WO2022009891A1 - Flavor enhancer - Google Patents

Flavor enhancer Download PDF

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Publication number
WO2022009891A1
WO2022009891A1 PCT/JP2021/025492 JP2021025492W WO2022009891A1 WO 2022009891 A1 WO2022009891 A1 WO 2022009891A1 JP 2021025492 W JP2021025492 W JP 2021025492W WO 2022009891 A1 WO2022009891 A1 WO 2022009891A1
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WO
WIPO (PCT)
Prior art keywords
mass
starch
flavor
food
less
Prior art date
Application number
PCT/JP2021/025492
Other languages
French (fr)
Japanese (ja)
Inventor
智貴 堀金
実奈 吉村
千弘 石川
Original Assignee
株式会社J-オイルミルズ
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Application filed by 株式会社J-オイルミルズ filed Critical 株式会社J-オイルミルズ
Priority to JP2022535353A priority Critical patent/JPWO2022009891A1/ja
Publication of WO2022009891A1 publication Critical patent/WO2022009891A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/10Multi-layered products
    • A21D13/16Multi-layered pastry, e.g. puff pastry; Danish pastry or laminated dough
    • A21D13/19Multi-layered pastry, e.g. puff pastry; Danish pastry or laminated dough with fillings
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L23/00Soups; Sauces; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof

Definitions

  • the present invention relates to a food flavor enhancer.
  • Patent Document 1 discloses a starch decomposition product having a glucose polymerization degree (DP) of 3 to 19 of 70 to 88% and a glucose polymerization degree (DP) of 8 to 12 of 12 to 28%.
  • the starch decomposition product has an excellent balance of basic physical properties such as sweetness, taste, osmotic pressure, viscosity, and hygroscopicity because the molecular weight distribution of the constituent sugars is concentrated in a specific range, and has an effect of enhancing flavor. Is said to have.
  • Patent Document 2 describes seasoning oil and low-molecular-weight starch of starch having a starch content of 75% by mass or more and an amylose content of 5% by mass or more as starch in the composition of 3% by mass or more and 45% by mass or less. 3.
  • the peak molecular weight of the low-molecular-weight starch is 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less, the cold water swelling degree of the composition at 25 ° C. is 5 or more and 20 or less, and the opening in the composition is 3.
  • a step of obtaining a food composition by blending with the starch and a method for producing a food containing the starch, which is said to be able to obtain a food having an enhanced flavor of seasoning oil.
  • the following flavor enhancer for foods eaten in paste form or fluid state method for producing foods eaten in paste form or fluid state, foods eaten in paste form or fluid state
  • a method for enhancing flavor is provided.
  • a flavor enhancer for foods that are eaten in paste or fluid form A flavor enhancer containing the following ingredient (A) as an active ingredient.
  • the content of the starch under the sieve and on the sieve with an opening of 0.038 mm is 50% by mass or more and 100% by mass or less [2].
  • the flavor enhancer according to [1] which contains the component (A) in an amount of 40% by mass or more and 100% by mass or less with respect to the entire flavor enhancer.
  • [6] [1] A method for producing a food, which comprises a step of blending the flavor enhancer according to any one of [1] to [5] into a food material.
  • [7] [1] A method for enhancing the flavor of a food, which comprises a step of applying the flavor enhancing agent according to any one of [1] to [5] to the food.
  • each component can be used alone or in combination of two or more.
  • the flavor enhancing means that the flavor of the food is felt more strongly than in the case where the flavor enhancing agent of the present embodiment is not applied.
  • the enhanced flavor is the flavor of the whole food, for example, a combination of salty taste, umami, sweetness, sourness, bitterness, pungent taste, and the aroma of the food.
  • the flavor-enhancing agent for foods eaten in the form of a paste or in a fluid state contains the following component (A) as an active ingredient.
  • the flavor enhancer in the present embodiment is preferably in the form of powder.
  • the flavor enhancer and the configuration thereof in the present embodiment will be described
  • the food in the present embodiment is a food that is eaten in the form of a paste or in a fluid state.
  • the paste-like food include kneaded wasabi, mustard, kneaded plum, kneaded sesame, and other kneaded foods derived from plant materials, and kneaded wasabi is preferable.
  • the kneaded food derived from a plant material may be a kneaded tube product filled in a tube container.
  • Specific examples of other pasty foods include fruit fillings such as ratatuille filling, curry filling, tuna filling, custard cream, chocolate cream, and apple filling, and ingredients such as ratatuiyu filling, curry filling, and apple filling.
  • a feeling of filling is preferable.
  • foods that are eaten in a fluid state include foods using ruu such as curry, hashed beef, and stew; pasta sauces such as carbonara sauce, cream sauce, and meat sauce, mabo tofu bean paste, Chinese beef, seasoning sauce, and dressing. , Mayonnaise, roasted meat sauce, pon vinegar, pot soup, sauces such as seasonings; soups such as ramen soup, consomme soup; jams such as strawberry jam, marmalade, jelly; soft food, thick food, mixer food, One selected from the group consisting of foods for people with swallowing difficulties such as liquid foods or nursing foods, and infant foods, preferably one selected from the group consisting of foods using ruu, sauces and soups.
  • the food is preferably one selected from the group consisting of roux-containing foods, sauces, soups, fillings and wasabi paste. It is also preferable that the food is one selected from the group consisting of curry, stew, pasta sauce, filling and wasabi paste.
  • the component (A) is a powder granule containing 75% by mass or more of starch.
  • the powdery granular material includes at least one of the powdery material and the granular material, and may include both the powdery material and the granular material.
  • the component (A) contains, as starch, low molecular weight starch having an amylose content of 5% by mass or more in the powder granules in an amount of 3% by mass or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3. ⁇ 10 3 or more and 5 ⁇ 10 4 or less, and the cold water swelling degree of the powdery granules at 25 ° C.
  • the content of the component (A) under the sieve of the sieve having an opening of 3.35 mm and on the sieve of the sieve having an opening of 0.038 mm is 50% by mass or more and 100% by mass or less.
  • the component (A) will be described in more detail.
  • the content of starch in the component (A) is 75% by mass or more, preferably 80% by mass or more, and more preferably 85% by mass or more, from the viewpoint of improving the flavor enhancing effect.
  • the upper limit of the starch content in the component (A) is not limited and is 100% by mass or less, but may be, for example, 99.5% by mass or less and 99% by mass or less depending on the properties of the food.
  • the component (A) as the starch, a low molecular weight starch made from starch having an amylose content of 5% by mass or more as a raw material is contained in a specific ratio, and a low molecular weight starch having a specific peak molecular weight is used. That is, the starch in the component (A) contains 3% by mass or more and 45% by mass or less of the low molecular weight starch made from starch having an amylose content of 5% by mass or more in the component (A), and the peak of the low molecular weight starch.
  • the molecular weight is 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less.
  • the peak molecular weight of the low molecular weight starch is 3 ⁇ 10 3 or more, preferably 8 ⁇ 10 3 or more, from the viewpoint of reducing an unfavorable texture and improving the flavor enhancing effect. From the same viewpoint, the peak molecular weight of the low molecular weight starch is 5 ⁇ 10 4 or less, preferably 3 ⁇ 10 4 or less, and more preferably 1.5 ⁇ 10 4 or less.
  • the method for measuring the peak molecular weight of starch after decomposition will be described in the section of Examples.
  • the low molecular weight starch is preferably one or more selected from the group consisting of acid-treated starch, oxidation-treated starch or enzyme-treated starch, and more preferably acid-treated, from the viewpoint of excellent production stability. It is starch.
  • the conditions of the acid treatment are not limited, but the treatment can be performed as follows, for example. After adding the starch having an amylose content of 5% by mass or more and water to the reaction apparatus, further acid is added. Alternatively, the acid water in which the acid is previously dissolved in water and the starch of the raw material are put into the reactor. From the viewpoint of more stable acid treatment, it is desirable that the total amount of starch in the reaction is uniformly dispersed in the aqueous phase or in a slurry state. For that purpose, the concentration of the starch slurry in the acid treatment is adjusted to be, for example, in the range of 10% by mass or more and 50% by mass or less, preferably 20% by mass or more and 40% by mass or less. If the slurry concentration is too high, the slurry viscosity may increase, making it difficult to stir a uniform slurry.
  • the acid used for the above acid treatment include inorganic acids such as hydrochloric acid, sulfuric acid, and nitric acid, which can be used regardless of the type and purity.
  • the acid concentration during the acid treatment for example, the acid concentration during the acid treatment.
  • 0.05 Normality (N) or more and 4N or less is preferable, 0.1N or more and 4N or less is more preferable, and 0.2N or more and 3N or less is further preferable.
  • the reaction temperature is preferably 30 ° C. or higher and 70 ° C. or lower, more preferably 35 ° C. or higher and 70 ° C. or lower, and even more preferably 35 ° C. or higher and 65 ° C. or lower.
  • the reaction time is preferably 0.5 hours or more and 120 hours or less, more preferably 1 hour or more and 72 hours or less, and further preferably 1 hour or more and 48 hours or less.
  • the content of the low molecular weight starch in the component (A) is 3% by mass or more and 8% by mass or more with respect to the entire component (A) from the viewpoint of reducing an unfavorable texture and improving the flavor enhancing effect. It is preferably 13% by mass or more, and more preferably 13% by mass or more.
  • the content of the low molecular weight starch in the component (A) is 45% by mass or less, preferably 35% by mass or less, preferably 25% by mass, based on the whole component (A) from the same viewpoint. The following is more preferable.
  • the amylose content in the raw material starch of the low molecular weight starch is 5% by mass or more, preferably 12% by mass or more, more preferably 22% by mass or more, still more preferably 45% by mass or more, still more preferably 55. By mass or more, more preferably 65% by mass or more.
  • the upper limit of the amylose content in the raw material starch of the low molecular weight starch is not limited and is 100% by mass or less, preferably 90% by mass or less, and more preferably 80% by mass or less.
  • starch having an amylose content of 5% by mass or more which is a raw material for low molecular weight starch, high amylose corn starch, corn starch, tapioca starch, sweet potato starch, horse belly starch, wheat starch, high amylose wheat starch, rice starch, green bean starch, pea starch, etc.
  • One or more selected from the group consisting of bean starch, sagoyashi starch, and processed starch obtained by chemically, physically or enzymatically processing these raw materials can be used.
  • High amylose cornstarch has an amylose content of 40% by mass or more and is available. Starch having an amylose content of 5% by mass or more is more preferably high amylose cornstarch having an amylose content of 40% by mass or more.
  • the degree of cold water swelling of the component (A) at 25 ° C. is 5 or more, preferably 5.5 or more, and more preferably 6 or more from the viewpoint of improving the flavor enhancing effect. Further, from the viewpoint of reducing an unfavorable texture and improving the flavor enhancing effect, the degree of cold water swelling of the component (A) at 25 ° C. is 20 or less, preferably 17 or less, more preferably 15 or less, still more preferably. Is 13 or less.
  • the degree of cold water swelling of the component (A) at 25 ° C. is measured by the following method. (1) The sample is heated and dried at 125 ° C.
  • the content of the component (A) under the sieve with a mesh size of 3.35 mm and on the sieve with a mesh size of 0.038 mm according to the JIS-Z8801-1 standard is 50 mass from the viewpoint of improving the flavor enhancing effect. % Or more, preferably 60% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more.
  • the content of the component (A) under the sieve with a mesh size of 3.35 mm and on the sieve with a mesh size of 0.038 mm according to the JIS-Z8801-1 standard is 100% by mass or less from the same viewpoint. , 99% by mass or less.
  • the content of the fraction on or under the sieve is the content of the fraction with respect to the entire component (A).
  • the content of the component (A) under the sieve of the 3.35 mm sieve and on the sieve of the sieve with the opening of 0.15 mm in the sieve of JIS-Z8801-1 standard is the flavor enhancement of the texture, the melting in the mouth and the content and aftertaste. From the viewpoint of improving the effect, for example, it is 30% by mass or more, preferably 40% by mass or more, more preferably 50% by mass or more, still more preferably 60% by mass or more, still more preferably 65% by mass or more. ..
  • the content of the component (A) under the sieve of the 3.35 mm sieve and on the sieve of the sieve having a mesh size of 0.15 mm in the sieve of JIS-Z8801-1 standard is from the viewpoint of improving the flavor enhancing effect of the taste. It is preferably 95% by mass or less, more preferably 92% by mass or less, still more preferably 88% by mass or less, and even more preferably 85% by mass or less.
  • starches can be used as the starch component other than the above-mentioned low molecular weight starch in the component (A).
  • any type of starch that is generally commercially available depending on the intended use, for example, starch for food is not limited, and for example, corn starch such as high amylose corn starch, corn starch, waxy corn starch, tapioca starch, and sweet potato.
  • corn starch such as high amylose corn starch, corn starch, waxy corn starch, tapioca starch, and sweet potato.
  • corn starch such as high amylose corn starch, corn starch, waxy corn starch, tapioca starch, and sweet potato.
  • wheat starch high amylose wheat starch, rice starch, bean starch such as green bean starch and pea starch, sagoyashi starch and processed starch obtained by chemically, physically or enzymatically processing these starches, etc. 1 You can choose more than seeds as appropriate.
  • the starch component other than the low molecular weight starch in the component (A) is preferably one or more selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and processed starch thereof. It contains starch, more preferably cornstarch, and even more preferably cornstarch.
  • the component (A) in the present embodiment may contain a component other than starch.
  • the components other than the starch include insoluble salts such as calcium carbonate and calcium sulfate, emulsifiers, pigments and the like, and it is preferable to add the insoluble salt, and the amount of the insoluble salt is 0.1% by mass. It is more preferably 2% by mass or less.
  • the emulsifier includes, for example, an emulsifier for food.
  • an emulsifier for food sucrose fatty acid ester, monoglycerin fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, acetate monoglyceride, lactic acid monoglyceride, citric acid monoglyceride, succinic acid monoglyceride, polysorbate, sorbitan fatty acid.
  • Nonionic surfactants such as esters, diacetyl tartrate monoglycerides; anionic surfactants; and amphoteric surfactants such as lecithin can be mentioned.
  • the emulsifier is preferably a nonionic surfactant, more preferably one or more selected from sucrose fatty acid ester and monoglycerin fatty acid ester, and further preferably monoglycerin fatty acid ester.
  • the content of the emulsifier in the component (A) is, for example, 0.5% by mass or more, preferably 0.6% by mass or more, and more preferably 0.9% by mass or more with respect to the entire component (A). ..
  • the content of the emulsifier in the component (A) is, for example, 11% by mass or less, preferably 9% by mass or less, and more preferably 6% by mass or less with respect to the entire component (A).
