WO2021128308A1 - Sewage treatment system and method for strengthening anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage - Google Patents

Sewage treatment system and method for strengthening anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage Download PDF

Info

Publication number
WO2021128308A1
WO2021128308A1 PCT/CN2019/129340 CN2019129340W WO2021128308A1 WO 2021128308 A1 WO2021128308 A1 WO 2021128308A1 CN 2019129340 W CN2019129340 W CN 2019129340W WO 2021128308 A1 WO2021128308 A1 WO 2021128308A1
Authority
WO
WIPO (PCT)
Prior art keywords
module
constructed wetland
wetland
tank
sewage treatment
Prior art date
Application number
PCT/CN2019/129340
Other languages
French (fr)
Chinese (zh)
Inventor
戴玉女
杨扬
熊春晖
张晓萌
唐小燕
Original Assignee
暨南大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 暨南大学 filed Critical 暨南大学
Publication of WO2021128308A1 publication Critical patent/WO2021128308A1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Definitions

  • the present invention relates to the technical field of water treatment, in particular to a sewage treatment system and method for enhancing anaerobic ammonia oxidation and denitrification and simultaneous dephosphorization of domestic sewage.
  • Constructed wetland is an economical, environmentally friendly and eco-friendly water treatment technology, which mainly includes three types: vertical flow constructed wetland, horizontal subsurface flow constructed wetland and surface flow constructed wetland. It treats sewage through the synergy of substrates, plants and microorganisms, which can not only effectively purify water quality, but also provide habitats for wild animals.
  • constructed wetlands are simple in structure, easy to maintain, and low in operating costs, so they are widely used in the treatment of multiple types of sewage.
  • the purpose of the present invention is to overcome the above-mentioned shortcomings of the prior art and provide a sewage treatment system that enhances the anaerobic amination and denitrification of domestic sewage while simultaneously dephosphorizing.
  • the present invention can significantly improve the effect of denitrification and phosphorus removal and effectively prevent wetland clogging. , Increase the service life of wetlands.
  • Another object of the present invention is to provide a method for treating sewage using the above sewage treatment system.
  • a sewage treatment system that strengthens the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage, including successively connected filter modules, Anaerobic-Aerobic-Anoxic Baffled Reactor (AOABRR) ) Module, water distribution module and combined constructed wetland module;
  • the filter module is connected to the AOABR module through a submersible pump, and the water distribution module is connected to the combined constructed wetland module through a lift pump;
  • the filter module is provided with a water inlet, and the combined constructed wetland module is provided The water outlet;
  • the filter module is a grid sedimentation tank;
  • the AOABR module includes an anaerobic tank, an aerobic tank and an anoxic tank connected in sequence;
  • the water distribution module is a collection tank;
  • the combined constructed wetland module consists of multiple It is composed of three-level constructed wetlands, and the multi-level constructed wetlands are arranged in a ladder structure from high to low according to
  • the filter module is a grid sedimentation tank with a pore size of 5mm, which is used to filter large debris in the sewage;
  • the water distribution module is connected to the combined constructed wetland module and is used to store the sewage in the AOABR module to facilitate different inlets.
  • the water load pumps sewage into the combined constructed wetland module.
  • an AOABR module is installed before the combined constructed wetland module, which greatly reduces the load of organic matter entering the constructed wetland and effectively reduces the risk of clogging of the constructed wetland.
  • the AOABR module after the sewage passes through the AOABR module, it not only reduces the nutrient influent load into the combined constructed wetland, but also increases the dissolved oxygen content of the combined constructed wetland influent.
  • the reduction of the organic matter load of the first-stage saturated flow wetland greatly increases the abundance of autotrophic anammox bacteria, and the increase in the dissolved oxygen content of the influent is also due to the conversion of ammonia nitrogen in the upper layer of the first-stage saturated flow wetland into Nitrate nitrogen and nitrite nitrogen provide conditions, which greatly promotes the first-stage saturated wet subterranean anaerobic ammonia oxidation denitrification, forming a simultaneous denitrification of short-cut nitrification and denitrification and anaerobic ammonia oxidation; at the same time, saturation There are aerobic, anoxic and anaerobic zones in the wetland.
  • the nitrification reaction in the aerobic zone and the anaerobic ammonia oxidation reaction in the anaerobic zone produce nitrate, which is a competitive denitrifying phosphorous under low-carbon conditions.
  • the phosphorus absorption reaction of bacteria in the hypoxic zone provides electron acceptors, thereby enhancing the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage by the water treatment system.
  • the sewage treatment system for enhanced anaerobic ammonia oxidation and dephosphorization of domestic sewage can remove 98% of COD Cr , 91.5% of total nitrogen, 98.2% of ammonia nitrogen and 92.7% of total phosphorus in sewage.
  • the effluent concentration of ammonia nitrogen and COD Cr can reach the surface water environmental quality standard (GB3838-2002) I to II water, the total phosphorus can reach VI to V, and the total nitrogen can reach V to inferior V.
  • the water inlets of the anaerobic tank, aerobic tank and anoxic tank are all set at the bottom end, and the water outlets are all set at the top end.
  • the water inlet of the aerobic tank is connected with the water outlet of the anaerobic tank, and after the water is discharged, it is connected with the water inlet of the anoxic tank; that is, the water flow patterns of the anaerobic tank, aerobic tank, and anoxic tank It is a zigzag style with bottom in and out.
  • both the anaerobic tank and the aerobic tank are provided with polyethylene fillers for the attachment and growth of microorganisms.
  • an aeration pump is provided in the aerobic tank to control the content of organic matter in the aerobic tank and the water quality of the constructed wetland.
  • the aeration volume of the aerobic tank is 0.3 ⁇ 0.35m 3 /h
  • the aeration time is 2 ⁇ 4h/d
  • the dissolved oxygen concentration is controlled at 2 ⁇ 5mg/L
  • the nitrate nitrogen can be removed in the non-aeration stage .
  • the water inlet mode of the AOABR is batch water inlet, the dissolved oxygen in the anoxic tank is controlled at 0.5-1.5 mg/L in the non-water inlet stage, the nitrate nitrogen can be further removed, and the oxygen-enriched wastewater from the aerobic tank enters through the baffle type In the anoxic tank, the dissolved oxygen in the anoxic tank is controlled at 1.5-4mg/L, and then the oxygenated sewage mainly containing ammonia nitrogen enters the water distribution module through the baffle.
  • the multi-level constructed wetland is a three-level or above constructed wetland.
  • the multi-level constructed wetland is a three-level constructed wetland.
  • the first stage of the multi-stage constructed wetland is a saturated flow wetland; the other stages are saturated flow or unsaturated flow wetlands.
  • the saturated flow wetland is a horizontal subsurface flow constructed wetland or a surface flow constructed wetland; the unsaturated flow wetland is a vertical flow constructed wetland.
  • the multi-level constructed wetland is a first-level horizontal subsurface flow constructed wetland, a second-level surface flow constructed wetland, and a third-level vertical flow constructed wetland that are sequentially connected from high to low; or the multi-level constructed wetland is from high to low.
  • the first-level surface flow constructed wetland, the second-level vertical flow constructed wetland and the third-level horizontal subsurface flow constructed wetland are sequentially connected.
  • each level of the multi-level constructed wetland is provided with large gravel and small gravel in sequence from bottom to top; wherein the particle size of the large gravel is 2 to 3 cm, and the particle size of the small gravel is 0.5 to 0.5 cm. 1cm; each level of the multi-level constructed wetland is provided with aquatic plants on the surface of the constructed wetland.
  • the aquatic plants are windmill grass, canna and Zai Lihua.
  • the thickness of the gravel in the vertical flow constructed wetland and the horizontal subsurface flow constructed wetland is 60cm, wherein the thickness of the large gravel is 10cm and the thickness of the small gravel is 50cm; the thickness of the gravel in the surface flow constructed wetland is 30cm, Among them, the thickness of the large gravel is 10cm, and the thickness of the small gravel is 20cm.
  • the aeration pump, submersible pump and lifting pump are all controlled by an automatic electronic control system.
  • the top of the water inlet of the sump is connected to the top of the water outlet of the anoxic tank.
  • the water inlet end of the combined constructed wetland module is connected to the water outlet end at the bottom of the water collection tank.
  • the present invention also claims a method for treating sewage using the above sewage treatment system, which includes the following steps:
  • the sewage is domestic sewage
  • the total nitrogen load of the sewage is preferably 10-50 mg/L
  • the total phosphorus load is preferably 1-3 mg/L
  • the COD Cr load is preferably 100-400 mg/L.
  • Sewage is pumped into the anaerobic tank in batches after being precipitated by the grid, and then enters the aerobic tank, anoxic tank and the collecting tank in turn through overflow.
  • the way for sewage to enter the AOABR module is batch inflow, once a day; the inflow mode of the water distribution module is batch inflow; the inflow mode of the combined constructed wetland module is continuous inflow, inflow
  • the load is 0.1 ⁇ 0.5m/d.
  • the aeration mode in the aerobic tank is intermittent aeration, the aeration volume is 0.3 to 0.35 m 3 /h, and the aeration time is 2 to 4 hours per day; the dissolved oxygen concentration in the aerobic tank is maintained at 2 ⁇ 5mg/L, nitrate nitrogen can be removed in the non-aeration stage.
  • the aeration time is 2 hours per day.
  • the dissolved oxygen in the anoxic tank is controlled at 0.5-1.5 mg/L during the non-inflow phase, nitrate nitrogen can be further removed, and the oxygen-enriched sewage of the aerobic tank enters the anoxic tank through a baffle, and the anoxic tank is dissolved
  • the oxygen can be controlled at 1.5-4mg/L, and then the oxygenated sewage mainly containing ammonia nitrogen enters the water distribution module through the baffle type.
  • the present invention uses the above-mentioned sewage treatment system. After the sewage enters the AOABR module and undergoes aeration treatment, the content of organic matter in the combined constructed wetland is greatly reduced, and the risk of clogging of the constructed wetland is effectively reduced; and the combined constructed wetland module is increased after the AOABR module.
  • the dissolved oxygen content of the influent promotes the nitrification of the first-level horizontal flow constructed wetland or the surface flow constructed wetland, thereby providing a substrate for the anaerobic ammonia oxidation reaction that does not depend on the denitrification of organic carbon sources.
  • the present invention has the following beneficial effects:
  • the sewage treatment system of the present invention still has a high denitrification and phosphorus removal effect.
  • the present invention can effectively reduce the content of organic matter entering the constructed wetland, greatly reduce the risk of clogging of the constructed wetland, and prolong the service life of the constructed wetland.
