WO2021140452A1 - Detergent composition, and cleaning sheet and cleaning method for hard surface - Google Patents
Detergent composition, and cleaning sheet and cleaning method for hard surface Download PDFInfo
- Publication number
- WO2021140452A1 WO2021140452A1 PCT/IB2021/050081 IB2021050081W WO2021140452A1 WO 2021140452 A1 WO2021140452 A1 WO 2021140452A1 IB 2021050081 W IB2021050081 W IB 2021050081W WO 2021140452 A1 WO2021140452 A1 WO 2021140452A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- component
- mass
- less
- detergent composition
- acid
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Definitions
- a cleaning agent composition, a hard surface cleaning sheet, and a hard surface cleaning method TECHNICAL FIELD This invention relates to a cleaning agent composition, a hard surface cleaning sheet, and a hard surface cleaning method.
- BACKGROUND OF THE INVENTION There are various hard surfaces made of tiles, plastics, metals, etc. in the living environment equipment of E1. These hard surfaces are exposed to environments where various dirt will adhere in life scenes. Among them, hard surfaces used in toilets, bathrooms, kitchens, etc. are also surfaces that people touch daily, so they tend to remain and accumulate a large amount of dirt, making it difficult to clean and remove.
- Patent Document 1 a wet wipe dedicated to kitchen cleaning and disinfection is disclosed.
- the functional liquid contains: sodium a-alkenyl sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate, C12 fatty alcohol polyoxyethylene (9) ether, disodium edetate, citric acid, sodium citrate, 1, 2-Propylene: Glycol, etc., and shows excellent cleaning power against stubborn denatured oil stains.
- Patent Literature 1 CN103340584 SUMMARY OF THE INVENTION
- the present invention provides a cleaning agent composition suitable for hard surface cleaning, which has high cleaning power against grease and dirt, and has less white residue after cleaning.
- the present inventors discovered that by combining specific polyoxyethylene glycerin fatty acid esters, specific surfactants, and specific acids and/or salts as effective cleaning ingredients in the detergent composition, the hydrophobicity of the detergent composition can be improved , The cleaning active ingredient in the detergent composition can be easily adsorbed on the grease dirt and improve the cleaning power against grease dirt.
- a small amount of cleaning active ingredients or cleaning auxiliary ingredients can achieve high cleaning power, and at the same time can significantly reduce the white residue as wiping marks after the cleaning composition cleans and wipes hard surfaces.
- white residue means that after the cleaning agent composition is cleaned on a hard surface, especially after wiping the hard surface, the volatiles such as water and ethanol on the hard surface volatilize and remain on the hard surface. White substance on the surface of the texture.
- the present invention relates to a detergent composition, which contains the following components (A) ⁇ (D), component (A): polyoxyethylene cargo oil fatty acid, wherein the polyoxyethylene glycerol fatty acid ester has an oxyethylene group The average added mole number is 10 moles or less, and has a linear or branched saturated or unsaturated fatty acyl group with a carbon number of 12 or less; component (B): water; component (C): other than component (A) Surfactant having an alkyl or alkenyl group with carbon atoms of 8-18; and component (D)-selected from one or more of the following components (D1) and (D2):
- (D2) Inorganic salt, in the detergent composition, when the content of component (A) is 0.35% by mass or more and 5% by mass or less, and the content of component (DO is in terms of acid, and the content of component (D2) is in terms of salt)
- the content of component (D) is 0.005 mass% or more and 0.4 mass% or less, and as the total content of component (A) and component (C), (A) + (C) is 10 mass% or less.
- the present invention relates to A hard surface cleaning sheet, which contains the cleaning agent composition of the present invention.
- the present invention relates to a hard surface cleaning method, which applies the cleaning agent composition of the present invention to hard surfaces for cleaning.
- the detergent composition of the present invention has high cleaning power against grease and dirt, and has the effect of less white residue after cleaning hard surfaces.
- the detergent composition of the present invention can be applied to various hard surfaces.
- white residue means that after the cleaning agent composition is cleaned on a hard surface, especially after wiping the hard surface, the residual water, ethanol and other volatiles on the hard surface will remain on the hard surface after volatilization. White substance on hard surfaces.
- the detergent composition of the present invention is a liquid detergent composition containing component (A), component (B), component (C), and component (D).
- the component (A) of the present invention is a polyoxyethylene glycerin fatty acid ester, wherein the average added mole number of the oxyethylene group of the polyoxyethylene glycerin fatty acid ester is 10 mol or less, and has A linear or branched saturated or unsaturated fatty acyl group having 12 to T carbon atoms.
- Ingredient (A) is a cleansing effective ingredient.
- the component (A) may contain 1 or more and 3 or less fatty acyl groups.
- the number of carbon atoms of the fatty acid that is the source of the fatty acid ester of the component (A) is preferably 8 or more and S.12 or less, and more preferably 8 or more and 10 or less from the viewpoint of improving the cleaning power.
- fatty acids one may be selected from various caprylic acids (for example, 2 ethylhexanoic acid), various nonanoic acids, various capric acids, various undecanoic acids, and various dodecanoic acids.
- various caprylic acids for example, 2 ethylhexanoic acid
- nonanoic acids for example, 2 ethylhexanoic acid
- capric acids for example, 2 ethylhexanoic acid
- undecanoic acids various dodecanoic acids.
- dodecanoic acids dodecanoic acids.
- fatty acids one or more fatty acids.
- the term “various” means to include various isomers of ortho, secondary, tertiary, and hetero.
- “various caprylic acids” include not only straight-chain n-octanoic acid, but also fatty acids with 8 carbon atoms in various isomers.
- the average number of moles of oxyethylene added is preferably more than 0, more preferably 4 or more, still more preferably 6 or more, and from the viewpoint of stability, it is preferably 9 or less, and more preferably 8 or less.
- component (A) include: polyoxyethylene glycerol (caprylic acid/capric acid) ester (the average number of moles of ethylene oxide added is 6 mol), and polyoxyethylene glycerol laurate (oxidized The average number of added moles of vinyl is 8 moles).
- the component (A) may be selected from one of the above-mentioned polyoxyethylene glycerin fatty acid esters, or two or more of them may be selected in combination.
- the content of the component (A) is 0.35% by mass or more, preferably 0.4% by mass or more, more preferably 0.5% by mass or more, and even more preferably 0.7% by mass % Or more, more preferably 0.8% by mass or more, still more preferably 1% by mass and 5% by mass or less, preferably 2.6% by mass or less, more preferably 1,3% by mass or less, and still more preferably 1.1% by mass or less.
- the content of the component (A) is 5% by mass or less, preferably 2.6% by mass or less, and more preferably 1.6% by mass or less.
- the component (B) of the detergent composition of the present invention is water. That is, the remainder other than the above-mentioned component (A), the following component (C), component (D), and other components is divided into component (B) water.
- the content of component (B) is 85% by mass or more, more preferably 90% by mass or more, even more preferably 95% by mass or more, still more preferably 96% by mass or more, and 99 Mass% or less, preferably 98 mass% or less.
- As the water ion-exchange water, sterile ion-exchange water, etc. are preferably used.
- the component (C) of the present invention is a surfactant having an alkyl or alkenyl group with 8 to 18 carbon atoms other than the component (A).
- the combination of ingredient (C) and ingredient (A) can increase the solubility of ingredient (A) in the composition and prevent its precipitation, which is beneficial to the performance of ingredient (A)'s cleaning performance.
- the surfactant of the component (C) is not particularly limited, and surfactants widely used in the field of cleaning compositions can be used. Specifically, it can be selected from (C1) nonionic surfactants and (C2) amphoteric surfaces. Active agent, and (C3) i type or two or more types of cationic surfactants.
- the (C1) nonionic surfactant may be one or more nonionic surfaces selected from alkyl glycosides, polyoxyethylene alkyl ethers, and polyoxyethylene alkenyl ethers Among them, the active agent is preferably an alkyl glycoside.
- a nonionic surfactant represented by the following general formula (1) can be cited.
- R ia represents a linear or branched alkyl or alkenyl group having 8 or more and 18 carbon atoms, preferably 12 or more and 14 or less, and R 2 represents an alkylene having 2 or more carbon atoms and 4 to T
- G represents a residue derived from a reducing sugar having 5 or 6 carbon atoms; s represents an average added mole number, which is a number of 0 to 5; t represents a number whose average value is 1 to 5.
- G includes residues derived from one or more monosaccharides selected from glucose and fructose. Also, about G Examples include residues derived from one or more polysaccharides selected from maltose and sucrose.
- G is preferably a residue of a monosaccharide derived from glucose.
- polyoxyethylene alkyl ether or polyoxyethylene alkenyl ether from the viewpoint of the cleaning power against oil stains, the number of carbon atoms of the alkyl group or alkenyl group is preferably 8 to 18, and the addition mole of the ethylene oxide The number is preferably 1 to 30 moles, and preferred specific examples thereof include polyoxyethylene hexyl decyl ether, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, and the like.
- (C2) Amphoteric Surfactant one or more amphoteric surfactants selected from the group consisting of amine oxide and betaine may be used. Among them, amine oxide is preferred. As a preferred specific example of amine oxide, one can cite:
- Octyl diyl amine oxide decyl dibasic amine oxide, lauryl dibasic amine oxide, myristyl dimethyl amine oxide, palmityl dimethyl amine oxide, stearyl dimethyl amine oxide
- betaine examples include: alkyl or alkenyl carbonyl betaine, amide betaine, sulfobetaine, amide sulfobetaine, imidazoline betaine, or phosphoric acid having an alkyl or alkenyl group having 8 or more and less than 8 carbon atoms Betaine.
- the (C3) cationic surfactant is preferably a mono- or di-long chain alkyl type quaternary ammonium salt.
- the component (C3) is preferably a cationic surfactant selected from the compound represented by the following general formula (2) and the compound represented by the general formula (3).
- At least one selected from the group consisting of R ib and R 2b represents an alkyl group having 8 or more carbon atoms and an alkenyl group having 8 or more and S.18 or less or 8 or more carbon atoms.
- R 3b R 4b is the same or different, and each represents an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group having 1 to 3 carbon atoms, or a polyoxyethylene group having an average added mole number of 10 or less
- R 5b represents an alkyl group having 8 or more and 18 or less carbon atoms, an alkenyl group having 8 or more and 18 or less carbon atoms, or a hydroxyalkyl group having 8 or more and 18 carbon atoms
- R 6b , R 7b is the same or different and each represents an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group having 1 to 3 carbon atoms or a polyoxyethylene group having an average added mole number of 1() or less
- R 8b It represents an alkylene group having a carbon number of 1 or more and mesh.
- r represents an anion residue such as a halogen ion or a sulfonic acid ion having a carbon number of i or more and R5 or less or a sulfuric acid ion having a carbon number of 1 or more and 5 or less.
- R 15 an alkyl group, alkenyl group or hydroxyalkyl group having 8 to 16 carbon atoms
- R a , R 3b and R 4b are the same or different, and each are an alkyl group having a carbon number of i or more and 3 or less, a hydroxyalkyl group, or a polyoxyethylene group having an average added mole number of 10 or less.
- R lh Ii R 2b are the same or different, respectively , Alkenyl or hydroxyalkyl, R 3 1R 4b are the same or different, and each is an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group, or a polyoxyethylene group having an average added mole number of 10 or less.
- a linear alkyl group having 12 or more and 16 or less carbon atoms is selected, R 6b and R are each preferably a methyl group, R 81 ⁇ is selected as a methylene group, and Z_ is a halogen ion, More preferably, it is chloride ion (cr).
- the cationic surfactant is preferably a cationic surfactant selected from the compounds represented by the above-mentioned remote formula (3).
- the component (C) one can be selected from the above-mentioned (C1) nonionic surfactants, (C2) amphoteric surfactants, and (C3) cationic surfactants. Or choose a combination of two or more.
- the content of the component (C) is 0.02% by mass or more, preferably 0.03% by mass or more, and from the viewpoint of reducing white residue , It is 5% by mass or less, preferably 3% by mass or less, more preferably 1% by mass or less, still more preferably 0.2% by mass or less, and still more preferably 0.1% by mass or less.
- the total content ((A) + (C)) of component (A) and component (C) is 10% by mass or less, preferably 3% by mass or less, preferably It is 2% by mass or less, more preferably 1.8% by mass or less, even more preferably 1.5% by mass or less, and is preferably 0.5% by mass or more, more preferably 0.8% by mass or more, and even more preferably 1% by mass or more.
- the polyoxyethylene glycerin fatty acid ester of component (A) and the surface of component (C) other than component (A) that have an alkyl or alkenyl group with 8 to 18 carbon atoms
- the mass ratio of the active agent in terms of (A)/(C) is 70 or less, preferably 60 or less, more preferably 20 to T, more preferably 10 to T, still more preferably 8 or less, and still more preferably It is 2 or more, preferably 3 or more, more preferably 4 or more, and even more preferably 5 or more.
- the component (D) of the present invention is one or two or more selected from the following components (D1) and (D2).
- the component (D1) is an organic acid or its salt.
- (D2) is an inorganic salt.
- the organic acid of the component (D1) specifically, acetic acid, lactic acid, malic acid, citric acid, succinic acid, adipic acid, ethylenediaminetetraacetic acid, ethylene glycol bis(2-aminoethyl ether) Acetic acid, benzoic acid, etc.
- the organic salt of component (D1) the above-mentioned organic acid, alkali metal, alkaline earth Metals, or salts of metals such as aluminum, etc., specifically, include: sodium acetate, potassium acetate, sodium lactate, potassium lactate, aluminum lactate, sodium malate, potassium malate, sodium citrate, potassium citrate, succinate Sodium, potassium succinate, sodium ethylenediaminetetraacetate, potassium ethylenediaminetetraacetate, ethane:diol bis(2-aminoethyl ether) sodium tetraacetate, ethane:diol bis(2-aminoethyl ether) ) Potassium tetraacetate, sodium benzoate, potassium benzoate, etc.
- Organic acids and their salts can be used singly or in combination of two or more. From the standpoint of improving stability and cleaning power, citric acid, monosodium citrate, disodium citrate, trisodium citrate, and monosodium citrate are preferred. Potassium, dipotassium citrate, tripotassium citrate, ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetic acid, trisodium ethylenediaminetetraacetic acid, ethylenediaminetetraacetic acid: dipotassium, ethylene: diaminetetraacetic acid three Potassium, ethylene glycol bis(2-aminoethyl bond) tetraacetic acid, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid disodium, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid trisodium , Ethylene glycol bis(2-aminoeth
- citric acid monosodium citrate, disodium citrate, trisodium citrate, disodium edetate, and trisodium edetate are more preferred. More preferred are citric acid, disodium citrate, and disodium edetate.
- the inorganic salt of component (D2) include salts of inorganic acids selected from hydrochloric acid, sulfuric acid, silicic acid, and carbonic acid with alkali metals, alkaline earth metals, or metals such as aluminum.
- the component (D) can be used in combination with the above component (D1) organic acid or its salt, the above component (D2) inorganic salt, or a combination of two or more types.
- the component (D) is the component (D1)
- the content of the component (D1) is 0.005 mass% or more in terms of acid, preferably 0.007 mass % Or more, more preferably 0.01% by mass or more, still more preferably 0.03% by mass or more, and from the viewpoints of improving the cleaning power of the composition and reducing white residue, it is 0.4% by mass or less, more preferably 0.3% by mass below, it is more preferably 0.2 quality
- the amount is less than %.
- the content of the component (D2) is 0.005% by mass or more in terms of salt, and the clumps are reduced From the viewpoint of white residue, it is 0.4% by mass or less, more preferably 0.3% by mass or less, and even more preferably 0.2% by mass or less.
- the content of ingredient (D1) is calculated as acid and the content of ingredient (D2) is calculated as salt
- the content of the component (D) is 0.005 mass% or more, preferably 0.007 mass% or more, more preferably 0.01 mass% or more, and still more preferably 0.03 mass% or more, and it improves the cleansing power of the composition From the viewpoint of reducing white residue, it is 0.4% by mass or less, more preferably 0.3% by mass or less, and further preferably 0.2% by mass or less.
