WO2021238811A1 - Metal-air battery - Google Patents

Metal-air battery Download PDF

Info

Publication number
WO2021238811A1
WO2021238811A1 PCT/CN2021/095305 CN2021095305W WO2021238811A1 WO 2021238811 A1 WO2021238811 A1 WO 2021238811A1 CN 2021095305 W CN2021095305 W CN 2021095305W WO 2021238811 A1 WO2021238811 A1 WO 2021238811A1
Authority
WO
WIPO (PCT)
Prior art keywords
cover
metal
protrusion
cavity
air
Prior art date
Application number
PCT/CN2021/095305
Other languages
French (fr)
Chinese (zh)
Inventor
易祖成
吴辉
Original Assignee
湖南西瑞尔新材料科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 湖南西瑞尔新材料科技有限公司 filed Critical 湖南西瑞尔新材料科技有限公司
Publication of WO2021238811A1 publication Critical patent/WO2021238811A1/en

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to the field of batteries, in particular to a metal-air battery.
  • Metal-air batteries use metals with relatively negative electrode potentials, such as magnesium, aluminum, zinc, mercury, iron, etc., as the negative electrode, and oxygen or pure oxygen in the air as the positive electrode. It has the advantages of high specific energy, low price and stable performance.
  • the metal-air battery usually has an accommodating cavity to contain the electrolyte solution, and the metal electrode plate is inserted into it.
  • the metal electrode plate is a consumable and needs to be replaced frequently. In the traditional metal-air battery, it is troublesome to replace the metal electrode plate and the operation is cumbersome.
  • the present invention aims to solve at least one of the technical problems existing in the prior art. For this reason, the present invention proposes a metal-air battery, which can easily replace the metal electrode plate.
  • a metal-air battery includes: a base case with a cavity, and an upper end of the outer wall has a buckle groove, the front and rear sides of the cavity and the upper end are both openings; two first air electrode films, It is attached to the front and rear sides of the cavity and is in contact with the outside air; two side plates are respectively connected to the front and rear sides of the base shell for pressing the first air electrode film to seal the front and rear sides of the cavity; the metal electrode cover, The cover is arranged at the opening at the upper end of the cavity, and the bottom is provided with a metal electrode plate inserted into the cavity; the base cover, the outer wall is movably provided with a buckle matching the buckle groove, and the buckle is buckled in the buckle groove to realize the base cover and the base shell Connect and press the metal electrode cover to achieve the sealing of the upper end of the cavity.
  • a metal-air battery has at least the following technical effects: the upper end of the cavity is covered by a metal electrode cover, and the metal electrode plate is inserted into the cavity. When the metal electrode plate needs to be replaced, the metal is directly taken out.
  • the electrode cover is sufficient, and the metal electrode cover realizes the position fixation and the sealing of the cavity through the pressing of the base cover.
  • the base cover is buckled on the base shell by a buckle, and the buckle is only required to be released from the buckle groove to realize the base cover Disassembly, and because the metal electrode cover is not connected by fasteners, it can be taken out directly, and it is convenient and simple to replace the metal electrode plate.
  • the base housing includes two half-shells, the two half-shells are symmetrically arranged and connected by fasteners, and the two first air electrode membranes are attached to the two half-shells. On the opposite side.
  • a second air electrode film is installed on the opposite sides of the two half-shells, and the half-shells and the corresponding first air electrode film and the second air electrode film form an electrolyte accommodating cavity,
  • the two half shells are formed with a first vent hole between the two second air electrode films so that the second air electrode film can be in contact with external air.
  • the upper end of the base case has a sunken first bonding surface
  • the metal electrode cover is bonded to the first bonding surface
  • a first sealing ring is embedded in the first bonding surface
  • the base cover includes a top cover and a bottom cover, the bottom cover is connected to the bottom of the top cover, and the bottom of the bottom cover abuts against the metal electrode cover and presses the metal electrode cover.
  • the middle of the metal electrode cover has a first protrusion protruding upward, the first protrusion passes through the bottom cover, and the center of the first protrusion has a through liquid filling port,
  • the top cover is provided with a downwardly convex sealing protrusion corresponding to the first protrusion, and the sealing protrusion abuts against the first protrusion and seals the filling port.
  • the bottom cover is provided with an upwardly protruding second protrusion corresponding to the sealing protrusion, and the center of the second protrusion has a central hole for the first protrusion to penetrate.
  • the bottom of the protrusion is at least partially embedded in the second protrusion.
  • a second sealing ring is sandwiched between the sealing protrusion and the first protrusion.
  • the outer end edge of the opening at the front and rear sides of the cavity has an annular bonding surface for bonding the first air electrode film
  • the side plate is provided with the side facing the opening with the
  • the annular pressing surface corresponds to the annular pressing surface
  • the annular pressing surface is provided with a number of blind holes
  • the side plate is provided with a second vent hole
  • the second vent hole is located in the surrounding of the annular pressing surface
  • a compression frame is sandwiched between the annular pressing surface and the annular bonding surface, and the compression frame is used to press the first air electrode under the pressing of the annular pressing surface of the side plate
  • the membrane is compressed on the annular fitting surface
  • a pre-tensioning spring is installed in the blind hole, and the pre-tensioning spring is used to apply an elastic pre-tensioning force to the compression frame to push it to the annular fitting surface.
  • the compression frame protrudes toward the side plate and is formed with a positioning post corresponding to the blind hole, and the positioning post is inserted into the blind hole and can extend along the blind hole. slide.
  • FIG. 1 is a schematic diagram of the structure in an exploded state of an embodiment of the present invention
  • Figure 2 is an internal cross-sectional view of an embodiment of the present invention.
  • Figure 3 is a schematic diagram of the exploded structure of the base cover
  • Figure 4 is an internal cross-sectional view of the base cover
  • Figure 5 is a schematic diagram of the structure of the base shell in an exploded state
  • Figure 6 is a schematic diagram of the structure of the half shell
  • Figure 7 is a schematic diagram of the structure of the side plate and the compression frame
  • Figure 8 is a structural schematic diagram of the side plate, the compression frame and the pre-tensioned spring in an exploded state
  • Figure 9 is a schematic diagram of the structure of the compression frame
  • Figure 10 is a schematic view of the front structure of the side plate
  • Fig. 11 is an enlarged view of A in Fig. 2;
  • Fig. 12 is an enlarged view of B in Fig. 2.
  • the second air electrode film 600 The second air electrode film 600.
  • connection should be interpreted broadly unless otherwise clearly specified and limited. For example, they can be fixed or detachable. Connected or integrally connected; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, and it can be the internal communication between two components.
  • connection should be interpreted broadly unless otherwise clearly specified and limited. For example, they can be fixed or detachable. Connected or integrally connected; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, and it can be the internal communication between two components.
  • connection can be fixed or detachable. Connected or integrally connected; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, and it can be the internal communication between two components.
  • the base case 100 has a cavity 110, and the upper end of the outer wall has a buckle groove 120, the front and rear sides and upper ends of the cavity 110 are open, and the buckle groove 120 is provided On the left and right side walls of the base shell 100.
  • the two first air electrode films 300 are attached to the front and rear sides of the cavity 110 and are in contact with the outside air; the two side plates 200 are respectively connected to the front and rear sides of the base shell 100 for pressing the first air electrode films 300 to achieve alignment.
  • the front and rear sides of the cavity 110 are sealed; the side plate 200 is detachably installed on the base shell 100 by fasteners.
  • the metal electrode cover 400 is disposed at the opening at the upper end of the cavity 110, and a metal electrode plate 410 inserted into the cavity 110 is provided at the bottom.
  • the outer wall of the base cover 500 is movably provided with a buckle 501 matching the buckle groove 120.
  • the buckle 501 is buckled in the buckle groove 120 to realize the connection between the base cover 500 and the base case 100, and the metal electrode cover 400 is pressed to achieve the cavity Seal at the upper end of 110.
  • the design of the buckle 501 and the buckle groove 120 facilitates the disassembly of the base cover 500.
  • the metal electrode cover 400 can be directly taken out, and the metal electrode cover 400 is pressed by the base cover 500 to achieve position fixation and sealing of the cavity.
  • the cover 500 is buckled on the base shell 100 by a buckle, and the buckle can be removed from the buckle groove.
  • the metal electrode cover can be taken out directly because it is not connected by fasteners. It is convenient and simple to replace the metal electrode plate. .
  • the base shell 100 includes two half shells 101, the two half shells 101 are symmetrically arranged and connected by fasteners, and the two first air electrode films 300 are attached On the opposite side of the two half-shells 101.
  • the two half-shells 101 are arranged opposite to each other, and the two half-shells 101 are provided with corresponding first connecting holes 134, and a connecting rod 103 is inserted into the first connecting hole 134.
  • the ends of the rod 103 There are threaded holes, and two first screws 104 correspondingly penetrate through the first connecting holes 134 of the two half-shells 101 and are connected with the threaded holes at the two ends of the round rod 103 and tightened, so that the two half-shells 101 are tightly tightened. Split together to form the base shell 100 and the cavity 110.
  • the second air electrode film 600 is installed on the opposite sides of the two half-shells 101, and the half-shell 101 and the corresponding first air electrode film 300 and the second air electrode film 600 form an electrolyte containment.
  • Cavities 190 as shown in FIG. 2, each of the two half-shells 101 forms two electrolyte accommodating cavities 190, and the metal electrode plate 410 has a plurality of them and is inserted into the two electrolyte accommodating cavities 190, respectively.
  • Such a plurality of air electrode films 600 and metal electrode plates 410 can increase the power of the battery.
  • the two half shells 101 are formed with a first vent hole 170 between the two second air electrode films 600 so that the second air electrode film 600 can be in contact with the outside air.
  • a closed cavity 180 is formed between the second air electrode membrane 600 and the half shell 101, and the first vent 170 allows the closed cavity 180 to communicate with the outside air.
  • the first vent hole 170 is formed by combining the concave holes 171 at the joint of the half shell 101.
  • the opposite sides of the two half-shells 101 are provided with a first stepped surface 160 that sinks inward, and the second air electrode film 600 is attached to the first stepped surface 160.
  • the two second A pressing member 700 is arranged between the outer circumference of the air electrode film 600. Under the action of the two half-shells 101 being screwed to each other, the pressing member 700 applies pressure to the second air electrode film 600 on both sides to ensure the second air electrode.
  • the film 600 is bonded to the first step surface 160 in a sealed manner.
  • the upper end of the base shell 100 has a sinking first bonding surface 102, that is, the upper end of the base shell 100 has a sinking step, and the metal electrode cover 400 is embedded in the sinking step and is attached to the first A bonding surface 102, and the first bonding surface 102 is embedded with a first sealing ring 430, the sealing effect can be ensured by the bonding of the metal electrode cover 400 to the first bonding surface 102 and the first sealing ring 430 .
  • the base cover 500 includes a top cover 510 and a bottom cover 520.
  • the bottom cover 520 is connected to the bottom of the top cover 510.
  • the cover 520 is embedded in the step at the upper end of the base shell 100, and the buckle 501 is pivotally connected to the left and right sides of the top cover 510 through a pivot shaft.
  • the bottom cover 520 and the top cover 510 form a cavity, which is used to place the electrical control components of the metal-air battery and serve as a circuit integration area.
  • the air electrode film and the metal electrode plate 410 both pass through the corresponding structure through conductive wires. Enter into the cavity for corresponding arrangement.
  • a number of threaded mounting holes 522 are provided around the bottom cover 520, and the top cover 510 is correspondingly provided with a second connecting hole 512.
  • the second screw 530 is connected in the threaded mounting hole 522 and penetrates the second connecting hole 512.
  • the diameter of the second connecting hole 512 is larger than that of the second screw 530.
