WO2020116671A1 - Biodegradable and environment-friendly modular toothbrush - Google Patents

Biodegradable and environment-friendly modular toothbrush Download PDF

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Publication number
WO2020116671A1
WO2020116671A1 PCT/KR2018/015303 KR2018015303W WO2020116671A1 WO 2020116671 A1 WO2020116671 A1 WO 2020116671A1 KR 2018015303 W KR2018015303 W KR 2018015303W WO 2020116671 A1 WO2020116671 A1 WO 2020116671A1
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WO
WIPO (PCT)
Prior art keywords
weight
parts
biodegradable
head portion
eco
Prior art date
Application number
PCT/KR2018/015303
Other languages
French (fr)
Korean (ko)
Inventor
이상호
이원섭
Original Assignee
주식회사 브러시월드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 주식회사 브러시월드 filed Critical 주식회사 브러시월드
Priority claimed from KR1020180154851A external-priority patent/KR102086746B1/en
Publication of WO2020116671A1 publication Critical patent/WO2020116671A1/en

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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B5/00Brush bodies; Handles integral with brushware
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/04Arranged like in or for toothbrushes
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses

Definitions

  • the present invention relates to a biodegradable prefabricated eco-friendly toothbrush.
  • the present invention relates to a biodegradable prefabricated eco-friendly toothbrush that can be disposed of by using the toothbrush head in the handle part at home, in a hotel, or outdoors.
  • the present invention is to be composed of a head portion that is assembled by fitting to the handle portion, the handle portion and the head portion is a biodegradable composition or bio-containing polyester-based polymers, polylactic acid, physical properties, lubricants, inorganic abrasives, etc. It relates to a biodegradable prefabricated eco-friendly toothbrush composed of a resin composition using a mass to prevent environmental pollution during disposal, easy to assemble and separate, and to selectively replace and use multiple heads.
  • the present invention relates to a biodegradable prefabricated eco-friendly toothbrush that is coated with a toothpaste on the filament of the head portion, and does not need to be provided with a separate toothpaste.
  • a toothbrush is composed of a head portion provided with a bristle and a handle portion integrally molded or assembled with the head portion.
  • such a toothbrush is formed of a general synthetic resin material (for example, polyethylene, polypropylene, nylon, etc.) for both the head part and the handle part, thereby contaminating the environment when they are discarded, and there is a problem that disposal is difficult.
  • these general synthetic resins take more than 100 to 200 years to be completely decomposed upon landfill, and produce various environmental problems such as environmental hormones, toxic and harmful substances when incinerated, and environmental treatment costs when disposed of.
  • the present applicant has developed a toothbrush configured to enable the head portion to be separated from the handle portion, and molded of a degradable material to facilitate disposal.
  • Handle part It is formed integrally with the front end of the handle portion, has a bottom surface coinciding with the bottom surface of the handle portion, the upper surface is formed lower than the height of the upper surface of the handle portion, and a press-fit hole is formed through the thickness direction in the center, and the press-in hole Locking protrusions are formed on both sides of the inner side, and left and right flow prevention grooves are formed at a boundary portion of the handle portion, and a front and rear flow prevention groove is formed in a region of the left and right flow prevention grooves; Consists of a seating plate seated on the base, a bristle brushed through an anchor on the upper surface of the seating plate, and fitted to the press-fit hole on the bottom surface, and press-fits formed with fitting grooves on both sides of which the locking projections are fitted.
  • Protrusions are formed, and the left and right flow prevention protrusions inserted into the left and right flow prevention grooves are formed in the neck portion facing the tip of the handle portion, and the front and rear flow prevention inserted into the front and rear flow prevention grooves are formed below the left and right flow prevention protrusions.
  • a brush portion formed with a projection the rest of the portion except for the bristles is made of a biodegradable resin composition or a biomass resin composition.
  • a toothbrush has a problem in that it is difficult to remove the handle portion, it is difficult to replace, and the bristles are not made of biodegradable materials, and to some extent, burdens environmental pollution.
  • the present invention is to improve the patent of the present applicant, as a biodegradable composition, to provide a biodegradable prefabricated eco-friendly toothbrush capable of completely removing the environmental pollution caused by disposing of the toothbrush by manufacturing the head portion, the toothbrush bar and the filament. .
  • Another object of the present invention is that the replacement of the head portion is used, and the user can selectively replace and use it, which is convenient, and the head portion is stably assembled so that there is no fall or shaking during use, and the head portion is replaced and used to save resources and , From the consumer's point of view, the aim is to provide a biodegradable prefabricated eco-friendly toothbrush with economic benefits due to the reduced price.
  • the present invention is to provide a biodegradable prefabricated eco-friendly toothbrush that can be used without the need for a separate toothpaste because the toothpaste is applied to the filament, and can be conveniently used at home as well as during travel.
  • the present invention is a prefabricated eco-friendly toothbrush
  • head part molded from a biodegradable composition
  • handle part and a filament planted in the head part
  • the head part and the handle part are assembled and used as a fit, and after use, the head part is separated and discarded.
  • a space in which the head portion is fitted is provided in the handle portion, and a projection portion in which the head portion is hung and fixed is provided in the space, and the head portion has a technical feature including that a groove into which the projection portion is fitted is provided. Is achieved.
  • the present invention prevents environmental pollution due to disposal by molding the handle portion, the head portion, and the filament with a biodegradable composition, and the handle portion and the head portion are separately combined to enable the replacement of the head portion, so that only a portion of the toothbrush is discarded when disposing. It is an invention that has the effect of being able to reduce the environmental burden and save resources, and also to give fun to users, especially children.
  • the present invention is provided by applying the toothpaste to the filament, it is configured to be able to brush without preparing a separate toothpaste, there is an effect that can be conveniently used outdoors, hotels, general homes, especially when traveling.
  • FIG. 1 is a side view showing an example of an eco-friendly toothbrush according to the present invention
  • Figure 2 is a side view showing an example of the head portion of the eco-friendly toothbrush according to the present invention
  • FIG. 3 is a side view of an eco-friendly toothbrush according to the present invention.
  • Figure 4 is a side view showing an assembly process of an eco-friendly toothbrush according to the present invention.
  • FIG. 5 is a cross-sectional view showing another embodiment of an eco-friendly toothbrush according to the present invention.
  • 6 to 8 is a side view and a perspective view showing another embodiment of an eco-friendly toothbrush according to the present invention.
  • FIG. 9 is a perspective view showing another embodiment of the present invention.
  • 10 to 14 is a side view and a perspective view showing another embodiment of an eco-friendly toothbrush according to the present invention.
  • 15 is a side view showing an example of a device for spraying liquid toothpaste applied to the present invention.
  • the toothbrush of the present invention comprises a handle portion 100, a head portion 200, and a filament 300, each of which is molded from a biodegradable composition.
  • the head part and the handle part are configured separately so that they are assembled and used in fitting when brushing teeth, and after use, only the head part is separated and disposed, thereby saving resources and reducing the burden on environmental pollution.
  • the handle part 100 is provided with a space in the front inside where the head part is fitted so that the head part is fitted, and an incision part 120 is provided to assemble the head part.
  • the incision part 120 is cut in the longitudinal direction, and is provided with a bottleneck to prevent separation of the fitted head part, and the protrusion 220 fitted to the incision part protrudes from the head part 200.
  • the projection 220 moves along the incision, and is assembled by forcibly fitting while passing through the bottle neck portion, thereby preventing departure.
  • FIG. 5 shows another embodiment of the present invention.
  • This embodiment is provided by protruding portion 122 on the top and bottom surfaces or side walls of the space 102 of the hand portion, and is formed by protruding the recess 222 that engages the protruding portion in the head portion 100, It is to provide an elasticity by providing an empty space 224 as shown in the drawing in the portion where the recess is formed.
  • the present invention of such a configuration is to assemble the head portion 200 into the space 102, and when the head portion 200 is pushed in, it is fitted into the protrusion and the recess, and when the protrusion is fitted, the empty space of the head portion is inserted. By this it is to be easily coupled while the recess is slightly pressed.
  • Attached 6 shows another embodiment of the present invention.
  • This embodiment is for rotationally coupled with the slide, and provided with a slide groove (104) in the longitudinal direction on the inner wall of the space (102) of the handle portion (100), a binding groove at the end of the slide groove (104) (106) is provided.
  • the head portion 200 is configured to be fitted while moving along the slide groove 104, reaching the binding groove, and rotating the user to be fitted into the binding groove by rotating.
  • the binding groove 106 is formed at an angle of at least 45° or more to prevent the detachment of the fixing piece.
  • each or more sides are provided as necessary. What can be done is natural.
  • the present invention made of such a configuration is to fit the fixing piece 240 into the slide groove 104 and rotate the pin piece when it reaches the end of the slide groove to be fitted into the binding groove, thereby fixing the head portion and the handle portion.
  • a magnet is provided on the fixing piece, and a metal piece is provided on a binding groove of a surface facing the magnet.
  • the fixed piece arrives at the end of the slide groove, and the magnet is pulled to the metal piece, so that the head is automatically rotated to facilitate the use.
  • the head portion 200 and the handle portion 100 are provided with protruding extension portions 162 and 262 of the same thickness, respectively, and the head portion is provided with engaging projections 260, corresponding to the handle portion.
  • the coupling grooves 262 are formed to be coupled to each other.
  • the toothbrush of this embodiment is composed of a handle portion 100 and a head portion 200, each of which is molded from a biodegradable composition.
  • the head portion 200 is configured with a base portion 201, a filament 300 planted in the base portion, and a neck portion 203 extending rearward of the base portion.
  • An assembly hole 202 in which the handle portion is fitted is formed in the neck portion 203, and a detachable portion 400 is provided in the assembly hole.
  • the handle portion 100 may be configured in various forms, such as a circular, square, elliptical, or geometrical shape, and various colors may be selected.
  • a fitting portion 102 fitted to the assembly hole 202 is provided at the front end of the handle portion 100, and a hooking ring (in which the hooking of the detachable portion 400 described later is fitted on the upper surface of the fitting portion 102) 104) is formed.
  • guide projections 106 are projected on both sides of the fitting portion 102, and the guide projections 106 are fitted on both sides of the assembly hole 202 of the head portion 200 to guide movement and prevent shaking during use.
  • the concave groove 206 can be formed.
  • the detachable portion 400 is to be assembled and separated the handle portion and the head portion, the pressing member 410, a guide member 420 for guiding the movement of the pressing member, and the hook 104 It consists of a detachable ring 440 to be hung, and a spring 430 to elastically support the detachable ring.
  • the guide member 420 of the detachable portion 400 is provided on the bottom surface of the head portion, that is, on the opposite side of the filament 300 to guide the movement of the pressing member, and the detachable ring is attached to the inside of the pressing member together. It is a moving configuration.
  • the detachable ring 440 is inserted into the guide hole 204 formed on the wall surface of the assembler as shown in the drawing, and the spring 430 elastically supports the detachable ring 440.
  • the biodegradable composition according to the present invention based on 100 parts by weight of the biodegradable aliphatic polyester polymer, 1 to 20 parts by weight of polylactic acid; 5-20 parts by weight of a property metering agent; 1 to 10 parts by weight of lubricant; And 1 to 15 parts by weight of an inorganic polishing agent.
  • the biodegradable aliphatic polyester-based polymer according to the present invention has good biodegradation by microorganisms, but has low mechanical properties and low thermal properties, and thus has limitations in replacing general-purpose polymers such as polyethylene (PE) in various applications. It is used as a substitute for a non-degradable general-purpose polymer in various applications that are discarded after short-term use.
  • PE polyethylene
  • Preferred biodegradable aliphatic polyester polymers include those containing polybutylene succinate (PBS), polycaprolactone (PCL), poly(butylene adipate) (PBA), polybutylene adipate-co-terephthalate (PBAT), or a mixture of at least one selected from them. It is good.
  • the content of the remaining components other than the biodegradable aliphatic polyester-based polymer constituting the biodegradable composition according to the present invention is based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer.
  • the polylactic acid (PLA) according to the present invention provides elasticity to the biodegradable composition, and has biodegradability by itself.
