WO2020072190A1 - Power delivery system and method - Google Patents
Power delivery system and methodInfo
- Publication number
- WO2020072190A1 WO2020072190A1 PCT/US2019/051344 US2019051344W WO2020072190A1 WO 2020072190 A1 WO2020072190 A1 WO 2020072190A1 US 2019051344 W US2019051344 W US 2019051344W WO 2020072190 A1 WO2020072190 A1 WO 2020072190A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrolyte
- power system
- electrical
- metallic device
- energy storage
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 45
- 238000004146 energy storage Methods 0.000 claims abstract description 45
- 239000003792 electrolyte Substances 0.000 claims description 190
- 238000004891 communication Methods 0.000 claims description 34
- 210000000352 storage cell Anatomy 0.000 claims description 12
- 238000002955 isolation Methods 0.000 claims description 9
- 230000008878 coupling Effects 0.000 claims description 8
- 238000010168 coupling process Methods 0.000 claims description 8
- 238000005859 coupling reaction Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 230000004888 barrier function Effects 0.000 claims description 7
- 230000004044 response Effects 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 2
- 238000007599 discharging Methods 0.000 abstract description 8
- 210000004027 cell Anatomy 0.000 description 59
- 239000000654 additive Substances 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 7
- 238000007747 plating Methods 0.000 description 7
- 239000000523 sample Substances 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002000 Electrolyte additive Substances 0.000 description 1
- 210000004460 N cell Anatomy 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000012772 electrical insulation material Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000008384 membrane barrier Effects 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012358 sourcing Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04186—Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04037—Electrical heating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04276—Arrangements for managing the electrolyte stream, e.g. heat exchange
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04574—Current
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04955—Shut-off or shut-down of fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present description relates to a system and method for sinking or sourcing electric power to or from an electric energy storage device.
- the methods and systems may be particularly useful for electrical power systems that include two electrolytes that are not in fluidic communication.
- An electrical energy storage device may store electrical power that has been generated via an array of photovoltaic cells, wind turbines, hydroelectric generators, or other sources so that the electrical power may be delivered to electrical loads at a later time when output of the electrical power source may be low or when electrical loads are high.
- the electrical energy storage device may be comprised of a plurality of cells that may be coupled in series to increase the electrical potential of the electrical energy storage device.
- the electrical energy storage device may also include cells that are electrical coupled in parallel to increase the output capacity of the electrical energy storage device. As electrical potential of an electrical energy storage device increases, there may be a higher propensity for the electrical energy storage device to seek a lower electrical potential (e.g., earth ground) and discharge to the lower electrical potential.
- a lower electrical potential e.g., earth ground
- the possibility of discharging the electrical energy storage device to an object that is at a lower electrical potential may be reduced via increasing electrical insulation around and within the electrical energy storage device, but increasing the quantity and quality of the electrical insulation material may significantly increase cost of the electrical energy storage device. Therefore, it may be desirable to provide a way of reducing a possibility of unintentionally discharging an electric energy storage device to an object at lower electrical potential without substantially increasing cost of the electric energy storage device.
- an electric energy storage cell including a positive reactor, a negative reactor, a barrier providing fluidic isolation between the positive reactor and the negative reactor, a first portion of a first electrolyte, and a first portion of a second electrolyte that is not in fluidic communication with the first electrolyte; a first fluidic passage housing a second portion of the first electrolyte that is in fluidic communication with the positive reactor; a second fluidic passage housing a second portion of the second electrolyte that is in fluidic communication with the negative reactor; and a metallic device that is in electrical communication with the first electrolyte and the second electrolyte, the metallic device electrically coupled to an earth ground reference.
- the approach may reduce power system cost. Further, the approach may be applied in a variety of ways that allow for a flexible system. In addition, the approach may reduce system weight and improve system reliability.
- FIG. 1 is a schematic diagram showing a single cell of an electric power storage and delivery system
- FIG. 2 is a schematic diagram of an electric power system in which a manifold voltage is reference to an earth ground potential;
- FIG. 3 shows a detailed schematic of one example of the electric power system of FIG. 2;
- FIG. 4 shows a detailed schematic of a second example electric power system
- FIG. 5 shows a detailed schematic of a third example electric power system
- FIG. 6 shows a detailed schematic of a fourth example electric power system
- FIG. 7 shows a flowchart of a method for operating the systems of FIGS. 1-6.
- the present description is related to storing and delivering power via an electric energy storage device (e.g., a direct current (DC) power source) as shown in FIG. 1.
