WO2021240386A1 - Consumable article for an aerosol generating device - Google Patents

Consumable article for an aerosol generating device Download PDF

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Publication number
WO2021240386A1
WO2021240386A1 PCT/IB2021/054579 IB2021054579W WO2021240386A1 WO 2021240386 A1 WO2021240386 A1 WO 2021240386A1 IB 2021054579 W IB2021054579 W IB 2021054579W WO 2021240386 A1 WO2021240386 A1 WO 2021240386A1
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WO
WIPO (PCT)
Prior art keywords
article
positive
heating element
plate
capsule
Prior art date
Application number
PCT/IB2021/054579
Other languages
French (fr)
Inventor
Claude Zominy
Original Assignee
Jt International Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jt International Sa filed Critical Jt International Sa
Priority to CA3170468A priority Critical patent/CA3170468A1/en
Priority to EP21735391.1A priority patent/EP4156993A1/en
Priority to US17/927,044 priority patent/US20230200440A1/en
Publication of WO2021240386A1 publication Critical patent/WO2021240386A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40Constructional details, e.g. connection of cartridges and battery parts
    • A24F40/42Cartridges or containers for inhalable precursors
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/10Devices using liquid inhalable precursors
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/30Devices using two or more structurally separated inhalable precursors, e.g. using two liquid precursors in two cartridges
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/50Control or monitoring
    • A24F40/57Temperature control

Definitions

  • the present disclosure relates generally to aerosol or vapor generating systems and devices, more particularly to aerosol or vapor generating devices with consumable articles such as removable capsules or other liquid-containing devices for removable connection to an aerosol or vapor generating device.
  • aerosol generating systems and devices also known as e-cigarettes, e-cigs (EC), electronic nicotine delivery systems (ENDS), electronic non-nicotine delivery systems (ENNDS), electronic smoking devices (ESDs), personal vaporizers (PV), inhalation devices, vapes, which can be used as an alternative to conventional smoking articles such as lit-end cigarettes, cigars, and pipes, is becoming increasingly popular and widespread.
  • e-cigarette liquid also known as e-cigarette liquid, e-cig liquids, e-liquid, juice, vapor juice, smoke juice, e-juice, e-fluid, vape oil
  • condensation aerosol also called vapor
  • e-cigarettes are known in the art and on a general level they comprise a mouthpiece arranged in fluid communication with a cartridge, inserted in the mouthpiece or an e-cigarette body to which the mouthpiece is connectable.
  • a heating element is further arranged in an airflow path between an outlet of a liquid chamber in the cartridge and the mouthpiece to allow vaporization of the liquid contained in the chamber into an aerosol.
  • the heating element may be arranged in connection with the body of the e-cigarette or in the cartridge itself and is designed to be electrically connected in use to a power supply or source. Control circuits, sensors and/or switches may also be provided for an improved control of the e-cigarette and its power/heating management.
  • heating element arrangements are known from the prior art for such aerosol generating systems. Most commonly found heating elements comprise resistive elements such as metal wire coils, which heat upon electrical connection to up to 450°C to generate an aerosol. These heating elements are cheap and easy to implement but do not allow proper control of the heating temperature of the liquid.
  • US 2017/0333650 describes for example an elongated heating element formed by a resistive lamella extending longitudinally in a cartridge parallel to an airflow path of the cartridge.
  • US2014366898 discloses a cartridge comprising multiple stacked compartments each surrounded by a liquid barrier. Each compartment contains vaporizable material and an individual heater, and each compartment is removable. The individual compartments and heaters are arranged in a stacked-series configuration. The cartridge includes a single central airpath therethrough the stacked compartments. A circuitry controls the selection of the electronic heaters to be activated utilizing push button controls and a power supply is connected to the heater wire of each individual heater of the several compartments.
  • the known devices however may present several weaknesses.
  • the activation of individual heaters to heat each of the vaporizable materials is complicated and not practical for the user.
  • heater arrangements of known devices are suffering limitations with regard to the possibility to adjust the aerosol temperature along the air flow channel of a cartridge.
  • heater and electrical arrangements of known devices may add complexity and diminish reliability in the known devices, especially when they are implemented with multiple elements requiring a multiplicity of contacts. All these limitations have an impact on the consumer satisfaction from a user perspective.
  • An aim of the present invention is to propose a device and methods where a plurality of, possibly different, vaporizable material or products may be used in a simple manner, in the form of capsules pre-filled with the vaporizable material or products.
  • a cartomizer in the frame of the present invention is to be understood as a cartridge containing an aerosol-forming (also called “vaporizable") material (for example an e-liquid or a wax or a gel) combined with heating means for heating and evaporating the material contained in the cartridge.
  • an aerosol-forming (also called “vaporizable") material for example an e-liquid or a wax or a gel
  • heating means for heating and evaporating the material contained in the cartridge.
  • the cartomizer may contain a plurality of different materials as will be apparent from the following description and embodiments of the invention.
  • the present invention concerns a consumable article for an aerosol generating device, the article comprising at least two capsules, each configured to contain a vaporizable material, each configured to rotate relative to another capsule and each containing a heating element for aerosolising said vaporizable material through an electric actuation of the heating element, wherein the article comprises a positive pole bus and a negative pole bus, wherein each heating element is individually connected to said positive pole bus and to said negative pole bus through a positive contact and a negative contact of said heating element , wherein the relative position of the positive and negative contacts of the heating element with respect to the positive pole bus and negative pole bus allows to set the temperature of the heating element in use.
  • the relative position of the positive and negative contacts of each of the heating elements with respect to the positive and negative pole buses may define an electrical resistance of the heating element.
  • a movement, such as a rotation, of each capsule determines the relative position of the positive and negative contacts of each of the heating elements with respect to the positive and negative pole buses.
