WO2020157935A1 - Flavor generating segment, and flavor generating article and flavor suction system comprising same - Google Patents

Flavor generating segment, and flavor generating article and flavor suction system comprising same Download PDF

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Publication number
WO2020157935A1
WO2020157935A1 PCT/JP2019/003472 JP2019003472W WO2020157935A1 WO 2020157935 A1 WO2020157935 A1 WO 2020157935A1 JP 2019003472 W JP2019003472 W JP 2019003472W WO 2020157935 A1 WO2020157935 A1 WO 2020157935A1
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WO
WIPO (PCT)
Prior art keywords
flavor
sheet
flavor generating
generating
segment
Prior art date
Application number
PCT/JP2019/003472
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French (fr)
Japanese (ja)
Inventor
渓介 春木
片山 和彦
Original Assignee
日本たばこ産業株式会社
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Publication date
Application filed by 日本たばこ産業株式会社 filed Critical 日本たばこ産業株式会社
Priority to PCT/JP2019/003472 priority Critical patent/WO2020157935A1/en
Priority to TW108105119A priority patent/TW202029890A/en
Publication of WO2020157935A1 publication Critical patent/WO2020157935A1/en

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F47/00Smokers' requisites not otherwise provided for

Definitions

  • the present invention relates to a flavor generating segment, a flavor generating article and a flavor suction system including the same.
  • Patent Document 1 discloses a tobacco segment crimped and gathered, and a non-combustion type aerosol suction system including the tobacco segment. In the tobacco segment, the sheet is solidly filled.
  • Patent Document 2 discloses a non-combustion type aerosol suction system including a rod formed by stacking a smokable material and the like.
  • non-combustion type flavor suction system stable delivery characteristics are required from the beginning of sucking to the end of sucking.
  • a flavor generation segment comprising one or more flavor generation sheets, The flavor generating sheet extends in the longitudinal direction, and is arranged concentrically around the longitudinal axis, At least one of the flavor generating sheets contains an additive acceptable for use in tobacco. Flavor generation segment.
  • the flavor generation segment according to any one of (1) to (4) including a plurality of the flavor generation sheets.
  • a heat transfer sheet extending in the longitudinal direction is further included between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer, and the heat transfer sheet is concentric with the flavor generating sheet.
  • the flavor-generating segment according to any one of (1) to (5) which is arranged in.
  • a flavor generating article comprising the flavor generating segment according to any one of (1) to (12) and a cooling unit, a filter, or both.
  • a flavor suction system comprising the flavor generating segment according to any one of (1) to (12) and a heater for heating the flavor generating segment.
  • the flavor generating segment has a space extending in the longitudinal direction between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer, and at least a part of the heater is The flavor suction system according to (15), which has a shape that can be positioned in a space.
  • the figure which shows one aspect of the flavor suction system of this invention The figure which shows the outline of the flavor generation segment of this invention.
  • Diagram showing the arrangement of heaters Diagram showing the outline of S OUT and S in The figure which shows the outline of the manufacturing method of the flavor generation segment of this invention.
  • positioning of a flavor generation sheet The figure which shows the outline of the flavor generation sheet where unevenness is provided Sectional photograph of the flavor generating segment obtained in Example 1 Delivery profile of the flavor generating segment obtained in Example 1 The figure which shows the outermost temperature of the flavor generation segment obtained in Example 1.
  • the flavor generation segment is a base material for generating flavor.
  • the flavor-generating article is an article capable of generating a flavor or an article capable of sucking a flavor, containing at least a flavor-generating segment.
  • the flavor-generating article includes a flavor-generating segment, but the flavor-generating segment itself may be the flavor-generating article.
  • the flavor suction system refers to a combination of a flavor generating article and a heating unit equipped with a heater.
  • the flavor generating segment of the present invention comprises one or more flavor generating sheets. At least one of the flavor generating sheets is an additive-containing sheet containing an additive that is acceptable for use in tobacco. That is, the flavor generating segment of the present invention comprises one flavor generating sheet and the flavor generating sheet is an additive-containing sheet, and a plurality of flavor generating sheets, one or more of which is an additive containing sheet. Including some embodiments. Even if only one additive-containing sheet is used, stable delivery characteristics can be achieved, but in the latter case, it is preferable to include more additive-containing sheets because more stable delivery characteristics can be achieved.
  • the present invention will be described below with reference to an embodiment in which a plurality of flavor generating sheets are provided and at least one of which is an additive-containing sheet unless otherwise specified.
  • the additive-containing is arranged to form a circle or approximately a circle about the longitudinal axis.
  • the present invention it is said that they are also arranged concentrically in this case.
  • the sheet refers to a shape having a pair of substantially parallel main surfaces and side surfaces.
  • the sheet is preferably produced by papermaking.
  • the longitudinal direction of the flavor generating segment is a direction orthogonal to the direction in which the flavor generating sheet is wound. Specifically, the direction of h in FIG. 2 and the direction of L in FIG. 8 is the longitudinal direction.
  • the longitudinal direction of the flavor-generating article may be regarded as the same as the longitudinal direction of the flavor-generating segment.
  • the shape of the flavor generating segment of the present invention is not limited, but it is preferably columnar.
  • the longitudinal direction is defined as the direction indicated by h.
  • the direction indicated by h is called the longitudinal direction for convenience.
  • the shape of the bottom surface is not limited and may be a polygon, a rounded polygon, a circle, an ellipse, or the like, and the width w is a diameter when the bottom surface is circular, a long diameter when the bottom surface is elliptical, a polygon, or a rounded polygon. In some cases it is the diameter of the circumscribing circle or the major axis of the circumscribing ellipse. For example, in the embodiment shown in FIG. 2, since the bottom surface is a circle, its diameter can be recognized, and the diameter is the width w and the length orthogonal to this is the height h.
  • the height h of the flavor generating segment 1 is preferably about 5 to 20 mm, and the width w is preferably about 4 to 9 mm.
  • the flavor generation segment 1 may include a wrapper at the outermost portion.
  • the wrapper may be a wrapping paper, or may be composed of the flavor generating sheet 10.
  • a flavor generating sheet is a sheet that generates a flavor, and includes a sheet in which a component capable of generating a flavor is supported on a sheet base material or a sheet composed of a material that generates a flavor.
  • a plurality of flavor generating sheets are arranged concentrically to form a flavor generating segment.
  • the component capable of generating a flavor include a flavor component contained in the tobacco raw material and a flavor component such as menthol.
  • the sheet base material include tobacco materials such as compressed tobacco pellets and tobacco powder. In the present invention, a tobacco material is preferable as the sheet base material.
  • the flavor generating sheet a tobacco sheet in which a base material sheet of a tobacco material is loaded with a component capable of generating a flavor if necessary is preferable.
  • the flavor generating sheet may generate an aerosol with heating.
  • An aerosol source such as glycerin, propylene glycol or a polyol such as 1,3-butanediol may be further added in order to accelerate the generation of aerosol.
  • the amount of such an aerosol source added is preferably 5 to 50% by weight, more preferably 10 to 30% by weight, based on the dry weight of the flavor generating sheet.
  • a polyol such as glycerin, propylene glycol and 1,3-butanediol may be added as a flavor component.
  • the flavor-generating sheet is also an aerosol-generating sheet if it contains an aerosol source or if the flavor component produces an aerosol. First, the aerosol generating sheet as a material before being concentrically arranged will be described.
  • the flavor generation segment includes a flavor generation sheet (additive-containing sheet) containing an additive that is allowed to be used in tobacco.
  • the additives that are allowed to be used in tobacco are described in, for example, the “Burning Control Agent” column of “Encyclopedia of Tobacco” (Tobacco Research Center).
  • the additive is preferably selected from the group consisting of organic acid metal salts, metal hydroxides, and combinations thereof.
  • organic acid metal salt include those added as a combustion enhancer to the cigarette paper of combustion type cigarette, and specific examples thereof include salts containing citric acid, tartaric acid, acetic acid, malic acid, formic acid and lactic acid.
  • metal component include those belonging to Group 1 or Group 2 of the periodic table. Of these, K, Na and the like are preferable.
  • the metal hydroxide include hydroxides of metals belonging to Group 2 of the periodic table, and among them, hydroxides of Mg and Ca are preferable.
  • the additive preferably has an endothermic peak between 100 and 400° C. when subjected to thermal analysis.
  • the endothermic peak examples include a peak due to a melting point and a peak due to a dehydration reaction of a hydrate.
  • sodium citrate usually exists as a dihydrate, but when it is heated, it dehydrates at 150° C. to be an anhydride.
  • Additives having such endothermic peaks are preferable because they can cool the aerosol appropriately. Therefore, the additive in the present invention also includes its hydrate.
  • the amount of the additive is preferably 0.5 to 1.5% by weight, more preferably 0.8 to 1.2% by weight, based on the weight of the flavor generating sheet.
  • At least one of the flavor generating sheets is an additive-containing sheet containing the additive, but the number of the additive-containing sheets is preferably 30% or more, more preferably 60% or more, and more preferably 100% or more of the total number of sheets. % Is more preferable.
  • the tobacco sheet can be appropriately produced by a known method such as papermaking, slurry and rolling. Specifically, in the case of papermaking, it can be manufactured by a method including the following steps. 1) Dried leaf tobacco raw material is roughly crushed and extracted with water to separate a water extract and a residue. 2) The water extract is dried under reduced pressure and concentrated. 3) Pulp is added to the residue, fiberized by a refiner, and then papermaking. 4) Add a concentrated solution of water extract to the paper sheet to make a dried tobacco sheet. In this case, a step of removing a part of components such as nitrosamine may be added (see JP-A-2004-510422).
  • the slurry method can be manufactured by a method including the following steps. 1) Mix water pulp binder and crushed tobacco. 2) Thinly (cast) the mixture and dry.
  • a non-woven tobacco sheet manufactured by a method including the following steps can also be used. 1) Mix powdered tobacco raw material and binder. 2) Sandwich the mixture with a non-woven fabric. 3) The laminate is formed into a constant shape by heat welding to obtain a non-woven tobacco sheet.
  • the composition of the tobacco sheet is not particularly limited, but for example, the content of the tobacco raw material is preferably 50 to 95% by weight based on the total weight of the tobacco sheet.
  • the tobacco sheet may contain a binder, and examples of the binder include guar gum, xanthan gum, CMC (carboxymethyl cellulose), CMC-Na (sodium salt of carboxymethyl cellulose) and the like.
  • the binder amount is preferably 2 to 20% by weight based on the total weight of the tobacco sheet.
  • the tobacco sheet may further contain other additives. Examples of other additives include fillers such as pulp.
  • the tobacco sheet contains a component capable of generating a flavor. Although a plurality of tobacco sheets are used in the present invention, all such tobacco sheets may have the same composition or physical properties, or some or all of the tobacco sheets may have different compositions or physical properties.
  • a sheet using a plant pulp other than the tobacco raw material as a sheet base material can be used.
  • a flavor generating sheet containing an additive can be manufactured by preparing a solution of the additive and applying or spraying the solution onto the flavor generating sheet.
  • the flavor generating sheet containing the additive can be produced by immersing the flavor generating sheet in a solution of the additive.
  • the solvent used for the solution is not limited, but alcohol such as ethanol is preferable.
  • the shape of the flavor generating sheet is not limited, but the shape of the sheet main surface is preferably quadrangular.
  • the thickness is not limited, it is preferably 200 to 600 ⁇ m in consideration of highly efficient heat exchange, strength of the flavor generating segment, and the like.
  • the thickness of each flavor generating sheet may be the same or different.
  • the length corresponding to the peripheral length when arranged concentrically is called the flavor generation sheet width W, and the length corresponding to the flavor generation segment length is called the flavor generation sheet length L. It is preferable that L is the same in all flavor generating sheets.
  • W it is preferable that W of the flavor generating sheet forming the outermost layer when arranged concentrically is larger than W of the flavor generating sheet forming the innermost layer. The reason for this will be described later.
  • At least one of the plurality of flavor generating sheets preferably has a surface treatment on a part or all of at least one surface.
  • the surface processing refers to processing for forming a plurality of irregularities on at least one main surface of the flavor generating sheet, that is, the front surface or the back surface.
  • the surface processing method is not particularly limited, and known processing such as crimping processing, embossing processing, debossing processing, cutting processing, and half cutting can be used.
  • the crimping process is a process of forming wrinkles on the sheet.
  • crimping is performed by providing wrinkles extending orthogonally to the sheet conveying direction on both the front surface and the back surface of the flavor generating sheet.
  • the convex portion provided on the roller extends perpendicularly to the sheet conveying direction.
  • the pitch between the apexes of the protrusions provided on the roller is preferably 0.5 to 2.0 mm. Therefore, the pitch of the flavor generating sheet is preferably 0.5 to 2.0 mm. Further, the pitch of the flavor generating sheet is preferably 1.5 to 20% with respect to the peripheral length of the wrapper or the wrapping paper.
  • the height H of the irregularities made by the crimp when the average thickness of the sheet and T av is preferably 1.05T av ⁇ 1.59T av.
  • the height H is defined as the distance from the bottom of the sheet to the top of the sheet when the crimped sheet is placed on a horizontal surface.
  • the embossing process and the debossing process are processes in which a convex processing tool is pressed against a sheet to form a recess on one side or both sides of the sheet.
  • Cutting is a process of removing a part of the sheet to form a recess, and may be performed by mechanical processing for mechanically cutting the sheet or by non-contact processing such as laser processing.
  • the half-cutting is a processing in which a cut is formed on one or both sides of the sheet to a depth such that the sheet is not cut, and preferably to a depth not more than half the sheet thickness.
  • a knife or a laser can be used for the half-cut processing.
  • by subjecting the flavor generating sheet to a surface treatment it is possible to efficiently form a non-contact portion, preferably a gap described later, when arranged concentrically.
  • the flavor generating sheet serving as the innermost layer is not surface-treated.
  • the pitch between the vertices of the convex portions of the flavor generating sheet may be the same or different within the same sheet. Further, the pitch between the vertices of the convex portions of each flavor generating sheet may be different for each sheet or may be the same.
  • FIG. 10 shows one aspect of the flavor generating sheet that has been cut.
  • 10 is a concave-convex flavor generating sheet
  • 10c is a convex portion (mountain portion)
  • 10r is a concave portion (groove portion)
  • f is a direction length (hereinafter also referred to as “groove width”) orthogonal to the direction in which the concave-convex extends
  • d is The length in the thickness direction (hereinafter also referred to as “groove depth”).
  • FIG. 10 shows the uneven flavor generating sheet 10 placed in a flat state. Further, although the figure shows a mode in which unevenness is provided on one side, the unevenness may be provided on both sides. In this case, the positions of the recesses on both sides may be the same or different.
  • the pitch Pt of the concavities and convexities be constant, and the cross-sectional shape of the recesses be substantially rectangular.
  • the sizes of d and f it is possible to control the delivery profile of the flavor and taste component in the flavor generating article.
  • nicotine can be mentioned.
  • f ⁇ d that is, when a sharp concave portion is provided
  • initial delivery can be improved.
  • f ⁇ d that is, when a broad concave portion is provided
  • the delivery can be increased to the final stage.
  • the groove width is preferably 10% or more and less than 50% with respect to the pitch, and the groove depth is preferably 50 to 99% with respect to the sheet thickness.
  • the groove width f is 0.1 to 0.5 mm and the groove depth d is appropriately selected from 0.3 to 0.59 mm.
  • the groove width is 50 to 90% with respect to the pitch, and the groove depth is 30% or more and less than 50% with respect to the sheet thickness.
  • f is 0.5 to 0.9 mm and d is appropriately selected from 0.1 to 0.3 mm.
  • the pitch Pt of the irregularities is not limited, but is preferably 0.5 to 1.5 mm, more preferably 0.8 to 1.2 mm.
  • each flavor generating sheet extends in the longitudinal direction of the flavor generating segment and is arranged concentrically by roll-up molding or the like.
  • “arranged concentrically” means that the centers of all flavor generating sheets are arranged at substantially the same position.
  • the intersection is defined by the major axis and the minor axis.
  • An axis passing through the center and parallel to the longitudinal direction is referred to as a "longitudinal axis that is the center of arrangement” or simply “center axis of arrangement”. As shown in FIG.
  • the center axis 12 of the arrangement is preferably the same as the axis passing through the center of the cross section of the flavor generating segment 1, that is, the center axis of the flavor generating segment, but is displaced from the center axis of the flavor generating segment 1.
  • the mode in which the centers are eccentric is also referred to as "arranged concentrically".
  • the central axis 12 of the arrangement may be offset from the center axis of the flavor generating segment 1 by about 0.1R to 0.7R.
  • the number of the flavor generating sheets 10 arranged concentrically is preferably 3 to 12.
  • the total weight of the plurality of flavor generating sheets included in the flavor generating segment is preferably 130 to 685 mg, and more preferably 200 to 350 mg.
  • each flavor generating sheet is arranged so as to have a non-contact portion between the adjacent sheets, there is a non-contact portion where the flavor generating sheets do not contact each other between at least one pair of the adjacent flavor generating sheets.
  • the aspect 1 in which the adjacent flavor generating sheets are not entirely in contact with each other in the circumferential direction and the aspect in which the flavor generating sheets are in contact with each other between at least one pair of the adjacent flavor generating sheets There are two.
  • “arranged concentrically” also includes aspect 2.
  • the flavor-generating sheet contains an aerosol source such as glycerin, but it is preferable to adjust the weight of the aerosol source contained in each flavor-generating sheet so that the delivery of the aerosol is uniform throughout the suction.
  • the weight of the aerosol source of each sheet is the same, the weight of the aerosol source per sheet thickness will be the same. Therefore, the amount of aerosol source that can be generated at the positions A, B, and C can be made substantially the same.
  • X Weight of the aerosol source contained in the sheet A covering the position of A: b: Thickness of the sheet B covering the position of B
  • Y Weight of the aerosol source contained in the sheet B covering the position of B: c: Thickness of the sheet C covering the position of C
  • Z Weight of aerosol source contained in sheet C covering position C
  • such a design is possible by providing a difference in the inner and outer circumferences of the cylindrically arranged sheets and a difference in the surface processing on the inner and outer surfaces.
  • a mode in which a large number of half cuts are provided on the inner surface and a small number of half cuts are provided on the surface can be considered.
  • by changing the weight of the flavor component and the flavor component contained in the sheet in the sheet arranged on the inner side and the sheet arranged on the outer side it is possible to change the flavor and taste at a desired timing during inhalation. it can.
  • Non-contact portion In Embodiment 2, the non-contact portion formed between the contact portion and the contact portion is referred to as "gap".
  • the non-contact portion formed between the contact portion and the contact portion is referred to as "gap".
  • the second mode is preferable in the present invention. In this case, it is more preferable that some or all of the gaps extend from the front end portion to the rear end portion of the flavor generating segment.
  • At least one of the flavor generating sheets and at least one of the flavor generating sheets adjacent to the flavor generating sheet are in contact with each other at least in part, but the plurality of flavor generating sheets are arranged in the circumferential direction, that is, in the winding direction. It is preferable that they are in contact with each other.
