WO2021230766A1

WO2021230766A1 - Complex for cleaning assorted surfaces

Info

Publication number: WO2021230766A1
Application number: PCT/RU2021/000132
Authority: WO
Inventors: Елена Юрьевна БЕЛОУС; Светлана Анатольевна ЗАКИРОВА
Original assignee: Общество С Ограниченной Ответственностью "Сплат Глобал"
Priority date: 2020-05-11
Filing date: 2021-03-26
Publication date: 2021-11-18
Also published as: RU2020116749A

Abstract

The invention relates to compositions containing active ingredients based on bacterial lysates, which can be used for producing cleaning agents, such as detergents for washing laundry, dishes, floors, toilets, sinks, bathrooms and glass. The claimed composition contains 1) a lysate of propionibacteria of the species Propionibacterium shermanii, 2) Gossypium Herbaceum seed extract, 3) glycerol, (4) a non-ionic surfactant based on a glycoside.

Description

COMPLEX FOR CLEANING VARIOUS SURFACES

FIELD OF TECHNOLOGY

The invention relates to compositions for household chemicals, more specifically to a complex of active ingredients based on bacterial lysate used for the preparation of detergents, such as detergents for washing clothes, washing dishes, floors, toilet bowl, sink, bathroom, glass, fabric softeners.

LEVEL OF TECHNOLOGY

Finding effective ingredients and their combinations as detergents for cleaning various types of surfaces is an everyday task for companies involved in the production of detergents. Today, there are many products on the market designed for cleaning various types of surfaces, which somehow cope with their purpose.

Known washing powder BIO-COLOR for colored linen with cotton extract, having the following composition: 5-15% zeolites, nonionic surfactants; <5% anionic surfactants, polycarboxylates, soap, enzymes, cotton extract (https://www.splat.ru/products/biomio/stiralnyy-poroshok-bio- color-s-ekstraktom-khlopka /).

Known fabric softener with eucalyptus essential oil and cotton extract BIO-SOFT, having the following composition: 5-15% cationic surfactants; <5% preservative (phenoxyethanol), natural perfume based on eucalyptus essential oil, cotton extract, citral, limonene, linalool (https://www.biomio.ru/item/l 33 /? Aroma_id = l 5).

Known means for washing dishes, vegetables and fruits with essential oil of mint and cotton extract BIO-CARE, having the following composition: 5-15% anionic surfactants, <5% nonionic surfactants, amphoteric surfactants, pH- regulators, antiseptic agent (silver citrate), mint essential oil, cotton seed extract, disodium EDTA salt (https://www.biomio.ru/item/135/).

Known composition and its use for the preparation of dishwashing detergents containing a compound selected from methylglycine diacetate, as well as its salts, bismuth salt and one homopolymer or copolymer of ethyleneimine. The composition provides inhibition of glass corrosion (RU 2623443 C2 publ. 26.06.2017 Cl 1D 3/33).

The known composition of the detergent, which can be used for manual and automatic washing of dishes and household appliances in everyday life and at public catering establishments. The composition contains, wt% nonionic surfactants - 20-40, carbamide - 3-8, glycerin - 2-5, lotions with perfume and dye based on ethyl alcohol denatured - 2-10, wheat germ oil - 0.001-0.1 and water. The tool provides an increase in washing action without harmful effects on the skin of the hands (RU 2198207 C2 publ. 10.02.2003 Cl 1D 1/66).

The compositions described above have a number of components that are undesirable for use in products that are in direct contact with the skin of the hands and are not safe for the environment. Anionic surfactants in the compositions are quite effective, however, the sulfate residue causes an aggressive effect on the skin of the hands, in particular, an increase in sensitivity and irritation of the skin of the hands with minimal contact. Synthetic preservatives such as phenoxyethanol, when used frequently in food formulations, are allergenic and irritating when used continuously.