  • the present invention can effectively reduce the pollution load entering the constructed wetland, greatly reduce the area occupied by the constructed wetland, and solve the disadvantage of using the constructed wetland to treat sewage with a large area.
  • Figure 1 is a schematic diagram of the structure of the sewage treatment system of the present invention.
  • FIG. 2 is a schematic diagram of the structure of the sewage treatment system of Embodiment 1.
  • FIG. 2 is a schematic diagram of the structure of the sewage treatment system of Embodiment 1.
  • Fig. 3 is a schematic diagram of the structure of the sewage treatment system of the second embodiment.
  • Fig. 4 shows changes in the relative abundance of nitrogen conversion function microorganisms in the first-level horizontal subsurface flow constructed wetland (A) and the first-level surface flow constructed wetland (B) with or without the AOABR module in the embodiment of the present invention.
  • test methods used in the following examples are conventional methods unless otherwise specified; the materials and reagents used, unless otherwise specified, are commercially available reagents and materials.
  • a sewage treatment system that strengthens the anaerobic ammonia oxidation and denitrification and dephosphorization of domestic sewage, as shown in Figures 1 and 2, includes a filter module, an AOABR module, a water distribution module, and a combined constructed wetland module connected in sequence;
  • the filter module passes diving Pump 2 is connected to the AOABR module, the water distribution module is connected to the combined constructed wetland module through the lift pump 9;
  • the filter module is provided with water inlets, and the combined constructed wetland module is provided with water outlets;
  • the filter module is the grid sedimentation tank 1;
  • the AOABR module includes sequentially connected Anaerobic tank 3, aerobic tank 4, and anoxic tank 5;
  • the water distribution module is water collection tank 8;
  • the combined constructed wetland module is composed of multi-level constructed wetlands, which are arranged in a ladder structure from high to low according to the direction of water flow; Multi-level constructed wetlands are the first-level horizontal subsurface flow constructed wetland
  • Multi-level constructed wetlands consist of large gravels and small gravels in order from bottom to top.
  • the particle size of the large gravel is 2 ⁇ 3cm
  • the particle size of the small gravel is 0.5 ⁇ 1cm
  • There are aquatic plants on the surface of each level of constructed wetland in constructed wetlands the thickness of gravel in vertical flow constructed wetland 12 and horizontal subsurface flow constructed wetland 10 is 60cm, among which the thickness of large gravel is 10cm, and the thickness of small gravel is 50cm; surface flow The thickness of gravel in constructed wetland 11 is 30cm, among which, the thickness of large gravel is 10cm, and the thickness of small gravel is 20cm; both anaerobic tank 3 and aerobic tank 4 are equipped with polyethylene film-coated packing 6; aerobic tank 4 There is an aeration pump 7; the aeration pump 7, the submersible pump 2 and the lifting pump 9 are all controlled by the automatic electronic control system 13; the top of the water inlet of the collection tank 8 is connected
  • the filter module is a grid sedimentation tank 1 with a pore size of 5mm; the length of the anaerobic tank 3 is 1m, the length of the aerobic tank 4 is 1.7m, the length of the anoxic tank 5 is 0.8m, and the width is 1.26m. , The height is 2.5m; the water capacity of the sump 8 is 2m 3 ; the length, width and height of the first-level horizontal subsurface flow constructed wetland 10, the second-level surface flow constructed wetland 11 and the third-level vertical flow constructed wetland 12 in the combined constructed wetland module They are 0.8m, 0.6m and 0.8m respectively; the aquatic plants are windmill grass, canna and Zaili flower.
  • the AOABR module is installed before the combined constructed wetland module, which can accelerate the degradation of organic matter in the sewage, greatly reduce the content of organic matter entering the constructed wetland, thereby reducing the risk of clogging of the constructed wetland, and prolonging the life of the constructed wetland; after passing the AOABR module,
  • the organic matter content entering the combined constructed wetland module is very low, which provides conditions for the growth of autotrophic anammox bacteria; in addition, aeration also increases the dissolved oxygen content of the constructed wetland water, and promotes the first level of subsurface flow in the upper layer of the constructed wetland.
  • the ammonia nitrogen is converted into nitrate nitrogen and nitrite nitrogen, thereby providing conditions for enhancing anaerobic ammonia oxidation denitrification.
  • the effluent of the AOABR module creates anoxic zones, aerobic, anoxic and anaerobic zones for the first-level saturated constructed wetland.
  • Nitric acid is produced by the aerobic nitrification reaction and the anaerobic ammonia oxidation reaction in the anaerobic zone.
  • Salt provides electron acceptors for phosphorus accumulating bacteria in the hypoxic zone, thereby strengthening the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage by the water treatment system.
  • a method for treating sewage using the above sewage treatment system includes the following steps:
  • the method of sewage entering the AOABR module is batch inflow, once a day; the inflow method of the water distribution module is batch inflow; the inflow method of the combined constructed wetland module is continuous inflow, and the influent load is 0.1m/ d;
  • the aeration mode of the aerobic tank 4 in the AOABR module is intermittent aeration, the aeration time is 2h per day, the dissolved oxygen concentration in the effluent of the AOABR module is controlled at 1.6 ⁇ 2.8mg/L, and the COD Cr concentration is controlled at 25 ⁇ 50mg/ L.
  • the load of total nitrogen in the raw sewage is 20-40mg/L, total phosphorus is 2.5-3.5mg/L, COD Cr is 150-400mg/L, total nitrogen removal rate is as high as 91.5%, ammonia nitrogen removal rate is as high as 98.2%, total phosphorus The removal rate is as high as 92.7%, and the COD Cr removal rate is as high as 98%.
  • a sewage treatment system that strengthens the anaerobic ammonia oxidation and denitrification and phosphorus removal of domestic sewage, as shown in Figures 1 and 3, includes a filter module, an AOABR module, a water distribution module and a combined constructed wetland module connected in sequence;
  • the filter module passes diving Pump 2 is connected to the AOABR module, the water distribution module is connected to the combined constructed wetland module through the lift pump 9;
  • the filter module is provided with water inlets, and the combined constructed wetland module is provided with water outlets;
  • the filter module is the grid sedimentation tank 1;
  • the AOABR module includes sequentially connected Anaerobic tank 3, aerobic tank 4, and anoxic tank 5;
  • the water distribution module is water collection tank 8;
  • the combined constructed wetland module is composed of multi-level constructed wetlands, which are arranged in a ladder structure from high to low according to the direction of water flow;
  • Multi-level constructed wetlands are the first-level surface flow constructed wetlands 11, the second
  • the particle size of the large gravel is 2 to 3 cm, and the particle size of the small gravel is 0.5 to 1 cm.
  • the surfaces of the constructed wetlands at all levels of the multi-level constructed wetlands are equipped with aquatic plants; vertical flow
  • the thickness of the gravel in the constructed wetland 12 and the horizontal subsurface flow constructed wetland 10 is 60cm, of which the thickness of the large gravel is 10cm and the thickness of the small gravel is 50cm;
  • the thickness of the gravel in the surface flow constructed wetland 11 is 30cm, of which the thickness of the large gravel
  • the thickness of the small gravel is 10cm, and the thickness of the small gravel is 20cm; both the anaerobic tank 3 and the aerobic tank 4 are equipped with polyethylene film-mounted packing 6;
  • the aerobic tank 4 is equipped with aeration pump 7; aeration pump 7, submersible pump 2
  • Both the lifting pump 9 and the lifting pump 9 are controlled by the automatic electronic control system 13; the top of the water inlet of the sump 8 is
  • the filter module is a grid sedimentation tank 1 with a pore size of 5mm; the length of the anaerobic tank 3 is 1m, the length of the aerobic tank 4 is 1.7m, the length of the anoxic tank 5 is 0.8m, and the width is 1.26m. , The height is 2.5m; the water capacity of the sump 8 is 2m 3 ; the length, width and height of the first-level surface flow constructed wetland 11, the second-level vertical flow constructed wetland 12 and the third-level horizontal subsurface flow constructed wetland 10 in the combined constructed wetland module They are 0.8m, 0.6m and 0.8m respectively; the aquatic plants are windmill grass, canna and Zaili flower.
  • the AOABR module is installed before the combined constructed wetland module, which can accelerate the degradation of organic matter in the sewage, greatly reduce the content of organic matter entering the constructed wetland, thereby reducing the risk of clogging of the constructed wetland, and prolonging the life of the constructed wetland; after passing the AOABR module,
  • the content of organic matter entering the combined constructed wetland module is very low, which provides conditions for the growth of autotrophic anammox bacteria; in addition, aeration also increases the dissolved oxygen content of the constructed wetland’s influent water and promotes the first-level surface flow in the upper layer of the constructed wetland.
  • the ammonia nitrogen is converted into nitrate nitrogen and nitrite nitrogen, thereby providing conditions for enhancing anaerobic ammonia oxidation denitrification.
  • the effluent of the AOABR module creates anoxic zones, aerobic, anoxic and anaerobic zones for the first-level saturated constructed wetland.
  • Nitric acid is produced by the aerobic nitrification reaction and the anaerobic ammonia oxidation reaction in the anaerobic zone.
  • Salt provides electron acceptors for phosphorus accumulating bacteria in the hypoxic zone, thereby strengthening the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage by the water treatment system.
  • a method for treating sewage using the above sewage treatment system includes the following steps:
  • the method of sewage entering the AOABR module is batch inflow, once a day; the inflow method of the water distribution module is batch inflow; the inflow method of the combined constructed wetland module is continuous inflow, and the influent load is 0.1m/ d;
  • the aeration mode of the aerobic tank 4 in the AOABR module is intermittent aeration, and the aeration time is 4 hours per day.
  • the concentration of dissolved oxygen in the effluent of the AOABR module is controlled at 1.4 ⁇ 4mg/L, and the concentration of COD Cr is controlled at 25 ⁇ 50mg/L. .
  • the load of total nitrogen in raw sewage is 20-40mg/L, total phosphorus is 2.5-3.5mg/L, COD Cr is 150-400mg/L, total nitrogen removal rate is as high as 92.9%, ammonia nitrogen removal rate is as high as 99.3%, total phosphorus The removal rate is as high as 85.7%, and the COD Cr removal rate is as high as 95.6%.
  • the relative abundance of nitrification and anammox functional genes in the first-level saturated constructed wetland is higher or significantly higher than without the AOABR module, but the denitrification functional genes are relatively
  • the abundance is opposite, which further illustrates that the sewage treatment system of the present invention can enhance the denitrification of domestic sewage by improving the anaerobic ammonia oxidation.
  • Example 1 and Example 2 showed no blockage after one and a half years of operation.