- other ingredients such as lower alcohols such as isopropanol, and diethylene glycol
- Solvents such as alcohol monobutyl ether; viscosity modifiers such as clay minerals and water-soluble polymer compounds; humectants such as glycerin and sorbitol; tactile enhancers such as cationized cellulose; enzymes, pigments, fragrances, antiseptics and antifungal agents, etc.
- the cleansing composition of the present invention can be produced by appropriately mixing each of the above-mentioned compounding components.
- the present invention provides a hard surface cleaning sheet, which contains the cleaning agent composition of the present invention.
- the cleaning sheet for hard surfaces of the present invention is composed of the cleaning composition of the present invention and a base.
- the substrate used in the present invention it has flexibility and can be impregnated with the detergent composition, and it is possible to use a substrate having sufficient strength without generating debris or the like.
- Examples of such a substrate include fibrous structures made of fibrous materials, such as various tissues, nonwoven fabrics, woven fabrics, or knitted fabrics. Examples of fibrous materials constituting these fibrous structures include cellulose fibers, modified cellulose fibers, synthetic fibers, and mixtures of two or more of these.
- the basis weight of the aforementioned substrate is preferably 30 g/m 2 or more, more preferably 40 g/m 2 or more, and even more preferably 50 g/m 2 or more, and It is preferably 200 g/m 2 or less, and more preferably 150 g/m 2 or less.
- the hard surface cleaning sheet of the present invention it can be prepared by impregnating a substrate with the detergent composition of the present invention in advance, or by impregnating a dry substrate with the detergent composition of the present invention immediately before use.
- Impregnation can be achieved by misting, extruding, or dropping the detergent composition of the present invention onto the substrate, or immersing the substrate in the detergent composition of the present invention.
- iTu says that the quality of the cleaning sheet cleaning composition is relative to
- the ratio of the mass of the matrix is preferably 100% by mass or more, more preferably 150% by mass or more, and preferably 900% by mass or less, more preferably 400% by mass or less, and still more preferably 350% by mass or less.
- the basis weight of the liquid cleaning agent composition for hard surfaces before impregnation is preferably 30 g/m 2 or more, more preferably 40 g/m 2 or more, and still more preferably 50 g/m 2 or more, and preferably 200 g/m 2 or less, more preferably 150 g/m 2 or less.
- the impregnation rate can be adjusted as needed from the viewpoint of reducing white residue and improving cleaning power, that is, depending on It is necessary to determine the amount of the cleaning agent composition and impregnate it into the matrix to form the hard surface cleaning sheet of the present invention.
- the present invention provides a hard surface cleaning method, which is to perform sassafras cleaning after applying the detergent composition of the present invention to a hard surface.
- a hard surface cleaning method which is to perform sassafras cleaning after applying the detergent composition of the present invention to a hard surface.
- the hard surface that can be wiped clean in the present invention, and examples include one or more solid hard surfaces selected from glass, ceramics, magnets, plastics, and stainless steel.
- the “hard surface” is not limited to flat or three-dimensional, but refers to a surface that can maintain a certain shape, as long as it can be cleaned, the hardness of the surface The degree is not limited.
- the object of the present invention is a hard surface, specifically, an article having a hard surface.
- Examples of items with hard surfaces include: stoves, range hoods, walls, workbenches, cabinets, microwave ovens, swimming box interiors, door frames, door handles, dining tables, floors, shelves, windows, furniture, mirrors, doors, remote controls Ware, toilet, toilet seat, wash basin, bathtub, kitchen sink, window glass, faucet, children's products (high chair, toys, game mat), etc.
- a method of wiping and cleaning the detergent composition of the present invention after it is applied to a hard surface the following methods (i) to (ii) can be cited.
- a method of wiping and cleaning a hard surface with a hard surface cleaning sheet containing the detergent composition of the present invention can be appropriately selected according to the width (area) of the hard surface and the like.
- the method is as follows: spray the detergent composition of the present invention on a hard surface with a sprayer or the like, or the detergent composition of the present invention can be extruded from a spray container such as a sprayer, a plastic squeeze bottle, etc.
- the cleaning composition of the present invention may be allowed to stay on a hard surface for preferably 0.5 minutes or more, more preferably It is 1 minute or more, and preferably 10 minutes or less, and then wipe cleaning is performed.
- a hard surface peripheral cleaning sheet that is pre-impregnated with the detergent composition of the present invention, or to spray or squeeze the detergent composition of the present invention immediately before use.
- At least one of the hard surface cleaning sheets formed by impregnating the dry substrate with the detergent composition of the present invention wipes and cleans the hard surface to achieve the effect of cleaning and decontamination.
- the hard surface cleaning sheet can be installed on a cleaning tool for wiping, or it can be directly held by hand for wiping.
- the temperature of the detergent composition of the present invention when wiping hard surfaces is preferably 5 ° C or higher, more preferably 10 ° C or higher, and even more preferably 15T : Above, and 11 is preferably 50 ° C or less, more preferably 401 or less, and still more preferably 30 ° C or less.
- a detergent composition which contains the following components (A) to (D), and component (A): polyoxyethylene glycerin fatty acid@ The average added mole number of the group is 10 moles or less, and has a linear or branched saturated or unsaturated fatty acyl group with a carbon number of 12 or less; component (B): water; component (C): component (A ) Other surfactants having an alkyl or alkenyl group having 8-18 carbon atoms; and component (D): one or more of the following components (D1) and (D2):
- (D2) Inorganic salt, in the detergent composition, the content of component (A) is 0.35% by mass or more and 5% by mass or less, the content of component (D1) is in terms of acid, and the content of component (D2) is in terms of salt In time, the content of component (D) is 0.005% by mass or more and 0.4% by mass or less, and as the total content of component (A) and component (C), (A) + (C) is 10% by mass or less.
- liquid detergent composition according to any one of the above ⁇ 1> ⁇ 3>, wherein the fatty acid is selected from various caprylic acid, various nonanoic acid, various decanoic acid, various ten One or more fatty acids in monoalkanoic acid and various dodecanoic acids.
- liquid detergent composition according to any one of the above ⁇ 1> ⁇ 4>, wherein, in the component (A), the average number of moles of oxyethylene added is preferably more than 0, more preferably 4 Above, further Preferably it is 9 or less, More preferably, it is 8 or less.
- ⁇ 6> The liquid detergent composition according to any one of the above ⁇ 1> to ⁇ 5 >, wherein the component (A) is polyoxyethylene glycerol (caprylic acid/capric acid) ester (average addition of ethylene oxide) The number of moles is 6 moles), and one or two of polyoxyethylene glycerol laurate (the average number of moles of oxyethylene added is 8 moles).
- the component (A) is polyoxyethylene glycerol (caprylic acid/capric acid) ester (average addition of ethylene oxide) The number of moles is 6 moles), and one or two of polyoxyethylene glycerol laurate (the average number of moles of oxyethylene added is 8 moles).
- the liquid detergent composition according to any one of the above ⁇ 1> ⁇ 6>, wherein, in the detergent composition, the content of the component (A) is 0.35% by mass or more, preferably 0.4% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.7% by mass or more, still more preferably 0.8% by mass or more, still more preferably 1% by mass or more, and 5% by mass or less, preferably 2.6% by mass or less, It is more preferably L6 mass% or less, more preferably L3 mass% or less, and still more preferably L1 mass% or less.
- liquid detergent composition according to any one of the above ⁇ 1> to ⁇ 7>, wherein, in the detergent composition, the content of the component (B) is 85% by mass or more, more preferably It is 90% by mass or more, more preferably 95% by mass or more, still more preferably 96% by mass or more, and 99% by mass or less, preferably 98% by mass or less.
- liquid detergent composition according to any one of the above ⁇ 1> ⁇ 8>, wherein the component (C) is selected from (C1) nonionic surfactants, (C2) amphoteric surfactants , And (C3) One or more of cationic surfactants.
- liquid detergent composition according to the above ⁇ 9>, wherein the (C1) ionic surfactant is one selected from the group consisting of alkyl glycosides, polyoxyethylene alkyl ethers, and polyoxyethylene alkenyl ethers
- the above nonionic surfactants are preferably alkyl glycosides.
- liquid detergent composition according to any one of the above ⁇ 1> ⁇ 12>, wherein, in the detergent composition, the content of the component (C) is 0.02% by mass or more, preferably 0.03% by mass or more, and 5% by mass or less, preferably 3% by mass or less, more preferably 1% by mass or less, even more preferably 0.2% by mass or less, and still more preferably 0.1% by mass or less.
- liquid detergent composition according to any one of the above ⁇ 1> ⁇ 13>, wherein the total content ((A) + (C)) of the component (A) and the component (C) is 10 % By mass or less, preferably 3% by mass or less, preferably 2% by mass or less, more preferably 1.8% by mass or less, still more preferably 1.5% by mass or less, and preferably 0.5% by mass or more, more preferably 0.8% by mass or more.
- One step is preferably 1% by mass or more.
- it is preferably 60 or less, more preferably 20 or less, more preferably 10 or less, still more preferably 8 or less, still more preferably 7 or less, and ⁇ ., is 2 or more, preferably 3 or more, and more preferably 4 or more , More preferably, it is 5 or more.
- liquid detergent composition according to any one of the above ⁇ 1> ⁇ 15>, wherein the component (Di) is selected from the group consisting of citric acid, monosodium citrate, disodium citrate, tri-citrate Sodium, monopotassium citrate, dipotassium citrate, tripotassium citrate, ethylene diamine tetraacetic acid, disodium edetate, trisodium edetate, dipotassium edetate, ethylene diamine Tripotassium tetraacetate, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid, ethylene glycol bis(2 aminoethyl ether) disodium tetraacetate, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid three One or more of sodium, ethylene glycol bis(2-aminoethyl ether) dipotassium tetraacetate, ethylene glycol bis(2-aminoe
- liquid detergent composition according to any one of the above ⁇ 1> ⁇ 15>, wherein the inorganic salt of component (D2) is selected from sodium chloride, potassium chloride, magnesium chloride, and calcium chloride
- the inorganic salt of component (D2) is selected from sodium chloride, potassium chloride, magnesium chloride, and calcium chloride
- the inorganic salt of component (D2) is selected from sodium chloride, potassium chloride, magnesium chloride, and calcium chloride
- the content of (D1) is 0.005% by mass or more in terms of acid, preferably 0.007% by mass or more, more It is preferably 0.01% by mass or more, more preferably 0.03% by mass or more, and 0.4% by mass or less, more preferably 0.3% by mass or less, and even more preferably 0.2% by mass or less.
- the content of the component (D2) in terms of salt is 0.005% by mass or more, and 0.4% by mass or less, more preferably 0.3% by mass or less, and even more preferably 0.2% by mass the following.
- ingredient (D) is a combination of ingredient (D1) and ingredient (D2)
- the content of ingredient (D1) is in terms of acid and the content of ingredient (D2) is in terms of salt
- the content of ingredient (D) is 0.005% by mass
- It is preferably 0.007 mass% or more, more preferably 0.01 mass% or more, still more preferably 0.03 mass% or more
- S is 0.4 mass% or less, more preferably 0.3 mass% or less, and even more preferably 0.2 mass% or less.
- component (D) is preferably selected from component (D1) organic acid or One or more of its salts.
- ⁇ 20> A hard surface cleaning sheet, wherein the hard surface cleaning sheet contains the cleaning agent composition described in any one of ⁇ 1> to ⁇ 19>.
- the hard surface cleaning described in the above ⁇ 20> or ⁇ 21>, wherein the ratio of the mass of the detergent composition to the mass of the substrate in the cleaning sheet [ie, (the mass of the detergent composition/non-impregnated The impregnation rate of the state (the mass of the substrate in the dry state) x100] is preferably 100% by mass or more, more preferably 150% by mass or more, and preferably 900% by mass or less, more preferably 400% by mass or less, and still more preferably 350% by mass or less.
- the object of the surface cleaning method is a hard surface.
- it can be stoves, range hoods, walls, workbenches, cabinets, microwave ovens, refrigerator interiors, door frames, door handles, dining tables, floors, shelves, windows , Furniture, mirrors, doors, remote controls, toilets, toilet seats, wash basins, bathtubs, kitchen sinks, window panes, faucets, children's products (high chairs, toys, game mats).
- the residual rate is less than 50%, and the residual rate is greater than 50% and less than 70%.
- the residual rate is more than 70%.
- the contents (mass%) of the compounding ingredients in Tables 1 to 4 are all values based on active ingredients.
- the respective compounding components used in the examples and comparative examples are collectively shown below.
- the content (% by mass) of the ingredient (D1) is a value based on the active ingredient in terms of acid.
- the content (% by mass) of the ingredient (D2) is the value based on the active ingredient in terms of salt.
- C2 Lauryl dimethyl amine oxide (trade name "AmpMtol 20N", manufactured by Kao Corporation, with an active ingredient content of 35%)
- C3 Benzyl-C 12-i6 -alkyl dimethyl chloride Ammonium (trade name "Sanisol B50", manufactured by Kao Corporation, active ingredient content is 50,8%)
- ⁇ (D1): Zi monohydrate citric acid (Fuso Chemical Co., Ltd., Ltd.) in an amount (m) is calculated in terms of the following acids: citric acid: 192.Bg/mol citric acid monohydrate rot 1: 2L0 .14g/mol in (citric acid) two m ( -hydrated citric acid) ⁇ 192.13/210.14
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
The present invention relates to a detergent composition, comprising the following ingredients (A) - (D): ingredient (A): an polyoxyethylene glycerol fatty acid ester; ingredient (B): water; ingredient (C): a surfactant having alkyl or alkenyl with a carbon atomic number of 8 to 18 other than ingredient (A); and ingredient (D) selected from one or two of: (D1) an organic acid or a salt thereof, and (D2) inorganic salts. In the detergent composition, the content of ingredient (A) is no less than 0.35 weight % and no more than 5 weight%; when the content of ingredient (D1) is on the basis of acid and the content of ingredient (D2) is on the basis of salt, the content of ingredient (D) is no less than 0.005 weight% and no more than 0.4 weight%; and as the total content of ingredients (A) and (C), (A) + (C) is no more than 10 weight%. The detergent composition of the present invention has a high cleaning power for grease and dirt, and has the effect of there being less white residue after cleaning a hard surface.
