WO2020247743A3 - Aerogels having a core-spoke polymeric matrix, methods of making, and uses thereof - Google Patents

Aerogels having a core-spoke polymeric matrix, methods of making, and uses thereof Download PDF

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Publication number
WO2020247743A3
WO2020247743A3 PCT/US2020/036313 US2020036313W WO2020247743A3 WO 2020247743 A3 WO2020247743 A3 WO 2020247743A3 US 2020036313 W US2020036313 W US 2020036313W WO 2020247743 A3 WO2020247743 A3 WO 2020247743A3
Authority
WO
WIPO (PCT)
Prior art keywords
core
making
methods
spoke
aerogels
Prior art date
Application number
PCT/US2020/036313
Other languages
French (fr)
Other versions
WO2020247743A2 (en
Inventor
David J. Irvin
Garrett D. Poe
Muhammad Ejaz
Marisa SNAPP-LEO
Original Assignee
Blueshift Materials, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Blueshift Materials, Inc. filed Critical Blueshift Materials, Inc.
Publication of WO2020247743A2 publication Critical patent/WO2020247743A2/en
Publication of WO2020247743A3 publication Critical patent/WO2020247743A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C08J9/286Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0091Preparation of aerogels, e.g. xerogels
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06Polymers provided for in subclass C08G
    • C08F290/068Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/001Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/002Dendritic macromolecules
    • C08G83/005Hyperbranched macromolecules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Silicon Polymers (AREA)
  • Silicon Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A hyperbranched organic aerogel, and methods for making and using the same, are disclosed. The aerogel can include a core/flexible spoke type structure. The aerogel can include flexible spokes that can include 3 to 8 flexible hydrocarbon-containing materials bonded to a core material. The core and flexible hydrocarbon-containing spacer material can include 1 to 3 A-X functional groups, where A is silicon (Si), phosphorous (P), or sulfur (S), and X is oxygen (O) or nitrogen (N).
PCT/US2020/036313 2019-06-06 2020-06-05 Aerogels having a core-spoke polymeric matrix, methods of making, and uses thereof WO2020247743A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962858180P 2019-06-06 2019-06-06
US62/858,180 2019-06-06

Publications (2)

Publication Number Publication Date
WO2020247743A2 WO2020247743A2 (en) 2020-12-10
WO2020247743A3 true WO2020247743A3 (en) 2021-01-14

Family

ID=71899820

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2020/036313 WO2020247743A2 (en) 2019-06-06 2020-06-05 Aerogels having a core-spoke polymeric matrix, methods of making, and uses thereof

Country Status (1)

Country Link
WO (1) WO2020247743A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113980342B (en) * 2021-08-19 2022-12-30 中国科学技术大学 Organosilicon polymer shape memory aerogel and preparation method thereof
CN117384557B (en) * 2023-11-01 2024-04-09 南雄市沃太化工有限公司 Low-temperature-resistant polyacrylate pressure-sensitive adhesive and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832386A (en) * 2017-01-09 2017-06-13 淮阴工学院 A kind of organic aerogel and its preparation method and application
WO2019006184A1 (en) * 2017-06-29 2019-01-03 Blueshift Materials, Inc. Hyperbranched poss-based polymer aerogels

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832386A (en) * 2017-01-09 2017-06-13 淮阴工学院 A kind of organic aerogel and its preparation method and application
WO2019006184A1 (en) * 2017-06-29 2019-01-03 Blueshift Materials, Inc. Hyperbranched poss-based polymer aerogels

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ASSEFA DAWIT ET AL: "Polymer-derived SiOC aerogel with hierarchical porosity through HF etching", CERAMICS INTERNATIONAL, ELSEVIER, AMSTERDAM, NL, vol. 42, no. 10, 20 April 2016 (2016-04-20), pages 11805 - 11809, XP029713606, ISSN: 0272-8842, DOI: 10.1016/J.CERAMINT.2016.04.101 *
GUOQING ZU ET AL: "Transparent, Superflexible Doubly Cross-Linked Polyvinylpolymethylsiloxane Aerogel Superinsulators via Ambient Pressure Drying", ACS NANO, vol. 12, no. 1, 11 January 2018 (2018-01-11), pages 521 - 532, XP055739365, ISSN: 1936-0851, DOI: 10.1021/acsnano.7b07117 *
RODOSEK MIRJANA ET AL: "Protective coatings for AA 2024 based on cyclotetrasiloxane and various alkoxysilanes", CORROSION SCIENCE, OXFORD, GB, vol. 126, 1 July 2017 (2017-07-01), pages 55 - 68, XP085183831, ISSN: 0010-938X, DOI: 10.1016/J.CORSCI.2017.06.011 *

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Publication number Publication date
WO2020247743A2 (en) 2020-12-10

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