WO2020168669A1 - Quantum dot liquid crystal display - Google Patents

Quantum dot liquid crystal display Download PDF

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Publication number
WO2020168669A1
WO2020168669A1 PCT/CN2019/094443 CN2019094443W WO2020168669A1 WO 2020168669 A1 WO2020168669 A1 WO 2020168669A1 CN 2019094443 W CN2019094443 W CN 2019094443W WO 2020168669 A1 WO2020168669 A1 WO 2020168669A1
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WO
WIPO (PCT)
Prior art keywords
quantum dot
layer
liquid crystal
crystal display
light
Prior art date
Application number
PCT/CN2019/094443
Other languages
French (fr)
Chinese (zh)
Inventor
周淼
Original Assignee
深圳市华星光电技术有限公司
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Publication of WO2020168669A1 publication Critical patent/WO2020168669A1/en

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings

Definitions

  • This application relates to the field of display technology, and in particular to a quantum dot liquid crystal display.
  • Quantum dot quantum dot material
  • QD quantum dot liquid crystal display panel
  • the energy efficiency of the quantum dot liquid crystal display panel is lower and the cost is higher.
  • the study found that the quantum dot film layer close to the backlight has the best luminous efficiency, so the quantum dot light guide plate has the highest theoretical excitation efficiency as the backlight source.
  • the thickness of the quantum dot film layer is relatively high, and the quantum dot light guide plate structure of the screen-printed quantum dot film layer cannot meet the brightness requirements of the backlight module. All the above defects limit the industrial application of quantum dot liquid crystal display panels and quantum dot light guide plates.
  • the existing quantum dot liquid crystal display due to the low excitation efficiency of the quantum dot liquid crystal display panel, is difficult to achieve the ideal high color gamut, wide viewing angle, and high energy efficiency requirements, which further leads to poor display effects.
  • the present application provides a quantum dot liquid crystal display, which can improve the display effect of the quantum dot liquid crystal display to solve the problem of the low excitation efficiency of the quantum dot liquid crystal display panel, which is difficult to achieve the ideal high color gamut , Wide viewing angle, high energy efficiency requirements, further leading to technical problems of poor display effect.
  • the present application provides a quantum dot liquid crystal display, including a backlight module and a liquid crystal display panel located above the backlight module, the backlight module includes a first quantum dot layer, and the liquid crystal display panel includes a second quantum dot Floor;
  • the backlight module includes at least a light guide plate, a low-refractive index resin layer disposed on the light-exit side surface of the light guide plate, and the first quantum dot layer, and the first quantum dot layer is coated on the low-refractive
  • the surface of the high-speed resin layer or the screen printing dots are on the lower surface of the light guide plate.
  • the liquid crystal display panel includes the second quantum dot film layer, the lower polarizing layer, the TFT array substrate, the liquid crystal layer, the color film substrate and Upper polarizing layer.
  • the liquid crystal display panel includes the second quantum dot film layer, prism sheet, lower polarizing layer, TFT array substrate, liquid crystal layer, color Film substrate and upper polarizing layer.
  • the liquid crystal display panel includes the second quantum dot film layer, a reflective polarizing brightness enhancement film, a lower polarizing layer, a TFT array substrate, Liquid crystal layer, color film substrate and upper polarizing layer.
  • the liquid crystal display panel includes the second quantum dot film layer, prism sheet, reflective polarizing brightening film, lower polarizing layer, and TFT arranged from bottom to top.
  • the liquid crystal display panel includes a lower polarizing layer, a TFT array substrate, a liquid crystal layer, a color film substrate, the second quantum dot film layer and Upper polarizing layer.
  • the liquid crystal display panel includes a third quantum dot film layer, a reflective polarizing brightness enhancement film, a lower polarizing layer, a TFT array substrate, and a liquid crystal layer arranged from bottom to top.
  • a color film substrate and an upper polarizing layer, the third quantum dot film layer is prepared by patterning the second quantum dot layer through screen printing or nanoimprinting methods.
  • the materials of the first quantum dot film layer and the second quantum dot film layer include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester.
  • the quantum dots include a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, and the red light material of the light-emitting core includes one of CdSe, Cd 2 SeTe and InAs or
  • the green material of the luminescent core includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe;
  • the inorganic protective shell layer includes one of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO or Many kinds.
  • the first quantum dot film layer and the second quantum dot film layer further include a high-stability composite quantum dot film structure, and the high-stability composite quantum dot film structure
  • the dot film layer structure is loaded with hydrogel, MOFs or CdSe-SiO 2 .
  • the beneficial effects of the present application are: the quantum dot liquid crystal display provided by the present application excites the liquid crystal display panel containing the quantum dot film layer above the quantum dot film layer on the backlight module, thereby increasing the viewing angle of the quantum dot liquid crystal display.
  • the energy consumption of the quantum dot liquid crystal display is further reduced, and the display effect of the quantum dot liquid crystal display is further improved.