Description
清洁 剂组合物 、 硬质表面清洁 片以及 硬质表面 清洁方法 技术 领域 本发 明涉及 一种清洁 剂组合物 、 硬质表面清 洁片以及 硬质表 面清 洁方 法。 背景 技术 在 E1绕我们的居 住环境 设备中存 在以磁 砖、 塑料、 金属等为村 料 的 各种硬质 表面, 这些硬质表 面在生 活场景 中暴露在 会附着 各种污 垢 的环 境中。 其中, 被用作卫生间、 浴室、 厨房等的 硬质表面 也为人 日 常接 触的表 面, 故而具有容 易残 留而蓄积 大量污垢 , 进而难以洗净 去 除 的性质。 在专 利文献 1 中, 公开了一种专用于 厨房清 洁消毒的 湿巾, 它是 将具 有清洁 消毒功 能的液体 均匀地 浸润于水 剌无纺 布膜上 而得到 的, 并且 记载有 该具有清洁 消毒功 能的液体 含有: a -烯基磺酸钠、脂肪醇聚 氧 乙烯醚硫酸 钠、 C12 脂肪醇聚 氧乙烯 (9)醚、 乙二胺四乙酸二钠 、 柠 檬酸 、 柠檬酸钠、 1,2 -丙:二醇等, 并且对于顽固的变性油污表现出优异 的清 洁力。 现有 技术 专利 文献 专利 文献 1: CN103340584 发明 内容 本发 明提供 一种例如 适合硬 质表面清 洁 的对 油脂污垢 的清洁 力 高 , 且清洁后的白色 残余少 的清洁剂组 合物。 本发 明人发现 : 通过在清洁剂 组合物 中并用特 定的聚 氧乙烯甘 油 脂肪 酸酯、特定的表 面活性 剂以及特 定的酸和 /或盐作为清洁有效成 分, 可 以提高清 洁剂组合 物的疏 水性, 在使周时清洁剂组 合物中 的清洁 有 效成 分很容 易吸附 于油脂污 垢弁提 高对于油 脂污垢 的清洁 力, 可以以
少量 的清洁 活性成 分或清洁 辅助成分 来实现 高清洁力 , 同时可以显著 降低 在 清洁 剂组合物 清洁擦拭 硬质表 面后的 作为擦拭 痕迹的 白色残 余 。 另外 , 在本说明书中 , “白色残余”是指 将清洁 剂组合物 于硬质 表面 进行清 洁后, 特别是擦 拭硬质表 面后, 硬质表面上水 、 乙醇等挥 发物 挥发后, 残留在硬质表面上 的白色 物质。 本发 明涉及一 种清洁剂 组合物 , 其含有以下成分 (A) 〜 (D), 成分 (A): 聚氧乙烯貨油脂肪酸亂 其中, 所述聚氧乙烯甘 油脂 肪酸 酯的氧化 乙烯基 的平均加 成摩尔数 为 10摩尔 以下, 并且具有碳原 子数 为 12以下的 直链或支 链的饱和 或不饱和 的脂肪 酰基; 成分 (B): 水; 成分 (C): 成分 (A) 以外的具有碳原子数为 8〜 18的烷基或烯基 的表 面活性剂 ; 以及 成分 (D)- 选自下述成 分 (D1)和成分 (D2) 中的 1种或 2种以 上: A cleaning agent composition, a hard surface cleaning sheet, and a hard surface cleaning method TECHNICAL FIELD This invention relates to a cleaning agent composition, a hard surface cleaning sheet, and a hard surface cleaning method. BACKGROUND OF THE INVENTION There are various hard surfaces made of tiles, plastics, metals, etc. in the living environment equipment of E1. These hard surfaces are exposed to environments where various dirt will adhere in life scenes. Among them, hard surfaces used in toilets, bathrooms, kitchens, etc. are also surfaces that people touch daily, so they tend to remain and accumulate a large amount of dirt, making it difficult to clean and remove. In Patent Document 1, a wet wipe dedicated to kitchen cleaning and disinfection is disclosed. It is obtained by evenly infiltrating a liquid with a cleaning and disinfection function on a water-saturated non-woven fabric film, and it is described as having a cleaning and disinfection function. The functional liquid contains: sodium a-alkenyl sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate, C12 fatty alcohol polyoxyethylene (9) ether, disodium edetate, citric acid, sodium citrate, 1, 2-Propylene: Glycol, etc., and shows excellent cleaning power against stubborn denatured oil stains. Prior Art Patent Literature Patent Literature 1: CN103340584 SUMMARY OF THE INVENTION The present invention provides a cleaning agent composition suitable for hard surface cleaning, which has high cleaning power against grease and dirt, and has less white residue after cleaning. The present inventors discovered that by combining specific polyoxyethylene glycerin fatty acid esters, specific surfactants, and specific acids and/or salts as effective cleaning ingredients in the detergent composition, the hydrophobicity of the detergent composition can be improved , The cleaning active ingredient in the detergent composition can be easily adsorbed on the grease dirt and improve the cleaning power against grease dirt. A small amount of cleaning active ingredients or cleaning auxiliary ingredients can achieve high cleaning power, and at the same time can significantly reduce the white residue as wiping marks after the cleaning composition cleans and wipes hard surfaces. In addition, in this specification, "white residue" means that after the cleaning agent composition is cleaned on a hard surface, especially after wiping the hard surface, the volatiles such as water and ethanol on the hard surface volatilize and remain on the hard surface. White substance on the surface of the texture. The present invention relates to a detergent composition, which contains the following components (A) ~ (D), component (A): polyoxyethylene cargo oil fatty acid, wherein the polyoxyethylene glycerol fatty acid ester has an oxyethylene group The average added mole number is 10 moles or less, and has a linear or branched saturated or unsaturated fatty acyl group with a carbon number of 12 or less; component (B): water; component (C): other than component (A) Surfactant having an alkyl or alkenyl group with carbon atoms of 8-18; and component (D)-selected from one or more of the following components (D1) and (D2):
(DO 有机酸或 其盐、 (DO organic acid or its salt,
(D2) 无机盐, 在所 述清洁剂 组合物中 , 成分(A) 的含量为 0.35质量%以上且 5 质量 %以下, 成分 (DO 的含量以酸 计、 成分(D2) 的含量以盐 时, 成分 (D)的含量 为 0,005质量%以上且 0.4质量%以下, 作为成分 (A) 和成 分 (C) 的合计含量, (A) + (C) 为 10质量%以下。 又, 本发明涉及一种 硬质表面 清洁片 , 其含有本发 明的清洁 剂组 合物 。 进而 , 本发明涉及一 种硬质表 面清洁 方法, 将本发明的清洁 剂组 合物 应用于硬 质表面进 行清洁 。 根据 本发明 , 本发明的清洁剂 组合物 对于油脂 污垢具 有高的 清洁 力 , 而且具有用于清 洁硬质 表面后 的白色残 余少的 效果。 本发明的清 洁剂 组合物可 以适用于 各种硬质 表面。 另外 , 在本说明书中 , “白色残余”是指 将清洁 剂组合物 于硬质 表面 进行清 洁后, 特别是擦 拭硬质表 面后, 硬质表面中残 留的水、 乙 醇等 挥发物挥 发后, 残留在硬质 表面上 的白色物 质。
具体 实施方式 (D2) Inorganic salt, in the detergent composition, when the content of component (A) is 0.35% by mass or more and 5% by mass or less, and the content of component (DO is in terms of acid, and the content of component (D2) is in terms of salt) The content of component (D) is 0.005 mass% or more and 0.4 mass% or less, and as the total content of component (A) and component (C), (A) + (C) is 10 mass% or less. Furthermore, the present invention relates to A hard surface cleaning sheet, which contains the cleaning agent composition of the present invention. Furthermore, the present invention relates to a hard surface cleaning method, which applies the cleaning agent composition of the present invention to hard surfaces for cleaning. According to the present invention , The detergent composition of the present invention has high cleaning power against grease and dirt, and has the effect of less white residue after cleaning hard surfaces. The detergent composition of the present invention can be applied to various hard surfaces. In this specification, "white residue" means that after the cleaning agent composition is cleaned on a hard surface, especially after wiping the hard surface, the residual water, ethanol and other volatiles on the hard surface will remain on the hard surface after volatilization. White substance on hard surfaces. Detailed ways
[清洁剂组合物 ] 本发 明的清 洁剂组合 物为含有 成分 (A)、 成分 (B)、 成分 (C) 以及 成分 (D) 的液体清洁剂组合物 。 [Cleanser composition] The detergent composition of the present invention is a liquid detergent composition containing component (A), component (B), component (C), and component (D).
< 成分 (A) > 本发 明的成分 (A) 是聚氧乙烯甘油脂 肪酸酯, 其中, 所述聚氧乙 烯甘 油脂肪酸 酯的氧 化乙烯基 的平均加 成摩尔数 为 10摩尔以下, 并且 具有 碳原子 数为 12以 T的直链或支 链的饱和 或不饱和 的脂肪 酰基。 成 分 (A) 为清洁有效成分。 成分 (A)可以 含有 1个以上且 3个以下的脂 肪酰基 。作为成分 (A) 的脂 肪酸酯 的来源 的脂肪酸 的碳原 子数, 从提高清洁力的 观点出发 , 优选 为 8个以上S.12个以下 , 更优选为 8个以上且 10个以下。 作为脂肪 酸 的具体例 子, 可以列举选 自各种辛酸 (例如, 也包括 2乙基己酸 ) 、 各种 壬酸、 各种癸酸、 各种十一烷酸和各 种十二烷 酸中的 1种以上的脂 肪酸 。 在本 发明中 , 所谓“各种”, 意味着包括 邻、 仲、 叔、 异的各种异 构物 。 例如, “各种辛酸”不仅 包括直链 正辛酸 , 也包括各种异 构物 的 碳原 子数为 8的脂肪酸 。 丛提 高清洁力 的观点 出发, 氧化乙烯 基的平 均加成摩 尔数优 选超 过 0, 更优选为 4以上, 进一步优选为 6以上, 并且, 从稳定性的观 点出 发 , 优选为 9以下, 更优选为 8以下。 作为 成分 (A) 的优选的具体例 , 可以列举: 聚氧乙烯甘油 (辛酸 /癸酸) 酯 (氧化乙烯基的平均加 成摩尔数 为 6摩尔)、 以及聚氧乙烯甘 油月 桂酸酯 (氧化乙烯基的平 均加成摩 尔数为 8摩尔)。 在本 发明的清 洁剂组合 物中, 成分 (A)可以丛上述 聚氧乙烯 甘油 脂肪 酸酯中 选择 1种使 , 或者选择 2种以上组合使 周。 在本发明 的清 洁剂 组合物中 , 从提高清洁力 的观点出 发, 成分 (A) 的含量为 0.35质 量% 以上, 优选为 0.4质量%以上, 更优选为 0.5质量%以上, 进一步优 选为 0.7质量%以上, 进一步优选为 0.8质量%以上, 更进一步优选 1质量 并且为 5质量%以下 , 优选 2.6质量%以下, 更优选 1,3质量%以 下 , 进一步优选 1。1质量%以下。 此外, 从减少白色残余的 观点出 发,
成分 (A) 的含量为 5质量%以下, 优选 2.6质量%以下, 更优选 1.6质量 % 以下。 <Component (A)> The component (A) of the present invention is a polyoxyethylene glycerin fatty acid ester, wherein the average added mole number of the oxyethylene group of the polyoxyethylene glycerin fatty acid ester is 10 mol or less, and has A linear or branched saturated or unsaturated fatty acyl group having 12 to T carbon atoms. Ingredient (A) is a cleansing effective ingredient. The component (A) may contain 1 or more and 3 or less fatty acyl groups. The number of carbon atoms of the fatty acid that is the source of the fatty acid ester of the component (A) is preferably 8 or more and S.12 or less, and more preferably 8 or more and 10 or less from the viewpoint of improving the cleaning power. As specific examples of fatty acids, one may be selected from various caprylic acids (for example, 2 ethylhexanoic acid), various nonanoic acids, various capric acids, various undecanoic acids, and various dodecanoic acids. One or more fatty acids. In the present invention, the term "various" means to include various isomers of ortho, secondary, tertiary, and hetero. For example, "various caprylic acids" include not only straight-chain n-octanoic acid, but also fatty acids with 8 carbon atoms in various isomers. From the viewpoint of improving the cleaning power, the average number of moles of oxyethylene added is preferably more than 0, more preferably 4 or more, still more preferably 6 or more, and from the viewpoint of stability, it is preferably 9 or less, and more preferably 8 or less. Preferable specific examples of component (A) include: polyoxyethylene glycerol (caprylic acid/capric acid) ester (the average number of moles of ethylene oxide added is 6 mol), and polyoxyethylene glycerol laurate (oxidized The average number of added moles of vinyl is 8 moles). In the detergent composition of the present invention, the component (A) may be selected from one of the above-mentioned polyoxyethylene glycerin fatty acid esters, or two or more of them may be selected in combination. In the detergent composition of the present invention, from the viewpoint of improving the cleaning power, the content of the component (A) is 0.35% by mass or more, preferably 0.4% by mass or more, more preferably 0.5% by mass or more, and even more preferably 0.7% by mass % Or more, more preferably 0.8% by mass or more, still more preferably 1% by mass and 5% by mass or less, preferably 2.6% by mass or less, more preferably 1,3% by mass or less, and still more preferably 1.1% by mass or less. In addition, from the viewpoint of reducing white residue, The content of the component (A) is 5% by mass or less, preferably 2.6% by mass or less, and more preferably 1.6% by mass or less.
< 成分 (B) > 本发 明的清 洁剂组合 物的成 分 (B) 是水。 g卩, 上述成分 (A)、 以及 下述成分 (C) 、 成分 (D) 以及其它成分以外的剩余部 分为成分 (B) 水。 在本 发明的清 洁剂组合 物中, 成分 (B) 的含量为 85质量%以上, 更优 选为 90质量%以上, 进一步优选为 95质量%以上 , 更进一步优选为 96质量 %以上, 并且为 99质量%以下, 优选为 98质量%以下。 水优选 为使用 离子交换 水、 灭菌离子交换 水等。 <Component (B)> The component (B) of the detergent composition of the present invention is water. That is, the remainder other than the above-mentioned component (A), the following component (C), component (D), and other components is divided into component (B) water. In the detergent composition of the present invention, the content of component (B) is 85% by mass or more, more preferably 90% by mass or more, even more preferably 95% by mass or more, still more preferably 96% by mass or more, and 99 Mass% or less, preferably 98 mass% or less. As the water, ion-exchange water, sterile ion-exchange water, etc. are preferably used.
< 成分 (C) > 本发 明的成分 (C) 是成分 (A) 以外的具有碳原子 数为 8〜 18的 烷基 或烯基的 表面活性 剂。 成分 (C) 与成分 (A) 并用后, 可以提高 成分 (A) 在组合物中的溶解 度, 防止其析 出, 从而有利于成 分 (A) 的清 洁性能 的发挥。 作为成分 (C) 的表面活性剂 , 没有特定限定 , 可 以使 用清洁组 合物领域 中广泛 使用的表 面活性剂 , 具体而言, 可以列 举选 自 (C1) 非离子表面活性剂、 (C2) 两性表面活性剂、 及 (C3) 阳离 子表面活 性剂中 的 i种或 2种以上。 <Component (C)> The component (C) of the present invention is a surfactant having an alkyl or alkenyl group with 8 to 18 carbon atoms other than the component (A). The combination of ingredient (C) and ingredient (A) can increase the solubility of ingredient (A) in the composition and prevent its precipitation, which is beneficial to the performance of ingredient (A)'s cleaning performance. The surfactant of the component (C) is not particularly limited, and surfactants widely used in the field of cleaning compositions can be used. Specifically, it can be selected from (C1) nonionic surfactants and (C2) amphoteric surfaces. Active agent, and (C3) i type or two or more types of cationic surfactants.
< (C1) 非离子表面活性剂 > 作为 (C1) 非离子表面活性剂 , 可以为选自烷 基糖苷 、 聚氧乙烯 烷基 醚或者聚 氧乙烯烯 基醚中 的 1种以上的非离子 表面活性 剂, 其中, 优选 为焼基糖 昔。 作为烷 基糖苷 的优选 的具体例 , 可以列举: 下述通式(1)所表示的 非离 子表面活 性剂。 <(C1) Nonionic Surfactant> The (C1) nonionic surfactant may be one or more nonionic surfaces selected from alkyl glycosides, polyoxyethylene alkyl ethers, and polyoxyethylene alkenyl ethers Among them, the active agent is preferably an alkyl glycoside. As a preferred specific example of the alkyl glycoside, a nonionic surfactant represented by the following general formula (1) can be cited.
Ria(OR2a)sGt (1) R ia (OR 2a ) s G t (1)
[式中, Ria表示直链或支链的 碳原子 数 8以上且 18以下、 优选为 12 以上 且 14以下的烷基或烯 基, R2 示碳原子 数 2以上 ii4以 T的亚烷基, G表 示碳原 子数 5或 6的来自还原糖的残 基; s表示平均加成摩 尔数, 为 0 以上 且 5以下的数; t表示其平均值 为 1以上且 5以下的数。 ] 通式 (1)中, 就它们的获取容易性及成 本的方面 而言 , 关于 G可以 列举 来自选 自葡萄糖 及果糖 中的 1种以上的单糖 类的残基 。 又, 关于 G
可 以列举来 自选自麦 芽糖及蔗 糖中的 1种以上的多糖类 的残基 。 G优选 为来 自蔔萄糖 的单糖类 的残基 。 作为 聚氧乙烯 烷基醚 或者聚氧 乙烯烯 基醚, 从对油污 的清洁力 的 观点 出发, 其焼基或 者缔基 的碳原子 数优选 为 8〜 18, 其环氧乙焼的加 成摩 尔数优选 为 1~30摩尔, 其优选的具体 例, 可以列举: 聚氧乙烯己 基癸 基醚、 聚氧乙烯月桂基 醚、 聚氧乙烯鲸 蜡基醚 、 聚氧乙烯硬脂基 醚等 。 [In the formula, R ia represents a linear or branched alkyl or alkenyl group having 8 or more and 18 carbon atoms, preferably 12 or more and 14 or less, and R 2 represents an alkylene having 2 or more carbon atoms and 4 to T G represents a residue derived from a reducing sugar having 5 or 6 carbon atoms; s represents an average added mole number, which is a number of 0 to 5; t represents a number whose average value is 1 to 5. ] In general formula (1), in terms of their availability and cost, G includes residues derived from one or more monosaccharides selected from glucose and fructose. Also, about G Examples include residues derived from one or more polysaccharides selected from maltose and sucrose. G is preferably a residue of a monosaccharide derived from glucose. As polyoxyethylene alkyl ether or polyoxyethylene alkenyl ether, from the viewpoint of the cleaning power against oil stains, the number of carbon atoms of the alkyl group or alkenyl group is preferably 8 to 18, and the addition mole of the ethylene oxide The number is preferably 1 to 30 moles, and preferred specific examples thereof include polyoxyethylene hexyl decyl ether, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, and the like.
