WO2020082339A1 - Graphene coating processing device - Google Patents

Graphene coating processing device Download PDF

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Publication number
WO2020082339A1
WO2020082339A1 PCT/CN2018/112123 CN2018112123W WO2020082339A1 WO 2020082339 A1 WO2020082339 A1 WO 2020082339A1 CN 2018112123 W CN2018112123 W CN 2018112123W WO 2020082339 A1 WO2020082339 A1 WO 2020082339A1
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Prior art keywords
workpiece
module
graphene
spraying
glue
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PCT/CN2018/112123
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French (fr)
Chinese (zh)
Inventor
陈英岳
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陈英岳
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Priority to PCT/CN2018/112123 priority Critical patent/WO2020082339A1/en
Publication of WO2020082339A1 publication Critical patent/WO2020082339A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C19/00Apparatus specially adapted for applying particulate materials to surfaces
    • B05C19/04Apparatus specially adapted for applying particulate materials to surfaces the particulate material being projected, poured or allowed to flow onto the surface of the work
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/184Preparation
    • C01B32/19Preparation by exfoliation

Definitions

  • the invention belongs to the technical field of graphene processing equipment, and in particular relates to a graphene coating processing device.
  • Graphene is a hexagonal two-dimensional carbon nanomaterial composed of carbon atoms with a honeycomb lattice. Due to its characteristic carbon atom lattice structure, graphene makes graphene have excellent optical, electrical, and mechanical properties, making graphene have important applications in materials science, micro-nano processing, energy, biomedicine, and drug delivery. prospect.
  • graphene is difficult to process on the surface of the workpiece as a coating because of its thin properties.
  • the mechanical peeling method is a method to obtain the thin layer material of graphene by using the friction and relative motion between the object and the graphene. This method is simple to operate, and the obtained graphene usually maintains a complete crystal structure, but the obtained sheet is small and the production efficiency is low.
  • the present invention provides a graphene coating processing device that can be used in large-scale industrial production, which can quickly produce graphene coating on the surface of the workpiece, thereby greatly improving the production efficiency of graphene application and reducing graphite The cost of ene-coated green tea.
  • the graphene coating processing device includes a rotating module, a glue spraying module, a spraying module, and a sticking module.
  • the rotating module is designed with a horizontal rotating shaft.
  • the rotating shaft is equipped with a ring-shaped workpiece.
  • the rotating shaft drives the workpiece to rotate.
  • the left side of the workpiece is equipped with a glue spray module.
  • the glue spray module is designed with a glue spray nozzle directly facing the surface of the workpiece.
  • a glue spray material is installed in the workpiece, the glue spray module sprays the atomized glue from the glue nozzle to the surface of the workpiece through a high-pressure air flow, the spray module is assembled at the lower part of the workpiece, and the spray module includes Facing the spray nozzle at the lower part of the workpiece, the spray module is equipped with graphene flakes in the spray module, and the graphene flakes are sprayed to the lower surface of the workpiece through the spray nozzle by the high-pressure air flow in the spray module;
  • a material brush is designed on the right side of the material nozzle, and the material brush is designed with bristles attached to the lower surface of the workpiece;
  • the adhesive module includes an output film, a waste film, a fixed runner, and an adjustment Runner, the output film is wrapped with adhesive tape, and the adhesive tape on the output film is wound from the fixed rotator and the adjusting rotator by being wound on the waste film, and the adhesive tape is adjusted from the fixed rotator and the rotator When the lower
  • the adjusting wheel is hinged to the fixed rotating shaft through an assembly plate.
  • a lower part of the spraying module is equipped with a pressurized tank, a pressurized air pump is installed in the pressurizing tank, a suction chamber is designed on the left and right sides of the spraying module, and the upper part of the suction chamber is provided with air intake
  • the mouth is facing the surface of the workpiece
  • the lower gas outlet of the suction chamber is connected to the inlet end of the pressurized air pump in the pressurized tank, and the outlet end of the pressurized air pump in the pressurized tank faces the spraying module Supply high pressure gas.
  • the upper part of the pressurizing box is designed with baffles located at the front and back positions of the spraying module.
  • the upper part of the pressurized tank is equipped with a bulk material chamber with an air inlet facing upward, and the bulk material chamber is connected to the air inlet of the pressurized air pump in the pressurized tank.
  • the spraying module includes a storage cavity, and an airflow cavity is designed at the lower part of the storage cavity, and both ends of the airflow cavity are respectively connected to the air outlet of the pressurization box and the spray nozzle, and the storage cavity
  • the lower part communicates with the upper part of the airflow chamber through a V-shaped groove
  • the storage chamber communicates with the intake end of the airflow chamber through a pipeline.
  • both the output film and the waste film are assembled on a horizontal rotating shaft that can be reversed forward and backward.
  • the graphene coating processing device mainly uses graphene sheet material as a raw material, and is used to coat a workpiece with an annular surface.
  • the workpiece is assembled on the rotating shaft of the rotating module, and the workpiece follows the rotation under the driving of the rotating shaft.
  • the glue spraying module sprays the rubber material on the surface of the workpiece through the glue nozzle, and The part of the rotating spraying rubber material rotates to the upper part of the spraying module.
  • the spraying module sprays the graphene on the surface of the workpiece rubber through the air flow containing graphene.
  • the workpiece of the spraying rubber part continues to rotate to the upper part of the brush
  • the graphite sheet can be evenly brushed to the surface of the workpiece rubber, and the excess graphene sheet can be brushed off.
  • the sheet part coated with graphene rotates to the lower part of the adhesive module, and the lower part of the adhesive module
  • the adhesive surface of the adhesive tape is attached to the surface of the graphene on the workpiece, and the graphene on the outer surface of the workpiece is peeled off, thereby obtaining a uniform thin layer of graphene. If a thinner layer or a single layer of graphene is needed, the peeling will be After the graphene rotates one circle, the peeling is performed until the desired thickness is peeled off.
  • the device is processed by an industrialized production method, and its production efficiency is greatly improved. At the same time, the device can not only be used to process a single layer of graphene coating, but also can be used to make multiple layers of graphene coating.
  • a layer of graphene is sprayed on the ring surface of the workpiece, continue on the workpiece graphene layer
  • the surface layer is subjected to the above operations again, and more glue layers and graphene superimposed material layers can be obtained on the workpiece surface, so that the workpiece surface coating has better electrical and physical properties.
  • FIG. 1 is a schematic diagram of the forward structure of the graphene coating processing device in operation.
  • FIG. 2 is a schematic structural diagram of a graphene coating processing device when discharging and collecting workpieces.