  • the method for producing the component (A) includes, for example, the following steps.
  • Step of preparing low molecular weight starch A step of reducing the molecular weight of raw material starch having an amylose content of 5% by mass or more to obtain a low molecular weight starch having a peak molecular weight of 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less.
  • Granulation step The raw material contains 3% by mass or more and 45% by mass or less of low-molecular-weight starch, and the total amount of low-molecular-weight starch and starch other than low-molecular-weight starch is 75% by mass or more.
  • the process of granulating The process of granulating.
  • the step of preparing low molecular weight starch is a step of decomposing starch having an amylose content of 5% by mass or more into low molecular weight starch.
  • the decomposition referred to here refers to decomposition accompanied by a reduction in the molecular weight of starch, and typical decomposition methods include decomposition by acid treatment, oxidation treatment, and enzyme treatment. Among these, acid treatment is preferable from the viewpoint of decomposition rate, cost, and reproducibility of decomposition reaction.
  • a general method used for granulating starch can be used, but it is generally used for heat gelatinization of starch in terms of achieving a predetermined degree of swelling in cold water. It is preferable to use the above method.
  • a method using a machine such as a drum dryer, a jet cooker, an extruder, or a spray dryer is known, but in the present embodiment, the component (A) in which the degree of swelling of cold water satisfies the above-mentioned specific condition. From the viewpoint of more reliably obtaining the above, heat gelatinization with an extruder or a drum dryer is preferable, and an extruder is more preferable.
  • extruder treatment usually, after adding water to a raw material containing starch to adjust the water content to about 10 to 60% by mass, for example, a barrel temperature of 30 to 200 ° C., an outlet temperature of 80 to 180 ° C., and a screw rotation speed of 100 to 100 to It is heated and expanded under the conditions of 1,000 rpm and a heat treatment time of 5 to 60 seconds.
  • the component (A) whose cold water swelling degree satisfies a specific condition can be obtained. Further, the granulated product obtained by heat gelatinization may be pulverized and sieved, if necessary, and the size thereof may be appropriately adjusted to obtain the component (A).
  • the component (A) obtained as described above is a powder granule containing low molecular weight starch, and the starch content, the degree of swelling in cold water, and the peak molecular weight of the low molecular weight starch all satisfy specific conditions. Therefore, by blending the flavor enhancer containing the component (A) into the food to be eaten in the form of a paste or in a fluid state, the unfavorable texture of the food can be reduced and the flavor enhancing effect can be improved.
  • the flavor enhancer in the present embodiment may contain a component other than the component (A).
  • a component other than the component (A) it is preferable to contain a powdery component.
  • the components other than the component (A) include unprocessed starch (raw starch), starches other than the component (A) such as processed starch; flour such as wheat flour; thickening polysaccharides such as xanthan gum; sugars; powdered form. Seasonings; emulsifiers and the like.
  • the content of the component (A) in the flavor enhancing agent in the present embodiment is preferably 40% by mass or more, more preferably 60% by mass or more, based on the whole flavor enhancing agent. , More preferably 70% by mass or more, still more preferably 80% by mass or more, and even more preferably 85% by mass or more. From the same viewpoint, the content of the component (A) in the flavor enhancer in the present embodiment is preferably 100% by mass or less, and may be 99% by mass or less.
  • the blending amount of the flavor enhancing agent in the food in the present embodiment is preferably 0.1% by mass or more, more preferably 0, with respect to the total amount of the food and the flavor enhancing agent. It is 0.4% by mass or more, more preferably 0.8% by mass or more. From the same viewpoint, the blending amount of the flavor enhancer in the food in the present embodiment is preferably 15% by mass or less, more preferably 10% by mass or less, still more preferably, with respect to the total amount of the food and the flavor enhancer. Is 8% by mass or less, more preferably 6% by mass or less, even more preferably 4.8% by mass or less, and particularly preferably 2.8% by mass or less.
  • the content of the component (A) in the food in the present embodiment is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, still more preferably 0, from the viewpoint of improving the flavor enhancing effect. It is 6.6% by mass or more. From the same viewpoint, the content of the flavor enhancer in the food in the present embodiment is preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 4% by mass or less, still more preferably 2 It is 4% by mass or less.
  • the flavor enhancer contains the component (A) as an effective component, it is possible to obtain, for example, a food in which at least one of the first taste, the middle taste and the aftertaste is enhanced. Further, according to the present embodiment, for example, it is possible to obtain a food having a good texture such as texture and melting in the mouth.
  • the method for producing a food product includes, for example, a step of blending a flavor enhancer into a food material.
  • the food material may be a raw material of food before cooking and a mixture thereof, and may contain ingredients, seasonings and the like. Examples of the ingredients include agricultural and marine products, and more specifically, fruits and vegetables such as vegetables and fruits; meats such as poultry and livestock meat; fish and shellfish such as fish, shellfish, shrimp, and crabs.
  • the food material may be a cooked material such as curry, hashed beef, stew, mapo tofu bean paste, soup, pasta sauce, filling, and kneaded wasabi.
  • the method for producing a food product includes, for example, a step of blending a flavor enhancer into a food material.
  • the method of blending the flavor enhancer into the food material is not limited.
  • the powdered wasabi which is the food material, is put into a bowl together with the flavor enhancer and water, and mixed with a mixer or the like to prepare the food. You can get kneaded wasabi.
  • the timing of adding the flavor enhancer and other raw materials is not limited, and the flavor enhancer may be added to the cooked wasabi.
  • a flavor enhancer may be added to the cooked food material to obtain the food, or a mixture of the food material and the flavor enhancer may be subjected to a cooking step. good.
  • cooking in the cooking process include baking, boiling, microwave oven heating, steaming, steam convection heating, and oil shavings.
  • the method for producing a food may include a step of heat-pressurizing treatment (for example, retort treatment), and more specifically, after a step of blending a flavor enhancer into a food material, the temperature is 100 ° C. to 130 ° C.
  • a step of performing a pressure heat treatment at 0.206 MPa for 1 to 60 minutes may be further included.
  • a room temperature storage step there may be a room temperature storage step, a room temperature retort storage step, a frozen storage step, or a refrigerated storage step before eating.
  • a reheating step at the time of eating.
  • the method of reheating for example, the same method as mentioned in the above-mentioned cooking can be applied.
  • the method for enhancing the flavor of a food product according to the present embodiment includes a step of applying a flavor enhancing agent containing the ingredient (A) as an active ingredient to a food product to be eaten in the form of a paste or in a fluid state.
  • the method for enhancing the flavor of the food is preferably a method for enhancing the flavor of the aftertaste. By enhancing the flavor of the aftertaste, it is also possible to add richness to the flavor of the food as a result.
  • the mixture was neutralized with 3% NaOH, washed with water, dehydrated and dried to obtain acid-treated high amylose cornstarch.
  • the peak molecular weight of the resulting acid-treated high-amylose cornstarch was measured by the following method, the peak molecular weight was 1.2 ⁇ 10 4.
  • the peak molecular weight was measured using an HPLC unit manufactured by Tosoh Corporation (pump DP-8020, RI detector RS-8021, degassing device SD-8022).
  • the sample was pulverized, and the fraction under the sieve with an opening of 0.15 mm was collected with a sieve of JIS-Z8801-1 standard.
  • the recovered fraction was suspended in the mobile phase at 1 mg / mL, and the suspension was heated at 100 ° C. for 3 minutes to completely dissolve it. Filtration was performed using a 0.45 ⁇ m filtration filter (DISMIC-25HP PTFE 0.45 ⁇ m manufactured by ADVANTEC), and the filtrate was used as an analysis sample.
  • Production Example 2 Production of powder granules 1 to 3 Cornstarch 79% by mass, acid-treated high amylose cornstarch 20% by mass obtained in Production Example 1, and calcium carbonate 1% by mass in a bag until sufficiently uniform. Mixed in. The mixture was pressure-heated using a twin-screw extruder (KEI-45 manufactured by Kowa Kogyo Co., Ltd.). The processing conditions are as follows. Raw material supply: 340 g / min Water: 20% by mass Barrel temperature: 50 ° C, 70 ° C, 100 ° C and 130 ° C from the raw material inlet to the outlet.
  • a flavor enhancer or other starch was added to a commercially available curry in the formulation shown in Table 3 and mixed.
  • the following procedure was performed without adding them.
  • 1. A commercially available retort curry (Miyagi Flour Milling Co., Ltd., adult large-sized curry (restaurant specification) 250 g) was opened and transferred to a bowl, and the curry ingredients were strained with a 1.2 mm mesh to obtain curry sauce. After that, 250 g of curry sauce was measured in a beaker. To this, the flavor enhancer and other starches were added so as to have the concentrations shown in Table 3, and the mixture was stirred well so as to be uniformly dispersed to obtain a mixture. 2. 2. Above 1.
  • the mixture obtained in 1) was filled in a transparent seal bag for retort and sealed. This was placed in a retort food autoclave (HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.) and heat-treated under pressure at 121 ° C. for 30 minutes. After pressure heat treatment, the seal bag was removed from the retort food autoclave and cooled to room temperature. 3. 3. 200 g of each obtained curry sample was transferred to a 200 mL tall beaker, wrapped for food, and bathed in a water bath heated to 60 ° C. to obtain curry as a food of each example.
  • HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.
  • the flavor-enhancing agents of each example containing the ingredient (A) as an active ingredient all showed an excellent flavor-enhancing effect. It was also good in mouthfeel and melting.
  • the particle size of the component (A) is 98.8% by mass under the mesh with an opening of 3.35 mm and on a sieve with a mesh of 0.038 mm, and the content is under a sieve with a mesh of 3.35 mm and on a sieve with a mesh of 0.15 mm.
  • the content of was 81.8% by mass, it was more excellent in terms of enhancing the flavor of the content and aftertaste, as well as the texture and melting in the mouth.
  • the richness of the curry was increased by enhancing the flavors of the content and aftertaste.
  • the content under the mesh of 3.35 mm and on the sieve of 0.038 mm is 98.7% by mass, and the content on the sieve of 3.35 mm and 0.15 mm is 75.0 mass.
  • the flavor of the first taste was further enhanced.
  • Comparative Examples 1 and 2 to which other starches were added were inferior to the flavor-enhancing agents of Examples in the flavor-enhancing effect, had a paste-like texture, and had a texture such as liquid texture and melting in the mouth. Was also unfavorable.
  • Example 3-1 (Test with wasabi paste) (Example 3-1 and control example 3)
  • a flavor enhancer was applied to kneaded wasabi.
  • Example 3-1 Manufacturing of wasabi paste
  • Water was added to powdered wasabi (manufactured by S & B, powdered wasabi) to prepare a base wasabi base, which was used as the kneaded wasabi of Control Example 3.
  • the component (A) powder granule 1 was added as a flavor enhancer and mixed.
  • Table 6 The materials and formulations of each example are shown in Table 6.
  • the kneaded wasabi to which the flavor enhancer of the example was applied had a pungent taste like wasabi as compared with the control example 3 even after 7 days of refrigerated storage, and the flavor was enhanced.
  • a pie with a filling was produced by the following procedure according to the formulation shown in Table 7. 1.
  • a flavor enhancer was placed in a commercially available ratatouille filling (ratatouille for commercial use, manufactured by Tanaka Foods Co., Ltd.), placed in a bowl and mixed evenly to prepare a mixture.
  • Above Place 30 g of the mixture prepared in step 1 on a thawed pie sheet (Oh my pie sheet, manufactured by Nippon Flour Mills Co., Ltd.) with the long side cut in half, cover it with a pie sheet of the same size from above, press the circumference with a fork, and center it. I made three notches. It was baked in a preheated oven at 220 ° C.
  • Example 4 In the filling to which the flavor enhancer of the example was applied (Examples 4-1 and 4-2), the control containing no flavor enhancer in any of the cases of room temperature storage, natural thawing after freezing storage, and reheating after freezing storage. Compared with Example 4, the filling flavor was enhanced. Further, even when xanthan gum was used in combination with the flavor enhancing agent, a flavor enhancing effect was observed (Example 4-2).
  • Mapo tofu was prepared and evaluated using a flavor enhancer consisting of powdery granule 1.
  • the proportions listed in Table 8 were weighed and mixed uniformly in a bowl. The obtained mixture was filled in a transparent seal bag for retort and sealed. This was placed in a retort food autoclave (HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.) and heat-treated under pressure at 121 ° C. for 30 minutes. After pressure heat treatment, the seal bag was removed from the retort food autoclave and cooled to room temperature.
  • HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.
  • Each of the obtained mapo tofu raw samples was stored in a constant temperature bath (LHL-114 type manufactured by Espec Co., Ltd.) set at 44 ° C. and 78% for 2 weeks.
  • Two expert panelists evaluated how to feel the flavor of the mapo tofu sample obtained in each example. The evaluation results are also shown in Table 8.
  • Example 6-1 and 6-2 control example 6
  • a curry was prepared and evaluated using a flavor enhancer composed of powder granule 1 or powder granule 4.
  • a flavor enhancer was added to a commercially available curry in the formulation shown in Table 9 and mixed.
  • the following procedure was performed without adding them. 1.
  • a commercially available retort curry (Miyagi Flour Milling Co., Ltd., adult large-sized curry (restaurant specification) 250 g) was opened and transferred to a bowl, and the curry ingredients were strained with a 1.2 mm mesh to obtain curry sauce. After that, 250 g of curry sauce was measured in a beaker.
  • the flavor enhancer and Garam Masada (manufactured by S & B Foods Co., Ltd.) were added so as to have the concentrations shown in Table 9, and the mixture was stirred well so as to be uniformly dispersed to obtain a mixture.
  • the mixture obtained in 1) was filled in a transparent seal bag for retort and sealed. This was placed in a retort food autoclave (HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.) and heat-treated under pressure at 121 ° C. for 30 minutes. After the pressure heat treatment, the seal bag was taken out from the retort food autoclave and stored at 24 ° C. for 90 days.
  • a ramen soup was prepared and evaluated according to the formulation shown in Table 10 using a flavor enhancer composed of powder granules 4.
  • Preparation of ramen soup 1. 1. Lard, grated garlic, grated ginger and flavor enhancer were added to a frying pan and fried for 40 seconds, then minced pork and doubanjiang were added and fried until the color of the minced pork changed. 2.1. Water, chicken glass soup granules, soy sauce, and miso were added to the mixture and boiled down to a boil to obtain miso ramen soup as a food in each example. Ten professional panelists evaluated how to feel the flavor of the ramen soup sample obtained in each example. The evaluation results are also shown in Table 10.

