WO2021090989A1 - Composition for reducing bad odours - Google Patents

Composition for reducing bad odours Download PDF

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Publication number
WO2021090989A1
WO2021090989A1 PCT/KR2019/015211 KR2019015211W WO2021090989A1 WO 2021090989 A1 WO2021090989 A1 WO 2021090989A1 KR 2019015211 W KR2019015211 W KR 2019015211W WO 2021090989 A1 WO2021090989 A1 WO 2021090989A1
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weight
acid
composition
ppm
parts
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PCT/KR2019/015211
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French (fr)
Korean (ko)
Inventor
심재성
오지영
임희정
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씨제이제일제당 (주)
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Priority to US17/617,488 priority Critical patent/US20220248724A1/en
Priority to PCT/KR2020/015551 priority patent/WO2021091327A1/en
Publication of WO2021090989A1 publication Critical patent/WO2021090989A1/en

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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/273—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption using adsorption or absorption agents, resins, synthetic polymers, or ion exchangers
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00—Function of food ingredients
    • A23V2200/15—Flavour affecting agent
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00—Food ingredients
    • A23V2250/02—Acid
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00—Food ingredients
    • A23V2250/08—Alcohol
    • A23V2250/082—Ethanol
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00—Food ingredients
    • A23V2250/20—Natural extracts
    • A23V2250/21—Plant extracts
    • A23V2250/2132—Other phenolic compounds, polyphenols

Definitions

  • the present application relates to a composition for reducing odor containing polyphenol and ethanol.
  • TMA trimethylamine
  • TMAO odorless trimethylamine oxide
  • a method of adding an acid to neutralize TMA, which is a basic substance, to remove the fishy smell, mainly using vinegar is a method of removing the fishy smell.
  • the amount of use is limited due to the strong flavor peculiar to vinegar.
  • TMA trimethylamine
  • an aspect of the present application provides a composition for reducing odor containing polyphenol and ethanol.
  • another aspect of the present application provides a method for reducing malodor comprising the step of adding a composition containing polyphenol and ethanol to a malodor product.
  • composition of the present application has an excellent ability to reduce trimethylamine (TMA), which is a cause of fishy smell, and when applied to cooking, it can effectively remove fishy smell and save flavor, and can be processed such as canned food, fish meat, and home convenience food (HMR). It has the advantage of being easy to apply to food.
  • TMA trimethylamine
  • the present application provides a composition for reducing odor containing polyphenol and ethanol.
  • polyphenol refers to a compound containing one or more phenols having one or more hydroxy groups in the molecule.
  • the polyphenol is a concept including derivatives such as polyphenol itself and its glycoside, its alkylated compound, and its esterified compound.
  • the polyphenol may include, without limitation, a polyphenol that achieves the object of the present application of reducing odor.
  • the polyphenols that can be used in the present application may be included without limitation, such as phenolic acid, flavonoids, stilbens, and lignin, and examples thereof include isoramnetin, isoramnetin.
  • Glycoside catechin, epicatechin, gallocatechin, epicatechin gallate, epigallocatechin, epigallocatechin gallate, ellagic acid, catechol, caffeic acid, caffeic acid ester, chlorogenic acid, camperol, camperol glycoside , Quercetin, quercetin glycoside, quercetagenin, genicetine, genicetine glycoside, tannic acid, anthocyanin, hydroquinone, hesperetin, hesperidine, gallic acid, gallic acid esters (lauryl gallate, propyl gallate, butyl gallate), 4 -Methylcatechol, 5-methylcatechol, 4-methoxycatechol, 5-methoxycatechol, methylcatechol-4-carboxylic acid, 2-methylresorcinol, 5-methylresorcinol, lignin, limo Citrin, Rimositrin Glycoside, Rimositrol, Luteolin, Luteolin Glycoside
  • polyphenol one or a combination of two or more selected from the group consisting of chlorogenic acid and caffeic acid may be used.
  • the chlorogenic acid is a compound in which caffeic acid and quinic acid are linked by an ester bond, and is represented by Formula 1 below.
  • the caffeic acid is a compound classified as hydroxy cinnamic acid, and is represented by Formula 2 below.
  • polyphenols may be used not only polyphenols derived from natural products, but also artificially synthesized polyphenols.
  • the natural product may be separated and purified by a method known in the art, for example, an extraction method, or a fermented product derived from a natural product may be used. Specifically, those derived from fermented vinegar may be used.
  • the fermented vinegar includes fermentation by a known method, and for example, may be obtained through primary fermentation of fermenting sugars such as glucose into ethanol and secondary fermentation of fermenting ethanol with acetic acid.
  • the natural product may be any material including polyphenols, without limitation, but may be plants. Specifically, Aloe, Anise Seed, Elder Tree, Spikeweed, Psyllium Seed, Orange Flower, Pimento Tree, Oregano, Valerian, Chamomile, Capsaicin Pepper, Cardamom, Cassia, Garlic, Caraway Seed, Clove, Cumin Seed, Coke Tree , Coriander seed, red tree, saffron, Japanese pepper tree, juniper berry, cinnamon, ginger, octagonal, St.
  • the polyphenol may be included in an amount of 0.01 parts by weight to 5 parts by weight based on 100 parts by weight of ethanol, but is not limited thereto.
  • the content of the polyphenol is one lower limit selected from 0.01 parts by weight, 0.02 parts by weight, 0.03 parts by weight, and 0.04 parts by weight based on 100 parts by weight of ethanol and/or 5 parts by weight, 3 parts by weight, 1 part by weight.
  • 0.7 parts by weight, 0.5 parts by weight, 0.45 parts by weight may be a content in a range consisting of one upper limit value selected from 0.4 parts by weight.
  • the content of the polyphenol is 0.01 parts by weight to 5 parts by weight, 0.02 parts by weight to 3 parts by weight, 0.03 parts by weight to 1 parts by weight, 0.03 parts by weight to 0.5 parts by weight, 0.03 parts by weight to 100 parts by weight of ethanol. It may be a content in the range of 0.45 parts by weight, or 0.04 parts by weight to 0.4 parts by weight. When the content of the polyphenol is within the above range, an effect of reducing odor may be expressed.
  • the content of the polyphenol may be the sum of the content of chlorogenic acid and caffeic acid.
  • the polyphenol may be included in an amount of 1 ppm to 300 ppm based on the total weight of the total composition, but is not limited thereto.
  • the content of the polyphenol is one lower limit selected from 1 ppm, 2 ppm, 2.5 ppm, 3 ppm, 4 ppm, 5 ppm, 10 ppm, 20 ppm, 25 ppm, and 27 ppm based on the total weight of the composition, and /Or 300 ppm, 280 ppm, 260 ppm, 200 ppm, 150 ppm, 100 ppm, 50 ppm, 40 ppm, 30 ppm, 29 ppm, and may be a content in a range consisting of one upper limit selected from 28 ppm .
  • the content of the polyphenol is 1 ppm to 300 ppm, 2 ppm to 280 ppm, 2 ppm to 200 ppm, 2 ppm to 50 ppm, 2.5 ppm to 200 ppm, 2.5 ppm to 100 ppm, 3 It may be in the range of ppm to 30 ppm, 3 ppm to 28 ppm, or 10 ppm to 200 ppm.
  • the content of the polyphenol is within the above range, an effect of reducing odor may be exhibited.
  • the content of the polyphenol may be the sum of the content of chlorogenic acid and caffeic acid.
  • chlorogenic acid may be included in an amount of 1 ppm to 250 ppm based on the total weight of the total composition, but is not limited thereto.
  • the chlorogenic acid is one lower limit selected from 1 ppm, 1.5 ppm, 2 ppm, 2.3 ppm, and 2.5 ppm based on the total weight of the composition and/or 250 ppm, 200 ppm, 150 ppm, 100 ppm, 50 ppm , 40 ppm, 30 ppm, and 25 ppm.
  • the content of chlorogenic acid is 1 ppm to 250 ppm, 2 ppm to 100 ppm, 2 ppm to 50 ppm, 2.3 ppm to 40 ppm, 2.3 ppm to 30 ppm, or 2.5 ppm to 25 ppm based on the total weight of the composition. It may be a content in the range of. When the content of chlorogenic acid is within the above range, an effect of reducing odor may be exhibited.
  • caffeic acid may be included in an amount of 0.1 ppm to 10 ppm based on the total weight of the total composition, but is not limited thereto.
  • the caffeic acid is one lower limit selected from 0.1 ppm, 0.2 ppm, 0.3 ppm, 0.4 ppm, and 0.5 ppm based on the total weight of the composition and/or 10 ppm, 5 ppm, 4 ppm, 3.5 ppm, 3 ppm, 2.7 It may be a content in a range consisting of one upper limit value selected from ppm, and 2.5 ppm.
  • the content of caffeic acid is 0.1 ppm to 10 ppm, 0.2 ppm to 5 ppm, 0.3 ppm to 3.5 ppm, 0.4 ppm to 3 ppm, 0.4 ppm to 2.7 ppm, or 0.5 ppm to 2.5 ppm of the total composition weight. It can be a range of content. When the content of chlorogenic acid is within the above range, an effect of reducing odor may be exhibited.
  • the caffeic acid may be included in an amount of 1 to 50 parts by weight relative to 100 parts by weight of chlorogenic acid, and specifically 5 to 30 parts by weight, 5 to 25 parts by weight, 7 to 30 parts by weight, It may be included in 7 parts by weight to 25 parts by weight, 9 parts by weight to 25 parts by weight, or 10 parts by weight to 20 parts by weight, but is not limited thereto.
  • Ethanol contained in the composition of the present application is a substance also called ethyl alcohol or alcohol, and is a main component of alcohol.
  • ethanol may be produced by fermenting carbohydrates such as sugar or starch, or synthesized from ethylene or acetylene.
  • ethanol may be included in an amount of 0.20% by weight to 1.20% by weight based on the total weight of the total composition, but is not limited thereto.
  • the ethanol is one lower limit selected from 0.20 wt%, 0.24 wt%, 0.28 wt%, 0.32 wt%, 0.36 wt%, 0.40 wt%, 0.44 wt%, and 0.48 wt% based on the total weight of the total composition and/ Alternatively, it may be a content in a range consisting of one upper limit value selected from 1.20% by weight, 1.16% by weight, 1.12% by weight, 1.08% by weight, 1.04% by weight, 1.00% by weight, 0.96% by weight, and 0.92% by weight.
  • the content of ethanol is 0.20 wt% to 1.20 wt%, 0.24 wt% to 1.16 wt%, 0.28 wt% to 1.12 wt%, 0.32 wt% to 1.08 wt%, 0.36 wt% to 1.04 based on the total weight of the composition. It may be included in an amount of wt%, 0.40 wt% to 1.00 wt%, 0.44 wt% to 0.96 wt%, or 0.48 wt% to 0.92 wt%. When the content of ethanol is within the above range, an effect of reducing odor may be exhibited.
  • the composition for reducing odor may further include an organic acid.
  • organic acid used in the present application refers to an organic compound having acidic properties in the broadest sense, and may typically include a carboxyl group (-COOH) or a sulfone group (-SO3H).
  • Organic acids that may be included in the composition of the present application include low-molecular organic acids such as citric acid, malic acid, succinic acid, lactic acid, or acetic acid, or ascorbic acid, or benzoic acid.
  • Polymeric organic acids such as, but are not limited thereto.
  • the organic acid that can be used in the present application may be one or more selected from the group consisting of citric acid, malic acid, succinic acid, lactic acid, or acetic acid, and more specifically, lactic acid or acetic acid, and more specifically It is acetic acid.
  • the organic acid may be included in an amount of 100 parts by weight to 600 parts by weight based on 100 parts by weight of ethanol, but is not limited thereto.