  • Figure 3 is a schematic diagram of the spray module.
  • the graphene coating processing device includes a rotating module 1, a glue spraying module 2, a spraying module 3, and a sticking module 4, and the rotating module 1 is designed with A horizontal rotating shaft, a ring-shaped workpiece 5 is assembled on the rotating shaft, the rotating shaft drives the workpiece 5 to rotate, and a glue spraying module 2 is mounted on the left side of the workpiece 5
  • the glue spray nozzle 21 is designed to face the surface of the workpiece 5, the glue spray material is contained in the workpiece, and the glue spray module 2 sprays the atomized glue from the glue spray nozzle 41 to the surface of the workpiece 5 through a high-pressure air flow.
  • the spraying module 3 is assembled on the lower part of the workpiece 5.
  • the spraying module 3 includes a spray nozzle 31 toward the lower part of the workpiece 5.
  • the spraying module 3 is equipped with graphene sheets and graphene sheets
  • a high-pressure airflow is used to spray the lower surface of the workpiece 5 through the spraying nozzle 31;
  • a material brush 6 is designed on the right side of the spraying nozzle 31, and the brush 6 is designed with bristles, the bristles Attached to the lower surface of the workpiece 5;
  • the adhesive module 4 includes an output film 41 and a waste film 42.
  • a tape is wound on the output film 41.
  • the tape on the output film 41 is wound from the fixed runner 43 and the adjusting runner 44 by being wound on the waste film On 42, the adhesive tape passes from the fixed runner 43 and the lower side of the adjusting runner 44 with the adhesive side down, and the upper part of the workpiece 5 is attached to the adhesive surface of the adhesive tape.
  • the graphene flakes described in this patent may use graphite powder or other graphite materials containing a multilayer graphene structure.
  • the graphene coating processing device mainly uses graphene sheet material as a raw material, and is used for coating processing on a workpiece 5 having an annular surface.
  • the workpiece 5 is assembled on the rotating shaft of the rotating module 1, and the workpiece 5 rotates following the rotation of the rotating shaft.
  • the glue spraying module 2 sprays the glue on the surface of the workpiece 5 through the glue nozzle 21
  • the part of the sprayed rubber material rotates to the upper part of the spraying module 3
  • the spraying module 3 sprays the graphene on the surface of the rubber material of the workpiece 5 through the air flow containing graphene, and the rubber material will directly Adhere to the column
  • the workpiece 5 sprayed with the rubber material continues to rotate to the upper part of the material brush 6, through the material brush 6, the graphite sheet can be evenly brushed to the surface of the workpiece 5 glue, and the excess graphene sheet material is brushed
  • the part of the sheet coated with graphene rotates to the lower part of the adhesive module 4
  • the adhesive surface of the adhesive tape at the lower part of the adhesive module 4 is attached to the surface of the graphene on the workpiece 5, and the surface of the workpiece 5
  • the graphene of the layer is peeled off to obtain a thin layer of
  • the graphene after the peeling is rotated once and then peeled off until the desired thickness is peeled off.
  • the device can be used not only to process a single layer of graphene coating, but also to make multiple layers of graphene coating. After spraying a layer of graphene on the annular surface of the workpiece 5, the graphene layer continues on the workpiece 5 After the above operation is performed again, more glue layers and graphene layers can be obtained on the surface of the workpiece 5, so that the surface coating of the workpiece 5 has better electrical and physical properties.
  • the adjusting rotating wheel 44 is hinged to the fixed rotating shaft 45 through an assembly plate.
  • the adhesive tape at the lower part of the adhesive module 4 is kept in a horizontal state and attached to the upper surface of the workpiece 5.
  • the fixed rotating shaft 45 is rotated to rotate the adjusting wheel 44 upward, so that the adhesive tape at the lower part of the adhesive module 4 is detached
  • the upper surface of the workpiece 5 can be easily removed from the rotating shaft of the rotating module 1 at this time, so that the workpiece can be replaced conveniently.
  • the lower part of the spraying module 3 is equipped with a pressurized tank 7, and a pressurized air pump is installed in the pressurized tank 7, and the left and right sides of the spraying module 3
  • a suction chamber 71 is designed.
  • the upper air inlet of the suction chamber 71 faces the surface of the workpiece 5.
  • the lower air outlet of the suction chamber 71 and the intake end of the pressurized air pump in the pressure box 7 Connected, the outlet end of the pressurized air pump in the pressurized tank 7 supplies high-pressure gas to the spraying module 3.
  • the pressurizing tank 7 can suck the graphene sheets that are not adhered to the front and back of the spray module 3 through the suction chamber 71, and these sheets can be pressed again by the pressurizing tank 7
  • the air pump is supplied to the spraying module 3 again for use, so that the use efficiency of the graphene material is higher.
  • the upper part of the pressurizing tank 7 is designed with baffles located at the front and rear positions of the spray module 3, the baffle at the front and rear positions of the pressurizing tank 7 and the suction chamber at the left and right positions 71 and the upper plate of the pressurizing tank 7 form a negative pressure chamber, and the upper part of the pressurizing tank 7 is equipped with a bulk material chamber 72 with an air inlet facing upward.
  • the bulk material chamber 72 and the pressurized air pump in the pressurizing tank 7 Connected to the suction port.
  • the negative pressure chamber formed in this way can better absorb the graphene material at the lower part of the workpiece 5, wherein the suction chambers 71 designed on the left and right are mainly used to absorb the graphene adhered on the surface of the workpiece 5, and the The bulk chamber 72 is mainly used to adsorb the graphene scattered in the negative pressure chamber during spraying, which can not only effectively prevent the graphene from drifting in the production space, but also make the overall use of graphene in the production process Higher efficiency, greatly reducing production costs.
  • the spraying module 3 When the spraying module 3 is specifically designed, as shown in FIGS. 1 and 3, it includes a storage chamber 32, and an airflow chamber 33 is designed at the lower part of the storage chamber 32, and both ends of the airflow chamber 33 are connected to The outlet end of the pressurized tank 7 and the spray nozzle 31, the lower part of the storage chamber 32 communicates with the upper part of the air flow chamber 33 through a V-shaped groove 34, and the storage chamber 32 communicates with the air flow chamber 33 through a pipeline The intake side is connected.
  • the storage cavity 32 is equipped with graphene sheets, and the graphene in the storage cavity 32 can fall into the airflow cavity 33 through the V-shaped groove 34, and the airflow passing through the airflow cavity 33 ,
  • the graphene sheet material is blown out from left to right, so that the graphene material is ejected from the nozzle 31 to the lower surface of the workpiece, the storage chamber 32 also passes through the pipeline and the inlet end of the airflow chamber 33 It is connected to ensure that the storage chamber 32 is in a positive pressure state, so that the graphene sheet material in the storage chamber 32 is ejected from the lower end of the V-shaped groove 34.
  • the output film 41 and the waste film 42 are assembled on a horizontal rotation shaft that can be reversed.
  • the adhesive of the adhesive tape be repeatedly adhered to the graphene sheet on the surface of the workpiece 5, so that the use efficiency of the adhesive tape is higher, and when the graphene sheet on the surface of the workpiece 5 has defects, it can be Graphene defect repairs make the coating produced by graphene sheets better.