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Abstract

A flavor enhancer for food consumed as a paste or a fluid state, the flavor enhancer containing a component (A) of the following description as an active ingredient: (1) the starch content is 75 mass% or above; (2) there is included 3 to 45 mass% inclusive of a low molecular weight starch of a starch having an amylose content of 5 mass% or above, the peak molecular weight of the low molecular weight starch being 3 × 103 to 5 × 104 inclusive; (3) the degree of swelling in cold water at 25°C is 5 to 20 inclusive; and (4) the contained amount of a fraction that is not captured by a sieve having a mesh of 3.35 mm and is captured by a sieve having a mesh of 0.038 mm is 50 to 100 mass% inclusive.

Description

風味増強剤Flavor enhancer
 本発明は、食品の風味増強剤に関する。 The present invention relates to a food flavor enhancer.
 近年、食の嗜好はますます多様化し、より美味しいものへのニーズが高まっている。そんな中、食品の風味を増強させることができる技術には食品業界等からの関心が集まっている。 In recent years, food tastes have become more diverse, and the need for more delicious foods has increased. Meanwhile, the food industry and others are paying attention to technologies that can enhance the flavor of food.
 特許文献1にはグルコース重合度(DP)3~19の含量が70~88%、かつ、グルコース重合度(DP)8~12の含量が12~28%の澱粉分解物が開示されており、当該澱粉分解物は、構成する糖の分子量分布が特定の範囲に集約されていることにより、甘味度、味質、浸透圧、粘度、吸湿性等の基本的物性のバランスに優れ、風味増強効果を有しているとされている。 Patent Document 1 discloses a starch decomposition product having a glucose polymerization degree (DP) of 3 to 19 of 70 to 88% and a glucose polymerization degree (DP) of 8 to 12 of 12 to 28%. The starch decomposition product has an excellent balance of basic physical properties such as sweetness, taste, osmotic pressure, viscosity, and hygroscopicity because the molecular weight distribution of the constituent sugars is concentrated in a specific range, and has an effect of enhancing flavor. Is said to have.
 特許文献2には、調味油と、澱粉含量が75質量%以上であり、澱粉として、アミロース含量5質量%以上である澱粉の低分子化澱粉を当該組成物中3質量%以上45質量%以下含み、低分子化澱粉のピーク分子量が3×10以上5×10以下であり、25℃における当該組成物の冷水膨潤度が5以上20以下であり、当該組成物中の目開き3.35mmの篩の篩下かつ目開き0.038mmの篩の篩上の含有量が60質量%以上100質量%以下である成分(A)とを混合して混合物を得る工程と、混合物を食品素材に配合し、食品組成物を得る工程と、を含む食品の製造方法が開示されており、これにより調味油の風味が増強された食品を得ることができるとされている。 Patent Document 2 describes seasoning oil and low-molecular-weight starch of starch having a starch content of 75% by mass or more and an amylose content of 5% by mass or more as starch in the composition of 3% by mass or more and 45% by mass or less. 3. The peak molecular weight of the low-molecular-weight starch is 3 × 10 3 or more and 5 × 10 4 or less, the cold water swelling degree of the composition at 25 ° C. is 5 or more and 20 or less, and the opening in the composition is 3. A step of mixing a component (A) having a content of 60% by mass or more and 100% by mass or less on a sieve having a mesh size of 0.038 mm and under a 35 mm sieve to obtain a mixture, and using the mixture as a food material. Disclosed is a step of obtaining a food composition by blending with the starch, and a method for producing a food containing the starch, which is said to be able to obtain a food having an enhanced flavor of seasoning oil.
特開2010-229234公報JP-A-2010-229234 国際公開第2020/027001公報International Publication No. 2020/027001
 しかしながら、特許文献1の方法では、当該澱粉分解物はそれ自体が甘みを有しているため、適用できる食品の範囲が制限されるという点で改善の余地があった。
 また、特許文献2の製造方法は、調味油と特定の成分を混合することで調味油の風味を増強する食品を得ることができるが、該成分をそのまま添加することでペースト状あるいは流動状態で喫食される食品そのものの風味を増強できることは開示も示唆もされていない。
However, in the method of Patent Document 1, since the starch decomposition product itself has sweetness, there is room for improvement in that the range of applicable foods is limited.
Further, in the production method of Patent Document 2, a food product that enhances the flavor of the seasoning oil can be obtained by mixing the seasoning oil and a specific component, but by adding the component as it is, a paste or a fluid state can be obtained. It is neither disclosed nor suggested that the flavor of the food itself to be eaten can be enhanced.
 そこで、本発明者等が鋭意検討したところ、ペースト状あるいは流動状態で喫食される食品において、特定の成分を含有させることで、該食品の風味を増強できることを見出し、本発明を完成させた。 Therefore, as a result of diligent studies by the present inventors, it was found that the flavor of the food can be enhanced by containing a specific component in the food to be eaten in the form of a paste or in a fluid state, and the present invention has been completed.
 すなわち、本発明によれば、以下のペースト状あるいは流動状態で喫食される食品の風味増強剤、ペースト状あるいは流動状態で喫食される食品の製造方法、ペースト状あるいは流動状態で喫食される食品の風味増強方法が提供される。
[1]
 ペースト状あるいは流動状態で喫食される食品の風味増強剤であって、
 以下の成分(A)を有効成分として含む、風味増強剤。
 成分(A):以下の条件(1)~(4)を満たす粉粒状物
 (1)澱粉含量が75質量%以上
 (2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×10以上5×10以下
 (3)25℃における冷水膨潤度が5以上20以下
 (4)目開き3.35mmの篩の篩下かつ目開き0.038mmの篩の篩上の含有量が50質量%以上100質量%以下
[2]
 前記成分(A)を当該風味増強剤全体に対して40質量%以上100質量%以下含有する、[1]に記載の風味増強剤。
[3]
 当該風味増強剤の前記食品への配合量が、前記食品および当該風味増強剤の合計量の0.1質量%以上15質量%以下である、[1]または[2]に記載の風味増強剤。
[4]
 前記食品が、ルウ使用食品、ソース類、スープ類、フィリングおよび練りわさびからなる群から選ばれる1種である、[1]乃至[3]いずれか1つに記載の風味増強剤。
[5]
 前記成分(A)の目開き3.35mmの篩の篩下かつ目開き0.15mmの篩の篩上の含有量が40質量%以上95質量%以下である、[1]乃至[4]いずれか1つに記載の風味増強剤。
[6]
 [1]乃至[5]いずれか1つに記載の風味増強剤を食品素材に配合する工程を含む、食品の製造方法。
[7]
 [1]乃至[5]いずれか1つに記載の風味増強剤を前記食品に適用する工程を含む、食品の風味増強方法。
[8]
 当該風味増強方法が、後味の風味増強方法である、[7]に記載の風味増強方法。
That is, according to the present invention, the following flavor enhancer for foods eaten in paste form or fluid state, method for producing foods eaten in paste form or fluid state, foods eaten in paste form or fluid state A method for enhancing flavor is provided.
[1]
A flavor enhancer for foods that are eaten in paste or fluid form.
A flavor enhancer containing the following ingredient (A) as an active ingredient.
Ingredient (A): Powder granules satisfying the following conditions (1) to (4) (1) Starch content of 75% by mass or more (2) 3% by mass of low-molecular-weight starch of starch having an amylose content of 5% by mass or more % Or more and 45% by mass or less, and the peak molecular weight of the low-molecular-weight starch is 3 × 10 3 or more and 5 × 10 4 or less. The content of the starch under the sieve and on the sieve with an opening of 0.038 mm is 50% by mass or more and 100% by mass or less [2].
The flavor enhancer according to [1], which contains the component (A) in an amount of 40% by mass or more and 100% by mass or less with respect to the entire flavor enhancer.
[3]
The flavor enhancer according to [1] or [2], wherein the amount of the flavor enhancer blended in the food is 0.1% by mass or more and 15% by mass or less of the total amount of the food and the flavor enhancer. ..
[4]
The flavor enhancer according to any one of [1] to [3], wherein the food is one selected from the group consisting of roux-containing foods, sauces, soups, fillings and wasabi paste.
[5]
The content of the component (A) under the sieve with a mesh size of 3.35 mm and on the sieve with a mesh size of 0.15 mm is 40% by mass or more and 95% by mass or less, any of [1] to [4]. The flavor enhancer according to one.
[6]
[1] A method for producing a food, which comprises a step of blending the flavor enhancer according to any one of [1] to [5] into a food material.
[7]
[1] A method for enhancing the flavor of a food, which comprises a step of applying the flavor enhancing agent according to any one of [1] to [5] to the food.
[8]
The flavor enhancing method according to [7], wherein the flavor enhancing method is an aftertaste flavor enhancing method.
 なお、これらの各構成の任意の組み合わせや、本発明の表現を方法、装置などの間で変換したものもまた本発明の態様として有効である。 It should be noted that any combination of these configurations and the conversion of the expression of the present invention between methods, devices and the like are also effective as aspects of the present invention.
 本発明によれば、風味が増強された食品を得ることができる。 According to the present invention, it is possible to obtain a food having an enhanced flavor.
 以下、本発明の実施の形態について、各成分の具体例を挙げて説明する。なお、数値範囲の「~」は、断りがなければ、以上から以下を表し、両端の数値をいずれも含む。また、各成分はいずれも単独でまたは2種以上を組み合わせて用いることができる。
 また、本明細書において、風味増強とは、本実施形態の風味増強剤を適用しない場合と比べて、その食品の風味がより強く感じられることをいう。また増強される風味とは、食品全体が持つ風味のことであり、たとえば、食品の塩味、旨味、甘味、酸味、苦味、辛み等の味、および食品の香りの組み合せである。
Hereinafter, embodiments of the present invention will be described with reference to specific examples of each component. Unless otherwise specified, "-" in the numerical range indicates the following from the above, and includes all the numerical values at both ends. In addition, each component can be used alone or in combination of two or more.
Further, in the present specification, the flavor enhancing means that the flavor of the food is felt more strongly than in the case where the flavor enhancing agent of the present embodiment is not applied. The enhanced flavor is the flavor of the whole food, for example, a combination of salty taste, umami, sweetness, sourness, bitterness, pungent taste, and the aroma of the food.
(風味増強剤)
 本実施形態において、ペースト状あるいは流動状態で喫食される食品の風味増強剤は、以下の成分(A)を有効成分として含む。
 成分(A):以下の条件(1)~(4)を満たす粉粒状物
 (1)澱粉含量が75質量%以上
 (2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、低分子化澱粉のピーク分子量が3×10以上5×10以下
 (3)25℃における冷水膨潤度が5以上20以下
 (4)目開き3.35mmの篩の篩下かつ目開き0.038mmの篩の篩上の含有量が50質量%以上100質量%以下
 ここで、本実施形態における風味増強剤は、好ましくは粉末状である。
 以下、本実施形態における風味増強剤とそれにかかる構成について説明する。
(Flavor enhancer)
In the present embodiment, the flavor-enhancing agent for foods eaten in the form of a paste or in a fluid state contains the following component (A) as an active ingredient.
Ingredient (A): Powder granules satisfying the following conditions (1) to (4) (1) Starch content of 75% by mass or more (2) 3% by mass of low molecular weight starch of starch having an amylose content of 5% by mass or more % Or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3 × 10 3 or more and 5 × 10 4 or less (3) Cold water swelling degree at 25 ° C is 5 or more and 20 or less (4) A sieve with an opening of 3.35 mm The content on the sieve of a sieve having an opening of 0.038 mm and under the sieve is 50% by mass or more and 100% by mass or less. Here, the flavor enhancer in the present embodiment is preferably in the form of powder.
Hereinafter, the flavor enhancer and the configuration thereof in the present embodiment will be described.
(食品)
 本実施形態における食品は、ペースト状あるいは流動状態で喫食される食品である。
 ペースト状食品の具体例として、練りわさび、練り辛子、練り梅、練りごま等の植物素材由来の練り食品が挙げられ、好ましくは練りわさびである。植物素材由来の練り食品は、チューブ容器に充填されてなる練りチューブ製品であってもよい。
 また、その他のペースト状食品の具体例として、ラタトゥイユフィリング、カレーフィリング、ツナフィリング、カスタードクリーム、チョコレートクリーム、アップルフィリングなどのフルーツフィリング等が挙げられ、ラタトゥイユフィリング、カレーフィリングおよびアップルフィリング等の具材感のあるフィリングが好ましい。
 流動状態で喫食される食品の具体例としては、カレー、ハッシュドビーフ、シチュー等のルウ使用食品;カルボナーラソース、クリームソース、ミートソース等のパスタソース、麻婆豆腐の餡、中華餡、シーズニングソース、ドレッシング、マヨネーズ、焼き肉のタレ、ポン酢、鍋つゆ、合わせ調味料等のソース類;ラーメンスープ、コンソメスープ等のスープ類;イチゴジャム、マーマレード、ゼリー等のジャム類;ソフト食、とろみ食、ミキサー食、流動食等の嚥下困難者用食品または介護食、および乳児食からなる群から選択される1種が挙げられ、好ましくはルウ使用食品、ソース類およびスープ類からなる群から選択される1種であり、より好ましくはルウ使用食品およびソース類からなる群から選択される1種であり、さらに好ましくはカレーおよび麻婆豆腐の餡からなる群から選択される1種である。
 食品は、好ましくはルウ使用食品、ソース類、スープ類、フィリングおよび練りわさびからなる群から選ばれる1種である。また、食品が、カレー、シチュー、パスタソース、フィリングおよび練りわさびからなる群から選ばれる1種であることも好ましい。
(Food)
The food in the present embodiment is a food that is eaten in the form of a paste or in a fluid state.
Specific examples of the paste-like food include kneaded wasabi, mustard, kneaded plum, kneaded sesame, and other kneaded foods derived from plant materials, and kneaded wasabi is preferable. The kneaded food derived from a plant material may be a kneaded tube product filled in a tube container.
Specific examples of other pasty foods include fruit fillings such as ratatuille filling, curry filling, tuna filling, custard cream, chocolate cream, and apple filling, and ingredients such as ratatuiyu filling, curry filling, and apple filling. A feeling of filling is preferable.
Specific examples of foods that are eaten in a fluid state include foods using ruu such as curry, hashed beef, and stew; pasta sauces such as carbonara sauce, cream sauce, and meat sauce, mabo tofu bean paste, Chinese beef, seasoning sauce, and dressing. , Mayonnaise, roasted meat sauce, pon vinegar, pot soup, sauces such as seasonings; soups such as ramen soup, consomme soup; jams such as strawberry jam, marmalade, jelly; soft food, thick food, mixer food, One selected from the group consisting of foods for people with swallowing difficulties such as liquid foods or nursing foods, and infant foods, preferably one selected from the group consisting of foods using ruu, sauces and soups. There is, more preferably one selected from the group consisting of foods containing ruu and sauces, and even more preferably one selected from the group consisting of curry and mabo tofu.