  • the part where the second screw penetrates into the second connecting hole 512 is covered with a rubber sleeve 531.
  • the rubber sleeve 531 is connected with the second connecting hole 512 by interference fit to realize the bottom cover 520.
  • the connection of the top cover 510 When disassembling, the second screw 530 does not need to be screwed, only the tightening force is overcome, and the bottom cover 520 and the top cover 510 are separated, which is convenient for disassembly.
  • the middle of the metal electrode cover 400 has a first protrusion 420 protruding upward, the first protrusion 420 passes through the bottom cover 520, and the center of the first protrusion 420 has a through liquid filling port 421.
  • the liquid filling port 421 is in communication with the cavity 110. Specifically, the liquid filling port 421 is in communication with the electrolyte accommodating cavity 190 to facilitate the addition of electrolyte liquid.
  • the top cover 510 is provided with a sealing protrusion 511 protruding downward corresponding to the first protrusion 420, and the sealing protrusion 511 abuts against the first protrusion 420 to seal the filling port 421. When the top cover 510 is removed, liquid can be added to the inside without removing the metal electrode cover 400, which is more convenient.
  • the bottom surface of the metal electrode cover 400 is provided with a clamping block 440 corresponding to the metal electrode plate 410.
  • the upper end of the metal electrode plate 410 is inserted into the clamping block 440, in order to provide better support for the metal electrode plate 410 and avoid metal electrodes.
  • the plate 410 is separated from the clamping block 440, the bottom of the cavity 110 is provided with a supporting plate 150 corresponding to the metal electrode plate 410, and the supporting plate 150 is provided with a V-shaped groove for the metal electrode plate 410 to be embedded.
  • a second sealing ring 540 is sandwiched between the sealing protrusion 511 and the first protrusion 420 to improve the sealing effect.
  • the bottom cover 520 is provided with a second protrusion 521 protruding upward corresponding to the sealing protrusion 511, and the center of the second protrusion 521 has a central hole 523 for the first protrusion 420 to penetrate.
  • the bottom of the sealing protrusion 511 is at least partially embedded in the second protrusion 521. The cooperation of the second protrusion 521 and the sealing protrusion 511 can achieve a certain positioning effect when the bottom cover 520 and the top cover 510 are installed in position.
  • the outer edges of the openings on the front and rear sides of the cavity 110 have a circular bonding surface for bonding the first air electrode film 300
  • the side plate 200 is provided with a circular bonding surface on the side facing the opening.
  • the ring-shaped pressing surface corresponding to the mating surface, the ring-shaped bonding surface surrounds the outer edge of the opening, and the first air electrode film 300 and the ring-shaped bonding surface are in close contact to seal the cavity side wall.
  • the annular pressing surface is provided with a number of blind holes 211
  • the side plate 200 is provided with a second vent hole 220
  • the second vent hole 220 penetrates the side plate 200
  • the second vent hole 220 is located in the surrounding range of the annular pressing surface.
  • the air hole 220 is used to pass external air into the surface of the first air electrode film 300; a pressing frame 260 is sandwiched between the annular pressing surface and the annular bonding surface, and the outline of the tight frame 260 corresponds to the annular bonding surface.
  • the contour of the inner ring of the compression frame 260 matches the corresponding opening edge.
  • the pressing frame 260 is located between the annular pressing surface and the annular bonding surface, and the pressing frame 260 is used to press the first air electrode film 300 on the annular bonding surface under the pressing of the annular pressing surface of the side plate 200 , The sealed connection of the first air electrode film 300 is realized.
  • a pre-tensioning spring 270 is installed in the blind hole 211, and the pre-tensioning spring 270 is used to apply an elastic pre-tensioning force to the pressing frame 260 to push it to the annular contact surface.
  • the ring-shaped bonding surface to bond the first air electrode film to ensure a good seal bonding, and use the ring-shaped pressing surface to press the compression frame against the first air electrode film to make the first air electrode film tightly close to the ring-shaped bonding surface
  • the pre-tensioning spring can provide a good pre-tensioning force, so that the compression frame still compresses the air battery membrane, unlike the prior art, When the side plate is slightly loosened, it will lose its pressing effect on the first air electrode membrane; in addition, the outward pushing force of the spring on the side plate will hold the side plate tight and play a certain role in preventing loosening; this application can be very good Prevent loosening and leakage
  • the annular bonding surface is a second step surface 140 formed by recessing the outer end surface of the opening edge inward, that is, a step plane formed by a step that sinks inward.
  • the air battery film 300 is embedded in the step formed by the recess and is attached to the second step surface 140. The step can limit the air battery film 300 and improve its installation accuracy.
  • the base shell 100 is provided with a mounting plane 130 on the peripheral side of the opening.
  • the mounting plane 130 is provided on the left and right sides, and the side plate 200 is provided with mounting fittings corresponding to the mounting plane 130.
  • the surface 241, the mounting surface 241 and the mounting plane 130 are provided with corresponding mounting holes to be connected and fixed by fasteners.
  • a number of first mounting holes 250 are provided on the mounting surface 241, and a number of second mounting holes 131 are correspondingly provided on the mounting plane 130.
  • the first mounting holes 250 and the second mounting holes 131 are aligned one by one and are fitted with
  • the third screw 133 and the second mounting hole 131 are threaded holes matching the third screw 133.
  • the close connection between the base shell 100 and the side plates is realized by surface-to-surface bonding.
  • an outward pushing force can be applied to the third screw 133 to tighten the third screw 133, which can prevent the third screw from loosening, prevent the side plate 200 from loosening, and improve the sealing stability.
  • the mounting surface 241 is provided with a raised limiting protrusion 240
  • the mounting plane 130 is provided with a limiting hole 132 into which the limiting protrusion 240 is inserted, passing through the limiting protrusion 240 Insert the limit hole 132 to realize the positioning and installation of the side plate 200 and the base shell 100. It is also possible to insert the limit protrusion 240 into the limit hole 132 and then screw the third screw to a certain extent during installation. The installation effect facilitates the alignment of the first installation hole 250 with the second installation hole 131, which makes the installation of the side plate 200 more convenient. It can be understood that the inner end edge of the limiting protrusion 240 is chamfered to facilitate insertion into the positioning hole.
  • an inwardly recessed groove is provided on the annular bonding surface, and a first sealing ring 141 is embedded in the groove.
  • the first sealing ring 141 improves the air battery membrane 300 and the annular adhesive The sealing performance of the joint surface.
  • the inner wall of the side plate 200 is provided with a protruding pressing frame 210 corresponding to the annular fitting surface, and the annular pressing surface is the inner surface of the pressing frame 210, that is, as shown in FIG. 5 Frame inner surface 213.
  • the blind hole 211 is formed by the inner surface of the pressing frame 210 extending outward.
  • the blind holes 211 are arranged along the contour of the pressing frame 210.
  • the second vent hole 220 is located within the frame selection range of the pressure frame 210.
  • the pressure frame 210 protrudes and forms an inwardly opening vent space 201 with the inner wall of the side plate 200.
  • the second vent hole 220 communicates with the vent space 201 to Air is introduced into the ventilation space 201, so that the air is in full contact with the electrode air film 300.
  • the pressure frame 210 of the present application only presses the side of the electrode air film to form
  • the vented space 201 can increase the contact area between the air and the electrode air film, and improve the battery performance. It can be understood that the opening is rectangular, correspondingly, the first air electrode film is also rectangular, and the pressing frame 210 is a rectangular frame to press the edge of the first air electrode film 300 correspondingly.
  • the compression frame 260 protrudes toward the side plate 200 to form a positioning post 261 corresponding to the blind hole 211.
  • the positioning post 261 is inserted into the blind hole 211 and can slide along the blind hole 211.
  • the blind hole 211 corresponds to the position of the positioning post 261 and the cross section is matched.
  • the positioning post 261 and the blind hole 211 can realize the alignment installation of the compression frame 260 and the compression frame 210.
  • the cooperation of the positioning post 261 and the blind hole 211 can also realize the sliding guide of the compression frame 260, and improve the stability of the relative position of the two.
  • the center of the positioning column 261 has a spring accommodating groove 262, the spring accommodating groove 262 is formed by extending the outer end surface of the positioning column 261 inward, and the spring accommodating groove 262 opens outward. It can be understood that the spring accommodating groove 262 is coaxial with the positioning column 261.
  • the pressing frame 260 is a rectangular frame to correspond to the rectangular first air electrode film.
  • the pre-tensioning spring 270 is placed in the spring accommodating groove 262 and the blind hole 211, that is, the pre-tensioning spring 270 is partially embedded in the spring accommodating groove 262, and partially protruding out of the spring accommodating groove 262 is placed in the blind hole 211.
  • the spring accommodating groove 262 and the blind hole 211 provide a better accommodating space for the pretension spring 270, and can limit the pretension spring 270 to a certain extent, so that the installation of the pretension spring 270 is also convenient.
  • the pretension spring 270 is a compression spring. One end of the pretension spring 270 abuts against the bottom of the spring accommodating groove 262, and the other end abuts against the bottom of the blind hole 211.
  • the pretension spring 270 is provided with the spring accommodating groove 262 and the blind hole. 211 axis parallel elasticity. When the pressing frame 260 is in contact with the pressing frame 210, the pre-tensioning spring 270 exerts an elastic force on the pressing frame 260 to push it away from the pressing frame 210.
  • the pressing frame 260 is pressed against the first air electrode film by the pressing frame 210 to realize the pressing and fixing of the first air electrode film, and the sealing contact between the first air electrode film and the base case is realized.
  • the pressing frame and the pressing frame 260 are in surface-to-surface contact with the first air electrode film, and the force distribution is balanced, and the sealing effect will not deteriorate due to partial depression and deformation due to point force.
  • the outer wall of the positioning post 261 and the blind hole 211 are in clearance fit.
  • the positioning post 261 and the blind hole 211 are cylindrical.
  • the bottom of the blind hole 211 has a vent hole 212 penetrating the side plate 200, and the vent hole 212 is located on the bottom wall of the blind hole 211 facing outward, so that the blind hole 211 and the side plate 200 The outside air is connected. Since the positioning post 261 and the blind hole 211 match, when the positioning post 261 is pressed into the blind hole 211, the air in it will be compressed, causing the insertion to be blocked. If the air overflow speed is not enough, there will still be a large air resistance. The pressure relief hole 212 can discharge the excess air to the outside to achieve the pressure relief effect, making the positioning post 261 more smoothly inserted and increasing the installation speed And efficiency.
  • the length of the positioning post 261 is less than the depth of the blind hole 211, which can prevent the positioning post 261 from abutting the bottom wall of the blind hole 211, causing structural interference, and avoiding the compression frame 210 and the compression frame
  • the inability of 260 to contact causes the contact surface between the pressing frame 210 and the pressing frame 260 to decrease, so that the pressure of the pressing frame 210 on the pressing frame 260 is not evenly distributed.
  • staggered ribs 230 are arranged in the frame selection area of the pressing frame 210, and the ribs 230 strengthen the structural strength of the side plate 200 to avoid damage caused by stress. As shown in Figs. 4 and 5, the side plate 200 is arched outward at the position of the pressing frame 210, so that the position is easily damaged by compression, and the reinforcing rib 230 can effectively strengthen the structural strength of the area.
  • both sides of the outer wall of the side plate 200 have hand-pull grooves 280 recessed toward the center, which facilitates the pulling down of the side plate 200 when the side plate 200 is removed.
  • the outer wall of the side plate 200 has a nameplate installation groove 290 recessed inward, and the nameplate can be installed to display the manufacturing information of the metal-air battery.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Hybrid Cells (AREA)

