WO2021038717A1 - Input/output structure of assembled battery pack and manufacturing method therefor - Google Patents

Input/output structure of assembled battery pack and manufacturing method therefor Download PDF

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Publication number
WO2021038717A1
WO2021038717A1 PCT/JP2019/033502 JP2019033502W WO2021038717A1 WO 2021038717 A1 WO2021038717 A1 WO 2021038717A1 JP 2019033502 W JP2019033502 W JP 2019033502W WO 2021038717 A1 WO2021038717 A1 WO 2021038717A1
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Prior art keywords
input
plate
output
current collector
battery pack
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PCT/JP2019/033502
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French (fr)
Japanese (ja)
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英俊 山岡
雅俊 山岡
誠志 池田
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有限会社山岡
株式会社ニチダイ
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Priority to JP2019571074A priority Critical patent/JP6807494B1/en
Priority to PCT/JP2019/033502 priority patent/WO2021038717A1/en
Publication of WO2021038717A1 publication Critical patent/WO2021038717A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to an input / output structure of an assembled battery pack capable of improving conductivity and energizing a large current.
  • a single cell or a multi-cell single battery is connected to the battery output terminal in parallel or in series by resistance welding or the like with a thin connecting terminal plate so that the desired capacity can be output. It is a thing.
  • a structure having the performance of a resin spring is resin-molded integrally with a charger case, and a metal terminal (metal terminal) is formed on the resin spring. (Hereinafter referred to as a contact) is embedded, the positive electrode and the negative electrode of the battery are connected to each other, and the battery is held in the charger case by the pressure of the resin spring.
  • rechargeable battery packs have come to be used as a power source for so-called electric vehicles, industrial equipment, home appliances, and various other equipment.
  • the reason is that it is clean energy, saves space, can be used repeatedly by charging, is easy to handle, and is highly safe.
  • a rechargeable battery pack (hereinafter referred to as a rechargeable battery pack) is used as the power source, it can be charged and used repeatedly when the power drops, and the internal combustion engine can be used as opposed to the fuel type power source up to that point. Since it does not need to be installed separately, it can contribute to the miniaturization of equipment, and has the advantage of low risk of fuel storage and handling.
  • the difference between the rechargeable battery pack and the replaceable battery pack is that the batteries themselves are rechargeable and different, of course, but with the adoption of rechargeable batteries, multiple rechargeable batteries are stored. This means that the case will not be opened or closed to replace the battery.
  • the power input / output structure of the rechargeable battery pack is different from the configuration in which the terminal is made of a thin copper plate having high conductivity as in Patent Document 1 above, and the power input / output structure is a single and thin plate, for example, a pure nickel plate.
  • a tab-shaped contact piece corresponding to the position of the rechargeable battery is formed, and this tab is welded to the terminal of the battery.
  • the reason for using a pure nickel plate is that it is resistant to corrosion and has high conductivity, welding with the terminal material of the rechargeable battery is good in terms of material compatibility, and the reason for thinning it with one sheet is the material of the pure nickel plate.
  • the unit price is high, but if it is composed of only one thin pure nickel plate, the welding with the terminal of the rechargeable battery may peel off even if it is welded no matter how much it is welded when bending occurs, and a large current This is because the nickel plate itself generates heat due to the intrinsic resistance of the nickel plate at the time of taking out, and a vicious cycle occurs in which the intrinsic resistance becomes higher due to self-heating.
  • the surface of the pure nickel plate on the side opposite to the side facing the rechargeable battery has more inherent resistance than nickel for the purpose of ensuring rigidity and forming an electrical input / output circuit.
  • a low constant thickness copper plate is provided.
  • the copper plate and the pure nickel plate are laminated, that is, in contact with each other, but conventionally, the copper plate and the pure nickel plate are integrated by laser welding in the vicinity of each contact piece (the molten state of the laser irradiation part).
  • the laser welded part a circuit was formed in which a pure nickel plate and a copper plate were electrically connected.
  • the laser-welded portion is in a conductive state when the pure nickel plate and the copper plate are melted and surely contact each other.
  • the other parts are only in contact with each other in a state of extremely low conductivity, the circuit from the pure nickel plate to the copper plate is only the laser-welded part as described above.
  • the circuit from the pure nickel plate to the copper plate is only laser-welded means that a circuit with a high resistance value of the current-carrying path is formed. Therefore, the conventional input / output structure is laser-welded. There is a problem that the portion generates heat, an output loss occurs during discharging, and only a current lower than the theoretical value can be output, and an input loss also occurs during charging, which takes time.
  • the problem to be solved by the present invention is that the pure nickel plate and the copper plate are partially joined by laser welding in the input / output structure of the conventional assembled battery pack, and this connection portion becomes a resistance. This causes heat generation, and output loss occurs during discharge, so that only a current lower than the theoretical value can be output. On the other hand, input loss occurs during charging, which takes time.
  • the input / output structure of the assembled battery pack of the present invention is a current collector plate provided in a case containing a plurality of batteries and formed with a current collector portion electrically connected to the positive electrode or negative electrode terminals of each of the plurality of batteries.
  • the main feature of this current collector plate is that the side facing the battery and the input / output plate provided on the opposite surface are surface-bonded.
  • a current collecting portion connected to the positive electrode or negative electrode terminal of each of the plurality of batteries is formed on the current collector plate, and the current collector plate is provided with a current collecting portion.
  • the main feature is that the input / output plates are laminated on the surface opposite to the side on which the battery is arranged, and the current collector plate and the input / output plate are laminated and then sintered and surface-bonded. Is
  • the current collector plate and the input / output plate are surface-bonded to increase the conductive area, so that the conductivity is improved and a large current can be energized.