  • the method for bringing adjacent flavor generating sheets into contact with each other is not particularly limited, and for example, by performing the above-mentioned surface treatment on at least one flavor generating sheet or by changing the width of each flavor generating sheet. You can As a method of bringing adjacent flavor generating sheets into contact with each other in the present invention, it is preferable to subject at least one of the flavor generating sheets to a surface treatment.
  • the surface-processed flavor generating sheet forms a convex portion in the circumferential direction when rolled up.
  • the position of this convex portion in the adjacent flavor generating sheet does not exist at the same position in the circumferential direction, that is, by shifting the phase of the unevenness in the circumferential direction of each flavor generating sheet,
  • the contact portion can be provided more reliably (see FIG. 3).
  • C is a contact portion and V is a gap.
  • the method of shifting the phase is not limited, but for example, changing the pitch of the surface processing for each flavor generating sheet, changing the thickness and width of each flavor generating sheet, changing the force applied in the winding direction during roll-up molding for each layer, etc. There is a method.
  • the contacts need not be glued.
  • the flavor generating sheet has a plurality of convex portions provided by the surface treatment, at least one of the convex portions may be in contact with the adjacent flavor generating sheet.
  • the longitudinal direction of the convex portion formed on the crimped sheet is parallel or substantially parallel to the longitudinal direction of the flavor generating segment. Is preferred.
  • the longitudinal direction of the convex portion is the direction in which the ridge line extends, and is the direction orthogonal to the sheet conveying direction during processing by the crimp roller.
  • the maximum value Gmax of the interlayer distance between two adjacent flavor generating sheets is larger than the maximum value Tmax of the flavor generating sheet thickness of at least one of the two adjacent flavor generating sheets.
  • the interlayer distance n formed between the nth sheet and the (n+1)th sheet in a certain cross section of the flavor generating segment 1 is measured to determine the maximum value G (n) max.
  • the thicknesses of the n-th sheet and the (n+1)-th sheet are measured, and the maximum values T (n) max and T (n+1) max are determined and compared. This measurement is performed for all layers. For example, when the number of sheets is 4, the measurement is performed on three layers. Then, it is confirmed that the following is satisfied in the cross section.
  • the maximum value Gmax of the interlayer distance between two adjacent flavor generating sheets is greater than the maximum value Tmax of the flavor generating sheet thickness of at least one of the two adjacent flavor generating sheets.
  • the following measurement is preferable.
  • the flavor generating segment 1 is impregnated with a low-viscosity curable resin (for example, an epoxy resin), the non-contact portion is filled with the resin, and then the resin is cured to prepare a measurement sample. Next, the measurement is performed while cutting the sample.
  • a low-viscosity curable resin for example, an epoxy resin
  • the ratio of the total amount of the non-contact portion in the flavor generating segment (hereinafter also referred to as “porosity”) is preferably 0.10 to 0.40, more preferably 0.15 to 0.36, and 0 Particularly preferably, it is 0.25 to 0.33.
  • porosity is preferably 0.10 to 0.40, more preferably 0.15 to 0.36, and 0 Particularly preferably, it is 0.25 to 0.33.
  • the shape of the flavor generating segment is maintained by the restoring force of the flavor generating sheet. That is, it is preferable that the arranged flavor generating sheet emits a force to spread to the outside by the restoring force, and the flavor generating sheet or the wrapper existing on the outside receives the force to maintain the shape of the flavor generating segment. .. Therefore, it is preferable that the restoring force of the flavor generating sheet 10 in , which is the innermost layer, is larger than the restoring force of the other flavor generating sheets, because the shape is more stable (FIG. 2). The restoring force can be adjusted by the thickness of the sheet and the presence or absence of surface treatment.
  • the wrapper preferably has an overlapping portion. It is preferable that the overlapping portion is bonded.
  • a configuration in which surface-processed flavor generating sheets and non-surface-processed flavor generating sheets are alternately present is also preferable.
  • it is preferable that the flavor generating sheet is subjected to half-cut processing as surface processing.
  • the flavor generating sheet 10 provided with unevenness may be arranged as shown in FIG. Specifically, the convex portions of each sheet can be arranged at substantially equal positions in the circumferential direction (FIG. 4(1)). Further, the recesses of the adjacent sheets in the circumferential direction can be arranged at substantially the same positions as the recesses of the adjacent uneven flavor generating sheet (FIG. 4(2)). Further, with respect to the flavor generating sheet 10 having both sides provided with protrusions and recesses, the protrusions of the respective flavor generating sheets can be arranged at substantially equal positions in the circumferential direction (FIGS. 4(3) and (4)). FIG.
  • FIG. 4(3) shows a mode in which the concavo-convex pattern is symmetrical on both sides of the flavor generating sheet
  • FIG. 4(4) shows a mode in which the concave portion on one surface of the flavor generating sheet exists at the position of the convex portion on the other surface. Indicates.
  • one flavor generating sheet is continuous in the circumferential direction.
  • the overlapping portions where the sheets overlap may or may not exist.
  • the overlapped portion is a portion where one end in the circumferential direction of the flavor generating sheet overlaps the other end in one aspect.
  • the presence of the overlapping portions at both ends has an advantage that the strength of the flavor generating segment can be improved.
  • the flavor generating sheet of the innermost layer is not bonded to a region in which one end in the circumferential direction exceeds the other end. This is because the presence of the adhesion region reduces the restoring force of the flavor generating sheet in the innermost layer.
  • both ends of the flavor generating sheet in the circumferential direction are in contact with each other and a mode in which they are separated from each other.
  • both ends of the flavor generating sheet of the innermost layer are not bonded. This is because if both ends are adhered, the restoring force of the flavor generating sheet in the innermost layer is reduced.
  • both ends of the flavor generating sheet in the circumferential direction are spaced apart from each other, that is, it is preferable to have a spacing portion between both ends.
  • the separation distance is not limited, but it is preferable that the distance between both ends of the flavor generating sheet is more than 0 mm and 2 mm or less. When separated in this way, both ends are also said to be adjacent.
  • the spacing portions 18 of the flavor generating sheet 10 are present at substantially the same position in the circumferential direction. The presence of the spacing portions at substantially the same position means that the spacing portions 18 penetrate from the outer peripheral portion toward the center of the arrangement. With such a structure, the production of the flavor generating segment 1 of the present invention becomes easier.
  • both ends of the flavor generating sheet may overlap.
  • the perimeter of the outermost flavor generating sheet is longer than the perimeter of the innermost flavor generating sheet.
  • the flavor generation segment may have a space near the central axis of the arrangement. Specifically, as shown in FIG. 2, a space 14 extending in the longitudinal direction may be provided between the central axis 12 of the arrangement and the flavor generating sheet 10 in which is the innermost layer.
  • the cross-sectional area of such a space is preferably 15 to 46% of the cross-sectional area of the flavor generating segment 1.
  • a space for housing a cylindrical heater as shown in FIG. 6A inside the segment can be secured.
  • the cross-sectional area of the space 14 is as small as possible.
  • the cross-sectional area of the space 14 is preferably equal to or less than the total cross-sectional area of the non-contact portion formed between two adjacent flavor generating sheets.
  • the center side in the cross section that is, the inner side of the innermost layer of the flavor generation sheet arranged concentrically, or the side opposite to the center in the cross section, that is, the flavor generation arranged concentrically
  • a heat conductive member may be provided further outside the outermost layer of the sheet.
  • the heat conductive member is preferably a sheet-shaped member (heat transfer sheet), and specifically, a metal sheet such as aluminum can be used.
  • the method for arranging the heat transfer sheet is not limited, but the heat transfer sheet may be arranged concentrically with the flavor generating sheet (see FIG. 2), or may be attached to the front surface or the back surface of the flavor generating sheet.
  • the position of arranging the heat transfer sheet is not limited, but it is preferable to dispose the heat transfer sheet close to the heater in the flavor generating system because heat generated from the heater can be efficiently conducted to each flavor generating sheet.
  • the heat conductive member is also arranged in the central portion.
  • the heat conductive member is also arranged on the outer peripheral side of the flavor generating segment.
  • FIG. 5 shows one mode of the flavor generating article.
  • 2 is a flavor generating article
  • 1 is a flavor generating segment
  • 20 is a mouthpiece
  • 22 is a filter
  • 24 is a cavity
  • 26 is a support member.
  • the central axis of the arrangement of the flavor generating segment 1 and the longitudinal direction of the flavor generating article 2 are parallel.
  • the support member and the cavity may be optionally provided in the flavor generating article.
  • the mouthpiece 20 is a member having a mouthpiece and may include a filter 22.
  • the size of the mouthpiece 20 is not limited, the mouthpiece 20 preferably has the same width as the flavor generating segment 1 and preferably has a length of 26 to 50 mm.
  • the filter 22 is preferably made of a material usually used in this field such as a cellulose acetate filter.
  • the length of the filter 22 is preferably 12 to 60% of the total length of the mouthpiece 20.
  • the cavity 24 is a space, and ventilation may be provided on the side surface of the wrapper forming the cavity 24.
  • the cavity 24 is a cooling unit that cools the heated flavor. Further, the cavity 24 also has a function of appropriately mixing flavor and air to adjust flavor and the like.
  • the length of the cavity 24 is preferably 8 to 77% of the total length of the mouthpiece 20.
  • the cavity 24 may be provided with cooling elements to enhance the cooling function. Examples of the cooling element include a polylactic acid sheet, and a plurality of polylactic acid sheets subjected to crimping can be used as the cooling element.
  • the support member 26 enhances the strength of the flavor generating article and retains its shape.
  • the support member 26 is preferably composed of a heat-resistant plastic such as cellulose acetate or polyether ether ketone (PEEK), silicon, ceramic or the like, which is a material usually used in this field.
  • PEEK polyether ether ketone
  • the support member for example, a cylindrical member having a space in the central axis in the longitudinal direction can be preferably used.
  • the length of the support member 26 is preferably 14 to 77% of the total length of the mouthpiece 20.
  • Flavor suction system The flavor suction system of the present invention includes a heater.
  • the heater preferably heats the flavor generating segment non-combustively, more preferably electrically.
  • the heater preferably includes a heating unit including a power source and the like.
  • FIG. 1 shows one embodiment of the flavor suction system of the present invention. In the figure, 1 is a flavor generating segment, 20 is a mouthpiece, 22 is a filter, 30 is a heater, and 32 is a heating unit.
  • the shape of the heater 30 is not limited, but it is preferable that a part of the heater 30 has a shape that can be arranged in the space 14 in the flavor generation segment.
  • it may be a sheet heater, a flat plate heater, or a tubular heater.
  • the sheet-shaped heater is a flexible sheet-shaped heater, and examples thereof include a heater including a film of a heat-resistant polymer such as polyimide (thickness: about 20 to 225 ⁇ m).
  • the plate heater is a rigid plate heater (thickness: about 200 to 500 ⁇ m), and for example, a heater having a resistor circuit on a plate base material and having that portion as a heat generating portion can be mentioned.
  • the tubular heater is a hollow or solid tubular heater, and examples thereof include a heater having a resistance circuit on the outer peripheral surface and using the portion as a heat generating portion.
  • the sectional shape of the cylindrical heater may be a circle, an ellipse, a polygon, a rounded polygon, or the like.
  • FIG. 6 is a sectional view of the flavor suction system of the present invention.
  • 30 is a heater and 10 is a flavor generating sheet.
  • the heater 30 can be arranged in the space 14 of the flavor generating segment.
  • FIG. 6A shows a mode in which the solid cylindrical heater 30 is arranged in the space
  • FIG. 6B shows a mode in which the flat plate heater 30 is arranged.
  • the flavor generating segment preferably has a heat transfer sheet arranged concentrically with the flavor generating sheet 10, and the heat transfer sheet is more preferably adjacent to the heater 30.
  • the flat plate heater and the tubular heater are suitable for heating the flavor generating sheet 10 from the inside.
  • the heater may be inserted so as to break the innermost flavor generating sheet 10 in or the flavor generating sheet 10 present in the vicinity thereof.
  • FIG. 7 shows a part of the cross section of the flavor generation segment 1 in which the heater 30 is arranged in the space 14.
  • the former cross-sectional area is represented by S in
  • the latter cross-sectional area is represented by S out .
  • S out is preferably greater than S in .
  • the relationship between S in and S out is more preferably maintained in the longitudinal direction of the flavor generating segment, and S in and S out are constant values in the longitudinal direction of the flavor generating segment. Is particularly preferable.
  • S out and S in can be measured by observing a plurality of cross sections of the flavor suction system 3 similarly to Gmax and Tmax. At this time, it is determined that the flavor generating sheet exists in the space between the flavor generating sheet 10 in and the flavor generating sheet 10 out .
  • the heater 30 can be arranged outside the flavor generating sheet 10 out which is the innermost layer. If the flavor generating segment 1 comprises a wrapper, the heater 30 may be located outside the wrapper. Further, as shown in FIG. 6D, the heater 30 can be arranged between the flavor generating sheets 10. As described above, the sheet-shaped heater is suitable for heating the flavor generating sheet 10 from the outside or the middle. The sheet heaters may have their ends separated or in contact with each other. Also in this aspect, it is preferable that the flavor generating segment has a heat transfer sheet arranged concentrically with the flavor generating sheet 10, and the heat transfer sheet is more preferably adjacent to the heater 30.
  • the manufacturing method of the flavor suction system 3 of the present invention is not limited, but the flavor generating segment 1, the mouthpiece 20, the heater 30 and the like are prepared respectively and can be manufactured by combining them.
  • a plurality of flavor generating sheets 10 having different widths W are prepared, and a laminated body 100 is prepared in which W is laminated so that W becomes smaller from the bottom portion to the top portion. It can be manufactured by passing it through a winding tube 6 and winding it up.
  • FIG. 8B is a view of the laminated body 100 viewed from the opening direction of the winding tube 6. However, the laminated body 100 is prepared such that a non-contact portion is formed between the flavor generating sheets adjacent to each other after roll-up molding.
  • the entire surfaces of the adjacent flavor generating sheets 10 are laminated without adhering, the parts of the adjacent flavor generating sheets 10 are adhered and laminated, or the entire surface or a part of the adjacent flavor generating sheets 10 is adhered.
  • the laminated body 100 can be prepared by gently adhering and laminating so as to peel off after roll-up molding. If necessary, a heat transfer sheet may be arranged in the laminate 100, or a wrapper may be arranged at the bottom of the laminate 100. Further, a space 14 can be formed by placing a cylindrical dummy such as a mandrel on the top of the laminated body 100 to form the flavor generating segment 1 and then removing the dummy.
  • the flavor suction system 3 can be manufactured by inserting the heater 30 into the space 14. Further, the flavor suction system 3 may be manufactured by passing the laminated body 100 having the heater 30 mounted on the top thereof through the winding tube 6.
  • the flavor suction system 3 can be manufactured by passing the laminated body 100 having the heater 30 arranged between the flavor generating sheets 10 or at the bottom thereof through the winding tube 6.
  • the mouthpiece 20 including the filter 22 may be prepared by a known method.
  • the flavor suction system 3 including the filter 22 can be manufactured by disposing the filter 22 at the rear end portion of the flavor suction system 3 and winding them with a wrapper. By disposing the support member 16 so as to abut the rear end of the flavor suction system 3 and further disposing the filter 22 at a distance, the flavor suction system 3 further including the support member 16 and the cavity 24 can be manufactured.
  • Example 1 350 g of tobacco cut was taken as one batch, and 12 times the water of the tobacco cut was added and mixed. The mixture was heated to 50° C. and the water-soluble component was extracted with a screw to obtain a tobacco material and an extract. The extract was concentrated, and then 15% by weight of glycerin was added to the concentrate to obtain an additive solution.
  • Laser processing was performed on one side of the flavor generating sheet using a laser processing machine (Trotec, speedy 100).
  • a recess having a groove width f of 0.2 mm and a groove depth d of 0.5 mm was provided.
  • the uneven pitch Pt was 1 mm.
  • a sodium citrate hydrate was dissolved in ethanol to prepare a solution having a sodium citrate hydrate concentration of 2.2% by weight. 100 mg of the solution was applied to 200 mg of the sheet and dried to prepare an additive-containing flavor generating sheet. The amount of sodium citrate hydrate added was 1.1% by weight based on the dry weight of the flavor generating sheet.
  • Three flavor generating sheets that have been subjected to the surface treatment and to which additives have been added are laminated on a wrapping paper with the surface-treated surface facing downward, and a cylindrical dummy is placed on the uppermost portion to form a laminate.
  • This laminated body is passed through a winding tube having a diameter of 7 mm to wind up a wrapping paper and a concave-convex flavor generating sheet, and then a cylindrical dummy is pulled out to form a tobacco segment which is a flavor generating segment having a space extending in the longitudinal direction in the central portion.
  • the uneven portion extended in the longitudinal direction of the segment.
  • the length L of the obtained tobacco segment was 12 mm.
  • the diameter of the cylindrical dummy was 3.2 mm.
  • the ratio was constant over the length of the flavor generating segment.
  • a 45 mm long wrapper was prepared, and the tobacco segment was placed on the wrapper such that the longitudinal direction of the wrapper and the longitudinal direction of the tobacco segment were in the same direction.
  • a hollow cylindrical acetate filter with a length of 8 mm was then prepared and placed on the wrapper adjacent to the tobacco segment. At this time, the central axes of the both were made to coincide with each other.
  • the wrapper was rolled up to obtain a flavor generating article 2 including a tobacco segment having a length of 12 mm, a hollow cylindrical acetate filter having a length of 8 mm, and a cavity having a length of 25 mm in this order.
  • a photograph of the cross-sectional view is shown in FIG.
  • a heating device for heating the obtained flavor generating article As a heating device for heating the obtained flavor generating article, a hollow cylindrical heater having a length of 12 mm and a diameter of 3.2 mm, a battery for heating the heater, and a control circuit for controlling the heater and the battery Then, a heating unit provided with a housing for mainizing each member was prepared. The hollow cylindrical heater was inserted into the space of the flavor generating article manufactured in Example 1 to obtain a flavor suction system.
  • an automatic smoking device (RM26 manufactured by Bolgwaldt) connected to a Cambridge filter
  • the automatic smoking device has an electrically controlled suction syringe and an electromagnetic valve between the syringe and the Cambridge filter whose flow path can be changed by a valve controller so that fluid communication with the Cambridge filter can be controlled. I was prepared. Each sample was connected to the Cambridge filter of the apparatus, and the component amount was measured according to the cumulative puff operation frequency. Specifically, the valve controller opened and closed the electromagnetic valve to connect the syringe during suction and the Cambridge filter for 2 seconds, and then released the Cambridge filter to the atmosphere for 28 seconds.
  • the Cambridge filter was collected to obtain an analysis sample in which the flavor of the puff was collected once.
  • the suction by the suction syringe was set so that the suction capacity was 55 mL/2 sec.
  • the quantification was carried out using a gas chromatograph-mass spectrometer (GC/MS) after shaking extraction of each Cambridge filter with 10 mL of EtOH solvent.
  • GC/MS gas chromatograph-mass spectrometer
  • Examples 2 and 3 A flavor suction system was produced and evaluated in the same manner as in Example 1 except that the additives and the amounts thereof were changed as shown in Table 1.
  • Example 1 A flavor suction system was produced and evaluated in the same manner as in Example 1 except that no additive was used. The results are shown in Table 1, FIG. 12 and FIG. FIG. 12 shows the delivery amounts of the components that affect the flavor and taste, and nicotine was used as the representative component.
  • Flavor generating segment 10 Flavor generating sheet 12 Central axis of arrangement 14 Space 16 Heat transfer sheet 18 Separation part 100 Laminate C Contact part V Gap G Distance between flavor generating sheets T Flavor generating sheet thickness L Flavor generating sheet length W Flavor generating Seat width 2 Flavor generating article 20 Mouthpiece 22 Filter 24 Cavity 26 Supporting member 3 Flavor suction system 30 Heater 32 Heating unit 6 winding tubes

