WO2021125595A1 - Tôle d'acier à haute résistance ayant une aptitude au façonnage supérieure, et son procédé de fabrication - Google Patents

Tôle d'acier à haute résistance ayant une aptitude au façonnage supérieure, et son procédé de fabrication Download PDF

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WO2021125595A1
WO2021125595A1 PCT/KR2020/016650 KR2020016650W WO2021125595A1 WO 2021125595 A1 WO2021125595 A1 WO 2021125595A1 KR 2020016650 W KR2020016650 W KR 2020016650W WO 2021125595 A1 WO2021125595 A1 WO 2021125595A1
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steel sheet
less
strength
workability
relational expression
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PCT/KR2020/016650
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English (en)
Korean (ko)
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이재훈
임영록
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주식회사 포스코
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Priority to EP20904161.5A priority Critical patent/EP4079905A4/fr
Priority to CN202080087079.XA priority patent/CN114846167A/zh
Priority to JP2022536968A priority patent/JP7554828B2/ja
Priority to US17/785,869 priority patent/US20230046327A1/en
Publication of WO2021125595A1 publication Critical patent/WO2021125595A1/fr
Priority to JP2024084221A priority patent/JP2024109830A/ja

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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/008—Heat treatment of ferrous alloys containing Si
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54—Furnaces for treating strips or wire
    • C21D9/68—Furnace coilers; Hot coilers
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the present invention relates to a steel sheet that can be used for automobile parts and the like, and to a steel sheet having excellent workability while having high strength characteristics and a method of manufacturing the same.
  • Patent Documents 1 and 2 As a technique for improving the workability of a steel sheet, a method of utilizing tempered martensite is disclosed in Patent Documents 1 and 2. Since tempered martensite made by tempering hard martensite is soft martensite, there is a difference in strength between tempered martensite and existing untempered martensite (fresh martensite). Therefore, when fresh martensite is suppressed and tempered martensite is formed, workability may be increased.
  • TRIP Transformation Induced Plasticity
  • Patent Document 3 discloses TRIP steel having excellent strength and workability.
  • Patent Document 3 including polygonal ferrite, retained austenite and martensite, it was attempted to improve ductility and workability, but bainite is the main phase, so high strength cannot be secured, and the tensile strength and elongation It can be seen that the balance (TS ⁇ El) also does not satisfy 22,000 MPa% or more.
  • Patent Document 1 Korean Patent Publication No. 10-2006-0118602
  • Patent Document 2 Japanese Patent Application Laid-Open No. 2009-019258
  • Patent Document 3 Korean Patent Publication No. 10-2014-0012167
  • a high-strength steel sheet having excellent ductility, bendability and hole expandability by optimizing the composition and microstructure of the steel sheet and a method for manufacturing the same can be provided.
  • High-strength steel sheet excellent in workability by weight, C: 0.25 to 0.75%, Si: 4.0% or less, Mn: 0.9 to 5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: 0.03% or less, including the remaining Fe and unavoidable impurities, as a microstructure, 30-70 vol% tempered martensite, 10-45 vol% bainite, 10-40 vol% of retained austenite, 3 to 20 vol% of ferrite and an unavoidable structure, and the following [Relational Expression 1] may be satisfied.
  • [Si+Al] F is the average total content of Si and Al contained in the ferrite (weight%)
  • [Si+Al] av is the average total content of Si and Al contained in the steel sheet (weight%) )to be.
  • the steel plate may further include any one or more of the following (1) to (9).
  • the total content of Si and Al (Si+Al) may be 1.0 to 6.0 wt%.
  • the steel sheet has a balance (B T E ) of tensile strength and elongation expressed by the following [Relational Expression 2] of 22,000 (MPa%) or more, and the tensile strength and hole expansion rate expressed by [Relational Expression 3] below
  • the balance (B T ⁇ H ) is 7*10 6 (MPa 2 % 1/2 ) or more
  • the bending workability ( BR ) expressed by [Relational Expression 4] below may be in the range of 0.5 to 3.0.
  • R means the minimum bending radius (mm) at which cracks do not occur after the 90° bending test
  • t means the thickness (mm) of the steel sheet.
  • High-strength steel sheet excellent in workability by weight, C: 0.25 to 0.75%, Si: 4.0% or less, Mn: 0.9 to 5.0%, Al: 5.0% or less, P: 0.15% or less , S: 0.03% or less, N: 0.03% or less, the remainder is a step of heating a steel slab containing Fe and unavoidable impurities, and hot rolling; winding the hot-rolled steel sheet; performing hot rolling annealing heat treatment on the wound steel sheet in a temperature range of 650 to 850° C.