The food is preferably one selected from the group consisting of roux-containing foods, sauces, soups, fillings and wasabi paste. It is also preferable that the food is one selected from the group consisting of curry, stew, pasta sauce, filling and wasabi paste.
(成分(A))
 成分(A)は、澱粉を75質量%以上含む粉粒状物である。ここで、粉粒状物とは、粉状物および粒状物のうち少なくとも一方を含むものであり、粉状物および粒状物の両方を含むものであってもよい。
 そして、成分(A)は、澱粉として、アミロース含量5質量%以上である澱粉の低分子化澱粉を粉粒状物中に3質量%以上45質量%以下含み、低分子化澱粉のピーク分子量が3×10以上5×10以下であって、25℃における粉粒状物の冷水膨潤度が5以上20以下である。さらに成分(A)は、目開き3.35mmの篩の篩下かつ目開き0.038mmの篩の篩上の含有量が50質量%以上100質量%以下である。
 以下、成分(A)についてさらに具体的に説明する。
(Ingredient (A))
The component (A) is a powder granule containing 75% by mass or more of starch. Here, the powdery granular material includes at least one of the powdery material and the granular material, and may include both the powdery material and the granular material.
The component (A) contains, as starch, low molecular weight starch having an amylose content of 5% by mass or more in the powder granules in an amount of 3% by mass or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3. × 10 3 or more and 5 × 10 4 or less, and the cold water swelling degree of the powdery granules at 25 ° C. is 5 or more and 20 or less. Further, the content of the component (A) under the sieve of the sieve having an opening of 3.35 mm and on the sieve of the sieve having an opening of 0.038 mm is 50% by mass or more and 100% by mass or less.
Hereinafter, the component (A) will be described in more detail.
 成分(A)中の澱粉の含有量は風味増強効果を向上させる観点から、75質量%以上であり、80質量%以上とすることが好ましく、85質量%以上とすることがさらに好ましい。
 また、成分(A)中の澱粉含量の上限に制限はなく、100質量%以下であるが、食品の性状等に応じてたとえば99.5質量%以下、99質量%以下としてもよい。
The content of starch in the component (A) is 75% by mass or more, preferably 80% by mass or more, and more preferably 85% by mass or more, from the viewpoint of improving the flavor enhancing effect.
The upper limit of the starch content in the component (A) is not limited and is 100% by mass or less, but may be, for example, 99.5% by mass or less and 99% by mass or less depending on the properties of the food.
 また、成分(A)は、上記澱粉として、アミロース含量5質量%以上の澱粉を原料とする低分子化澱粉を特定の割合で含み、低分子化澱粉として特定のピーク分子量のものが用いられる。すなわち、成分(A)中の澱粉が、アミロース含量5質量%以上の澱粉を原料とする低分子化澱粉を成分(A)中に3質量%以上45質量%以下含み、低分子化澱粉のピーク分子量が3×10以上5×10以下である。 Further, as the component (A), as the starch, a low molecular weight starch made from starch having an amylose content of 5% by mass or more as a raw material is contained in a specific ratio, and a low molecular weight starch having a specific peak molecular weight is used. That is, the starch in the component (A) contains 3% by mass or more and 45% by mass or less of the low molecular weight starch made from starch having an amylose content of 5% by mass or more in the component (A), and the peak of the low molecular weight starch. The molecular weight is 3 × 10 3 or more and 5 × 10 4 or less.
 低分子化澱粉のピーク分子量は、好ましくない食感を低減し、風味増強効果を向上させる観点から、3×10以上であり、8×10以上とすることが好ましい。また、低分子化澱粉のピーク分子量は、同様の観点から、5×10以下であり、3×10以下とすることが好ましく、1.5×10以下とすることがさらに好ましい。なお、分解後の澱粉のピーク分子量の測定方法については、実施例の項に記載する。 The peak molecular weight of the low molecular weight starch is 3 × 10 3 or more, preferably 8 × 10 3 or more, from the viewpoint of reducing an unfavorable texture and improving the flavor enhancing effect. From the same viewpoint, the peak molecular weight of the low molecular weight starch is 5 × 10 4 or less, preferably 3 × 10 4 or less, and more preferably 1.5 × 10 4 or less. The method for measuring the peak molecular weight of starch after decomposition will be described in the section of Examples.
 低分子化澱粉は、その製造安定性に優れる観点から、好ましくは、酸処理澱粉、酸化処理澱粉または酵素処理澱粉からなる群から選択される1種または2種以上であり、より好ましくは酸処理澱粉である。 The low molecular weight starch is preferably one or more selected from the group consisting of acid-treated starch, oxidation-treated starch or enzyme-treated starch, and more preferably acid-treated, from the viewpoint of excellent production stability. It is starch.
 上記酸処理の条件は、問わないが、例えば、以下のように処理することができる。
 上記アミロース含量5質量%以上の澱粉と水を反応装置に投入した後、さらに酸を投入する。あるいは水に酸をあらかじめ溶解させた酸水と原料の澱粉を反応装置に投入する。酸処理をより安定的に行う観点からは、反応中の澱粉の全量が水相内に均質に分散した状態、またはスラリー化した状態にあることが望ましい。そのためには、酸処理を行う上での澱粉スラリーの濃度を、たとえば10質量%以上50質量%以下、好ましくは20質量%以上40質量%以下の範囲になるように調整する。スラリー濃度が高すぎると、スラリー粘度が上昇し、均一なスラリーの攪拌が難しくなる場合がある。
The conditions of the acid treatment are not limited, but the treatment can be performed as follows, for example.
After adding the starch having an amylose content of 5% by mass or more and water to the reaction apparatus, further acid is added. Alternatively, the acid water in which the acid is previously dissolved in water and the starch of the raw material are put into the reactor. From the viewpoint of more stable acid treatment, it is desirable that the total amount of starch in the reaction is uniformly dispersed in the aqueous phase or in a slurry state. For that purpose, the concentration of the starch slurry in the acid treatment is adjusted to be, for example, in the range of 10% by mass or more and 50% by mass or less, preferably 20% by mass or more and 40% by mass or less. If the slurry concentration is too high, the slurry viscosity may increase, making it difficult to stir a uniform slurry.
 上記酸処理に用いられる酸として、具体的には塩酸、硫酸、硝酸などの無機酸が挙げられ、種類、純度などを問わず利用できる。 Specific examples of the acid used for the above acid treatment include inorganic acids such as hydrochloric acid, sulfuric acid, and nitric acid, which can be used regardless of the type and purity.
 酸処理反応において、たとえば酸処理時の酸濃度は.0.05規定度(N)以上4N以下が好ましく、0.1N以上4N以下がより好ましく、0.2N以上3N以下がさらに好ましい。また、反応温度は、30℃以上70℃以下が好ましく、35℃以上70℃以下がより好ましく、35℃以上65℃以下がさらに好ましい。反応時間は、0.5時間以上120時間以下が好ましく、1時間以上72時間以下がより好ましく、1時間以上48時間以下がさらに好ましい。 In the acid treatment reaction, for example, the acid concentration during the acid treatment. 0.05 Normality (N) or more and 4N or less is preferable, 0.1N or more and 4N or less is more preferable, and 0.2N or more and 3N or less is further preferable. The reaction temperature is preferably 30 ° C. or higher and 70 ° C. or lower, more preferably 35 ° C. or higher and 70 ° C. or lower, and even more preferably 35 ° C. or higher and 65 ° C. or lower. The reaction time is preferably 0.5 hours or more and 120 hours or less, more preferably 1 hour or more and 72 hours or less, and further preferably 1 hour or more and 48 hours or less.
 成分(A)中の低分子化澱粉の含有量は好ましくない食感を低減し、風味増強効果を向上させる観点から、成分(A)全体に対して3質量%以上であり、8質量%以上であることが好ましく、13質量%以上とすることがさらに好ましい。
 一方、成分(A)中の低分子化澱粉の含有量は、同様の観点から、成分(A)全体に対して45質量%以下であり、35質量%以下であることが好ましく、25質量%以下とすることがさらに好ましい。
The content of the low molecular weight starch in the component (A) is 3% by mass or more and 8% by mass or more with respect to the entire component (A) from the viewpoint of reducing an unfavorable texture and improving the flavor enhancing effect. It is preferably 13% by mass or more, and more preferably 13% by mass or more.
On the other hand, the content of the low molecular weight starch in the component (A) is 45% by mass or less, preferably 35% by mass or less, preferably 25% by mass, based on the whole component (A) from the same viewpoint. The following is more preferable.
 また、低分子化澱粉の原料澱粉中のアミロース含量は、5質量%以上であり、好ましくは12質量%以上、より好ましくは22質量%以上、さらに好ましくは45質量%以上、さらにより好ましくは55質量%以上、よりいっそう好ましくは65質量%以上である。なお、低分子化澱粉の原料澱粉中のアミロース含量の上限に制限はなく、100質量%以下であり、好ましくは90質量%以下、より好ましくは80質量%以下である。 The amylose content in the raw material starch of the low molecular weight starch is 5% by mass or more, preferably 12% by mass or more, more preferably 22% by mass or more, still more preferably 45% by mass or more, still more preferably 55. By mass or more, more preferably 65% by mass or more. The upper limit of the amylose content in the raw material starch of the low molecular weight starch is not limited and is 100% by mass or less, preferably 90% by mass or less, and more preferably 80% by mass or less.
 低分子化澱粉の原料であるアミロース含量5質量%以上の澱粉として、ハイアミロースコーンスターチ、コーンスターチ、タピオカ澱粉、甘藷澱粉、馬鈴薯澱粉、小麦澱粉、ハイアミロース小麦澱粉、米澱粉、緑豆澱粉やエンドウ澱粉等の豆澱粉、サゴヤシ澱粉および、これらの原料を化学的、物理的または酵素的に加工した加工澱粉からなる群から選択される1種または2種以上を用いることができる。好ましくない食感を低減し、風味増強効果を向上させる観点から、ハイアミロースコーンスターチ、コーンスターチ、および、タピオカ澱粉から選択される1種または2種以上を用いることが好ましく、ハイアミロースコーンスターチを用いることがより好ましい。ハイアミロースコーンスターチのアミロース含量は、40質量%以上のものが入手可能である。アミロース含量5質量%以上の澱粉は、より好ましくはアミロース含量が40質量%以上のハイアミロースコーンスターチである。 As starch having an amylose content of 5% by mass or more, which is a raw material for low molecular weight starch, high amylose corn starch, corn starch, tapioca starch, sweet potato starch, horse belly starch, wheat starch, high amylose wheat starch, rice starch, green bean starch, pea starch, etc. One or more selected from the group consisting of bean starch, sagoyashi starch, and processed starch obtained by chemically, physically or enzymatically processing these raw materials can be used. From the viewpoint of reducing an unfavorable texture and improving the flavor enhancing effect, it is preferable to use one or more selected from high amylose cornstarch, cornstarch, and tapioca starch, and it is preferable to use high amylose cornstarch. More preferred. High amylose cornstarch has an amylose content of 40% by mass or more and is available. Starch having an amylose content of 5% by mass or more is more preferably high amylose cornstarch having an amylose content of 40% by mass or more.
 また、成分(A)の25℃における冷水膨潤度は、風味増強効果を向上させる観点から、5以上であり、好ましくは5.5以上であり、さらに好ましくは6以上である。
 また、好ましくない食感を低減し、風味増強効果を向上させる観点から、成分(A)の25℃における冷水膨潤度は20以下であり、好ましくは17以下、さらに好ましくは15以下、さらにより好ましくは13以下である。
 ここで、成分(A)の25℃における冷水膨潤度は、以下の方法で測定される。
(1)試料を、水分計(研精工業株式会社製、型番MX-50)を用いて、125℃で加熱乾燥させて水分測定し、得られた水分値から乾物質量を算出する。
(2)この乾物質量換算で試料1gを25℃の水50mLに分散した状態にし、30分間25℃の恒温槽の中でゆるやかに撹拌した後、3000rpmで10分間遠心分離(遠心分離機:日立工機社製、日立卓上遠心機CT6E型;ローター:T4SS型スイングローター;アダプター:50TC×2Sアダプター)し、沈殿層と上澄層に分ける。
(3)上澄層を取り除き、沈殿層質量を測定し、これをB(g)とする。
(4)沈殿層を乾固(105℃、恒量)したときの質量をC(g)とする。
(5)BをCで割った値を冷水膨潤度とする。
The degree of cold water swelling of the component (A) at 25 ° C. is 5 or more, preferably 5.5 or more, and more preferably 6 or more from the viewpoint of improving the flavor enhancing effect.
Further, from the viewpoint of reducing an unfavorable texture and improving the flavor enhancing effect, the degree of cold water swelling of the component (A) at 25 ° C. is 20 or less, preferably 17 or less, more preferably 15 or less, still more preferably. Is 13 or less.
Here, the degree of cold water swelling of the component (A) at 25 ° C. is measured by the following method.
(1) The sample is heated and dried at 125 ° C. using a moisture meter (manufactured by Kensei Kogyo Co., Ltd., model number MX-50) to measure the moisture content, and the amount of dry substance is calculated from the obtained moisture value.
(2) Disperse 1 g of the sample in 50 mL of water at 25 ° C in terms of the amount of dry matter, stir gently in a constant temperature bath at 25 ° C for 30 minutes, and then centrifuge at 3000 rpm for 10 minutes (centrifuge: Hitachi). Hitachi desktop centrifuge CT6E type; rotor: T4SS type swing rotor; adapter: 50TC x 2S adapter) manufactured by Koki Co., Ltd., and separated into a settling layer and a supernatant layer.
(3) The supernatant layer is removed, the mass of the precipitate layer is measured, and this is designated as B (g).
(4) Let C (g) be the mass when the precipitate layer is dried to dryness (105 ° C., constant amount).
(5) The value obtained by dividing B by C is defined as the degree of cold water swelling.