Abstract

Disclosed in the present invention is a metal-air battery, comprising: a base housing, having a cavity, and an upper end of an outer wall being provided with a snap groove; two first air electrode films, attached to a front side and a rear side of the cavity and coming in contact with external air; two side plates, configured to press the first air electrode films to achieve sealing of the front side and the rear side of the cavity; a metal electrode cover, a metal electrode plate inserted into the cavity being provided at a bottom thereof; and a base cover, a snap member engaged with the snap groove being movably provided on an outer wall thereof. In the present invention, an upper end of the cavity is sealed by means of the metal electrode cover, the metal electrode plate is inserted into the cavity, and when the metal electrode plate needs to be replaced, it is only required to directly take out the metal electrode cover; position fixing of the metal electrode cover and sealing of the cavity are realized by means of the abutment of the base cover, the base cover is fastened on the base housing by means of the snap member, and disassembly of the base cover can be achieved only by disengaging the snap member from the snap groove; the metal electrode cover can be directly taken out due to the fact that the metal electrode cover is not connected by means of a fastener, and therefore, replacement of the metal electrode plate is convenient and simple.

Description

一种金属空气电池A metal-air battery 技术领域Technical field
本发明涉及电池领域,特别是涉及一种金属空气电池。The present invention relates to the field of batteries, in particular to a metal-air battery.
背景技术Background technique
金属空气电池是以电极电位较负的金属如镁、铝、锌、汞、铁等作负极,以空气中的氧或纯氧作正极。其具有比能量高、价格便宜和性能稳定的优点。Metal-air batteries use metals with relatively negative electrode potentials, such as magnesium, aluminum, zinc, mercury, iron, etc., as the negative electrode, and oxygen or pure oxygen in the air as the positive electrode. It has the advantages of high specific energy, low price and stable performance.
金属空气电池通常具有一个容纳腔以容纳电解质溶液,金属电极板则插入其中,金属电极板属于耗材,需要经常更换,传统的金属空气电池,更换金属电极板较为麻烦,操作繁琐。The metal-air battery usually has an accommodating cavity to contain the electrolyte solution, and the metal electrode plate is inserted into it. The metal electrode plate is a consumable and needs to be replaced frequently. In the traditional metal-air battery, it is troublesome to replace the metal electrode plate and the operation is cumbersome.
发明内容Summary of the invention
本发明旨在至少解决现有技术中存在的技术问题之一。为此,本发明提出一种金属空气电池,能够方便地更换金属电极板。The present invention aims to solve at least one of the technical problems existing in the prior art. For this reason, the present invention proposes a metal-air battery, which can easily replace the metal electrode plate.
根据本发明的第一方面实施例的金属空气电池,包括:基壳,具有一空腔,且外壁上端具有扣槽,所述空腔前后侧以及上端均为开口;两个第一空气电极膜,贴设于空腔前后侧并与外部空气接触;两个侧板,分别连接于基壳前后侧,用于将第一空气电极膜压紧以实现对空腔前后侧的密封;金属电极盖,盖设于空腔上端开口处,且底部设有插入空腔的金属电极板;基盖,外壁活动设有与扣槽匹配的卡扣,通过卡扣扣设于扣槽实现基盖与基壳的连接并压紧金属电极盖以实现对空腔上端的密封。A metal-air battery according to an embodiment of the first aspect of the present invention includes: a base case with a cavity, and an upper end of the outer wall has a buckle groove, the front and rear sides of the cavity and the upper end are both openings; two first air electrode films, It is attached to the front and rear sides of the cavity and is in contact with the outside air; two side plates are respectively connected to the front and rear sides of the base shell for pressing the first air electrode film to seal the front and rear sides of the cavity; the metal electrode cover, The cover is arranged at the opening at the upper end of the cavity, and the bottom is provided with a metal electrode plate inserted into the cavity; the base cover, the outer wall is movably provided with a buckle matching the buckle groove, and the buckle is buckled in the buckle groove to realize the base cover and the base shell Connect and press the metal electrode cover to achieve the sealing of the upper end of the cavity.
根据本发明实施例的一种金属空气电池,至少具有如下技术效果:通过金属电极盖对空腔上端进行封盖,且将金属电极板插入空腔内,需要更换金属电极板时,直接取出金属电极盖即可,且金属电极盖通过基盖的抵压实现位置固定以及对空腔的密封,基盖通过卡扣扣设于基壳上,只需要卡扣脱离扣槽即可实现基盖的拆卸,而金属电极盖由于没有通过紧固件连接,可直接取出,更换金属电极板方便简单。A metal-air battery according to an embodiment of the present invention has at least the following technical effects: the upper end of the cavity is covered by a metal electrode cover, and the metal electrode plate is inserted into the cavity. When the metal electrode plate needs to be replaced, the metal is directly taken out. The electrode cover is sufficient, and the metal electrode cover realizes the position fixation and the sealing of the cavity through the pressing of the base cover. The base cover is buckled on the base shell by a buckle, and the buckle is only required to be released from the buckle groove to realize the base cover Disassembly, and because the metal electrode cover is not connected by fasteners, it can be taken out directly, and it is convenient and simple to replace the metal electrode plate.
根据本发明的一些实施例,所述基壳包括两个半壳,两个所述半壳对称设置并通过紧固件连接拼合,两个第一空气电极膜贴设于两个所述半壳的相背的一侧。According to some embodiments of the present invention, the base housing includes two half-shells, the two half-shells are symmetrically arranged and connected by fasteners, and the two first air electrode membranes are attached to the two half-shells. On the opposite side.
根据本发明的一些实施例,两个所述半壳相向的一侧均安装有第二空气电极膜,所述半壳与对应的第一空气电极膜和第二空气电极膜形成电解质容纳腔,两个所述半壳在两个第二空气电极膜之间形成有第一通气孔以使第二空气电极膜能与外部空气接触。According to some embodiments of the present invention, a second air electrode film is installed on the opposite sides of the two half-shells, and the half-shells and the corresponding first air electrode film and the second air electrode film form an electrolyte accommodating cavity, The two half shells are formed with a first vent hole between the two second air electrode films so that the second air electrode film can be in contact with external air.
根据本发明的一些实施例,所述基壳上端具有下沉的第一贴合面,所述金属电极盖贴合于第一贴合面,且第一贴合面内嵌入有第一密封圈。According to some embodiments of the present invention, the upper end of the base case has a sunken first bonding surface, the metal electrode cover is bonded to the first bonding surface, and a first sealing ring is embedded in the first bonding surface .
根据本发明的一些实施例,所述基盖包括顶盖和底盖,所述底盖连接于顶盖底部,所述底盖底部与金属电极盖相抵并压紧金属电极盖。According to some embodiments of the present invention, the base cover includes a top cover and a bottom cover, the bottom cover is connected to the bottom of the top cover, and the bottom of the bottom cover abuts against the metal electrode cover and presses the metal electrode cover.
根据本发明的一些实施例,所述金属电极盖中部具有朝上凸起的第一凸起,所述第一凸起穿过底盖,所述第一凸起中心具有贯通的加液口,所述顶盖对应第一凸起设有朝下凸起的密封凸起,所述密封凸起与第一凸起相抵并将加液口密封。According to some embodiments of the present invention, the middle of the metal electrode cover has a first protrusion protruding upward, the first protrusion passes through the bottom cover, and the center of the first protrusion has a through liquid filling port, The top cover is provided with a downwardly convex sealing protrusion corresponding to the first protrusion, and the sealing protrusion abuts against the first protrusion and seals the filling port.
根据本发明的一些实施例,所述底盖对应密封凸起设有朝上凸起的第二凸起,所述第二凸起中心具有供第一凸起穿入的中心孔,所述密封凸起底部至少部分嵌入第二凸起。According to some embodiments of the present invention, the bottom cover is provided with an upwardly protruding second protrusion corresponding to the sealing protrusion, and the center of the second protrusion has a central hole for the first protrusion to penetrate. The bottom of the protrusion is at least partially embedded in the second protrusion.
根据本发明的一些实施例,所述密封凸起与第一凸起之间夹设有第二密封圈。According to some embodiments of the present invention, a second sealing ring is sandwiched between the sealing protrusion and the first protrusion.
根据本发明的一些实施例,所述空腔前后侧的开口处外端边缘具有一供第一空气电极膜贴合的环形贴合面,所述侧板朝向开口的一侧设有与所述环形贴合面对应的环形压紧面,所述环形压紧面设有若干盲孔,所述侧板设有第二通气孔,所述第二通气孔位于所述环形压紧面的包围范围内;所述环形压紧面和所述环形贴合面之间夹设有压紧框,所述压紧框用于在所述侧板环形压紧面的抵压下将第一空气电极膜压紧于环形贴合面上;盲孔内安装有预紧弹簧,所述预紧弹簧用于对所述压紧框施加将其推向所述环形贴合面的弹性预紧力。According to some embodiments of the present invention, the outer end edge of the opening at the front and rear sides of the cavity has an annular bonding surface for bonding the first air electrode film, and the side plate is provided with the side facing the opening with the The annular pressing surface corresponds to the annular pressing surface, the annular pressing surface is provided with a number of blind holes, the side plate is provided with a second vent hole, and the second vent hole is located in the surrounding of the annular pressing surface Within the range; a compression frame is sandwiched between the annular pressing surface and the annular bonding surface, and the compression frame is used to press the first air electrode under the pressing of the annular pressing surface of the side plate The membrane is compressed on the annular fitting surface; a pre-tensioning spring is installed in the blind hole, and the pre-tensioning spring is used to apply an elastic pre-tensioning force to the compression frame to push it to the annular fitting surface.
根据本发明的一些实施例,所述压紧框朝向所述侧板凸起形成有与所述盲孔对应匹配的定位柱,所述定位柱插入所述盲孔内并可沿所述盲孔滑动。According to some embodiments of the present invention, the compression frame protrudes toward the side plate and is formed with a positioning post corresponding to the blind hole, and the positioning post is inserted into the blind hole and can extend along the blind hole. slide.
本发明的附加方面和优点将在下面的描述中部分给出,部分将从下面的描述中变得明显,或通过本发明的实践了解到。The additional aspects and advantages of the present invention will be partially given in the following description, and some will become obvious from the following description, or be understood through the practice of the present invention.
附图说明Description of the drawings
下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the drawings and embodiments.
图1是本发明实施例的分解状态结构示意图;FIG. 1 is a schematic diagram of the structure in an exploded state of an embodiment of the present invention;
图2是本发明实施例的内部剖视图;Figure 2 is an internal cross-sectional view of an embodiment of the present invention;
图3是基盖的分解结构示意图;Figure 3 is a schematic diagram of the exploded structure of the base cover;
图4是基盖的内部剖视图;Figure 4 is an internal cross-sectional view of the base cover;
图5是基壳的分解状态结构示意图;Figure 5 is a schematic diagram of the structure of the base shell in an exploded state;
图6是半壳的结构示意图;Figure 6 is a schematic diagram of the structure of the half shell;
图7是侧板、压紧框的结构示意图;Figure 7 is a schematic diagram of the structure of the side plate and the compression frame;
图8是侧板、压紧框和预紧弹簧的分解状态结构示意图;Figure 8 is a structural schematic diagram of the side plate, the compression frame and the pre-tensioned spring in an exploded state;
图9是压紧框的结构示意图;Figure 9 is a schematic diagram of the structure of the compression frame;
图10是侧板的正面结构示意图;Figure 10 is a schematic view of the front structure of the side plate;