The task to which the claimed group of inventions is directed is to develop a universal complex that serves as the basis for cleaning products for various surfaces (fabrics, floor coverings, plumbing, etc.), safe for hands while maintaining its functionality. The technical result of the claimed group of inventions consists in the development of a complex of active ingredients and agents based on it for the effective removal of contaminants of various nature while maintaining a beneficial effect on the sensitive skin of the hands and the environment as a whole.

The claimed technical result is achieved by the fact that the complex of active ingredients for use in detergents contains 1) lysate of propionic acid bacteria of the species Propionibacterium shermanii (Propionibacterium freudenreichii subsp. Shermanii), 2) seed extract

Gossypium Herbaceum, 3) glycerin, 4) glycoside-based non-ionic surfactant.

A decyl glycoside such as Plantacare 2000 UP, Glucopon 215 UP or Natural APG HG 0814CM, or a cocoglycoside such as Natural APG HG 0814R37 or Plantacare 818 UP can be used as the glycoside-based nonionic surfactant.

In an embodiment, a complex is provided in which the detergent is a laundry detergent or a delicate laundry detergent or a baby linen detergent.

In an embodiment, a complex is provided in which the detergent is a dishwashing detergent, preferably a detergent in the form of a soap.

In an embodiment, a complex is proposed, in which the detergent is a means for cleaning floors, a toilet bowl, a sink, a bathtub or glasses.

Also declared is a detergent containing the claimed complex of active ingredients. The detergent may additionally contain silver, citric acid, essential oil, cocamidopropyl betaine, sodium cocoamphoacetate, sodium ethylhexyliminodipropionate such as Mackam OiP-40, sodium C 12 -C 18 alkyl sulfate, potassium cocoate such as Mackadet 40K, sodium cocoyl glutamate Amisoft CS 22, coconut sodium such as Sulfopon 1216 G, palm esterquat such as Rewoquat WE 28, glyceret-6 cocoate such as Levenol F-200, Lamesoft PO 65, Laureth-9 & Laureth-3, Laureth-7 Gifran 7M, Dehypound SK 7 , Dehypon E-127, Glucotain Sense, Plantatex LLE, tetrasodium glutamate diacetate, Dissolvine GL-47-S - chelate.

The detergent according to the claimed invention may be a laundry detergent or a delicate laundry detergent or a baby linen detergent or dishwashing detergent. And can be made in soap form.

The detergent can be for cleaning floors, a toilet, a sink, a bathtub, or glass.

The claimed complex of active ingredients can be used in the manufacture of detergents or detergents for washing clothes or detergents for delicate laundry or detergents for washing children's linen or dishwashing detergents or detergents for cleaning floors, toilet bowl, sink, bathtub or glass.

DETAILED DESCRIPTION OF THE INVENTION

The authors of the invention found that the combination of lysate of propionic acid bacteria of the species Propionibacterium shermanii, extract of seeds of Gossypium Herbaceum, glycerin, non-ionic surfactant based on glycoside led to an improved, super-total (synergistic) effect, which made it possible to reduce the individual content of ingredients while maintaining beneficial effects and thereby reduce the burden on the environment.

A non-ionic surfactant (surfactant) based on a glycoside has an amphoteric nature, due to which it effectively wets the contaminated surface, destroys and removes contaminants through the formation of lamellar layers. Glycosidic non-ionic surfactant has a high foaming ability while maintaining fine mesh foam for effective removal of dirt in low concentration and delicate action on various surfaces. Glycerin molecules complement the action of the glycoside-based non-ionic surfactant by associating with water molecules and allowing them to better penetrate deeper into the dirt. Gossypium Herbaceum Seed Extract contains glycosides, saponins, various phenolic compounds and lipases that stabilize foam and enhance the action of surfactants to remove impurities. Additionally, glycerin and Gossypium Herbaceum extract have the ability to moisturize the skin of the hands with constant use, which ensures the restoration of the skin when using household chemicals in the current epidemiological situation. Lysate of propionic acid bacteria Propionibacterium shermanii preserves the beneficial microflora of the skin of the hands, since resident microorganisms protect against opportunistic microorganisms and are involved in maintaining the immune function of the skin. Thus, the complex of active ingredients has a synergistic effect on the washing of various surfaces, fabrics and has a beneficial effect on the skin of the hands.