  • the preferred amount of polylactic acid can be changed according to the user's choice, but is recommended to be 1 to 20 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
  • the water metering agent according to the present invention is used to supplement the properties of a biodegradable aliphatic polyester-based polymer that is easily fractured due to its toughness, that is, a high strength but lacks elongation.
  • a biodegradable aliphatic polyester-based polymer that is easily fractured due to its toughness, that is, a high strength but lacks elongation.
  • any of them may be used, but divalent alcohol or glycerol obtained from diethylene glycol, trihydric alcohol obtained from trimethylol propane, succinic acid, or divalent acid obtained from adipic acid It is recommended to use those produced by condensation polymerization from the anhydride form of, but it is recommended that the weight average molecular weight is 50,000 to 150,000 Da, and that the melting index is 20 to 30 g/10min dihydric alcohol, trihydric alcohol, glycerol, succinic acid, adip It is preferable to use a finic acid or a mixture of at least one selected from
  • the preferred polycaprolactone has a molecular weight of 30,000 to 60,000 Da, a melt index of 20 to 30 g/10min, and a melting point of 58 to 60°C is recommended.
  • the amount of the physical property metering agent according to the present invention can be changed according to the user's choice, but preferably 5 to 20 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer.
  • the lubricant according to the present invention is for improving the lubricity of the handle part, the head part or the bristles using the biodegradable composition, and for this purpose, any conventional lubricant in the art may be used, but preferably for a long time
  • the fatty acid ester having a HLB value (Hydrophile-Lipophile balance value) in the range of 7.0 to 16.0, specifically glycerin fatty acid ester, sorbitan indicates the ratio of the hydrophilic component and the lipophilic component in the molecule. It is preferred to use fatty acid esters, pyridoxine fatty acid esters or mixtures of at least one selected from them.
  • the amount of the lubricant according to the present invention can be changed according to the user's choice, but preferably 1 to 10 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
  • the inorganic abrasive according to the present invention is intended to improve the stiffness and flexural restoration properties of the biodegradable monofilament composition and at the same time improve the cleaning power, and any inorganic abrasive having this purpose may be used, but preferably toothpaste composition
  • any inorganic abrasive having this purpose may be used, but preferably toothpaste composition
  • the average particle size of the inorganic abrasive is preferably several nanometers to several micrometers, preferably 10nm to 100 ⁇ m.
  • the amount of the inorganic abrasive according to the present invention can be changed according to the user's choice, but preferably 1 to 15 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
  • biodegradable monofilament according to the present invention may further include one or more types of adducts of the following specific embodiments.
  • the biodegradable monofilament composition according to the present invention is a natural emulsion harmless to the human body, and may further include 1 to 15 parts by weight of a food additive based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
  • the food additive is specifically made of a product such as a bristle, it is possible to prevent the gums from being scratched by maintaining a smooth state by imparting excellent smoothness to the surface as well as focusing properties.
  • the food additive is a natural emulsion flows out to the filament surface during the drawing process for manufacturing the monofilament, and heat treatment is performed in this state, thereby improving strength and hardness as well as providing excellent smoothness.
  • Preferred food additives are natural emulsions extracted from coconut, palm, soybean, cacao, etc., or at least one mixture selected from these natural emulsions.
  • the biodegradable composition according to the present invention is 1 to 100 parts by weight of sodium bentonite based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer in order to improve the strength by densifying the pores of the biodegradable composition and preventing the release of moisture. It may further include 10 parts by weight.
  • the sodium bentonite absorbs a large amount of water, expands several times the original volume, becomes a gel-like state, and densely fills pores of the composition, thereby preventing the release of moisture and improving strength, thereby contributing to crack prevention.
  • the biodegradable monofilament composition according to the present invention is 0.1 to 3 based on 100 parts by weight of starch ether as a biodegradable aliphatic polyester polymer to improve self-leveling (self-charging performance). It may further include parts by weight.
  • the biodegradable composition according to the present invention further comprises 0.1 to 2 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer of diphenylmethane diisocyanate to control the viscosity of the biodegradable monofilament composition. can do.
  • the biodegradable composition according to the present invention may further include 1 to 5 parts by weight of magnesium carbonate (magnesium carboneate) based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer, the magnesium carbonate being white and light As a material that is easy to break, it is also used as a raw material for cosmetics.
  • magnesium carbonate When magnesium carbonate is included in the biodegradable monofilament composition, it increases the crystallinity of the biodegradable monofilament composition to improve rigidity, transparency, and gloss, as well as biodegradable mono It is to give the dual function of adjusting the pH of the filament composition.
  • the biodegradable composition according to the present invention may further include 0.1 to 2 parts by weight based on 100 parts by weight of stearic acid based on the biodegradable aliphatic polyester polymer to improve dispersibility of the biodegradable monofilament composition. have.
  • the biodegradable composition according to the present invention is 0.1 to 3 parts by weight based on 100 parts by weight of 1,3-propane diol based on 100 parts by weight of the biodegradable aliphatic polyester polymer to improve the moisturizing and antiseptic power of the biodegradable composition. It may contain 1,3-propane diol has a low viscosity and absorbency, and is less sticky. When included in the biodegradable composition, the composition has an advantage of improving the moisturizing power and using less preservative, so that the preservative power is also increased.
  • the biodegradable composition according to the present invention readily reacts with a transition metal such as iron in the soil when the biodegradable monofilament composition is decomposed in the soil to easily break the carbon-carbon bond of the biodegradable monofilament composition.
  • a transition metal such as iron
  • the biodegradable monofilament composition is decomposed in the soil to easily break the carbon-carbon bond of the biodegradable monofilament composition.
  • linoleic acid may further include 0.1 to 2 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer.
  • the biodegradable composition according to the present invention is based on 100 parts by weight of a biodegradable aliphatic polyester-based polymer based on hydroxybenzopinone (Hydroxybenzophenone) in order to prevent the photodegradation of the biodegradable composition by UV light 0.1 to 3 parts by weight may be further included.
  • a biodegradable aliphatic polyester-based polymer based on hydroxybenzopinone Hydrobenzophenone
  • the biodegradable composition according to the present invention is 0.1 to 100 parts by weight of polyvinyl alcohol based on 100 parts by weight of the biodegradable aliphatic polyester polymer to improve the compatibility between the biodegradable aliphatic polyester polymer and polylactic acid. It may further include 3 parts by weight.
  • the biodegradable monofilament composition according to the present invention comprises a mixture of urea and alum in which a urea and alum compound are mixed in a weight ratio of 1 to 3 to improve plasticization by destroying the structure of the aliphatic polyester polymer. It may further include 0.1 to 3 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer. When using 0.1 parts or less based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer, the desired effect cannot be obtained, and 3 parts by weight Exceeding wealth adversely affects other raw materials, thereby deteriorating the mechanical properties of the final product.
  • the biodegradable composition according to the present invention is 0.1 based on 100 parts by weight of a biodegradable aliphatic polyester-based polymer of tert-butyl perbenzoate in order to improve tensile strength, viscoelasticity, coolability, etc. of the biodegradable composition. It may further include to 2 parts by weight.
  • the biodegradable composition according to the present invention removes the phenomenon of easily breaking or tearing the composition, and dibenzoyl peroxide is used as a biodegradable aliphatic polyester-based polymer 100 parts by weight to improve processability. It may further include 0.1 to 3 parts by weight.
  • the biodegradable composition according to the present invention may further include 0.1 to 2 parts by weight based on 100 parts by weight of calcium stearate to improve the flowability of the biodegradable monofilament composition based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer. have.
  • the present invention may be composed of a resin composition using biomass.
  • the resin composition using biomass is 5 to 70% by weight of polymer resin, 20 to 70% by weight of biomass, 2 to 20% by weight of PBAT, PBS, PBAT/PBS polymer or a mixture thereof, 2 to 20% by weight of biodegradable resin %, 2 to 10% by weight of calcium carbonate, 1 to 10% by weight of a surfactant, 1 to 5% by weight of a release agent, 1 to 5% by weight of a stabilizer, and a resin composition using a biomass comprising 1 to 5% by weight of a binder do.
  • the resin composition using the biomass of the present invention is 5 to 70% by weight of polypropylene as the polymer resin, 20 to 70% by weight of cellulose as the biomass, 2 to 20% by weight of PBAT, and polylactic acid 2 as the biodegradable resin.
  • PBAT polypropylene
  • polylactic acid 2 as the biodegradable resin.
  • the biomass contains a material derived from a renewable organic resource, and is chemically or biologically synthesized and can be used as a polymer material, which is environmentally friendly.
  • Animal biomass It is recommended to use fatty acids, seaweeds, or mixtures of vegetable oils made of biomass elastomers by polymerizing with natural fibers, cellulose, ligno cellulose, starch, and diene polymers, but natural fibers, cellulose, and ligno are recommended.
  • Cellulose, starch, fatty acids of vegetable oils, seaweeds or mixtures thereof are preferred.
  • biomass according to the present invention may be referred to as a biomass resin or biopolymer, for ease of description of the present invention, all of the biomass resin or biopolymer will be referred to collectively as biomass.
  • the liquid toothpaste according to the present invention is applied to the filament, and the liquid toothpaste has allantoin as a main component, a wetting agent, a sweetener, a regulator, a preservative, an antioxidant, a foaming agent, a solvent, a flavoring agent, a coloring agent, and a solvent of 96% ethanol Is mixed.
  • the preferred amount of toothpaste is 2 to 10 g applied to one toothbrush, and 5 g is best applied.
  • the sweetener according to the present invention is to improve the aesthetics that close to the tongue, and a mixture of at least one or more of xylitol, sodium saccharinate, erythritol, dihydrochalcone, glycine, and D-phenylalanine is used, and in the present invention, saccharin sodium hydrate It is best to include one or both of xylitol,
  • the wetting agent and the pH adjusting agent may be any conventional wetting agent and adjusting agent in the art, but preferably, glycerin as the wetting agent and citric acid and sodium citrate hydrate are preferable as the wetting agent.
  • the preservative according to the present invention is methyl paraben, and the sulfate agent is ascorbic acid.
  • the preservative and the sulfate agent may be selected as those commonly used in toothpaste.
  • the foaming agent is preferably sodium lauryl sulfate, and the solubilizing agent is polyoxyethylene cured castor oil.
  • the flavoring agent according to the present invention is a natural flavoring agent used in natural extracts such as fruit and plant extracts and toothpaste, and preferably at least one of peppermint oil, lemon mint flavor, orange oil, eucalyptus oil, and L-menthol, or Use more.
  • the liquid toothpaste according to the present invention with respect to 100 parts by weight of allantoin, 4,000 to 6,000 parts by weight of a wetting agent, 150 to 250 parts by weight of a sweetener, 4,000 to 5,000 parts by weight of a wetting agent, 120 to 130 parts by weight of a control agent, 130 to 160 parts by weight of a preservative, oxidation 5 to 15 parts by weight of the preventive agent, 8,000 to 10,000 parts by weight of the foaming agent, 2,800 to 3,500 parts by weight of the solubilizer and 5 to 15 parts by weight of the flavoring agent, 5 to 15 parts by weight of the colorant, and 150 to 250 parts by weight of the solvent are mixed.
  • the present invention is based on 100 parts by weight of allantoin, 5,000 parts by weight of glycerin, 200 parts by weight of sodium saccharinate, 30 parts by weight of citric acid, 100 parts by weight of sodium citrate, 150 parts by weight of methylparaben, 10 parts by weight of ascorbic acid, Sodium lauryl sulfate 9,000 parts by weight, 3,300 parts by weight of polyoxyethylene cured castor oil, 3 parts by weight of peppermint oil, 3 parts by weight of lemon mint flavor, 5 parts by weight of orange oil, 10 parts by weight of blue No. 1 as colorant, 200 parts by weight of ethanol
  • the liquid toothpaste is constituted, and the liquid toothpaste is put into the following feeder and sprayed onto the filament to be applied.
  • the liquid toothpaste according to the present invention is automatically injected through this injection nozzle in a state in which it is injected into a tank.
  • the present invention is provided with a spray nozzle 30 on the top of the conveyor 20, the spray nozzle 30 is provided with a connecting pipe 40 connected to the liquid toothpaste tank, and supplying air to the top of the nozzle
  • a pump not shown
  • the top surface of the conveyor 20 has a configuration in which the head portion is fitted and seated portions 50 are seated at equal intervals.
  • the present invention relates to a toothbrush, which can be used outdoors as well as in general homes, and is molded with a biodegradable composition so that there is no burden on environmental pollution.

