WO2021007645A1 - A device for treating a bottom-hole formation wellbore - Google Patents
A device for treating a bottom-hole formation wellbore Download PDFInfo
- Publication number
- WO2021007645A1 WO2021007645A1 PCT/CA2019/050970 CA2019050970W WO2021007645A1 WO 2021007645 A1 WO2021007645 A1 WO 2021007645A1 CA 2019050970 W CA2019050970 W CA 2019050970W WO 2021007645 A1 WO2021007645 A1 WO 2021007645A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- chemical composition
- weight
- combustible chemical
- wellbore
- ammonium nitrate
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 239000000126 substance Substances 0.000 claims abstract description 28
- 239000006185 dispersion Substances 0.000 claims abstract description 15
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000010304 firing Methods 0.000 claims abstract description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000007789 sealing Methods 0.000 claims abstract description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 17
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 claims description 12
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- -1 polytetrafluoroethylene Polymers 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 230000035699 permeability Effects 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B37/00—Methods or apparatus for cleaning boreholes or wells
- E21B37/06—Methods or apparatus for cleaning boreholes or wells using chemical means for preventing or limiting, e.g. eliminating, the deposition of paraffins or like substances
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B36/00—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
- E21B36/008—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones using chemical heat generating means
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B37/00—Methods or apparatus for cleaning boreholes or wells
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B37/00—Methods or apparatus for cleaning boreholes or wells
- E21B37/08—Methods or apparatus for cleaning boreholes or wells cleaning in situ of down-hole filters, screens, e.g. casing perforations, or gravel packs
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/255—Methods for stimulating production including the injection of a gaseous medium as treatment fluid into the formation
Definitions
- the present invention relates to a device for treating a wellbore and, in particular, to a device which generates hydrochloric acid gas, hydrofluoric acid gas or a combination thereof to treat a bottom-hole of a wellbore.
- a decrease in the permeability of a bottom-hole formation of a wellbore may result in a decrease in hydrocarbon recovery.
- the decrease in the permeability of the bottom-hole formation may be the result of dilatation due to asphaltic deposits or volumetric readjustments of bore space structure.
- the decrease in the permeability of the bottom-hole formation may be the result of clogging from clay swelling or deposits of foreign matter such as mechanical impurities, filtrates, well knitting, drill-in fluids, well development fluids, and cement.
- Sand and paraffin-hydrate plugs are also known to cause a decrease in the permeability of the bottom-hole formation as are calcium carbonate scale, calcium sulfate scale, and other scale. It is therefore desirable to treat the bottom-hole formation of a wellbore to increase the permeability of a bottom-hole formation and increase hydrocarbon recovery.
- the device comprises a firing head and seal block assembly at a proximal end thereof and a bullnose assembly at a distal end thereof.
- a carrier tube extends between the firing head and seal block assembly and the bullnose assembly.
- the carrier tube contains a combustible chemical composition which generates hydrochloric acid gas or hydrofluoric acid gas or a combination thereof when combusted.
- a dispersion tube extends from the carrier tube.
- the dispersion tube has a lateral opening. The lateral opening may be a slot or an aperture.
- the combustible chemical composition may comprise between 30% and 60% by weight hexachloroethane and between 40% and 70% by weight ammonium nitrate.
- the combustible chemical composition may alternatively comprise between 30% and 60% by weight polyvinyl chloride and between 40% and 70% by weight ammonium nitrate.
- the combustible chemical composition may still alternatively comprise between 0% and 5% by weight polyvinyl chloride, between 25% and 55% by weight hexachloroethane, and between 40% and 70% by weight ammonium nitrate.
- the combustible chemical composition may still yet alternatively comprise between 5% and 25% by weight polytetrafluoroethylene, between 25% and 55% by weight hexachloroethane, and between 40% and 70% by weight ammonium nitrate.
- the combustible chemical composition may be disposed in a sleeve.
- the sleeve may be a polyvinyl chloride sleeve.
- the combustible chemical composition may include a plurality of solid puck shaped members.
- the combustible chemical composition may further include an adhesive binding adjacent ones of the solid puck shaped members.
- the combustible chemical composition may further include a combustion catalyst.
- Figure 1 is an elevation, partially sectional, view showing a device for treating a bottom-hole formation of a vertical wellbore
- Figure 2 is an exploded, perspective view of the device for treating a bottom- hole formation of a wellbore shown in Figure 1;
- Figure 3 is an elevation, fragmentary and partially sectional, view of the device for treating a bottom -hole formation of a wellbore shown in Figure 1;
- Figure 4 is an exploded, perspective view of another device for treating a bottom-hole formation of a wellbore.
- Figure 5 is an exploded, perspective view of still another device for treating a bottom-hole formation of a wellbore.
- a device 10 for treating a bottom-hole formation 12 of a wellbore 14 The device 10 is lowered into the wellbore 14 by a wireline 16 in this example. However, in other examples, coiled tubing or other suitable means may be employed to lower the device 10 into the wellbore 14.
- the wellbore 14 is cased with a perforated casing 18.
- the device 10 may also be employed to treat a wellbore provided with a slotted liner or an open hole wellbore.
