WO2020065909A1 - Slit coater, coating method, and display device production method - Google Patents

Slit coater, coating method, and display device production method Download PDF

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Publication number
WO2020065909A1
WO2020065909A1 PCT/JP2018/036219 JP2018036219W WO2020065909A1 WO 2020065909 A1 WO2020065909 A1 WO 2020065909A1 JP 2018036219 W JP2018036219 W JP 2018036219W WO 2020065909 A1 WO2020065909 A1 WO 2020065909A1
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Prior art keywords
liquid material
discharge port
coater
coated
slit coater
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PCT/JP2018/036219
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French (fr)
Japanese (ja)
Inventor
杉本 宏
哲憲 田中
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シャープ株式会社
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Priority to PCT/JP2018/036219 priority Critical patent/WO2020065909A1/en
Publication of WO2020065909A1 publication Critical patent/WO2020065909A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C5/00Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
    • B05C5/02Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work

Definitions

  • the present invention relates to a slit coater, a coating method, and a method for manufacturing a display device.
  • Patent Document 1 discloses a slit coater for manufacturing a display device.
  • Patent Document 1 In the configuration of Patent Document 1, there is a problem that foreign matter accumulated at the end of the coater head (slit nozzle) is discharged from the discharge port and is applied (discharged) to the substrate (coated surface).
  • a slit coater includes a coater head provided with a supply port through which a liquid material is supplied and a discharge port that discharges the liquid material on a surface to be coated, and both ends in a longitudinal direction of the coater head.
  • a discharge port for discharging the liquid material in the end portion other than the surface to be coated is provided separately from the discharge port.
  • FIG. 5 is a flowchart illustrating an example of a method for manufacturing a display device. It is sectional drawing of the display area of a display device.
  • FIG. 2A is a block diagram illustrating a configuration of the slit coater according to the first embodiment. It is a top view showing composition of a slit coater of Embodiment 1, and (b) is bb sectional drawing of (a). It is a top view which shows the example of a structure of the discharge port and discharge port of a slit coater. (A), (b) is explanatory drawing which shows operation
  • FIG. (A) is a top view showing a modification of the slit coater of Embodiment 1, and (b) is a bb sectional view of (a).
  • (A) is a top view showing a modification of the slit coater of Embodiment 1
  • (b) is a bb sectional view of (a).
  • (A), (b) is sectional drawing which shows the modification of the slit coater of Embodiment 1.
  • FIG. (A) is a block diagram which shows the modification of the slit coater of Embodiment 2
  • (b) is explanatory drawing which shows the operation
  • FIG. 13 is a block diagram illustrating a configuration of a slit coater according to a third embodiment.
  • FIG. 14 is a block diagram illustrating a configuration of a slit coater according to a fourth embodiment.
  • FIG. 1 is a flowchart illustrating an example of a method for manufacturing a display device.
  • FIG. 2A is a cross-sectional view illustrating a configuration on a supporting substrate
  • FIG. 2B is a configuration illustrating a configuration on a lower film. It is sectional drawing.
  • the resin layer 12 is formed on the translucent support substrate 100 (for example, mother glass) (Step S1).
  • the barrier layer 3 is formed (Step S2).
  • the TFT layer 4 is formed (Step S3).
  • a top emission type light emitting element layer 5 is formed (Step S4).
  • the sealing layer 6 is formed (Step S5).
  • an upper surface film is attached on the sealing layer 6 (Step S6).
  • the support substrate 100 is separated from the resin layer 12 by laser light irradiation or the like (Step S7).
  • Step S8 the lower surface film 10 is attached to the lower surface of the resin layer 12 (Step S8).
  • the laminate including the lower film 10, the resin layer 12, the barrier layer 3, the TFT layer 4, the light emitting element layer 5, and the sealing layer 6 is divided to obtain a plurality of pieces (Step S9).
  • the functional film 39 is attached to the obtained individual pieces (Step S10).
  • an electronic circuit board (a driver chip, a flexible printed board, or the like) is mounted on the terminal portion in the frame area (step S11). Steps S1 to S11 are performed by a display device manufacturing apparatus (including a film forming apparatus that performs each step of steps S1 to S5).
  • the barrier layer 3 is a layer that prevents foreign substances such as water, oxygen, and mobile ions from entering the TFT layer 4 and the light emitting element layer 5.
  • the semiconductor layer 15 of the TFT layer 4 can be made of low-temperature polysilicon (LTPS) or an oxide semiconductor (for example, an In-Ga-Zn-O-based semiconductor).
  • the transistor Tr is configured to include the semiconductor layer 15 and the gate electrode GE.
  • the gate electrode GE, the gate wiring GH, the capacitor electrode CE, and the source wiring SH included in the TFT layer 4 are, for example, single-layer metal films containing at least one of aluminum, tungsten, molybdenum, tantalum, chromium, titanium, and copper. Or it is constituted by a multilayer metal film.
  • the inorganic insulating films 16, 18, and 19 can be composed of, for example, a silicon oxide (SiOx) film, a silicon nitride (SiNx) film, or a laminated film of these films formed by a CVD method.
  • the interlayer insulating film 21 can be made of, for example, an applyable organic material such as polyimide or acrylic resin.
  • the light emitting element layer 5 includes the anode 22, an edge cover 23 covering the edge of the anode 22, an EL (electroluminescence) layer 24, and a cathode 25 above the EL layer 24.
  • an applyable organic material such as polyimide or acrylic resin can be used.
  • the display element includes a light-emitting element ES (for example, OLED: organic light-emitting diode, QLED: quantum dot light-emitting diode) formed on the light-emitting element layer 5 including the island-shaped anode 22, the EL layer 24, and the cathode 25; A control circuit for the element ES (formed on the TFT layer 4 and including the transistor Tr).
  • ES light-emitting element
  • ES for example, OLED: organic light-emitting diode, QLED: quantum dot light-emitting diode
  • the EL layer 24 is formed by, for example, stacking a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer in this order from the lower layer side.
  • the light emitting layer is formed in an island shape by an evaporation method or an ink jet method so as to overlap the opening of the third resin layer (edge cover) 23.
  • Other layers are formed in an island shape or a solid shape (common layer). Further, a configuration in which one or more of the hole injection layer, the hole transport layer, the electron transport layer, and the electron injection layer are not formed is also possible.
  • an FMM fine metal mask
  • the FMM is a sheet having a large number of through-holes (for example, made of Invar material), and an island-shaped light-emitting layer (corresponding to one sub-pixel) is formed by an organic substance passing through one through-hole.
  • the light emitting layer of the QLED can form an island-shaped light emitting layer (corresponding to one sub-pixel), for example, by inkjet coating a solvent in which quantum dots are diffused.
  • the anode (anode) 22 is made of, for example, a laminate of ITO (Indium Tin Oxide) and Ag (silver) or an alloy containing Ag, and has light reflectivity.
  • the cathode (cathode) 25 can be made of a light-transmitting conductive material such as an MgAg alloy (extremely thin film), ITO, or IZO (Indium Zinc Oxide).
  • the light emitting element ES is an OLED
  • holes and electrons are recombined in the light emitting layer due to a driving current between the anode 22 and the cathode 25, and light is emitted in a process in which the generated excitons transition to the ground state.
  • the cathode 25 is translucent and the anode 22 is light-reflective, the light emitted from the EL layer 24 is directed upward, resulting in top emission.
  • the light emitting device ES is a QLED
  • holes and electrons are recombined in the light emitting layer due to the driving current between the anode 22 and the cathode 25, and the excitons generated by the recombination generate conduction band levels of the quantum dots.
  • Light (fluorescence) is emitted in the process of transitioning from to the valence band (valence band).
  • a light emitting element (such as an inorganic light emitting diode) other than the OLED and QLED may be formed in the light emitting element layer 5.
  • the sealing layer 6 is translucent, and covers an inorganic sealing film 26 covering the cathode 25, an organic buffer film 27 above the inorganic sealing film 26, and an inorganic sealing film 28 above the organic buffer film 27. And The sealing layer 6 covering the light emitting element layer 5 prevents foreign substances such as water, oxygen, and mobile ions from penetrating into the light emitting element layer 5.
  • the lower surface film 10 is, for example, a PET film for realizing a display device having excellent flexibility by peeling off the support substrate 100 and attaching the lower surface film 10 to the lower surface of the resin layer 12.
  • the functional film 39 has, for example, at least one of an optical compensation function, a touch sensor function, and a protection function.
  • FIG. 3A is a block diagram illustrating a configuration of the slit coater according to the first embodiment.
  • FIG. 4A is a plan view illustrating a configuration of the slit coater according to the first embodiment
  • FIG. 4B is a cross-sectional view taken along line bb of FIG. 4A.
  • FIG. 5 is a plan view showing a configuration example of a discharge port and a discharge port of the slit coater.
  • the slit coater SC is used, for example, in the process of forming the resin layer (resin film) 12, the interlayer insulating film (resin film) 21, and the edge cover (resin film) 23 in FIG.