  • the steel slab may further include any one or more of the following (1) to (9).
  • the total content of Si and Al contained in the steel slab (Si+Al) may be 1.0 to 6.0 wt%.
  • the steel slab may be heated to a temperature range of 1000 ⁇ 1350 °C, finish hot rolling in a temperature range of 800 ⁇ 1000 °C.
  • the hot-rolled steel sheet may be wound in a temperature range of 300 ⁇ 600 °C.
  • the rolling reduction of the cold rolling may be 30 to 90%.
  • the cooling rate of the secondary cooling may be 1°C/s or more.
  • a steel sheet particularly suitable for automobile parts because it has excellent strength as well as excellent workability such as ductility, bending workability and hole expandability.
  • the present invention relates to a high-strength steel sheet having excellent workability and a method for manufacturing the same, and preferred embodiments of the present invention will be described below.
  • Embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the embodiments described below.
  • the present embodiments are provided in order to further detail the present invention to those of ordinary skill in the art to which the present invention pertains.
  • the inventors of the present invention in transformation induced plasticity (TRIP) steel containing bainite, tempered martensite, retained austenite and ferrite, promotes the stabilization of retained austenite and, at the same time, retained austenite and ferrite
  • TRIP transformation induced plasticity
  • High-strength steel sheet excellent in workability by weight, C: 0.25 to 0.75%, Si: 4.0% or less, Mn: 0.9 to 5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: 0.03% or less, including the remaining Fe and unavoidable impurities, as a microstructure, 30-70 vol% tempered martensite, 10-45 vol% bainite, 10-40 vol% of retained austenite, 3 to 20 vol% of ferrite and an unavoidable structure, and the following [Relational Expression 1] may be satisfied.
  • [Si+Al] F is the average total content of Si and Al contained in the ferrite (weight%)
  • [Si+Al] av is the average total content of Si and Al contained in the steel sheet (weight%) )to be.
  • High-strength steel sheet excellent in workability by weight, C: 0.25 to 0.75%, Si: 4.0% or less, Mn: 0.9 to 5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: 0.03% or less, remaining Fe and unavoidable impurities, and additionally Ti: 0.5% or less (including 0%), Nb: 0.5% or less (including 0%), V: 0.5% or less (including 0%), Cr: 3.0% or less (including 0%), Mo: 3.0% or less (including 0%), Cu: 4.5% or less (including 0%), Ni: 4.5% or less (including 0%) , B: 0.005% or less (including 0%), Ca: 0.05% or less (including 0%), REM excluding Y: 0.05% or less (including 0%), Mg: 0.05% or less (including 0%), W : 0.5% or less (including 0%), Zr: 0.5% or less (including 0%), Sb: 0.
  • Carbon (C) is an element essential for securing the strength of a steel sheet, and is also an element for stabilizing retained austenite, which contributes to the improvement of ductility of the steel sheet. Therefore, the present invention may contain 0.25% or more of carbon (C) to achieve such an effect.
  • a preferred carbon (C) content may be greater than 0.25%, may be greater than 0.27%, and may be greater than or equal to 0.30%. More preferably, the carbon (C) content may be 0.31% or more.
  • the present invention may limit the upper limit of the carbon (C) content to 0.75%.
  • the carbon (C) content may be 0.70% or less, and a more preferable carbon content (C) may be 0.67% or less.
  • Silicon (Si) is an element that contributes to strength improvement by solid solution strengthening, and is also an element that improves workability by strengthening ferrite and homogenizing the structure.
  • silicon (Si) is an element contributing to generation of retained austenite by suppressing precipitation of cementite. Therefore, in the present invention, silicon (Si) may be necessarily added to achieve such an effect.
  • a preferable silicon (Si) content may be 0.02% or more, and a more preferable silicon (Si) content may be 0.05% or more.
  • the silicon (Si) content exceeds a certain level, it not only causes a plating defect problem such as non-plating in the plating process, but also reduces the weldability of the steel sheet.
  • the present invention provides an upper limit of the silicon (Si) content can be limited to 4.0%.
  • a preferable upper limit of the silicon (Si) content may be 3.8%, and a more preferable upper limit of the silicon (Si) content may be 3.5%.