图11是图2的A处放大视图;Fig. 11 is an enlarged view of A in Fig. 2;
图12是图2的B处放大视图。Fig. 12 is an enlarged view of B in Fig. 2.
附图标记:Reference signs:
基壳100、半壳101、第一贴合面102、空腔110、扣槽120、安装平面130、第二安装孔131、限位孔132、第三螺钉133、第二台阶面140、第一密封圈141、托板150、第一台阶面160、第一通气孔170、密闭腔体180、电解质容纳腔190;The base shell 100, the half shell 101, the first bonding surface 102, the cavity 110, the buckle groove 120, the mounting plane 130, the second mounting hole 131, the limiting hole 132, the third screw 133, the second step surface 140, the first A sealing ring 141, a supporting plate 150, a first step surface 160, a first vent 170, a closed cavity 180, and an electrolyte containing cavity 190;
侧板200、抵压框210、盲孔211、泄气孔212、抵压框内表面213、第二通气孔220、加强筋230、限位凸部240、安装贴合面241、第一安装孔250、压紧框260、定位柱261、弹簧容置槽262、预紧弹簧270、手抠槽280、铭牌安装槽290; Side plate 200, pressure frame 210, blind hole 211, vent 212, pressure frame inner surface 213, second vent 220, stiffener 230, limiting protrusion 240, mounting surface 241, first mounting hole 250. Compression frame 260, positioning post 261, spring accommodating groove 262, pre-tensioning spring 270, hand-pull groove 280, nameplate installation groove 290;
第一空气电极膜300;金属电极盖400、金属电极板410、第一凸起420、加液口421、第一密封圈430;The first air electrode film 300; the metal electrode cover 400, the metal electrode plate 410, the first protrusion 420, the filling port 421, the first sealing ring 430;
基盖500,卡扣501、顶盖510、密封凸起511、第二连接孔512、底盖520、第二凸起521、螺纹安装孔522、中心孔523、第二螺钉530、第二密封圈540; Base cover 500, buckle 501, top cover 510, sealing protrusion 511, second connecting hole 512, bottom cover 520, second protrusion 521, threaded mounting hole 522, center hole 523, second screw 530, second seal Circle 540;
第二空气电极膜600。The second air electrode film 600.
具体实施方式Detailed ways
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能理解为对本发明的限制。The embodiments of the present invention are described in detail below. Examples of the embodiments are shown in the accompanying drawings, in which the same or similar reference numerals indicate the same or similar elements or elements with the same or similar functions. The embodiments described below with reference to the drawings are exemplary, and are only used to explain the present invention, but should not be construed as limiting the present invention.
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明的描述中,除非另有说明,“多个”的含义是两个或两个以上。In the description of the present invention, it should be understood that the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", " "Back", "Left", "Right", "Vertical", "Horizontal", "Top", "Bottom", "Inner", "Outer", "Axial", "Radial", "Circumferential" The orientation or positional relationship of the other indications is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the pointed device or element must have a specific orientation or a specific orientation. The azimuth structure and operation cannot be understood as a limitation of the present invention. In addition, the features defined with "first" and "second" may explicitly or implicitly include one or more of these features. In the description of the present invention, unless otherwise specified, "plurality" means two or more.
在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、 “相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that the terms "installation", "connection", and "connection" should be interpreted broadly unless otherwise clearly specified and limited. For example, they can be fixed or detachable. Connected or integrally connected; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, and it can be the internal communication between two components. For those of ordinary skill in the art, the specific meaning of the above-mentioned terms in the present invention can be understood in specific situations.
参照图1至图12,本发明实施例的一种金属空气电池,基壳100,具有一空腔110,且外壁上端具有扣槽120,空腔110前后侧以及上端均为开口,扣槽120设于基壳100左右侧壁上。1 to 12, a metal-air battery according to an embodiment of the present invention, the base case 100 has a cavity 110, and the upper end of the outer wall has a buckle groove 120, the front and rear sides and upper ends of the cavity 110 are open, and the buckle groove 120 is provided On the left and right side walls of the base shell 100.
两个第一空气电极膜300贴设于空腔110前后侧并与外部空气接触;两个侧板200分别连接于基壳100前后侧,用于将第一空气电极膜300压紧以实现对空腔110前后侧的密封;侧板200通过紧固件可拆卸地安装于基壳100上。The two first air electrode films 300 are attached to the front and rear sides of the cavity 110 and are in contact with the outside air; the two side plates 200 are respectively connected to the front and rear sides of the base shell 100 for pressing the first air electrode films 300 to achieve alignment. The front and rear sides of the cavity 110 are sealed; the side plate 200 is detachably installed on the base shell 100 by fasteners.
金属电极盖400盖设于空腔110上端开口处,且底部设有插入空腔110的金属电极板410。基盖500外壁活动设有与扣槽120匹配的卡扣501,通过卡扣501扣设于扣槽120实现基盖500与基壳100的连接,并压紧金属电极盖400以实现对空腔110上端的密封。卡扣501与扣槽120的设计方便基盖500的拆卸。The metal electrode cover 400 is disposed at the opening at the upper end of the cavity 110, and a metal electrode plate 410 inserted into the cavity 110 is provided at the bottom. The outer wall of the base cover 500 is movably provided with a buckle 501 matching the buckle groove 120. The buckle 501 is buckled in the buckle groove 120 to realize the connection between the base cover 500 and the base case 100, and the metal electrode cover 400 is pressed to achieve the cavity Seal at the upper end of 110. The design of the buckle 501 and the buckle groove 120 facilitates the disassembly of the base cover 500.
本发明实施例提供的金属空气电池,需要更换金属电极板410时,直接取出金属电极盖400即可,且金属电极盖400通过基盖500的抵压实现位置固定以及对空腔的密封,基盖500通过卡扣扣设于基壳100上,只需要卡扣脱离扣槽即可实现基盖的拆卸,而金属电极盖由于没有通过紧固件连接,可直接取出,更换金属电极板方便简单。For the metal-air battery provided by the embodiment of the present invention, when the metal electrode plate 410 needs to be replaced, the metal electrode cover 400 can be directly taken out, and the metal electrode cover 400 is pressed by the base cover 500 to achieve position fixation and sealing of the cavity. The cover 500 is buckled on the base shell 100 by a buckle, and the buckle can be removed from the buckle groove. The metal electrode cover can be taken out directly because it is not connected by fasteners. It is convenient and simple to replace the metal electrode plate. .
参照图5所示,在本发明的一些实施例中,基壳100包括两个半壳101,两个半壳101对称设置并通过紧固件连接拼合,两个第一空气电极膜300贴设于两个半壳101的相背的一侧。具体的,如图5所示,两个半壳101相对设置,两个半壳101设有对应的第一连接孔134,第一连接孔134内穿插有一连接圆杆103,圆杆103两端设有螺纹孔,两个第一螺钉104对应从两个半壳101的第一连接孔134穿入并与分别与圆杆103两端的螺纹孔连接并拧紧,这样将两个半壳101紧紧拼合在一起形成基壳100和空腔110。Referring to FIG. 5, in some embodiments of the present invention, the base shell 100 includes two half shells 101, the two half shells 101 are symmetrically arranged and connected by fasteners, and the two first air electrode films 300 are attached On the opposite side of the two half-shells 101. Specifically, as shown in FIG. 5, the two half-shells 101 are arranged opposite to each other, and the two half-shells 101 are provided with corresponding first connecting holes 134, and a connecting rod 103 is inserted into the first connecting hole 134. The ends of the rod 103 There are threaded holes, and two first screws 104 correspondingly penetrate through the first connecting holes 134 of the two half-shells 101 and are connected with the threaded holes at the two ends of the round rod 103 and tightened, so that the two half-shells 101 are tightly tightened. Split together to form the base shell 100 and the cavity 110.
在本发明的一些实施例中,两个半壳101相向的一侧均安装有第二空气电极膜600,半壳101与对应的第一空气电极膜300和第二空气电极膜600形成电解质容纳腔190,如图2所示,两个半壳101各形成两个电解质容纳腔190,金属电极板410具有多个并分别插入两个电解质容纳腔190内。这样多个空气电极膜600和金属电极板410可提高电池的功率。两个半壳101在两个第二空气电极膜600之间形成有第一通气孔170 以使第二空气电极膜600能与外部空气接触。具体的,第二空气电极膜600与半壳101之间形成一密闭腔体180,第一通气孔170则使该密闭腔体180与外部空气连通。第一通气孔170由半壳101拼合处的凹孔171拼合形成。具体的,两个半壳101相向的一侧设有朝内下沉的第一台阶面160,第二空气电极膜600贴合于第一台阶面160,为了实现紧密贴合,两个第二空气电极膜600外周之间设置有压紧件700,在两个半壳101拧紧相互贴合的作用下,压紧件700对两侧的第二空气电极膜600施加压力以保证第二空气电极膜600与第一台阶面160的密封贴合。In some embodiments of the present invention, the second air electrode film 600 is installed on the opposite sides of the two half-shells 101, and the half-shell 101 and the corresponding first air electrode film 300 and the second air electrode film 600 form an electrolyte containment. Cavities 190, as shown in FIG. 2, each of the two half-shells 101 forms two electrolyte accommodating cavities 190, and the metal electrode plate 410 has a plurality of them and is inserted into the two electrolyte accommodating cavities 190, respectively. Such a plurality of air electrode films 600 and metal electrode plates 410 can increase the power of the battery. The two half shells 101 are formed with a first vent hole 170 between the two second air electrode films 600 so that the second air electrode film 600 can be in contact with the outside air. Specifically, a closed cavity 180 is formed between the second air electrode membrane 600 and the half shell 101, and the first vent 170 allows the closed cavity 180 to communicate with the outside air. The first vent hole 170 is formed by combining the concave holes 171 at the joint of the half shell 101. Specifically, the opposite sides of the two half-shells 101 are provided with a first stepped surface 160 that sinks inward, and the second air electrode film 600 is attached to the first stepped surface 160. In order to achieve a close fit, the two second A pressing member 700 is arranged between the outer circumference of the air electrode film 600. Under the action of the two half-shells 101 being screwed to each other, the pressing member 700 applies pressure to the second air electrode film 600 on both sides to ensure the second air electrode. The film 600 is bonded to the first step surface 160 in a sealed manner.
在本发明的一些实施例中,基壳100上端具有下沉的第一贴合面102,即基壳100上端具有下沉的台阶,金属电极盖400嵌入下沉的台阶内并贴合于第一贴合面102,且第一贴合面102内嵌入有第一密封圈430,通过金属电极盖400与第一贴合面102的贴合以及第一密封圈430的作用,可以保证密封效果。In some embodiments of the present invention, the upper end of the base shell 100 has a sinking first bonding surface 102, that is, the upper end of the base shell 100 has a sinking step, and the metal electrode cover 400 is embedded in the sinking step and is attached to the first A bonding surface 102, and the first bonding surface 102 is embedded with a first sealing ring 430, the sealing effect can be ensured by the bonding of the metal electrode cover 400 to the first bonding surface 102 and the first sealing ring 430 .
在本发明的一些实施例中,基盖500包括顶盖510和底盖520,底盖520连接于顶盖510底部,底盖520底部与金属电极盖400相抵并压紧金属电极盖400,底盖520嵌入基壳100上端的台阶内,卡扣501通过枢接轴枢接在顶盖510左右两侧。具体的,底盖520与顶盖510形成一个腔体,该腔体用于放置金属空气电池的电控部件和作为线路集成区域,空气电极膜和金属电极板410均通过导电线穿过相应结构进入到该腔体内进行相应布置。In some embodiments of the present invention, the base cover 500 includes a top cover 510 and a bottom cover 520. The bottom cover 520 is connected to the bottom of the top cover 510. The cover 520 is embedded in the step at the upper end of the base shell 100, and the buckle 501 is pivotally connected to the left and right sides of the top cover 510 through a pivot shaft. Specifically, the bottom cover 520 and the top cover 510 form a cavity, which is used to place the electrical control components of the metal-air battery and serve as a circuit integration area. The air electrode film and the metal electrode plate 410 both pass through the corresponding structure through conductive wires. Enter into the cavity for corresponding arrangement.