Abstract

Disclosed is a sewage treatment system for strengthening anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage, the system comprising a filtering module, an anaerobic-aerobic-anoxic baffled reactor AOABR module, a water distribution module and a combined constructed wetland module, which are connected in succession. By arranging the AOABR module at the front end of the combined constructed wetland module, an organic load entering the constructed wetland can be reduced, the risk of the wetland becoming blocked is reduced, the abundance of anaerobic ammonia oxidation autotrophic bacteria in a first-stage saturated flow wetland is increased, an ammonia nitrogen substrate required for an anaerobic ammonia oxidation reaction is retained and micro-aerobic conditions are created on on the surface layer of the wetland to form a nitrite nitrogen substrate. Under the condition of a low-organic-matter load, the mutual benefit and symbiosis of denitrifying and dephosphorizing bacteria and anaerobic ammonium oxidation bacteria in a saturated flow wetland are also facilitated, the coupled synergistic removal of nitrogen and phosphorus is realized under the conditions of low energy consumption and carbon limitation, and by combining multi-stage saturated and unsaturated flow wetlands, the total nitrogen removal efficiency and the total phosphorus removal efficiency can be up to 90% or above.

Description

一种强化生活污水厌氧氨氧化脱氮同时除磷的污水处理系统及方法Sewage treatment system and method for strengthening anaerobic ammonia oxidation denitrification and simultaneous dephosphorization of domestic sewage 技术领域Technical field
本发明涉及水处理技术领域,具体地涉及一种强化生活污水厌氧氨氧化脱氮同时除磷的污水处理系统及方法。The present invention relates to the technical field of water treatment, in particular to a sewage treatment system and method for enhancing anaerobic ammonia oxidation and denitrification and simultaneous dephosphorization of domestic sewage.
背景技术Background technique
人工湿地是一种经济、环保和生态友好的水处理技术,主要包括垂直流人工湿地、水平潜流人工湿地和表面流人工湿地三种类型。其通过基质、植物和微生物的协同作用对污水进行处理,不仅可以有效的净化水质,而且可以为野生动物提供栖息地。另外,与传统污水处理系统相比,人工湿地构造简单、易维护,并且运行成本低,所以被广泛应用于多类污水的处理中。Constructed wetland is an economical, environmentally friendly and eco-friendly water treatment technology, which mainly includes three types: vertical flow constructed wetland, horizontal subsurface flow constructed wetland and surface flow constructed wetland. It treats sewage through the synergy of substrates, plants and microorganisms, which can not only effectively purify water quality, but also provide habitats for wild animals. In addition, compared with traditional sewage treatment systems, constructed wetlands are simple in structure, easy to maintain, and low in operating costs, so they are widely used in the treatment of multiple types of sewage.
目前,人们普遍利用组合人工湿地存在不同的好氧厌氧环境通过硝化反硝化作用提高脱氮效果,但是,人工湿地存在易堵塞的缺点,为了解决这个问题,通常会在人工湿地前端加好氧或者厌氧生物处理系统,大大削减进入人工湿地中的有机物含量,从而降低人工湿地堵塞的风险。然而,有机碳源的减少导致后续人工湿地反硝化脱氮受到很大的限制,人们通常会选择外源性有机碳源的投加来提高脱氮效果,但势必增加人工湿地的运维成本。At present, people generally use the different aerobic and anaerobic environments in the combined constructed wetland to improve the denitrification effect through nitrification and denitrification. However, the constructed wetland has the disadvantage of easy clogging. In order to solve this problem, aerobic is usually added at the front end of the constructed wetland. Or anaerobic biological treatment system, which greatly reduces the content of organic matter entering the constructed wetland, thereby reducing the risk of clogging of the constructed wetland. However, the reduction of organic carbon sources has led to great restrictions on the subsequent denitrification and denitrification of constructed wetlands. People usually choose the addition of exogenous organic carbon sources to improve the denitrification effect, but it will inevitably increase the operation and maintenance costs of constructed wetlands.
另外,人工湿地中磷的去除则更加困难,其中主要依赖于基质吸附,其次是植物和部分微生物的吸收同化。然而,人工湿地基质经过长时间运行后,会出现吸附饱和的现象。对此,人们通常会采取一些措施(例如更换填料)来重新恢复人工湿地的除磷性能,但这样就会破坏人工湿地原有的生态系统结构,也会增加人工湿地的运行成本。In addition, the removal of phosphorus in constructed wetlands is more difficult, which mainly relies on substrate adsorption, followed by the absorption and assimilation of plants and some microorganisms. However, after long-term operation of the constructed wetland substrate, adsorption saturation will occur. In this regard, people usually take some measures (such as replacing fillers) to restore the phosphorus removal performance of the constructed wetland, but this will destroy the original ecosystem structure of the constructed wetland and increase the operating cost of the constructed wetland.
因此,针对目前存在的问题,有必要开发一种不依赖于有机碳源限制的新型脱氮污水处理系统,同时解决人工湿地易堵塞和除磷效能不稳定的问题。Therefore, in view of the existing problems, it is necessary to develop a new type of denitrification sewage treatment system that does not rely on the restriction of organic carbon sources, while solving the problems of easy clogging of constructed wetlands and unstable phosphorus removal efficiency.
发明内容Summary of the invention
本发明的目的是为了克服现有技术的上述不足,提供一种强化生活污水厌氧氨化脱氮同时除磷的污水处理系统,本发明能够显著提高脱氮除磷效果,并有效预防湿地堵塞,增加湿地的使用寿命。The purpose of the present invention is to overcome the above-mentioned shortcomings of the prior art and provide a sewage treatment system that enhances the anaerobic amination and denitrification of domestic sewage while simultaneously dephosphorizing. The present invention can significantly improve the effect of denitrification and phosphorus removal and effectively prevent wetland clogging. , Increase the service life of wetlands.
本发明的另一目的在于提供一种利用上述污水处理系统处理污水的方法。Another object of the present invention is to provide a method for treating sewage using the above sewage treatment system.
为了实现上述目的,本发明是通过以下方案予以实现的:In order to achieve the above objectives, the present invention is achieved through the following solutions:
一种强化生活污水厌氧氨氧化脱氮同时除磷的污水处理系统,包括顺次连接的过滤模块、厌氧-好氧-缺氧折流式反应器(Anaerobic-Oxic-Anoxic Baffled Reactor,AOABRR)模块、配水模块和组合人工湿地模块;所述过滤模块通过潜水泵与AOABR模块相连,配水模块通过提升泵与组合人工湿地模块相连;所述过滤模块设置进水口,所述组合人工湿地模块设置出水口;所述过滤模块为格栅沉淀池;所述AOABR模块包括顺次相连的厌氧池、好氧池和缺氧池;所述配水模块为集水池;所述组合人工湿地模块由多级人工湿地构成,多级人工湿地按水流方向从高至低依次排列呈阶梯结构。A sewage treatment system that strengthens the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage, including successively connected filter modules, Anaerobic-Aerobic-Anoxic Baffled Reactor (AOABRR) ) Module, water distribution module and combined constructed wetland module; the filter module is connected to the AOABR module through a submersible pump, and the water distribution module is connected to the combined constructed wetland module through a lift pump; the filter module is provided with a water inlet, and the combined constructed wetland module is provided The water outlet; the filter module is a grid sedimentation tank; the AOABR module includes an anaerobic tank, an aerobic tank and an anoxic tank connected in sequence; the water distribution module is a collection tank; the combined constructed wetland module consists of multiple It is composed of three-level constructed wetlands, and the multi-level constructed wetlands are arranged in a ladder structure from high to low according to the direction of water flow.
其中,过滤模块为孔径大小为5mm的格栅沉淀池,用于过滤污水中的大块杂物;配水模块,与组合人工湿地模块相连,用于存储AOABR模块中的污水,方便以不同的进水负荷将污水泵入组合人工湿地模块中。Among them, the filter module is a grid sedimentation tank with a pore size of 5mm, which is used to filter large debris in the sewage; the water distribution module is connected to the combined constructed wetland module and is used to store the sewage in the AOABR module to facilitate different inlets. The water load pumps sewage into the combined constructed wetland module.
本发明所述污水处理系统,在组合人工湿地模块前设置AOABR模块,大大减少进入人工湿地中的有机物负荷,有效降低人工湿地堵塞的风险。另外,污水经过AOABR模块后,不仅减少了进入组合人工湿中营养盐的进水负荷,而且还增加了组合人工湿地进水的溶解氧含量。其中,第一级饱和流湿地进水有机物负荷的减少大大提高了自养厌氧氨氧化菌的丰度,且进水溶解氧含量的增加也为第一级饱和流湿地上层中的氨氮转化为硝酸态氮和亚硝酸态氮提供条件,从而大大促进了第一级饱和流湿地下层厌氧氨氧化脱氮,形成了短程硝化反硝化和厌氧氨氧化的同步脱氮;与此同时,饱和流湿地中存在好氧、缺氧和厌氧区,其中好氧区中的硝化反应和厌氧区的厌氧氨氧化反应产生了硝酸盐,为低碳条件下具有竞争优势的反硝化聚磷菌在缺氧区中发生吸磷反应提供了电子受体,从而强化了水处理系统对生活污水的厌氧氨氧化脱氮和除磷。In the sewage treatment system of the present invention, an AOABR module is installed before the combined constructed wetland module, which greatly reduces the load of organic matter entering the constructed wetland and effectively reduces the risk of clogging of the constructed wetland. In addition, after the sewage passes through the AOABR module, it not only reduces the nutrient influent load into the combined constructed wetland, but also increases the dissolved oxygen content of the combined constructed wetland influent. Among them, the reduction of the organic matter load of the first-stage saturated flow wetland greatly increases the abundance of autotrophic anammox bacteria, and the increase in the dissolved oxygen content of the influent is also due to the conversion of ammonia nitrogen in the upper layer of the first-stage saturated flow wetland into Nitrate nitrogen and nitrite nitrogen provide conditions, which greatly promotes the first-stage saturated wet subterranean anaerobic ammonia oxidation denitrification, forming a simultaneous denitrification of short-cut nitrification and denitrification and anaerobic ammonia oxidation; at the same time, saturation There are aerobic, anoxic and anaerobic zones in the wetland. The nitrification reaction in the aerobic zone and the anaerobic ammonia oxidation reaction in the anaerobic zone produce nitrate, which is a competitive denitrifying phosphorous under low-carbon conditions. The phosphorus absorption reaction of bacteria in the hypoxic zone provides electron acceptors, thereby enhancing the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage by the water treatment system.