  • FIG. 1 is a schematic structural diagram of a first embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 2 is a schematic structural diagram of a second embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 3 is a schematic structural diagram of a third embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 4 is a schematic structural diagram of a fourth embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 5 is a schematic structural diagram of a fifth embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 6 is a schematic structural diagram of a sixth embodiment of a quantum dot liquid crystal display of this application.
  • FIG. 7 is a schematic structural diagram of a seventh embodiment of a quantum dot liquid crystal display of this application.
  • FIG. 8 is a schematic structural diagram of an eighth embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 9 is a schematic structural diagram of a ninth embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 10 is a schematic structural diagram of a tenth embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 11 is a schematic structural diagram of an eleventh embodiment of a quantum dot liquid crystal display according to this application.
  • FIG. 12 is a schematic structural diagram of a twelfth embodiment of a quantum dot liquid crystal display according to this application.
  • This application is directed to the existing quantum dot liquid crystal display. Due to the low excitation efficiency of the quantum dot liquid crystal display panel, it is difficult to achieve the ideal high color gamut, wide viewing angle, and high energy efficiency requirements, which further leads to the technical problem of poor display effect.
  • the embodiment can solve this defect.
  • FIG. 1 it is a schematic structural diagram of a first embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides a quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10; the backlight module 10 at least includes a light guide plate 11 arranged on the guide The low refractive index resin layer 12 and the first quantum dot layer 13 on the light emitting side surface of the light plate 11, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 It includes the second quantum dot film layer 21, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25 and the upper polarizing layer 26 arranged from bottom to top.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 2 it is a schematic structural diagram of a second embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper polarizing layer 26 arranged from bottom to top.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 3 it is a schematic structural diagram of a third embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes the second quantum dot film layer 21, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper polarizing layer 26 arranged from bottom to top.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 4 it is a schematic structural diagram of a fourth embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper Polarization layer 26.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 5 it is a schematic structural diagram of a fifth embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color filter substrate 25, the second quantum dot film layer 21 and an upper polarizing layer 26 arranged from bottom to top.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 6 it is a schematic structural diagram of a sixth embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes a third quantum dot film layer 29, a reflective polarizing brightness enhancement film 28, a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color film substrate 25, and an upper polarizing layer 26 arranged from bottom to top.
  • the third quantum dot film layer 29 is prepared by patterning the second quantum dot layer 21 through screen printing or nanoimprinting.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 7 it is a schematic structural diagram of a seventh embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides a quantum dot liquid crystal display, comprising: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11 arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal display
  • the panel 20 includes the second quantum dot film layer 21, a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color film substrate 25 and an upper polarizing layer 26 arranged from bottom to top.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 8 it is a schematic structural diagram of an eighth embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10; the backlight module 10 at least includes a light guide plate 11, which is arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25 and the upper polarizing layer 26 arranged from bottom to top.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 9 it is a schematic structural diagram of a ninth embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13; the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes the second quantum dot film layer 21, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper polarizing layer arranged from bottom to top. 26.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 10 it is a schematic structural diagram of a tenth embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, comprising: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, which is arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, and the color film substrate 25 arranged from bottom to top. And the upper polarizing layer 26.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • FIG. 11 it is a schematic structural diagram of an eleventh embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color filter substrate 25, the second quantum dot film layer 21 and an upper polarizing layer 26 arranged from bottom to top.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, thereby effectively balancing the brightness of each viewing angle of the liquid crystal display.
  • FIG. 12 it is a schematic structural diagram of a twelfth embodiment of a quantum dot liquid crystal display of this application.
  • the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes a third quantum dot film layer 29, a reflective polarizing brightness enhancement film 28, a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color film substrate 25, and an upper polarizing layer 26 arranged from bottom to top.
  • the third quantum dot film layer 29 is prepared by patterning the second quantum dot layer 21 through screen printing or nanoimprinting methods.
  • the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
  • the polymer matrix is a resin transparent material
  • the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester
  • the dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
  • the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
  • the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21
  • Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
  • This application designs a quantum dot liquid crystal display, which uses a quantum dot light guide plate structure to excite a quantum dot liquid crystal display panel, and obtains a quantum dot display with high color gamut, wide viewing angle, low energy consumption and suitable for mass production.
  • the quantum dot luminescent material uses a high-stability composite quantum dot film structure, which is loaded with hydrogel, MOFs or CdSe-SiO 2.
  • the common feature of these materials is that they have barriers. The effect of improving water and oxygen and drug resistance, saving barrier film and reducing cost.
  • the beneficial effects of the present application are: the quantum dot liquid crystal display provided by the present application excites the liquid crystal display panel containing the quantum dot film layer above the quantum dot film layer on the backlight module, thereby increasing the viewing angle of the quantum dot liquid crystal display.
  • the energy consumption of the quantum dot liquid crystal display is further reduced, and the display effect of the quantum dot liquid crystal display is further improved.

