WO2020238253A1 - Recirculating aquaculture water treatment system integrating tailwater treatment - Google Patents

Recirculating aquaculture water treatment system integrating tailwater treatment Download PDF

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Publication number
WO2020238253A1
WO2020238253A1 PCT/CN2020/071814 CN2020071814W WO2020238253A1 WO 2020238253 A1 WO2020238253 A1 WO 2020238253A1 CN 2020071814 W CN2020071814 W CN 2020071814W WO 2020238253 A1 WO2020238253 A1 WO 2020238253A1
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water treatment
tank
ozone
biological filter
water
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PCT/CN2020/071814
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French (fr)
Chinese (zh)
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江兴龙
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集美大学
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K63/00Receptacles for live fish, e.g. aquaria; Terraria
    • A01K63/04Arrangements for treating water specially adapted to receptacles for live fish
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K63/00Receptacles for live fish, e.g. aquaria; Terraria
    • A01K63/04Arrangements for treating water specially adapted to receptacles for live fish
    • A01K63/042Introducing gases into the water, e.g. aerators, air pumps
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K63/00Receptacles for live fish, e.g. aquaria; Terraria
    • A01K63/04Arrangements for treating water specially adapted to receptacles for live fish
    • A01K63/045Filters for aquaria
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/023Reactive oxygen species, singlet oxygen, OH radical
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/005Combined electrochemical biological processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/08Aerobic processes using moving contact bodies
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/301Aerobic and anaerobic treatment in the same reactor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • C02F3/303Nitrification and denitrification treatment characterised by the nitrification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • C02F3/305Nitrification and denitrification treatment characterised by the denitrification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used

Definitions

  • the invention relates to an integrated water treatment system for circulating aquaculture and tail water treatment.
  • Circulating aquaculture has developed rapidly in recent years, and the scale of aquaculture has been expanding.
  • the types of freshwater circulating aquaculture mainly include eel, sturgeon, cod, tilapia and Litopenaeus vannamei, etc., which have the advantages of water saving, land saving, high yield, high efficiency and high quality and safety of aquatic products.
  • eel sturgeon
  • cod cod
  • tilapia tilapia
  • Litopenaeus vannamei etc.
  • the tail water needs to be discharged from the system.
  • the tail water can be used to thicken and dehydrate the sewage to form a mud cake.
  • the current circulating water aquaculture water treatment system is based on the biological characteristics and ecological habits of the aquaculture objects (such as fish and shrimp) and the safe concentration requirements for the main factors of water quality such as ammonia nitrogen and nitrite nitrogen.
  • the treatment process and the construction of the corresponding water treatment unit enable the water quality of the circulating aquaculture water to meet the healthy aquaculture requirements of the aquaculture objects and realize the healthy growth of the aquaculture objects. It does not have the function of treating tail water up to standard discharge.
  • the technical problem to be solved by the present invention is to provide an integrated water treatment system for circulating aquaculture and tail water treatment, which has the characteristics of high water treatment efficiency and continuous maintenance of high water quality in the breeding system, and the water cycle utilization rate can reach 95% ⁇ 98%; not only can fully meet the healthy breeding needs of the breeding objects and realize the healthy growth of the breeding objects, but also has the tail water treatment function, which can achieve the discharge of the tail water up to the standard.
  • the present invention is realized as follows:
  • the water treatment system includes a sewage collection tank, a physical filtration device, an electrode-suspended filler coupled biological filter treatment unit, an ozone and ultraviolet combination to kill pathogenic microorganisms and sludge Concentration and dehydration device; the sewage collection tank is connected with a physical filter device, the physical filter device is connected to an electrode-suspended filler coupled biological filter processing unit, and the electrode-suspended filler coupled biological filter processing unit is combined with ozone ultraviolet rays
  • the pathogen-killing microorganism pool is arranged adjacently.
  • the sewage collection tank, the physical filter device, the electrode-suspended filler coupling biological filter processing unit, and the ozone-ultraviolet combination pathogen-killing microorganism pool are all connected to the sludge concentration and dehydration device.
  • the combined pathogenic microorganism pool is also connected to the breeding pool;
  • the electrode-suspended filler coupled biological filter processing unit includes a biological filter, a suspended filler, a direct current cathode and anode electrode array combination, an electric stirring device, and a carbon source supplement device.
  • the suspended filler is arranged in the biological filter, and the direct current
  • the cathode and anode electrode array combination is arranged on the upper part of the biological filter
  • the electric stirring device is arranged on the lower part of the biological filter
  • the bottom of the biological filter is arranged with a sludge bucket
  • the electric stirring device is arranged on Above the sludge bucket
  • the carbon source supplement device is connected to the biological filter through a pipeline;
  • the volume ratio of the suspended filler to the water in the biological filter is 20% to 50%, and the density of the suspended filler is 0.92 to 0.98 g/cm 3 ;
  • the anode in the DC cathode and anode electrode array combination is iron,
  • the cathode is iron, carbon or copper;
  • the rotational speed of the electric stirring device is 100-300 r/min.
  • the suspended filler is made of high-density polyethylene with a specific surface area greater than 500 m 2 /m 3 .
  • the distance between adjacent electrodes of the direct current cathode and anode electrode array combination is 2-30 cm
  • the operating voltage and current are respectively: the direct current voltage is 12 to 36 V
  • the micro current density is 0.1 to 1.0 mA/cm 2 .
  • the biological filter is a combination of more than two cells in series, and some or all of the cells can be equipped with a direct current cathode and anode electrode array combination.
  • the physical filtering device is an automatic backwash screen filter, a micro filter or an arc screen.
  • the ozone-ultraviolet combination inactivating pathogenic microorganisms tank includes an ozone tank and an ultraviolet lamp-aeration tank which are arranged adjacently, and a microporous aeration pan is arranged at the bottom of the ozone tank, and the microporous aeration pan is connected to the outside of the tank.
  • the ultraviolet lamp-the upper part of the aeration tank is provided with an ultraviolet lamp
  • the bottom of the ultraviolet lamp-the aeration tank is provided with an aeration microporous tube
  • the aeration microporous tube is connected to the air pump outside the tank
  • the water inlet of the ultraviolet lamp-aeration tank is set at the bottom
  • the water outlet is set at the upper part
  • the bottom of the ozone tank and the ultraviolet lamp-aeration tank are both provided with a sludge bucket, and the sludge bucket is The mud thickening and dewatering device is connected.
  • the ozone generator inputs ozone 4 to 12 times a day to treat the water body, and each lasts for 20-60 minutes; the hydraulic residence time in the ultraviolet lamp-aeration tank is 15-40 minutes.
  • the ultraviolet lamp is immersed.
  • the present invention mainly integrates iron cation phosphate precipitation reaction, iron cation hydrate and its polymer flocculation precipitation effect on phosphorus and other particles, nitrification through a series of physical, chemical and microbiological actions produced in the biological filter. Reaction and denitrification reaction, etc., to achieve continuous, stable and efficient phosphorus and nitrogen removal, organic matter degradation and suspended solids concentration reduction effects. It has the advantages of simple device structure, less sludge production and no secondary pollution.
  • the invention integrally realizes the dual functions of circulating aquaculture water treatment and tail water up-to-standard discharge treatment, and has the advantages of saving land, high water treatment efficiency, low investment and operating costs, simple management and the like.
  • the invention has the characteristics of high water treatment efficiency and continuous maintenance of high water quality in the breeding system, and the water cycle utilization rate can reach 95% to 98%; it can not only fully meet the healthy breeding needs of the breeding objects, and realize the healthy growth of the breeding objects, but also has a tail.
  • the water treatment function can realize the discharge of tail water up to standard. It solves the problem that the current circulating aquaculture water treatment system has a single function and does not have the ability to discharge the tail water up to the standard.
  • Figure 1 is a schematic diagram of the structure of the present invention.
  • Fig. 2 is a schematic diagram of the combined structure of the electrode-suspended filler coupled biological filter processing unit and the ozone-ultraviolet combined anti-pathogenic microorganism pool in the present invention.
  • the present invention relates to an integrated water treatment system for circulating aquaculture and tail water treatment.
  • the water treatment system includes a sewage collection tank 1, a physical filter device 2, an electrode-suspended filler coupled biological filter processing unit 3.
  • the ozone and ultraviolet combination kill pathogenic microorganism pool 4 and the sludge thickening and dewatering device 5;
  • the sewage collection tank 1 is connected to the physical filter device 2, and the physical filter device 2 is connected to the electrode-suspended filler coupling biological filter processing unit 3.
  • the electrode-suspended filler coupling biological filter processing unit 3 is arranged adjacent to the ozone-ultraviolet combination inactivating pathogenic microorganism pool 4, the sewage collection tank 1, the physical filter device 2, the electrode-suspended filler coupled biological filter processing unit 3.
  • the ozone-ultraviolet combined pathogenic microorganism pool 4 is connected to the sludge thickening and dewatering device 5, and the ozone-ultraviolet combined pathogenic microorganism pool 4 is also connected to the breeding pool 6;
  • the electrode-suspended filler coupled biological filter processing unit 3 includes a biological filter 31, a suspended filler 32, a direct current cathode and anode electrode array combination 33, an electric stirring device 34, and a carbon source supplement device 35.
  • the suspended filler 32 is installed in the biological filter.
  • the direct current cathode and anode electrode array assembly 33 is arranged at the upper part of the biological filter tank 31
  • the electric stirring device 34 is arranged at the lower part of the biological filter tank 31
  • the bottom of the biological filter tank 31 A sludge bucket 7 is provided, the electric stirring device 34 is installed above the sludge bucket 7, and the carbon source supplement device 35 is connected to the biological filter 31 through a pipeline;
  • the volume ratio of the suspended filler 32 to the water in the biological filter 31 is 20% to 50%, and the density of the suspended filler 32 is 0.92 to 0.98 g/cm 3 ; in the direct current cathode and anode electrode array combination 33
  • the anode is iron, and the cathode is iron, carbon or copper; the rotational speed of the electric stirring device 34 is 100-300 r/min.