 成分(A)の、JIS-Z8801-1規格における目開き3.35mmの篩の篩下かつ目開き0.038mmの篩の篩上の含有量は、風味増強効果を向上させる観点から、50質量%以上であり、好ましくは60質量%以上、より好ましくは70質量%以上、さらに好ましくは80質量%以上、さらにより好ましくは90質量%以上である。
 成分(A)の、JIS-Z8801-1規格における目開き3.35mmの篩の篩下かつ目開き0.038mmの篩の篩上の含有量は、同様の観点から、100質量%以下であり、99質量%以下であってもよい。
 ここで、成分(A)の粒度について、篩上または篩下の画分の含有量は、成分(A)全体に対する画分の含有量である。
The content of the component (A) under the sieve with a mesh size of 3.35 mm and on the sieve with a mesh size of 0.038 mm according to the JIS-Z8801-1 standard is 50 mass from the viewpoint of improving the flavor enhancing effect. % Or more, preferably 60% by mass or more, more preferably 70% by mass or more, still more preferably 80% by mass or more, still more preferably 90% by mass or more.
The content of the component (A) under the sieve with a mesh size of 3.35 mm and on the sieve with a mesh size of 0.038 mm according to the JIS-Z8801-1 standard is 100% by mass or less from the same viewpoint. , 99% by mass or less.
Here, regarding the particle size of the component (A), the content of the fraction on or under the sieve is the content of the fraction with respect to the entire component (A).
 成分(A)の、JIS-Z8801-1規格の篩における3.35mmの篩の篩下かつ目開き0.15mmの篩の篩上の含有量は、口触り、口溶けおよび中味、後味の風味増強効果を向上させる観点から、たとえば30質量%以上であり、好ましくは40質量%以上であり、より好ましくは50質量%以上、さらに好ましくは60質量%以上、さらにより好ましくは65質量%以上である。
 成分(A)の、JIS-Z8801-1規格の篩における3.35mmの篩の篩下かつ目開き0.15mmの篩の篩上の含有量は、先味の風味増強効果を向上させる観点から、好ましくは95質量%以下であり、より好ましくは92質量%以下、さらに好ましくは88質量%以下、さらにより好ましくは85質量%以下である。
The content of the component (A) under the sieve of the 3.35 mm sieve and on the sieve of the sieve with the opening of 0.15 mm in the sieve of JIS-Z8801-1 standard is the flavor enhancement of the texture, the melting in the mouth and the content and aftertaste. From the viewpoint of improving the effect, for example, it is 30% by mass or more, preferably 40% by mass or more, more preferably 50% by mass or more, still more preferably 60% by mass or more, still more preferably 65% by mass or more. ..
The content of the component (A) under the sieve of the 3.35 mm sieve and on the sieve of the sieve having a mesh size of 0.15 mm in the sieve of JIS-Z8801-1 standard is from the viewpoint of improving the flavor enhancing effect of the taste. It is preferably 95% by mass or less, more preferably 92% by mass or less, still more preferably 88% by mass or less, and even more preferably 85% by mass or less.
 本実施形態において、成分(A)中の上記低分子化澱粉以外の澱粉成分としては、様々な澱粉を使用することができる。具体的には、用途に応じて一般に市販されている澱粉、たとえば食品用の澱粉であれば、種類を問わないが、たとえば、ハイアミロースコーンスターチ、コーンスターチ、ワキシーコーンスターチ等のとうもろこし澱粉、タピオカ澱粉、甘藷澱粉、馬鈴薯澱粉、小麦澱粉、ハイアミロース小麦澱粉、米澱粉、緑豆澱粉やエンドウ澱粉等の豆澱粉、サゴヤシ澱粉およびこれらの澱粉を化学的、物理的または酵素的に加工した加工澱粉などから、1種以上を適宜選ぶことができる。成分(A)中の上記低分子化澱粉以外の澱粉成分は、好ましくは、とうもろこし澱粉、小麦澱粉、馬鈴薯澱粉、タピオカ澱粉およびこれらの加工澱粉からなる群から選択される1種または2種以上の澱粉を含有し、より好ましくは、コーンスターチを含有し、さらに好ましくはコーンスターチである。 In the present embodiment, various starches can be used as the starch component other than the above-mentioned low molecular weight starch in the component (A). Specifically, any type of starch that is generally commercially available depending on the intended use, for example, starch for food, is not limited, and for example, corn starch such as high amylose corn starch, corn starch, waxy corn starch, tapioca starch, and sweet potato. From starch, potato starch, wheat starch, high amylose wheat starch, rice starch, bean starch such as green bean starch and pea starch, sagoyashi starch and processed starch obtained by chemically, physically or enzymatically processing these starches, etc. 1 You can choose more than seeds as appropriate. The starch component other than the low molecular weight starch in the component (A) is preferably one or more selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and processed starch thereof. It contains starch, more preferably cornstarch, and even more preferably cornstarch.
 また、本実施形態における成分(A)には、澱粉以外の成分を配合することもできる。
 澱粉以外の成分の具体例としては、炭酸カルシウム、硫酸カルシウムなどの不溶性塩、乳化剤、および色素などが挙げられ、不溶性塩を配合することが好ましく、不溶性塩の配合量は、0.1質量%以上2質量%以下であることがより好ましい。
Further, the component (A) in the present embodiment may contain a component other than starch.
Specific examples of the components other than the starch include insoluble salts such as calcium carbonate and calcium sulfate, emulsifiers, pigments and the like, and it is preferable to add the insoluble salt, and the amount of the insoluble salt is 0.1% by mass. It is more preferably 2% by mass or less.
 成分(A)に乳化剤を含む場合、乳化剤としては、たとえば食品用の乳化剤が挙げられる。
 具体的には、ショ糖脂肪酸エステル、モノグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、酢酸モノグリセリド、乳酸モノグリセリド、クエン酸モノグリセリド、コハク酸モノグリセリド、ポリソルベート、ソルビタン脂肪酸エステル、ジアセチル酒石酸モノグリセリド等のノニオン界面活性剤;アニオン界面活性剤;およびレシチン等の両性界面活性剤が挙げられる。
 乳化剤は、好ましくはノニオン界面活性剤であり、より好ましくはショ糖脂肪酸エステルおよびモノグリセリン脂肪酸エステルから選ばれる1種以上であり、さらに好ましくはモノグリセリン脂肪酸エステルである。
 成分(A)中の乳化剤の含有量は、成分(A)全体に対してたとえば0.5質量%以上であり、好ましくは0.6質量%以上、より好ましくは0.9質量%以上である。また、成分(A)中の乳化剤の含有量は、成分(A)全体に対してたとえば11質量%以下であり、好ましくは9質量%以下、さらに好ましくは6質量%以下である。
When the component (A) contains an emulsifier, the emulsifier includes, for example, an emulsifier for food.
Specifically, sucrose fatty acid ester, monoglycerin fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, acetate monoglyceride, lactic acid monoglyceride, citric acid monoglyceride, succinic acid monoglyceride, polysorbate, sorbitan fatty acid. Nonionic surfactants such as esters, diacetyl tartrate monoglycerides; anionic surfactants; and amphoteric surfactants such as lecithin can be mentioned.
The emulsifier is preferably a nonionic surfactant, more preferably one or more selected from sucrose fatty acid ester and monoglycerin fatty acid ester, and further preferably monoglycerin fatty acid ester.
The content of the emulsifier in the component (A) is, for example, 0.5% by mass or more, preferably 0.6% by mass or more, and more preferably 0.9% by mass or more with respect to the entire component (A). .. The content of the emulsifier in the component (A) is, for example, 11% by mass or less, preferably 9% by mass or less, and more preferably 6% by mass or less with respect to the entire component (A).
 次に、成分(A)の製造方法を説明する。成分(A)の製造方法は、たとえば、以下の工程を含む。
(低分子化澱粉の調製工程)アミロース含量5質量%以上の原料澱粉を低分子化処理してピーク分子量が3×10以上5×10以下の低分子化澱粉を得る工程。
(造粒工程)原料に低分子化澱粉を3質量%以上45質量%以下含み、かつ低分子化澱粉と低分子化澱粉以外の澱粉の合計が75質量%以上である、原料を加熱糊化して造粒する工程。
Next, a method for producing the component (A) will be described. The method for producing the component (A) includes, for example, the following steps.
(Step of preparing low molecular weight starch) A step of reducing the molecular weight of raw material starch having an amylose content of 5% by mass or more to obtain a low molecular weight starch having a peak molecular weight of 3 × 10 3 or more and 5 × 10 4 or less.
(Granulation step) The raw material contains 3% by mass or more and 45% by mass or less of low-molecular-weight starch, and the total amount of low-molecular-weight starch and starch other than low-molecular-weight starch is 75% by mass or more. The process of granulating.
 低分子化澱粉の調製工程は、アミロース含量5質量%以上の澱粉を分解して低分子化澱粉とする工程である。ここでいう分解とは、澱粉の低分子化を伴う分解をいい、代表的な分解方法として酸処理や酸化処理、酵素処理による分解が挙げられる。この中でも、分解速度やコスト、分解反応の再現性の観点から、好ましくは酸処理である。 The step of preparing low molecular weight starch is a step of decomposing starch having an amylose content of 5% by mass or more into low molecular weight starch. The decomposition referred to here refers to decomposition accompanied by a reduction in the molecular weight of starch, and typical decomposition methods include decomposition by acid treatment, oxidation treatment, and enzyme treatment. Among these, acid treatment is preferable from the viewpoint of decomposition rate, cost, and reproducibility of decomposition reaction.
 また、造粒工程には、澱粉の造粒に使用されている一般的な方法を用いることができるが、所定の冷水膨潤度とする点で、澱粉の加熱糊化に使用されている一般的な方法を用いることが好ましい。具体的には、ドラムドライヤー、ジェットクッカー、エクストルーダー、スプレードライヤーなどの機械を使用した方法が知られているが、本実施形態において、冷水膨潤度が上述した特定の条件を満たす成分(A)をより確実に得る観点から、エクストルーダーやドラムドライヤーによる加熱糊化が好ましく、エクストルーダーがより好ましい。
 エクストルーダー処理する場合は通常、澱粉を含む原料に加水して水分含量を10~60質量%程度に調整した後、たとえばバレル温度30~200℃、出口温度80~180℃、スクリュー回転数100~1,000rpm、熱処理時間5~60秒の条件で、加熱膨化させる。
Further, in the granulation step, a general method used for granulating starch can be used, but it is generally used for heat gelatinization of starch in terms of achieving a predetermined degree of swelling in cold water. It is preferable to use the above method. Specifically, a method using a machine such as a drum dryer, a jet cooker, an extruder, or a spray dryer is known, but in the present embodiment, the component (A) in which the degree of swelling of cold water satisfies the above-mentioned specific condition. From the viewpoint of more reliably obtaining the above, heat gelatinization with an extruder or a drum dryer is preferable, and an extruder is more preferable.
In the case of extruder treatment, usually, after adding water to a raw material containing starch to adjust the water content to about 10 to 60% by mass, for example, a barrel temperature of 30 to 200 ° C., an outlet temperature of 80 to 180 ° C., and a screw rotation speed of 100 to 100 to It is heated and expanded under the conditions of 1,000 rpm and a heat treatment time of 5 to 60 seconds.
 本実施形態において、たとえば上記特定の原料を加熱糊化する工程により、冷水膨潤度が特定の条件を満たす成分(A)を得ることができる。また、加熱糊化して得られた造粒物を、必要に応じて、粉砕し、篩い分けをし、大きさを適宜調整して、成分(A)を得るとよい。 In the present embodiment, for example, by the step of heating and gelatinizing the above-mentioned specific raw material, the component (A) whose cold water swelling degree satisfies a specific condition can be obtained. Further, the granulated product obtained by heat gelatinization may be pulverized and sieved, if necessary, and the size thereof may be appropriately adjusted to obtain the component (A).
 以上により得られる成分(A)は、低分子化澱粉を含む粉粒状物であって、澱粉含量、冷水膨潤度、および、低分子化澱粉のピーク分子量がいずれも特定の条件を満たす構成となっているため、成分(A)を含む風味増強剤をペースト状あるいは流動状態で喫食される食品に配合することで、食品の好ましくない食感を低減し、風味増強効果を向上させることができる。 The component (A) obtained as described above is a powder granule containing low molecular weight starch, and the starch content, the degree of swelling in cold water, and the peak molecular weight of the low molecular weight starch all satisfy specific conditions. Therefore, by blending the flavor enhancer containing the component (A) into the food to be eaten in the form of a paste or in a fluid state, the unfavorable texture of the food can be reduced and the flavor enhancing effect can be improved.
(その他の成分)
 本実施形態における風味増強剤は、成分(A)以外の成分を含んでもよい。風味増強剤が成分(A)以外の成分を含む場合、粉体状の成分を含むことが好ましい。成分(A)以外の成分の具体例としては、未加工澱粉(生澱粉)、加工澱粉等の成分(A)以外の澱粉;小麦粉等の穀粉;キサンタンガム等の増粘多糖類;糖類;粉末状の調味料;乳化剤等が挙げられる。
(Other ingredients)
The flavor enhancer in the present embodiment may contain a component other than the component (A). When the flavor enhancer contains a component other than the component (A), it is preferable to contain a powdery component. Specific examples of the components other than the component (A) include unprocessed starch (raw starch), starches other than the component (A) such as processed starch; flour such as wheat flour; thickening polysaccharides such as xanthan gum; sugars; powdered form. Seasonings; emulsifiers and the like.
 本実施形態における風味増強剤中、成分(A)の含有量は、風味増強効果を向上させる観点から、風味増強剤全体に対し、好ましくは40質量%以上であり、より好ましくは60質量%以上、さらに好ましくは70質量%以上、さらにより好ましくは80質量%以上、よりいっそう好ましくは85質量%以上である。
 本実施形態における風味増強剤中、成分(A)の含有量は、同様の観点から、好ましくは100質量%以下であり、99質量%以下であってもよい。
From the viewpoint of improving the flavor enhancing effect, the content of the component (A) in the flavor enhancing agent in the present embodiment is preferably 40% by mass or more, more preferably 60% by mass or more, based on the whole flavor enhancing agent. , More preferably 70% by mass or more, still more preferably 80% by mass or more, and even more preferably 85% by mass or more.
From the same viewpoint, the content of the component (A) in the flavor enhancer in the present embodiment is preferably 100% by mass or less, and may be 99% by mass or less.
 本実施形態における食品中、風味増強剤の配合量は、風味増強効果を向上させる観点から、食品および風味増強剤の合計量に対し、好ましくは0.1質量%以上であり、より好ましくは0.4質量%以上、さらに好ましくは0.8質量%以上である。
 本実施形態における食品中、風味増強剤の配合量は、同様の観点から、食品および風味増強剤の合計量に対し、好ましくは15質量%以下であり、より好ましくは10質量%以下、さらに好ましくは8質量%以下、さらにより好ましくは6質量%以下、よりいっそう好ましくは4.8質量%以下、殊更好ましくは2.8質量%以下である。
From the viewpoint of improving the flavor enhancing effect, the blending amount of the flavor enhancing agent in the food in the present embodiment is preferably 0.1% by mass or more, more preferably 0, with respect to the total amount of the food and the flavor enhancing agent. It is 0.4% by mass or more, more preferably 0.8% by mass or more.