  • the organic acid is one selected from 100 parts by weight, 150 parts by weight, 180 parts by weight, 200 parts by weight, 210 parts by weight, 220 parts by weight, 230 parts by weight, 240 parts by weight, and 242 parts by weight based on 100 parts by weight of ethanol. Consisting of a lower limit and/or an upper limit selected from 600 parts by weight, 500 parts by weight, 400 parts by weight, 350 parts by weight, 300 parts by weight, 280 parts by weight, 260 parts by weight, 250 parts by weight, and 245 parts by weight. It can be a range of content.
  • the content of the organic acid is 100 parts by weight to 600 parts by weight, 150 parts by weight to 500 parts by weight, 200 parts by weight to 400 parts by weight, 220 parts by weight to 300 parts by weight, 230 to 260 parts by weight based on 100 parts by weight of ethanol. It may be part by weight, 240 parts by weight to 250 parts by weight, or 242 parts by weight to 245 parts by weight.
  • the organic acid may be included in an amount of 1% to 2.4% by weight based on the total weight of the total composition, but is not limited thereto.
  • the organic acid is one lower limit selected from 1% by weight, 1.05% by weight, 1.1% by weight, 1.15% by weight, 1.2% by weight, 1.25% by weight, 1.3% by weight, and 1.35% by weight relative to the total weight of the total composition and/ Alternatively, it may be a content in a range consisting of one upper limit value selected from 2.4% by weight, 2.35% by weight, 2.3% by weight, 2.25% by weight, 2.2% by weight, 2.15% by weight, 2.1% by weight, and 2.05% by weight.
  • the content of the organic acid is 1% to 2.4% by weight, 1.05% to 2.35% by weight, 1.1% to 2.3% by weight, 1.15% to 2.25% by weight, 1.2% to 2.2% by weight, based on the total weight of the composition. It may be included in an amount of weight %, 1.25 weight% to 2.15 weight %, 1.3 weight% to 2.1 weight %, or 1.35 weight% to 2.05 weight %.
  • the content of the organic acid is within the above range, an effect of reducing odor may be exhibited.
  • the acetic acid may be 50% by weight or more, 70% by weight or more, 80% by weight or more, 85% by weight or more, or 90% by weight or more with respect to 100% by weight of the total organic acid. Specifically, it may be 90% to 100% by weight, 90% to 99% by weight, or 90% to 97% by weight.
  • the organic acid may be used not only an organic acid derived from a natural product, but also an artificially synthesized organic acid.
  • the natural product may be separated and purified by a method known in the art, for example, an extraction method, or a fermented product derived from a natural product may be used. Specifically, those derived from fermented vinegar may be used.
  • the fermented vinegar includes fermentation by a known method, and for example, may be obtained through primary fermentation of fermenting glucose or the like into ethanol and secondary fermentation of fermenting ethanol with acetic acid.
  • the natural product may be any material containing an organic acid without limitation, but may be a plant. Specifically, Aloe, Anise Seed, Elder Tree, Spikeweed, Psyllium Seed, Orange Flower, Pimento Tree, Oregano, Valerian, Chamomile, Capsaicin Pepper, Cardamom, Cassia, Garlic, Caraway Seed, Clove, Cumin Seed, Coke Tree , Coriander seed, red tree, saffron, Japanese pepper tree, juniper berry, cinnamon, ginger, octagonal, St.
  • a product including the composition for reducing odor of the present application may be included.
  • the product of the present application may be applied without limitation, such as food, feed, household goods, industrial goods, etc.
  • specific food or feed include processed grain products, vegetables, fruits, dried or cut products of vegetables, fruit juice, vegetable juice, Mixed juice of vegetables and fruits, chips, noodles, processed livestock food, processed seafood, processed dairy food, fermented milk food, microbial fermented food, confectionery bakery, seasonings, fish/meat products, acidic beverages, processed foods, convenience foods, licorice , Herbs, insect feed, livestock feed, pet feed, etc., but are not limited thereto.
  • the product of the present application may be taste alcohol.
  • odor refers to an unpleasant or disgusting odor generated by a component contained in the product itself or a secondary chemical change of the component or a substance incorporated from the outside.
  • the substances that generate the odor may be, for example, nitrogen compounds, sulfur compounds, lower fatty acids, carbonyl compounds, esters, phenols, alcohols, hydrocarbons, or chlorine compounds.
  • the odor may be fishy.
  • the fishy smell may be a fishy smell derived from plants or seafood, and specifically, may be a fishy smell derived from fish.
  • the nitrogen compound may be included without limitation as long as it is a substance capable of generating odors such as ammonia, trimethylamine, piperidine, and trimethyl oxide, but may be specifically trimethylamine.
  • composition of the present application may adjust the final weight or volume of the composition by adding purified water in addition to the above-described components.
  • composition of the present application may itself be used as a composition for reducing odor, but may be used as a sauce by adding additional ingredients such as sugars or seasoning ingredients, or applied to processed aquatic products.
  • Sugar components that can be further added to the composition of the present application include monosaccharides such as glucose, fructose, and galactose; Disaccharides such as sucrose, maltose, and lactose; Oligosaccharides in which three or more monosaccharides are bound; Examples include polysaccharides such as starch and glycogen, but are not limited thereto.
  • An amino acid component may be further added as a seasoning component to the composition of the present application, and a ginger concentrate or rosemary concentrate may be further included as a spice component.
  • the amino acid component of the seasoning may be derived from a natural product, produced by fermentation, or artificially synthesized.
  • composition of the present application includes various nutrients, vitamins, electrolytes, flavoring agents, colorants, pectic acid, salts of pectic acid, alginic acid, salts of alginic acid, organic acids, protective colloid thickeners, pH adjusters, stabilizers, It may further contain preservatives, glycerin, alcohols or carbonation agents.
  • the composition of the present application may include vitamins A, C, D, E, B1, B2, B6, B12, niacin, biotin, folate, panthotenic acid, and the like.
  • I can.
  • it may contain minerals such as zinc (Zn), iron (Fe), calcium (Ca), chromium (Cr), magnesium (Mg), manganese (Mn), copper (Cu), and chromium (Cr).
  • amino acids such as lysine, tryptophan, cysteine, and valine may be included.
  • monosaccharides such as glucose and fructose
  • Disaccharides such as maltose and sucrose
  • Polysaccharides such as dextrin and cyclodextrin
  • Sugar alcohols such as xylitol, sorbitol, and erythritol
  • potassium sorbate sodium benzoate, salicylic acid, sodium dehydroacetate, and the like
  • Bleached powder highly bleached powder, sodium hypochlorite, etc.
  • BHA butylhydroxyanisole
  • BHT butylhydroxytoleuene
  • Tar colors as colorants
  • As a coloring agent sodium nitrite, sodium nitrite; Sodium sulfite as bleach; As a seasoning, MSG sodium glutamate
  • Natural sweeteners such as taumatin and stevia extract as sweeteners, synthetic sweeteners such as saccharin and aspartame; Vanillin and lactones as flavorings
  • Alum D potassium hydrogen stannate as an expanding agent
  • It may contain food additives such as reinforcing agents, emulsifying agents, thickening agents (thickening agents), coating agents, gum base agents, antifoaming agents, solvents, and improving agents.
  • the additive may be selected according to the type of food and used in an appropriate amount.
  • Another aspect of the present application provides a method for reducing malodor comprising the step of adding the composition of the present application described above to a malodor product.
  • the contents of the composition are the same as those described in one aspect of the present application, and thus, overlapping descriptions will not be made.
  • the polyphenols used in the experiment were purchased from Sigma-aldrich (USA) and used.
  • Cheongju including about 16% (w/w) ethanol
  • acetic acid was purchased from Daejeonghwageum
  • purified water was JT Baker It was purchased from and used.
  • a composition for removing fishy smell was prepared with the composition of the ingredients shown in Table 1 below.
  • TMA trimethylamine
  • the flesh of the fresh mackerel purchased on the market was separated, homogenized with a mixer, and 6.3% (w/w) of the sample prepared in Experimental Example 1 was added, and the mixture was allowed to sleep for 30 minutes or more.
  • the mackerel treated with each sample was heated at about 90° C. for about 10 minutes. During heating, the mackerel was turned over so that it did not burn.
  • TMA Trimethylamine
  • TMA trimethylamine
  • Apple fermented vinegar containing polyphenols CJ CheilJedang 25% (w/w), fructose (CJ CheilJedang) 25% (w/w), sugar (CJ CheilJedang) 15% (w/w), Cheongju (Including about 16% (w/w) ethanol, Morning of Upo) 5% (w/w) and other (including ginger or rosemary extract) were prepared.
  • the taste wine containing ginger is described as CJ Matsool ginger
  • the taste wine containing rosemary is described as CJ Matsool rosemary.
  • Matsul (Lotte, hereinafter, commercially available Matsul) was purchased and used in a comparative experiment for analysis of organic acids, using Matsul ginger, Matsul rosemary, and existing commercially available alcohol as active ingredients. Organic acid analysis was carried out through the following method.
  • Ultimate3000 HPLC (Thermo Dionex, USA) was used as an analyzer for chlorogenic acid and caffeic acid, and the column was Inno C-18 column (Younginbiochrom, Korea (5 ⁇ m, 4.6x250mm).
  • the column temperature was set to 30° C.
  • the mobile phase was 0.1% TFA solution and acetonitrile, 0-25 minutes, 10% acetonitrile; 25-30 minutes, 60% acetonitrile; 30- A gradient was applied to 35 minutes 100% acetonitrile; 35-36 minutes 100% acetonitrile; 36-40 minutes 10% acetonitrile
  • the solvent flow rate was 0.8 ml/min, and the wavelength of the detector was 280 nm, 340 nm, and 254 nm were used, and the results of the analysis of the content of chlorogenic acid and caffeic acid are shown in Table 4.

Abstract

The present application relates to a composition for reducing bad odours, the composition comprising polyphenol and ethanol, and a method for reducing bad odours comprising a step of adding the composition to a product that has a bad odour.

Description

악취 저감용 조성물 Composition for reducing odor
본 출원은 폴리페놀 및 에탄올을 포함하는 악취 저감용 조성물에 관한 것이다. The present application relates to a composition for reducing odor containing polyphenol and ethanol.
생선 비린내는 부패 과정 중 트리메틸아민(trimethylamine; TMA) 생성 및 불포화 지방산 산화 등 복합적인 요인에 의해 발생한다. 특히 수산물 신선도 지표로도 사용되는 TMA 경우, 신선육에는 거의 존재하지 않으나 사후 무취 상태인 트리메틸아민 옥사이드(trimethylamine oxide; TMAO) 성분이 세균성 효소 작용에 의해 TMA로 환원되면서 비린내를 발생시키는 것으로 알려져 있다. 일반적으로 생선 비린내 제거를 위해 염기성인 TMA를 중화시키기 위한 산을 첨가하는 방법으로, 주로 식초를 사용하여 비린내를 제거하는 방법이 있다. 그러나 식초 특유의 강한 향미에 의해 사용량이 제한적인 단점이 있다. Fishy smell is caused by complex factors such as the production of trimethylamine (TMA) and oxidation of unsaturated fatty acids during the spoilage process. In particular, in the case of TMA, which is also used as an indicator of freshness of seafood, it is known that the odorless trimethylamine oxide (TMAO) component, which is rarely present in fresh meat, is reduced to TMA by the action of bacterial enzymes, resulting in a fishy smell. In general, a method of adding an acid to neutralize TMA, which is a basic substance, to remove the fishy smell, mainly using vinegar, is a method of removing the fishy smell. However, there is a disadvantage that the amount of use is limited due to the strong flavor peculiar to vinegar.
종래 기술로서 생선 비린내를 제거하기 위한 다양한 기술들이 개발되어 왔으나(대한민국 등록특허 제 10-1928965호, 대한민국 등록특허 제10-1647778호, 대한민국 공개특허 10-2019-0055941호), 비린내 저감 효과가 제한적이었다. As a conventional technique, various technologies for removing fishy smell have been developed (Korean Patent Registration No. 10-1928965, Korean Patent Registration No. 10-1647778, Korean Patent Publication No. 10-2019-0055941), but the effect of reducing fishy smell is limited. Was.