- the device 10 may be deployed in a vertical wellbore or horizontal wellbore.
- the device may be deployed in a producing wellbore or an injection wellbore.
- the device 10 is shown in greater detail in Figure 2.
- the device 10 comprises a firing head and sealing block assembly 30 at a proximal end thereof and a bullnose assembly 32 at a distal end thereof.
- a proximal end of a spacer tube 34 is coupled to the firing head and sealing block assembly 30.
- a carrier tube 36 is coupled to a distal end of the spacer tube 34.
- a dispersion tube 38 is coupled to a distal end of the carrier tube 36.
- a distal end of the dispersion tube is coupled to the bullnose assembly 32.
- There is a plurality of openings in the dispersion tube 38 which, in this example, are in the form of slots 40a and 40b.
- the carrier tube 36 contains a combustible chemical composition which generates hydrochloric acid gas or hydrofluoric acid gas or a combination thereof when combusted.
- Figure 3 shows a combustible chemical composition 42 contained in the carrier tube 36.
- the combustible chemical composition 42 is contained in the carrier tube 36 and comprises a plurality of puck shaped members, for example, puck shaped member 44a and 44b which are fitted into the carrier tube 36.
- a charge wire 46 provides a charge to combust the combustible chemical composition 42 contained in the carrier tube 36.
- at least one of the puck shaped members is a combustion catalyst comprising epoxy resin, potassium dichromate, and ammonium nitrate.
- a combustion catalyst is not required, but any suitable combustion catalyst may be employed.
- Examples of the combustible chemical compositions are set out below. Examples 1-3 and 5-7 generate hydrochloric acid gas and examples 4 and 8 generate hydrochloric acid gas and hydrofluoric acid gas.
- Chlorinated polyvinyl 0% to 5%
- the device 10 may also be employed to treat a wellbore provided with a slotted liner or an open hole wellbore. It will also be understood by a person skilled in the art that the device 10 may be deployed in a vertical wellbore or horizontal wellbore. It will further be understood by a person skilled in the art that the device may be deployed in a producing wellbore or an injection wellbore. A perforating gun may be used with the device 10. Packers may also be employed to isolate the devices. [0019] Figure 4 shows another device 50 for treating a bottom -hole formation of a wellbore.
- the device 50 is substantially similar to the device shown in Figures 1 to 3 with the notable exception that the dispersion tube 52 has lateral openings in the form of apertures 54a and 54b.
- Figure 5 shows still another device 60 for treating a bottom-hole formation of a wellbore.
- the device 60 is substantially similar to the device shown in Figures 1 to 3 with the notable exception that there is no dispersion tube and the carrier tube 62 has lateral openings in the form of apertures 64a and 64b.
Landscapes
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Geochemistry & Mineralogy (AREA)
- Fluid Mechanics (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Incineration Of Waste (AREA)
- Fuel Cell (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Fire-Extinguishing Compositions (AREA)
- Drying Of Semiconductors (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA3143625A CA3143625A1 (en) | 2019-07-12 | 2019-07-12 | A device for treating a bottom-hole formation wellbore |
US17/597,594 US20220259945A1 (en) | 2019-07-12 | 2019-07-12 | Device for treating a bottom-hole formation wellbore |
EP19937754.0A EP3997305A4 (en) | 2019-07-12 | 2019-07-12 | A device for treating a bottom-hole formation wellbore |
AU2019457059A AU2019457059A1 (en) | 2019-07-12 | 2019-07-12 | A device for treating a bottom-hole formation wellbore |
PCT/CA2019/050970 WO2021007645A1 (en) | 2019-07-12 | 2019-07-12 | A device for treating a bottom-hole formation wellbore |
IL289755A IL289755A (en) | 2019-07-12 | 2019-07-12 | A device for treating a bottom-hole formation wellbore |
BR112022000567A BR112022000567A2 (en) | 2019-07-12 | 2019-07-12 | Device for treating a downhole formation from a wellbore |
PE2022000058A PE20221246A1 (en) | 2019-07-12 | 2019-07-12 | A DEVICE FOR TREATING A BOTTOM FORMATION OF A WELL ENCLOSURE |
ECSENADI20222883A ECSP22002883A (en) | 2019-07-12 | 2022-01-12 | A DEVICE FOR TREATING A BOTTOM FORMATION OF A WELL ENCLOSURE |
CONC2022/0001421A CO2022001421A2 (en) | 2019-07-12 | 2022-02-11 | A device for treating a bottom formation of a well enclosure |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CA2019/050970 WO2021007645A1 (en) | 2019-07-12 | 2019-07-12 | A device for treating a bottom-hole formation wellbore |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2021007645A1 true WO2021007645A1 (en) | 2021-01-21 |
Family