如图4所示,底盖520四周设有若干螺纹安装孔522,顶盖510对应设有第二连接孔512,第二螺钉530连接在螺纹安装孔522内并穿入第二连接孔512,第二连接孔512直径大于第二螺钉530,第二螺钉穿入第二连接孔512的部分套设有橡胶套531,橡胶套531通过过盈配合与第二连接孔512连接以实现底盖520和顶盖510的连接。拆卸时,不需要拧第二螺钉530,只需要克服紧配力,将底盖520和顶盖510分离即可,拆卸方便。As shown in FIG. 4, a number of threaded mounting holes 522 are provided around the bottom cover 520, and the top cover 510 is correspondingly provided with a second connecting hole 512. The second screw 530 is connected in the threaded mounting hole 522 and penetrates the second connecting hole 512. The diameter of the second connecting hole 512 is larger than that of the second screw 530. The part where the second screw penetrates into the second connecting hole 512 is covered with a rubber sleeve 531. The rubber sleeve 531 is connected with the second connecting hole 512 by interference fit to realize the bottom cover 520. And the connection of the top cover 510. When disassembling, the second screw 530 does not need to be screwed, only the tightening force is overcome, and the bottom cover 520 and the top cover 510 are separated, which is convenient for disassembly.
在本发明的一些实施例中,金属电极盖400中部具有朝上凸起的第一凸起420,第一凸起420穿过底盖520,第一凸起420中心具有贯通的加液口421,加液口421与空腔110连通,具体的,加液口421与电解质容纳腔190连通以方便添加电解质液体。顶盖510对应第一凸起420设有朝下凸起的密封凸起511,密封凸起511与第一凸起420相抵以将加液口421密封。当取下顶盖510后即可往内添加液体,而不需要取下金属电极盖400,更加方便。In some embodiments of the present invention, the middle of the metal electrode cover 400 has a first protrusion 420 protruding upward, the first protrusion 420 passes through the bottom cover 520, and the center of the first protrusion 420 has a through liquid filling port 421. The liquid filling port 421 is in communication with the cavity 110. Specifically, the liquid filling port 421 is in communication with the electrolyte accommodating cavity 190 to facilitate the addition of electrolyte liquid. The top cover 510 is provided with a sealing protrusion 511 protruding downward corresponding to the first protrusion 420, and the sealing protrusion 511 abuts against the first protrusion 420 to seal the filling port 421. When the top cover 510 is removed, liquid can be added to the inside without removing the metal electrode cover 400, which is more convenient.
如图12所示,金属电极盖400底面对应金属电极板410设有夹紧块440,金属电 极板410上端插入夹紧块440内,为了对金属电极板410提供较好的支撑,避免金属电极板410脱离夹紧块440,空腔110底部对应金属电极板410设有托板150,托板150设有V型槽以便金属电极板410嵌入。As shown in FIG. 12, the bottom surface of the metal electrode cover 400 is provided with a clamping block 440 corresponding to the metal electrode plate 410. The upper end of the metal electrode plate 410 is inserted into the clamping block 440, in order to provide better support for the metal electrode plate 410 and avoid metal electrodes. The plate 410 is separated from the clamping block 440, the bottom of the cavity 110 is provided with a supporting plate 150 corresponding to the metal electrode plate 410, and the supporting plate 150 is provided with a V-shaped groove for the metal electrode plate 410 to be embedded.
在本发明的进一步实施例中,密封凸起511与第一凸起420之间夹设有第二密封圈540,以提高密封效果。In a further embodiment of the present invention, a second sealing ring 540 is sandwiched between the sealing protrusion 511 and the first protrusion 420 to improve the sealing effect.
在本发明的一些实施例中,底盖520对应密封凸起511设有朝上凸起的第二凸起521,第二凸起521中心具有供第一凸起420穿入的中心孔523,密封凸起511底部至少部分嵌入第二凸起521。通过第二凸起521和密封凸起511配合能实现底盖520和顶盖510对位安装时起到一定的定位作用。In some embodiments of the present invention, the bottom cover 520 is provided with a second protrusion 521 protruding upward corresponding to the sealing protrusion 511, and the center of the second protrusion 521 has a central hole 523 for the first protrusion 420 to penetrate. The bottom of the sealing protrusion 511 is at least partially embedded in the second protrusion 521. The cooperation of the second protrusion 521 and the sealing protrusion 511 can achieve a certain positioning effect when the bottom cover 520 and the top cover 510 are installed in position.
在本发明的一些实施例中,空腔110前后侧的开口处外端边缘具有一供第一空气电极膜300贴合的环形贴合面,侧板200朝向开口的一侧设有与环形贴合面对应的环形压紧面,环形贴合面沿开口的外端边缘环绕,第一空气电极膜300与环形贴合面紧贴能对空腔侧壁进行密封。In some embodiments of the present invention, the outer edges of the openings on the front and rear sides of the cavity 110 have a circular bonding surface for bonding the first air electrode film 300, and the side plate 200 is provided with a circular bonding surface on the side facing the opening. The ring-shaped pressing surface corresponding to the mating surface, the ring-shaped bonding surface surrounds the outer edge of the opening, and the first air electrode film 300 and the ring-shaped bonding surface are in close contact to seal the cavity side wall.
环形压紧面设有若干盲孔211,侧板200设有第二通气孔220,第二通气孔220贯穿侧板200,第二通气孔220位于环形压紧面的包围范围内,第二通气孔220用于将外部的空气通入至第一空气电极膜300表面;环形压紧面和环形贴合面之间夹设有压紧框260,紧框260轮廓与环形贴合面对应,且压紧框260的内圈轮廓与对应的开口边缘匹配。压紧框260位于环形压紧面和环形贴合面之间,压紧框260用于在侧板200环形压紧面的抵压下将第一空气电极膜300压紧于环形贴合面上,实现第一空气电极膜300的密封连接。盲孔211内安装有预紧弹簧270,预紧弹簧270用于对压紧框260施加将其推向环形贴合面的弹性预紧力。The annular pressing surface is provided with a number of blind holes 211, the side plate 200 is provided with a second vent hole 220, the second vent hole 220 penetrates the side plate 200, and the second vent hole 220 is located in the surrounding range of the annular pressing surface. The air hole 220 is used to pass external air into the surface of the first air electrode film 300; a pressing frame 260 is sandwiched between the annular pressing surface and the annular bonding surface, and the outline of the tight frame 260 corresponds to the annular bonding surface. And the contour of the inner ring of the compression frame 260 matches the corresponding opening edge. The pressing frame 260 is located between the annular pressing surface and the annular bonding surface, and the pressing frame 260 is used to press the first air electrode film 300 on the annular bonding surface under the pressing of the annular pressing surface of the side plate 200 , The sealed connection of the first air electrode film 300 is realized. A pre-tensioning spring 270 is installed in the blind hole 211, and the pre-tensioning spring 270 is used to apply an elastic pre-tensioning force to the pressing frame 260 to push it to the annular contact surface.
利用环形贴合面供第一空气电极膜贴合以保证良好的密封贴合,利用环形压紧面将压紧框紧压第一空气电极膜,使第一空气电极膜与环形贴合面紧贴,实现良好的密封;且由于都是面面贴合,作用力分布均衡,不会由于点受力导致局部凹陷变形而造成密封效果变差;再加上预紧弹簧的作用,当侧板的连接轻微松动,不再紧压压紧框和第一空气电极膜时,预紧弹簧可以很好地提供预紧力,使得压紧框仍然压紧空气电池膜,而不像现有技术,当侧板轻微松动后即失去对第一空气电极膜的压紧作用;另外弹簧对侧板的向外推的作用力将侧板撑紧,起到一定预防松动的作用;本申请能很好的预防松动和漏液,提高密封性能。Use the ring-shaped bonding surface to bond the first air electrode film to ensure a good seal bonding, and use the ring-shaped pressing surface to press the compression frame against the first air electrode film to make the first air electrode film tightly close to the ring-shaped bonding surface To achieve a good seal; and because they are all face-to-face, the force distribution is balanced, and the sealing effect will not deteriorate due to partial depression and deformation caused by the point force; coupled with the action of the pre-tension spring, when the side plate When the connection is slightly loosened and the compression frame and the first air electrode membrane are no longer tightly compressed, the pre-tensioning spring can provide a good pre-tensioning force, so that the compression frame still compresses the air battery membrane, unlike the prior art, When the side plate is slightly loosened, it will lose its pressing effect on the first air electrode membrane; in addition, the outward pushing force of the spring on the side plate will hold the side plate tight and play a certain role in preventing loosening; this application can be very good Prevent loosening and leakage, and improve sealing performance.
在本发明的一些实施例中,环形贴合面为开口边缘的外端面朝内凹陷形成的第二 台阶面140,即由向内下沉的台阶形成的台阶平面。如图3所示,空气电池膜300嵌入凹陷形成的台阶内并与第二台阶面140贴合,台阶能对空气电池膜300限位,提高其安装精度。In some embodiments of the present invention, the annular bonding surface is a second step surface 140 formed by recessing the outer end surface of the opening edge inward, that is, a step plane formed by a step that sinks inward. As shown in FIG. 3, the air battery film 300 is embedded in the step formed by the recess and is attached to the second step surface 140. The step can limit the air battery film 300 and improve its installation accuracy.
在本发明的一些实施例中,基壳100在开口周侧设有安装平面130,具体的,安装平面130设于左右两侧,侧板200设有与安装平面130对应贴合的安装贴合面241,安装贴合面241和安装平面130设有对应的安装孔以通过紧固件连接固定。具体的,安装贴合面241上设有若干第一安装孔250,安装平面130上对应设有若干第二安装孔131,第一安装孔250与第二安装孔131一一对齐并装入有第三螺钉133,第二安装孔131为与第三螺钉133匹配的螺纹孔。通过面面贴合实现基壳100与侧板的紧密相连。另外,由于预紧弹簧270的作用,可以对第三螺钉133施加向外的推力,将第三螺钉133撑紧,能预防第三螺钉松动,预防侧板200松动,提高密封稳定性。In some embodiments of the present invention, the base shell 100 is provided with a mounting plane 130 on the peripheral side of the opening. Specifically, the mounting plane 130 is provided on the left and right sides, and the side plate 200 is provided with mounting fittings corresponding to the mounting plane 130. The surface 241, the mounting surface 241 and the mounting plane 130 are provided with corresponding mounting holes to be connected and fixed by fasteners. Specifically, a number of first mounting holes 250 are provided on the mounting surface 241, and a number of second mounting holes 131 are correspondingly provided on the mounting plane 130. The first mounting holes 250 and the second mounting holes 131 are aligned one by one and are fitted with The third screw 133 and the second mounting hole 131 are threaded holes matching the third screw 133. The close connection between the base shell 100 and the side plates is realized by surface-to-surface bonding. In addition, due to the action of the pre-tensioning spring 270, an outward pushing force can be applied to the third screw 133 to tighten the third screw 133, which can prevent the third screw from loosening, prevent the side plate 200 from loosening, and improve the sealing stability.
在本发明的进一步实施例中,安装贴合面241上设有凸起的限位凸部240,安装平面130设有供限位凸部240插入的限位孔132,通过限位凸部240插入限位孔132,实现侧板200与基壳100的定位安装,也可以在安装的时候,先让限位凸部240插入限位孔132后再拧装第三螺钉,起到一定的预安装的效果方便第一安装孔250与第二安装孔131对齐,使得侧板200安装更加方便。可以理解的是,限位凸部240内端边缘具有倒角以方便插入定位孔。In a further embodiment of the present invention, the mounting surface 241 is provided with a raised limiting protrusion 240, and the mounting plane 130 is provided with a limiting hole 132 into which the limiting protrusion 240 is inserted, passing through the limiting protrusion 240 Insert the limit hole 132 to realize the positioning and installation of the side plate 200 and the base shell 100. It is also possible to insert the limit protrusion 240 into the limit hole 132 and then screw the third screw to a certain extent during installation. The installation effect facilitates the alignment of the first installation hole 250 with the second installation hole 131, which makes the installation of the side plate 200 more convenient. It can be understood that the inner end edge of the limiting protrusion 240 is chamfered to facilitate insertion into the positioning hole.
