WO2021114602A1 - 3d printing method and 3d printing system - Google Patents

3d printing method and 3d printing system Download PDF

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Publication number
WO2021114602A1
WO2021114602A1 PCT/CN2020/097098 CN2020097098W WO2021114602A1 WO 2021114602 A1 WO2021114602 A1 WO 2021114602A1 CN 2020097098 W CN2020097098 W CN 2020097098W WO 2021114602 A1 WO2021114602 A1 WO 2021114602A1
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Prior art keywords
print head
printing
resin
sample
layer
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PCT/CN2020/097098
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French (fr)
Chinese (zh)
Inventor
夏春光
亚历山大斯洛克
约翰科瓦拉
杰森巴希
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深圳摩方新材科技有限公司
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Priority to PCT/CN2020/097098 priority Critical patent/WO2021114602A1/en
Publication of WO2021114602A1 publication Critical patent/WO2021114602A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B29C64/129Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/20Apparatus for additive manufacturing; Details thereof or accessories therefor
    • B29C64/264Arrangements for irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y30/00Apparatus for additive manufacturing; Details thereof or accessories therefor

Definitions

  • the invention relates to 3D printing technology, in particular to a 3D printing method and a 3D printing system.
  • Rapid prototyping includes a series of technologies that can be used to create real scale models of production components directly from computer aided design (computer aided design CAD) in a fast (faster than before) way. Since its disclosure in US Patent 4,575,330, stereolithography technology has greatly helped engineers visualize complex 3D part geometries, detect errors in prototype schematics, test key components, and verify with relatively low cost and faster timeframes than before. Theoretical design.
  • micro-electro-mechanical systems led to the emergence of micro-stereolithography ( ⁇ SL), which inherited the basic principles of traditional stereolithography. But it has a higher spatial resolution. For example, K Ikuta and K.
  • the invention of projection micro-stereolithography (P ⁇ SL) by Bertsch et al. has greatly increased the speed.
  • "Micro-stereolithography technology using liquid crystal display as a dynamic mask generator” Microsystem Technologies, p42-47, 1997; Beluze et al., "Micro-stereolithography technology: a new process for constructing complex 3D objects, MEM/MOEM Symposium on the design, testing and micromachining of ", SPIE Conference Proceedings, v3680, n2, p808-817, 1999.
  • the core of this technology is a high-resolution spatial light modulator, which can be a liquid crystal display (LCD) panel or a digital light processing (DLP) panel, both of which can be obtained from the microdisplay industry.
  • LCD liquid crystal display
  • DLP digital light processing
  • the display size of the DLP chip is currently limited to about 13mm. Therefore, when the projected pixel size is the same as the physical pixel size (5 to 8 microns), a single exposure area will be limited to half an inch. In order to print on a larger area with a single projection, the size of the projected pixels needs to be increased, thereby reducing the printing resolution (that is, the size of the projected pixels).
  • the first uses a free surface, and the layer thickness is defined by the distance between the resin free surface and the sample stage. Due to the slow viscous movement of the resin, it takes more than half an hour to define a 10um thick resin layer with a viscosity of 50cPs when the printing area is larger than 1cm x 1cm.
  • the second and third methods use transparent films or hard windows. Similarly, for these two cases, there is currently no good way to define a resin layer of 10um or less on an area of 5cm X 5cm or larger, especially for the film case, even if it is faster than the free surface case , It is still unimaginable slow.
  • a hard window the fluid force generated when the two surfaces of the sample and the hard window approach and separate before or after exposure is large enough to damage the sample.
  • a 3D printing method including:
  • Slicing generating a 3D digital model of the sample to be printed, cutting the 3D digital model into an image sequence, each image in the image sequence represents a layer of the 3D digital model, and controlling the printing direction of the print head according to the slicing direction of the model;
  • the image is sent to the micro display device, and the micro display device with a light source projects the image on the interface between the transparent window at one end of the print head and the resin through the projection lens;
  • the image acquisition unit collects the image reflected by the spectroscope and detects the quality of the projected image, and prints according to the quality control of the detection;
  • Exposure printing The micro display device with a light source irradiates the projected image with light, and the exposure produces a cured layer, which represents the corresponding layer of the projected image in the 3D digital model.
  • the print head moves to a new area, the cone of the print head The hard edge of the end is used as a resin layer scraper.
  • the coating thickness is determined by the gap between the end of the print head and the top layer of the sample. Since the print head is located 1 to 5 mm below the free surface of the resin, the resin behind it flows and covers the previous Bare area
  • the sample and the substrate are immersed in the resin and immersed 2mm to 8mm so that the new resin covers the top surface of the sample, and then the substrate drives the sample Return to position and adjust the distance between the print head and the sample to the thickness of the next layer.
  • the print head moves in from the outside of the sample, scrapes, coats and gradually exposes the new image. The print head pushes the excess resin back into the resin tank.
  • the print head has a hollow trapezoidal cylindrical structure, and a lock ring is provided at the tapered end of the print head.
  • the tapered end of the print head covers the non-stick film and forms a transparent window, and the lock ring is placed on the transparent The upper part of the window.
  • the print head is located at the lower part of the substrate for printing, the transparent window of the print head is located 0.5-2mm below the free surface of the resin, and the print head and the substrate move relative to each other in the X/Y/Z direction to define the layer And the splicing layer is faceted.
  • the substrate is set on a printing platform, and the printing platform drives the substrate to move in the X, Y, and Z directions according to printing.
  • the head pressure is to compensate for the deformation of the transparent window caused by contact with the printing resin.
  • P 0 is the pressure of the atmospheric pressure of the non-adhesive film of the print head
  • P 1 ⁇ 1 gh
  • ⁇ 1 is the resin density, g acceleration of gravity, and h
  • the depth of the non-stick film of the print head under the resin; during printing, the pressure in the print head is controlled by the flow of gas. If the pressure sensor detects the difference between the pressure of the print head and the set pressure, the mass flow controller is controlled according to the PID setting Adjust the flow rate until the pressure in the print head reaches the set value.
  • it further includes a restrictor arranged at the downstream outlet of the print head, the restrictor is in a flow-blocking state, and the flow rate of the restrictor is proportional to the pressure of the print head.
  • the printed image is larger than a single exposure size
  • stitch printing is performed, the image is divided into layer parts, the layer parts are printed step by step, and the edges are stitched together into a whole layer, and each layer part overlaps on the stitching edge. -20 microns.
  • error compensation is performed on the X/Y direction movement coordinates of the printing platform (X 0 +XError(X 0 ,Y 0 ),Y 0 +YError(X 0 ,Y 0 )), (X 0 ,Y 0 ) are theoretical coordinates,
  • XError(X 0 ,Y 0 ) C 1 +C 2 +C 3 Y 0 +C 4 X 0 Y 0 +C 5 X 0 2 +C 6 Y 0 2
  • YError(X 0 ,Y 0 ) D 1 +D 2 +D 3 Y 0 +D 4 X 0 Y 0 +D 5 X 0 2 +D 6 Y 0 2
  • the measurement error of the stitching point in the X direction is calculated by the quadratic least squares method.
  • the D 1 -D 6 polynomial coefficients are calculated based on the measurement error of the splicing point in the Y direction by the quadratic least squares fitting calculation during splicing printing.
  • the micro display device when the print head is moved and stopped for exposure, the micro display device is controlled to project a picture on the center of the non-stick film of the print head, and the image acquisition unit captures and analyzes the imaging quality, and compares the imaging with the set theoretical value Compare, if the non-stick mold of the print head is deformed, according to the deformation formula
  • Adjust the flow to adjust the pressure in the print head is proportional to the pressure difference, ⁇ Poisson coefficient, a is the radius of the non-stick mold of the print head, E Young's modulus, h is The thickness of the non-stick mold of the print head, p is the pressure difference between the two sides of the non-stick mold of the print head.
  • a 3D printing system including: an image system that establishes a 3D digital model and cuts the 3D digital model into an image sequence, a control system, and a micro-display of the interface between the non-stick mold and the resin that is controlled to receive the series of pictures and project them to the print head A device, a projection lens set corresponding to the micro display device and controlled to perform projection, an image acquisition unit that collects and detects the quality of the projected image, and is set corresponding to the image acquisition unit and reflects the projected image to the image acquisition
  • the unit receives and collects the spectroscope, the printing platform, the resin tank provided on the printing platform and loaded with resin, the lifting device provided on the printing platform, the substrate provided in the resin tank and connected with the lifting device, and the A print head with a hollow trapezoidal structure corresponding to the substrate, the hard edge of the print head is used as a squeegee to scrape the resin during printing, and the print head includes: an inner cavity of a hollow trapezoidal cylinder, and a lower
  • the above-mentioned 3D printing method and 3D printing system use the hard edge of the lower end of the print head as a coating scraper, and the splicing movement and the coating step are performed at the same time, which saves time and improves efficiency.
  • non-stick membrane is used to make the membrane and the sample stagger and separate, which reduces the force on the sample during separation by an order of magnitude.
  • a unique method of stitching multiple exposure printing is used to solve the problem, which can move the image (lens) or the sample. Save time and improve efficiency.
  • FIG. 1 is a schematic diagram of a part of the structure of a 3D printing system according to an embodiment of the present invention
  • FIG. 2 is a cross-sectional view of a partial structure of a print head according to an embodiment of the present invention
  • FIG. 3 is a schematic diagram of trajectory errors in the x and y directions of the 3D printing system during splicing printing according to an embodiment of the present invention
  • FIG. 4 is a schematic diagram of three exposure modes according to an embodiment of the present invention.
  • FIG. 5 is a schematic diagram of a printing process with a print head located above a substrate according to an embodiment of the present invention
  • FIG. 6 is a schematic diagram of a printing process in which the substrate is located above the print head according to an embodiment of the present invention
  • FIG. 7 is a schematic diagram of a meniscus printing process according to an embodiment of the present invention.
  • the 3D printing method according to an embodiment of the present invention includes:
  • Slicing generating a 3D digital model of the sample to be printed, cutting the 3D digital model into an image sequence, each image in the image sequence represents a layer of the 3D digital model, and controlling the printing direction of the print head according to the slicing direction of the model;
  • the image is sent to the micro display device, and the micro display device with a light source projects the image on the interface between the transparent window at one end of the print head and the resin through the projection lens;
  • the image acquisition unit collects the image reflected by the spectroscope and detects the quality of the projected image, and prints according to the quality control of the detection;
  • Exposure printing The micro display device with a light source irradiates the projected image with light, and the exposure produces a cured layer, which represents the corresponding layer of the projected image in the 3D digital model.
  • the print head moves to a new area, the cone of the print head The hard edge of the end is used as a resin layer scraper.
  • the thickness of the coating is determined by the gap between the end of the print head and the top layer of the sample.
  • the resin behind the print head flows and covers the previously exposed area;
  • the micro display device of the present invention is a DLP with a 405 nm light source.
  • the printing of the present invention starts from the establishment of a geometric model by a computer or an image system, and the 3D digital model is cut into a two-dimensional picture in one direction, which is generally black and white, and may have grayscale. Each picture represents a thin layer in the 3D digital model.
  • the slicing direction of the model will be the printing direction of the printer.
  • the resulting series of pictures will be read by the printer in turn and projected on the interface between the non-stick film and resin at the end of the print head through DLP with a 405-nanometer light source.
  • a graphic image acquisition unit such as a CCD camera will be removed from the spectroscope.
  • the reflected image judges the quality of the projected image.
  • a certain thickness of cured layer will be produced where there is light, which represents the corresponding layer in the model represented by the projected picture.
  • the print head will move away from the sample.
  • the sample stage will return according to different printing forms. After returning, the distance between the print head and the sample is the thickness of the next layer to be printed, and the gap between the sample and the print head film will be filled with the resin needed to print the next layer Floor. The exposure is repeated in sequence, and the model is copied in the resin tank as the sample stage descends layer by layer.
  • micro display devices such as LCD or DLP chips have a certain size, such as 1920X1080 pixel DLP, with an optical precision of ten microns
  • the printing area covered by a chip is only 19.2mmX10.8mm. Therefore, when the size of the sample is smaller than a chip When covering an area, we call it single projection mode.
  • the present invention adopts the splicing printing mode. In the stitching printing mode, the picture representing the first layer of the model will be further cut into multiple pictures that are not larger than a single DLP resolution, that is, the layer part.
  • a 3800X2000 pixel picture can be cut into four 1900X1000 sub-pictures, and each sub-picture will represent a quarter of the area in a layer. For each layer in the model, it will be completed through multiple exposures, and all the sub-pictures of the current layer are projected in turn.
  • a certain amount of overlap is usually given, usually 5-20 microns.
  • the position and overlap of the exposure of each area are precisely controlled by the XY axis combination.
  • There are two coordinate systems in the system one is a DLP/LCD vertical coordinate system, and the other is a motion coordinate system composed of XY axes.
  • the two coordinate systems are not completely parallel due to mechanical assembly errors, there will be misalignment errors in adjacent areas during stitching and printing. For this reason, the measured error is compensated in the stitching printing mode. Due to the existence of the X and Y axes of the printing platform, for samples smaller than the printer's print format, multiple identical samples can be printed repeatedly in the entire format, which can increase the speed of mass production. This is the matrix printing mode.
  • the transparent window of the print head is 0.5-2mm below the free surface of the resin, and the print head and the substrate move relative to each other in the X/Y/Z direction to define the layer and splicing layer facets.
  • the sample and substrate are immersed in resin and immersed 2mm to 8mm so that the new resin covers the top surface of the sample, and then the substrate drives the sample back to position, adjust the print head and sample The distance between is the thickness of the next layer to be printed.
  • the print head moves in from the outside of the sample, scrapes, coats and gradually exposes the new layer, while the print head pushes the excess resin back into the resin tank.
  • the print head 30 of this embodiment has a hollow trapezoidal cylindrical structure, and a lock ring 36 is provided at the tapered end.
  • the tapered end of the print head 30 covers the non-stick film and forms a transparent window 34.
  • the lock ring 36 is placed on the upper part of the transparent window 34.
  • the substrate of this embodiment is set on a printing platform, and the printing platform drives the substrate to move in the X, Y, and Z directions according to printing.
  • P 0 is the pressure of the air atmosphere where the non-stick film of the print head is located
  • P 1 ⁇ 1 gh
  • ⁇ 1 is the resin density, g acceleration of gravity
  • h is the depth of the non-stick film of the print head under the resin; when printing, air is passed through
  • the flow rate controls the pressure in the print head. If the pressure sensor detects that the pressure of the print head is different from the set pressure, the mass flow controller is controlled to adjust the flow according to the PID setting until the pressure in the print head reaches the set value.
  • the print head 30 of this embodiment further includes a flow restrictor 312 provided at the downstream outlet of the print head 30.
  • the orifice of the orifice at the downstream outlet of the restrictor 312 is small enough ( ⁇ 50 microns) to be in a flow-blocking state, and its flow rate is only proportional to the upstream pressure in the print head.
  • the upstream mass flow controller (MFC mass flow controller) will increase the flow appropriately according to the PID (Proportion Integration Differentiation) setting , Until the pressure in the print head reaches the set value. vice versa.
  • the printed image is larger than a single exposure size, stitch printing is performed, the image is divided into multiple layer parts, the layer parts are printed step by step, and the overlapping edges are stitched into a whole layer, and each layer part overlaps on the stitching edge 5-20 microns.
  • the printing process first generates a 3D model in a computer or image system, and then cuts the digital model into a series of images, where each image represents a layer of the model (such as 5 to 20 microns).
  • the control computer or imaging system sends the image to the micro display device (such as DLP (digital light processing) or LCD (liquid crystal display)), and the image is projected onto the bottom surface of the print head (wet surface) through the projection lens )on.
  • the bright areas converge, while the dark areas remain liquid. Due to the size limitation of LCD or DLP chips, such as a DLP chip with 1920X1080 pixels at 10um printing optical resolution, a single exposure only covers an area of 19.2mmX10.8mm.
  • the cross section of the sample is larger than 19.2mmX10.8mm, it cannot be printed using a single exposure method.
  • the invention provides a multi-exposure splicing printing method.
  • the image representing the layer of the 3D model is further divided into multiple smaller images or layer parts, each of which is not larger than the DLP pixel resolution.
  • an image with a pixel resolution of 3800X2000 can be divided into four 1900X1000 sub-images, and each sub-image represents a quarter of the layer.
  • the entire layer of the model will be printed section by section based on the sub-image.
  • XY printing platform components can precisely control the precise position and overlap amount.
  • A is the size of a single exposure
  • B is the result of accurate alignment in the x direction
  • C is the result of an error offset in the x direction
  • B' is the result of accurate alignment in the y direction
  • the error requirement is less than 10um, and the assembly tolerance of the stage is usually within the allowable range; and the offset is not linear with the moving distance of the printing platform. Therefore, in the present invention, the offset is measured at 5 or more uniformly distributed points in the x and y directions of the square sample printed in the full range.