  • the slit coater SC drives a control unit 40 that controls each unit of the slit coater SC, a coater head 50 that discharges a liquid material (also referred to as a slit nozzle), and a coater head 50.
  • a head driving unit 60 that supplies the liquid material L to the coater head 50; and a recovery mechanism 80 that recovers the liquid material Lh.
  • the coater head 50 has an elongated cylindrical housing, and is set so as to straddle the substrate TK placed on the stage ST. Both ends E1 and E2 in the longitudinal direction of the coater head 50 do not overlap with the substrate TK in plan view.
  • the coater head 50 has a supply port 51 for receiving the supply of the liquid material L from the liquid material supply unit 70, a discharge port 52 for discharging the liquid material Lk to the upper surface (application surface) of the substrate TK, and a longitudinal end of the coater head 50. Discharge ports 53 and 54 are provided for discharging the liquid material Lh (the liquid material likely to include the foreign matter Pz) in the end portions E1 and E2 in the directions.
  • the distance between the discharge port 52 and the upper surface of the substrate TK is 100 ⁇ m to 300 ⁇ m.
  • the substrate TK may be, for example, the support substrate 100 in FIG. 2 or a laminate of the support substrate 100, the resin layer 12, the barrier layer 3, and a part of the TFT layer 4 (up to the source layer including the source wiring SH). Is also good.
  • the liquid material L is, for example, a precursor (polyamic acid) of polyimide.
  • foreign matter Pz silicon-based or metal-based substance
  • foreign matter Pz a substance in which the liquid material is solidified
  • these foreign matter Pz tends to accumulate at the longitudinal ends E1 and E2 of the coater head 50.
  • a discharge port 52 and discharge ports 53 and 54 are provided on the bottom surface of the coater head 50 facing the surface to be coated, and a discharge port 53 is formed at one end E1 of the coater head 50 in the longitudinal direction.
  • An outlet 54 is formed at the end E2.
  • the discharge port 52 is formed in the gap between the discharge ports 53 and 54 so as to be separated from the discharge ports 53 and 54.
  • the supply port 51 is provided at the center of the coater head 50 (a gap between both ends E1 and E2). Providing the supply port 51 at the center makes it easier to adjust the pressure in the head than when it is provided at both ends.
  • the discharge port 52 includes a plurality of discharge slits 52s arranged in the longitudinal direction of the coater head (a direction orthogonal to the coater moving direction), and the discharge port 53 includes a plurality of discharge slits 53s arranged in the longitudinal direction.
  • the discharge port 54 is composed of a plurality of discharge slits 54s arranged in the longitudinal direction.
  • the separation distance Df (longitudinal separation distance) between the discharge port 52 and the discharge ports 53 and 54 is larger than the width dimension Wy (size in the longitudinal direction) of the discharge port. Therefore, it is possible to reliably discharge the liquid material from the discharge ports 53 and 54 while preventing the liquid material from being discharged more than necessary to a portion other than the upper surface of the substrate TK.
  • the opening areas of the discharge slits 53s and 54s are smaller than the opening area of the discharge slit 52s.
  • the width Wy of the discharge ports 53 and 54 is smaller than the width Wx of the discharge port 52, and the width Wd of the discharge slits 53s and 54s is smaller than the width Wk of the discharge slit.
  • the collection mechanism 80 includes a storage section 83 for receiving the liquid material Lh discharged below the discharge ports 53 and 54, and a discharge pipe section 84 for flowing the stored liquid material Lh.
  • the head driving section 60 drives the coater head 50 in the direction of the arrow in FIG. 4A (downward in the figure) based on the instruction signal from the control section 40.
  • the liquid material supply unit 70 supplies the liquid material L to the coater head 50 from a liquid material tank (not shown) based on an instruction signal from the control unit 40.
  • FIGS. 6A and 6B are explanatory diagrams showing the operation of the slit coater of the first embodiment.
  • the liquid material Lh including the foreign matter Pz is discharged from the discharge ports 53 and 54 and stored in the storage section 83 during the application period in which the liquid material Lk is coated on the substrate TK.
  • the possibility that the foreign matter Pz in the coater head 50 is discharged from the discharge port 52 and applied to the substrate TK is reduced.
  • the discharge slits 53s and 54s of the discharge ports 53 and 54 the liquid material at the end is discharged from the discharge slits 53s and 54s by the pressure in the head during the coating period (the pressure of the liquid material filled in the coater head). Shape.
  • the liquid material Lh may not be discharged during the application period, and may be discharged from the discharge ports 53 and 54 during a maintenance period provided after the application period.
  • the discharge slits 53s and 54s of the discharge ports 53 and 54 are formed so that the liquid material Lh is not discharged from the discharge ports 53 and 54 by the pressure in the head during the application period.
  • the pressure in the head is set higher than that in the application period, and the liquid material Lh at the end is discharged from the outlets 53 and 54.
  • FIG. 7 (a) is a plan view showing a modification of the slit coater of Embodiment 1
  • FIG. 7 (b) is a cross-sectional view taken along the line bb of FIG. 7 (a).
  • a discharge port 53 can be provided only at one end E1 of the coater head 50.
  • FIG. 8A is a plan view showing a modification of the slit coater according to the first embodiment
  • FIG. 8B is a cross-sectional view taken along line bb of FIG.
  • the outlets 53 and 54 are provided on the bottom surface of the coater head 50, but the present invention is not limited to this.
  • discharge ports 53 and 54 may be provided on two side surfaces (both side surfaces perpendicular to the bottom surface) of the coater head 50 facing in the longitudinal direction.
  • FIGS. 9A and 9B are cross-sectional views showing a modification of the slit coater of the first embodiment.
  • a housing 83 that wraps the outlets 53 and 54 (formed on the bottom surfaces of both ends E1 and E2) of the coater head 50 may be attached to the coater head 50
  • a housing 83 that wraps the outlets 53 and 54 (formed on the side surfaces of both ends E1 and E2) of the coater head 50 may be attached to the coater head 50.
  • FIG. 10A is a block diagram illustrating a modified example of the slit coater according to the second embodiment
  • FIG. 10B is an explanatory diagram illustrating an operation of the slit coater illustrated in FIG.
  • the liquid material Lh at the end is discharged from the outlets 53 and 54, but is not limited thereto.
  • a suction unit 81 is provided in the collection mechanism 80, and during the maintenance period after the application period (for example, after applying a predetermined number of substrates), the liquid material Lh at the end is discharged to the outlets 53 and 54. It can also be sucked out and discharged. Note that, during the application period, the liquid material Lh at the end can be sucked and discharged from the discharge ports 53 and 54.
  • FIG. 11 is a block diagram illustrating a configuration of the slit coater according to the third embodiment.
  • FIG. 12A is a plan view showing the configuration of the slit coater according to the third embodiment
  • FIG. 12B is a cross-sectional view taken along line bb of FIG. 12A.
  • the collection unit 80 is provided with the transport units 82a and 82b.
  • the transport unit 82a includes a plurality of rollers Ra arranged in the traveling direction below the coater head 50, intersects one end E1 of the coater head 50, and overlaps the discharge port 53 in a plan view.
  • the transport section 82b includes a plurality of rollers Rb arranged in the traveling direction below the coater head 50, crosses the other end E2 of the coater head 50, and overlaps the discharge port 54 in a plan view.
  • the liquid material Lh discharged from the discharge ports 53 and 54 is transported by the rotating rollers Ra and Rb, and is collected in the storage unit 83. Thereby, the discharge efficiency from the discharge ports 53 and 54 can be increased, and the rebound of the liquid material can be prevented.
  • the discharge of the liquid material Lh may be performed during the application period as shown in FIG. 6A, or may be performed during the maintenance period as shown in FIG. 6B.
  • the top positions (vertical positions) of the plurality of rollers Ra and Rb may be lower than the outlets 53 and 54, but the top positions of the rollers Ra and Rb are determined by the level of the upper surface (coated surface) of the substrate TK. (Vertical position).
  • FIG. 13 is a block diagram illustrating a configuration of the slit coater according to the fourth embodiment.
  • a recycling unit 85 is provided in the collection mechanism 80.
  • the recycling unit 85 removes foreign matter by passing the liquid material Lh collected through the storage unit 83 and the drainage unit 84 through a filter, and returns the liquid material Lc containing no foreign matter to the liquid material supply unit 70. This eliminates waste of the liquid material and can reduce the cost.
  • liquid material L a polyimide precursor is mentioned, but it is not limited to this. Any liquid material that can be applied on the substrate may be used. For example, a resist material used in the film forming step of FIG. 1 may be used.
  • the plurality of discharge slits 52s functioning as the discharge ports 52 are provided in the coater head 50, but the present invention is not limited to this.
  • the number of the discharge slits 52s may be one.
  • a plurality of discharge slits 53s or a plurality of discharge slits 54s are provided at both ends of the coater head 50, but the present invention is not limited to this.
  • One discharge slit may be provided at each end.
  • ⁇ A form in which a plurality of forms in the first to fourth embodiments are combined is also included in the present embodiment.