Abstract

A quantum dot liquid crystal display, comprising: a backlight module and a liquid crystal display panel; the backlight module comprises a first quantum dot layer, and the liquid crystal display panel comprises a second quantum dot layer; the backlight module comprises at least a light guide plate, a low-refractive-index resin layer provided on a light-emitting side surface of the light guide plate, and the first quantum dot layer, and the first quantum dot layer is coated on the surface of the low-refractive-index resin layer or dotted, by means of screen printing on the lower surface of the light guide plate.

Description

量子点液晶显示器Quantum dot liquid crystal display 技术领域Technical field
本申请涉及显示技术领域,尤其涉及一种量子点液晶显示器。This application relates to the field of display technology, and in particular to a quantum dot liquid crystal display.
背景技术Background technique
目前由于量子点材料(Quantum Dot,QD)本身所具有的高色纯度、光谱连续可调等优异性质,使其成为21世纪最为优秀的发光材料,可以在显示色域上大幅度提高现有LCD的色彩表现,因此近年来其显示应用被广泛研究。现有的QD-OC(量子点液晶显示面板)具有视角极大,色域较高的优势。但是量子点液晶显示面板的能效较低,成本较高。研究发现量子点膜层贴近背光发光效率最优,因此量子点导光板作为背光源的理论激发效率最高。但由于树脂体系对量子点膜层的分散性的限制,量子点膜层的厚度较高,且网印量子点膜层的网点的量子点导光板结构无法达到背光模组的亮度要求。以上这些都缺陷限制了量子点液晶显示面板、量子点导光板的产业化应用。At present, due to the excellent properties of quantum dot material (Quantum Dot, QD), such as high color purity and continuous adjustable spectrum, it becomes the most excellent luminescent material in the 21st century, which can greatly improve the display color gamut of existing LCDs. Color performance, so its display applications have been widely studied in recent years. The existing QD-OC (quantum dot liquid crystal display panel) has the advantages of a large viewing angle and a high color gamut. However, the energy efficiency of the quantum dot liquid crystal display panel is lower and the cost is higher. The study found that the quantum dot film layer close to the backlight has the best luminous efficiency, so the quantum dot light guide plate has the highest theoretical excitation efficiency as the backlight source. However, due to the restriction of the dispersion of the quantum dot film layer by the resin system, the thickness of the quantum dot film layer is relatively high, and the quantum dot light guide plate structure of the screen-printed quantum dot film layer cannot meet the brightness requirements of the backlight module. All the above defects limit the industrial application of quantum dot liquid crystal display panels and quantum dot light guide plates.
综上所述,现有的量子点液晶显示器,由于量子点液晶显示面板激发效率低的原因,较难达到理想的高色域、广视角、高能效要求,进一步导致显示效果不佳。To sum up, due to the low excitation efficiency of the quantum dot liquid crystal display panel, it is difficult for the existing quantum dot liquid crystal display to meet the ideal high color gamut, wide viewing angle, and high energy efficiency requirements, which further leads to poor display effects.
技术问题technical problem
现有的量子点液晶显示器,由于量子点液晶显示面板激发效率低的原因,较难达到理想的高色域、广视角、高能效要求,进一步导致显示效果不佳。The existing quantum dot liquid crystal display, due to the low excitation efficiency of the quantum dot liquid crystal display panel, is difficult to achieve the ideal high color gamut, wide viewing angle, and high energy efficiency requirements, which further leads to poor display effects.
技术解决方案Technical solutions
本申请提供一种量子点液晶显示器,能够提升量子点液晶显示器的显示效果,以解决现有的量子点液晶显示器,由于量子点液晶显示面板激发效率低的原因,较难达到理想的高色域、广视角、高能效要求,进一步导致显示效果不佳的技术问题。The present application provides a quantum dot liquid crystal display, which can improve the display effect of the quantum dot liquid crystal display to solve the problem of the low excitation efficiency of the quantum dot liquid crystal display panel, which is difficult to achieve the ideal high color gamut , Wide viewing angle, high energy efficiency requirements, further leading to technical problems of poor display effect.
为解决上述问题,本申请提供的技术方案如下:To solve the above problems, the technical solutions provided by this application are as follows:
本申请提供一种量子点液晶显示器,包括:背光模组以及位于所述背光模组上方的液晶显示面板,所述背光模组包括第一量子点层,所述液晶显示面板包括第二量子点层;The present application provides a quantum dot liquid crystal display, including a backlight module and a liquid crystal display panel located above the backlight module, the backlight module includes a first quantum dot layer, and the liquid crystal display panel includes a second quantum dot Floor;
其中,所述背光模组至少包括导光板、设置在所述导光板出光侧表面的低折射率树脂层以及所述第一量子点层,所述第一量子点层涂布于所述低折射率树脂层的表面或网印网点于所述导光板的下表面。Wherein, the backlight module includes at least a light guide plate, a low-refractive index resin layer disposed on the light-exit side surface of the light guide plate, and the first quantum dot layer, and the first quantum dot layer is coated on the low-refractive The surface of the high-speed resin layer or the screen printing dots are on the lower surface of the light guide plate.