本发明提供的强化生活污水厌氧氨氧化脱氮同时除磷的污水处理系统能够去除污水中98%的COD Cr,91.5%的总氮,98.2%的氨氮和92.7%的总磷。其中氨氮和COD Cr的出水浓度可以达到地表水环境质量标准(GB3838-2002)的I~II类水,总磷可以达到VI~V类,总氮可达到V~劣V类。 The sewage treatment system for enhanced anaerobic ammonia oxidation and dephosphorization of domestic sewage provided by the present invention can remove 98% of COD Cr , 91.5% of total nitrogen, 98.2% of ammonia nitrogen and 92.7% of total phosphorus in sewage. Among them, the effluent concentration of ammonia nitrogen and COD Cr can reach the surface water environmental quality standard (GB3838-2002) I to II water, the total phosphorus can reach VI to V, and the total nitrogen can reach V to inferior V.
优选地,所述厌氧池、好氧池和缺氧池的进水口均设置在底端,出水口均设置在顶端。其中,所述好氧池的进水口与厌氧池的出水口相连接,其出水后与缺氧池的进水口相连接;即所述厌氧池、好氧池和缺氧池的水流模式为底进表出的折流式。Preferably, the water inlets of the anaerobic tank, aerobic tank and anoxic tank are all set at the bottom end, and the water outlets are all set at the top end. Wherein, the water inlet of the aerobic tank is connected with the water outlet of the anaerobic tank, and after the water is discharged, it is connected with the water inlet of the anoxic tank; that is, the water flow patterns of the anaerobic tank, aerobic tank, and anoxic tank It is a zigzag style with bottom in and out.
优选地,所述厌氧池和好氧池内均设有聚乙烯填料,用于微生物的附着生长。Preferably, both the anaerobic tank and the aerobic tank are provided with polyethylene fillers for the attachment and growth of microorganisms.
优选地,所述好氧池内设有曝气泵,用于控制好氧池中有机物含量和人工湿地的进水水质。其中,所述好氧池的曝气量为0.3~0.35m 3/h,曝气时间为2~4h/d,溶解氧浓度控 制在2~5mg/L,非曝气阶段硝态氮得以去除。 Preferably, an aeration pump is provided in the aerobic tank to control the content of organic matter in the aerobic tank and the water quality of the constructed wetland. Wherein, the aeration volume of the aerobic tank is 0.3~0.35m 3 /h, the aeration time is 2~4h/d, the dissolved oxygen concentration is controlled at 2~5mg/L, and the nitrate nitrogen can be removed in the non-aeration stage .
所述AOABR的进水模式为批次进水,缺氧池在非进水阶段溶解氧控制在0.5~1.5mg/L,硝态氮可进一步去除,好氧池富氧污水通过折流式进入缺氧池时,缺氧池溶解氧控制在1.5~4mg/L,随后以氨氮为主的含氧污水通过折流式进入配水模块。The water inlet mode of the AOABR is batch water inlet, the dissolved oxygen in the anoxic tank is controlled at 0.5-1.5 mg/L in the non-water inlet stage, the nitrate nitrogen can be further removed, and the oxygen-enriched wastewater from the aerobic tank enters through the baffle type In the anoxic tank, the dissolved oxygen in the anoxic tank is controlled at 1.5-4mg/L, and then the oxygenated sewage mainly containing ammonia nitrogen enters the water distribution module through the baffle.
优选地,所述多级人工湿地为三级或三级以上的人工湿地。Preferably, the multi-level constructed wetland is a three-level or above constructed wetland.
更优选地,所述多级人工湿地为三级人工湿地。More preferably, the multi-level constructed wetland is a three-level constructed wetland.
优选地,所述多级人工湿地的第一级为饱和流湿地;其他级为饱和流或非饱和流湿地。Preferably, the first stage of the multi-stage constructed wetland is a saturated flow wetland; the other stages are saturated flow or unsaturated flow wetlands.
更优选地,所述饱和流湿地为水平潜流人工湿地或表面流人工湿地;所述非饱和流湿地为垂直流人工湿地。More preferably, the saturated flow wetland is a horizontal subsurface flow constructed wetland or a surface flow constructed wetland; the unsaturated flow wetland is a vertical flow constructed wetland.
即,所述多级人工湿地为由高到低顺次连接的一级水平潜流人工湿地、二级表面流人工湿地和三级垂直流人工湿地;或所述多级人工湿地为由高到低顺次连接的一级表面流人工湿地、二级垂直流人工湿地和三级水平潜流人工湿地。That is, the multi-level constructed wetland is a first-level horizontal subsurface flow constructed wetland, a second-level surface flow constructed wetland, and a third-level vertical flow constructed wetland that are sequentially connected from high to low; or the multi-level constructed wetland is from high to low. The first-level surface flow constructed wetland, the second-level vertical flow constructed wetland and the third-level horizontal subsurface flow constructed wetland are sequentially connected.
优选地,所述多级人工湿地的各级人工湿地中由下到上依次设有大砾石和小砾石;其中,所述大砾石的粒径为2~3cm,小砾石的粒径为0.5~1cm;所述多级人工湿地的各级人工湿地表面均设有水生植物。Preferably, each level of the multi-level constructed wetland is provided with large gravel and small gravel in sequence from bottom to top; wherein the particle size of the large gravel is 2 to 3 cm, and the particle size of the small gravel is 0.5 to 0.5 cm. 1cm; each level of the multi-level constructed wetland is provided with aquatic plants on the surface of the constructed wetland.
更优选地,所述水生植物为风车草、美人蕉和再力花。More preferably, the aquatic plants are windmill grass, canna and Zai Lihua.
优选地,所述垂直流人工湿地和水平潜流人工湿地中砾石的厚度为60cm,其中,大砾石的厚度为10cm,小砾石的厚度为50cm;所述表面流人工湿地中砾石的厚度为30cm,其中,大砾石的厚度为10cm,小砾石的厚度为20cm。Preferably, the thickness of the gravel in the vertical flow constructed wetland and the horizontal subsurface flow constructed wetland is 60cm, wherein the thickness of the large gravel is 10cm and the thickness of the small gravel is 50cm; the thickness of the gravel in the surface flow constructed wetland is 30cm, Among them, the thickness of the large gravel is 10cm, and the thickness of the small gravel is 20cm.
优选地,所述曝气泵、潜水泵和提升泵均通过自动电子控制系统进行控制。Preferably, the aeration pump, submersible pump and lifting pump are all controlled by an automatic electronic control system.
优选地,所述集水池的进水口顶端与缺氧池顶端的出水口相连。Preferably, the top of the water inlet of the sump is connected to the top of the water outlet of the anoxic tank.
优选地,所述组合人工湿地模块的进水端与集水池底部的出水端相连。Preferably, the water inlet end of the combined constructed wetland module is connected to the water outlet end at the bottom of the water collection tank.
本发明还请求保护一种利用上述污水处理系统处理污水的方法,包括以下步骤:The present invention also claims a method for treating sewage using the above sewage treatment system, which includes the following steps:
污水由进水口进入过滤模块,经过格栅过滤和初步沉淀作用,通过潜水泵泵入AOABR模块,并经AOABR处理后流向配水模块,再通过提升泵连续泵入组合人工湿地模块,最后由出水口流出。Sewage enters the filter module from the water inlet, passes through the grid filter and preliminary sedimentation, is pumped into the AOABR module through the submersible pump, and flows to the water distribution module after AOABR treatment, and then continuously pumped into the combined constructed wetland module through the lift pump, and finally from the water outlet Outflow.
所述污水为生活污水,所述污水的总氮负荷优选为10~50mg/L,总磷负荷优选为1~3mg/L,COD Cr负荷优选为100~400mg/L。污水经过格栅沉淀后批次泵入厌氧池中,然后通过溢流的方式依次进入好氧池、缺氧池和集水池中。 The sewage is domestic sewage, the total nitrogen load of the sewage is preferably 10-50 mg/L, the total phosphorus load is preferably 1-3 mg/L, and the COD Cr load is preferably 100-400 mg/L. Sewage is pumped into the anaerobic tank in batches after being precipitated by the grid, and then enters the aerobic tank, anoxic tank and the collecting tank in turn through overflow.
优选地,污水进入AOABR模块的方式为批次进水,每天1次;所述配水模块的进水 方式为批次进水;所述组合人工湿地模块的进水方式为连续进水,进水负荷为0.1~0.5m/d。Preferably, the way for sewage to enter the AOABR module is batch inflow, once a day; the inflow mode of the water distribution module is batch inflow; the inflow mode of the combined constructed wetland module is continuous inflow, inflow The load is 0.1~0.5m/d.
优选地,所述好氧池中的曝气方式为间歇性曝气,曝气量为0.3~0.35m 3/h,曝气时间为每天2~4h;所述好氧池溶解氧浓度保持在2~5mg/L,非曝气阶段硝态氮得以去除。 Preferably, the aeration mode in the aerobic tank is intermittent aeration, the aeration volume is 0.3 to 0.35 m 3 /h, and the aeration time is 2 to 4 hours per day; the dissolved oxygen concentration in the aerobic tank is maintained at 2~5mg/L, nitrate nitrogen can be removed in the non-aeration stage.
更优选地,所述曝气时间为每天2h。More preferably, the aeration time is 2 hours per day.
优选地,所述缺氧池在非进水阶段溶解氧控制在0.5~1.5mg/L,硝态氮可进一步去除,好氧池富氧污水通过折流式进入缺氧池,缺氧池溶解氧可控制在1.5~4mg/L,随后以氨氮为主的含氧污水通过折流式进入配水模块。Preferably, the dissolved oxygen in the anoxic tank is controlled at 0.5-1.5 mg/L during the non-inflow phase, nitrate nitrogen can be further removed, and the oxygen-enriched sewage of the aerobic tank enters the anoxic tank through a baffle, and the anoxic tank is dissolved The oxygen can be controlled at 1.5-4mg/L, and then the oxygenated sewage mainly containing ammonia nitrogen enters the water distribution module through the baffle type.
本发明通过利用上述污水处理系统,污水进入AOABR模块经过曝气处理后,大大减少进入组合人工湿地中有机物的含量,有效降低人工湿地堵塞的风险;并且经过AOABR模块后增加了组合人工湿地模块的进水溶解氧含量,促进第一级水平流人工湿地或表面流人工湿地的硝化作用,从而为不依赖于有机碳源脱氮的厌氧氨氧化反应提供底物。The present invention uses the above-mentioned sewage treatment system. After the sewage enters the AOABR module and undergoes aeration treatment, the content of organic matter in the combined constructed wetland is greatly reduced, and the risk of clogging of the constructed wetland is effectively reduced; and the combined constructed wetland module is increased after the AOABR module. The dissolved oxygen content of the influent promotes the nitrification of the first-level horizontal flow constructed wetland or the surface flow constructed wetland, thereby providing a substrate for the anaerobic ammonia oxidation reaction that does not depend on the denitrification of organic carbon sources.
与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:
(1)在不添加外来有机碳源的情况下,本发明的污水处理系统仍具有较高的脱氮除磷效果。(1) Without the addition of external organic carbon sources, the sewage treatment system of the present invention still has a high denitrification and phosphorus removal effect.
(2)本发明能够有效的减少进入人工湿地中有机物的含量,大大降低了人工湿地堵塞的风险,延长了人工湿地的使用寿命。(2) The present invention can effectively reduce the content of organic matter entering the constructed wetland, greatly reduce the risk of clogging of the constructed wetland, and prolong the service life of the constructed wetland.