  • An object of the present invention is to suppress at least output loss in an assembled battery pack.
  • the purpose of this is to form a current collector plate that forms a current collector portion that is electrically connected to the terminals of the positive electrode or the negative electrode of each of the plurality of batteries, and an input that is provided on the opposite surface of the current collector plate from the side facing the battery. This was achieved by surface-joining the output plate.
  • so-called pure nickel which is an alloy having excellent corrosion resistance in a wide range of corrosive environments and having high conductivity in the nickel group, for the current collector plate.
  • a nickel plate or other conductive metal may be used.
  • the thickness of the current collector plate is 0.1 to 0.2 mm. If it is thicker than 0.2 mm, it becomes difficult to melt at the joint surface, which is an advantage of resistance welding, and it is necessary to set a large melting current value, which damages the battery terminals due to the large current and causes serious problems such as liquid leakage. It can be a factor to cause it. On the other hand, if it is thinner than 0.1 mm, the current collecting efficiency deteriorates, and when a rechargeable battery is used as the battery, it becomes difficult to weld the rechargeable battery to the terminal.
  • the thickness is 0.5 to 2.0 mm. If it is thinner than 0.5 mm, rigidity may not be ensured. In addition, if it is thicker than 2.0 mm, it becomes unnecessarily thick and wasteful, and the assembled battery pack becomes heavy, which not only increases the cost but also deteriorates the performance of the assembled battery pack due to this increased weight (high). It can be a load).
  • the input / output structure of the assembled battery pack forms the method of the present invention, that is, a current collecting portion connected to the positive electrode or negative electrode terminal of each of the plurality of batteries is formed on the current collecting plate, and the battery of the current collecting plate is formed. It is manufactured by laminating an input / output plate on a surface opposite to the side on which the current collector plate is arranged, and sintering and surface-bonding the current collector plate and the input / output plate in a laminated state.
  • the sintering temperature is set in the sintering furnace. It is held at a temperature of about 90% of the melting point of the material of the input / output plate for a certain period of time, and then rapidly cooled.
  • the current collector plate and the input / output plate are joined in terms of both physical and electrical surfaces, and thus the conductive area increases. As a result, the current-carrying path becomes low resistance, and when a rechargeable battery is used as the battery, input / output loss can be suppressed.
  • the input / output structure of the assembled battery pack (hereinafter referred to as the input / output structure) is the following provided on the inner surfaces of the positive electrode and the negative electrode of each rechargeable battery B in the case 2 for accommodating the plurality of rechargeable batteries B in the assembled battery pack 1. Means the structure of.
  • a current collecting portion 3a electrically connected to each terminal of the positive electrode and the negative electrode of each rechargeable battery B is formed.
  • a current collecting plate 3 made of pure nickel and having a thickness of 0.15 mm.
  • an input / output plate 4 made of copper and having a thickness of 1.0 mm, which is provided on the surface of the current collector plate 3 opposite to the side facing the rechargeable battery B, is surface-bonded.
  • the current collecting portion 3a of the current collecting plate 3 may be formed so that the current collecting portion 3a remains integrally from the current collecting plate 3, for example, by punching, and the shape of the current collecting portion 3a is as follows.
  • the shape may be such that welding with the rechargeable battery B is easy and reliable.
  • the current collecting portion 3a is slightly folded back to the side opposite to the input / output plate 4 side before sintering with the input / output plate 4. By doing so, the current collecting portion 3a is not integrated with the input / output plate 4, and can be freely bent and adjusted to the rechargeable battery B side.
  • the input / output plate 4 has nickel-plated layers 4a and 4b formed on both sides of the side laminated on the current collector plate 3 and the opposite side thereof, respectively. The reason for this is that the input / output plate 4 is prevented from being oxidized.
  • the nickel-plated layer 4a on the side of the input / output plate 4 to be laminated on the current collector plate 3 is sintered in the materials of the current collector plate 3 and the input / output plate 4 when the current collector plate 3 is sintered. Be integrated.
  • the input / output structure of the present invention having the above configuration is manufactured as follows. As shown in FIG. 2A, a current collecting portion 3a connected to the terminals of the positive electrode or the negative electrode of each of the plurality of rechargeable batteries B is formed on the current collecting plate 3, and for example, in the case of this example, the current collecting portion 3a is formed.
  • the input / output plates 4 were slightly folded back to the side opposite to the side on which the input / output plates 4 were laminated, and the nickel-plated layers 4a and 4b were applied to the surface of the current collector plate 3 opposite to the side on which the rechargeable battery B was arranged as described above.
  • the input / output plates 4 are laminated, and at this time, in a state where the current collector plate 3 and the input / output plate 4 are laminated, they are sintered under the following conditions and the butted laminated surfaces are surface-bonded.
  • the sintering conditions are, for example, when the thickness of each of the current collector plate 3 and the input / output 4 is in the above range, the temperature is about 90% of the melting point of the material of the input / output 4 in the sintering furnace. It may be done under the condition that it is held for a certain period of time and then rapidly cooled.
  • a sintered layer 5 in which the current collector plate 3 and the nickel-plated layer 4a of the input / output plate 4 laminated and abutted are integrated by sintering appears.
  • the sintered layer 5 serves as a conductive surface between the current collector plate 3 and the input / output plate 4.
  • the input / output structure of the present invention electrically and physically connects each of the current collecting portions 3a and the respective connection terminals of the plurality of rechargeable batteries B, for example, by welding. Put it in case 2. In this way, the assembled battery pack 1 is completed.