It should be noted that the complex can be used for washing various surfaces and washing all types of fabrics. The active components of the complex together do not change the strength characteristics of the fibers of the fabric, protect the colored fibers from color washout, make the fabric softer to the touch during prolonged washings and facilitate ironing, which expands the scope of the complex in the composition of detergents.

The glycoside can be a decylglycoside such as Plantacare 2000 UP, Glucopon 215 UP or Natural APG HG 0814CM, a cocoglycoside such as Natural APG HG 0814R37 or Plantacare 818 UP.

Additionally, the detergent may contain silver (for example, in the form of a silver salt such as silver citrate), citric acid, essential oil, cocamidopropyl betaine, sodium cocoamphoacetate, sodium ethylhexyliminodipropionate such as Muscat CHP-40, sodium C 12-C18 alkyl sulfate, potassium cocoate such as Mackadet 40K, sodium cocoyl glutamate such as Amisoft CS 22, sodium coco sulfate such as Sulfopon 1216 G, palm esterquat WE such as Rewo 28, glyceret-6 cocoate such as Levenol F-200, Lamesoft PO 65, Laureth-9 & Laureth-3, laureth-7 Gifran 7M, Dehypound SK 7, Dehypon E-127, Glucotain Sense, Plantatex LLE, glutamate diacetate tetrasodium , Dissolvine GL-47-S - chelate.

The content of lysate of propionic acid bacteria of the species Propionibacterium shermanii in the detergents according to the invention can be in the range from 0.001 to 1 May. % depending on the type of product and the intensity of the desired properties. Thus, the lysate of propionic acid bacteria of the species Propionibacterium shermanii can be contained in an amount from 0.001 to 1 May. %, from 0.002 to May 1. %, from 0.003 to May 1. %, from 0.004 to May 1. %, from 0.005 to May 1. %, from 0.006 to May 1. %, from 0.007 to May 1. %, from 0.008 to May 1. %, from 0.009 to May 1. %, from 0.01 to May 1. %, from 0.02 to May 1. %, from 0.03 to May 1. %, from 0.04 to May 1. %, from 0.05 to May 1. %, from 0.06 to May 1. %, from 0.07 to May 1. %, from 0.08 to May 1. %, from 0.09 to May 1. %, from 0.1 to May 1. %, from 0.2 to May 1. %, from 0.3 to May 1,%, from 0.4 to May 1. %, from 0.5 to 1 May. %, from 0.6 to May 1. %, from 0.7 to May 1. %, from 0.8 to May 1. %, from 0.9 to May 1. %.

The Gossypium Herbaceum seed extract can be an INCI product: Hydrolysed cotton (seed) protein from various manufacturers, for example, COLTIDE ™ COTTON-LQ- (WD) from Croda.

The content of the Gossypium Herbaceum seed extract according to the invention can be in the range from 0.001 to May 1. % depending on the type of product and the intensity of the desired properties. So, the extract of seeds of Gossypium Herbaceum can be contained in an amount from 0.001 to 1 May. %, from 0.002 to May 1. %, from 0.003 to May 1. %, from 0.004 to May 1. %, from 0.005 to May 1. %, from 0.006 to May 1. %, from 0.007 to May 1. %, from

0.008 to May 1. %, from 0.009 to May 1. %, from 0.01 to May 1. %, from 0.02 to May 1. %, from 0.03 to May 1. %, from 0.04 to May 1. %, from 0.05 to May 1. %, from 0.06 to May 1. %, from 0.07 to May 1. %, from 0.08 to May 1. %, from 0.09 to May 1. %, from 0.1 to May 1. %, from 0.2 to May 1. %, from 0.3 to May 1. %, from 0.4 to May 1. %, from 0.5 to 1 May. %, from 0.6 to May 1. %, from 0.7 to May 1. %, from 0.8 to May 1. %, from 0.9 to May 1. %.