Abstract

A graphene coating processing device, comprising a rotation module (1), an adhesive-spraying module (2), a material-spraying module (3), and a material-adhering module (4). The rotation module (1), by means of a rotation shaft, drives a workpiece (5) to rotate. The adhesive-spraying module (2) is assembled to the left side of the workpiece (5), and by means of a high-pressure airflow, sprays an atomized adhesive material from an adhesive-spraying nozzle (21) onto a surface of the workpiece (5). In the material-spraying module (3), a graphene material is sprayed onto the surface of a lower portion of the workpiece (5) by means of a material-spraying nozzle (31) and using a high-pressure airflow. The material-adhering module (4) comprises an output adhesive roll (41), a waste adhesive roll (42), a fixed rotating wheel (43), and an adjustable rotating wheel (44). Adhesive tape on the output adhesive roll (41) winds around the fixed rotating wheel (43) and the adjustable rotating wheel (44), and winds onto the waste adhesive roll (42). An upper portion of the workpiece (5) adheres to an adhesive surface of the adhesive tape. In the present device, a graphene coating can be rapidly produced on the surface of the workpiece (5), thereby improving production efficiency when graphene is used, and lowering production costs in graphene coating.

Description

石墨烯涂层加工装置Graphene coating processing device 技术领域Technical field
本发明属于石墨烯加工设备技术领域,具体涉及一种石墨烯涂层加工装置。The invention belongs to the technical field of graphene processing equipment, and in particular relates to a graphene coating processing device.
背景技术Background technique
石墨烯是由碳原子组成的六角型呈蜂巢晶格的二维碳纳米材料。石墨烯由于其特征的碳原子晶格组成结构,使得石墨烯具有优异的光学、电学、力学特性,使得石墨烯在材料学、微纳加工、能源、生物医学和药物传递等方面具有重要的应用前景。但是石墨烯由于其及其单薄的特性,很难以涂层的方式加工在工件的表面。其中机械剥离法是利用物体与石墨烯之间的摩擦和相对运动,得到石墨烯薄层材料的一种方法。这种方法操作简单,得到的石墨烯通常保持着完整的晶体结构,但是得到的片层小,生产效率低。Graphene is a hexagonal two-dimensional carbon nanomaterial composed of carbon atoms with a honeycomb lattice. Due to its characteristic carbon atom lattice structure, graphene makes graphene have excellent optical, electrical, and mechanical properties, making graphene have important applications in materials science, micro-nano processing, energy, biomedicine, and drug delivery. prospect. However, graphene is difficult to process on the surface of the workpiece as a coating because of its thin properties. Among them, the mechanical peeling method is a method to obtain the thin layer material of graphene by using the friction and relative motion between the object and the graphene. This method is simple to operate, and the obtained graphene usually maintains a complete crystal structure, but the obtained sheet is small and the production efficiency is low.
发明内容Summary of the invention
针对以上问题,本发明提供一种可以用于大批量工业生产的石墨烯涂层加工装置,可以快速在工件的表面生产出石墨烯涂层,从而大大提高石墨烯应用时的生产效率,降低石墨烯涂层的生茶成本。In view of the above problems, the present invention provides a graphene coating processing device that can be used in large-scale industrial production, which can quickly produce graphene coating on the surface of the workpiece, thereby greatly improving the production efficiency of graphene application and reducing graphite The cost of ene-coated green tea.
本发明解决其技术问题所采用的技术方案是:该石墨烯涂层加工装置包括旋转模块、喷胶模块、喷料模块、粘料模块,所述旋转模块上设计有水平的旋转轴,所述旋转轴上装配有环形的工件,所述旋转轴带动所述工件旋转运 动,所述工件的左侧装配有喷胶模块,所述喷胶模块上设计有正对工件表面的喷胶嘴,所述工件内装有喷胶材料,所述喷胶模块通过高压气流将雾化的胶料从喷胶嘴喷射到工件表面,所述喷料模块装配在所述工件的下部,所述喷料模块包括朝向所述工件下部的喷料嘴,所述喷料模块内部装配有石墨烯片料,石墨烯片料在所述喷料模块内利用高压气流通过喷料嘴喷射到工件下部表面;所述喷料嘴的右侧设计有料刷,所述料刷上设计有刷毛,所述刷毛贴附在所述工件下部表面;所述粘料模块包括输出胶卷、废料胶卷、固定转轮、调节转轮,所述输出胶卷上缠绕有胶布,所述输出胶卷上的胶布从固定转轮、调节转轮上缠绕通过接绕在所述废料胶卷上,所述胶布从固定转轮,调节转轮下部通过时有胶一面朝下,所述工件上部贴附在胶布的有胶面。The technical solution adopted by the present invention to solve its technical problems is that the graphene coating processing device includes a rotating module, a glue spraying module, a spraying module, and a sticking module. The rotating module is designed with a horizontal rotating shaft. The rotating shaft is equipped with a ring-shaped workpiece. The rotating shaft drives the workpiece to rotate. The left side of the workpiece is equipped with a glue spray module. The glue spray module is designed with a glue spray nozzle directly facing the surface of the workpiece. A glue spray material is installed in the workpiece, the glue spray module sprays the atomized glue from the glue nozzle to the surface of the workpiece through a high-pressure air flow, the spray module is assembled at the lower part of the workpiece, and the spray module includes Facing the spray nozzle at the lower part of the workpiece, the spray module is equipped with graphene flakes in the spray module, and the graphene flakes are sprayed to the lower surface of the workpiece through the spray nozzle by the high-pressure air flow in the spray module; A material brush is designed on the right side of the material nozzle, and the material brush is designed with bristles attached to the lower surface of the workpiece; the adhesive module includes an output film, a waste film, a fixed runner, and an adjustment Runner, the output film is wrapped with adhesive tape, and the adhesive tape on the output film is wound from the fixed rotator and the adjusting rotator by being wound on the waste film, and the adhesive tape is adjusted from the fixed rotator and the rotator When the lower part passes, the glue side faces down, and the upper part of the workpiece is attached to the glue side of the tape.
作为优选,所述调节转轮通过装配板铰接在固定转轴上。Advantageously, the adjusting wheel is hinged to the fixed rotating shaft through an assembly plate.
