WO2020031567A1 - Flocculation and sedimentation device, and startup method thereof - Google Patents

Flocculation and sedimentation device, and startup method thereof Download PDF

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Publication number
WO2020031567A1
WO2020031567A1 PCT/JP2019/026497 JP2019026497W WO2020031567A1 WO 2020031567 A1 WO2020031567 A1 WO 2020031567A1 JP 2019026497 W JP2019026497 W JP 2019026497W WO 2020031567 A1 WO2020031567 A1 WO 2020031567A1
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Prior art keywords
coagulation
tank
sedimentation
sludge
cyclone
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PCT/JP2019/026497
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French (fr)
Japanese (ja)
Inventor
田中 一平
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栗田工業株式会社
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Priority to KR1020217000420A priority Critical patent/KR20210035801A/en
Publication of WO2020031567A1 publication Critical patent/WO2020031567A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/01Separation of suspended solid particles from liquids by sedimentation using flocculating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/02Settling tanks with single outlets for the separated liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/02Settling tanks with single outlets for the separated liquid
    • B01D21/04Settling tanks with single outlets for the separated liquid with moving scrapers
    • B01D21/06Settling tanks with single outlets for the separated liquid with moving scrapers with rotating scrapers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/02Settling tanks with single outlets for the separated liquid
    • B01D21/08Settling tanks with single outlets for the separated liquid provided with flocculating compartments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/24Feed or discharge mechanisms for settling tanks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/24Feed or discharge mechanisms for settling tanks
    • B01D21/2488Feed or discharge mechanisms for settling tanks bringing about a partial recirculation of the liquid, e.g. for introducing chemical aids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/26Separation of sediment aided by centrifugal force or centripetal force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/26Separation of sediment aided by centrifugal force or centripetal force
    • B01D21/267Separation of sediment aided by centrifugal force or centripetal force by using a cyclone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/28Mechanical auxiliary equipment for acceleration of sedimentation, e.g. by vibrators or the like
    • B01D21/286Means for gentle agitation for enhancing flocculation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/30Control equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/30Control equipment
    • B01D21/305Control of chemical properties of a component, e.g. control of pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5209Regulation methods for flocculation or precipitation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5227Processes for facilitating the dissolution of solid flocculants in water

Definitions

  • the present invention relates to a coagulation sedimentation apparatus for adding a sedimentation promoting agent and a coagulant to raw water containing a suspended substance to cause coagulation and sedimentation to separate sludge and treated water, and a control method therefor.
  • the present invention particularly relates to a coagulation and sedimentation apparatus configured to separate a slurry extracted from a sedimentation tank into sludge and a sedimentation promoting material by a cyclone, and to return the sedimentation promoting material to the coagulation tank, and a method of starting the same.
  • a coagulation sedimentation device that separates and removes suspended substances (hereinafter sometimes referred to as SS [Suspended ⁇ Solid] ⁇ ) from raw water by coagulation and sedimentation.
  • a flocculation tank for forming flocculated floc by adding a sedimentation promoting material and a flocculant; a sedimentation tank for sedimenting and separating flocculated floc flowing out of the flocculation tank; and a cyclone for separating the slurry drawn out from the sedimentation tank into particulate matter and sludge.
  • Patent Documents 1 to 3 There are known devices that are configured to return granular materials to a coagulation tank and discharge sludge.
  • the inorganic coagulant is added to the raw water introduced into the coagulation tank, the mixture is stirred with a stirrer, then the polymer coagulant is added, and the mixture is stirred with a stirrer to obtain a granular material.
  • Agglomerated flocs are formed together with (sand etc.).
  • the coagulated water is introduced into a sedimentation tank to separate it by sedimentation, and the treated water flows out from the upper part of the sedimentation tank. Further, the slurry is extracted from the lower part of the settling tank by a pump and sent to a cyclone.
  • the slurry is centrifuged into sludge and particulate matter, and the separated sludge is discharged out of the coagulation settling apparatus.
  • the particulate matter separated by the cyclone is returned to the flocculation tank and reused for sedimentation.
  • a flow control valve is provided in a sludge return line for returning at least a part of the sludge discharged from the cyclone to the flocculation tank, and when the SS concentration of the raw water is low, the sludge return amount is increased, and the SS concentration is increased. It is described that control is performed so as to reduce the sludge return amount when the value is high (paragraph 0072).
  • the tanks of the industrial sedimentation equipment should be used when the equipment is started or when the equipment is restarted after maintenance. Is not filled with water.
  • the coagulated sedimentation layer is portable, drain water from each tank and extract the sedimentation promoting material during non-rainfall.
  • water is poured into each tank of the coagulation sedimentation apparatus, and then operation is resumed by receiving drainage from the yard (hereinafter referred to as yard drainage).
  • the water in each tank (water in the tank) has a remarkably low SS concentration
  • the yard wastewater flows into the coagulation sedimentation device at the beginning of rainfall, the yard wastewater is diluted with the water in the tank.
  • the SS concentration in the tank is low.
  • SS concentration is not sufficient because it is not concentrated. Therefore, the concentration of sludge discharged from the coagulation sedimentation device becomes low.
  • the extraction from the sedimentation tank may be intermittently operated in order to promote the concentration of SS.