  • the bottom surface of the coater head faces the surface to be coated,
  • the bottom surface of the coater head faces the surface to be coated,
  • a coater head including a supply port to which a liquid material is supplied and a discharge port for discharging the liquid material on a surface to be coated is provided, and at least one of both ends in the longitudinal direction of the coater head has an end portion other than the surface to be coated.
  • a method for manufacturing a display device including a resin film In the step of forming the resin film, a coater head including a supply port to which a liquid material as a resin material is supplied and a discharge port for discharging the liquid material on a surface to be coated is provided, and both ends in a longitudinal direction of the coater head.
  • the discharge material for discharging the liquid material in the end portion other than the surface to be coated is provided with a slit coater provided apart from the discharge port, and the liquid material is discharged from the discharge port to the surface to be coated.

Abstract

This slit coater comprises a coater head (50) that is provided with a feed port (51) to which a liquid material is supplied and with a dispensing port (52) for dispensing the liquid material on a surface that is being coated. On at least one of the two ends (E1, E2) of the coater head in the longitudinal direction, a discharge port (53, 54) for discharging liquid material (Lh), which is inside the end, to the outside of the surface being coated is provided so as to be separated from the dispensing port (52).

Description

スリットコータ、塗布方法、表示デバイスの製造方法Slit coater, coating method, display device manufacturing method
 本発明は、スリットコータ、塗布方法、及び表示デバイスの製造方法に関する。 The present invention relates to a slit coater, a coating method, and a method for manufacturing a display device.
 特許文献1には、表示デバイスを製造するためのスリットコータが開示されている。 Patent Document 1 discloses a slit coater for manufacturing a display device.
日本国公開特許公報「特開2007-203293(2007年8月16日)公開」Japanese Unexamined Patent Publication "Japanese Patent Application Laid-Open No. 2007-203293 (August 16, 2007)"
 特許文献1の構成では、コータヘッド(スリットノズル)の端部に溜まった異物が吐出口から吐き出され、基板(被塗布面)に塗布(吐出)される問題を生じることがある。 構成 In the configuration of Patent Document 1, there is a problem that foreign matter accumulated at the end of the coater head (slit nozzle) is discharged from the discharge port and is applied (discharged) to the substrate (coated surface).
 本発明の一態様のスリットコータは、液材が供給される供給口と、被塗布面に前記液材を吐出する吐出口とが設けられたコータヘッドを備え、前記コータヘッドの長手方向の両端部の少なくとも一方に、前記被塗布面以外に端部内の液材を排出する排出口が、前記吐出口から離間して設けられている。 A slit coater according to one embodiment of the present invention includes a coater head provided with a supply port through which a liquid material is supplied and a discharge port that discharges the liquid material on a surface to be coated, and both ends in a longitudinal direction of the coater head. In at least one of the portions, a discharge port for discharging the liquid material in the end portion other than the surface to be coated is provided separately from the discharge port.
 本発明の一態様によれば、コータヘッド内の異物が被塗布面に吐出されるのを防止することができる。 According to one aspect of the present invention, it is possible to prevent foreign matter in the coater head from being discharged to the surface to be coated.
表示デバイスの製造方法の一例を示すフローチャートである。5 is a flowchart illustrating an example of a method for manufacturing a display device. 表示デバイスの表示領域の断面図である。It is sectional drawing of the display area of a display device. (a)は実施形態1のスリットコータの構成を示すブロック図である。FIG. 2A is a block diagram illustrating a configuration of the slit coater according to the first embodiment. 実施形態1のスリットコータの構成を示す平面図であり、(b)は、(a)のb-b断面図である。It is a top view showing composition of a slit coater of Embodiment 1, and (b) is bb sectional drawing of (a). スリットコータの吐出口および排出口の構成例を示す平面図である。It is a top view which shows the example of a structure of the discharge port and discharge port of a slit coater. (a)(b)は、実施形態1のスリットコータの動作を示す説明図である。(A), (b) is explanatory drawing which shows operation | movement of the slit coater of Embodiment 1. FIG. (a)は、実施形態1のスリットコータの変形例を示す平面図であり、(b)は、(a)のb-b断面図である。(A) is a top view showing a modification of the slit coater of Embodiment 1, and (b) is a bb sectional view of (a). (a)は、実施形態1のスリットコータの変形例を示す平面図であり、(b)は、(a)のb-b断面図である。(A) is a top view showing a modification of the slit coater of Embodiment 1, and (b) is a bb sectional view of (a). (a)(b)は、実施形態1のスリットコータの変形例を示す断面図である。(A), (b) is sectional drawing which shows the modification of the slit coater of Embodiment 1. FIG. (a)は、実施形態2のスリットコータの変形例を示すブロック図であり、(b)は、(a)のスリットコータの動作を示す説明図である。(A) is a block diagram which shows the modification of the slit coater of Embodiment 2, (b) is explanatory drawing which shows the operation | movement of the slit coater of (a). 実施形態3のスリットコータの構成を示すブロック図である。FIG. 13 is a block diagram illustrating a configuration of a slit coater according to a third embodiment. (a)は、実施形態3のスリットコータの構成を示す平面図であり、(b)は、(a)のb-b断面図である。(A) is a plan view showing the configuration of the slit coater of Embodiment 3, and (b) is a bb cross-sectional view of (a). 実施形態4のスリットコータの構成を示すブロック図である。FIG. 14 is a block diagram illustrating a configuration of a slit coater according to a fourth embodiment.
 図1は、表示デバイスの製造方法の一例を示すフローチャートであり、図2(a)は、支持基板上の構成を示す断面図であり、図2(b)は、下面フィルム上の構成を示す断面図である。 FIG. 1 is a flowchart illustrating an example of a method for manufacturing a display device. FIG. 2A is a cross-sectional view illustrating a configuration on a supporting substrate, and FIG. 2B is a configuration illustrating a configuration on a lower film. It is sectional drawing.
 図1・図2に示すように、フレキシブルな表示デバイス2を製造する場合、まず、透光性の支持基板100(例えば、マザーガラス)上に樹脂層12を形成する(ステップS1)。次いで、バリア層3を形成する(ステップS2)。次いで、TFT層4を形成する(ステップS3)。次いで、トップエミッション型の発光素子層5を形成する(ステップS4)。これにより、表示領域に発光素子ESが形成される。次いで、封止層6を形成する(ステップS5)。次いで、封止層6上に上面フィルムを貼り付ける(ステップS6)。次いで、レーザ光の照射等によって支持基板100を樹脂層12から剥離する(ステップS7)。次いで、樹脂層12の下面に下面フィルム10を貼り付ける(ステップS8)。次いで、下面フィルム10、樹脂層12、バリア層3、TFT層4、発光素子層5、封止層6を含む積層体を分断し、複数の個片を得る(ステップS9)。次いで、得られた個片に機能フィルム39を貼り付ける(ステップS10)。次いで、額縁領域の端子部に、電子回路基板(ドライバチップ、フレキシブルプリント基板等)を実装する(ステップS11)。なお、ステップS1~S11は、表示デバイス製造装置(ステップS1~S5の各工程を行う成膜装置を含む)が行う。 As shown in FIGS. 1 and 2, when manufacturing the flexible display device 2, first, the resin layer 12 is formed on the translucent support substrate 100 (for example, mother glass) (Step S1). Next, the barrier layer 3 is formed (Step S2). Next, the TFT layer 4 is formed (Step S3). Next, a top emission type light emitting element layer 5 is formed (Step S4). Thereby, the light emitting element ES is formed in the display area. Next, the sealing layer 6 is formed (Step S5). Next, an upper surface film is attached on the sealing layer 6 (Step S6). Next, the support substrate 100 is separated from the resin layer 12 by laser light irradiation or the like (Step S7). Next, the lower surface film 10 is attached to the lower surface of the resin layer 12 (Step S8). Next, the laminate including the lower film 10, the resin layer 12, the barrier layer 3, the TFT layer 4, the light emitting element layer 5, and the sealing layer 6 is divided to obtain a plurality of pieces (Step S9). Next, the functional film 39 is attached to the obtained individual pieces (Step S10). Next, an electronic circuit board (a driver chip, a flexible printed board, or the like) is mounted on the terminal portion in the frame area (step S11). Steps S1 to S11 are performed by a display device manufacturing apparatus (including a film forming apparatus that performs each step of steps S1 to S5).
 樹脂層12の材料としては、例えばポリイミド等が挙げられる。バリア層3は、水、酸素、可動イオン等の異物がTFT層4および発光素子層5に侵入することを防ぐ層であり、例えば、CVD法により形成される、酸化シリコン膜、窒化シリコン膜、あるいは酸窒化シリコン膜、またはこれらの積層膜で構成することができる。 ポ リ イ ミ ド As a material of the resin layer 12, for example, polyimide or the like can be used. The barrier layer 3 is a layer that prevents foreign substances such as water, oxygen, and mobile ions from entering the TFT layer 4 and the light emitting element layer 5. For example, a silicon oxide film, a silicon nitride film, Alternatively, it can be composed of a silicon oxynitride film or a stacked film of these.