  • a predetermined relative position of the positive and negative contacts of each of the heating elements with respect to the positive and negative pole buses enable to disconnect one of the positive and negative contacts from its positive pole bus or negative pole bus, thereby disconnecting the heating element.
  • the capsules comprise at least one attachment means configured to connect one capsule to another so that they can rotate freely between them.
  • each capsule contains a different vaporizable material. In other embodiments, each capsule may contain the same vaporizable material. In other embodiments, some capsules may contain a same vaporizable material and other capsule(s) another vaporizable material.
  • the article and/orthe capsules comprise stopping means to block the movement of each capsule.
  • stopping means comprise mechanical stops.
  • Such stopping means may comprise molded protuberances on the walls of the article and/or capsule. In other embodiments, protuberances may be added parts on the article and/or capsule.
  • the heating elements comprise a C-shaped plate with an outer periphery and an opening and mesh material on at least one side of the disc plate.
  • An outer periphery of the disc- plate circumference is sandwiched between two parts of a carrier module in such away to contact the vaporizable material which surrounds the outersurface of the carrier module.
  • the vaporizable material enters the carrier module through the mesh material for example by capillarity and is then evaporated by the heat generated through the disc-shaped heating element.
  • the disc plate comprises means for holding the mesh material.
  • the mesh element may be attached to the disc element by means of crimping ears or other equivalent means such as clips, ears, lugs etc. or a combination thereof.
  • the disc-shaped element may preferably be realized as a C-shaped element, the extremities of which having the function of electrical contacts.
  • a heat gradient may be achieved in radial direction of the disc-shaped element between said outer periphery and said opening, the temperature being proportional to the current distribution, enabling a selective evaporation of substance provided in the vaporizable material.
  • the temperature gradient allows to have the higher temperature aligned with the temperature for the highest constituent in the e-liquid, such as about 200°C to 230°C, and the lowest value should be about room temperature, such as about 30°C, to avoid overheating the liquid in contact with the mesh. Accordingly, a temperature gradient will be about 170°C to 200°C.
  • other values may be possible depending on the conditions and the vaporizable material.
  • the opening is at the center of the plate.
  • a thickness of the plate measured in a transversal cross-section thereof perpendicular to sides of the plate is variable between the outer periphery of the plate to the opening.
  • the variable thickness gradually diminishes between the outer periphery and the opening.
  • a largest dimension of the opening is at most equal to a width of the plate, said width being measured from the outer periphery to an outer edge of the opening in a direction passing through the centre of the opening
  • the thickness profile of the disc plate diminishes to reach a sharp end or a flat end.
  • the disc plate is made for example of metal material and the mesh material is made for example of sintered or non-sintered metal fiber material or other porous materials
  • the disc plate material and mesh material must resist to typical temperatures used to vaporize e- liquid, i.e., should not deform.
  • Materials for the disc plate should be conductive and have a resistance as appropriate for implementing the heating with the current source available according to the principles of the present invention.
  • Typical non-limiting illustrative examples of materials are Nickel, Nichrome, Kanthal, Tungsten, stainless steel, and/or alloys of these materials.
  • each capsule are arranged such that the central opening from one heating element is aligned along a longitudinal axis with the opening of the other heating element, thereby defining an air flow channel.
  • the disc plate of the heating element is placed substantially perpendicularly to airflow
  • the present invention concerns an aerosol generating device comprising a consumable article as defined in the present application.
  • the consumable article may be a cartomizer.
  • a cartomizer in the frame of the present invention is to be understood as a cartridge containing an aerosol-forming material combined with heating means for heating and evaporating the material contained in the cartridge.
  • the present invention concerns an aerosol generating device, such as an e- cigarette, comprising an article as defined in the present application.
  • the device may be an e- cigarette for example.
  • FIGURE 1 illustrates an embodiment of an aerosol generating device according to the present invention.
  • FIGURE 2 illustrates a schematic top view of an embodiment of a capsule according to the present invention.
  • FIGURE 3 illustrates a schematic top view of an embodiment of a device according to the present invention.
  • FIGURES 4 - 6 illustrate schematic top views of embodiments of a consumable article according to the present invention.
  • FIGURE 7 illustrates a schematic top view of a heating element according to an embodiment of the present invention.
  • FIGURES 8A to 8C illustrate embodiments of disc plates according to the present invention.
  • FIGURE 9 illustrates an embodiment of a disc plate with a mesh material according to the present invention.
  • FIGURES 10A-10D illustrate embodiments of means to attach mesh material to a disc plate according to the present invention.
  • FIGURE 11A illustrates an embodiment of a consumable article according to the present invention in perspective and partial cut view.
  • FIGURE 11 B illustrates a top view of an embodiment of a consumable article according to the present invention.
  • FIGURE 11C illustrates an embodiment of a part of a consumable article according to the present invention in perspective and partial cut view.
  • FIGURE 11 D illustrates a cut view of the part of FIGURE 11C.
  • vaporizable material is used to designate any material that is vaporizable at a temperature up to 400°C, preferably up to 350°C, for example aerosol generating liquid, gel, wax and the like.
  • the aerosol generating device 1 comprises a body, which comprises at its distal end 2 for example an energy source (such as a battery), electronics forthe management of the device (IC, memory etc.), the body further containing at its proximal end (close to a mouthpiece 5) a consumable article such as a cartomizer2a a plurality of capsules 3 (in this nonlimiting example three capsules 3) that are stacked one onto the other, at least one common bus 4 and a mouthpiece 5.
  • the stacked capsules 3 form an airflow channel 6 through which a vapor 7 formed by heating of a vaporizable material, contained in the capsules 3 is directed into the mouthpiece 5 for inhalation by a user.
  • the capsules 3 comprise attachment means, such as clipping means, allowing them to be attached together.
  • attachment means such as clipping means, allowing them to be attached together.
  • the attachment means allow the capsule 3 to rotate freely once attached to each other.