  • Joining method Laser welding / "Total area" of current collector plate 3: 11900 mm 2 -"Matching area" between the current collector plate 3 and the input / output plate 4: 8284 mm 2 ⁇ "Joining area”: ⁇ 1mm x 15 points at 30 places Joining area 450mm 2 -Ratio of joint area to butt area: Approximately 5.4% (Approximately 3.8% of total area)
  • the present invention has a maximum since about 8200Mm 2 by sintering respect 8284Mm 2 of butting area in surface bonding, energizable area (current path) is next theory 99.0%, substantially from the rechargeable battery B Since the current value of the limit could be taken out and it did not lead to an increase in the resistance of the energization path, no loss occurred as heat (no heat was generated at the abutting surface of the current collector plate 3 and the input / output plate 4). ..
  • the present invention has improved conductivity and can be energized with a large current. Further, according to the present invention, since sintering is performed in a sintering furnace, there is an advantage that a large amount of input / output structures can be manufactured with high quality. Further, in the present invention, since the current collector plate 3 and the input / output plate 4 are firmly integrated by sintering, troubles such as (laser) welding failure or peeling of the laser welded portion due to vibration or the like as in the conventional case. Will not occur.
  • the input / output plate 4 is a single plate. Since the portion corresponding to the electric portion 3a is not sintered, the input / output plate 4 may have a configuration in which a hole surrounding the current collecting portion 3a is formed.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

Provided is an input/output structure of an assembled battery pack capable of achieving improved conductance and conduction of a large current. The input/output structure of an assembled battery pack 1 according to the present invention is formed by the face-to-face bonding of a current collector plate 3, which has formed thereon current-collecting parts 3a to be electrically connected to positive electrodes or negative electrodes of a plurality of rechargeable batteries B disposed inside a case 2 accommodating the plurality of rechargeable batteries B, with an input/output plate 4 disposed on the opposite surface of the current collector plate 3 from the side facing the rechargeable batteries B. As a result of this structure, because almost the entire abutment area between the current collector plate 3 and the input/output plate 4 forms an electrical conduction path, a resistance value is extremely low and there is no loss due to generation of heat.

Description

組電池パックの入出力構造とその製造方法Input / output structure of assembled battery pack and its manufacturing method
 本発明は、導電率が向上し、かつ大電流通電が可能な組電池パックの入出力構造に関する。 The present invention relates to an input / output structure of an assembled battery pack capable of improving conductivity and energizing a large current.
 従来、大容量の電力を要する場合、もちろんその電力を出力する電池を製作すればよいが、製作コストなどの観点で、例えば既存のサイズ及び出力の電池(繰り返し使う場合は充電池)を多数筐体に収納したいわゆる組電池パックが用いられる。 Conventionally, when a large amount of electric power is required, of course, a battery that outputs the electric power may be manufactured. However, from the viewpoint of manufacturing cost, for example, a large number of batteries of existing size and output (rechargeable battery in the case of repeated use) are used. A so-called assembled battery pack stored in the body is used.
 組電池パックは、単セル又は複数セルの単電池を薄板の連絡端子板にて、並列又は直列に電池出力端子に抵抗溶接等で接続を行い、希望の容量を出力することができるようにしたものである。 In the assembled battery pack, a single cell or a multi-cell single battery is connected to the battery output terminal in parallel or in series by resistance welding or the like with a thin connecting terminal plate so that the desired capacity can be output. It is a thing.
 具体的には、例えば特許文献1の図4を参照した従来例に示されるように、樹脂スプリングの性能を保有する構造を、充電器ケースと一体に樹脂成型し、その樹脂スプリングに金属端子(以下、接点という)を埋め込み、電池の正極及び負極をそれぞれ接続すると共に、樹脂スプリングの圧力によって、電池を充電器ケース内に保持した構成である。 Specifically, for example, as shown in a conventional example with reference to FIG. 4 of Patent Document 1, a structure having the performance of a resin spring is resin-molded integrally with a charger case, and a metal terminal (metal terminal) is formed on the resin spring. (Hereinafter referred to as a contact) is embedded, the positive electrode and the negative electrode of the battery are connected to each other, and the battery is held in the charger case by the pressure of the resin spring.
 近年、いわゆる電気自動車、産業機器、家電、様々な機器の動力源として充電型の組電池パックが用いられるようになってきている。その理由はクリーンなエネルギーで省スペース、充電により繰り返しの使用が可能で取り扱い簡単かつ安全性が高いためである。 In recent years, rechargeable battery packs have come to be used as a power source for so-called electric vehicles, industrial equipment, home appliances, and various other equipment. The reason is that it is clean energy, saves space, can be used repeatedly by charging, is easy to handle, and is highly safe.
 充電池を用いた組電池パック(以下、充電型組電池パックという)を動力源とすれば、電力が低下すれば充電して繰り返し使え、それまでの燃料型の動力源に対し、内燃機関を別途設ける必要がないので機器の小型化に貢献でき、燃料の保管や取扱の危険度が低という利点がある。 If a rechargeable battery pack (hereinafter referred to as a rechargeable battery pack) is used as the power source, it can be charged and used repeatedly when the power drops, and the internal combustion engine can be used as opposed to the fuel type power source up to that point. Since it does not need to be installed separately, it can contribute to the miniaturization of equipment, and has the advantage of low risk of fuel storage and handling.