  • Aluminum (Al) is an element that deoxidizes by combining with oxygen in steel.
  • aluminum (Al) is also an element that suppresses cementite precipitation and stabilizes retained austenite, similarly to silicon (Si). Therefore, in the present invention, aluminum (Al) may be necessarily added to achieve such an effect.
  • a preferable aluminum (Al) content may be 0.05% or more, and a more preferable aluminum (Al) content may be 0.1% or more.
  • the present invention can limit the upper limit of the aluminum (Al) content to 5.0%. .
  • the upper limit of the preferable aluminum (Al) content may be 4.75%, and the more preferable upper limit of the aluminum (Al) content may be 4.5%.
  • the total content (Si+Al) of silicon (Si) and aluminum (Al) is preferably 1.0 to 6.0%. Since silicon (Si) and aluminum (Al) are components that affect microstructure formation in the present invention, affecting ductility, bendability and hole expandability, the total content of silicon (Si) and aluminum (Al) is 1.0 ⁇ It is preferably 6.0%. More preferably, the total content (Si+Al) of silicon (Si) and aluminum (Al) may be 1.5% or more, and may be 4.0% or less.
  • Manganese (Mn) is a useful element for increasing both strength and ductility. Therefore, the present invention may limit the lower limit of the manganese (Mn) content to 0.9% in order to achieve such an effect.
  • a preferred lower limit of the manganese (Mn) content may be 1.0%, and a more preferred lower limit of the manganese (Mn) content may be 1.1%.
  • the present invention may limit the upper limit of the manganese (Mn) content to 5.0%.
  • a preferable upper limit of the manganese (Mn) content may be 4.7%, and a more preferable upper limit of the manganese (Mn) content may be 4.5%.
  • Phosphorus (P) is an element that is contained as an impurity and deteriorates impact toughness. Therefore, it is preferable to manage the content of phosphorus (P) to 0.15% or less.
  • Sulfur (S) is an element that is contained as an impurity to form MnS in the steel sheet and deteriorate ductility. Therefore, the content of sulfur (S) is preferably 0.03% or less.
  • Nitrogen (N) is an element that causes cracks in the slab by forming nitride during continuous casting as it is contained as an impurity. Therefore, the content of nitrogen (N) is preferably 0.03% or less.
  • the steel sheet of the present invention has an alloy composition that may be additionally included in addition to the above-described alloy components, which will be described in detail below.
  • Titanium (Ti), niobium (Nb), and vanadium (V) are elements that make precipitates and refine crystal grains, and are elements that also contribute to the improvement of strength and impact toughness of a steel sheet, so the present invention provides titanium (Ti) for this effect. ), at least one of niobium (Nb) and vanadium (V) may be added. However, when the respective contents of titanium (Ti), niobium (Nb) and vanadium (V) exceed a certain level, excessive precipitates are formed to decrease impact toughness and increase manufacturing cost, so the present invention Silver may limit the content of titanium (Ti), niobium (Nb), and vanadium (V) to 0.5% or less, respectively.
  • Chromium (Cr) and molybdenum (Mo) are elements that not only suppress austenite decomposition during alloying treatment, but also stabilize austenite in the same way as manganese (Mn), so the present invention provides chromium (Cr) and At least one of molybdenum (Mo) may be added.
  • the present invention may limit the content of chromium (Cr) and molybdenum (Mo) to 3.0% or less, respectively.
  • Copper (Cu) and nickel (Ni) are elements that stabilize austenite and inhibit corrosion.
  • copper (Cu) and nickel (Ni) are also elements that are concentrated on the surface of the steel sheet to prevent hydrogen intrusion from moving into the steel sheet, thereby suppressing delayed hydrogen destruction. Accordingly, in the present invention, at least one of copper (Cu) and nickel (Ni) may be added for such an effect.
  • the content of copper (Cu) and nickel (Ni) exceeds a certain level, it causes not only excessive characteristic effects, but also an increase in manufacturing cost. Therefore, in the present invention, the content of copper (Cu) and nickel (Ni) is increased, respectively. It can be limited to 4.5% or less.
  • Boron (B) is an element that improves hardenability to increase strength, and is also an element that suppresses nucleation of grain boundaries. Therefore, in the present invention, boron (B) may be added for this effect. However, when the content of boron (B) exceeds a certain level, it causes excessive characteristic effects as well as an increase in manufacturing cost, so the present invention may limit the content of boron (B) to 0.005% or less.