- the electric energy storage device may store electrical energy that is generated via photovoltaic cells, hydroelectric power, wind power, or via chemical energy.
- the electric energy storage device may output DC power that may be distributed as alternating current AC after a conversion process.
- the electric energy storage device may be an iron flow device as shown in FIGS. 1-6.
- the electric energy storage device may include a heater that is referenced to ground as shown in FIGS. 2 and 3.
- an electrolyte distribution manifold may be referenced to earth ground as shown in FIG.
- FIGS. 1-6 may be operated according to the method of FIG. 7 to store and deliver electrical power.
- the IFB cell 175 is an electric energy storage device.
- the IFB cell may be supplied with plating electrolyte 160 (e.g., FeCL 2 ) that is stored in plating electrolyte tank 100.
- the IFB may also include redox electrolyte 161 that is stored in redox electrolyte tank 101.
- the plating electrolyte and redox electrolyte may be a suitable salt dissolved in water, such as FeCb or FeCb. Both the plating electrolyte and redox electrolyte may use the same salt at different molar concentrations, a feature of the IFB not available in batteries with different reactive compounds.
- Tank 100 may be in fluidic communication with negative reactor 122.
- Tank 101 may be in fluidic communication with positive reactor 124.
- Electrolyte in tank 100 and negative reactor 122 is in fluidic isolation from electrolyte in tank 101 and positive reactor 124. Separating the negative and positive reactors and their respective electrolytes is barrier 120.
- the barrier may embodied as a membrane barrier, such as an ion exchange membrane or a microporous membrane, placed between the plating electrolyte and redox electrolyte to prevent electrolyte cross-over and provide ionic conductivity.
- Sensors 102 and 104 may be used to determine the chemical properties of the electrolyte, including pH and may be embodied as an optical sensor. Probes 126 and 128 may additionally or alternatively be used to determine the chemical properties (discussed below) of the electrolytes. Other examples may have a plating electrolyte probe, plating electrolyte sensor, redox electrolyte probe, redox electrolyte sensor, or some combination thereof. The probe may also be placed inside the reacting portion of the IFB in negative reactor 122 and positive reactor 124. An acid additive may be stored in additional tanks 106 and 108. These may contain different additives and be controlled by different routines.
- the IFB may also have either a positive side additive or a negative side additive and not both.
- the positive side additive may be accelerated into the positive reactor 122 by positive additive pump 112, the negative additive may be accelerated into the negative reactor 124 by negative additive pump 110.
- the electrolyte additives may be pumped into tanks 100 and 101. Pumps 110 and 112 may be actuated via a control system 150 communicatively coupled to the pumps. The control system may be responsive to probe 126, probe 128, sensor 102, sensor 104, or any combination thereof.
- Electrolyte may be pumped to or from the negative reactor 122 by pump 131. Electrolyte may be pumped to or from the positive reactor 125 via pump 130.
- the IFB includes a negative electrode 114 and a positive electrode 116.
- Control system 150 may include inputs and outputs 154 (e.g., digital inputs, digital outputs, analog inputs, analog outputs, pulse width outputs, etc.), a central processor 152, random-access memory 155, and read-only (e.g., non-transitory memory) 156.
- inputs and outputs 154 e.g., digital inputs, digital outputs, analog inputs, analog outputs, pulse width outputs, etc.
- central processor 152 e.g., random-access memory 155
- read-only e.g., non-transitory memory
- FIG. 2 a schematic block diagram of an electric power system that includes a plurality of the IFB cells l75a-l75e shown in a circuit that includes modeled resistances.
- the schematic block diagram shows passages or conduits 290 that distribute electrolyte to the positive reactors of IFB cells !75a-l75e.
- a similar schematic may be generated for electrolyte that is distributed to negative reactors of IFB cells l75a-l75e, except that passages or conduits 290 would distributed to the negative reactors (e.g., 290 connections to the negative sides of 175 a- 175 e).
- IFB cell stack 225 is comprised of five cells electrically coupled in series, but the cell stack 225 may include from 1 to N cells connected in series where N is an integer number of a last cell in the cell stack 225.
- a lowest electrical potential 235 of IFB cell stack 225 is provided at a negative terminal of the first cell l75a.
- a highest electrical potential 236 of IFB cell stack 225 is provided at the positive terminal of N 111 cell l75e.
- Resistances 250 represent the internal resistances of IFB cells l75a-l75e, and each resistance 250 is nominally equal to the internal resistances 250 of the other IFB cells l75a- l75e.
