compact wear-resistant coating on the surface of a low carbon steel, so as to solve the problem of poor compactness of the wear-resistant coating prepared by supersonic spraying in the prior art.
  • the present invention provides the following scheme:
  • a preparation method of a dense wear-resistant coating on a low-carbon steel surface comprising:
  • the Si, W, Ti, Al, Cr, Ni, La and Fe elemental powders are weighed according to the preset ratio; the preset ratio is: the Si is 8.5-10.5wt.%, and the W is 6.5 ⁇ 8.5wt.%, the Ti is 4.5 ⁇ 7.5wt.%, the Al is 2.5 ⁇ 4.5wt.%, the Cr is 12 ⁇ 20wt.%, the Ni is 5.5 ⁇ 10.5wt.%, so the The La is 1-2% wt.%, and the balance is the Fe;
  • the weighed powder is ball-milled and mixed in a ball mill, and then dried to obtain a filling powder;
  • the filling powder is placed in a U-shaped steel strip groove;
  • the U-shaped steel strip groove is made of cold-rolled strip steel;
  • the rust on the surface of the low carbon steel to be coated is removed to obtain the decontaminated low carbon steel to be coated;
  • the coating is remelted by a non-melting tungsten argon arc machine to obtain a dense wear-resistant coating.
  • the mixing time of the ball milling is 4-6 hours, the drying temperature is 120-150° C., and the drying time is 1-2 hours.
  • the ball mill is a planetary ball mill.
  • the weight ratio of the filling powder to the U-shaped steel strip groove is (0.4-0.6):1.
  • the wire drawing speed of the wire drawing machine is 160-220 mm/s, and the preset diameter of the powder core wire material is 2 mm.
  • the rust on the surface of the low carbon steel to be coated is removed to obtain the decontaminated low carbon steel to be coated, which specifically includes:
  • the 14-25 mesh brown corundum is used for sand blasting under the air pressure of 0.7MPa to remove the rust on the surface of the low carbon steel to be coated, and the decontaminated low carbon steel to be coated is obtained.
  • the parameters of the supersonic arc spraying equipment in spraying are: the spraying voltage of the supersonic arc spraying equipment is 25-30V, the spraying current of the supersonic arc spraying equipment is 150-180A, and the spraying air pressure of the supersonic arc spraying equipment. 0.7 ⁇ 1.2MPa, the spraying distance of the supersonic arc spraying equipment is 180 ⁇ 220mm, the wire feeding speed of the supersonic arc spraying equipment is 78 ⁇ 85cm/min, the moving speed of the spray gun is 12 ⁇ 18mm/s, and the spraying thickness is 1.5mm ⁇ 2.5mm.
  • the parameters of the non-melting tungsten argon arc machine in remelting are: remelting current 100-150A, remelting voltage 18-24V, remelting speed 100-150mm/min, argon gas flow 8- 12L/min.
  • the ball milling mixing time is 5h
  • the drying temperature is 130°C
  • the drying time is 1.5h.
  • the weight ratio of the filling powder to the U-shaped steel strip groove is 0.5:1.
  • the present invention discloses the following technical effects:
  • the invention provides a method for preparing a dense wear-resistant coating on the surface of low carbon steel.
  • the element powder is weighed according to a preset ratio, the weighed powder is ball-milled, mixed, dried, and then placed on a U-shaped steel belt.
  • the wire drawing machine is used to draw the powder core wire; the supersonic arc spraying equipment is used to spray the prepared powder core wire to the treated low carbon steel surface to form a spray coating, and finally the spray coating is carried out by argon arc remelting.
  • the coating is remelted to obtain a dense wear-resistant coating.
  • the preparation method of the invention is simple, the prepared dense wear-resistant coating has a certain thickness and dense structure, can realize automatic production, and has low cost, and provides a new way for supersonic spraying to prepare the wear-resistant coating.
  • Fig. 1 is the flow chart of the preparation method of a kind of low carbon steel surface dense wear-resistant coating provided by the first embodiment of the present invention
  • Fig. 2 is the metallographic micrograph of the dense wear-resistant coating prepared by the second embodiment of the present invention.
  • Fig. 3 is the metallographic micrograph of the dense wear-resistant coating prepared by Example 3 of the present invention.
  • Fig. 4 is the microhardness diagram of the dense wear-resistant coating prepared according to the third embodiment of the present invention.
  • FIG. 5 is a graph of relative wear resistance of the prepared dense wear-resistant coating provided in Example 3 of the present invention.
  • the purpose of the present invention is to provide a preparation method of a compact wear-resistant coating on the surface of a low carbon steel, so as to solve the problem of poor compactness of the wear-resistant coating prepared by supersonic spraying in the prior art.
  • FIG. 1 is a flowchart of a method for preparing a dense wear-resistant coating on a low-carbon steel surface according to Embodiment 1 of the present invention. As shown in FIG. 1 , a preparation method of a dense and wear-resistant coating on a low-carbon steel surface of the present invention Methods include:
  • the preset ratio is: the Si is 8.5-10.5wt.%, the W is 6.5-8.5wt.%, the Ti is 4.5-7.5wt.%, the Al is 2.5-4.5wt.%, the Cr is 12-20wt.%, and the Ni is 5.5-10.5wt.% , the La is 1-2% wt.%, and the balance is the Fe.
  • the weighed powder is ball-milled and mixed in a ball mill, and the mixed powder is uniformly dried to obtain a filling powder.
  • the weighed powder is placed in a planetary ball mill, and ball-milled and mixed at room temperature for 4-6 hours. After mixing, drying is performed at a temperature of 120-150° C. for 1-2 hours to obtain the filling powder.
  • the U-shaped steel strip groove is made of cold-rolled strip steel.
  • cold-rolled strip steel is selected as the coating layer of the powder core wire, and the filling powder is added into the U-shaped steel strip groove, and the weight ratio of the filling powder to the U-shaped steel strip groove is (0.4-0.6 ):1.
  • the prepared powder core wire is sprayed onto the surface of the treated mild steel by using a supersonic arc spraying equipment to form a coating.
  • the parameters of the spraying process are the spraying voltage of the supersonic arc spraying equipment of 25 to 30V, the spraying current of the supersonic arc spraying equipment of 150 to 180A, the spraying pressure of the The spraying distance is 180-220mm, the wire feeding speed of the supersonic arc spraying equipment is 78-85cm/min, the moving speed of the spray gun is 12-18mm/s, and the spraying thickness is 1.5mm-2.5mm.
  • the coating is remelted by using a non-melting tungsten argon arc machine to obtain a wear-resistant coating.
  • a non-melting electrode tungsten electrode argon arc machine is used to remelt the sprayed coating to obtain a wear-resistant coating.
  • the parameters of the argon arc remelting process are: remelting current 100-150A, remelting voltage 18-24V, remelting speed 100-150mm/min, and argon flow rate 8-12L/min.
  • the ball milling mixing time is 5h
  • the drying temperature is 130°C
  • the drying time is 1.5h.
  • the weight ratio of the filling powder to the U-shaped steel strip groove is 0.5:1.
  • the wire drawing speed of the wire drawing machine is 200 mm/s.
  • the parameters of the supersonic arc spraying equipment in spraying are: the spraying voltage of the supersonic arc spraying equipment is 28V, the spraying current of the supersonic arc spraying equipment is 160A, the spraying air pressure of the supersonic arc spraying equipment is 1.0MPa, the The spraying distance of the arc spraying equipment is 190mm, the wire feeding speed of the supersonic arc spraying equipment is 80cm/min, and the moving speed of the spray gun is 15mm/s.
  • the parameters of the non-melting tungsten argon arc machine in remelting are: remelting current 120A, remelting voltage 20V, remelting speed 120mm/min, and argon flow rate 10L/min.
  • the present invention provides Embodiment 2.
  • the low-carbon steel is Q235 steel.
  • the preparation method includes the preparation of powder core wire material and the preparation of wear-resistant coating.
  • the powder core wire material is sprayed on the surface of carbon steel first, and then argon arc remelting is performed.
  • the powder core wire is prepared by filling powder and U-shaped steel belt groove, and the weight percentage of the filling powder is: 9.5wt.% Si, 7wt.% W, 5.5wt.% Ti, 3wt.% Al, 15% wt. % Cr, 7.5 wt. % Ni, 1% wt. % La, the balance is Fe, the diameter of the core wire is 2.0 mm, and the filling rate is 42%.
  • a preparation method of a compact wear-resistant coating on a low-carbon steel surface of the present invention comprises the following steps:
  • step 201 the powder is weighed according to the above proportion, and the weighed powder is placed in a planetary ball mill for ball-milling and mixing at room temperature for 5 hours;
  • Step 202 selecting cold-rolled strip steel as the coating layer of the powder core wire, adding filling powder into the U-shaped steel strip groove, and the weight ratio of the filling powder to the U-shaped steel strip groove is 0.5:1.
  • step 203 the U-shaped groove covered with the filling powder is closed, and then drawn on a wire drawing machine through a wire drawing die to form a tubular welding wire at a speed of 160-220 mm/s to obtain a powder core wire with a diameter of 2.0 mm.
  • Step 204 the surface of the Q235 steel is sandblasted with 14-25 mesh brown corundum under a pressure of 0.7 MPa to remove the rust on the surface.
  • Step 205 the prepared powder core wire is sprayed on the treated Q235 steel surface by using supersonic arc spraying equipment to form a coating; wherein the parameters of the spraying process are spraying current 160A, spraying voltage 28V, spraying air pressure 1.0MPa, spraying distance 190mm, wire feeding speed 80cm/min, spray gun moving speed 15mm/s, spray thickness 2mm.
  • the parameters of the spraying process are spraying current 160A, spraying voltage 28V, spraying air pressure 1.0MPa, spraying distance 190mm, wire feeding speed 80cm/min, spray gun moving speed 15mm/s, spray thickness 2mm.