From the same viewpoint, the blending amount of the flavor enhancer in the food in the present embodiment is preferably 15% by mass or less, more preferably 10% by mass or less, still more preferably, with respect to the total amount of the food and the flavor enhancer. Is 8% by mass or less, more preferably 6% by mass or less, even more preferably 4.8% by mass or less, and particularly preferably 2.8% by mass or less.
 本実施形態における食品中、成分(A)の含有量は、風味増強効果を向上させる観点から、好ましくは0.1質量%以上であり、より好ましくは0.2質量%以上、さらに好ましくは0.6質量%以上である。
 本実施形態における食品中、風味増強剤の含有量は、同様の観点から、好ましくは10質量%以下であり、より好ましくは7質量%以下、さらに好ましくは4質量%以下、さらにより好ましくは2.4質量%以下である。
The content of the component (A) in the food in the present embodiment is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, still more preferably 0, from the viewpoint of improving the flavor enhancing effect. It is 6.6% by mass or more.
From the same viewpoint, the content of the flavor enhancer in the food in the present embodiment is preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 4% by mass or less, still more preferably 2 It is 4% by mass or less.
 本実施形態においては、風味増強剤が成分(A)を有効分として含むため、たとえば先味、中味および後味の少なくとも一つの風味が増強された食品を得ることができる。また、本実施形態によれば、たとえば、口触りや口溶け等の食感が良好な食品を得ることもできる。 In the present embodiment, since the flavor enhancer contains the component (A) as an effective component, it is possible to obtain, for example, a food in which at least one of the first taste, the middle taste and the aftertaste is enhanced. Further, according to the present embodiment, for example, it is possible to obtain a food having a good texture such as texture and melting in the mouth.
(食品素材)
 本実施形態において、食品の製造方法は、たとえば風味増強剤を食品素材に配合する工程を含む。
 食品素材は、調理前の食品の原材料、およびこれらの混合物であってもよく、具材、調味料等を含んでもよい。
 具材の例として、農海産物が挙げられ、さらに具体的には、野菜、果物等の青果物;家禽肉、畜肉等の肉類;魚類、貝類、エビ、カニ等の魚介類が挙げられる。
 また、食品素材は、カレー、ハッシュドビーフ、シチュー、麻婆豆腐の餡、スープ、パスタソース、フィリング、練りわさび等の調理済み素材であってもよい。
(Food material)
In the present embodiment, the method for producing a food product includes, for example, a step of blending a flavor enhancer into a food material.
The food material may be a raw material of food before cooking and a mixture thereof, and may contain ingredients, seasonings and the like.
Examples of the ingredients include agricultural and marine products, and more specifically, fruits and vegetables such as vegetables and fruits; meats such as poultry and livestock meat; fish and shellfish such as fish, shellfish, shrimp, and crabs.
Further, the food material may be a cooked material such as curry, hashed beef, stew, mapo tofu bean paste, soup, pasta sauce, filling, and kneaded wasabi.
(食品の製造方法)
 本実施形態において、食品の製造方法は、たとえば風味増強剤を食品素材に配合する工程を含む。
 風味増強剤を食品素材に配合する方法は、限定されず、たとえば練りわさびであれば、食品素材である粉わさびを、風味増強剤および水とともにボウルに入れ、ミキサー等で混合して食品である練りわさびを得ることができる。この際、風味増強剤とその他の原材料を添加するタイミングは限定されず、調理済み練りわさびに風味増強剤を加えてもよい。
 同様に、カレーやフィリング等の食品の場合、調理済み食品素材に風味増強剤を加えて食品を得てもよいし、食品素材と風味増強剤との混合物の状態で、加熱調理工程を経てもよい。加熱調理工程における加熱調理の具体例として、焼成、ボイル、電子レンジ加熱、蒸煮、スチームコンベクション加熱、油ちょう等が挙げられる。
 また、食品の製造方法には、加熱加圧処理(たとえばレトルト処理)する工程を含んでもよく、さらに具体的には、風味増強剤を食品素材に配合する工程の後、100℃~130℃、0.206MPaで1~60分間、加圧加熱処理をする工程をさらに含んでもよい。
(Food manufacturing method)
In the present embodiment, the method for producing a food product includes, for example, a step of blending a flavor enhancer into a food material.
The method of blending the flavor enhancer into the food material is not limited. For example, in the case of kneaded wasabi, the powdered wasabi, which is the food material, is put into a bowl together with the flavor enhancer and water, and mixed with a mixer or the like to prepare the food. You can get kneaded wasabi. At this time, the timing of adding the flavor enhancer and other raw materials is not limited, and the flavor enhancer may be added to the cooked wasabi.
Similarly, in the case of foods such as curry and fillings, a flavor enhancer may be added to the cooked food material to obtain the food, or a mixture of the food material and the flavor enhancer may be subjected to a cooking step. good. Specific examples of cooking in the cooking process include baking, boiling, microwave oven heating, steaming, steam convection heating, and oil shavings.
Further, the method for producing a food may include a step of heat-pressurizing treatment (for example, retort treatment), and more specifically, after a step of blending a flavor enhancer into a food material, the temperature is 100 ° C. to 130 ° C. A step of performing a pressure heat treatment at 0.206 MPa for 1 to 60 minutes may be further included.
 本実施形態の食品の製造方法において、喫食前に室温保存工程、常温レトルト保存工程、冷凍保存工程あるいは冷蔵保存工程があってもよい。また、上記保存工程後、喫食時に再加熱工程があってもよい。再加熱の方法には、たとえば上述の加熱調理で挙げられた方法と同じものが適用可能である。 In the method for producing food of the present embodiment, there may be a room temperature storage step, a room temperature retort storage step, a frozen storage step, or a refrigerated storage step before eating. Further, after the storage step, there may be a reheating step at the time of eating. As the method of reheating, for example, the same method as mentioned in the above-mentioned cooking can be applied.
(食品の風味増強方法)
 本実施形態の食品の風味増強方法は、ペースト状あるいは流動状態で喫食される食品に、成分(A)を有効成分とする風味増強剤を適用する工程を含む。上記食品の風味増強方法は、好ましくは後味の風味増強方法である。後味の風味を増強することによって、結果として食品の風味に濃厚さを付与することもできる。
 ペースト状あるいは流動状態で喫食される食品、風味増強剤、成分(A)の詳しい内容は、上述の(食品)、(風味増強剤)、(成分(A))の項にてそれぞれ説明しているので省略する。
(Food flavor enhancement method)
The method for enhancing the flavor of a food product according to the present embodiment includes a step of applying a flavor enhancing agent containing the ingredient (A) as an active ingredient to a food product to be eaten in the form of a paste or in a fluid state. The method for enhancing the flavor of the food is preferably a method for enhancing the flavor of the aftertaste. By enhancing the flavor of the aftertaste, it is also possible to add richness to the flavor of the food as a result.
The detailed contents of the food, the flavor enhancer, and the ingredient (A) that are eaten in the form of a paste or in a fluid state will be described in the above-mentioned sections (Food), (Flavor enhancer), and (Ingredient (A)), respectively. Since it is present, it is omitted.
 以下に本発明の実施例を示すが、本発明の趣旨はこれらに限定されるものではない。
 以下、断りの無い場合、「%」とは、「質量%」である。
Examples of the present invention are shown below, but the gist of the present invention is not limited thereto.
Hereinafter, unless otherwise specified, "%" is "mass%".
 原材料として、主に以下のものを使用した。
(澱粉)
コーンスターチ:コーンスターチY、株式会社J-オイルミルズ製
ハイアミロースコーンスターチ:HS-7(アミロース含量:70質量%)、株式会社J-オイルミルズ製
ワキシーコーンスターチ:ワキシーコーンスターチY、株式会社J-オイルミルズ製
加工澱粉1:テクステイドA、日本エヌエスシー社製
(その他の成分)
乳化剤(モノグリセリン脂肪酸エステル):ポエムP(V)S、理研ビタミン株式会社製
キサンタンガム:キサンタンガムFJ、ユングブンツラワー社製
The following materials were mainly used as raw materials.
(starch)
Cornstarch: Cornstarch Y, J-Oil Mills Co., Ltd. High Amylose Cornstarch: HS-7 (amylose content: 70% by mass), J-Oil Mills Co., Ltd. Waxi Corn Starch: Waxi Corn Starch Y, J-Oil Mills Co., Ltd. Processing Starch 1: Textide A, manufactured by Nippon NSC Co., Ltd. (other ingredients)
Emulsifier (monoglycerin fatty acid ester): Poem P (V) S, manufactured by RIKEN Vitamin Co., Ltd. Xanthan gum: Xanthan gum FJ, manufactured by Jungbuntslawer
 <成分(A)の製造>
(製造例1)低分子化澱粉の製造
 本例では、成分(A)(粉粒状物1~4)の原料となる低分子化澱粉として酸処理ハイアミロースコーンスターチを製造した。
 ハイアミロースコーンスターチを水に懸濁して35.6%(w/w)スラリーを調製し、50℃に加温した。そこへ、攪拌しながら4.25Nに調製した塩酸水溶液をスラリー質量比で1/9倍量加え反応を開始した。16時間反応後、3%NaOHで中和し、水洗、脱水、乾燥し、酸処理ハイアミロースコーンスターチを得た。
 得られた酸処理ハイアミロースコーンスターチのピーク分子量を以下の方法で測定したところ、ピーク分子量は1.2×10であった。
<Manufacturing of component (A)>
(Production Example 1) Production of Low-Molecularized Starch In this example, acid-treated high amylose cornstarch was produced as the low-molecular-weight starch as a raw material for the components (A) (powder granules 1 to 4).
High amylose cornstarch was suspended in water to prepare a 35.6% (w / w) slurry, which was heated to 50 ° C. A hydrochloric acid aqueous solution prepared at 4.25 N was added thereto with stirring in an amount of 1/9 times the mass ratio of the slurry, and the reaction was started. After the reaction for 16 hours, the mixture was neutralized with 3% NaOH, washed with water, dehydrated and dried to obtain acid-treated high amylose cornstarch.
The peak molecular weight of the resulting acid-treated high-amylose cornstarch was measured by the following method, the peak molecular weight was 1.2 × 10 4.
(ピーク分子量の測定方法)
 ピーク分子量の測定は、東ソー株式会社製HPLCユニットを使用しておこなった(ポンプDP-8020、RI検出器RS-8021、脱気装置SD-8022)。
(1)試料を粉砕し、JIS-Z8801-1規格の篩で、目開き0.15mm篩下の画分を回収した。この回収画分を移動相に1mg/mLとなるように懸濁し、懸濁液を100℃3分間加熱して完全に溶解した。0.45μmろ過フィルター(ADVANTEC社製、DISMIC-25HP PTFE 0.45μm)を用いてろ過を行い、ろ液を分析試料とした。
(2)以下の分析条件で分子量を測定した。
カラム:TSKgel α-M(7.8mmφ、30cm)(東ソー株式会社製)2本
流速:0.5mL/min
移動相:5mM 硝酸ナトリウム含有90%(v/v)ジメチルスルホキシド溶液
カラム温度:40℃
分析量:0.2mL
(3)検出器データを、ソフトウェア(マルチステーションGPC-8020model
IIデータ収集ver5.70、東ソー株式会社製)にて収集し、分子量ピークを計算した。
 検量線には、分子量既知のプルラン(Shodex Standard P-82、昭和電工株式会社製)を使用した。
(Measurement method of peak molecular weight)
The peak molecular weight was measured using an HPLC unit manufactured by Tosoh Corporation (pump DP-8020, RI detector RS-8021, degassing device SD-8022).
(1) The sample was pulverized, and the fraction under the sieve with an opening of 0.15 mm was collected with a sieve of JIS-Z8801-1 standard. The recovered fraction was suspended in the mobile phase at 1 mg / mL, and the suspension was heated at 100 ° C. for 3 minutes to completely dissolve it. Filtration was performed using a 0.45 μm filtration filter (DISMIC-25HP PTFE 0.45 μm manufactured by ADVANTEC), and the filtrate was used as an analysis sample.
(2) The molecular weight was measured under the following analytical conditions.
Column: TSKgel α-M (7.8 mmφ, 30 cm) (manufactured by Tosoh Corporation) 2 Flow rate: 0.5 mL / min
Mobile phase: 90% (v / v) dimethyl sulfoxide solution containing 5 mM sodium nitrate Column temperature: 40 ° C.
Analysis volume: 0.2 mL
(3) The detector data is converted into software (multi-station GPC-8020model).
II data collection ver 5.70, manufactured by Tosoh Corporation) was used to calculate the molecular weight peak.
Pullulan (Shodex Standard P-82, manufactured by Showa Denko KK) with a known molecular weight was used for the calibration curve.
(製造例2)粉粒状物1~3の製造
 コーンスターチ79質量%、製造例1で得られた酸処理ハイアミロースコーンスターチ20質量%、および、炭酸カルシウム1質量%を充分に均一になるまで袋内で混合した。2軸エクストルーダー(幸和工業社製KEI-45)を用いて、混合物を加圧加熱処理した。処理条件は、以下の通りである。
原料供給:340g/分
加水:20質量%
バレル温度:原料入口から出口に向かって50℃、70℃、100℃および130℃
出口温度:130-150℃
スクリューの回転数250rpm
 このようにしてエクストルーダー処理により得られた加熱糊化物を110℃にて乾燥し、水分含量を約10質量%に調整した。
 次いで、乾燥した加熱糊化物を、卓上カッター粉砕機で粉砕した後、JIS-Z8801-1規格の篩で篩分けした。篩分けした加熱糊化物を、表1の配合割合で混合し、以下の3種の成分(A)(粉粒状物1~3)を調製した。
(Production Example 2) Production of powder granules 1 to 3 Cornstarch 79% by mass, acid-treated high amylose cornstarch 20% by mass obtained in Production Example 1, and calcium carbonate 1% by mass in a bag until sufficiently uniform. Mixed in. The mixture was pressure-heated using a twin-screw extruder (KEI-45 manufactured by Kowa Kogyo Co., Ltd.). The processing conditions are as follows.
Raw material supply: 340 g / min Water: 20% by mass
Barrel temperature: 50 ° C, 70 ° C, 100 ° C and 130 ° C from the raw material inlet to the outlet.
Outlet temperature: 130-150 ° C
Screw rotation speed 250 rpm
The heated paste obtained by the extruder treatment in this manner was dried at 110 ° C. to adjust the water content to about 10% by mass.