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  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
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Abstract

The present invention relates to an environment-friendly modular toothbrush and has: a head part which is formed from a biodegradable composition; a handle part; and filaments which are implanted in the head part. The head part and the handle part are assembled and used by insertion. The head part is detached and discarded after use. The handle part has a space into which the head part is inserted. A protrusion portion for latching and fixing the head part is provided in the space. The head part has a groove into which the protrusion portion is inserted.

Description

생분해성 조립식 친환경 칫솔Biodegradable prefabricated eco-friendly toothbrush
본 발명은 생분해성 조립식 친환경 칫솔에 관한 것이다.The present invention relates to a biodegradable prefabricated eco-friendly toothbrush.
더 상세하게는 일반 가정에서는 물론 호텔, 야외에서 핸들부에 칫솔 헤드부를 끼워 사용한 다음 폐기할 수 있도록 한 생분해성 조립식 친환경 칫솔에 관한 것이다. More specifically, the present invention relates to a biodegradable prefabricated eco-friendly toothbrush that can be disposed of by using the toothbrush head in the handle part at home, in a hotel, or outdoors.
본 발명은 핸들부에 끼워맞춤으로 조립되는 헤드부로 구성되도록 하되, 이 핸들부와 헤드부가 폴리에스테르계 고분자, 폴리락틱산, 물성계량제, 윤활제, 및 무기연마제 등을 포함하는 생분해성 조성물 또는 바이오 매스를 이용한 수지 조성물로 구성되어 폐기 시 환경 오염을 방지하고, 조립 및 분리가 용이하며, 여러 개의 헤드부를 선택적으로 교체하며 사용할 수 있는 생분해성 조립식 친환경 칫솔에 관한 것이다. The present invention is to be composed of a head portion that is assembled by fitting to the handle portion, the handle portion and the head portion is a biodegradable composition or bio-containing polyester-based polymers, polylactic acid, physical properties, lubricants, inorganic abrasives, etc. It relates to a biodegradable prefabricated eco-friendly toothbrush composed of a resin composition using a mass to prevent environmental pollution during disposal, easy to assemble and separate, and to selectively replace and use multiple heads.
또 본 발명은 헤드부의 필라멘트에 치약이 도포되어, 별도의 치약을 구비할 필요가 없고, 사용 후 헤드부를 분리하여 폐기한 다음 다른 헤드부를 끼워 사용할 수 있는 생분해성 조립식 친환경 칫솔에 관한 것이다.In addition, the present invention relates to a biodegradable prefabricated eco-friendly toothbrush that is coated with a toothpaste on the filament of the head portion, and does not need to be provided with a separate toothpaste.
일반적으로 칫솔은 칫솔모가 구비된 헤드부와, 이 헤드부에 일체로 성형되거나 절첩식 등으로 조립되는 핸들부로 구성된다. In general, a toothbrush is composed of a head portion provided with a bristle and a handle portion integrally molded or assembled with the head portion.
종래 이러한 칫솔은 헤드부 및 핸들부가 모두 일반 합성수지재(예를 들어, polyethylene, polypropylene, nylon 등)로 성형 되어 있어서 이들이 버려질 경우 환경을 오염시키며, 폐기가 곤란한 문제가 있었다. 즉 이들 일반 합성수지는 매립 시 완전히 분해되려면 100 ~ 200년 이상이 소요되고, 소각 시 환경호르몬과 유독, 유해물질이 발생하며, 폐기 시 환경처리비용이 소요되는 등 여러 문제점을 안고 있다.Conventionally, such a toothbrush is formed of a general synthetic resin material (for example, polyethylene, polypropylene, nylon, etc.) for both the head part and the handle part, thereby contaminating the environment when they are discarded, and there is a problem that disposal is difficult. In other words, these general synthetic resins take more than 100 to 200 years to be completely decomposed upon landfill, and produce various environmental problems such as environmental hormones, toxic and harmful substances when incinerated, and environmental treatment costs when disposed of.
이를 개선하기 위해, 국내실용신안등록 제20-0354838호(이하 '선행기술' 이라 함)에서는 헤드부의 브러시 일부분을 헤드부로부터 착탈 가능하게 구성하여, 브러시 손상시에 여타 부위는 그대로 사용하고 손상된 브러시만을 새로운 브러시로 교환하여 재사용할 수 있으므로 유해 폐기물 발생량을 현저히 줄일 수 있고, 칫솔 전체를 구입하는 것에 비하여 구입비용을 절감할 수 있어서 종전의 문제점을 어느 정도 해소할 수 있었다.In order to improve this, in Korean Utility Model Registration No. 20-0354838 (hereinafter referred to as'prior art'), a part of the brush in the head part is detachable from the head part, and when the brush is damaged, other parts are used as they are and the damaged brush Since the bay can be reused by replacing it with a new brush, it is possible to significantly reduce the amount of hazardous waste and to reduce the purchase cost compared to purchasing the entire toothbrush, thereby solving some of the previous problems.
그러나 이러한 칫솔도 폐기에 따른 환경 오염에 대한 부담은 근본적인 해결책은 되지 못하고 있다. However, such a toothbrush is not a fundamental solution to the burden of environmental pollution due to disposal.
이에 본 출원인은 헤드부가 핸들부로부터 절단 분리가 가능하게 구성하고, 분해성 재질로 성형하여 폐기가 용이하도록 한 칫솔을 개발한 바 있다. Accordingly, the present applicant has developed a toothbrush configured to enable the head portion to be separated from the handle portion, and molded of a degradable material to facilitate disposal.
국내 등록특허 10-1427317호는 본 출원인에 의해 개발된 친환경 칫솔로써, Domestic registered patent 10-1427317 is an eco-friendly toothbrush developed by the applicant,
핸들부; 상기 핸들부의 선단에 일체로 형성되며, 상기 핸들부의 밑면과 일치하는 밑면을 가지며, 상면은 상기 핸들부의 상면 높이에 비해 낮게 형성되고, 중앙에는 압입홀이 두께방향으로 관통되게 형성되며, 상기 압입홀 내의 양 측면에는 걸림돌기가 형성되고, 상기 핸들부의 경계부위에는 좌우 유동방지홈이 형성되며, 상기 좌우 유동방지홈의 영역 내에는 전후 유동방지홈이 형성된 받침부; 상기 받침부 상에 안착되는 안착판, 상기 안착판의 상면에 앵커를 매개로 식모되는 칫솔모로 구성되고, 저면에는 상기 압입홀에 끼움 결합되며, 양측면에 상기 걸림돌기가 끼움 결합되는 끼움홈이 형성된 압입돌기가 형성되고, 상기 핸들부의 선단과 마주하는 네크부에는 상기 좌우 유동방지홈에 삽입되는 좌우 유동방지돌기가 형성되며, 상기 좌우 유동방지돌기의 하부에는 상기 전후 유동방지홈에 삽입되는 전후 유동방지돌기가 형성된 브러시부;로 포함하며, 상기 칫솔모를 제외한 나머지 부분이 생분해성 수지 조성물 또는 바이오매스 수지 조성물로 이루어진 것이다. 그러나 이와 같은 칫솔은 핸들부를 분리하기 어렵고, 교체가 어려우며, 또한 칫솔모가 생분해성 물질로 제작되지 않아 어느 정도는 환경 오염에 부담을 줄 수 밖에 없는 문제가 있다. Handle part; It is formed integrally with the front end of the handle portion, has a bottom surface coinciding with the bottom surface of the handle portion, the upper surface is formed lower than the height of the upper surface of the handle portion, and a press-fit hole is formed through the thickness direction in the center, and the press-in hole Locking protrusions are formed on both sides of the inner side, and left and right flow prevention grooves are formed at a boundary portion of the handle portion, and a front and rear flow prevention groove is formed in a region of the left and right flow prevention grooves; Consists of a seating plate seated on the base, a bristle brushed through an anchor on the upper surface of the seating plate, and fitted to the press-fit hole on the bottom surface, and press-fits formed with fitting grooves on both sides of which the locking projections are fitted. Protrusions are formed, and the left and right flow prevention protrusions inserted into the left and right flow prevention grooves are formed in the neck portion facing the tip of the handle portion, and the front and rear flow prevention inserted into the front and rear flow prevention grooves are formed below the left and right flow prevention protrusions. Included as; a brush portion formed with a projection, the rest of the portion except for the bristles is made of a biodegradable resin composition or a biomass resin composition. However, such a toothbrush has a problem in that it is difficult to remove the handle portion, it is difficult to replace, and the bristles are not made of biodegradable materials, and to some extent, burdens environmental pollution.
본 발명은 이와 같은 본 출원인의 특허를 개량한 것으로, 생분해성 조성물로, 헤드부와 칫솔대 그리고 필라멘트를 제조하여 칫솔 폐기에 따른 환경 오염을 완전히 제거할 수 있는 생분해성 조립식 친환경 칫솔을 제공하는 데 있다. The present invention is to improve the patent of the present applicant, as a biodegradable composition, to provide a biodegradable prefabricated eco-friendly toothbrush capable of completely removing the environmental pollution caused by disposing of the toothbrush by manufacturing the head portion, the toothbrush bar and the filament. .
본 발명의 다른 목적은 헤드부의 교체가 이용하고, 사용자가 선택적으로 교체하며 사용할 수 있어 편리하고, 헤드부가 안정적으로 조립되어 사용 중 빠지거나 흔들림이 없으며, 또한 헤드부만 교체 사용함으로써 자원을 절감하고, 소비자의 입장에서는 가격이 하락되어 경제적인 이득이 있는 생분해성 조립식 친환경 칫솔을 제공하는 데 있다.Another object of the present invention is that the replacement of the head portion is used, and the user can selectively replace and use it, which is convenient, and the head portion is stably assembled so that there is no fall or shaking during use, and the head portion is replaced and used to save resources and , From the consumer's point of view, the aim is to provide a biodegradable prefabricated eco-friendly toothbrush with economic benefits due to the reduced price.
또한 본 발명은 필라멘트에 치약이 도포되어 별도의 치약을 구비할 필요 없이 사용이 가능하고, 가정에서는 물론 여행 중 편리하게 사용할 수 있는 생분해성 조립식 친환경 칫솔을 제공하는 데 있다. In addition, the present invention is to provide a biodegradable prefabricated eco-friendly toothbrush that can be used without the need for a separate toothpaste because the toothpaste is applied to the filament, and can be conveniently used at home as well as during travel.
본 발명은 조립식 친환경 칫솔로써, The present invention is a prefabricated eco-friendly toothbrush,
생분해성된 조성물로 성형된 헤드부와, 핸들부 그리고 상기 헤드부에 심어지는 필라멘트로 구성되고, 상기 헤드부와 핸들부는 끼워맞춤으로 조립되어 사용되고, 사용 후 헤드부를 분리하여 폐기하는 것이며, It is composed of a head part molded from a biodegradable composition, a handle part and a filament planted in the head part, and the head part and the handle part are assembled and used as a fit, and after use, the head part is separated and discarded.
상기 핸들부에 상기 헤드부가 끼워지는 공간이 마련되고, 이 공간에 상기 헤드부가 걸려 고정될 수 있는 돌출부가 구비되고, 헤드부에는 이 돌출부가 끼워지는 요홈이 마련된 것을 포함하는 기술적인 특징을 갖는 것으로 달성된다. A space in which the head portion is fitted is provided in the handle portion, and a projection portion in which the head portion is hung and fixed is provided in the space, and the head portion has a technical feature including that a groove into which the projection portion is fitted is provided. Is achieved.
본 발명은 생분해성 조성물로 핸들부와 헤드부 그리고 필라멘트를 성형하여 폐기에 따른 환경 오염을 방지하고, 핸들부와 헤드부가 분리 결합되어 헤드부의 교체 사용이 가능함으로써, 폐기 시 칫솔 전체가 아닌 일부만 폐기할 수 있어 환경 부담을 줄이고 자원을 절감할 수 있으며, 사용자 특히 어린이들에게 재미도 줄 수 있는 효과를 갖는 발명이다. The present invention prevents environmental pollution due to disposal by molding the handle portion, the head portion, and the filament with a biodegradable composition, and the handle portion and the head portion are separately combined to enable the replacement of the head portion, so that only a portion of the toothbrush is discarded when disposing. It is an invention that has the effect of being able to reduce the environmental burden and save resources, and also to give fun to users, especially children.
또한 본 발명은 필라멘트에 치약이 도포되어 제공됨으로써, 별도의 치약을 준비하지 않아도 양치가 가능하도록 구성되며, 야외나 호텔, 일반 가정 특히 여행 시 편리하게 사용할 수 있는 효과가 있다.In addition, the present invention is provided by applying the toothpaste to the filament, it is configured to be able to brush without preparing a separate toothpaste, there is an effect that can be conveniently used outdoors, hotels, general homes, especially when traveling.
도 1은 본 발명에 따른 친환경 칫솔의 일 예를 일측면도,1 is a side view showing an example of an eco-friendly toothbrush according to the present invention,
도 2는 본 발명에 따른 친환경 칫솔의 헤드부의 일예를 나타낸 일측도,Figure 2 is a side view showing an example of the head portion of the eco-friendly toothbrush according to the present invention,
도 3은 본 발명에 따른 친환경 칫솔의 일측면도ㅡ3 is a side view of an eco-friendly toothbrush according to the present invention;
도 4는 본 발명에 따른 친환경 칫솔의 조립 과정을 나타낸 일측면도,Figure 4 is a side view showing an assembly process of an eco-friendly toothbrush according to the present invention,
도 5는 본 발명에 따른 친환경 칫솔의 다른 실시 예를 나타낸 단면도,5 is a cross-sectional view showing another embodiment of an eco-friendly toothbrush according to the present invention,
도 6 내지 8은 본 발명에 따른 친환경 칫솔의 또 다른 실시 예를 나타낸 일측면도 및 사시도, 6 to 8 is a side view and a perspective view showing another embodiment of an eco-friendly toothbrush according to the present invention,
도 9은 본 발명의 또 다른 실시 예를 나타낸 사시도,9 is a perspective view showing another embodiment of the present invention,
도 10 내지 도 14는 본 발명에 따른 친환경 칫솔의 또 다른 실시 예를 나타낸 일측면도 및 사시도, 10 to 14 is a side view and a perspective view showing another embodiment of an eco-friendly toothbrush according to the present invention,
도 15는 본 발명에 적용되어 액상 치약을 분사하는 장치의 일 예를 나타낸 일측면도. 15 is a side view showing an example of a device for spraying liquid toothpaste applied to the present invention.