 TFT層4の半導体層15には、低温ポリシリコン(LTPS)あるいは酸化物半導体(例えば、In-Ga-Zn-O系の半導体)を用いることができる。半導体層15およびゲート電極GEを含むようにトランジスタTrが構成される。 低温 The semiconductor layer 15 of the TFT layer 4 can be made of low-temperature polysilicon (LTPS) or an oxide semiconductor (for example, an In-Ga-Zn-O-based semiconductor). The transistor Tr is configured to include the semiconductor layer 15 and the gate electrode GE.
 TFT層4に含まれる、ゲート電極GE、ゲート配線GH、容量電極CE、およびソース配線SHは、例えば、アルミニウム、タングステン、モリブデン、タンタル、クロム、チタン、銅の少なくとも1つを含む単層金属膜あるいは複層金属膜によって構成される。 The gate electrode GE, the gate wiring GH, the capacitor electrode CE, and the source wiring SH included in the TFT layer 4 are, for example, single-layer metal films containing at least one of aluminum, tungsten, molybdenum, tantalum, chromium, titanium, and copper. Or it is constituted by a multilayer metal film.
 無機絶縁膜16・18・19は、例えば、CVD法によって形成された、酸化シリコン(SiOx)膜あるいは窒化シリコン(SiNx)膜またはこれらの積層膜によって構成することができる。層間絶縁膜21は、例えば、ポリイミド、アクリル樹脂等の塗布可能な有機材料によって構成することができる。 (4) The inorganic insulating films 16, 18, and 19 can be composed of, for example, a silicon oxide (SiOx) film, a silicon nitride (SiNx) film, or a laminated film of these films formed by a CVD method. The interlayer insulating film 21 can be made of, for example, an applyable organic material such as polyimide or acrylic resin.
 発光素子層5は、アノード22と、アノード22のエッジを覆うエッジカバー23と、EL(エレクトロルミネッセンス)層24と、EL層24よりも上層のカソード25とを含む。エッジカバー23には、例えば、ポリイミド、アクリル樹脂等の塗布可能な有機材料を用いることができる。 The light emitting element layer 5 includes the anode 22, an edge cover 23 covering the edge of the anode 22, an EL (electroluminescence) layer 24, and a cathode 25 above the EL layer 24. For the edge cover 23, for example, an applyable organic material such as polyimide or acrylic resin can be used.
 表示領域では、サブ画素ごとに表示素子が設けられる。表示素子は、島状のアノード22、EL層24、およびカソード25を含んで発光素子層5に形成される発光素子ES(例えば、OLED:有機発光ダイオード、QLED:量子ドット発光ダイオード)と、発光素子ESの制御回路(TFT層4に形成され、トランジスタTrを含む)とで構成される。 表示 In the display area, a display element is provided for each sub-pixel. The display element includes a light-emitting element ES (for example, OLED: organic light-emitting diode, QLED: quantum dot light-emitting diode) formed on the light-emitting element layer 5 including the island-shaped anode 22, the EL layer 24, and the cathode 25; A control circuit for the element ES (formed on the TFT layer 4 and including the transistor Tr).
 EL層24は、例えば、下層側から順に、正孔注入層、正孔輸送層、発光層、電子輸送層、電子注入層を積層することで構成される。発光層は、蒸着法あるいはインクジェット法によって、第3樹脂層(エッジカバー)23の開口に重なるように島状に形成される。他の層は、島状あるいはベタ状(共通層)に形成する。また、正孔注入層、正孔輸送層、電子輸送層、電子注入層のうち1以上の層を形成しない構成も可能である。 The EL layer 24 is formed by, for example, stacking a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer in this order from the lower layer side. The light emitting layer is formed in an island shape by an evaporation method or an ink jet method so as to overlap the opening of the third resin layer (edge cover) 23. Other layers are formed in an island shape or a solid shape (common layer). Further, a configuration in which one or more of the hole injection layer, the hole transport layer, the electron transport layer, and the electron injection layer are not formed is also possible.
 OLEDの発光層を蒸着形成する場合は、FMM(ファインメタルマスク)を用いる。FMMは多数の貫通孔を有するシート(例えば、インバー材製)であり、1つの貫通孔を通過した有機物質によって島状の発光層(1つのサブ画素に対応)が形成される。 In the case where the light emitting layer of the OLED is formed by vapor deposition, an FMM (fine metal mask) is used. The FMM is a sheet having a large number of through-holes (for example, made of Invar material), and an island-shaped light-emitting layer (corresponding to one sub-pixel) is formed by an organic substance passing through one through-hole.
 QLEDの発光層は、例えば、量子ドットを拡散させた溶媒をインクジェット塗布することで、島状の発光層(1つのサブ画素に対応)を形成することができる。 The light emitting layer of the QLED can form an island-shaped light emitting layer (corresponding to one sub-pixel), for example, by inkjet coating a solvent in which quantum dots are diffused.
 アノード(陽極)22は、例えばITO(Indium Tin Oxide)とAg(銀)あるいはAgを含む合金との積層によって構成され、光反射性を有する。カソード(陰極)25は、MgAg合金(極薄膜)、ITO、IZO(Indium zinc Oxide)等の透光性の導電材で構成することができる。 The anode (anode) 22 is made of, for example, a laminate of ITO (Indium Tin Oxide) and Ag (silver) or an alloy containing Ag, and has light reflectivity. The cathode (cathode) 25 can be made of a light-transmitting conductive material such as an MgAg alloy (extremely thin film), ITO, or IZO (Indium Zinc Oxide).
 発光素子ESがOLEDである場合、アノード22およびカソード25間の駆動電流によって正孔と電子が発光層内で再結合し、これによって生じたエキシトンが基底状態に遷移する過程で光が放出される。カソード25が透光性であり、アノード22が光反射性であるため、EL層24から放出された光は上方に向かい、トップエミッションとなる。 When the light emitting element ES is an OLED, holes and electrons are recombined in the light emitting layer due to a driving current between the anode 22 and the cathode 25, and light is emitted in a process in which the generated excitons transition to the ground state. . Since the cathode 25 is translucent and the anode 22 is light-reflective, the light emitted from the EL layer 24 is directed upward, resulting in top emission.
 発光素子ESがQLEDである場合、アノード22およびカソード25間の駆動電流によって正孔と電子が発光層内で再結合し、これによって生じたエキシトンが、量子ドットの伝導帯準位(conduction band)から価電子帯準位(valence band)に遷移する過程で光(蛍光)が放出される。 When the light emitting device ES is a QLED, holes and electrons are recombined in the light emitting layer due to the driving current between the anode 22 and the cathode 25, and the excitons generated by the recombination generate conduction band levels of the quantum dots. Light (fluorescence) is emitted in the process of transitioning from to the valence band (valence band).
 発光素子層5には、前記のOLED、QLED以外の発光素子(無機発光ダイオード等)を形成してもよい。 発 光 A light emitting element (such as an inorganic light emitting diode) other than the OLED and QLED may be formed in the light emitting element layer 5.
 封止層6は透光性であり、カソード25を覆う無機封止膜26と、無機封止膜26よりも上層の有機バッファ膜27と、有機バッファ膜27よりも上層の無機封止膜28とを含む。発光素子層5を覆う封止層6は、水、酸素、可動イオン等の異物の発光素子層5への浸透を防いでいる。 The sealing layer 6 is translucent, and covers an inorganic sealing film 26 covering the cathode 25, an organic buffer film 27 above the inorganic sealing film 26, and an inorganic sealing film 28 above the organic buffer film 27. And The sealing layer 6 covering the light emitting element layer 5 prevents foreign substances such as water, oxygen, and mobile ions from penetrating into the light emitting element layer 5.
 下面フィルム10は、支持基板100を剥離した後に樹脂層12の下面に貼り付けることで柔軟性に優れた表示デバイスを実現するための、例えばPETフィルムである。機能フィルム39は、例えば、光学補償機能、タッチセンサ機能、保護機能の少なくとも1つを有する。 The lower surface film 10 is, for example, a PET film for realizing a display device having excellent flexibility by peeling off the support substrate 100 and attaching the lower surface film 10 to the lower surface of the resin layer 12. The functional film 39 has, for example, at least one of an optical compensation function, a touch sensor function, and a protection function.
 〔実施形態1〕
 図3(a)は実施形態1のスリットコータの構成を示すブロック図である。図4(a)は、実施形態1のスリットコータの構成を示す平面図であり、図4(b)は、図4(a)のb-b断面図である。図5は、スリットコータの吐出口および排出口の構成例を示す平面図である。
[Embodiment 1]
FIG. 3A is a block diagram illustrating a configuration of the slit coater according to the first embodiment. FIG. 4A is a plan view illustrating a configuration of the slit coater according to the first embodiment, and FIG. 4B is a cross-sectional view taken along line bb of FIG. 4A. FIG. 5 is a plan view showing a configuration example of a discharge port and a discharge port of the slit coater.