在本发明的一些实施例中,环形贴合面上设有朝内凹陷形成的凹槽,凹槽内嵌装有第一密封圈141,通过第一密封圈141提高空气电池膜300与环形贴合面的密封性能。In some embodiments of the present invention, an inwardly recessed groove is provided on the annular bonding surface, and a first sealing ring 141 is embedded in the groove. The first sealing ring 141 improves the air battery membrane 300 and the annular adhesive The sealing performance of the joint surface.
在本发明的一些实施例中,侧板200内壁对应环形贴合面设有一凸起的抵压框210,环形压紧面为抵压框210的内表面,即如图5所示的抵压框内表面213。盲孔211由抵压框210内表面朝外延伸而成。盲孔211沿抵压框210的轮廓排列设置。In some embodiments of the present invention, the inner wall of the side plate 200 is provided with a protruding pressing frame 210 corresponding to the annular fitting surface, and the annular pressing surface is the inner surface of the pressing frame 210, that is, as shown in FIG. 5 Frame inner surface 213. The blind hole 211 is formed by the inner surface of the pressing frame 210 extending outward. The blind holes 211 are arranged along the contour of the pressing frame 210.
第二通气孔220位于抵压框210的框选范围内,抵压框210凸起并与侧板200内壁形成一开口朝内的通气空间201,第二通气孔220与该通气空间201连通以将空气导入通气空间201,使空气与电极空气膜300全面接触,相比于侧板200内壁与电极空气膜全面贴合,本申请的抵压框210仅压紧电极空气膜的侧边,形成的通气空间201可提高空气与电极空气膜的接触面积,提高电池性能。可以理解的是,开口呈矩形,对应的,第一空气电极膜也为矩形,抵压框210为矩形框以对应压住第一空气电极膜300的边缘。The second vent hole 220 is located within the frame selection range of the pressure frame 210. The pressure frame 210 protrudes and forms an inwardly opening vent space 201 with the inner wall of the side plate 200. The second vent hole 220 communicates with the vent space 201 to Air is introduced into the ventilation space 201, so that the air is in full contact with the electrode air film 300. Compared with the full bonding of the inner wall of the side plate 200 and the electrode air film, the pressure frame 210 of the present application only presses the side of the electrode air film to form The vented space 201 can increase the contact area between the air and the electrode air film, and improve the battery performance. It can be understood that the opening is rectangular, correspondingly, the first air electrode film is also rectangular, and the pressing frame 210 is a rectangular frame to press the edge of the first air electrode film 300 correspondingly.
在本发明的一些实施例中,压紧框260朝向侧板200凸起形成有与盲孔211对应 匹配的定位柱261,定位柱261插入盲孔211内并可沿盲孔211滑动。盲孔211与定位柱261位置对应,且截面匹配,定位柱261与盲孔211能实现压紧框260与抵压框210的对位安装。定位柱261与盲孔211的配合还能实现压紧框260的滑动导向,提高两者相对位置的稳定性。In some embodiments of the present invention, the compression frame 260 protrudes toward the side plate 200 to form a positioning post 261 corresponding to the blind hole 211. The positioning post 261 is inserted into the blind hole 211 and can slide along the blind hole 211. The blind hole 211 corresponds to the position of the positioning post 261 and the cross section is matched. The positioning post 261 and the blind hole 211 can realize the alignment installation of the compression frame 260 and the compression frame 210. The cooperation of the positioning post 261 and the blind hole 211 can also realize the sliding guide of the compression frame 260, and improve the stability of the relative position of the two.
在本发明的一些实施例中,定位柱261中心具有弹簧容置槽262,弹簧容置槽262由定位柱261外端面朝内延伸而成,弹簧容置槽262开口朝外。可以理解的是,弹簧容置槽262与定位柱261同轴。压紧框260为矩形框以对应矩形的第一空气电极膜。预紧弹簧270置于弹簧容置槽262和盲孔211内,即预紧弹簧270部分嵌入弹簧容置槽262内,部分伸出弹簧容置槽262置于盲孔211内。弹簧容置槽262和盲孔211给预紧弹簧270提供较好的容置空间,能对预紧弹簧270进行一定的限位,使得预紧弹簧270安装也方便。具体的,预紧弹簧270为压簧,预紧弹簧270一端与弹簧容置槽262槽底相抵,另一端与盲孔211孔底相抵,预紧弹簧270提供与弹簧容置槽262和盲孔211轴线平行的弹力。当压紧框260与抵压框210相贴时,预紧弹簧270对压紧框260施加推动其远离抵压框210的弹力。通过抵压框210将压紧框260压向第一空气电极膜实现第一空气电极膜的压紧固定,实现第一空气电极膜与基壳的密封接触。且抵压框、压紧框260与第一空气电极膜为面面接触,作用力分布均衡,不会由于点受力导致局部凹陷变形而造成密封效果变差。In some embodiments of the present invention, the center of the positioning column 261 has a spring accommodating groove 262, the spring accommodating groove 262 is formed by extending the outer end surface of the positioning column 261 inward, and the spring accommodating groove 262 opens outward. It can be understood that the spring accommodating groove 262 is coaxial with the positioning column 261. The pressing frame 260 is a rectangular frame to correspond to the rectangular first air electrode film. The pre-tensioning spring 270 is placed in the spring accommodating groove 262 and the blind hole 211, that is, the pre-tensioning spring 270 is partially embedded in the spring accommodating groove 262, and partially protruding out of the spring accommodating groove 262 is placed in the blind hole 211. The spring accommodating groove 262 and the blind hole 211 provide a better accommodating space for the pretension spring 270, and can limit the pretension spring 270 to a certain extent, so that the installation of the pretension spring 270 is also convenient. Specifically, the pretension spring 270 is a compression spring. One end of the pretension spring 270 abuts against the bottom of the spring accommodating groove 262, and the other end abuts against the bottom of the blind hole 211. The pretension spring 270 is provided with the spring accommodating groove 262 and the blind hole. 211 axis parallel elasticity. When the pressing frame 260 is in contact with the pressing frame 210, the pre-tensioning spring 270 exerts an elastic force on the pressing frame 260 to push it away from the pressing frame 210. The pressing frame 260 is pressed against the first air electrode film by the pressing frame 210 to realize the pressing and fixing of the first air electrode film, and the sealing contact between the first air electrode film and the base case is realized. In addition, the pressing frame and the pressing frame 260 are in surface-to-surface contact with the first air electrode film, and the force distribution is balanced, and the sealing effect will not deteriorate due to partial depression and deformation due to point force.
在本发明的一些实施例中,为了方便定位柱261插入盲孔211,减少插入阻力,定位柱261外壁与盲孔211为间隙配合。具体的,定位柱261和盲孔211呈圆柱形。In some embodiments of the present invention, in order to facilitate the insertion of the positioning post 261 into the blind hole 211 and reduce the insertion resistance, the outer wall of the positioning post 261 and the blind hole 211 are in clearance fit. Specifically, the positioning post 261 and the blind hole 211 are cylindrical.
参照图3,在本发明的一些实施例中,盲孔211底部具有贯穿侧板200的泄气孔212,泄气孔212位于盲孔211朝外的底壁上,以使盲孔211与侧板200外侧的空气连通。由于定位柱261和盲孔211匹配,当定位柱261压入盲孔211内时,会对其中的空气进行压缩,导致插入受阻,就算定位柱261与盲孔211为间隙配合,由于其间隙较小,空气溢出速度也不够,仍然会存在较大的空气阻力,而泄压孔212则可以将多余的空气排出至外部,达到泄压的效果,使得定位柱261插入更加顺畅,提高安装的速度和效率。3, in some embodiments of the present invention, the bottom of the blind hole 211 has a vent hole 212 penetrating the side plate 200, and the vent hole 212 is located on the bottom wall of the blind hole 211 facing outward, so that the blind hole 211 and the side plate 200 The outside air is connected. Since the positioning post 261 and the blind hole 211 match, when the positioning post 261 is pressed into the blind hole 211, the air in it will be compressed, causing the insertion to be blocked. If the air overflow speed is not enough, there will still be a large air resistance. The pressure relief hole 212 can discharge the excess air to the outside to achieve the pressure relief effect, making the positioning post 261 more smoothly inserted and increasing the installation speed And efficiency.
参照图3,在本发明的一些实施例中,定位柱261长度小于盲孔211深度,这样可以防止定位柱261与盲孔211底壁相抵,造成结构干涉,避免抵压框210与压紧框260不能相贴而造成抵压框210与压紧框260的接触面减少,从而使得抵压框210对压紧框260的压力不够均衡分布。3, in some embodiments of the present invention, the length of the positioning post 261 is less than the depth of the blind hole 211, which can prevent the positioning post 261 from abutting the bottom wall of the blind hole 211, causing structural interference, and avoiding the compression frame 210 and the compression frame The inability of 260 to contact causes the contact surface between the pressing frame 210 and the pressing frame 260 to decrease, so that the pressure of the pressing frame 210 on the pressing frame 260 is not evenly distributed.
在本发明的一些实施例中,抵压框210的框选范围内设有横纵交错的加强筋230,加强筋230加强侧板200的结构强度,避免其受力而造成损坏。如图4和图5所示,侧板200在抵压框210位置朝外拱起,使得该位置容易受压损坏,加强筋230可有效加强该区域的结构强度。In some embodiments of the present invention, staggered ribs 230 are arranged in the frame selection area of the pressing frame 210, and the ribs 230 strengthen the structural strength of the side plate 200 to avoid damage caused by stress. As shown in Figs. 4 and 5, the side plate 200 is arched outward at the position of the pressing frame 210, so that the position is easily damaged by compression, and the reinforcing rib 230 can effectively strengthen the structural strength of the area.
参照图7,在本发明的一些实施例中,侧板200外壁两侧具有朝中间凹陷形成的手抠槽280,方便拆卸侧板200时,抠下侧板200。另外,在本发明的一些实施例中,侧板200外壁具有朝内凹陷形成的铭牌安装槽290,可以安装铭牌以显示金属空气电池的制造信息。Referring to FIG. 7, in some embodiments of the present invention, both sides of the outer wall of the side plate 200 have hand-pull grooves 280 recessed toward the center, which facilitates the pulling down of the side plate 200 when the side plate 200 is removed. In addition, in some embodiments of the present invention, the outer wall of the side plate 200 has a nameplate installation groove 290 recessed inward, and the nameplate can be installed to display the manufacturing information of the metal-air battery.
在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示意性实施例”、“示例”、“具体示例”或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, descriptions with reference to the terms "one embodiment", "some embodiments", "exemplary embodiments", "examples", "specific examples" or "some examples" etc. mean to combine the embodiments The specific features, structures, materials, or characteristics described in the examples are included in at least one embodiment or example of the present invention. In this specification, the schematic representations of the above-mentioned terms do not necessarily refer to the same embodiment or example. Moreover, the described specific features, structures, materials or characteristics can be combined in any one or more embodiments or examples in a suitable manner.
尽管已经示出和描述了本发明的实施例,本领域的普通技术人员可以理解:在不脱离本发明的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those of ordinary skill in the art can understand that various changes, modifications, substitutions and modifications can be made to these embodiments without departing from the principle and purpose of the present invention. The scope of the present invention is defined by the claims and their equivalents.