이하 본 발명의 바람직한 실시 예를 첨부된 도면에 의거하여 상세히 설명하면 다음과 같다. Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도면에서 본 발명의 칫솔은 핸들부(100)와, 헤드부(200) 그리고 필라멘트(300)로 구성되고, 각각은 생분해성 조성물로 성형된다. In the drawings, the toothbrush of the present invention comprises a handle portion 100, a head portion 200, and a filament 300, each of which is molded from a biodegradable composition.
본 본 발명에서 상기 헤드부와 핸들부는 분리 구성되어 양치를 할 때에는 끼워맞춤으로 조립하여 사용하고, 사용 후에는 헤드부만 분리하여 폐기하는 것으로, 자원을 절감하고, 환경 오염에 대한 부담을 줄이도록 하는 것이지만, 경우에 따라서는 헤드부와 핸들부를 일체로 성형하는 것도 가능하다. In the present invention, the head part and the handle part are configured separately so that they are assembled and used in fitting when brushing teeth, and after use, only the head part is separated and disposed, thereby saving resources and reducing the burden on environmental pollution. However, in some cases, it is also possible to integrally mold the head portion and the handle portion.
본 발명에 따른 상기 핸들부(100)는, 헤드부가 끼워지는 전방 안쪽으로 공간이 마련되어 헤드부가 끼워지도록 하고, 절개부(120)를 구비하여 헤드부가 조립되록 한다. The handle part 100 according to the present invention is provided with a space in the front inside where the head part is fitted so that the head part is fitted, and an incision part 120 is provided to assemble the head part.
상기 절개부(120)는 길이 방향으로 절개되고, 병목부를 구비하여 끼워진 헤드부의 이탈을 방지하는 것으로, 상기 헤드부(200)에는 이 절개부에 끼워지는 돌기(220)가 돌출되어 있다. The incision part 120 is cut in the longitudinal direction, and is provided with a bottleneck to prevent separation of the fitted head part, and the protrusion 220 fitted to the incision part protrudes from the head part 200.
다시 말해, 상기 헤드부(200)를 핸드부에 마련된 공간에 끼워 조립하면, 돌기(220)가 절개부를 따라 이동하고, 병목부를 지나면서 억지 끼워맞춤으로 조립되어 이탈이 방지되는 것이다. In other words, when the head portion 200 is inserted into the space provided in the hand portion and assembled, the projection 220 moves along the incision, and is assembled by forcibly fitting while passing through the bottle neck portion, thereby preventing departure.
첨부된 도 5는 본 발명의 다른 실시 예를 나타낸 것이다. Figure 5 shows another embodiment of the present invention.
이 실시 예는 상기 핸드부의 공간(102) 상면 및 바닥면 또는 측벽에 돌출부(122)를 구비하고, 헤드부(100)에는 상기 돌출부가 끼워져 걸리도록 하는 요홈부(222)를 돌출시켜 형성하되, 이 요홈부가 형성된 부위에 도면과 같이 빈공간(224)을 마련하여 탄력을 갖도록 하는 것이다. This embodiment is provided by protruding portion 122 on the top and bottom surfaces or side walls of the space 102 of the hand portion, and is formed by protruding the recess 222 that engages the protruding portion in the head portion 100, It is to provide an elasticity by providing an empty space 224 as shown in the drawing in the portion where the recess is formed.
이러한 구성의 본 발명은, 헤드부(200)를 상기 공간(102)에 끼워 조립하는 것으로, 헤드부(200)를 밀어 넣으면, 돌출부와 요홈부에 끼워져 고정되는데 돌출부가 끼워질 때 헤드부의 빈공간에 의해 요홈부가 약간 눌리면서 쉽게 결합되도록 하는 것이다. The present invention of such a configuration is to assemble the head portion 200 into the space 102, and when the head portion 200 is pushed in, it is fitted into the protrusion and the recess, and when the protrusion is fitted, the empty space of the head portion is inserted. By this it is to be easily coupled while the recess is slightly pressed.
물론 사용 후 분리시에도 편하게 빼낼 수 있는 장점도 있다. Of course, there is also an advantage that can be easily taken out even after use.
첨부된 6은 본 발명의 또 다른 실시 예를 나타낸 것이다. Attached 6 shows another embodiment of the present invention.
이 실시 예는 슬라이드와 회전식으로 결합하기 위한 것으로, 핸들부(100)의 공간(102) 내측벽에 길이 방향으로 슬라이드홈(104)을 구비하고, 이 슬라이드홈(104)의 끝부분에 결착홈(106)이 마련된 구성이다.This embodiment is for rotationally coupled with the slide, and provided with a slide groove (104) in the longitudinal direction on the inner wall of the space (102) of the handle portion (100), a binding groove at the end of the slide groove (104) (106) is provided.
상기 헤드부(200)에는 슬라이드홈(104)을 따라 이동하며 끼워지고, 상기 결착홈에 도달하며 사용자가 회전시켜 결착홈에 끼워지도록 하는 고정편(240)이 갖추어진 구성이다. The head portion 200 is configured to be fitted while moving along the slide groove 104, reaching the binding groove, and rotating the user to be fitted into the binding groove by rotating.
상기 결착홈(106)은 적어도 45°이상 각도로 형성되어 고정편의 이탈을 방지하게 된다, 한편, 도면에는 상기 슬라이드홈과 고정편이 하나씩만 도시되어 있으나, 필요에 따라서는 양측 각각 또는 그 이상이 구비될 수 있는 것은 당연한 것이다. The binding groove 106 is formed at an angle of at least 45° or more to prevent the detachment of the fixing piece. On the other hand, although only one slide groove and the fixing piece are shown in the drawing, each or more sides are provided as necessary. What can be done is natural.
이러한 구성으로 이루어진 본 발명은, 슬라이드홈(104)에 상기 고정편(240)을 맞춰 끼우고, 고정편이 슬라이드홈 끝에 도달하면 회전시켜 결착홈에 끼워지도록 함으로써, 헤드부와 핸들부를 고정시키는 것이다. The present invention made of such a configuration is to fit the fixing piece 240 into the slide groove 104 and rotate the pin piece when it reaches the end of the slide groove to be fitted into the binding groove, thereby fixing the head portion and the handle portion.
본 발명은 다른 실시 예로, 상기 고정편에 자석을 구비하고, 상기 자석이 마주보는 면의 결착홈에는 금속편을 구비하는 것이다. 이러한 구성은 고정편이 슬라이드홈의 끝부분에 도착하며, 자석이 금속편을 당기게 됨으로써 자동으로 헤드부가 회전하도록 하여 사용의 편의성을 도모할 수 있다. In another embodiment of the present invention, a magnet is provided on the fixing piece, and a metal piece is provided on a binding groove of a surface facing the magnet. In such a configuration, the fixed piece arrives at the end of the slide groove, and the magnet is pulled to the metal piece, so that the head is automatically rotated to facilitate the use.
첨부된 도 9는 본 발명의 또 다른 실시 예를 나타낸 것이다. 9 shows another embodiment of the present invention.
이 실시 예는 헤드부(200)와 핸들부(100) 각각에 동일한 두께의 돌출연장부(162)(262)를 구비하고, 헤드부에는 결합돌기(260)를 구비하고, 핸들부에는 이에 대응하는 결합홈(262)을 형성하여 서로 결합되도록 하는 것이다. In this embodiment, the head portion 200 and the handle portion 100 are provided with protruding extension portions 162 and 262 of the same thickness, respectively, and the head portion is provided with engaging projections 260, corresponding to the handle portion. The coupling grooves 262 are formed to be coupled to each other.
여기서 결합홈과 결합돌기는 동일한 모양으로 구성되는 것은 당연하다. It is natural that the coupling groove and the coupling protrusion are configured in the same shape.
첨부된 도 10 내지 14는 본 발명의 또 다른 실 시예를 나타낸 것이다. 10 to 14 of the accompanying drawings shows another embodiment of the present invention.
이 실시 예의 칫솔은 핸들부(100)와, 헤드부(200)로 구성되고, 각각은 생분해성 조성물로 성형된다. The toothbrush of this embodiment is composed of a handle portion 100 and a head portion 200, each of which is molded from a biodegradable composition.
상기 헤드부(200)는, 베이스부(201)와 이 베이스부에 심어지는 필라멘트(300)와 상기 베이스부의 후방으로 연장된 넥크부(203)가 갖추어진 구성이다. The head portion 200 is configured with a base portion 201, a filament 300 planted in the base portion, and a neck portion 203 extending rearward of the base portion.
상기 넥크부(203)에는 상기 핸들부가 끼워지는 조립공(202)이 형성되고, 이 조립공에 착탈부(400)가 구비되는 것이다. An assembly hole 202 in which the handle portion is fitted is formed in the neck portion 203, and a detachable portion 400 is provided in the assembly hole.
상기 핸들부(100)는, 측 단면이 원형, 사각 또는 타원 또는 기하학적 형상 등 여러 형태로 구성될 수 있고, 색상 또한 다양한 색상이 선택될 수 있다. The handle portion 100 may be configured in various forms, such as a circular, square, elliptical, or geometrical shape, and various colors may be selected.
상기 핸들부(100)의 선단에는 상기 조립공(202)에 끼워지는 끼움부(102)가 구비되고, 이 끼움부(102)의 상면에는 후술하는 착탈부(400)의 걸림이 끼워지는 걸림 고리(104)가 형성된 구성이다. A fitting portion 102 fitted to the assembly hole 202 is provided at the front end of the handle portion 100, and a hooking ring (in which the hooking of the detachable portion 400 described later is fitted on the upper surface of the fitting portion 102) 104) is formed.
또한 상기 끼움부(102)의 양측면에는 가이드 돌기(106)가 돌출되며, 상기 헤드부(200)의 조립공(202) 양측면에는 이 가이드돌기(106)가 끼워져 이동을 안내하며, 사용 중 흔들림을 방지할 수 있는 요홈(206)이 형성된 구성이다. In addition, guide projections 106 are projected on both sides of the fitting portion 102, and the guide projections 106 are fitted on both sides of the assembly hole 202 of the head portion 200 to guide movement and prevent shaking during use. The concave groove 206 can be formed.
한편, 상기 착탈부(400)는 핸들부와 헤드부가 조립, 분리되도록 하는 것으로, 누름부재(410)와, 이 누름부재의 이동을 안내하는 안내부재(420)와, 상기 걸림고리(104)가 걸어지는 착탈고리(440)와, 이 착탈고리를 탄력 지지하는 스프링(430)으로 구성된다. On the other hand, the detachable portion 400 is to be assembled and separated the handle portion and the head portion, the pressing member 410, a guide member 420 for guiding the movement of the pressing member, and the hook 104 It consists of a detachable ring 440 to be hung, and a spring 430 to elastically support the detachable ring.
상기 착탈부(400)의 안내부재(420)는, 헤드부의 저면 다시 말해 필라멘트(300)의 대향측에 구비되어 누름부재의 이동을 안내하고, 상기 누름부재의 내측에 상기 착탈고리가 접착되어 함께 이동하는 구성이다. The guide member 420 of the detachable portion 400 is provided on the bottom surface of the head portion, that is, on the opposite side of the filament 300 to guide the movement of the pressing member, and the detachable ring is attached to the inside of the pressing member together. It is a moving configuration.
상기 착탈고리(440)는 도면과 같이 조립공의 벽면에 형성된 가이드 구멍(204)에 끼워져 이동하며, 상기 스프링(430)은 착탈고리(440)를 탄력 지지한다. The detachable ring 440 is inserted into the guide hole 204 formed on the wall surface of the assembler as shown in the drawing, and the spring 430 elastically supports the detachable ring 440.
생분해성 조성물Biodegradable composition
본 발명에 따른 생분해성 조성물은, 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로, 폴리락틱산 1 내지 20중량부; 물성계량제 5 내지 20중량부; 윤활제 1 내지 10중량부; 및 무기연마제 1 내지 15중량부를 포함한다.The biodegradable composition according to the present invention, based on 100 parts by weight of the biodegradable aliphatic polyester polymer, 1 to 20 parts by weight of polylactic acid; 5-20 parts by weight of a property metering agent; 1 to 10 parts by weight of lubricant; And 1 to 15 parts by weight of an inorganic polishing agent.
본 발명에 따른 생분해성 지방족 폴리에스테르계 고분자는 미생물에 의한 생분해는 잘 일어나지만, 기계적 물성 및 열적물성이 낮아 다양한 응용분야에서 폴리에틸렌(PE)과 같은 범용성 고분자를 대체하기에 한계가 있지만, 일회용 혹은 단기 사용한 후 폐기되는 여러 응용분야에서 비분해성인 범용성 고분자의 대체제로 사용되고 있다.The biodegradable aliphatic polyester-based polymer according to the present invention has good biodegradation by microorganisms, but has low mechanical properties and low thermal properties, and thus has limitations in replacing general-purpose polymers such as polyethylene (PE) in various applications. It is used as a substitute for a non-degradable general-purpose polymer in various applications that are discarded after short-term use.
바람직한 생분해성 지방족 폴리에스테르계 고분자는 PBS(polybutylene succinate), PCL(polycaprolactone), PBA[poly(butylene adipate)], PBAT(polybutylene adipate-co-terephthalate) 또는 이들로부터 선택된 적어도 하나 이상의 혼합물인 것을 포함하는 것이 좋다.Preferred biodegradable aliphatic polyester polymers include those containing polybutylene succinate (PBS), polycaprolactone (PCL), poly(butylene adipate) (PBA), polybutylene adipate-co-terephthalate (PBAT), or a mixture of at least one selected from them. It is good.
본 발명에 따른 생분해성 조성물을 구성하는 생분해성 지방족 폴리에스테르계 고분자 외 나머지 성분들의 함량은 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 한다.The content of the remaining components other than the biodegradable aliphatic polyester-based polymer constituting the biodegradable composition according to the present invention is based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer.
본 발명에 따른 폴리락틱산(PLA, polylactic acid)은 생분해성 조성물에 탄성을 제공하는 동시에, 그 자체로 생분해성을 갖는다.The polylactic acid (PLA) according to the present invention provides elasticity to the biodegradable composition, and has biodegradability by itself.
바람직한 폴리락틱산의 사용량은 사용자의 선택에 따라 변경 가능하지만, 추천하기로는 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 1 내지 20중량부인 것이 좋다.The preferred amount of polylactic acid can be changed according to the user's choice, but is recommended to be 1 to 20 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