< (C2) 两性表面活 性剂> 作为 (C2) 两性表面活 性剂, 可以为选自氧化 胺和甜 菜碱 中的 1 种以 上的两性 表面活 性剂, 其中, 优选为氧化胺 。 作为 氧化胺的 优选的具 体例, 可以列举 : <(C2) Amphoteric Surfactant> As the (C2) Amphoteric Surfactant, one or more amphoteric surfactants selected from the group consisting of amine oxide and betaine may be used. Among them, amine oxide is preferred. As a preferred specific example of amine oxide, one can cite:
(1)辛基二 基氧 化胺、 癸基二 ¥基氧 化胺、 月桂基二平基 氧化胺 、 肉豆 蔻基二 甲基氧化 胺、 棕榈基二 甲基氧化 胺、 硬脂基二 甲基氧化 胺 等烷 基 (碳原子数 8以上且 18以下)二烷基 (碳原子数 1以上且 3以下)氧化 胺; (1) Octyl diyl amine oxide, decyl dibasic amine oxide, lauryl dibasic amine oxide, myristyl dimethyl amine oxide, palmityl dimethyl amine oxide, stearyl dimethyl amine oxide Alkyl (8 or more and 18 or less carbon atoms) dialkyl (1 or more and 3 or less carbon atoms) amine oxides such as amines;
(2)月桂酰胺丙 基二 甲基氧化胺 、 肉豆蔻酰胺丙 基二 甲基氧化胺 、 棕榈 油来源 脂肪酰胺 丙基二 甲基氧 化胺、 硬脂酰胺 丙基二 甲基氧化 胺 等脂 肪酸 (碳原子数 8以上且 18以下)酰胺丙基 二烷基 (碳原子数 1以上且 3以下)氧 化胺。 其中 , 就配合稳定性 的观点 而言, 更优选为 (1)烷基 (碳原子数 8以 上且 18以下)二烷基 (碳原子数 1以上且 3以下)氧化胺。 作为甜 菜碱 , 可以列举: 碳原子数为 8以上 il8以下的烷 基或者烯 基 的羰基甜 菜碱、 酰胺甜菜碱、 磺基甜菜碱 、 酰胺磺基甜菜 碱、 咪哇 啉甜 菜碱、 或磷酸廳 甜菜碱 。 (2) Lauramide propyl dimethyl amine oxide, myristamide propyl dimethyl amine oxide, palm oil-derived fatty acid amide propyl dimethyl amine oxide, stearyl amide propyl dimethyl amine oxide and other fatty acids ( Carbon number 8 or more and 18 or less) amidopropyl dialkyl (carbon number 1 or more and 3 or less) amine oxide. Among them, from the viewpoint of compounding stability, (1) alkyl (8 or more and 18 or less carbon atoms) dialkyl (1 or more and 3 or less carbon atoms) amine oxide is more preferable. Examples of the betaine include: alkyl or alkenyl carbonyl betaine, amide betaine, sulfobetaine, amide sulfobetaine, imidazoline betaine, or phosphoric acid having an alkyl or alkenyl group having 8 or more and less than 8 carbon atoms Betaine.
< (C3 ) 阳离子表面活性剂 > 作为 (C3) 阳离子表面 活性剂 , 优选为单或二长链烷 基型季 铵盐。 作为 成分 (C3 ), 优选为选自下述通式 (2)所表示的化合物 及通式 (3)所 表示 的化合物 中的阳 离子表面 活性剂 。
<(C3) Cationic Surfactant> The (C3) cationic surfactant is preferably a mono- or di-long chain alkyl type quaternary ammonium salt. The component (C3) is preferably a cationic surfactant selected from the compound represented by the following general formula (2) and the compound represented by the general formula (3).
[通式 (2)中,选自 Rib及 R2b中的至少一者表示碳原子数 8以上 iil8以 下的烷基 、 碳原子数 8以上S.18以下 的烯基或 碳原子 数 8以上S.18以下 的羟基烷 基, 其余表示碳原 子数 1以上 M3以下的烷 基、 碳原子数 1以上 且 3以下的羟基烷基 或平均 加成摩 尔数 10以下的聚氧 乙烯基 , R3b R4b 相同或不 同, 分别表示碳原 子数 1以上且 3以下的烷基 、 碳原子数 1以上 且 3以下的羟基烷基 或平均加 成摩尔 数 10以下的聚氧乙烯 基, Y—表示卤 素离子 、 或碳原子数 1以上且 5以下的磺酸 离子或 碳原子 数 1以上 15以
[In the general formula (2), at least one selected from the group consisting of R ib and R 2b represents an alkyl group having 8 or more carbon atoms and an alkenyl group having 8 or more and S.18 or less or 8 or more carbon atoms. S.18 or less hydroxyalkyl group, and the remainder represents an alkyl group having 1 or more carbon atoms and less than M3, a hydroxyalkyl group having 1 or more and 3 or less carbon atoms, or a polyoxyethylene group having an average added mole number of 10 or less, R 3b R 4b is the same or different, and each represents an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group having 1 to 3 carbon atoms, or a polyoxyethylene group having an average added mole number of 10 or less, and Y—represents halogen Ions, or sulfonic acid ions with 1 to 5 carbon atoms, or 1 to 15 carbon atoms
[通式 (3)中, R5b表示碳原子数 8以上 il8以下的烷基、 碳原子数 8 以上且 18以下的烯基或碳原 子数 8以上且 18以下的羟基 烷基, R6b、 R7b 相同或不 同, 分别表示碳原 子数 1以上且 3以下的烷基、 碳原子数 1以上 且 3以下的羟基烷基 或平均加 成摩尔 数 1()以下的聚氧乙烯基, R8b表示碳 原子数 1以上目 .3以下的亚烷基; r表示卤素离 子、或碳原子 数 i以上 R5 以下的磺 酸离子 或碳原 子数 1以上且 5以下的硫酸 离子这样 的阴离 子残 基。 ] 在 为单长链 烷基型季 铵盐的情 形时, 在遥式 (2)中, 优选为, R15^ 碳 原子数 8以上且 16以下的烷基、 烯基或羟基烷基 , Ra、 R3b R4b相同 或不同 , 分别为碳原子数 i以上且 3以下的烷基、 羟基烷基 或平均 加成 摩 尔数 10以下的聚氧 乙烯基 。 在 为二长链 烷基型季 铵盐的情 形时, 在遥式 (2)中, 优选为, RlhIi R2b相 同或不同 ,分别
、烯基或羟基 烷 基 , R3lR4b相同 或不同 , 分别为碳原子数 1以上且 3以下的烷基 、 羟基 烷 基或平 均加成摩 尔数 10以下的聚氧 乙烯基 。
在通 式(3)中, 选为碳 原子数 12以上且 16以下的直链烷基, R6b、 1^ 分别优选 为甲基 , R81^选为亚甲基 , Z_为卤素离子, 进而优选为氯 化物 离子(cr)。 作为 阳离子表 面活性 剂, 优选为选自 上述遥式 (3)所表示的化合物 中 的阳离子表 面活性 剂。 在本 发明的清 洁剂组合 物中, 作为成分 (C), 可以从上述 (C1) 非离 子表面活 性剂、 (C2)两性表面活性 剂、 及(C3) 阳离子表面活性 剂中 选择 1种使用, 或者选择 2种以上组 合使用 。 在本发明的清 洁剂组 合物 中, 从提高清洁 力的观点 出发, 成分 (C) 的含量为 0.02质量%以 上 , 优选为 0,03质量%以上, 并§., 丛减少白色残余的观 点出发, 为 5 质量 %以下, 优选为 3质量%以下, 更优选为 1质量%以下, 进一步优选 0,2质量%以下 , 更进一步优选为 0.1质量%以下。 进而 ; 从兼顾提高清洁 力和减少 白色残 余的观 点出发, 成分 (A) 和成 分 (C) 的合计含量 ( (A) + (C) ) 为 10质量%以下, 优选为 3 质量 %以下, 优选为 2质量%以下, 更优选 1.8质量%以下, 进一步优选 1.5质量%以下 , 并且, 优选为 0,5质量%以上, 更优选为 0,8质量%以上, 进一 步优选为 1质量%以上。 此外 ; 为了得到充分的 清洁力 , 成分(A) 的聚氧乙烯甘油 脂肪酸 酯和 成分 (C) 成分的成分 (A) 以外的具有碳原子 数为 8~18的烷基或 烯基 的表面活 性剂的质 量比以 (A) /(C)计为 70以下, 优选为 60以下, 更优 选为 20以 T, 更优选为 10以 T, 进一步优选为 8以下, 更进一步优
为 2以上, 优选为 3以上, 更优选为 4以上, 进一步 优选 为 5以上。 [In the general formula (3), R 5b represents an alkyl group having 8 or more and 18 or less carbon atoms, an alkenyl group having 8 or more and 18 or less carbon atoms, or a hydroxyalkyl group having 8 or more and 18 carbon atoms, R 6b , R 7b is the same or different and each represents an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group having 1 to 3 carbon atoms or a polyoxyethylene group having an average added mole number of 1() or less, R 8b It represents an alkylene group having a carbon number of 1 or more and mesh. 3 or less; r represents an anion residue such as a halogen ion or a sulfonic acid ion having a carbon number of i or more and R5 or less or a sulfuric acid ion having a carbon number of 1 or more and 5 or less. ] In the case of a single-long-chain alkyl type quaternary ammonium salt, in the remote formula (2), R 15 ^ an alkyl group, alkenyl group or hydroxyalkyl group having 8 to 16 carbon atoms, R a , R 3b and R 4b are the same or different, and each are an alkyl group having a carbon number of i or more and 3 or less, a hydroxyalkyl group, or a polyoxyethylene group having an average added mole number of 10 or less. In the case of a di-long chain alkyl type quaternary ammonium salt, in the remote formula (2), it is preferable that R lh Ii R 2b are the same or different, respectively , Alkenyl or hydroxyalkyl, R 3 1R 4b are the same or different, and each is an alkyl group having 1 to 3 carbon atoms, a hydroxyalkyl group, or a polyoxyethylene group having an average added mole number of 10 or less. In the general formula (3), a linear alkyl group having 12 or more and 16 or less carbon atoms is selected, R 6b and R are each preferably a methyl group, R 81 ^ is selected as a methylene group, and Z_ is a halogen ion, More preferably, it is chloride ion (cr). The cationic surfactant is preferably a cationic surfactant selected from the compounds represented by the above-mentioned remote formula (3). In the detergent composition of the present invention, as the component (C), one can be selected from the above-mentioned (C1) nonionic surfactants, (C2) amphoteric surfactants, and (C3) cationic surfactants. Or choose a combination of two or more. In the detergent composition of the present invention, from the viewpoint of improving the cleaning power, the content of the component (C) is 0.02% by mass or more, preferably 0.03% by mass or more, and from the viewpoint of reducing white residue , It is 5% by mass or less, preferably 3% by mass or less, more preferably 1% by mass or less, still more preferably 0.2% by mass or less, and still more preferably 0.1% by mass or less. Furthermore; from the viewpoint of both improving cleaning power and reducing white residue, the total content ((A) + (C)) of component (A) and component (C) is 10% by mass or less, preferably 3% by mass or less, preferably It is 2% by mass or less, more preferably 1.8% by mass or less, even more preferably 1.5% by mass or less, and is preferably 0.5% by mass or more, more preferably 0.8% by mass or more, and even more preferably 1% by mass or more. In addition; in order to obtain sufficient cleaning power, the polyoxyethylene glycerin fatty acid ester of component (A) and the surface of component (C) other than component (A) that have an alkyl or alkenyl group with 8 to 18 carbon atoms The mass ratio of the active agent in terms of (A)/(C) is 70 or less, preferably 60 or less, more preferably 20 to T, more preferably 10 to T, still more preferably 8 or less, and still more preferably It is 2 or more, preferably 3 or more, more preferably 4 or more, and even more preferably 5 or more.