  • the suspended filler 32 is made of high-density polyethylene with a specific surface area greater than 500 m 2 /m 3 .
  • the distance between adjacent electrodes of the direct current cathode and anode electrode array combination 33 is 2-30 cm, the operating voltage and current are respectively: the direct current voltage is 12 to 36 V, and the micro current density is 0.1 to 1.0 mA/cm 2 .
  • the biological filter 31 is a combination of two or more tank bodies in series, and a direct current cathode and anode electrode array combination 33 may be provided in part or all of the tank bodies.
  • the physical filtration device 2 is an automatic backwashing screen filter, a micro filter or an arc screen.
  • the ozone-ultraviolet combination inactivating pathogenic microorganisms pool 4 includes an ozone pool 41 and an ultraviolet lamp-aeration pool 42 which are adjacently arranged.
  • the bottom of the ozone pool 41 is provided with a microporous aeration pan 411, the microporous aeration pan 411 Connected to the ozone generator outside the tank;
  • the ultraviolet lamp-aeration tank 42 is provided with an ultraviolet lamp 421 at the upper part, and the bottom of the ultraviolet lamp-aeration tank 42 is provided with an oxygen-enhancing microporous tube 422, the oxygen-enhancing micro The orifice tube 422 is connected with an air pump outside the tank.
  • the water inlet of the ultraviolet lamp-aeration tank 42 is set at the bottom, and the water outlet is set at the upper part; the bottom of the ozone tank 41 and the ultraviolet lamp-aeration tank 42 are both set.
  • the sludge bucket 7 is connected to the sludge thickening and dewatering device 5.
  • the ozone generator inputs ozone 4 to 12 times a day to treat the water body, and the duration of each time is 20-60 minutes; the hydraulic residence time in the ultraviolet lamp-aeration tank 42 is 15-40 minutes.
  • the ultraviolet lamp 421 is immersed.
  • the working process of the present invention is as follows: after the farming tail water enters the sewage collection tank 1, it is extracted by the water pump into the physical filter device 2, and the filtered water enters the electrode-suspended filler coupling biological filter processing unit 3, and contains residual bait and feces
  • the backflush water ( ⁇ 1.5%) of other large particles enters the sludge thickening and dewatering device 5; in the sludge thickening and dewatering device 5, the thickened and dewatered sludge is formed into a mud cake, and the organic fertilizer is transported out of the system, and the concentrated and filtered
  • the water returns to the sewage collection tank 1, or is discharged out of the system; in the electrode-suspended filler coupled biological filter processing unit 3, a sludge bucket 7 is provided at the bottom of the biological filter 31, which can be discharged regularly.
  • the sludge water ( ⁇ 3 %) is discharged into the sludge thickening and dewatering device 5; the water treated by the electrode-suspended filler coupling biological filter processing unit 3 flows into the ozone and ultraviolet combination to kill pathogenic microorganisms pool 4 to kill pathogenic microorganisms and moderate aeration to obtain purification
  • the purified water flows back to the breeding pond; the ozone-ultraviolet combined anti-pathogenic microorganism pond 4 is equipped with a sludge bucket 7, which can be discharged regularly, and the sludge water ( ⁇ 0.5%) is discharged into the sludge thickening and dewatering device 5.
  • Sewage collection tank 1 mainly collects the aquaculture tail water discharged from all aquaculture tanks. More than 2 submersible pumps (1 of which are spare) are installed in the tank to extract the water to the physical filtration device 2.
  • the physical filtration device 2 is a physical filtration device such as an automatic backwashing screen filter, a microfilter or an arc screen, which separates large particulate matter in the water, and automatically backflushes the water containing large particulate matter such as residual bait and feces ( ⁇ 1.5%) enter the sludge dewatering and thickening device 5, and the water filtered by the screen enters the electrode-suspended filler coupling biological filter processing unit 3.
  • an automatic backwashing screen filter such as an automatic backwashing screen filter, a microfilter or an arc screen
  • electrode-suspended filler coupling biological filter processing unit 3 The working principle of electrode-suspended filler coupling biological filter processing unit 3 is as follows:
  • iron (anode) Due to the action of the direct current electric field of the direct current cathode and anode electrode array 33, the iron (anode) generates a large amount of iron cations, and the large amount of Fe 2+ and Fe 3+ produced reacts with the phosphate in the aquaculture tail water to form Granular, insoluble substances settle in the bottom sludge bucket 7 of the biological filter 31; at the same time, iron cations undergo a series of hydrolytic polymerization reactions, Fe 2+ and Fe 3+ and their hydrates such as iron hydroxide It has strong flocculation and precipitation effects on phosphorus, and can also generate polymers with adsorption and coagulation effects, such as part of Fe 3+ hydrolysis, such as [Fe 2 (OH) 2 ] 4+ , [Fe 3 ( OH) 4 ] 5+ , [Fe 5 (OH) 9 ] 6+ and other polynuclear hydroxyl complexes, which can act as flocculants and can interact with some suspended
  • Utilizing the dissolved oxygen contained in the aquaculture tail water and the oxygen produced by the electrolysis of the iron anode water can provide a large number of nitrosating and nitrifying bacteria in the biofilm attached to the suspended filler 32 with the dissolved oxygen required for the nitrification reaction, so that the ammonia It is converted into nitrite nitrogen and nitrate nitrogen, so there is no need to set up air pump to increase oxygen; at the same time, due to the rapid consumption of dissolved oxygen, the water in the pool, especially the underwater layer of the pool, quickly forms an anoxic or anaerobic water environment, which promotes the denitrification and denitrification reaction The progress.
  • the heterotrophic denitrifying bacteria in the pond use the organic carbon source in the aquaculture water as an electron donor to cause a denitrification reaction, so that the nitrate nitrogen eventually generates nitrogen through the denitrification reaction and overflows the system to be removed.
  • the hydrogen produced by the cathode electrolysis of water can be used as an electron donor for hydrogen autotrophic denitrifying bacteria, and the CO 2 in the tail water can provide an inorganic carbon source for these autotrophic bacteria, and an autotrophic denitrification reaction occurs to make nitrates. Nitrogen generates nitrogen gas through denitrification reaction and overflows the system to be removed.
  • the hydrogen produced by the electrolysis of water can stimulate the growth and metabolism of autotrophic denitrifying bacteria attached to the surface of the suspended filler 32.
  • the redox substances produced by the electrolysis provide a suitable environment for the growth and reproduction of microorganisms, which is beneficial to the growth of autotrophic denitrifying bacteria.
  • the denitrification process provides inorganic carbon sources and electron donors to further promote the autotrophic denitrification process, thereby improving the removal of total nitrogen.
  • the suspended filler with a density of 0.92 ⁇ 0.98g/cm 3 has greater friction, which can better remove the surface oxide of (anode) iron and prevent (anode) iron
  • the surface is passivated by forming a dense covering layer with oxide, which affects the normal progress of the electrode electrolysis reaction and effectively solves the passivation problem of (anode) iron.
  • the micro current can strengthen the bacteria and other microorganisms in the biofilm on the suspended filler 32, can change the permeability of the bacterial cell membrane, and help the enzymes in the bacterial cell membrane to pass through the cell membrane to the wastewater for a series of enzymatic reactions. It increases the contact between the enzymes in the cell membrane and the reaction substrate in the water, thereby enhancing the effect of degrading nitrogen and phosphorus in aquaculture wastewater to a certain extent; in addition, the microcurrent can also directly stimulate and strengthen the activity of extracellular enzymes secreted by certain bacteria. Promote the degradation of nitrogen, phosphorus and other pollutants in the water.
  • the carbon source supplement device 35 is used to add supplementary carbon sources such as brown sugar. It can be equipped with an automatic dosing device, regularly add a certain amount of brown sugar to the solution tank, start the mixer for dissolution, and automatically put a certain amount into the pool through the metering pump through the pipeline to continuously and quickly promote the heterotrophic denitrification reaction get on.
  • heterotrophic denitrification is several times (about 7 times) faster than autotrophic denitrification, at the same time, the population growth and propagation speed of heterotrophic denitrifying bacteria are higher than that of autotrophic denitrifying bacteria. Therefore, adding additional organic carbon sources such as brown sugar can significantly accelerate denitrification and denitrification.
  • the removal rate of TP has a certain positive correlation with the removal rate of TN, that is, when the TN removal effect is good, TP also has a good removal effect.
  • the iron electrode can provide electrons required for the denitrification reaction, has a certain enhanced denitrification effect, promotes the reduction of the mass concentration of NO 3 -- N and TN, and is beneficial to promote the phosphorus accumulating bacteria in the filler biofilm and in the water Biological phosphorus removal, synergistically promotes the removal of TP.
  • the supplementary carbon source used in the present invention efficiently promotes the denitrification device, which greatly promotes the continuous progress of denitrification and promotes the reduction of NO 3 -- N and TN mass concentrations.
  • the electrode-suspended filler coupling technology of the present invention and the supplementary carbon source efficiently promote the integration and integration of the denitrification technology and cooperate with each other to improve the efficiency and removal rate of nitrogen and phosphorus removal.
  • Sludge thickening and dewatering device 5 Using sludge filter press equipment or setting up filter layer drying tank facilities, the thickened and dewatered sludge is formed into mud cake (organic fertilizer) and transported out of the system, and the filtered water is Return to the sewage collection tank 1, or discharge out of the system.