[선행기술문헌] [Prior technical literature]
[특허문헌] [Patent Literature]
대한민국 등록특허 제10-1928965호 Korean Patent Registration No. 10-1928965
대한민국 등록특허 제10-1647778호 Korean Patent Registration No. 10-1647778
대한민국 공개특허 제10-2019-0055941호 Republic of Korea Patent Publication No. 10-2019-0055941
상술한 종래 기술의 문제점을 극복하기 위해, 본 출원은 생선 비린내의 원인 물질인 트리메틸아민(TMA) 저감 효과가 매우 뛰어나고, 요리 적용시 생선 비린내와 잡내를 효과적으로 제거하고 풍미를 살려주며, 나아가 통조림, 어육, 가정 간편식과 같은 가공식품에도 적용하기 쉬운, 악취 저감용 조성물을 제공하는 것을 목적으로 한다. In order to overcome the problems of the prior art described above, the present application has an excellent effect of reducing trimethylamine (TMA), which is a causative agent of fishy smell, effectively removes fishy smell and bad smell when cooking, and saves flavor, and further, canned food, It is an object of the present invention to provide a composition for reducing odor, which is easy to apply to processed foods such as fish meat and household convenience meals.
상기의 목적을 달성하기 위하여, 본 출원의 일 측면은 폴리페놀 및 에탄올을 포함하는 악취 저감용 조성물을 제공한다. In order to achieve the above object, an aspect of the present application provides a composition for reducing odor containing polyphenol and ethanol.
상기의 목적을 달성하기 위하여, 본 출원의 다른 측면은 폴리페놀 및 에탄올을 포함하는 조성물을 악취 생성물에 첨가하는 단계를 포함하는 악취 저감 방법을 제공한다. In order to achieve the above object, another aspect of the present application provides a method for reducing malodor comprising the step of adding a composition containing polyphenol and ethanol to a malodor product.
본 출원의 조성물은 생선 비린내 원인 물질인 트리메틸아민(TMA)의 감소능이 매우 뛰어나며, 요리에 적용시 생선 비린내를 효과적으로 제거하고 풍미를 살려줄 수 있고, 통조림, 어육, 가정 간편식(HMR)와 같은 가공식품에도 적용하기 쉬운 이점을 가진다. The composition of the present application has an excellent ability to reduce trimethylamine (TMA), which is a cause of fishy smell, and when applied to cooking, it can effectively remove fishy smell and save flavor, and can be processed such as canned food, fish meat, and home convenience food (HMR). It has the advantage of being easy to apply to food.
다만, 본 출원의 효과는 상기에서 언급한 효과로 제한되지 아니하며, 언급되지 않은 또 다른 효과들은 하기의 기재로부터 당업자에게 명확히 이해될 수 있을 것이다. However, the effects of the present application are not limited to the above-mentioned effects, and other effects not mentioned will be clearly understood by those skilled in the art from the following description.
이하, 본 출원을 구체적으로 설명한다. Hereinafter, the present application will be described in detail.
본 출원의 일 측면에 따르면, 본 출원은 폴리페놀 및 에탄올을 포함하는 악취 저감용 조성물을 제공한다. According to an aspect of the present application, the present application provides a composition for reducing odor containing polyphenol and ethanol.
본 출원에서 사용되는 용어 “폴리페놀”은 분자내에 하나 이상의 히드록시기를 갖는 페놀을 하나 이상 포함하는 화합물을 의미한다. 상기 폴리페놀은 폴리페놀 자체 및 이의 배당체, 이의 알킬화 화합물, 이의 에스터화 화합물 등 유도체(derivatives)도 포함하는 개념이다. The term "polyphenol" as used in the present application refers to a compound containing one or more phenols having one or more hydroxy groups in the molecule. The polyphenol is a concept including derivatives such as polyphenol itself and its glycoside, its alkylated compound, and its esterified compound.
상기 폴리페놀은 악취 저감이라는 본 출원의 목적을 달성하는 폴리페놀은 제한없이 포함할 수 있다. 구체적으로, 본 출원에서 사용될 수 있는 폴리페놀은 페놀릭산(Phenolic acid), 플라보노이드(Flavoids), 스틸벤(stilbens), 리그난(lignin) 등 제한없이 포함될 수 있으며, 일례로 이소람네틴, 이소람네틴 글리코사이드, 카테킨, 에피카테킨, 갈로카테킨, 에피카테킨 갈레이트, 에피갈로카테킨, 에피갈로카테킨 갈레이트, 엘라그산, 카테콜, 카페산, 카페산 에스테르, 클로로젠산, 켐페롤, 켐페롤 글리코사이드, 퀘르세틴, 퀘르세틴 글리코사이드, 퀘르세타게닌, 게니세틴, 게니세틴 글리코사이드, 탄닌산, 안토시아닌, 하이드로퀴논, 헤스페레틴, 헤스페리딘, 갈산, 갈산 에스테르(갈산 라우릴, 갈산 프로필, 갈산 부틸), 4-메틸카테콜, 5-메틸카테콜, 4-메톡시카테콜, 5-메톡시카테콜, 메틸카테콜-4-카복실산, 2-메틸레조르시놀, 5-메틸레조르시놀, 리그닌, 리모시트린, 리모시트린 글리코사이드, 리모시트롤, 루테올린, 루테올린 글리코사이 드, 루테올리니딘, 루테올리니딘 글리코사이드, 루틴, 레조르신, 레스베라트롤, 레조르시놀, 로이코시아니딘, 로이코델피니딘, 또는 퀴닌산 등을 들 수 있으나, 이에 한정되지 않는다. The polyphenol may include, without limitation, a polyphenol that achieves the object of the present application of reducing odor. Specifically, the polyphenols that can be used in the present application may be included without limitation, such as phenolic acid, flavonoids, stilbens, and lignin, and examples thereof include isoramnetin, isoramnetin. Glycoside, catechin, epicatechin, gallocatechin, epicatechin gallate, epigallocatechin, epigallocatechin gallate, ellagic acid, catechol, caffeic acid, caffeic acid ester, chlorogenic acid, camperol, camperol glycoside , Quercetin, quercetin glycoside, quercetagenin, genicetine, genicetine glycoside, tannic acid, anthocyanin, hydroquinone, hesperetin, hesperidine, gallic acid, gallic acid esters (lauryl gallate, propyl gallate, butyl gallate), 4 -Methylcatechol, 5-methylcatechol, 4-methoxycatechol, 5-methoxycatechol, methylcatechol-4-carboxylic acid, 2-methylresorcinol, 5-methylresorcinol, lignin, limo Citrin, Rimositrin Glycoside, Rimositrol, Luteolin, Luteolin Glycoside, Luteolinidine, Luteolinidine Glycoside, Rutin, Resorcin, Resveratrol, Resorcinol, Leucocyanidin, Leicodelpinidine, or And quinic acid, but are not limited thereto.
구체적으로 본 출원에서 폴리페놀은 클로로젠산 및 카페산으로 이루어지는 군에서 선택되는 하나 또는 둘 이상의 조합을 사용할 수 있다. Specifically, in the present application, as the polyphenol, one or a combination of two or more selected from the group consisting of chlorogenic acid and caffeic acid may be used.
본 출원에서 상기 클로로젠산은 카페산(caffeic acid)와 퀴닌산(quinic acid)이 에스테르 결합으로 연결된 화합물이며 아래의 화학식 1로 표시된다. In the present application, the chlorogenic acid is a compound in which caffeic acid and quinic acid are linked by an ester bond, and is represented by Formula 1 below.
[화학식 1] [Formula 1]
Figure PCTKR2019015211-appb-I000001
Figure PCTKR2019015211-appb-I000001
본 출원에서 상기 카페산은 하이드록시 신남산으로 분류되는 화합물로서, 아래의 화학식 2로 표시된다. In the present application, the caffeic acid is a compound classified as hydroxy cinnamic acid, and is represented by Formula 2 below.
[화학식 2] [Formula 2]
Figure PCTKR2019015211-appb-I000002
Figure PCTKR2019015211-appb-I000002
본 출원에서 폴리페놀은 천연물로부터 유래된 폴리페놀 뿐만 아니라 인공적으로 합성된 폴리페놀도 사용할 수 있다. In the present application, polyphenols may be used not only polyphenols derived from natural products, but also artificially synthesized polyphenols.
구체적으로, 상기 천연물로부터 당업계에 공지된 방법, 예를 들어 추출방법에 의해 분리 정제한 것을 사용하거나, 천연물의 발효물로부터 유래된 것을 사용할 수 있다. 구체적으로, 발효식초로부터 유래된 것을 사용할 수 있다. Specifically, the natural product may be separated and purified by a method known in the art, for example, an extraction method, or a fermented product derived from a natural product may be used. Specifically, those derived from fermented vinegar may be used.
상기 발효식초는 공지된 방법으로 발효하는 것을 포함하며, 일례로 포도당 등 당류를 에탄올로 발효하는 1차 발효 및 에탄올을 초산으로 발효하는 2차 발효를 통해 수득한 것일 수 있다. The fermented vinegar includes fermentation by a known method, and for example, may be obtained through primary fermentation of fermenting sugars such as glucose into ethanol and secondary fermentation of fermenting ethanol with acetic acid.
상기 천연물은 폴리페놀을 포함하는 어느 물질이든 제한없이 이용가능하나, 식물일 수 있다. 구체적으로 알로에, 아니스 씨드, 딱총나무, 가시오가피, 차전자피, 오렌지 플라워, 피멘토나무, 오레가노, 쥐오줌풀, 캐모마일, 캅사이신 페퍼, 카다몬, 계수나무, 마늘, 캐러웨이 씨드, 정향, 커민 씨드, 콜라나무, 고수풀 씨드, 붉나무, 사프란, 산초나무, 쥬니퍼 베리, 시나몬, 생강, 팔각, 세인트 존스 워트, 셀러리 씨드, 세이보리, 참깨, 식용 대황, 타라곤, 터메릭, 엉겅퀴, 딜 씨드, 육두구, 쐐기풀, 하이비스커스, 풍년화, 자작나무, 바질, 비터 오렌지, 회향, 앵초, 호로파, 버베나, 월계수, 홉, 볼도, 와사비, 양귀비 씨드, 오배자, 매리골드, 마롱, 마조람, 머스터드, 밀푀유, 민트 잎, 멜리사, 육두구, 린덴, 용담, 로즈힙, 로즈마리, 로즈마리너스 오피시널리스, 해바라기 씨드, 그레이프 과피, 사과, 당근 잎, 바나나, 딸기, 살구나무, 복숭아, 자두, 파인애플, 나시배, 감나무, 체리, 파파야, 망고, 아보카도, 멜론, 비파나무, 무화과, 키위, 푸룬, 블루베리, 블랙베리, 라즈베리, 크랜베리, 커피콩, 카카오콩, 그레이프 씨드, 그레이프 프루트 씨드, 피칸 넛, 캐슈 넛, 밤, 코코넛, 피넛, 월넛, 녹차잎, 홍차잎, 우롱차잎, 담배, 들깨잎, 가든타임, 세이지, 라벤더, 스페아민트, 페퍼민트, 스팟 엉겅퀴, 히솝, 스위트 바질, 매리골드, 민들레, 아티초크, 저맨캐모마일, 짚신나물, 감초, 아니스, 서양톱풀, 유칼립투스, 쓴쑥, 밭삼, 땅두릅, 호로파, 꽃고추, 회향, 고추, 고수풀 씨드, 캐러웨이 씨드, 회향 씨드, 생강, 겨자무, 오레가노 마조람, 오레가노(origanum valgare), 머스터드, 파슬리, 후추, 세이보리, 타라곤, 쿠르크마, 고추냉이, 딜 씨드, 또는 감귤류 과일 등일 수 있다. The natural product may be any material including polyphenols, without limitation, but may be plants. Specifically, Aloe, Anise Seed, Elder Tree, Spikeweed, Psyllium Seed, Orange Flower, Pimento Tree, Oregano, Valerian, Chamomile, Capsaicin Pepper, Cardamom, Cassia, Garlic, Caraway Seed, Clove, Cumin Seed, Coke Tree , Coriander seed, red tree, saffron, Japanese pepper tree, juniper berry, cinnamon, ginger, octagonal, St. John's wort, celery seed, savory, sesame, edible rhubarb, tarragon, turmeric, thistle, dill seed, nutmeg, nettle, hibiscus, Weathered flowers, birch, basil, bitter orange, fennel, primrose, fenugreek, verbena, laurel, hops, boldo, wasabi, poppy seed, five baeja, marigold, maroon, marjoram, mustard, wheatfeuille, mint leaves, melissa, Nutmeg, Linden, Gentian, Rosehip, Rosemary, Rosemarinus Officials, Sunflower Seed, Grape Peel, Apple, Carrot Leaf, Banana, Strawberry, Apricot Tree, Peach, Plum, Pineapple, Nashi Pear, Persimmon Tree, Cherry, Papaya, Mango, avocado, melon, loquat, fig, kiwi, prune, blueberry, blackberry, raspberry, cranberry, coffee bean, cacao bean, grape seed, grapefruit seed, pecan nut, cashew nut, chestnut, coconut, peanut, Walnut, green tea leaves, black tea leaves, oolong tea leaves, tobacco, perilla leaves, garden thyme, sage, lavender, spemint, peppermint, spot thistle, hyssop, sweet basil, marigold, dandelion, artichoke, german chamomile, sandalwood, Licorice, Anise, Yarrow, Eucalyptus, Bitter Mugwort, Wild Ginseng, Earthworm, Fenugreek, Red Pepper, Fennel, Red Pepper, Coriander Seed, Caraway Seed, Fennel Seed, Ginger, Mustard Radish, Oregano Marjoram, Origanum valgare, Mustard , Parsley, pepper, savory, tarragon, curkma, wasabi, dill seeds, or citrus fruits.