  • the offset error curve of at least second-order polynomial interpolation will be introduced into the translation in the XY direction to compensate for the offset, so as to ensure that the accuracy of the spliced printed samples is within the specification range.
  • XError(X 0 ,Y 0 ) C 1 +C 2 +C 3 Y 0 +C 4 X 0 Y 0 +C 5 X 0 2 +C 6 Y 0 2
  • YError(X 0 ,Y 0 ) D 1 +D 2 +D 3 Y 0 +D 4 X 0 Y 0 +D 5 X 0 2 +D 6 Y 0 2
  • the measurement error of the stitching point in the X direction is calculated by the quadratic least squares method.
  • the D 1 -D 6 polynomial coefficients are calculated based on the measurement error of the splicing point in the Y direction by the quadratic least squares fitting calculation during splicing printing.
  • XError(x,y) C 1 +C 2 x+C 3 y+C 4 xy+C 5 x ⁇ 2+C 6 y ⁇ 2,
  • C 1 ⁇ 6 and D 1 ⁇ 6 can be calculated by the quadratic least squares fitting calculation based on the measurement errors in the X direction and the Y direction at 171 points. In this way, the axis movement error distribution in the entire printing area is obtained.
  • These two error formulas will be used to correct the movement error of the axis. For example, the axis will go to the theoretical value (X 0 , Y 0 ). According to the error formula, the control command of the axis requires the axis to go to (X 0 +XError (X 0 ,Y 0 ),Y 0 +YError(X 0 ,Y 0 )).
  • the image acquisition unit captures and analyzes the imaging quality, and compares the imaging with the set theoretical value. If the print head is not sticky Mold deformation, according to the deformation formula
  • Adjust the flow rate to adjust the pressure in the print head is proportional to the pressure difference, ⁇ Poisson coefficient, a is the radius of the non-stick mold of the print head or half of the diagonal length, E Yang The modulus, h is the thickness of the non-stick mold of the print head, and p is the pressure difference between the two sides of the non-stick mold of the print head.
  • the 3D printing system 100 of an embodiment of the present invention includes: an image system that establishes a 3D digital model and cuts the 3D digital model into an image sequence, a control system, and a controlled receiving image and projecting it to the print head
  • the micro display device 50 of the interface between the non-stick mold and the resin, the projection lens 40 that is set corresponding to the micro display device and controlled to perform projection, the image acquisition unit 55 that collects and detects the quality of the projected image, and the image acquisition unit 55 corresponds to Set and reflect the projected image to the image acquisition unit 55 to receive and collect the spectroscope 60, the printing platform 80, the resin tank 70 arranged on the printing platform 80 and loaded with resin, the lifting device 85 arranged on the printing platform 80, and the setting A substrate 90 in the resin tank 70 and connected to the lifting device 85, and a print head 30 with a hollow trapezoidal structure provided corresponding to the substrate 90.
  • the print head 30 includes: a hollow trapezoidal inner cavity 32, a transparent window 34 formed by a non-stick film covering the lower end, a lock ring 36 arranged at the lower end and placed on the upper part of the transparent window, and arranged at the upper end to control the input gas
  • a mass flow controller 38 for the pressure of the flow to the non-stick film and a restrictor 39 provided at the downstream outlet of the print head 30 and placed on the upper part of the lock ring 36.
  • the image system and control system of this embodiment can be implemented by using the computer 20, or can be implemented by using a graphics processing chip and a control chip, respectively.
  • micro display device of this embodiment is a DLP or LCD chip. Of course, other chips can also be used as needed.
  • the image acquisition unit of this embodiment can be implemented by using a CCD.
  • CCD complementary metal-oxide-semiconductor
  • other devices with image acquisition and processing functions such as CMOS, can also be used.
  • the substrate 90 of this embodiment is connected by a substrate arm 92 lifting device 85.
  • the lifting device 85 is provided on the printing platform 80.
  • the 3D printing method of the present invention provides a method to control the layer thickness in a larger printing area more accurately and faster at a greater speed, for example, a 10cm ⁇ 10cm printing area with a layer thickness of 10um.
  • the print head is immersed several millimeters in the photosensitive resin. In another embodiment, the print head is a few hundred microns above the resin surface where the resin meniscus is formed.
  • the print head of this embodiment can be as large as one exposure of the entire DLP chip, or it can cover only a part of the DLP chip.
  • the 3D printing method of the present invention not only greatly improves the dimensional accuracy of samples printed using, for example, a projection micro-stereolithography system, but also greatly improves the printing speed by eliminating the need to close or separate two contact surfaces in resin.
  • the tapered end (small end of the trapezoid) of the print head of this embodiment is covered and sealed by covering a non-stick transparent film to form a transparent window.
  • the transparent window of this embodiment can be made of a gas-permeable material, especially an oxygen-permeable material, such as polydimethylsiloxane (PDMS) or Teflon AF (DuPont).
  • PDMS polydimethylsiloxane
  • Teflon AF DuPont
  • the print head of this embodiment may be provided with an ultrasonic source with a frequency exceeding 10 kHz to increase the flow rate of the resin during its movement when it is in contact with the resin.
  • the print head of this embodiment can be controlled by pressure to compensate for the deformation of the transparent window caused by contact with the printing resin.
  • the pressure control gas can prevent the sample from sticking to the transparent window during the polymerization process, and the gas can be oxygen or a mixture thereof.
  • the printing platform is used to move in the XY direction to provide three printing modes.
  • a single exposure mode When only a sample smaller than the size of a single exposure is needed, it is called a single exposure mode. If multiple samples are needed, the printing platform will gradually move and print the same samples in the array, which is called the array exposure mode.
  • the system When the sample size increases to exceed the size of a single exposure, the system will further divide a layer into multiple parts by overlapping 5 ⁇ m to 20 ⁇ m on the common or adjacent edges, and stitch adjacent parts into a whole layer. Stitching exposure mode. It is also possible to combine stitching mode and array mode.
  • the interpolation offset error curve based on the measurement data from the actual sample will be used to perform mechanical tolerance compensation during the translation of the printing platform in the XY direction to ensure that the accuracy of the spliced printed sample is within the specification range.
  • the print head 30 is immersed in the resin for 1 to 10 mm.
  • the hard edge of the cone end of the print head will act as a resin coating blade.
  • the coating thickness is determined by the gap between the flat end of the print head and the top layer of the sample.
  • the resin behind the print head flows under the action of gravity and surface tension and covers the previously exposed area.
  • the print head will move beyond the boundary of the sample before the sample stage moves down to a thickness to define the next layer of fresh resin.
  • the print head will move in and begin to scan and print the next layer step by step.
  • the sample stage of the present invention can drive the sample to move in the X, Y, and Z directions. You can also move the print heads to move each other by keeping the sample still.
  • the print head is 100 to 500 microns above the resin level together with the top layer of the sample.
  • the sample and substrate will be immersed 2mm to 8mm into the free surface of the resin so that the fresh resin covers the top surface of the sample. Then, the sample will return with a gap equal to the thickness of the next layer from the print head. Likewise, the print head will move in from the outside of the sample, scratch, coat, and gradually expose a new layer.
  • the size of the transparent window of the print head of the present invention should cover the projection of a single DLP/LCD chip. For example, if the projection of a 17mm chip is 20mm and the pixel resolution is 10 ⁇ m, the diameter of the window can be about 22mm.
  • the transparent window at the tapered end of the print head 30 of this embodiment may be a DuPont Teflon AF2400 film with a thickness of 130 ⁇ m, which is breathable and has good light transmittance. Gas permeability, especially oxygen permeability, makes the film non-sticky during photopolymerization, because oxygen is a photocrosslinking inhibitor.
  • the transparent window of the print head can also be made of polydimethylsiloxane (PDMS) film, or surface-coated with polydimethylsiloxane (PDMS).
  • is the Poisson's ratio of the membrane
  • is the radius of the cone of the circular membrane
  • E is the Young's modulus
  • h is the thickness
  • p is the pressure difference between the two sides of the membrane.
  • the combination of a mass flow controller (MFC), a restrictor located downstream and a pressure sensor on the print head will control the pressure P in the print head.
  • MFC mass flow controller
  • the thickness of the non-stick oxygen suppression layer can be improved by increasing the oxygen concentration in the print head; therefore, MFC can use the flow rate of various oxygen concentration mixtures to control the pressure.
  • the printing process of an embodiment of the present invention starts with generating a 3D model in a computer, and then cutting the digital model into a series of images, each of which represents a layer (5 to 20 microns) of the model, and the control computer sends the image to the micro display
  • the device is such as LCD or DLP chip, and then the image is projected onto the bottom surface (wet surface) of the print head through a projection lens.
  • the bright areas converge, while the dark areas remain liquid.
  • Due to the size limitation of the LCD or DLP chip for example, a DLP chip with 1920X1080 pixels at 10um printing optical resolution, a single exposure only covers an area of 19.2mmX10.8mm. Therefore, if the cross-section of the sample is larger than 19.2mmX10.8mm, the single exposure method cannot be used for printing.
  • the present invention proposes a multi-exposure splicing printing method.
  • the image representing a layer of the 3D model is further divided into a plurality of smaller images or layer parts, each image is not larger than the DLP pixel resolution.
  • an image with a pixel resolution of 3800X2000 can be divided into four 1900X1000 sub-images, each of which represents a quarter of the layer.
  • the entire layer of the model will be printed step by step based on the sub-images.
  • the edges usually overlap by about 5-20 microns.
  • the printing platform can precisely control the precise position and overlap amount.
  • the invention is provided with two coordinate systems: one is the vertical coordinate system with the DLP/LCD, and the other is the movement coordinate system of the printing platform along the XY direction.
  • A is the size of a single exposure
  • B is the result of accurate alignment in the x direction
  • C is the result of an error offset in the x direction
  • B' is the result of accurate alignment in the y direction
  • the offset is measured on at least 5 uniformly distributed points in the x and y directions of the square sample printed in the full range.
  • the at least second-order polynomial error curve obtained by the least square fitting method will be used in the translation of the printing platform in the XY direction to compensate for the offset, so as to ensure that the accuracy of the spliced printed samples is within the specification range.
  • the present invention provides three printing modes ( Figure 4).
  • the printing platform When only a sample smaller than a single exposure size needs to be printed, the printing platform will not move during the printing process, which is called single exposure mode. If multiple identical samples are required, the printing platform will gradually move in the XY direction and print the same samples in an array, which is called the array exposure mode. For small batch production, this mode is much faster than the repeated single exposure mode.
  • the system When the sample size increases beyond the size of a single exposure, the system will further divide a layer into multiple parts by overlapping 5 ⁇ m to 20 ⁇ m on the common edge, and stitch adjacent parts into a whole layer. This is the stitching exposure mode.
  • the splicing mode can be used in combination with the array mode.
  • the print head 30 is located on the top of the substrate and is immersed in the resin by 1 to 10 mm ( Figure 5).
  • the depth of immersion depends on the viscosity of the resin, and thinner resins perform shallower immersion.
  • the projection lens projects the image from the LCD or DLP chip to the lower surface (wet surface) of the transparent print head.
  • the print platform in the stitching and array exposure printing mode moves along the X and Y directions or controls the print head along X Move in the /Y direction to move the print head to an adjacent area for the next exposure, but there is an overlap of about 5-20 microns on the common side, thereby fusing the adjacent parts together.
  • the hard edge of the cone end of the print head will act as a resin coating blade.
  • the coating thickness is determined by the gap between the flat end of the print head and the top layer of the sample.
  • the resin behind the print head flows under the action of gravity and surface tension and covers the previously exposed area. After printing a complete layer, the print head will move beyond the boundary of the sample before the sample stage moves down the thickness of one layer to define the next layer of fresh resin.
  • is the fluid stress tensor
  • p is the pressure
  • I is the definite tensor
  • is the fluid viscosity
  • is the velocity gradient tensor (or fluid strain tensor).
  • the configuration of the sample can be moved in the XYZ direction, or the print head can be moved while the sample remains stationary to achieve relative movement between the print head and the sample.
  • the positions of the print head and the sample substrate can be reversed.
  • the transparent window of the print head is 0.5mm to 2mm below the free surface of the resin.
  • the substrate is on the top and moves in the XYZ direction to define the layer and splicing layer sides.
  • the printed part can be guaranteed to last tens of hours without being soaked in resin during the printing process. This may be required for some hydrogel resins, because prolonged soaking in the resin will cause the printed parts to swell, which can lead to dimensional errors.
  • an ultrasonic source with a frequency greater than 10 kHz is introduced into the print head, for example, a piezoelectric ceramic is closely attached to the print head housing to increase the flow speed of the resin.
  • the print head and the top layer of the sample are raised to 100 to 500 microns above the free surface of the resin; the height depends on the viscosity of the resin.
  • the steps for printing the entire layer are the same as the above steps, but after one layer is printed, the sample and the substrate will be immersed in resin 2mm to 8mm together so that fresh resin covers the upper surface of the sample. Then, the sample will move back to the height of the print head but one small step less, which is equivalent to the thickness of the next layer.
  • the print head will move in from the outside of the sample, scratch, coat, and gradually expose a new layer. In this way, the print head pushes the excess resin back into the resin tank.
  • the invention prints on a larger area at a faster speed than the current one.
  • the 3D printing method of this embodiment generate a 3D digital model of the sample or object to be printed in a computer, and then cut the digital model into a series of image sequences, each image in the image sequence represents a layer of the 3D digital model, In this way, after each layer is formed, the sample or object is already formed.
  • the transparent print head includes a tapered end with a smooth surface.
  • the print head is located next to a resin tank containing photosensitive resin and a substrate (such as a sample holder) used to fix the sample during printing.
  • the smooth tapered end of the print head is in contact with the photosensitive resin.
  • the coating thickness is defined by the gap between the smooth tapered end of the print head and the top layer of the sample. Or if there is no print layer before, the coating thickness is the gap between the smooth tapered end of the print head and the substrate used to fix the sample.
  • the images in the image sequence will be sent to the LCD or DLP chip.
  • the chip and the light source project the image onto the smooth cone end of the transparent print head through the projection lens together with the light source, and begin to cure in the photosensitive resin area where the projected image allows the light source to reach.
  • the sample substrate and/or print head When the image is larger than the size of a single exposure or subsequent coating is to be performed, the sample substrate and/or print head will be moved to continue printing.
  • the substrate and/or the print head are moved along the X, Y, Z direction or the X, Y direction by a high-precision positioning device, and the substrate and/or the print head can be positioned in a new area or depth.
  • the interpolation offset error curve of the sample measurement data can be input into the printing platform to compensate for errors caused by mechanical tolerances.
  • the smooth tapered end of the print head is covered by a non-stick transparent and breathable film to form a transparent window and sealed, thereby preventing deformation due to the adhesion of the print head to the layer or premature curing of the resin. Accumulation at the tapered end of the print head.
  • oxygen can inhibit free radical chain reactions and can deform the print head due to the pressure of the introduced air/gas. Therefore, the pressure in the print head is usually controlled by introducing a controllable amount of gas, such as oxygen, to compensate for the deformation of the transparent window caused by the contact between the transparent window of the print head and the printing resin.
  • the digital image of the computer is projected on the transparent window of the transparent print head by the LCD or DLP microdisplay chip together with the light source through the projection lens, where the projection lens has an optical axis that intersects the sample or substrate.
  • the projection lens is located above the sample or substrate, and between the surface of the substrate and the CCD (Charge Coupled Device).
  • CCD Charge Coupled Device
  • CCD can monitor the projection on the print head, and can be focused along the optical axis through the projection lens.
  • the movement and position of the sample or substrate along the X, Y and Z directions are controlled by the printing platform.
  • the 3D printing method of the present invention enables the coating to be printed on a larger area and at a faster speed.
  • the method includes:
  • the resin tank is equipped with photosensitive resin and a substrate for fixing the sample during the printing process.
  • the end of the transparent print head is provided with a smooth tapered end in contact with the photosensitive resin.
  • the edge of the smooth cone end of the print head will act as a squeegee by moving the excess resin, so that the thickness of the coating is equal to the gap between the smooth cone end of the print head and the top layer of the sample. Or, when the coating previously used for the sample has not been printed, the thickness of the coating will be equal to the gap between the smooth tapered end of the print head and the substrate used to fix the sample.
  • the sample substrate and/or print head When the image is larger than the size of a single exposure or a subsequent coating application is to be performed, the sample substrate and/or print head will be moved to continue printing the image.
  • the printing platform can drive the substrate or sample to move in the X/Y direction, and the lifting device can drive the substrate or sample to move up and down.
  • the flat tapered end of the print head of this embodiment is covered and sealed by a transparent window formed of a non-sticky, transparent, and air-permeable film.
  • the material of the transparent window is an oxygen permeable material.
  • the material of the transparent window is polydimethylsiloxane or fluororesin Teflon AF.
  • the print head is controlled to move to an adjacent area for the next exposure.
  • the hard edge of the cone end of the print head will be used as a resin coating scraper, and the thickness of the subsequent coating is determined by the gap between the smooth cone end of the print head and the top layer of the sample.