  • the sedimentation promoting material when the sedimentation promoting material is contained in the sludge as in the present invention, the sedimentation promoting material accumulates in the bottom pit of the sedimentation tank or in the drawing line, and there is a concern that the sedimentation promoting material is fixed. is there.
  • the present invention prevents the discharge of low-concentration sludge at the time of startup of a portable coagulation sedimentation device or a coagulation sedimentation device in which water to be treated flows into a coagulation sedimentation device in a state where water is filled in each coagulation tank. It is an object of the present invention to provide a coagulating sedimentation apparatus capable of shortening the start-up time by increasing the SS concentration and a method for starting the same.
  • the coagulation and sedimentation apparatus of the present invention has a first coagulation tank into which raw water is introduced and performs coagulation treatment with a first coagulation agent, and a first coagulation treatment water discharged from the first coagulation tank, and a second coagulation agent.
  • the sludge circulation line is connected to the first coagulation tank, and the coagulation and sedimentation device has switching means for switching between the sludge circulation line and the sludge discharge line.
  • a control means for controlling the switching means so as to be connected to a line or branched to the sludge discharge line and the sludge circulation line to discharge at least part of the separated sludge from the cyclone continuously or intermittently out of the system. It is characterized by having.
  • control means an SS meter provided in the separated sludge line or the sludge circulation line, and the separated sludge from the cyclone until the detected SS concentration of the SS meter rises to a predetermined concentration.
  • the amount of the first coagulant added to the first coagulation tank and the amount of the first coagulant added to the second coagulation tank are at least part of the time until the SS concentration detected by the SS meter rises to a predetermined concentration.
  • a coagulant addition amount control unit for increasing the addition amount of the second coagulant is provided.
  • the switching unit is controlled to return the separated sludge from the cyclone to the first coagulation tank for a predetermined time after starting supply of raw water to the first coagulation tank. It has a timer.
  • the amount of the first coagulant added to the first coagulation tank and the second coagulation agent are added to the first coagulation tank during at least a part of a period after the start of the supply of the raw water to the first coagulation tank until a predetermined time elapses.
  • a coagulant addition amount control unit for increasing the amount of the second coagulant added to the coagulation tank is provided.
  • a raw water is introduced, a first coagulation tank for coagulation treatment with a first coagulant, and a first coagulation treatment water discharged from the first coagulation tank are introduced.
  • a second coagulation tank for coagulating with a coagulant and a sedimentation promoting material a sedimentation tank into which second coagulation treatment water discharged from the second coagulation tank is introduced, and sedimented and separated into treated water and slurry;
  • a cyclone for returning the separated sedimentation promoting material to the second flocculation tank, wherein the separated sludge line from the cyclone sludge outlet is a sludge discharge line and a sludge discharge line.
  • a method for activating a coagulation sedimentation device which is branched into a circulation line and the sludge circulation line is connected to the first coagulation tank.
  • the coagulation / sedimentation device When the coagulation / sedimentation device is started, the separated sludge from the cyclone is passed through the sludge circulation line. No. It returned to flocculation tank, after start end of the aggregated precipitate device and switches to continuously or intermittently out of the system discharging at least a portion of the separated sludge from the cyclone.
  • the amount of the first coagulant added to the first coagulation tank and the amount of the second coagulant added to the second coagulation tank are increased when the coagulation settling apparatus is started.
  • the raw water is yard drainage.
  • the separated sludge discharged from the cyclone is returned to the first flocculation tank when the flocculation and settling apparatus is started, so that the low-concentration sludge is prevented from being discharged.
  • the SS concentration in the system increases at an early stage, and the start-up time is shortened.
  • the coagulation action is enhanced by increasing the amount of the first coagulant added when the coagulation and sedimentation apparatus is started, and the discharge of low-concentration sludge is prevented. Further, by increasing the amount of the second coagulant to be added to the first coagulant, insufficient coagulation can be prevented.
  • FIG. 1 shows a coagulation-sedimentation apparatus 1 according to a first embodiment.
  • This coagulation-sedimentation apparatus 1 includes a first coagulation tank 2, a second coagulation tank 3, and a sedimentation tank 4 disposed adjacent to the first coagulation tank 2.
  • Raw water is introduced into the first flocculation tank 2 through a raw water introduction line 5, an inorganic flocculant (PAC in FIG. 1) is added as a first flocculant by a first chemical injection device 6, and stirred by a stirrer 7. Is done.
  • the inorganic flocculant flocculates the suspended substance to generate fine flocs.
  • the first coagulation tank 2 is provided with a pH meter and a pH adjuster (caustic soda, sulfuric acid, hydrochloric acid, etc.), and maintains the pH in the first coagulation tank 2 within a predetermined range. It is configured to be able to.
  • the first coagulation treatment water from the first coagulation tank 2 is introduced into the second coagulation tank 3 through the advection port 8, and a polymer coagulant (polymer) is added as a second coagulant by the second chemical infusion device 9.
  • a sedimentation promoting material such as sand is added to the second flocculation tank 3, and fine floc is taken into the sedimentation promoting material via the polymer flocculant by stirring by the stirrer 10, and the flocculation floc having a large specific gravity is added. To grow.