Next, the dried heated paste was pulverized with a tabletop cutter crusher and then sieved with a JIS-Z8801-1 standard sieve. The sieved heated pastes were mixed at the blending ratios shown in Table 1 to prepare the following three types of components (A) (powder granules 1 to 3).
(冷水膨潤度の測定方法)
(1)試料を、水分計(研精工業株式会社製、型番MX-50)を用いて、125℃で加熱乾燥させて水分測定し、得られた水分値から乾燥物質量を算出した。
(2)この乾燥物質量換算で試料1gを25℃の水50mLに分散した状態にし、30分間25℃の恒温槽の中でゆるやかに撹拌した後、3000rpmで10分間遠心分離(遠心分離機:日立工機社製、日立卓上遠心機CT6E型;ローター:T4SS型スイングローター;アダプター:50TC×2Sアダプタ)し、沈殿層と上澄層に分けた。
(3)上澄層を取り除き、沈殿層質量を測定し、これをB(g)とした。
(4)沈殿層を乾固(105℃、恒量)したときの質量をC(g)とした。
(5)BをCで割った値を冷水膨潤度とした。
(Measuring method of cold water swelling degree)
(1) The sample was heated and dried at 125 ° C. using a moisture meter (manufactured by Kensei Kogyo Co., Ltd., model number MX-50) to measure the moisture content, and the amount of dried substance was calculated from the obtained moisture value.
(2) Disperse 1 g of the sample in 50 mL of water at 25 ° C in terms of the amount of this dry substance, stir gently in a constant temperature bath at 25 ° C for 30 minutes, and then centrifuge at 3000 rpm for 10 minutes (centrifuge: Hitachi Koki Co., Ltd., Hitachi desktop centrifuge CT6E type; rotor: T4SS type swing rotor; adapter: 50TC x 2S adapter), and separated into a precipitate layer and a supernatant layer.
(3) The supernatant layer was removed, the mass of the precipitate layer was measured, and this was designated as B (g).
(4) The mass when the precipitate layer was dried to dryness (105 ° C., constant amount) was defined as C (g).
(5) The value obtained by dividing B by C was defined as the degree of cold water swelling.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
注)表1中、例えば、「3.35mm篩下、1.4mm篩上」とは、「JIS-Z8801-1規格の目開き3.35mmの篩の篩下かつ1.4mmの篩の篩上」を意味する。 Note) In Table 1, for example, "below 3.35 mm sieve, above 1.4 mm sieve" means "under the sieve of 3.35 mm sieve and 1.4 mm sieve of JIS-Z8801-1 standard". Means "above".
(製造例3)粉粒状物4の製造
 コーンスターチ77質量%、製造例1で得られた酸処理ハイアミロースコーンスターチ20質量%、炭酸カルシウム1質量%、および乳化剤2質量%を充分に均一になるまで袋内で混合した。2軸エクストルーダー(幸和工業社製KEI-45)を用いて、混合物を加圧加熱処理した。処理条件は、以下の通りである。
原料供給:275g/分
加水:22質量%
バレル温度:原料入口から出口に向かって50℃、70℃、100℃および130℃
出口温度:130-150℃
スクリューの回転数230rpm
 このようにしてエクストルーダー処理により得られた加熱糊化物を110℃にて乾燥し、水分含量を約10質量%に調整した。
 次いで、乾燥した加熱糊化物を、卓上カッター粉砕機で粉砕した後、JIS-Z8801-1規格の篩で篩分けした。篩分けした加熱糊化物を、表2の配合割合で混合し、以下の成分(A)(粉粒状物4)を調製した。なお、冷水膨潤度は上述の方法にて測定した。
(Production Example 3) Production of powder granule 4 Until 77% by mass of cornstarch, 20% by mass of acid-treated high amylose cornstarch obtained in Production Example 1, 1% by mass of calcium carbonate, and 2% by mass of emulsifier become sufficiently uniform. Mixed in the bag. The mixture was pressure-heated using a twin-screw extruder (KEI-45 manufactured by Kowa Kogyo Co., Ltd.). The processing conditions are as follows.
Raw material supply: 275 g / min Water: 22% by mass
Barrel temperature: 50 ° C, 70 ° C, 100 ° C and 130 ° C from the raw material inlet to the outlet.
Outlet temperature: 130-150 ° C
Screw rotation speed 230 rpm
The heated paste obtained by the extruder treatment in this manner was dried at 110 ° C. to adjust the water content to about 10% by mass.
Next, the dried heated paste was pulverized with a tabletop cutter crusher and then sieved with a JIS-Z8801-1 standard sieve. The sieved heated pastes were mixed at the blending ratios shown in Table 2 to prepare the following components (A) (powder granules 4). The degree of cold water swelling was measured by the above method.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 (カレーでの試験1)
 (実施例1-1~1-3、比較例1~2、対照例1)
 本例では、以下の方法で風味増強剤をレトルトカレーに適用し、評価した。
(Curry test 1)
(Examples 1-1 to 1-3, Comparative Examples 1 and 2, Control Example 1)
In this example, the flavor enhancer was applied to the retort curry and evaluated by the following method.
(カレーの調製)
 市販のカレーに、風味増強剤または他の澱粉を表3に記載の配合で添加して混合した。なお、対照例については、これらを添加せずに以下の手順をおこなった。
1.市販のレトルトカレー(宮城製粉社製、おとなの大盛カレー(レストラン仕様)250g)を開封してボウルに移し、カレーの具材を目開き1.2mmの網で濾し、カレーソースを得た。その後、カレーソース250gをビーカーに測りとった。これに、風味増強剤およびその他の澱粉の添加量が表3に記載の濃度となるように添加し、均一に分散するように良く撹拌し、混合物を得た。
2.上記1.で得られた混合物をレトルト用透明シール袋に充填し、シールした。これをレトルト食品用オートクレーブ(平山製作所社製 HLM-36LBC型レトルト滅菌器)に入れ、121℃、30分間、加圧加熱処理した。加圧加熱処理後、シール袋をレトルト食品用オートクレーブから取り出し、室温まで冷ました。
3.得られた各カレーサンプル200gを200mLのトールビーカーに移して食品用ラップをし、60℃に加熱したウォーターバスに湯浴し、各例の食品としてのカレーを得た。
(Preparation of curry)
A flavor enhancer or other starch was added to a commercially available curry in the formulation shown in Table 3 and mixed. For the control examples, the following procedure was performed without adding them.
1. 1. A commercially available retort curry (Miyagi Flour Milling Co., Ltd., adult large-sized curry (restaurant specification) 250 g) was opened and transferred to a bowl, and the curry ingredients were strained with a 1.2 mm mesh to obtain curry sauce. After that, 250 g of curry sauce was measured in a beaker. To this, the flavor enhancer and other starches were added so as to have the concentrations shown in Table 3, and the mixture was stirred well so as to be uniformly dispersed to obtain a mixture.
2. 2. Above 1. The mixture obtained in 1) was filled in a transparent seal bag for retort and sealed. This was placed in a retort food autoclave (HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.) and heat-treated under pressure at 121 ° C. for 30 minutes. After pressure heat treatment, the seal bag was removed from the retort food autoclave and cooled to room temperature.
3. 3. 200 g of each obtained curry sample was transferred to a 200 mL tall beaker, wrapped for food, and bathed in a water bath heated to 60 ° C. to obtain curry as a food of each example.
 各例で得られたカレーサンプルの風味の感じ方、口触りおよび口溶けを、5名の専門パネラーが表4に記載の基準にて評価し、対照例1を2点とした場合の評点が、平均点で2点超のものを合格とした。評価結果を表3にあわせて示す。 The taste, texture and melting of the curry sample obtained in each example were evaluated by five specialized panelists according to the criteria shown in Table 4, and the score when control example 1 was 2 points was given. Those with an average score of more than 2 were accepted. The evaluation results are also shown in Table 3.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 表4において、風味の感じ方(先味、中味、後味)、口触りおよび口溶けとは、それぞれ、以下のとおりである。
先味:口に入れてすぐに感じる風味の強さ
中味:咀嚼中に感じる風味の強さ
後味:飲み込んだ後に残る風味の強さ
口触り:液体の舌触り
口溶け:口に入れた際の食感
In Table 4, how to feel the flavor (first taste, middle taste, aftertaste), texture and melting in the mouth are as follows.
First taste: The strength of the flavor that you feel immediately after putting it in your mouth Contents: The strength of the flavor that you feel during chewing Aftertaste: The strength of the flavor that remains after swallowing
 表3の結果より、成分(A)を有効成分とする各実施例の風味増強剤はいずれも優れた風味増強効果を示した。また、口触りおよび口溶けにおいても良好だった。
 成分(A)の粒度が、目開き3.35mm篩下かつ目開き0.038mm篩上の含有量が98.8質量%、並びに、目開き3.35mm篩下かつ目開き0.15mm篩上の含有量が81.8質量%の場合、中味および後味の風味増強並びに口触り、口溶けの点でより優れていた。また、中味および後味の風味増強により、カレーの濃厚感も増していた。
 また、目開き3.35mm篩下かつ目開き0.038mm篩上の含有量が98.7質量%、並びに、目開き3.35mm篩下、0.15mm篩上の含有量が75.0質量%の場合、先味の風味がより増強されていた。
 一方、その他の澱粉を加えた比較例1および2は、風味増強効果において実施例の風味増強剤よりも劣っており、かつ糊っぽさがあり、液体の口触り、口溶けなどの食感についても好ましいものではなかった。
From the results in Table 3, the flavor-enhancing agents of each example containing the ingredient (A) as an active ingredient all showed an excellent flavor-enhancing effect. It was also good in mouthfeel and melting.
The particle size of the component (A) is 98.8% by mass under the mesh with an opening of 3.35 mm and on a sieve with a mesh of 0.038 mm, and the content is under a sieve with a mesh of 3.35 mm and on a sieve with a mesh of 0.15 mm. When the content of was 81.8% by mass, it was more excellent in terms of enhancing the flavor of the content and aftertaste, as well as the texture and melting in the mouth. In addition, the richness of the curry was increased by enhancing the flavors of the content and aftertaste.
Further, the content under the mesh of 3.35 mm and on the sieve of 0.038 mm is 98.7% by mass, and the content on the sieve of 3.35 mm and 0.15 mm is 75.0 mass. In the case of%, the flavor of the first taste was further enhanced.
On the other hand, Comparative Examples 1 and 2 to which other starches were added were inferior to the flavor-enhancing agents of Examples in the flavor-enhancing effect, had a paste-like texture, and had a texture such as liquid texture and melting in the mouth. Was also unfavorable.
 (カレーでの試験2)
 (実施例2-1~2-4、対照例2)
 本例では、風味増強剤として成分(A)粉粒状物1のみを用い食品への含有させる量を変えたこと、対照例2を2点として評価したこと以外は「カレーでの試験1」と同じ手順でレトルトカレーに適用し、同じ手法で評価した。各例の配合及び評価結果を表5に示す。
(Curry test 2)
(Examples 2-1 to 2-4, control example 2)
In this example, "Test 1 in curry" was used except that the amount of the component (A) powder and granules 1 used as the flavor enhancer was changed and the amount of the component (A) contained in the food was changed, and the control example 2 was evaluated as 2 points. It was applied to retort curry by the same procedure and evaluated by the same method. Table 5 shows the formulation and evaluation results of each example.
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
 表5の結果より、成分(A)を有効成分とする各実施例の風味増強剤を所定量含有する場合、いずれも優れた風味増強効果を示した。また、口触りおよび口溶けにおいても良好だった。
 風味増強剤の含有量としては、食品全体に対し0.3質量%以上2.9質量%以下の場合、先味、中味および後味の風味増強並びに口触り、口溶けの点で優れており、0.3質量%以上1.0質量%以下の場合より優れており、0.5質量%以上1.0質量%以下の場合さらに優れていた。
From the results shown in Table 5, when the flavor-enhancing agent of each example containing the component (A) as an active ingredient was contained in a predetermined amount, all of them showed an excellent flavor-enhancing effect. It was also good in mouthfeel and melting.
When the content of the flavor enhancer is 0.3% by mass or more and 2.9% by mass or less with respect to the whole food, it is excellent in terms of flavor enhancement of first taste, content and aftertaste, texture and melting in the mouth, and is 0. It was superior to the case of 0.3% by mass or more and 1.0% by mass or less, and further superior to the case of 0.5% by mass or more and 1.0% by mass or less.
 (練りわさびでの試験)
 (実施例3-1、対照例3)
 本例では、風味増強剤を練りわさびに適用した。
(Test with wasabi paste)
(Example 3-1 and control example 3)
In this example, a flavor enhancer was applied to kneaded wasabi.
(練りわさびの製造)
 粉末わさび(S&B社製、粉わさび)に水を添加し、元になるわさびベースを作製し、対照例3の練りわさびとした。実施例3-1については、その後、風味増強剤として成分(A)粉粒状物1を添加し、混合した。各例の材料および配合を表6に示す。
(Manufacturing of wasabi paste)
Water was added to powdered wasabi (manufactured by S & B, powdered wasabi) to prepare a base wasabi base, which was used as the kneaded wasabi of Control Example 3. For Example 3-1 after that, the component (A) powder granule 1 was added as a flavor enhancer and mixed. The materials and formulations of each example are shown in Table 6.
(評価)
 各例で得られた練りわさびの冷蔵保存7日後の風味の強さを1名の専門パネラーが評価した。
 各例で得られた練りわさびの一部をろ紙(桐山製作所社製、桐山ロート濾紙 150mm No.5A)上に載せたものをバットに並べ、上からラップをし冷蔵庫にして保管した。冷蔵保存7日後の風味の強さを1名の専門パネラーが評価した。評価結果を表6にあわせて示す。
(evaluation)
One professional panelist evaluated the strength of the flavor of the wasabi paste obtained in each example after 7 days of refrigerated storage.
A part of the wasabi obtained in each example was placed on a filter paper (Kiriyama Glass Co., Ltd., Kiriyama funnel filter paper 150 mm No. 5A), arranged on a vat, wrapped from above, and stored in a refrigerator. One professional panelist evaluated the strength of the flavor after 7 days of refrigerated storage. The evaluation results are also shown in Table 6.
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
 実施例の風味増強剤を適用した練りわさびは、冷蔵保存7日後でも対照例3と比較してわさびらしい辛味が感じられ、風味が増強されていた。 The kneaded wasabi to which the flavor enhancer of the example was applied had a pungent taste like wasabi as compared with the control example 3 even after 7 days of refrigerated storage, and the flavor was enhanced.