 スリットコータSCは、例えば、図2の樹脂層(樹脂膜)12、層間絶縁膜(樹脂膜)21、エッジカバー(樹脂膜)23の形成工程で用いる。 The slit coater SC is used, for example, in the process of forming the resin layer (resin film) 12, the interlayer insulating film (resin film) 21, and the edge cover (resin film) 23 in FIG.
 図3・図4に示すように、スリットコータSCは、当該スリットコータSCの各部を制御する制御部40と、液材を吐出するコータヘッド50(スリットノズルとも称する)と、コータヘッド50を駆動するヘッド駆動部60と、コータヘッド50に液材Lを供給する液材供給部70と、液材Lhを回収する回収機構80とを備える。 As shown in FIGS. 3 and 4, the slit coater SC drives a control unit 40 that controls each unit of the slit coater SC, a coater head 50 that discharges a liquid material (also referred to as a slit nozzle), and a coater head 50. A head driving unit 60 that supplies the liquid material L to the coater head 50; and a recovery mechanism 80 that recovers the liquid material Lh.
 コータヘッド50は、細長の筒状筐体を有し、ステージSTに載置された基板TKを跨ぐようにセットされる。コータヘッド50の長手方向の両端部E1・E2は、平面視において基板TKと重ならない。 The coater head 50 has an elongated cylindrical housing, and is set so as to straddle the substrate TK placed on the stage ST. Both ends E1 and E2 in the longitudinal direction of the coater head 50 do not overlap with the substrate TK in plan view.
 コータヘッド50には、液材供給部70から液材Lの供給を受ける供給口51と、基板TKの上面(被塗布面)に液材Lkを吐出する吐出口52と、コータヘッド50の長手方向の端部E1・E2内の液材Lh(異物Pzを含むおそれが高い液材)を排出する排出口53・54とが設けられる。吐出口52と基板TKの上面との距離は、100μm~300μmである。 The coater head 50 has a supply port 51 for receiving the supply of the liquid material L from the liquid material supply unit 70, a discharge port 52 for discharging the liquid material Lk to the upper surface (application surface) of the substrate TK, and a longitudinal end of the coater head 50. Discharge ports 53 and 54 are provided for discharging the liquid material Lh (the liquid material likely to include the foreign matter Pz) in the end portions E1 and E2 in the directions. The distance between the discharge port 52 and the upper surface of the substrate TK is 100 μm to 300 μm.
 基板TKは、例えば、図2の支持基板100でもよいし、支持基板100、樹脂層12、バリア層3およびTFT層4の一部(ソース配線SHを含むソースレイアまで)の積層体であってもよい。 The substrate TK may be, for example, the support substrate 100 in FIG. 2 or a laminate of the support substrate 100, the resin layer 12, the barrier layer 3, and a part of the TFT layer 4 (up to the source layer including the source wiring SH). Is also good.
 液材Lは、例えば、ポリイミドの前駆体(ポリアミック酸)であるが、液材供給部70から供給される液材Lに異物Pz(ケイ素系や金属系の物質)が混入している場合があり、加えて、コータヘッド50の止液領域でも異物Pz(液材が固形化した物質)が生じることもあり、これら異物Pzは、コータヘッド50の長手方向の端部E1・E2に溜まり易い。 The liquid material L is, for example, a precursor (polyamic acid) of polyimide. However, there is a case where foreign matter Pz (silicon-based or metal-based substance) is mixed in the liquid material L supplied from the liquid material supply unit 70. In addition, in addition, foreign matter Pz (a substance in which the liquid material is solidified) may be generated even in the liquid stopping area of the coater head 50, and these foreign matter Pz tends to accumulate at the longitudinal ends E1 and E2 of the coater head 50. .
 図4では、被塗布面と対向する、コータヘッド50の底面に、吐出口52および排出口53・54が設けられ、コータヘッド50の長手方向の一端部E1に排出口53が形成され、他端部E2に排出口54が形成される。吐出口52は、排出口53・54の間隙に、排出口53・54から離間するように形成される。
供給口51は、コータヘッド50の中央部(両端部E1・E2の間隙)に設けられる。供給口51を中央部に設けることで、両端部に設ける場合よりもヘッド内の圧力調整が容易になる。
In FIG. 4, a discharge port 52 and discharge ports 53 and 54 are provided on the bottom surface of the coater head 50 facing the surface to be coated, and a discharge port 53 is formed at one end E1 of the coater head 50 in the longitudinal direction. An outlet 54 is formed at the end E2. The discharge port 52 is formed in the gap between the discharge ports 53 and 54 so as to be separated from the discharge ports 53 and 54.
The supply port 51 is provided at the center of the coater head 50 (a gap between both ends E1 and E2). Providing the supply port 51 at the center makes it easier to adjust the pressure in the head than when it is provided at both ends.
 図5に示すように、吐出口52は、コータヘッドの長手方向(コータ移動方向に直交する方向)に並ぶ複数の吐出スリット52sからなり、排出口53は、長手方向に並ぶ複数の排出スリット53sからなり、排出口54は、長手方向に並ぶ複数の排出スリット54sからなる。吐出口52と排出口53・54との離間距離Df(長手方向の離間距離)は、排出口の幅寸法Wy(長手方向のサイズ)よりも大きい。よって、基板TKの上面以外の箇所に対して、必要以上に液材が排出されるのを防ぎつつ、排出口53・54から確実に液材を排出することができる。 As shown in FIG. 5, the discharge port 52 includes a plurality of discharge slits 52s arranged in the longitudinal direction of the coater head (a direction orthogonal to the coater moving direction), and the discharge port 53 includes a plurality of discharge slits 53s arranged in the longitudinal direction. The discharge port 54 is composed of a plurality of discharge slits 54s arranged in the longitudinal direction. The separation distance Df (longitudinal separation distance) between the discharge port 52 and the discharge ports 53 and 54 is larger than the width dimension Wy (size in the longitudinal direction) of the discharge port. Therefore, it is possible to reliably discharge the liquid material from the discharge ports 53 and 54 while preventing the liquid material from being discharged more than necessary to a portion other than the upper surface of the substrate TK.
 また、排出スリット53s・54sの開口面積は、吐出スリット52sの開口面積よりも小さい。なお、排出口53・54の幅寸法Wyは、吐出口52の幅寸法Wxよりも小さく、排出スリット53s・54sの幅寸法Wdは、吐出スリットの幅寸法Wkよりも小さい。 開口 The opening areas of the discharge slits 53s and 54s are smaller than the opening area of the discharge slit 52s. The width Wy of the discharge ports 53 and 54 is smaller than the width Wx of the discharge port 52, and the width Wd of the discharge slits 53s and 54s is smaller than the width Wk of the discharge slit.
 回収機構80は、排出口53・54の下方において排出された液材Lhを受ける収容部83と、収容された液材Lhを流すための排管部84とを含む。 The collection mechanism 80 includes a storage section 83 for receiving the liquid material Lh discharged below the discharge ports 53 and 54, and a discharge pipe section 84 for flowing the stored liquid material Lh.
 ヘッド駆動部60は、制御部40からの指示信号に基づいて、コータヘッド50を、図4(a)の矢印方向(図の下側)に駆動させる。液材供給部70は、制御部40からの指示信号に基づいて、図略の液材槽から液材Lをコータヘッド50に供給する。 (4) The head driving section 60 drives the coater head 50 in the direction of the arrow in FIG. 4A (downward in the figure) based on the instruction signal from the control section 40. The liquid material supply unit 70 supplies the liquid material L to the coater head 50 from a liquid material tank (not shown) based on an instruction signal from the control unit 40.
 図6(a)(b)は、実施形態1のスリットコータの動作を示す説明図である。図6(a)の場合、基板TKに液材Lkを塗布する塗布期間に、排出口53・54から異物Pzを含む液材Lhが排出され、収容部83に収容される。これにより、コータヘッド50内の異物Pzが吐出口52から吐出され、基板TKに塗布されるおそれが低減する。排出口53・54の排出スリット53s・54sについては、塗布期間のヘッド内圧力(コータヘッド内に充填される液材の圧力)で端部の液材が排出スリット53s・54sから吐出されるような形状とする。 FIGS. 6A and 6B are explanatory diagrams showing the operation of the slit coater of the first embodiment. In the case of FIG. 6A, the liquid material Lh including the foreign matter Pz is discharged from the discharge ports 53 and 54 and stored in the storage section 83 during the application period in which the liquid material Lk is coated on the substrate TK. Thereby, the possibility that the foreign matter Pz in the coater head 50 is discharged from the discharge port 52 and applied to the substrate TK is reduced. Regarding the discharge slits 53s and 54s of the discharge ports 53 and 54, the liquid material at the end is discharged from the discharge slits 53s and 54s by the pressure in the head during the coating period (the pressure of the liquid material filled in the coater head). Shape.