Abstract

A flavor generating segment comprising at least one flavor generating sheet, wherein the flavor generating sheet extends in a longitudinal direction and is concentrically arranged about the longitudinal axis, and the at least one flavor generating sheet contains an additive that is permitted for use with tobacco.

Description

香味発生セグメント、ならびにこれを備える香味発生物品および香味吸引システムFlavor generating segment, flavor generating article and flavor suction system including the same
 本発明は、香味発生セグメント、ならびにこれを備える香味発生物品および香味吸引システムに関する。 The present invention relates to a flavor generating segment, a flavor generating article and a flavor suction system including the same.
 従来たばこの代替として非燃焼型香味吸引システムの開発が進められている。例えば特許文献1には、捲縮加工およびギャザー加工が施されたたばこセグメント、およびこれを備える非燃焼型エアロゾル吸引システムが開示されている。係るたばこセグメントにおいては当該シートが中実に充填されている。また特許文献2には喫煙可能材料等を積層してなるロッドを備える非燃焼型エアロゾル吸引システムが開示されている。 Developed a non-combustion type flavor suction system as an alternative to conventional cigarettes. For example, Patent Document 1 discloses a tobacco segment crimped and gathered, and a non-combustion type aerosol suction system including the tobacco segment. In the tobacco segment, the sheet is solidly filled. Further, Patent Document 2 discloses a non-combustion type aerosol suction system including a rod formed by stacking a smokable material and the like.
特表2014-515274号公報Japanese Patent Publication No. 2014-515274 国際公開第2016/156510号International Publication No. 2016/156510
 非燃焼型香味吸引システムにおいては、吸始めから吸終わりまでにわたって安定したデリバリー特性が求められる。かかる事情を鑑み、本発明は、安定したデリバリー特性を有する香味発生セグメント、これを備える香味発生物品および香味吸引システムを提供することを課題とする。  In non-combustion type flavor suction system, stable delivery characteristics are required from the beginning of sucking to the end of sucking. In view of such circumstances, it is an object of the present invention to provide a flavor generating segment having stable delivery characteristics, a flavor generating article including the flavor generating segment, and a flavor suction system.
(1)1枚以上の香味発生シートを備える香味発生セグメントであって、
 前記香味発生シートは、長手方向に延在し、かつ当該長手方向軸を中心として同心状に配置されており、
 前記香味発生シートの少なくとも1枚は、たばこに使用することが許容される添加剤を含有する、
香味発生セグメント。
(2)前記添加剤が、有機酸金属塩、金属水酸化物、およびこの組合せからなる群から選択される、(1)に記載の香味発生セグメント。
(3)前記添加剤が周期表の第1族または第2族に属する元素を含む、(1)または(2)に記載の香味発生セグメント。
(4)前記添加剤の量が、前記香味発生シートの重量に対して0.5~1.5重量%である、(1)~(3)のいずれかに記載の香味発生セグメント。
(5)前記香味発生シートを複数備える、(1)~(4)のいずれかに記載の香味発生セグメント。
(6)前記配置の中心である長手方向軸と最内層の香味発生シートとの間に、当該長手方向に延在する伝熱シートをさらに含み、当該伝熱シートが前記香味発生シートと同心状に配置されている、(1)~(5)のいずれかに記載の香味発生セグメント。
(7)前記香味発生シートの全枚数中に占める前記添加剤を含有する香味発生シートの全枚数の割合が30%以上である、(1)~(6)のいずれかに記載の香味発生セグメント。
(8)前記割合が60%以上である、(7)に記載の香味発生セグメント。
(9)前記割合が100%である、(8)に記載の香味発生セグメント。
(10)前記香味発生シートのうち少なくとも1枚は、片面または両面の一部または全部に表面加工が施されている、(1)~(9)のいずれかに記載の香味発生セグメント。
(11)前記表面加工によって表面に凹凸が設けられ、その凹部および凸部は香味発生セグメントの長手方向に延びている、(10)に記載の香味発生セグメント。
(12)前記配置の中心である長手方向軸と、最内層の香味発生シートとの間に、当該長手方向に延在する空間を有する、(1)~(11)のいずれかに記載の香味発生セグメント。
(13)前記(1)~(12)のいずれかに記載の香味発生セグメントと、冷却部またはフィルタあるいはその両方を備える香味発生物品。
(14)フィルタを備え、当該フィルタ側から吸引可能な(13)に記載の香味発生物品。
(15)前記(1)~(12)のいずれかに記載の香味発生セグメントと、当該香味発生セグメントを加熱するヒーターとを備える、香味吸引システム。
(16)前記香味発生セグメントが、前記配置の中心である長手方向軸と最内層の香味発生シートとの間に、当該長手方向に延在する空間を有し、前記ヒーターの少なくとも一部が当該空間内に位置づけることが可能な形状を具備する、(15)に記載の香味吸引システム。
(1) A flavor generation segment comprising one or more flavor generation sheets,
The flavor generating sheet extends in the longitudinal direction, and is arranged concentrically around the longitudinal axis,
At least one of the flavor generating sheets contains an additive acceptable for use in tobacco.
Flavor generation segment.
(2) The flavor generating segment according to (1), wherein the additive is selected from the group consisting of organic acid metal salts, metal hydroxides, and combinations thereof.
(3) The flavor generating segment according to (1) or (2), wherein the additive contains an element belonging to Group 1 or Group 2 of the periodic table.
(4) The flavor generating segment according to any one of (1) to (3), wherein the amount of the additive is 0.5 to 1.5% by weight based on the weight of the flavor generating sheet.
(5) The flavor generation segment according to any one of (1) to (4), including a plurality of the flavor generation sheets.
(6) A heat transfer sheet extending in the longitudinal direction is further included between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer, and the heat transfer sheet is concentric with the flavor generating sheet. The flavor-generating segment according to any one of (1) to (5), which is arranged in.
(7) The flavor generating segment according to any one of (1) to (6), wherein the ratio of the total number of the flavor generating sheets containing the additive to the total number of the flavor generating sheets is 30% or more. ..
(8) The flavor generating segment according to (7), wherein the ratio is 60% or more.
(9) The flavor generation segment according to (8), wherein the ratio is 100%.
(10) The flavor generating segment according to any one of (1) to (9), wherein at least one of the flavor generating sheets has one or both surfaces partially or wholly surface-treated.
(11) The flavor generating segment according to (10), wherein unevenness is provided on the surface by the surface processing, and the recesses and protrusions extend in the longitudinal direction of the flavor generating segment.
(12) The flavor according to any one of (1) to (11), which has a space extending in the longitudinal direction between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer. Occurrence segment.
(13) A flavor generating article comprising the flavor generating segment according to any one of (1) to (12) and a cooling unit, a filter, or both.
(14) The flavor generating article according to (13), which includes a filter and can be sucked from the filter side.
(15) A flavor suction system comprising the flavor generating segment according to any one of (1) to (12) and a heater for heating the flavor generating segment.
(16) The flavor generating segment has a space extending in the longitudinal direction between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer, and at least a part of the heater is The flavor suction system according to (15), which has a shape that can be positioned in a space.
本発明の香味吸引システムの一態様を示す図The figure which shows one aspect of the flavor suction system of this invention. 本発明の香味発生セグメントの概要を示す図The figure which shows the outline of the flavor generation segment of this invention. 本発明の香味発生セグメントの一部の概要を示す図The figure which shows the outline of a part of flavor generation segment of this invention. 香味発生シートの配置の一態様を示す図The figure which shows one aspect of arrangement|positioning of a flavor generation sheet. 本発明の香味発生物品の概要を示す図The figure which shows the outline of the flavor generation|occurrence|production article of this invention. ヒーターの配置を示す図Diagram showing the arrangement of heaters OUTとSinの概要を示す図Diagram showing the outline of S OUT and S in 本発明の香味発生セグメントの製造方法の概要を示す図The figure which shows the outline of the manufacturing method of the flavor generation segment of this invention. 香味発生シートの配置の一態様を示す図The figure which shows one aspect of arrangement|positioning of a flavor generation sheet. 凹凸が設けられた香味発生シートの概要を示す図The figure which shows the outline of the flavor generation sheet where unevenness is provided 実施例1で得た香味発生セグメントの断面写真Sectional photograph of the flavor generating segment obtained in Example 1 実施例1で得た香味発生セグメントのデリバリープロファイルDelivery profile of the flavor generating segment obtained in Example 1 実施例1で得た香味発生セグメントの最外部温度を示す図The figure which shows the outermost temperature of the flavor generation segment obtained in Example 1.
 本発明において、香味発生セグメントとは香味を発生するための基材である。香味発生物品とは少なくとも香味発生セグメントを含み、香味を発生可能な物品あるいは香味を吸引可能な物品である。香味発生物品は香味発生セグメントを含むが、香味発生セグメント自体が香味発生物品であってもよい。香味吸引システムとは香味発生物品と、ヒータを備えた加熱ユニットとの組合せをいう。 In the present invention, the flavor generation segment is a base material for generating flavor. The flavor-generating article is an article capable of generating a flavor or an article capable of sucking a flavor, containing at least a flavor-generating segment. The flavor-generating article includes a flavor-generating segment, but the flavor-generating segment itself may be the flavor-generating article. The flavor suction system refers to a combination of a flavor generating article and a heating unit equipped with a heater.
 1.香味発生セグメント
 本発明の香味発生セグメントは1枚以上の香味発生シートを備える。香味発生シートの少なくとも1枚はたばこに使用することが許容される添加剤を含有する添加剤含有シートである。すなわち、本発明の香味発生セグメントは、1枚の香味発生シートを備えかつ当該香味発生シートが添加剤含有シートである態様と、複数の香味発生シートを備えその1枚以上が添加剤含有シートである態様を含む。添加剤含有シートが1枚であっても安定したデリバリー特性を達成できるが、後者の場合においてより多くの添加剤含有シートを含むとより安定したデリバリー特性を達成できるので好ましい。よって、以下、特に断らない限り、複数の香味発生シートを備えその1枚以上が添加剤含有シートである態様を例にして本発明を説明する。香味発生セグメントが1枚の香味発生シートを備えかつ当該香味発生シートが添加剤含有シートである態様においては、添加剤含有は長手方向軸を中心として円または略円を形成するように配置されるが、便宜上、本発明においてはこの場合も同心状に配置されているという。
1. Flavor Generating Segment The flavor generating segment of the present invention comprises one or more flavor generating sheets. At least one of the flavor generating sheets is an additive-containing sheet containing an additive that is acceptable for use in tobacco. That is, the flavor generating segment of the present invention comprises one flavor generating sheet and the flavor generating sheet is an additive-containing sheet, and a plurality of flavor generating sheets, one or more of which is an additive containing sheet. Including some embodiments. Even if only one additive-containing sheet is used, stable delivery characteristics can be achieved, but in the latter case, it is preferable to include more additive-containing sheets because more stable delivery characteristics can be achieved. Therefore, the present invention will be described below with reference to an embodiment in which a plurality of flavor generating sheets are provided and at least one of which is an additive-containing sheet unless otherwise specified. In embodiments in which the flavor-generating segment comprises a single flavor-generating sheet and the flavor-generating sheet is an additive-containing sheet, the additive-containing is arranged to form a circle or approximately a circle about the longitudinal axis. However, for convenience, in the present invention, it is said that they are also arranged concentrically in this case.
 本発明においてシートとは、略平行な1対の主面、および側面を有する形状をいう。シートは抄紙によって製造されることが好ましい。本発明において香味発生セグメントの長手方向とは、香味発生シートを巻き回す方向と直交する方向である。具体的には、図2におけるh、図8におけるLの方向が長手方向である。また、香味発生物品がロッド状であることが好ましいため、かかる香味発生物品における長手方向を香味発生セグメントの長手方向と同一とみなしてもよい。本発明の香味発生セグメントの一態様を図2に示す。図2において、10は香味発生シート、12は配置の中心となる長手方向軸、14は空間、16は伝熱シート、18は離間部である。本発明の香味発生セグメントの形状は限定されないが、柱状であることが好ましい。本発明の香味発生セグメント1は、以下のように定義されるアスペクト比が1以上である形状を満たす柱状形状を有していることが好ましい。
 アスペクト比=h/w
 wは柱状体の底面の幅、hは高さであり、h≧wであることが好ましい。しかし、本発明においては、上述した通り、長手方向はhで示された方向であると規定している。したがって、w≧hである場合においてもhで示された方向を便宜上長手方向と呼ぶ。底面の形状は限定されず、多角、角丸多角、円、楕円等であってよく、幅wは当該底面が円形の場合は直径、楕円形である場合は長径、多角形または角丸多角である場合は外接円の直径または外接楕円の長径である。例えば、図2に示す態様においては、底面が円であるのでその直径を認定でき、当該直径が幅w、これに直交する長さが高さhとなる。香味発生セグメント1の高さhは5~20mm程度、幅wは4~9mm程度であることが好ましい。図示されていないが、香味発生セグメント1は最外部にラッパーを備えていてもよい。ラッパーは巻紙であってもよいし、香味発生シート10から構成されていてもよい。
In the present invention, the sheet refers to a shape having a pair of substantially parallel main surfaces and side surfaces. The sheet is preferably produced by papermaking. In the present invention, the longitudinal direction of the flavor generating segment is a direction orthogonal to the direction in which the flavor generating sheet is wound. Specifically, the direction of h in FIG. 2 and the direction of L in FIG. 8 is the longitudinal direction. Further, since the flavor-generating article is preferably rod-shaped, the longitudinal direction of the flavor-generating article may be regarded as the same as the longitudinal direction of the flavor-generating segment. One aspect of the flavor generating segment of the present invention is shown in FIG. In FIG. 2, 10 is a flavor generating sheet, 12 is a longitudinal axis that is the center of the arrangement, 14 is a space, 16 is a heat transfer sheet, and 18 is a separating portion. The shape of the flavor generating segment of the present invention is not limited, but it is preferably columnar. The flavor generating segment 1 of the present invention preferably has a columnar shape that satisfies the shape defined as follows with an aspect ratio of 1 or more.
Aspect ratio = h/w
w is the width of the bottom surface of the columnar body, h is the height, and it is preferable that h≧w. However, in the present invention, as described above, the longitudinal direction is defined as the direction indicated by h. Therefore, even when w≧h, the direction indicated by h is called the longitudinal direction for convenience. The shape of the bottom surface is not limited and may be a polygon, a rounded polygon, a circle, an ellipse, or the like, and the width w is a diameter when the bottom surface is circular, a long diameter when the bottom surface is elliptical, a polygon, or a rounded polygon. In some cases it is the diameter of the circumscribing circle or the major axis of the circumscribing ellipse. For example, in the embodiment shown in FIG. 2, since the bottom surface is a circle, its diameter can be recognized, and the diameter is the width w and the length orthogonal to this is the height h. The height h of the flavor generating segment 1 is preferably about 5 to 20 mm, and the width w is preferably about 4 to 9 mm. Although not shown, the flavor generation segment 1 may include a wrapper at the outermost portion. The wrapper may be a wrapping paper, or may be composed of the flavor generating sheet 10.
 香味発生シートとは、香味を発生するシートであり、香味を発生しうる成分をシート基材に担持させてなるシートまたは香味を発生する材料で構成されたシートが挙げられる。複数の香味発生シートが同心状に配置されて香味発生セグメントを構成する。香味を発生しうる成分としては、例えば、たばこ原料に含まれる香喫味成分やメントール等の香料成分等が挙げられる。シート基材としては、例えば、圧縮たばこペレットやたばこ粉末等のたばこ材料等が挙げられる。本発明において、シート基材としてはたばこ材料が好ましい。すなわち香味発生シートとしては、たばこ材料の基材シートに必要に応じて香味を発生しうる成分を担持したたばこシートが好ましい。香味発生シートは、加熱に伴ってエアロゾルを発生してもよい。エアロゾルの発生を促進するためにグリセリン、プロピレングリコール、1,3-ブタンジオール等のポリオール等のエアロゾル源をさらに添加してもよい。かかるエアロゾル源の添加量は、香味発生シートの乾燥重量に対して5~50重量%が好ましく、10~30重量%がより好ましい。グリセリン、プロピレングリコール、1,3-ブタンジオール等のポリオールは香喫味成分として添加してもよい。エアロゾル源を含む場合または香味成分がエアロゾルを発生する場合、香味発生シートはエアロゾル発生シートでもある。まずは同心状に配置される前の素材としてのエアロゾル発生シートについて説明する。 A flavor generating sheet is a sheet that generates a flavor, and includes a sheet in which a component capable of generating a flavor is supported on a sheet base material or a sheet composed of a material that generates a flavor. A plurality of flavor generating sheets are arranged concentrically to form a flavor generating segment. Examples of the component capable of generating a flavor include a flavor component contained in the tobacco raw material and a flavor component such as menthol. Examples of the sheet base material include tobacco materials such as compressed tobacco pellets and tobacco powder. In the present invention, a tobacco material is preferable as the sheet base material. That is, as the flavor generating sheet, a tobacco sheet in which a base material sheet of a tobacco material is loaded with a component capable of generating a flavor if necessary is preferable. The flavor generating sheet may generate an aerosol with heating. An aerosol source such as glycerin, propylene glycol or a polyol such as 1,3-butanediol may be further added in order to accelerate the generation of aerosol. The amount of such an aerosol source added is preferably 5 to 50% by weight, more preferably 10 to 30% by weight, based on the dry weight of the flavor generating sheet. A polyol such as glycerin, propylene glycol and 1,3-butanediol may be added as a flavor component. The flavor-generating sheet is also an aerosol-generating sheet if it contains an aerosol source or if the flavor component produces an aerosol. First, the aerosol generating sheet as a material before being concentrically arranged will be described.
 1)添加剤
 本発明において香味発生セグメントは、たばこに使用することが許容される添加剤を含有する香味発生シート(添加剤含有シート)を備える。たばこに使用することが許容される添加剤とは、例えば「たばこの事典」(財団法人たばこ総合研究センター)の「燃焼調節剤」の欄に記載されている。香味発生セグメントが添加剤を含有する香味発生シートを備えることで、吸始めから吸終わりまでにわたって安定したデリバリー特性が達成される。この理由は限定されないが、当該添加剤が熱伝導調整剤として機能しヒータから香味発生シートへの熱の伝わり方をコントロール可能であるためと推察される。