또한, 본 발명에 따른 물본 발명에 따른 물성계량제는 인성, 즉 강도는 높지만 신장률이 부족해 쉽게 파단되는 생분해성 지방족 폴리에스테르계 고분자의 특성을 보완하기 위해 사용된 것으로서, 이러한 목적을 갖는 당업계의 통상적인 물성계량제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 디에틸렌 글리콜로 얻어지는 2가 알코올 또는 글리세롤, 트리메틸올 프로판으로부터 얻어지는 3가 알코올과 숙신산, 아디핀산으로부터 얻어지는 2가 산 또는 2가 산의 무수물 형태로부터 축중합에 의해 제조되는 것을 사용하는 것이 좋지만, 추천하기로는 중량 평균 분자량이 50,000 내지 150,000Da이며, 용융지수 20 내지 30g/10min인 2가 알코올, 3가 알코올, 글리세롤, 숙신산, 아디핀산 또는 이들로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋다.성계량제는 필요에 따라 폴리카프로락톤을 단독 및/또는 부가적으로 더 사용할 수 있다.In addition, the water metering agent according to the present invention is used to supplement the properties of a biodegradable aliphatic polyester-based polymer that is easily fractured due to its toughness, that is, a high strength but lacks elongation. As long as it is a general property-metering agent, any of them may be used, but divalent alcohol or glycerol obtained from diethylene glycol, trihydric alcohol obtained from trimethylol propane, succinic acid, or divalent acid obtained from adipic acid It is recommended to use those produced by condensation polymerization from the anhydride form of, but it is recommended that the weight average molecular weight is 50,000 to 150,000 Da, and that the melting index is 20 to 30 g/10min dihydric alcohol, trihydric alcohol, glycerol, succinic acid, adip It is preferable to use a finic acid or a mixture of at least one selected from these. [0055] The polymeter may be used alone and/or additionally, polycaprolactone, if necessary.
바람직한 폴리카프로락톤은 분자량이 30,000 내지 60,000Da이고, 용융지수는 20 내지 30g/10min이며, 융점은 58 내지 60℃인 것을 사용하는 것을 추천한다. The preferred polycaprolactone has a molecular weight of 30,000 to 60,000 Da, a melt index of 20 to 30 g/10min, and a melting point of 58 to 60°C is recommended.
본 발명에 따른 물성계량제의 사용량은 사용자의 선택에 따라 변경 가능하지만, 바람직하게는 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 5 내지 20중량부인 것이 좋다.The amount of the physical property metering agent according to the present invention can be changed according to the user's choice, but preferably 5 to 20 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer.
본 발명에 따른 윤활제는 생분해성 조성물을 이용한 핸들부, 헤드부 또는 칫솔모의 윤활성을 향상시키기 위한 것으로서, 이러한 목적을 위해 당업계의 통상적인 윤활제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 장시간 동안의 방사시 친유성 성분이 증가하기 때문에 분자내 친수성 성분과 친유성 성분의 비율을 나타내는 HLB값(Hydrophile-Lipophile balance value)이 7.0 내지 16.0의 범위인 지방산 에스테르, 특정적으로 글리세린 지방산 에스테르, 솔비탄 지방산 에스테르, 피리독신 지방산 에스테르 또는 이들로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋다.The lubricant according to the present invention is for improving the lubricity of the handle part, the head part or the bristles using the biodegradable composition, and for this purpose, any conventional lubricant in the art may be used, but preferably for a long time Since the lipophilic component increases during spinning, the fatty acid ester having a HLB value (Hydrophile-Lipophile balance value) in the range of 7.0 to 16.0, specifically glycerin fatty acid ester, sorbitan, indicates the ratio of the hydrophilic component and the lipophilic component in the molecule. It is preferred to use fatty acid esters, pyridoxine fatty acid esters or mixtures of at least one selected from them.
본 발명에 따른 윤활제의 사용량은 사용자의 선택에 따라 변경 가능하지만, 바람직하게는 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 1 내지 10중량부인 것이 좋다.The amount of the lubricant according to the present invention can be changed according to the user's choice, but preferably 1 to 10 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
본 발명에 따른 무기연마제는 생분해성 모노필라멘트 조성물의 강성도와 굴곡복원률 특성을 개선함과 동시에 세정력을 향상시키기 위한 것으로서, 이러한 목적을 갖는 무기연마제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 치약 구성 성분으로 통상 사용하는 이산화규산(실리카), 인산칼슘, 탄산칼슘, 무수규산, 수산화알루미늄 또는 이들로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋다.The inorganic abrasive according to the present invention is intended to improve the stiffness and flexural restoration properties of the biodegradable monofilament composition and at the same time improve the cleaning power, and any inorganic abrasive having this purpose may be used, but preferably toothpaste composition As a component, it is preferable to use silicic acid (silica), calcium phosphate, calcium carbonate, silicic anhydride, aluminum hydroxide, or a mixture of at least one selected from these.
이때, 상기 무기연마제의 평균입자크기는 수 나노미터 내지 수 마이크로미터, 바람직하게는 10nm 내지 100㎛의 크기를 갖는 것이 좋다.At this time, the average particle size of the inorganic abrasive is preferably several nanometers to several micrometers, preferably 10nm to 100㎛.
본 발명에 따른 무기연마제의 사용량은 사용자의 선택에 따라 변경 가능하지만, 바람직하게는 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 1 내지 15중량부인 것이 좋다.The amount of the inorganic abrasive according to the present invention can be changed according to the user's choice, but preferably 1 to 15 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
한편, 본 발명에 따른 생분해성 모노필라멘트는 하기의 특정 양태의 부가물을 1종 또는 1종 이상 더 포함할 수 있다.Meanwhile, the biodegradable monofilament according to the present invention may further include one or more types of adducts of the following specific embodiments.
특정 양태로서, 본 발명에 따른 생분해성 모노필라멘트 조성물은 인체에 무해한 천연 유제로서, 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 1 내지 15중량부의 식품첨가제를 더 포함할 수 있다.As a specific aspect, the biodegradable monofilament composition according to the present invention is a natural emulsion harmless to the human body, and may further include 1 to 15 parts by weight of a food additive based on 100 parts by weight of the biodegradable aliphatic polyester polymer.
여기서, 상기 식품 첨가제는 특정적으로 칫솔모 등의 제품으로 제작되는 경우, 집속성은 물론 표면에 우수한 평활성을 부여하여 매끄러운 상태를 유지시켜 잇몸이 긁히는 일이 없도록 할 수 있다.Here, when the food additive is specifically made of a product such as a bristle, it is possible to prevent the gums from being scratched by maintaining a smooth state by imparting excellent smoothness to the surface as well as focusing properties.
또한, 상기 식품첨가제는 모노필라멘트를 제조하기 위한 인발 과정에서 천연유제가 필라멘트 표면으로 흘러나오고, 이 상태에서 열처리가 이루어짐으로써, 강도 및 경도 향상은 물론 우수한 평활성을 제공하게 된다. In addition, the food additive is a natural emulsion flows out to the filament surface during the drawing process for manufacturing the monofilament, and heat treatment is performed in this state, thereby improving strength and hardness as well as providing excellent smoothness.
바람직한 식품첨가제는 코코넛, 야자, 콩, 카카오피 등에서 추출하는 천연 유제 또는 이들 천연 유제로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋다.Preferred food additives are natural emulsions extracted from coconut, palm, soybean, cacao, etc., or at least one mixture selected from these natural emulsions.
다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 조성물의 공극을 치밀하게 하고 수분의 방출을 방지함으로써 강도를 향상시키기 위하여 나트륨벤토나이트를 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 1 내지 10중량부로 더 포함할 수 있다.In another specific aspect, the biodegradable composition according to the present invention is 1 to 100 parts by weight of sodium bentonite based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer in order to improve the strength by densifying the pores of the biodegradable composition and preventing the release of moisture. It may further include 10 parts by weight.
상기 나트륨벤토나이트는 많은 양의 물을 흡수해 원래 부피의 여러 배로 팽창되며 겔과 같은 상태가 되어 조성물의 공극을 치밀하게 매우게 되어 수분의 방출을 방지하고 강도를 향상시켜 균열방지에 기여하게 된다.The sodium bentonite absorbs a large amount of water, expands several times the original volume, becomes a gel-like state, and densely fills pores of the composition, thereby preventing the release of moisture and improving strength, thereby contributing to crack prevention.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 모노필라멘트 조성물은 셀프 레벨링(자기충전성능)을 개선하기 위하여 스타치에테르(Starch ether)를 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 3중량부 더 포함할 수 있다.In another specific embodiment, the biodegradable monofilament composition according to the present invention is 0.1 to 3 based on 100 parts by weight of starch ether as a biodegradable aliphatic polyester polymer to improve self-leveling (self-charging performance). It may further include parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 모노필라멘트 조성물의 점도를 조절하기 위하여 디페닐메탄디이소시아네이트를 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 2중량부 더 포함할 수 있다.As another specific aspect, the biodegradable composition according to the present invention further comprises 0.1 to 2 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer of diphenylmethane diisocyanate to control the viscosity of the biodegradable monofilament composition. can do.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 1 내지 5중량부로 마그네슘 카보네이트(magnesium carboneate)를 더 포함할 수 있는데, 마그네슘 카보네이트는 백색이면서 가볍고 부수러지기 쉬운 물질로서 화장품의 원료로도 사용되는데 마그네슘 카보네이트가 생분해성 모노필라멘트 조성물에 포함되면 생분해성 모노필라멘트 조성물의 결정화도를 증대하여 강성, 투명성 및 광택성 등을 향상시킬 뿐만 아니라, 생분해성 모노필라멘트 조성물 pH도 조절하는 이중의 기능을 부여하게 되는 것이다.As another specific aspect, the biodegradable composition according to the present invention may further include 1 to 5 parts by weight of magnesium carbonate (magnesium carboneate) based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer, the magnesium carbonate being white and light As a material that is easy to break, it is also used as a raw material for cosmetics. When magnesium carbonate is included in the biodegradable monofilament composition, it increases the crystallinity of the biodegradable monofilament composition to improve rigidity, transparency, and gloss, as well as biodegradable mono It is to give the dual function of adjusting the pH of the filament composition.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 모노필라멘트 조성물의 분산성을 향상시키기 위하여 스테아르산을 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 2중량부 더 포함할 수 있다.As another specific aspect, the biodegradable composition according to the present invention may further include 0.1 to 2 parts by weight based on 100 parts by weight of stearic acid based on the biodegradable aliphatic polyester polymer to improve dispersibility of the biodegradable monofilament composition. have.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 조성물의 보습력 및 방부력 향상을 위하여 1,3-프로판 디올을 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 3중량부 더 포함할 수 있는데 1,3-프로판 디올은 낮은 점성과 흡수력이 있으며 끈적임이 적어 이를 생분해성 조성물에 포함하면 조성물의 보습력이 향상되고 방부제를 적게 사용하게 되는 잇점이 있어 방부력 또한 상승되게 되는 것이다.In another specific embodiment, the biodegradable composition according to the present invention is 0.1 to 3 parts by weight based on 100 parts by weight of 1,3-propane diol based on 100 parts by weight of the biodegradable aliphatic polyester polymer to improve the moisturizing and antiseptic power of the biodegradable composition. It may contain 1,3-propane diol has a low viscosity and absorbency, and is less sticky. When included in the biodegradable composition, the composition has an advantage of improving the moisturizing power and using less preservative, so that the preservative power is also increased.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 모노필라멘트 조성물이 토양속에서 분해될 때 토양속의 철 등과 같은 전이금속과 반응하여 생분해성 모노필라멘트 조성물의 탄소-탄소 결합을 쉽게 파괴할 수 있도록 하기 위하여 리놀레산을 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 2중량부 더 포함할 수 있다.In yet another specific embodiment, the biodegradable composition according to the present invention readily reacts with a transition metal such as iron in the soil when the biodegradable monofilament composition is decomposed in the soil to easily break the carbon-carbon bond of the biodegradable monofilament composition. In order to be able to contain linoleic acid may further include 0.1 to 2 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 조성물이 자외선에 의한 광산화반응(Photooxidation)을 방지하기 위하여 하이드록시벤조피논(Hydroxybenzophenone)을 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 3중량부 더 포함할 수 있다.As another specific aspect, the biodegradable composition according to the present invention is based on 100 parts by weight of a biodegradable aliphatic polyester-based polymer based on hydroxybenzopinone (Hydroxybenzophenone) in order to prevent the photodegradation of the biodegradable composition by UV light 0.1 to 3 parts by weight may be further included.