  • the rare earth element means scandium (Sc), yttrium (Y), and a lanthanide element. Since rare earth elements (REM) other than calcium (Ca), magnesium (Mg), and yttrium (Y) are elements that contribute to the improvement of ductility of a steel sheet by spheroidizing sulfides, the present invention provides calcium (Ca), At least one of rare earth elements (REM) other than magnesium (Mg) and yttrium (Y) may be added.
  • the present invention provides calcium ( Ca), magnesium (Mg), and the content of rare earth elements (REM) excluding yttrium (Y) may be limited to 0.05% or less, respectively.
  • tungsten (W) and zirconium (Zr) are elements that increase the strength of a steel sheet by improving hardenability
  • one or more of tungsten (W) and zirconium (Zr) may be added for this effect.
  • the present invention sets the content of tungsten (W) and zirconium (Zr) to 0.5 % or less.
  • antimony (Sb) and tin (Sn) are elements that improve the plating wettability and plating adhesion of the steel sheet
  • at least one of antimony (Sb) and tin (Sn) may be added for such an effect.
  • the content of antimony (Sb) and tin (Sn) exceeds a certain level, the brittleness of the steel sheet increases and cracks may occur during hot working or cold working, so the present invention provides antimony (Sb) and tin (Sn) ) may be limited to 0.5% or less, respectively.
  • yttrium (Y) and hafnium (Hf) are elements that improve the corrosion resistance of the steel sheet
  • at least one of yttrium (Y) and hafnium (Hf) may be added for this effect.
  • the present invention sets the content of yttrium (Y) and hafnium (Hf) to 0.2% or less, respectively. can be limited
  • cobalt (Co) is an element that increases the TRIP effect by promoting bainite transformation
  • cobalt (Co) may be added for this effect.
  • the present invention may limit the content of cobalt (Co) to 1.5% or less.
  • the high-strength steel sheet having excellent workability according to an aspect of the present invention may include remaining Fe and other unavoidable impurities in addition to the above-described components.
  • unintended impurities from raw materials or the surrounding environment may inevitably be mixed in the normal manufacturing process, it cannot be completely excluded. Since these impurities are known to those of ordinary skill in the art, all contents thereof are not specifically mentioned in the present specification.
  • additional addition of effective ingredients other than the above-mentioned ingredients is not entirely excluded.
  • the high-strength steel sheet having excellent workability according to an aspect of the present invention may include tempered martensite, bainite, retained austenite and ferrite as a microstructure.
  • the high strength steel sheet having excellent workability according to an aspect of the present invention by volume fraction, is 30 to 70% tempered martensite, 10 to 45% bainite, 10 to 40% retained austenite, It may contain 3-20% ferrite and unavoidable texture.
  • fresh martensite, perlite, martensite martensite (Martensite Austenite Constituent, M-A) and the like may be included. When fresh martensite or pearlite is excessively formed, the workability of the steel sheet may decrease or the fraction of retained austenite may be reduced.
  • the average total content of silicon (Si) and aluminum (Al) contained in the steel sheet ([Si+Al] av , wt% ) to the average total content ([Si+Al] F , wt%) of silicon (Si) and aluminum (Al) contained in ferrite may satisfy the range of 1.02 to 1.45.
  • the high-strength steel sheet excellent in workability has a balance (B T E ) of tensile strength and elongation expressed by the following [Relational Expression 2] of 22,000 (MPa%) or more, and the following [Relational Expression 2] 3] the tensile strength and the hole expansion rate balance (B T ⁇ H) 7 ⁇ 10 6, and (MPa 2% 1/2) or more, the bending rate, expressed in [expression 4] below, in which is represented by (B R ) satisfies the range of 0.5 to 3.0, so it can have excellent balance between strength and ductility and balance between strength and hole expandability, as well as have excellent bendability.
  • R means the minimum bending radius (mm) at which cracks do not occur after the 90° bending test
  • t means the thickness (mm) of the steel sheet.
  • the present invention it is important to stabilize the retained austenite in the steel sheet because it is intended to simultaneously secure excellent ductility and bendability as well as high strength properties.
  • it is necessary to enrich carbon (C) and manganese (Mn) in ferrite, bainite, and tempered martensite of the steel sheet into austenite.