  • FIG. 2 A top view of a capsule 3 is illustrated in figure 2.
  • the capsule 3 comprises a heating element 10 with electrical contacts 11 , 12 and first and second capsule stopper means 13,13a.
  • the heating element 10 will be described in more detail hereunder in the present application.
  • Figure 3 illustrates a top view of the proximal end of the consumable article 2a. It comprises two common bus bars: one positive pole bus bar 4a and one negative pole bus bar 4. Of course, the positive and negative poles may be inverted.
  • the proximal end also comprises first and second device stopper means 15, 15a. Stopper means 13,13a, 15, 15a may be molded protuberances for example.
  • Figure 4 illustrates a top view of a capsule 3 in the proximal end of a consumable article 2a.
  • the capsule is disconnected meaning only one electrical contact 12 is connected to the bus bar 4' and clockwise rotation of the capsule 3 with respect to the device 2 is prevented by the stopper means 13' and 15a. This eliminates the need for any On/Off switch separate from the capsule to disconnect the capsule.
  • Figure 5 illustrates another top view of a capsule 3 in the proximal end of a consumable article 2a of a device 1.
  • the capsule 3 is rotated counterclockwise with respect to the device 2 so that now both electrical contacts 11 and 12 are connected to the respective bus bars 4,4a.
  • the electrical path between the two bar bus contacts is the longest so that electrical resistance is higher, current is lower and temperature is lower in the heating element 10. This eliminates the need for any power distribution element that is separate from the capsule.
  • Figure 6 illustrates another top view of a capsule 3 in the proximal end of a consumable article 2a of a device 1.
  • the capsule 3 is further rotated counterclockwise so that both electrical contacts 11 and 12 are still connected to the respective bus bars 4, 4a but the electrical path between the two bar bus contacts is the shortest so that electrical resistance is lower, current is higher and the temperature is higher in the heating element 10.
  • Both stopping means 13, 15 are in contact so a further rotation of the capsule 3 is prevented. Accordingly, the disclosed construction and means allow in a simple way (by rotation of the capsule 3) to determine the temperature of the heating means that will be applied to the vaporizable material of the capsule.
  • the user may in a simple manner choose a desired position for each capsule 3 so that the proper temperature is applied to the vaporizable material of the respective capsule 3.
  • the temperature may depend for example on the vaporizable material (for example a set value or recommended value) or on the tastes of the user in case of an e-cigarette.
  • FIGS 7 to 10C illustrate in more detail embodiments of heating means that may be used with the capsules of the present invention.
  • the heating means comprise a heating disc plate 10 having a general C-shape as shown in figure 7.
  • the disc plate 10 comprises an opening 10a preferably placed at the center of the plate 10.
  • the disc plate 10 further comprises contacts 11 and 12, reference 11 illustrating a positive contact and reference 12 illustrating a negative contact.
  • the electrical contacts 11 , 12 may be integral with the plate 10 or may be attached and electrically connected to the plate 10.
  • one contact 11 or 12 may be integral with the plate 10 and the other contact 12 or 11 may be attached and electrically connected to the disc plate 10.
  • reference 11 may illustrate the negative contact and reference 12 the positive contact.
  • the temperature gradient is schematically illustrated with the lowest temperature at the periphery of the disc plate which is also the entry point of the vaporizable material as marked in figure 1 and the hottest zone being around the opening 10a of the disc plate 10.
  • a mesh is placed at least on one side of the disc plate as illustrated in figure 9 and 10A, 10C.
  • Figures 8A to 8C illustrates embodiment of the disc plate 10 in cross-section.
  • the disc plate 10 seen in transversal cross section taken along a central symmetry axis Z-Z’ passing through the centre of the opening 10a may present a different profile: for example in figure 8A, the profile is a constant thickness.
  • figure 8B another profile is shown whereby the thickness gradually diminishes between the outer periphery of the plate and the opening 10a to reach a sharp end forming a rim 11a of said opening 10a.
  • figure 8C another example is shown where the rim 11 a is formed of a flat and not a sharp one.
  • the angle a will be in a range from about 5° to about 45.
  • the transversal shape will have an effect on the heating time and the temperature gradient and the shape may be adjusted to reach a desired effect, for example a heating time and/or temperature or performance.
  • Figure 9 illustrates an example of a disc plate 10 with a mesh 14 in cross-section according to embodiments of the present invention.
  • the disc plate 10 of this figure corresponds to the embodiment of figure 8A for illustrative purposes and the disc plate 10 may also be as illustrated in figures 8B or 8C or another disc plate according to the present invention.
  • the mesh 14 may be on one side of the disc plate 10 or on both sides.
  • Figure 10A illustrates examples of means used to attach the mesh 14 to the disc plate 10.
  • clips 20 as illustrated on the left side of the assembly of the disc plate 10 and mesh 14, or a part 21 of the disc plate 10 as schematically illustrated on the right side of the assembly disc plate 10 and mesh 14.
  • the part 21 may be an ear of the disc plate 10 for example for crimping the mesh 14.
  • the means may be placed on the outer periphery of the disc plate 10 or they may be placed in the opening 10a or both.
  • one preferably uses more than one of said means, for example at least three clips 20 placed around the periphery of the disc plate and/or around the periphery of the opening 10a.
  • the same construction may be followed for the ears 21.
  • Other equivalent means may be envisaged and different means may be combined together as well.
  • Figures 10B illustrates a top view of a disc plate 10 with ears 21 on the outer periphery of the plate and ears 22 on the periphery of the opening 10a.
  • four ears 21 and three ears 22 are illustrated but less than four/three or more than four/three may be used.
  • the numbers of ears 21 and 22 may be the same or different.
  • the ears 21 , 22 may be replaced by clips 20, or one may use a combination of clips 20 and ears 21 , 22.
  • Figures 10C and 10D illustrate top view and side cut view of a disc plate 10 with a mesh 14 that is fixed by the ears 21 , 22.