作为优选,所述喷料模块的下部装配有加压箱,所述加压箱内装配有加压气泵,所述喷料模块的左右设计有吸料腔,所述吸料腔的上部进气口正对所述工件的表面,所述吸料腔的下部出气口与加压箱内加压气泵的进气端相连,所述加压箱内加压气泵的出气端对所述喷料模块供应高压气。Preferably, a lower part of the spraying module is equipped with a pressurized tank, a pressurized air pump is installed in the pressurizing tank, a suction chamber is designed on the left and right sides of the spraying module, and the upper part of the suction chamber is provided with air intake The mouth is facing the surface of the workpiece, the lower gas outlet of the suction chamber is connected to the inlet end of the pressurized air pump in the pressurized tank, and the outlet end of the pressurized air pump in the pressurized tank faces the spraying module Supply high pressure gas.
作为优选,所述加压箱上部设计有位于所述喷料模块前后位置的挡板,所述加压箱前后位置的挡板与左右位置的吸料腔以及加压箱上板构成负压腔,所述加压箱上部装配有吸气口朝上的散料腔,所述散料腔与所述加压箱内加压气泵的吸气口相连。Preferably, the upper part of the pressurizing box is designed with baffles located at the front and back positions of the spraying module. The upper part of the pressurized tank is equipped with a bulk material chamber with an air inlet facing upward, and the bulk material chamber is connected to the air inlet of the pressurized air pump in the pressurized tank.
作为优选,所述喷料模块包括储料腔,所述储料腔下部设计有气流腔,所述气流腔的两端分别连接于加压箱的出气端和喷料嘴,所述储料腔下部通过V型槽与所述气流腔上部连通,所述储料腔通过管路与所述气流腔的进气端相连通。Preferably, the spraying module includes a storage cavity, and an airflow cavity is designed at the lower part of the storage cavity, and both ends of the airflow cavity are respectively connected to the air outlet of the pressurization box and the spray nozzle, and the storage cavity The lower part communicates with the upper part of the airflow chamber through a V-shaped groove, and the storage chamber communicates with the intake end of the airflow chamber through a pipeline.
作为优选,所述输出胶卷、废料胶卷均装配在可以正反转的水平旋转轴上。Preferably, both the output film and the waste film are assembled on a horizontal rotating shaft that can be reversed forward and backward.
本发明的有益效果在于:该石墨烯涂层加工装置主要以石墨烯片料为原料,用来对具有环形面的工件进行涂层加工。该装置工作时,工件装配在所述旋转模块的转轴上,在转轴的带动下,工件跟随旋转,这时所述喷胶模块会通过喷胶嘴向工件的表面喷涂胶料,随着工件的旋转喷涂胶料的部分旋转到喷料模块上部,喷料模块通过含有石墨烯的气流,将石墨烯喷涂在工件胶料表面,喷涂胶料部位的工件继续旋转到料刷的上部,通过料刷可以将石墨片料均匀的刷到工件胶料的表面,并将多余石墨烯片料刷掉,随着工件继续旋转涂抹了石墨烯的片料部分转动到粘料模块下部,粘料模块下部的胶布的胶面贴附在工件上石墨烯的表面,将工件表面外层的石墨烯剥离掉,从而得到薄层均匀的石墨烯,如果需要更薄层数或者单层的石墨烯,就将剥离后石墨烯转动一圈后再进行剥离,直到剥离到需要的厚度。该装置通过工业化的生产方式进行加工,其生产效率大大提高。同时该装置不仅可以用来加工单层的石墨烯涂层,也可以用来制作多层的石墨烯涂层,当工件的环形表面喷涂好一层的石墨烯后,继续在工件石墨烯层的表层再次进行上述操作,就可以在工件表面得到更多胶层和石墨烯叠加的料层,使得工件表面涂层具有更好的电学和物理学性能。The beneficial effect of the present invention is that the graphene coating processing device mainly uses graphene sheet material as a raw material, and is used to coat a workpiece with an annular surface. When the device is working, the workpiece is assembled on the rotating shaft of the rotating module, and the workpiece follows the rotation under the driving of the rotating shaft. At this time, the glue spraying module sprays the rubber material on the surface of the workpiece through the glue nozzle, and The part of the rotating spraying rubber material rotates to the upper part of the spraying module. The spraying module sprays the graphene on the surface of the workpiece rubber through the air flow containing graphene. The workpiece of the spraying rubber part continues to rotate to the upper part of the brush The graphite sheet can be evenly brushed to the surface of the workpiece rubber, and the excess graphene sheet can be brushed off. As the workpiece continues to rotate, the sheet part coated with graphene rotates to the lower part of the adhesive module, and the lower part of the adhesive module The adhesive surface of the adhesive tape is attached to the surface of the graphene on the workpiece, and the graphene on the outer surface of the workpiece is peeled off, thereby obtaining a uniform thin layer of graphene. If a thinner layer or a single layer of graphene is needed, the peeling will be After the graphene rotates one circle, the peeling is performed until the desired thickness is peeled off. The device is processed by an industrialized production method, and its production efficiency is greatly improved. At the same time, the device can not only be used to process a single layer of graphene coating, but also can be used to make multiple layers of graphene coating. When a layer of graphene is sprayed on the ring surface of the workpiece, continue on the workpiece graphene layer The surface layer is subjected to the above operations again, and more glue layers and graphene superimposed material layers can be obtained on the workpiece surface, so that the workpiece surface coating has better electrical and physical properties.
附图说明BRIEF DESCRIPTION
图1是石墨烯涂层加工装置工作时正向的结构示意图。FIG. 1 is a schematic diagram of the forward structure of the graphene coating processing device in operation.
图2是石墨烯涂层加工装置对工件进行放料和收料时的结构示意图。FIG. 2 is a schematic structural diagram of a graphene coating processing device when discharging and collecting workpieces.
图3是喷料模块的结构示意图。Figure 3 is a schematic diagram of the spray module.
[根据细则91更正 10.01.2019][Corrected according to Rule 91 10.01.2019]
具体实施方式detailed description
下面结合实施例对本发明进一步说明:The present invention is further described below in conjunction with examples:
如图1中实施例所示,在本实施例中,该石墨烯涂层加工装置包括旋转模块1、喷胶模块2、喷料模块3、粘料模块4,所述旋转模块1上设计有水平的旋转轴,所述旋转轴上装配有环形的工件5,所述旋转轴带动所述工件5旋转运动,所述工件5的左侧装配有喷胶模块2,所述喷胶模块2上设计有正对工件5表面的喷胶嘴21,所述工件内装有喷胶材料,所述喷胶模块2通过高压气流将雾化的胶料从喷胶嘴41喷射到工件5表面,所述喷料模块3装配在所述工件5的下部,所述喷料模块3包括朝向所述工件5下部的喷料嘴31,所述喷料模块3内部装配有石墨烯片料,石墨烯片料在所述喷料模块3内利用高压气流通过喷料嘴31喷射到工件5下部表面;所述喷料嘴31的右侧设计有料刷6,所述料刷6上设计有刷毛,所述刷毛贴附在所述工件5下部表面;所述粘料模块4包括输出胶卷41、废料胶卷42、固定转轮43、调节转轮44,所述输出胶卷41上缠绕有胶布,所述输出胶卷41上的胶布从固定转轮43、调节转轮44上缠绕通过接绕在所述废料胶卷42上,所述胶布从固定转轮43,调节转轮44下部通过时有胶一面朝下,所述工件5上部贴附在胶布的有胶面。在本专利中所述的石墨烯片料可以使用石墨粉,也可以使用其它含有多层石墨烯结构的石墨材料。As shown in the embodiment in FIG. 1, in this embodiment, the graphene coating processing device includes a rotating module 1, a glue spraying module 2, a spraying module 3, and a sticking module 4, and the rotating module 1 is designed with A horizontal rotating shaft, a ring-shaped workpiece 5 is assembled on the rotating shaft, the rotating shaft drives the workpiece 5 to rotate, and a glue spraying module 2 is mounted on the left side of the workpiece 5 The glue spray nozzle 21 is designed to face the surface of the workpiece 5, the glue spray material is contained in the workpiece, and the glue spray module 2 sprays the atomized glue from the glue spray nozzle 41 to the surface of the workpiece 5 through a high-pressure air flow. The spraying module 3 is assembled on the lower part of the workpiece 5. The spraying module 3 includes a spray nozzle 31 toward the lower part of the workpiece 5. The spraying module 3 is equipped with graphene sheets and graphene sheets In the spraying module 3, a high-pressure airflow is used to spray the lower surface of the workpiece 5 through the spraying nozzle 31; a material brush 6 is designed on the right side of the spraying nozzle 31, and the brush 6 is designed with bristles, the bristles Attached to the lower surface of the workpiece 5; the adhesive module 4 includes an output film 41 and a waste film 42. A fixed runner 43 and an adjusting runner 44. A tape is wound on the output film 41. The tape on the output film 41 is wound from the fixed runner 43 and the adjusting runner 44 by being wound on the waste film On 42, the adhesive tape passes from the fixed runner 43 and the lower side of the adjusting runner 44 with the adhesive side down, and the upper part of the workpiece 5 is attached to the adhesive surface of the adhesive tape. The graphene flakes described in this patent may use graphite powder or other graphite materials containing a multilayer graphene structure.
该石墨烯涂层加工装置主要以石墨烯片料为原料,用来对具有环形面的工件5进行涂层加工。该装置工作时,工件5装配在所述旋转模块1的转轴上,在转轴的带动下,工件5跟随旋转,这时所述喷胶模块2会通过喷胶嘴21向 工件5的表面喷涂胶料,随着工件5的旋转喷涂胶料的部分旋转到喷料模块3上部,喷料模块3通过含有石墨烯的气流,将石墨烯喷涂在工件5胶料表面,胶料会直接将石墨烯粘附柱,这时喷涂胶料部位的工件5继续旋转到料刷6的上部,通过料刷6可以将石墨片料均匀的刷到工件5胶料的表面,并将多余石墨烯片料刷掉,随着工件5继续旋转涂抹了石墨烯的片料部分转动到粘料模块4下部,粘料模块4下部的胶布的胶面贴附在工件5上石墨烯的表面,将工件5表面外层的石墨烯剥离掉,从而得到薄层均匀的石墨烯,如果需要更薄层数或者单层的石墨烯,就将剥离后石墨烯转动一圈后再进行剥离,直到剥离到需要的厚度。该装置不仅可以用来加工单层的石墨烯涂层,也可以用来制作多层的石墨烯涂层,当工件5的环形表面喷涂好一层的石墨烯后,继续在工件5石墨烯层的表层再次进行上述操作,就可以在工件5表面得到更多胶层和石墨烯叠加的料层,使得工件5表面涂层具有更好的电学和物理学性能。The graphene coating processing device mainly uses graphene sheet material as a raw material, and is used for coating processing on a workpiece 5 having an annular surface. When the device is in operation, the workpiece 5 is assembled on the rotating shaft of the rotating module 1, and the workpiece 5 rotates following the rotation of the rotating shaft. At this time, the glue spraying module 2 sprays the glue on the surface of the workpiece 5 through the glue nozzle 21 As the workpiece 5 rotates, the part of the sprayed rubber material rotates to the upper part of the spraying module 3, and the spraying module 3 sprays the graphene on the surface of the rubber material of the workpiece 5 through the air flow containing graphene, and the rubber material will directly Adhere to the column, at this time, the workpiece 5 sprayed with the rubber material continues to rotate to the upper part of the material brush 6, through the material brush 6, the graphite sheet can be evenly brushed to the surface of the workpiece 5 glue, and the excess graphene sheet material is brushed When the workpiece 5 continues to rotate, the part of the sheet coated with graphene rotates to the lower part of the adhesive module 4, the adhesive surface of the adhesive tape at the lower part of the adhesive module 4 is attached to the surface of the graphene on the workpiece 5, and the surface of the workpiece 5 The graphene of the layer is peeled off to obtain a thin layer of graphene. If a thinner layer or a single layer of graphene is needed, the graphene after the peeling is rotated once and then peeled off until the desired thickness is peeled off. The device can be used not only to process a single layer of graphene coating, but also to make multiple layers of graphene coating. After spraying a layer of graphene on the annular surface of the workpiece 5, the graphene layer continues on the workpiece 5 After the above operation is performed again, more glue layers and graphene layers can be obtained on the surface of the workpiece 5, so that the surface coating of the workpiece 5 has better electrical and physical properties.
在具体设计时,如图1和图2所示,所述调节转轮44通过装配板铰接在固定转轴45上。当需要所述粘料模块4正常工作时,如图1所示,粘料模块4下部的胶布保持在水平状态,贴附在所述工件5上部表面。而当需要将工件5从所述旋转模块1的旋转轴上取出时,通过所述旋转所述固定转轴45,使得所述调节转轮44向上转动,使得所述粘料模块4下部的胶布脱离所述工件5上表面,如图2所示,此时,可以方便的将所述工件5从所述旋转模块1的旋转轴上取出,从而方便的进行更换工件。In a specific design, as shown in FIGS. 1 and 2, the adjusting rotating wheel 44 is hinged to the fixed rotating shaft 45 through an assembly plate. When the adhesive module 4 needs to work normally, as shown in FIG. 1, the adhesive tape at the lower part of the adhesive module 4 is kept in a horizontal state and attached to the upper surface of the workpiece 5. When the workpiece 5 needs to be taken out from the rotating shaft of the rotating module 1, the fixed rotating shaft 45 is rotated to rotate the adjusting wheel 44 upward, so that the adhesive tape at the lower part of the adhesive module 4 is detached As shown in FIG. 2, the upper surface of the workpiece 5 can be easily removed from the rotating shaft of the rotating module 1 at this time, so that the workpiece can be replaced conveniently.