  • crushed slag can be used as a sedimentation promoting material.
  • the average particle size of the sedimentation promoting material is preferably about 0.01 to 0.5 mm, and the true specific gravity is preferably 2 or more, particularly 2.5 or more and 4 or less, but is not limited thereto.
  • the second flocculated water containing the flocculated floc that has grown flows over the overflow weir 12 and is introduced into the sedimentation tank 4.
  • the second flocculated water descends along the weir plate of the overflow weir 12, then rises, passes through the separator, and flows into the outflow chamber 15.
  • flocculated flocs in the second flocculated water are precipitated.
  • a separator composed of a plurality of inclined plates 13 is provided at the upper part in the sedimentation tank 4 to promote sedimentation and separation of flocculated flocs.
  • the treated water that has passed through the separator is taken out of the outflow pipe 16 through the outflow chamber 15.
  • a rake 14 is provided in the settling tank 4.
  • a drawing line 17 for extracting a slurry containing precipitated flocculated flocs is connected to the bottom of the settling tank 4.
  • a drawing pump 18 is provided to the cyclone 20 for drawing the slurry.
  • the cyclone 20 is installed such that the axial direction is a vertical direction.
  • the sent slurry is separated by centrifugation into sludge collected at the axis of the cyclone and sedimentation promoting material collected at the peripheral surface on the cyclone side.
  • the separated sedimentation promoting material is returned from the bottom of the cyclone 20 to the second flocculation tank 3 again by the pipe 19 and is used for circulation.
  • the separated sludge collected on the axis side in the cyclone 20 flows out to a pipe 21 (separated sludge line) connected to a sludge outlet at the center of the upper surface of the cyclone 20.
  • the pipe 21 branches into pipes 22 and 25.
  • Pipe 22 is connected to pipe 24 via valve 23.
  • a sludge discharge line is constituted by the pipes 22, 24 and the valve 23.
  • the pipe 25 can return the separated sludge to the first flocculation tank 2 via the valve 26 and the pipe 27.
  • a sludge circulation line is constituted by the pipes 25 and 27 and the valve 26.
  • the valves 23 and 26 constitute switching means.
  • An SS meter 28 such as an optical turbidity meter is installed in the pipe 27, and the detection signal is input to the controller 30.
  • the valves 23 and 26 are controlled by the controller 30 to switch ON / OFF or adjust the flow rate.
  • fresh water having relatively high clarity such as clean water, well water, river water, rain water, and purified water is filled in each of the tanks 2, 3, and 4 to a specified water level. . This is to check whether the tanks 2 to 4 and the members are damaged.
  • the raw water mixes with the fresh water in the first flocculation tank 2, is diluted and subjected to flocculation treatment, flows into the sedimentation tank 4 via the second flocculation tank 3, sedimentation and separation of flocculated floc, and the treated water (clear water) ) Is discharged from the pipe 16.
  • the SS concentration in each of the coagulation tanks 2 and 3 is low.
  • the SS concentration of the precipitated slurry is also low. Therefore, the SS concentration of the separated sludge separated by the cyclone 20 is low, and it is not appropriate to discharge the sludge as it is.
  • valve 23 is closed and the valve 26 is opened when the coagulation and sedimentation apparatus 1 is started, and the entire amount of the separated sludge from the cyclone 20 is returned from the pipe 27 to the first coagulation tank 2.
  • the SS concentration of the separated sludge flowing in the pipe 27 is measured by the SS meter 28, and the detection signal is input to the controller 30.
  • the controller 30 controls the valve 23 until the SS concentration detected by the SS meter 28 reaches a preset predetermined concentration (in the case of the coagulation sedimentation apparatus for treating yard wastewater, about 10 to 50 g / L, particularly about 15 to 30 g / L). Is closed and the valve 26 is opened to return the entire amount of the separated sludge to the first flocculation tank 2.
  • the controller 30 opens the valve 23 and closes the valve 26, and discharges the entire amount of the separated sludge from the cyclone 20 from the pipe 24.
  • the entire amount of sludge is discharged from the pipe 24, but a part of the separated sludge from the cyclone 20 is discharged from the pipe 27 to the first pipe 27. It may be returned to the coagulation tank 2. Further, the separation sludge may be discharged intermittently instead of continuously.
  • the amount of the coagulant added by the first and second chemical infusion devices 6 and 9 is fixed (quantitative addition method).
  • the SS concentration of the raw water may be detected, and the added amount of the flocculant may be controlled according to the detection result.
  • FIG. 2 shows an aggregating and settling apparatus 1A according to a second embodiment.
  • the controller 30 is configured to control the first and second chemical injection devices 6 and 9 as described later.
  • Other configurations of the coagulation and sedimentation apparatus 1A are the same as those of the coagulation and sedimentation apparatus 1, and the same reference numerals indicate the same parts.
  • the controller 30 controls opening and closing of the valves 23 and 26 according to the same starting method as in the first embodiment until the detected concentration of the SS meter 28 rises to a predetermined value when the coagulating sedimentation apparatus 1A is started. .
  • the controller 30 further controls the inorganic coagulant and the polymer by the first and second dispensing devices 6 and 9 until the concentration detected by the SS meter 28 increases to a predetermined value.