(3)本发明能够有效的减少进入人工湿地的污染负荷,大大减少了人工湿地的占地面积,解决了利用人工湿地处理污水占地面积大的缺点。(3) The present invention can effectively reduce the pollution load entering the constructed wetland, greatly reduce the area occupied by the constructed wetland, and solve the disadvantage of using the constructed wetland to treat sewage with a large area.
附图说明Description of the drawings
图1为本发明污水处理系统的结构示意图。Figure 1 is a schematic diagram of the structure of the sewage treatment system of the present invention.
图2为实施例1的污水处理系统结构示意图。FIG. 2 is a schematic diagram of the structure of the sewage treatment system of Embodiment 1. FIG.
图3为实施例2的污水处理系统结构示意图。Fig. 3 is a schematic diagram of the structure of the sewage treatment system of the second embodiment.
图4为本发明实施例中有无AOABR模块时第一级水平潜流人工湿地(A)和第一级表面流人工湿地(B)中氮转化功能微生物相对丰度的变化情况。Fig. 4 shows changes in the relative abundance of nitrogen conversion function microorganisms in the first-level horizontal subsurface flow constructed wetland (A) and the first-level surface flow constructed wetland (B) with or without the AOABR module in the embodiment of the present invention.
附图标记:1-格栅沉淀池;2-潜水泵;3-厌氧池;4-好氧池;5-缺氧池;6-聚乙烯挂膜填料;7-曝气泵;8-集水池;9-提升泵;10-水平潜流人工湿地;11-表面流人工湿地;12-垂直流人工湿地;13-自动电子控制系统。Reference signs: 1-grid sedimentation tank; 2-submersible pump; 3-anaerobic tank; 4-aerobic tank; 5-anoxic tank; 6-polyethylene film-coated packing; 7-aeration pump; 8- Catchment pool; 9-lift pump; 10-horizontal subsurface flow constructed wetland; 11-surface flow constructed wetland; 12-vertical flow constructed wetland; 13-automatic electronic control system.
具体实施方式Detailed ways
下面结合说明书附图及具体实施例对本发明作出进一步地详细阐述,所述实施例只用 于解释本发明,并非用于限定本发明的范围。下述实施例中所使用的试验方法如无特殊说明,均为常规方法;所使用的材料、试剂等,如无特殊说明,为可从商业途径得到的试剂和材料。The present invention will be further described in detail below in conjunction with the accompanying drawings of the specification and specific embodiments. The embodiments are only used to explain the present invention and are not used to limit the scope of the present invention. The test methods used in the following examples are conventional methods unless otherwise specified; the materials and reagents used, unless otherwise specified, are commercially available reagents and materials.
实施例1Example 1
一种强化生活污水厌氧氨氧化脱氮同时除磷的污水处理系统,如图1、2所示,包括顺次连接的过滤模块、AOABR模块、配水模块和组合人工湿地模块;过滤模块通过潜水泵2与AOABR模块相连,配水模块通过提升泵9与组合人工湿地模块相连;过滤模块设置进水口,组合人工湿地模块设置出水口;过滤模块为格栅沉淀池1;AOABR模块包括顺次相连的厌氧池3、好氧池4和缺氧池5;配水模块为集水池8;组合人工湿地模块由多级人工湿地构成,多级人工湿地按水流方向从高至低依次排列呈阶梯结构;多级人工湿地为由高到低顺次连接的一级水平潜流人工湿地10(饱和流湿地)、二级表面流人工湿地11(饱和流湿地)和三级垂直流人工湿地12(非饱和流湿地);多级人工湿地的各级人工湿地中由下到上依次设有大砾石和小砾石,其中,大砾石的粒径为2~3cm,小砾石的粒径为0.5~1cm;多级人工湿地的各级人工湿地表面均设有水生植物;垂直流人工湿地12和水平潜流人工湿地10中砾石的厚度为60cm,其中,大砾石的厚度为10cm,小砾石的厚度为50cm;表面流人工湿地11中砾石的厚度为30cm,其中,大砾石的厚度为10cm,小砾石的厚度为20cm;厌氧池3和好氧池4中均设有聚乙烯挂膜填料6;好氧池4中设有曝气泵7;曝气泵7、潜水泵2和提升泵9均通过自动电子控制系统13进行控制;集水池8的进水口顶端与缺氧池5顶端的出水口相连;组合人工湿地模块的进水端与集水池8底部的出水端相连。A sewage treatment system that strengthens the anaerobic ammonia oxidation and denitrification and dephosphorization of domestic sewage, as shown in Figures 1 and 2, includes a filter module, an AOABR module, a water distribution module, and a combined constructed wetland module connected in sequence; the filter module passes diving Pump 2 is connected to the AOABR module, the water distribution module is connected to the combined constructed wetland module through the lift pump 9; the filter module is provided with water inlets, and the combined constructed wetland module is provided with water outlets; the filter module is the grid sedimentation tank 1; the AOABR module includes sequentially connected Anaerobic tank 3, aerobic tank 4, and anoxic tank 5; the water distribution module is water collection tank 8; the combined constructed wetland module is composed of multi-level constructed wetlands, which are arranged in a ladder structure from high to low according to the direction of water flow; Multi-level constructed wetlands are the first-level horizontal subsurface flow constructed wetland 10 (saturated flow wetland), the second-level surface flow constructed wetland 11 (saturated flow wetland), and the third-level vertical flow constructed wetland 12 (unsaturated flow wetland) connected in sequence from high to low. Wetlands); Multi-level constructed wetlands consist of large gravels and small gravels in order from bottom to top. Among them, the particle size of the large gravel is 2~3cm, and the particle size of the small gravel is 0.5~1cm; There are aquatic plants on the surface of each level of constructed wetland in constructed wetlands; the thickness of gravel in vertical flow constructed wetland 12 and horizontal subsurface flow constructed wetland 10 is 60cm, among which the thickness of large gravel is 10cm, and the thickness of small gravel is 50cm; surface flow The thickness of gravel in constructed wetland 11 is 30cm, among which, the thickness of large gravel is 10cm, and the thickness of small gravel is 20cm; both anaerobic tank 3 and aerobic tank 4 are equipped with polyethylene film-coated packing 6; aerobic tank 4 There is an aeration pump 7; the aeration pump 7, the submersible pump 2 and the lifting pump 9 are all controlled by the automatic electronic control system 13; the top of the water inlet of the collection tank 8 is connected with the outlet of the top of the hypoxic tank 5; combined manual The water inlet end of the wetland module is connected with the water outlet end at the bottom of the collecting basin 8.
其中,过滤模块为孔径大小为5mm的格栅沉淀池1;厌氧池3的长度为1m、好氧池4的长度为1.7m、缺氧池5的长度为0.8m,宽均为1.26m,高均为2.5m;集水池8水容量为2m 3;组合人工湿地模块中一级水平潜流人工湿地10、二级表面流人工湿地11和三级垂直流人工湿地12的长、宽和高分别为0.8m、0.6m和0.8m;水生植物为风车草、美人蕉和再力花。 Among them, the filter module is a grid sedimentation tank 1 with a pore size of 5mm; the length of the anaerobic tank 3 is 1m, the length of the aerobic tank 4 is 1.7m, the length of the anoxic tank 5 is 0.8m, and the width is 1.26m. , The height is 2.5m; the water capacity of the sump 8 is 2m 3 ; the length, width and height of the first-level horizontal subsurface flow constructed wetland 10, the second-level surface flow constructed wetland 11 and the third-level vertical flow constructed wetland 12 in the combined constructed wetland module They are 0.8m, 0.6m and 0.8m respectively; the aquatic plants are windmill grass, canna and Zaili flower.
本实施例在组合人工湿地模块前设置AOABR模块,能够加快污水中有机物的降解,大大降低进入人工湿地中有机物的含量,进而减少人工湿地堵塞的风险,延长人工湿地的寿命;通过AOABR模块后,进入组合人工湿地模块的有机物含量非常低,为自养厌氧氨氧化细菌的生长提供条件;另外,曝气还增加了人工湿地进水的溶解氧含量,促进第一级水平潜流人工湿地上层中的氨氮转化为硝酸盐氮和亚硝酸盐氮,从而为增强厌氧氨氧化脱 氮提供条件。与此同时,AOABR模块的出水为一级饱和人工湿地创造了缺氧区域,好氧、缺氧和厌氧区,其中好氧中的硝化反应和厌氧区的厌氧氨氧化反应产生了硝酸盐,为缺氧区的聚磷菌吸磷提供电子受体,从而强化了水处理系统对生活污水的厌氧氨氧化脱氮和除磷。In this embodiment, the AOABR module is installed before the combined constructed wetland module, which can accelerate the degradation of organic matter in the sewage, greatly reduce the content of organic matter entering the constructed wetland, thereby reducing the risk of clogging of the constructed wetland, and prolonging the life of the constructed wetland; after passing the AOABR module, The organic matter content entering the combined constructed wetland module is very low, which provides conditions for the growth of autotrophic anammox bacteria; in addition, aeration also increases the dissolved oxygen content of the constructed wetland water, and promotes the first level of subsurface flow in the upper layer of the constructed wetland. The ammonia nitrogen is converted into nitrate nitrogen and nitrite nitrogen, thereby providing conditions for enhancing anaerobic ammonia oxidation denitrification. At the same time, the effluent of the AOABR module creates anoxic zones, aerobic, anoxic and anaerobic zones for the first-level saturated constructed wetland. Nitric acid is produced by the aerobic nitrification reaction and the anaerobic ammonia oxidation reaction in the anaerobic zone. Salt provides electron acceptors for phosphorus accumulating bacteria in the hypoxic zone, thereby strengthening the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage by the water treatment system.
一种利用上述污水处理系统处理污水的方法,包括以下步骤:A method for treating sewage using the above sewage treatment system includes the following steps:
污水由进水口进入过滤模块,经过格栅过滤和初步沉淀作用,通过潜水泵2泵入AOABR模块去除污染物,并经曝气处理后流向配水模块,再通过提升泵9连续泵入组合人工湿地模块,最后由出水口流出。Sewage enters the filter module from the water inlet, passes grid filtration and preliminary sedimentation, is pumped into the AOABR module through the submersible pump 2 to remove pollutants, and flows to the water distribution module after aeration treatment, and then continuously pumped into the combined constructed wetland through the lift pump 9 The module finally flows out from the water outlet.
其中,污水进入AOABR模块的方式为批次进水,每天1次;配水模块的进水方式为批次进水;组合人工湿地模块的进水方式为连续进水,进水负荷为0.1m/d;AOABR模块中好氧池4的曝气方式为间歇性曝气,曝气时间为每天2h,AOABR模块出水溶解氧浓度控制在1.6~2.8mg/L,COD Cr浓度控制在25~50mg/L。 Among them, the method of sewage entering the AOABR module is batch inflow, once a day; the inflow method of the water distribution module is batch inflow; the inflow method of the combined constructed wetland module is continuous inflow, and the influent load is 0.1m/ d; The aeration mode of the aerobic tank 4 in the AOABR module is intermittent aeration, the aeration time is 2h per day, the dissolved oxygen concentration in the effluent of the AOABR module is controlled at 1.6~2.8mg/L, and the COD Cr concentration is controlled at 25~50mg/ L.