- Resistances 253a-253e represent cell to cell resistances in the manifold ant farm layout.
- Resistance 252 is a stack manifold to heater electrolyte distribution resistance (e.g., a resistance of the electrolyte in the passage between the electrolyte distribution manifold 260 and heater 210).
- IFB cell stack 225 may receive electrical power from electric energy sources (e.g., photovoltaic cells, wind turbines, hydroelectric generators, etc.) 279. IFB cell stack 225 may also supply electrical power to electrical energy consumers (e.g., house hold appliances, industrial motors, vehicle propulsion sources, etc.) 278. Contactor 277 may be opened to electrically isolate IFB cell stack 225 from electrical energy sources 279 and electrical energy consumers 278. Likewise, contactor 277 may be closed to electrically couple IFB cell stack 225 to electrical energy sources 279 and electrical energy consumers 278. Electrical energy sources 279 and electrical energy consumers 278 are external to IFB cell stack 225.
- electric energy sources e.g., photovoltaic cells, wind turbines, hydroelectric generators, etc.
- IFB cell stack 225 may also supply electrical power to electrical energy consumers (e.g., house hold appliances, industrial motors, vehicle propulsion sources, etc.) 278.
- Contactor 277 may be opened to electrically isolate IFB cell stack 225 from
- Electrolyte may be distributed from tank 101 to IFB cell stack 225 via pump 130, heater 210, passages or conduits 290, and electrolyte distribution manifold 260.
- Electrolyte may be distributed from IFB cell stack 225 to tank 101 via pump 130, heater 210, passages or conduits 290, and electrolyte distribution manifold 260.
- Electrolyte may be heated as it passes through heater 210.
- heater 210 includes a metallic (e.g., titanium) housing 211 (e.g., a tubular housing) that covers and seals heating element (e.g., resistive) 214 from electrolyte.
- Housing 211 may be in electrical communication with a first electrolyte and a second electrolyte as shown in greater detail in FIG. 3.
- Heater 210 may also include a conductor 212 that electrically couples housing 211 to earth ground 202.
- a voltage may be generated across optional current sense resistor 220 when a current flows from housing 211 to earth ground 202. If controller 150 senses a current that is greater than a threshold amount of current via the voltage generated via resistor 220, controller 150 may deactivate IFB cell stack 225 by opening contactor 277 and deactivating pump 130.
- Electrolyte may be heated via power source 230 supplying electrical energy to heating element 214.
- FIG. 3 a detailed schematic of one example of the electric power system in FIG. 2 is shown.
- FIG. 3 includes some components that have been previously introduced in FIGS. 1 and 2. The numbering of these components is consistent in FIG. 3. The description of these components is consistent throughout the figures. Therefore, a description of previously introduced components is omitted for the sake of brevity. Newly identified components in FIG. 3 are included in the description of FIG. 3.
- Electrolyte distribution manifold 260 is coupled to a plurality of IFB cells l75a- l75e (l75a and l75e are specifically identified) that form IFB cell stack 225.
- a first electrolyte 161 is supplied to positive reactors 124 and a second electrolyte is supplied to negative reactors 122.
- Conduits or passages 290 supply the first electrolyte to positive reactors 124 via electrolyte distribution manifold 260 and via a section of conduits or passages coupling pump 130 to electrolyte distribution manifold 260.
- conduits or passages 390 supply the second electrolyte to negative reactors 122 via electrolyte distribution manifold 260 and via a section of conduits or passages coupling pump 131 to electrolyte distribution manifold 260.
- Conduit or passage 290 includes a section 350 where first electrolyte 161 is enclosed in housing 329 and separated from second electrolyte 162 via heater 210 and baffle 330.
- Heater 210 is simultaneously in physical and electrical communication with first electrolyte 161 and second electrolyte 162.
- Baffle 330 extends from heater 210 to housing 329 such that first electrolyte 161 and second electrolyte 162 are not in fluidic communication.
- baffle 330 holds heater 330 stationary inside of housing 329.
- Baffle 330 may be welded or otherwise coupled to heater housing 211 and housing 329.
- Heater 210 may be activated via supplying power to heater 210 via conductors 3 l3a and 3 l3b and power source 230. Thus, heater 210 may simultaneously heat first electrolyte 161 and second electrolyte 162.
- Heater housing 211 is of metallic construction and it is directly electrically coupled to earth ground 202 via sole conductor 333.