< 成分 (D) > 本发 明的成分 (D) 是选自下述成 分 (D1) 和成分 (D2) 中的 1 种或 2种以上, 其中, 成分 (D1) 为有机酸或其盐, 成分 (D2) 为无 机盐 。 作为 成分 (D1) 的有机酸, 具体而言, 可以列举乙酸 、 乳酸、 苹 果酸 、 柠檬酸、 琥珀酸、 己二酸、 乙二胺四乙酸、 乙二醇双(2氨 基乙 基醚 ) 四乙酸、 苯甲酸等。 作为 成分 (D1) 的有机盐, 可以列举上述有机 酸与碱 金属、 碱土
金属 、 或者铝等金属 所形成 的盐等 , 具体而言, 可以列举 : 乙酸钠、 乙酸 钾、 乳酸钠、 乳酸钾、 乳酸铝、 苹果酸钠、 苹果酸钾 、 柠檬酸钠、 柠檬 酸钾、 琥珀酸钠、 琥珀酸钾、 乙二胺四乙酸钠 、 乙二胺四乙酸 钾、 乙:二醇双 (2 -氨基乙基醚) 四乙酸钠、 乙:二醇双(2 -氨基乙基醚) 四乙 酸钾 、 苯甲酸钠、 苯甲酸钾等 。 有机 酸及其 盐可以使 用 1种或组合 2种以上使用 , 从提高稳定性 、 清洁 力的观 点出发, 优选为柠檬酸、 柠檬酸一钠、 柠檬酸二钠 、 柠檬 酸三 钠、 柠檬酸一钾 、 柠檬酸二钾、 柠檬酸三钾、 乙二胺四乙酸、 乙 二胺 四乙酸 二钠、 乙二胺四乙酸三 钠, 乙二胺四乙 酸:二钾、 乙:二胺四 乙酸 三钾、 乙二醇双 (2 -氨基乙基鍵) 四乙酸、 乙二醇双 (2 -氨基乙基 醚)四 乙酸二钠 、 乙二醇双(2 -氨基乙基醚)四乙酸三钠 、乙二醇双 (2 - 氨基 乙基醚 ) 四乙酸二钾、 乙二醇双 (2 -氨基乙基醚) 四乙酸三钾、 苯 甲酸 钠、 苯甲酸钾等 。 这些中, 更优选柠檬 酸、 柠檬酸一钠 、 柠檬酸 二钠 、 柠檬酸三钠、 乙二胺四乙酸二 钠、 乙二胺四 乙酸三钠 。 进一步 优选柠 檬酸、 柠檬酸二钠、 乙二胺四乙 酸二钠。 作为 成分 (D2) 的无机盐, 可以列举选自盐酸 、 硫酸、 硅酸、 碳 酸 中的无机 酸与碱金 属、 碱土金属 、 或者铝等金属 所形成 的盐等 , 具 体而 言, 可以列举 : 氯化钠、 氯化钾、 氯化镁、 氯化钙、 氯化铝、 硫 酸钠 、 硫酸钾、 硫酸镁、 硫酸铝、 硅酸钠、 碳酸钠、 碳酸钾、 碳酸氢 钠、 碳酸氢钾等。 这些无机酸 及其盐 可以使 1种或将 2种以上组 合使 用 , 从提高稳定性 、 清洁力的观点 出发, 优选为氯化 钙、 硫酸镁、 氯 化铝 。 在本 发明的清 洁剂组 合物中 , 成分 (D) 可以伙上述成分 (D1) 有机 酸或其 盐、 上述成分 (D2) 无机盐中选择 1种使用, 或者选择 2种 以上 组合使 , 其中, 优选选自成分 (D1) 有机酸或其盐中的 1种或 2 种以 上。 在本 发明的清 洁剂组 合物中 , 当成分 (D) 为成分 (D1) 时, 丛 提高 组合物清 洁力的观 点出发 , 成分 (D1) 的含量以酸计算为 0.005质 量%以 上, 优选 0.007质量%以上, 更优选为 0,01质量%以上, 进一步优 选为 0.03质量%以上, 并且从提高组合 物清洁 力和减少 白色残余 的观点 出发 , 为 0.4质量%以下, 更优选为 0。3质量%以下, 进一步优选为 0.2质
量% 以下。 在本 发明的清 洁剂组 合物中 , 当成分 (D) 为成分 (D2) 时, 从 提高 组合物清 洁力的观 点出发 , 成分 (D2) 的含量以盐计算为 0.005质 量% 以上, 并且丛减 少白色残 余的观 点出发 , 为 0.4质量%以下, 更优 选为 0,3质量%以下, 进一步优选 为 0.2质量%以下。 在本 发明的清 洁剂组 合物中 , 当成分 (D) 为成分 (D1) 和成分 (D2) 的组合时, 成分 (D1) 的含量以酸计且成 分 (D2) 的含量以盐 计, 从提高组合 物清洁力 的观点 出发, 成分(D) 的含量为 0,005质量% 以上 , 优选 0.007质量%以上, 更优选为 0.01质量%以上, 进一步优选为 0.03质量%以 上, 并且丛提 高组合物 清洁力 和减少 白色残 余的观 点出 发, 为 0,4质量%以下, 更优选为 0.3质量%以下, 迸一步优选为 0.2质量 % 以下。 <Component (D)> The component (D) of the present invention is one or two or more selected from the following components (D1) and (D2). Among them, the component (D1) is an organic acid or its salt. (D2) is an inorganic salt. As the organic acid of the component (D1), specifically, acetic acid, lactic acid, malic acid, citric acid, succinic acid, adipic acid, ethylenediaminetetraacetic acid, ethylene glycol bis(2-aminoethyl ether) Acetic acid, benzoic acid, etc. As the organic salt of component (D1), the above-mentioned organic acid, alkali metal, alkaline earth Metals, or salts of metals such as aluminum, etc., specifically, include: sodium acetate, potassium acetate, sodium lactate, potassium lactate, aluminum lactate, sodium malate, potassium malate, sodium citrate, potassium citrate, succinate Sodium, potassium succinate, sodium ethylenediaminetetraacetate, potassium ethylenediaminetetraacetate, ethane:diol bis(2-aminoethyl ether) sodium tetraacetate, ethane:diol bis(2-aminoethyl ether) ) Potassium tetraacetate, sodium benzoate, potassium benzoate, etc. Organic acids and their salts can be used singly or in combination of two or more. From the standpoint of improving stability and cleaning power, citric acid, monosodium citrate, disodium citrate, trisodium citrate, and monosodium citrate are preferred. Potassium, dipotassium citrate, tripotassium citrate, ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetic acid, trisodium ethylenediaminetetraacetic acid, ethylenediaminetetraacetic acid: dipotassium, ethylene: diaminetetraacetic acid three Potassium, ethylene glycol bis(2-aminoethyl bond) tetraacetic acid, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid disodium, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid trisodium , Ethylene glycol bis(2-aminoethyl ether) dipotassium tetraacetate, ethylene glycol bis(2-aminoethyl ether) tripotassium tetraacetate, sodium benzoate, potassium benzoate, etc. Among these, citric acid, monosodium citrate, disodium citrate, trisodium citrate, disodium edetate, and trisodium edetate are more preferred. More preferred are citric acid, disodium citrate, and disodium edetate. Examples of the inorganic salt of component (D2) include salts of inorganic acids selected from hydrochloric acid, sulfuric acid, silicic acid, and carbonic acid with alkali metals, alkaline earth metals, or metals such as aluminum. Specifically, they include: chlorine Sodium chloride, potassium chloride, magnesium chloride, calcium chloride, aluminum chloride, sodium sulfate, potassium sulfate, magnesium sulfate, aluminum sulfate, sodium silicate, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, etc. These inorganic acids and their salts may be used singly or in combination of two or more, and from the viewpoint of improving stability and cleaning power, calcium chloride, magnesium sulfate, and aluminum chloride are preferred. In the detergent composition of the present invention, the component (D) can be used in combination with the above component (D1) organic acid or its salt, the above component (D2) inorganic salt, or a combination of two or more types. It is preferably one or two or more selected from the organic acids or their salts as the component (D1). In the detergent composition of the present invention, when the component (D) is the component (D1), from the viewpoint of improving the cleaning power of the composition, the content of the component (D1) is 0.005 mass% or more in terms of acid, preferably 0.007 mass % Or more, more preferably 0.01% by mass or more, still more preferably 0.03% by mass or more, and from the viewpoints of improving the cleaning power of the composition and reducing white residue, it is 0.4% by mass or less, more preferably 0.3% by mass Below, it is more preferably 0.2 quality The amount is less than %. In the detergent composition of the present invention, when the component (D) is the component (D2), from the viewpoint of improving the cleaning power of the composition, the content of the component (D2) is 0.005% by mass or more in terms of salt, and the clumps are reduced From the viewpoint of white residue, it is 0.4% by mass or less, more preferably 0.3% by mass or less, and even more preferably 0.2% by mass or less. In the detergent composition of the present invention, when ingredient (D) is a combination of ingredient (D1) and ingredient (D2), the content of ingredient (D1) is calculated as acid and the content of ingredient (D2) is calculated as salt, from From the viewpoint of improving the cleansing power of the composition, the content of the component (D) is 0.005 mass% or more, preferably 0.007 mass% or more, more preferably 0.01 mass% or more, and still more preferably 0.03 mass% or more, and it improves the cleansing power of the composition From the viewpoint of reducing white residue, it is 0.4% by mass or less, more preferably 0.3% by mass or less, and further preferably 0.2% by mass or less.
<其 它成分 > 在本 发明的清 洁剂组 合物中 , 除了上述成分 以外, 还可以在不损 害本 发明的 目的或者 效果 的范_ 内配 合其它成 分, 例如: 异丙醇等 低 级醇 、 二乙二醇单丁 醚等溶 剂; 粘土矿物、 水溶性高分子化 合物等 粘 度调 节剂; 甘油、 山梨糖醇等保 湿剂; 阳离子化纤维素等 触感提高 剂; 酶、 色素、 香料、 防腐 ·防霉剂等。 本发 明的清 洁剂组合 物可以通 过适当 混合上 述各配合 成分来 进行 制造 。 <Other ingredients> In the detergent composition of the present invention, in addition to the above-mentioned ingredients, other ingredients, such as lower alcohols such as isopropanol, and diethylene glycol, may be blended within a range that does not impair the purpose or effects of the present invention. Solvents such as alcohol monobutyl ether; viscosity modifiers such as clay minerals and water-soluble polymer compounds; humectants such as glycerin and sorbitol; tactile enhancers such as cationized cellulose; enzymes, pigments, fragrances, antiseptics and antifungal agents, etc. . The cleansing composition of the present invention can be produced by appropriately mixing each of the above-mentioned compounding components.
[硬质表面 清洁 片] 本发 明提供 一种硬质 表面用清 洁片 , 其含有本发明 的清洁剂 组合 物 。 本发明的硬质表 面用清 洁片由本 发明的 清洁剂组 合物 、 和基体构 成 。 作为 本发明所 使用的基 体, 具有可挠性 , 且可含浸清洁剂组 合物, 可使 用具有充 分的强 度而不产 生碎渣等 的基体 。 作为 此种基体 , 可以列举由 纤维状材 料构成 的纤维构 造体, 例如 各种 纸巾、 无纺布、 织布或者编布 。 作为构成这些纤 维构造 体的纤维 状材 料, 例如可以 列举纤维 素系纤维 、 改性纤维素系 纤维、 合成纤维 及这 些中的 两种以上 的混合 物等。 此外, 使气泡分散在树 脂中而获 得 的 多孔质构造 体(例如海绵)也可用作上述 基体。
此外 , 就清洁剂组合 物的保 持性的观 点而言 , 上述基体的 基重优 选为 30 g/m2以上, 更优选为 40 g/m2以上, 进一步优选为 50 g/m2以上, 并且 优选为 200 g/m2以下, 更优选为 150 g/m2以下。 作为 本发明 的硬质表 面清洁 片, 其可以使基 体预先含 浸有本 发明 的清 洁剂组 合物而成 、 或者在即将 使用之前 使干燥 的基体 含浸有本 发 明 的清洁剂组 合物而成 。含浸可 以通过将 本发明 的清洁剂组 合物啧雾 、 挤 出、 滴加至基体 , 或者将基体浸 渍于本发 明的清 洁剂组合 物中等 方 式来 实现。 在使 基体预 先含浸有 本发明 的清洁剂 组合物 而成的硬 质表面 用清 洁片 的情形 时, 就减少白色 残余、 提高清洁力的观 点 iTu言, 清洁片屮 清洁 剂组合物 的质量相 对于基体 质量的 比例[即,(清洁剂组合物的质量 /未含浸 状态(干燥状态)的基体的质 量)x100]的含浸率优选为 100质量% 以上 , 更优选为 150质量%以上, 并且优选为 900质量%以下, 更优选为 400质量 %以下, 进而优选 为 350质量%以下。 如果含浸 率为 100质量% 以上 , 则可以充分提 高清洁力 。 如果为 900质量%以下, 则可以有效减 少 白色残余 。 此外 , 就清洁剂组合 物的保 持性的观 点而言 , 硬质表面用液 体清 洁剂 组合物的 含浸前 的基重优选 为 30g/m2以上, 更优选为 40g/m2以上, 进一 步优选为 50g/m2以上, 并 优选为 200g/m2以下, 更优选为 150g/m2 以下 。 在即 将使 之 前使干燥 的基体 含浸有 本发明 的清洁剂 组合物 而成 的清 洁片的 情形时 , 就减少白色残 余、 提高清洁力 的观点 而言, 含浸 率可 以视需 要而调节 , 即, 视需要确定清洁 剂组合物 的量 , 并使其含 浸至 基体中 而成为本 发明的硬 质表面用 清洁片 。 [Hard Surface Cleaning Sheet] The present invention provides a hard surface cleaning sheet, which contains the cleaning agent composition of the present invention. The cleaning sheet for hard surfaces of the present invention is composed of the cleaning composition of the present invention and a base. As the substrate used in the present invention, it has flexibility and can be impregnated with the detergent composition, and it is possible to use a substrate having sufficient strength without generating debris or the like. Examples of such a substrate include fibrous structures made of fibrous materials, such as various tissues, nonwoven fabrics, woven fabrics, or knitted fabrics. Examples of fibrous materials constituting these fibrous structures include cellulose fibers, modified cellulose fibers, synthetic fibers, and mixtures of two or more of these. In addition, a porous structure (for example, sponge) obtained by dispersing bubbles in a resin can also be used as the above-mentioned matrix. In addition, from the viewpoint of the retention of the detergent composition, the basis weight of the aforementioned substrate is preferably 30 g/m 2 or more, more preferably 40 g/m 2 or more, and even more preferably 50 g/m 2 or more, and It is preferably 200 g/m 2 or less, and more preferably 150 g/m 2 or less. As the hard surface cleaning sheet of the present invention, it can be prepared by impregnating a substrate with the detergent composition of the present invention in advance, or by impregnating a dry substrate with the detergent composition of the present invention immediately before use. Impregnation can be achieved by misting, extruding, or dropping the detergent composition of the present invention onto the substrate, or immersing the substrate in the detergent composition of the present invention. In the case of a hard surface cleaning sheet formed by impregnating a substrate with the detergent composition of the present invention in advance, from the viewpoint of reducing white residue and improving cleaning power, iTu says that the quality of the cleaning sheet cleaning composition is relative to The ratio of the mass of the matrix [ie, (the mass of the detergent composition/the mass of the matrix in the non-impregnated state (dry state)) x 100] is preferably 100% by mass or more, more preferably 150% by mass or more, and preferably 900% by mass or less, more preferably 400% by mass or less, and still more preferably 350% by mass or less. If the impregnation rate is 100% by mass or more, the cleaning power can be sufficiently improved. If it is 900% by mass or less, white residue can be effectively reduced. In addition, from the viewpoint of the retention of the cleaning agent composition, the basis weight of the liquid cleaning agent composition for hard surfaces before impregnation is preferably 30 g/m 2 or more, more preferably 40 g/m 2 or more, and still more preferably 50 g/m 2 or more, and preferably 200 g/m 2 or less, more preferably 150 g/m 2 or less. In the case of a cleaning sheet formed by impregnating a previously dried substrate with the detergent composition of the present invention, the impregnation rate can be adjusted as needed from the viewpoint of reducing white residue and improving cleaning power, that is, depending on It is necessary to determine the amount of the cleaning agent composition and impregnate it into the matrix to form the hard surface cleaning sheet of the present invention.
[硬质表面清洁 方法] 本发 明提供 一种硬质 表面清 洁方法 , 其是将本发明 的清洁剂 组合 物应 用于硬质 表面后 , 进行檫拭清洁 。 作为 本发明 的可进行 擦拭清 洁的硬质 表面并 无特别 限制, 可以列 举 : 选自玻璃、 陶器、 磁器、 塑料、 以及不锈钢中 的 1种或 2种以上的 固体 的硬质 表面。 并且, 所述 “硬质表面”不限于平面 的或者 立体的 , 是指 能保持 一定形 状的表面 , 只要能够进行 清洁处 理, 对其硬度 的程
度没 有限定 。 本发 明的对象 为硬质表 面, 具体而言 为具有 硬质表面 的物品 。 作 为具 有硬质表 面的物 品, 可以列举: 火炉、 抽油烟机、 墙壁、 工作台、 橱柜 、 微波炉、 泳箱内部、 门框、 门把手、 餐桌、 地板、 架子、 窗户、 家具 、 镜子、 门、 遥控器、 马桶、 马桶座圈、 洗手盆、 浴缸、 厨房的 水槽 、 窗玻璃、 水龙头、 儿童 品 (高脚椅、 玩具、 游戏垫) 等。 作为 将本发 明的清洁 剂组合物 应周于 硬质表面 后进行 擦拭清洁 的 方式 , 可以列举下述 (i)〜 (ii)的方法。 [Hard Surface Cleaning Method] The present invention provides a hard surface cleaning method, which is to perform sassafras cleaning after applying the detergent composition of the present invention to a hard surface. There are no particular restrictions on the hard surface that can be wiped clean in the present invention, and examples include one or more solid hard surfaces selected from glass, ceramics, magnets, plastics, and stainless steel. In addition, the “hard surface” is not limited to flat or three-dimensional, but refers to a surface that can maintain a certain shape, as long as it can be cleaned, the hardness of the surface The degree is not limited. The object of the present invention is a hard surface, specifically, an article having a hard surface. Examples of items with hard surfaces include: stoves, range hoods, walls, workbenches, cabinets, microwave ovens, swimming box interiors, door frames, door handles, dining tables, floors, shelves, windows, furniture, mirrors, doors, remote controls Ware, toilet, toilet seat, wash basin, bathtub, kitchen sink, window glass, faucet, children's products (high chair, toys, game mat), etc. As a method of wiping and cleaning the detergent composition of the present invention after it is applied to a hard surface, the following methods (i) to (ii) can be cited.