原污水当中总氮的负荷为20~40mg/L,总磷为2.5~3.5mg/L,COD Cr为150~400mg/L,总氮去除率高达91.5%,氨氮去除率高达98.2%,总磷去除率高达92.7%,COD Cr去除率高达98%。 The load of total nitrogen in the raw sewage is 20-40mg/L, total phosphorus is 2.5-3.5mg/L, COD Cr is 150-400mg/L, total nitrogen removal rate is as high as 91.5%, ammonia nitrogen removal rate is as high as 98.2%, total phosphorus The removal rate is as high as 92.7%, and the COD Cr removal rate is as high as 98%.
实施例2Example 2
一种强化生活污水厌氧氨氧化脱氮同时除磷的污水处理系统,如图1、3所示,包括顺次连接的过滤模块、AOABR模块、配水模块和组合人工湿地模块;过滤模块通过潜水泵2与AOABR模块相连,配水模块通过提升泵9与组合人工湿地模块相连;过滤模块设置进水口,组合人工湿地模块设置出水口;过滤模块为格栅沉淀池1;AOABR模块包括顺次相连的厌氧池3、好氧池4和缺氧池5;配水模块为集水池8;组合人工湿地模块由多级人工湿地构成,多级人工湿地按水流方向从高至低依次排列呈阶梯结构;多级人工湿地为由高到低顺次连接的一级表面流人工湿地11、二级垂直流人工湿地12和三级水平潜流人工湿地10;多级人工湿地的各级人工湿地中由下到上依次设有大砾石和小砾石,其中,大砾石的粒径为2~3cm,小砾石的粒径为0.5~1cm;多级人工湿地的各级人工湿地表面均设有水生植物;垂直流人工湿地12和水平潜流人工湿地10中砾石的厚度为60cm,其中,大砾石的厚度为10cm,小砾石的厚度为50cm;表面流人工湿地11中砾石的厚度为30cm,其中,大砾石的厚度为10cm,小砾石的厚度为20cm;厌氧池3和好氧池4中均设有聚乙烯挂膜填料6;好氧池4中设有曝气泵7;曝气泵7、潜水泵2和提升泵9均通过自动电子控制系统13进行控制;集水池8的进水口顶端与缺氧池5顶端的出水口 相连;组合人工湿地模块的进水端与集水池8底部的出水端相连。A sewage treatment system that strengthens the anaerobic ammonia oxidation and denitrification and phosphorus removal of domestic sewage, as shown in Figures 1 and 3, includes a filter module, an AOABR module, a water distribution module and a combined constructed wetland module connected in sequence; the filter module passes diving Pump 2 is connected to the AOABR module, the water distribution module is connected to the combined constructed wetland module through the lift pump 9; the filter module is provided with water inlets, and the combined constructed wetland module is provided with water outlets; the filter module is the grid sedimentation tank 1; the AOABR module includes sequentially connected Anaerobic tank 3, aerobic tank 4, and anoxic tank 5; the water distribution module is water collection tank 8; the combined constructed wetland module is composed of multi-level constructed wetlands, which are arranged in a ladder structure from high to low according to the direction of water flow; Multi-level constructed wetlands are the first-level surface flow constructed wetlands 11, the second-level vertical flow constructed wetlands 12 and the third-level horizontal subsurface flow constructed wetlands 10 that are connected sequentially from high to low; There are large gravels and small gravels in sequence on the upper part. Among them, the particle size of the large gravel is 2 to 3 cm, and the particle size of the small gravel is 0.5 to 1 cm. The surfaces of the constructed wetlands at all levels of the multi-level constructed wetlands are equipped with aquatic plants; vertical flow The thickness of the gravel in the constructed wetland 12 and the horizontal subsurface flow constructed wetland 10 is 60cm, of which the thickness of the large gravel is 10cm and the thickness of the small gravel is 50cm; the thickness of the gravel in the surface flow constructed wetland 11 is 30cm, of which the thickness of the large gravel The thickness of the small gravel is 10cm, and the thickness of the small gravel is 20cm; both the anaerobic tank 3 and the aerobic tank 4 are equipped with polyethylene film-mounted packing 6; the aerobic tank 4 is equipped with aeration pump 7; aeration pump 7, submersible pump 2 Both the lifting pump 9 and the lifting pump 9 are controlled by the automatic electronic control system 13; the top of the water inlet of the sump 8 is connected with the water outlet on the top of the anoxic tank 5; the water inlet of the combined constructed wetland module is connected with the water outlet of the bottom of the sump 8.
其中,过滤模块为孔径大小为5mm的格栅沉淀池1;厌氧池3的长度为1m、好氧池4的长度为1.7m、缺氧池5的长度为0.8m,宽均为1.26m,高均为2.5m;集水池8水容量为2m 3;组合人工湿地模块中一级表面流人工湿地11、二级垂直流人工湿地12和三级水平潜流人工湿地10的长、宽和高分别为0.8m、0.6m和0.8m;水生植物为风车草、美人蕉和再力花。 Among them, the filter module is a grid sedimentation tank 1 with a pore size of 5mm; the length of the anaerobic tank 3 is 1m, the length of the aerobic tank 4 is 1.7m, the length of the anoxic tank 5 is 0.8m, and the width is 1.26m. , The height is 2.5m; the water capacity of the sump 8 is 2m 3 ; the length, width and height of the first-level surface flow constructed wetland 11, the second-level vertical flow constructed wetland 12 and the third-level horizontal subsurface flow constructed wetland 10 in the combined constructed wetland module They are 0.8m, 0.6m and 0.8m respectively; the aquatic plants are windmill grass, canna and Zaili flower.
本实施例在组合人工湿地模块前设置AOABR模块,能够加快污水中有机物的降解,大大降低进入人工湿地中有机物的含量,进而减少人工湿地堵塞的风险,延长人工湿地的寿命;通过AOABR模块后,进入组合人工湿地模块的有机物含量非常低,为自养厌氧氨氧化细菌的生长提供条件;另外,曝气还增加了人工湿地进水的溶解氧含量,促进第一级表面流人工湿地上层中的氨氮转化为硝酸盐氮和亚硝酸盐氮,从而为增强厌氧氨氧化脱氮提供条件。与此同时,AOABR模块的出水为一级饱和人工湿地创造了缺氧区域,好氧、缺氧和厌氧区,其中好氧中的硝化反应和厌氧区的厌氧氨氧化反应产生了硝酸盐,为缺氧区的聚磷菌吸磷提供电子受体,从而强化了水处理系统对生活污水的厌氧氨氧化脱氮和除磷。In this embodiment, the AOABR module is installed before the combined constructed wetland module, which can accelerate the degradation of organic matter in the sewage, greatly reduce the content of organic matter entering the constructed wetland, thereby reducing the risk of clogging of the constructed wetland, and prolonging the life of the constructed wetland; after passing the AOABR module, The content of organic matter entering the combined constructed wetland module is very low, which provides conditions for the growth of autotrophic anammox bacteria; in addition, aeration also increases the dissolved oxygen content of the constructed wetland’s influent water and promotes the first-level surface flow in the upper layer of the constructed wetland. The ammonia nitrogen is converted into nitrate nitrogen and nitrite nitrogen, thereby providing conditions for enhancing anaerobic ammonia oxidation denitrification. At the same time, the effluent of the AOABR module creates anoxic zones, aerobic, anoxic and anaerobic zones for the first-level saturated constructed wetland. Nitric acid is produced by the aerobic nitrification reaction and the anaerobic ammonia oxidation reaction in the anaerobic zone. Salt provides electron acceptors for phosphorus accumulating bacteria in the hypoxic zone, thereby strengthening the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage by the water treatment system.
一种利用上述污水处理系统处理污水的方法,包括以下步骤:A method for treating sewage using the above sewage treatment system includes the following steps:
污水由进水口进入过滤模块,经过格栅过滤和初步沉淀作用,通过潜水泵2泵入AOABR模块去除污染物,并经曝气处理后流向配水模块,再通过提升泵9连续泵入组合人工湿地模块,最后由出水口流出。Sewage enters the filter module from the water inlet, passes grid filtration and preliminary sedimentation, is pumped into the AOABR module through the submersible pump 2 to remove pollutants, and flows to the water distribution module after aeration treatment, and then continuously pumped into the combined constructed wetland through the lift pump 9 The module finally flows out from the water outlet.
其中,污水进入AOABR模块的方式为批次进水,每天1次;配水模块的进水方式为批次进水;组合人工湿地模块的进水方式为连续进水,进水负荷为0.1m/d;AOABR模块中好氧池4的曝气方式为间歇性曝气,曝气时间为每天4h,AOABR模块出水溶解氧浓度控制在1.4~4mg/L,COD Cr浓度控制在25~50mg/L。 Among them, the method of sewage entering the AOABR module is batch inflow, once a day; the inflow method of the water distribution module is batch inflow; the inflow method of the combined constructed wetland module is continuous inflow, and the influent load is 0.1m/ d; The aeration mode of the aerobic tank 4 in the AOABR module is intermittent aeration, and the aeration time is 4 hours per day. The concentration of dissolved oxygen in the effluent of the AOABR module is controlled at 1.4~4mg/L, and the concentration of COD Cr is controlled at 25~50mg/L. .
原污水当中总氮的负荷为20~40mg/L,总磷为2.5~3.5mg/L,COD Cr为150~400mg/L,总氮去除率高达92.9%,氨氮去除率高达99.3%,总磷去除率高达85.7%,COD Cr去除率高达95.6%。 The load of total nitrogen in raw sewage is 20-40mg/L, total phosphorus is 2.5-3.5mg/L, COD Cr is 150-400mg/L, total nitrogen removal rate is as high as 92.9%, ammonia nitrogen removal rate is as high as 99.3%, total phosphorus The removal rate is as high as 85.7%, and the COD Cr removal rate is as high as 95.6%.
如图4所示,在有AOABR模块时,第一级饱和人工湿地中的硝化和厌氧氨氧化功能基因的相对丰度要高于或显著高于没有AOABR模块时,但是反硝化功能基因相对丰度却相反,进一步说明本发明的污水处理系统可以通过提高厌氧氨氧化作用强化生活污水脱氮。As shown in Figure 4, with the AOABR module, the relative abundance of nitrification and anammox functional genes in the first-level saturated constructed wetland is higher or significantly higher than without the AOABR module, but the denitrification functional genes are relatively The abundance is opposite, which further illustrates that the sewage treatment system of the present invention can enhance the denitrification of domestic sewage by improving the anaerobic ammonia oxidation.
此外,实施例1和实施例2的人工湿地系统在运行一年半后,均无堵塞现象。In addition, the constructed wetland system of Example 1 and Example 2 showed no blockage after one and a half years of operation.
最后所应当说明的是,以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制,对于本领域的普通技术人员来说,在上述说明及思路的基础上还可以做出其它不同形式的变化或变动,这里无需也无法对所有的实施方式予以穷举。凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明权利要求的保护范围之内。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and not to limit the scope of protection of the present invention. For those of ordinary skill in the art, they can also make decisions based on the above descriptions and ideas. For other changes or changes in different forms, it is not necessary and impossible to enumerate all the implementation methods here. Any modification, equivalent replacement and improvement made within the spirit and principle of the present invention shall be included in the protection scope of the claims of the present invention.