  • the disc plate material and mesh material must resist to typical temperatures used to vaporize e-liquid, i.e. should not deform or be damaged/transformed by the temperature ofthe device.
  • Materials forthe disc plate should be conductive and have a resistance as appropriate for implementing the heating with the current source available according to the principles ofthe present invention.
  • Materials forthe mesh should be suitable forthe intended use and able to allow the vaporizable material to permeate through the mesh material by capillarity and to evaporate by the heat generated by means of the disc plate.
  • Materials include metals, alloys, mix therefrom and other equivalent materials such as Nickel, Nichrome, Kanthal, Tungsten, stainless steel, and/or alloys of these materials.
  • FIGS 11 A to 11D illustrate in more detail embodiments of a capsule 3 according to the present invention.
  • the capsule 3 comprises a clamping head 30 comprising several clipping ears 31. These clipping ears 31 have a spring effect and allow an assembly of two capsules 3 by insertion in internal cavity 32 of another capsule 3.
  • the internal cavity 32 is shaped to receive the ears 31 , as illustrated in figures 11A-11D.
  • the numbers of ears 31 may be less than four as illustrated in figure 11 B, for example three, or more than four.
  • These ears 31 allow an easy assembly and disassembly of capsules 30 to each other, while also allowing a relative rotation of the capsules 3.
  • Other equivalent means to the ears 31 are of course possible in the frame of the present invention for achieving the same result.
  • Figure 11C illustrates the internal cradle 35 with an upper cradle 36 and a lower cradle 37.
  • the internal cradle 35 is used to carry the heating element (disc 10 and mesh 14) and is in the capsule 3 as shown in figure 11 A.
  • Figure 11 D illustrates a partial cut view of the cradles 36, 36 and the contact zone between the mesh 14 and the reservoir 8 of the capsule containing the vaporizable material, such as an e- liquid, allowing the vaporizable material to permeate through the mesh material.
  • the vaporizable material such as an e- liquid

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Abstract

The present invention concerns a consumable article (2a) for an aerosol generating device (1), the article comprising at least two capsules (3) configured to contain a vaporizable material and each containing a heating element (10) for aerosolising said vaporizable material through an electric actuation of the heating element, wherein the article (2a) comprises a positive pole bus (4,4a) and a negative pole bus (4a, 4), wherein each heating element (10) is individually connected to said positive pole bus and to said negative pole bus (4,4a) through a positive contact (11) and a negative contact (12) of said heating element, wherein the relative position of the positive and negative contacts (11,12) of the heating element (10) with respect to the positive pole bus and negative pole bus (4,4a) allows to set the temperature of the heating element in use.

Description

CONSUMABLE ARTICLE FOR AN AEROSOL GENERATING DEVICE
TECHNICAL FIELD
The present disclosure relates generally to aerosol or vapor generating systems and devices, more particularly to aerosol or vapor generating devices with consumable articles such as removable capsules or other liquid-containing devices for removable connection to an aerosol or vapor generating device.
BACKGROUND
The use of aerosol generating systems and devices, also known as e-cigarettes, e-cigs (EC), electronic nicotine delivery systems (ENDS), electronic non-nicotine delivery systems (ENNDS), electronic smoking devices (ESDs), personal vaporizers (PV), inhalation devices, vapes, which can be used as an alternative to conventional smoking articles such as lit-end cigarettes, cigars, and pipes, is becoming increasingly popular and widespread. The most commonly used e- cigarettes are usually battery powered and use a resistance heating element to heat and atomize a liquid containing nicotine (also known as e-cigarette liquid, e-cig liquids, e-liquid, juice, vapor juice, smoke juice, e-juice, e-fluid, vape oil), to produce a condensation aerosol (often called vapor) which can be inhaled by a user.
These e-cigarettes are known in the art and on a general level they comprise a mouthpiece arranged in fluid communication with a cartridge, inserted in the mouthpiece or an e-cigarette body to which the mouthpiece is connectable. A heating element is further arranged in an airflow path between an outlet of a liquid chamber in the cartridge and the mouthpiece to allow vaporization of the liquid contained in the chamber into an aerosol. The heating element may be arranged in connection with the body of the e-cigarette or in the cartridge itself and is designed to be electrically connected in use to a power supply or source. Control circuits, sensors and/or switches may also be provided for an improved control of the e-cigarette and its power/heating management.
Various heating element arrangements are known from the prior art for such aerosol generating systems. Most commonly found heating elements comprise resistive elements such as metal wire coils, which heat upon electrical connection to up to 450°C to generate an aerosol. These heating elements are cheap and easy to implement but do not allow proper control of the heating temperature of the liquid.
Beyond wire coils, more sophisticated resistive heating elements comprising laminar components have also been proposed in the prior art. US 2017/0333650 describes for example an elongated heating element formed by a resistive lamella extending longitudinally in a cartridge parallel to an airflow path of the cartridge.
In the art, it is also known to provide e-cigarettes with cartridges containing several (different) e- liquids. US2014366898 for example discloses a cartridge comprising multiple stacked compartments each surrounded by a liquid barrier. Each compartment contains vaporizable material and an individual heater, and each compartment is removable. The individual compartments and heaters are arranged in a stacked-series configuration. The cartridge includes a single central airpath therethrough the stacked compartments. A circuitry controls the selection of the electronic heaters to be activated utilizing push button controls and a power supply is connected to the heater wire of each individual heater of the several compartments.
The known devices however may present several weaknesses. In particular, with existing devices where a plurality of vaporizable materials are present, the activation of individual heaters to heat each of the vaporizable materials is complicated and not practical for the user. Furthermore, heater arrangements of known devices are suffering limitations with regard to the possibility to adjust the aerosol temperature along the air flow channel of a cartridge. In addition, heater and electrical arrangements of known devices may add complexity and diminish reliability in the known devices, especially when they are implemented with multiple elements requiring a multiplicity of contacts. All these limitations have an impact on the consumer satisfaction from a user perspective.