본 출원에서 폴리페놀은 에탄올 100 중량부 대비 0.01 중량부 내지 5 중량부의 함량으로 포함될 수 있으나, 이에 제한되지 않는다. In the present application, the polyphenol may be included in an amount of 0.01 parts by weight to 5 parts by weight based on 100 parts by weight of ethanol, but is not limited thereto.
구체적으로, 상기 폴리페놀의 함량은 에탄올 100 중량부 대비 0.01 중량부, 0.02 중량부, 0.03 중량부, 및 0.04 중량부로부터 선택된 하나의 하한 값 및/또는 5 중량부, 3 중량부, 1 중량부, 0.7 중량부, 0.5 중량부, 0.45 중량부, 0.4 중량부로부터 선택된 하나의 상한 값으로 구성되는 범위의 함량일 수 있다. Specifically, the content of the polyphenol is one lower limit selected from 0.01 parts by weight, 0.02 parts by weight, 0.03 parts by weight, and 0.04 parts by weight based on 100 parts by weight of ethanol and/or 5 parts by weight, 3 parts by weight, 1 part by weight. , 0.7 parts by weight, 0.5 parts by weight, 0.45 parts by weight, may be a content in a range consisting of one upper limit value selected from 0.4 parts by weight.
일례로, 상기 폴리페놀의 함량은 에탄올 100 중량부 대비 0.01 중량부 내지5 중량부, 0.02 중량부 내지 3 중량부, 0.03 중량부 내지 1 중량부, 0.03 중량부 내지 0.5 중량부, 0.03 중량부 내지 0.45 중량부, 또는 0.04 중량부 내지 0.4 중량부의 범위의 함량일 수 있다. 폴리페놀의 함량이 상기 범위일 경우 악취 저감 효과가 발현될 수 있다.As an example, the content of the polyphenol is 0.01 parts by weight to 5 parts by weight, 0.02 parts by weight to 3 parts by weight, 0.03 parts by weight to 1 parts by weight, 0.03 parts by weight to 0.5 parts by weight, 0.03 parts by weight to 100 parts by weight of ethanol. It may be a content in the range of 0.45 parts by weight, or 0.04 parts by weight to 0.4 parts by weight. When the content of the polyphenol is within the above range, an effect of reducing odor may be expressed.
상기 폴리페놀의 함량은 클로로젠산과 카페산의 함량 합계일 수 있다. The content of the polyphenol may be the sum of the content of chlorogenic acid and caffeic acid.
본 출원에서 폴리페놀은 전체 조성물 총 중량 대비 1 ppm 내지 300 ppm의 함량으로 포함될 수 있으나, 이에 제한되지 않는다. In the present application, the polyphenol may be included in an amount of 1 ppm to 300 ppm based on the total weight of the total composition, but is not limited thereto.
구체적으로, 상기 폴리페놀의 함량은 전체 조성물 중량 대비 1 ppm, 2 ppm, 2.5 ppm, 3 ppm, 4 ppm, 5 ppm, 10 ppm, 20 ppm, 25 ppm, 및 27 ppm으로부터 선택된 하나의 하한 값 및/또는 300 ppm, 280 ppm, 260 ppm, 200 ppm, 150 ppm, 100 ppm, 50 ppm, 40 ppm, 30 ppm, 29 ppm, 및 28 ppm으로부터 선택된 하나의 상한 값으로 구성되는 범위의 함량일 수 있다. Specifically, the content of the polyphenol is one lower limit selected from 1 ppm, 2 ppm, 2.5 ppm, 3 ppm, 4 ppm, 5 ppm, 10 ppm, 20 ppm, 25 ppm, and 27 ppm based on the total weight of the composition, and /Or 300 ppm, 280 ppm, 260 ppm, 200 ppm, 150 ppm, 100 ppm, 50 ppm, 40 ppm, 30 ppm, 29 ppm, and may be a content in a range consisting of one upper limit selected from 28 ppm .
일례로, 상기 폴리페놀의 함량은 전체 조성물 중량 대비 1 ppm 내지 300 ppm, 2 ppm 내지 280 ppm, 2 ppm 내지 200 ppm, 2 ppm 내지 50 ppm, 2.5 ppm 내지 200 ppm, 2.5 ppm 내지 100 ppm, 3 ppm 내지 30 ppm, 3 ppm 내지 28 ppm, 또는 10 ppm 내지 200 ppm, 의 범위의 함량일 수 있다. 폴리페놀의 함량이 상기 범위일 경우 악취 저감 효과가 발현될 수 있다. For example, the content of the polyphenol is 1 ppm to 300 ppm, 2 ppm to 280 ppm, 2 ppm to 200 ppm, 2 ppm to 50 ppm, 2.5 ppm to 200 ppm, 2.5 ppm to 100 ppm, 3 It may be in the range of ppm to 30 ppm, 3 ppm to 28 ppm, or 10 ppm to 200 ppm. When the content of the polyphenol is within the above range, an effect of reducing odor may be exhibited.
상기 폴리페놀의 함량은 클로로젠산과 카페산의 함량 합계일 수 있다.The content of the polyphenol may be the sum of the content of chlorogenic acid and caffeic acid.
본 출원에서 클로로젠산은 전체 조성물 총 중량 대비 1 ppm 내지 250 ppm의 함량으로 포함될 수 있으나, 이에 제한되지 않는다.In the present application, chlorogenic acid may be included in an amount of 1 ppm to 250 ppm based on the total weight of the total composition, but is not limited thereto.
구체적으로, 상기 클로로젠산은 전체 조성물 총 중량 대비 1 ppm, 1.5 ppm, 2 ppm, 2.3 ppm, 및 2.5 ppm 으로부터 선택된 하나의 하한 값 및/또는 250 ppm, 200 ppm, 150 ppm, 100 ppm, 50 ppm, 40 ppm, 30 ppm, 및 25 ppm 으로부터 선택된 하나의 상한 값으로 구성되는 범위의 함량일 수 있다. Specifically, the chlorogenic acid is one lower limit selected from 1 ppm, 1.5 ppm, 2 ppm, 2.3 ppm, and 2.5 ppm based on the total weight of the composition and/or 250 ppm, 200 ppm, 150 ppm, 100 ppm, 50 ppm , 40 ppm, 30 ppm, and 25 ppm.
일례로, 상기 클로로젠산의 함량은 전체 조성물 중량 대비 1 ppm 내지 250 ppm, 2 ppm 내지 100 ppm, 2 ppm 내지 50 ppm, 2.3 ppm 내지 40 ppm, 2.3 ppm 내지 30 ppm, 또는 2.5 ppm 내지 25 ppm의 범위의 함량일 수 있다. 클로로젠산의 함량이 상기 범위일 경우 악취 저감 효과가 발현될 수 있다. For example, the content of chlorogenic acid is 1 ppm to 250 ppm, 2 ppm to 100 ppm, 2 ppm to 50 ppm, 2.3 ppm to 40 ppm, 2.3 ppm to 30 ppm, or 2.5 ppm to 25 ppm based on the total weight of the composition. It may be a content in the range of. When the content of chlorogenic acid is within the above range, an effect of reducing odor may be exhibited.
본 출원에서 카페산은 전체 조성물 총 중량 대비 0.1 ppm 내지 10 ppm의 함량으로 포함될 수 있으나, 이에 제한되지 않는다.In the present application, caffeic acid may be included in an amount of 0.1 ppm to 10 ppm based on the total weight of the total composition, but is not limited thereto.
구체적으로 상기 카페산은 전체 조성물 총 중량 대비 0.1 ppm, 0.2 ppm, 0.3 ppm, 0.4 ppm, 및 0.5 ppm 으로부터 선택된 하나의 하한 값 및/또는 10 ppm, 5 ppm, 4 ppm, 3.5 ppm, 3 ppm, 2.7 ppm, 및 2.5 ppm으로부터 선택된 하나의 상한 값으로 구성되는 범위의 함량일 수 있다. Specifically, the caffeic acid is one lower limit selected from 0.1 ppm, 0.2 ppm, 0.3 ppm, 0.4 ppm, and 0.5 ppm based on the total weight of the composition and/or 10 ppm, 5 ppm, 4 ppm, 3.5 ppm, 3 ppm, 2.7 It may be a content in a range consisting of one upper limit value selected from ppm, and 2.5 ppm.
일례로, 상기 카페산의 함량은 전체 조성물 중량 대비 0.1 ppm 내지 10 ppm, 0.2 ppm 내지 5 ppm, 0.3 ppm 내지 3.5 ppm, 0.4 ppm 내지 3 ppm, 0.4 ppm 내지 2.7 ppm, 또는 0.5 ppm 내지 2.5 ppm의 범위의 함량일 수 있다. 클로로젠산의 함량이 상기 범위일 경우 악취 저감 효과가 발현될 수 있다. For example, the content of caffeic acid is 0.1 ppm to 10 ppm, 0.2 ppm to 5 ppm, 0.3 ppm to 3.5 ppm, 0.4 ppm to 3 ppm, 0.4 ppm to 2.7 ppm, or 0.5 ppm to 2.5 ppm of the total composition weight. It can be a range of content. When the content of chlorogenic acid is within the above range, an effect of reducing odor may be exhibited.
상기 카페산은 상기 클로로젠산 100 중량부 대비 1 중량부 내지 50 중량부의 함량으로 포함될 수 있으며, 구체적으로 5 중량부 내지 30 중량부, 5 중량부 내지 25 중량부, 7 중량부 내지 30 중량부, 7 중량부 내지 25 중량부, 9 중량부 내지 25 중량부, 또는 10 중량부 내지 20 중량부로 포함될 수 있으나 이에 제한되지 않는다. The caffeic acid may be included in an amount of 1 to 50 parts by weight relative to 100 parts by weight of chlorogenic acid, and specifically 5 to 30 parts by weight, 5 to 25 parts by weight, 7 to 30 parts by weight, It may be included in 7 parts by weight to 25 parts by weight, 9 parts by weight to 25 parts by weight, or 10 parts by weight to 20 parts by weight, but is not limited thereto.