1) Additive In the present invention, the flavor generation segment includes a flavor generation sheet (additive-containing sheet) containing an additive that is allowed to be used in tobacco. The additives that are allowed to be used in tobacco are described in, for example, the “Burning Control Agent” column of “Encyclopedia of Tobacco” (Tobacco Research Center). By providing the flavor generating sheet in which the flavor generating segment contains an additive, stable delivery characteristics can be achieved from the beginning of sucking to the end of sucking. The reason for this is not limited, but it is presumed that the additive functions as a heat conduction adjusting agent and can control how heat is transmitted from the heater to the flavor generating sheet.
 当該添加剤としては有機酸金属塩、金属水酸化物、およびこの組合せからなる群から選択されることが好ましい。有機酸金属塩としては、燃焼型たばこの巻紙に助燃剤として添加される物を挙げることができ、具体的にはクエン酸、酒石酸、酢酸、リンゴ酸、ギ酸、乳酸を含む塩が挙げられる。その金属成分としては、周期表の第1族または第2族に属するものが挙げられる。中でも、K、Na等が好ましい。金属水酸化物としては、周期表の第2族に属する金属の水酸化物が挙げられ、中でも、Mg、Caの水酸化物が好ましい。また、当該添加剤は熱分析をした際に100~400℃の間に吸熱ピークを有することが好ましい。吸熱ピークとしては、融点に起因するピークや、水和物の脱水反応に起因するピークが挙げられる。例えばクエン酸ナトリウムは通常二水和物として存在するが、これを加熱すると150℃で脱水して無水物となる。このような吸熱ピークを持つ添加剤はエアロゾルを適度に冷却できるので好ましい。従って本発明における前記添加剤はその水和物も含む。 The additive is preferably selected from the group consisting of organic acid metal salts, metal hydroxides, and combinations thereof. Examples of the organic acid metal salt include those added as a combustion enhancer to the cigarette paper of combustion type cigarette, and specific examples thereof include salts containing citric acid, tartaric acid, acetic acid, malic acid, formic acid and lactic acid. Examples of the metal component include those belonging to Group 1 or Group 2 of the periodic table. Of these, K, Na and the like are preferable. Examples of the metal hydroxide include hydroxides of metals belonging to Group 2 of the periodic table, and among them, hydroxides of Mg and Ca are preferable. Further, the additive preferably has an endothermic peak between 100 and 400° C. when subjected to thermal analysis. Examples of the endothermic peak include a peak due to a melting point and a peak due to a dehydration reaction of a hydrate. For example, sodium citrate usually exists as a dihydrate, but when it is heated, it dehydrates at 150° C. to be an anhydride. Additives having such endothermic peaks are preferable because they can cool the aerosol appropriately. Therefore, the additive in the present invention also includes its hydrate.
 前記添加剤の量は、香味発生シートの重量に対して好ましくは0.5~1.5重量%、より好ましくは0.8~1.2重量%である。 The amount of the additive is preferably 0.5 to 1.5% by weight, more preferably 0.8 to 1.2% by weight, based on the weight of the flavor generating sheet.
 香味発生シートの内、少なくとも1枚は前記添加剤を含む添加剤含有シートであるが、当該添加剤含有シートの枚数は、全枚数中の30%以上が好ましく、60%以上がより好ましく、100%がさらに好ましい。 At least one of the flavor generating sheets is an additive-containing sheet containing the additive, but the number of the additive-containing sheets is preferably 30% or more, more preferably 60% or more, and more preferably 100% or more of the total number of sheets. % Is more preferable.
 2)調製
 香味発生シートがたばこシートである場合、たばこシートは抄造、スラリー、圧延、等の公知の方法で適宜製造できる。具体的に抄造の場合は、以下の工程を含む方法で製造できる。1)乾燥葉たばこ原料を粗砕し、水で抽出して水抽出物と残渣に分離する。2)水抽出物を減圧乾燥して濃縮する。3)残渣にパルプを加え、リファイナで繊維化した後、抄紙する。4)抄紙したシートに水抽出物の濃縮液を添加して乾燥したばこシートとする。この場合、ニトロソアミン等の一部の成分を除去する工程を加えてもよい(特表2004-510422号公報参照)。スラリー法の場合は、以下の工程を含む方法で製造できる。1)水パルプバインダと、砕いたたばこを混合する。2)当該混合物を薄く延ばして(キャストして)乾燥する。この他、国際公開第2014/104078号に記載されているように、以下の工程を含む方法によって製造された不織布状のたばこシートを用いることもできる。1)粉粒状のたばこ原料と結合剤を混合する。2)当該混合物を不織布によって挟む。3)当該積層物を熱溶着によって一定形状に成形し、不織布状のたばこシートを得る。たばこシートの組成は特に限定されないが、例えば、たばこ原料の含有量はたばこシート全重量に対して50~95重量%であることが好ましい。また、たばこシートはバインダを含んでもよく、係るバインダとしては、例えば、グアーガム、キサンタンガム、CMC(カルボキシメチルセルロース)、CMC-Na(カルボキシメチルセルロースのナトリウム塩)等が挙げられる。バインダ量としては、たばこシート全重量に対して2~20重量%であることが好ましい。たばこシートはさらに他の添加剤含んでもよい。他の添加剤としては、例えばパルプなどのフィラーを挙げることができる。前述のとおり、たばこシートは香味を発生しうる成分を含む。本発明においては複数のたばこシートを用いるが、係るたばこシートはすべて同じ組成あるいは物性であってもよいし、各たばこシートの中の一部または全部が異なる組成あるいは物性であってもよい。香味発生シートがたばこシート以外である場合、例えばたばこ原料以外の植物パルプをシート基材として用いたシートを用いることができる。
2) Preparation When the flavor generating sheet is a tobacco sheet, the tobacco sheet can be appropriately produced by a known method such as papermaking, slurry and rolling. Specifically, in the case of papermaking, it can be manufactured by a method including the following steps. 1) Dried leaf tobacco raw material is roughly crushed and extracted with water to separate a water extract and a residue. 2) The water extract is dried under reduced pressure and concentrated. 3) Pulp is added to the residue, fiberized by a refiner, and then papermaking. 4) Add a concentrated solution of water extract to the paper sheet to make a dried tobacco sheet. In this case, a step of removing a part of components such as nitrosamine may be added (see JP-A-2004-510422). The slurry method can be manufactured by a method including the following steps. 1) Mix water pulp binder and crushed tobacco. 2) Thinly (cast) the mixture and dry. In addition, as described in WO2014/104078, a non-woven tobacco sheet manufactured by a method including the following steps can also be used. 1) Mix powdered tobacco raw material and binder. 2) Sandwich the mixture with a non-woven fabric. 3) The laminate is formed into a constant shape by heat welding to obtain a non-woven tobacco sheet. The composition of the tobacco sheet is not particularly limited, but for example, the content of the tobacco raw material is preferably 50 to 95% by weight based on the total weight of the tobacco sheet. Further, the tobacco sheet may contain a binder, and examples of the binder include guar gum, xanthan gum, CMC (carboxymethyl cellulose), CMC-Na (sodium salt of carboxymethyl cellulose) and the like. The binder amount is preferably 2 to 20% by weight based on the total weight of the tobacco sheet. The tobacco sheet may further contain other additives. Examples of other additives include fillers such as pulp. As described above, the tobacco sheet contains a component capable of generating a flavor. Although a plurality of tobacco sheets are used in the present invention, all such tobacco sheets may have the same composition or physical properties, or some or all of the tobacco sheets may have different compositions or physical properties. When the flavor generating sheet is other than the tobacco sheet, for example, a sheet using a plant pulp other than the tobacco raw material as a sheet base material can be used.
 前記添加剤の溶液を調製して香味発生シートに当該溶液を塗布または噴霧することで、添加剤を含有する香味発生シートを製造できる。あるいは、添加剤の溶液に香味発生シートを浸漬することによっても添加剤を含有する香味発生シートを製造できる。当該溶液に用いる溶媒は限定されないが、エタノールなどのアルコールが好ましい。 A flavor generating sheet containing an additive can be manufactured by preparing a solution of the additive and applying or spraying the solution onto the flavor generating sheet. Alternatively, the flavor generating sheet containing the additive can be produced by immersing the flavor generating sheet in a solution of the additive. The solvent used for the solution is not limited, but alcohol such as ethanol is preferable.
 3)寸法等
 香味発生シートの形状は限定されないがシート主面の形状が四角形であることが好ましい。厚みは限定されないが、高効率の熱交換や香味発生セグメントの強度等を考慮すると、200~600μmが好ましい。各香味発生シートの厚みは同じであってもよいし異なっていてもよい。同心状に配置された際に周長さに対応する長さを香味発生シート幅Wといい、香味発生セグメント長さに対応する長さを香味発生シート長さLという。Lはすべての香味発生シートにおいて同じであることが好ましい。Wに関しては、同心状に配置された際に最外層を構成する香味発生シートのWが、最内層を構成する香味発生シートのWよりも大きいことが好ましい。この理由は後述する。
3) Dimension etc. The shape of the flavor generating sheet is not limited, but the shape of the sheet main surface is preferably quadrangular. Although the thickness is not limited, it is preferably 200 to 600 μm in consideration of highly efficient heat exchange, strength of the flavor generating segment, and the like. The thickness of each flavor generating sheet may be the same or different. The length corresponding to the peripheral length when arranged concentrically is called the flavor generation sheet width W, and the length corresponding to the flavor generation segment length is called the flavor generation sheet length L. It is preferable that L is the same in all flavor generating sheets. Regarding W, it is preferable that W of the flavor generating sheet forming the outermost layer when arranged concentrically is larger than W of the flavor generating sheet forming the innermost layer. The reason for this will be described later.
 4)表面加工
 複数の香味発生シートのうち少なくとも1枚は、少なくとも一方の面の一部または全部に表面加工が施されていることが好ましい。本発明において表面加工とは、香味発生シートの少なくとも一方の主面、即ち表面または裏面に複数の凹凸を形成する加工をいう。表面加工の方法としては特に限定されず、捲縮加工、エンボス加工、デボス加工、切削加工、ハーフカット等の公知の加工を用いることができる。本発明において捲縮加工とはシートにしわを設ける加工である。例えば、表面に複数の凸部を有する一対のローラ間に香味発生シートを通すことによって、香味発生シートの表面と裏面の両方にシート搬送方向に直交して延びるしわを設けて捲縮加工を施すことができる。係るローラに設けられた凸部は、シート搬送方向に直交して延びている。ローラに設けられた凸部の頂点間のピッチは0.5~2.0mmが好ましい。そのため、香味発生シートのピッチは0.5~2.0mmであることが好ましい。また、香味発生シートのピッチは、ラッパーあるいは巻紙の周長さに対して1.5~20%であることが好ましい。また、捲縮によってできた凹凸の高さHはシートの平均厚みをTavとするとき、1.05Tav~1.59Tavであることが好ましい。高さHは、捲縮加工されたシートを水平な面に載置した際にシート底部からシート頂点までの距離として定義される。エンボス加工やデボス加工とは、凸状の加工具をシートに押しつけてシートの片面または両面に凹部を形成する加工である。切削はシートの一部を除去して凹部を設ける加工であり、機械的にシートを切削する機械加工によって行ってもよいし、レーザー加工等の非接触加工によって行ってもよい。ハーフカット加工とは、シートの片面または両面に、シートが切断されない程度の深さ、好ましくはシート厚みの半分以下の深さの切込みを設ける加工である。ハーフカット加工にはナイフやレーザーを用いることができる。後述するとおり、香味発生シートに表面加工を施すことで、同心状に配置した場合に効率よく非接触部、好ましくは後述する隙間を形成できる。ただし、最内層となる香味発生シートは表面加工が施されていないことが好ましい。なお香味発生シートの凸部の頂点間のピッチは同一シート内ですべて同一であってもよいし、異なっていてもよい。また、各香味発生シートの凸部の頂点間のピッチは、シート毎に異なっていてもよいし、同一であってもよい。
4) Surface treatment At least one of the plurality of flavor generating sheets preferably has a surface treatment on a part or all of at least one surface. In the present invention, the surface processing refers to processing for forming a plurality of irregularities on at least one main surface of the flavor generating sheet, that is, the front surface or the back surface. The surface processing method is not particularly limited, and known processing such as crimping processing, embossing processing, debossing processing, cutting processing, and half cutting can be used. In the present invention, the crimping process is a process of forming wrinkles on the sheet. For example, by passing a flavor generating sheet between a pair of rollers having a plurality of convex portions on the front surface, crimping is performed by providing wrinkles extending orthogonally to the sheet conveying direction on both the front surface and the back surface of the flavor generating sheet. be able to. The convex portion provided on the roller extends perpendicularly to the sheet conveying direction. The pitch between the apexes of the protrusions provided on the roller is preferably 0.5 to 2.0 mm. Therefore, the pitch of the flavor generating sheet is preferably 0.5 to 2.0 mm. Further, the pitch of the flavor generating sheet is preferably 1.5 to 20% with respect to the peripheral length of the wrapper or the wrapping paper. The height H of the irregularities made by the crimp when the average thickness of the sheet and T av, is preferably 1.05T av ~ 1.59T av. The height H is defined as the distance from the bottom of the sheet to the top of the sheet when the crimped sheet is placed on a horizontal surface. The embossing process and the debossing process are processes in which a convex processing tool is pressed against a sheet to form a recess on one side or both sides of the sheet. Cutting is a process of removing a part of the sheet to form a recess, and may be performed by mechanical processing for mechanically cutting the sheet or by non-contact processing such as laser processing. The half-cutting is a processing in which a cut is formed on one or both sides of the sheet to a depth such that the sheet is not cut, and preferably to a depth not more than half the sheet thickness. A knife or a laser can be used for the half-cut processing. As will be described later, by subjecting the flavor generating sheet to a surface treatment, it is possible to efficiently form a non-contact portion, preferably a gap described later, when arranged concentrically. However, it is preferable that the flavor generating sheet serving as the innermost layer is not surface-treated. The pitch between the vertices of the convex portions of the flavor generating sheet may be the same or different within the same sheet. Further, the pitch between the vertices of the convex portions of each flavor generating sheet may be different for each sheet or may be the same.
 図10に切削加工を施した香味発生シートの一態様を示す。図中、10は凹凸香味発生シート、10cは凸部(山部)、10rは凹部(溝部)、fは凹凸が延びる方向に直交する方向長さ(以下「溝幅」ともいう)、dは厚み方向長さ(以下「溝深さ」ともいう)である。図10は、平坦な状態に置いた凹凸香味発生シート10を示す。また、当該図は片面に凹凸を設けた態様を示すが、凹凸は両面に設けられていてもよい。この場合、両面の凹部の位置は同じでもよいし、異なっていてもよい。 Fig. 10 shows one aspect of the flavor generating sheet that has been cut. In the figure, 10 is a concave-convex flavor generating sheet, 10c is a convex portion (mountain portion), 10r is a concave portion (groove portion), f is a direction length (hereinafter also referred to as “groove width”) orthogonal to the direction in which the concave-convex extends, and d is The length in the thickness direction (hereinafter also referred to as “groove depth”). FIG. 10 shows the uneven flavor generating sheet 10 placed in a flat state. Further, although the figure shows a mode in which unevenness is provided on one side, the unevenness may be provided on both sides. In this case, the positions of the recesses on both sides may be the same or different.
 加工容易性の観点から凹凸のピッチPtは一定であることが好ましく、凹部の断面形状は略矩形であることが好ましい。この場合、dとfの大きさを調整することで、香味発生物品としたときの香喫味成分のデリバリープロフィールを制御できる。香喫味成分の代表例としてはニコチンが挙げられる。例えば、(i)f<dである場合すなわちシャープな凹部を設ける場合は、初期のデリバリーを高めることができる。また、(ii)f≧dである場合すなわちブロードな凹部を設ける場合は、終盤までデリバリーを高めることができる。一態様において、(i)の場合、溝幅はピッチに対して10%以上50%未満、溝深さはシート厚さに対して50~99%であることが好ましい。例えばシート厚みが0.6mmでピッチが1mmである場合、溝幅fは0.1~0.5mm、溝深さdは0.3~0.59mmから適宜選択される。(ii)の場合、溝幅はピッチに対して50~90%、溝深さはシート厚さに対して30%以上50%未満である。例えばシート厚みが0.6mmでピッチが1mmである場合、fは0.5~0.9mm、dは0.1~0.3mmから適宜選択される。1枚の凹凸香味発生シートにおいて、溝幅および溝深さが一定でない場合は、その平均値をfおよびdとすることができる。凹凸のピッチPtは限定されないが、0.5~1.5mmが好ましく、0.8~1.2mmがより好ましい。 From the viewpoint of workability, it is preferable that the pitch Pt of the concavities and convexities be constant, and the cross-sectional shape of the recesses be substantially rectangular. In this case, by adjusting the sizes of d and f, it is possible to control the delivery profile of the flavor and taste component in the flavor generating article. As a typical example of the flavor and taste component, nicotine can be mentioned. For example, when (i) f<d, that is, when a sharp concave portion is provided, initial delivery can be improved. When (ii) f≧d, that is, when a broad concave portion is provided, the delivery can be increased to the final stage. In one aspect, in the case of (i), the groove width is preferably 10% or more and less than 50% with respect to the pitch, and the groove depth is preferably 50 to 99% with respect to the sheet thickness. For example, when the sheet thickness is 0.6 mm and the pitch is 1 mm, the groove width f is 0.1 to 0.5 mm and the groove depth d is appropriately selected from 0.3 to 0.59 mm. In the case of (ii), the groove width is 50 to 90% with respect to the pitch, and the groove depth is 30% or more and less than 50% with respect to the sheet thickness. For example, when the sheet thickness is 0.6 mm and the pitch is 1 mm, f is 0.5 to 0.9 mm and d is appropriately selected from 0.1 to 0.3 mm. If the groove width and the groove depth are not constant in one unevenness flavor generating sheet, the average values thereof can be set to f and d. The pitch Pt of the irregularities is not limited, but is preferably 0.5 to 1.5 mm, more preferably 0.8 to 1.2 mm.
 次に、同心状に配置された香味発生シートについて説明する。
 1)同心状に配置された複数の香味発生シート
 各香味発生シートは巻上成形等により、香味発生セグメントの長手方向に延在し、同心状に配置されている。本発明において「同心状に配置されている」とは、すべての香味発生シートの中心が略同じ位置にあるように配置されていることをいう。ただし、香味発生シートが断面楕円形に配置されている場合は、長軸と短軸の交点を中心とする。当該中心を通り長手方向に平行な軸を「配置の中心である長手方向軸」または単に「配置の中心軸」という。図2に示すとおり、配置の中心軸12は、香味発生セグメント1の断面中央を通る軸すなわち香味発生セグメントの中心軸と同一であることが好ましいが、香味発生セグメント1の中心軸よりずれていてもよい。このように本発明においては、中心が偏心している態様も「同心状に配置されている」という。例えば、香味発生セグメント1の幅が2Rである場合、配置の中心軸12は、香味発生セグメント1の中心軸から0.1R~0.7R程度外側にずれていてもよい。本発明においては、同心状に配置された香味発生シート10の数は3枚~12枚であることが好ましい。香味発生シートの数を係る数とすることにより、十分な量の香味成分を発生させることができると共に、後述する隙間として十分なスペースを確保でき、発生した香味のデリバリ効率を高めることができる。また、香味発生セグメントに含まれる複数の香味発生シートは、総重量が130~685mgであることが好ましく、200~350mgであることが好ましい。
Next, the flavor generating sheets arranged concentrically will be described.