SUMMARY
An aim of the present invention is to propose a device and methods where a plurality of, possibly different, vaporizable material or products may be used in a simple manner, in the form of capsules pre-filled with the vaporizable material or products.
A cartomizer in the frame of the present invention is to be understood as a cartridge containing an aerosol-forming (also called "vaporizable") material (for example an e-liquid or a wax or a gel) combined with heating means for heating and evaporating the material contained in the cartridge. In addition, the cartomizer may contain a plurality of different materials as will be apparent from the following description and embodiments of the invention.
On a general level, the present invention concerns a consumable article for an aerosol generating device, the article comprising at least two capsules, each configured to contain a vaporizable material, each configured to rotate relative to another capsule and each containing a heating element for aerosolising said vaporizable material through an electric actuation of the heating element, wherein the article comprises a positive pole bus and a negative pole bus, wherein each heating element is individually connected to said positive pole bus and to said negative pole bus through a positive contact and a negative contact of said heating element , wherein the relative position of the positive and negative contacts of the heating element with respect to the positive pole bus and negative pole bus allows to set the temperature of the heating element in use.
In embodiments the relative position of the positive and negative contacts of each of the heating elements with respect to the positive and negative pole buses may define an electrical resistance of the heating element.
In embodiments a movement, such as a rotation, of each capsule determines the relative position of the positive and negative contacts of each of the heating elements with respect to the positive and negative pole buses.
In embodiments a predetermined relative position of the positive and negative contacts of each of the heating elements with respect to the positive and negative pole buses, enable to disconnect one of the positive and negative contacts from its positive pole bus or negative pole bus, thereby disconnecting the heating element.
In embodiments the capsules comprise at least one attachment means configured to connect one capsule to another so that they can rotate freely between them.
In embodiments each capsule contains a different vaporizable material. In other embodiments, each capsule may contain the same vaporizable material. In other embodiments, some capsules may contain a same vaporizable material and other capsule(s) another vaporizable material.
In embodiments the article and/orthe capsules comprise stopping means to block the movement of each capsule.
In embodiments the stopping means comprise mechanical stops. Such stopping means may comprise molded protuberances on the walls of the article and/or capsule. In other embodiments, protuberances may be added parts on the article and/or capsule.
In embodiments the heating elements comprise a C-shaped plate with an outer periphery and an opening and mesh material on at least one side of the disc plate. An outer periphery of the disc- plate circumference is sandwiched between two parts of a carrier module in such away to contact the vaporizable material which surrounds the outersurface of the carrier module. The vaporizable material enters the carrier module through the mesh material for example by capillarity and is then evaporated by the heat generated through the disc-shaped heating element. In embodiments the disc plate comprises means for holding the mesh material. The mesh element may be attached to the disc element by means of crimping ears or other equivalent means such as clips, ears, lugs etc. or a combination thereof. The disc-shaped element may preferably be realized as a C-shaped element, the extremities of which having the function of electrical contacts. A heat gradient may be achieved in radial direction of the disc-shaped element between said outer periphery and said opening, the temperature being proportional to the current distribution, enabling a selective evaporation of substance provided in the vaporizable material. For example, the temperature gradient allows to have the higher temperature aligned with the temperature for the highest constituent in the e-liquid, such as about 200°C to 230°C, and the lowest value should be about room temperature, such as about 30°C, to avoid overheating the liquid in contact with the mesh. Accordingly, a temperature gradient will be about 170°C to 200°C. Of course, other values may be possible depending on the conditions and the vaporizable material.
In embodiments the opening is at the center of the plate.
In embodiments a thickness of the plate measured in a transversal cross-section thereof perpendicular to sides of the plate is variable between the outer periphery of the plate to the opening. Preferably, the variable thickness gradually diminishes between the outer periphery and the opening.
In embodiments a largest dimension of the opening is at most equal to a width of the plate, said width being measured from the outer periphery to an outer edge of the opening in a direction passing through the centre of the opening
In embodiments the thickness profile of the disc plate diminishes to reach a sharp end or a flat end.
In embodiments the disc plate is made for example of metal material and the mesh material is made for example of sintered or non-sintered metal fiber material or other porous materials The disc plate material and mesh material must resist to typical temperatures used to vaporize e- liquid, i.e., should not deform. Materials for the disc plate should be conductive and have a resistance as appropriate for implementing the heating with the current source available according to the principles of the present invention. Typical non-limiting illustrative examples of materials are Nickel, Nichrome, Kanthal, Tungsten, stainless steel, and/or alloys of these materials.
In embodiment the heating elements of each capsule are arranged such that the central opening from one heating element is aligned along a longitudinal axis with the opening of the other heating element, thereby defining an air flow channel. In embodiments the disc plate of the heating element is placed substantially perpendicularly to airflow
In embodiments the present invention concerns an aerosol generating device comprising a consumable article as defined in the present application. The consumable article may be a cartomizer. A cartomizer in the frame of the present invention is to be understood as a cartridge containing an aerosol-forming material combined with heating means for heating and evaporating the material contained in the cartridge.
In embodiments the present invention concerns an aerosol generating device, such as an e- cigarette, comprising an article as defined in the present application. The device may be an e- cigarette for example.
The above and other objects, features and advantages of the present invention and the manner of realizing them will become more apparent, and the invention itself will best be understood from a study of the following description with reference to the attached drawings showing some preferred embodiments of the invention.
BRIEF DESCRIPTION OF THE DRAWINGS
The accompanying drawings, which are incorporated herein and constitute part of this specification, illustrate embodiments of the invention, and together with the general description given above and the detailed description given below, explain features of the invention.
FIGURE 1 illustrates an embodiment of an aerosol generating device according to the present invention.