The content of glycerin in the compositions according to the invention can range from 1 to 10% by weight. depending on the type of product and the intensity of the desired properties. Glycerin can be contained in an amount from 1 to 10 May. %, from 2 to 9 May. %, from 3 to 8 May. %, from 4 to 7 May. %, from 5 to 6 May. %, including 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5 , 9, 9.5 or 10 May. %.

The content of the glycoside-based nonionic surfactant can range from 1 to 10 wt%. depending on the type of product and the intensity of the desired properties. Glycerin can be contained in an amount from 1 to 10 May. %, from 2 to 9 May. %, from 3 to 8 May. %, from 4 to 7 May. %, from 5 to 6 May. %.

The inventors have discovered the advantages of combining a lysate of propionic acid bacteria of the species Propionibacterium shermanii and an extract of Gossypium Herbaceum seeds with nonionic surfactants based on a glycoside in the presence of glycerol. Improved, super-cumulative (synergistic) action made it possible to reduce the individual content of each of the components while maintaining the beneficial effects and thereby reduce the burden on the environment.

Nonionic glycoside surfactants can be a decylglycoside such as Plantacare 2000 UP from Basf contains Alkipolyglycoside C 10-16 (INCI: Alkylpolyglycoside C 10-16), Alkipolyglycoside C8-10 (INCI: Alkyl polyglycoside C8-10), or Basf's Glucopon 215 UP contains Caprylyl / Decyl Glucoside (INCI: Caprylyl & Decyl Glucoside) or Natural APG HG 0814CM manufactured by H ^ contains D-glucopyranose oligomers C10-16-alkyl glycosides (INCI: D-Glucopyranose, oligomeric, C10-16-alkyl glycosides), D-glucopyranose oligomers decyl octyl glycosides (INCI: D- Glucopyranose, oligomers decyl octyl glycosides) or Natural APG HG 0814R37 produced by ^ contains D-glucopyranose oligomers C 10-16-alkyl glycosides (INCI: D-Glucopyranose, oligomeric, C 10-16-alkyl glycosides), D-glucopyranose oligomers decyl octyl glycosides (INCI : D-Glucopyranose, oligomers, decyl octyl glycosides), or Plantacare 818 UP from Basf contains Polyalkylglycoside C8-16 (INCI: Polyalkylglycoside C8-16).

The content of Plantacare 2000 UP in the detergents according to the invention can range from 1 to 10 May. % depending on the type of product and the intensity of the desired properties. Thus, Plantacare 2000 UP can be contained in quantities from 1 to 10 May. %, from 2 to 9 May. %, from 3 to 8 May. %, from 4 to 7 May. %, from 5 to 6 May. %, including 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6.6.5, 7, 7.5, 8, 8.5 , 9, 9.5 or 10 May. %

The content of Glucopon 215 UP according to the invention can be in the range from 1 to 10 May. % depending on the type of product and the intensity of the desired properties. So, Glucopon 215 UP can be contained in quantities from 1 to 10 May. %, from 2 to 9 May. %, from 3 to 8 May. %, from 4 to 7 May. %, from 5 to 6 May. %, including 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6.6.5, 7, 7.5, 8, 8.5 , 9, 9.5 or 10 May. %

The content of Natural APG HG 0814CM according to the invention can be in the range from 1 to 10 May. % depending on the type of product and the intensity of the desired properties. So, NaturalAPG HG 0814CM can be contained in an amount from 1 to 10 May. %, from 2 to 9 May. %, from 3 to 8 May. %, from 4 to 7 May. %, from 5 to 6 May. %, including 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6.6.5, 7, 7.5, 8, 8.5 , 9, 9.5 or 10 May. %

The content of Natural APG HG 0814R37 according to the invention can be in the range from 1 to 10 May. % depending on the type of product and the intensity of the desired properties. So, NaturalAPG HG 0814R37 can contained in an amount from 1 to 10 May. %, from 2 to 9 May. %, from 3 to 8 wt.%, from 4 to 7 May. %, from 5 to 6 May. %, including 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6.6.5, 7, 7.5, 8, 8.5 , 9, 9.5 or 10 May. %.