 充電型組電池パックが電池取替型の組電池パックと異なる点は、電池自体が充電可不可で異なることはもちろんであるが、充電池を採用することに伴って該充電池を複数収納したケースを電池交換のために開閉することがないということである。 The difference between the rechargeable battery pack and the replaceable battery pack is that the batteries themselves are rechargeable and different, of course, but with the adoption of rechargeable batteries, multiple rechargeable batteries are stored. This means that the case will not be opened or closed to replace the battery.
 それゆえ、充電型電池パックの電力の入出力構造は、上記特許文献1のように導電性の高い銅の薄板でなる端子と単に接触する構成とは異なり、一枚のそして薄い例えば純ニッケル板に充電池配置位置に対応したタブ状の接点片を形成し、このタブを電池の端子と溶接する構成となっている。 Therefore, the power input / output structure of the rechargeable battery pack is different from the configuration in which the terminal is made of a thin copper plate having high conductivity as in Patent Document 1 above, and the power input / output structure is a single and thin plate, for example, a pure nickel plate. A tab-shaped contact piece corresponding to the position of the rechargeable battery is formed, and this tab is welded to the terminal of the battery.
 純ニッケル板を使う理由は腐食に強いと共に導電率も高く、充電池の端子材料との溶接が材料の相性において良好であること、また、一枚で薄くしている理由は純ニッケル板の材料単価が高いこと、であるが、一枚の薄い純ニッケル板だけで構成すると、撓みが発生するといくら溶接していたとしても充電池の端子との溶接が剥離する可能性あると共に、大電流の取り出し時にニッケル板の固有抵抗でニッケル板自体が発熱し、自己発熱により一層固有抵抗が高くなるという悪循環が生じるためである。 The reason for using a pure nickel plate is that it is resistant to corrosion and has high conductivity, welding with the terminal material of the rechargeable battery is good in terms of material compatibility, and the reason for thinning it with one sheet is the material of the pure nickel plate. The unit price is high, but if it is composed of only one thin pure nickel plate, the welding with the terminal of the rechargeable battery may peel off even if it is welded no matter how much it is welded when bending occurs, and a large current This is because the nickel plate itself generates heat due to the intrinsic resistance of the nickel plate at the time of taking out, and a vicious cycle occurs in which the intrinsic resistance becomes higher due to self-heating.
 上記不具合解消のために、純ニッケル板において充電池に面する側の反対側の面に、剛性を確保することと電気的な入出力回路を形成することを目的としたニッケルよりも固有抵抗の低い一定厚みの銅板を設けている。 In order to solve the above problems, the surface of the pure nickel plate on the side opposite to the side facing the rechargeable battery has more inherent resistance than nickel for the purpose of ensuring rigidity and forming an electrical input / output circuit. A low constant thickness copper plate is provided.
 銅板と純ニッケル板とは積層されて、つまり接触させているが、従来、この銅板と純ニッケル板とは、各接点片の近傍をレーザー溶接することで一体(レーザー照射箇所の溶融状態)とされ、レーザー溶接部分において純ニッケル板と銅板とを電気的に接続した回路を構成していた。 The copper plate and the pure nickel plate are laminated, that is, in contact with each other, but conventionally, the copper plate and the pure nickel plate are integrated by laser welding in the vicinity of each contact piece (the molten state of the laser irradiation part). In the laser welded part, a circuit was formed in which a pure nickel plate and a copper plate were electrically connected.
 上記、従来において、純ニッケル板と銅板とを部分的にレーザー溶接により一体としていた理由は、銅は固有抵抗が低く生産コストの安い抵抗溶接での接合が不安定で困難なためである。 In the past, the reason why the pure nickel plate and the copper plate were partially integrated by laser welding is that copper has low intrinsic resistance and it is difficult to join by resistance welding, which has a low production cost.
 しかしながら、従来の純ニッケル板と銅板とを部分的にレーザー溶接により一体とする手法であると、レーザー溶接された部分は、純ニッケル板と銅板とが溶融して確実に接触して導電状態となるが、それ以外の部分は導電性が極めて低い状態で接触しているだけなので、純ニッケル板から銅板に至る回路としては前記のとおりレーザー溶接された部分だけとなる。 However, in the conventional method of partially integrating the pure nickel plate and the copper plate by laser welding, the laser-welded portion is in a conductive state when the pure nickel plate and the copper plate are melted and surely contact each other. However, since the other parts are only in contact with each other in a state of extremely low conductivity, the circuit from the pure nickel plate to the copper plate is only the laser-welded part as described above.
 そして、純ニッケル板から銅板に至る回路がレーザー溶接された部分のみと言うことは、通電経路の抵抗値が高い回路が形成されていることであり、よって、従来の入出力構造は、レーザー溶接部分が発熱して、放電時には出力ロスが生じて理論値より低い電流しか出力できないこととなると共に充電時には同じく入力ロスが生じて時間がかかるという問題があった。 The fact that the circuit from the pure nickel plate to the copper plate is only laser-welded means that a circuit with a high resistance value of the current-carrying path is formed. Therefore, the conventional input / output structure is laser-welded. There is a problem that the portion generates heat, an output loss occurs during discharging, and only a current lower than the theoretical value can be output, and an input loss also occurs during charging, which takes time.
実用新案登録第3096247号公報(図4)Utility Model Registration No. 3096247 (Fig. 4)
 本発明が解決しようとする問題は、従来の組電池パックの入出力構造おいて純ニッケル板と銅版とをレーザー溶接にて部分的に接合したことに起因して、この接続部分が抵抗となって発熱し、放電時には出力ロスが生じて理論値より低い電流しか出力できないこととなる一方で、充電時には入力ロスが生じて時間がかかるという点、である。 The problem to be solved by the present invention is that the pure nickel plate and the copper plate are partially joined by laser welding in the input / output structure of the conventional assembled battery pack, and this connection portion becomes a resistance. This causes heat generation, and output loss occurs during discharge, so that only a current lower than the theoretical value can be output. On the other hand, input loss occurs during charging, which takes time.
