WO2020245735A1 - Non-flammable thermal insulating composite substrate for motor vehicles and production method - Google Patents

Non-flammable thermal insulating composite substrate for motor vehicles and production method Download PDF

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Publication number
WO2020245735A1
WO2020245735A1 PCT/IB2020/055224 IB2020055224W WO2020245735A1 WO 2020245735 A1 WO2020245735 A1 WO 2020245735A1 IB 2020055224 W IB2020055224 W IB 2020055224W WO 2020245735 A1 WO2020245735 A1 WO 2020245735A1
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WO
WIPO (PCT)
Prior art keywords
barrier
composite substrate
textile component
motor vehicles
thermal insulating
Prior art date
Application number
PCT/IB2020/055224
Other languages
French (fr)
Inventor
Nicolò MOSCA
Original Assignee
Agotex S.R.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agotex S.R.L. filed Critical Agotex S.R.L.
Priority to EP20742917.6A priority Critical patent/EP3962725A1/en
Priority to US17/616,540 priority patent/US20220250367A1/en
Publication of WO2020245735A1 publication Critical patent/WO2020245735A1/en

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    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00—Making preforms
    • B29B11/14—Making preforms characterised by structure or composition
    • B29B11/16—Making preforms characterised by structure or composition comprising fillers or reinforcement
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
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    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B32B2262/144—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/07—Parts immersed or impregnated in a matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/10—Fibres of continuous length
    • B32B2305/20—Fibres of continuous length in the form of a non-woven mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/308—Heat stability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B32B2307/734—Dimensional stability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

Non-flammable thermal insulating composite substrate (10) for motor vehicles comprising: textile component (11) constituted by a layer of needle-sewn non-woven fabric composed of a percentage of pre-oxidized polyacrylonitrile fiber comprised between 40% and 70%, preferably 58% and of the remaining percentage of polyethylene glycol-terephthalate fiber, said textile component (11) having weight preferably 400 gr/m2; barrier (12) fixed to the textile component (11) by means of a spreading process, constituted by a thermoplastic resin based on low density polyethylene added with non-halogen flame retardants, said barrier (12) having weight preferably 100 gr/m2; said composite substrate (10) having the following features: - thickness comprised between 2 mm and 5 mm, preferably 3.8 mm; - weight comprised between 300 gr/m2 and 700 gr/m2, preferably 500 gr/m2; - odorless; - no emission of fumes; - dimensionally stable, even at heatstroke, with a maximum variation of 1%; - non-flammability.