(1)对硬质表面喷 雾或涂布 本发 明的清洁 剂组合物 后进行擦 拭清洁 的方 法; (1) A method of wiping and cleaning after spraying or coating the cleaning composition of the present invention on a hard surface;
(ii)用含有本发明的清 洁剂组合 物的硬质 表面清 洁片对硬 质表面进 行擦 拭清洁 的方法。 在上 述 (i)的方法中, 对硬质表面喷雾或 涂布本 发明的清 洁剂组 合 物的 方法可根 据硬质 表面的宽 度 (面积)等而适当地选择 。优选为如下方 法 : 利 喷雾器等对硬 质表面 喷雾本发 明的清洁 剂组合 物, 或者也可 使本 发明的清 洁剂组 合物 自啧雾器、 塑料挤瓶等喷出 容器挤 出至硬质 表面 , 或者也可以用滴 管将本发 明的清洁 剂组合物 滴加至 硬质表面 后, 用海 绵、 纸 、 无纺布、 编布、 织布等进行擦拭 清洁 , 由此将应 于 硬质 表面的清 洁剂组合 物自硬质 表面去 除, 从而实现清洁去 污的效果 。 进而 , 在上述 (i)的方法中, 就提高清洁力的观 点而言 , 可以在啧 雾或 者涂布之 后, 使本发明 的清洁剂组 合物在硬 质表面 停留优选 为 0.5 分钟 以上、 更优选为 1分钟以上、 并且优选为 10分钟以下, 然后进行擦 拭清 洁。 在上 述 (ii)的方法中, 可以使用选自预先含浸有 本发明 的清洁剂 组 合物 而成的 硬质表面 周清洁 片、 或者在即将 使用之 前将本 发明的清 洁 剂组 合物通过 喷雾、 挤出等使干燥的 基体含浸 有本发 明的清 洁剂组合 物而 成的硬 质表面用 清洁片 中的至 少一种对 硬质表面 进行擦 拭清洁 , 丛而 实现清洁 去污的效 果。 进而 , 所述硬质 表面 清 洁片可 以安 装在打 扫工 具上而 用于擦 拭 , 也可直接用手拿 着而 于擦 拭。 上述 (i)〜 (ii)的方法可以单独使用, 也可以组合使 .用。 在组合使用
的情 况下, 例如, 在使用硬质表面 清洁 it进行擦拭时 , 也可一边另 外将 本发明 的清洁剂 组合物 啧雾或者 排出至 硬质表面 同时进行 擦拭 。 通过 组合使用 这些方法 , 丛而提高清洁 去污效果 。 在用 上述方法 (i)和 /或(ii)对硬质表面进行擦拭清洁后, 视需要也可 进一 步用水进 行冲洗 。 就提 高清洁力 、 减少白色残 留的观 点而言 , 对硬质表面进行 擦拭 清洁 时的本发 明的清洁 剂组合物 的温度优 选为 5°C以上, 更优选为 10°C 以上 , 进而优选为 15T:以上, 并 11优选为 50°C以下, 更优选为 401以 下 , 进而优选为 30°C以下。 (ii) A method of wiping and cleaning a hard surface with a hard surface cleaning sheet containing the detergent composition of the present invention. In the method of (i) above, the method of spraying or applying the detergent composition of the present invention to the hard surface can be appropriately selected according to the width (area) of the hard surface and the like. Preferably, the method is as follows: spray the detergent composition of the present invention on a hard surface with a sprayer or the like, or the detergent composition of the present invention can be extruded from a spray container such as a sprayer, a plastic squeeze bottle, etc. to the hard surface , Or you can also use a dropper to drop the detergent composition of the present invention onto a hard surface, and then wipe and clean it with sponge, paper, non-woven fabric, woven cloth, woven cloth, etc., so that it will be applied to the hard surface The cleaning agent composition is removed from the hard surface, thereby achieving the effect of cleaning and decontamination. Furthermore, in the method of (i) above, from the viewpoint of improving the cleaning power, after spraying or coating, the cleaning composition of the present invention may be allowed to stay on a hard surface for preferably 0.5 minutes or more, more preferably It is 1 minute or more, and preferably 10 minutes or less, and then wipe cleaning is performed. In the above-mentioned method (ii), it is possible to use a hard surface peripheral cleaning sheet that is pre-impregnated with the detergent composition of the present invention, or to spray or squeeze the detergent composition of the present invention immediately before use. At least one of the hard surface cleaning sheets formed by impregnating the dry substrate with the detergent composition of the present invention wipes and cleans the hard surface to achieve the effect of cleaning and decontamination. Furthermore, the hard surface cleaning sheet can be installed on a cleaning tool for wiping, or it can be directly held by hand for wiping. The methods (i) to (ii) above can be used alone or in combination. Used in combination In the case of, for example, when wiping with a hard surface cleaning it, it is also possible to spray or discharge the detergent composition of the present invention to a hard surface while wiping. By using these methods in combination, the cleaning effect is improved. After wiping and cleaning the hard surface with the above methods (i) and/or (ii), it can be further rinsed with water as needed. From the viewpoint of improving cleaning power and reducing white residue, the temperature of the detergent composition of the present invention when wiping hard surfaces is preferably 5 ° C or higher, more preferably 10 ° C or higher, and even more preferably 15T : Above, and 11 is preferably 50 ° C or less, more preferably 401 or less, and still more preferably 30 ° C or less.
<本 发明的方 式> 以下 例示本 发明的方 式。 在这些方式 中, 可适当应 用本发 明清洁 剂组合 物、 硬质表面用 清洁片、 以及硬质表面清洁 方法中 阐述的事 项。 <1> 一种清洁 剂组合物 , 其中, 含有以下成分 (A) ~ (D), 成分 (A): 聚氧乙烯甘油脂肪酸 @旨, 其中, 所述聚氧乙烯甘油脂 肪酸 酯的氧化 乙烯基 的平均加 成摩尔数 为 10摩尔 以下, 并且具有碳原 子数 为 12以下的 直链或支 链的饱和 或不饱和 的脂肪 酰基; 成分 (B): 水; 成分 (C): 成分 (A) 以外的具有碳原子数为 8〜 18的烷基或烯基 的表 面活性剂 ; 以及 成分 (D): 选自下述成分 (D1)和成分 (D2) 中的 1种或 2种以 上: <Mode of the present invention> The mode of the present invention is exemplified below. Among these methods, the items described in the cleaning composition of the present invention, the cleaning sheet for hard surfaces, and the cleaning method for hard surfaces can be suitably applied. <1> A detergent composition, which contains the following components (A) to (D), and component (A): polyoxyethylene glycerin fatty acid@ The average added mole number of the group is 10 moles or less, and has a linear or branched saturated or unsaturated fatty acyl group with a carbon number of 12 or less; component (B): water; component (C): component (A ) Other surfactants having an alkyl or alkenyl group having 8-18 carbon atoms; and component (D): one or more of the following components (D1) and (D2):
(DO 有机酸或 其盐、 (DO organic acid or its salt,
(D2) 无机盐, 在所 述清洁 剂组合物 中, 成分 (A) 的含量为 0.35质量%以上且 5 质量 %以下, 成分 (D1) 的含量以酸计、 成分 (D2) 的含量以盐计时, 成分 (D) 的含量为 0.005质量%以上且 0.4质量%以下, 作为成分 (A) 和成 分 (C) 的合计含量, (A) + (C) 为 10质量%以下。 (D2) Inorganic salt, in the detergent composition, the content of component (A) is 0.35% by mass or more and 5% by mass or less, the content of component (D1) is in terms of acid, and the content of component (D2) is in terms of salt In time, the content of component (D) is 0.005% by mass or more and 0.4% by mass or less, and as the total content of component (A) and component (C), (A) + (C) is 10% by mass or less.
<2> 如上述<1 >所述 的液体清 洁剂组合物 , 其中, 成分(A)可 以含 有 1个以上且 3个以下的脂肪 酰基。 <2> The liquid detergent composition as described in the above <1>, wherein the component (A) may contain one or more and three or less fatty acyl groups.
<3> 如上述<1 >或<2 >所述的 液体清洁 剂组合物 , 其中, 成为 成分 (A) 的脂肪酸酯的来 源的脂肪 酸的碳 原子数 , 优选为 8个以上
12个以 下, 更优选为 8个以上且 10个以下。 <3> The liquid detergent composition as described in the above <1> or <2>, wherein the number of carbon atoms of the fatty acid that is the source of the fatty acid ester of the component (A) is preferably 8 or more 12 or less, more preferably 8 or more and 10 or less.
<4> 如上 述 < 1 >~<3> 中任 一项所述 的液体 清洁剂组 合物, 其 中 , 作为脂肪酸, 为选自各 种辛酸 、 各种壬酸、 各种癸酸、 各种十一 烷酸 和各种十 二烷酸 中的 1种以上的脂肪 酸。 <4> The liquid detergent composition according to any one of the above <1>~<3>, wherein the fatty acid is selected from various caprylic acid, various nonanoic acid, various decanoic acid, various ten One or more fatty acids in monoalkanoic acid and various dodecanoic acids.
<5> 如上 述 < 1 >~<4> 中任 一项所述 的液体 清洁剂组 合物, 其 中 , 成分 (A) 中, 氧化乙烯基的平均加成 摩尔数优 选超过 0, 更优选 为 4以上, 进一步
优选为 9以下, 更优选为 8以下。 <5> The liquid detergent composition according to any one of the above <1>~<4>, wherein, in the component (A), the average number of moles of oxyethylene added is preferably more than 0, more preferably 4 Above, further Preferably it is 9 or less, More preferably, it is 8 or less.
< 6 >如上述 < 1 > ~ < 5 >中任一项所述的液体清洁剂组 合物, 其 中 , 成分 (A) 为聚氧乙烯甘油 (辛酸 /癸酸) 酯 (氧化乙烯基的平均 加成 摩尔数 为 6摩尔)、 以及聚氧乙烯甘油月 桂酸酯 (氧化乙烯基的 平 均加 成摩尔数 为 8摩尔) 中的 1种或 2种。 <6> The liquid detergent composition according to any one of the above <1> to <5 >, wherein the component (A) is polyoxyethylene glycerol (caprylic acid/capric acid) ester (average addition of ethylene oxide) The number of moles is 6 moles), and one or two of polyoxyethylene glycerol laurate (the average number of moles of oxyethylene added is 8 moles).
<7> 如上 述 < 1 >~<6> 中任 一项所述 的液体 清洁剂组 合物, 其 中 , 在所述清洁剂组合 物中, 成分 (A) 的含量为 0.35质量%以上, 优 选为 0.4质量%以上, 更优选为 0.5质量%以上, 进一步优选为 0.7质量% 以上 , 进一步优选为 0.8质量%以上, 更进一步优选 1质量%以上, 并且 为 5质量%以下, 优选 2.6质量%以下, 更优选 L6质量%以下, 更优选 L3 质量 %以下, 进一步优选 L1质量%以下。 <7> The liquid detergent composition according to any one of the above <1>~<6>, wherein, in the detergent composition, the content of the component (A) is 0.35% by mass or more, preferably 0.4% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.7% by mass or more, still more preferably 0.8% by mass or more, still more preferably 1% by mass or more, and 5% by mass or less, preferably 2.6% by mass or less, It is more preferably L6 mass% or less, more preferably L3 mass% or less, and still more preferably L1 mass% or less.
< 8 >如上述 < 1 > ~ < 7 >中任一项所述的液体清洁剂组 合物, 其 中 , 在所述清洁剂组合 物中, 成分 (B) 的含量为 85质量%以上, 更优 选为 90质量%以上, 进一步优选 为 95质量%以上, 更进一步优选为 96 质量 %以上, 并且为 99质量%以下, 优选为 98质量%以下。 <8> The liquid detergent composition according to any one of the above <1> to <7>, wherein, in the detergent composition, the content of the component (B) is 85% by mass or more, more preferably It is 90% by mass or more, more preferably 95% by mass or more, still more preferably 96% by mass or more, and 99% by mass or less, preferably 98% by mass or less.
<9> 如上 述 < 1 >~<8> 中任 一项所述 的液体 清洁剂组 合物, 其 中 , 成分 (C) 为选自 (C1) 非离子表面活性剂、 (C2) 两性表面活性 剂、 及 (C3) 阳离子表面活性剂中的 1种或 2种以上。 <9> The liquid detergent composition according to any one of the above <1>~<8>, wherein the component (C) is selected from (C1) nonionic surfactants, (C2) amphoteric surfactants , And (C3) One or more of cationic surfactants.
< 10>如上述 <9> 所述的液 体清洁 剂组合物 , 其中, (C1) 离 子表 面活性 剂为选 自烷基糖苷 、 聚氧乙烯烷基 醚或者 聚氧乙 烯烯基醚 中的 1种以上的非离子表 面活性 剂, 优选为烷基糖 苷。 <10> The liquid detergent composition according to the above <9>, wherein the (C1) ionic surfactant is one selected from the group consisting of alkyl glycosides, polyoxyethylene alkyl ethers, and polyoxyethylene alkenyl ethers The above nonionic surfactants are preferably alkyl glycosides.
< 11>如上述 <9> 所述的液 体清洁 剂组合物 , 其中, (C2)两性 表面 活性剂为 选自氧化 胺和甜 菜碱中的 1种以上的两性表面 活性剂 , 优 选为氧 化胺 。 <11> The liquid detergent composition as described in the above <9>, wherein the (C2) amphoteric surfactant is one or more amphoteric surfactants selected from the group consisting of amine oxide and betaine, preferably amine oxide.
< 12>如上述 <9> 所述的液 体清洁 剂组合物 , 其中, (C3) 阳离
子表 面活性剂 为单或二 长链烷基 型季铵盐 。 <12> The liquid detergent composition as described in the above <9>, wherein (C3) positive Subsurfactants are mono- or di-long chain alkyl type quaternary ammonium salts.
< 13 >如上述 < 1 >~< 12>中任 一项所述 的液体 清洁剂组 合物, 其 中, 在所述清洁剂 组合物 中, 成分 (C) 的含量为 0.02质量%以上, 优选 为 0.03质量%以上, 并且为 5质量%以下, 优选为 3质量%以下, 更 优选 为 1质量%以下, 进一步优选 0.2质量%以下, 更进一步优 选为 0.1 质量 %以下。 <13> The liquid detergent composition according to any one of the above <1>~<12>, wherein, in the detergent composition, the content of the component (C) is 0.02% by mass or more, preferably 0.03% by mass or more, and 5% by mass or less, preferably 3% by mass or less, more preferably 1% by mass or less, even more preferably 0.2% by mass or less, and still more preferably 0.1% by mass or less.
< 14>如上 述 < 1 >~< 13 >中任一项所述 的液体 清洁剂组 合物, 其 中, 成分 (A) 和成分 (C) 的合计含量 ( (A) + (C) ) 为 10质量 % 以下, 优选为 3质量%以下, 优选为 2质量%以下, 更优选 1.8质量%以 下 , 进一步优选 1.5质量%以下, 并且, 优选为 0.5质量%以上, 更优选 为 0.8质量%以上, 迸一步优选为 1质量%以上。 <14> The liquid detergent composition according to any one of the above <1>~<13>, wherein the total content ((A) + (C)) of the component (A) and the component (C) is 10 % By mass or less, preferably 3% by mass or less, preferably 2% by mass or less, more preferably 1.8% by mass or less, still more preferably 1.5% by mass or less, and preferably 0.5% by mass or more, more preferably 0.8% by mass or more. One step is preferably 1% by mass or more.
< 15>如上 述 < 1 >~< 14>中任 一项所述 的液体 清洁剂组 合物, 其 中, 成分 (A) 和成分 (C) 的质量比以 (A) / (C) 计为 70以下, 优选 为 60以下, 更优选为 20以下, 更优选为 10以下, 进一步优选为 8以 下 , 更进一步优选为 7以下, 并§., 为 2以上, 优选为 3以上, 更优选为 4以上 , 进一步优选为 5以上。 <15> The liquid detergent composition according to any one of the above <1>~<14>, wherein the mass ratio of the component (A) to the component (C) is calculated as (A)/(C) 70 Hereinafter, it is preferably 60 or less, more preferably 20 or less, more preferably 10 or less, still more preferably 8 or less, still more preferably 7 or less, and §., is 2 or more, preferably 3 or more, and more preferably 4 or more , More preferably, it is 5 or more.
< 16>如上 述 < 1 >~< 15>中任 一项所述 的液体 清洁剂组 合物, 其 中, 成分 (Di) 为选自柠檬酸、 柠檬酸一钠、 柠檬酸二钠 、 柠檬酸 三钠 、 柠檬酸一钾、 柠檬酸二钾、 柠檬酸三 钾、 乙二胺四 乙酸, 乙二 胺 四乙酸二 钠、 乙二胺四 乙酸三钠 , 乙二胺四乙酸 二钾、 乙二胺四乙 酸三 钾、 乙二醇双 (2氨基乙基 醚)四乙酸 、 乙二醇双(2氨 基乙基酸 ) 四 乙酸二钠 、 乙二醇双 (2 -氨基乙基醚) 四乙酸三钠、 乙二醇双 (2 - 氨基 乙基醚 ) 四乙酸二钾、 乙二醇双 (2 -氨基乙基醚) 四乙酸三钾、 苯 甲酸 钠、 苯甲酸钾中 的 1种以上。 <16> The liquid detergent composition according to any one of the above <1>~<15>, wherein the component (Di) is selected from the group consisting of citric acid, monosodium citrate, disodium citrate, tri-citrate Sodium, monopotassium citrate, dipotassium citrate, tripotassium citrate, ethylene diamine tetraacetic acid, disodium edetate, trisodium edetate, dipotassium edetate, ethylene diamine Tripotassium tetraacetate, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid, ethylene glycol bis(2 aminoethyl ether) disodium tetraacetate, ethylene glycol bis(2-aminoethyl ether) tetraacetic acid three One or more of sodium, ethylene glycol bis(2-aminoethyl ether) dipotassium tetraacetate, ethylene glycol bis(2-aminoethyl ether) tripotassium tetraacetate, sodium benzoate, and potassium benzoate.