  • carbon (C) is concentrated in austenite by utilizing ferrite, the strength of the steel sheet may be insufficient due to the low strength characteristics of ferrite, and excessive interphase hardness difference may occur, thereby reducing the hole expansion rate (HER). Therefore, the present invention intends to enrich carbon (C) and manganese (Mn) into austenite by utilizing bainite and tempered martensite.
  • the present invention provides an average of silicon (Si) and aluminum (Al) contained in ferrite with respect to the average total content ([Si+Al] av , wt%) of silicon (Si) and aluminum (Al) contained in the steel sheet. Since the ratio of the total content ([Si+Al] F , wt%) is limited to 1.02 or more, it is possible to effectively reduce the hardness difference between the phases of the soft tissue and the hard tissue. On the other hand, if the content of silicon (Si) and aluminum (Al) in the ferrite is excessive, rather the ferrite is excessively hardened and the workability is deteriorated.
  • the present invention relates to the average total content of silicon (Si) and aluminum (Al) contained in the steel sheet ([Si+Al] av , weight %) of silicon (Si) and aluminum (Al) contained in ferrite according to the present invention. ) of the average total content ([Si+Al] F , wt%) may be limited to 1.45 or less.
  • the steel sheet containing retained austenite has excellent ductility and bendability due to transformation-induced plasticity that occurs during transformation from austenite to martensite during processing.
  • the fraction of retained austenite is less than a certain level, the balance between tensile strength and elongation (TS ⁇ El) may be less than 22,000 MPa%, or the bending workability (R/t) may exceed 3.0.
  • TS ⁇ El tensile strength and elongation
  • R/t bending workability
  • the fraction of retained austenite exceeds a certain level, local elongation may be reduced.
  • the fraction of residual austenite can be limited in the range of 10 to 40% by volume.
  • both untempered martensite (fresh martensite) and tempered martensite are microstructures that improve the strength of the steel sheet.
  • fresh martensite has a property of greatly reducing the ductility and hole expandability of the steel sheet. This is because the microstructure of tempered martensite is softened by the tempering heat treatment. Therefore, in the present invention, it is preferable to utilize tempered martensite in order to provide a steel sheet having excellent balance between strength and ductility, balance between strength and hole expandability, and bending workability.
  • the present invention is tempered martensite in order to obtain a steel sheet excellent in the balance of tensile strength and elongation (TS ⁇ El), the balance of tensile strength and hole expansion rate (TS 2 ⁇ HER 1/2 ) and bending workability (R/t).
  • the fraction of can be limited to the range of 30 to 70 vol%.
  • bainite is appropriately included as a microstructure. It is preferable Only when the bainite fraction is above a certain level, the balance between tensile strength and elongation (TS ⁇ El) of 22,000 MPa% or more, and balance of tensile strength and hole expansion ratio of 7*10 6 (MPa 2 % 1/2 ) or more (TS 2 ⁇ HER) 1/2 ) and a bending workability (R/t) of 0.5 to 3.0 can be secured.
  • the present invention can limit the fraction of bainite in the range of 10 to 45 vol%.
  • the present invention may limit the fraction of ferrite to a range of 3 to 20 vol%.
  • a method of manufacturing a high-strength steel sheet according to an aspect of the present invention includes the steps of preparing a steel slab having a predetermined component, heating the steel slab, and hot rolling; winding the hot-rolled steel sheet; performing hot rolling annealing heat treatment on the wound steel sheet in a temperature range of 650 to 850° C.
  • a steel slab having a predetermined component is prepared. Since the steel slab of the present invention has an alloy composition corresponding to the alloy composition of the steel plate described above, the description of the alloy composition of the steel slab is replaced with the description of the alloy composition of the steel plate described above.
  • the prepared steel slab may be heated to a certain temperature range, and the heating temperature of the steel slab at this time may be in the range of 1000 to 1350 °C. If the heating temperature of the steel slab is less than 1000°C, it may be hot rolled in the temperature range below the target finish hot rolling temperature range. If the heating temperature of the steel slab exceeds 1350°C, it will reach the melting point of the steel and melt. because it has potential.
  • the heated steel slab may be hot rolled to provide a hot rolled steel sheet.
  • the finish hot rolling temperature during hot rolling is preferably in the range of 800 to 1000 °C. If the finish hot rolling temperature is less than 800 °C, excessive rolling load may be a problem, and if the finish hot rolling temperature exceeds 1000 °C, coarse grains of the hot rolled steel sheet are formed, which may cause deterioration of the physical properties of the final steel sheet. Because.