1) Multiple flavor generating sheets arranged concentrically Each flavor generating sheet extends in the longitudinal direction of the flavor generating segment and is arranged concentrically by roll-up molding or the like. In the present invention, “arranged concentrically” means that the centers of all flavor generating sheets are arranged at substantially the same position. However, when the flavor generating sheets are arranged in an elliptical cross section, the intersection is defined by the major axis and the minor axis. An axis passing through the center and parallel to the longitudinal direction is referred to as a "longitudinal axis that is the center of arrangement" or simply "center axis of arrangement". As shown in FIG. 2, the center axis 12 of the arrangement is preferably the same as the axis passing through the center of the cross section of the flavor generating segment 1, that is, the center axis of the flavor generating segment, but is displaced from the center axis of the flavor generating segment 1. Good. As described above, in the present invention, the mode in which the centers are eccentric is also referred to as "arranged concentrically". For example, when the width of the flavor generating segment 1 is 2R, the central axis 12 of the arrangement may be offset from the center axis of the flavor generating segment 1 by about 0.1R to 0.7R. In the present invention, the number of the flavor generating sheets 10 arranged concentrically is preferably 3 to 12. By setting the number of flavor generating sheets to such a number, it is possible to generate a sufficient amount of flavor components, secure a sufficient space as a gap described below, and improve the efficiency of delivering the generated flavor. Further, the total weight of the plurality of flavor generating sheets included in the flavor generating segment is preferably 130 to 685 mg, and more preferably 200 to 350 mg.
 各香味発生シートは隣接するシート間に非接触部を有するように配置されるので、少なくとも1対の隣接する前記香味発生シート間に当該香味発生シート同士が接触しない非接触部を有する。この場合、隣接する香味発生シート同士が周方向にわたって全部が接触していない態様1と、少なくとも1対の隣接する前記香味発生シート間に当該香味発生シート同士が接触している接触部を有する態様2が存在する。本発明において「同心状に配置されている」とは態様2も含む。 Since each flavor generating sheet is arranged so as to have a non-contact portion between the adjacent sheets, there is a non-contact portion where the flavor generating sheets do not contact each other between at least one pair of the adjacent flavor generating sheets. In this case, the aspect 1 in which the adjacent flavor generating sheets are not entirely in contact with each other in the circumferential direction and the aspect in which the flavor generating sheets are in contact with each other between at least one pair of the adjacent flavor generating sheets There are two. In the present invention, “arranged concentrically” also includes aspect 2.
 前述のとおり香味発生シートはグリセリンなどのエアロゾル源を含むが、吸引の終始にわたってエアロゾルのデリバリーが均一になるように各香味発生シートに含まれるエアロゾル源の重量を調整することが好ましい。例えば図9(1)に示すように、香味発生セグメントの中心から外側に向かってA~Cの位置を特定し、当該位置を含む領域にそれぞれ同じ厚みのシートが存在する場合を考える(図9(2))。この場合、各シートのエアロゾル源の重量が同じであれば、シート厚み当たりのエアロゾル源の重量は同じになる。このためA、B、Cの位置で発生しうるエアロゾル源の量をほぼ同じとすることができる。 As described above, the flavor-generating sheet contains an aerosol source such as glycerin, but it is preferable to adjust the weight of the aerosol source contained in each flavor-generating sheet so that the delivery of the aerosol is uniform throughout the suction. For example, as shown in FIG. 9(1), consider the case where the positions A to C are specified from the center of the flavor generation segment toward the outside, and sheets having the same thickness are present in the regions including the positions (see FIG. 9). (2)). In this case, if the weight of the aerosol source of each sheet is the same, the weight of the aerosol source per sheet thickness will be the same. Therefore, the amount of aerosol source that can be generated at the positions A, B, and C can be made substantially the same.
 一方、当該位置を含む領域に異なる厚みのシートが存在する場合(図9(3))、各シートのエアロゾル源の重量が同じであってもシート厚み当たりのエアロゾル源の重量は異なるので、A、B、Cの位置で発生しうるエアロゾル源の量も異なる。この場合、以下の関係を満たすようにシートを設計すれば、A、B、Cの位置で発生しうるエアロゾル源の量をほぼ同じとすることができる。
 X/a=Y/b=Z/c
  a:Aの位置をカバーするシートAの厚み、
  X:Aの位置をカバーするシートAに含まれるエアロゾル源の重量
  b:Bの位置をカバーするシートBの厚み、
  Y:Bの位置をカバーするシートBに含まれるエアロゾル源の重量
  c:Cの位置をカバーするシートCの厚み、
  Z:Cの位置をカバーするシートCに含まれるエアロゾル源の重量
On the other hand, when sheets with different thicknesses exist in the region including the position (FIG. 9(3)), even if the weight of the aerosol source of each sheet is the same, the weight of the aerosol source per sheet thickness is different. The amount of aerosol source that can be generated at positions B, C is also different. In this case, if the sheet is designed so as to satisfy the following relationship, the amounts of aerosol sources that can be generated at the positions A, B, and C can be made substantially the same.
X/a=Y/b=Z/c
a: the thickness of the sheet A covering the position A,
X: Weight of the aerosol source contained in the sheet A covering the position of A: b: Thickness of the sheet B covering the position of B,
Y: Weight of the aerosol source contained in the sheet B covering the position of B: c: Thickness of the sheet C covering the position of C,
Z: Weight of aerosol source contained in sheet C covering position C
 例えば円筒状に配置されたシートの内外周差や内外表面において表面加工に差を設ける等によってもこのような設計が可能となる。後者の場合、例えば内表面にハーフカットを多く設け、該表面にはハーフカットを少なく設けるなどの態様が考えられる。さらに、内側に配置される当該シートと外側に配置される当該シートにおいて、当該シートに含まれる香喫味成分および香料成分の重量を変えることで、吸引時に所望のタイミングで香喫味を変化させることもできる。 For example, such a design is possible by providing a difference in the inner and outer circumferences of the cylindrically arranged sheets and a difference in the surface processing on the inner and outer surfaces. In the latter case, for example, a mode in which a large number of half cuts are provided on the inner surface and a small number of half cuts are provided on the surface can be considered. Furthermore, by changing the weight of the flavor component and the flavor component contained in the sheet in the sheet arranged on the inner side and the sheet arranged on the outer side, it is possible to change the flavor and taste at a desired timing during inhalation. it can.
 2)非接触部
 態様2において接触部分と接触部分との間に形成された非接触部分を「隙間」という。態様2においては、隣接しているシート同士の間に複数の隙間が長手方向に沿って形成されるので、香味流路を確保して香味デリバリ効率を向上することができ、さらには接触部分を介してヒータからの熱を外側の香味発生シートに伝達できるので伝熱効率を高めることができる。よって本発明においては態様2が好ましい。この場合、一部または全部の隙間は、香味発生セグメントの先端部から後端部にわたって延びていることがより好ましい。
2) Non-contact portion In Embodiment 2, the non-contact portion formed between the contact portion and the contact portion is referred to as "gap". In the aspect 2, since a plurality of gaps are formed along the longitudinal direction between the adjacent sheets, it is possible to secure the flavor flow path and improve the flavor delivery efficiency, and further to improve the flavor contact efficiency. The heat from the heater can be transferred to the flavor generating sheet on the outside, so that the heat transfer efficiency can be improved. Therefore, the second mode is preferable in the present invention. In this case, it is more preferable that some or all of the gaps extend from the front end portion to the rear end portion of the flavor generating segment.
 態様2において、ある香味発生シートと係る香味発生シートに隣接する香味発生シートの少なくとも一つは、少なくとも一部で接触しているが、香味発生シート同士は、周方向つまり巻き回す方向において、複数個所で接触していることが好ましい。このように隣接する香味発生シート同士を接触させる方法としては特に限定されず、例えば前述の表面加工を少なくとも一つの香味発生シートに施すことや、各香味発生シートの幅を変えること等によって行うことができる。本発明において隣接する香味発生シート同士を接触させる方法としては、少なくとも一つの前述の香味発生シートに表面処理を施すことが好ましい。表面加工された香味発生シートは巻き上げられた際に周方向に凸部を形成する。巻き上げられた複数の香味発生シートのうち、隣接する香味発生シートにおけるこの凸部の位置を周方向において同一の位置に存在させない、すなわち各香味発生シートの周方向における凹凸の位相をずらすことによって、より確実に前記接触部を設けることができる(図3参照)。図3においてCは接触部、Vは隙間である。位相をずらす方法は限定されないが、例えば香味発生シート毎に表面加工のピッチを変える、各香味発生シートの厚さや幅を変更する、巻上げ成形時に巻上方向に掛ける力を層毎に変える等の方法が挙げられる。前記接触部は接着されている必要はない。香味発生シートが表面処理によって設けられた凸部を複数具備する場合、少なくとも係る凸部のうちの一つが隣接する香味発生シートと接触していればよい。前記隙間を香味発生セグメントの先端部から後端部にわたって延在させるために、捲縮加工されたシートに形成された凸部の長手方向は香味発生セグメントの長手方向と平行または略平行であることが好ましい。凸部の長手方向とは稜線の延びる方向であり、捲縮ローラーによる加工時のシート搬送方向に直交する方向である。 In Aspect 2, at least one of the flavor generating sheets and at least one of the flavor generating sheets adjacent to the flavor generating sheet are in contact with each other at least in part, but the plurality of flavor generating sheets are arranged in the circumferential direction, that is, in the winding direction. It is preferable that they are in contact with each other. Thus, the method for bringing adjacent flavor generating sheets into contact with each other is not particularly limited, and for example, by performing the above-mentioned surface treatment on at least one flavor generating sheet or by changing the width of each flavor generating sheet. You can As a method of bringing adjacent flavor generating sheets into contact with each other in the present invention, it is preferable to subject at least one of the flavor generating sheets to a surface treatment. The surface-processed flavor generating sheet forms a convex portion in the circumferential direction when rolled up. Among the plurality of rolled flavor generating sheets, the position of this convex portion in the adjacent flavor generating sheet does not exist at the same position in the circumferential direction, that is, by shifting the phase of the unevenness in the circumferential direction of each flavor generating sheet, The contact portion can be provided more reliably (see FIG. 3). In FIG. 3, C is a contact portion and V is a gap. The method of shifting the phase is not limited, but for example, changing the pitch of the surface processing for each flavor generating sheet, changing the thickness and width of each flavor generating sheet, changing the force applied in the winding direction during roll-up molding for each layer, etc. There is a method. The contacts need not be glued. When the flavor generating sheet has a plurality of convex portions provided by the surface treatment, at least one of the convex portions may be in contact with the adjacent flavor generating sheet. In order to extend the gap from the front end portion to the rear end portion of the flavor generating segment, the longitudinal direction of the convex portion formed on the crimped sheet is parallel or substantially parallel to the longitudinal direction of the flavor generating segment. Is preferred. The longitudinal direction of the convex portion is the direction in which the ridge line extends, and is the direction orthogonal to the sheet conveying direction during processing by the crimp roller.
 隣接する2つの香味発生シートの層間距離の最大値Gmaxは、当該隣接する2つの香味発生シートのうちの少なくとも一方の香味発生シート厚みの最大値Tmaxよりも大きいことが好ましい。このことは以下の方法で確認できる。図3に示すように香味発生セグメント1のある断面においてn番目のシートと(n+1)番目のシート間に形成される層間距離nを測定して最大値G(n)maxを決定する。次いでn番目のシートと(n+1)番目のシートの厚みを測定して最大値T(n)maxおよびT(n+1)maxを決定して比較する。この測定を総ての層間について実施する。例えば、シート枚数が4枚である場合、3つの層間について測定を実施する。そして当該断面において以下を満たすことを確認する。
  G(1)max>T(1)maxまたはG(1)max>T(2)max
  G(2)max>T(2)maxまたはG(2)max>T(3)max
  G(3)max>T(3)maxまたはG(3)max>T(4)max
It is preferable that the maximum value Gmax of the interlayer distance between two adjacent flavor generating sheets is larger than the maximum value Tmax of the flavor generating sheet thickness of at least one of the two adjacent flavor generating sheets. This can be confirmed by the following method. As shown in FIG. 3, the interlayer distance n formed between the nth sheet and the (n+1)th sheet in a certain cross section of the flavor generating segment 1 is measured to determine the maximum value G (n) max. Next, the thicknesses of the n-th sheet and the (n+1)-th sheet are measured, and the maximum values T (n) max and T (n+1) max are determined and compared. This measurement is performed for all layers. For example, when the number of sheets is 4, the measurement is performed on three layers. Then, it is confirmed that the following is satisfied in the cross section.
G (1) max>T (1) max or G (1) max>T (2) max
G (2) max>T (2) max or G (2) max>T (3) max
G (3) max>T (3) max or G (3) max>T (4) max
 この関係が任意の断面で満たされるとき、隣接する2つの香味発生シートの層間距離の最大値Gmaxは、当該隣接する2つの香味発生シートのうちの少なくとも一方の香味発生シート厚みの最大値Tmaxよりも大きいという。香味発生シート10が固定されていないために測定が困難である場合は、次のように測定することが好ましい。まず、香味発生セグメント1を低粘度の硬化性樹脂(例えばエポキシ樹脂)に含浸させて非接触部を樹脂で充填した後に当該樹脂を硬化して測定用サンプルを調製する。次いで、当該サンプルを切断しながら前記測定を実施する。 When this relationship is satisfied in an arbitrary cross section, the maximum value Gmax of the interlayer distance between two adjacent flavor generating sheets is greater than the maximum value Tmax of the flavor generating sheet thickness of at least one of the two adjacent flavor generating sheets. Is also big. When it is difficult to measure the flavor generating sheet 10 because it is not fixed, the following measurement is preferable. First, the flavor generating segment 1 is impregnated with a low-viscosity curable resin (for example, an epoxy resin), the non-contact portion is filled with the resin, and then the resin is cured to prepare a measurement sample. Next, the measurement is performed while cutting the sample.
 香味発生セグメントにおける非接触部の総量の割合(以下「空隙率」ともいう)は、0.10~0.40であることが好ましく、0.15~0.36であることがより好ましく、0.25~0.33であることが特に好ましい。空隙率を好ましい範囲とすることによって、効率的に香味を供給することができる。また、空隙率をより好ましい範囲とすることにより、吸引初期から終期に渡って、香味発生セグメント中のシートに含まれる香喫味成分の効率的な放出を維持することができる。 The ratio of the total amount of the non-contact portion in the flavor generating segment (hereinafter also referred to as “porosity”) is preferably 0.10 to 0.40, more preferably 0.15 to 0.36, and 0 Particularly preferably, it is 0.25 to 0.33. By setting the porosity within the preferable range, the flavor can be efficiently supplied. Further, by setting the porosity to a more preferable range, it is possible to maintain the efficient release of the flavor component contained in the sheet in the flavor generating segment from the initial stage of suction to the final stage.
 3)構成等
 香味発生セグメントは、香味発生シートの復元力によって形状が維持されていることが好ましい。つまり、配置された香味発生シートは復元力によって外側に広がろうとする力を発し、その力を外側に存在する香味発生シートまたはラッパーが受け止めることによって香味発生セグメントの形状が維持されることが好ましい。したがって最内層の香味発生シート10inの復元力が、それ以外の香味発生シートの復元力よりも大きいと形状がより安定するので好ましい(図2)。復元力はシートの厚みや表面加工の有無によって調整できる。シートが厚いほど、または表面加工がなされていない方が復元力は大きい。従って、最内層の香味発生シート10inとして表面加工されていないシートを用いることが好ましい。具体的に復元力の程度は、垂直に立てた金属棒へシートを巻き付け、巻き付けに資する力を開放した結果得られるシート端面間の距離を測定することで評価できる。このように、複数の香味発生シートを特定の構成とすることによって香味発生セグメントに機能を付与できる。形状等をより安定させる観点から、ラッパーはオーバーラップ部分を有することが好ましい。当該オーバーラップ部分は接着されていることが好ましい。
3) Configuration etc. It is preferable that the shape of the flavor generating segment is maintained by the restoring force of the flavor generating sheet. That is, it is preferable that the arranged flavor generating sheet emits a force to spread to the outside by the restoring force, and the flavor generating sheet or the wrapper existing on the outside receives the force to maintain the shape of the flavor generating segment. .. Therefore, it is preferable that the restoring force of the flavor generating sheet 10 in , which is the innermost layer, is larger than the restoring force of the other flavor generating sheets, because the shape is more stable (FIG. 2). The restoring force can be adjusted by the thickness of the sheet and the presence or absence of surface treatment. The thicker the sheet, or the more untreated the surface, the greater the restoring force. Therefore, it is preferable to use a sheet that is not surface-treated as the innermost flavor generating sheet 10 in . Specifically, the degree of restoring force can be evaluated by winding the sheet around a vertically standing metal rod and measuring the distance between the sheet end faces obtained as a result of releasing the force that contributes to the winding. In this way, a function can be imparted to the flavor generation segment by making the plurality of flavor generation sheets have a specific configuration. From the viewpoint of further stabilizing the shape and the like, the wrapper preferably has an overlapping portion. It is preferable that the overlapping portion is bonded.
 この他に、例えば表面加工香味発生シートおよび非表面加工香味発生シートが交互に存在する構成も好ましい。この場合、香味発生セグメントの形状維持と隙間の確保を両立できる。また、香味発生シートの一方の面のみに表面加工を施し、当該加工面が配置の中心軸側を向く態様も好ましい。この場合、香味発生セグメントの強度を向上できる。係る態様とするために、香味発生シートには表面加工としてハーフカット加工が施されていることが好ましい。 In addition to this, for example, a configuration in which surface-processed flavor generating sheets and non-surface-processed flavor generating sheets are alternately present is also preferable. In this case, it is possible to maintain the shape of the flavor generation segment and secure the gap. It is also preferable that only one surface of the flavor generating sheet is subjected to surface processing, and the processed surface faces the central axis side of the arrangement. In this case, the strength of the flavor generating segment can be improved. In order to have such a mode, it is preferable that the flavor generating sheet is subjected to half-cut processing as surface processing.