在本申请实施例所提供的量子点液晶显示器中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。In the quantum dot liquid crystal display provided by the embodiment of the present application, the liquid crystal display panel includes the second quantum dot film layer, the lower polarizing layer, the TFT array substrate, the liquid crystal layer, the color film substrate and Upper polarizing layer.
在本申请实施例所提供的量子点液晶显示器中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、棱镜片、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。In the quantum dot liquid crystal display provided by the embodiment of the application, the liquid crystal display panel includes the second quantum dot film layer, prism sheet, lower polarizing layer, TFT array substrate, liquid crystal layer, color Film substrate and upper polarizing layer.
在本申请实施例所提供的量子点液晶显示器中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、反射式偏光增亮膜、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。In the quantum dot liquid crystal display provided by the embodiment of the present application, the liquid crystal display panel includes the second quantum dot film layer, a reflective polarizing brightness enhancement film, a lower polarizing layer, a TFT array substrate, Liquid crystal layer, color film substrate and upper polarizing layer.
在本申请实施例所提供的量子点液晶显示器中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、棱镜片、反射式偏光增亮膜、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。In the quantum dot liquid crystal display provided by the embodiment of the present application, the liquid crystal display panel includes the second quantum dot film layer, prism sheet, reflective polarizing brightening film, lower polarizing layer, and TFT arranged from bottom to top. Array substrate, liquid crystal layer, color filter substrate and upper polarizing layer.
在本申请实施例所提供的量子点液晶显示器中,所述液晶显示面板包括由下到上设置的下偏光层、TFT阵列基板、液晶层、彩膜基板、所述第二量子点膜层以及上偏光层。In the quantum dot liquid crystal display provided by the embodiment of the present application, the liquid crystal display panel includes a lower polarizing layer, a TFT array substrate, a liquid crystal layer, a color film substrate, the second quantum dot film layer and Upper polarizing layer.
在本申请实施例所提供的量子点液晶显示器中,所述液晶显示面板包括由下到上设置的第三量子点膜层、反射式偏光增亮膜、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层,所述第三量子点膜层是所述第二量子点层经过网印或纳米压印方法图案化后制备而成。In the quantum dot liquid crystal display provided by the embodiment of the present application, the liquid crystal display panel includes a third quantum dot film layer, a reflective polarizing brightness enhancement film, a lower polarizing layer, a TFT array substrate, and a liquid crystal layer arranged from bottom to top. , A color film substrate and an upper polarizing layer, the third quantum dot film layer is prepared by patterning the second quantum dot layer through screen printing or nanoimprinting methods.
在本申请实施例所提供的量子点液晶显示器中,所述第一量子点膜层以及所述第二量子点膜层的材料包括聚合物基质及分散于聚合物基质中的量子点。In the quantum dot liquid crystal display provided by the embodiment of the present application, the materials of the first quantum dot film layer and the second quantum dot film layer include a polymer matrix and quantum dots dispersed in the polymer matrix.
在本申请实施例所提供的量子点液晶显示器中,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 In the quantum dot liquid crystal display provided by the embodiments of the present application, the polymer matrix is a resin transparent material, and the resin transparent material includes acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester. One or more of the quantum dots; the quantum dots include a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, and the red light material of the light-emitting core includes one of CdSe, Cd 2 SeTe and InAs or The green material of the luminescent core includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO or Many kinds.
在本申请实施例所提供的量子点液晶显示器中,所述第一量子点膜层以及所述第二量子点膜层还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2In the quantum dot liquid crystal display provided by the embodiment of the present application, the first quantum dot film layer and the second quantum dot film layer further include a high-stability composite quantum dot film structure, and the high-stability composite quantum dot film structure The dot film layer structure is loaded with hydrogel, MOFs or CdSe-SiO 2 .
有益效果Beneficial effect
本申请的有益效果为:本申请提供的量子点液晶显示器,通过背光模组上的量子点膜层激发位于其上方的含量子点膜层的液晶显示面板,增加了量子点液晶显示器的视角,进一步降低了量子点液晶显示器的能耗,更进一步提升了量子点液晶显示器的显示效果。The beneficial effects of the present application are: the quantum dot liquid crystal display provided by the present application excites the liquid crystal display panel containing the quantum dot film layer above the quantum dot film layer on the backlight module, thereby increasing the viewing angle of the quantum dot liquid crystal display. The energy consumption of the quantum dot liquid crystal display is further reduced, and the display effect of the quantum dot liquid crystal display is further improved.
附图说明Description of the drawings
为了更清楚地说明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单介绍,显而易见地,下面描述中的附图仅仅是申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to explain the embodiments or the technical solutions in the prior art more clearly, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the drawings in the following description are only for application. For some embodiments, those of ordinary skill in the art can obtain other drawings based on these drawings without creative work.
图1为本申请量子点液晶显示器第一实施例的结构示意图。FIG. 1 is a schematic structural diagram of a first embodiment of a quantum dot liquid crystal display according to this application.
图2为本申请量子点液晶显示器第二实施例的结构示意图。2 is a schematic structural diagram of a second embodiment of a quantum dot liquid crystal display according to this application.