본 출원의 조성물에 포함되는 에탄올은 에틸알코올 또는 주정(酒精)이라고도 불리는 물질로서, 술의 주성분이다. Ethanol contained in the composition of the present application is a substance also called ethyl alcohol or alcohol, and is a main component of alcohol.
본 출원에서 에탄올은 당 또는 녹말과 같은 탄수화물을 발효시켜 생성된 것을 사용하거나, 또는 에틸렌 또는 아세틸렌으로부터 합성된 것을 사용할 수도 있다.In the present application, ethanol may be produced by fermenting carbohydrates such as sugar or starch, or synthesized from ethylene or acetylene.
본 출원에서 에탄올은 전체 조성물 총 중량 대비 0.20 중량% 내지 1.20 중량%의 함량으로 포함될 수 있으나, 이에 제한되지 않는다.In the present application, ethanol may be included in an amount of 0.20% by weight to 1.20% by weight based on the total weight of the total composition, but is not limited thereto.
구체적으로 상기 에탄올은 전체 조성물 총 중량 대비 0.20 중량%, 0.24 중량%, 0.28 중량%, 0.32 중량%, 0.36 중량%, 0.40 중량%, 0.44 중량%, 및 0.48 중량%으로부터 선택된 하나의 하한 값 및/또는 1.20 중량%, 1.16 중량%, 1.12 중량%, 1.08 중량%, 1.04 중량%, 1.00 중량%, 0.96 중량%, 및 0.92 중량%으로부터 선택된 하나의 상한 값으로 구성되는 범위의 함량일 수 있다. Specifically, the ethanol is one lower limit selected from 0.20 wt%, 0.24 wt%, 0.28 wt%, 0.32 wt%, 0.36 wt%, 0.40 wt%, 0.44 wt%, and 0.48 wt% based on the total weight of the total composition and/ Alternatively, it may be a content in a range consisting of one upper limit value selected from 1.20% by weight, 1.16% by weight, 1.12% by weight, 1.08% by weight, 1.04% by weight, 1.00% by weight, 0.96% by weight, and 0.92% by weight.
일례로, 상기 에탄올의 함량은 전체 조성물 중량 대비, 0.20 중량% 내지 1.20 중량%, 0.24 중량% 내지 1.16 중량%, 0.28 중량% 내지 1.12 중량%, 0.32 중량% 내지 1.08 중량%, 0.36 중량% 내지 1.04 중량%, 0.40 중량% 내지 1.00 중량%, 0.44 중량% 내지 0.96 중량%, 또는 0.48 중량% 내지 0.92 중량%의 함량으로 포함될 수 있다. 에탄올의 함량이 상기 범위일 경우 악취 저감 효과가 발현될 수 있다.As an example, the content of ethanol is 0.20 wt% to 1.20 wt%, 0.24 wt% to 1.16 wt%, 0.28 wt% to 1.12 wt%, 0.32 wt% to 1.08 wt%, 0.36 wt% to 1.04 based on the total weight of the composition. It may be included in an amount of wt%, 0.40 wt% to 1.00 wt%, 0.44 wt% to 0.96 wt%, or 0.48 wt% to 0.92 wt%. When the content of ethanol is within the above range, an effect of reducing odor may be exhibited.
본 출원의 일 구현예에서, 악취 저감용 조성물은 유기산을 더 포함할 수 있다. 본 출원에서 사용되는 용어 "유기산"은 가장 넓은 의미로는 산성 특성을 갖는 유기 화합물을 의미하며, 대표적으로 카르복실기(-COOH) 또는 설폰기(-SO3H)를 포함할 수 있다. In one embodiment of the present application, the composition for reducing odor may further include an organic acid. The term "organic acid" used in the present application refers to an organic compound having acidic properties in the broadest sense, and may typically include a carboxyl group (-COOH) or a sulfone group (-SO3H).
본 출원 조성물에 포함될 수 있는 유기산은 시트르산(citric acid), 말산(malic acid), 숙신산(succinic acid), 젖산(lactic acid), 또는 초산(acetic acid) 등과 같은 저분자 유기산 또는 아스코르빈산, 또는 안식향산과 같은 고분자 유기산을 예로 들 수 있으나, 이에 한정되지 않는다. Organic acids that may be included in the composition of the present application include low-molecular organic acids such as citric acid, malic acid, succinic acid, lactic acid, or acetic acid, or ascorbic acid, or benzoic acid. Polymeric organic acids such as, but are not limited thereto.
구체적으로, 본 출원에서 사용될 수 있는 유기산은 시트르산, 말산, 숙신산, 젖산, 또는 초산으로 이루어지는 군에서 선택되는 1종 이상일 수 있고, 보다 구체적으로는 젖산, 또는 초산(acetic acid)이며, 보다 더 구체적으로는 초산이다. Specifically, the organic acid that can be used in the present application may be one or more selected from the group consisting of citric acid, malic acid, succinic acid, lactic acid, or acetic acid, and more specifically, lactic acid or acetic acid, and more specifically It is acetic acid.
본 출원에서 유기산은 에탄올 100 중량부 대비 100 중량부 내지 600 중량부의 함량으로 포함될 수 있으나, 이에 제한되지 않는다. In the present application, the organic acid may be included in an amount of 100 parts by weight to 600 parts by weight based on 100 parts by weight of ethanol, but is not limited thereto.
구체적으로 상기 유기산은 에탄올 100 중량부 대비 100 중량부, 150 중량부, 180 중량부, 200 중량부, 210 중량부, 220 중량부, 230 중량부, 240 중량부, 및 242 중량부에서 선택된 하나의 하한 값 및/또는 600 중량부, 500 중량부, 400 중량부, 350 중량부, 300 중량부, 280 중량부, 260 중량부, 250 중량부, 및 245 중량부에서 선택된 하나의 상한 값으로 구성되는 범위의 함량일 수 있다.Specifically, the organic acid is one selected from 100 parts by weight, 150 parts by weight, 180 parts by weight, 200 parts by weight, 210 parts by weight, 220 parts by weight, 230 parts by weight, 240 parts by weight, and 242 parts by weight based on 100 parts by weight of ethanol. Consisting of a lower limit and/or an upper limit selected from 600 parts by weight, 500 parts by weight, 400 parts by weight, 350 parts by weight, 300 parts by weight, 280 parts by weight, 260 parts by weight, 250 parts by weight, and 245 parts by weight. It can be a range of content.
일례로, 상기 유기산의 함량은 에탄올 100 중량부 대비 100 중량부 내지 600 중량부, 150 중량부 내지 500 중량부, 200 중량부 내지 400 중량부, 220 중량부 내지 300 중량부, 230 중량부 내지 260 중량부, 240 중량부 내지 250 중량부, 또는 242 중량부 내지 245 중량부일 수 있다. As an example, the content of the organic acid is 100 parts by weight to 600 parts by weight, 150 parts by weight to 500 parts by weight, 200 parts by weight to 400 parts by weight, 220 parts by weight to 300 parts by weight, 230 to 260 parts by weight based on 100 parts by weight of ethanol. It may be part by weight, 240 parts by weight to 250 parts by weight, or 242 parts by weight to 245 parts by weight.
본 출원에서 유기산은 전체 조성물 총 중량 대비 1 중량% 내지 2.4 중량%의 함량으로 포함될 수 있으나, 이에 제한되지 않는다. In the present application, the organic acid may be included in an amount of 1% to 2.4% by weight based on the total weight of the total composition, but is not limited thereto.
구체적으로 상기 유기산은 전체 조성물 총 중량 대비 1 중량%, 1.05 중량%, 1.1 중량%, 1.15 중량%, 1.2 중량%, 1.25 중량%, 1.3 중량%, 및 1.35 중량%으로부터 선택된 하나의 하한 값 및/또는 2.4 중량%, 2.35 중량%, 2.3 중량%, 2.25 중량%, 2.2 중량%, 2.15 중량%, 2.1 중량%, 및 2.05 중량%으로부터 선택된 하나의 상한 값으로 구성되는 범위의 함량일 수 있다. Specifically, the organic acid is one lower limit selected from 1% by weight, 1.05% by weight, 1.1% by weight, 1.15% by weight, 1.2% by weight, 1.25% by weight, 1.3% by weight, and 1.35% by weight relative to the total weight of the total composition and/ Alternatively, it may be a content in a range consisting of one upper limit value selected from 2.4% by weight, 2.35% by weight, 2.3% by weight, 2.25% by weight, 2.2% by weight, 2.15% by weight, 2.1% by weight, and 2.05% by weight.
일례로, 상기 유기산의 함량은 전체 조성물 중량 대비, 1 중량% 내지 2.4 중량%, 1.05 중량% 내지 2.35 중량%, 1.1 중량% 내지 2.3 중량%, 1.15 중량% 내지 2.25 중량%, 1.2 중량% 내지 2.2 중량%, 1.25 중량% 내지 2.15 중량%, 1.3 중량% 내지 2.1 중량%, 또는 1.35 중량% 내지 2.05 중량%의 함량으로 포함될 수 있다. 유기산의 함량이 상기 범위일 경우 악취 저감 효과가 발현될 수 있다. For example, the content of the organic acid is 1% to 2.4% by weight, 1.05% to 2.35% by weight, 1.1% to 2.3% by weight, 1.15% to 2.25% by weight, 1.2% to 2.2% by weight, based on the total weight of the composition. It may be included in an amount of weight %, 1.25 weight% to 2.15 weight %, 1.3 weight% to 2.1 weight %, or 1.35 weight% to 2.05 weight %. When the content of the organic acid is within the above range, an effect of reducing odor may be exhibited.
상기 초산은 전체 유기산 100 중량% 대비 50 중량% 이상, 70 중량% 이상, 80 중량% 이상, 85 중량% 이상, 또는 90 중량% 이상일 수 있다. 구체적으로 90 중량% 내지 100 중량%, 90 중량% 내지 99 중량%, 또는 90 중량% 내지 97 중량% 일 수 있다. The acetic acid may be 50% by weight or more, 70% by weight or more, 80% by weight or more, 85% by weight or more, or 90% by weight or more with respect to 100% by weight of the total organic acid. Specifically, it may be 90% to 100% by weight, 90% to 99% by weight, or 90% to 97% by weight.
본 출원의 일 구현예에서, 유기산은 천연물로부터 유래된 유기산 뿐만 아니라 인공적으로 합성된 유기산도 사용할 수 있다. In the exemplary embodiment of the present application, the organic acid may be used not only an organic acid derived from a natural product, but also an artificially synthesized organic acid.
구체적으로 상기 천연물로부터 당업계에 공지된 방법, 예를 들어 추출방법에 의해 분리 정제한 것을 사용하거나, 천연물의 발효물로부터 유래된 것을 사용할 수 있다. 구체적으로, 발효식초로부터 유래된 것을 사용할 수 있다. Specifically, the natural product may be separated and purified by a method known in the art, for example, an extraction method, or a fermented product derived from a natural product may be used. Specifically, those derived from fermented vinegar may be used.
상기 발효식초는 공지된 방법으로 발효하는 것을 포함하며, 일례로 포도당 등을 에탄올로 발효하는 1차 발효 및 에탄올을 초산으로 발효하는 2차 발효를 통해 수득한 것일 수 있다. The fermented vinegar includes fermentation by a known method, and for example, may be obtained through primary fermentation of fermenting glucose or the like into ethanol and secondary fermentation of fermenting ethanol with acetic acid.