  • the thickness of the coating will be equal to the gap between the smooth tapered end of the print head and the substrate for fixing the sample.
  • the interpolation offset error curve based on the sample measurement data enters the printing platform and moves in the X/Y direction for compensation to compensate for mechanical tolerances to ensure that the accuracy of the spliced printed samples is within the specifications.
  • an ultrasonic source with a frequency greater than 10 kHz is incorporated into the print head to increase the resin flow speed.
  • the deformation of the transparent window of the print head caused by contact with the printing resin is compensated by controlling the pressure in the print head.
  • the print head is immersed in the photosensitive resin by 1 to 10 mm. If the coating has not been applied, raise the print head together with the top layer or substrate of the sample to 100 to 500 microns above the photosensitive resin. At this time, the print head forms a photosensitive resin meniscus by contacting the photosensitive resin.
  • the pressure inside the print head is achieved by controlling the pressure of the gas introduced into the print head.
  • the gas introduced into the print head includes oxygen or a mixed gas of oxygen.
  • the digital image from the computer is projected by the LCD or DLP microdisplay chip together with the light source through the projection lens to the print head with a sealed, optically transparent and smooth cone end that is breathable.
  • the projection lens has an optical axis that intersects the sample or the substrate, and the projection lens is located above the substrate and between the substrate and the charge coupled device.
  • the charge-coupled device can monitor the projection on the print head, and can focus along the optical axis through the projection lens.
  • the movement and position of the sample substrate in the X, Y and Z directions are controlled by three precision workbenches.
  • the print head is located above the substrate. In another embodiment, the substrate is located above the print head.
  • this application can be provided as methods, systems, or computer program products. Therefore, this application may adopt the form of a complete hardware embodiment, a complete software embodiment, or an embodiment combining software and hardware. Moreover, this application may adopt the form of a computer program product implemented on one or more computer-usable storage media (including but not limited to disk storage, CD-ROM, optical storage, etc.) containing computer-usable program codes.
  • computer-usable storage media including but not limited to disk storage, CD-ROM, optical storage, etc.
  • These computer program instructions can also be stored in a computer-readable memory that can guide a computer or other programmable data processing equipment to work in a specific manner, so that the instructions stored in the computer-readable memory produce an article of manufacture including the instruction device.
  • the device implements the functions specified in one process or multiple processes in the flowchart and/or one block or multiple blocks in the block diagram.
  • These computer program instructions can also be loaded on a computer or other programmable data processing equipment, so that a series of operation steps are executed on the computer or other programmable equipment to produce computer-implemented processing, so as to execute on the computer or other programmable equipment.
  • the instructions provide steps for implementing the functions specified in one process or multiple processes in the flowchart and/or one block or multiple blocks in the block diagram.

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Abstract

A 3D printing method and system, comprising: generating a 3D digital model of a sample to be printed and cutting the 3D digital model into an image sequence; sending the images to a micro-display device, the micro-display device provided with a light source projecting the images by means of a projection lens onto an interface of an oxygen-permeable film or hard window and resin at one end of a print head; an image acquisition unit collects the images reflected back by a spectroscope and detects the quality of the projection images, and printing is controlled on the basis of the detected quality; performing exposure printing; after one layer is printed, adjusting back to position and adjusting the up-down distance between the print head and the sample to print the thickness of the next layer, the gap between the sample and the transparent window of the print head being filled with the resin required to print the next layer; and repeating exposure and printing in turn until printing is complete and the model is replicated in the resin tank; the present 3D printing method and system use the hard edge of the lower end of the print head as a coating scraper, and simultaneously implement the splicing movement and coating steps, saving time and increasing efficiency.

Description

3D打印方法及3D打印系统3D printing method and 3D printing system 技术领域Technical field
本发明涉及3D打印技术,特别涉及一种3D打印方法及3D打印系统。The invention relates to 3D printing technology, in particular to a 3D printing method and a 3D printing system.
背景技术Background technique
立体光刻技术最初被认为是一种快速成型技术。快速原型包括一系列技术,这些技术可用于以快速(比以前更快)的方式直接从计算机辅助设计(computer aided design CAD)创建生产组件的真实比例模型。自从美国专利4,575,330中公开以来,立体光刻技术已极大地帮助工程师可视化复杂的三维零件几何形状,检测原型示意图中的错误,测试关键部件以及以相对较低的成本和比以前更快的时限验证理论设计。Stereo lithography was initially considered a rapid prototyping technology. Rapid prototyping includes a series of technologies that can be used to create real scale models of production components directly from computer aided design (computer aided design CAD) in a fast (faster than before) way. Since its disclosure in US Patent 4,575,330, stereolithography technology has greatly helped engineers visualize complex 3D part geometries, detect errors in prototype schematics, test key components, and verify with relatively low cost and faster timeframes than before. Theoretical design.
在过去的几十年中,对微机电系统(micro-electro-mechanical systems MEMS)领域的不断投资导致了微立体光刻(micro-stereolithographyμSL)的出现,它继承了传统立体光刻的基本原理,但具有更高的空间分辨率。例如K Ikuta和K.Hirowatari,“使用立体平版印刷术和金属模制进行真正的三维微制造”,1993年第六届IEEE微电子机械系统研讨会,借助单光子聚合和双光子聚合技术的辅助,微立体光刻的分辨率进一步增强到了小于200nm;例如S.Maruo和K.Ikuta,“通过使用单光子吸收的聚合进行三维微加工”,Appl.Phys.Lett.,vol.76,2000;S.Maruo和S.Kawata,“用于三维微制造的两光子吸收的近红外光聚合”,J.MEMS,vol.7,pp.411,1998;S.Kawata,H.B.Sun,T.Tanaka and K.Takada,“功能微设备的细化特征”,《自然》,412卷,第697页,2001。In the past few decades, continuous investment in the field of micro-electro-mechanical systems (MEMS) led to the emergence of micro-stereolithography (μSL), which inherited the basic principles of traditional stereolithography. But it has a higher spatial resolution. For example, K Ikuta and K. Hirowatari, "True three-dimensional micro-manufacturing using stereolithography and metal molding", the 6th IEEE Symposium on Microelectronics and Mechanical Systems in 1993, with the aid of single-photon polymerization and two-photon polymerization technology , The resolution of micro-stereolithography has been further enhanced to less than 200nm; for example, S.Maruo and K.Ikuta, "Three-dimensional micromachining by polymerization using single photon absorption", Appl.Phys.Lett.,vol.76,2000; S.Maruo and S.Kawata, "Two-photon absorption near-infrared photopolymerization for three-dimensional microfabrication", J.MEMS, vol. 7, pp.411, 1998; S. Kawata, HBSun, T. Tanaka and K.Takada, "Refined Features of Functional Microdevices", "Nature", Volume 412, Page 697, 2001.
Bertsch等人的投影微立体光刻技术(PμSL)的发明极大地提高了速度。“使用液晶显示器作为动态掩模发生器的微立体光刻技术”,Microsystem Technologies,p42-47,1997年;Beluze等人,“微立体光刻技术:构建复杂3D对象的新工艺,MEM/MOEM的设计,测试和微加工专题讨论会”,SPIE会议论文集,v3680,n2,p808-817,1999。这项技术的核心是高分辨率空间光调制器,它可以是液晶显示器(LCD)面板或数字光处理(DLP)面板,它们均可从微型显示器行业获得。The invention of projection micro-stereolithography (PμSL) by Bertsch et al. has greatly increased the speed. "Micro-stereolithography technology using liquid crystal display as a dynamic mask generator", Microsystem Technologies, p42-47, 1997; Beluze et al., "Micro-stereolithography technology: a new process for constructing complex 3D objects, MEM/MOEM Symposium on the design, testing and micromachining of ", SPIE Conference Proceedings, v3680, n2, p808-817, 1999. The core of this technology is a high-resolution spatial light modulator, which can be a liquid crystal display (LCD) panel or a digital light processing (DLP) panel, both of which can be obtained from the microdisplay industry.
尽管投影微立体光刻技术已经成功地实现了具有良好分辨率的快速制造速度,但仍需要进一步的改进。Although projection micro-stereolithography technology has successfully achieved rapid manufacturing speed with good resolution, further improvements are still needed.
DLP芯片的显示尺寸目前被限制为大约13mm,因此,当投影像素尺寸与物理像素尺寸(5至8微米)相同时,单个曝光区域将被限制为半英寸。为了以单投影在更大的区域上打印,需要增加投影像素的尺寸,从而降低打印分辨率(即投影像素的尺寸)。The display size of the DLP chip is currently limited to about 13mm. Therefore, when the projected pixel size is the same as the physical pixel size (5 to 8 microns), a single exposure area will be limited to half an inch. In order to print on a larger area with a single projection, the size of the projected pixels needs to be increased, thereby reducing the printing resolution (that is, the size of the projected pixels).
在投影微立体光刻(PμSL)中,有三种类型的树脂层定义方法:第一种使用自由表面,其层厚由树脂自由表面与样品台之间的距离定义。由于树脂的缓慢粘性运动,当打印面积大于1cm X1cm时,定义粘度为50cPs的10um厚树脂层需要花费超过半小时的时间。第二种和第三种方法使用透明膜或硬窗。同样,对于这两种情况,目前都没有一种好的方法来在5cm X 5cm或更大的区域上定义10um或更薄的树脂层,特别是对于膜情况,即使它比自由表面情况更快,也仍然无法想象的慢。对于硬窗情况,在样品和硬窗体两个表面在曝光前或曝光后接近和分离时产生的流体作用力力足够大,大到会损坏样品。In projection micro-stereolithography (PμSL), there are three types of resin layer definition methods: the first uses a free surface, and the layer thickness is defined by the distance between the resin free surface and the sample stage. Due to the slow viscous movement of the resin, it takes more than half an hour to define a 10um thick resin layer with a viscosity of 50cPs when the printing area is larger than 1cm x 1cm. The second and third methods use transparent films or hard windows. Similarly, for these two cases, there is currently no good way to define a resin layer of 10um or less on an area of 5cm X 5cm or larger, especially for the film case, even if it is faster than the free surface case , It is still unimaginable slow. In the case of a hard window, the fluid force generated when the two surfaces of the sample and the hard window approach and separate before or after exposure is large enough to damage the sample.
在所有3D打印技术中,尺寸复制的准确性和效率非常重要。例如,在浸入式投影微立体光刻(PμSL)系统中(图1),对所有层的尺寸控制中拥有高精度和高效率非常重要,只有这样实际的CAD模型才可以在短时间内被精确复制出来。In all 3D printing technologies, the accuracy and efficiency of size reproduction are very important. For example, in the immersion projection micro-stereolithography (PμSL) system (Figure 1), it is very important to have high precision and high efficiency in the size control of all layers. Only in this way can the actual CAD model be accurate in a short time. Copy it out.
发明内容Summary of the invention
基于此,有必要提供一种可提高打印效率的3D打印方法。Based on this, it is necessary to provide a 3D printing method that can improve printing efficiency.
同时提供一种可提高打印效率的3D打印系统。At the same time, a 3D printing system that can improve printing efficiency is provided.
一种3D打印方法,包括:A 3D printing method, including:
切片:生成待打印的样品的3D数字模型,将3D数字模型切成图像序列,所述图像序列中的每个图像表示3D数字模型的一层,根据模型的切片方向控制打印头的打印方向;Slicing: generating a 3D digital model of the sample to be printed, cutting the 3D digital model into an image sequence, each image in the image sequence represents a layer of the 3D digital model, and controlling the printing direction of the print head according to the slicing direction of the model;
投影:将图像发送至微显示器件,带有光源的微显示器件通过投影镜头将图像投影到打印头的一端的透明窗和树脂的交界面上;Projection: The image is sent to the micro display device, and the micro display device with a light source projects the image on the interface between the transparent window at one end of the print head and the resin through the projection lens;
图像检测:图像采集单元采集分光镜反射回来的图像并检测投影图像的质 量,根据检测的质量控制进行打印;Image detection: The image acquisition unit collects the image reflected by the spectroscope and detects the quality of the projected image, and prints according to the quality control of the detection;
曝光打印:带有光源的微显示器件用光照射投影图像,曝光产生固化层,代表投影图像在3D数字模型中相应的一层,当一次曝光结束,打印头移至新区域,打印头的锥端的硬边缘被用作树脂层刮刀,涂层厚度由打印头的端部与样品顶层之间的间隙确定,由于打印头位于树脂自由面下方1到5毫米,其后方的树脂流动并覆盖先前的裸露区域;Exposure printing: The micro display device with a light source irradiates the projected image with light, and the exposure produces a cured layer, which represents the corresponding layer of the projected image in the 3D digital model. When an exposure is over, the print head moves to a new area, the cone of the print head The hard edge of the end is used as a resin layer scraper. The coating thickness is determined by the gap between the end of the print head and the top layer of the sample. Since the print head is located 1 to 5 mm below the free surface of the resin, the resin behind it flows and covers the previous Bare area
继续曝光打印:一层打印完毕后,控制打印头移动离开打印区域,打印头与样品平移脱离,调整打印头或样品台回位,打印头移动到样品边界之外,调整打印头与样品之间的上下距离为打印下一层的厚度,样品与打印头的透明窗之间的缝隙充满打印下一层所需的树脂,依次重复曝光打印,打印头刮擦、涂覆逐步曝光新一层,打印下一层,直至打印完毕,模型在树脂槽中被复制出来。Continue to expose and print: After one layer is printed, control the print head to move away from the print area, move the print head away from the sample, adjust the print head or sample stage to return, move the print head outside the boundary of the sample, adjust the print head and sample The upper and lower distance is the thickness of the next layer to be printed. The gap between the sample and the transparent window of the print head is filled with the resin needed to print the next layer. The exposure and printing are repeated in sequence, and the print head is scratched and coated to gradually expose a new layer. Print the next layer until the printing is completed and the model is copied in the resin tank.
在优选的实施例中,在树脂弯月面式打印中,当完成一层打印后,样品与基板浸入树脂中并浸入2mm至8mm,以使新的树脂覆盖样品的顶面,然后基板带动样品回位,调整打印头与样品之间距离为打印下一层的厚度,打印头从样品外部移入、刮擦、涂覆并逐步曝光新图,打印头会将多余树脂推回到树脂槽中。In a preferred embodiment, in resin meniscus printing, after one layer of printing is completed, the sample and the substrate are immersed in the resin and immersed 2mm to 8mm so that the new resin covers the top surface of the sample, and then the substrate drives the sample Return to position and adjust the distance between the print head and the sample to the thickness of the next layer. The print head moves in from the outside of the sample, scrapes, coats and gradually exposes the new image. The print head pushes the excess resin back into the resin tank.
在优选的实施例中,打印头为中空梯形柱体结构,其锥端端部设置一个锁环,所述打印头的锥端覆盖不粘膜并形成透明窗,所述锁环置于所述透明窗上部。In a preferred embodiment, the print head has a hollow trapezoidal cylindrical structure, and a lock ring is provided at the tapered end of the print head. The tapered end of the print head covers the non-stick film and forms a transparent window, and the lock ring is placed on the transparent The upper part of the window.
在优选的实施例中,打印头位于基板下部进行打印,所述打印头的透明窗位于树脂的自由表面下方0.5-2mm,打印头与基板之间沿X/Y/Z方向相对移动以定义层和拼接层分面。In a preferred embodiment, the print head is located at the lower part of the substrate for printing, the transparent window of the print head is located 0.5-2mm below the free surface of the resin, and the print head and the substrate move relative to each other in the X/Y/Z direction to define the layer And the splicing layer is faceted.
在优选的实施例中,所述基板设置在打印平台上,打印平台带动基板根据打印在X、Y、Z方向上移动,曝光打印或继续曝光打印时,根据P=P 0+P 1控制打印头压力以补偿其与打印树脂接触而引起透明窗的变形,P 0为打印头的不粘膜接触的空气大气压的压力,P 1=ρ 1gh,ρ 1为树脂密度,g重力加速度,h为打印头的不粘膜在树脂下面的深度;打印时,通过气体的流量控制打印头中的压力,若压力传感器检测到打印头的压力与设定压力有差异时,控制质量流量控制器根据PID设置调整流量,直至打印头中的压力达到设定值。 In a preferred embodiment, the substrate is set on a printing platform, and the printing platform drives the substrate to move in the X, Y, and Z directions according to printing. When exposure printing or continuing exposure printing, the printing is controlled according to P=P 0 +P 1 The head pressure is to compensate for the deformation of the transparent window caused by contact with the printing resin. P 0 is the pressure of the atmospheric pressure of the non-adhesive film of the print head, P 11 gh, ρ 1 is the resin density, g acceleration of gravity, and h The depth of the non-stick film of the print head under the resin; during printing, the pressure in the print head is controlled by the flow of gas. If the pressure sensor detects the difference between the pressure of the print head and the set pressure, the mass flow controller is controlled according to the PID setting Adjust the flow rate until the pressure in the print head reaches the set value.