The content of Plantacare 818 UP according to the invention can range from 1 to 10 May. % depending on the type of product and the intensity of the desired properties. Thus, Plantacare 818 UP can be contained in quantities from 1 to 10 May. %, from 2 to 9 May. %, from 3 to 8 May. %, from 4 to 7 May. %, from 5 to 6 May. %, including 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6.6.5, 7, 7.5, 8, 8.5 , 9, 9.5 or 10 May. %.

REWOQUAT WE 28 RM contains Dihydrogenated Palmoylethyl Hydroxyethylmonium Methosulfate (INCI: Dihydrogenated Palmoylethyl Hydroxyethylmonium Methosulfate) and Isopropanol (INCI: Isopropanol). PROTECTOL PECO contains 2-Phenoxyethanol (INCI: Phenoxyethanol). Optiphen BD contains Benzyl alcohol (INCI: Benzyl alcohol), Benzoic acid (INCI: Benzoic acid), Dehydroacetic acid (INCI: Dehydroacetic acid). COLTIDE COTTON-LQ- (WD) contains Hydrolysed Cotton Protein (INCI: Hydrolysed cotton protein) and 2- Phenoxyethanol (INCI: Phenoxyethanol). Plantacare 2000 UP contains Alkipolyglycoside C 10-16 (INCI: Alkylpolyglycoside Cl 0-16), Alkipolyglycoside C8-10 (INCI: Alkyl polyglycoside C8-10). Plantacare 818 UP contains Polyalkylglycoside C8-16 (INCI: Polyalkylglycoside C8-16). Sulfopon 1216 G contains sodium salts of sulfuric acid and mono-C12-18-alkyl esters (INCI: Sulfuric acid, mono-C 12-18-alkyl esters, sodium salts). GlucoTain Sense PE drum 200 contains 1-Deoxy-1- (methyl- (C18 and Cl 8 (unsaturated)) - alkanoyl) amino) -E ⁾ -Glucitol (INCI: l-Deoxy-l- (methyl- (C18 and Cl 8 (unsaturated)) - alkanoyl) amino) - D-Glucitol). Lamesoft PO 65 contains C16-18 and C18-unsaturated. mono- and diglycerides; D-Glucopyranose, oligomers, decyl octyl glycosides; D-Glucopyranose, oligomers, C10-16 alkyl glycosides; citric acid (INCI: Glycerides, C 16-18 and C18-unsatd. mono- and di-; D-Glucopyranose, oligomers, decyloctylglycosides; D-Glucopyranose, oligomeric, C10-16-alkylglycosides; Citric acid). Dehyton PK 45 contains C8-18 / 18-unsaturation. amidopropyl betaine (INCI: C8-18 / 18-unsatd. amidopropyl betaine). PURAC FCC 80 contains L-lactic acid (INCI: L-lactic acid). Trilon M Granules SG contains Trisodium salt of Methylglycinediacetic acid (MGDA). MACKADET 40-K contains Potassium Cocoate (INCI: Potassium Cocoate). LEVENOL F-200 contains Glycereth-6 Cocoate (INCI: Glycereth-6 Cocoate).