< 17>如上 述 < 1 >~< 15>中任 一项所述 的液体 清洁剂组 合物, 其 中, 成分(D2) 的无机盐为选 自氯化钠 、 氯化钾、 氯化镁、 氯化钙、 氯化 铝、 硫酸钠、 硫酸钾、 硫酸镁 、 硫酸铝、 硅酸钠、 碳酸钠、 碳酸 钾、 碳酸氢钠、 碳酸氢钾中的 1种以上。 <17> The liquid detergent composition according to any one of the above <1>~<15>, wherein the inorganic salt of component (D2) is selected from sodium chloride, potassium chloride, magnesium chloride, and calcium chloride One or more of, aluminum chloride, sodium sulfate, potassium sulfate, magnesium sulfate, aluminum sulfate, sodium silicate, sodium carbonate, potassium carbonate, sodium bicarbonate, and potassium bicarbonate.
< 18 >如上述 < 1 >〜 < 17 >中任一项所述的液体清洁剂 组合物 , 其 中, 在所述清洁 剂组合物 中, 在成分 (D) 为成分 (D1) 时, 成分<18> The liquid detergent composition according to any one of the above <1>~<17>, wherein, in the detergent composition, when the component (D) is the component (D1), the component
(D1) 的含量以酸计 算为 0.005质量%以上, 优选 0.007质量%以上, 更
优选 为 0,01质量%以上, 进一步优选为 0.03质量%以上, 并且为 0.4质量 % 以下, 更优选为 0。3质量%以下, 进一步优选为 0.2质量%以下。 在成 分 (D)为成分 (D2)时, 成分(D2)的含量 以盐 算为 0.005 质量 %以上, 并 为 0.4质量%以下, 更优选为 0.3质量%以下, 进一步 优选 为 0,2质量%以下。 在成 分 (D) 为成分 (D1) 和成分 (D2) 的组合时, 成分 (D1) 的含 量以酸计 且成分 (D2) 的含量以盐计, 成分 (D) 的含量为 0.005 质量 %, 优选 0,007质量%以上, 更优选为 0.01质量%以上, 进一步优选 为 0.03质量%以上, 并 S为 0,4质量%以下, 更优选为 0.3质量%以下, 进 一步 优选为 0.2质量%以下。 The content of (D1) is 0.005% by mass or more in terms of acid, preferably 0.007% by mass or more, more It is preferably 0.01% by mass or more, more preferably 0.03% by mass or more, and 0.4% by mass or less, more preferably 0.3% by mass or less, and even more preferably 0.2% by mass or less. When the component (D) is the component (D2), the content of the component (D2) in terms of salt is 0.005% by mass or more, and 0.4% by mass or less, more preferably 0.3% by mass or less, and even more preferably 0.2% by mass the following. When ingredient (D) is a combination of ingredient (D1) and ingredient (D2), the content of ingredient (D1) is in terms of acid and the content of ingredient (D2) is in terms of salt, and the content of ingredient (D) is 0.005% by mass, It is preferably 0.007 mass% or more, more preferably 0.01 mass% or more, still more preferably 0.03 mass% or more, and S is 0.4 mass% or less, more preferably 0.3 mass% or less, and even more preferably 0.2 mass% or less.
< 19>如上 述 < 1 >~< 17>中任一 项所述 的液体 清洁剂组 合物, 其 中, 在所述清洁剂 组合物 中, 成分 (D) 优选选自成分 (D1) 有机 酸或 其盐中 的 1种或 2种以上。 <19> The liquid detergent composition according to any one of the above <1>~<17>, wherein, in the detergent composition, component (D) is preferably selected from component (D1) organic acid or One or more of its salts.
<20>— 种硬质 表面清洁 片, 其中, 所述 硬质表面 清洁片 含有上述 < 1 >~< 19>中任 一项所述 的清洁 剂组合 物。 <20>—A hard surface cleaning sheet, wherein the hard surface cleaning sheet contains the cleaning agent composition described in any one of <1> to <19>.
<21 >如上 述 <20> 所述 的硬质表 面清洁 , 其中, 所述硬质表 面清 洁片, 其是使基体预先 含浸有 本发明的 清洁剂 组合物而 成、 或者 在即 将使 之前 使干燥 的基体含 浸有本发 明的清 洁剂组合物 而成。 <21> The hard surface cleaning as described in the above <20>, wherein the hard surface cleaning sheet is prepared by impregnating a substrate with the detergent composition of the present invention in advance, or drying immediately before using The matrix is impregnated with the detergent composition of the present invention.
<22> 如上 述 <20> 或<21 >所述 的硬质 表面清 洁 , 其中, 清 洁片 中清洁剂 组合物的 质量相对 于基体质 量的比 例[即,(清洁剂组合物 的质 量 /未含浸状态(干燥状态)的基体的质量)x100]的含浸率优选为 100 质量 %以上, 更优选为 150质量%以上, 弁且优选为 900质量%以下, 更 优选 为 400质量%以下, 进而优选为 350质量%以下。 <22> The hard surface cleaning described in the above <20> or <21>, wherein the ratio of the mass of the detergent composition to the mass of the substrate in the cleaning sheet [ie, (the mass of the detergent composition/non-impregnated The impregnation rate of the state (the mass of the substrate in the dry state) x100] is preferably 100% by mass or more, more preferably 150% by mass or more, and preferably 900% by mass or less, more preferably 400% by mass or less, and still more preferably 350% by mass or less.
<23> 如上述 <20>~<22> 中任一项 所述的硬 质表面清 洁片, 其 中 ,硬质表面 液体清 洁剂组合 物的含浸 前的基 重优选为 30g/m2以上, 更优 选为 40g/m2以上,迸一步优 选为 50g/m2以上,并且优选 为 200g/m2 以下 , 更优选为 150g/m2以下。 <23> The hard surface cleaning sheet according to any one of the above <20> to <22>, wherein the basis weight of the hard surface liquid cleaning agent composition before impregnation is preferably 30 g/m 2 or more, more It is preferably 40 g/m 2 or more, further preferably 50 g/m 2 or more, and preferably 200 g/m 2 or less, more preferably 150 g/m 2 or less.
<24> — 种硬质 表面清 洁方法 , 其中, 将上述 < 1 >~< 19>中任 一项 所述的清 洁剂组合 物应用于 硬质表面 进行清 洁。 <24>-a hard surface cleaning method, wherein the cleaning agent composition described in any one of the above <1>~<19> is applied to the hard surface for cleaning.
<25> 如上 述 <24> 所述 的硬质表 面清洁 方法, 其中, 所述硬质
表面 清洁方 法的对象 为硬质表 面, 作为具有 硬质表面 的物品 , 可以为 火炉 、 抽油烟机、 墙壁、 工作台、 橱柜、 微波炉、 冰箱内部、 门框、 门把 手、 餐桌、 地板、 架子、 窗户、 家具、 镜子、 门、 遥控器、 马桶、 马桶 座圈、 洗手盆 、 浴缸、 厨房的水槽、 窗玻璃、 水龙头、 儿童 品 (高脚 椅、 玩具、 游戏垫)。 <25> The hard surface cleaning method as described in the above <24>, wherein the hard surface The object of the surface cleaning method is a hard surface. As objects with a hard surface, it can be stoves, range hoods, walls, workbenches, cabinets, microwave ovens, refrigerator interiors, door frames, door handles, dining tables, floors, shelves, windows , Furniture, mirrors, doors, remote controls, toilets, toilet seats, wash basins, bathtubs, kitchen sinks, window panes, faucets, children's products (high chairs, toys, game mats).
< 26 >如上述 < 24 >或 < 25 >所述的硬质表面清 洁方法 , 其中, 所述 硬质表面 清洁方法 为下述 (i)〜 (ii)中的任一种, <26> The hard surface cleaning method described in the above <24> or <25 >, wherein the hard surface cleaning method is any one of the following (i) to (ii),
(i)对硬质表面喷 雾或涂布 本发 明的清洁 剂组合物 后进行擦 拭清洁 的方 法; (i) A method of wiping and cleaning a hard surface after spraying or coating the detergent composition of the present invention;
(ii)用含有本发明的清 洁剂组合 物的硬质 表面清 洁片对硬 质表面进 行擦 拭清洁 的方法。 实施例 以下 表示实施 例以及 比较例。 实施例是对 本发明的 例示进行 说明, 并没 有限定本 发明。 另外 , 在以下单独记为“% ”的情况下, 只要没有特别 说明就意 味着 “质量% ”。 实施例 1~33、 比较例 1〜 2 使用 下述配合 成分制 备表 1~4所示的清洁剂 组合物, 并对以下项 目 进行 评 。 将结果示于表 1〜 4。 (ii) A method of wiping and cleaning a hard surface with a hard surface cleaning sheet containing the detergent composition of the present invention. Examples The following shows examples and comparative examples. The examples are illustrative of the present invention, but do not limit the present invention. In addition, when it is separately described as "%" below, it means "% by mass" unless otherwise specified. Examples 1 to 33 and Comparative Examples 1 to 2 used the following ingredients to prepare the detergent compositions shown in Tables 1 to 4, and evaluated the following items. The results are shown in Tables 1 to 4.
[清洁力] 评价 对于变性 油污的清 洁力。 将 0.02g菜籽油均匀 地涂抹 在不 锈钢 it的单面上 (70mmx25mm) ( 1/2< (涂抹面积 /不锈钢片的单面 的面积) <3/4 )o 将其在 1701:保温 炉中 放置 0.5h, 然后冷却至室温 并称量 , 将该重量计为 W1。 裁剪 出数片长 宽为 100mmx70mm 的无 纺布 (基体为合成纤维 , 基 重为 40±4g/m2, 大和纺织株式会社 ), 在这些无纺布上分 别滴加 表 1~4 中 各个实施 例和 比较例的 清洁剂 组合物 lml, 制作硬质表面 用清洁 片 ([清洁剂 组合物 的质 量 /未含浸状 态 (干燥状态) 的基 体的 质量 ] x 100-320质量 % )。 然后将 其包 裹 在 已用 铝 箔包 裹 的橡 皮 擦 ( 15mmx40mmxl Omni ) —h。
用包 裹上 含浸有 实施 例 i的清洁剂 组合 物的清 洁片 的橡 皮擦的 15mmx40mm 的 面擦拭不 锈钢表面 1次。 等待 10 分钟, 再次称量不锈 钢; t, 将该重量 ih为 W2。 彻底去 除不锈 钢片上的 污渍, 干燥并称量 , 将该重量计为 W0 。 清洁力 二[ (W1 W2) /(Wi-WO) j*i00 (%) [Cleaning power] Evaluate the cleaning power against denatured oil stains. Spread 0.02g rapeseed oil evenly on the single side of stainless steel it (70mmx25mm) (1/2< (application area/single side area of stainless steel sheet) <3/4) o Put it in 1701: holding furnace Leave it for 0.5h, then cool to room temperature and weigh it, and calculate the weight as W1. Cut out several pieces of non-woven fabric with length and width of 100mmx70mm (the matrix is synthetic fiber, the basis weight is 40±4g/m 2 , Daiwa Textile Co., Ltd.), and each of the implementations in Tables 1 to 4 are added to these non-woven fabrics. 1 ml of the cleaning composition of the example and the comparative example was used to prepare a hard surface cleaning sheet ([mass of the cleaning composition/mass of the substrate in the non-impregnated state (dry state)] x 100-320% by mass). Then wrap it in an eraser (15mmx40mmxl Omni)-h that has been wrapped in aluminum foil. The surface of the stainless steel was wiped once with the 15mmx40mm surface of the eraser wrapped with the cleaning sheet impregnated with the cleaning agent composition of Example i. Wait for 10 minutes, weigh the stainless steel again; t, set the weight ih as W2. The stains on the stainless steel sheet are thoroughly removed, dried and weighed, and the weight is counted as W0. Cleaning power two [(W1 W2) / (Wi-WO) j*i00 (%)
WO 、 W1和 W2在测定时 取小数 点后 5位进行计算。将 算 结果记录 到表 格中。 然后 , 重复上述操作 , 使 与实施例 1相同的擦拭方法 完成表 1~4 中剩 余的实施 例 /比较例。 When measuring WO, W1 and W2, take 5 decimal places for calculation. Record the calculation results in the table. Then, repeat the above operations to complete the remaining examples/comparative examples in Tables 1 to 4 using the same wiping method as in Example 1.