 図6(b)のように、塗布期間には液材Lhの排出をせず、塗布期間後に設けられるメンテナンス期間に排出口53・54から液材Lhを排出させてもよい。排出口53・54の排出スリット53s・54sについては、塗布期間のヘッド内圧力で液材Lhが排出口53・54から吐出されない形状とする。また、メンテナンス期間には、塗布期間よりもヘッド内圧力を高めて、端部の液材Lhを排出口53・54から吐出させる。このとき、吐出口52からも液材が吐出されるため、ステージSTを汚さないように収容パンあるいはダミー基板を載置しておくことが望ましい。 As shown in FIG. 6B, the liquid material Lh may not be discharged during the application period, and may be discharged from the discharge ports 53 and 54 during a maintenance period provided after the application period. The discharge slits 53s and 54s of the discharge ports 53 and 54 are formed so that the liquid material Lh is not discharged from the discharge ports 53 and 54 by the pressure in the head during the application period. In the maintenance period, the pressure in the head is set higher than that in the application period, and the liquid material Lh at the end is discharged from the outlets 53 and 54. At this time, since the liquid material is also discharged from the discharge port 52, it is desirable to place a storage pan or a dummy substrate so as not to stain the stage ST.
 図7(a)は、実施形態1のスリットコータの変形例を示す平面図であり、図7(b)は、図7(a)のb-b断面図である。図7に示すように、コータヘッド50の片側の端部E1にだけ排出口53を設けることもできる。 7 (a) is a plan view showing a modification of the slit coater of Embodiment 1, and FIG. 7 (b) is a cross-sectional view taken along the line bb of FIG. 7 (a). As shown in FIG. 7, a discharge port 53 can be provided only at one end E1 of the coater head 50.
 図8(a)は、実施形態1のスリットコータの変形例を示す平面図であり、図8(b)は、(a)のb-b断面図である。図4では、コータヘッド50の底面に排出口53・54を設けているがこれに限定されない。図8に示すように、コータヘッド50の長手方向に向かい合う2つの側面(底面に垂直な両側面)に排出口53・54を設けることもできる。 FIG. 8A is a plan view showing a modification of the slit coater according to the first embodiment, and FIG. 8B is a cross-sectional view taken along line bb of FIG. In FIG. 4, the outlets 53 and 54 are provided on the bottom surface of the coater head 50, but the present invention is not limited to this. As shown in FIG. 8, discharge ports 53 and 54 may be provided on two side surfaces (both side surfaces perpendicular to the bottom surface) of the coater head 50 facing in the longitudinal direction.
 図9(a)(b)は、実施形態1のスリットコータの変形例を示す断面図である。図9(a)のように、コータヘッド50の排出口53・54(両端部E1・E2の底面に形成されている)を包むような収容部83をコータヘッド50に取り付けてもよいし、図9(b)のように、コータヘッド50の排出口53・54(両端部E1・E2の側面に形成されている)を包むような収容部83をコータヘッド50に取り付けてもよい。 FIGS. 9A and 9B are cross-sectional views showing a modification of the slit coater of the first embodiment. As shown in FIG. 9A, a housing 83 that wraps the outlets 53 and 54 (formed on the bottom surfaces of both ends E1 and E2) of the coater head 50 may be attached to the coater head 50, As shown in FIG. 9B, a housing 83 that wraps the outlets 53 and 54 (formed on the side surfaces of both ends E1 and E2) of the coater head 50 may be attached to the coater head 50.
 〔実施形態2〕
 図10(a)は実施形態2のスリットコータの変形例を示すブロック図であり、図10(b)は、(a)のスリットコータの動作を示す説明図である。実施形態1では、端部の液材Lhを排出口53・54から吐出させているが、これに限定されない。図10のように、回収機構80に吸引部81を設け、塗布期間後(例えば、規定数の基板に塗布を行った後)のメンテナンス期間に、端部の液材Lhを排出口53・54から吸引し、排出させることもできる。なお、塗布期間に、端部の液材Lhを排出口53・54から吸引し、排出させることもできる。
[Embodiment 2]
FIG. 10A is a block diagram illustrating a modified example of the slit coater according to the second embodiment, and FIG. 10B is an explanatory diagram illustrating an operation of the slit coater illustrated in FIG. In the first embodiment, the liquid material Lh at the end is discharged from the outlets 53 and 54, but is not limited thereto. As shown in FIG. 10, a suction unit 81 is provided in the collection mechanism 80, and during the maintenance period after the application period (for example, after applying a predetermined number of substrates), the liquid material Lh at the end is discharged to the outlets 53 and 54. It can also be sucked out and discharged. Note that, during the application period, the liquid material Lh at the end can be sucked and discharged from the discharge ports 53 and 54.
 〔実施形態3〕
 図11は、実施形態3のスリットコータの構成を示すブロック図である。図12(a)は、実施形態3のスリットコータの構成を示す平面図であり、図12(b)は、図12(a)のb-b断面図である。実施形態3では、回収機構80に搬送部82a・82bが設けられる。図11に示すように、搬送部82aは、コータヘッド50の下側においてその進行方向に並ぶ複数のローラRaを含み、コータヘッド50の一端部E1と交差し、平面視において排出口53と重なる。搬送部82bは、コータヘッド50の下側においてその進行方向に並ぶ複数のローラRbを含み、コータヘッド50の他端部E2と交差し、平面視において排出口54と重なる。
[Embodiment 3]
FIG. 11 is a block diagram illustrating a configuration of the slit coater according to the third embodiment. FIG. 12A is a plan view showing the configuration of the slit coater according to the third embodiment, and FIG. 12B is a cross-sectional view taken along line bb of FIG. 12A. In the third embodiment, the collection unit 80 is provided with the transport units 82a and 82b. As illustrated in FIG. 11, the transport unit 82a includes a plurality of rollers Ra arranged in the traveling direction below the coater head 50, intersects one end E1 of the coater head 50, and overlaps the discharge port 53 in a plan view. . The transport section 82b includes a plurality of rollers Rb arranged in the traveling direction below the coater head 50, crosses the other end E2 of the coater head 50, and overlaps the discharge port 54 in a plan view.
 実施形態3では、排出口53・54から排出された液材Lhが、回転するローラRa・Rbによって搬送され、収容部83に回収される。これにより、排出口53・54からの排出効率が高まるとともに、液材の跳ね返り等も防ぐことができる。液材Lhの排出は、図6(a)のように塗布期間でもよいし、図6(b)のようにメンテナンス期間でもよい。 In the third embodiment, the liquid material Lh discharged from the discharge ports 53 and 54 is transported by the rotating rollers Ra and Rb, and is collected in the storage unit 83. Thereby, the discharge efficiency from the discharge ports 53 and 54 can be increased, and the rebound of the liquid material can be prevented. The discharge of the liquid material Lh may be performed during the application period as shown in FIG. 6A, or may be performed during the maintenance period as shown in FIG. 6B.
 複数のローラRa・Rbのトップ位置(鉛直方向の位置)は、排出口53・54よりも下方であればよいが、ローラRa・Rbのトップ位置を基板TKの上面(被塗布面)のレベル(鉛直方向の位置)に合わせることもできる。 The top positions (vertical positions) of the plurality of rollers Ra and Rb may be lower than the outlets 53 and 54, but the top positions of the rollers Ra and Rb are determined by the level of the upper surface (coated surface) of the substrate TK. (Vertical position).
 〔実施形態4〕
 図13は、実施形態4のスリットコータの構成を示すブロック図である。実施形態4では、回収機構80にリサイクリング部85が設けられる。リサイクリング部85は、収容部83および排管部84を介して回収した液材Lhをフィルタに通して異物を取り除き、異物の含まない液材Lcを液材供給部70に戻す。こうすれば、液材の無駄がなくなり、コスト削減を図ることができる。
[Embodiment 4]
FIG. 13 is a block diagram illustrating a configuration of the slit coater according to the fourth embodiment. In the fourth embodiment, a recycling unit 85 is provided in the collection mechanism 80. The recycling unit 85 removes foreign matter by passing the liquid material Lh collected through the storage unit 83 and the drainage unit 84 through a filter, and returns the liquid material Lc containing no foreign matter to the liquid material supply unit 70. This eliminates waste of the liquid material and can reduce the cost.
 〔各実施形態について〕
 液材Lの一例としてポリイミドの前駆体を挙げているがこれに限定されない。基板上に塗布可能な液材であれば何でもよい。例えば、図1の成膜工程で用いられるレジスト材であってもよい。
[For each embodiment]
As an example of the liquid material L, a polyimide precursor is mentioned, but it is not limited to this. Any liquid material that can be applied on the substrate may be used. For example, a resist material used in the film forming step of FIG. 1 may be used.
 各実施形態では、コータヘッド50に吐出口52として機能する吐出スリット52sを複数設けているがこれに限定されない。吐出スリット52sは1つでもよい。 In each embodiment, the plurality of discharge slits 52s functioning as the discharge ports 52 are provided in the coater head 50, but the present invention is not limited to this. The number of the discharge slits 52s may be one.