 本発明の組電池パックの入出力構造は、複数の電池を収納したケース内に設けられる、複数の電池の各々の正極又は負極の端子に電気的に接続する集電部位を形成した集電板と、この集電板における電池に臨む側と反対面に設けた入出力板とを面接合してなることを主要な特徴としている。また、本発明は、上記の組電池パックの入出力構造を得るために、集電板に複数の電池の各々の正極又は負極の端子に接続する集電部位を形成し、前記集電板の電池が配置される側とは反対側の面に入出力板を積層し、前記集電板と前記入出力板とを積層した状態でこれらを焼結して面接合することを主要な特徴としている The input / output structure of the assembled battery pack of the present invention is a current collector plate provided in a case containing a plurality of batteries and formed with a current collector portion electrically connected to the positive electrode or negative electrode terminals of each of the plurality of batteries. The main feature of this current collector plate is that the side facing the battery and the input / output plate provided on the opposite surface are surface-bonded. Further, in the present invention, in order to obtain the input / output structure of the assembled battery pack, a current collecting portion connected to the positive electrode or negative electrode terminal of each of the plurality of batteries is formed on the current collector plate, and the current collector plate is provided with a current collecting portion. The main feature is that the input / output plates are laminated on the surface opposite to the side on which the battery is arranged, and the current collector plate and the input / output plate are laminated and then sintered and surface-bonded. Is
 本発明では、集電板と入出力板とが面接合されて導電面積が増加することで、導電率が向上し、かつ大電流通電が可能となる。 In the present invention, the current collector plate and the input / output plate are surface-bonded to increase the conductive area, so that the conductivity is improved and a large current can be energized.
本発明の組電池パックの入出力構造を示す分解斜視図である。It is an exploded perspective view which shows the input / output structure of the assembled battery pack of this invention. (a)(b)は本発明の組電池パックの入出力構造を示す分解斜視図である。(A) and (b) are exploded perspective views showing the input / output structure of the assembled battery pack of the present invention.
 本発明の目的は、組電池パックにおいて少なくとも出力のロスを抑制することにある。そして、この目的は、複数の電池の各々の正極又は負極の端子に電気的に接続する集電部位を形成した集電板と、この集電板における電池に臨む側と反対面に設けた入出力板と、を面接合することで達成した。 An object of the present invention is to suppress at least output loss in an assembled battery pack. The purpose of this is to form a current collector plate that forms a current collector portion that is electrically connected to the terminals of the positive electrode or the negative electrode of each of the plurality of batteries, and an input that is provided on the opposite surface of the current collector plate from the side facing the battery. This was achieved by surface-joining the output plate.
 なお、本発明において、集電板にはニッケル基において広範囲な腐食環境に対して優れた耐食性を有し、かつ導電性の高い合金であるいわゆる純ニッケルを採用することが望ましい。なお、コスト面を考慮するとニッケル板や他の導電金属を採用しても構わない。 In the present invention, it is desirable to use so-called pure nickel, which is an alloy having excellent corrosion resistance in a wide range of corrosive environments and having high conductivity in the nickel group, for the current collector plate. In consideration of cost, a nickel plate or other conductive metal may be used.
 また、集電板の厚みは、0.1~0.2mmとすることが望ましい。0.2mmより厚くなると、抵抗溶接の長所である接合面での溶融が困難となり、溶融電流値を大きく設定する必要があり、大電流によって電池端子にダメージを与え、液漏れ等重大な不具合を起こす要因となる可能性がある。一方、0.1mmより薄くすると、集電効率が悪くなる他、電池として充電池を採用した場合、該充電池の端子への溶接が困難となる。 Further, it is desirable that the thickness of the current collector plate is 0.1 to 0.2 mm. If it is thicker than 0.2 mm, it becomes difficult to melt at the joint surface, which is an advantage of resistance welding, and it is necessary to set a large melting current value, which damages the battery terminals due to the large current and causes serious problems such as liquid leakage. It can be a factor to cause it. On the other hand, if it is thinner than 0.1 mm, the current collecting efficiency deteriorates, and when a rechargeable battery is used as the battery, it becomes difficult to weld the rechargeable battery to the terminal.
 一方、入出力板は、銅を採用することが望ましい。入出力板として銅を採用するとした場合、厚みが0.5~2.0mmとすることが望ましい。0.5mmより薄くなると剛性を確保できない可能性がある。また、2.0mmより厚くなると不必要に厚くなって無駄となると共に、組電池パックが重くなり、コストアップとなるばかりか、この増加重量に起因して組電池パックのパフォーマンスも低下する(高負荷となる)可能性がある。 On the other hand, it is desirable to use copper for the input / output plate. When copper is used as the input / output plate, it is desirable that the thickness is 0.5 to 2.0 mm. If it is thinner than 0.5 mm, rigidity may not be ensured. In addition, if it is thicker than 2.0 mm, it becomes unnecessarily thick and wasteful, and the assembled battery pack becomes heavy, which not only increases the cost but also deteriorates the performance of the assembled battery pack due to this increased weight (high). It can be a load).