ID=74209645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA2019/050970 WO2021007645A1 (en) | 2019-07-12 | 2019-07-12 | A device for treating a bottom-hole formation wellbore |
Country Status (10)
Country | Link |
---|---|
US (1) | US20220259945A1 (en) |
EP (1) | EP3997305A4 (en) |
AU (1) | AU2019457059A1 (en) |
BR (1) | BR112022000567A2 (en) |
CA (1) | CA3143625A1 (en) |
CO (1) | CO2022001421A2 (en) |
EC (1) | ECSP22002883A (en) |
IL (1) | IL289755A (en) |
PE (1) | PE20221246A1 (en) |
WO (1) | WO2021007645A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024012718A2 (en) | 2022-07-14 | 2024-01-18 | ISOL8 (Holdings) Limited | Plug barrier material |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3145770A (en) * | 1961-01-27 | 1964-08-25 | Pan American Petroleum Corp | Method and apparatus for stimulating and testing earth formations |
RU2329374C2 (en) * | 2006-05-22 | 2008-07-20 | Казанский государственный энергетический университет (КГЭУ) | Facility for near-wellbore treatment and method for near-wellbore treatment |
US20110315387A1 (en) * | 2010-06-25 | 2011-12-29 | Marat Shatikovich Gamerov | System and method for cleaning a bottom-hole formation zone of a wellbore |
CA2716975A1 (en) * | 2010-09-17 | 2012-03-17 | Lamrock Canada Incorporated | A device for treating a bottom-hole formation zone of a wellbore |
US20120199351A1 (en) | 2008-03-26 | 2012-08-09 | Robertson Michael C | Method for removing a consumable downhole tool |
RU2487237C1 (en) * | 2012-03-20 | 2013-07-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский государственный энергетический университет" (ФГБОУ ВПО "КГЭУ") | Device for treatment of bottomhole formation zone of a well and method for treatment of bottomhole formation zone of well |
WO2019153093A1 (en) * | 2018-02-09 | 2019-08-15 | Lamrock Canada Incorporated | A device for treating a bottom-hole formation wellbore |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3076507A (en) * | 1958-05-16 | 1963-02-05 | William G Sweetman | Chemical cutting method and apparatus for use in wells |
US4352397A (en) * | 1980-10-03 | 1982-10-05 | Jet Research Center, Inc. | Methods, apparatus and pyrotechnic compositions for severing conduits |
-
2019
- 2019-07-12 US US17/597,594 patent/US20220259945A1/en active Pending
- 2019-07-12 PE PE2022000058A patent/PE20221246A1/en unknown
- 2019-07-12 IL IL289755A patent/IL289755A/en unknown
- 2019-07-12 EP EP19937754.0A patent/EP3997305A4/en active Pending
- 2019-07-12 AU AU2019457059A patent/AU2019457059A1/en active Pending
- 2019-07-12 WO PCT/CA2019/050970 patent/WO2021007645A1/en active Application Filing
- 2019-07-12 BR BR112022000567A patent/BR112022000567A2/en unknown
- 2019-07-12 CA CA3143625A patent/CA3143625A1/en active Pending
-
2022
- 2022-01-12 EC ECSENADI20222883A patent/ECSP22002883A/en unknown
- 2022-02-11 CO CONC2022/0001421A patent/CO2022001421A2/en unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3145770A (en) * | 1961-01-27 | 1964-08-25 | Pan American Petroleum Corp | Method and apparatus for stimulating and testing earth formations |
RU2329374C2 (en) * | 2006-05-22 | 2008-07-20 | Казанский государственный энергетический университет (КГЭУ) | Facility for near-wellbore treatment and method for near-wellbore treatment |
US20120199351A1 (en) | 2008-03-26 | 2012-08-09 | Robertson Michael C | Method for removing a consumable downhole tool |
US20110315387A1 (en) * | 2010-06-25 | 2011-12-29 | Marat Shatikovich Gamerov | System and method for cleaning a bottom-hole formation zone of a wellbore |
CA2716975A1 (en) * | 2010-09-17 | 2012-03-17 | Lamrock Canada Incorporated | A device for treating a bottom-hole formation zone of a wellbore |
CA2716975C (en) | 2010-09-17 | 2018-05-01 | Lamrock Canada Incorporated | A device for treating a bottom-hole formation zone of a wellbore |
RU2487237C1 (en) * | 2012-03-20 | 2013-07-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский государственный энергетический университет" (ФГБОУ ВПО "КГЭУ") | Device for treatment of bottomhole formation zone of a well and method for treatment of bottomhole formation zone of well |
WO2019153093A1 (en) * | 2018-02-09 | 2019-08-15 | Lamrock Canada Incorporated | A device for treating a bottom-hole formation wellbore |
Non-Patent Citations (1)
Title |
---|
See also references of EP3997305A4 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024012718A2 (en) | 2022-07-14 | 2024-01-18 | ISOL8 (Holdings) Limited | Plug barrier material |
Also Published As
Publication number | Publication date |
---|---|
AU2019457059A1 (en) | 2022-03-03 |
US20220259945A1 (en) | 2022-08-18 |
ECSP22002883A (en) | 2022-04-29 |
PE20221246A1 (en) | 2022-08-15 |
EP3997305A1 (en) | 2022-05-18 |
CO2022001421A2 (en) | 2022-04-29 |
CA3143625A1 (en) | 2021-01-21 |
EP3997305A4 (en) | 2023-07-26 |
IL289755A (en) | 2022-07-01 |
BR112022000567A2 (en) | 2022-03-15 |
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