  • step 206 the sprayed coating is remelted by a non-melting tungsten argon arc machine to obtain a dense wear-resistant coating.
  • argon arc remelting process parameters are remelting current 120A, remelting voltage 20V, remelting speed 120mm/min, and argon gas flow rate 10L/min.
  • the cross-sectional morphology of the dense wear-resistant coating in this example was analyzed using an Axio Lab.Al analytical grade upright material microscope, and the results are shown in Figure 2.
  • the dense wear-resistant coating prepared in the embodiment of the present invention has a good metallurgical bond with the substrate, no defects such as pores are generated, and the structure is uniformly distributed in a dendritic shape.
  • the low-carbon steel is Q235 steel in a method for preparing a dense wear-resistant coating on a low-carbon steel surface.
  • the preparation method includes the preparation of powder core wire material and the preparation of wear-resistant coating.
  • the powder core wire material is sprayed on the surface of carbon steel first, and then argon arc remelting is performed.
  • the powder core wire material is prepared by filling powder and U-shaped steel belt groove, and the weight percentage of the powder core wire material is: 9.5wt.% Si, 7.5wt.% W, 6.5wt.% Ti, 3wt% % Al, 18% wt. % Cr, 8 wt. % Ni, 1.5 wt. % La, the balance is Fe, the diameter of the core wire is 2.0 mm, and the filling rate is 42%.
  • a preparation method of a compact wear-resistant coating on a low-carbon steel surface of the present invention comprises the following steps:
  • step 301 the powder is weighed according to the above proportion, and the weighed powder is placed in a planetary ball mill for ball milling and mixing at room temperature for 5 hours; the mixed powder after ball milling is kept at 130°C for 1.5 hours to obtain a filling powder.
  • Step 302 selecting cold-rolled strip steel as the coating layer of the powder core wire, adding filling powder into the U-shaped steel strip groove, and the weight ratio of the filling powder to the U-shaped steel strip groove is 0.5:1.
  • Step 303 the U-shaped groove covered with the powder filling is closed, and then drawn into a tubular welding wire at a speed of 160-220 mm/s through a wire drawing die on a wire drawing machine to obtain a powder core wire with a diameter of 2.0 mm.
  • Step 304 the surface of the Q235 steel is sandblasted with 14-25 mesh brown corundum under a pressure of 0.7 MPa to remove the rust on the surface.
  • Step 305 the prepared powder core wire is sprayed on the treated Q235 steel surface by using supersonic arc spraying equipment to form a coating; wherein the parameters of the spraying process are spraying current 160A, spraying voltage 28V, spraying air pressure 1.0MPa, spraying distance 190mm, wire feeding speed 80cm/min, spray gun moving speed 15mm/s, spray thickness 2mm.
  • the parameters of the spraying process are spraying current 160A, spraying voltage 28V, spraying air pressure 1.0MPa, spraying distance 190mm, wire feeding speed 80cm/min, spray gun moving speed 15mm/s, spray thickness 2mm.
  • step 306 the sprayed coating is remelted using a non-melting tungsten argon arc machine to obtain a dense wear-resistant coating.
  • argon arc remelting process parameters are remelting current 120A, remelting voltage 20V, remelting speed 120mm/min, and argon gas flow rate 10L/min.
  • the cross-sectional morphology of the dense wear-resistant coating in this example was analyzed using an Axio Lab.Al analytical grade upright material microscope, and the results are shown in Figure 3.
  • the dense wear-resistant coating prepared in the embodiment of the present invention has a good metallurgical bond with the substrate, no defects such as pores are generated, and the structure is uniformly distributed in a dendritic shape.
  • the HVST-1000 Vickers hardness tester is used to test the hardness of the dense wear-resistant coating in this example.
  • the test results are: the hardness of the supersonic spray coating is 515HV, and the hardness of the coating after argon arc remelting treatment is 848HV ⁇ 892HV, it can be seen that the hardness of the coating is increased by 1.6 to 1.7 times after argon arc remelting treatment, as shown in Figure 4.
  • the friction and wear of the dense wear-resistant coating in this example was tested by the MMS-2A friction and wear tester.
  • the test results are: the relative wear resistance after argon arc remelting is 7 times higher than that of the base Q235 steel, which is higher than that of the base Q235 steel.
  • the wear resistance of the HVAC sprayed coating is increased by a factor of 3, and the results are shown in Figure 5.
  • the invention provides a preparation method of the dense wear-resistant coating on the surface of low carbon steel, which adopts supersonic arc spraying and argon arc heavy
  • the melt-phase combination method can obtain coatings with high density and high hardness, thereby promoting the application of coatings in wear-resistant environments.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