Claims (10)

  1. 一种强化生活污水厌氧氨氧化脱氮同时除磷的污水处理系统,其特征在于,包括顺次连接的过滤模块、AOABR模块、配水模块和组合人工湿地模块;所述过滤模块通过潜水泵(2)与AOABR模块相连,配水模块通过提升泵(9)与组合人工湿地模块相连;所述过滤模块设置进水口,所述组合人工湿地模块设置出水口;所述过滤模块为格栅沉淀池(1);所述AOABR模块包括顺次相连的厌氧池(3)、好氧池(4)和缺氧池(5);所述配水模块为集水池(8);所述组合人工湿地模块由多级人工湿地构成,多级人工湿地按水流方向从高至低依次排列呈阶梯结构。A sewage treatment system for enhancing the anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage, which is characterized in that it comprises a filter module, an AOABR module, a water distribution module and a combined constructed wetland module connected in sequence; the filter module passes through a submersible pump ( 2) Connected to the AOABR module, the water distribution module is connected to the combined constructed wetland module through the lift pump (9); the filter module is provided with a water inlet, the combined constructed wetland module is provided with a water outlet; the filter module is a grid sedimentation tank ( 1); The AOABR module includes an anaerobic tank (3), an aerobic tank (4), and an anoxic tank (5) connected in sequence; the water distribution module is a collecting tank (8); the combined constructed wetland module It is composed of multi-level constructed wetlands, which are arranged in a stepped structure according to the direction of water flow from high to low.
  2. 根据权利要求1所述污水处理系统,其特征在于,所述厌氧池(3)、好氧池(4)和缺氧池(5)的进水口均设置在底端,出水口均设置在顶端。The sewage treatment system according to claim 1, wherein the water inlets of the anaerobic tank (3), aerobic tank (4) and anoxic tank (5) are all set at the bottom end, and the water outlets are all set at the bottom top.
  3. 根据权利要求2所述污水处理系统,其特征在于,所述厌氧池(3)和好氧池(4)内均设有聚乙烯填料;所述好氧池(4)内设有曝气泵(7)。The sewage treatment system according to claim 2, wherein the anaerobic tank (3) and the aerobic tank (4) are both equipped with polyethylene filler; the aerobic tank (4) is equipped with aeration Pump (7).
  4. 根据权利要求1所述污水处理系统,其特征在于,所述多级人工湿地为三级或三级以上的人工湿地。The sewage treatment system according to claim 1, wherein the multi-level constructed wetland is a three-level or more constructed wetland.
  5. 根据权利要求1所述污水处理系统,其特征在于,所述多级人工湿地的第一级为饱和流湿地;其他级为饱和流或非饱和流湿地。The sewage treatment system according to claim 1, wherein the first stage of the multi-stage constructed wetland is a saturated flow wetland; the other stages are a saturated flow or an unsaturated flow wetland.
  6. 根据权利要求1所述污水处理系统,其特征在于,所述曝气泵(7)、潜水泵(2)和提升泵(9)均通过自动电子控制系统进行控制。The sewage treatment system according to claim 1, wherein the aeration pump (7), the submersible pump (2) and the lift pump (9) are all controlled by an automatic electronic control system.
  7. 一种污水处理方法,其特征在于,利用权利要求1至6任一所述污水处理系统,污水由进水口进入过滤模块,经过格栅过滤和初步沉淀作用,通过潜水泵(2)批次泵入AOABR水处理模块,并经AOABR处理后流向配水模块,再通过提升泵(9)连续泵入组合人工湿地模块,最后由出水口流出。A sewage treatment method, characterized in that, using the sewage treatment system of any one of claims 1 to 6, the sewage enters the filter module from the water inlet, passes through the grid filtration and preliminary sedimentation, and then passes through the submersible pump (2) batch pump Enter the AOABR water treatment module, and flow to the water distribution module after AOABR treatment, and then continuously pump into the combined constructed wetland module through the lift pump (9), and finally flow out from the water outlet.
  8. 根据权利要求7所述污水处理方法,其特征在于,所述组合人工湿地模块的进水方式为连续进水,进水负荷为0.1~0.5m/d。The sewage treatment method according to claim 7, wherein the water inlet method of the combined constructed wetland module is continuous water inlet, and the water inlet load is 0.1-0.5 m/d.
  9. 根据权利要求7所述污水处理方法,其特征在于,所述好氧池(4)的曝气量为0.3~0.35m 3/h,曝气时间为2~4h/d,溶解氧浓度为2~5mg/L。 The sewage treatment method according to claim 7, characterized in that the aeration volume of the aerobic tank (4) is 0.3~0.35m 3 /h, the aeration time is 2~4h/d, and the dissolved oxygen concentration is 2 ~5mg/L.
  10. 根据权利要求7所述污水处理方法,其特征在于,所述缺氧池(5)的溶解氧为1.5~4mg/L,其在非进水阶段溶解氧为0.5~1.5mg/L。The sewage treatment method according to claim 7, characterized in that the dissolved oxygen in the anoxic tank (5) is 1.5-4 mg/L, and the dissolved oxygen in the non-water inlet stage is 0.5-1.5 mg/L.
PCT/CN2019/129340 2019-12-26 2019-12-27 Sewage treatment system and method for strengthening anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage WO2021128308A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201911367092.6A CN110921833B (en) 2019-12-26 2019-12-26 Sewage treatment system and method for strengthening anaerobic ammonia oxidation denitrification and phosphorus removal of domestic sewage
CN201911367092.6 2019-12-26