  • the addition amount of the flocculant is larger than the standard addition amount during the steady operation (for example, 1.5 to 5 times the standard addition amount, particularly 2 to 5 times the standard addition amount).
  • the aggregation effect in the first and second aggregation tanks 2 and 3 is increased, and the SS concentration of the slurry precipitated in the precipitation tank 4 is increased.
  • the concentration of sludge separated by the cyclone 20 quickly increases to a predetermined value.
  • FIG. 3 shows a coagulation-sedimentation apparatus 1B according to a third embodiment.
  • a timer 31 is provided instead of the controller 30 to control the opening and closing of the valves 23 and 26. Also, the SS meter 28 is omitted.
  • Other configurations are the same as those of the coagulation and sedimentation apparatus 1 of FIG. 1, and the same reference numerals indicate the same parts.
  • the valve 26 is opened and the valve 23 is closed until a predetermined time has elapsed from the start of the flow of raw water into the coagulation and sedimentation device 1B when the coagulation and sedimentation device 1B is started.
  • the entire amount of the separated sludge is returned to the first flocculation tank 2.
  • the valve 26 is closed and the valve 23 is opened, and the entire amount of the separated sludge from the cyclone 20 is discharged from the pipe 24.
  • a part of the separated sludge from the cyclone 20 may be returned to the first flocculation tank 2 from the pipe 27, or may be intermittent treatment instead of continuous treatment.
  • the predetermined time is preferably about 0.5 to 4 times the HRT of the coagulation sedimentation apparatus 1B.
  • the SS concentration of the slurry precipitated in the precipitation tank 4 increases early.
  • the concentration of sludge separated by the cyclone 20 increases early.
  • FIG. 4 shows a coagulating sedimentation apparatus 1C according to a fourth embodiment.
  • the coagulation and sedimentation device 1C includes a timer 31 as in the coagulation and sedimentation device 1B of FIG. 3, and further includes a controller 32 that controls the amount of coagulant added by the first and second chemical injection devices 6, 9. I have.
  • the timer 31 opens the valve 26 and closes the valve 23 until a predetermined time elapses from the start of inflow of raw water into the coagulation and sedimentation apparatus 1C (start of operation of the raw water pump), similarly to the coagulation and sedimentation apparatus 1B of FIG.
  • the entire amount of the separated sludge from the cyclone 20 is returned to the first flocculation tank 2.
  • the valve 26 is closed and the valve 23 is opened, and the entire amount of the separated sludge from the cyclone 20 is discharged from the pipe 24.
  • a part of the separated sludge from the cyclone 20 may be returned to the first flocculation tank 2 from the pipe 27, or may be intermittent treatment instead of continuous treatment.
  • the controller 32 controls the inorganic coagulant and the polymer by the first and second chemical injection devices 6 and 9 until a predetermined time elapses from the start of the coagulation and sedimentation device 1C (start of the timer 31 (start of operation of the raw water pump)).
  • the addition amount of the flocculant is made larger than the standard addition amount in the steady operation (for example, 1.5 to 5 times the standard addition amount, respectively).
  • the control by the timer as in the third and fourth embodiments is particularly effective when the SS concentration in the raw water is stable (the fluctuation width is relatively small).
  • the coagulation sedimentation apparatus and its activation method according to the present invention are suitable for treating yard wastewater, but can also be applied to other various wastewater treatments.
  • ⁇ “ Starting up ”of the coagulation sedimentation apparatus in the present invention includes not only the start of operation of the newly installed apparatus but also the first start of operation after draining water from each tank, such as for maintenance and transportation.
  • the kind of the inorganic flocculant and the polymer flocculant used in the present invention is not particularly limited, and examples of the inorganic flocculant include polyaluminum chloride (PAC), ferric chloride, ferric sulfate, and polyiron sulfate. Can be used.
  • PAC polyaluminum chloride
  • ferric chloride ferric chloride
  • ferric sulfate ferric sulfate
  • polyiron sulfate can be used.
  • the polymer flocculant for example, a nonionic, cationic, anionic or amphoteric polymer flocculant can be used.
  • the above embodiment is an example of the present invention, and the present invention may be applied to other modes.
  • the SS meter is provided on the pipe 27, but may be provided on the pipe 21 or 25.
  • the period in which the amount of addition of various coagulants is increased may be a part of the period in which the valve 26 is open.

Abstract

A flocculation and sedimentation device and startup method thereof are provided with which is it possible to prevent discharge of low-concentration sludge when, at start-up of a portable-type flocculation and sedimentation device or a flocculation and sedimentation device with the flocculation tanks filled with water, water to be treated flows into the flocculation and sedimentation device. The flocculation and sedimentation device 1 is provided with a first flocculation tank 2 which subjects raw water to flocculation treatment with a first flocculant, a second flocculation tank 3 which subjects the first flocculated water to flocculation treatment with a second flocculant and a sedimentation promoter, and a sedimentation tank 4 which settles and separates the second flocculated water into treated water and a slurry, and a cyclone 20 which separates the slurry extracted from the sedimentation tank 4 into a separated sludge and the sedimentation promoter, and which returns the separated sedimentation promoter into the second flocculation tank 3; the flocculation and sedimentation device 1 is characterized by being provided with a controller 30 which returns the separated sludge from the cyclone to the first flocculation tank 2 at start-up of the flocculation and sedimentation device 1, and, after completing start-up, controls a switching means to perform switching such that at least part of the separated sludge from the cyclone 20 is discharged to outside of the system.