Claims (10)

  1. 一种金属空气电池,其特征在于包括:A metal-air battery, characterized in that it comprises:
    基壳(100),具有一空腔(110),且外壁上端具有扣槽(120),所述空腔(110)前后侧以及上端均为开口;The base shell (100) has a cavity (110), and the upper end of the outer wall has a buckle groove (120), and the front and back sides and the upper end of the cavity (110) are open;
    两个第一空气电极膜(300),贴设于所述空腔(110)前后侧并与外部空气接触;Two first air electrode films (300) are attached to the front and rear sides of the cavity (110) and are in contact with the outside air;
    两个侧板(200),分别连接于所述基壳(100)前后侧,用于将所述第一空气电极膜(300)压紧以实现对所述空腔(110)前后侧的密封;Two side plates (200), respectively connected to the front and rear sides of the base shell (100), are used to compress the first air electrode film (300) to achieve sealing of the front and rear sides of the cavity (110) ;
    金属电极盖(400),盖设于所述空腔(110)上端开口处,且底部设有插入所述空腔(110)的金属电极板(410);A metal electrode cover (400) is provided at the upper opening of the cavity (110), and a metal electrode plate (410) inserted into the cavity (110) is provided at the bottom;
    基盖(500),外壁活动设有与所述扣槽(120)匹配的卡扣(501),通过所述卡扣(501)扣设于所述扣槽(120)实现所述基盖(500)与所述基壳(100)的连接,并压紧所述金属电极盖(400)以实现对所述空腔(110)上端的密封。The base cover (500), the outer wall is movably provided with a buckle (501) matching the buckle groove (120), and the base cover ( 500) is connected with the base shell (100), and the metal electrode cover (400) is pressed tightly to realize the sealing of the upper end of the cavity (110).
  2. 根据权利要求1所述的金属空气电池,其特征在于:所述基壳(100)包括两个半壳(101),两个所述半壳(101)对称设置并通过紧固件连接拼合,两个所述第一空气电极膜(300)贴设于两个所述半壳(101)的相背的一侧。The metal-air battery according to claim 1, characterized in that: the base shell (100) comprises two half shells (101), and the two half shells (101) are symmetrically arranged and connected by fasteners. The two first air electrode films (300) are attached to the opposite sides of the two half shells (101).
  3. 根据权利要求2所述的金属空气电池,其特征在于:两个所述半壳(101)相向的一侧均安装有第二空气电极膜(600),所述半壳(101)与对应的所述第一空气电极膜(300)和所述第二空气电极膜(600)形成电解质容纳腔(190),两个所述半壳(101)在两个所述第二空气电极膜(600)之间形成有第一通气孔(170)以使所述第二空气电极膜(600)能与外部空气接触。The metal-air battery according to claim 2, characterized in that: a second air electrode membrane (600) is installed on the opposite sides of the two half-shells (101), and the half-shells (101) and the corresponding The first air electrode film (300) and the second air electrode film (600) form an electrolyte accommodating cavity (190), and the two half shells (101) are connected to the two second air electrode films (600). A first vent hole (170) is formed between) so that the second air electrode film (600) can be in contact with external air.
  4. 根据权利要求1所述的金属空气电池,其特征在于:所述基壳(100)上端具有下沉的第一贴合面(102),所述金属电极盖(400)贴合于所述第一贴合面(102),且所述第一贴合面(102)内嵌入有第一密封圈(430)。The metal-air battery according to claim 1, characterized in that: the upper end of the base shell (100) has a sunken first bonding surface (102), and the metal electrode cover (400) is bonded to the first bonding surface (102). A bonding surface (102), and a first sealing ring (430) is embedded in the first bonding surface (102).
  5. 根据权利要求1所述的金属空气电池,其特征在于:所述基盖(500)包括顶盖(510)和底盖(520),所述底盖(520)连接于所述顶盖(510)底部,所述底盖(520)底部与所述金属电极盖(400)相抵并压紧所述金属电极盖(400)。The metal-air battery according to claim 1, wherein the base cover (500) comprises a top cover (510) and a bottom cover (520), and the bottom cover (520) is connected to the top cover (510). ) At the bottom, the bottom of the bottom cover (520) abuts against the metal electrode cover (400) and compresses the metal electrode cover (400).
  6. 根据权利要求5所述的金属空气电池,其特征在于:所述金属电极盖(400)中部具有朝上凸起的第一凸起(420),所述第一凸起(420)穿过所述底盖(520),所述第一凸起(420)中心具有贯通的加液口(421),所述顶盖(510)对应所述第一凸起(420)设有朝下凸起的密封凸起(511),所述密封凸起(511)与所述第一凸起(420)相抵 以将所述加液口(421)密封。The metal-air battery according to claim 5, characterized in that: the middle part of the metal electrode cover (400) has a first protrusion (420) protruding upward, and the first protrusion (420) passes through the The bottom cover (520), the center of the first protrusion (420) has a through liquid filling port (421), and the top cover (510) is provided with a downward protrusion corresponding to the first protrusion (420) The sealing protrusion (511) of the sealing protrusion (511) abuts against the first protrusion (420) to seal the filling port (421).
  7. 根据权利要求6所述的金属空气电池,其特征在于:所述底盖(520)对应密封凸起(511)设有朝上凸起的第二凸起(521),所述第二凸起(521)中心具有供所述第一凸起(420)穿入的中心孔(523),所述密封凸起(511)底部至少部分嵌入所述中心孔(523)。The metal-air battery according to claim 6, characterized in that: the bottom cover (520) is provided with a second protrusion (521) protruding upward corresponding to the sealing protrusion (511), and the second protrusion The center of the (521) has a central hole (523) for the first protrusion (420) to penetrate, and the bottom of the sealing protrusion (511) is at least partially embedded in the central hole (523).
  8. 根据权利要求6所述的金属空气电池,其特征在于:所述密封凸起(511)与所述第一凸起(420)之间夹设有第二密封圈(540)。The metal-air battery according to claim 6, characterized in that: a second sealing ring (540) is sandwiched between the sealing protrusion (511) and the first protrusion (420).
  9. 根据权利要求1所述的金属空气电池,其特征在于:所述空腔(110)前后侧的开口处外端边缘具有一供第一空气电极膜(300)贴合的环形贴合面,所述侧板(200)朝向环形贴合面的一侧设有与所述环形贴合面对应的环形压紧面,所述环形压紧面设有若干盲孔(211),所述侧板(200)设有第二通气孔(220),所述第二通气孔(220)位于所述环形压紧面的包围范围内;所述环形压紧面和所述环形贴合面之间夹设有压紧框(260),所述压紧框(260)用于在所述侧板(200)环形压紧面的抵压下将第一空气电极膜(300)压紧于环形贴合面上;所述盲孔(211)内安装有预紧弹簧(270),所述预紧弹簧(270)用于对所述压紧框(260)施加将其推向所述环形贴合面的弹性预紧力。The metal-air battery according to claim 1, wherein the outer edge of the opening at the front and rear sides of the cavity (110) has an annular bonding surface for bonding the first air electrode film (300), so The side of the side plate (200) facing the annular bonding surface is provided with an annular pressing surface corresponding to the annular pressing surface, the annular pressing surface is provided with a plurality of blind holes (211), and the side plate (200) A second vent hole (220) is provided, the second vent hole (220) is located in the surrounding range of the annular pressing surface; the annular pressing surface and the annular fitting surface are sandwiched between A compression frame (260) is provided, and the compression frame (260) is used to press the first air electrode film (300) against the ring under the pressure of the ring pressing surface of the side plate (200) On the surface; the blind hole (211) is installed with a pre-tension spring (270), the pre-tension spring (270) is used to apply the compression frame (260) to push it toward the annular fitting surface The elastic pre-tightening force.
  10. 根据权利要求9所述的金属空气电池,其特征在于:所述压紧框(260)朝向所述侧板(200)凸起形成有与所述盲孔(211)对应匹配的定位柱(261),所述定位柱(261)插入所述盲孔(211)内并可沿所述盲孔(211)滑动。The metal-air battery according to claim 9, characterized in that: the compression frame (260) is protruding toward the side plate (200) and is formed with positioning posts (261) corresponding to the blind holes (211). ), the positioning post (261) is inserted into the blind hole (211) and can slide along the blind hole (211).
PCT/CN2021/095305 2020-05-25 2021-05-21 Metal-air battery WO2021238811A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202020902566.4 2020-05-25
CN202020902566.4U CN212033096U (en) 2020-05-25 2020-05-25 Metal-air battery