 各実施形態では、コータヘッド50の両端部それぞれに排出スリット53sあるいは排出スリット54sを複数設けているがこれに限定されない。両端部それぞれに1つの排出スリットを1つ設けてもよい。 In each embodiment, a plurality of discharge slits 53s or a plurality of discharge slits 54s are provided at both ends of the coater head 50, but the present invention is not limited to this. One discharge slit may be provided at each end.
 実施の形態1~4のなかの複数の形態を組み合わせた形態も本実施形態に含まれる。 形態 A form in which a plurality of forms in the first to fourth embodiments are combined is also included in the present embodiment.
 〔まとめ〕
 〔態様1〕
 液材が供給される供給口と、被塗布面に前記液材を吐出する吐出口とが設けられたコータヘッドを備え、
 前記コータヘッドの長手方向の両端部の少なくとも一方に、前記被塗布面以外に端部内の液材を排出する排出口が、前記吐出口から離間して設けられているスリットコータ。
[Summary]
[Aspect 1]
A supply port to which a liquid material is supplied, and a coater head provided with a discharge port for discharging the liquid material on a surface to be coated,
A slit coater in which a discharge port for discharging a liquid material in an end portion other than the surface to be coated is provided at at least one of both ends in a longitudinal direction of the coater head, away from the discharge port.
 〔態様2〕
 前記コータヘッドは、細長の筒体であり、前記供給口は、前記長手方向の中央部に設けられている例えば態様1に記載のスリットコータ。
[Aspect 2]
The slit coater according to aspect 1, for example, wherein the coater head is an elongated tubular body, and the supply port is provided at a central portion in the longitudinal direction.
 〔態様3〕
 前記コータヘッドの底面が前記被塗布面と対向し、
 前記吐出口および前記排出口が前記コータヘッドの底面に設けられている例えば態様1又は態様2に記載のスリットコータ。
[Aspect 3]
The bottom surface of the coater head faces the surface to be coated,
The slit coater according to mode 1 or mode 2, for example, wherein the discharge port and the discharge port are provided on a bottom surface of the coater head.
 〔態様4〕
 前記コータヘッドの底面が前記被塗布面と対向し、
 前記吐出口が前記コータヘッドの底面に設けられ、前記排出口が前記コータヘッドの側面に設けられている例えば態様1又は態様2に記載のスリットコータ。
[Aspect 4]
The bottom surface of the coater head faces the surface to be coated,
The slit coater according to, for example, aspect 1 or aspect 2, wherein the discharge port is provided on a bottom surface of the coater head, and the discharge port is provided on a side surface of the coater head.
 〔態様5〕
 前記排出口と前記吐出口との形状が異なる例えば態様1~態様4のいずれか1つに記載のスリットコータ。
[Aspect 5]
The slit coater according to any one of aspects 1 to 4, wherein the shape of the discharge port and the shape of the discharge port are different.
 〔態様6〕
 前記排出口から排出された液材を回収する回収機構が設けられている例えば態様1~態様5のいずれか1つに記載のスリットコータ。
[Aspect 6]
The slit coater according to any one of the first to fifth aspects, for example, provided with a recovery mechanism for recovering the liquid material discharged from the discharge port.
 〔態様7〕
 前記回収機構は、排出された液材を受ける収容部を含む例えば態様6に記載のスリットコータ。
[Aspect 7]
The slit coater according to aspect 6, for example, wherein the recovery mechanism includes a storage unit that receives the discharged liquid material.
 〔態様8〕
 前記回収機構は、複数のローラによって排出された液材を搬送する搬送部を含む例えば態様6に記載のスリットコータ。
[Aspect 8]
The slit coater according to aspect 6, for example, wherein the recovery mechanism includes a transport unit that transports the liquid material discharged by a plurality of rollers.
 〔態様9〕
 前記回収機構は、前記排出口から液材を吸引する吸引部を含む例えば態様6に記載のスリットコータ。
[Aspect 9]
The slit coater according to aspect 6, for example, wherein the recovery mechanism includes a suction unit that suctions the liquid material from the outlet.
 〔態様10〕
 前記回収機構は、回収した液材をフィルタに通して異物を取り除いた後に液材の供給源に戻すリサイクリング部を含む例えば態様6~態様9のいずれか1つに記載のスリットコータ。
[Aspect 10]
The slit coater according to any one of the sixth to ninth aspects, for example, wherein the recovery mechanism includes a recycling unit that returns the recovered liquid material to a supply source of the liquid material after removing foreign matter through a filter.
 〔態様11〕
 前記吐出口と前記排出口との離間距離が、前記排出口の幅寸法よりも大きい例えば態様1~態様10のいずれか1つに記載のスリットコータ。
[Aspect 11]
The slit coater according to any one of aspects 1 to 10, for example, wherein a distance between the discharge port and the discharge port is larger than a width dimension of the discharge port.
 〔態様12〕
 前記コータヘッドは、前記吐出口として機能する複数の吐出スリット、および前記排出口として機能する複数の排出スリットを含む例えば態様1に記載のスリットコータ。
[Aspect 12]
The slit coater according to example 1, wherein the coater head includes a plurality of discharge slits functioning as the discharge ports and a plurality of discharge slits functioning as the discharge ports.
 〔態様13〕
 前記複数の各排出スリットの開口面積は、前記複数の各吐出スリットの開口面積よりも小さい例えば態様12に記載のスリットコータ。
[Aspect 13]
The slit coater according to aspect 12, for example, wherein an opening area of each of the plurality of discharge slits is smaller than an opening area of each of the plurality of discharge slits.
 〔態様14〕
 前記吐出口と前記被塗布面との距離が100μm~300μmである例えば態様1~態様13のいずれか1つに記載のスリットコータ。
[Aspect 14]
14. The slit coater according to any one of aspects 1 to 13, wherein the distance between the discharge port and the surface to be coated is 100 μm to 300 μm.
 〔態様15〕
 前記液材は、ポリイミドの前駆体である例えば態様1~態様14のいずれか1つに記載のスリットコータ。
[Aspect 15]
15. The slit coater according to any one of aspects 1 to 14, for example, wherein the liquid material is a precursor of polyimide.
 〔態様16〕
 前記液材は、レジスト材である例えば態様1~態様14のいずれか1つに記載のスリットコータ。
[Aspect 16]
15. The slit coater according to any one of aspects 1 to 14, wherein the liquid material is a resist material.
 〔態様17〕
 液材が供給される供給口および被塗布面に前記液材を吐出する吐出口を含むコータヘッドを備え、前記コータヘッドの長手方向の両端部の少なくとも一方に、前記被塗布面以外に端部内の液材を排出する排出口が前記吐出口から離間して設けられたスリットコータを用いて、前記吐出口から前記被塗布面に前記液材を塗布する塗布方法。
[Aspect 17]
A coater head including a supply port to which a liquid material is supplied and a discharge port for discharging the liquid material on a surface to be coated is provided, and at least one of both ends in the longitudinal direction of the coater head has an end portion other than the surface to be coated. A coating method for applying the liquid material to the surface to be coated from the discharge port using a slit coater provided with a discharge port for discharging the liquid material separated from the discharge port.
 〔態様18〕
 メンテナンス期間に、前記被塗布面に液材を塗布する期間よりも前記コータヘッド内の液材圧力を高めることで前記排出口から前記液材を排出する例えば態様17に記載の塗布方法。
[Aspect 18]
The coating method according to, for example, aspect 17, wherein during the maintenance period, the liquid material is discharged from the discharge port by increasing the liquid material pressure in the coater head as compared with a period during which the liquid material is coated on the surface to be coated.
 〔態様19〕
 吸引部を用いて、前記液材を前記排出口から外部に吸引する例えば態様17に記載の塗布方法。
[Aspect 19]
The coating method according to, for example, aspect 17, wherein the liquid material is sucked outside from the outlet using a suction unit.
 〔態様20〕
 樹脂膜を含む表示デバイスの製造方法であって、
 前記樹脂膜の形成工程では、樹脂材料である液材が供給される供給口および被塗布面に前記液材を吐出する吐出口を含むコータヘッドを備えるとともに、前記コータヘッドの長手方向の両端部の少なくとも一方に、前記被塗布面以外に端部内の液材を排出する排出口が前記吐出口から離間して設けられたスリットコータを用いて、前記吐出口から前記被塗布面に前記液材を塗布する、表示デバイスの製造方法。
[Aspect 20]
A method for manufacturing a display device including a resin film,
In the step of forming the resin film, a coater head including a supply port to which a liquid material as a resin material is supplied and a discharge port for discharging the liquid material on a surface to be coated is provided, and both ends in a longitudinal direction of the coater head. In at least one of the above, the discharge material for discharging the liquid material in the end portion other than the surface to be coated is provided with a slit coater provided apart from the discharge port, and the liquid material is discharged from the discharge port to the surface to be coated. A method for manufacturing a display device.