 凹凸を設けた香味発生シート10は図4に示すように配置されてもよい。具体的に周方向において各シートの凸部を略等しい位置に配置することができる(図4(1))。また、周方向において隣接する各シートの凹部を隣接する凹凸香味発生シートの凹部と略等しい位置に配置することができる(図4(2))。さらに、両面に凹凸を設けた香味発生シート10についても、周方向において各凹凸香味発生シートの凸部を略等しい位置に配置することができる(図4(3)、(4))。図4(3)は凹凸パターンが香味発生シートの両面で対称である態様を、図4(4)は香味発生シートの一方の面の凹部が、他方の面の凸部の位置に存在する態様を示す。 The flavor generating sheet 10 provided with unevenness may be arranged as shown in FIG. Specifically, the convex portions of each sheet can be arranged at substantially equal positions in the circumferential direction (FIG. 4(1)). Further, the recesses of the adjacent sheets in the circumferential direction can be arranged at substantially the same positions as the recesses of the adjacent uneven flavor generating sheet (FIG. 4(2)). Further, with respect to the flavor generating sheet 10 having both sides provided with protrusions and recesses, the protrusions of the respective flavor generating sheets can be arranged at substantially equal positions in the circumferential direction (FIGS. 4(3) and (4)). FIG. 4(3) shows a mode in which the concavo-convex pattern is symmetrical on both sides of the flavor generating sheet, and FIG. 4(4) shows a mode in which the concave portion on one surface of the flavor generating sheet exists at the position of the convex portion on the other surface. Indicates.
 図2に示すとおり、1つの香味発生シートは周方向において連続していることが好ましい。1つの香味発生シートにおいては、シートが重なり合うオーバーラップ部は存在してもよいし存在しなくてもよい。オーバーラップ部とは、一態様において香味発生シートの周方向における一方の端が、他方の端を超えて重なりあった部分である。両端の重なった部分が存在すると、香味発生セグメントの強度を向上できるという利点がある。ただし、最内層の香味発生シートは、周方向における一方の端が他方の端を超える領域と接着されていないことが好ましい。当該接着領域が存在すると最内層の香味発生シートの復元力が低下するからである。 As shown in FIG. 2, it is preferable that one flavor generating sheet is continuous in the circumferential direction. In one flavor generating sheet, the overlapping portions where the sheets overlap may or may not exist. The overlapped portion is a portion where one end in the circumferential direction of the flavor generating sheet overlaps the other end in one aspect. The presence of the overlapping portions at both ends has an advantage that the strength of the flavor generating segment can be improved. However, it is preferable that the flavor generating sheet of the innermost layer is not bonded to a region in which one end in the circumferential direction exceeds the other end. This is because the presence of the adhesion region reduces the restoring force of the flavor generating sheet in the innermost layer.
 一方、オーバーラップ部が存在しないと、空気流路を容易に確保できるという利点がある。オーバーラップ部が存在しない態様においては、香味発生シートの周方向における両端同士が接触している態様、離間している態様がある。両端同士が接触している態様においては、最内層の香味発生シートの両端は接着されていないことが好ましい。両端が接着されていると最内層の香味発生シートの復元力が低下するからである。 On the other hand, if there is no overlapping part, there is an advantage that the air flow path can be easily secured. In the mode in which the overlapping portion does not exist, there are a mode in which both ends of the flavor generating sheet in the circumferential direction are in contact with each other and a mode in which they are separated from each other. In the case where both ends are in contact with each other, it is preferable that both ends of the flavor generating sheet of the innermost layer are not bonded. This is because if both ends are adhered, the restoring force of the flavor generating sheet in the innermost layer is reduced.
 香味発生セグメント1の製造の製造しやすさの観点からは、香味発生シートの周方向における両端同士が離間している態様、すなわち両端間に離間部を有することが好ましい。離間距離は限定されないが、香味発生シートの両端部の距離にして0mmを超え2mm以下であることが好ましい。このように離間している場合、両端は近接しているともいう。さらに、後者の態様において図2に示すように、香味発生シート10の離間部18は、周方向において略同じ位置に存在することが好ましい。離間部が略同じ位置に存在するとは、離間部18が、外周部から配置の中心に向かって貫通していることを意味する。このような構造とすることで本発明の香味発生セグメント1の製造がより容易になる。ただし、ラッパーとして香味発生シート10を使用する場合、当該香味発生シートは両端が重なっていてもよい。 From the viewpoint of the ease of manufacturing the flavor generating segment 1, it is preferable that both ends of the flavor generating sheet in the circumferential direction are spaced apart from each other, that is, it is preferable to have a spacing portion between both ends. The separation distance is not limited, but it is preferable that the distance between both ends of the flavor generating sheet is more than 0 mm and 2 mm or less. When separated in this way, both ends are also said to be adjacent. Further, in the latter mode, as shown in FIG. 2, it is preferable that the spacing portions 18 of the flavor generating sheet 10 are present at substantially the same position in the circumferential direction. The presence of the spacing portions at substantially the same position means that the spacing portions 18 penetrate from the outer peripheral portion toward the center of the arrangement. With such a structure, the production of the flavor generating segment 1 of the present invention becomes easier. However, when the flavor generating sheet 10 is used as the wrapper, both ends of the flavor generating sheet may overlap.
 前述のとおり最外層の香味発生シートの周長さは、最内層の香味発生シートの周長さよりも長いことが好ましい。後述するとおり、複数の香味発生シートを平らに積層した積層体を巻上成形して香味発生セグメントを形成することできるが、この場合、周長さを前述のようにすると香味発生セグメントの形成が容易となる。 As described above, it is preferable that the perimeter of the outermost flavor generating sheet is longer than the perimeter of the innermost flavor generating sheet. As described below, it is possible to form a flavor-generating segment by roll-up molding a laminate in which a plurality of flavor-generating sheets are laminated flat, but in this case, when the circumference is set as described above, the flavor-generating segment is formed. It will be easy.
 香味発生セグメントは配置の中心軸近傍に空間を有していてもよい。具体的には図2に示すとおり、配置の中心軸12と、最内層の香味発生シート10inとの間に、当該長手方向に延在する空間14を有していてもよい。かかる空間の断面積は香味発生セグメント1の断面積の15~46%であることが好ましい。空間14の断面積を好ましい範囲内とすることによって、例えば図6(A)に示すような円筒状のヒータをセグメント内部に収容するための空間を確保できる。また、図6(C)に記載のように外周から香味発生セグメントを加熱する場合、係る空間14の断面積は極力小さい方が好ましい。具体的には空間14の断面積は隣接する2つの香味発生シートの間に形成される非接触部の断面積の総和以下であることが好ましい。 The flavor generation segment may have a space near the central axis of the arrangement. Specifically, as shown in FIG. 2, a space 14 extending in the longitudinal direction may be provided between the central axis 12 of the arrangement and the flavor generating sheet 10 in which is the innermost layer. The cross-sectional area of such a space is preferably 15 to 46% of the cross-sectional area of the flavor generating segment 1. By setting the cross-sectional area of the space 14 within the preferable range, for example, a space for housing a cylindrical heater as shown in FIG. 6A inside the segment can be secured. When heating the flavor generating segment from the outer periphery as shown in FIG. 6C, it is preferable that the cross-sectional area of the space 14 is as small as possible. Specifically, the cross-sectional area of the space 14 is preferably equal to or less than the total cross-sectional area of the non-contact portion formed between two adjacent flavor generating sheets.
 係る香味発生セグメントにおいては、断面における中心側、即ち、同心状に配置された香味発生シートの最内層よりもさらに内側、あるいは断面における中心とは反対側、即ち、同心状に配置された香味発生シートの最外層よりもさらに外側に、熱伝導性部材を設けてもよい。熱伝導性部材としては、シート状の部材(伝熱シート)であることが好ましく、具体的にはアルミニウム等の金属シート等を用いることができる。係る伝熱シートを配置する方法は限定されないが、香味発生シートと同心状に配置されていてもよいし(図2参照)、香味発生シートの表面または裏面に貼付けられていてもよい。 In such a flavor generation segment, the center side in the cross section, that is, the inner side of the innermost layer of the flavor generation sheet arranged concentrically, or the side opposite to the center in the cross section, that is, the flavor generation arranged concentrically A heat conductive member may be provided further outside the outermost layer of the sheet. The heat conductive member is preferably a sheet-shaped member (heat transfer sheet), and specifically, a metal sheet such as aluminum can be used. The method for arranging the heat transfer sheet is not limited, but the heat transfer sheet may be arranged concentrically with the flavor generating sheet (see FIG. 2), or may be attached to the front surface or the back surface of the flavor generating sheet.
 伝熱シートを配置する位置は限定されないが、香味発生システムとしたときにヒータと近接するように配置するとヒータから発生する熱を効率的に各香味発生シートに伝導することができるので好ましい。詳しくは後述するが、図6(A)、(B)、(B’)に示すように香味発生セグメントの中心部にヒータ30が配置される場合は、熱伝導性部材も当該中心部に配置されることが好ましい。また、図6(C)に示すように香味発生セグメントの外周にヒータが配置される場合は、係る熱伝導性部材も香味発生セグメントの外周側に配置されることが好ましい。 The position of arranging the heat transfer sheet is not limited, but it is preferable to dispose the heat transfer sheet close to the heater in the flavor generating system because heat generated from the heater can be efficiently conducted to each flavor generating sheet. As will be described later in detail, when the heater 30 is arranged in the central portion of the flavor generating segment as shown in FIGS. 6A, 6B, and 6B′, the heat conductive member is also arranged in the central portion. Preferably. Further, when the heater is arranged on the outer periphery of the flavor generating segment as shown in FIG. 6C, it is preferable that the heat conductive member is also arranged on the outer peripheral side of the flavor generating segment.
 2.香味発生物品
 図5に香味発生物品の一態様を示す。図5において、2は香味発生物品、1は香味発生セグメント、20はマウスピース、22はフィルター、24はキャビティ、26は支持部材である。香味発生セグメント1の配置の中心軸と香味発生物品2の長手方向は平行である。上記のとおり、支持部材やキャビティは香味発生物品に任意に設けてよい。マウスピース20は吸口部を備える部材でありフィルター22を含んでいてもよい。マウスピース20の寸法も限定されないが、香味発生セグメント1と同じ幅を有することが好ましく、長さは26~50mmであることが好ましい。
2. Flavor Generating Article FIG. 5 shows one mode of the flavor generating article. In FIG. 5, 2 is a flavor generating article, 1 is a flavor generating segment, 20 is a mouthpiece, 22 is a filter, 24 is a cavity, and 26 is a support member. The central axis of the arrangement of the flavor generating segment 1 and the longitudinal direction of the flavor generating article 2 are parallel. As described above, the support member and the cavity may be optionally provided in the flavor generating article. The mouthpiece 20 is a member having a mouthpiece and may include a filter 22. Although the size of the mouthpiece 20 is not limited, the mouthpiece 20 preferably has the same width as the flavor generating segment 1 and preferably has a length of 26 to 50 mm.
 フィルター22はセルロースアセテートフィルター等の当該分野で通常使用される材料で構成されることが好ましい。フィルター22の長さはマウスピース20の全長の12~60%であることが好ましい。 The filter 22 is preferably made of a material usually used in this field such as a cellulose acetate filter. The length of the filter 22 is preferably 12 to 60% of the total length of the mouthpiece 20.
 キャビティ24は空間であり、キャビティ24を形成するラッパーの側面にはベンチレーションが設けられていてもよい。キャビティ24は加熱された香味を冷却する冷却部である。また、キャビティ24は香味と空気を適度に混合して香喫味を調製する等の機能も担う。キャビティ24の長さはマウスピース20の全長の8~77%であることが好ましい。冷却機能を高めるためにキャビティー24は冷却要素を備えていてもよい。冷却要素としては例えばポリ乳酸シート等が挙げられ、複数のポリ乳酸シートに捲縮加工を施したものを冷却要素として用いることができる。 The cavity 24 is a space, and ventilation may be provided on the side surface of the wrapper forming the cavity 24. The cavity 24 is a cooling unit that cools the heated flavor. Further, the cavity 24 also has a function of appropriately mixing flavor and air to adjust flavor and the like. The length of the cavity 24 is preferably 8 to 77% of the total length of the mouthpiece 20. The cavity 24 may be provided with cooling elements to enhance the cooling function. Examples of the cooling element include a polylactic acid sheet, and a plurality of polylactic acid sheets subjected to crimping can be used as the cooling element.
 支持部材26は、香味発生物品の強度を高めて形状を保持する。支持部材26はセルロースアセテート、ポリエーテルエーテルケトン(PEEK)等の耐熱性プラスチック、シリコン、セラミック等、当該分野で通常使用される材料で構成されることが好ましい。また支持部材としては、例えば、長手方向中心軸に空間を設けたような円筒状の部材を好適に用いることができる。支持部材26の長さはマウスピース20の全長の14~77%であることが好ましい。 The support member 26 enhances the strength of the flavor generating article and retains its shape. The support member 26 is preferably composed of a heat-resistant plastic such as cellulose acetate or polyether ether ketone (PEEK), silicon, ceramic or the like, which is a material usually used in this field. Further, as the support member, for example, a cylindrical member having a space in the central axis in the longitudinal direction can be preferably used. The length of the support member 26 is preferably 14 to 77% of the total length of the mouthpiece 20.
 3.香味吸引システム
 本発明の香味吸引システムは、ヒーターを備える。ヒーターは、好ましくは非燃焼式に、より好ましくは電気的に香味発生セグメントを加熱する。ヒーターは電源等を備える加熱ユニットを備えることが好ましい。図1に本発明の香味吸引システムの一態様を示す。図中、1は香味発生セグメント、20はマウスピース、22はフィルター、30はヒーター、32は加熱ユニットである。
3. Flavor suction system The flavor suction system of the present invention includes a heater. The heater preferably heats the flavor generating segment non-combustively, more preferably electrically. The heater preferably includes a heating unit including a power source and the like. FIG. 1 shows one embodiment of the flavor suction system of the present invention. In the figure, 1 is a flavor generating segment, 20 is a mouthpiece, 22 is a filter, 30 is a heater, and 32 is a heating unit.
 ヒーター30の形状は限定されないが、ヒーター30の一部が香味発生セグメントにおける前記空間14に配置可能な形状を有していることが好ましい。例えばシート状ヒーター、平板状ヒーター、筒状ヒーターであってよい。シート状ヒーターとは柔軟なシート形のヒーターであり、例えばポリイミド等の耐熱性ポリマーのフィルム(厚み20~225μm程度)を含むヒーターが挙げられる。平板状ヒーターとは剛直な平板形のヒーター(厚み200~500μm程度)であり、例えば平板基材上に抵抗回路を有し当該部分を発熱部とするヒーターが挙げられる。筒状ヒーターとは中空または中実の筒形のヒーターであり、例えば、外周面に抵抗回路を有し当該部分を発熱部とするヒーターが挙げられる。筒状ヒーターの断面形状は円、楕円、多角、角丸多角等であってよい。 The shape of the heater 30 is not limited, but it is preferable that a part of the heater 30 has a shape that can be arranged in the space 14 in the flavor generation segment. For example, it may be a sheet heater, a flat plate heater, or a tubular heater. The sheet-shaped heater is a flexible sheet-shaped heater, and examples thereof include a heater including a film of a heat-resistant polymer such as polyimide (thickness: about 20 to 225 μm). The plate heater is a rigid plate heater (thickness: about 200 to 500 μm), and for example, a heater having a resistor circuit on a plate base material and having that portion as a heat generating portion can be mentioned. The tubular heater is a hollow or solid tubular heater, and examples thereof include a heater having a resistance circuit on the outer peripheral surface and using the portion as a heat generating portion. The sectional shape of the cylindrical heater may be a circle, an ellipse, a polygon, a rounded polygon, or the like.
 ヒーターは任意の配置であってよいが、以下、図6を用いて好ましい態様を説明する。図6は本発明の香味吸引システムの断面図である。図6において30はヒーター、10は香味発生シートである。 The heater may be arranged arbitrarily, but the preferred embodiment will be described below with reference to FIG. FIG. 6 is a sectional view of the flavor suction system of the present invention. In FIG. 6, 30 is a heater and 10 is a flavor generating sheet.
 図6(A)、(B)に示すとおり、ヒーター30は、香味発生セグメントの空間14に配置できる。図6Aは当該空間に中実の筒状ヒーター30が配置された態様を、図6(B)は平板上ヒーター30が配置された態様を示す。図示していないが、香味発生セグメントは、香味発生シート10と同心状に配置されている伝熱シートを有することが好ましく、当該伝熱シートはヒーター30と隣接していることがより好ましい。このように、平板状ヒーターおよび筒状ヒーターは香味発生シート10を内側から加熱する場合に好適である。図6(B’)に示すように平板状ヒーターを用いる場合、最内層の香味発生シート10inあるいはこれとその近傍に存在する香味発生シート10を破るように当該ヒーターを貫入させてもよい。 As shown in FIGS. 6A and 6B, the heater 30 can be arranged in the space 14 of the flavor generating segment. FIG. 6A shows a mode in which the solid cylindrical heater 30 is arranged in the space, and FIG. 6B shows a mode in which the flat plate heater 30 is arranged. Although not shown, the flavor generating segment preferably has a heat transfer sheet arranged concentrically with the flavor generating sheet 10, and the heat transfer sheet is more preferably adjacent to the heater 30. Thus, the flat plate heater and the tubular heater are suitable for heating the flavor generating sheet 10 from the inside. When a flat heater is used as shown in FIG. 6(B'), the heater may be inserted so as to break the innermost flavor generating sheet 10 in or the flavor generating sheet 10 present in the vicinity thereof.
 図6(A)、(B)に示すようなヒーター30が空間14に配置されている場合、最内層の香味発生シート10inから配置の中心軸方向側にわたって存在する空隙の断面積は、最内層の香味発生シートから外周側にわたって存在する非接触部の総断面積よりも小さいことが好ましい。図7にヒーター30が空間14に配置されている香味発生セグメント1の断面の一部を示す。図7において前者の断面積はSinで、後者の断面積はSoutで表される。本実施態様においては、SoutがSinより大きいことが好ましい。また、係るSinとSoutとの関係性は、香味発生セグメントの長手方向にわたって維持されていることがより好ましく、香味発生セグメントの長手方向にわたって、SinとSoutとが一定の値であることが特に好ましい。 When the heater 30 as shown in FIGS. 6A and 6B is arranged in the space 14, the cross-sectional area of the void existing from the flavor generating sheet 10 in of the innermost layer to the central axis direction side of the arrangement is the largest. It is preferably smaller than the total cross-sectional area of the non-contact portion existing from the flavor generating sheet of the inner layer to the outer peripheral side. FIG. 7 shows a part of the cross section of the flavor generation segment 1 in which the heater 30 is arranged in the space 14. In FIG. 7, the former cross-sectional area is represented by S in and the latter cross-sectional area is represented by S out . In this embodiment, S out is preferably greater than S in . Further, the relationship between S in and S out is more preferably maintained in the longitudinal direction of the flavor generating segment, and S in and S out are constant values in the longitudinal direction of the flavor generating segment. Is particularly preferable.