在优选的实施例中,,还包括设置在打印头的下游出口的限流器,限流器处 于阻流状态,限流器流量与打印头压力成正比。In a preferred embodiment, it further includes a restrictor arranged at the downstream outlet of the print head, the restrictor is in a flow-blocking state, and the flow rate of the restrictor is proportional to the pressure of the print head.
在优选的实施例中,,若打印图像大于单个曝光尺寸则进行拼接打印,将图像划分为层部分,逐步打印层部分,并叠边拼接成整层,每个层部分在拼接边上重叠5-20微米。In a preferred embodiment, if the printed image is larger than a single exposure size, stitch printing is performed, the image is divided into layer parts, the layer parts are printed step by step, and the edges are stitched together into a whole layer, and each layer part overlaps on the stitching edge. -20 microns.
在优选的实施例中,,打印时,对打印平台的X/Y方向运动坐标进行误差补偿(X 0+XError(X 0,Y 0),Y 0+YError(X 0,Y 0)),(X 0,Y 0)为理论坐标, In a preferred embodiment, when printing, error compensation is performed on the X/Y direction movement coordinates of the printing platform (X 0 +XError(X 0 ,Y 0 ),Y 0 +YError(X 0 ,Y 0 )), (X 0 ,Y 0 ) are theoretical coordinates,
XError(X 0,Y 0)=C 1+C 2+C 3Y 0+C 4X 0Y 0+C 5X 0 2+C 6Y 0 2 XError(X 0 ,Y 0 )=C 1 +C 2 +C 3 Y 0 +C 4 X 0 Y 0 +C 5 X 0 2 +C 6 Y 0 2
YError(X 0,Y 0)=D 1+D 2+D 3Y 0+D 4X 0Y 0+D 5X 0 2+D 6Y 0 2 YError(X 0 ,Y 0 )=D 1 +D 2 +D 3 Y 0 +D 4 X 0 Y 0 +D 5 X 0 2 +D 6 Y 0 2
C 1-C 6多项式系数,基于拼接打印时,拼接点于X方向上测量误差用二次最小二乘法拟合计算得出, C 1 -C 6 polynomial coefficients, based on the stitching and printing, the measurement error of the stitching point in the X direction is calculated by the quadratic least squares method.
D 1-D 6多项式系数,基于拼接打印时,拼接点于Y方向上测量误差用二次最小二乘法拟合计算得出。 The D 1 -D 6 polynomial coefficients are calculated based on the measurement error of the splicing point in the Y direction by the quadratic least squares fitting calculation during splicing printing.
在优选的实施例中,,当打印头移动后停下准备曝光时,控制微显示器件先在打印头的不粘膜中心投影图片,图像采集单元捕捉并分析成像质量,将成像与设置的理论值比较,若打印头的不粘模变形,根据变形公式In a preferred embodiment, when the print head is moved and stopped for exposure, the micro display device is controlled to project a picture on the center of the non-stick film of the print head, and the image acquisition unit captures and analyzes the imaging quality, and compares the imaging with the set theoretical value Compare, if the non-stick mold of the print head is deformed, according to the deformation formula
Figure PCTCN2020097098-appb-000001
Figure PCTCN2020097098-appb-000001
调整流量以调整打印头中的压力,打印头锥端设置的不粘膜的变形与压力差成正比,υ泊松系数,a为打印头的不粘模的半径,E杨氏模量,h为打印头的不粘模的厚度,p为打印头不粘模的两边的压力差。Adjust the flow to adjust the pressure in the print head. The deformation of the non-stick film set at the cone end of the print head is proportional to the pressure difference, υ Poisson coefficient, a is the radius of the non-stick mold of the print head, E Young's modulus, h is The thickness of the non-stick mold of the print head, p is the pressure difference between the two sides of the non-stick mold of the print head.
一种3D打印系统,包括:建立3D数字模型并将3D数字模型切成图像序列的图像系统、控制系统、受控接收系列图片并投影到打印头的不粘模与树脂的交界面的微显示器件、与所述微显示器件对应设置并受控进行投影的投影镜头、采集并检测投影图像的质量的图像采集单元、与所述图像采集单元相应设置并将投影的图像反射给所述图像采集单元进行接收采集的分光镜、打印平台、设置在所述打印平台上并装载有树脂的树脂槽、设置在打印平台上的升降装置、设置在树脂槽中并与升降装置连接的基板、与所述基板相应设置的中空梯形体结构的打印头,所述打印头的硬边缘作为刮刀使用、打印时刮擦树脂,所述打印头包括:中空的梯形柱体的内腔、覆设在下端的不粘膜形成的透明窗、设置 在下端并置于透明窗上部的锁环、设置在上端并受控控制输入气体流量对不粘膜的压力的质量流量控制器、设置在打印头的下游出口并置于锁环上部的限流器。A 3D printing system, including: an image system that establishes a 3D digital model and cuts the 3D digital model into an image sequence, a control system, and a micro-display of the interface between the non-stick mold and the resin that is controlled to receive the series of pictures and project them to the print head A device, a projection lens set corresponding to the micro display device and controlled to perform projection, an image acquisition unit that collects and detects the quality of the projected image, and is set corresponding to the image acquisition unit and reflects the projected image to the image acquisition The unit receives and collects the spectroscope, the printing platform, the resin tank provided on the printing platform and loaded with resin, the lifting device provided on the printing platform, the substrate provided in the resin tank and connected with the lifting device, and the A print head with a hollow trapezoidal structure corresponding to the substrate, the hard edge of the print head is used as a squeegee to scrape the resin during printing, and the print head includes: an inner cavity of a hollow trapezoidal cylinder, and a lower end A transparent window formed by a non-stick film, a lock ring arranged at the lower end and placed on the upper part of the transparent window, a mass flow controller arranged at the upper end and controlled control of the pressure of the input gas flow on the non-stick film, and arranged at the downstream outlet of the print head juxtaposed The restrictor on the upper part of the lock ring.
上述3D打印方法及3D打印系统,采用打印头的下端的硬边缘作为涂层刮刀,拼接移动和涂层步骤同时进行,节约了时间,提高了效率。The above-mentioned 3D printing method and 3D printing system use the hard edge of the lower end of the print head as a coating scraper, and the splicing movement and the coating step are performed at the same time, which saves time and improves efficiency.
另利用不粘膜,使得膜与样品是相切错开分离,数量级的减少了分离时对样品的作用力。In addition, the non-stick membrane is used to make the membrane and the sample stagger and separate, which reduces the force on the sample during separation by an order of magnitude.
另采用独特的拼接多次曝光打印的方法解决,可以移动图像(镜头),也可以移动样品。节约了时间,提高了效率。In addition, a unique method of stitching multiple exposure printing is used to solve the problem, which can move the image (lens) or the sample. Save time and improve efficiency.
另对于粘度高(>500cPs)的树脂,使用一张覆盖整个打印幅面(>50mmX50mm)大小的膜时,每次要涂非常薄(~10微米)的树脂层几乎是不可能的,因为在那么大幅面下,膜的张力所能提供的树脂驱动压力梯度是非常小的,使得树脂流动极其缓慢。本发明采用比打印幅面小的很多的膜,从而在同样的膜变形情况下,数量级的提高树脂的驱动压力梯度而提高打印速度和精度。On the other hand, for resins with high viscosity (>500cPs), it is almost impossible to apply a very thin (~10 microns) resin layer every time when a film covering the entire print width (>50mmX50mm) is used. In large format, the resin driving pressure gradient provided by the tension of the film is very small, making the resin flow extremely slow. The invention adopts a film much smaller than the printing width, so that under the same film deformation, the driving pressure gradient of the resin is increased by an order of magnitude to increase the printing speed and accuracy.
附图说明Description of the drawings
图1为本发明一实施例的3D打印系统的部分结构示意图;FIG. 1 is a schematic diagram of a part of the structure of a 3D printing system according to an embodiment of the present invention;
图2为本发明一实施例的打印头的部分结构剖视图;2 is a cross-sectional view of a partial structure of a print head according to an embodiment of the present invention;
图3为本发明一实施例的3D打印系统在拼接打印时在x和y方向上的轨迹误差示意图;FIG. 3 is a schematic diagram of trajectory errors in the x and y directions of the 3D printing system during splicing printing according to an embodiment of the present invention;
图4为本发明一实施例的三种曝光模式的示意图;4 is a schematic diagram of three exposure modes according to an embodiment of the present invention;
图5为本发明一实施例的打印头位于基板上方的打印过程示意图;5 is a schematic diagram of a printing process with a print head located above a substrate according to an embodiment of the present invention;
图6为本发明一实施例的基板位于打印头上方的打印过程示意图;6 is a schematic diagram of a printing process in which the substrate is located above the print head according to an embodiment of the present invention;
图7为本发明一实施例的弯月面式的打印过程示意图。FIG. 7 is a schematic diagram of a meniscus printing process according to an embodiment of the present invention.
具体实施方式Detailed ways
本发明一实施例的3D打印方法,包括:The 3D printing method according to an embodiment of the present invention includes:
切片:生成待打印的样品的3D数字模型,将3D数字模型切成图像序列,所述图像序列中的每个图像表示3D数字模型的一层,根据模型的切片方向控制 打印头的打印方向;Slicing: generating a 3D digital model of the sample to be printed, cutting the 3D digital model into an image sequence, each image in the image sequence represents a layer of the 3D digital model, and controlling the printing direction of the print head according to the slicing direction of the model;
投影:将图像发送至微显示器件,带有光源的微显示器件通过投影镜头将图像投影到打印头的一端的透明窗和树脂的交界面上;Projection: The image is sent to the micro display device, and the micro display device with a light source projects the image on the interface between the transparent window at one end of the print head and the resin through the projection lens;
图像检测:图像采集单元采集分光镜反射回来的图像并检测投影图像的质量,根据检测的质量控制进行打印;Image detection: The image acquisition unit collects the image reflected by the spectroscope and detects the quality of the projected image, and prints according to the quality control of the detection;
曝光打印:带有光源的微显示器件用光照射投影图像,曝光产生固化层,代表投影图像在3D数字模型中相应的一层,当一次曝光结束,打印头移至新区域,打印头的锥端的硬边缘被用作树脂层刮刀,涂层厚度由打印头的端部与样品顶层之间的间隙确定,打印头后方的树脂流动并覆盖先前的裸露区域;Exposure printing: The micro display device with a light source irradiates the projected image with light, and the exposure produces a cured layer, which represents the corresponding layer of the projected image in the 3D digital model. When an exposure is over, the print head moves to a new area, the cone of the print head The hard edge of the end is used as a resin layer scraper. The thickness of the coating is determined by the gap between the end of the print head and the top layer of the sample. The resin behind the print head flows and covers the previously exposed area;
继续曝光打印:一层打印完毕后,控制打印头移动离开打印区域,打印头与样品平移脱离,调整打印头或样品台回位,打印头移动到样品边界之外,调整打印头与样品之间的上下距离为打印下一层的厚度,样品与打印头的透明窗之间的缝隙充满打印下一层所需的树脂,依次重复曝光打印,打印头刮擦、涂覆逐步曝光新一层,打印下一层,直至打印完毕,模型在树脂槽中被复制出来。Continue to expose and print: After one layer is printed, control the print head to move away from the print area, move the print head away from the sample, adjust the print head or sample stage to return, move the print head outside the boundary of the sample, adjust the print head and sample The upper and lower distance is the thickness of the next layer to be printed. The gap between the sample and the transparent window of the print head is filled with the resin needed to print the next layer. The exposure and printing are repeated in sequence, and the print head is scratched and coated to gradually expose a new layer. Print the next layer until the printing is completed and the model is copied in the resin tank.
进一步,优选的,本发明的微显示器件为带有405纳米光源的DLP。Further, preferably, the micro display device of the present invention is a DLP with a 405 nm light source.
本发明的打印从计算机或图像系统建立几何模型开始,3D数字模型在一个方向上被切成二维图片,一般是黑白,可以有灰度。每一张图片代表着3D数字模型中的一薄层。模型的切片方向将是打印机的打印方向。产生的一系列图片会依次被打印机读取并通过带405纳米光源的DLP投影到打印头上的端部设置的不粘膜和树脂的交界面上,同时图形图像采集单元如CCD摄像头会从分光镜反射回来的图像判读投影图像的质量。在一定的曝光时间内,有光的地方会产生一定厚度的固化层,它代表了投影图片所代表的模型中对应的一层。当上一层完成曝光打印后,打印头会和样品平移脱离。The printing of the present invention starts from the establishment of a geometric model by a computer or an image system, and the 3D digital model is cut into a two-dimensional picture in one direction, which is generally black and white, and may have grayscale. Each picture represents a thin layer in the 3D digital model. The slicing direction of the model will be the printing direction of the printer. The resulting series of pictures will be read by the printer in turn and projected on the interface between the non-stick film and resin at the end of the print head through DLP with a 405-nanometer light source. At the same time, a graphic image acquisition unit such as a CCD camera will be removed from the spectroscope. The reflected image judges the quality of the projected image. Within a certain exposure time, a certain thickness of cured layer will be produced where there is light, which represents the corresponding layer in the model represented by the projected picture. When the upper layer is exposed and printed, the print head will move away from the sample.
样品台会根据不同的打印形式回位,回位后,打印头和样品的距离是要打印的下一层的厚度,样品和打印头薄膜间的缝隙会充满了打印下一层所需的树脂层。依次重复曝光,随着样品台的逐层下降,模型在树脂槽中被复制出来。The sample stage will return according to different printing forms. After returning, the distance between the print head and the sample is the thickness of the next layer to be printed, and the gap between the sample and the print head film will be filled with the resin needed to print the next layer Floor. The exposure is repeated in sequence, and the model is copied in the resin tank as the sample stage descends layer by layer.
由于微显示器件如LCD或DLP芯片都有一定的大小,比如1920X1080像素的DLP,在十微米的光学精度下,一个芯片所覆盖的打印面积只有19.2mmX10.8mm.因此当样品的尺寸小于一个芯片覆盖区域时,我们称为单投影模式。当样品尺寸超出一块芯片所覆盖的范围时,本发明采用拼接的打印模 式。在拼接打印模式下,代表模型一层的图片会进一步被切成多张不大于单个DLP解析度的图片即层部分。如,3800X2000像素的图片可以被切成分割成四张1900X1000的子图片,每张子图片将代表一层中的四分之一的区域。对于模型中的每一层,将通过多次曝光完成,依次投影当前层的所有子图片即层部分。相邻区域/图片的交界处为了提高力学性能通常会给与一定的重叠量,通常是5-20微米。每个区域的曝光的位置和重叠都由XY轴组合精确控制。系统中有两个坐标系,一个是DLP/LCD垂直坐标系,还有一个是XY轴组成的运动坐标系。如果这两个坐标系之间由于机械组装的误差而不完全平行,就会在拼接打印中相邻的区域出现错位误差。为此,在拼接打印模式中对测量得到的误差进行补偿。由于打印平台X、Y轴的存在,对于比打印机的打印幅面小的样品,可以在整个幅面内重复打印多个同样的样品,这样可以提高量产时的速度,这就是矩阵打印模式。Since micro display devices such as LCD or DLP chips have a certain size, such as 1920X1080 pixel DLP, with an optical precision of ten microns, the printing area covered by a chip is only 19.2mmX10.8mm. Therefore, when the size of the sample is smaller than a chip When covering an area, we call it single projection mode. When the sample size exceeds the range covered by a chip, the present invention adopts the splicing printing mode. In the stitching printing mode, the picture representing the first layer of the model will be further cut into multiple pictures that are not larger than a single DLP resolution, that is, the layer part. For example, a 3800X2000 pixel picture can be cut into four 1900X1000 sub-pictures, and each sub-picture will represent a quarter of the area in a layer. For each layer in the model, it will be completed through multiple exposures, and all the sub-pictures of the current layer are projected in turn. In order to improve the mechanical properties at the junction of adjacent areas/pictures, a certain amount of overlap is usually given, usually 5-20 microns. The position and overlap of the exposure of each area are precisely controlled by the XY axis combination. There are two coordinate systems in the system, one is a DLP/LCD vertical coordinate system, and the other is a motion coordinate system composed of XY axes. If the two coordinate systems are not completely parallel due to mechanical assembly errors, there will be misalignment errors in adjacent areas during stitching and printing. For this reason, the measured error is compensated in the stitching printing mode. Due to the existence of the X and Y axes of the printing platform, for samples smaller than the printer's print format, multiple identical samples can be printed repeatedly in the entire format, which can increase the speed of mass production. This is the matrix printing mode.
当打印头位于基板下部进行打印,打印头的透明窗于树脂的自由表面下方0.5-2mm,打印头与基板之间沿X/Y/Z方向相对移动以定义层和拼接层分面。When the print head is located on the lower part of the substrate for printing, the transparent window of the print head is 0.5-2mm below the free surface of the resin, and the print head and the substrate move relative to each other in the X/Y/Z direction to define the layer and splicing layer facets.