  • mud cake organic fertilizer
  • the ozone and ultraviolet combination kill pathogenic microorganism pool 4 is formed by the combination of ozone pool 41 and ultraviolet lamp-aeration pool 42.
  • the combined pool is adjacent to the electrode-suspended filler coupled biological filter processing unit 3, and the water treated by the electrode-suspended filler coupled biological filter processing unit 3 flows into the ozone pool 41, and is set on the lower or bottom layer of the water in the ozone pool 41
  • the microporous aeration pan 411 is connected to the ozone generator outside the pool through a pipeline, and ozone is input at regular intervals (usually 4-12 times a day) to treat the water body.
  • the single duration of ozone treatment is 20-60min;
  • the treated water flows into the UV lamp-aeration tank 42, where the upper and middle layer of the water in the pool is provided with an immersion UV lamp 421 or the upper layer is provided with a UV lamp 421, and the bottom layer is provided with an oxygen-enhancing microporous tube 422, which is connected by a pipe
  • the air pump outside the pool the air is fed into the oxygen-enhancing microporous tube 422 to add oxygen to the pool water.
  • the continuously generated tiny bubbles can clean the quartz tube wall of the UV lamp 421 to prevent adhesion of attachments and maintain high UV Light transmittance; the pool water in the ultraviolet lamp-aeration tank 42 flows from bottom to top at a certain flow rate to produce an upward flow, which flows through the ultraviolet light area constructed by the combination of ultraviolet light 421.
  • the ozone in the water is in the ultraviolet light Under the irradiation of, it can generate more oxidative hydroxyl radicals.
  • the hydroxyl radicals will quickly react with oxidizable substances in the water to accelerate the decomposition of ozone. Because hydroxyl radicals are more oxidizing than ozone, they can be deeply oxidized.
  • the residual ozone concentration prevents the residual ozone concentration from entering the breeding pond with the effluent and endangering the breeding animals;
  • the hydraulic residence time HRT of the water treatment in the ultraviolet lamp-aeration tank 42 is about 15-40 minutes, and the purified water after treatment is set in the upper part of the pond
  • the water collection pipe at the water outlet is collected and then connected to the drain pipe to flow out and return to the breeding pond 6.
  • a sludge bucket 7 is installed at the bottom of the ozone tank 41 and the ultraviolet lamp-aeration tank 42 to settle the sludge in the water.
  • the sludge bucket 7 is equipped with a sludge discharge pipe to regularly discharge sewage containing sludge. To sludge thickening and dewatering device 5.
  • the water in the aquaculture pond refers to the water quality in the aquaculture pond in the circulating water aquaculture system during the breeding period;
  • the treated effluent refers to the purified water quality after the ozone-ultraviolet combination kills pathogenic microorganism tank 4;
  • the external drainage refers to the sludge through the sludge thickening and dewatering device The filtered water after concentrated dehydration can be discharged from the system.
  • the water quality in the aquaculture pond in the recirculating aquaculture system during the aquaculture period can meet the Class III water quality standard in the National Surface Water Environmental Quality Standard (GB3838-2002) and the National Fishery Water Quality Standard (GB11607-1989) ;
  • the quality of the discharged water outside the system can meet the national "Surface Water Environmental Quality Standards" (GB3838-2002) in the Class III water quality standards and the "Freshwater Farming Tail Water Discharge Requirements" (SC/T 9101) stipulated in the first level discharge standards .
  • the present invention mainly integrates iron cation phosphate precipitation reaction, iron cation hydrate and its polymer flocculation precipitation effect on phosphorus and other particles, nitrification through a series of physical, chemical and microbiological actions produced in the biological filter. Reaction and denitrification reaction, etc., to achieve continuous, stable and efficient phosphorus and nitrogen removal, organic matter degradation and suspended solids concentration reduction effects. It has the advantages of simple device structure, less sludge production and no secondary pollution.
  • the invention integrally realizes the dual functions of circulating aquaculture water treatment and tail water up-to-standard discharge treatment, and has the advantages of saving land, high water treatment efficiency, low investment and operating costs, simple management and the like.
  • the invention has the characteristics of high water treatment efficiency and continuous maintenance of high water quality in the breeding system, and the water cycle utilization rate can reach 95% to 98%; it can not only fully meet the healthy breeding needs of the breeding objects, and realize the healthy growth of the breeding objects, but also has a tail.
  • the water treatment function can realize the discharge of tail water up to standard. It solves the problem that the current circulating aquaculture water treatment system has a single function and does not have the ability to discharge the tail water up to the standard.

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Abstract

Disclosed is a recirculating aquaculture water treatment system integrating tailwater treatment, the system comprising: a wastewater collection tank (1), a physical filtration device (2), a biofilter processing unit employing electrode and suspended-filler coupling technology (3), and an ozone-ultraviolet combined pathogen-killing microorganism tank (4), which are connected in sequence. The wastewater collection tank (1), the physical filtration device (2), the biofilter processing unit employing electrode and suspended-filler coupling technology (3), and the ozone-ultraviolet combined pathogen-killing microorganism tank (4) are all connected to a sludge thickening and dewatering device (5). The ozone-ultraviolet combined pathogen-killing microorganism tank (4) is further connected to an aquaculture tank (6). The invention helps sustain the water quality of the aquaculture system.

Description

一种循环水养殖暨尾水处理一体化水处理系统Integrated water treatment system for circulating aquaculture and tail water treatment 技术领域Technical field
本发明涉及一种循环水养殖暨尾水处理一体化水处理系统。The invention relates to an integrated water treatment system for circulating aquaculture and tail water treatment.
背景技术Background technique
循环水养殖近些年来发展迅速,养殖规模日益扩大。淡水循环水养殖的种类主要有鳗鲡、鲟鱼、鳕鱼、罗非鱼和凡纳滨对虾等,具有节水、节地、高产、高效和水产品优质安全的优点。虽然目前许多的日水循环利用率可达90%以上,甚至国际领先水平的最高水循环利用率可达97%。但是,一般每天仍然有10%左右的较高浓度的废水(主要是水处理过程中,处理单元的反冲水或排污水,含残饵、粪便、脱落的生物膜等高浓度氮和磷污泥水)尾水需要排出系统外,该尾水除了可使用压滤机或其他的颗粒物污泥浓缩脱水设备设施对该污水进行污泥浓缩脱水形成泥饼外运外,剩余的大部份污水(≥98%)中含有高浓度的总氮(一般>5mg/L)和总磷(一般>1mg/L),即循环水养殖系统产生的外排尾水,超过了《淡水养殖尾水排放要求》(SC/T 9101)规定的排放标准,也超过了国家《地表水环境质量标准》(GB3838-2002)中的III类水质标准。目前对循环水养殖系统产生的外排养殖尾水基本未经处理直接排放至周边水域,极少数的在系统外另外再建设生态塘、人工湿地或结合使用化学药剂絮凝沉淀等深度处理,以实现达标排放。但,需要增加占地面积,设备设施投资和运行成本。许多养殖场因受土地面积限制和处理成本高的问题,未能开展尾水排放处理,污染了周边水域环境或面临因环保不达标而被强制停产的问题。Circulating aquaculture has developed rapidly in recent years, and the scale of aquaculture has been expanding. The types of freshwater circulating aquaculture mainly include eel, sturgeon, cod, tilapia and Litopenaeus vannamei, etc., which have the advantages of water saving, land saving, high yield, high efficiency and high quality and safety of aquatic products. Although many of the current daily water cycle utilization rates can reach more than 90%, even the highest international water cycle utilization rate can reach 97%. However, generally there is still about 10% of high-concentration wastewater every day (mainly in the water treatment process, the backwash water or sewage of the treatment unit, containing residual bait, feces, and falling biofilms and other high-concentration nitrogen and phosphorus pollution Sludge) The tail water needs to be discharged from the system. In addition to the filter press or other particulate sludge thickening and dewatering equipment, the tail water can be used to thicken and dehydrate the sewage to form a mud cake. Most of the remaining sewage (≥98%) contains high concentrations of total nitrogen (generally> 5mg/L) and total phosphorus (generally> 1mg/L), that is, the effluent tail water produced by the recirculating aquaculture system, which exceeds the "Freshwater Aquaculture Tail Water Discharge" The discharge standards stipulated in "Requirements" (SC/T 9101) also exceed the Class III water quality standards in the National Environmental Quality Standards for Surface Water (GB3838-2002). At present, the effluent aquaculture tail water produced by the circulating aquaculture system is basically discharged directly to the surrounding waters without treatment. A very small number of additional ecological ponds, artificial wetlands or combined use of chemical flocculation and sedimentation are further processed outside the system to achieve Discharge. However, it needs to increase the floor space, equipment investment and operating costs. Many farms have failed to carry out tail water discharge treatment due to land area restrictions and high treatment costs, polluting the surrounding water environment or facing the problem of forced suspension of production due to non-compliance with environmental protection standards.
当前的循环水养殖水处理系统,主要依据养殖对象(如鱼虾类)的生物学特性、生态习性和对水质主要因子如氨氮和亚硝酸盐氮等的安全浓度需求,有针对性地设计水处理工艺和构建相应的水处理单元,使循环养殖用水的水质能符合养殖对象的健康养殖需求,实现养殖对象的健康生长。而不具备对尾水达标排放的处理功能。The current circulating water aquaculture water treatment system is based on the biological characteristics and ecological habits of the aquaculture objects (such as fish and shrimp) and the safe concentration requirements for the main factors of water quality such as ammonia nitrogen and nitrite nitrogen. The treatment process and the construction of the corresponding water treatment unit enable the water quality of the circulating aquaculture water to meet the healthy aquaculture requirements of the aquaculture objects and realize the healthy growth of the aquaculture objects. It does not have the function of treating tail water up to standard discharge.