  • the hot-rolled steel sheet after the hot rolling has been completed may be cooled at an average cooling rate of 10° C./s or more, and may be wound at a temperature of 300 to 600° C. If the coiling temperature is less than 300 °C, winding is not easy, and when the coiling temperature exceeds 600 °C, the surface scale (scale) is formed to the inside of the hot-rolled steel sheet This is because it may make pickling difficult.
  • the hot rolling annealing heat treatment can be performed for 600 to 1700 seconds in a temperature range of 650 to 850 °C.
  • the hot rolling annealing heat treatment temperature is less than 650° C. or less than 600 seconds, which is the hot rolling annealing heat treatment time, the strength of the hot rolling annealing heat treated steel sheet is high, and subsequent cold rolling may not be easy.
  • the hot-rolling annealing heat treatment temperature exceeds 850° C. or the hot-rolling annealing heat treatment time exceeds 1700 seconds, pickling may not be easy due to a scale formed deep inside the steel sheet.
  • pickling may be performed, and cold rolling may be performed.
  • cold rolling is preferably performed at a cumulative reduction ratio of 30 to 90%. When the cumulative reduction ratio of cold rolling exceeds 90%, it may be difficult to perform cold rolling in a short time due to the high strength of the steel sheet.
  • the cold-rolled steel sheet may be manufactured as an unplated cold-rolled steel sheet through an annealing heat treatment process, or may be manufactured as a plated steel sheet through a plating process to impart corrosion resistance.
  • plating methods such as hot-dip galvanizing, electro-galvanizing, and hot-dip aluminum plating may be applied, and the method and type thereof are not particularly limited.
  • an annealing heat treatment process is performed.
  • the cold-rolled steel sheet is heated (primary heating) to a temperature range of Ac1 or more and less than Ac3 (ideal range), and maintained (primary maintenance) in the temperature range for 50 seconds or more. If the primary heating or primary maintenance temperature is Ac3 or higher (single-phase region), the desired ferrite structure cannot be realized, so the desired level of [Si+Al] F / [Si+Al] av and tensile strength and hole expansion rate The balance of TS 2 ⁇ HER 1/2 cannot be implemented. In addition, when the primary heating or primary maintenance temperature is in a temperature range less than Ac1, sufficient heating is not performed, so there is a fear that the microstructure of the present invention may not be realized even by subsequent heat treatment. The average temperature increase rate of the primary heating may be 5 °C / s or more.
  • the structure may not be sufficiently homogenized and the physical properties of the steel sheet may be deteriorated.
  • the upper limit of the primary holding time is not particularly limited, the primary heating time is preferably limited to 1200 seconds or less in order to prevent a decrease in toughness due to grain coarsening.
  • the primary maintenance After the primary maintenance, it can be cooled (primary cooling) to a primary cooling stop temperature of 100 to 300°C at a primary cooling rate of 1°C/s or more at an average cooling rate.
  • the upper limit of the primary cooling rate does not need to be specifically defined, but is preferably set to 100°C/s or less.
  • the primary cooling stop temperature is less than 100 ° C, tempered martensite is excessively formed and the amount of residual austenite is insufficient, so [Si+Al] F / [Si+Al] av , tensile strength and elongation of the steel sheet balance (TS ⁇ El) and bending workability (R/t) may be reduced.
  • heating to a secondary heating temperature of 300 to 500 °C at a secondary heating rate of 5 °C/s or more at an average temperature increase rate, and maintaining at the temperature range for more than 50 seconds (secondary maintenance) can do.
  • the upper limit of the secondary temperature increase rate does not need to be particularly specified, but is preferably set to 100°C/s or less. If the secondary heating or secondary holding temperature is less than 300 ° C, or the holding time is less than 50 seconds, tempered martensite is excessively formed, and the silicon (Si) and aluminum (Al) content control in the steel is insufficient, so the purpose It is difficult to secure the retained austenite fraction.
  • the secondary maintenance After the secondary maintenance, it can be cooled to room temperature (secondary cooling) at an average cooling rate of 1°C/s or more.
  • the high-strength steel sheet with excellent workability manufactured by the above-described manufacturing method may include tempered martensite, bainite, retained austenite and ferrite as a microstructure, and as a preferred example, 30 to 70% by volume fraction of tempered martensite, 10-45% bainite, 10-40% retained austenite, 3-20% ferrite and unavoidable structure.