在弯月面式打印中,当完成一层打印后,样品与基板浸入树脂中并浸入2mm至8mm,以使新的树脂覆盖样品的顶面,然后基板带动样品回位,调整打印头与样品之间距离为打印下一层的厚度,打印头从样品外部移入、刮擦、涂覆并逐步曝光新层,同时打印头将多余树脂推回到树脂槽中。In meniscus printing, when one layer of printing is completed, the sample and substrate are immersed in resin and immersed 2mm to 8mm so that the new resin covers the top surface of the sample, and then the substrate drives the sample back to position, adjust the print head and sample The distance between is the thickness of the next layer to be printed. The print head moves in from the outside of the sample, scrapes, coats and gradually exposes the new layer, while the print head pushes the excess resin back into the resin tank.
进一步,本实施例的打印头30为中空梯形柱体结构,其锥端端部设置一个锁环36。打印头30的锥端覆盖不粘膜并形成透明窗34。锁环36置于透明窗34上部。Furthermore, the print head 30 of this embodiment has a hollow trapezoidal cylindrical structure, and a lock ring 36 is provided at the tapered end. The tapered end of the print head 30 covers the non-stick film and forms a transparent window 34. The lock ring 36 is placed on the upper part of the transparent window 34.
进一步,本实施例的基板设置在打印平台上,打印平台带动基板根据打印在X、Y、Z方向上移动,曝光打印或继续曝光打印时,根据P=P 0+P 1控制打印头压力以补偿其与打印树脂接触而引起薄膜透明窗的变形。P 0为打印头的不粘膜所处空气大气压的压力,P 1=ρ 1gh,ρ 1为树脂密度,g重力加速度,h为打印头的不粘膜在树脂下面的深度;打印时,通过气体的流量控制打印头中的压力,若压力传感器检测到打印头的压力与设定压力有差异时,控制质量流量控制器根据PID设置调整流量,直至打印头中的压力达到设定值。 Further, the substrate of this embodiment is set on a printing platform, and the printing platform drives the substrate to move in the X, Y, and Z directions according to printing. When exposure printing or continuing exposure printing, the pressure of the print head is controlled according to P=P 0 +P 1 It compensates for the deformation of the transparent window of the film caused by its contact with the printing resin. P 0 is the pressure of the air atmosphere where the non-stick film of the print head is located, P 1 = ρ 1 gh, ρ 1 is the resin density, g acceleration of gravity, h is the depth of the non-stick film of the print head under the resin; when printing, air is passed through The flow rate controls the pressure in the print head. If the pressure sensor detects that the pressure of the print head is different from the set pressure, the mass flow controller is controlled to adjust the flow according to the PID setting until the pressure in the print head reaches the set value.
进一步,本实施例的打印头30还包括:设置在打印头30的下游出口的限流器312。在下游出口的小孔的限流器312的小孔足够小(<50微米)处于阻流状态,它的流量只跟上游即打印头中压力成正比。Furthermore, the print head 30 of this embodiment further includes a flow restrictor 312 provided at the downstream outlet of the print head 30. The orifice of the orifice at the downstream outlet of the restrictor 312 is small enough (<50 microns) to be in a flow-blocking state, and its flow rate is only proportional to the upstream pressure in the print head.
当打印头30的压力传感器测到的实际压力比设置的压力低时,设置在上游的质量流量控制器(MFC mass flow controller)就根据PID(比例积分微分Proportion Integration Differentiation)的设置适当的增加流量,直到打印头里的压力达到设定值。反之亦然。When the actual pressure measured by the pressure sensor of the print head 30 is lower than the set pressure, the upstream mass flow controller (MFC mass flow controller) will increase the flow appropriately according to the PID (Proportion Integration Differentiation) setting , Until the pressure in the print head reaches the set value. vice versa.
进一步,本实施例中,若打印图像大于单个曝光尺寸则进行拼接打印,将图像划分为多个层部分,逐步打印层部分,并叠边拼接成整层,每个层部分在拼接边上重叠5-20微米。Further, in this embodiment, if the printed image is larger than a single exposure size, stitch printing is performed, the image is divided into multiple layer parts, the layer parts are printed step by step, and the overlapping edges are stitched into a whole layer, and each layer part overlaps on the stitching edge 5-20 microns.
打印过程首先在计算机或图像系统中生成3D模型,然后将数字模型切成一系列图像,其中每个图像代表模型的一层(如5到20微米)。控制计算机或图像系统将图像发送到微显示器件(如DLP(digital light processing数字光处理)或LCD(liquid crystal display液晶显示面板)),并且图像通过投影镜头投射到打印头的底表面(湿表面)上。亮区聚合,而暗区保持液态。由于LCD或DLP芯片的尺寸限制,例如在10um打印光学分辨率下具有1920X1080像素的DLP芯片,单个曝光仅覆盖19.2mmX10.8mm的面积。因此,如果样品的横截面大于19.2mmX10.8mm,则无法使用单个曝光方法进行打印。本发明提供了一种多重曝光的拼接打印方法。通过这种方法,代表3D模型层的图像被进一步分为多个较小的图像即层部分,每个图像不大于DLP像素分辨率。例如,像素分辨率为3800X2000的图像可以分为四个1900X1000子图像,每个子图像代表该层的四分之一。结果,将基于子图像逐节打印模型的整个图层。为了提高相邻部分的共用边缘的机械强度,通常在边缘上存在约5-20微米的重叠。The printing process first generates a 3D model in a computer or image system, and then cuts the digital model into a series of images, where each image represents a layer of the model (such as 5 to 20 microns). The control computer or imaging system sends the image to the micro display device (such as DLP (digital light processing) or LCD (liquid crystal display)), and the image is projected onto the bottom surface of the print head (wet surface) through the projection lens )on. The bright areas converge, while the dark areas remain liquid. Due to the size limitation of LCD or DLP chips, such as a DLP chip with 1920X1080 pixels at 10um printing optical resolution, a single exposure only covers an area of 19.2mmX10.8mm. Therefore, if the cross section of the sample is larger than 19.2mmX10.8mm, it cannot be printed using a single exposure method. The invention provides a multi-exposure splicing printing method. In this way, the image representing the layer of the 3D model is further divided into multiple smaller images or layer parts, each of which is not larger than the DLP pixel resolution. For example, an image with a pixel resolution of 3800X2000 can be divided into four 1900X1000 sub-images, and each sub-image represents a quarter of the layer. As a result, the entire layer of the model will be printed section by section based on the sub-image. In order to improve the mechanical strength of the shared edge of adjacent parts, there is usually an overlap of about 5-20 microns on the edge.
XY打印平台组件可精确控制精确的位置和重叠量。有两种坐标系:一种与DLP/LCD面板垂直坐标系,另一种是打印平台于XY轴组成的运动坐标系。当这两个坐标系由于装配公差而不平行时,在相邻截面的公共边上将存在偏移误差。如图3所示,A是单个曝光的大小;B是在x方向上精确对齐的结果;C是在x方向上有误差偏移的结果;B’是沿y方向精确对齐的结果;C’是误差在y方向上偏移的结果。在精密打印中,误差要求小于10um,载物台装配公差通常在允许范围内;并且偏移量与打印平台移动距离不是线性的。因此,在本发明中,在全范围打印的正方形样本的x和y方向上的5个或更多个均匀分布的点处测量偏移。至少二阶多项式内插的偏移误差曲线将被引入XY方向的平移中,以补偿偏移,从而确保拼接打印样本的精度在规格范围内。XY printing platform components can precisely control the precise position and overlap amount. There are two coordinate systems: one is the vertical coordinate system with the DLP/LCD panel, and the other is the movement coordinate system composed of the XY axis of the printing platform. When the two coordinate systems are not parallel due to assembly tolerances, there will be offset errors on the common edges of adjacent sections. As shown in Figure 3, A is the size of a single exposure; B is the result of accurate alignment in the x direction; C is the result of an error offset in the x direction; B'is the result of accurate alignment in the y direction; C' It is the result of the error offset in the y direction. In precision printing, the error requirement is less than 10um, and the assembly tolerance of the stage is usually within the allowable range; and the offset is not linear with the moving distance of the printing platform. Therefore, in the present invention, the offset is measured at 5 or more uniformly distributed points in the x and y directions of the square sample printed in the full range. The offset error curve of at least second-order polynomial interpolation will be introduced into the translation in the XY direction to compensate for the offset, so as to ensure that the accuracy of the spliced printed samples is within the specification range.
打印时,对打印平台的X/Y方向运动坐标进行误差补偿(X 0+XError(X 0,Y 0),Y 0+YError(X 0,Y 0)),(X 0,Y 0)为理论坐标, When printing, perform error compensation (X 0 +XError(X 0 ,Y 0 ),Y 0 +YError(X 0 ,Y 0 )) on the X/Y direction movement coordinates of the printing platform, (X 0 ,Y 0 ) is Theoretical coordinates,
XError(X 0,Y 0)=C 1+C 2+C 3Y 0+C 4X 0Y 0+C 5X 0 2+C 6Y 0 2 XError(X 0 ,Y 0 )=C 1 +C 2 +C 3 Y 0 +C 4 X 0 Y 0 +C 5 X 0 2 +C 6 Y 0 2
YError(X 0,Y 0)=D 1+D 2+D 3Y 0+D 4X 0Y 0+D 5X 0 2+D 6Y 0 2 YError(X 0 ,Y 0 )=D 1 +D 2 +D 3 Y 0 +D 4 X 0 Y 0 +D 5 X 0 2 +D 6 Y 0 2
C 1-C 6多项式系数,基于拼接打印时,拼接点于X方向上测量误差用二次最小二乘法拟合计算得出, C 1 -C 6 polynomial coefficients, based on the stitching and printing, the measurement error of the stitching point in the X direction is calculated by the quadratic least squares method.
D 1-D 6多项式系数,基于拼接打印时,拼接点于Y方向上测量误差用二次最小二乘法拟合计算得出。 The D 1 -D 6 polynomial coefficients are calculated based on the measurement error of the splicing point in the Y direction by the quadratic least squares fitting calculation during splicing printing.
具体的如为了精确(<10微米误差)的拼接打印,先在全幅面样品台上拼接打印20X10块连接的大小19.2X10.8X0.1毫米厚的长方形,若这些方块的前后左右有理论上100微米的重叠,这些方块将提供19X9个拼接点数据以及它们的坐标。打印的样品从样品台上取下前测量实际在X方向和Y方向的重叠量,比如实际在X方向的拼接重叠是80,那在这坐标点的X方向的误差就是XError(x,y)=100-80=20微米,重复的测量就会的得到19X9=171个点在X方向的误差,同时也得到了同样171个点Y方向的误差。Specifically, for precise stitching and printing (<10 microns error), first stitch and print 20X10 pieces of connected rectangles with a thickness of 19.2X10.8X0.1 mm on the full-frame sample table. If there are theoretically 100 squares on the front, back, left, and right of these squares. With a micron overlap, these squares will provide 19X9 splicing point data and their coordinates. Measure the actual overlap amount in the X direction and Y direction before the printed sample is removed from the sample stage. For example, the actual splicing overlap in the X direction is 80, and the error in the X direction at this coordinate point is XError(x,y) =100-80=20 microns, repeated measurement will get 19X9=171 points of error in the X direction, and also get the same 171 points of error in the Y direction.
假设在整个打印平台的XY远动系统的二次误差函数是:Assume that the quadratic error function of the XY telecontrol system on the entire printing platform is:
XError(x,y)=C 1+C 2x+C 3y+C 4xy+C 5x^2+C 6y^2, XError(x,y)=C 1 +C 2 x+C 3 y+C 4 xy+C 5 x^2+C 6 y^2,
YError(x,y)=D 1+D 2x+D 3y+D 4xy+D 5x^2+D 6y^2, YError(x,y)=D 1 +D 2 x+D 3 y+D 4 xy+D 5 x^2+D 6 y^2,
这里x,y是坐标,C和D是多项式系数。C 1~6和D 1~6可以基于171个点上X方向和Y方向的测量误差用二次最小二乘法拟合计算得出。这样就得到了在整个打印区域内轴的运动误差分布。这两个误差公式将用于纠正轴的运动误差时,比如轴要走到理论值(X 0,Y 0)的地方,根据误差公式,轴的控制指令则要求轴走到(X 0+XError(X 0,Y 0),Y 0+YError(X 0,Y 0))。 Here x, y are coordinates, and C and D are polynomial coefficients. C 1~6 and D 1~6 can be calculated by the quadratic least squares fitting calculation based on the measurement errors in the X direction and the Y direction at 171 points. In this way, the axis movement error distribution in the entire printing area is obtained. These two error formulas will be used to correct the movement error of the axis. For example, the axis will go to the theoretical value (X 0 , Y 0 ). According to the error formula, the control command of the axis requires the axis to go to (X 0 +XError (X 0 ,Y 0 ),Y 0 +YError(X 0 ,Y 0 )).
当打印头移动后停下准备曝光时,控制微显示器件先在打印头的不粘膜中心投影图片,图像采集单元捕捉并分析成像质量,将成像与设置的理论值比较,若打印头的不粘模变形,根据变形公式When the print head stops and prepares for exposure after moving, control the micro display device to project a picture on the center of the non-stick film of the print head. The image acquisition unit captures and analyzes the imaging quality, and compares the imaging with the set theoretical value. If the print head is not sticky Mold deformation, according to the deformation formula
Figure PCTCN2020097098-appb-000002
Figure PCTCN2020097098-appb-000002
调整流量以调整打印头中的压力,打印头锥端设置的不粘膜的变形与压力 差成正比,υ泊松系数,a为打印头的不粘模的半径或对角线长度一半,E杨氏模量,h为打印头的不粘模的厚度,p为打印头不粘模的两边的压力差。Adjust the flow rate to adjust the pressure in the print head, the deformation of the non-stick film set at the cone end of the print head is proportional to the pressure difference, υ Poisson coefficient, a is the radius of the non-stick mold of the print head or half of the diagonal length, E Yang The modulus, h is the thickness of the non-stick mold of the print head, and p is the pressure difference between the two sides of the non-stick mold of the print head.
如图1、图2所示,本发明一实施例的3D打印系统100包括:建立3D数字模型并将3D数字模型切成图像序列的图像系统、控制系统、受控接收图像并投影到打印头的不粘模与树脂的交界面的微显示器件50、与微显示器件对应设置并受控进行投影的投影镜头40、采集并检测投影图像的质量的图像采集单元55、与图像采集单元55相应设置并将投影的图像反射给图像采集单元55接收采集的分光镜60、打印平台80、设置在打印平台80上并装载有树脂的树脂槽70、设置在打印平台80上的升降装置85、设置在树脂槽70中并与升降装置85连接的基板90、与基板90相应设置的中空梯形体结构的打印头30。As shown in Figures 1 and 2, the 3D printing system 100 of an embodiment of the present invention includes: an image system that establishes a 3D digital model and cuts the 3D digital model into an image sequence, a control system, and a controlled receiving image and projecting it to the print head The micro display device 50 of the interface between the non-stick mold and the resin, the projection lens 40 that is set corresponding to the micro display device and controlled to perform projection, the image acquisition unit 55 that collects and detects the quality of the projected image, and the image acquisition unit 55 corresponds to Set and reflect the projected image to the image acquisition unit 55 to receive and collect the spectroscope 60, the printing platform 80, the resin tank 70 arranged on the printing platform 80 and loaded with resin, the lifting device 85 arranged on the printing platform 80, and the setting A substrate 90 in the resin tank 70 and connected to the lifting device 85, and a print head 30 with a hollow trapezoidal structure provided corresponding to the substrate 90.
打印头30包括:中空的梯形体的内腔32、覆设在下端的不粘膜形成的透明窗34、设置在下端并置于透明窗上部的锁环36、设置在上端并受控控制输入气体流量对不粘膜的压力的质量流量控制器38、设置在打印头30的下游出口并置于锁环36上部的限流器39。The print head 30 includes: a hollow trapezoidal inner cavity 32, a transparent window 34 formed by a non-stick film covering the lower end, a lock ring 36 arranged at the lower end and placed on the upper part of the transparent window, and arranged at the upper end to control the input gas A mass flow controller 38 for the pressure of the flow to the non-stick film, and a restrictor 39 provided at the downstream outlet of the print head 30 and placed on the upper part of the lock ring 36.
本实施例的图像系统、控制系统可采用计算机20进行完成,也可以分别采用图形处理芯片、控制芯片进行。The image system and control system of this embodiment can be implemented by using the computer 20, or can be implemented by using a graphics processing chip and a control chip, respectively.
进一步,本实施例的微显示器件为DLP或LCD芯片。当然也可根据需要采用其他芯片。Further, the micro display device of this embodiment is a DLP or LCD chip. Of course, other chips can also be used as needed.
优选的,本实施例的图像采集单元可采用CCD进行实现。当然也可采用其它具有图像采集处理功能的器件如CMOS等。Preferably, the image acquisition unit of this embodiment can be implemented by using a CCD. Of course, other devices with image acquisition and processing functions, such as CMOS, can also be used.