 m+1枚の香味発生シートが存在する場合、隣接する2つの香味発生シートの層間はm個存在する。各層間における非接触部の断面積をSmとすると、Sout=S1+・・・+Smが成り立つ。このとき、任意のSmは、Sm>Sinの関係を満たすことがより好ましい。Sm>Sinという関係は、香味発生セグメントの長手方向にわたって維持されていることがさらに好ましく、香味発生セグメントの長手方向にわたって、SmとSinの値とが、それぞれ一定の値であることが特に好ましい。係る好ましい構成により、空気と香味発生シートとの接触効率が高まるので、効率的な熱交換および香味発生を達成できる。SoutおよびSinは、GmaxおよびTmaxと同様に香味吸引システム3の複数の断面を観察することで測定できる。この際、香味発生シート10inおよび香味発生シート10outの離間部には香味発生シートが存在するとして測定する。 When there are m+1 flavor generating sheets, there are m layers between two adjacent flavor generating sheets. Letting S m be the cross-sectional area of the non-contact portion between the layers, S out =S 1 +... +S m . At this time, it is more preferable that any S m satisfy the relationship of S m >S in . The relationship of S m >S in is more preferably maintained along the longitudinal direction of the flavor generating segment, and the values of S m and S in are constant over the longitudinal direction of the flavor generating segment. Is particularly preferable. With such a preferable configuration, the contact efficiency between the air and the flavor generating sheet is increased, so that efficient heat exchange and flavor generation can be achieved. S out and S in can be measured by observing a plurality of cross sections of the flavor suction system 3 similarly to Gmax and Tmax. At this time, it is determined that the flavor generating sheet exists in the space between the flavor generating sheet 10 in and the flavor generating sheet 10 out .
 図6(C)に示すとおり、ヒーター30は、最内層の香味発生シート10outの外側に配置できる。香味発生セグメント1がラッパーを備える場合、ヒーター30はラッパーの外側に配置してもよい。また図6(D)に示すとおり、ヒーター30は、香味発生シート10の間に配置できる。このように、シート状ヒータは、香味発生シート10を外側からまたは中間から加熱する場合に好適である。シート状ヒータは端部が離間していてもよいし、接触していてもよい。本態様においても、香味発生セグメントは、香味発生シート10と共に同心状に配置されている伝熱シートを有することが好ましく、当該伝熱シートはヒーター30と隣接していることがより好ましい。 As shown in FIG. 6C, the heater 30 can be arranged outside the flavor generating sheet 10 out which is the innermost layer. If the flavor generating segment 1 comprises a wrapper, the heater 30 may be located outside the wrapper. Further, as shown in FIG. 6D, the heater 30 can be arranged between the flavor generating sheets 10. As described above, the sheet-shaped heater is suitable for heating the flavor generating sheet 10 from the outside or the middle. The sheet heaters may have their ends separated or in contact with each other. Also in this aspect, it is preferable that the flavor generating segment has a heat transfer sheet arranged concentrically with the flavor generating sheet 10, and the heat transfer sheet is more preferably adjacent to the heater 30.
 4.製造方法
 本発明の香味吸引システム3の製造方法は限定されないが、香味発生セグメント1、マウスピース20、ヒーター30等の構成要素をそれぞれ準備して、これらを組合せることで製造できる。
4. Manufacturing Method The manufacturing method of the flavor suction system 3 of the present invention is not limited, but the flavor generating segment 1, the mouthpiece 20, the heater 30 and the like are prepared respectively and can be manufactured by combining them.
 図8に示すように、香味発生セグメント1は、幅Wの異なる複数の香味発生シート10を準備して、底部から頂部に向かってWが小さくなるように積層した積層体100を調製し、これを巻管6に通して巻き上げ成形することで製造できる。図8(B)は巻管6の開口部方向から積層体100を見た図である。ただし、積層体100は巻上げ成形後に隣接する前記香味発生シート間に非接触部が形成されるように調製される。例えば、隣接する香味発生シート10同士の全面を接着せずに積層する、隣接する香味発生シート10同士の一部を接着して積層する、あるいは隣接する香味発生シート10同士の全面あるいは一部を、巻上げ成形後に剥がれるように軽度に接着して積層することで積層体100を調製できる。必要に応じて積層体100の中に伝熱シートを配置してもよいし、積層体100の最底部にラッパーを配置してもよい。さらに積層体100の最頂部にマンドレル等の筒状ダミーを載置して香味発生セグメント1を形成した後に、当該ダミーを除去することで空間14を形成することができる。 As shown in FIG. 8, in the flavor generating segment 1, a plurality of flavor generating sheets 10 having different widths W are prepared, and a laminated body 100 is prepared in which W is laminated so that W becomes smaller from the bottom portion to the top portion. It can be manufactured by passing it through a winding tube 6 and winding it up. FIG. 8B is a view of the laminated body 100 viewed from the opening direction of the winding tube 6. However, the laminated body 100 is prepared such that a non-contact portion is formed between the flavor generating sheets adjacent to each other after roll-up molding. For example, the entire surfaces of the adjacent flavor generating sheets 10 are laminated without adhering, the parts of the adjacent flavor generating sheets 10 are adhered and laminated, or the entire surface or a part of the adjacent flavor generating sheets 10 is adhered. The laminated body 100 can be prepared by gently adhering and laminating so as to peel off after roll-up molding. If necessary, a heat transfer sheet may be arranged in the laminate 100, or a wrapper may be arranged at the bottom of the laminate 100. Further, a space 14 can be formed by placing a cylindrical dummy such as a mandrel on the top of the laminated body 100 to form the flavor generating segment 1 and then removing the dummy.
 ヒーター30として平板状ヒーターまたは筒状ヒーターを用いる場合は、空間14に当該ヒーター30を挿入して香味吸引システム3を製造できる。また、最頂部に当該ヒーター30を載置した積層体100を巻管6に通して香味吸引システム3を製造してもよい。 When a flat heater or a tubular heater is used as the heater 30, the flavor suction system 3 can be manufactured by inserting the heater 30 into the space 14. Further, the flavor suction system 3 may be manufactured by passing the laminated body 100 having the heater 30 mounted on the top thereof through the winding tube 6.
 ヒーター30としてシート状ヒーターを用いる場合は、香味発生シート10の間または最底部に当該ヒーター30を配置した積層体100を巻管6に通して香味吸引システム3を製造できる。 When a sheet-shaped heater is used as the heater 30, the flavor suction system 3 can be manufactured by passing the laminated body 100 having the heater 30 arranged between the flavor generating sheets 10 or at the bottom thereof through the winding tube 6.
 フィルター22を含むマウスピース20は公知の方法で調製してよい。例えば、香味吸引システム3の後端部にフィルター22を配置して、これらをラッパーで巻くことによってフィルター22を備える香味吸引システム3を製造できる。香味吸引システム3の後端部に当接するように支持部材16を配置し、さらに離間してフィルター22を配置すれば、支持部材16およびキャビティ24をさらに備える香味吸引システム3を製造できる。 The mouthpiece 20 including the filter 22 may be prepared by a known method. For example, the flavor suction system 3 including the filter 22 can be manufactured by disposing the filter 22 at the rear end portion of the flavor suction system 3 and winding them with a wrapper. By disposing the support member 16 so as to abut the rear end of the flavor suction system 3 and further disposing the filter 22 at a distance, the flavor suction system 3 further including the support member 16 and the cavity 24 can be manufactured.
[実施例1]
 たばこ刻を1バッチ分として350g計量し、当該たばこ刻の12倍の水を加えて混合した。当該混合物を50℃に加熱しスクリューにて水溶性成分を抽出して、たばこ材料と抽出液を得た。当該抽出液を濃縮し、次いで濃縮液に対し15重量%のグリセリンを添加して添加液を得た。
[Example 1]
350 g of tobacco cut was taken as one batch, and 12 times the water of the tobacco cut was added and mixed. The mixture was heated to 50° C. and the water-soluble component was extracted with a screw to obtain a tobacco material and an extract. The extract was concentrated, and then 15% by weight of glycerin was added to the concentrate to obtain an additive solution.
 一方、板パルプを準備し、これに水を加えて解砕した。前記たばこ材料に対して7重量%の解砕パルプを混合した。リファイナーを用いて当該混合物を叩解し、固形分濃度が1.5重量%となるように水を加えてスラリーを調製した。当該スラリーを用いて抄紙し、120℃で乾燥してベースシートを得た。当該ベースシートに前記添加液を含浸した。次いで当該シートを120℃で乾燥し、22℃/60%の調和条件にて静置して、香味発生シートを得た。得られた香味発生シートの坪量は503.5g/m2、厚さは583.3μmであった。 Meanwhile, plate pulp was prepared, and water was added to the plate pulp to crush it. 7% by weight of crushed pulp was mixed with the tobacco material. The mixture was beaten using a refiner and water was added so that the solid content concentration was 1.5% by weight to prepare a slurry. Paper was made using the slurry and dried at 120° C. to obtain a base sheet. The base sheet was impregnated with the additive solution. Then, the sheet was dried at 120° C., and allowed to stand under a harmony condition of 22° C./60% to obtain a flavor generating sheet. The basis weight of the obtained flavor generating sheet was 503.5 g/m 2 , and the thickness was 583.3 μm.
 レーザー加工機(Trotec社製、speedy 100)を用いて香味発生シートの片面にレーザー加工を施した。当該加工によって溝幅f0.2mm、溝深さd0.5mmの凹部が設けられた。凹凸のピッチPtは1mmであった。 Laser processing was performed on one side of the flavor generating sheet using a laser processing machine (Trotec, speedy 100). By the processing, a recess having a groove width f of 0.2 mm and a groove depth d of 0.5 mm was provided. The uneven pitch Pt was 1 mm.
 クエン酸Na水和物をエタノールに溶解し、クエン酸Na水和物濃度が2.2重量%である溶液を調製した。前記シート200mgに対して当該溶液100mgを塗布し、乾燥して添加剤含有香味発生シートを製造した。クエン酸Na水和物の添加量は、香味発生シートの乾燥重量に対して1.1重量%であった。 A sodium citrate hydrate was dissolved in ethanol to prepare a solution having a sodium citrate hydrate concentration of 2.2% by weight. 100 mg of the solution was applied to 200 mg of the sheet and dried to prepare an additive-containing flavor generating sheet. The amount of sodium citrate hydrate added was 1.1% by weight based on the dry weight of the flavor generating sheet.
 当該表面加工を施しかつ添加剤を加えた3枚の香味発生シートを、表面加工した面が下向きになるように巻紙の上に積層し、さらに最上部に円筒状ダミーを載置して積層体を得た。この積層体を直径が7mmの巻管に通して巻紙および凹凸香味発生シートを巻き上げた後、円筒状ダミーを引き抜いて、中央部に長手方向に延在する空間を有する香味発生セグメントであるたばこセグメントを製造した。凹凸部はセグメントの長手方向に延びていた。得られたたばこセグメントの長さLは12mmであった。円筒状ダミーの直径は3.2mmであった。当該割合は、香味発生セグメントの長手方向にわたって一定であった。 Three flavor generating sheets that have been subjected to the surface treatment and to which additives have been added are laminated on a wrapping paper with the surface-treated surface facing downward, and a cylindrical dummy is placed on the uppermost portion to form a laminate. Got This laminated body is passed through a winding tube having a diameter of 7 mm to wind up a wrapping paper and a concave-convex flavor generating sheet, and then a cylindrical dummy is pulled out to form a tobacco segment which is a flavor generating segment having a space extending in the longitudinal direction in the central portion. Was manufactured. The uneven portion extended in the longitudinal direction of the segment. The length L of the obtained tobacco segment was 12 mm. The diameter of the cylindrical dummy was 3.2 mm. The ratio was constant over the length of the flavor generating segment.
 長さ45mmのラッパーを準備し、当該ラッパーの長手方向と前記たばこセグメントの長手方向が同一方向になるように、当該ラッパーの上に当該たばこセグメントを載置した。次いで長さ8mmの中空円筒状のアセテートフィルタを準備し、前記ラッパーの上に前記たばこセグメントに隣接して載置した。この際、両者の中心軸が一致するようにした。ラッパーを巻き上げて、長さ12mmのたばこセグメント、長さ8mmの中空円筒状のアセテートフィルタ、および長さ25mmのキャビティの順に各セグメントを備える香味発生物品2を得た。その断面図の写真を図11に示す。 A 45 mm long wrapper was prepared, and the tobacco segment was placed on the wrapper such that the longitudinal direction of the wrapper and the longitudinal direction of the tobacco segment were in the same direction. A hollow cylindrical acetate filter with a length of 8 mm was then prepared and placed on the wrapper adjacent to the tobacco segment. At this time, the central axes of the both were made to coincide with each other. The wrapper was rolled up to obtain a flavor generating article 2 including a tobacco segment having a length of 12 mm, a hollow cylindrical acetate filter having a length of 8 mm, and a cavity having a length of 25 mm in this order. A photograph of the cross-sectional view is shown in FIG.
 得られた香味発生物品を加熱するための加熱デバイスとして、長さ12mm、直径3.2mmの中空円筒状ヒータと、当該ヒータを加熱するためのバッテリと、ヒータおよびバッテリを制御するための制御回路と、各部材を主要するためのハウジングを備えた加熱ユニットを準備した。中空円筒状ヒータを、実施例1で製造した香味発生物品の空間に挿入して、香味吸引システムを得た。 As a heating device for heating the obtained flavor generating article, a hollow cylindrical heater having a length of 12 mm and a diameter of 3.2 mm, a battery for heating the heater, and a control circuit for controlling the heater and the battery Then, a heating unit provided with a housing for mainizing each member was prepared. The hollow cylindrical heater was inserted into the space of the flavor generating article manufactured in Example 1 to obtain a flavor suction system.
 ケンブリッジフィルタを接続した自動喫煙装置(Bolgwaldt社製 RM26)を用い、香味吸引システムを喫煙に供した際のニコチン量およびグリセリン量を測定した。当該自動喫煙装置は電気制御された吸引用シリンジを有し、ケンブリッジフィルタとの流体連通が制御できるように、シリンジとケンブリッジフィルタとの間に、バルブコントローラによって流路を変えることのできる電磁弁を備えていた。当該装置のケンブリッジフィルタに各サンプルを接続して、積算パフ動作回数に応じて、成分量を測定した。具体的には、バルブコントローラによって電磁弁の開閉動作を行い、吸引中のシリンジとケンブリッジフィルタとを2秒間に亘って接続した後、ケンブリッジフィルタを大気中に28秒間にわたって解放した。このような動作を1回の擬似的なパフ動作として擬似的なパフ動作を1回行った後に、ケンブリッジフィルタを回収して1回のパフの香味を捕集した分析サンプルを得た。吸引用シリンジによる吸引は吸引容量55mL/2secとなるように設定した。定量は、各ケンブリッジフィルタを10mLのEtOH溶媒で振とう抽出し、ガスクロマトグラフ-質量分析器(GC/MS)を用いて実施した。結果を表1に示す。また、香味発生物品の表面であって、香味発生シートの長手方向中央部の位置の表面に熱電対を設置して、香味発生物品の最外部の温度変化を測定した。 Using an automatic smoking device (RM26 manufactured by Bolgwaldt) connected to a Cambridge filter, the amount of nicotine and the amount of glycerin when the flavor suction system was subjected to smoking were measured. The automatic smoking device has an electrically controlled suction syringe and an electromagnetic valve between the syringe and the Cambridge filter whose flow path can be changed by a valve controller so that fluid communication with the Cambridge filter can be controlled. I was prepared. Each sample was connected to the Cambridge filter of the apparatus, and the component amount was measured according to the cumulative puff operation frequency. Specifically, the valve controller opened and closed the electromagnetic valve to connect the syringe during suction and the Cambridge filter for 2 seconds, and then released the Cambridge filter to the atmosphere for 28 seconds. After performing such a pseudo puff operation once as such a pseudo puff operation, the Cambridge filter was collected to obtain an analysis sample in which the flavor of the puff was collected once. The suction by the suction syringe was set so that the suction capacity was 55 mL/2 sec. The quantification was carried out using a gas chromatograph-mass spectrometer (GC/MS) after shaking extraction of each Cambridge filter with 10 mL of EtOH solvent. The results are shown in Table 1. In addition, a thermocouple was installed on the surface of the flavor-generating article, which was located at the central position in the longitudinal direction of the flavor-generating sheet, and the outermost temperature change of the flavor-generating article was measured.
[実施例2、3]
 添加剤およびその量を表1に示すように変更した以外は、実施例1と同様にして香味吸引システムを製造し、評価した。
[Examples 2 and 3]
A flavor suction system was produced and evaluated in the same manner as in Example 1 except that the additives and the amounts thereof were changed as shown in Table 1.
[比較例1]
 添加剤を用いなかった以外は、実施例1と同様にして香味吸引システムを製造し、評価した。これらの結果を表1、図12、図13に示す。図12は香喫味に影響を与える成分のデリバリー量を示すが、その代表成分としてニコチンを採用した。
[Comparative Example 1]
A flavor suction system was produced and evaluated in the same manner as in Example 1 except that no additive was used. The results are shown in Table 1, FIG. 12 and FIG. FIG. 12 shows the delivery amounts of the components that affect the flavor and taste, and nicotine was used as the representative component.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1に示すとおり、実施例と比較例ではトータルデリバリー量に大差は見られなかった。しかし図12に示すとおり、実施例では喫煙の終始にわたってデリバリーのばらつきが小さく、安定したデリバリーが達成された。図13に示すとおり実施例の香味発生システムでは最外の温度上昇が抑制されており、このことによって喫煙の終始にわたる安定なデリバリーが達成されたと考えられる。香味シートへの熱の伝わり方はデリバリー特性に大きな影響を与えるが、添加剤によって香味シートへの熱の伝わり方が異なるので添加剤の選択によってデリバリープロファイルを制御することが可能となった。 As shown in Table 1, there was no significant difference in the total delivery amount between the example and the comparative example. However, as shown in FIG. 12, in the examples, there was little variation in delivery throughout smoking, and stable delivery was achieved. As shown in FIG. 13, in the flavor generating system of the example, the outermost temperature rise was suppressed, and it is considered that the stable delivery throughout the smoking was achieved by this. The way heat is transferred to the flavor sheet has a great influence on the delivery characteristics, but the way heat is transferred to the flavor sheet varies depending on the additive, so that it is possible to control the delivery profile by selecting the additive.
 1 香味発生セグメント
  10 香味発生シート
  12 配置の中心軸
  14 空間
  16 伝熱シート
  18 離間部
  100 積層体
 C 接触部
 V 隙間
 G 香味発生シート間距離
 T 香味発生シート厚み
 L 香味発生シート長さ
 W 香味発生シート幅