Publications (1)

Publication Number Publication Date
WO2021128308A1 true WO2021128308A1 (en) 2021-07-01

Family

ID=69861046

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2019/129340 WO2021128308A1 (en) 2019-12-26 2019-12-27 Sewage treatment system and method for strengthening anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage

Country Status (2)

Country Link
CN (1) CN110921833B (en)
WO (1) WO2021128308A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113582340A (en) * 2021-08-04 2021-11-02 深圳市环保科技集团有限公司 Industrial wastewater total nitrogen treatment system
CN113845233A (en) * 2021-11-04 2021-12-28 盐城师范学院 Adjustable anti-blocking wetland system
CN116216906A (en) * 2023-03-02 2023-06-06 温州大学 Device suitable for advanced treatment of tail water of sewage biochemical process and application method of device
CN117185589A (en) * 2023-11-02 2023-12-08 四川省生态环境科学研究院 Advanced treatment integrated device for live pig breeding wastewater

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111392868B (en) * 2020-04-02 2020-12-22 乐清市泰博恒电子科技有限公司 Anti-blocking early warning system and method for constructed wetland
CN112010506A (en) * 2020-08-28 2020-12-01 桂林理工大学 Wetland pretreatment integrated device
CN112811575A (en) * 2021-01-11 2021-05-18 上海环保工程成套有限公司 Ecological type farming-pasturing area resident domestic sewage treatment equipment
CN115215446A (en) * 2022-07-29 2022-10-21 江苏河马井股份有限公司 Method for treating sewage by adding hydrogen peroxide

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6117323A (en) * 1997-03-18 2000-09-12 Haggerty; Ken Process for the biological treatment of wastewater with periods of biomass starvation
CN102086061A (en) * 2010-12-17 2011-06-08 哈尔滨工业大学 AOA (Angles-Of-Arrival) continuous flow biological nitrogen and phosphorus removal process for sewage treatment
CN102260021A (en) * 2011-06-01 2011-11-30 同济大学 Process and device for deep denitrogenation of domestic wastewater without additional carbon source
US20130277302A1 (en) * 2012-04-24 2013-10-24 Klaus Doelle Water treatment system
CN110127953A (en) * 2019-06-05 2019-08-16 北京市水科学技术研究院 A kind of artificial swamp short distance nitration/denitrification biological denitrogenation system and method
CN110436620A (en) * 2019-08-30 2019-11-12 杭州沁霖生态科技有限公司 A kind of wetland and its treatment process of simultaneous denitrification

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000037463A (en) * 2000-04-26 2000-07-05 지영호 The sequencing combination of anaerobic, oxic and anoxic vessels for effective denitrification and dephosphorus in waste water
CN203021402U (en) * 2012-12-21 2013-06-26 东华大学 Internal carbon sourced-oxygen enriched cascade-combination constructed wetland engineering reactor
CN103130384A (en) * 2013-03-29 2013-06-05 黄河勘测规划设计有限公司 Multi-baffle subsurface flow constructed wetland system
CN103936161B (en) * 2014-04-25 2015-09-30 暨南大学 A kind of plant carbon source strengthened artificial wet land that utilizes is to the method and system of low-carbon high-nitrogen sewage denitrogenation
WO2015172066A1 (en) * 2014-05-08 2015-11-12 The Trustees Of Princeton University Methods and compositions for nitrogen removal using feammox microorganisms
CN204211541U (en) * 2014-08-29 2015-03-18 暨南大学 The vertical marsh sewage treatment system of a kind of backflow
CN104876399B (en) * 2015-05-26 2017-01-11 浙江正境环保科技有限公司 Multistage-series constructed wetland sewage treatment system and method based on solar energy
CN205045961U (en) * 2015-10-16 2016-02-24 宁波中汇环保工程有限公司 Treatment of domestic sewage constructed wetland system
CN205635295U (en) * 2016-05-31 2016-10-12 郑州大学 Ecological processing system of sewage
CN107963786A (en) * 2017-12-14 2018-04-27 湖南大辰环保科技有限公司 A kind of sewage water treatment method and system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6117323A (en) * 1997-03-18 2000-09-12 Haggerty; Ken Process for the biological treatment of wastewater with periods of biomass starvation
CN102086061A (en) * 2010-12-17 2011-06-08 哈尔滨工业大学 AOA (Angles-Of-Arrival) continuous flow biological nitrogen and phosphorus removal process for sewage treatment
CN102260021A (en) * 2011-06-01 2011-11-30 同济大学 Process and device for deep denitrogenation of domestic wastewater without additional carbon source
US20130277302A1 (en) * 2012-04-24 2013-10-24 Klaus Doelle Water treatment system
CN110127953A (en) * 2019-06-05 2019-08-16 北京市水科学技术研究院 A kind of artificial swamp short distance nitration/denitrification biological denitrogenation system and method
CN110436620A (en) * 2019-08-30 2019-11-12 杭州沁霖生态科技有限公司 A kind of wetland and its treatment process of simultaneous denitrification

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113582340A (en) * 2021-08-04 2021-11-02 深圳市环保科技集团有限公司 Industrial wastewater total nitrogen treatment system
CN113845233A (en) * 2021-11-04 2021-12-28 盐城师范学院 Adjustable anti-blocking wetland system
CN116216906A (en) * 2023-03-02 2023-06-06 温州大学 Device suitable for advanced treatment of tail water of sewage biochemical process and application method of device
CN117185589A (en) * 2023-11-02 2023-12-08 四川省生态环境科学研究院 Advanced treatment integrated device for live pig breeding wastewater
CN117185589B (en) * 2023-11-02 2024-02-27 四川省生态环境科学研究院 Advanced treatment integrated device for live pig breeding wastewater

Also Published As

Publication number Publication date
CN110921833B (en) 2021-09-24
CN110921833A (en) 2020-03-27

Similar Documents

Publication Publication Date Title
WO2021128308A1 (en) Sewage treatment system and method for strengthening anaerobic ammonia oxidation denitrification and dephosphorization of domestic sewage
CN102531298B (en) Sewage treatment device and method for enhanced denitrification A/A/O (Anodic Aluminum Oxide) and deoxygenation BAF (Biological Aerated Filter)
CN110255714B (en) Low-carbon-source urban sewage treatment system and method
CN102583743B (en) Dual-sludge denitrification dephosphorizing and denitrifying A/A-O device and method
CN110482701B (en) Step-by-step water multi-stage AO series connection efficient biological denitrification system and method
CN103172226B (en) Surface water stagnation type baffling wetland system for synchronously and intensively removing nitrogen, phosphorus and estrogen
CN104016479A (en) Tower-type self-circulation aerobic degradation reactor and aerobic degradation method using same
CN104193090A (en) Sludge drying sewage treatment system and method
CN210855718U (en) Novel rural sewage treatment system
CN112374696A (en) System and method for treating sewage by multistage multi-point water inflow enhanced denitrification
CN103936154A (en) Biological aerated filter system and sewage treatment method thereof
CN103641241B (en) Preposed denitrification aeration biofilter and method for treating sewage
CN109626563A (en) A kind of domestic sewage in rural areas deep denitrification method
CN105110462A (en) Device and method for quickly achieving shortcut nitrification of high-ammonia-nitrogen waste water biological aerated filter
CN112499765A (en) Aerobic-anaerobic three-phase pulse type step water inlet wetland system
CN218811069U (en) Sewage treatment system of SBR is reinforceed to biomembrane carrier
CN103693818B (en) Coking wastewater biochemical treatment and sedimentation tank
CN110407327A (en) A kind of micro- method for exposing high efficient vertical flow constructed wetland and submerged plant ecological pond combined system and its handling tail water
CN105753251A (en) Sewage treatment system and sewage treatment method
CN205501069U (en) Electroplate organic waste water's many first biochemical system of catalytic oxidation combination
CN205442996U (en) Sewage treatment system
CN204958514U (en) Realize nitrifying device of high ammonia -nitrogen concentration waste water bological aerated filter short distance fast
CN211847346U (en) Sewage treatment system for strengthening anaerobic ammonia oxidation denitrification and simultaneous phosphorus removal of domestic sewage
CN207313240U (en) A kind of multistage OA-MBR oxidation ditches
CN203593663U (en) Pre-denitrification biological aerated filter

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 19957082

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 19957082

Country of ref document: EP

Kind code of ref document: A1