图3为本申请量子点液晶显示器第三实施例的结构示意图。FIG. 3 is a schematic structural diagram of a third embodiment of a quantum dot liquid crystal display according to this application.
图4为本申请量子点液晶显示器第四实施例的结构示意图。4 is a schematic structural diagram of a fourth embodiment of a quantum dot liquid crystal display according to this application.
图5为本申请量子点液晶显示器第五实施例的结构示意图。5 is a schematic structural diagram of a fifth embodiment of a quantum dot liquid crystal display according to this application.
图6为本申请量子点液晶显示器第六实施例的结构示意图。FIG. 6 is a schematic structural diagram of a sixth embodiment of a quantum dot liquid crystal display of this application.
图7为本申请量子点液晶显示器第七实施例的结构示意图。FIG. 7 is a schematic structural diagram of a seventh embodiment of a quantum dot liquid crystal display of this application.
图8为本申请量子点液晶显示器第八实施例的结构示意图。FIG. 8 is a schematic structural diagram of an eighth embodiment of a quantum dot liquid crystal display according to this application.
图9为本申请量子点液晶显示器第九实施例的结构示意图。FIG. 9 is a schematic structural diagram of a ninth embodiment of a quantum dot liquid crystal display according to this application.
图10为本申请量子点液晶显示器第十实施例的结构示意图。FIG. 10 is a schematic structural diagram of a tenth embodiment of a quantum dot liquid crystal display according to this application.
图11为本申请量子点液晶显示器第十一实施例的结构示意图。FIG. 11 is a schematic structural diagram of an eleventh embodiment of a quantum dot liquid crystal display according to this application.
图12为本申请量子点液晶显示器第十二实施例的结构示意图。FIG. 12 is a schematic structural diagram of a twelfth embodiment of a quantum dot liquid crystal display according to this application.
本发明的实施方式Embodiments of the invention
以下各实施例的说明是参考附加的图示,用以例示本申请可用以实施的特定实施例。本申请所提到的方向用语,例如[上]、[下]、[前]、[后]、[左]、[右]、[内]、[外]、[侧面]等,仅是参考附加图式的方向。因此,使用的方向用语是用以说明及理解本申请,而非用以限制本申请。在图中,结构相似的单元是用以相同标号表示。The description of the following embodiments refers to the attached drawings to illustrate specific embodiments that can be implemented in this application. The directional terms mentioned in this application, such as [Up], [Down], [Front], [Back], [Left], [Right], [Inner], [Outer], [Side], etc., are for reference only The direction of the additional schema. Therefore, the directional terms used are used to illustrate and understand the application, rather than to limit the application. In the figure, units with similar structures are indicated by the same reference numerals.
本申请针对现有的量子点液晶显示器,由于量子点液晶显示面板激发效率低的原因,较难达到理想的高色域、广视角、高能效要求,进一步导致显示效果不佳的技术问题,本实施例能够解决该缺陷。This application is directed to the existing quantum dot liquid crystal display. Due to the low excitation efficiency of the quantum dot liquid crystal display panel, it is difficult to achieve the ideal high color gamut, wide viewing angle, and high energy efficiency requirements, which further leads to the technical problem of poor display effect. The embodiment can solve this defect.
如图1所示,为本申请量子点液晶显示器第一实施例的结构示意图。其中,本申请提供一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20;所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点层13涂布于所述低折射率树脂层12的表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 1, it is a schematic structural diagram of a first embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides a quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10; the backlight module 10 at least includes a light guide plate 11 arranged on the guide The low refractive index resin layer 12 and the first quantum dot layer 13 on the light emitting side surface of the light plate 11, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 It includes the second quantum dot film layer 21, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25 and the upper polarizing layer 26 arranged from bottom to top.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图2所示,为本申请量子点液晶显示器第二实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点层13涂布于所述低折射率树脂层12的表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、棱镜片27、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 2, it is a schematic structural diagram of a second embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper polarizing layer 26 arranged from bottom to top.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图3所示,为本申请量子点液晶显示器第三实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点层13涂布于所述低折射率树脂层12的表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、反射式偏光增亮膜28、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 3, it is a schematic structural diagram of a third embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes the second quantum dot film layer 21, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper polarizing layer 26 arranged from bottom to top.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图4所示,为本申请量子点液晶显示器第四实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点层13涂布于所述低折射率树脂层12的表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、棱镜片27、反射式偏光增亮膜28、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 4, it is a schematic structural diagram of a fourth embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper Polarization layer 26.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图5所示,为本申请量子点液晶显示器第五实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点层13涂布于所述低折射率树脂层12的表面;所述液晶显示面板20包括由下到上设置的下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25、所述第二量子点膜层21以及上偏光层26。As shown in FIG. 5, it is a schematic structural diagram of a fifth embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color filter substrate 25, the second quantum dot film layer 21 and an upper polarizing layer 26 arranged from bottom to top.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图6所示,为本申请量子点液晶显示器第六实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点层13涂布于所述低折射率树脂层12的表面;所述液晶显示面板20包括由下到上设置的第三量子点膜层29、反射式偏光增亮膜28、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26,所述第三量子点膜层29是所述第二量子点层21经过网印或纳米压印方法图案化后制备而成。