- first electrolyte 161 and second electrolyte 162 may be reference to earth ground via heater housing 211 so that a voltage of a terminal of cell IFB stack 225 that has a highest electrical potential referenced to earth ground may be reduced as compared to what it would be if the negative terminal of IFB cell stack 225 with the lowest electrical potential were referenced to earth ground. As such, a possibility of unintended discharging IFB cell stack 225 may be reduced.
- Pumps 130 and 131 supply the first electrolyte 161 and the second electrolyte from tanks 101 and 100. Once the first electrolyte and the second electrolyte 162 pass through positive and negative reactors 124 and 122, the first electrolyte 161 and the second electrolyte 162 are returned to tanks 101 and 100 via an electrolyte merging manifold 312 and passages or conduits 308 and 314.
- FIG. 4 a detailed schematic of a second example electric power system is shown.
- the system of FIG. 4 includes some components that have been previously introduced in FIGS. 1-3. The numbering of these components is consistent in FIG. 4. The description of these components is consistent throughout the figures. Therefore, a description of previously introduced components is omitted for the sake of brevity. Newly identified components in FIG. 4 are included in the description of FIG. 4.
- conduits or passages 290 and 390 supply first and second electrolytes to positive and negative reactors 122 and 124.
- the passages 290 and 390 extend from pumps 130 and 131 to electrolyte distribution manifold 260.
- Electrolyte distribution manifold 260 may be of metallic construction so that first electrolyte 161 and second electrolyte 162 may be referenced to a same electrical potential. In other words, electrolyte distribution manifold 260 provides a metallic conductive path for current flow between the first electrolyte 161 and the second electrolyte 162 while the first electrolyte 161 is not in fluidic communication with the second electrolyte 162.
- electrolyte distribution manifold 260 is electrically coupled to earth ground 202 so that first and second electrolytes may be referenced to a same reference level.
- This allows a voltage of a terminal of cell IFB stack 225 that has a highest electrical potential referenced to earth ground to be reduced as compared to what it would be if it were referenced to the lowest electrical potential negative terminal of IFB cell stack 225 and the lowest electrical potential negative terminal of IFB cell stack 225 was referenced to earth ground. Accordingly, a possibility of unintended discharging IFB cell stack 225 may be reduced.
- First and second electrolytes 161 and 162 flow from electrolyte distribution manifold 260, through positive and negative reactors 122 and 124, and electrolyte merging manifold 312 before returning to tanks 100 and 101.
- heater 210 is not shown, but one may be included if desired. However, if heater 210 is included, heater 210 is not referenced to earth ground because electrolyte distribution manifold 260 is referenced to ground.
- electrolyte merging manifold 312 may be of metallic construction and it may be electrically coupled to earth ground instead of electrolyte distribution manifold 260. Additionally, a current sense resistor may be provided between earth ground 202 and electrolyte distribution manifold 260 for ground fault detection.
- FIG. 5 a detailed schematic of a third example electric power system is shown.
- the system of FIG. 5 includes some components that have been previously introduced in FIGS. 1-3. The numbering of these components is consistent in FIG. 5. The description of these components is consistent throughout the figures. Therefore, a description of previously introduced components is omitted for the sake of brevity. Newly identified components in FIG. 5 are included in the description of FIG. 5.
- conduits or passages 290 and 390 again supply first and second electrolytes 161 and 162 to positive and negative reactors 122 and 124.
- a single pump 531 provides motive force to first electrolyte 161 and second electrolyte 162 while there is no fluidic communication between first electrolyte 161 and second electrolyte 162.
- Sole pump 531 includes first impeller 504 that operates on first electrolyte 161 and second impeller 506 that operates on second electrolyte 162.
- First impeller 504 and second impeller 506 are rotated via motor 528.
- Pump 531 includes a housing 502 that may be of metallic construction so that first electrolyte and second electrolyte may be referenced to a same electrical potential.
- Housing 502 is electrically coupled to earth ground 202.
- housing 502 provides a metallic conductive path for current flow between the first electrolyte and the second electrolyte while the first electrolyte is not in fluidic communication with the second electrolyte.
- This allows a voltage of a terminal of cell IFB stack 225 that has a highest electrical potential referenced to earth ground to be reduced as compared to what it would be if it were referenced to the lowest electrical potential negative terminal of IFB cell stack 225 and the lowest electrical potential negative terminal of IFB cell stack 225 was referenced to earth ground. Accordingly, a possibility of unintended discharging IFB cell stack 225 may be reduced.
- This example illustrates a pump with two impellers and a single motor, but other configurations may include two motors and two impellers in a single housing so that a metallic conductive path for current flow between the first electrolyte and the second electrolyte may be maintained.