发明概述Summary of the invention
技术问题technical problem
本发明要解决的技术问题,在于提供一种循环水养殖暨尾水处理一体化水处理系统,其具有水处理效率高,能持续维持养殖系统水质优的特点,水循环利用率可达95%~98%;不仅能充分满足养殖对象的健康养殖需求,实现养殖对象的健康生长,而且具有尾水处理功能,可实现尾水达标排放。The technical problem to be solved by the present invention is to provide an integrated water treatment system for circulating aquaculture and tail water treatment, which has the characteristics of high water treatment efficiency and continuous maintenance of high water quality in the breeding system, and the water cycle utilization rate can reach 95%~ 98%; not only can fully meet the healthy breeding needs of the breeding objects and realize the healthy growth of the breeding objects, but also has the tail water treatment function, which can achieve the discharge of the tail water up to the standard.
问题的解决方案The solution to the problem
技术解决方案Technical solutions
本发明是这样实现的:The present invention is realized as follows:
一种循环水养殖暨尾水处理一体化水处理系统,所述水处理系统包括集污池、物理过滤装置、电极-悬浮填料耦合生物滤池处理单元、臭氧紫外线组合灭病原微生物池以及污泥浓缩脱水装置;所述集污池与物理过滤装置相连接,所述物理过滤装置连接至电极-悬浮填料耦合生物滤池处理单元,所述电极-悬浮填料耦合生物滤池处理单元与臭氧紫外线组合灭病原微生物池相邻设置,所述集污池、物理过滤装置、电极-悬浮填料耦合生物滤池处理单元、臭氧紫外线组合灭病原微生物池均与污泥浓缩脱水装置相连接,所述臭氧紫外线组合灭病原微生物池还与养殖池相连;An integrated water treatment system for circulating aquaculture and tail water treatment. The water treatment system includes a sewage collection tank, a physical filtration device, an electrode-suspended filler coupled biological filter treatment unit, an ozone and ultraviolet combination to kill pathogenic microorganisms and sludge Concentration and dehydration device; the sewage collection tank is connected with a physical filter device, the physical filter device is connected to an electrode-suspended filler coupled biological filter processing unit, and the electrode-suspended filler coupled biological filter processing unit is combined with ozone ultraviolet rays The pathogen-killing microorganism pool is arranged adjacently. The sewage collection tank, the physical filter device, the electrode-suspended filler coupling biological filter processing unit, and the ozone-ultraviolet combination pathogen-killing microorganism pool are all connected to the sludge concentration and dehydration device. The combined pathogenic microorganism pool is also connected to the breeding pool;
所述电极-悬浮填料耦合生物滤池处理单元包括生物滤池、悬浮填料、直流阴阳电极列阵组合、电动搅拌装置以及碳源补充装置,所述悬浮填料设置在生物滤池内,所述直流阴阳电极列阵组合设置在所述生物滤池的上部,所述电动搅拌装置设置在所述生物滤池的下部,所述生物滤池的底部设置有污泥斗,所述电动搅拌装置设置在污泥斗上方,所述碳源补充装置通过管道连接至生物滤池;The electrode-suspended filler coupled biological filter processing unit includes a biological filter, a suspended filler, a direct current cathode and anode electrode array combination, an electric stirring device, and a carbon source supplement device. The suspended filler is arranged in the biological filter, and the direct current The cathode and anode electrode array combination is arranged on the upper part of the biological filter, the electric stirring device is arranged on the lower part of the biological filter, the bottom of the biological filter is arranged with a sludge bucket, and the electric stirring device is arranged on Above the sludge bucket, the carbon source supplement device is connected to the biological filter through a pipeline;
所述悬浮填料与所述生物滤池内水体的体积比为20%~50%,所述悬浮填料的密度为0.92~0.98g/cm 3;所述直流阴阳电极列阵组合中阳极为铁,阴极为铁、碳或铜;所述电动搅拌装置的转速为100~300r/min。 The volume ratio of the suspended filler to the water in the biological filter is 20% to 50%, and the density of the suspended filler is 0.92 to 0.98 g/cm 3 ; the anode in the DC cathode and anode electrode array combination is iron, The cathode is iron, carbon or copper; the rotational speed of the electric stirring device is 100-300 r/min.
进一步地,所述悬浮填料为高密度聚乙烯材质,比表面积大于500m 2/m 3Further, the suspended filler is made of high-density polyethylene with a specific surface area greater than 500 m 2 /m 3 .
进一步地,所述直流阴阳电极列阵组合的相邻电极之间的间距为2-30cm,运行电压和电流分别为:直流电压为12~36V,微电流密度为0.1~1.0mA/cm 2Further, the distance between adjacent electrodes of the direct current cathode and anode electrode array combination is 2-30 cm, the operating voltage and current are respectively: the direct current voltage is 12 to 36 V, and the micro current density is 0.1 to 1.0 mA/cm 2 .
进一步地,所述生物滤池为2个以上池体串联组合,可部分或全部池体设置直流阴阳电极列阵组合。Further, the biological filter is a combination of more than two cells in series, and some or all of the cells can be equipped with a direct current cathode and anode electrode array combination.
进一步地,所述物理过滤装置为自动反冲筛网过滤器、微滤机或弧形筛。Further, the physical filtering device is an automatic backwash screen filter, a micro filter or an arc screen.
进一步地,所述臭氧紫外线组合灭病原微生物池包括相邻设置的臭氧池和紫外灯-增氧池,所述臭氧池底部设置有微孔曝气盘,所述微孔曝气盘与池体外的臭氧发生器相连;所述紫外灯-增氧池上部设置有紫外灯,所述紫外灯-增氧池的底部设置有增氧微孔管,所述增氧微孔管与池体外的气泵相连,所述紫外灯-增氧池的进水口设置在底部,出水口设置在上部;所述臭氧池和紫外灯-增氧池的底部均设置有污泥斗,所述污泥斗与污泥浓缩脱水装置相连接。Further, the ozone-ultraviolet combination inactivating pathogenic microorganisms tank includes an ozone tank and an ultraviolet lamp-aeration tank which are arranged adjacently, and a microporous aeration pan is arranged at the bottom of the ozone tank, and the microporous aeration pan is connected to the outside of the tank. Connected to the ozone generator; the ultraviolet lamp-the upper part of the aeration tank is provided with an ultraviolet lamp, the bottom of the ultraviolet lamp-the aeration tank is provided with an aeration microporous tube, the aeration microporous tube is connected to the air pump outside the tank Connected, the water inlet of the ultraviolet lamp-aeration tank is set at the bottom, and the water outlet is set at the upper part; the bottom of the ozone tank and the ultraviolet lamp-aeration tank are both provided with a sludge bucket, and the sludge bucket is The mud thickening and dewatering device is connected.
进一步地,所述臭氧发生器每天4~12次输入臭氧对水体进行处理,每次持续时间20~60min;所述紫外灯-增氧池内的水力停留时间为15~40min。Further, the ozone generator inputs ozone 4 to 12 times a day to treat the water body, and each lasts for 20-60 minutes; the hydraulic residence time in the ultraviolet lamp-aeration tank is 15-40 minutes.
进一步地,所述紫外灯为浸没式设置。Further, the ultraviolet lamp is immersed.
发明的有益效果The beneficial effects of the invention
有益效果Beneficial effect
本发明具有如下优点:The present invention has the following advantages:
总之,本发明主要通过在生物滤池中产生的系列物理、化学和微生物作用,综合铁阳离子磷酸盐沉析反应、铁阳离子水化物及其多聚物对磷及其他颗粒物的絮凝沉淀作用、硝化反应和反硝化反应等,达到持续、稳定、高效的除磷脱氮、降解有机质和降低悬浮物浓度效果。具有装置结构简单、产污泥量少和无二次污染等优点。In short, the present invention mainly integrates iron cation phosphate precipitation reaction, iron cation hydrate and its polymer flocculation precipitation effect on phosphorus and other particles, nitrification through a series of physical, chemical and microbiological actions produced in the biological filter. Reaction and denitrification reaction, etc., to achieve continuous, stable and efficient phosphorus and nitrogen removal, organic matter degradation and suspended solids concentration reduction effects. It has the advantages of simple device structure, less sludge production and no secondary pollution.
本发明一体化地实现循环水养殖用水处理和尾水达标排放处理的双功能,具有节地,水处理效率高,投资和运行成本低,管理简便等优点。本发明具有水处理效率高,能持续维持养殖系统水质优的特点,水循环利用率可达95%~98%;不仅能充分满足养殖对象的健康养殖需求,实现养殖对象的健康生长,而且具有尾水处理功能,可实现尾水达标排放。解决了当前的循环水养殖水处理系统功能单一,不具备尾水达标排放处理能力的问题。The invention integrally realizes the dual functions of circulating aquaculture water treatment and tail water up-to-standard discharge treatment, and has the advantages of saving land, high water treatment efficiency, low investment and operating costs, simple management and the like. The invention has the characteristics of high water treatment efficiency and continuous maintenance of high water quality in the breeding system, and the water cycle utilization rate can reach 95% to 98%; it can not only fully meet the healthy breeding needs of the breeding objects, and realize the healthy growth of the breeding objects, but also has a tail. The water treatment function can realize the discharge of tail water up to standard. It solves the problem that the current circulating aquaculture water treatment system has a single function and does not have the ability to discharge the tail water up to the standard.
对附图的简要说明Brief description of the drawings
附图说明Description of the drawings
下面参照附图结合实施例对本发明作进一步的说明。The present invention will be further described below with reference to the drawings and embodiments.