As shown in FIG. 6, it is a schematic structural diagram of a sixth embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light exit side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot layer 13 is coated on the surface of the low refractive index resin layer 12; the liquid crystal display panel 20 includes a third quantum dot film layer 29, a reflective polarizing brightness enhancement film 28, a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color film substrate 25, and an upper polarizing layer 26 arranged from bottom to top. The third quantum dot film layer 29 is prepared by patterning the second quantum dot layer 21 through screen printing or nanoimprinting.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图7所示,为本申请量子点液晶显示器第七实施例的结构示意图。其中,本申请提供一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点膜层13使用网印法网点于所述导光板11的下表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 7, it is a schematic structural diagram of a seventh embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides a quantum dot liquid crystal display, comprising: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11 arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal display The panel 20 includes the second quantum dot film layer 21, a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color film substrate 25 and an upper polarizing layer 26 arranged from bottom to top.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图8所示,为本申请量子点液晶显示器第八实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20;所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点膜层13使用网印法网点于所述导光板11的下表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、棱镜片27、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 8, it is a schematic structural diagram of an eighth embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10; the backlight module 10 at least includes a light guide plate 11, which is arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25 and the upper polarizing layer 26 arranged from bottom to top.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图9所示,为本申请量子点液晶显示器第九实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13;所述第一量子点膜层13使用网印法网点于所述导光板11的下表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、反射式偏光增亮膜28、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 9, it is a schematic structural diagram of a ninth embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13; the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes the second quantum dot film layer 21, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, the color film substrate 25, and the upper polarizing layer arranged from bottom to top. 26.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图10所示,为本申请量子点液晶显示器第十实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点膜层13使用网印法网点于所述导光板11的下表面;所述液晶显示面板20包括由下到上设置的所述第二量子点膜层21、棱镜片27、反射式偏光增亮膜28、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26。As shown in FIG. 10, it is a schematic structural diagram of a tenth embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, comprising: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, which is arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes the second quantum dot film layer 21, the prism sheet 27, the reflective polarizing brightness enhancement film 28, the lower polarizing layer 22, the TFT array substrate 23, the liquid crystal layer 24, and the color film substrate 25 arranged from bottom to top. And the upper polarizing layer 26.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
如图11所示,为本申请量子点液晶显示器第十一实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点膜层13使用网印法网点于所述导光板11的下表面;所述液晶显示面板20包括由下到上设置的下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25、所述第二量子点膜层21以及上偏光层26。As shown in FIG. 11, it is a schematic structural diagram of an eleventh embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color filter substrate 25, the second quantum dot film layer 21 and an upper polarizing layer 26 arranged from bottom to top.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, thereby effectively balancing the brightness of each viewing angle of the liquid crystal display.
如图12所示,为本申请量子点液晶显示器第十二实施例的结构示意图。其中,本申请提供另一种量子点液晶显示器,包括:背光模组10以及位于所述背光模组10上方的液晶显示面板20,所述背光模组10至少包括导光板11、设置在所述导光板11出光侧表面的低折射率树脂层12以及所述第一量子点层13,所述第一量子点膜层13使用网印法网点于所述导光板11的下表面;所述液晶显示面板20包括由下到上设置的第三量子点膜层29、反射式偏光增亮膜28、下偏光层22、TFT阵列基板23、液晶层24、彩膜基板25以及上偏光层26,所述第三量子点膜层29是所述第二量子点层21经过网印或纳米压印方法图案化后制备而成。As shown in FIG. 12, it is a schematic structural diagram of a twelfth embodiment of a quantum dot liquid crystal display of this application. Wherein, the present application provides another quantum dot liquid crystal display, including: a backlight module 10 and a liquid crystal display panel 20 located above the backlight module 10, the backlight module 10 at least includes a light guide plate 11, arranged on the The low refractive index resin layer 12 on the light-emitting side surface of the light guide plate 11 and the first quantum dot layer 13, the first quantum dot film layer 13 is dotted on the lower surface of the light guide plate 11 by screen printing; the liquid crystal The display panel 20 includes a third quantum dot film layer 29, a reflective polarizing brightness enhancement film 28, a lower polarizing layer 22, a TFT array substrate 23, a liquid crystal layer 24, a color film substrate 25, and an upper polarizing layer 26 arranged from bottom to top. The third quantum dot film layer 29 is prepared by patterning the second quantum dot layer 21 through screen printing or nanoimprinting methods.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21的材料包括聚合物基质及分散于聚合物基质中的量子点。Specifically, the materials of the first quantum dot film layer 13 and the second quantum dot film layer 21 include a polymer matrix and quantum dots dispersed in the polymer matrix.