Description

“Non-flammable thermal insulating composite substrate for motor vehicles and production
method”
Description
Field of the art
The present invention operates in the field of heat-protective materials, in particular in the automotive field. More in detail, the present invention proposes a new and innovative material for protecting against heat which is non-flammable.
Prior art
In the automotive field, research on new materials and, in particular, on new polymers, is always at the forefront due to the increasing market needs. Both clients and international laws have for years pushed automobile manufacturers to constantly innovate the materials in order to provide maximum technical performances as well as savings in terms of weight, emissions and performances of the vehicle.
Among the most important features that determine consumer preference, there is without a doubt the comfort conditions of the driver and passenger compartment, which thus must not be affected by the heat coming from the engine or coming from the exhaust manifolds and from the muffler itself and possibly from the battery compartment of hybrid or electric cars. In order to ensure the correct climate conditions inside the vehicle, numerous materials have therefore been developed that act as heat barrier.
The heat barriers are variously situated on the vehicles, especially close to the engine and engine compartment so that this is not overheated, starting spontaneous combustion or even fire, and also for ensuring the comfort of the driver/vehicle compartment interior, protecting it from the high temperatures produced.
The problem pertaining to this type of constituent element of the vehicle lies in the fact that optimal features are obtained from the combination of mechanical and thermal properties of multiple materials.
When multiple materials are arranged in layers, there is the risk of separation of the different layers. Analogously, when a more rigid material is coupled to a less rigid material, there is a crushing of this second material, with consequent loss of the requested performances.
When multiple materials are worked together in order to combine the properties thereof in a single monolithic and hence indivisible object, the production process comprises various steps that increase the cost of the finished object and hence lower the profitability of the industrial plant engaged in the production thereof.
More in detail, the coupling of a textile material and of a plastic is often attained with mechanical fastening or by means of glue, increasing the weight and decreasing the seal between the various materials.
Several interational patents regard this vehicle component type, such as the patent of Korean origin, extended worldwide as WO 2016 190 596. Such patent regards a polyketone fiber material obtained via centrifugation of the copolymer, washing, drying and stretching. The polyketone fiber has excellent properties of mechanical stress resistance, elongation, water resistance, heat resistance and heat conductivity and allows the production of objects that are highly resistant to high temperatures, and even antiprojectile.
Even if the quality of the object thus produced is high, given the high production cost this is used for tanks and other military equipment, while it is not convenient for larger productions. The object of the present patent is therefore that of uniting the advantages of coupling materials with the due technical performances, of indivisibility of the obtained composite and of inexpensive production costs.
Description of the invention
According to the present invention, a non-flammable and thermal insulating composite substrate for motor vehicles is attained which effectively resolves the abovementioned problems.
The features of non-flammability and of no emission of fumes are manifested when the substrate is exposed to the flame on the textile side.
This advantageously comprises a textile component treated in an impregnating bath which renders it a preferably water-oil repellent barrier.
The textile component is constituted by a layer of needle-sewn non-woven fabric composed of a percentage of pre-oxidized polyacrylonitrile fiber comprised between 40% and 70%, preferably 58% and of the remaining percentage of polyethylene glycol-terephthalate fiber. The textile component has weight comprised between 200 gr/m2 and 600 gr/m2, preferably 400 gr/m2.
The barrier, according to a production process described below, will be advantageously fixed to a surface of the textile component. Said barrier is constituted by a thermoplastic resin based on low density polyethylene added with non-halogen flame retardants.
It can be made of polyethylene, polyamide or of ethylene vinyl acetate and will have weight comprised between 30 gr/m2 and 150 gr/m2, preferably 100 gr/m2.
Overall, the composite substrate will have the following features:
- thickness comprised between 2 mm and 5 mm, preferably 3.8 mm;
- weight comprised between 300 gr/m2 and 700 gr/m2, preferably 500 gr/m2;
- odorless;
- no emission of fumes if exposed to the flame on the textile side;
- non-flammable if exposed to the flame on the textile side;
- dimensionally stable, even to heatstroke, with a maximum variation of 1%.
Preferably it will also have the characteristic of being water-oil repellent.
Several particular embodiments have the advantage of being recyclable. The composite substrate, object of the present industrial invention patent application, once molded on the face that has the barrier formed with the desired plastic finishes, as described below, results non-flammable and lacks emission of fumes even if exposed to the flame on both faces.
In the automotive field, the composite substrate, object of the present invention, is used for being inserted in an injection mold to be co-molded with a predetermined plastic polymer, on the face that has the barrier formed thereon. The composite substrate in fact adheres to the plastic polymer at the outer surface provided with the barrier which, being slightly rough, due to a plurality of troughs and projections, allows the strong and stable fixing of said plastic polymer on the composite substrate. In addition, the presence of the aforesaid barrier prevents, during the molding step and especially during injection of the plastic polymer, the plastic polymer being heated and hence in the liquid state from traversing and spreading into the underlying non-flammable and thermal insulating textile layer which must instead be strictly maintained intact. The present industrial invention patent application intends to describe and claim an innovative non-flammable thermal insulating composite substrate, adapted to become a monolithic element provided with a molded side, on which injection molded plastic elements are present, in turn anchored on the face of a barrier-forming layer stably connected, this time by means of its opposite face, to a non-flammable and thermal insulating textile mattress.
The advantages offered by the present invention are evident in light of the description set forth up to now and will be even clearer due to the enclosed figures and to the relative detailed description.
Descrrotion of the figures
The invention will be described hereinbelow in at least one preferred embodiment by way of a non-limiting example with the aid of the enclosed figures, in which:
- FIGURE 1 shows a schematic section of the composite material that forms the substrate 10, object of the present invention.
- FIGURE 2 illustrates the scheme of the production plant for making the claimed composite substrate 10.
Detailed description of the invention
The present invention will now be illustrated as a merely exemplifying but non-limiting or non-binding example, with reference to the figures which illustrate several embodiments relative to the present inventive concept.
With reference to FIG. 2, the production plant adapted to make the composite substrate 10, object of the present invention, is shown.
This consists of an unrolling roller 100, a plurality of first tensioning rollers 110-110’, a tank 120 of barrier-forming agent 12, an oven 122 and a dispenser device 124, a plurality of rolling rolls 130-130’, a cooling device 140, a plurality of second tensioning rollers 150-150’ and a rolling roller 160.
The attainment method then provides for:
- A first step of unrolling a roll of textile component 11, by means of said unrolling roller 100. The textile component 11 is constituted by a layer of needle-sewn non- woven fabric composed of pre-oxidized polyacrylonitrile fiber in a percentage that varies from 40% to 70% preferably 58% and by the remaining percentage of polyethylene glycol-terephthalate fiber;
- A second step of tensioning and aligning said textile component 11 by means of the first tensioning rollers 110-110’;
- A third step of heating a predetermined quantity of barrier-forming agent 12 at a temperature comprised between 50°C and 350°C. The barrier-forming agent 12 is constituted by a low density polyethylene powder added with non-halogen flame retardants and it is stored in a tank 120 connected to the oven 122 where the heating occurs; - A fourth step of spreading the barrier-forming agent 12 on one face of the textile component 11 by means of a dispenser 124;
- A fifth step of rolling the barrier-forming agent 12 on the textile component 11 by means of the rolling rolls 130-130’;
- A sixth step of cooling the barrier-forming agent 12 by means of a cooling device 140. The cooling of the barrier-forming agent 12 on the textile component 11 determines the irreversible adhesion and hence generates the desired composite substrate 10;
- A seventh step of tensioning and aligning the composite substrate 10 just produced, by means of the second tensioning rollers 150-150’;
- An eighth step of rolling the composite substrate 10 by means of a rolling roller 160.
Finally, it is clear that modifications, additions or variations that are obvious for the man skilled in the art can be made to the invention described up to now, without departing from the protective scope provided by the enclosed claims.