Publications (1)

Publication Number Publication Date
WO2021238811A1 true WO2021238811A1 (en) 2021-12-02

Family

ID=73480058

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2021/095305 WO2021238811A1 (en) 2020-05-25 2021-05-21 Metal-air battery

Country Status (2)

Country Link
CN (1) CN212033096U (en)
WO (1) WO2021238811A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117524612A (en) * 2023-11-02 2024-02-06 湖北美瑞特空调系统有限公司 Base and equipment of thermistor

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN212033096U (en) * 2020-05-25 2020-11-27 湖南西瑞尔新材料科技有限公司 Metal-air battery

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2575855Y (en) * 2002-09-23 2003-09-24 林雍荏 Card connector
US20160020498A1 (en) * 2013-03-25 2016-01-21 Sharp Kabushiki Kaisha Metal-air battery
CN105428755A (en) * 2015-12-28 2016-03-23 台州非常新能源科技有限公司 Portable metal-air battery stand-by power supply
CN205355210U (en) * 2015-12-21 2016-06-29 深圳海能动力控股有限公司 Air battery
CN208478424U (en) * 2018-07-06 2019-02-05 杨俊� A kind of portable combined special power supply box body structure
CN212033096U (en) * 2020-05-25 2020-11-27 湖南西瑞尔新材料科技有限公司 Metal-air battery

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2575855Y (en) * 2002-09-23 2003-09-24 林雍荏 Card connector
US20160020498A1 (en) * 2013-03-25 2016-01-21 Sharp Kabushiki Kaisha Metal-air battery
CN205355210U (en) * 2015-12-21 2016-06-29 深圳海能动力控股有限公司 Air battery
CN105428755A (en) * 2015-12-28 2016-03-23 台州非常新能源科技有限公司 Portable metal-air battery stand-by power supply
CN208478424U (en) * 2018-07-06 2019-02-05 杨俊� A kind of portable combined special power supply box body structure
CN212033096U (en) * 2020-05-25 2020-11-27 湖南西瑞尔新材料科技有限公司 Metal-air battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117524612A (en) * 2023-11-02 2024-02-06 湖北美瑞特空调系统有限公司 Base and equipment of thermistor
CN117524612B (en) * 2023-11-02 2024-05-14 湖北美瑞特空调系统有限公司 Assembling equipment for thermistor

Also Published As

Publication number Publication date
CN212033096U (en) 2020-11-27

Similar Documents

Publication Publication Date Title
WO2021238811A1 (en) Metal-air battery
US20100330416A1 (en) Electrolyte injection and explosion proof device for use in power batteries
JP6987371B2 (en) Full tab assembly structure of lithium battery cover plate
US6791825B1 (en) Tablet computer housing and method of construction
CN115117578B (en) Sealing nail and application thereof, sealing assembly and application and sealing method thereof
WO2020258376A1 (en) Battery formation device
KR20100014664A (en) Battery mouth-sealing assembly and battery including the same
WO2024045458A1 (en) Top cover assembly, battery, and electric device
JP2023537543A (en) Top Cover Assembly for Batteries, Batteries, and Devices Using Batteries as Power Sources
CN209183611U (en) Battery modules
EP4095992A1 (en) Button battery, battery sealing structure, and pre-assembly unit
CN207141419U (en) Attachment means and unmanned plane device
KR20170088032A (en) Device for compensating assembling power of fuel cell stack
CN217954922U (en) Wrist-watch compresses tightly fixed subassembly from top to bottom
US11646469B2 (en) Battery pack case and battery pack
CN216793833U (en) Battery cover plate and battery pack
EP3836129B1 (en) Led display waterproof structure
CN212033149U (en) Air electrode membrane mounting structure and metal-air battery
CN219066991U (en) Battery top cap subassembly and battery
WO2020103151A1 (en) Battery housing, battery assembly, electronic device, and battery assembly method
CN212033094U (en) Metal-air battery side plate and metal-air battery
CN210379152U (en) Battery case and sealing structure thereof
CN108110201B (en) Pole piece fixing mechanism and button cell
CN218101496U (en) Switching device, battery pack and vehicle
CN207394749U (en) A kind of assembly type light bar connector

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21814027

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 21814027

Country of ref document: EP

Kind code of ref document: A1