在具体设计时,如图1和图2所示,所述喷料模块3的下部装配有加压箱7,所述加压箱7内装配有加压气泵,所述喷料模块3的左右设计有吸料腔71,所述吸料腔71的上部进气口正对所述工件5的表面,所述吸料腔71的下部 出气口与加压箱7内加压气泵的进气端相连,所述加压箱7内加压气泵的出气端对所述喷料模块3供应高压气。这样所述加压箱7就可以通过所述吸料腔71将喷料模块3前后没有被粘附的石墨烯片料吸走,而且这些片料可以被再次的通过加压箱7的加压气泵再次供应给所述喷料模块3进行使用,从而使得石墨烯材料的使用效率更高。In the specific design, as shown in FIGS. 1 and 2, the lower part of the spraying module 3 is equipped with a pressurized tank 7, and a pressurized air pump is installed in the pressurized tank 7, and the left and right sides of the spraying module 3 A suction chamber 71 is designed. The upper air inlet of the suction chamber 71 faces the surface of the workpiece 5. The lower air outlet of the suction chamber 71 and the intake end of the pressurized air pump in the pressure box 7 Connected, the outlet end of the pressurized air pump in the pressurized tank 7 supplies high-pressure gas to the spraying module 3. In this way, the pressurizing tank 7 can suck the graphene sheets that are not adhered to the front and back of the spray module 3 through the suction chamber 71, and these sheets can be pressed again by the pressurizing tank 7 The air pump is supplied to the spraying module 3 again for use, so that the use efficiency of the graphene material is higher.
另外如图1和图2所示,所述加压箱7上部设计有位于所述喷料模块3前后位置的挡板,所述加压箱7前后位置的挡板与左右位置的吸料腔71以及加压箱7上板构成负压腔,所述加压箱7上部装配有吸气口朝上的散料腔72,所述散料腔72与所述加压箱7内加压气泵的吸气口相连。这样构成的所述负压腔可以更好的对工件5下部的石墨烯材料进行吸取,其中左右设计的所述吸料腔71主要用来进行吸取工件5表面粘附的石墨烯,而所述散料腔72主要用来吸附进行喷料时,飘散在所述负压腔内的石墨烯,这样不仅可以有效防止石墨烯在生产空间的飘散,同时可以使得生产过程中的石墨烯整体的使用效率更高,大大降低生产成本。In addition, as shown in FIGS. 1 and 2, the upper part of the pressurizing tank 7 is designed with baffles located at the front and rear positions of the spray module 3, the baffle at the front and rear positions of the pressurizing tank 7 and the suction chamber at the left and right positions 71 and the upper plate of the pressurizing tank 7 form a negative pressure chamber, and the upper part of the pressurizing tank 7 is equipped with a bulk material chamber 72 with an air inlet facing upward. The bulk material chamber 72 and the pressurized air pump in the pressurizing tank 7 Connected to the suction port. The negative pressure chamber formed in this way can better absorb the graphene material at the lower part of the workpiece 5, wherein the suction chambers 71 designed on the left and right are mainly used to absorb the graphene adhered on the surface of the workpiece 5, and the The bulk chamber 72 is mainly used to adsorb the graphene scattered in the negative pressure chamber during spraying, which can not only effectively prevent the graphene from drifting in the production space, but also make the overall use of graphene in the production process Higher efficiency, greatly reducing production costs.
所述喷料模块3在具体设计时,如图1和图3所示,包括储料腔32,所述储料腔32下部设计有气流腔33,所述气流腔33的两端分别连接于加压箱7的出气端和喷料嘴31,所述储料腔32下部通过V型槽34与所述气流腔33上部连通,所述储料腔32通过管路与所述气流腔33的进气端相连通。所述储料腔32内装配有石墨烯片料,储料腔32内的石墨烯可以通过所述V型槽34掉落到所述气流腔33内,随着气流腔33内通入的气流,从左到右将石墨烯片料吹出,使得石墨烯材料从所述喷料嘴31喷出到工件下部表面,所述储料腔32也过管路与所述气流腔33的进气端相连,这样可以保证所述储料腔32处于正压状态,便于所述储料腔32内的石墨烯片料从所述V型槽34下端 喷出。When the spraying module 3 is specifically designed, as shown in FIGS. 1 and 3, it includes a storage chamber 32, and an airflow chamber 33 is designed at the lower part of the storage chamber 32, and both ends of the airflow chamber 33 are connected to The outlet end of the pressurized tank 7 and the spray nozzle 31, the lower part of the storage chamber 32 communicates with the upper part of the air flow chamber 33 through a V-shaped groove 34, and the storage chamber 32 communicates with the air flow chamber 33 through a pipeline The intake side is connected. The storage cavity 32 is equipped with graphene sheets, and the graphene in the storage cavity 32 can fall into the airflow cavity 33 through the V-shaped groove 34, and the airflow passing through the airflow cavity 33 , The graphene sheet material is blown out from left to right, so that the graphene material is ejected from the nozzle 31 to the lower surface of the workpiece, the storage chamber 32 also passes through the pipeline and the inlet end of the airflow chamber 33 It is connected to ensure that the storage chamber 32 is in a positive pressure state, so that the graphene sheet material in the storage chamber 32 is ejected from the lower end of the V-shaped groove 34.
在具体设计时,所述输出胶卷41、废料胶卷42均装配在可以正反转的水平旋转轴上。这样不仅可以使用胶布的胶面对工件5表面的石墨烯片料进行反复粘附,使得胶布的使用效率更高,同时当工件5表面的石墨烯片料具有缺损时,可以通过这种方式将石墨烯缺损补齐,使得石墨烯片料生产出的涂层效果更好。In a specific design, the output film 41 and the waste film 42 are assembled on a horizontal rotation shaft that can be reversed. In this way, not only can the adhesive of the adhesive tape be repeatedly adhered to the graphene sheet on the surface of the workpiece 5, so that the use efficiency of the adhesive tape is higher, and when the graphene sheet on the surface of the workpiece 5 has defects, it can be Graphene defect repairs make the coating produced by graphene sheets better.
以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention and are not intended to limit the present invention. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection of the present invention Within range.