 上記の組電池パックの入出力構造は、本発明の方法、すなわち、集電板に複数の電池の各々の正極又は負極の端子に接続する集電部位を形成し、前記集電板の電池が配置される側とは反対側の面に入出力板を積層し、前記集電板と前記入出力板とを積層した状態でこれらを焼結して面接合することで製造する。 The input / output structure of the assembled battery pack forms the method of the present invention, that is, a current collecting portion connected to the positive electrode or negative electrode terminal of each of the plurality of batteries is formed on the current collecting plate, and the battery of the current collecting plate is formed. It is manufactured by laminating an input / output plate on a surface opposite to the side on which the current collector plate is arranged, and sintering and surface-bonding the current collector plate and the input / output plate in a laminated state.
 上記において、集電板と入出力板との焼結は、集電板を純ニッケル、入出力板を銅、として各々の板厚が上記範囲のとき、焼結炉にて、焼結温度が入出力板の材料の融点の9割程度の温度で一定時間保持し、後に急冷する、といった手法で行われる。 In the above, in the sintering of the current collector plate and the input / output plate, when the current collector plate is pure nickel and the input / output plate is copper and the respective plate thicknesses are in the above range, the sintering temperature is set in the sintering furnace. It is held at a temperature of about 90% of the melting point of the material of the input / output plate for a certain period of time, and then rapidly cooled.
 このように、集電板と入出力板とを焼結により一体とすることで、溶接と異なり、物理的にも電気的にも面的に接合されることとなり、よって、導電面積が増加して通電経路が低抵抗となり、電池として充電池を採用した場合には入出力のロスを抑制することができるようになる。 By integrating the current collector plate and the input / output plate by sintering in this way, unlike welding, the current collector plate and the input / output plate are joined in terms of both physical and electrical surfaces, and thus the conductive area increases. As a result, the current-carrying path becomes low resistance, and when a rechargeable battery is used as the battery, input / output loss can be suppressed.
 以下、本発明の一実施例について図1及び図2を用いて説明する。本例では、電池として例えば充放電自在な充電池Bを用いた構成で説明する。組電池パックの入出力構造(以下、入出力構造という)は、組電池パック1内の複数の充電池Bを収納するケース2における各々の充電池Bの正極と負極の内面に設けられた次の構造を意味する。 Hereinafter, an embodiment of the present invention will be described with reference to FIGS. 1 and 2. In this example, a configuration using, for example, a rechargeable battery B that can be charged and discharged as the battery will be described. The input / output structure of the assembled battery pack (hereinafter referred to as the input / output structure) is the following provided on the inner surfaces of the positive electrode and the negative electrode of each rechargeable battery B in the case 2 for accommodating the plurality of rechargeable batteries B in the assembled battery pack 1. Means the structure of.
 すなわち、入出力構造は、各々の充電池Bの正極と負極のそれぞれの端子に電気的に接続する集電部位3aを形成した例えば本例では純ニッケルでなる厚み0.15mmの集電板3と、この集電板3における充電池Bに臨む側と反対面に設けた例えば本例では銅でなる厚み1.0mmの入出力板4と、を面接合してなる。 That is, in the input / output structure, a current collecting portion 3a electrically connected to each terminal of the positive electrode and the negative electrode of each rechargeable battery B is formed. For example, in this example, a current collecting plate 3 made of pure nickel and having a thickness of 0.15 mm. And, for example, in this example, an input / output plate 4 made of copper and having a thickness of 1.0 mm, which is provided on the surface of the current collector plate 3 opposite to the side facing the rechargeable battery B, is surface-bonded.
 集電板3における集電部位3aは、図示するように、例えば打ち抜き加工により該集電板3から集電部位3aが一体的に残るように形成すればよく、集電部位3aの形状は、充電池Bとの溶接が容易かつ確実となるような形状とすればよい。 As shown in the figure, the current collecting portion 3a of the current collecting plate 3 may be formed so that the current collecting portion 3a remains integrally from the current collecting plate 3, for example, by punching, and the shape of the current collecting portion 3a is as follows. The shape may be such that welding with the rechargeable battery B is easy and reliable.
 なお、集電部位3aは、入出力板4との焼結の前に、該入出力板4側と反対側へ若干折り返しておく。こうすることで集電部位3aが入出力板4と一体化せず、充電池B側に自由に折り曲げ調整可能となる。 The current collecting portion 3a is slightly folded back to the side opposite to the input / output plate 4 side before sintering with the input / output plate 4. By doing so, the current collecting portion 3a is not integrated with the input / output plate 4, and can be freely bent and adjusted to the rechargeable battery B side.
 入出力板4は、集電板3に積層される側と、この反対側と、の両面に各々ニッケルメッキ層4a,4bが形成されている。この理由は、入出力板4の酸化防止となるためである。なお、入出力板4における集電板3に積層される側のニッケルメッキ層4aは、該集電板3と焼結される際に集電板3と入出力板4の材料において焼結により一体化される。 The input / output plate 4 has nickel-plated layers 4a and 4b formed on both sides of the side laminated on the current collector plate 3 and the opposite side thereof, respectively. The reason for this is that the input / output plate 4 is prevented from being oxidized. The nickel-plated layer 4a on the side of the input / output plate 4 to be laminated on the current collector plate 3 is sintered in the materials of the current collector plate 3 and the input / output plate 4 when the current collector plate 3 is sintered. Be integrated.