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 지방족 폴리에스테르계 고분자와 폴리락틱산간의 상용성을 향상시키기 위하여 폴리비닐알콜을 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 3중량부 더 포함할 수 있다.As another specific aspect, the biodegradable composition according to the present invention is 0.1 to 100 parts by weight of polyvinyl alcohol based on 100 parts by weight of the biodegradable aliphatic polyester polymer to improve the compatibility between the biodegradable aliphatic polyester polymer and polylactic acid. It may further include 3 parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 모노필라멘트 조성물은 지방족 폴리에스테르계 고분자의 구조를 파괴시켜 가소화를 향상시키기 위하여 우레아와 명반화합물이 1;3의 중량비로 혼합된 우레아 및 명반 혼합물을 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있는데, 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1부 이하를 사용할 경우 목적한 효과를 얻을수 없고, 3중량부를 초과하면 타원료에 악영향을 미쳐서 최종제품의 기계적인 물성이 저하된다.As another specific aspect, the biodegradable monofilament composition according to the present invention comprises a mixture of urea and alum in which a urea and alum compound are mixed in a weight ratio of 1 to 3 to improve plasticization by destroying the structure of the aliphatic polyester polymer. It may further include 0.1 to 3 parts by weight based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer. When using 0.1 parts or less based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer, the desired effect cannot be obtained, and 3 parts by weight Exceeding wealth adversely affects other raw materials, thereby deteriorating the mechanical properties of the final product.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 조성물의 인장강도, 점탄성, 냉각성 등을 향상시키기 위하여 3차-부틸퍼벤조에이트를 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 2중량부 더 포함할 수 있다.As another specific aspect, the biodegradable composition according to the present invention is 0.1 based on 100 parts by weight of a biodegradable aliphatic polyester-based polymer of tert-butyl perbenzoate in order to improve tensile strength, viscoelasticity, coolability, etc. of the biodegradable composition. It may further include to 2 parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 조성물이 쉽게 부서지거나 찢어지는 현상을 없애고, 가공성을 향상시키기 위하여 디벤조일 퍼옥사이드(Dibenzoyl peroxide)를 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 3중량부 더 포함할 수 있다.As another specific aspect, the biodegradable composition according to the present invention removes the phenomenon of easily breaking or tearing the composition, and dibenzoyl peroxide is used as a biodegradable aliphatic polyester-based polymer 100 parts by weight to improve processability. It may further include 0.1 to 3 parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 생분해성 조성물은 생분해성 모노필라멘트 조성물의 흐름성을 향상시키기 스테아르산 칼슘을 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로 0.1 내지 2중량부 더 포함할 수 있다.As another specific aspect, the biodegradable composition according to the present invention may further include 0.1 to 2 parts by weight based on 100 parts by weight of calcium stearate to improve the flowability of the biodegradable monofilament composition based on 100 parts by weight of the biodegradable aliphatic polyester-based polymer. have.
다른 실시 예로 본 발명은 바이오 매스를 이용한 수지 조성물로 구성될 수도 있다. 여기서 바이오 매스를 이용한 수지 조성물은, 고분자 수지 5 내지 70중량%, 바이오매스 20 내지 70중량%, PBAT, PBS, PBAT/PBS 중합체 또는 이들의 혼합물 2 내지 20중량%, 생분해성 수지 2 내지 20중량%, 탄산칼슘 2 내지 10중량%, 계면활성제 1 내지 10중량%, 이형제 1 내지 5중량%, 안정제 1 내지 5중량%, 및 바인더 1 내지 5중량%를 포함하는 바이오매스를 이용한 수지 조성물을 제공한다.In another embodiment, the present invention may be composed of a resin composition using biomass. Here, the resin composition using biomass is 5 to 70% by weight of polymer resin, 20 to 70% by weight of biomass, 2 to 20% by weight of PBAT, PBS, PBAT/PBS polymer or a mixture thereof, 2 to 20% by weight of biodegradable resin %, 2 to 10% by weight of calcium carbonate, 1 to 10% by weight of a surfactant, 1 to 5% by weight of a release agent, 1 to 5% by weight of a stabilizer, and a resin composition using a biomass comprising 1 to 5% by weight of a binder do.
바람직하기로, 본 발명의 바이오 매스를 이용한 수지 조성물은, 고분자 수지로서 폴리프로필렌 5 내지 70중량%, 바이오매스로서 셀룰로스 20 내지 70중량%, PBAT 2 내지 20중량%, 생분해성 수지로서 폴리유산 2 내지 20중량%, 탄산칼슘 2 내지 10중량%, 계면활성제로서 암모늄 라우릴 설페이트 1 내지 10중량%, 이형제로서 스테아르산아연 1 내지 5중량%, 안정제로서 펙틴 1 내지 5중량%, 및 셀룰로우스계 바인더 1 내지 5중량%를 포함한다. Preferably, the resin composition using the biomass of the present invention is 5 to 70% by weight of polypropylene as the polymer resin, 20 to 70% by weight of cellulose as the biomass, 2 to 20% by weight of PBAT, and polylactic acid 2 as the biodegradable resin. To 20% by weight, 2 to 10% by weight of calcium carbonate, 1 to 10% by weight of ammonium lauryl sulfate as a surfactant, 1 to 5% by weight of zinc stearate as a release agent, 1 to 5% by weight of pectin as a stabilizer, and cellulose System binder 1 to 5% by weight.
여기서 상기 바이오 매스는 재생 가능한 유기자원 유래의 물질을 함유하며, 화학적 또는 생물학적으로 합성되어 고분자 재료로 사용될 수 있어 친환경적인 것으로서, 당업계의 통상적인 바이오매스라면 특별히 한정되지 않지만, 바람직하게는 식물계/동물계 바이오매스; 천연섬유, 셀룰로스, 리그노 셀룰로스, 전분, 디엔계 고분자와 중합반응하여 바이오매스 탄성체로 제조된 식물성 오일의 지방산, 해조류 또는 이들의 혼합물을 사용하는 것이 좋지만, 추천하기로는 천연섬유, 셀룰로스, 리그노셀룰로스, 전분, 식물성 오일의 지방산, 해조류 또는 이들의 혼합물을 사용하는 것이 좋다.Here, the biomass contains a material derived from a renewable organic resource, and is chemically or biologically synthesized and can be used as a polymer material, which is environmentally friendly. Animal biomass; It is recommended to use fatty acids, seaweeds, or mixtures of vegetable oils made of biomass elastomers by polymerizing with natural fibers, cellulose, ligno cellulose, starch, and diene polymers, but natural fibers, cellulose, and ligno are recommended. Cellulose, starch, fatty acids of vegetable oils, seaweeds or mixtures thereof are preferred.
또한 본 발명에 따른 바이오매스는 바이오매스 수지, 바이오폴리머로 지칭될 수 있지만, 본 발명의 용이한 설명을 위해, 상기 바이오매스 수지 또는 바이오폴리머 모두를 바이오매스로 통칭하여 지칭하기로 한다.In addition, although the biomass according to the present invention may be referred to as a biomass resin or biopolymer, for ease of description of the present invention, all of the biomass resin or biopolymer will be referred to collectively as biomass.
액상 치약Liquid toothpaste
본 발명에 따른 액상 치약은 상기 필라멘트에 도포되는 것으로, 이 액상 치약은 알란토민을 주성분으로, 습윤제, 감미제, 조절제, 보존제, 산화방지제, 기포제, 기용제, 착향제, 착색제 그리고 에탄올 96%의 용제가 혼합되는 것이다.The liquid toothpaste according to the present invention is applied to the filament, and the liquid toothpaste has allantoin as a main component, a wetting agent, a sweetener, a regulator, a preservative, an antioxidant, a foaming agent, a solvent, a flavoring agent, a coloring agent, and a solvent of 96% ethanol Is mixed.
바람직한 치약 사용량은 칫솔 1개에 대하여 2 내지 10g이 도포되며, 5g이 도포하는 것이 가장 좋다.The preferred amount of toothpaste is 2 to 10 g applied to one toothbrush, and 5 g is best applied.
본 발명에 따른 상기 감미제는 혀에 닫는 미감을 좋게 하는 것으로, 자일리톨, 사카린나트륨수화물, 에리스리톨, 디히드로칼콘, 글리신, D-페닐알라닌 중 적어도 어느 또는 그 이상의 혼합물이 사용되며, 본 발명에서는 사카린나트륨수화물 자일리톨 중 하나 또는 2가지 모두가 포함되는 것이 가장 좋다, The sweetener according to the present invention is to improve the aesthetics that close to the tongue, and a mixture of at least one or more of xylitol, sodium saccharinate, erythritol, dihydrochalcone, glycine, and D-phenylalanine is used, and in the present invention, saccharin sodium hydrate It is best to include one or both of xylitol,
상기 습윤제와, pH조절제는 당 업계의 통상적인 습윤제 및 조절제라면 어떠한 것을 사용하여도 무방하지만 바람직하게는 습윤제로 글리세린, 조절제로는 구연산과 시트로산나트륨수화물이 좋다. The wetting agent and the pH adjusting agent may be any conventional wetting agent and adjusting agent in the art, but preferably, glycerin as the wetting agent and citric acid and sodium citrate hydrate are preferable as the wetting agent.
본 발명에 따른 보존제는 메틸파라벤이 사용되고, 황산화제는 아스코르브산이 사용된다. 물론 상기 보존제와 황산화제는 치약에 통상적으로 사용되는 것이 선택될 수 있음은 당연한 것이다. The preservative according to the present invention is methyl paraben, and the sulfate agent is ascorbic acid. Of course, it is natural that the preservative and the sulfate agent may be selected as those commonly used in toothpaste.
기포제는 라우릴황산나트륨이 바람직하며, 가용화제는 폴리옥시에틸렌경화피마자유를 사용한다. The foaming agent is preferably sodium lauryl sulfate, and the solubilizing agent is polyoxyethylene cured castor oil.
본 발명에 따른 착향제는 과일 및 식물 추출물 등의 천연 추출물과 치약에 사용되는 통상의 착향제가 사용되며, 바람직하게는 박하유, 레몬민트향, 오렌지유, 유칼리유, L-멘톨 중 적어도 하나 또는 그 이상을 사용한다. The flavoring agent according to the present invention is a natural flavoring agent used in natural extracts such as fruit and plant extracts and toothpaste, and preferably at least one of peppermint oil, lemon mint flavor, orange oil, eucalyptus oil, and L-menthol, or Use more.
본 발명에 따른 액상 치약은, 알란토인 100중량부에 대하여 습윤제 4,000 내지 6,000중량부, 감미제 150 내지 250중량부, 습윤제 4,000 내지 5,000 중량부, 조절제 120 내지 130 중량부, 보존제 130 내지 160 중량부, 산화방지제 5 내지 15 중량부, 기포제 8,000 내지 10,000 중량부, 가용화제 2,800 내지 3,500 중량부 및 착향제 5 내지 15 중량부, 착색제 5 내지 15 중량부 및 용제 150 내지 250중량부가 혼합되는 것이다. The liquid toothpaste according to the present invention, with respect to 100 parts by weight of allantoin, 4,000 to 6,000 parts by weight of a wetting agent, 150 to 250 parts by weight of a sweetener, 4,000 to 5,000 parts by weight of a wetting agent, 120 to 130 parts by weight of a control agent, 130 to 160 parts by weight of a preservative, oxidation 5 to 15 parts by weight of the preventive agent, 8,000 to 10,000 parts by weight of the foaming agent, 2,800 to 3,500 parts by weight of the solubilizer and 5 to 15 parts by weight of the flavoring agent, 5 to 15 parts by weight of the colorant, and 150 to 250 parts by weight of the solvent are mixed.
바람직하기로 본 발명은 알란토인 100중량부를 기준으로, 글리세린 5,000중량부, 사카린나트륨수화물 200 중량부, 구연산 30중량부, 시트르산나트륨수화물 100중량부, 메틸파라벤 150중량부, 아스코르부산 10중량부, 라우릴황산나트륨 9,000 중량부, 폴리옥시에틸렌경화피마자유 3,300중량부, 박하유 3중량부, 레몬민트향 3중량부, 오렌지유 5중량부, 착색제로 청색 1호 10중량부, 에탄올 200중량부를 포함하는 액상 치약을 구성하고, 이 액상 치약을 하기 공급기에 투입하여 필라멘트에 분사하여 도포하는 것이다. Preferably, the present invention is based on 100 parts by weight of allantoin, 5,000 parts by weight of glycerin, 200 parts by weight of sodium saccharinate, 30 parts by weight of citric acid, 100 parts by weight of sodium citrate, 150 parts by weight of methylparaben, 10 parts by weight of ascorbic acid, Sodium lauryl sulfate 9,000 parts by weight, 3,300 parts by weight of polyoxyethylene cured castor oil, 3 parts by weight of peppermint oil, 3 parts by weight of lemon mint flavor, 5 parts by weight of orange oil, 10 parts by weight of blue No. 1 as colorant, 200 parts by weight of ethanol The liquid toothpaste is constituted, and the liquid toothpaste is put into the following feeder and sprayed onto the filament to be applied.
본 발명에 따른 상기 액상 치약은 탱크에 투입된 상태에서, 이 분사 노즐을 통해 자동으로 분사되는 것이다. The liquid toothpaste according to the present invention is automatically injected through this injection nozzle in a state in which it is injected into a tank.
다시 말해 본 발명은 컨베이어(20)의 상부에 분사 노즐(30)을 구비하고, 이 분사 노즐(30)에 액상 치약 탱크와 연결되는 연결관(40)이 구비되고, 노즐의 상부에는 에어를 공급하는 펌프(미도시)가 연결되는 구성이다. In other words, the present invention is provided with a spray nozzle 30 on the top of the conveyor 20, the spray nozzle 30 is provided with a connecting pipe 40 connected to the liquid toothpaste tank, and supplying air to the top of the nozzle This is a configuration in which a pump (not shown) is connected.
상기 컨베이어(20)의 상면에는 헤드부가 끼워져 안착되는 안착부(50)가 등간격으로 설치된 구성이다. The top surface of the conveyor 20 has a configuration in which the head portion is fitted and seated portions 50 are seated at equal intervals.
이러한 구성의 본 발명은 펌프가 가동하여 분사 노즐에 에어를 공급하면 이 에어가 안착부에 끼워진 헤드부의 필라멘트에 분사되어 건조 및 세척이 이루어지도록 하고, 에어가 연속으로 분사되면 노즐 내부에 저압이 형성되어 탱크의 액상 치약을 흡인하고, 흡인된 치약이 사방으로 분사되며 치약에 도포되는 것이다. In the present invention of this configuration, when the pump is operated to supply air to the injection nozzle, this air is sprayed onto the filament of the head part fitted to the seating portion to be dried and washed, and when air is continuously sprayed, low pressure is formed inside the nozzle. It becomes a suction of the liquid toothpaste in the tank, and the aspirated toothpaste is sprayed in all directions and applied to the toothpaste.
본 발명은 칫솔에 관한 것으로, 일반 가정은 물론 야외에서 사용될 수 있으며, 생분해성 조성물로 성형되어 환경 오염에 부담이 없는 것이다.The present invention relates to a toothbrush, which can be used outdoors as well as in general homes, and is molded with a biodegradable composition so that there is no burden on environmental pollution.