Components of the complex 1) lysate of propionic acid bacteria of the species Propionibacterium shermanii, 2) extract of seeds of Gossypium Herbaceum, 3) glycerin, 4) nonionic surfactant based on glycoside can be present in various mass ratios in the complex according to the invention and, accordingly, in any means containing it. Preferably, the mass ratio of the components 1: 2: 3: 4 in the complex can be: (0.001-1): (0.001-1): (1-10): (1-10), incl. (0.01-1): (0.01-1): (1-10): (1-10), (0.1-1): (0.1-1): (1-10): (1-10), (1): (1): (1-10): (1-10), (0.01-1): (0.01-1): (1-8): (1 -8), (0.01-1): (0.01-1): (1-6): (1-6), (0.01-1): (0.01-1): (1 -4): (1-4), (0.01-1): (0.01-1): (1-2): (1-2), (0.01-1): (0.01 -1): (1): (1), or 1: 1: 1: 1.

EXAMPLES

Example 1. Study of the synergism of active components The complex of active components according to the invention (table 1) was studied in the composition of detergents on the same basis.

Table 1

Table 2 shows the results on the effectiveness of compositions K1-K9 in the composition of dishwashing detergent in points. Composition K9 (control), which does not contain any of the components according to the invention, was taken as the baseline. Scores are given from 1 to 10 in relation to this control composition, where 10 is the best value. The main effects of the composition were the effective removal of impurities of various nature from the surface of the dishes, the skin tolerance of the product and the beneficial effect on the skin of the hands.

table 2

Table 3 shows the results on the effectiveness of the compositions K1-K9 in the composition of the detergent in points. Composition K9 (control), which does not contain any of the components according to the invention, was taken as the baseline. Scores are given from 1 to 10 in relation to this control composition, where 10 is the best value. The main effects of the composition were effective cleaning of fabric fibers, preservation of the shape and color of fabrics, effective and safe action on fabric fibers during washing and softening effect on fibers. Table 3

Table 4 shows the results on the effectiveness of the compositions K1-K9 in the composition of the floor cleaner in points. Composition K9 (control), which does not contain any of the components according to the invention, was taken as the baseline. Scores are given from 1 to 10 in relation to this control composition, where 10 is the best value. The main effects of the composition were to effectively remove impurities of various natures from the floor surface, gently affect various surfaces (laminate, linoleum, parquet boards, ceramic tiles, plastic, stone and wood floors) and give shine, skin tolerance of the product and a beneficial effect on the skin of the hands. ...

Table 4

From the data presented in tables 2-4, it follows that the complex of active ingredients in accordance with the claimed invention exhibits an unexpected synergistic effect.

The claimed invention is also illustrated by the following examples with specific compositions of various agents.

Table 5. Basis for laundry detergent N ° 1.

Table 6. Basis for laundry detergents according to the invention JNel.

Table 7. The basis of fabric softener L ° 1 with a reduced content of ingredients.

Table 8. Comparative effectiveness of fabric softener Nsl, fabric softener according to the invention .Nel, fabric softener N2I with reduced content of ingredients. The composition of the N2I fabric softener is taken as the baseline. The scores are numbered from 1 to 10 in relation to the baseline, where 10 is the best value.

Table 8

As can be seen from the data included in Table 8, the effectiveness of fabric softener Nel and fabric softener N ° 1 with reduced ingredients of the invention were similar, and simultaneously higher than that of fabric softener N "1 (control), which makes it possible to reduce load on the environment and achieve economic benefits while maintaining the effective action of the tool.

The developed complex has a natural origin and biodegradability of more than 60% in 28 days. Components e are aimed at reducing the concentration of active and auxiliary substances in the composition of surface cleaners to reduce the time of biodegradation and reduce the load on the ecosystem.

Table 9. Basis of fabric softener K 2.

Table 10. Fabric softener base according to the invention> D ° 2.

Table 11. Fabric softener N ° 2 base with reduced ingredients.

Table 12. Composition of liquid hand soap.

Table 13. Composition of liquid detergent.

Table 14 presents the results for assessing the effect on sensitive skin of the hands of surface cleaners in points. The scores are from 1 to 10, where 10 is the best value for a gentle effect on sensitive skin of the hands (no increase in sensitivity). The main effects of the products were a beneficial effect on the skin of the hands due to an increase in the state of moisture, restoration of the skin, maintaining a normal microbiota of the skin of the hands and a softening effect.