- First and second electrolytes flow from electrolyte distribution manifold 260, through positive and negative reactors 122 and 124, and electrolyte merging manifold 312 before returning to tanks 100 and 101.
- heater 210 is not shown, but one may be included if desired. However, if heater 210 is included, heater 210 is not referenced to earth ground because housing 502 is referenced to ground. Additionally, a current sense resistor may be provided between earth ground 202 and housing 502 for ground fault detection.
- FIG. 6 a detailed schematic of a third example electric power system is shown.
- the system of FIG. 6 includes some components that have been previously introduced in FIGS. 1-5. The numbering of these components is consistent in FIG. 6. Therefore, a description of previously introduced components is omitted for the sake of brevity. Newly identified components in FIG. 6 are included in the description of FIG. 6.
- the system of FIG. 6 includes a pump 531 that is similar to pump 531 in FIG. 5, but pump 531 in this example includes slip rings 630 or a different known device that permits impellers 506 and 504 to be electrically coupled to earth ground 202.
- Impellers 504 and 506 may be of metallic construction. Impellers 504 and 506 are in electrical communication with each other such that there is a metallic conductive path for current flow between the first electrolyte and the second electrolyte while the first electrolyte is not in fluidic communication with the second electrolyte.
- the housing 502 may be non-metallic.
- FIGS. 1-6 provide for an electrical power system, comprising: an electric energy storage cell including a positive reactor, a negative reactor, a barrier providing fluidic isolation between the positive reactor and the negative reactor, a first portion of a first electrolyte, and a first portion of a second electrolyte that is not in fluidic communication with the first electrolyte; a first fluidic passage housing a second portion of the first electrolyte that is in fluidic communication with the positive reactor; a second fluidic passage housing a second portion of the second electrolyte that is in fluidic communication with the negative reactor; and a metallic device that is in physical and electrical communication with the first electrolyte and the second electrolyte, the metallic device electrically coupled to a reference electrical potential.
- an electric energy storage cell including a positive reactor, a negative reactor, a barrier providing fluidic isolation between the positive reactor and the negative reactor, a first portion of a first electrolyte, and a first portion of a second electrolyte that is not in fluidic communication with
- the electric power system includes where the reference electrical potential is an earth ground potential, and further comprising: at least one pump that is in fluidic communication with the first fluidic passage.
- the electric power system further comprises at least one pump that is in fluidic communication with the second fluidic passage.
- the metallic device may be contemporaneously touching both the first electrolyte and the second electrolyte.
- the electric power system includes where the metallic device is positioned along the first and second fluidic passages.
- the electric power system includes where the metallic device is a fluid manifold that directs the first electrolyte and the second electrolyte to a plurality of electric energy storage cells.
- the electric power system includes where the metallic device is a heating element.
- the electric power system includes where the metallic device is a housing of a pump.
- the electric power system includes where the metallic device is an impeller of a pump.
- the system of FIGS. 1-6 also provides for an electrical power system, comprising: a plurality of electric energy storage cells, each of the plurality of electric energy storage cells including a positive reactor, a negative reactor, a barrier providing fluidic isolation between the positive reactor and the negative reactor, a first portion of a first electrolyte, and a first portion of a second electrolyte that is not in fluidic communication with the first electrolyte; a manifold including a plurality of passages including the first electrolyte and the second electrolyte; one or more pumps configured to deliver the first electrolyte and the second electrolyte to the plurality of electric energy storage cells; and a metallic device that is in physical and electrical communication with the first electrolyte and the second electrolyte, the metallic device electrically coupled to a reference electrical potential.
- the electric power system includes where the reference electrical potential is an earth ground potential, and where the metallic device is directly electrically coupled to the earth ground potential.
- the electric power system includes where the reference electrical potential is an earth ground potential, and where the metallic device is electrically coupled to the earth ground potential via a current sensing device.
- the electrical power system further comprises a controller including executable instructions stored in non-transitory memory for deactivating the electrical power system in response to an electrical current that is greater than a threshold current flowing through the current sensing device.
- the electrical power system includes where deactivating the electrical power system includes deactivating the one or more pumps.
- the electrical power system includes where the metallic device is a heating element.