L'invention concerne un procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone, le procédé consistant à : peser des poudres de Si, W, Ti, Al, Cr, Ni, La et Fe élémentaires à un rapport prédéfini ; broyer par boulets et mélanger les poudres pesées dans un broyeur à boulets et, après leur mélange uniforme, les sécher de manière à obtenir une poudre de charge ; placer la poudre de charge dans une rainure d'une bande d'acier en forme de U ; fermer une extrémité ouverte de la rainure de bande d'acier en forme de U dans laquelle la poudre de charge est placée et réaliser un tréfilage sur la rainure de bande d'acier en forme de U fermée au moyen d'une tréfileuse, de manière à obtenir un fil à noyau de poudre présentant un diamètre prédéfini ; éliminer la saleté et la rouille de la surface de l'acier à faible teneur en carbone à revêtir pour obtenir de l'acier à faible teneur en carbone décontaminé à revêtir ; revêtir par pulvérisation le fil à noyau en poudre sur la surface de l'acier à faible teneur en carbone décontaminé à revêtir au moyen d'un dispositif de pulvérisation à arc supersonique, de manière à former un revêtement ; et refondre le revêtement au moyen d'une machine de soudage à arc de tungstène non fondu pour obtenir un revêtement compact résistant à l'usure. Le revêtement compact résistant à l'usure obtenu à l'aide du procédé de préparation susmentionné de la présente invention présente une bonne compacité.
PCT/CN2020/102579 2020-07-17 2020-07-17 Procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone WO2022011663A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2023503178A JP7457427B2 (ja) 2020-07-17 2020-07-17 低炭素鋼表面の緻密な耐摩耗コーティングの製造方法
PCT/CN2020/102579 WO2022011663A1 (fr) 2020-07-17 2020-07-17 Procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone
CN202080006607.4A CN113166918B (zh) 2020-07-17 2020-07-17 一种低碳钢表面致密耐磨涂层的制备方法
ZA2022/03916A ZA202203916B (en) 2020-07-17 2022-04-06 Method for preparing compact wear-resistant coating on low-carbon steel surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2020/102579 WO2022011663A1 (fr) 2020-07-17 2020-07-17 Procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone

Publications (1)

Publication Number Publication Date
WO2022011663A1 true WO2022011663A1 (fr) 2022-01-20

Family

ID=76879307

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2020/102579 WO2022011663A1 (fr) 2020-07-17 2020-07-17 Procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone

Country Status (4)

Country Link
JP (1) JP7457427B2 (fr)
CN (1) CN113166918B (fr)
WO (1) WO2022011663A1 (fr)
ZA (1) ZA202203916B (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52117841A (en) * 1976-03-31 1977-10-03 Toyo Karoraijingu Kougiyou Kk Hot run table roller having wearrresisting coat
CN204805815U (zh) * 2015-06-26 2015-11-25 河北建投国融能源服务有限公司 一种密封连接接头的低温省煤器管
CN106435430A (zh) * 2016-12-13 2017-02-22 江西省科学院应用物理研究所 一种提高热喷涂MCrAlY涂层抗氧化性能的方法
CN110819931A (zh) * 2019-11-29 2020-02-21 山东交通学院 一种粉芯焊丝及其制备方法和应用、多孔涂层及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3925050A1 (de) * 1989-07-28 1991-01-31 Basf Ag Schutzschichten aus keramiken des germaniums
CN101532121B (zh) * 2009-04-13 2010-10-20 姚庆君 一种金属表面电弧喷熔加工工艺
JP6391154B2 (ja) 2013-09-20 2018-09-19 アイエヌジ商事株式会社 鉄基合金及び合金溶着方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52117841A (en) * 1976-03-31 1977-10-03 Toyo Karoraijingu Kougiyou Kk Hot run table roller having wearrresisting coat
CN204805815U (zh) * 2015-06-26 2015-11-25 河北建投国融能源服务有限公司 一种密封连接接头的低温省煤器管
CN106435430A (zh) * 2016-12-13 2017-02-22 江西省科学院应用物理研究所 一种提高热喷涂MCrAlY涂层抗氧化性能的方法
CN110819931A (zh) * 2019-11-29 2020-02-21 山东交通学院 一种粉芯焊丝及其制备方法和应用、多孔涂层及其制备方法

Also Published As

Publication number Publication date
CN113166918A (zh) 2021-07-23
CN113166918B (zh) 2022-10-14
JP2023534301A (ja) 2023-08-08
ZA202203916B (en) 2022-05-25
JP7457427B2 (ja) 2024-03-28

Similar Documents

Publication Publication Date Title
US6571472B2 (en) Restoration of thickness to load-bearing gas turbine engine components
CN108677129A (zh) 一种FeCoNiCrSiAl高熵合金涂层及其制备方法
CN102154609A (zh) 一种高精度辊件耐磨涂层的制备方法
CN106835112A (zh) 一种镁合金表面冷喷涂420不锈钢复合涂层的制备方法
CN107236331B (zh) 耐高温腐蚀涂料及其制备方法以及耐高温腐蚀涂层及其制备方法
CN105861974A (zh) 一种抗冲蚀及气蚀磨损复合涂层
CN106893961A (zh) 一种强化水轮机叶片表面的超音速火焰喷涂方法
CN109811294A (zh) 一种用超音速火焰喷涂增强水轮机叶片表面的方法
CN104831208A (zh) 高耐磨铁基热喷涂涂层材料及其制备方法
CN107419213B (zh) 一种金属基体的表面防腐方法
CN105385978A (zh) 一种电弧喷涂方法
CN113215515B (zh) 一种镍基高温合金体积损伤多工艺复合再制造方法
WO2022011663A1 (fr) Procédé de préparation d'un revêtement compact résistant à l'usure sur une surface en acier à faible teneur en carbone
CN113278960B (zh) 一种新型等离子堆焊Fe-Mo2FeB2过渡层的制备方法
CN111763939B (zh) 一种多尺度TiC陶瓷相增强TiAl3/TiAl双相复合涂层及其制备方法
WO2021103426A1 (fr) Fil à noyau de poudre, procédé de préparation et utilisation associés, et revêtement poreux et procédé préparation associé
CN112281105A (zh) 一种金属陶瓷复合涂层及其制备方法和应用
CN110195205A (zh) 一种材料表面防腐耐磨合金涂层的制备方法
CN111004991A (zh) 一种热作模具钢高耐磨高耐蚀保护层的制备方法
CN106756729A (zh) 一种FeB/Co耐锌液腐蚀耐磨金属陶瓷涂层及制备方法
CN104264150B (zh) 一种耐磨性和疲劳性能较好的TiN涂层模具
CN110699627A (zh) 一种耐腐蚀电弧喷涂粉芯丝材及涂层制备方法
CN109628927A (zh) 一种用于海工液压活塞杆的抗磨耐蚀镍基碳化硅复合涂层及其制备方法
CN115287573A (zh) 铁基含Al2O3/B4C复合陶瓷的高速电弧喷涂粉芯丝材及涂层的制备方法
CN108265260B (zh) 一种镍铬硼硅耐磨耐疲劳涂层的制备方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20945185

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2023503178

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20945185

Country of ref document: EP

Kind code of ref document: A1

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) - FORM 1205A (29.06.2023)

122 Ep: pct application non-entry in european phase

Ref document number: 20945185

Country of ref document: EP

Kind code of ref document: A1