FIGURE 2 illustrates a schematic top view of an embodiment of a capsule according to the present invention.
FIGURE 3 illustrates a schematic top view of an embodiment of a device according to the present invention.
FIGURES 4 - 6 illustrate schematic top views of embodiments of a consumable article according to the present invention.
FIGURE 7 illustrates a schematic top view of a heating element according to an embodiment of the present invention. FIGURES 8A to 8C illustrate embodiments of disc plates according to the present invention.
FIGURE 9 illustrates an embodiment of a disc plate with a mesh material according to the present invention.
FIGURES 10A-10D illustrate embodiments of means to attach mesh material to a disc plate according to the present invention.
FIGURE 11A illustrates an embodiment of a consumable article according to the present invention in perspective and partial cut view.
FIGURE 11 B illustrates a top view of an embodiment of a consumable article according to the present invention.
FIGURE 11C illustrates an embodiment of a part of a consumable article according to the present invention in perspective and partial cut view.
FIGURE 11 D illustrates a cut view of the part of FIGURE 11C.
In the present application, identical reference numerals are used, where possible, to designate identical elements that are common to the figures. Also, the drawings are simplified for illustration purposes and may not be depicted to scale.
DETAILED DESCRIPTION OF SEVERAL EMBODIMENTS
In the following description, the principles the present invention will be detailed with reference to an e-cigarette, but they are not limited to this illustrative embodiment and applicable to other similar device which are suitable to use a consumable article with a vaporizable material.
The term vaporizable material is used to designate any material that is vaporizable at a temperature up to 400°C, preferably up to 350°C, for example aerosol generating liquid, gel, wax and the like.
In an embodiment, the aerosol generating device 1 comprises a body, which comprises at its distal end 2 for example an energy source (such as a battery), electronics forthe management of the device (IC, memory etc.), the body further containing at its proximal end (close to a mouthpiece 5) a consumable article such as a cartomizer2a a plurality of capsules 3 (in this nonlimiting example three capsules 3) that are stacked one onto the other, at least one common bus 4 and a mouthpiece 5. The stacked capsules 3 form an airflow channel 6 through which a vapor 7 formed by heating of a vaporizable material, contained in the capsules 3 is directed into the mouthpiece 5 for inhalation by a user.
The capsules 3 comprise attachment means, such as clipping means, allowing them to be attached together. In addition, the attachment means allow the capsule 3 to rotate freely once attached to each other.
A top view of a capsule 3 is illustrated in figure 2. The capsule 3 comprises a heating element 10 with electrical contacts 11 , 12 and first and second capsule stopper means 13,13a. The heating element 10 will be described in more detail hereunder in the present application.
Figure 3 illustrates a top view of the proximal end of the consumable article 2a. It comprises two common bus bars: one positive pole bus bar 4a and one negative pole bus bar 4. Of course, the positive and negative poles may be inverted. The proximal end also comprises first and second device stopper means 15, 15a. Stopper means 13,13a, 15, 15a may be molded protuberances for example.
Figure 4 illustrates a top view of a capsule 3 in the proximal end of a consumable article 2a. In the illustrated position, the capsule is disconnected meaning only one electrical contact 12 is connected to the bus bar 4' and clockwise rotation of the capsule 3 with respect to the device 2 is prevented by the stopper means 13' and 15a. This eliminates the need for any On/Off switch separate from the capsule to disconnect the capsule.
Figure 5 illustrates another top view of a capsule 3 in the proximal end of a consumable article 2a of a device 1. In the illustrated position, the capsule 3 is rotated counterclockwise with respect to the device 2 so that now both electrical contacts 11 and 12 are connected to the respective bus bars 4,4a. The electrical path between the two bar bus contacts is the longest so that electrical resistance is higher, current is lower and temperature is lower in the heating element 10. This eliminates the need for any power distribution element that is separate from the capsule.
Figure 6 illustrates another top view of a capsule 3 in the proximal end of a consumable article 2a of a device 1. In the illustrated position, with respect to figure 5, the capsule 3 is further rotated counterclockwise so that both electrical contacts 11 and 12 are still connected to the respective bus bars 4, 4a but the electrical path between the two bar bus contacts is the shortest so that electrical resistance is lower, current is higher and the temperature is higher in the heating element 10. Both stopping means 13, 15 are in contact so a further rotation of the capsule 3 is prevented. Accordingly, the disclosed construction and means allow in a simple way (by rotation of the capsule 3) to determine the temperature of the heating means that will be applied to the vaporizable material of the capsule. When the device 1 comprises several stacked capsules 3 as in figure 1 , the user may in a simple manner choose a desired position for each capsule 3 so that the proper temperature is applied to the vaporizable material of the respective capsule 3. The temperature may depend for example on the vaporizable material (for example a set value or recommended value) or on the tastes of the user in case of an e-cigarette.
Figures 7 to 10C illustrate in more detail embodiments of heating means that may be used with the capsules of the present invention.
In embodiments, the heating means according to the present application comprise a heating disc plate 10 having a general C-shape as shown in figure 7. The disc plate 10 comprises an opening 10a preferably placed at the center of the plate 10. The disc plate 10 further comprises contacts 11 and 12, reference 11 illustrating a positive contact and reference 12 illustrating a negative contact. The electrical contacts 11 , 12 may be integral with the plate 10 or may be attached and electrically connected to the plate 10. Alternatively, one contact 11 or 12 may be integral with the plate 10 and the other contact 12 or 11 may be attached and electrically connected to the disc plate 10. Also, reference 11 may illustrate the negative contact and reference 12 the positive contact.
In figure 7, the temperature gradient is schematically illustrated with the lowest temperature at the periphery of the disc plate which is also the entry point of the vaporizable material as marked in figure 1 and the hottest zone being around the opening 10a of the disc plate 10.