Description

凝集沈殿装置及びその起動方法Coagulation sedimentation apparatus and start-up method thereof
 本発明は、懸濁物質を含む原水に沈降促進材と凝集剤を添加して凝集沈殿させて汚泥と処理水とに分離する凝集沈殿装置およびその制御方法に関する。本発明は、とくに沈殿槽から抜き出したスラリーをサイクロンにより汚泥と沈降促進材とに分離し、沈降促進材を凝集槽に返送するよう構成された凝集沈殿装置およびその起動方法に関する。 (4) The present invention relates to a coagulation sedimentation apparatus for adding a sedimentation promoting agent and a coagulant to raw water containing a suspended substance to cause coagulation and sedimentation to separate sludge and treated water, and a control method therefor. The present invention particularly relates to a coagulation and sedimentation apparatus configured to separate a slurry extracted from a sedimentation tank into sludge and a sedimentation promoting material by a cyclone, and to return the sedimentation promoting material to the coagulation tank, and a method of starting the same.
 懸濁物質(以下、SS[Suspended Solid] と称することもある。)を原水中から凝集沈殿により分離除去する凝集沈殿装置として、原水に粒径10~200μm程度の粒状物(砂など)よりなる沈降促進材と凝集剤とを添加して凝集フロックを形成させる凝集槽と、凝集槽から流出する凝集フロックを沈降分離する沈殿槽と、沈殿槽から引き抜いたスラリーを粒状物と汚泥に分離するサイクロンとを備え、粒状物を凝集槽に返送し、汚泥を排出するよう構成された装置が知られている(特許文献1~3)。 A coagulation sedimentation device that separates and removes suspended substances (hereinafter sometimes referred to as SS [Suspended {Solid]}) from raw water by coagulation and sedimentation. A flocculation tank for forming flocculated floc by adding a sedimentation promoting material and a flocculant; a sedimentation tank for sedimenting and separating flocculated floc flowing out of the flocculation tank; and a cyclone for separating the slurry drawn out from the sedimentation tank into particulate matter and sludge. There are known devices that are configured to return granular materials to a coagulation tank and discharge sludge (Patent Documents 1 to 3).
 特許文献1~3の凝集沈殿装置にあっては、凝集槽に導入された原水に無機凝集剤を添加して攪拌機で攪拌し、次いで高分子凝集剤を添加し、攪拌機で攪拌して粒状物(砂など)とともに凝集フロックを形成させる。この凝集処理水を沈殿槽に導入して沈降分離し、沈殿槽上部から処理水を流出させる。また、沈殿槽の下部からポンプによりスラリーを抜き出し、サイクロンに送る。サイクロンでは、スラリーを汚泥と粒状物とに遠心分離し、分離された汚泥が凝集沈殿装置外に排出される。サイクロンで分離された粒状物は凝集槽に返送され、再度沈殿分離に利用される。 In the coagulation and sedimentation apparatuses of Patent Documents 1 to 3, the inorganic coagulant is added to the raw water introduced into the coagulation tank, the mixture is stirred with a stirrer, then the polymer coagulant is added, and the mixture is stirred with a stirrer to obtain a granular material. (Agglomerated flocs are formed together with (sand etc.). The coagulated water is introduced into a sedimentation tank to separate it by sedimentation, and the treated water flows out from the upper part of the sedimentation tank. Further, the slurry is extracted from the lower part of the settling tank by a pump and sent to a cyclone. In the cyclone, the slurry is centrifuged into sludge and particulate matter, and the separated sludge is discharged out of the coagulation settling apparatus. The particulate matter separated by the cyclone is returned to the flocculation tank and reused for sedimentation.
 特許文献3には、サイクロンから排出される汚泥の少なくとも一部を凝集槽に戻す汚泥返送ラインに流量コントロール弁を設け、原水のSS濃度が低い場合には汚泥返送量を多くし、該SS濃度が高い場合には汚泥返送量を少なくするよう制御することが記載されている(0072段落)。 In Patent Document 3, a flow control valve is provided in a sludge return line for returning at least a part of the sludge discharged from the cyclone to the flocculation tank, and when the SS concentration of the raw water is low, the sludge return amount is increased, and the SS concentration is increased. It is described that control is performed so as to reduce the sludge return amount when the value is high (paragraph 0072).
特開2000-317220号公報JP 2000-317220 A 特開2002-355507号公報JP-A-2002-355507 特開2014-237122号公報JP 2014-237122 A
 製鉄所やセメント工場など、敷地面積が大きいヤードの降雨排水を処理する施設に設置された凝集沈殿装置の場合、装置立ち上げ時やメンテナンス後の装置再立ち上げ時は、業種沈殿装置の各槽に水張りがされていない。また凝集沈殿層を可搬式とする場合は非降雨時は各槽内の水を抜くと共に沈殿促進材を抽出しておく。降雨時にはまず凝集沈殿装置の各槽に水を張り、次にヤードからの排水(以下、ヤード排水という。)を受け入れて運転再開する。 In the case of coagulation sedimentation equipment installed in a facility that treats rainwater drainage in large yards, such as steelworks and cement factories, the tanks of the industrial sedimentation equipment should be used when the equipment is started or when the equipment is restarted after maintenance. Is not filled with water. When the coagulated sedimentation layer is portable, drain water from each tank and extract the sedimentation promoting material during non-rainfall. At the time of rainfall, first, water is poured into each tank of the coagulation sedimentation apparatus, and then operation is resumed by receiving drainage from the yard (hereinafter referred to as yard drainage).