- FIG. 7 a method for operating the electric energy system as shown in FIGS. 1-6 is shown. Portions of method of FIG. 7 may be included as executable instructions stored in non-transitory memory of the system of FIGS. 1-7, while other portions of the method may be performed via humans or robots. In addition, the methods of FIG. 7 may work in cooperation with the system of FIGS. 1-6 to receive data and adjust actuators to control the system of FIGS. 1-6 or external systems in the physical or real world. [0042] At 702, fluidic isolation is provided between a first electrolyte and a second electrolyte. The fluidic isolation may be provided via transporting the first and second electrolytes in closed passages or conduits. Further, the fluidic isolation may be maintained in electric energy storage cells via a membrane. The first and second electrolytes may also be maintained in separate tanks. Method 700 proceeds to 704.
- method 700 provides electrical connectivity between the first electrolyte and the second electrolyte via a metallic device (e.g., a pump housing, pump impeller, heater housing, electrolyte manifold, etc.).
- a metallic device e.g., a pump housing, pump impeller, heater housing, electrolyte manifold, etc.
- the first electrolyte and the second electrolyte may be in direct physical contact with the device.
- Method 700 proceeds to 706.
- method 700 the device is directly coupled to earth ground.
- the device may be directly coupled to a current sense resistor and the current sense resistor may be directly coupled to earth ground.
- a single or sole connection between the electrical power system and earth ground may be made via the device described at 704.
- Method 700 proceeds to 708.
- Vstack- is the voltage at the lowest potential terminal of the IFB cell stack referenced to earth ground
- V oc is the average open circuit cell voltage
- N is the actual total number of cells in the cell stack
- V s tack+ is the voltage at the highest potential terminal of the IFB cell stack referenced to earth ground.
- method 700 judges if operation of the electric power system is desired. Operation of the electric power system may be desired when it is desired for the electric power system to store charge from a power source or when it is desired for the electric power system to deliver charge to an electrical power consumer. Operation of the electric power system may be requested via a switch or via exchange of data between two controllers. If operation of the electric power system is requested, the answer is yes and method 700 proceeds to 710. Otherwise, the answer is no and method 700 proceeds to 720. [0047] At 720, method 700 deactivates one or more electrolyte pumps (e.g., ceases to rotate the pumps and ceases to supply energy to the pumps). Method 700 proceeds to 722.
- electrolyte pumps e.g., ceases to rotate the pumps and ceases to supply energy to the pumps.
- method 700 opens an electrical contactor (e.g., switch) and electrically isolates the electric power system from external power sources and loads. Method 700 proceeds to exit.
- electrical contactor e.g., switch
- method 700 activates one or more electrolyte pumps (e.g., rotates the pumps and supplies energy to the pumps). Method 700 proceeds to 714.
- electrolyte pumps e.g., rotates the pumps and supplies energy to the pumps.
- method 700 closes an electrical contactor and electrically couples the electric power system to external power sources and loads. Method 700 proceeds to 716.
- the electrical power system receives charge from external power systems and/or delivers electrical power to electrical power consumers.
- Method 700 proceeds to exit.
- earth ground may be an electrical potential that may be observed at a metal rod after the metal rod has been driven into the earth’s surface to a predetermined depth.
- the method of FIG. 7 provides for a method for an electric power system, comprising: supplying a first electrolyte a positive reactor of an electric energy storage device and a second electrolyte to a negative reactor of the electric energy storage device, the first electrolyte not in fluidic communication with the second electrolyte; and electrically coupling the first electrolyte to the second electrolyte via a metallic device, the metallic device in physical contact with the first electrolyte and the second electrolyte.
- the method further comprises electrically coupling the metallic device to an earth ground potential.
- the method further comprises deactivating the electric energy storage device in response to an electrical current flowing between the earth ground potential and the metallic device being greater than a threshold electrical current.
- the method further comprises heating the first electrolyte and the second electrolyte via the metallic device.
- the method further comprises supplying the first electrolyte and the second electrolyte via a single pump that includes the metallic device.
- the method includes where the metallic device is an impeller of the single pump.
- control and estimation routines included herein can be used with various power conversion system configurations.
- the control methods and routines disclosed herein may be stored as executable instructions in non-transitory memory and may be carried out by the control system including the controller in combination with the various sensors, actuators, and other system hardware.
- the specific routines described herein may represent one or more of any number of processing strategies such as event-driven, interrupt- driven, multi-tasking, multi-threading, and the like.
- various actions, operations, and/or functions illustrated may be performed in the sequence illustrated, in parallel, or in some cases omitted.
- the order of processing is not necessarily required to achieve the features and advantages of the example embodiments described herein, but is provided for ease of illustration and description.