 2 香味発生物品
  20 マウスピース
  22 フィルター
  24 キャビティ
  26 支持部材

 3 香味吸引システム
  30 ヒーター
  32 加熱ユニット

 6 巻管

                                                                                
1 Flavor generating segment 10 Flavor generating sheet 12 Central axis of arrangement 14 Space 16 Heat transfer sheet 18 Separation part 100 Laminate C Contact part V Gap G Distance between flavor generating sheets T Flavor generating sheet thickness L Flavor generating sheet length W Flavor generating Seat width

2 Flavor generating article 20 Mouthpiece 22 Filter 24 Cavity 26 Supporting member

3 Flavor suction system 30 Heater 32 Heating unit

6 winding tubes

Claims (16)

  1.  1枚以上の香味発生シートを備える香味発生セグメントであって、
     前記香味発生シートは、長手方向に延在し、かつ当該長手方向軸を中心として同心状に配置されており、
     前記香味発生シートの少なくとも1枚は、たばこに使用することが許容される添加剤を含有する、
    香味発生セグメント。
    A flavor generation segment comprising one or more flavor generation sheets,
    The flavor generating sheet extends in the longitudinal direction, and is arranged concentrically around the longitudinal axis,
    At least one of the flavor generating sheets contains an additive acceptable for use in tobacco.
    Flavor generation segment.
  2.  前記添加剤が、有機酸金属塩、金属水酸化物、およびこの組合せからなる群から選択される、請求項1に記載の香味発生セグメント。 The flavor-generating segment according to claim 1, wherein the additive is selected from the group consisting of organic acid metal salts, metal hydroxides, and combinations thereof.
  3.  前記添加剤が周期表の第1族または第2族に属する元素を含む、請求項1または2に記載の香味発生セグメント。 The flavor generating segment according to claim 1 or 2, wherein the additive contains an element belonging to Group 1 or Group 2 of the periodic table.
  4.  前記添加剤の量が、前記香味発生シートの重量に対して0.5~1.5重量%である、請求項1~3のいずれかに記載の香味発生セグメント。 The flavor generating segment according to any one of claims 1 to 3, wherein the amount of the additive is 0.5 to 1.5% by weight based on the weight of the flavor generating sheet.
  5.  前記香味発生シートを複数備える、請求項1~4のいずれかに記載の香味発生セグメント。 The flavor generation segment according to any one of claims 1 to 4, comprising a plurality of the flavor generation sheets.
  6.  前記配置の中心である長手方向軸と最内層の香味発生シートとの間に、当該長手方向に延在する伝熱シートをさらに含み、当該伝熱シートが前記香味発生シートと同心状に配置されている、請求項1~5のいずれかに記載の香味発生セグメント。 Between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer, further includes a heat transfer sheet extending in the longitudinal direction, the heat transfer sheet is arranged concentrically with the flavor generating sheet. The flavor generating segment according to any one of claims 1 to 5.
  7.  前記香味発生シートの全枚数中に占める前記添加剤を含有する香味発生シートの全枚数の割合が30%以上である、請求項1~6のいずれかに記載の香味発生セグメント。 The flavor generating segment according to any one of claims 1 to 6, wherein the ratio of the total number of the flavor generating sheets containing the additive to the total number of the flavor generating sheets is 30% or more.
  8.  前記割合が60%以上である、請求項7に記載の香味発生セグメント。 The flavor generating segment according to claim 7, wherein the ratio is 60% or more.
  9.  前記割合が100%である、請求項8に記載の香味発生セグメント。 The flavor generating segment according to claim 8, wherein the ratio is 100%.
  10.  前記香味発生シートのうち少なくとも1枚は、片面または両面の一部または全部に表面加工が施されている、請求項1~9のいずれかに記載の香味発生セグメント。 The flavor generating segment according to any one of claims 1 to 9, wherein at least one of the flavor generating sheets has a surface treatment on a part or all of one side or both sides.
  11.  前記表面加工によって表面に凹凸が設けられ、その凹部および凸部は香味発生セグメントの長手方向に延びている、請求項10に記載の香味発生セグメント。 The flavor-generating segment according to claim 10, wherein the surface treatment is provided with unevenness, and the concave portion and the convex portion extend in the longitudinal direction of the flavor-generating segment.
  12.  前記配置の中心である長手方向軸と、最内層の香味発生シートとの間に、当該長手方向に延在する空間を有する、請求項1~11のいずれかに記載の香味発生セグメント。 The flavor generating segment according to any one of claims 1 to 11, which has a space extending in the longitudinal direction between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer.
  13.  請求項1~12のいずれかに記載の香味発生セグメントと、冷却部またはフィルタあるいはその両方を備える香味発生物品。 A flavor generating article comprising the flavor generating segment according to any one of claims 1 to 12 and a cooling unit, a filter, or both.
  14.  フィルタを備え、当該フィルタ側から吸引可能な請求項13に記載の香味発生物品。 The flavor-generating article according to claim 13, which is provided with a filter and can be sucked from the filter side.
  15.  請求項1~12のいずれかに記載の香味発生セグメントと、当該香味発生セグメントを加熱するヒーターとを備える、香味吸引システム。 A flavor suction system comprising the flavor generating segment according to any one of claims 1 to 12 and a heater for heating the flavor generating segment.
  16.  前記香味発生セグメントが、前記配置の中心である長手方向軸と最内層の香味発生シートとの間に、当該長手方向に延在する空間を有し、前記ヒーターの少なくとも一部が当該空間内に位置づけることが可能な形状を具備する、請求項15に記載の香味吸引システム。                                                                          The flavor generating segment, between the longitudinal axis that is the center of the arrangement and the flavor generating sheet of the innermost layer, has a space extending in the longitudinal direction, at least a portion of the heater in the space. 16. The flavor suction system of claim 15, comprising a positionable shape. ________________________________________________________________
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