상기 천연물은 유기산을 포함하는 어느 물질이든 제한없이 이용가능하나, 식물일 수 있다. 구체적으로 알로에, 아니스 씨드, 딱총나무, 가시오가피, 차전자피, 오렌지 플라워, 피멘토나무, 오레가노, 쥐오줌풀, 캐모마일, 캅사이신 페퍼, 카다몬, 계수나무, 마늘, 캐러웨이 씨드, 정향, 커민 씨드, 콜라나무, 고수풀 씨드, 붉나무, 사프란, 산초나무, 쥬니퍼 베리, 시나몬, 생강, 팔각, 세인트 존스 워트, 셀러리 씨드, 세이보리, 참깨, 식용 대황, 타라곤, 터메릭, 엉겅퀴, 딜 씨드, 육두구, 쐐기풀, 하이비스커스, 풍년화, 자작나무, 바질, 비터 오렌지, 회향, 앵초, 호로파, 버베나, 월계수, 홉, 볼도, 와사비, 양귀비 씨드, 오배자, 매리골드, 마롱, 마조람, 머스터드, 밀푀유, 민트 잎, 멜리사, 육두구, 린덴, 용담, 로즈힙, 로즈마리, 로즈마리너스 오피시널리스, 해바라기 씨드, 그레이프 과피, 사과, 당근 잎, 바나나, 딸기, 살구나무, 복숭아, 자두, 파인애플, 나시배, 감나무, 체리, 파파야, 망고, 아보카도, 멜론, 비파나무, 무화과, 키위, 푸룬, 블루베리, 블랙베리, 라즈베리, 크랜베리, 커피콩, 카카오콩, 그레이프 씨드, 그레이프 프루트 씨드, 피칸 넛, 캐슈 넛, 밤, 코코넛, 피넛, 월넛, 녹차잎, 홍차잎, 우롱차잎, 담배, 들깨잎, 가든타임, 세이지, 라벤더, 스페아민트, 페퍼민트, 스팟 엉겅퀴, 히솝, 스위트 바질, 매리골드, 민들레, 아티초크, 저맨캐모마일, 짚신나물, 감초, 아니스, 서양톱풀, 유칼립투스, 쓴쑥, 밭삼, 땅두릅, 호로파, 꽃고추, 회향, 고추, 고수풀 씨드, 캐러웨이 씨드, 회향 씨드, 생강, 겨자무, 오레가노 마조람, 오레가노(origanum valgare), 머스터드, 파슬리, 후추, 세이보리, 타라곤, 쿠르크마, 고추냉이, 딜 씨드, 또는 감귤류 과일 등일 수 있다. The natural product may be any material containing an organic acid without limitation, but may be a plant. Specifically, Aloe, Anise Seed, Elder Tree, Spikeweed, Psyllium Seed, Orange Flower, Pimento Tree, Oregano, Valerian, Chamomile, Capsaicin Pepper, Cardamom, Cassia, Garlic, Caraway Seed, Clove, Cumin Seed, Coke Tree , Coriander seed, red tree, saffron, Japanese pepper tree, juniper berry, cinnamon, ginger, octagonal, St. John's wort, celery seed, savory, sesame, edible rhubarb, tarragon, turmeric, thistle, dill seed, nutmeg, nettle, hibiscus, Weathered flowers, birch, basil, bitter orange, fennel, primrose, fenugreek, verbena, laurel, hops, boldo, wasabi, poppy seed, five baeja, marigold, maroon, marjoram, mustard, wheatfeuille, mint leaves, melissa, Nutmeg, Linden, Gentian, Rosehip, Rosemary, Rosemarinus Officials, Sunflower Seed, Grape Peel, Apple, Carrot Leaf, Banana, Strawberry, Apricot Tree, Peach, Plum, Pineapple, Nashi Pear, Persimmon Tree, Cherry, Papaya, Mango, avocado, melon, loquat, fig, kiwi, prune, blueberry, blackberry, raspberry, cranberry, coffee bean, cacao bean, grape seed, grapefruit seed, pecan nut, cashew nut, chestnut, coconut, peanut, Walnut, green tea leaves, black tea leaves, oolong tea leaves, tobacco, perilla leaves, garden thyme, sage, lavender, spemint, peppermint, spot thistle, hyssop, sweet basil, marigold, dandelion, artichoke, german chamomile, sandalwood, Licorice, Anise, Yarrow, Eucalyptus, Bitter Mugwort, Wild Ginseng, Earthworm, Fenugreek, Red Pepper, Fennel, Red Pepper, Coriander Seed, Caraway Seed, Fennel Seed, Ginger, Mustard Radish, Oregano Marjoram, Origanum valgare, Mustard , Parsley, pepper, savory, tarragon, curkma, wasabi, dill seeds, or citrus fruits.
본 출원의 일 구현예에서, 본 출원의 악취 저감용 조성물을 포함하는 제품을 포함할 수 있다. In one embodiment of the present application, a product including the composition for reducing odor of the present application may be included.
본 출원의 제품은 식품, 사료, 생활용품, 공업용품 등 제한 없이 적용될 수 있으며, 구체적인 식품 또는 사료의 예로는, 곡류가공품, 야채, 과일, 야채의 건조제품이나 절단제품, 과일쥬스, 야채쥬스, 야채와 과일의 혼합쥬스, 칩류, 면류, 축산가공식품, 수산가공식품, 유가공식품, 발효유식품, 미생물발효식품, 제과제빵, 양념류, 어/육가공류, 산성음료수, 가공식품류, 간편식류, 감초류, 허브류, 곤충 사료류, 가축 사료류, 애완동물 사료류 등이 있으나 이에 제한되는 것은 아니다. The product of the present application may be applied without limitation, such as food, feed, household goods, industrial goods, etc., and examples of specific food or feed include processed grain products, vegetables, fruits, dried or cut products of vegetables, fruit juice, vegetable juice, Mixed juice of vegetables and fruits, chips, noodles, processed livestock food, processed seafood, processed dairy food, fermented milk food, microbial fermented food, confectionery bakery, seasonings, fish/meat products, acidic beverages, processed foods, convenience foods, licorice , Herbs, insect feed, livestock feed, pet feed, etc., but are not limited thereto.
구체적으로 본 출원의 제품은 맛술일 수 있다. Specifically, the product of the present application may be taste alcohol.
본 출원에서 "악취"는 제품에 포함된 성분 자체 또는 이 성분의 2차적인 화학적 변화 또는 외부로부터 혼입된 물질에 의해 발생되는 불쾌감 또는 혐오감을 주는 냄새를 의미한다. In the present application, "odor" refers to an unpleasant or disgusting odor generated by a component contained in the product itself or a secondary chemical change of the component or a substance incorporated from the outside.
상기 악취를 발생시키는 물질은 일례로 질소화합물, 황화합물, 저급지방산류, 카르보닐 화합물, 에스테르류, 페놀류, 알코올류, 탄화수소류, 또는 염소화합물일 수 있다. The substances that generate the odor may be, for example, nitrogen compounds, sulfur compounds, lower fatty acids, carbonyl compounds, esters, phenols, alcohols, hydrocarbons, or chlorine compounds.
구체적으로, 상기 악취는 비린내일 수 있다. 상기 비린내는 식물 또는 해산물로부터 유래되는 비린내일 수 있으며, 구체적으로 어류에서 유래되는 비린내일 수 있다. Specifically, the odor may be fishy. The fishy smell may be a fishy smell derived from plants or seafood, and specifically, may be a fishy smell derived from fish.
상기 질소화합물은 암모니아, 트리메틸아민, 피페리딘, 트리메틸옥사이드 등 악취를 발생할 수 있는 물질이면 제한없이 포함할 수 있으나, 구체적으로 트리메틸아민일 수 있다. The nitrogen compound may be included without limitation as long as it is a substance capable of generating odors such as ammonia, trimethylamine, piperidine, and trimethyl oxide, but may be specifically trimethylamine.
본 출원의 조성물은 상기 설명된 성분 들 이외에 정제수를 추가 첨가함으로써 조성물의 최종 중량 또는 부피를 조절할 수 있다. The composition of the present application may adjust the final weight or volume of the composition by adding purified water in addition to the above-described components.
본 출원의 조성물은 그 자체로 악취 저감용 조성물로 사용될 수 있으나, 당류 또는 조미료 성분과 같은 추가 성분을 더 첨가하여 소스로 사용하거나 수산물 가공식품에 적용할 수 있다. The composition of the present application may itself be used as a composition for reducing odor, but may be used as a sauce by adding additional ingredients such as sugars or seasoning ingredients, or applied to processed aquatic products.
본 출원 조성물에 더 첨가할 수 있는 당류 성분은 포도당, 과당, 갈락토오스와 같은 단당류; 수크로오스, 맥아당, 젖당과 같은 이당류; 단당류가 3 개 이상 결합된 올리고당류; 전분, 글리코겐과 같은 다당류를 예로 들 수 있으나, 이에 한정되지 않는다. Sugar components that can be further added to the composition of the present application include monosaccharides such as glucose, fructose, and galactose; Disaccharides such as sucrose, maltose, and lactose; Oligosaccharides in which three or more monosaccharides are bound; Examples include polysaccharides such as starch and glycogen, but are not limited thereto.
본 출원 조성물에 조미료 성분으로 아미노산 성분을 더 첨가할 수 있고, 향신료 성분으로 생강농축액 또는 로즈마리 농축액을 더 포함할 수 있다. 상기 조미료의 아미노산 성분은 천연물로부터 유래된 것, 발효에 의해 생성된 것, 또는 인공적으로 합성된 것을 사용할 수 있다. An amino acid component may be further added as a seasoning component to the composition of the present application, and a ginger concentrate or rosemary concentrate may be further included as a spice component. The amino acid component of the seasoning may be derived from a natural product, produced by fermentation, or artificially synthesized.
본 출원의 조성물은 폴리페놀 성분 이외에 여러 가지 영양제, 비타민, 전해질, 풍미제, 착색제, 펙트산, 펙트산의 염, 알긴 산, 알긴산의 염, 유기산, 보호성 콜로이드 증점제, pH 조절제, 안정화제, 방부제, 글리세린, 알코올 또는 탄산화제 등을 추가로 함유할 수 있다. In addition to the polyphenol component, the composition of the present application includes various nutrients, vitamins, electrolytes, flavoring agents, colorants, pectic acid, salts of pectic acid, alginic acid, salts of alginic acid, organic acids, protective colloid thickeners, pH adjusters, stabilizers, It may further contain preservatives, glycerin, alcohols or carbonation agents.