(パイのフィリング試験)
 (実施例4-1~4-2、対照例4)
 本例では、ラタトゥイユフィリングを使用し、風味増強剤を配合したパイを作製した。
(Pie filling test)
(Examples 4-1 to 4-2, control example 4)
In this example, ratatouille filling was used to prepare a pie containing a flavor enhancer.
(フィリング入りパイの製造方法)
 表7に記載の配合により、フィリング入りパイを下記手順で製造した。
1.市販のラタトゥイユフィリング(業務用旨味広がるラタトゥイユ、田中食品興業所社製)に風味増強剤を入れ、ボウルに入れ均一になるように混合し、混合物を作製した。
2.上記1.で作製した混合物を30gずつ、長辺を1/2にカットした解凍済みパイシート(オーマイパイシート、日本製粉株式会社製)に載せ、上から同じサイズのパイシートで覆い、周りをフォークで押さえ、中央に3本切込みを入れた。予熱したオーブンにて220℃、20分で焼成した。
3.得られたパイのうち、一部は食品用ビニール袋でくるみ室温で一日保管した。その他は食品用ビニール袋でくるみ-20℃で3日冷凍保管し、6時間室温で自然解凍した。また一部は-20℃で3日冷凍保管し、電子レンジ(700W、1分)にて解凍後、オーブントースター(1000W、2分)にて再加熱した。
4.専門パネラー5名で喫食し、風味の強さを合議で評価した。評価結果を表7にあわせて示す。
(Manufacturing method of filling pie)
A pie with a filling was produced by the following procedure according to the formulation shown in Table 7.
1. 1. A flavor enhancer was placed in a commercially available ratatouille filling (ratatouille for commercial use, manufactured by Tanaka Foods Co., Ltd.), placed in a bowl and mixed evenly to prepare a mixture.
2. 2. Above 1. Place 30 g of the mixture prepared in step 1 on a thawed pie sheet (Oh my pie sheet, manufactured by Nippon Flour Mills Co., Ltd.) with the long side cut in half, cover it with a pie sheet of the same size from above, press the circumference with a fork, and center it. I made three notches. It was baked in a preheated oven at 220 ° C. for 20 minutes.
3. 3. Some of the obtained pies were wrapped in food plastic bags and stored at room temperature for one day. Others were wrapped in a plastic bag for food and stored frozen at -20 ° C for 3 days, and naturally thawed at room temperature for 6 hours. A part of the product was frozen and stored at −20 ° C. for 3 days, thawed in a microwave oven (700 W, 1 minute), and then reheated in an oven toaster (1000 W, 2 minutes).
4. Five specialized panelists ate and evaluated the strength of the flavor in a joint manner. The evaluation results are also shown in Table 7.
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
 実施例の風味増強剤を適用したフィリング(実施例4-1、4-2)では、室温保管、冷凍保管後自然解凍、冷凍保管後再加熱、のいずれの場合でも風味増強剤を含まない対照例4と比較して、フィリングの風味が増強されていた。
 また、風味増強剤にキサンタンガムが併用されていても、風味増強効果が見られた(実施例4-2)。
In the filling to which the flavor enhancer of the example was applied (Examples 4-1 and 4-2), the control containing no flavor enhancer in any of the cases of room temperature storage, natural thawing after freezing storage, and reheating after freezing storage. Compared with Example 4, the filling flavor was enhanced.
Further, even when xanthan gum was used in combination with the flavor enhancing agent, a flavor enhancing effect was observed (Example 4-2).
 (実施例5-1、5-2、対照例5)
 本例では、粉粒状物1からなる風味増強剤を用いて麻婆豆腐を調製し、評価した。
(麻婆豆腐の調製)
 表8に記載の割合を計量し、ボウルの中で均一に混合した。
 得られた混合物をレトルト用透明シール袋に充填し、シールした。これをレトルト食品用オートクレーブ(平山製作所社製 HLM-36LBC型レトルト滅菌器)に入れ、121℃、30分間、加圧加熱処理した。加圧加熱処理後、シール袋をレトルト食品用オートクレーブから取り出し、室温まで冷ました。
 得られた各麻婆豆腐の素サンプルを44℃、78%に設定した恒温槽(エスペック株式会社製 LHL-114型)に2週間保管した。
 2週間保管後の麻婆豆腐の素サンプル33.7質量部に対して、加熱済み豚挽き肉12.4質量部、みじん切りした長ネギを9質量部加え、IHコンロ(TOSHIBA MR-20ED)でメモリ5で1分間加熱した。
 そこに豆腐を44.9質量部加え、強火で1分間加熱し、各例における食品として麻婆豆腐を得た。
 各例で得られた麻婆豆腐サンプルの風味の感じ方について、2名の専門パネラーが評価した。評価結果を表8にあわせて示す。
(Examples 5-1 and 5-2, Control Example 5)
In this example, Mapo tofu was prepared and evaluated using a flavor enhancer consisting of powdery granule 1.
(Preparation of mapo tofu)
The proportions listed in Table 8 were weighed and mixed uniformly in a bowl.
The obtained mixture was filled in a transparent seal bag for retort and sealed. This was placed in a retort food autoclave (HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.) and heat-treated under pressure at 121 ° C. for 30 minutes. After pressure heat treatment, the seal bag was removed from the retort food autoclave and cooled to room temperature.
Each of the obtained mapo tofu raw samples was stored in a constant temperature bath (LHL-114 type manufactured by Espec Co., Ltd.) set at 44 ° C. and 78% for 2 weeks.
Add 12.4 parts by mass of cooked minced pork and 9 parts by mass of chopped minced meat to 33.7 parts by mass of the mapo tofu raw sample after storage for 2 weeks, and use an IH stove (TOSHIBA MR-20ED) to store 5 parts of memory. Was heated for 1 minute.
44.9 parts by mass of tofu was added thereto, and the mixture was heated over high heat for 1 minute to obtain mapo tofu as a food in each example.
Two expert panelists evaluated how to feel the flavor of the mapo tofu sample obtained in each example. The evaluation results are also shown in Table 8.
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
 表8に記載の成分の詳細を以下に示す。
でん粉:アクトボディATP-25、株式会社J-オイルミルズ製
Details of the components listed in Table 8 are shown below.
Starch: Actbody ATP-25, manufactured by J-Oil Mills Co., Ltd.
 (実施例6-1、6-2、対照例6)
 本例では、粉粒状物1または粉粒状物4からなる風味増強剤を用いてカレーを調製し、評価した。
(カレーの調製)
 市販のカレーに、風味増強剤を表9に記載の配合で添加して混合した。なお、対照例については、これらを添加せずに以下の手順をおこなった。
1.市販のレトルトカレー(宮城製粉社製、おとなの大盛カレー(レストラン仕様)250g)を開封してボウルに移し、カレーの具材を目開き1.2mmの網で濾し、カレーソースを得た。その後、カレーソース250gをビーカーに測りとった。これに、風味増強剤およびガラムマサダ(エスビー食品株式会社製)の添加量が表9に記載の濃度となるように添加し、均一に分散するように良く撹拌し、混合物を得た。
2.上記1.で得られた混合物をレトルト用透明シール袋に充填し、シールした。これをレトルト食品用オートクレーブ(平山製作所社製 HLM-36LBC型レトルト滅菌器)に入れ、121℃、30分間、加圧加熱処理した。加圧加熱処理後、シール袋をレトルト食品用オートクレーブから取り出し、24℃で90日間保管した。
3.得られた各カレーサンプル200gをレトルト包装のまま、60℃に加熱したウォーターバスに湯浴し、各例における食品としてカレーを得た。
 各例で得られたカレーの風味の感じ方ついて、2名の専門パネラーが評価した。評価結果を表9に合わせて示す。
(Examples 6-1 and 6-2, control example 6)
In this example, a curry was prepared and evaluated using a flavor enhancer composed of powder granule 1 or powder granule 4.
(Preparation of curry)
A flavor enhancer was added to a commercially available curry in the formulation shown in Table 9 and mixed. For the control examples, the following procedure was performed without adding them.
1. 1. A commercially available retort curry (Miyagi Flour Milling Co., Ltd., adult large-sized curry (restaurant specification) 250 g) was opened and transferred to a bowl, and the curry ingredients were strained with a 1.2 mm mesh to obtain curry sauce. After that, 250 g of curry sauce was measured in a beaker. To this, the flavor enhancer and Garam Masada (manufactured by S & B Foods Co., Ltd.) were added so as to have the concentrations shown in Table 9, and the mixture was stirred well so as to be uniformly dispersed to obtain a mixture.
2. 2. Above 1. The mixture obtained in 1) was filled in a transparent seal bag for retort and sealed. This was placed in a retort food autoclave (HLM-36LBC type retort sterilizer manufactured by Hirayama Seisakusho Co., Ltd.) and heat-treated under pressure at 121 ° C. for 30 minutes. After the pressure heat treatment, the seal bag was taken out from the retort food autoclave and stored at 24 ° C. for 90 days.
3. 3. 200 g of each obtained curry sample was bathed in a water bath heated to 60 ° C. in a retort package to obtain curry as a food in each example.
Two professional panelists evaluated how to feel the flavor of the curry obtained in each example. The evaluation results are shown in Table 9.
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000009
(実施例7-1、対照例7-1、7-2)
 本例では、粉粒状物4からなる風味増強剤を用いて、表10の配合でラーメンスープを調製し、評価した。
(ラーメンスープの調製)
1.フライパンにラード、おろしにんにく、おろししょうがおよび風味増強剤を投入し40秒炒めた後、さらに豚挽肉および豆板醤を加え、豚挽肉の色が変わるまで炒めた。
2.1.に水、鶏ガラスープ顆粒、醤油、および味噌を加えて、沸騰するまで煮詰め、各例における食品として味噌ラーメンスープを得た。
 各例で得られたラーメンスープサンプルの風味の感じ方について、10名の専門パネラーが評価した。評価結果を表10にあわせて示す。
(Example 7-1, Control Examples 7-1, 7-2)
In this example, a ramen soup was prepared and evaluated according to the formulation shown in Table 10 using a flavor enhancer composed of powder granules 4.
(Preparation of ramen soup)
1. 1. Lard, grated garlic, grated ginger and flavor enhancer were added to a frying pan and fried for 40 seconds, then minced pork and doubanjiang were added and fried until the color of the minced pork changed.
2.1. Water, chicken glass soup granules, soy sauce, and miso were added to the mixture and boiled down to a boil to obtain miso ramen soup as a food in each example.
Ten professional panelists evaluated how to feel the flavor of the ramen soup sample obtained in each example. The evaluation results are also shown in Table 10.
Figure JPOXMLDOC01-appb-T000010
Figure JPOXMLDOC01-appb-T000010
 この出願は、2020年7月10日に出願された日本出願特願2020-119307号を基礎とする優先権を主張し、その開示のすべてをここに取り込む。 This application claims priority on the basis of Japanese Application Japanese Patent Application No. 2020-119307 filed on July 10, 2020, and incorporates all of its disclosures herein.

Claims (8)

  1.  ペースト状あるいは流動状態で喫食される食品の風味増強剤であって、
     以下の成分(A)を有効成分として含む、風味増強剤。
     成分(A):以下の条件(1)~(4)を満たす粉粒状物
     (1)澱粉含量が75質量%以上
     (2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×10以上5×10以下
     (3)25℃における冷水膨潤度が5以上20以下
     (4)目開き3.35mmの篩の篩下かつ目開き0.038mmの篩の篩上の含有量が50質量%以上100質量%以下
    A flavor enhancer for foods that are eaten in paste or fluid form.
    A flavor enhancer containing the following ingredient (A) as an active ingredient.
    Ingredient (A): Powder granules satisfying the following conditions (1) to (4) (1) Starch content of 75% by mass or more (2) 3% by mass of low molecular weight starch of starch having an amylose content of 5% by mass or more % Or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3 × 10 3 or more and 5 × 10 4 or less. The content under the sieve and on the sieve with an opening of 0.038 mm is 50% by mass or more and 100% by mass or less.
  2.  前記成分(A)を当該風味増強剤全体に対して40質量%以上100質量%以下含有する、請求項1に記載の風味増強剤。 The flavor enhancer according to claim 1, which contains the component (A) in an amount of 40% by mass or more and 100% by mass or less with respect to the entire flavor enhancer.
  3.  当該風味増強剤の前記食品への配合量が、前記食品および当該風味増強剤の合計量の0.1質量%以上15質量%以下である、請求項1または2に記載の風味増強剤。 The flavor enhancer according to claim 1 or 2, wherein the amount of the flavor enhancer blended in the food is 0.1% by mass or more and 15% by mass or less of the total amount of the food and the flavor enhancer.
  4.  前記食品が、ルウ使用食品、ソース類、スープ類、フィリングおよび練りわさびからなる群から選ばれる1種である、請求項1乃至3いずれか1項に記載の風味増強剤。 The flavor enhancer according to any one of claims 1 to 3, wherein the food is one selected from the group consisting of roux-using foods, sauces, soups, fillings and wasabi paste.
  5.  前記成分(A)の目開き3.35mmの篩の篩下かつ目開き0.15mmの篩の篩上の含有量が40質量%以上95質量%以下である、請求項1乃至4いずれか1項に記載の風味増強剤。 Any one of claims 1 to 4, wherein the content of the component (A) under a sieve having a mesh size of 3.35 mm and on a sieve having a mesh size of 0.15 mm is 40% by mass or more and 95% by mass or less. The flavor enhancer described in the section.
  6.  請求項1乃至5いずれか1項に記載の風味増強剤を食品素材に配合する工程を含む、食品の製造方法。 A method for producing a food product, which comprises a step of blending the flavor enhancer according to any one of claims 1 to 5 into a food material.
  7.  請求項1乃至5いずれか1項に記載の風味増強剤を前記食品に適用する工程を含む、食品の風味増強方法。 A method for enhancing the flavor of a food, which comprises a step of applying the flavor enhancing agent according to any one of claims 1 to 5 to the food.
  8.  当該風味増強方法が、後味の風味増強方法である、請求項7に記載の風味増強方法。 The flavor enhancing method according to claim 7, wherein the flavor enhancing method is an aftertaste flavor enhancing method.
PCT/JP2021/025492 2020-07-10 2021-07-06 Flavor enhancer WO2022009891A1 (en)

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JP5551846B1 (en) * 2013-02-26 2014-07-16 株式会社J−オイルミルズ Composition, clothing using the same, food and drink, and feed, and method for producing the composition
JP2018174925A (en) * 2017-04-19 2018-11-15 株式会社J−オイルミルズ Foods and manufacturing method thereof
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* Cited by examiner, † Cited by third party
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