Table 14

The above data are part of the data obtained in the course of confirmation of the achievement of the technical result of the claimed invention and in no way limit the scope of the invention. The experiments carried out confirmed the effectiveness of the developed universal complex of active ingredients, which has a synergistic effect for use in various detergents, including fabrics, floor coverings, sanitary ware, dishes and glasses.

Claims

CLAIM

1. A complex of active ingredients for use in detergents, consisting of 1) lysate of propionic acid bacteria of the species Propionibacterium shermanii, 2) extract of seeds of Gossypium Herbaceum, 3) glycerin, 4) non-ionic surfactant based on glycoside.

2. The complex according to claim 1, characterized in that the nonionic glycoside-based surfactant is a decylglycoside selected from Plantacare 2000 UP or Glucopon 215 UP or Natural APG HG 0814CM, or a cocoglycoside selected from Natural APG HG 0814R37 or Plantacare 818 UP.

3. A complex according to claim 1 or 2, characterized in that the detergent is a laundry detergent.

4. A complex according to claim 3, characterized in that the laundry detergent is a delicate laundry detergent.

5. The complex according to claim 3, characterized in that the laundry detergent is a detergent for washing children's clothes.

6. A complex according to claim 1 or 2, characterized in that the detergent is a dishwashing detergent.

7. A complex according to claim 1 or 2, characterized in that the detergent is in the form of a soap.

8. The complex according to claim 1 or 2, characterized in that the detergent is a means for cleaning floors, a toilet bowl, a sink, a bathtub or glass.

9. Means for washing containing a complex according to any one of paragraphs. 12.

10. The agent according to claim 9, characterized in that it additionally contains silver, citric acid, essential oil, cocamidopropyl betaine, sodium cocoamphoacetate, sodium ethylhexylimino dipropionate, such as Mackam OiP-40, sodium C 12-C 18 alkyl sulfate, potassium cocoate, such as Mackadet 40K, sodium cocoyl glutamate such as Amisoft CS 22, sodium coco sulfate such as Sulfopon 1216 G, palm esterquat such as Rewoquat WE 28, glyceret-6 cocoate such as Levenol F-200, Lamesoft PO 65, Laureth-9 & Laureth-Z, laureth-7 Gifran 7M, Dehypound SK 7, Dehypon E-127, Glucotain Sense, Plantatex LLE, tetrasodium glutamate diacetate, Dissolvine GL-47-S - chelate.

11. A detergent according to claim 9 or 10, characterized in that the detergent is a laundry detergent.

12. A detergent according to claim 11, characterized in that the laundry detergent is a delicate laundry detergent.

13. A detergent according to claim 11, characterized in that the laundry detergent is a detergent for washing children's clothes.

14. A detergent according to claim 9 or 10, characterized in that the detergent is a dishwashing detergent.

15. A detergent according to claim 9 or 10, characterized in that the detergent is in the form of a soap.

16. A detergent according to claim 9 or 10, characterized in that the detergent is a detergent for cleaning floors, a toilet bowl, a sink, a bathtub or glasses.

17. The use of a complex of active ingredients according to any one of claims. 1-2 for the manufacture of detergents according to any one of paragraphs. 9-16.

18. Use according to claim 17, characterized in that the detergent is a laundry detergent.

19. Use according to claim 18, characterized in that the laundry detergent is a delicate laundry detergent.

20. Use according to claim 18, characterized in that the laundry detergent is a laundry detergent for children.

21. Use according to claim 17, characterized in that the detergent is a dishwashing detergent.

22. Use according to claim 17, characterized in that the detergent is in the form of a soap.

23. Use according to claim 17, characterized in that the detergent is a detergent for cleaning floors, a toilet bowl, a sink, a bathtub or glass.