进一步,本实施例的基板90通过基板臂92升降装置85连接。升降装置85设置在打印平台80上。Furthermore, the substrate 90 of this embodiment is connected by a substrate arm 92 lifting device 85. The lifting device 85 is provided on the printing platform 80.
本发明的3D打印方法,提供了以更大的速度更精确和更快地控制较大打印区域中的层厚度的方法,例如,具有10um层厚度的10cmX10cm印刷区域。The 3D printing method of the present invention provides a method to control the layer thickness in a larger printing area more accurately and faster at a greater speed, for example, a 10cm×10cm printing area with a layer thickness of 10um.
本发明一实施例中,将打印头浸没在光敏树脂中几毫米。在另一实施例中,打印头在形成树脂弯月面的树脂表面上方几百微米。In an embodiment of the present invention, the print head is immersed several millimeters in the photosensitive resin. In another embodiment, the print head is a few hundred microns above the resin surface where the resin meniscus is formed.
本实施例的打印头可以与整个DLP芯片的一次曝光一样大,也可以仅覆盖DLP芯片的一部分。本发明的3D打印方法不仅大大提高了使用例如投影微立体光刻系统打印的样品的尺寸精度,而且通过消除了在树脂中进行闭合或分离两个接触表面的需要,也大大提高了打印速度。The print head of this embodiment can be as large as one exposure of the entire DLP chip, or it can cover only a part of the DLP chip. The 3D printing method of the present invention not only greatly improves the dimensional accuracy of samples printed using, for example, a projection micro-stereolithography system, but also greatly improves the printing speed by eliminating the need to close or separate two contact surfaces in resin.
本实施例的打印头的锥端(梯形体的小端)通过覆盖不粘透明膜形成透明窗进行覆盖密封。本实施例的透明窗可采用气体可渗透的材料,特别是氧气可渗透的材料,例如,聚二甲基硅氧烷(PDMS)或特氟隆AF(杜邦)。The tapered end (small end of the trapezoid) of the print head of this embodiment is covered and sealed by covering a non-stick transparent film to form a transparent window. The transparent window of this embodiment can be made of a gas-permeable material, especially an oxygen-permeable material, such as polydimethylsiloxane (PDMS) or Teflon AF (DuPont).
本实施例的打印头可以设置超过10kHz的频率的超声源,以在与树脂接触时在其运动期间增加树脂的流速。The print head of this embodiment may be provided with an ultrasonic source with a frequency exceeding 10 kHz to increase the flow rate of the resin during its movement when it is in contact with the resin.
本实施例的打印头可以通过压力控制以补偿由于与打印树脂的接触而引起的透明窗的变形。压力控制气体可以是防止样品在聚合过程中粘附到透明窗上,气体可以为氧气或其混合物。The print head of this embodiment can be controlled by pressure to compensate for the deformation of the transparent window caused by contact with the printing resin. The pressure control gas can prevent the sample from sticking to the transparent window during the polymerization process, and the gas can be oxygen or a mixture thereof.
本发明一实施例中,利用打印平台于XY方向移动,提供三种打印模式。当只需要一个小于单次曝光大小的样本时,就称为单次曝光模式。如果需要多个样本,则打印平台将逐步移动并在阵列中打印相同的样本,这称为阵列曝光模式。当样本大小增加到超过单次曝光的大小时,系统将通过在公共边或临接边上重叠5μm至20μm,将一层进一步分成多个部分,并将相邻部分拼接成整层,这是拼接曝光模式。也可以将拼接模式与阵列模式结合使用。In an embodiment of the present invention, the printing platform is used to move in the XY direction to provide three printing modes. When only a sample smaller than the size of a single exposure is needed, it is called a single exposure mode. If multiple samples are needed, the printing platform will gradually move and print the same samples in the array, which is called the array exposure mode. When the sample size increases to exceed the size of a single exposure, the system will further divide a layer into multiple parts by overlapping 5μm to 20μm on the common or adjacent edges, and stitch adjacent parts into a whole layer. Stitching exposure mode. It is also possible to combine stitching mode and array mode.
本发明基于来自实际样本的测量数据的内插偏移误差曲线将用于在打印平台于XY方向平移中,进行机械公差补偿,以确保拼接打印样本的精度在规格范围内。In the present invention, the interpolation offset error curve based on the measurement data from the actual sample will be used to perform mechanical tolerance compensation during the translation of the printing platform in the XY direction to ensure that the accuracy of the spliced printed sample is within the specification range.
本发明一实施例中,打印头30浸没在树脂中1至10毫米。当一次曝光结束并且打印头移至新区域时,打印头锥端的硬边缘将用作树脂涂层刮刀。涂层厚度由打印头的平头和样品顶层之间的间隙确定。当打印头移至相邻区域时,打印头后方的树脂在重力和表面张力的作用下流动并覆盖先前的裸露区域。在打印完整个层之后,在样品台向下移动一层厚度以定义下一层新鲜树脂之前,打印头将移动到样品边界之外。定义新层后,打印头将移入并开始逐步扫描和打印下一层。In an embodiment of the present invention, the print head 30 is immersed in the resin for 1 to 10 mm. When an exposure is over and the print head moves to a new area, the hard edge of the cone end of the print head will act as a resin coating blade. The coating thickness is determined by the gap between the flat end of the print head and the top layer of the sample. When the print head moves to an adjacent area, the resin behind the print head flows under the action of gravity and surface tension and covers the previously exposed area. After printing a complete layer, the print head will move beyond the boundary of the sample before the sample stage moves down to a thickness to define the next layer of fresh resin. After defining the new layer, the print head will move in and begin to scan and print the next layer step by step.
本发明的样品台可带动样品沿X、Y、Z方向移动。也可以通过在保持样品静止,移动打印头以进行相互移动。The sample stage of the present invention can drive the sample to move in the X, Y, and Z directions. You can also move the print heads to move each other by keeping the sample still.
本发明一优选实施例中,打印头与样品的顶层一起在树脂水平之上100至500微米。在此打印头配置中,完成一层打印后,样品和基板将浸入树脂自由面2mm至8mm,以使新鲜的树脂覆盖样品的顶面。然后,样品将以与打印头距离等于下一层厚度的间隙回位。同样,打印头将从样品外部移入、刮擦、涂覆并逐步曝光新层。In a preferred embodiment of the invention, the print head is 100 to 500 microns above the resin level together with the top layer of the sample. In this print head configuration, after one layer is printed, the sample and substrate will be immersed 2mm to 8mm into the free surface of the resin so that the fresh resin covers the top surface of the sample. Then, the sample will return with a gap equal to the thickness of the next layer from the print head. Likewise, the print head will move in from the outside of the sample, scratch, coat, and gradually expose a new layer.
本发明的打印头透明窗的大小应覆盖单个DLP/LCD芯片投影。例如,17mm芯片的投影为20mm,像素分辨率为10μm,那么窗口的直径可以为22mm左右。进一步,本实施例的打印头30锥端处的透明窗可以为厚度为130μm的杜邦特富龙AF2400膜,该膜是透气的并且具有很好的透光性。气体的渗透性,尤其是氧气的渗透性,使膜在光聚合过程中不粘,因为氧气是一种光交联抑制剂。 打印头的透明窗也可以采用聚二甲基硅氧烷(PDMS)膜、或进行表面涂覆聚二甲基硅氧烷(PDMS)。The size of the transparent window of the print head of the present invention should cover the projection of a single DLP/LCD chip. For example, if the projection of a 17mm chip is 20mm and the pixel resolution is 10μm, the diameter of the window can be about 22mm. Furthermore, the transparent window at the tapered end of the print head 30 of this embodiment may be a DuPont Teflon AF2400 film with a thickness of 130 μm, which is breathable and has good light transmittance. Gas permeability, especially oxygen permeability, makes the film non-sticky during photopolymerization, because oxygen is a photocrosslinking inhibitor. The transparent window of the print head can also be made of polydimethylsiloxane (PDMS) film, or surface-coated with polydimethylsiloxane (PDMS).
由于打印头可以浸入树脂中,打印头的锥端通过一个锁环紧紧的密封在液体中。假定不粘膜具有线弹性,液压引起的树脂中的不粘膜中心的挠度或变形用下式表示:Since the print head can be immersed in resin, the tapered end of the print head is tightly sealed in the liquid by a lock ring. Assuming that the non-stick film has linear elasticity, the deflection or deformation of the center of the non-stick film in the resin caused by hydraulic pressure is expressed by the following formula:
Figure PCTCN2020097098-appb-000003
Figure PCTCN2020097098-appb-000003
其中υ是膜的泊松比,ɑ是圆形膜锥端的半径,E是杨氏模量,h是厚度,p是膜两侧的压差。它表明打印头锥端的透明窗的变形与压力差成正比;因此,可以通过控制打印头中的压力以及两侧的压力差来消除薄膜的变形。Where υ is the Poisson's ratio of the membrane, ɑ is the radius of the cone of the circular membrane, E is the Young's modulus, h is the thickness, and p is the pressure difference between the two sides of the membrane. It shows that the deformation of the transparent window at the cone end of the print head is proportional to the pressure difference; therefore, the deformation of the film can be eliminated by controlling the pressure in the print head and the pressure difference on both sides.
打印头30的透明窗于湿表面上的液体压力可以通过p=ρgh来计算,其中ρ是树脂的密度,g是重力加速度,h是树脂从自由表面开始的深度。因此,应控制打印头内部的压力以补偿液体压力。这样就消除了薄膜透明窗的变形。质量流量控制器(MFC),设置在下游的限流器和打印头上的压力传感器的组合将控制打印头中的压力P。不粘氧抑制层的厚度可以通过增加打印头中的氧浓度来改善;因此,MFC可以使用各种氧气浓度混合物的流量来控制压力。The liquid pressure of the transparent window of the print head 30 on the wet surface can be calculated by p=ρgh, where ρ is the density of the resin, g is the acceleration of gravity, and h is the depth of the resin from the free surface. Therefore, the pressure inside the print head should be controlled to compensate for the liquid pressure. This eliminates the deformation of the transparent window of the film. The combination of a mass flow controller (MFC), a restrictor located downstream and a pressure sensor on the print head will control the pressure P in the print head. The thickness of the non-stick oxygen suppression layer can be improved by increasing the oxygen concentration in the print head; therefore, MFC can use the flow rate of various oxygen concentration mixtures to control the pressure.
本发明一实施例的打印过程从在计算机中生成3D模型开始,然后将数字模型切成一系列图像,每个图像代表模型的一层(5至20微米),控制计算机将图像发送到微显示器件如于LCD或DLP芯片,然后通过投影镜头将图像投影到打印头的底表面(湿表面)上。亮区聚合,而暗区保持液态。由于LCD或DLP芯片的尺寸限制,例如在10um打印光学分辨率下具有1920X1080像素的DLP芯片,单次曝光仅覆盖19.2mmX10.8mm的面积。因此,如果样品的横截面大于19.2mmX10.8mm,则无法使用单次曝光方法进行打印。The printing process of an embodiment of the present invention starts with generating a 3D model in a computer, and then cutting the digital model into a series of images, each of which represents a layer (5 to 20 microns) of the model, and the control computer sends the image to the micro display The device is such as LCD or DLP chip, and then the image is projected onto the bottom surface (wet surface) of the print head through a projection lens. The bright areas converge, while the dark areas remain liquid. Due to the size limitation of the LCD or DLP chip, for example, a DLP chip with 1920X1080 pixels at 10um printing optical resolution, a single exposure only covers an area of 19.2mmX10.8mm. Therefore, if the cross-section of the sample is larger than 19.2mmX10.8mm, the single exposure method cannot be used for printing.
本发明提出了一种多重曝光的拼接打印方法。通过这种方法,代表3D模型的一层的图像被进一步分为多个较小的图像即层部分,每个图像不大于DLP像素分辨率。例如,像素分辨率为3800X2000的图像可以分为四个1900X1000子图像,每个子图像即层部分代表该层的四分之一。结果,将基于子图像逐步打印模型的整个图层。为了提高相邻部分的共用边缘的机械强度,边缘上通常重叠约5-20微米。The present invention proposes a multi-exposure splicing printing method. In this way, the image representing a layer of the 3D model is further divided into a plurality of smaller images or layer parts, each image is not larger than the DLP pixel resolution. For example, an image with a pixel resolution of 3800X2000 can be divided into four 1900X1000 sub-images, each of which represents a quarter of the layer. As a result, the entire layer of the model will be printed step by step based on the sub-images. In order to improve the mechanical strength of the shared edges of adjacent parts, the edges usually overlap by about 5-20 microns.
打印平台可精确控制精确的位置和重叠量。本发明设置有两种坐标系:一种与DLP/LCD的垂直坐标系,另一种是打印平台沿XY方向的运动坐标系。当这两个坐标系由于装配公差而不平行时,在相邻截面的公共边上将存在偏移 误差。如图3所示,A是单次曝光的大小;B是在x方向上精确对齐的结果;C是在x方向上有误差偏移的结果;B’是沿y方向精确对齐的结果;C’是误差在y方向上偏移的结果。The printing platform can precisely control the precise position and overlap amount. The invention is provided with two coordinate systems: one is the vertical coordinate system with the DLP/LCD, and the other is the movement coordinate system of the printing platform along the XY direction. When the two coordinate systems are not parallel due to assembly tolerances, there will be offset errors on the common edges of adjacent sections. As shown in Figure 3, A is the size of a single exposure; B is the result of accurate alignment in the x direction; C is the result of an error offset in the x direction; B'is the result of accurate alignment in the y direction; C 'Is the result of the error offset in the y direction.
在误差要求小于10μm的精密打印中,打印平台的装配公差很难在允许范围内;而且轴定位的偏移量与打印平台移动距离不是线性的。在本发明中,在全范围打印的正方形样本的x和y方向上的至少5个均匀分布的点上测量偏移。用最小二乘法拟合得到的至少二阶多项式误差曲线将用于打印平台在XY方向的平移中,以补偿偏移,从而确保拼接打印样本的精度在规格范围内。In precision printing with an error requirement of less than 10 μm, it is difficult for the assembly tolerance of the printing platform to be within the allowable range; and the offset of the axis positioning and the movement distance of the printing platform are not linear. In the present invention, the offset is measured on at least 5 uniformly distributed points in the x and y directions of the square sample printed in the full range. The at least second-order polynomial error curve obtained by the least square fitting method will be used in the translation of the printing platform in the XY direction to compensate for the offset, so as to ensure that the accuracy of the spliced printed samples is within the specification range.
本发明提供了三种打印模式(图4)。当只需要打印一个小于单个曝光尺寸的样品时,打印平台在打印过程中不会移动,这称为单次曝光模式。如果需要多个相同的样本,则打印平台于XY方向将逐步移动并以阵列形式打印相同的样本,这称为阵列曝光模式。对于小批量生产,此模式比重复单次曝光模式快得多。当样本大小增加到超过单次曝光的大小时,系统将通过在公共边缘上重叠5μm至20μm,将一层进一步分成多个部分,并将相邻部分拼接成整层。这是拼接曝光模式。当一个样品需要多个相同的样本但由于样品大于单次曝光而需要拼接曝光时,可以将拼接模式与阵列模式结合使用。The present invention provides three printing modes (Figure 4). When only a sample smaller than a single exposure size needs to be printed, the printing platform will not move during the printing process, which is called single exposure mode. If multiple identical samples are required, the printing platform will gradually move in the XY direction and print the same samples in an array, which is called the array exposure mode. For small batch production, this mode is much faster than the repeated single exposure mode. When the sample size increases beyond the size of a single exposure, the system will further divide a layer into multiple parts by overlapping 5μm to 20μm on the common edge, and stitch adjacent parts into a whole layer. This is the stitching exposure mode. When a sample requires multiple identical samples but splicing exposure is required because the sample is larger than a single exposure, the splicing mode can be used in combination with the array mode.
本发明一实施例中,打印头30位于基板的顶部,并浸入树脂中1至10毫米(图5)。浸入深度取决于树脂的粘度,较薄的树脂进行较浅的浸没。投影镜头将图像从LCD或DLP芯片投射到透明打印头的下表面(湿表面),完成一次曝光后,在拼接和阵列曝光打印模式下的打印平台沿X、Y方向移动或控制打印头沿X/Y方向移动,将打印头移至相邻区域以进行下一次曝光,但在公共边上有大约5-20微米的重叠,从而将相邻部分融合在一起。当打印头移至新区域时,打印头锥端的坚硬边缘将用作树脂涂层刮刀。涂层厚度由打印头的平头和样品顶层之间的间隙确定。当打印头移至相邻区域时,打印头后方的树脂在重力和表面张力的作用下流动并覆盖先前的裸露区域。在打印完整个层之后,在样品台向下移动一层的厚度去定义下一层新鲜树脂之前,打印头将移动到样品边界之外。In an embodiment of the present invention, the print head 30 is located on the top of the substrate and is immersed in the resin by 1 to 10 mm (Figure 5). The depth of immersion depends on the viscosity of the resin, and thinner resins perform shallower immersion. The projection lens projects the image from the LCD or DLP chip to the lower surface (wet surface) of the transparent print head. After one exposure is completed, the print platform in the stitching and array exposure printing mode moves along the X and Y directions or controls the print head along X Move in the /Y direction to move the print head to an adjacent area for the next exposure, but there is an overlap of about 5-20 microns on the common side, thereby fusing the adjacent parts together. When the print head is moved to a new area, the hard edge of the cone end of the print head will act as a resin coating blade. The coating thickness is determined by the gap between the flat end of the print head and the top layer of the sample. When the print head moves to an adjacent area, the resin behind the print head flows under the action of gravity and surface tension and covers the previously exposed area. After printing a complete layer, the print head will move beyond the boundary of the sample before the sample stage moves down the thickness of one layer to define the next layer of fresh resin.
