WO2021001750A1 - Composition insecticide synergique de méthoxyfénozide, de benzoate d'émamectine et de biostimulants - Google Patents

Composition insecticide synergique de méthoxyfénozide, de benzoate d'émamectine et de biostimulants Download PDF

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Publication number
WO2021001750A1
WO2021001750A1 PCT/IB2020/056154 IB2020056154W WO2021001750A1 WO 2021001750 A1 WO2021001750 A1 WO 2021001750A1 IB 2020056154 W IB2020056154 W IB 2020056154W WO 2021001750 A1 WO2021001750 A1 WO 2021001750A1
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Prior art keywords
plant
concentrate
composition
insecticidal composition
methoxyfenozide
Prior art date
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PCT/IB2020/056154
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English (en)
Inventor
Kenal V. Shah
Bhavesh V. Shah
Arvind Kumar Singh
Dipakkumar Patel
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Gsp Crop Science Pvt. Ltd.
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Publication date
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Priority to BR112021016721A priority Critical patent/BR112021016721A2/pt
Publication of WO2021001750A1 publication Critical patent/WO2021001750A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers
    • C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Definitions

  • the present invention relates to synergistic mixtures of Methoxyfenozide, Emamectin Benzoate and Biostimulants wherein Biostimulants are selected from Fulvic acid, Humic Acid, Amino acid, or Chitosan.
  • the present invention more particularly relates to insecticidal compositions and a method of preparation thereof.
  • Methoxyfenozide is a carbohydrazide and is a low toxicity insecticides with chemical name N'-tert-Butyl-N'-(3,5-dimethylbenzoyl)-3-methoxy-2- methylbenzohydrazide .
  • Emamectin is the 4”-deoxy-4”-methylamino derivative of abamectin, a 16- membered macrocyclic lactone produced by the fermentation of the soil actinomycete Streptomyces avermitilis. It is generally prepared as the salt with benzoic acid, Emamectin benzoate.
  • CN103548821A discloses a combination of Emamectin Benzoate and Methoxyfenozide .
  • Agricultural biostimulants include diverse formulations of compounds, substances and micro-organisms that are applied to plants or soils to improve crop vigour, yields, quality and tolerance of abiotic stresses. Biostimulants foster plant growth and development throughout the crop life cycle from seed germination to plant maturity in a number of demonstrated ways, including but not limited to:
  • Biostimulants operate through different mechanisms than fertilisers, regardless of the presence of nutrients in the products.
  • Biostimulants differ from crop protection products because they act only on the plant’s vigour and do not have any direct actions against pests or disease. Crop biostimulation is thus complementary to crop nutrition and crop protection.
  • the present inventors have surprisingly developed an insecticidal composition
  • an insecticidal composition comprising Methoxyfenozide, Emamectin benzoate and Biostimulants wherein Biostimulants are selected from Fulvic acid, Humic acid, Amino acid or Chitosan which increase the yield and plant vigour of the treated plant.
  • It is an object of the present invention to provide an insecticidal composition comprising Methoxyfenozide, Emamectin Benzoate and Biostimulants wherein Biostimulants are selected from Fulvic acid, Humic Acid, Amino acid, or Chitosan.
  • It is another object of the present invention to provide an insecticidal composition comprising Methoxyfenozide, Emamectin Benzoate and Biostimulants wherein Biostimulants are selected from Fulvic acid, Humic Acid, Amino acid, or Chitosan which improve the yield and plant vigour of the treated plant.
  • synergistic insecticidal composition comprising:
  • Emamectin Benzoate in the range from 0.1 to 20% by weight of the composition.
  • the present invention relates to insecticidal mixtures of Methoxyfenozide, Emamectin Benzoate and Biostimulants wherein Biostimulants are selected from Fulvic acid, Humic Acid, Amino acid, or Chitosan.
  • Biostimulants wherein Biostimulants are selected from Fulvic acid, Humic Acid, Amino acid, or Chitosan.
  • an insecticidal composition comprising Methoxyfenozide, Emamectin Benzoate and Biostimulants wherein Biostimulants are selected from Fulvic acid, Humic Acid, Amino acid, or Chitosan with the following mass percentage of the composition:
  • Biostimulants are selected from Fulvic acid, Humic acid, Chitosan, or Amino acid such as Glycine, Proline, Hydroxyproline, Glutamic acid, Alanine, Arginine, Phenylalanine.
  • composition may be formulated as Suspension concentrate (SC) or Water dispersible granule (WG or WDG).
  • SC Suspension concentrate
  • WG Water dispersible granule
  • composition of the present invention further comprises inactive excipients.
  • a method of preparing a stable, non phytotoxic formulation of the present invention includes foliar spray, Seed treatment or treatment to planting materials, soil application.
  • the lists of crops which can be protected by the insecticidal composition of the present invention are GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinamm), Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (C