  • the high-strength steel sheet with excellent workability produced by the above-described manufacturing method as shown in the following [Relational Expression 1], the average total content of silicon (Si) and aluminum (Al) contained in the steel sheet ([Si + Al] av , weight %) of the average total content of silicon (Si) and aluminum (Al) contained in ferrite ([Si+Al] F , wt%) may satisfy the range of 1.02 to 1.45, and the following [Relational Expression]
  • the balance of tensile strength and elongation expressed in 2] (B T E ) is 22,000 (MPa%) or more
  • the balance between tensile strength and hole expansion rate (B T H ) expressed in [Relational Expression 3] below is 7*10 6 (MPa 2 % 1/2 ) or more
  • the bending workability ( BR ) expressed by [Relational Expression 4] below may satisfy the range of 0.5 to 3.0.
  • R means the minimum bending radius (mm) at which cracks do not occur after the 90° bending test
  • t means the thickness (mm) of the steel sheet.
  • a steel slab having a thickness of 100 mm having the alloy composition shown in Table 1 (the remainder being Fe and unavoidable impurities) was prepared, heated at 1200° C., and then finish hot rolling was performed at 900° C. Then, it was cooled at an average cooling rate of 30° C./s, and wound at the coiling temperature of Tables 2 and 3 to prepare a hot-rolled steel sheet having a thickness of 3 mm.
  • the hot rolled steel sheet was subjected to hot rolling annealing heat treatment under the conditions of Tables 2 and 3. Then, after removing the surface scale by pickling, cold rolling was performed to a thickness of 1.5 mm.
  • the microstructure of the thus prepared steel sheet was observed and the results are shown in Tables 6 and 7.
  • ferrite (F), bainite (B), tempered martensite (TM), and perlite (P) were observed through SEM after nital etching the polished specimen cross section.
  • the fractions of bainite and tempered martensite, which are difficult to distinguish among them, were calculated using an expansion curve after evaluation of dilatation.
  • fresh martensite (FM) and retained austenite (residual ⁇ ) are also difficult to distinguish
  • the fraction of retained austenite calculated by X-ray diffraction method is subtracted from the fraction of martensite and retained austenite observed by the SEM. The value was determined as the fresh martensite fraction.
  • the average total content ([Si+Al] F , wt%) of silicon (Si) and aluminum (Al) contained in ferrite was measured using an EPMA (Electron Probe MicroAnalyser), and the silicon (Si) and The average total content of aluminum (Al) ([Si+Al] av , wt%) was calculated from the alloy composition content of the steel sheet.
  • EPMA Electro Probe MicroAnalyser
  • TS and elongation were evaluated through a tensile test, and tensile strength (TS) and elongation were evaluated using specimens taken according to JIS No. (El) was measured.
  • the bending workability (R/t) was evaluated by the V-bending test, and the minimum bending radius R where cracks do not occur after 90° bending test by taking a specimen based on the 90° direction with respect to the rolling direction of the rolled sheet It was calculated by dividing by the thickness t of .
  • the hole expansion rate (HER) was evaluated through the hole expansion test, and after forming a 10mm ⁇ punching hole (die inner diameter 10.3mm, clearance 12.5%), a conical punch with an apex angle of 60° was applied with the burr of the punching hole outside. After inserting into the punching hole in the desired direction, pressing and expanding the periphery of the punching hole at a moving speed of 20 mm/min, it was calculated using the following [Relational Expression 5].
  • Hole expansion rate (HER, %) ⁇ (D - D 0 ) / D 0 ⁇ x 100
  • D means the hole diameter (mm) when the crack penetrates the steel plate along the thickness direction
  • D 0 means the initial hole diameter (mm).
  • Hot-rolled steel sheet coiling temperature (°C) Hot-rolled steel sheet annealing temperature (°C) Hot-rolled steel sheet annealing time (s) Primary average heating rate (°C/s) Primary holding temperature section (°C) 1st holding time (s)
  • Hot-rolled steel sheet coiling temperature (°C) Hot-rolled steel sheet annealing temperature (°C) Hot-rolled steel sheet annealing time (s) Primary average heating rate (°C/s) Primary holding temperature section (°C) 1st holding time (s) 26 L 550 700 1400 10 Lee Sang Station 120 27 M 450 800 1000 10 Lee Sang Station 120 28 N 400 750 1100 10 Lee Sang Station 120 29 O 500 800 1500 10 Lee Sang Station 120 30 P 550 700 1300 10 Lee Sang Station 120 31 Q 450 800 1200 10 Lee Sang Station 120 32 R 500 700 1400 10 Lee Sang Station 120 33 S 550 750 1200 10 Lee Sang Station 120 34 T 550 750 1100 10 Lee Sang Station 120 35 U 400 800 1000 10 Lee Sang Station 120 36 V 500 700 1200 10 Lee Sang Station 120 37 W 450 800 1400 10 Lee Sang Station 120 38 X 450 700 1500 10 Lee Sang Station 120 39 Y 500 750 1100 10 Lee Sang Station 120 40 XA 500
  • Specimens 2 to 5 overlap the alloy composition range of the present invention, but since the hot rolling annealing temperature and time are out of the scope of the present invention, it can be confirmed that pickling failure occurs or fracture occurs during cold rolling.