 各槽内に張られた水(槽内水)は、SS濃度が著しく低いため、降雨開始当初にヤード排水が凝集沈殿装置に流入した場合、ヤード排水が槽内水で希釈されるので、各槽内のSS濃度が低い。また、たとえ水張りを行わず直接ヤード排水が流入したとしても未濃縮のため、SS濃度は十分ではない。そのため、凝集沈殿装置から排出される汚泥濃度が低いものとなる。
 なお、従来の沈殿槽ではSSの濃縮を促進するために、沈殿槽からの引抜を間欠で運転することがある。しかし、本発明のように汚泥中に沈降促進材を含む場合は沈殿槽底部ピットや引抜ライン中に沈降促進材が蓄積し、固着する懸念があるため、引抜は原則連続運転することが通常である。
Since the water in each tank (water in the tank) has a remarkably low SS concentration, if the yard wastewater flows into the coagulation sedimentation device at the beginning of rainfall, the yard wastewater is diluted with the water in the tank. The SS concentration in the tank is low. In addition, even if yard wastewater directly flows in without filling, SS concentration is not sufficient because it is not concentrated. Therefore, the concentration of sludge discharged from the coagulation sedimentation device becomes low.
In addition, in the conventional sedimentation tank, the extraction from the sedimentation tank may be intermittently operated in order to promote the concentration of SS. However, when the sedimentation promoting material is contained in the sludge as in the present invention, the sedimentation promoting material accumulates in the bottom pit of the sedimentation tank or in the drawing line, and there is a concern that the sedimentation promoting material is fixed. is there.
 本発明は、可搬式の凝集沈殿装置や、各凝集槽に水を張った状態の凝集沈殿装置に被処理水が流入する凝集沈殿装置の起動時における低濃度汚泥の排出を防止し、早期にSS濃度を上昇させることで、立ち上げ時間を短縮することができる凝集沈殿装置及びその起動方法を提供することを目的とする。 The present invention prevents the discharge of low-concentration sludge at the time of startup of a portable coagulation sedimentation device or a coagulation sedimentation device in which water to be treated flows into a coagulation sedimentation device in a state where water is filled in each coagulation tank. It is an object of the present invention to provide a coagulating sedimentation apparatus capable of shortening the start-up time by increasing the SS concentration and a method for starting the same.
 本発明の凝集沈殿装置は、原水が導入され、第1凝集剤により凝集処理する第1凝集槽と、該第1凝集槽から排出された第1凝集処理水が導入され、第2凝集剤と沈降促進材により凝集処理する第2凝集槽と、該第2凝集槽から排出された第2凝集処理水が導入され、処理水とスラリーとに沈降分離する沈殿槽と、該沈殿槽から抜き出したスラリーを分離汚泥と沈降促進材とに分離し、分離した沈降促進材を該第2凝集槽に戻すサイクロンとを備え、該サイクロンの汚泥出口からの分離汚泥ラインが汚泥排出ラインと汚泥循環ラインとに分岐され、該汚泥循環ラインが前記第1凝集槽に接続されており、該汚泥循環ラインと汚泥排出ラインとの切替手段を有する凝集沈殿装置において、該凝集沈殿装置の起動時には該分離汚泥ラインを該汚泥循環ラインに接続して該サイクロンからの分離汚泥を該汚泥循環ラインを通じて該第1凝集槽に返送し、該凝集沈殿装置の起動終了後には連続的または間欠的に該分離汚泥ラインを該汚泥排出ラインに接続するかまたは該汚泥排出ライン及び汚泥循環ラインに分岐して該サイクロンからの分離汚泥の少なくとも一部を連続的又は間欠的に系外排出するように前記切替手段を制御する制御手段を備えたことを特徴とする。 The coagulation and sedimentation apparatus of the present invention has a first coagulation tank into which raw water is introduced and performs coagulation treatment with a first coagulation agent, and a first coagulation treatment water discharged from the first coagulation tank, and a second coagulation agent. A second coagulation tank for coagulation treatment with a sedimentation promoting material, a second coagulation treatment water discharged from the second coagulation tank, introduced thereinto, and a sedimentation tank for sedimentation and separation into treated water and slurry, and withdrawn from the sedimentation tank A cyclone for separating the slurry into separated sludge and a sedimentation promoting material and returning the separated sedimentation promoting material to the second flocculation tank, wherein a separated sludge line from a sludge outlet of the cyclone is a sludge discharge line and a sludge circulation line. And the sludge circulation line is connected to the first coagulation tank, and the coagulation and sedimentation device has switching means for switching between the sludge circulation line and the sludge discharge line. The dirt Connected to a circulation line, the separated sludge from the cyclone is returned to the first coagulation tank through the sludge circulation line, and after the start of the coagulation settling apparatus, the separated sludge line is discharged continuously or intermittently. A control means for controlling the switching means so as to be connected to a line or branched to the sludge discharge line and the sludge circulation line to discharge at least part of the separated sludge from the cyclone continuously or intermittently out of the system. It is characterized by having.