구체적으로, 본 출원의 조성물은 비타민 A, C, D, E, B1, B2, B6, B12, 니아신(niacin), 비오틴(biotin), 폴레이트(folate), 판토텐산(panthotenic acid) 등을 포함할 수 있다. 또한, 아연(Zn), 철(Fe), 칼슘(Ca), 크롬(Cr), 마그네슘(Mg), 망간(Mn), 구리(Cu), 크륨(Cr) 등의 미네랄을 포함할 수 있다. 또한, 라이신, 트립토판, 시스테인, 발린 등의 아미노산을 포함할 수 있다. 또한, 포도당, 과당과 같은 모노사카라이드; 말토스, 수크로스와 같은 다이사카라이드; 덱스트린, 사이클로덱스트린과 같은 폴리사카라이드; 자일리톨, 소르비톨, 에리트리톨 등의 당알콜을 포함할 수 있다. 또한, 방부제로서 소르빈산 칼륨, 벤조산나트륨, 살리실산, 데히드로초산나트륨 등; 살균제로서 표백분과 고도 표백분, 차아염소산나트륨 등; 산화방지제로서 부틸히드록시아니졸(BHA), 부틸히드록시톨류엔(BHT) 등; 착색제로서 타르색소; 발색제로서, 아질산 나트륨, 아초산 나트륨; 표백제로서 아황산나트륨; 조미료로서, MSG 글루타민 산나트륨; 감미료로서 타우마틴, 스테비아 추출물과 같은 천연 감미제, 사카린, 아스파르탐과 같은 합성 감미제; 향료로서 바닐린, 락톤류; 팽창제로서 명반, D주석산수소칼륨; 강화제, 유화제, 증점제(호료), 피막제, 검기초제, 거품억제제, 용제, 개량제 등의 식품 첨가물(food additives)을 포함할 수 있다. 상기 첨가물은 식품의 종류에 따라 선별되고 적절한 양으로 사용될 수 있다.Specifically, the composition of the present application may include vitamins A, C, D, E, B1, B2, B6, B12, niacin, biotin, folate, panthotenic acid, and the like. I can. In addition, it may contain minerals such as zinc (Zn), iron (Fe), calcium (Ca), chromium (Cr), magnesium (Mg), manganese (Mn), copper (Cu), and chromium (Cr). In addition, amino acids such as lysine, tryptophan, cysteine, and valine may be included. In addition, monosaccharides such as glucose and fructose; Disaccharides such as maltose and sucrose; Polysaccharides such as dextrin and cyclodextrin; Sugar alcohols, such as xylitol, sorbitol, and erythritol, may be contained. Further, as preservatives, potassium sorbate, sodium benzoate, salicylic acid, sodium dehydroacetate, and the like; Bleached powder, highly bleached powder, sodium hypochlorite, etc. as a disinfectant; As antioxidants, butylhydroxyanisole (BHA), butylhydroxytoleuene (BHT), etc.; Tar colors as colorants; As a coloring agent, sodium nitrite, sodium nitrite; Sodium sulfite as bleach; As a seasoning, MSG sodium glutamate; Natural sweeteners such as taumatin and stevia extract as sweeteners, synthetic sweeteners such as saccharin and aspartame; Vanillin and lactones as flavorings; Alum, D potassium hydrogen stannate as an expanding agent; It may contain food additives such as reinforcing agents, emulsifying agents, thickening agents (thickening agents), coating agents, gum base agents, antifoaming agents, solvents, and improving agents. The additive may be selected according to the type of food and used in an appropriate amount.
본 출원의 다른 측면은 상기 설명된 본 출원 조성물을 악취 생성물에 첨가하는 단계를 포함하는 악취 저감 방법을 제공한다. Another aspect of the present application provides a method for reducing malodor comprising the step of adding the composition of the present application described above to a malodor product.
본 출원의 다른 측면인 악취 저감 방법에서 조성물에 관한 내용은 상기 본 출원의 일 측면에서 설명한 바와 동일하므로, 중복하여 설명하지 않는다. In the method for reducing odor, which is another aspect of the present application, the contents of the composition are the same as those described in one aspect of the present application, and thus, overlapping descriptions will not be made.
이하, 본 출원을 실시예에 의하여 상세히 설명한다. Hereinafter, the present application will be described in detail by examples.
단, 하기 실시예는 본 출원을 구체적으로 예시하는 것이며, 본 출원의 내용이 하기 실시예에 의해 한정되지 아니한다. However, the following examples specifically illustrate the present application, and the contents of the present application are not limited by the following examples.
실험예 1: 생선 비린내 제거용 조성물의 제조 Experimental Example 1: Preparation of a composition for removing fish smell
1. 실험 재료 1. Experimental material
실험에 사용한 폴리페놀인 클로로젠산, 카페산은 시그마-알드리치(Sigma-aldrich)사(USA)에서 구입하여 사용하였다. 에탄올으로서 사용한 청주(에탄올 약 16%(w/w) 포함)는 우포의 아침으로부터 구입하였고, 초산(acetic acid)은 대정화금으로부터 구입하였고, 정제수는 J.T. Baker 로부터 구입하여 사용하였다. The polyphenols used in the experiment, chlorogenic acid and caffeic acid, were purchased from Sigma-aldrich (USA) and used. Cheongju (including about 16% (w/w) ethanol) used as ethanol was purchased from Morning of Upo, acetic acid was purchased from Daejeonghwageum, and purified water was JT Baker It was purchased from and used.
2. 조성물의 성분 구성 2. Composition of the composition
아래 표 1에 나타낸 성분 구성으로 생선 비린내 제거용 조성물을 제조하였다. 제조한 각각의 조성물(실시예 및 비교예)에 대해 트리메틸아민(TMA) 저감 효과를 확인하였다. A composition for removing fishy smell was prepared with the composition of the ingredients shown in Table 1 below. For each of the prepared compositions (Examples and Comparative Examples), the effect of reducing trimethylamine (TMA) was confirmed.
구성Configuration 실시예1Example 1 실시예2Example 2 실시예3Example 3 실시예4Example 4 비교예1(무처리구)Comparative Example 1 (no treatment) 비교예2Comparative Example 2
클로로젠산Chlorogenic acid 2.5ppm2.5ppm 25.0ppm25.0ppm 2.5ppm2.5ppm 25.0ppm25.0ppm -- --
카페산Caffeic acid 0.5ppm0.5ppm 2.5ppm2.5ppm 0.5ppm0.5ppm 2.5ppm2.5ppm -- --
청주*Rice wine* 4.383%4.383% 4.383%4.383% 4.383%4.383% 4.383%4.383% -- --
초산 Acetic acid -- -- 1.7%1.7% 1.7%1.7% -- 1.7%1.7%
(* 에탄올 함량 환산 시 0.7%(w/w))(* 0.7% (w/w) in terms of ethanol content)
실험예 2: 트리메틸아민(TMA) 저감 효과 확인Experimental Example 2: Trimethylamine (TMA) reduction effect confirmation
1. 생선 비린내 저감 효과 확인1. Confirmation of fish smell reduction effect
시중에서 구입한 생고등어의 살을 분리하여 믹서로 균질하고 실험예 1에서 제조한 시료를 6.3%(w/w) 첨가하여 30분 이상 재웠다. 각 시료를 처리한 고등어를 약 90℃에서 약 10분 가열하였다. 가열 중에 고등어가 타지 않도록 뒤집어 주었다.The flesh of the fresh mackerel purchased on the market was separated, homogenized with a mixer, and 6.3% (w/w) of the sample prepared in Experimental Example 1 was added, and the mixture was allowed to sleep for 30 minutes or more. The mackerel treated with each sample was heated at about 90° C. for about 10 minutes. During heating, the mackerel was turned over so that it did not burn.
2. 트리메틸아민(TMA) 성분 및 함량 분석 2. Trimethylamine (TMA) component and content analysis
다음의 방법을 통해 폴리페놀 조성물에서 트리메틸아민(TMA) 성분을 확인하였다. 휘발성 물질의 분석을 위한 흡착은 SPME(Solid Phase Microextraction Fiber Holder, Supelco., Bellefonte, PA, USA)는 DVB/CAR/PDMS(50/30 μm)를 사용하여 전처리하였다. 전처리한 추출물 1mL을 20 mL EPA 바이알(vial)에 넣은 후 PTFE/Silicon으로 캡핑(capping) 하였다. 조성물을 첨가한 바이알(vial)에 SPME 니들(needle)을 삽입한 후, 60 ℃에서 30분간 흡착 후 GC/MS 분석에 이용하였다. The trimethylamine (TMA) component was confirmed in the polyphenol composition through the following method. Adsorption for the analysis of volatile substances was pretreated using DVB/CAR/PDMS (50/30 μm) in SPME (Solid Phase Microextraction Fiber Holder, Supelco., Bellefonte, PA, USA). 1 mL of the pretreated extract was put into a 20 mL EPA vial and then capped with PTFE/Silicon. After inserting an SPME needle into a vial to which the composition was added, it was adsorbed at 60° C. for 30 minutes and used for GC/MS analysis.
GC/MS분석은 Agilent gas chromatograph (GC2010 plus, Agilent,USA )을 사용하고 컬럼(column)은 DB-WAX Capillary (thickness: 0.25 μm, length: 60m, Diameter: 0.25 mm)를 사용하였다. He을 캐리어 가스(carrier gas)로 사용하고, 컬럼오븐온도(column oven temperature)는 130℃, 인젝션 온도(injection temperature)는 200℃, 총 유량(total flow)은 1.10 mL/min, 총 프로그램 시간(total program time)은 60분으로 설정한 후 분석을 실시하였다. 조성물 중의 TMA에 대한 정량은 시료 1.0g에 내부표준물질(internal standard)로서 20 mg/L 3-heptanol 30uL를 첨가하여 시료내 휘발성 향기 성분의 함량을 상대 정량(comparative relative quantification)으로 하여 계산하여 정량 하였다. Agilent gas chromatograph (GC2010 plus, Agilent, USA) was used for GC/MS analysis, and DB-WAX Capillary (thickness: 0.25 μm, length: 60 m, Diameter: 0.25 mm) was used as the column. He is used as a carrier gas, the column oven temperature is 130℃, the injection temperature is 200℃, the total flow is 1.10 mL/min, and the total program time ( total program time) was set to 60 minutes, and then the analysis was performed. Quantification of TMA in the composition is quantified by adding 20 mg/L 3-heptanol 30uL as an internal standard to 1.0 g of a sample and calculating the content of volatile fragrance components in the sample as a comparative relative quantification. I did.
3. 트리메틸아민 저감 결과 확인3. Trimethylamine reduction result confirmation
하기 표 2와 같이 폴리페놀과 에탄올을 첨가한 실시예 1 내지 4에서 아무것도 처리하지 않은 비교예 1, 초산만 처리한 비교예 2에 비해서 TMA 저감 효과가 우수한 것을 확인하였다. 특히, 초산을 추가로 첨가한 실시예 3, 4에서 초산 단독(비교예 2), 폴리페놀 및 에탄올(실시예 1, 2)의 TMA 저감량에 비해서 TMA 저감량이 우수한 것을 확인하여, 초산, 폴리페놀, 에탄올 조합 간에도 시너지 효과가 있음을 확인하였다. As shown in Table 2 below, in Examples 1 to 4 in which polyphenol and ethanol were added, it was confirmed that the TMA reduction effect was excellent compared to Comparative Example 1 in which nothing was treated and Comparative Example 2 in which only acetic acid was treated. In particular, in Examples 3 and 4 in which acetic acid was additionally added, it was confirmed that the TMA reduction amount was superior to that of acetic acid alone (Comparative Example 2), polyphenol and ethanol (Examples 1 and 2). , It was confirmed that there is a synergistic effect between the ethanol combination.
구성Configuration TMA함량(ppb)TMA content (ppb)
실시예1Example 1 474474
실시예2Example 2 461461
실시예3Example 3 350350
실시예4Example 4 410410
비교예1Comparative Example 1 543543
비교예2Comparative Example 2 508508
실험예 3: 맛술 제품 제조 및 성분 분석 Experimental Example 3: Preparation of taste wine products and analysis of ingredients
1. 맛술 제품 제조 1. Manufacture of taste wine products
폴리페놀이 포함된 사과발효식초(CJ제일제당) 25%(w/w), 과당(CJ제일제당) 25%(w/w), 설탕(CJ제일제당) 15%(w/w), 청주(에탄올 약 16%(w/w) 포함, 우포의아침) 5%(w/w) 및 기타 (생강 또는 로즈마리 추출물 포함)한 맛술을 제조하였다. 생강이 포함된 맛술은 이하에서 CJ 맛술 생강으로, 로즈마리가 포함된 맛술은 CJ 맛술 로즈마리로 기재하였다.Apple fermented vinegar containing polyphenols (CJ CheilJedang) 25% (w/w), fructose (CJ CheilJedang) 25% (w/w), sugar (CJ CheilJedang) 15% (w/w), Cheongju (Including about 16% (w/w) ethanol, Morning of Upo) 5% (w/w) and other (including ginger or rosemary extract) were prepared. In the following, the taste wine containing ginger is described as CJ Matsool ginger, and the taste wine containing rosemary is described as CJ Matsool rosemary.
2. 성분 분석 1-유기산 분석 2. Component Analysis 1-Organic Acid Analysis
맛술 생강과 맛술 로즈마리와 기존 시판되고 있는 주정을 유효 성분으로 한 맛술(롯데, 이하, 시판 맛술)을 구입하여, 유기산 분석의 비교 실험에 사용하였다. 유기산 분석은 다음의 방법을 통하여 진행하였다. Matsul (Lotte, hereinafter, commercially available Matsul) was purchased and used in a comparative experiment for analysis of organic acids, using Matsul ginger, Matsul rosemary, and existing commercially available alcohol as active ingredients. Organic acid analysis was carried out through the following method.