Claims (6)

  1. 一种石墨烯涂层加工装置,它包括旋转模块(1)、喷胶模块(2)、喷料模块(3)、粘料模块(4),所述旋转模块(1)上设计有水平的旋转轴,所述旋转轴上装配有环形的工件(5),所述旋转轴带动所述工件(5)旋转运动,其特征在于:所述工件(5)的左侧装配有喷胶模块(2),所述喷胶模块(2)上设计有正对工件(5)表面的喷胶嘴(21),所述工件内装有喷胶材料,所述喷胶模块(2)通过高压气流将雾化的胶料从喷胶嘴(41)喷射到工件(5)表面,所述喷料模块(3)装配在所述工件(5)的下部,所述喷料模块(3)包括朝向所述工件(5)下部的喷料嘴(31),所述喷料模块(3)内部装配有石墨烯片料,石墨烯片料在所述喷料模块(3)内利用高压气流通过喷料嘴(31)喷射到工件(5)下部表面;所述喷料嘴(31)的右侧设计有料刷(6),所述料刷(6)上设计有刷毛,所述刷毛贴附在所述工件(5)下部表面;所述粘料模块(4)包括输出胶卷(41)、废料胶卷(42)、固定转轮(43)、调节转轮(44),所述输出胶卷(41)上缠绕有胶布,所述输出胶卷(41)上的胶布从固定转轮(43)、调节转轮(44)上缠绕通过接绕在所述废料胶卷(42)上,所述胶布从固定转轮(43),调节转轮(44)下部通过时有胶一面朝下,所述工件(5)上部贴附在胶布的有胶面。A graphene coating processing device, which includes a rotating module (1), a glue spraying module (2), a spraying module (3), and a sticking material module (4). The rotating module (1) is designed with a horizontal A rotating shaft, on which a ring-shaped workpiece (5) is assembled, the rotating shaft drives the workpiece (5) to rotate, and is characterized in that a glue spray module ( 2), the glue spraying module (2) is designed with a glue spraying nozzle (21) directly facing the surface of the workpiece (5), the glue spraying material is contained in the workpiece, and the glue spraying module (2) will The atomized glue is sprayed from the glue nozzle (41) to the surface of the workpiece (5). The spraying module (3) is mounted on the lower part of the workpiece (5). The spraying module (3) includes A spray nozzle (31) at the lower part of the work piece (5), and the spray module (3) is equipped with graphene flakes inside, and the graphene flakes pass through the spray material in the spray module (3) with high-pressure air flow The nozzle (31) sprays onto the lower surface of the workpiece (5); the right side of the spray nozzle (31) is designed with a material brush (6), and the material brush (6) is designed with bristles, and the bristles are attached to the The lower surface of the workpiece (5); the adhesive module (4 ) Includes an output film (41), a waste film (42), a fixed wheel (43), and an adjusting wheel (44), the output film (41) is wrapped with a tape, and the output film (41) has a tape It is wound around the waste film (42) from the fixed runner (43) and the adjusting runner (44). When the tape passes from the fixed runner (43) and the lower part of the adjusting runner (44), there are The glue side faces down, and the upper part of the workpiece (5) is attached to the glued surface of the tape.
  2. 根据权利要求1所述的石墨烯涂层加工装置,其特征在于:所述调节转轮(44)通过装配板铰接在固定转轴(45)上。The graphene coating processing device according to claim 1, characterized in that the adjusting rotating wheel (44) is hinged on a fixed rotating shaft (45) through an assembly plate.
  3. [根据细则91更正 10.01.2019] 
    根据权利要求1所述的石墨烯涂层加工装置,其特征在于:所述喷料模块(3)的下部装配有加压箱(7),所述加压箱(7)内装配有加压气泵,所述喷料模块(3)的左右设计有吸料腔(71),所述吸料腔(71)的上部进气口正对所述工件(5)的表面,所述吸料腔(71)的下部出气口与加压 箱(7)内加压气泵的进气端相连,所述加压箱(7)内加压气泵的出气端对所述喷料模块(3)供应高压气。
    [Correction according to Rule 91 10.01.2019]
    The graphene coating processing device according to claim 1, characterized in that: the lower part of the spraying module (3) is equipped with a pressurized box (7), and the pressurized box (7) is equipped with a pressurized box An air pump, a suction chamber (71) is designed on the left and right sides of the spraying module (3), the upper air inlet of the suction chamber (71) is directly facing the surface of the workpiece (5), the suction chamber The lower air outlet of (71) is connected to the intake end of the pressurized air pump in the pressurized tank (7), and the output end of the pressurized air pump in the pressurized tank (7) supplies high pressure to the spraying module (3) gas.
  4. [根据细则91更正 10.01.2019] 
    根据权利要求3所述的石墨烯涂层加工装置,其特征在于:所述加压箱(7)上部设计有位于所述喷料模块(3)前后位置的挡板,所述加压箱(7)前后位置的挡板与左右位置的吸料腔(71)以及加压箱(7)上板构成负压腔,所述加压箱(7)上部装配有吸气口朝上的散料腔(72),所述散料腔(72)与所述加压箱(7)内加压气泵的吸气口相连。
    [Correction according to Rule 91 10.01.2019]
    The graphene coating processing device according to claim 3, characterized in that: the upper part of the pressure box (7) is designed with baffles located at the front and back of the spraying module (3), and the pressure box ( 7) The baffle plate at the front and rear positions, the suction chamber (71) at the left and right positions and the upper plate of the pressure box (7) form a negative pressure chamber, and the upper part of the pressure box (7) is equipped with bulk materials with suction ports facing upward Cavity (72), the bulk material cavity (72) is connected to the suction port of the pressurized air pump in the pressurized tank (7).
  5. [根据细则91更正 10.01.2019] 
    根据权利要求1所述的石墨烯涂层加工装置,其特征在于:所述喷料模块(3)包括储料腔(32),所述储料腔(32)下部设计有气流腔(33),所述气流腔(33)的两端分别连接于加压箱(7)的出气端和喷料嘴(31),所述储料腔(32)下部通过V型槽(34)与所述气流腔(33)上部连通,所述储料腔(32)通过管路与所述气流腔(33)的进气端相连通。
    [Correction according to Rule 91 10.01.2019]
    The graphene coating processing device according to claim 1, characterized in that the spraying module (3) includes a storage chamber (32), and an air flow chamber (33) is designed at the lower part of the storage chamber (32) , The two ends of the airflow chamber (33) are respectively connected to the air outlet of the pressurizing box (7) and the spray nozzle (31), and the lower part of the storage chamber (32) passes through the V-shaped groove (34) and the The upper part of the airflow chamber (33) communicates, and the storage chamber (32) communicates with the intake end of the airflow chamber (33) through a pipeline.
  6. [根据细则91更正 10.01.2019] 
    根据权利要求1所述的石墨烯涂层加工装置,其特征在于:所述输出胶卷(41)、废料胶卷(42)均装配在可以正反转的水平旋转轴上。
    [Correction according to Rule 91 10.01.2019]
    The graphene coating processing device according to claim 1, characterized in that the output film (41) and the waste film (42) are assembled on a horizontal rotating shaft that can be reversed.
PCT/CN2018/112123 2018-10-26 2018-10-26 Graphene coating processing device WO2020082339A1 (en)