  • Specimen 12 had a low primary cooling stop temperature, so tempered martensite was excessively formed, and retained austenite was low.
  • [Si+Al] F / [Si+Al] av was greater than 1.45, the balance of tensile strength and elongation (TS ⁇ El) was less than 22,000 MPa%, and the bending workability (R/t) was 3.0. can be seen to exceed .
  • Specimen 13 had a high primary cooling stop temperature, so bainite was excessively formed, and tempered martensite was less formed.
  • TS ⁇ El tensile strength and elongation
  • TS 2 ⁇ HER 1/2 tensile strength and hole expansion rate
  • Specimen 14 had a low secondary heating or holding temperature, so tempered martensite was excessively formed and retained austenite was low.
  • [Si+Al] F / [Si+Al] av exceeded 1.45, the balance of tensile strength and elongation (TS ⁇ El) was less than 22,000 MPa%, and the bending workability (R/t) was 3.0 can be seen to exceed .
  • Specimen 15 had insufficient residual austenite formation due to high secondary heating or holding temperature, [Si+Al] F / [Si+Al] av exceeding 1.45, and the balance of tensile strength and elongation (TS ⁇ El) was 22,000 MPa. It can be seen that less than %
  • Specimen 16 had insufficient secondary holding time, so tempered martensite was excessively formed, and retained austenite was low.
  • [Si+Al] F / [Si+Al] av exceeded 1.45, the balance of tensile strength and elongation (TS ⁇ El) was less than 22,000 MPa%, and the bending workability (R/t) was 3.0 can be seen to exceed .
  • Specimens 40 to 48 meet the manufacturing conditions presented in the present invention, but are outside the alloy composition range.
  • [Si+Al] F / [Si+Al] av of the present invention the balance of tensile strength and elongation (TS ⁇ El), and the balance of tensile strength and hole expansion (TS 2 ⁇ HER 1/2 ) are 7*10 It can be seen that 6 (MPa 2 % 1/2 ) and bending workability (R/t) conditions are not satisfied at the same time.
  • specimen 42 the total content of aluminum (Al) and silicon (Si) is less than 1.0%, [Si+Al] F / [Si+Al] av , the balance of tensile strength and elongation (TS ⁇ El) and bending workability ( R/t) condition is not satisfied.

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Abstract

La présente invention concerne une tôle d'acier qui peut être utilisée pour des pièces d'automobile et similaires, et concerne une tôle d'acier ayant un équilibre de résistance-ductilité et de résistance-expansion de trou supérieur et une aptitude au façonnage sous flexion supérieure, et un procédé de fabrication de celle-ci.
PCT/KR2020/016650 2019-12-18 2020-11-24 Tôle d'acier à haute résistance ayant une aptitude au façonnage supérieure, et son procédé de fabrication WO2021125595A1 (fr)

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EP20904161.5A EP4079905A4 (fr) 2019-12-18 2020-11-24 Tôle d'acier à haute résistance ayant une aptitude au façonnage supérieure, et son procédé de fabrication
CN202080087079.XA CN114846167A (zh) 2019-12-18 2020-11-24 加工性优异的高强度钢板及其制造方法
JP2022536968A JP7554828B2 (ja) 2019-12-18 2020-11-24 加工性に優れた高強度鋼板及びその製造方法
US17/785,869 US20230046327A1 (en) 2019-12-18 2020-11-24 High strength steel sheet having superior workability and method for manufacturing same
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JP2023507956A (ja) 2023-02-28
EP4079905A1 (fr) 2022-10-26
JP2024109830A (ja) 2024-08-14
KR102321287B1 (ko) 2021-11-03
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