- One or more of the illustrated actions, operations and/or functions may be repeatedly performed depending on the particular strategy being used. Further, at least a portion of the described actions, operations and/or functions may graphically represent code to be programmed into non-transitory memory of the computer readable storage medium in the control system.
- the control actions may also transform the operating state of one or more sensors or actuators in the physical world when the described actions are carried out by executing the instructions in a system including the various described hardware components in combination with one or more controllers.
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Abstract
Description
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Priority Applications (4)
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JP2021518606A JP7426384B2 (en) | 2018-10-05 | 2019-09-16 | Iron redox flow batteries, power systems and methods |
EP19869405.1A EP3857634A4 (en) | 2018-10-05 | 2019-09-16 | Power delivery system and method |
CN201980079239.3A CN113169357A (en) | 2018-10-05 | 2019-09-16 | Power delivery system and method |
AU2019352859A AU2019352859A1 (en) | 2018-10-05 | 2019-09-16 | Power delivery system and method |
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US16/153,447 US10930949B2 (en) | 2018-10-05 | 2018-10-05 | Power delivery system and method |
US16/153,447 | 2018-10-05 |
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EP (1) | EP3857634A4 (en) |
JP (1) | JP7426384B2 (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
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US11025072B2 (en) | 2018-10-17 | 2021-06-01 | Ess Tech, Inc. | System and method for operating an electrical energy storage system |
US10879544B2 (en) | 2018-11-02 | 2020-12-29 | Ess Tech, Inc. | System and method for determining state of charge for an electric energy storage device |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020144895A1 (en) | 2001-02-15 | 2002-10-10 | Caliper Technologies Corp. | Methods and systems for enhanced fluid delivery of electrical currents to fluidic systems |
WO2006076059A2 (en) * | 2005-01-10 | 2006-07-20 | Vrb Power Systems, Inc. | System and method for optimizing efficiency and power output from a vanadium redox battery energy storage system |
US20110223450A1 (en) * | 2008-07-07 | 2011-09-15 | Enervault Corporation | Cascade Redox Flow Battery Systems |
US20170141420A1 (en) * | 2014-07-08 | 2017-05-18 | Nissan Motor Co., Ltd. | Cell system and control method for cell system |
US20170200936A1 (en) * | 2012-09-05 | 2017-07-13 | Ess Tech, Inc. | Internally manifolded flow cell for an all-iron hybrid flow battery |
US20180175430A1 (en) | 2016-12-19 | 2018-06-21 | Vionx Energy Corporation | Modular and scalable flow battery system |
WO2018129026A1 (en) * | 2017-01-04 | 2018-07-12 | Saudi Arabian Oil Company | Mechanical energy storage in flow batteries to enhance energy storage |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1923220U (en) * | 1965-04-09 | 1965-09-09 | Qvf Glastechnik G M B H | PLASTIC COMPONENT ASSEMBLED WITH A METAL PART, FOR EXAMPLE, PUMP IMPELLER WITH METAL SHAFT. |
FR2254118B1 (en) * | 1973-12-06 | 1980-01-04 | Comp Generale Electricite | |
JPS57180081A (en) * | 1981-04-27 | 1982-11-05 | Agency Of Ind Science & Technol | Piping method for redox-flow type battery |
FI96797C (en) * | 1993-08-10 | 1999-01-19 | Abb Installaatiot Oy | System for cooling the supply air in an air conditioner |
JP3488118B2 (en) * | 1999-02-23 | 2004-01-19 | 住友電気工業株式会社 | Electrolyte circulation device for electrolyte circulation type battery |
JP2000341964A (en) * | 1999-05-28 | 2000-12-08 | Sumitomo Electric Ind Ltd | Multilevel inverter |
EP1287260A1 (en) * | 2000-06-08 | 2003-03-05 | Powercell Corporation | Submersible electrolyte circulation system |
JP2002015762A (en) * | 2000-06-28 | 2002-01-18 | Sumitomo Electric Ind Ltd | Redox flow battery |
US6764782B2 (en) * | 2001-06-14 | 2004-07-20 | General Motors Corporation | Electrical isolation system for a fuel cell stack and method of operating a fuel cell stack |