 上記構成の本発明の入出力構造は、次のようにして製造される。図2(a)に示すように、集電板3に複数の充電池Bの各々の正極又は負極の端子に接続する集電部位3aを形成し、例えば本例の場合は集電部位3aを入出力板4が積層される側と反対側へ若干だけ折り返し、集電板3の充電池Bが配置される側とは反対側の面に上記のとおりニッケルメッキ層4a,4bが施された入出力板4を積層し、このとき、集電板3と入出力板4とを積層した状態で以下の条件で焼結して突き合せた積層面を面的に接合する。 The input / output structure of the present invention having the above configuration is manufactured as follows. As shown in FIG. 2A, a current collecting portion 3a connected to the terminals of the positive electrode or the negative electrode of each of the plurality of rechargeable batteries B is formed on the current collecting plate 3, and for example, in the case of this example, the current collecting portion 3a is formed. The input / output plates 4 were slightly folded back to the side opposite to the side on which the input / output plates 4 were laminated, and the nickel-plated layers 4a and 4b were applied to the surface of the current collector plate 3 opposite to the side on which the rechargeable battery B was arranged as described above. The input / output plates 4 are laminated, and at this time, in a state where the current collector plate 3 and the input / output plate 4 are laminated, they are sintered under the following conditions and the butted laminated surfaces are surface-bonded.
 焼結条件は、本例においては、例えば、集電板3及び入出力4のそれぞれの板厚が上記範囲のとき、焼結炉にて、入出力4の材料の融点の9割程度の温度で一定時間保持し、後に急冷する、といったといった条件で行えばよい。これにより、図2(b)に示すように、集電板3と積層されて突き合された入出力板4のニッケルメッキ層4aとが焼結にて一体となった焼結層5が現れ、この焼結層5が集電板3と入出力板4との導電面となる。 In this example, the sintering conditions are, for example, when the thickness of each of the current collector plate 3 and the input / output 4 is in the above range, the temperature is about 90% of the melting point of the material of the input / output 4 in the sintering furnace. It may be done under the condition that it is held for a certain period of time and then rapidly cooled. As a result, as shown in FIG. 2B, a sintered layer 5 in which the current collector plate 3 and the nickel-plated layer 4a of the input / output plate 4 laminated and abutted are integrated by sintering appears. The sintered layer 5 serves as a conductive surface between the current collector plate 3 and the input / output plate 4.
 上記の後、本発明の入出力構造は、本例では、集電部位3a各々と複数の充電池Bのそれぞれの接続端子を、必要に応じて例えば溶接により電気的かつ物理的に接続し、ケース2へ納める。こうして組電池パック1が完成することとなる。 After the above, in this example, the input / output structure of the present invention electrically and physically connects each of the current collecting portions 3a and the respective connection terminals of the plurality of rechargeable batteries B, for example, by welding. Put it in case 2. In this way, the assembled battery pack 1 is completed.
 続いて、本発明の入出力構造の効果、すなわち導電効率について行った試験結果を説明する。以下の導電効率では、充電池B、集電板3及び入出力板4の材料、寸法を同じ条件とした入出力構造において、集電板3と入出力板4の接合条件だけを異ならせて、つまり通電可能面積を異ならせて、この通電可能面積を通電経路の理論上の最大値として各々を評価した。 Next, the test results of the effect of the input / output structure of the present invention, that is, the conductive efficiency will be described. In the following conductivity efficiencies, in the input / output structure in which the materials and dimensions of the rechargeable battery B, the current collector plate 3 and the input / output plate 4 are the same, only the joining conditions of the current collector plate 3 and the input / output plate 4 are different. That is, the energizable areas were different, and each was evaluated with this energable area as the theoretical maximum value of the energization path.
(従来例)接合手法:レーザー溶接
・集電板3の「総面積」:11900mm2
・集電板3と入出力板4との「突合面積」:8284mm2
・「接合面積」:φ1mm×15点を30カ所 接合面積450mm2
・突合面積に対する接合面積の割合:約5.4%(総面積に対しては約3.8%)
(Conventional example) Joining method: Laser welding / "Total area" of current collector plate 3: 11900 mm 2
-"Matching area" between the current collector plate 3 and the input / output plate 4: 8284 mm 2
・ "Joining area": φ1mm x 15 points at 30 places Joining area 450mm 2
-Ratio of joint area to butt area: Approximately 5.4% (Approximately 3.8% of total area)
(本発明)接合手法:焼結
・集電板3の「総面積」:11900mm2
・集電板3と入出力板4との「突合面積」:8284mm2
・「接合面積」:約8200mm2
・突合面積に対する接合面積の割合:約99.0%(総面積に対しては約69.0%)
(Invention) Joining method: "Total area" of sintered / current collector plate 3: 11900 mm 2
-"Matching area" between the current collector plate 3 and the input / output plate 4: 8284 mm 2
・ "Joining area": Approximately 8200 mm 2
-Ratio of joint area to butt area: about 99.0% (about 69.0% of total area)
 以上の結果から、従来例では、そもそも突合面積が8284mm2 存在するにも拘わらず、レーザー溶接により450mm2 しか接合していないので、通電可能面積(通電経路)は理論上5.4%しかなく、通電経路が限られているので、その分が抵抗となり、熱としてロスが生じ、通電経路の抵抗が上昇することとなった(集電板3と入出力板4との溶接部が発熱した)。 These results, in the conventional example, the first place the butting area despite the presence 8284Mm 2, since no 450 mm 2 only joined by laser welding, energizable area (current path) is only theoretically 5.4% Since the energization path is limited, that amount becomes resistance, loss occurs as heat, and the resistance of the energization path increases (the welded part between the current collector plate 3 and the input / output plate 4 generates heat. ).