[白色残余] 评 对于 硬质表面 清洁后 的白色残 余。 取一 片经过清 洁处理的 玻璃板 (中国台湾 玻璃工业 股份有 限公司, 大小 为 30cmx30cmx().5cm)。 将无 纺布 (基体为合成纤维 , 基重为 40±4g/m2, 大和纺织株式会 社 )裁剪为 20cmxl4cm大小 的数片 , 对这些无纺布, 分别滴加表 1〜 4中 各个 实施例 和比较例 的清洁 剂组合物 4mL, 由此制成硬质表 面 清洁 片 (清洁剂组合 物的 质量 /未含浸状 态 (干燥状态 ) 的基体的 质量 :320% )。 用此 清洁片擦 拭玻璃 板的任 意一面 (从玻璃板的一 个边缘至 另一 个边 缘) , 来回 10次直至液体浸润整个 玻璃 。 然后, 对擦拭过的玻璃 板 , 拍摄照片, 对其进行图像处理 (使肋 mageJ), 测定玻璃板上的白色 残余 的残留面 积, 以玻璃板的处 理面积为 基准算 出白色残 余的残 留率, 并按 照以下基 准进行 评价。 白色 残余的评 价基准 [White residue] Comment on the white residue after cleaning the hard surface. Take a cleaned glass plate (China Taiwan Glass Industry Co., Ltd., size 30cmx30cmx().5cm). The non-woven fabric (matrix is synthetic fiber, basis weight is 40±4g/m 2 , Daiwa Textile Co., Ltd.) is cut into several pieces of 20cmxl4cm size, and each of the examples in Tables 1 to 4 are added dropwise to these non-woven fabrics. With 4 mL of the detergent composition of the comparative example, a hard surface cleaning sheet (mass of the detergent composition/mass of the substrate in the non-impregnated state (dry state): 320%) was thus prepared. Use this cleaning sheet to wipe any side of the glass plate (from one edge of the glass plate to the other edge), back and forth 10 times until the liquid soaks the entire glass. Then, take a picture of the wiped glass plate, perform image processing on it (make ribs mageJ), measure the residual area of white residue on the glass plate, calculate the residual rate of white residue based on the treated area of the glass plate, and The evaluation was performed according to the following criteria. Evaluation criteria for white residue
++: 残留率为 50%以下 残 留率为大于 50%小于 70% 残留率为 70%以上 再者 , 表 1〜 4 中的配合成分的含量 (质量%) 均为基于有效成分 的数 值。 实施例以及 比较例 中使用 的各配合 成分一 并如以 下所示 。 此 外 , 成分 (D1) 的含量 (质量%) 为基于有效成分 以酸计的 数值。 成 分 (D2) 的含量 (质量%) 为基于有效成分以盐计 的数值 。
<成 分 (A) > 聚氧 乙烯甘油 (辛酸 /癸酸) 酯 (商品名 “TEGOSOFT GMC6”, Evonik Nutrition & Care GmbH制造, 有效成分含量为 100%) ++: The residual rate is less than 50%, and the residual rate is greater than 50% and less than 70%. The residual rate is more than 70%. In addition, the contents (mass%) of the compounding ingredients in Tables 1 to 4 are all values based on active ingredients. The respective compounding components used in the examples and comparative examples are collectively shown below. In addition, the content (% by mass) of the ingredient (D1) is a value based on the active ingredient in terms of acid. The content (% by mass) of the ingredient (D2) is the value based on the active ingredient in terms of salt. <Ingredient (A)> Polyoxyethylene glycerin (caprylic acid/capric acid) ester (trade name "TEGOSOFT GMC6", manufactured by Evonik Nutrition & Care GmbH, 100% active ingredient content)
<成 分 (C) > <Component (C) >
*(C1): Cu)_16烷基糖苷(商品名 “MAYDOL 12”, Kao Corporation 制造 , 有效成分含量 为 40%) * (C1): C u )_ 16 alkyl glycosides (trade name "MAYDOL 12", manufactured by Kao Corporation, 40% active ingredient content)
* ( C2): 月桂基二甲 基氧 化 胺 (商品名 “AmpMtol 20N”, Kao Corporation制造, 有效成分含量为 35%) (C3): 苄基 -C12-i6-烷基二甲基氯化铵 (商品名 “Sanisol B50”, Kao Corporation制造, 有效成分含量为 50,8%) * (C2): Lauryl dimethyl amine oxide (trade name "AmpMtol 20N", manufactured by Kao Corporation, with an active ingredient content of 35%) (C3): Benzyl-C 12-i6 -alkyl dimethyl chloride Ammonium (trade name "Sanisol B50", manufactured by Kao Corporation, active ingredient content is 50,8%)
<成 分 (D) > (D1) : 二水合乙二胺 四乙酸二销 I(Nagase Chemtex Corporation 制造 ) , 其含量 (m) 以酸计的计算公式如 下: <Component (D)> (D1): Ethylenediaminetetraacetic acid dihydrate I (manufactured by Nagase Chemtex Corporation), the content (m) in terms of acid is calculated as follows:
EDTA.2Na,2H20 的分 子量: 372.25g/mol、 The molecular weight of EDTA.2Na,2H 2 0: 372.25g/mol,
· (D1) : 一水合梓檬酸 (Fuso Chemical Co., Ltd。制造) , 其含 量 (m) 以酸计的计算公 式如下 : 柠檬 酸: 192.Bg/mol 一水 合朽1檬酸: 2l0.14g/mol in(梓檬酸)二 m(—水合梓檬酸) ¥ 192.13/210.14 · (D1): Zi monohydrate citric acid (Fuso Chemical Co., Ltd., Ltd.) in an amount (m) is calculated in terms of the following acids: citric acid: 192.Bg/mol citric acid monohydrate rot 1: 2L0 .14g/mol in (citric acid) two m ( -hydrated citric acid) ¥ 192.13/210.14
* (D2) : 氯化铝 (A1C13)) * (D2): Aluminum chloride (A1C1 3 ))
<其 它成分 > <Other ingredients >
·尼泊 金甲酯 (Ueno Fine Chemicals Industry, Ltd.制造,有效成分含 量为 100%) 乙醇 (GODO SHUSEI CO., Ltd.制造, 有效成分含量为 95%)
表
· Methyl Paraben (manufactured by Ueno Fine Chemicals Industry, Ltd., active ingredient content is 100%) Ethanol (manufactured by GODO SHUSEI CO., Ltd., active ingredient content is 95%) table
表 1、 2中, 根据实施例 1〜 7与比较例 1~2的结果可知, 在配合成分 (A) 至本发明的清 洁剂组合 物的情形 时, 成分 (A) 的含量如果在本 发明 的范围 内, 清洁力变高。 表 3中,根据实施例 16〜 21的结果可知,在配合成分(A)和成分(C) 至本 发明的清 洁剂组合 物的情形 时, 成分 (A) 相对于成分 (C) 的质 量 比 (A) /(C) 如果在本发明的范围内, 清洁力变高。 表 4中, 根据实施例 22 33的结果可知, 在作为成分 (D)配 合成分 (D1)和 /或成分(D2)至本发明 的清洁剂组 合物的情 形时,成分 (D1) 以酸 计、 成分 (D2) 以盐计时, 成分 (D) 的含量如果在本发明 的范 围内 , 白色残余减少 。
In Tables 1 and 2, according to the results of Examples 1 to 7 and Comparative Examples 1 to 2, it can be seen that when ingredient (A) is blended into the detergent composition of the present invention, if the content of ingredient (A) is in the present invention Within the range, the cleaning power becomes higher. In Table 3, based on the results of Examples 16 to 21, it can be seen that when component (A) and component (C) are blended into the detergent composition of the present invention, the mass ratio of component (A) to component (C) (A)/(C) If it is within the scope of the present invention, the cleaning power becomes higher. In Table 4, according to the results of Examples 22 to 33, when the component (D1) and/or the component (D2) are blended as the component (D) into the detergent composition of the present invention, the component (D1) is calculated as acid , Component (D2) is measured by salt. If the content of component (D) is within the scope of the present invention, the white residue will be reduced.
Claims
1 . 一种清洁剂组合 物, 其中, 所述 清洁剂组合 物含有 以下成分 (A) 〜 (D), 成分 (A): 聚氧乙烯貨油脂肪酸亂 其中, 所述聚氧乙烯甘 油脂 肪酸 酯的氧化 乙烯基 的平均加 成摩尔数 为 10摩尔 以下, 并且具有碳原 子数 为 12以下的 直链或支 链的饱和 或不饱和 的脂肪 酰基; 成分 (B): 水; 成分 (C): 成分 (A) 以外的具有碳原子数为 8〜 18的烷基或者烯 基的 表面活性 剂; 以及 成分 (D)- 选自下述成分 (D1) 和成分(D2) 中的 1种或 2种以 上: 成分 (D1): 有机酸或其盐、 成分 (D2): 无机盐, 在所 述清洁剂 组合物中 , 成分(A) 的含量为 0.35质量%以上且 5 质量 %以下, 成分 (D1) 的含量以酸计、 成分 (D2) 的含量以盐 时, 成分 (D)的含量 为 0.005质量%以上且 0.4质量%以下, 作为成分 (A) 和成 分 (C) 的合计含量, (A) + (C) 为 10质量%以下。 1. A detergent composition, wherein the detergent composition contains the following components (A) to (D), component (A): polyoxyethylene cargo oil fatty acid, the polyoxyethylene glycerin fatty acid The average added mole number of the oxyethylene group of the ester is 10 moles or less, and has a linear or branched saturated or unsaturated fatty acyl group with a carbon number of 12 or less; component (B): water; component (C) : Surfactant having an alkyl group or alkenyl group with 8-18 carbon atoms other than component (A); and component (D)-one selected from the following components (D1) and (D2) or Two or more types: component (D1): organic acid or its salt, component (D2): inorganic salt, in the detergent composition, the content of component (A) is 0.35% by mass or more and 5% by mass or less, component When the content of (D1) is based on acid and the content of component (D2) is based on salt, the content of component (D) is 0.005 mass% to 0.4 mass%, as the total content of component (A) and component (C), (A) + (C) is 10% by mass or less.
2. 如权利要求 1所述的清洁 剂组合物 , 其中, 成分 (A) 的含量为 0.35质量%以上且 2,6质量%以下。 2. The detergent composition according to claim 1, wherein the content of the component (A) is 0.35% by mass or more and 2,6% by mass or less.
3. 如权利要求 1所述的 清洁剂组 合物, 其中, 成分 (A) 的含量为().35质量%以上且 1.3质量%以下。 3. The detergent composition according to claim 1, wherein the content of the component (A) is (). 35% by mass or more and 1.3% by mass or less.
4. 如权利要求 1所述的清洁 剂组合物 , 其中, 成分 (B) 的含量为 85质量%以上 。 4. The detergent composition according to claim 1, wherein the content of the component (B) is 85 mass% or more.
6. 如权利要求 1~5中任一项所 述的清洁 剂组合物 , 其中, 作为 成分 (A) 相对于成分 (C) 的质量比, (A) /(C) 为 70 以 下 6. The detergent composition according to any one of claims 1 to 5, wherein, as the mass ratio of component (A) to component (C), (A)/(C) is 70 or less
7. 如权利要求 1〜 5中任一项所述的清洁 剂组合物 , 其中, 作为成 分 (A)相对于成 分 (C) 的质量比, (A) /(C)为 8以下。 7. The detergent composition according to any one of claims 1 to 5, wherein, as the mass ratio of the component (A) to the component (C), (A)/(C) is 8 or less.
8. 如权利要求 1〜 7中任一项所述的清洁 剂组合物 , 其中, 作为 成分 (A)相对于 成分 (C) 的质量比, (A) /(C)为 3以上。 8. The detergent composition according to any one of claims 1 to 7, wherein, as a mass ratio of component (A) to component (C), (A)/(C) is 3 or more.
9. 如权利要求 1〜 7中任一项所述的清洁 剂组合物 , 其中, 作为成 分 (A)相对于成 分 (C) 的质量比, (A) /(C)为 4以上。 9. The detergent composition according to any one of claims 1 to 7, wherein, as a mass ratio of the component (A) to the component (C), (A)/(C) is 4 or more.
10. 如权利要求 1~9中任一项所 述的清洁 剂组合物 , 其中, 成分 (A) 的脂肪酸来 源为选 自辛酸、 壬酸、 癸酸、 十一烷酸和十 二烷 酸中的 1种或 2种以上 。 10. The detergent composition according to any one of claims 1 to 9, wherein the fatty acid source of component (A) is selected from the group consisting of caprylic acid, nonanoic acid, capric acid, undecanoic acid and dodecanoic acid One or two or more of the same.
11. 如权利要求 1〜 10中任一项所述的清洁剂组合 物, 其中, 成分 (C) 的表面活性剂为选 自 (C1) 离子表面活性剂 、 (C2) 两性 表面活性 剂、 及 (C3) 阳离子表面活性剂 中的 1种或 2种以上。 11. The detergent composition according to any one of claims 1 to 10, wherein the surfactant of component (C) is selected from (C1) ionic surfactants, (C2) amphoteric surfactants, and (C3) One or more of cationic surfactants.
12. 如权利要求 1〜 11中任一项所述的清洁剂组合 物, 其中, 所述 成分 (D) 为选自成分 (D1) 有机酸或其盐中的 1种或 2种 以上 。 12. The cleansing composition according to any one of claims 1 to 11, wherein the component (D) is one or two or more selected from the organic acid or the salt of the component (D1).
13. 一种硬质表面清 洁片, 其中, 所述 硬质表面 清洁片含 有权利要 求 1~12中任一 项所述的 清洁剂组 合物 。 13. A hard surface cleaning sheet, wherein the hard surface cleaning sheet contains the cleaning agent composition according to any one of claims 1-12.
14. 一种硬质表面清 洁方法 , 其中, 将权利 要求 1〜 12中任一项所述的清洁剂组合物 应用于硬 质表面 进 行清 洁。
14. A method for cleaning a hard surface, wherein the cleaning agent composition according to any one of claims 1 to 12 is applied to a hard surface for cleaning.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2022541300A JP2023509949A (en) | 2020-01-10 | 2021-01-07 | CLEANING COMPOSITION, CLEANING SHEET FOR HARD SURFACE AND HARD SURFACE CLEANING METHOD |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010026344.5 | 2020-01-10 | ||
CN202010026344 | 2020-01-10 | ||
CN202011598850.8 | 2020-12-29 | ||
CN202011598850.8A CN113105953A (en) | 2020-01-10 | 2020-12-29 | Cleaning agent composition, hard surface cleaning sheet, and hard surface cleaning method |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2021140452A1 true WO2021140452A1 (en) | 2021-07-15 |
Family
ID=76709131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2021/050081 WO2021140452A1 (en) | 2020-01-10 | 2021-01-07 | Detergent composition, and cleaning sheet and cleaning method for hard surface |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP2023509949A (en) |
CN (1) | CN113105953A (en) |
TW (1) | TW202132553A (en) |
WO (1) | WO2021140452A1 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6451138A (en) * | 1987-07-24 | 1989-02-27 | Henkel Kgaa | Gloss thick liquid containing no alkanol amine |
GB2475790A (en) * | 2009-11-26 | 2011-06-01 | Byotrol Plc | Anti-microbial wipe |
JP2012521281A (en) * | 2009-03-26 | 2012-09-13 | バブルズ アンド ビヨンド ゲーエムベーハー | Methods and compositions for cleaning objects |
JP2014181206A (en) * | 2013-03-19 | 2014-09-29 | Mandom Corp | Aqueous cleansing cosmetic |
WO2015156387A1 (en) * | 2014-04-11 | 2015-10-15 | 花王株式会社 | Skin cleanser composition |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2363819A1 (en) * | 1999-12-27 | 2001-07-05 | Taiho Industries Co., Ltd. | Hard surface treating agent, stain-proofing agent and method for surface treatment |
SG11201909839XA (en) * | 2017-10-17 | 2019-11-28 | Kao Corp | Liquid detergent composition for hard surface |
WO2019167997A1 (en) * | 2018-03-02 | 2019-09-06 | 花王株式会社 | Fungicidal detergent composition for rigid surface |
-
2020
- 2020-12-29 CN CN202011598850.8A patent/CN113105953A/en active Pending
-
2021
- 2021-01-06 TW TW110100461A patent/TW202132553A/en unknown
- 2021-01-07 WO PCT/IB2021/050081 patent/WO2021140452A1/en active Application Filing
- 2021-01-07 JP JP2022541300A patent/JP2023509949A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6451138A (en) * | 1987-07-24 | 1989-02-27 | Henkel Kgaa | Gloss thick liquid containing no alkanol amine |
JP2012521281A (en) * | 2009-03-26 | 2012-09-13 | バブルズ アンド ビヨンド ゲーエムベーハー | Methods and compositions for cleaning objects |
GB2475790A (en) * | 2009-11-26 | 2011-06-01 | Byotrol Plc | Anti-microbial wipe |
JP2014181206A (en) * | 2013-03-19 | 2014-09-29 | Mandom Corp | Aqueous cleansing cosmetic |
WO2015156387A1 (en) * | 2014-04-11 | 2015-10-15 | 花王株式会社 | Skin cleanser composition |
Also Published As
Publication number | Publication date |
---|---|
CN113105953A (en) | 2021-07-13 |
TW202132553A (en) | 2021-09-01 |
JP2023509949A (en) | 2023-03-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US11485937B2 (en) | Low-VOC cleaning substrates and compositions comprising a quat and solvent mixture | |
JP4097600B2 (en) | Hard surface cleaning agent containing ethylene oxide / propylene oxide block copolymer surfactant | |
CA2452962C (en) | Thickened toilet bowl cleaner | |
JP3908535B2 (en) | Cleaning and maintenance of hard surface cleaning compositions, pre-moistened wipes, methods of use, and improved appearance and / or hygiene under such compositions or wipes and forced conditions without rinsing Articles containing instructions for ease of use. | |
AU2002361849A1 (en) | Thickened toilet bowl cleaner | |
TWI680182B (en) | Detergent composition for hard surface, detergent article for hard surface, method for cleaning floor, and method for reducing scratch on tile floor | |
WO2019235424A1 (en) | Liquid detergent composition for tableware and/or rigid kitchen articles | |
JP5819684B2 (en) | Liquid detergent composition for hard surfaces | |
US20090270305A1 (en) | Cleaning composition | |
EP1343867B1 (en) | Antimicrobial wipe | |
WO2021140452A1 (en) | Detergent composition, and cleaning sheet and cleaning method for hard surface | |
JP5552041B2 (en) | Cleaning composition for water wiping | |
TW201920639A (en) | Liquid detergent composition for hard surfaces | |
WO2004074417A1 (en) | Antimicrobial cleaning compositions | |
WO2010139107A1 (en) | Cleaning compositions and methods | |
JP3326052B2 (en) | Liquid detergent composition | |
JP6158065B2 (en) | Cleaning composition for hard surface | |
JP6749959B2 (en) | Floor feel improver | |
TW202204586A (en) | Detergent composition for hard surfaces | |
WO2002090484A2 (en) | Hard surface cleaning wipe | |
JP2022161849A (en) | Acidic washing agent composition | |
JP2000239699A (en) | Cleaning sheet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 21738263 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2022541300 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 21738263 Country of ref document: EP Kind code of ref document: A1 |