图1为本发明的结构示意图。Figure 1 is a schematic diagram of the structure of the present invention.
图2为本发明中电极-悬浮填料耦合生物滤池处理单元、臭氧紫外线组合灭病原微生物池配合结构示意图。Fig. 2 is a schematic diagram of the combined structure of the electrode-suspended filler coupled biological filter processing unit and the ozone-ultraviolet combined anti-pathogenic microorganism pool in the present invention.
发明实施例Invention embodiment
本发明的实施方式Embodiments of the invention
参阅图1-2,本发明涉及一种循环水养殖暨尾水处理一体化水处理系统,所述水处理系统包括集污池1、物理过滤装置2、电极-悬浮填料耦合生物滤池处理单元3、臭氧紫外线组合灭病原微生物池4以及污泥浓缩脱水装置5;所述集污池1与物理过滤装置2相连接,所述物理过滤装置2连接至电极-悬浮填料耦合生物滤池处理单元3,所述电极-悬浮填料耦合生物滤池处理单元3与臭氧紫外线组合灭病原微生物池4相邻设置,所述集污池1、物理过滤装置2、电极-悬浮填料耦合生物滤池处理单元3、臭氧紫外线组合灭病原微生物池4均与污泥浓缩脱水装置5相连接,所述臭氧紫外线组合灭病原微生物池4还与养殖池6相连;Referring to Figures 1-2, the present invention relates to an integrated water treatment system for circulating aquaculture and tail water treatment. The water treatment system includes a sewage collection tank 1, a physical filter device 2, an electrode-suspended filler coupled biological filter processing unit 3. The ozone and ultraviolet combination kill pathogenic microorganism pool 4 and the sludge thickening and dewatering device 5; the sewage collection tank 1 is connected to the physical filter device 2, and the physical filter device 2 is connected to the electrode-suspended filler coupling biological filter processing unit 3. The electrode-suspended filler coupling biological filter processing unit 3 is arranged adjacent to the ozone-ultraviolet combination inactivating pathogenic microorganism pool 4, the sewage collection tank 1, the physical filter device 2, the electrode-suspended filler coupled biological filter processing unit 3. The ozone-ultraviolet combined pathogenic microorganism pool 4 is connected to the sludge thickening and dewatering device 5, and the ozone-ultraviolet combined pathogenic microorganism pool 4 is also connected to the breeding pool 6;
所述电极-悬浮填料耦合生物滤池处理单元3包括生物滤池31、悬浮填料32、直流阴阳电极列阵组合33、电动搅拌装置34以及碳源补充装置35,所述悬浮填料32设置在生物滤池31内,所述直流阴阳电极列阵组合33设置在所述生物滤池31的上部,所述电动搅拌装置34设置在所述生物滤池31的下部,所述生物滤池31的底部设置有污泥斗7,所述电动搅拌装置34设置在污泥斗7上方,所述碳源补充装置35通过管道连接至生物滤池31;The electrode-suspended filler coupled biological filter processing unit 3 includes a biological filter 31, a suspended filler 32, a direct current cathode and anode electrode array combination 33, an electric stirring device 34, and a carbon source supplement device 35. The suspended filler 32 is installed in the biological filter. In the filter tank 31, the direct current cathode and anode electrode array assembly 33 is arranged at the upper part of the biological filter tank 31, the electric stirring device 34 is arranged at the lower part of the biological filter tank 31, and the bottom of the biological filter tank 31 A sludge bucket 7 is provided, the electric stirring device 34 is installed above the sludge bucket 7, and the carbon source supplement device 35 is connected to the biological filter 31 through a pipeline;
所述悬浮填料32与所述生物滤池31内水体的体积比为20%~50%,所述悬浮填料32的密度为0.92~0.98g/cm 3;所述直流阴阳电极列阵组合33中阳极为铁,阴极为铁、碳或铜;所述电动搅拌装置34的转速为100~300r/min。 The volume ratio of the suspended filler 32 to the water in the biological filter 31 is 20% to 50%, and the density of the suspended filler 32 is 0.92 to 0.98 g/cm 3 ; in the direct current cathode and anode electrode array combination 33 The anode is iron, and the cathode is iron, carbon or copper; the rotational speed of the electric stirring device 34 is 100-300 r/min.
所述悬浮填料32为高密度聚乙烯材质,比表面积大于500m 2/m 3The suspended filler 32 is made of high-density polyethylene with a specific surface area greater than 500 m 2 /m 3 .
所述直流阴阳电极列阵组合33的相邻电极之间的间距为2-30cm,运行电压和电流分别为:直流电压为12~36V,微电流密度为0.1~1.0mA/cm 2The distance between adjacent electrodes of the direct current cathode and anode electrode array combination 33 is 2-30 cm, the operating voltage and current are respectively: the direct current voltage is 12 to 36 V, and the micro current density is 0.1 to 1.0 mA/cm 2 .
所述生物滤池31为2个以上池体串联组合,可部分或全部池体设置直流阴阳电极列阵组合33。The biological filter 31 is a combination of two or more tank bodies in series, and a direct current cathode and anode electrode array combination 33 may be provided in part or all of the tank bodies.
所述物理过滤装置2为自动反冲筛网过滤器、微滤机或弧形筛。The physical filtration device 2 is an automatic backwashing screen filter, a micro filter or an arc screen.
所述臭氧紫外线组合灭病原微生物池4包括相邻设置的臭氧池41和紫外灯-增氧池42,所述臭氧池41底部设置有微孔曝气盘411,所述微孔曝气盘411与池体外的臭氧发生器相连;所述紫外灯-增氧池42上部设置有紫外灯421,所述紫外灯-增氧池42的底部设置有增氧微孔管422,所述增氧微孔管422与池体外的气泵相连,所述紫外灯-增氧池42的进水口设置在底部,出水口设置在上部;所述臭氧池41和紫外灯-增氧池42的底部均设置有污泥斗7,所述污泥斗7与污泥浓缩脱水装置5相连接。The ozone-ultraviolet combination inactivating pathogenic microorganisms pool 4 includes an ozone pool 41 and an ultraviolet lamp-aeration pool 42 which are adjacently arranged. The bottom of the ozone pool 41 is provided with a microporous aeration pan 411, the microporous aeration pan 411 Connected to the ozone generator outside the tank; the ultraviolet lamp-aeration tank 42 is provided with an ultraviolet lamp 421 at the upper part, and the bottom of the ultraviolet lamp-aeration tank 42 is provided with an oxygen-enhancing microporous tube 422, the oxygen-enhancing micro The orifice tube 422 is connected with an air pump outside the tank. The water inlet of the ultraviolet lamp-aeration tank 42 is set at the bottom, and the water outlet is set at the upper part; the bottom of the ozone tank 41 and the ultraviolet lamp-aeration tank 42 are both set The sludge bucket 7 is connected to the sludge thickening and dewatering device 5.
所述臭氧发生器每天4~12次输入臭氧对水体进行处理,每次持续时间20~60min;所述紫外灯-增氧池42内的水力停留时间为15~40min。The ozone generator inputs ozone 4 to 12 times a day to treat the water body, and the duration of each time is 20-60 minutes; the hydraulic residence time in the ultraviolet lamp-aeration tank 42 is 15-40 minutes.
所述紫外灯421为浸没式设置。本发明工作过程如下:养殖尾水进入集污池1后,经水泵抽提进入物理过滤装置2,经过滤后的水进入电极-悬浮填料耦合生物滤池处理单元3,而含残饵和粪便等大颗粒物质的反冲水(≤1.5%)进入污泥浓缩脱水装置5;在污泥浓缩脱水装置5中将浓缩脱水后的污泥形成泥饼有机肥外运离开系统,浓缩滤出的水则返回集污池1,或排出系统外;在电极-悬浮填料耦合生物滤池处理单元3中,生物滤池31底部设有污泥斗7,可定期排污,该污泥水(≤3%)则排入污泥浓缩脱水装置5;经电极-悬浮填料耦合生物滤池处理单元3处理后的水,流入臭氧紫外线组合灭病原微生物池4进行杀灭病原微生物和适度增氧后得到净化水,该净化水再流回养殖池;臭氧紫外线组合灭病原微生物池4设有污泥斗7,可定期排污,该污泥水(≤0.5%)排入污泥浓缩脱水装置5。The ultraviolet lamp 421 is immersed. The working process of the present invention is as follows: after the farming tail water enters the sewage collection tank 1, it is extracted by the water pump into the physical filter device 2, and the filtered water enters the electrode-suspended filler coupling biological filter processing unit 3, and contains residual bait and feces The backflush water (≤1.5%) of other large particles enters the sludge thickening and dewatering device 5; in the sludge thickening and dewatering device 5, the thickened and dewatered sludge is formed into a mud cake, and the organic fertilizer is transported out of the system, and the concentrated and filtered The water returns to the sewage collection tank 1, or is discharged out of the system; in the electrode-suspended filler coupled biological filter processing unit 3, a sludge bucket 7 is provided at the bottom of the biological filter 31, which can be discharged regularly. The sludge water (≤3 %) is discharged into the sludge thickening and dewatering device 5; the water treated by the electrode-suspended filler coupling biological filter processing unit 3 flows into the ozone and ultraviolet combination to kill pathogenic microorganisms pool 4 to kill pathogenic microorganisms and moderate aeration to obtain purification The purified water flows back to the breeding pond; the ozone-ultraviolet combined anti-pathogenic microorganism pond 4 is equipped with a sludge bucket 7, which can be discharged regularly, and the sludge water (≤0.5%) is discharged into the sludge thickening and dewatering device 5.