 一方、本発明は、突合面積の8284mm2 に対して焼結により約8200mm2 が面接合しているので、通電可能面積(通電経路)は理論上99.0%となり、充電池Bからほぼ最大限の電流値が取り出せ、通電経路の抵抗上昇にはつながらなかったことから、熱としてロスが生じることがなかった(集電板3と入出力板4の突合面での発熱は生じなかった)。 On the other hand, the present invention has a maximum since about 8200Mm 2 by sintering respect 8284Mm 2 of butting area in surface bonding, energizable area (current path) is next theory 99.0%, substantially from the rechargeable battery B Since the current value of the limit could be taken out and it did not lead to an increase in the resistance of the energization path, no loss occurred as heat (no heat was generated at the abutting surface of the current collector plate 3 and the input / output plate 4). ..
 以上のことから、本発明は、導電率が向上し、かつ大電流通電が可能であることが判明した。また、本発明であれば、焼結炉にて焼結するので、高品質で多量の入出力構造を製作できるという利点もある。さらに、本発明は、焼結により集電板3と入出力板4とを強固に一体化しているので、従来のように(レーザー)溶接不良、あるいは振動等によるレーザー溶接部位の剥がれ等のトラブルが発生することはない。 From the above, it was found that the present invention has improved conductivity and can be energized with a large current. Further, according to the present invention, since sintering is performed in a sintering furnace, there is an advantage that a large amount of input / output structures can be manufactured with high quality. Further, in the present invention, since the current collector plate 3 and the input / output plate 4 are firmly integrated by sintering, troubles such as (laser) welding failure or peeling of the laser welded portion due to vibration or the like as in the conventional case. Will not occur.
 なお、本発明は、上記では充電池Bを採用した例を示したが、放電のみの通常の電池を採用しても構わないほか、上記では入出力板4に一枚板としているが、集電部位3aに対応する部位は焼結しないので、入出力板4において該集電部位3aを包囲される孔を形成した構成であってもよい。 In the present invention, an example in which the rechargeable battery B is adopted is shown above, but a normal battery that only discharges may be adopted, and in the above, the input / output plate 4 is a single plate. Since the portion corresponding to the electric portion 3a is not sintered, the input / output plate 4 may have a configuration in which a hole surrounding the current collecting portion 3a is formed.
 こうすれば、集電板3と入出力板4とを積層する際に、上記では集電部位3aを該入出力板の積層側と反対側へ折り返すようにしたが、この手間を省くことができ、重量削減と焼結時間の短縮化を図ることができると共に、集電部位3aと充電池Bの接続端子との溶接が、該孔を介して行えるので作業性が向上することとなる。 In this way, when the current collector plate 3 and the input / output plate 4 are laminated, the current collector portion 3a is folded back to the side opposite to the laminated side of the input / output plate, but this time and effort can be saved. This makes it possible to reduce the weight and the sintering time, and the workability is improved because the current collecting portion 3a and the connection terminal of the rechargeable battery B can be welded through the holes.
 1 組電池パック
 2 ケース
 3 集電板
  3a 集電部位
 4 入出力板
  4a,4b ニッケルメッキ層
 5 焼結層
 B 充電池
1 set battery pack 2 case 3 current collector plate 3a current collector part 4 input / output plate 4a, 4b nickel-plated layer 5 sintered layer B rechargeable battery

Claims (2)

  1.  複数の電池を収納したケース内に設けられる、複数の電池の各々の正極又は負極の端子に電気的に接続する集電部位を形成した集電板と、この集電板における電池に臨む側と反対面に設けた入出力板とを面接合してなることを特徴とする組電池パックの入出力構造。 A current collector plate provided in a case containing a plurality of batteries and formed with a current collector portion electrically connected to the positive electrode or negative electrode terminals of each of the plurality of batteries, and a side of the current collector plate facing the battery. The input / output structure of the assembled battery pack is characterized by being surface-bonded to the input / output plates provided on the opposite surfaces.
  2.  集電板に複数の電池の各々の正極又は負極の端子に接続する集電部位を形成し、前記集電板の電池が配置される側とは反対側の面に入出力板を積層し、前記集電板と前記入出力板とを積層した状態でこれらを焼結して面接合することを特徴とする組電池パックの入出力構造の製造方法。 A current collecting portion connected to the positive electrode or negative electrode terminal of each of the plurality of batteries is formed on the current collecting plate, and an input / output plate is laminated on the surface of the current collecting plate opposite to the side on which the battery is arranged. A method for manufacturing an input / output structure of an assembled battery pack, characterized in that the current collector plate and the input / output plate are laminated and then sintered and surface-bonded.
PCT/JP2019/033502 2019-08-27 2019-08-27 Input/output structure of assembled battery pack and manufacturing method therefor WO2021038717A1 (en)

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JP2006139987A (en) * 2004-11-11 2006-06-01 Hitachi Cable Ltd Plate-shaped wiring material for battery pack, and the battery pack
JP2013109934A (en) * 2011-11-21 2013-06-06 Sanyo Electric Co Ltd Battery pack
JP2013535784A (en) * 2010-09-07 2013-09-12 エルジー・ケム・リミテッド High power and large capacity battery pack

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JP2004265610A (en) * 2003-01-23 2004-09-24 Sony Corp Lead terminal and power supply device
JP2004311165A (en) * 2003-04-04 2004-11-04 Sony Corp Battery pack
JP2006139987A (en) * 2004-11-11 2006-06-01 Hitachi Cable Ltd Plate-shaped wiring material for battery pack, and the battery pack
JP2013535784A (en) * 2010-09-07 2013-09-12 エルジー・ケム・リミテッド High power and large capacity battery pack
JP2013109934A (en) * 2011-11-21 2013-06-06 Sanyo Electric Co Ltd Battery pack

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