 本発明の一態様では、前記制御手段として、前記分離汚泥ラインまたは前記汚泥循環ラインに設けられたSS計と、該SS計の検出SS濃度が所定濃度に上昇するまで前記サイクロンからの分離汚泥を前記第1凝集槽に返送するように前記切替手段を制御する制御器とを備える。 In one aspect of the present invention, as the control means, an SS meter provided in the separated sludge line or the sludge circulation line, and the separated sludge from the cyclone until the detected SS concentration of the SS meter rises to a predetermined concentration. A controller for controlling the switching means so as to return to the first coagulation tank.
 本発明の一態様では、前記SS計の検出SS濃度が所定濃度に上昇するまでの期間の少なくとも一部において、前記第1凝集槽への第1凝集剤の添加量および第2凝集槽への第2凝集剤の添加量を増大させる凝集剤添加量制御部が設けられている。 In one aspect of the present invention, the amount of the first coagulant added to the first coagulation tank and the amount of the first coagulant added to the second coagulation tank are at least part of the time until the SS concentration detected by the SS meter rises to a predetermined concentration. A coagulant addition amount control unit for increasing the addition amount of the second coagulant is provided.
 本発明の一態様では、前記制御手段として、前記第1凝集槽への原水供給開始後、所定時間、前記サイクロンからの分離汚泥を前記第1凝集槽に返送するように前記切替手段を制御するタイマーを備える。 In one aspect of the present invention, as the control unit, the switching unit is controlled to return the separated sludge from the cyclone to the first coagulation tank for a predetermined time after starting supply of raw water to the first coagulation tank. It has a timer.
 本発明の一態様では、前記第1凝集槽への原水供給開始後、所定時間が経過するまでの期間の少なくとも一部において、前記第1凝集槽への第1凝集剤の添加量および第2凝集槽への第2凝集剤の添加量を増大させる凝集剤添加量制御部が設けられている。 In one aspect of the present invention, the amount of the first coagulant added to the first coagulation tank and the second coagulation agent are added to the first coagulation tank during at least a part of a period after the start of the supply of the raw water to the first coagulation tank until a predetermined time elapses. A coagulant addition amount control unit for increasing the amount of the second coagulant added to the coagulation tank is provided.
 本発明の凝集沈殿装置の制御方法は、原水が導入され、第1凝集剤により凝集処理する第1凝集槽と、該第1凝集槽から排出された第1凝集処理水が導入され、第2凝集剤と沈降促進材により凝集処理する第2凝集槽と、該第2凝集槽から排出された第2凝集処理水が導入され、処理水とスラリーとに沈降分離する沈殿槽と、該沈殿槽から抜き出したスラリーを分離汚泥と沈降促進材とに分離し、分離した沈降促進材を該第2凝集槽に戻すサイクロンとを備え、該サイクロンの汚泥出口からの分離汚泥ラインが汚泥排出ラインと汚泥循環ラインとに分岐され、該汚泥循環ラインが前記第1凝集槽に接続されている凝集沈殿装置の起動方法において、該凝集沈殿装置の起動時には該サイクロンからの分離汚泥を該汚泥循環ラインを通じて該第1凝集槽に返送し、該凝集沈殿装置の起動終了後には該サイクロンからの分離汚泥の少なくとも一部を連続的又は間欠的に系外排出するように切り替えることを特徴とする。 In the method for controlling the coagulation sedimentation apparatus of the present invention, a raw water is introduced, a first coagulation tank for coagulation treatment with a first coagulant, and a first coagulation treatment water discharged from the first coagulation tank are introduced. A second coagulation tank for coagulating with a coagulant and a sedimentation promoting material, a sedimentation tank into which second coagulation treatment water discharged from the second coagulation tank is introduced, and sedimented and separated into treated water and slurry; And a cyclone for returning the separated sedimentation promoting material to the second flocculation tank, wherein the separated sludge line from the cyclone sludge outlet is a sludge discharge line and a sludge discharge line. A method for activating a coagulation sedimentation device which is branched into a circulation line and the sludge circulation line is connected to the first coagulation tank. When the coagulation / sedimentation device is started, the separated sludge from the cyclone is passed through the sludge circulation line. No. It returned to flocculation tank, after start end of the aggregated precipitate device and switches to continuously or intermittently out of the system discharging at least a portion of the separated sludge from the cyclone.
 本発明の一態様では、前記凝集沈殿装置の起動時に、前記第1凝集槽への第1凝集剤添加量および第2凝集槽への第2凝集剤の添加量を増加させる。 In one aspect of the present invention, the amount of the first coagulant added to the first coagulation tank and the amount of the second coagulant added to the second coagulation tank are increased when the coagulation settling apparatus is started.
 本発明の一態様では、前記原水がヤード排水である。 In one embodiment of the present invention, the raw water is yard drainage.