Claims (12)

  1. 조립식 친환경 칫솔로써, As a prefabricated eco-friendly toothbrush,
    생분해성된 조성물로 성형된 헤드부와, 핸들부 그리고 상기 헤드부에 심어지는 필라멘트로 구성되고, Consists of a head portion molded from a biodegradable composition, a handle portion and a filament planted on the head portion,
    상기 헤드부와 핸들부는 끼워맞춤으로 조립되어 사용되고, 사용 후 헤드부를 분리하여 폐기하는 것을 포함하는 생분해성 조립식 친환경 칫솔. The head portion and the handle portion are assembled and used by fitting, and a biodegradable prefabricated eco-friendly toothbrush comprising separating and disposing the head portion after use.
  2. 친환경 칫솔로써, As an eco-friendly toothbrush,
    생분해성 조성물로 모노필라멘트를 성형하고, The monofilament is molded with a biodegradable composition,
    상기 모노필라멘트는 헤드부에 심은 상태에서 이 모노필라멘트에 액상 치약이 도포되며, The monofilament is a liquid toothpaste applied to the monofilament while being planted in the head portion,
    상기 헤드부와, 이 헤드부가 끼워지는 핸들부를 각각 별도로 성형하여 사용 시에는 결합하고, 사용 후에는 헤드부를 분리하여 폐기토록 하되, The head portion and the handle portion to which the head portion is fitted are separately molded to be combined when used, and after use, the head portion is separated and discarded.
    상기 헤드부와 핸들부는 생분해성 조성물로 성형된 것을 포함하는 생분해성 필라멘트에 치약이 도포된 친환경 칫솔. The head portion and the handle portion is an eco-friendly toothbrush coated with a toothpaste on a biodegradable filament comprising a molded with a biodegradable composition.
  3. 제 1항 또는 제 2항 있어서, According to claim 1 or 2,
    상기 핸들부에 상기 헤드부가 끼워지는 공간이 마련되고, 이 공간에 상기 헤드부가 걸려 고정될 수 있는 돌출부가 구비되고, 헤드부에는 이 돌출부가 끼워지는 요홈이 마련된 것을 포함하는 생분해성 조립식 친환경 칫솔. A space in which the head portion is fitted to the handle portion is provided, a protrusion portion that can be fixed to the head portion is provided in the space, and a head portion is provided with a groove into which the protrusion portion is fitted.
  4. 제 3항에 있어서, According to claim 3,
    상기 헤드부의 요홈이 형성된 부위의 내부가 빈공간으로 구성되어 탄력적으로 돌출부가 끼워지도록 하는 것을 포함하는 생분해성 조립식 친환경 칫솔. A biodegradable prefabricated eco-friendly toothbrush that includes an inside of a portion where the groove of the head portion is formed to be formed of an empty space so that a protrusion is elastically fitted.
  5. 제 1항 또는 제 2항에 있어서, The method according to claim 1 or 2,
    상기 헤드부와 핸들부 각각에 돌출 연장부를 구비되고, 헤드부에는 결합돌기를 구비하며, 핸드불에 이에 대응하는 결합홈이 형성된 것을 포함하는 생분해성 조립식 친환경 칫솔. A biodegradable prefabricated eco-friendly toothbrush comprising a protruding extension in each of the head portion and a handle portion, a coupling protrusion provided in the head portion, and a coupling groove corresponding to the handbulb.
  6. 제 1항 또는 제 2항 있어서, According to claim 1 or 2,
    상기 핸들부에 절개부를 구비하고, 헤드부에는 돌기를 구비하여 끼워맞춤으로 조립되도록 하는 것을 포함하는 생분해성 조립식 친환경 칫솔. A biodegradable prefabricated eco-friendly toothbrush comprising an incision in the handle portion and a protrusion in the head portion to be assembled by fitting.
  7. 제 1항 또는 제 2항에 있어서, The method according to claim 1 or 2,
    상기 헤드부와 핸들부는 일체로 성형되고, 이 헤드부에 모노필라멘트가 심어지고, 노모필라멘트에는 액상 치약이 도포되는 것을 포함하는 생분해성 조립식 친환경 칫솔. The head portion and the handle portion are integrally molded, a monofilament is planted on the head portion, and a biodegradable prefabricated eco-friendly toothbrush comprising a liquid toothpaste applied to the nomofilament.
  8. 제 1항 또는 제 2항에 있어서, The method according to claim 1 or 2,
    상기 헤드부에 구비되며, 누름부재를 누르면 착탈부재가 이동하며, 핸들부에 형성된 걸림고리를 걸어 고정시키거나 걸림을 해지하여 분리가 이루어지도록 하는 착탈부;가 구비된 것을 포함하는 생분해성 조립식 친환경 칫솔. It is provided on the head portion, the detachable member moves when the pressing member is pressed, and a detachable portion for fixing or releasing the locking hook formed on the handle portion to separate is made. toothbrush.
  9. 제 8항에 있어서, The method of claim 8,
    상기 헤드부에 핸들부가 끼워지는 조립공이 형성되고, 이 조립공의 벽면에 형성된 가이드구멍에 착탈고리가 끼워져 이동하는 것을 포함하는 생분해성 조립식 친환경 칫솔. A biodegradable prefabricated eco-friendly toothbrush comprising an assembly hole in which the handle portion is fitted to the head portion, and a detachable ring is fitted into the guide hole formed on the wall surface of the assembly hole.
  10. 제 8항에 있어서, The method of claim 8,
    상기 핸들부에 상기 조립공에 끼워지는 돌출부가 구비되고, 이 돌출부에 걸림고리가 형성되어 상기 착탈고리에 걸려 고정되도록 하는 생분해성 조립식 친환경 칫솔. A biodegradable prefabricated eco-friendly toothbrush that is provided with a protrusion fitted to the assembly hole in the handle portion, and a hooking ring is formed in the protrusion to be fixed to the detachable ring.
  11. 제 1항 또는 제 2항에 있어서, The method according to claim 1 or 2,
    상기 액상 치약은 알란토인 100중량부를 기준으로, 습윤제 4,000 내지 6,000중량부; 감미제 150 내지 250중량부; pH조절제 100 내지 150 중량부; 보존제 120 내지 160 중량부; 황산화제 3 내지 15 중량부; 기포제 8,000 내지 10,000 중량부; 가용화제 2,800 내지 3,500 중량부; 착향제 3 내지 15 중량부; 착색제 3 내지 15 중량부 및 용제 150 내지 250중량부가 혼합된 것을 포함하는 생분해성 조립식 친환경 칫솔. The liquid toothpaste is based on 100 parts by weight of allantoin, 4,000 to 6,000 parts by weight of the wetting agent; Sweeteners 150 to 250 parts by weight; pH adjusting agent 100 to 150 parts by weight; 120 to 160 parts by weight of a preservative; 3 to 15 parts by weight of a sulfate agent; Foaming agent 8,000 to 10,000 parts by weight; 2,800 to 3,500 parts by weight of solubilizer; Flavoring agent 3 to 15 parts by weight; A biodegradable prefabricated eco-friendly toothbrush comprising a mixture of 3 to 15 parts by weight of colorant and 150 to 250 parts by weight of solvent.
  12. 제 1항 또는 제 2항에 있어서,The method according to claim 1 or 2,
    상기 필라멘트와 헤드부, 핸들부를 성형하는 상기 생분성해성 조성물은 생분해성 지방족 폴리에스테르계 고분자 100중량부 기준으로, 폴리락틱산 1 내지 20중량부; 물성계량제 5 내지 20중량부; 윤활제 1 내지 10중량부; 및 무기연마제 1 내지 15중량부가 혼합된 것을 포함하는 생분해성 조립식 친환경 칫솔. The biodegradable composition for forming the filament, the head portion, and the handle portion includes 1 to 20 parts by weight of polylactic acid based on 100 parts by weight of a biodegradable aliphatic polyester polymer; 5-20 parts by weight of a property metering agent; 1 to 10 parts by weight of lubricant; And 1 to 15 parts by weight of an inorganic abrasive mixture.
PCT/KR2018/015303 2018-12-05 2018-12-05 Biodegradable and environment-friendly modular toothbrush WO2020116671A1 (en)