  • the insecticidal composition of the present invention can be used to control the Insects from the order of the Lepidoptera, for example cutworm Agrotis ypsilon, sugarcane shoot borer Chile infuscatellus, sugarcane stalk borer Chile partellus, sugarcane internode borer Chilo sacchariphagus, paddy/rice stem borer, Chile suppressalis, rice leaffolder Cnaphalocrocis medinalis, apple colding moth Cydia pomonella, okra fruit borer Earias vittella, Earias insulana, Tomato fruit borer Helicoverpa armigera, tobacco budworm Helicoverpa virescens, corn earworm Helicoverpa zea, cabbage webworm Hellula undalis, Brinjal fruit and shoot borer Eeucinodes orbonalis, bean pod borer Maruca vitrata, Maruca testulalis, armyworm Mythimna separata, cotton pinkbollworm Pectin
  • Beetles (Coleoptera), for example Anthonomus grandis, Bruchus lentis, Diabrotica semipunctata, Diabrotica virgifera, Dicladispa armigera, Epila-chna varivestis, Holotrichia bicolor, Holotrichia consanguinea, Holotrichia serrata, Leptinotarsa decemlineata, Phyllotreta chrysocephala, Popillia japonica.
  • Flies mosquitoes (Diptera), e.g. Atherigona orientalis, Calliphora vicina, Dacus cucurbi-tae, Liriomyza trifolii, Melanagromyza obtuse.
  • Thrips e.g. Dichromothrips ssp, Frankliniella occidentalis, Scirtothrips citri, Scirtothrips dorsalis, Thrips oryzae, Thrips palmi and Thrips tabaci.
  • Termites e.g. Calotermes flavicollis, Coptotermes formosanus, Heterotermes aureus, Leucotermes flavipes, Microtermes obesi, Odontotermes obesus, Reticulitermes flavipes, Termes natalensis.
  • True bugs e.g. Cotton leafhopper Amrasca biguttula biguttula, Amrasca devastans, Mango hopper Amritodus atkinsoni, Idioscopus spp., cotton aphid Aphis gossypii, groundnut aphid Aphis crassivora, whitefly Bemisia argentifolii, Bemisia tabaci, cabbage aphid Brevicoryne brassicae, red gram bug Clavigralla gibbosa, leaf hopper Empoasca fabae, Lygus pratensis, Macrosiphum avenae, Myzus persicae, Nilaparvata lugens, Nephotettix virescens, Nephotettix nigropictus, Planococcus spp., Pseudococcus spp., Pyrilla perpusilla, Rhopalosiphum maid
  • Arachnoidea such as arachnids (Acarina / plant mites), e.g. of the families Argasidae, Ixodidae and Sarcoptidae, such as Amblyomma variegatum, Ambryomma maculatum, Boophilus microplus, Eriophyidae spp. such as Aculus pointedendali, Phyllocoptrata oleivora and Eriophyes sheldoni; Tarsonemidae spp. such as Phytonemus pallidus and Polyphagotarsonemus latus; Tenuipalpidae spp.
  • Tetra-nychidae spp. such as Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, Panony-chus citri, and Oligonychus pratensis; Araneida, e.g. Latrodectus mactans, and Loxos-celes reclusa.
  • the insecticidal composition of the present invention can be applied to any and all developmental stages of pests, such as egg, nymph, larva, pupa and adult.
  • the pests may be controlled by contacting the target pest, its food supply, habitat, breeding ground or its locus with a pesticidally effective amount of the inventive mixtures or of compositions comprising the mixtures.
  • the insecticidal composition of the present invention is uses to improve the plant health.
  • the term“health of a plant” or“plant health” is defined as a condition of the plant and/or its products.
  • the health of a plant when applying the insecticidal composition of the present invention is increased independently of the insecticidal properties of the active ingredients used because the increase in health is not based upon the reduced pest pressure but instead on complex physiological and metabolic reactions which result for example in an activation of the plant's own natural defense system.
  • the health of a plant is increased even in the absence of pest pressure.
  • the health of a plant is increased both in the presence and absence of biotic or abiotic stress factors.
  • the above identified indicators for the health condition of a plant may be interdependent or they may result from each other.
  • An increase in plant vigor may for example result in an increased yield and/or tolerance to abiotic or biotic stress.
  • One indicator for the condition of the plant is the yield.“Yield” is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals).
  • the plant products may in addition be further utilized and/or processed after harvesting.
  • the insecticidal composition of the present invention is used to increase plant logitivity (plant life).
  • the yield of the treated plant is increased.
  • the yield of the plants treated according to the insecticidal composition of the present invention is increased synergistically.
  • “increased yield” of a plant in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the insecticidal composition of the present invention.
  • Increased yield can be characterized, among others, by the following improved properties of the plant: increased plant, weight, increased plant height, increased biomass such as higher overall fresh weight (FW), increased number of flowers per plant, higher grain yield, more tillers or side shoots (branches), larger leaves, increased shoot growth, increased protein content, increased oil content, increased starch content, increased pigment content, increased leaf are index.
  • the yield is increased by at least 4 %, preferable by 5 to 10%, more preferable by 10 to 20%, or even 20 to 30% compared to the untreated control plants or plants treated with pesticides in a way different from the method of the present invention.
  • the yield increase may even be higher.
  • a further indicator for the condition of the plant is the plant vigor.
  • the plant vigor becomes manifest in several aspects such as the general visual appearance.
  • the plant vigor of the treated plant is increased.
  • the plant vigor of the plants treated with insecticidal composition of the present invention is increased synergistically.
  • Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), improved emergence, enhanced root growth and/or more developed root system, enhanced nodulation, in particular rhizobial nodulation, bigger leaf blade, bigger size, increased plant weight, increased plant height, increased tiller number, increased number of side shoots, increased number of flowers per plant, increased shoot growth, increased root growth (extensive root system), increased yield when grown on poor soils or unfavorable climate, enhanced photosynthetic activity (e.g.
  • the improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the mixture or active ingredients (components).
  • Another indicator for the condition of the plant is the“quality” of a plant and/or its products.
  • the quality of the treated plant is increased.
  • the quality of the plants treated with the insecticidal composition of the present invention is increased synergistically.
  • enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the insecticidal composition of the present invention.
  • Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content, increased protein content, increased content of fatty acids, increased metabolite content, increased carotenoid content, increased sugar content, increased amount of essential amino acids, improved nutrient composition, improved protein composition, improved composition of fatty acids, improved metabolite composition, improved carotenoid composition, improved sugar composition, improved amino acids composition, improved or optimal fruit color, improved leaf color, higher storage capacity, higher processability of the harvested products.
  • Another indicator for the condition of the plant is the plant’s tolerance or resistance to biotic and/or abiotic stress factors.
  • Biotic and abiotic stress can have harmful effects on plants.
  • Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes.
  • “enhanced tolerance or resistance to biotic and/or abiotic stress factors” means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with insecticidal composition of the present invention and (2.) that the negative effects are not diminished by a direct action of the insecticidal composition of the present invention on the stress factors, e.g. by its fungicidal or insecticidal action which directly destroys the microorganisms or pests, but rather by a stimulation of the plants' own defensive reactions against said stress factors.
  • Step 1 Gum Solution should be made 12-18 hour prior to use. Take required quantity of water, biocide, and defoamer and homogenise, then slowly add gum powder to it and stir till complete dissolution.
  • Step 2 Charge required quantity of DM water need to be taken in designated vessel for Suspension concentrate production.
  • Step 3 Add required quantity of Wetting agent, antifreeze, dispersing agent & suspending agents and homogenise the contents for 45 - 60 minutes using high shear homogeniser.
  • Step 4 Then add technical and other remaining adjuvants excluding‘thickener’ are added to it and homogenised to get uniform slurry ready for grinding.
  • Step 5 Before grinding half the quantity of antifoam was added and then material was subjected to grinding in Dyno mill till desired particle size is achieved.
  • Step 6 Half quantity of the antifoam was added after grinding process completes and before sampling for in process analysis.
  • Step 7 Finally add gum solution to this formulation and send to QC for quality check.
  • Amino acid use in the above experiments are selected as“mixture of amino acids, (atleast two) selected from Glycine, Proline, Hydroxyproline, Glutamic acid, Alanine, Arginine, or Phenylalanine.
  • synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.
  • Ratio of O/E > 1 means synergism observed.
  • Crop stage 75 days
  • Spray volume 500 liter per hectare
  • the chilli green fruit yield data (gram per plot) was collected by weighing the freshly picked green fruit from entire plot.
  • the field trials data shows that synergistic activities of methoxyfenozide+emamectin benzoate +fulvic acid (Tl) and methoxyfenozide+emamectin benzoate+amino acid (T2) has been observed in terms of efficacy against fruit borer larval control in chilli crop.
  • the field trial results presented in table 3 shows synergistic activity between three active ingredient of methoxyfenozide+emamectin benzoate+fulvic acid (Tl) and methoxyfenozide+emamectin benzoate+amino acid (T2) has been observed by giving more number of twigs per plant, more number of flower per plant and number of green chilli fruits per plant.
  • the green chilli fruit yield has been obtained from the treatment of methoxyfenozide+emamectin benzoate+fulvic acid (Tl) and methoxyfenozide+ emamectin benzoate+amino acid (T2).
  • the inventive synergistic mixture of methoxyfenozide+ emamectin benzoate +fulvic acid and methoxyfenozide+ emamectin benzoate +amino acid shows excellent synergistic control of fruit borer and also giving highest number of twigs, flower, green fruits per plant and green chilli fruit yield compared to their solo and all other prior art treatments.
  • EXPERIMENT 2 Control of diamond back moth (Plutella xylostella) in cabbage crop.
  • Table 4 Synergistic larval control of diamond backmoth (Plutella xylostella) in cabbage crop
  • the laboratory bioassay of feeding test on diamond backmoth shows that methoxyfenozide + emamectin benzoate+fulvic acid and methoxyfenozide+ emamectin benzoate +amino acid shows synergism in terms of larval control compared to the other prior art treatments.