具体的,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 Specifically, the polymer matrix is a resin transparent material, and the resin transparent material includes one or more of acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester; The dot includes a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, the red light material of the light-emitting core includes one or more of CdSe, Cd 2 SeTe and InAs; the green light material of the light-emitting core It includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one or more of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO.
具体的,所述第一量子点膜层13以及所述第二量子点膜层21还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2Specifically, the first quantum dot film layer 13 and the second quantum dot film layer 21 further include a high stability composite quantum dot film structure, and the high stability composite quantum dot film structure is loaded with a hydrogel , MOFs or CdSe-SiO 2 .
具体的,当光经过所述导光板11的出光侧射出时,经所述第一量子点膜层13后激发出较窄半高宽的激发光,再经过所述第二量子点膜层21激发出更窄半高宽的激发光,从而可提升显示装置的色域范围,改善画面品质。这是由于量子点本身具备光转换能力,在受到蓝光激发的情况下,发生电子跃迁,而后以荧光辐射的形式完成电子空穴的复合;作为典型的零维纳米材料,量子点在各个方向均具有量子限域范围内的尺寸,因此其荧光辐射不存在方向选择性,受激发后可以360°无差别地辐射荧光,从而能够有效平衡液晶显示器的各视角亮度。Specifically, when light is emitted through the light exit side of the light guide plate 11, the excitation light with a narrower half-height width is excited after passing through the first quantum dot film layer 13, and then passes through the second quantum dot film layer 21 Exciting excitation light with a narrower half-height width can increase the color gamut of the display device and improve picture quality. This is because the quantum dot itself has the ability to convert light. When excited by blue light, an electron transition occurs, and then the electron-hole recombination is completed in the form of fluorescent radiation; as a typical zero-dimensional nanomaterial, the quantum dot is uniform in all directions. It has a size within the quantum confinement range, so its fluorescent radiation has no direction selectivity. After being excited, it can radiate the fluorescent light at 360° without difference, which can effectively balance the brightness of each viewing angle of the liquid crystal display.
本申请设计了一种量子点液晶显示器,采用量子点导光板结构激发量子点液晶显示面板的形式,得到了一种高色域、广视角、低能耗且适合量产的量子点显示器。其中的量子点发光材料选用了高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 2,这些材料的共同特点是具有阻隔水氧、耐药性提高的作用,节省的阻挡膜层,降低成本。 This application designs a quantum dot liquid crystal display, which uses a quantum dot light guide plate structure to excite a quantum dot liquid crystal display panel, and obtains a quantum dot display with high color gamut, wide viewing angle, low energy consumption and suitable for mass production. Among them, the quantum dot luminescent material uses a high-stability composite quantum dot film structure, which is loaded with hydrogel, MOFs or CdSe-SiO 2. The common feature of these materials is that they have barriers. The effect of improving water and oxygen and drug resistance, saving barrier film and reducing cost.
本申请的有益效果为:本申请提供的量子点液晶显示器,通过背光模组上的量子点膜层激发位于其上方的含量子点膜层的液晶显示面板,增加了量子点液晶显示器的视角,进一步降低了量子点液晶显示器的能耗,更进一步提升了量子点液晶显示器的显示效果。The beneficial effects of the present application are: the quantum dot liquid crystal display provided by the present application excites the liquid crystal display panel containing the quantum dot film layer above the quantum dot film layer on the backlight module, thereby increasing the viewing angle of the quantum dot liquid crystal display. The energy consumption of the quantum dot liquid crystal display is further reduced, and the display effect of the quantum dot liquid crystal display is further improved.
综上所述,虽然本申请已以优选实施例揭露如上,但上述优选实施例并非用以限制本申请,本领域的普通技术人员,在不脱离本申请的精神和范围内,均可作各种更动与润饰,因此本申请的保护范围以权利要求界定的范围为准。In summary, although the application has been disclosed as above in preferred embodiments, the above-mentioned preferred embodiments are not intended to limit the application, and those of ordinary skill in the art can make various decisions without departing from the spirit and scope of the application. Such changes and modifications, so the protection scope of this application is subject to the scope defined by the claims.

Claims (10)

  1. 一种量子点液晶显示器,其中,包括:背光模组以及位于所述背光模组上方的液晶显示面板,所述背光模组包括第一量子点层,所述液晶显示面板包括第二量子点层;A quantum dot liquid crystal display, comprising: a backlight module and a liquid crystal display panel located above the backlight module, the backlight module includes a first quantum dot layer, and the liquid crystal display panel includes a second quantum dot layer ;
    其中,所述背光模组至少包括导光板、设置在所述导光板出光侧表面的低折射率树脂层以及所述第一量子点层,所述第一量子点层涂布于所述低折射率树脂层的表面或网印网点于所述导光板的下表面。Wherein, the backlight module includes at least a light guide plate, a low-refractive index resin layer disposed on the light-exit side surface of the light guide plate, and the first quantum dot layer, and the first quantum dot layer is coated on the low-refractive The surface of the high-speed resin layer or the screen printing dots are on the lower surface of the light guide plate.