According to an embodiment of the present invention, a mesh is placed at least on one side of the disc plate as illustrated in figure 9 and 10A, 10C.
Figures 8A to 8C illustrates embodiment of the disc plate 10 in cross-section. According to these exemplary embodiments, the disc plate 10 seen in transversal cross section taken along a central symmetry axis Z-Z’ passing through the centre of the opening 10a may present a different profile: for example in figure 8A, the profile is a constant thickness. In figure 8B, another profile is shown whereby the thickness gradually diminishes between the outer periphery of the plate and the opening 10a to reach a sharp end forming a rim 11a of said opening 10a. In figure 8C, another example is shown where the rim 11 a is formed of a flat and not a sharp one. Considering an angle a defined between a median plane M of the disc plate 10 and a line parallel to the upper surface U or lower surface L of the disc intersecting the longitudinal axis Z-Z’ at the centre of the opening 11 , the angle a will be in a range from about 5° to about 45. In all these embodiments, the transversal shape will have an effect on the heating time and the temperature gradient and the shape may be adjusted to reach a desired effect, for example a heating time and/or temperature or performance.
Figure 9 illustrates an example of a disc plate 10 with a mesh 14 in cross-section according to embodiments of the present invention. The disc plate 10 of this figure corresponds to the embodiment of figure 8A for illustrative purposes and the disc plate 10 may also be as illustrated in figures 8B or 8C or another disc plate according to the present invention. The mesh 14 may be on one side of the disc plate 10 or on both sides.
Figure 10A illustrates examples of means used to attach the mesh 14 to the disc plate 10. For example, one may use clips 20 as illustrated on the left side of the assembly of the disc plate 10 and mesh 14, or a part 21 of the disc plate 10 as schematically illustrated on the right side of the assembly disc plate 10 and mesh 14. The part 21 may be an ear of the disc plate 10 for example for crimping the mesh 14. The means may be placed on the outer periphery of the disc plate 10 or they may be placed in the opening 10a or both. In order to maintain the mesh 14 on the disc plate 10, one preferably uses more than one of said means, for example at least three clips 20 placed around the periphery of the disc plate and/or around the periphery of the opening 10a. The same construction may be followed for the ears 21. Other equivalent means may be envisaged and different means may be combined together as well.
Figures 10B illustrates a top view of a disc plate 10 with ears 21 on the outer periphery of the plate and ears 22 on the periphery of the opening 10a. In this example, four ears 21 and three ears 22 are illustrated but less than four/three or more than four/three may be used. Also the numbers of ears 21 and 22 may be the same or different. The ears 21 , 22 may be replaced by clips 20, or one may use a combination of clips 20 and ears 21 , 22.
Figures 10C and 10D illustrate top view and side cut view of a disc plate 10 with a mesh 14 that is fixed by the ears 21 , 22.
According to the present invention, the disc plate material and mesh material must resist to typical temperatures used to vaporize e-liquid, i.e. should not deform or be damaged/transformed by the temperature ofthe device. Materials forthe disc plate should be conductive and have a resistance as appropriate for implementing the heating with the current source available according to the principles ofthe present invention. Materials forthe mesh should be suitable forthe intended use and able to allow the vaporizable material to permeate through the mesh material by capillarity and to evaporate by the heat generated by means of the disc plate. Materials include metals, alloys, mix therefrom and other equivalent materials such as Nickel, Nichrome, Kanthal, Tungsten, stainless steel, and/or alloys of these materials. Figures 11 A to 11D illustrate in more detail embodiments of a capsule 3 according to the present invention. The capsule 3 comprises a clamping head 30 comprising several clipping ears 31. These clipping ears 31 have a spring effect and allow an assembly of two capsules 3 by insertion in internal cavity 32 of another capsule 3. The internal cavity 32 is shaped to receive the ears 31 , as illustrated in figures 11A-11D. The numbers of ears 31 may be less than four as illustrated in figure 11 B, for example three, or more than four. These ears 31 allow an easy assembly and disassembly of capsules 30 to each other, while also allowing a relative rotation of the capsules 3. Other equivalent means to the ears 31 are of course possible in the frame of the present invention for achieving the same result.
Figure 11C illustrates the internal cradle 35 with an upper cradle 36 and a lower cradle 37. The internal cradle 35 is used to carry the heating element (disc 10 and mesh 14) and is in the capsule 3 as shown in figure 11 A.
Figure 11 D illustrates a partial cut view of the cradles 36, 36 and the contact zone between the mesh 14 and the reservoir 8 of the capsule containing the vaporizable material, such as an e- liquid, allowing the vaporizable material to permeate through the mesh material.
The present description is neither intended nor should it be construed as being representative of the full extent and scope of the present invention. The present invention is set forth in various levels of detail herein as well as in the attached drawings and in the detailed description of the invention and no limitation as to the scope of the present invention is intended by either the inclusion or non-inclusion of elements, components, etc. Additional aspects of the present invention have become more readily apparent from the detailed description, particularly when taken together with the drawings.
Moreover, exemplary embodiments have been described to provide an overall understanding of the principles of the structure, function, manufacture, and use of the systems and methods disclosed herein. One or more examples of these embodiments are illustrated in the accompanying drawings. Those skilled in the art will understand that the systems and methods specifically described herein and illustrated in the accompanying drawings are non-limiting exemplary embodiments and that the scope of the present invention is defined not solely by the claims. The features illustrated or described in connection with an exemplary embodiment may be combined with the features of other embodiments. Such modifications and variations are intended to be included within the scope of the present invention. A number of problems with conventional methods and systems are noted herein and the methods and systems disclosed herein may address one or more of these problems. By describing these problems, no admission as to their knowledge in the art is intended. A person having ordinary skill in the art will appreciate that, although certain methods and systems are described herein with respect to embodiments of the present invention, the scope of the present invention is not so limited. Moreover, while this invention has been described in conjunction with a number of embodiments, it is evident that many alternatives, modifications and variations would be or are apparent to those of ordinary skill in the applicable arts. Accordingly, it is intended to embrace all such alternatives, modifications, equivalents and variations that are within the spirit and scope of this invention.