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne des mélanges synergiques de méthoxyfénozide, de benzoate d'émamectine et de biostimulants, les biostimulants étant choisis parmi l'acide fulvique, l'acide humique, le chitosane ou l'acide aminé tel que la glycine, la proline, l'hydroxyproline, l'acide glutamique, l'alanine, l'arginine ou la phénylalanine. La présente invention concerne plus particulièrement une composition insecticide synergique de i) méthoxyfénozide, benzoate d'émamectine et acide fulvique, ii) méthoxyfénozide, de benzoate d'émamectine et acide humique, iii) méthoxyfénozide, benzoate d'émamectine et acide aminé, iv) méthoxyfénozide, benzoate d'émamectine et chitosane, et un procédé de préparation desdites compositions.
PCT/IB2020/056154 2019-07-02 2020-06-30 Composition insecticide synergique de méthoxyfénozide, de benzoate d'émamectine et de biostimulants WO2021001750A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BR112021016721A BR112021016721A2 (pt) 2019-07-02 2020-06-30 Composição insecticida sinergística de metoxifenozida, benzoato de emamectina e biostimulantes

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Application Number Priority Date Filing Date Title
IN201921026375 2019-07-02
IN201921026375 2019-07-02

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WO2021001750A1 true WO2021001750A1 (fr) 2021-01-07

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101692819A (zh) * 2009-07-21 2010-04-14 深圳诺普信农化股份有限公司 一种有协同增效作用的农药组合物及其应用
CN103548821A (zh) * 2013-11-06 2014-02-05 南京南农农药科技发展有限公司 一种甲氨基阿维菌素苯甲酸盐·甲氧虫酰肼油悬浮剂
US20160270407A1 (en) * 2013-11-08 2016-09-22 Novozymes Bioag A/S Compositions and methods for treating pests
WO2017006248A1 (fr) * 2015-07-06 2017-01-12 Quimica Lucava, S.A. De C.V. Composition agrochimique qui comprend un mélange d'insecticide et un biostimulant, son procédé de préparation et son utilisation en agriculture pour lutter contre des nuisibles
IN201621027690A (de) * 2016-08-12 2018-02-16 Pesticidal composition of methoxyfenozide and insecticides
US10206402B2 (en) * 2014-02-14 2019-02-19 Nanjing Scienx Biological Technology Co., Ltd. Environmentally-friendly emamectin benzoate preparation and preparation method therefor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101692819A (zh) * 2009-07-21 2010-04-14 深圳诺普信农化股份有限公司 一种有协同增效作用的农药组合物及其应用
CN103548821A (zh) * 2013-11-06 2014-02-05 南京南农农药科技发展有限公司 一种甲氨基阿维菌素苯甲酸盐·甲氧虫酰肼油悬浮剂
US20160270407A1 (en) * 2013-11-08 2016-09-22 Novozymes Bioag A/S Compositions and methods for treating pests
US10206402B2 (en) * 2014-02-14 2019-02-19 Nanjing Scienx Biological Technology Co., Ltd. Environmentally-friendly emamectin benzoate preparation and preparation method therefor
WO2017006248A1 (fr) * 2015-07-06 2017-01-12 Quimica Lucava, S.A. De C.V. Composition agrochimique qui comprend un mélange d'insecticide et un biostimulant, son procédé de préparation et son utilisation en agriculture pour lutter contre des nuisibles
IN201621027690A (de) * 2016-08-12 2018-02-16 Pesticidal composition of methoxyfenozide and insecticides

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