JP2004162735A (en) * | 2002-11-08 | 2004-06-10 | Sumitomo Electric Ind Ltd | Valve cover |
JP2004265821A (en) * | 2003-03-04 | 2004-09-24 | Sumitomo Electric Ind Ltd | Operation method of redox flow battery, electrode plate for battery, and redox flow battery system |
US10651492B2 (en) * | 2010-06-22 | 2020-05-12 | Vrb Energy Inc. | Integrated system for electrochemical energy storage system |
JP5679520B2 (en) * | 2011-07-19 | 2015-03-04 | 住友電気工業株式会社 | Redox flow battery, |
JP5518038B2 (en) * | 2011-12-26 | 2014-06-11 | 三菱重工業株式会社 | Battery system and ground fault location determination method |
MX2015001279A (en) * | 2012-07-27 | 2015-10-29 | Lockheed Martin Advanced Energy Storage Llc | Electrochemical systems featuring high open circuit potential. |
ES2633572T3 (en) * | 2012-09-18 | 2017-09-22 | Sumitomo Electric Industries, Ltd. | Redox flow battery |
JP6098998B2 (en) | 2013-09-12 | 2017-03-22 | 住友電気工業株式会社 | Battery cell stack and redox flow battery |
DE102014102352A1 (en) * | 2014-02-24 | 2015-08-27 | Ge Energy Power Conversion Technology Limited | Battery storage system with arc fault protection, energy conversion system and protection method |
NO337089B1 (en) * | 2014-03-13 | 2016-01-18 | Defa As | Fluid heating device |
CN203746978U (en) * | 2014-03-31 | 2014-07-30 | 大连融科储能技术发展有限公司 | Flow battery system suitable for outdoor placement |
CN103985893B (en) * | 2014-06-01 | 2017-01-11 | 广东金光高科股份有限公司 | Automatic controller for intermittent work of liquid flow pump of lithium ion flow battery |
AU2018258692B2 (en) | 2017-04-28 | 2023-07-27 | Ess Tech, Inc. | Methods and systems for operating a redox flow battery system |
CN110574200B (en) | 2017-04-28 | 2023-06-06 | Ess技术有限公司 | Methods and systems for rebalancing electrolytes of redox flow battery systems |
US10811993B2 (en) | 2017-12-15 | 2020-10-20 | Ess Tech, Inc. | Power conversion system and method |
-
2018
- 2018-10-05 US US16/153,447 patent/US10930949B2/en active Active
-
2019
- 2019-09-16 CN CN201980079239.3A patent/CN113169357A/en active Pending
- 2019-09-16 EP EP19869405.1A patent/EP3857634A4/en active Pending
- 2019-09-16 WO PCT/US2019/051344 patent/WO2020072190A1/en unknown
- 2019-09-16 AU AU2019352859A patent/AU2019352859A1/en active Pending
- 2019-09-16 JP JP2021518606A patent/JP7426384B2/en active Active
-
2021
- 2021-01-20 US US17/153,766 patent/US11837759B2/en active Active
-
2023
- 2023-10-26 US US18/495,580 patent/US20240063410A1/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020144895A1 (en) | 2001-02-15 | 2002-10-10 | Caliper Technologies Corp. | Methods and systems for enhanced fluid delivery of electrical currents to fluidic systems |
WO2006076059A2 (en) * | 2005-01-10 | 2006-07-20 | Vrb Power Systems, Inc. | System and method for optimizing efficiency and power output from a vanadium redox battery energy storage system |
US20110223450A1 (en) * | 2008-07-07 | 2011-09-15 | Enervault Corporation | Cascade Redox Flow Battery Systems |
US20170200936A1 (en) * | 2012-09-05 | 2017-07-13 | Ess Tech, Inc. | Internally manifolded flow cell for an all-iron hybrid flow battery |
US20170141420A1 (en) * | 2014-07-08 | 2017-05-18 | Nissan Motor Co., Ltd. | Cell system and control method for cell system |
US20180175430A1 (en) | 2016-12-19 | 2018-06-21 | Vionx Energy Corporation | Modular and scalable flow battery system |
WO2018129026A1 (en) * | 2017-01-04 | 2018-07-12 | Saudi Arabian Oil Company | Mechanical energy storage in flow batteries to enhance energy storage |
Non-Patent Citations (1)
Title |
---|
See also references of EP3857634A4 |
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JP2022504262A (en) | 2022-01-13 |
CN113169357A (en) | 2021-07-23 |
US10930949B2 (en) | 2021-02-23 |
EP3857634A4 (en) | 2021-11-24 |
JP7426384B2 (en) | 2024-02-01 |
US20240063410A1 (en) | 2024-02-22 |
US20210210775A1 (en) | 2021-07-08 |
AU2019352859A1 (en) | 2021-05-06 |
EP3857634A1 (en) | 2021-08-04 |
US11837759B2 (en) | 2023-12-05 |
US20200112040A1 (en) | 2020-04-09 |
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