Claims

1 . A consumable article (2a) for an aerosol generating device (1), the article comprising at least two capsules (3), each configured to contain a vaporizable material, each configured to rotate relative to another capsule and each containing a heating element (10) for aerosolising said vaporizable material through an electric actuation of the heating element, wherein the article (2a) comprises a positive pole bus (4,4a) and a negative pole bus (4a, 4), wherein each heating element (10) is individually connected to said positive pole bus and to said negative pole bus (4,4a) through a positive contact (11) and a negative contact (12) ofsaid heating element, wherein the relative position ofthe positive and negative contacts (11 ,12) of the heating element (10) with respect to the positive pole bus and negative pole bus (4,4a) allows to set the temperature ofthe heating element in use.
2. The article as defined in claim 1 , wherein the relative position ofthe positive and negative contacts (11 ,12) of each of the heating elements (10) with respect to the positive and negative pole buses (4,4a) defines an electrical resistance ofthe heating element (10).
3. The article as defined in claim 1 or 2, wherein the rotation ofthe capsules (3) determines the relative position ofthe positive and negative contacts (11 ,12) of each ofthe heating elements (10) with respect to the positive and negative pole buses (4,4a).
4. The article as defined in one of the preceding claims, wherein a predetermined relative position of the positive and negative contacts (11 ,12) of each of the heating elements (10) with respect to the positive and negative pole buses (4,4a), enables to disconnect one of the positive and negative contacts from its positive pole bus or negative pole bus, thereby disconnecting the heating element (10).
5. The article as defined in one ofthe preceding claims, wherein the capsules (3) comprise at least one attachment means configured to connect one capsule to another so that they can rotate freely between them.
6. The article as defined in one ofthe preceding claims, wherein each capsule (3) contains a different vaporizable material.
7. The article as defined in one ofthe preceding claims, wherein said article (2a) and/or said capsules (3) comprise stopping means (13,13a, 15, 15a) to block the movement of each capsule.
8. The article as defined in the preceding claim, wherein the stopping means comprise mechanical stops.
9. The article as defined in one of claims 6-8, wherein each heating element comprises a C- shaped plate (10) with an outer periphery and a central opening and mesh material (14) on at least one side of the plate, wherein the outer periphery of the plate (10) and the mesh material (14) are configured to be in contact with vaporizable material (21).
10. The article as defined in the preceding claim, wherein the plate (10) comprises means for holding the mesh material (20,21 ,22).
11. The article according to claim 9 or 12, wherein a thickness of the plate (10) measured in a transversal cross-section thereof perpendicular to sides of the plate is variable between from the outer periphery of the plate to the opening (10a), and preferably gradually reduces from the outer periphery to the opening (10a).
12. The article as defined in one of the preceding claims 9 to 11 , wherein a largest dimension of the opening (11) is at most equal to a width of the plate (10), said width being measured from the outer periphery to an outer edge of the opening in a direction passing through the centre of the opening
13. The article as defined in one of the preceding claims 10 to 15, wherein the disc plate (10) is made of a metal and the mesh material is made of a metal, sintered or not, such as nickel, nichrome, kanthal, tungsten, stainless steel.
14. The article as defined in the preceding claims, wherein the heating elements of each capsule are arranged such that the central opening from one heating element is aligned along a longitudinal axis with the opening of the other heating element, thereby defining an air flow channel (6).
15. An aerosol generating device (1) comprising an article (2a) as defined in one of the preceding claims, wherein the positive and negative pole buses are connected to a power supply.
PCT/IB2021/054579 2020-05-28 2021-05-26 Consumable article for an aerosol generating device WO2021240386A1 (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140261408A1 (en) * 2013-03-15 2014-09-18 R.J. Reynolds Tobacco Company Cartridge for an aerosol delivery device and method for assembling a cartridge for a smoking article
US20140366898A1 (en) 2013-06-14 2014-12-18 Ploom, Inc. Multiple heating elements with separate vaporizable materials in an electric vaporization device
WO2015076515A1 (en) * 2013-11-22 2015-05-28 박선순 Multi-purpose and multi-functional health care steam inhaler having assembly type multi-cartomizer coupled in shared manner to smart phone
US20160366940A1 (en) * 2014-02-28 2016-12-22 Kimree Hi-Tech Inc. Electronic cigarette and electronic cigarette atomization control method
US20170333650A1 (en) 2014-12-11 2017-11-23 Nicoventures Holdings Limited Aerosol provision systems
US20180027876A1 (en) * 2016-07-28 2018-02-01 Rai Strategic Holdings, Inc. Aerosol delivery devices including a selector and related methods

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140261408A1 (en) * 2013-03-15 2014-09-18 R.J. Reynolds Tobacco Company Cartridge for an aerosol delivery device and method for assembling a cartridge for a smoking article
US20140366898A1 (en) 2013-06-14 2014-12-18 Ploom, Inc. Multiple heating elements with separate vaporizable materials in an electric vaporization device
WO2015076515A1 (en) * 2013-11-22 2015-05-28 박선순 Multi-purpose and multi-functional health care steam inhaler having assembly type multi-cartomizer coupled in shared manner to smart phone
US20160366940A1 (en) * 2014-02-28 2016-12-22 Kimree Hi-Tech Inc. Electronic cigarette and electronic cigarette atomization control method
US20170333650A1 (en) 2014-12-11 2017-11-23 Nicoventures Holdings Limited Aerosol provision systems
US20180027876A1 (en) * 2016-07-28 2018-02-01 Rai Strategic Holdings, Inc. Aerosol delivery devices including a selector and related methods

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