유기산 분석은 0.2μm membrane filter로 여과한 후 HPLC로 분석하였다. 이때 column은 YMCpak ODS-AQ(8.3 Х 250 mm, YMC Co., Ltd., Tokyo, Japan)를 사용하였으며, column 온도는 35℃, mobile phase은 10 mM phosphate buffer, flow rate은 0.7 mL/min, 검출기는 photodiodearray(PDA) detector, Waters 2414(Waters Co.)로 분석하였다. 표준물질은 oxalic acid, citric acid, succinic acid, tartaric acid, malic acid 및 lactic acid (Sigma Co.)를 일정량을 혼합하여 증류수에 녹여 표준 용액으로 사용하였다. 시료와 표준 물의 유기산 성분은 머무른 시간(tR)을 비교하여 확인하였고, 각각의 표준물질 검량곡선을 작성 peak의 면적으로 개별 유기산 성분의 함량을 측정하였다. 측정 결과를 표 3에 나타내었다. Organic acid analysis was performed by HPLC after filtering through a 0.2 μm membrane filter. At this time, YMCpak ODS-AQ (8.3 Х 250 mm, YMC Co., Ltd., Tokyo, Japan) was used as the column, the column temperature was 35°C, the mobile phase was 10 mM phosphate buffer, and the flow rate was 0.7 mL/min, The detector was analyzed with a photodiodearray (PDA) detector, Waters 2414 (Waters Co.). As a standard, a certain amount of oxalic acid, citric acid, succinic acid, tartaric acid, malic acid, and lactic acid (Sigma Co.) were mixed and dissolved in distilled water to use as a standard solution. The organic acid component of the sample and the standard water was confirmed by comparing the retention time (tR), and each standard substance calibration curve was prepared and the content of the individual organic acid component was measured by the area of the peak. Table 3 shows the measurement results.
3. 성분 분석2- 폴리페놀 성분 분석 3. Component Analysis 2- Polyphenol Component Analysis
CJ 맛술 생강, CJ 맛술 로즈마리와 시판 맛술을 구입하여, 폴리페놀 성분을 분석하여 비교하였다. 폴리페놀 성분 분석은 다음의 방법을 통해 진행하였다. CJ Matsul Ginger, CJ Matsul Rosemary and commercial Matsul were purchased, and polyphenol components were analyzed and compared. Analysis of the polyphenol component was carried out through the following method.
클로로젠산(chlorogenic acid), 카페산(caffeic acid) 분석기기로는 Ultimate3000 HPLC (Thermo Dionex, USA)을 사용하였고, 컬럼(column)은 Inno C-18 column (Younginbiochrom, Korea(5㎛, 4.6x250mm)을 사용하였다. 컬럼 온도는 30℃로 하였고, 이동상은 0.1% TFA 용액과 아세토나이트릴을 이용하였으며, 0-25 분, 10% 아세토나이트릴; 25-30 분, 60% 아세토나이트릴; 30-35 분 100% 아세토나이트릴; 35-36분 100% 아세토나이트릴; 36-40 분 10% 아세토나이트릴로 구배(gradient)를 주었다. 용매 유속 0.8ml/min으로 하였으며, 검출기(Detector)의 파장은 280nm, 340nm, 254nm를 사용하였다. 클로로젠산 및 카페산 함량 분석 결과를 표 4에 나타내었다. Ultimate3000 HPLC (Thermo Dionex, USA) was used as an analyzer for chlorogenic acid and caffeic acid, and the column was Inno C-18 column (Younginbiochrom, Korea (5㎛, 4.6x250mm). The column temperature was set to 30° C., the mobile phase was 0.1% TFA solution and acetonitrile, 0-25 minutes, 10% acetonitrile; 25-30 minutes, 60% acetonitrile; 30- A gradient was applied to 35 minutes 100% acetonitrile; 35-36 minutes 100% acetonitrile; 36-40 minutes 10% acetonitrile The solvent flow rate was 0.8 ml/min, and the wavelength of the detector was 280 nm, 340 nm, and 254 nm were used, and the results of the analysis of the content of chlorogenic acid and caffeic acid are shown in Table 4.
4. 성분 분석 실험 결과 4. Component analysis experiment results
하기 표 3(맛술의 유기산 분석 결과) 및 표 4(맛술의 폴리페놀 분석 결과)에 나타난 바와 같이, 기존 시판 맛술은 유기산 함량이 낮았으며, 폴리페놀 성분인 클로로젠산 및 카페산은 포함되지 않은 것으로 확인되었다. (n.d.는 측정되지 않은 것을 의미한다.) As shown in Table 3 (analysis result of organic acid of Matsuri) and Table 4 (a result of analysis of polyphenol of Matsuri), existing commercially available Matsuri had a low organic acid content, and did not contain chlorogenic acid and caffeic acid, which are polyphenol components. Confirmed. (n.d. means not measured.)
NoNo 샘플 명칭Sample name 유기산Organic acid
시트르산Citric acid 말산Malic acid 숙신산Succinic acid 젖산Lactic acid 포름산Formic acid 아세트산Acetic acid 합계Sum
1One CJ 맛술생강 CJ Matsuol Ginger n.dn.d 0.4610.461 0.1140.114 0.1250.125 n.dn.d 16.81916.819 17.51817.518
22 CJ 맛술로즈마리CJ Massulose Marie 0.9220.922 0.6540.654 0.1300.130 0.2180.218 n.dn.d 17.47917.479 19.40419.404
33 시판 맛술Commercial taste sake 0.0860.086 n.dn.d n.dn.d 0.0880.088 n.dn.d 0.0300.030 0.2040.204
No.No. 제품명product name 클로로젠산Chlorogenic acid 카페산Caffeic acid
1One CJ 맛술 로즈마리CJ Massage Rosemary 5.68445.6844 1.3081.308
22 CJ 맛술 생강CJ Matsul Ginger 2.52022.5202 0.54020.5402
33 롯데 미림Lotte Mirim n.d.n.d. n.d. n.d.
실험예 4: 맛술 제품의 트리메틸아민 저감 효과 확인 Experimental Example 4: Confirmation of the effect of reducing trimethylamine in taste wine products
실험예 3에서 제조한 CJ 맛술 생강, CJ 맛술 로즈마리와 시판 맛술의 트리메틸아민(TMA) 성분의 저감 효과를 확인하였다. 트리메틸아민 성분 저감 효과 확인 방법은 실험예2에서 기재한 바와 동일하다. 트리메틸아민의 저감 효과 분석한 결과는 아래 표 5에 나타내었다. 하기 표 5(TMA 저감 효과 분석 결과)에서 보여지는 바와 같이, 폴리페놀 및 에탄올이 포함된 CJ 맛술 생강, CJ 맛술 로즈마리 조성물은 TMA 저감율이 매우 높게 나타난 반면, 시판 맛술은 TMA 저감 효과가 낮았다. The effect of reducing the ingredients of CJ Matsul ginger prepared in Experimental Example 3, CJ Matsul rosemary, and trimethylamine (TMA) components of commercially available Matsul was confirmed. The method of confirming the effect of reducing the trimethylamine component is the same as described in Experimental Example 2. The results of analyzing the reduction effect of trimethylamine are shown in Table 5 below. As shown in Table 5 below (Results of TMA reduction effect analysis), the composition of CJ Matsul ginger and CJ Matsul rosemary containing polyphenol and ethanol showed a very high TMA reduction rate, whereas the commercially available Matsul had a low TMA reduction effect.
구분division TMA(ppb)TMA(ppb) %환산%exchange
무처리구No treatment 16051605 100.00100.00
CJ 맛술 생강CJ Matsul Ginger 816816 50.8150.81
CJ 맛술 로즈마리CJ Massage Rosemary 721721 44.9444.94
시판 맛술 Commercial taste sake 15311531 95.3595.35
상기에서는 본 출원의 대표적인 실시예를 예시적으로 설명하였으나, 본 출원의 범위는 상기와 같은 특정 실시예만 한정되지 아니하며, 해당 분야에서 통상의 지식을 가진 자라면 본 출원의 청구범위에 기재된 범주 내에서 적절하게 변경이 가능할 것이다. In the above, exemplary embodiments of the present application have been exemplarily described, but the scope of the present application is not limited to the specific embodiments as described above, and those of ordinary skill in the relevant field are within the scope of the claims of the present application. It will be possible to change appropriately in

Claims (14)

  1. 폴리페놀 및 에탄올을 포함하는 악취 저감용 조성물. A composition for reducing odor containing polyphenols and ethanol.
  2. 청구항 1에 있어서, 상기 폴리페놀은 클로로젠산 및 카페산으로 이루어지는 군에서 선택되는 하나 이상인 것인 악취 저감용 조성물. The composition of claim 1, wherein the polyphenol is at least one selected from the group consisting of chlorogenic acid and caffeic acid.
  3. 청구항 1에 있어서, 유기산을 더 포함하는 것인 악취 저감용 조성물. The composition for reducing odor of claim 1, further comprising an organic acid.
  4. 청구항 3에 있어서, 상기 유기산은 시트르산, 말산, 숙신산, 젖산, 및 초산으로 이루어지는 군에서 선택되는 1종 이상인 것인 악취 저감용 조성물. The composition of claim 3, wherein the organic acid is at least one selected from the group consisting of citric acid, malic acid, succinic acid, lactic acid, and acetic acid.
  5. 청구항 1에 있어서, 폴리페놀은 발효 식초로부터 유래된 것인 악취 저감용 조성물. The composition of claim 1, wherein the polyphenol is derived from fermented vinegar.
  6. 청구항 3에 있어서, 상기 유기산은 발효 식초로부터 유래된 것인 악취 저감용 조성물. The composition of claim 3, wherein the organic acid is derived from fermented vinegar.
  7. 청구항 1에 있어서, 상기 폴리페놀의 함량은 전체 에탄올 100 중량부 대비 0.01 중량부 내지 5 중량부인 것인 악취 저감용 조성물. The composition for reducing odor of claim 1, wherein the content of the polyphenol is 0.01 parts by weight to 5 parts by weight based on 100 parts by weight of total ethanol.
  8. 청구항 7에 있어서, 상기 폴리페놀 함량은 클로로젠산과 카페산의 함량 합계인 것인 악취 저감용 조성물. The composition of claim 7, wherein the polyphenol content is the sum of the contents of chlorogenic acid and caffeic acid.
  9. 청구항 3에 있어서, 상기 유기산의 함량은 에탄올 100 중량부 대비 100 중량부 내지 600 중량부인 것인 악취 저감용 조성물. The composition of claim 3, wherein the content of the organic acid is 100 parts by weight to 600 parts by weight based on 100 parts by weight of ethanol.
  10. 청구항 1에 있어서, 상기 악취는 비린내인 것인 악취 저감용 조성물. The composition for reducing odor of claim 1, wherein the odor is fishy.
  11. 청구항 1에 있어서, 상기 악취는 질소화합물에 의해 발생되는 것인 악취 저감용 조성물. The composition of claim 1, wherein the malodor is generated by nitrogen compounds.
  12. 청구항 1 내지 청구항 11 중 어느 하나에 기재된 조성물을 악취 생성물에 첨가하는 것을 포함하는 악취 저감 방법. A method for reducing malodor comprising adding the composition according to any one of claims 1 to 11 to a malodor product.
  13. 청구항 1 내지 청구항 11 중 어느 하나에 기재된 조성물을 포함하는 제품.An article comprising the composition according to any one of claims 1 to 11.
  14. 청구항 13에 있어서, 상기 제품은 맛술인 것인 제품. The product according to claim 13, wherein the product is a taste liquor.
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