WO2020046648A8 - Process to maintain high solvency of recycle solvent during upgrading of steam cracked tar - Google Patents

Process to maintain high solvency of recycle solvent during upgrading of steam cracked tar Download PDF

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Publication number
WO2020046648A8
WO2020046648A8 PCT/US2019/047279 US2019047279W WO2020046648A8 WO 2020046648 A8 WO2020046648 A8 WO 2020046648A8 US 2019047279 W US2019047279 W US 2019047279W WO 2020046648 A8 WO2020046648 A8 WO 2020046648A8
Authority
WO
WIPO (PCT)
Prior art keywords
recycle solvent
tar
reduced reactivity
produce
maintain high
Prior art date
Application number
PCT/US2019/047279
Other languages
French (fr)
Other versions
WO2020046648A1 (en
Inventor
Kapil KANDEL
Teng Xu
Glenn A. Heeter
Frank Cheng-Yu Wang
Anthony S. Mennito
David T. Ferrughelli
Krystle J. Emanuele
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to SG11202101197XA priority Critical patent/SG11202101197XA/en
Priority to CN201980056568.6A priority patent/CN112601801A/en
Publication of WO2020046648A1 publication Critical patent/WO2020046648A1/en
Publication of WO2020046648A8 publication Critical patent/WO2020046648A8/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/72Controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/36Controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/18Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen-generating compounds, e.g. ammonia, water, hydrogen sulfide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/10Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for with the aid of centrifugal force

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Processes for improving hydrocarbon feedstock compatibility are provided. More specifically, a process for preparing a liquid hydrocarbon product includes heat soaking a tar stream to produce a reduced reactivity tar and blending the reduced reactivity tar with a utility fluid comprising recycle solvent to produce a lower viscosity, reduced reactivity tar. The process also includes hydroprocessing the lower viscosity, reduced reactivity tar at a temperature of greater than 350°C to produce a total liquids product containing the liquid hydrocarbon product and the recycle solvent. The process further includes separating the recycle solvent from the total liquids product, where the recycle solvent has the SBN of greater than 110, and flowing the recycle solvent to the reduced reactivity tar for blending to produce the lower viscosity, reduced reactivity tar.
PCT/US2019/047279 2018-08-30 2019-08-20 Process to maintain high solvency of recycle solvent during upgrading of steam cracked tar WO2020046648A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
SG11202101197XA SG11202101197XA (en) 2018-08-30 2019-08-20 Process to maintain high solvency of recycle solvent during upgrading of steam cracked tar
CN201980056568.6A CN112601801A (en) 2018-08-30 2019-08-20 Method for maintaining high solubility of recycled solvent in upgrading process of steam cracked tar

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201862724949P 2018-08-30 2018-08-30
US62/724,949 2018-08-30
EP18209046.4 2018-11-29
EP18209046 2018-11-29

Publications (2)

Publication Number Publication Date
WO2020046648A1 WO2020046648A1 (en) 2020-03-05
WO2020046648A8 true WO2020046648A8 (en) 2020-11-19

Family

ID=67777495

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2019/047279 WO2020046648A1 (en) 2018-08-30 2019-08-20 Process to maintain high solvency of recycle solvent during upgrading of steam cracked tar

Country Status (3)

Country Link
CN (1) CN112601801A (en)
SG (1) SG11202101197XA (en)
WO (1) WO2020046648A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021236326A1 (en) * 2020-05-22 2021-11-25 Exxonmobil Chemical Patents Inc. Fluid for tar hydroprocessing

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5997723A (en) 1998-11-25 1999-12-07 Exxon Research And Engineering Company Process for blending petroleum oils to avoid being nearly incompatible
US8083931B2 (en) 2006-08-31 2011-12-27 Exxonmobil Chemical Patents Inc. Upgrading of tar using POX/coker
EP2751232B1 (en) * 2011-08-31 2016-11-16 ExxonMobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis products
CN110072980B (en) * 2016-12-16 2021-11-30 埃克森美孚化学专利公司 Pyrolysis tar conversion
US10988698B2 (en) * 2016-12-16 2021-04-27 Exxonmobil Chemical Patents Inc. Pyrolysis tar pretreatment

Also Published As

Publication number Publication date
SG11202101197XA (en) 2021-04-29
CN112601801A (en) 2021-04-02
WO2020046648A1 (en) 2020-03-05

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