各设备的工作原理如下:The working principle of each device is as follows:
1、集污池1主要是汇集全部养殖池排出的养殖尾水,池内设置2台以上潜水泵(其中1台为备用),把池水抽提至物理过滤装置2。1. Sewage collection tank 1 mainly collects the aquaculture tail water discharged from all aquaculture tanks. More than 2 submersible pumps (1 of which are spare) are installed in the tank to extract the water to the physical filtration device 2.
2、物理过滤装置2为自动反冲筛网过滤器、微滤机或弧形筛等物理过滤设备,分离水中的大颗粒物质,自动把含残饵和粪便等大颗粒物质的反冲水(≤1.5%)进入污泥脱水浓缩装置5,而经筛网过滤后的水进入电极-悬浮填料耦合生物滤池处理单元3。2. The physical filtration device 2 is a physical filtration device such as an automatic backwashing screen filter, a microfilter or an arc screen, which separates large particulate matter in the water, and automatically backflushes the water containing large particulate matter such as residual bait and feces ( ≤1.5%) enter the sludge dewatering and thickening device 5, and the water filtered by the screen enters the electrode-suspended filler coupling biological filter processing unit 3.
3、电极-悬浮填料耦合生物滤池处理单元3的工作原理如下:3. The working principle of electrode-suspended filler coupling biological filter processing unit 3 is as follows:
(1)由于直流阴阳电极列阵组合33的直流电场的作用,铁(阳极)生成大量的铁阳离子,产生的大量Fe 2+和Fe 3+与养殖尾水中的磷酸盐发生沉析反应,形成颗粒状、非溶解性的物质而沉降于生物滤池31的底部污泥斗7内;同时,铁阳离子经过一系列水解聚合反应,Fe 2+和Fe 3+以及它们的水化物如氢氧化铁等对磷都具有较强的絮凝、沉淀作用,还可生成具有吸附凝聚作用的多聚物,如部份Fe 3+水解产生的如[Fe 2(OH) 2] 4+、[Fe 3(OH) 4] 5+、[Fe 5(OH) 9] 6+等多核羟基络合物,可以起到絮凝剂的作用,能与养殖尾水中一些悬浮物质(含悬浮态磷,包括生物磷和难溶磷酸盐颗粒)、颗粒物质和电解质等发生沉聚作用,而沉降于生物滤池31的底部污泥斗7内。 (1) Due to the action of the direct current electric field of the direct current cathode and anode electrode array 33, the iron (anode) generates a large amount of iron cations, and the large amount of Fe 2+ and Fe 3+ produced reacts with the phosphate in the aquaculture tail water to form Granular, insoluble substances settle in the bottom sludge bucket 7 of the biological filter 31; at the same time, iron cations undergo a series of hydrolytic polymerization reactions, Fe 2+ and Fe 3+ and their hydrates such as iron hydroxide It has strong flocculation and precipitation effects on phosphorus, and can also generate polymers with adsorption and coagulation effects, such as part of Fe 3+ hydrolysis, such as [Fe 2 (OH) 2 ] 4+ , [Fe 3 ( OH) 4 ] 5+ , [Fe 5 (OH) 9 ] 6+ and other polynuclear hydroxyl complexes, which can act as flocculants and can interact with some suspended substances (including suspended phosphorus, including biological phosphorus and The insoluble phosphate particles, particulate matter, electrolytes, etc. undergo a sedimentation effect and settle in the bottom sludge bucket 7 of the biological filter 31.
(2)利用养殖尾水中含有的溶解氧及铁阳极电解水而产生的氧气,可为悬浮填料32附着的生物膜中大量的亚硝化和硝化细菌提供进行硝化反应所需要的溶解氧,使氨氮转化为亚硝酸氮和硝酸氮,因此不需设置气泵增氧;同时,由于溶解氧的迅速消耗,使池内水体,特别是池水下层快速形成缺氧或厌氧水环境,推动反硝化脱氮反应的进行。(2) Utilizing the dissolved oxygen contained in the aquaculture tail water and the oxygen produced by the electrolysis of the iron anode water can provide a large number of nitrosating and nitrifying bacteria in the biofilm attached to the suspended filler 32 with the dissolved oxygen required for the nitrification reaction, so that the ammonia It is converted into nitrite nitrogen and nitrate nitrogen, so there is no need to set up air pump to increase oxygen; at the same time, due to the rapid consumption of dissolved oxygen, the water in the pool, especially the underwater layer of the pool, quickly forms an anoxic or anaerobic water environment, which promotes the denitrification and denitrification reaction The progress.
(3)池中存在的异养反硝化菌利用养殖水中的有机碳源做电子供体,发生反硝化反应,使硝酸盐氮最终经反硝化反应生成氮气而溢出系统从而被去除。(3) The heterotrophic denitrifying bacteria in the pond use the organic carbon source in the aquaculture water as an electron donor to cause a denitrification reaction, so that the nitrate nitrogen eventually generates nitrogen through the denitrification reaction and overflows the system to be removed.
(4)阴极电解水产生的氢气,可以作为氢自养反硝化细菌的电子供体,而尾水中的CO 2可为这些自养菌提供无机碳源,发生自养反硝化反应,使硝酸盐氮经反硝化反应生成氮气而溢出系统从而被去除。 (4) The hydrogen produced by the cathode electrolysis of water can be used as an electron donor for hydrogen autotrophic denitrifying bacteria, and the CO 2 in the tail water can provide an inorganic carbon source for these autotrophic bacteria, and an autotrophic denitrification reaction occurs to make nitrates. Nitrogen generates nitrogen gas through denitrification reaction and overflows the system to be removed.
此外,电解水产生的氢气,可刺激悬浮填料32表面附着的自养反硝化菌的生长代谢,同时,电解产生的氧化还原物质为微生物生长繁殖提供了适宜的环境,为自养反硝化菌的反硝化过程提供无机碳源和电子供体,进一步促进自养反硝化过程,从而提高了对总氮的去除。In addition, the hydrogen produced by the electrolysis of water can stimulate the growth and metabolism of autotrophic denitrifying bacteria attached to the surface of the suspended filler 32. At the same time, the redox substances produced by the electrolysis provide a suitable environment for the growth and reproduction of microorganisms, which is beneficial to the growth of autotrophic denitrifying bacteria. The denitrification process provides inorganic carbon sources and electron donors to further promote the autotrophic denitrification process, thereby improving the removal of total nitrogen.
(5)利用悬浮填料32的密度(0.92~0.98g/cm 3)接近于淡水,在生物滤池水体中易形成均匀的悬浮态,同时,在电动搅拌装置34的持续慢速搅动与水流流经下,可形成流化态,使悬浮填料32附着的生物膜容易与养殖废水中的污染物质持续流动接触,不仅有助于提高硝化反应及反硝化反应的速率,而且有利于悬浮填料32与水流不断摩擦与流经电极表面,同等体积下密度为0.92~0.98g/cm 3的悬浮填料摩擦力更大,能更好的去除(阳极)铁的表面被氧化物,防止(阳极)铁的表面被氧化物形成致密覆盖层而被钝化,影响电极电解反应的正常进行,有效解决了(阳极)铁的钝化问题。 (5) Utilizing the density (0.92~0.98g/cm 3 ) of the suspended filler 32 is close to fresh water, it is easy to form a uniform suspension in the water body of the biological filter. At the same time, the continuous slow stirring of the electric stirring device 34 and the water flow Under the condition, a fluidized state can be formed, so that the biofilm attached to the suspended filler 32 is easy to continuously flow and contact with the pollutants in the aquaculture wastewater, which not only helps to increase the rate of nitrification and denitrification reactions, but also facilitates the suspension of the filler 32 and The water flow continuously rubs and flows through the surface of the electrode. Under the same volume, the suspended filler with a density of 0.92~0.98g/cm 3 has greater friction, which can better remove the surface oxide of (anode) iron and prevent (anode) iron The surface is passivated by forming a dense covering layer with oxide, which affects the normal progress of the electrode electrolysis reaction and effectively solves the passivation problem of (anode) iron.
(6)微电流可对悬浮填料32上生物膜中细菌等微生物起强化作用,可改变细菌细胞膜的通透性,有助于细菌细胞膜内的酶通过细胞膜至废水中进行系列的酶促反应,增加了胞膜内的酶与水中反应底物的接触,从而一定程度上加强了降解养殖废水中氮磷的效果;此外,微电流也可直接刺激强化某些细菌分泌的胞外酶的活性,促进对水中氮磷及其他污染物的降解。(6) The micro current can strengthen the bacteria and other microorganisms in the biofilm on the suspended filler 32, can change the permeability of the bacterial cell membrane, and help the enzymes in the bacterial cell membrane to pass through the cell membrane to the wastewater for a series of enzymatic reactions. It increases the contact between the enzymes in the cell membrane and the reaction substrate in the water, thereby enhancing the effect of degrading nitrogen and phosphorus in aquaculture wastewater to a certain extent; in addition, the microcurrent can also directly stimulate and strengthen the activity of extracellular enzymes secreted by certain bacteria. Promote the degradation of nitrogen, phosphorus and other pollutants in the water.
(7)由于养殖尾水中的有机碳浓度一般较低,很快将被消耗完毕,为促进池中异养反硝化反应的进行,通过碳源补充装置35进行补充碳源如红糖等的投放。可配置自动投加装置,定期将一定量的红糖加入溶液桶,启动搅伴机进行溶解,经计量泵,通过管道按一定的量自动投入池中,以持续快速地促进异养反硝化反应的进行。(7) Since the concentration of organic carbon in the aquaculture tail water is generally low and will be consumed soon, in order to promote the progress of the heterotrophic denitrification reaction in the pond, the carbon source supplement device 35 is used to add supplementary carbon sources such as brown sugar. It can be equipped with an automatic dosing device, regularly add a certain amount of brown sugar to the solution tank, start the mixer for dissolution, and automatically put a certain amount into the pool through the metering pump through the pipeline to continuously and quickly promote the heterotrophic denitrification reaction get on.