通过将打印头移至样品边界之外,打印头与样品之间的相互作用力仅为流体剪切力。该力远小于现有投影微立体光刻中典型存在的树脂中两个表面的垂直或法向分离。如下式所示:By moving the print head outside the boundary of the sample, the interaction force between the print head and the sample is only the fluid shear force. This force is much smaller than the vertical or normal separation of the two surfaces in the resin that is typical in existing projection micro-stereolithography. As shown in the following formula:
σ=-pI+2μεσ=-pI+2με
这里σ是流体应力张量,p是压力,I是确定张量,μ是流体粘度,ε是速度梯度张量(或流体应变张量)。对于两个几乎接触的表面,以10mm/s的速 度在粘度为50cPs的树脂中正常分离时,真空效果约为1e5Pas。但是,如果两个表面以20μm的间隙彼此切成薄片,则力约为1e2Pas。因此,该方法大大降低了损坏样品的可能性。定义新层后,打印头将移入并开始逐步扫描和打印下一层。Here σ is the fluid stress tensor, p is the pressure, I is the definite tensor, μ is the fluid viscosity, and ε is the velocity gradient tensor (or fluid strain tensor). For two surfaces that are almost in contact, when they are normally separated in a resin with a viscosity of 50cPs at a speed of 10mm/s, the vacuum effect is about 1e5Pas. However, if the two surfaces are sliced from each other with a gap of 20 μm, the force is about 1e2Pas. Therefore, this method greatly reduces the possibility of damage to the sample. After defining the new layer, the print head will move in and begin to scan and print the next layer step by step.
在本发明中,可沿XYZ方向移动样本的配置,也可以在样本保持静止的情况下移动打印头以实现打印头与样本之间的相对运动。In the present invention, the configuration of the sample can be moved in the XYZ direction, or the print head can be moved while the sample remains stationary to achieve relative movement between the print head and the sample.
如图6所示,在另一个实施例中,打印头和样品基板位置可以对调。打印头的透明窗在树脂的自由表面下方为0.5mm至2mm。基板位于顶部,并在XYZ方向上移动以定义层和拼接层侧面。在这种构造中,已打印的部分在打印过程中可以保证持续数十小时不浸泡在树脂中。这对于某些水凝胶树脂可能是需要的,因为长时间浸泡在树脂中会导致打印零件膨胀,从而导致尺寸误差。As shown in Fig. 6, in another embodiment, the positions of the print head and the sample substrate can be reversed. The transparent window of the print head is 0.5mm to 2mm below the free surface of the resin. The substrate is on the top and moves in the XYZ direction to define the layer and splicing layer sides. In this configuration, the printed part can be guaranteed to last tens of hours without being soaked in resin during the printing process. This may be required for some hydrogel resins, because prolonged soaking in the resin will cause the printed parts to swell, which can lead to dimensional errors.
随着树脂粘度的增加,树脂流动并覆盖印刷区域所花费的时间将越来越长。As the viscosity of the resin increases, it will take longer and longer for the resin to flow and cover the printed area.
进一步,优选实施例中将频率大于10kHz的超声源引入打印头,比如在打印头外壳上紧贴压电陶瓷,来增加树脂的流动速度。Further, in a preferred embodiment, an ultrasonic source with a frequency greater than 10 kHz is introduced into the print head, for example, a piezoelectric ceramic is closely attached to the print head housing to increase the flow speed of the resin.
如图7所示,本发明又一实施例中,将打印头与样品的顶层一起提高到树脂自由面之上100至500微米;高度又取决于树脂的粘度。在此弯月面打印头配置中,打印整个层的步骤与上述步骤相同,但是在完成一层打印后,样品和基板一起将浸入树脂2mm至8mm,以使新鲜的树脂覆盖样品的上表面。然后,样品将向打印头高度移回但少一小步,这个小步等同于下一层的厚度。同样,打印头将从样品外部移入、刮擦、涂覆并逐步曝光新层。这样,打印头会将多余的树脂推回到树脂槽中。As shown in FIG. 7, in another embodiment of the present invention, the print head and the top layer of the sample are raised to 100 to 500 microns above the free surface of the resin; the height depends on the viscosity of the resin. In this meniscus print head configuration, the steps for printing the entire layer are the same as the above steps, but after one layer is printed, the sample and the substrate will be immersed in resin 2mm to 8mm together so that fresh resin covers the upper surface of the sample. Then, the sample will move back to the height of the print head but one small step less, which is equivalent to the thickness of the next layer. Likewise, the print head will move in from the outside of the sample, scratch, coat, and gradually expose a new layer. In this way, the print head pushes the excess resin back into the resin tank.
本发明以比目前更快的速度打印在更大的面积上。The invention prints on a larger area at a faster speed than the current one.
本实施例的3D打印方法:生成要在计算机中打印的样品或对象的3D数字模型,然后将数字模型切成一系列图像序列,图像序列中的每个图像都代表3D数字模型的一层,这样,在每一层生成之后,样品或物体就已经成型了。The 3D printing method of this embodiment: generate a 3D digital model of the sample or object to be printed in a computer, and then cut the digital model into a series of image sequences, each image in the image sequence represents a layer of the 3D digital model, In this way, after each layer is formed, the sample or object is already formed.
透明打印头包括一个表面平滑的锥端,打印头位于装有感光树脂和在打印中用于固定样品的基板(例如样品架)的树脂槽旁边,其中打印头的平滑锥端与感光树脂接触。将透明打印头移入到既定位置,从而可选择性移动光敏树脂的位置,在此移动过程中,打印头的平滑锥端的边缘能将树脂刮走。通过打印头平滑锥端和样品顶层之间的间隙来定义涂层厚度。或者如果之前没有任何打印层,涂层厚度则为打印头平滑锥端和用于固定样品的基板之间的间隙。The transparent print head includes a tapered end with a smooth surface. The print head is located next to a resin tank containing photosensitive resin and a substrate (such as a sample holder) used to fix the sample during printing. The smooth tapered end of the print head is in contact with the photosensitive resin. Move the transparent print head to a predetermined position, so that the position of the photosensitive resin can be selectively moved. During this movement, the edge of the smooth cone end of the print head can scrape the resin away. The coating thickness is defined by the gap between the smooth tapered end of the print head and the top layer of the sample. Or if there is no print layer before, the coating thickness is the gap between the smooth tapered end of the print head and the substrate used to fix the sample.
打印头放置好后,图像序列中的图像将被发送到LCD或DLP芯片。芯片与光源一起通过投影镜头将图像投射到透明打印头的平滑锥端上,并开始在投影 图像允许光源到达的光敏树脂区域中进行固化。After the print head is placed, the images in the image sequence will be sent to the LCD or DLP chip. The chip and the light source project the image onto the smooth cone end of the transparent print head through the projection lens together with the light source, and begin to cure in the photosensitive resin area where the projected image allows the light source to reach.
当图像大于单次曝光的大小或要进行后续涂层时,样品基板和/或打印头会被移动来继续进行打印。When the image is larger than the size of a single exposure or subsequent coating is to be performed, the sample substrate and/or print head will be moved to continue printing.
基板和/或打印头通过高精度定位设备沿X,Y,Z方向或X,Y方向移动,可以将基板和/或打印头定位在新的区域或深度。The substrate and/or the print head are moved along the X, Y, Z direction or the X, Y direction by a high-precision positioning device, and the substrate and/or the print head can be positioned in a new area or depth.
可以将样品测量数据的内插偏移误差曲线输入打印平台,从而补偿由于机械公差引起的误差。The interpolation offset error curve of the sample measurement data can be input into the printing platform to compensate for errors caused by mechanical tolerances.
在许多实施例中,打印头的平滑锥端被不粘的透明透气的膜覆盖形成透明窗并密封,从而防止了由于打印头粘附到层导致的变形或由于树脂的过早固化而导致的在打印头锥端的堆积。例如,氧气可以抑制自由基链反应,可以使打印头因引入的空气/气体压力导致变形。因此,通常通过引入可控量的气体,例如氧气,来控制打印头中的压力以补偿由于打印头的透明窗与打印树脂的接触而引起的透明窗的变形。In many embodiments, the smooth tapered end of the print head is covered by a non-stick transparent and breathable film to form a transparent window and sealed, thereby preventing deformation due to the adhesion of the print head to the layer or premature curing of the resin. Accumulation at the tapered end of the print head. For example, oxygen can inhibit free radical chain reactions and can deform the print head due to the pressure of the introduced air/gas. Therefore, the pressure in the print head is usually controlled by introducing a controllable amount of gas, such as oxygen, to compensate for the deformation of the transparent window caused by the contact between the transparent window of the print head and the printing resin.
计算机的数字图像由LCD或DLP微显示芯片与光源一起通过投影镜头投影到透明打印头的透明窗上,其中投影镜头具有与样品或基板相交的光轴。投影镜头位于样品或基板上方,并且位于基板的表面和CCD(电荷耦合器件)之间。CCD(电荷耦合器件)能够监控打印头上的投影,并且可以沿着光轴通过投影镜头聚焦。其中样品或基板沿X,Y和Z方向上的运动和位置由打印平台控制。The digital image of the computer is projected on the transparent window of the transparent print head by the LCD or DLP microdisplay chip together with the light source through the projection lens, where the projection lens has an optical axis that intersects the sample or substrate. The projection lens is located above the sample or substrate, and between the surface of the substrate and the CCD (Charge Coupled Device). CCD (Charge Coupled Device) can monitor the projection on the print head, and can be focused along the optical axis through the projection lens. The movement and position of the sample or substrate along the X, Y and Z directions are controlled by the printing platform.
本发明的3D打印方法相比目前可用的方法,该方法能使涂层在更大面积和以更快的速度被打印。该方法包括:Compared with the currently available methods, the 3D printing method of the present invention enables the coating to be printed on a larger area and at a faster speed. The method includes:
生成要在计算机中打印的样品的3D数字模型,然后将3D数字模型切成图像序列,其中图像序列中的每个图像代表3D数字模型的一层。Generate a 3D digital model of the sample to be printed in the computer, and then slice the 3D digital model into an image sequence, where each image in the image sequence represents a layer of the 3D digital model.
将透明打印头置于在树脂槽附近。该树脂槽装设有感光树脂的和一个用于在打印过程中固定样品的基板。其中透明打印头的端部设置有与光敏树脂接触的平滑锥端。Place the transparent print head near the resin tank. The resin tank is equipped with photosensitive resin and a substrate for fixing the sample during the printing process. Wherein, the end of the transparent print head is provided with a smooth tapered end in contact with the photosensitive resin.
将透明打印头移动到用于选择性曝光光敏树脂的位置。其中,打印头的平滑锥端的边缘将通过移动多余的树脂来充当刮板,从而使涂层的厚度等于打印头的平滑锥端与样品顶层之间的间隙。或者,当之前用于样品的涂层还没有被打印时,涂层的厚度将等于打印头的平滑锥端与用于固定样品的基板之间的间隙。Move the transparent print head to a position for selective exposure of photosensitive resin. Among them, the edge of the smooth cone end of the print head will act as a squeegee by moving the excess resin, so that the thickness of the coating is equal to the gap between the smooth cone end of the print head and the top layer of the sample. Or, when the coating previously used for the sample has not been printed, the thickness of the coating will be equal to the gap between the smooth tapered end of the print head and the substrate used to fix the sample.
将图像序列中的的一个图像发送到LCD或DLP芯片,并与光源一起通过投影镜头将图像投影到透明打印头的平滑锥端上,从而在投影图像允许来自光源的光到达感光树脂的区域内开始固化感光树脂。Send an image in the image sequence to the LCD or DLP chip, and project the image on the smooth cone end of the transparent print head through the projection lens together with the light source, so that the projected image allows the light from the light source to reach the photosensitive resin area Start curing the photosensitive resin.
当图像大于单次曝光的尺寸或要进行后续涂层应用时,样品基板和/或打印头将被移动去继续打印图像。When the image is larger than the size of a single exposure or a subsequent coating application is to be performed, the sample substrate and/or print head will be moved to continue printing the image.
打印平台可带动基板或样品沿X/Y方向移动,通过升降装置带动基板或样品升降运动。The printing platform can drive the substrate or sample to move in the X/Y direction, and the lifting device can drive the substrate or sample to move up and down.
本实施例的打印头的平坦的锥端由不粘的、透明的、透气膜形成的透明窗覆盖并密封。透明窗的材料为透氧材料。透明窗的材料采用聚二甲基硅氧烷或氟树脂Teflon AF。The flat tapered end of the print head of this embodiment is covered and sealed by a transparent window formed of a non-sticky, transparent, and air-permeable film. The material of the transparent window is an oxygen permeable material. The material of the transparent window is polydimethylsiloxane or fluororesin Teflon AF.
当一个曝光完成时,在拼接和阵列曝光打印模式下,控制打印头移动到相邻区域以进行下一次曝光。其中,当打印头移动到新区域时,打印头锥端的硬边缘将用作树脂涂层刮刀,将随后的涂层的厚度由打印头的平滑锥端和样品顶层之间间隙确定。或者在没有任何形成样品的涂层被打印时,该涂层的厚度将等于打印头的平滑锥端与用于固定样品的基板之间的间隙。When one exposure is completed, in the stitching and array exposure printing mode, the print head is controlled to move to an adjacent area for the next exposure. Among them, when the print head moves to a new area, the hard edge of the cone end of the print head will be used as a resin coating scraper, and the thickness of the subsequent coating is determined by the gap between the smooth cone end of the print head and the top layer of the sample. Or when no sample-forming coating is printed, the thickness of the coating will be equal to the gap between the smooth tapered end of the print head and the substrate for fixing the sample.
拼接打印时,完成曝光的区域与相邻区域之间的公共边缘上采用5-20微米的重叠,从而将区域融合在一起。When stitching and printing, an overlap of 5-20 microns is used on the common edge between the exposed area and the adjacent area to fuse the areas together.
基于样品测量数据的内插偏移误差曲线进入打印平台于X/Y方向移动中进行补偿,以补偿机械公差来确保拼接打印样品的精度在规格内。The interpolation offset error curve based on the sample measurement data enters the printing platform and moves in the X/Y direction for compensation to compensate for mechanical tolerances to ensure that the accuracy of the spliced printed samples is within the specifications.
本发明一优选实施例中将一个具有大于10kHz频率的超声源被结合到打印头中以提升树脂流动速度。In a preferred embodiment of the present invention, an ultrasonic source with a frequency greater than 10 kHz is incorporated into the print head to increase the resin flow speed.
另通过控制打印头中的压力来补偿由于与打印树脂接触而引起的打印头的透明窗的变形。In addition, the deformation of the transparent window of the print head caused by contact with the printing resin is compensated by controlling the pressure in the print head.
本发明优选实施例中,打印头被浸入光敏树脂中1至10毫米。如果尚未涂覆涂层,则将打印头与样品的顶层或基板一起提高至光敏树脂之上100至500微米,此时打印头通过与光敏树脂接触而形成一个光敏树脂弯月面。In a preferred embodiment of the present invention, the print head is immersed in the photosensitive resin by 1 to 10 mm. If the coating has not been applied, raise the print head together with the top layer or substrate of the sample to 100 to 500 microns above the photosensitive resin. At this time, the print head forms a photosensitive resin meniscus by contacting the photosensitive resin.
打印头内的压力是通过控制引入到打印头中的气体的压力进行实现。引入打印头的气体包括氧气或氧气混合气体。The pressure inside the print head is achieved by controlling the pressure of the gas introduced into the print head. The gas introduced into the print head includes oxygen or a mixed gas of oxygen.