  2. 根据权利要求1所述的量子点液晶显示器,其中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。The quantum dot liquid crystal display according to claim 1, wherein the liquid crystal display panel comprises the second quantum dot film layer, a lower polarizing layer, a TFT array substrate, a liquid crystal layer, a color film substrate and Upper polarizing layer.
  3. 根据权利要求1所述的量子点液晶显示器,其中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、棱镜片、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。The quantum dot liquid crystal display according to claim 1, wherein the liquid crystal display panel comprises the second quantum dot film layer, prism sheet, lower polarizing layer, TFT array substrate, liquid crystal layer, color Film substrate and upper polarizing layer.
  4. 根据权利要求1所述的量子点液晶显示器,其中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、反射式偏光增亮膜、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。The quantum dot liquid crystal display according to claim 1, wherein the liquid crystal display panel comprises the second quantum dot film layer, a reflective polarizing brightness enhancement film, a lower polarizing layer, a TFT array substrate, Liquid crystal layer, color film substrate and upper polarizing layer.
  5. 根据权利要求1所述的量子点液晶显示器,其中,所述液晶显示面板包括由下到上设置的所述第二量子点膜层、棱镜片、反射式偏光增亮膜、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层。The quantum dot liquid crystal display according to claim 1, wherein the liquid crystal display panel comprises the second quantum dot film layer, prism sheet, reflective polarizing brightness enhancement film, lower polarizing layer, TFT arranged from bottom to top. Array substrate, liquid crystal layer, color filter substrate and upper polarizing layer.
  6. 根据权利要求1所述的量子点液晶显示器,其中,所述液晶显示面板包括由下到上设置的下偏光层、TFT阵列基板、液晶层、彩膜基板、所述第二量子点膜层以及上偏光层。The quantum dot liquid crystal display according to claim 1, wherein the liquid crystal display panel comprises a lower polarizing layer, a TFT array substrate, a liquid crystal layer, a color film substrate, the second quantum dot film layer and Upper polarizing layer.
  7. 根据权利要求1所述的量子点液晶显示器,其中,所述液晶显示面板包括由下到上设置的第三量子点膜层、反射式偏光增亮膜、下偏光层、TFT阵列基板、液晶层、彩膜基板以及上偏光层,所述第三量子点膜层是所述第二量子点层经过网印或纳米压印方法图案化后制备而成。The quantum dot liquid crystal display according to claim 1, wherein the liquid crystal display panel comprises a third quantum dot film layer, a reflective polarizing brightness enhancement film, a lower polarizing layer, a TFT array substrate, and a liquid crystal layer arranged from bottom to top. , A color film substrate and an upper polarizing layer, the third quantum dot film layer is prepared by patterning the second quantum dot layer through a screen printing or nanoimprinting method.
  8. 根据权利要求1所述的量子点液晶显示器,其中,所述第一量子点膜层以及所述第二量子点膜层的材料包括聚合物基质及分散于聚合物基质中的量子点。2. The quantum dot liquid crystal display of claim 1, wherein the materials of the first quantum dot film layer and the second quantum dot film layer include a polymer matrix and quantum dots dispersed in the polymer matrix.
  9. 根据权利要求8所述的量子点液晶显示器,其中,所述聚合物基质为树脂透明材料,所述树脂透明材料包括丙烯酸系树脂、环氧树脂、环烯烃聚合物、有机硅烷类树脂以及纤维酯中的一种或多种;所述量子点包括发光核与包裹于所述发光核外的无机保护壳层,所述发光核的红光材料包括CdSe、Cd 2SeTe及InAs中的一种或多种;所述发光核的绿光材料包括ZnCdSe 2、InP及Cd 2SSe中的一种或多种;所述无机保护壳层包括CdS、ZnSe、ZnCdS 2、ZnS及ZnO中的一种或多种。 The quantum dot liquid crystal display according to claim 8, wherein the polymer matrix is a resin transparent material, and the resin transparent material includes acrylic resin, epoxy resin, cycloolefin polymer, organosilane resin, and cellulose ester One or more of the quantum dots; the quantum dots include a light-emitting core and an inorganic protective shell layer wrapped around the light-emitting core, and the red light material of the light-emitting core includes one of CdSe, Cd 2 SeTe and InAs or The green material of the luminescent core includes one or more of ZnCdSe 2 , InP, and Cd 2 SSe; the inorganic protective shell layer includes one of CdS, ZnSe, ZnCdS 2 , ZnS, and ZnO or Many kinds.
  10. 根据权利要求8所述的量子点液晶显示器,其中,所述第一量子点膜层以及所述第二量子点膜层还包括高稳定性复合量子点膜层结构,所述高稳定性复合量子点膜层结构装载有水凝胶、MOFs或者CdSe-SiO 28. The quantum dot liquid crystal display according to claim 8, wherein the first quantum dot film layer and the second quantum dot film layer further comprise a high stability composite quantum dot film structure, and the high stability composite quantum dot The dot film layer structure is loaded with hydrogel, MOFs or CdSe-SiO 2 .
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