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PCT/CN2018/112123 WO2020082339A1 (en) 2018-10-26 2018-10-26 Graphene coating processing device

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Citations (6)

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CN203947303U (en) * 2014-07-02 2014-11-19 时兴纺整(苏州)有限公司 A kind of gluing dusting device
CN104445158A (en) * 2014-10-23 2015-03-25 江阴碳谷科技有限公司 Graphene stripping device, graphene production system and graphene production method
CN105921369A (en) * 2016-06-16 2016-09-07 安庆市恒昌机械制造有限责任公司 Material adding device and technology
CN107812679A (en) * 2017-10-31 2018-03-20 洛阳菁洲纳米科技有限公司 A kind of spraying method of graphene coating
CN107964294A (en) * 2017-12-11 2018-04-27 大连理工大学 A kind of PFA coatings containing micro-nano compounded mix and preparation method thereof
US20180171251A1 (en) * 2012-07-19 2018-06-21 Uchicago Argonne, Llc Superlubricating graphene and graphene oxide films

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180171251A1 (en) * 2012-07-19 2018-06-21 Uchicago Argonne, Llc Superlubricating graphene and graphene oxide films
CN203947303U (en) * 2014-07-02 2014-11-19 时兴纺整(苏州)有限公司 A kind of gluing dusting device
CN104445158A (en) * 2014-10-23 2015-03-25 江阴碳谷科技有限公司 Graphene stripping device, graphene production system and graphene production method
CN105921369A (en) * 2016-06-16 2016-09-07 安庆市恒昌机械制造有限责任公司 Material adding device and technology
CN107812679A (en) * 2017-10-31 2018-03-20 洛阳菁洲纳米科技有限公司 A kind of spraying method of graphene coating
CN107964294A (en) * 2017-12-11 2018-04-27 大连理工大学 A kind of PFA coatings containing micro-nano compounded mix and preparation method thereof

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