来自计算机的数字图像由LCD或DLP微显示芯片与光源一起通过投影镜头投影到拥有密封,光学透明且具有可透气的平滑锥端的打印头上。其中投影镜头具有与样品或基板相交的光轴,投影镜头位于基板上方,并且位于基板与电荷耦合器件之间。其中的电荷耦合器件能够监测打印头上的投影,并且可通过投影镜头沿光轴聚焦。其中样品基板在X,Y和Z方向上的运动和位置由三个精密工作台控制。在一实施例中打印头位于基板上方。在另一实施例中基板位于打印头上方。The digital image from the computer is projected by the LCD or DLP microdisplay chip together with the light source through the projection lens to the print head with a sealed, optically transparent and smooth cone end that is breathable. The projection lens has an optical axis that intersects the sample or the substrate, and the projection lens is located above the substrate and between the substrate and the charge coupled device. The charge-coupled device can monitor the projection on the print head, and can focus along the optical axis through the projection lens. The movement and position of the sample substrate in the X, Y and Z directions are controlled by three precision workbenches. In one embodiment, the print head is located above the substrate. In another embodiment, the substrate is located above the print head.
以上述依据本申请的理想实施例为启示,通过上述的说明内容,相关工作 人员完全可以在不偏离本项申请技术思想的范围内,进行多样的变更以及修改。本项申请的技术性范围并不局限于说明书上的内容,必须要根据权利要求范围来确定其技术性范围。Taking the above-mentioned ideal embodiment based on this application as inspiration, and through the above description, relevant staff can make various changes and modifications without departing from the scope of the technical idea of this application. The technical scope of this application is not limited to the content in the specification, and its technical scope must be determined according to the scope of the claims.
本领域内的技术人员应明白,本申请的实施例可提供为方法、系统、或计算机程序产品。因此,本申请可采用完全硬件实施例、完全软件实施例、或结合软件和硬件方面的实施例的形式。而且,本申请可采用在一个或多个其中包含有计算机可用程序代码的计算机可用存储介质(包括但不限于磁盘存储器、CD-ROM、光学存储器等)上实施的计算机程序产品的形式。Those skilled in the art should understand that the embodiments of the present application can be provided as methods, systems, or computer program products. Therefore, this application may adopt the form of a complete hardware embodiment, a complete software embodiment, or an embodiment combining software and hardware. Moreover, this application may adopt the form of a computer program product implemented on one or more computer-usable storage media (including but not limited to disk storage, CD-ROM, optical storage, etc.) containing computer-usable program codes.
本申请是参照根据本申请实施例的方法、设备(系统)、和计算机程序产品的流程图和/或方框图来描述的。应理解可由计算机程序指令实现流程图和/或方框图中的每一流程和/或方框、以及流程图和/或方框图中的流程和/或方框的结合。可提供这些计算机程序指令到通用计算机、专用计算机、嵌入式处理机或其他可编程数据处理设备的处理器以产生一个机器,使得通过计算机或其他可编程数据处理设备的处理器执行的指令产生用于实现在流程图一个流程或多个流程和/或方框图一个方框或多个方框中指定的功能的装置。This application is described with reference to flowcharts and/or block diagrams of methods, devices (systems), and computer program products according to embodiments of this application. It should be understood that each process and/or block in the flowchart and/or block diagram, and the combination of processes and/or blocks in the flowchart and/or block diagram can be realized by computer program instructions. These computer program instructions can be provided to the processor of a general-purpose computer, a special-purpose computer, an embedded processor, or other programmable data processing equipment to generate a machine, so that the instructions executed by the processor of the computer or other programmable data processing equipment are generated It is a device that realizes the functions specified in one process or multiple processes in the flowchart and/or one block or multiple blocks in the block diagram.
这些计算机程序指令也可存储在能引导计算机或其他可编程数据处理设备以特定方式工作的计算机可读存储器中,使得存储在该计算机可读存储器中的指令产生包括指令装置的制造品,该指令装置实现在流程图一个流程或多个流程和/或方框图一个方框或多个方框中指定的功能。These computer program instructions can also be stored in a computer-readable memory that can guide a computer or other programmable data processing equipment to work in a specific manner, so that the instructions stored in the computer-readable memory produce an article of manufacture including the instruction device. The device implements the functions specified in one process or multiple processes in the flowchart and/or one block or multiple blocks in the block diagram.
这些计算机程序指令也可装载到计算机或其他可编程数据处理设备上,使得在计算机或其他可编程设备上执行一系列操作步骤以产生计算机实现的处理,从而在计算机或其他可编程设备上执行的指令提供用于实现在流程图一个流程或多个流程和/或方框图一个方框或多个方框中指定的功能的步骤。These computer program instructions can also be loaded on a computer or other programmable data processing equipment, so that a series of operation steps are executed on the computer or other programmable equipment to produce computer-implemented processing, so as to execute on the computer or other programmable equipment. The instructions provide steps for implementing the functions specified in one process or multiple processes in the flowchart and/or one block or multiple blocks in the block diagram.

Claims (10)

  1. 一种3D打印方法,其特征在于,包括:A 3D printing method is characterized in that it comprises:
    切片:生成待打印的样品的3D数字模型,将3D数字模型切成图像序列,所述图像序列中的每张图像表示3D数字模型的一层,根据模型的切片方向控制打印头的打印方向;Slicing: generating a 3D digital model of the sample to be printed, cutting the 3D digital model into an image sequence, each image in the image sequence represents a layer of the 3D digital model, and controlling the printing direction of the print head according to the slicing direction of the model;
    投影:将图像发送至微显示器件,带有光源的微显示器件通过投影镜头将图像投影到打印头的一端的透明窗和树脂的交界面上;Projection: The image is sent to the micro display device, and the micro display device with a light source projects the image on the interface between the transparent window at one end of the print head and the resin through the projection lens;
    图像检测:图像采集单元采集通过分光镜反射回来的图像并检测投影图像的质量,根据检测的质量控制进行打印;Image detection: The image acquisition unit collects the image reflected by the spectroscope and detects the quality of the projected image, and prints according to the quality control of the detection;
    曝光打印:带有光源的微显示器件用光照射投影图像,曝光产生固化层,代表投影图像在3D数字模型中相应的一层,当一次曝光结束,打印头移至新区域,打印头的锥端的硬边缘被用作树脂层刮刀,涂层厚度由打印头的端部与样品顶层之间的间隙确定,由于打印头位于树脂自由面下方1到5毫米,其后方的树脂流动并覆盖先前的裸露区域;Exposure printing: The micro display device with a light source irradiates the projected image with light, and the exposure produces a cured layer, which represents the corresponding layer of the projected image in the 3D digital model. When an exposure is over, the print head moves to a new area, the cone of the print head The hard edge of the end is used as a resin layer scraper. The coating thickness is determined by the gap between the end of the print head and the top layer of the sample. Since the print head is located 1 to 5 mm below the free surface of the resin, the resin behind it flows and covers the previous Bare area
    继续曝光打印:一层打印完毕后,控制打印头移动离开打印区域,打印头与样品平移脱离,调整打印头或样品台回位,打印头移动到样品边界之外,调整打印头与样品之间的上下距离为打印下一层的厚度,样品与打印头的透明窗之间的缝隙充满打印下一层所需的树脂,依次重复曝光打印,打印头刮擦、涂覆逐步曝光新一层,打印下一层,直至打印完毕,模型在树脂槽中被复制出来。Continue to expose and print: After one layer is printed, control the print head to move away from the print area, move the print head away from the sample, adjust the print head or sample stage to return, move the print head outside the boundary of the sample, adjust the print head and sample The upper and lower distance is the thickness of the next layer to be printed. The gap between the sample and the transparent window of the print head is filled with the resin needed to print the next layer. The exposure and printing are repeated in sequence, and the print head is scratched and coated to gradually expose a new layer. Print the next layer until the printing is completed and the model is copied in the resin tank.
  2. 根据权利要求1所述的3D打印方法,其特征在于,在树脂弯月面式打印中,当完成一层打印后,样品与基板浸入树脂中2mm至8mm,以使新的树脂覆盖样品的顶面,然后基板带动样品回位到树脂自由面上500微米到1000微米,调整打印头与样品之间距离为打印下一层的厚度,打印头从样品外部移入、刮擦、涂覆并逐步曝光新层,同时打印头把多余树脂推回到树脂槽中。The 3D printing method according to claim 1, wherein in resin meniscus printing, after one layer of printing is completed, the sample and the substrate are immersed in the resin by 2mm to 8mm, so that the new resin covers the top of the sample. Then the substrate drives the sample back to the free surface of the resin from 500 microns to 1000 microns. Adjust the distance between the print head and the sample to the thickness of the next layer. The print head moves in from the outside of the sample, scratches, coats, and gradually exposes. New layer, while the print head pushes the excess resin back into the resin tank.
  3. 根据权利要求1所述的3D打印方法,其特征在于,所述打印头为中空梯形柱体结构,其锥端端部设置一个锁环,所述打印头的锥端覆盖不粘膜并形成透明窗,所述锁环置于所述透明窗上部。The 3D printing method according to claim 1, wherein the print head has a hollow trapezoidal cylindrical structure, and a lock ring is provided at the tapered end of the print head, and the tapered end of the print head covers the non-stick film and forms a transparent window , The lock ring is placed on the upper part of the transparent window.
  4. 根据权利要求1所述的3D打印方法,其特征在于,所述打印头位于基板下部进行打印,所述打印头的透明窗位于树脂的自由表面下方0.5-2mm,打印头与基板之间沿X/Y/Z方向相对移动以定义层和拼接层分面。The 3D printing method according to claim 1, wherein the print head is located at the lower part of the substrate for printing, the transparent window of the print head is located 0.5-2mm below the free surface of the resin, and the gap between the print head and the substrate /Y/Z direction relative movement to define the layer and splicing layer facet.
  5. 根据权利要求1至4任意一项所述的3D打印方法,其特征在于,所述基板设置在打印平台上,打印平台带动基板根据打印在X、Y、Z方向上移动,曝光打印或继续曝光打印时,根据P=P 0+P 1控制打印头压力以补偿其与打印树脂接触而引起薄膜透明窗的变形,P 0为打印头的不粘膜接触的空气大气压,P 1=ρ 1gh,ρ 1为树脂密度,g重力加速度,h为打印头的不粘膜在树脂里的深度;打印时,通过气体的流量控制打印头中的压力,若压力传感器检测到打印头的压力与设定压力有差异时,控制质量流量控制器根据PID设置调整流量,直至打印头中的压力达到设定值。 The 3D printing method according to any one of claims 1 to 4, wherein the substrate is arranged on a printing platform, and the printing platform drives the substrate to move in the X, Y, and Z directions according to the printing, and exposes printing or continues to expose During printing, the pressure of the print head is controlled according to P=P 0 +P 1 to compensate for the deformation of the transparent window of the film caused by its contact with the printing resin. P 0 is the atmospheric pressure of the air in contact with the non-stick film of the print head, P 11 gh, ρ 1 is the resin density, g acceleration of gravity, h is the depth of the non-stick film of the print head in the resin; during printing, the pressure in the print head is controlled by the flow of gas, if the pressure sensor detects the pressure of the print head and the set pressure When there is a difference, control the mass flow controller to adjust the flow according to the PID setting until the pressure in the print head reaches the set value.
  6. 根据权利要求5所述的3D打印方法,其特征在于,还包括设置在打印头的下游出口的限流器,限流器处于阻流状态,限流器流量与打印头压力成正比。The 3D printing method according to claim 5, further comprising a restrictor arranged at the downstream outlet of the print head, the restrictor is in a flow blocking state, and the flow of the restrictor is proportional to the pressure of the print head.
  7. 根据权利要求1至4任意一项所述的3D打印方法,其特征在于,若打印图像大于单个曝光尺寸则进行拼接打印,将图像划分为多个层部分,逐步曝光每个层部分,并叠边拼接成整层,每个层部分在拼接边上与相邻图像重叠5-20微米。The 3D printing method according to any one of claims 1 to 4, wherein if the printed image is larger than a single exposure size, stitch printing is performed, the image is divided into multiple layers, and each layer is gradually exposed and stacked The edges are stitched into a whole layer, and each layer part overlaps the adjacent image by 5-20 microns on the stitching edge.
  8. 根据权利要求6所述的3D打印方法,其特征在于,打印时,对打印平台的X/Y方向运动坐标进行误差补偿(X 0+XError(X 0,Y 0),Y 0+YError(X 0,Y 0)),(X 0,Y 0)为理论坐标, The 3D printing method according to claim 6, characterized in that, during printing, error compensation is performed on the X/Y direction movement coordinates of the printing platform (X 0 +XError(X 0 ,Y 0 ),Y 0 +YError(X 0 ,Y 0 )), (X 0 ,Y 0 ) are theoretical coordinates,
    XError(X 0,Y 0)=C 1+C 2+C 3Y 0+C 4X 0Y 0+C 5X 0 2+C 6Y 0 2 XError(X 0 ,Y 0 )=C 1 +C 2 +C 3 Y 0 +C 4 X 0 Y 0 +C 5 X 0 2 +C 6 Y 0 2
    YError(X 0,Y 0)=D 1+D 2+D 3Y 0+D 4X 0Y 0+D 5X 0 2+D 6Y 0 2 YError(X 0 ,Y 0 )=D 1 +D 2 +D 3 Y 0 +D 4 X 0 Y 0 +D 5 X 0 2 +D 6 Y 0 2
    C 1-C 6多项式系数,基于拼接打印时,拼接点于X方向上测量误差用二次最小二乘法拟合计算得出, C 1 -C 6 polynomial coefficients, based on the stitching and printing, the measurement error of the stitching point in the X direction is calculated by the quadratic least squares method.
    D 1-D 6多项式系数,基于拼接打印时,拼接点于Y方向上测量误差用二次最小二乘法拟合计算得出。 The D 1 -D 6 polynomial coefficients are calculated based on the measurement error of the splicing point in the Y direction by the quadratic least squares fitting calculation during splicing printing.
  9. 根据权利要求1至4任意一项所述的3D打印方法,其特征在于,当打印头移动后停下准备曝光时,控制微显示器件先在打印头的不粘膜中心投影图片,图像采集单元捕捉并分析成像质量,将成像与设置的理论值比较,若打印头的不粘模变形,根据变形公式
    Figure PCTCN2020097098-appb-100001
    The 3D printing method according to any one of claims 1 to 4, characterized in that, when the print head is moved and stopped to prepare for exposure, the micro display device is controlled to first project a picture on the center of the non-stick film of the print head, and the image acquisition unit captures And analyze the imaging quality, compare the imaging with the set theoretical value, if the non-stick mold of the print head is deformed, according to the deformation formula
    Figure PCTCN2020097098-appb-100001
    调整流量以调整打印头中的压力,打印头锥端设置的不粘膜的变形与压力差成正比,υ泊松系数,a为打印头的不粘模的半径,E杨氏模量,h为打印头的不粘模的厚度,p为打印头不粘模的两边的压力差。Adjust the flow to adjust the pressure in the print head. The deformation of the non-stick film set at the cone end of the print head is proportional to the pressure difference, υ Poisson coefficient, a is the radius of the non-stick mold of the print head, E Young's modulus, h is The thickness of the non-stick mold of the print head, p is the pressure difference between the two sides of the non-stick mold of the print head.
  10. 一种3D打印系统,包括:建立3D数字模型并将3D数字模型切成图像序列的图像系统、控制系统、受控接收系列图片并投影到打印头的不粘模与树脂的交界面的微显示器件、与所述微显示器件对应设置并受控进行投影的投影镜头、采集并检测投影图像的质量的图像采集单元、与所述图像采集单元相应设置并将投影的图像反射给所述图像采集单元进行接收采集的分光镜、打印平台、设置在所述打印平台上并装载有树脂的树脂槽、设置在打印平台上的升降装置、设置在树脂槽中并与升降装置连接的基板、与所述基板相应设置的中空梯形柱体结构的打印头,其特征在于,所述打印头下端的硬边缘作为刮刀使用、打印时刮擦树脂,所述打印头包括:中空的梯形柱体的内腔、覆设在下端的不粘膜形成的透明窗、设置在下端并置于透明窗上部的锁环、设置在上端并受控控制输入气体流量对打印头的压力进行实时调整的质量流量控制器、设置在打印头的下游出口并置于锁环上部的限流器。A 3D printing system, including: an image system that establishes a 3D digital model and cuts the 3D digital model into an image sequence, a control system, and a micro-display of the interface between the non-stick mold and the resin that is controlled to receive the series of pictures and project them to the print head A device, a projection lens that is set corresponding to the micro display device and controlled to perform projection, an image acquisition unit that collects and detects the quality of the projected image, and is set corresponding to the image acquisition unit and reflects the projected image to the image acquisition The unit receives and collects the spectroscope, the printing platform, the resin tank provided on the printing platform and loaded with resin, the lifting device provided on the printing platform, the substrate provided in the resin tank and connected with the lifting device, and the The print head with a hollow trapezoidal column structure corresponding to the substrate is characterized in that the hard edge at the lower end of the print head is used as a squeegee to scrape resin during printing, and the print head includes: an inner cavity of a hollow trapezoidal column , The transparent window formed by the non-stick film covering the lower end, the lock ring arranged on the lower end and placed on the upper part of the transparent window, the mass flow controller that is set on the upper end and controls the input gas flow to adjust the pressure of the print head in real time, A flow restrictor located at the downstream outlet of the print head and placed on top of the lock ring.
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