由于异养反硝化的反应速率要几倍(约7倍)快速于自养反硝化反应,同时,异养反硝化菌的种群生长和扩繁速度均高于自养反硝化菌群。因此添加如红糖等补充有机碳源,可明显加速反硝化脱氮。Because the reaction rate of heterotrophic denitrification is several times (about 7 times) faster than autotrophic denitrification, at the same time, the population growth and propagation speed of heterotrophic denitrifying bacteria are higher than that of autotrophic denitrifying bacteria. Therefore, adding additional organic carbon sources such as brown sugar can significantly accelerate denitrification and denitrification.
而TP的去除率与TN去除率具有一定的正相关性,即TN去除效果好时,TP也具有较好的去除效果。本发明中,铁电极可提供反硝化反应需要的电子,具有一定的强化反硝化作用,促进NO 3 --N和TN质量浓度的下降,有利于促进填料生物膜中及水体中的聚磷菌生物除磷,协同促进TP的去除。此外,本发明使用的补充碳源高效促进反硝化装置,极大地促进了反硝化的持续进行,促进NO 3 --N和TN质量浓度的下降。协同促进了持续深度去除TP浓度。因此,本发明的电极-悬浮填料耦合技术与补充碳源高效促进反硝化技术集成融合一体,互相协同,提升了脱氮除磷效率和去除率。 And the removal rate of TP has a certain positive correlation with the removal rate of TN, that is, when the TN removal effect is good, TP also has a good removal effect. In the present invention, the iron electrode can provide electrons required for the denitrification reaction, has a certain enhanced denitrification effect, promotes the reduction of the mass concentration of NO 3 -- N and TN, and is beneficial to promote the phosphorus accumulating bacteria in the filler biofilm and in the water Biological phosphorus removal, synergistically promotes the removal of TP. In addition, the supplementary carbon source used in the present invention efficiently promotes the denitrification device, which greatly promotes the continuous progress of denitrification and promotes the reduction of NO 3 -- N and TN mass concentrations. Synergy promotes continuous deep removal of TP concentration. Therefore, the electrode-suspended filler coupling technology of the present invention and the supplementary carbon source efficiently promote the integration and integration of the denitrification technology and cooperate with each other to improve the efficiency and removal rate of nitrogen and phosphorus removal.
4、污泥浓缩脱水装置5,采用污泥压滤机设备或设置滤水层干化池设施,将浓缩脱水后的污泥形成泥饼(有机肥)外运离开系统,滤出的水则返回集污池1,或排出系统外。4. Sludge thickening and dewatering device 5. Using sludge filter press equipment or setting up filter layer drying tank facilities, the thickened and dewatered sludge is formed into mud cake (organic fertilizer) and transported out of the system, and the filtered water is Return to the sewage collection tank 1, or discharge out of the system.
5、臭氧紫外线组合灭病原微生物池4由臭氧池41和紫外灯-增氧池42组合形成 。该组合池与电极-悬浮填料耦合生物滤池处理单元3相邻,经电极-悬浮填料耦合生物滤池处理单元3处理后的水流入臭氧池41,在臭氧池41内水体的下层或底层设置微孔曝气盘411,经管道连接池外的臭氧发生器,每天定时(一般每天4~12次)输入臭氧对水体进行处理,臭氧处理的单次持续时间20~60min;5. The ozone and ultraviolet combination kill pathogenic microorganism pool 4 is formed by the combination of ozone pool 41 and ultraviolet lamp-aeration pool 42. The combined pool is adjacent to the electrode-suspended filler coupled biological filter processing unit 3, and the water treated by the electrode-suspended filler coupled biological filter processing unit 3 flows into the ozone pool 41, and is set on the lower or bottom layer of the water in the ozone pool 41 The microporous aeration pan 411 is connected to the ozone generator outside the pool through a pipeline, and ozone is input at regular intervals (usually 4-12 times a day) to treat the water body. The single duration of ozone treatment is 20-60min;
处理后的水流入紫外灯-增氧池42,池内水体的中上层设置浸没式紫外灯421或在上层设置紫外灯421,底层设置增氧微孔管422,增氧微孔管422经管道连接池外的气泵,空气输入增氧微孔管422内对池水增氧,同时,持续产生的微小气泡可对紫外灯421的外套石英管壁起到清洗作用,防止附着物粘附,维持紫外线高透光率;紫外灯-增氧池42内的池水以一定流速从下向上流动,产生上向流,流经由紫外灯421组合构建的紫外光区,在紫外光区内,水中的臭氧在紫外线的照射下,可生成氧化性更强的羟基自由基,羟基自由基会迅速和水中可被氧化的物质发生反应从而加速臭氧的分解,由于羟基自由基比臭氧具有更强的氧化性,可以深度氧化并迅速和水体中可被氧化的物质发生反应,从而达到更强的杀灭水中细菌、病毒、真菌、微藻、寄生虫、虫卵及孢子等微生物的能力,同时高效地去除了水体中臭氧浓度的残余,避免臭氧浓度的残余随出水进入养殖池,危及养殖动物;紫外灯-增氧池42内水处理的水力停留时间HRT约15~40min,处理后的净化水从设置在池上部出水口的集水管汇集后接排水管流出,返回至养殖池6。此外,在臭氧池41和紫外灯-增氧池42的底部都设置了污泥斗7,用于沉淀水中的污泥等,污泥斗7设置了排泥管可定期排出含污泥的污水至污泥浓缩脱水装置5。The treated water flows into the UV lamp-aeration tank 42, where the upper and middle layer of the water in the pool is provided with an immersion UV lamp 421 or the upper layer is provided with a UV lamp 421, and the bottom layer is provided with an oxygen-enhancing microporous tube 422, which is connected by a pipe The air pump outside the pool, the air is fed into the oxygen-enhancing microporous tube 422 to add oxygen to the pool water. At the same time, the continuously generated tiny bubbles can clean the quartz tube wall of the UV lamp 421 to prevent adhesion of attachments and maintain high UV Light transmittance; the pool water in the ultraviolet lamp-aeration tank 42 flows from bottom to top at a certain flow rate to produce an upward flow, which flows through the ultraviolet light area constructed by the combination of ultraviolet light 421. In the ultraviolet light area, the ozone in the water is in the ultraviolet light Under the irradiation of, it can generate more oxidative hydroxyl radicals. The hydroxyl radicals will quickly react with oxidizable substances in the water to accelerate the decomposition of ozone. Because hydroxyl radicals are more oxidizing than ozone, they can be deeply oxidized. Oxidize and quickly react with oxidizable substances in the water body, thereby achieving a stronger ability to kill bacteria, viruses, fungi, microalgae, parasites, eggs and spores and other microorganisms in the water, while efficiently removing the water The residual ozone concentration prevents the residual ozone concentration from entering the breeding pond with the effluent and endangering the breeding animals; the hydraulic residence time HRT of the water treatment in the ultraviolet lamp-aeration tank 42 is about 15-40 minutes, and the purified water after treatment is set in the upper part of the pond The water collection pipe at the water outlet is collected and then connected to the drain pipe to flow out and return to the breeding pond 6. In addition, a sludge bucket 7 is installed at the bottom of the ozone tank 41 and the ultraviolet lamp-aeration tank 42 to settle the sludge in the water. The sludge bucket 7 is equipped with a sludge discharge pipe to regularly discharge sewage containing sludge. To sludge thickening and dewatering device 5.
以下结合具体实施例对本发明作进一步的说明。The present invention will be further described below in conjunction with specific embodiments.
应用上述方法和装置,构建了循环水养殖暨尾水处理一体化水处理系统,应用于鳗鱼循环水养殖,水循环利用率高达98%,监测结果数据如下:Using the above methods and devices, an integrated water treatment system for circulating aquaculture and tail water treatment was constructed, which was applied to eel circulating aquaculture, and the water cycle utilization rate was as high as 98%. The monitoring results are as follows:
Figure PCTCN2020071814-appb-000001
Figure PCTCN2020071814-appb-000001
上述表中,养殖池水指养殖期间循环水养殖系统中养殖池内水体水质;处理出水指经臭氧紫外线组合灭病原微生物池4处理后的净化水水质;外排水指经污泥浓缩脱水装置5污泥浓缩脱水处理后的滤出水,可排出系统外的排放水。In the above table, the water in the aquaculture pond refers to the water quality in the aquaculture pond in the circulating water aquaculture system during the breeding period; the treated effluent refers to the purified water quality after the ozone-ultraviolet combination kills pathogenic microorganism tank 4; the external drainage refers to the sludge through the sludge thickening and dewatering device The filtered water after concentrated dehydration can be discharged from the system.
从表中数据可知,养殖期间循环水养殖系统中养殖池内水体水质可可符合国家《地表水环境质量标准》(GB3838-2002)中的III类水质标准及国家《渔业水质标准》(GB11607-1989);排出系统外的排放水水质可符合国家《地表水环境质量标准》(GB3838-2002)中的III类水质标准及《淡水养殖尾水排放要求》(SC/T 9101)规定的一级排放标准。From the data in the table, it can be seen that the water quality in the aquaculture pond in the recirculating aquaculture system during the aquaculture period can meet the Class III water quality standard in the National Surface Water Environmental Quality Standard (GB3838-2002) and the National Fishery Water Quality Standard (GB11607-1989) ; The quality of the discharged water outside the system can meet the national "Surface Water Environmental Quality Standards" (GB3838-2002) in the Class III water quality standards and the "Freshwater Farming Tail Water Discharge Requirements" (SC/T 9101) stipulated in the first level discharge standards .