 2  表示デバイス
 3  バリア層
 4  TFT層
 5  発光素子層
 6  封止層
 50 コータヘッド
 51 供給口
 52 吐出口
 53・54 排出口
 52 吐出スリット
 53s・54s 排出スリット
 ST ステージ
 TK 基板
 82a・82b 搬送部
 83 収容部
Reference Signs List 2 display device 3 barrier layer 4 TFT layer 5 light emitting element layer 6 sealing layer 50 coater head 51 supply port 52 discharge port 53/54 discharge port 52 discharge slit 53s / 54s discharge slit ST stage TK substrate 82a / 82b transport unit 83 accommodation Department

Claims (20)

  1.  液材が供給される供給口と、被塗布面に前記液材を吐出する吐出口とが設けられたコータヘッドを備え、
     前記コータヘッドの長手方向の両端部の少なくとも一方に、前記被塗布面以外に端部内の液材を排出する排出口が、前記吐出口から離間して設けられているスリットコータ。
    A supply port to which a liquid material is supplied, and a coater head provided with a discharge port for discharging the liquid material on a surface to be coated,
    A slit coater in which a discharge port for discharging a liquid material in an end portion other than the surface to be coated is provided at at least one of both ends in a longitudinal direction of the coater head, away from the discharge port.
  2.  前記コータヘッドは、細長の筒体であり、前記供給口は、前記長手方向の中央部に設けられている請求項1に記載のスリットコータ。 The slit coater according to claim 1, wherein the coater head is an elongated tubular body, and the supply port is provided at a central portion in the longitudinal direction.
  3.  前記コータヘッドの底面が前記被塗布面と対向し、
     前記吐出口および前記排出口が前記コータヘッドの底面に設けられている請求項1又は請求項2に記載のスリットコータ。
    The bottom surface of the coater head faces the surface to be coated,
    The slit coater according to claim 1, wherein the discharge port and the discharge port are provided on a bottom surface of the coater head.
  4.  前記コータヘッドの底面が前記被塗布面と対向し、
     前記吐出口が前記コータヘッドの底面に設けられ、前記排出口が前記コータヘッドの側面に設けられている請求項1又は請求項2に記載のスリットコータ。
    The bottom surface of the coater head faces the surface to be coated,
    The slit coater according to claim 1, wherein the discharge port is provided on a bottom surface of the coater head, and the discharge port is provided on a side surface of the coater head.
  5.  前記排出口と前記吐出口との形状が異なる請求項1~請求項4のいずれか1項に記載のスリットコータ。 The slit coater according to any one of claims 1 to 4, wherein the discharge port and the discharge port have different shapes.
  6.  前記排出口から排出された液材を回収する回収機構が設けられている請求項1~請求項5のいずれか1項に記載のスリットコータ。 The slit coater according to any one of claims 1 to 5, further comprising a recovery mechanism for recovering the liquid material discharged from the discharge port.
  7.  前記回収機構は、排出された液材を受ける収容部を含む請求項6に記載のスリットコータ。 7. The slit coater according to claim 6, wherein the recovery mechanism includes a storage unit that receives the discharged liquid material.
  8.  前記回収機構は、複数のローラによって排出された液材を搬送する搬送部を含む請求項6に記載のスリットコータ。 The slit coater according to claim 6, wherein the recovery mechanism includes a transport unit that transports the liquid material discharged by the plurality of rollers.
  9.  前記回収機構は、前記排出口から液材を吸引する吸引部を含む請求項6に記載のスリットコータ。 The slit coater according to claim 6, wherein the recovery mechanism includes a suction unit that suctions the liquid material from the discharge port.
  10.  前記回収機構は、回収した液材をフィルタに通して異物を取り除いた後に液材の供給源に戻すリサイクリング部を含む請求項6~請求項9のいずれか1項に記載のスリットコータ。 The slit coater according to any one of claims 6 to 9, wherein the collection mechanism includes a recycling unit that passes the collected liquid material through a filter to remove foreign substances and then returns the collected liquid material to a liquid material supply source.
  11.  前記吐出口と前記排出口との離間距離が、前記排出口の幅寸法よりも大きい請求項1~請求項10のいずれか1項に記載のスリットコータ。 The slit coater according to any one of claims 1 to 10, wherein a separation distance between the discharge port and the discharge port is larger than a width dimension of the discharge port.
  12.  前記コータヘッドは、前記吐出口として機能する複数の吐出スリット、および前記排出口として機能する複数の排出スリットを含む請求項1に記載のスリットコータ。 The slit coater according to claim 1, wherein the coater head includes a plurality of discharge slits functioning as the discharge port and a plurality of discharge slits functioning as the discharge port.
  13.  前記複数の各排出スリットの開口面積は、前記複数の各吐出スリットの開口面積よりも小さい請求項12に記載のスリットコータ。 The slit coater according to claim 12, wherein an opening area of each of the plurality of discharge slits is smaller than an opening area of each of the plurality of discharge slits.
  14.  前記吐出口と前記被塗布面との距離が100μm~300μmである請求項1~請求項13のいずれか1項に記載のスリットコータ。 The slit coater according to any one of claims 1 to 13, wherein a distance between the discharge port and the surface to be coated is 100 μm to 300 μm.
  15.  前記液材は、ポリイミドの前駆体である請求項1~請求項14のいずれか1項に記載のスリットコータ。 The slit coater according to any one of claims 1 to 14, wherein the liquid material is a precursor of polyimide.
  16.  前記液材は、レジスト材である請求項1~請求項14のいずれか1項に記載のスリットコータ。 The slit coater according to any one of claims 1 to 14, wherein the liquid material is a resist material.
  17.  液材が供給される供給口および被塗布面に前記液材を吐出する吐出口を含むコータヘッドを備え、前記コータヘッドの長手方向の両端部の少なくとも一方に、前記被塗布面以外に端部内の液材を排出する排出口が前記吐出口から離間して設けられたスリットコータを用いて、前記吐出口から前記被塗布面に前記液材を塗布する塗布方法。 A coater head including a supply port to which the liquid material is supplied and a discharge port for discharging the liquid material on a surface to be coated is provided, and at least one of both ends in the longitudinal direction of the coater head has an end portion other than the surface to be coated. A coating method for applying the liquid material to the surface to be coated from the discharge port using a slit coater provided with a discharge port for discharging the liquid material separated from the discharge port.
  18.  メンテナンス期間に、前記被塗布面に液材を塗布する期間よりも前記コータヘッド内の液材圧力を高めることで前記排出口から前記液材を排出する請求項17に記載の塗布方法。 18. The coating method according to claim 17, wherein in the maintenance period, the liquid material is discharged from the discharge port by increasing a liquid material pressure in the coater head as compared with a period in which the liquid material is coated on the surface to be coated.
  19.  吸引部を用いて、前記液材を前記排出口から外部に吸引する請求項17に記載の塗布方法。 18. The coating method according to claim 17, wherein the liquid material is sucked outside from the outlet using a suction unit.
  20.  樹脂膜を含む表示デバイスの製造方法であって、
     前記樹脂膜の形成工程では、樹脂材料である液材が供給される供給口および被塗布面に前記液材を吐出する吐出口を含むコータヘッドを備えるとともに、前記コータヘッドの長手方向の両端部の少なくとも一方に、前記被塗布面以外に端部内の液材を排出する排出口が前記吐出口から離間して設けられたスリットコータを用いて、前記吐出口から前記被塗布面に前記液材を塗布する、表示デバイスの製造方法。
    A method for manufacturing a display device including a resin film,
    In the step of forming the resin film, a coater head including a supply port to which a liquid material as a resin material is supplied and a discharge port for discharging the liquid material on a surface to be coated is provided, and both ends in a longitudinal direction of the coater head. In at least one of the above, the discharge material for discharging the liquid material in the end portion other than the surface to be coated is provided with a slit coater provided apart from the discharge port, and the liquid material is discharged from the discharge port to the surface to be coated. A method for manufacturing a display device.
PCT/JP2018/036219 2018-09-28 2018-09-28 Slit coater, coating method, and display device production method WO2020065909A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009000596A (en) * 2007-06-20 2009-01-08 Tokyo Ohka Kogyo Co Ltd Coating liquid supply system
WO2012140905A1 (en) * 2011-04-15 2012-10-18 パナソニック株式会社 Substrate coating method and substrate coating device as well as organic electroluminescent element production method using said method
JP2014147857A (en) * 2013-01-31 2014-08-21 Hitachi Vehicle Energy Ltd Die coater
JP2018149468A (en) * 2017-03-10 2018-09-27 株式会社Screenホールディングス Nozzle cleaning device and nozzle cleaning method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009000596A (en) * 2007-06-20 2009-01-08 Tokyo Ohka Kogyo Co Ltd Coating liquid supply system
WO2012140905A1 (en) * 2011-04-15 2012-10-18 パナソニック株式会社 Substrate coating method and substrate coating device as well as organic electroluminescent element production method using said method
JP2014147857A (en) * 2013-01-31 2014-08-21 Hitachi Vehicle Energy Ltd Die coater
JP2018149468A (en) * 2017-03-10 2018-09-27 株式会社Screenホールディングス Nozzle cleaning device and nozzle cleaning method

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