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KR10-2018-0154850 2018-12-05
KR1020180154851A KR102086746B1 (en) 2018-12-05 2018-12-05 Eco-friendly toothbrush with toothpaste on biodegradable filament
KR20180154850 2018-12-05
KR10-2018-0154851 2018-12-05

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022146273A1 (en) * 2020-12-31 2022-07-07 Ozcan And Ozcan Arastirma Gelistirme Ve Danismanlik Ltd. Sti. Biodegradable toothbrush with interchangable brush tip and interchangable interdental brush placed on the handle
WO2023275581A1 (en) * 2021-06-30 2023-01-05 Societe Industrielle De Matieres Plastiques Applicator device for applying a fluid or pasty cosmetic product, obtained by moulding a biomaterial, and associated biomaterial

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR940004928Y1 (en) * 1991-10-16 1994-07-23 주식회사 기아정기 Control device of tailgate for truck
KR20110096404A (en) * 2010-02-22 2011-08-30 박용태 Disposable toothbrush which is edible
KR101612430B1 (en) * 2015-04-03 2016-04-15 주식회사 브러시월드 Eco-friendly toothbrush
KR101759573B1 (en) * 2016-12-21 2017-07-20 주식회사 브러시월드 Eco-friendly toothbrush
KR101761198B1 (en) * 2016-04-25 2017-07-25 (주)수호천사엔젤 Disposable toothbrush coated liquid type toothpaate

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Publication number Priority date Publication date Assignee Title
KR940004928Y1 (en) * 1991-10-16 1994-07-23 주식회사 기아정기 Control device of tailgate for truck
KR20110096404A (en) * 2010-02-22 2011-08-30 박용태 Disposable toothbrush which is edible
KR101612430B1 (en) * 2015-04-03 2016-04-15 주식회사 브러시월드 Eco-friendly toothbrush
KR101761198B1 (en) * 2016-04-25 2017-07-25 (주)수호천사엔젤 Disposable toothbrush coated liquid type toothpaate
KR101759573B1 (en) * 2016-12-21 2017-07-20 주식회사 브러시월드 Eco-friendly toothbrush

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022146273A1 (en) * 2020-12-31 2022-07-07 Ozcan And Ozcan Arastirma Gelistirme Ve Danismanlik Ltd. Sti. Biodegradable toothbrush with interchangable brush tip and interchangable interdental brush placed on the handle
WO2023275581A1 (en) * 2021-06-30 2023-01-05 Societe Industrielle De Matieres Plastiques Applicator device for applying a fluid or pasty cosmetic product, obtained by moulding a biomaterial, and associated biomaterial

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