总之,本发明主要通过在生物滤池中产生的系列物理、化学和微生物作用,综合铁阳离子磷酸盐沉析反应、铁阳离子水化物及其多聚物对磷及其他颗粒物的絮凝沉淀作用、硝化反应和反硝化反应等,达到持续、稳定、高效的除磷脱氮、降解有机质和降低悬浮物浓度效果。具有装置结构简单、产污泥量少和无二次污染等优点。In short, the present invention mainly integrates iron cation phosphate precipitation reaction, iron cation hydrate and its polymer flocculation precipitation effect on phosphorus and other particles, nitrification through a series of physical, chemical and microbiological actions produced in the biological filter. Reaction and denitrification reaction, etc., to achieve continuous, stable and efficient phosphorus and nitrogen removal, organic matter degradation and suspended solids concentration reduction effects. It has the advantages of simple device structure, less sludge production and no secondary pollution.
本发明一体化地实现循环水养殖用水处理和尾水达标排放处理的双功能,具有节地,水处理效率高,投资和运行成本低,管理简便等优点。本发明具有水处 理效率高,能持续维持养殖系统水质优的特点,水循环利用率可达95%~98%;不仅能充分满足养殖对象的健康养殖需求,实现养殖对象的健康生长,而且具有尾水处理功能,可实现尾水达标排放。解决了当前的循环水养殖水处理系统功能单一,不具备尾水达标排放处理能力的问题。The invention integrally realizes the dual functions of circulating aquaculture water treatment and tail water up-to-standard discharge treatment, and has the advantages of saving land, high water treatment efficiency, low investment and operating costs, simple management and the like. The invention has the characteristics of high water treatment efficiency and continuous maintenance of high water quality in the breeding system, and the water cycle utilization rate can reach 95% to 98%; it can not only fully meet the healthy breeding needs of the breeding objects, and realize the healthy growth of the breeding objects, but also has a tail. The water treatment function can realize the discharge of tail water up to standard. It solves the problem that the current circulating aquaculture water treatment system has a single function and does not have the ability to discharge the tail water up to the standard.
虽然以上描述了本发明的具体实施方式,但是熟悉本技术领域的技术人员应当理解,我们所描述的具体的实施例只是说明性的,而不是用于对本发明的范围的限定,熟悉本领域的技术人员在依照本发明的精神所作的等效的修饰以及变化,都应当涵盖在本发明的权利要求所保护的范围内。Although the specific embodiments of the present invention are described above, those skilled in the art should understand that the specific embodiments described by us are only illustrative, and are not used to limit the scope of the present invention. The equivalent modifications and changes made by the skilled person in accordance with the spirit of the present invention should all fall within the protection scope of the claims of the present invention.

Claims (8)

  1. 一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述水处理系统包括集污池、物理过滤装置、电极-悬浮填料耦合生物滤池处理单元、臭氧紫外线组合灭病原微生物池以及污泥浓缩脱水装置;所述集污池与物理过滤装置相连接,所述物理过滤装置连接至电极-悬浮填料耦合生物滤池处理单元,所述电极-悬浮填料耦合生物滤池处理单元与臭氧紫外线组合灭病原微生物池相邻设置,所述集污池、物理过滤装置、电极-悬浮填料耦合生物滤池处理单元、臭氧紫外线组合灭病原微生物池均与污泥浓缩脱水装置相连接,所述臭氧紫外线组合灭病原微生物池还与养殖池相连;An integrated water treatment system for circulating aquaculture and tail water treatment, characterized in that: the water treatment system includes a sewage collection tank, a physical filtration device, an electrode-suspended filler coupling biological filter treatment unit, and a combination of ozone and ultraviolet rays to kill pathogenic microorganisms Tank and sludge thickening and dewatering device; the sludge collection tank is connected to a physical filter device, the physical filter device is connected to an electrode-suspended filler coupled biological filter processing unit, and the electrode-suspended filler coupled biological filter processing unit Adjacent to the ozone-ultraviolet combined pathogenic microorganisms tank, the sewage collection tank, the physical filter device, the electrode-suspended filler coupling biological filter processing unit, and the ozone-ultraviolet combined pathogenic microorganisms tank are all connected to the sludge concentration and dehydration device. The ozone-ultraviolet combination inactivating pathogenic microorganism pool is also connected to the breeding pool;
    所述电极-悬浮填料耦合生物滤池处理单元包括生物滤池、悬浮填料、直流阴阳电极列阵组合、电动搅拌装置以及碳源补充装置,所述悬浮填料设置在生物滤池内,所述直流阴阳电极列阵组合设置在所述生物滤池的上部,所述电动搅拌装置设置在所述生物滤池的下部,所述生物滤池的底部设置有污泥斗,所述电动搅拌装置设置在污泥斗上方,所述碳源补充装置通过管道连接至生物滤池;The electrode-suspended filler coupled biological filter processing unit includes a biological filter, a suspended filler, a direct current cathode and anode electrode array combination, an electric stirring device, and a carbon source supplement device. The suspended filler is arranged in the biological filter, and the direct current The cathode and anode electrode array combination is arranged on the upper part of the biological filter, the electric stirring device is arranged on the lower part of the biological filter, the bottom of the biological filter is arranged with a sludge bucket, and the electric stirring device is arranged on Above the sludge bucket, the carbon source supplement device is connected to the biological filter through a pipeline;
    所述悬浮填料与所述生物滤池内水体的体积比为20%~50%,所述悬浮填料的密度为0.92~0.98g/cm 3;所述直流阴阳电极列阵组合中阳极为铁,阴极为铁、碳或铜;所述电动搅拌装置的转速为100~300r/min。 The volume ratio of the suspended filler to the water in the biological filter is 20% to 50%, and the density of the suspended filler is 0.92 to 0.98 g/cm 3 ; the anode in the DC cathode and anode electrode array combination is iron, The cathode is iron, carbon or copper; the rotational speed of the electric stirring device is 100-300 r/min.
  2. 根据权利要求1所述的一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述悬浮填料为高密度聚乙烯材质,比表面积大于500m 2/m 3The integrated water treatment system for circulating aquaculture and tail water treatment according to claim 1, wherein the suspended filler is made of high-density polyethylene with a specific surface area greater than 500 m 2 /m 3 .
  3. 根据权利要求1所述的一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述直流阴阳电极列阵组合的相邻电极之间的间距为2-30cm,运行电压和电流分别为:直流电压为12~36V, 微电流密度为0.1~1.0mA/cm 2The integrated water treatment system for circulating aquaculture and tail water treatment according to claim 1, wherein the distance between adjacent electrodes of the direct current cathode and anode electrode array combination is 2-30 cm, and the operating voltage and The currents are respectively: DC voltage is 12-36V, and micro-current density is 0.1-1.0mA/cm 2 .
  4. 根据权利要求1所述的一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述生物滤池为2个以上池体串联组合,可部分或全部池体设置直流阴阳电极列阵组合。The integrated water treatment system for circulating aquaculture and tail water treatment according to claim 1, characterized in that: the biological filter is a combination of more than two tank bodies in series, and some or all of the tank bodies can be equipped with direct current cathode and anode electrodes Array combination.
  5. 根据权利要求1所述的一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述物理过滤装置为自动反冲筛网过滤器、微滤机或弧形筛。The integrated water treatment system for circulating aquaculture and tail water treatment according to claim 1, wherein the physical filtration device is an automatic backwash screen filter, a micro filter or an arc screen.
  6. 根据权利要求1所述的一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述臭氧紫外线组合灭病原微生物池包括相邻设置的臭氧池和紫外灯-增氧池,所述臭氧池底部设置有微孔曝气盘,所述微孔曝气盘与池体外的臭氧发生器相连;所述紫外灯-增氧池上部设置有紫外灯,所述紫外灯-增氧池的底部设置有增氧微孔管,所述增氧微孔管与池体外的气泵相连,所述紫外灯-增氧池的进水口设置在底部,出水口设置在上部;所述臭氧池和紫外灯-增氧池的底部均设置有污泥斗,所述污泥斗与污泥浓缩脱水装置相连接。The integrated water treatment system for circulating aquaculture and tail water treatment according to claim 1, characterized in that: the ozone-ultraviolet combination kills pathogenic microorganisms pool comprises adjacently arranged ozone pool and ultraviolet lamp-aeration pool, The bottom of the ozone tank is provided with a microporous aeration pan, the microporous aeration pan is connected to the ozone generator outside the tank; the upper part of the ultraviolet lamp-aeration tank is provided with a ultraviolet lamp, the ultraviolet lamp-aeration The bottom of the pool is provided with an oxygen-enhancing microporous tube, which is connected to an air pump outside the pool, the water inlet of the ultraviolet lamp-aeration pool is arranged at the bottom, and the water outlet is arranged at the upper part; the ozone pool A sludge bucket is provided at the bottom of the ultraviolet lamp-aeration tank, and the sludge bucket is connected with the sludge thickening and dewatering device.
  7. 根据权利要求6所述的一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述臭氧发生器每天4~12次输入臭氧对水体进行处理,每次持续时间20~60min;所述紫外灯-增氧池内的水力停留时间为15~40min。The integrated water treatment system for circulating aquaculture and tail water treatment according to claim 6, characterized in that the ozone generator inputs ozone 4 to 12 times a day to treat the water body, and the duration of each time is 20 to 60 minutes. The hydraulic residence time in the ultraviolet lamp-aeration tank is 15-40min.
  8. 根据权利要求6所述的一种循环水养殖暨尾水处理一体化水处理系统,其特征在于:所述紫外灯为浸没式设置。The integrated water treatment system for circulating aquaculture and tail water treatment according to claim 6, wherein the ultraviolet lamp is immersed.
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