Claims

Claims
1. Non-flammable thermal insulating composite substrate (10) for motor vehicles, characterized in that it comprises a textile component (11) and a barrier (12);
said textile component (11) consisting of a layer of needle-sewn non-woven fabric composed of a percentage of pre-oxidized polyacrylonitrile fiber ranging from 40% to 70%, preferably 58% and of the remaining percentage of polyethylene glycol- terephthalate fiber, said textile component (11) having a weight of between 200 g/m2 and 600 g/m2, preferably 400 g/m2;
said barrier (12) being irreversibly fixed to a surface of said textile component (11) through a spreading process; said barrier (12) consisting of a thermoplastic resin based on low density polyethylene added with non-halogen flame retardants, said barrier (12) having a weight of between 30 g/m2 and 150 g/m2, preferably 100 g/m2;
said composite substrate (10) having the following features:
- thickness of between 2 mm and 5 mm, preferably 3.8 mm;
- weight of between 300 g/m2 and 700 g/m2, preferably 500 g/m2;
- odorless;
- no emission of fumes when exposed to the flame at said textile component (11);
- dimensionally stable, even at heatstroke, with a maximum variation of 1%;
- non-flammability when exposed to the flame at said textile component (11).
2. Non-flammable thermal insulating composite substrate (10) for motor vehicles, according to the preceding claim 1, characterized in that said barrier (12) is made of polyethylene and is provided with reliefs and recesses which increase the adhesion thereof.
3. Non-flammable thermal insulating composite substrate (10) for motor vehicles, according to the preceding claim 1, characterized in that said barrier (12) is made of polyamide and is provided with reliefs and recesses which increase the adhesion thereof.
4. Non-flammable thermal insulating composite substrate (10) for motor vehicles, according to the preceding claim 1, characterized in that said barrier (12) is made of ethylene vinyl acetate and is provided with reliefs and recesses which increase the adhesion thereof.
5. Non-flammable thermally insulating composite substrate (10) for motor vehicles, according to any one of the preceding claims, characterized in that by impregnating said textile component (11) in a bath, it becomes a water-oil repellent barrier.
6. Non-flammable thermal insulating composite substrate (10) for motor vehicles, according to any one of the preceding claims, characterized in that it comprises a layer made of any plastic polymer (13), engaged externally to said barrier (12).
7. Use of a non-flammable thermal insulating composite substrate (10) for motor vehicles, wherein said substrate (10) is inserted in an injection mold to be co-molded with a predetermined plastic polymer, said composite substrate (10) adhering to the plastic polymer at the outer surface (12.2) of said barrier (12).
8. Method for producing a non-flammable thermal insulating composite substrate (10) for motor vehicles, characterized in that it comprises the steps of:
- unrolling a roll of textile component (11) according to claim 1, by means of an unrolling roller (100);
- tensioning and aligning said textile component (11) through a plurality of first tensioning rollers (110-110’);
- heating a predetermined amount of barrier-forming agent (12), according to any
- one of the preceding claims 1 to 4, at a temperature ranging from 50°C to 350°C; said heating taking place in a special oven (122);
- spreading said barrier (12) on one face of said textile component (11) through a dispenser (124);
- rolling said barrier (12) onto said textile component (11) through a plurality of rolling rolls (130-130’);
- cooling said barrier-forming agent (12) by means of a cooling device (140) and irreversible adhesion between said textile component (11) and said barrierforming agent (12), generating said composite substrate (10);
- tensioning and aligning said composite substrate (10) through a plurality of second tensioning rollers (150-150’);
- rolling said composite substrate (10) by means of a rolling roller (160).
9. Method for producing a non-flammable thermal insulating composite substrate (10) for motor vehicles, according to the preceding claim, characterized in that it comprises a step for storing said barrier-forming material (12) in a special tank (120) in which said barrier-forming material (12) is stored in powder; said tank (120) being connected to said oven (122) in turn upstream of said dispenser (124).
PCT/IB2020/055224 2019-06-06 2020-06-03 Non-flammable thermal insulating composite substrate for motor vehicles and production method WO2020245735A1 (en)

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WO2005115739A1 (en) * 2004-05-28 2005-12-08 Du Pont-Toray Company, Ltd. Easily moldable acoustic material
EP2754373A1 (en) * 2012-11-08 2014-07-16 Yoshidafusa Orimono Co., Ltd. Flame-retardant planar body, carpeting resistant to generating hazardous gases that uses said flame-retardant planar body, and method for producing said carpeting resistant to generating hazardous gases
WO2016190596A2 (en) 2015-05-27 2016-12-01 (주)효성 Industrial polyketone product comprising polyketone fibers and method for manufacturing same
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WO2019090659A1 (en) * 2017-11-10 2019-05-16 3M Innovative Properties Company Thermal insulators and methods thereof

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WO2005115739A1 (en) * 2004-05-28 2005-12-08 Du Pont-Toray Company, Ltd. Easily moldable acoustic material
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