 本発明の凝集沈殿装置及びその起動方法では、凝集沈殿装置の起動時に、サイクロンから排出される分離汚泥を第1凝集槽に返送するので、低濃度汚泥の排出が防止される。これにより、早期に系内のSS濃度が上昇し、立ち上げ時間が短縮される。 According to the present invention, the separated sludge discharged from the cyclone is returned to the first flocculation tank when the flocculation and settling apparatus is started, so that the low-concentration sludge is prevented from being discharged. As a result, the SS concentration in the system increases at an early stage, and the start-up time is shortened.
 本発明の一態様では、凝集沈殿装置の起動時に、第1凝集剤の添加量を多くすることにより、凝集作用が強化され、さらに低濃度汚泥の排出が防止される。また第1凝集剤に対して不足しないよう第2凝集剤の添加量を多くすることにより、凝集不良が防止される。 の 一 In one embodiment of the present invention, the coagulation action is enhanced by increasing the amount of the first coagulant added when the coagulation and sedimentation apparatus is started, and the discharge of low-concentration sludge is prevented. Further, by increasing the amount of the second coagulant to be added to the first coagulant, insufficient coagulation can be prevented.
実施の形態に係る凝集沈殿装置の構成図である。It is a block diagram of the coagulation sedimentation apparatus which concerns on embodiment. 実施の形態に係る凝集沈殿装置の構成図である。It is a block diagram of the coagulation sedimentation apparatus which concerns on embodiment. 実施の形態に係る凝集沈殿装置の構成図である。It is a block diagram of the coagulation sedimentation apparatus which concerns on embodiment. 実施の形態に係る凝集沈殿装置の構成図である。It is a block diagram of the coagulation sedimentation apparatus which concerns on embodiment.
 以下に、本発明の望ましい実施の形態を、図面を参照して説明する。図1は、第1の実施の形態に係る凝集沈殿装置1を示している。この凝集沈殿装置1は、第1凝集槽2と、第2凝集槽3と、それに隣接配置された沈殿槽4を備えている。 Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings. FIG. 1 shows a coagulation-sedimentation apparatus 1 according to a first embodiment. This coagulation-sedimentation apparatus 1 includes a first coagulation tank 2, a second coagulation tank 3, and a sedimentation tank 4 disposed adjacent to the first coagulation tank 2.
 第1凝集槽2には、原水導入ライン5を介して原水が導入され、第1凝集剤として無機凝集剤(図1ではPAC)が第1薬注装置6によって添加されて、攪拌機7によって攪拌される。第1凝集槽2においては、無機凝集剤が懸濁物質を凝集させて微細なフロックが生成する。 Raw water is introduced into the first flocculation tank 2 through a raw water introduction line 5, an inorganic flocculant (PAC in FIG. 1) is added as a first flocculant by a first chemical injection device 6, and stirred by a stirrer 7. Is done. In the first flocculation tank 2, the inorganic flocculant flocculates the suspended substance to generate fine flocs.
 図示は省略するが、第1凝集槽2には、pH計及びpH調整剤(苛性ソーダ、硫酸、塩酸など)の添加装置が設けられており、第1凝集槽2内のpHを所定範囲に維持できるよう構成されている。 Although not shown, the first coagulation tank 2 is provided with a pH meter and a pH adjuster (caustic soda, sulfuric acid, hydrochloric acid, etc.), and maintains the pH in the first coagulation tank 2 within a predetermined range. It is configured to be able to.
 第1凝集槽2からの第1凝集処理水は移流口8を介して第2凝集槽3に導入され、第2凝集剤として高分子凝集剤(ポリマー)が第2薬注装置9によって添加される。第2凝集槽3内には、砂などの沈降促進材が添加されており、攪拌機10による攪拌により、微細フロックが高分子凝集剤を介して沈降促進材に取り込まれて、比重の大きい凝集フロックに成長する。 The first coagulation treatment water from the first coagulation tank 2 is introduced into the second coagulation tank 3 through the advection port 8, and a polymer coagulant (polymer) is added as a second coagulant by the second chemical infusion device 9. You. A sedimentation promoting material such as sand is added to the second flocculation tank 3, and fine floc is taken into the sedimentation promoting material via the polymer flocculant by stirring by the stirrer 10, and the flocculation floc having a large specific gravity is added. To grow.
 沈降促進材としては、砂のほか、各種スラグの破砕物なども用いることができる。沈降促進材の平均粒径は0.01~0.5mm程度が好ましく、真比重は2以上特に2.5以上で4以下が好ましいが、これに限定されない。 砂 In addition to sand, crushed slag can be used as a sedimentation promoting material. The average particle size of the sedimentation promoting material is preferably about 0.01 to 0.5 mm, and the true specific gravity is preferably 2 or more, particularly 2.5 or more and 4 or less, but is not limited thereto.
 成長した凝集フロックを含む第2凝集処理水は、越流堰12を越流して沈殿槽4に導入される。第2凝集処理水は、越流堰12の堰板に沿って下降した後、上昇してセパレータを通過し、流出室15に流入する。沈殿槽4では、第2凝集処理水中の凝集フロックが沈殿する。 {Circle around (2)} The second flocculated water containing the flocculated floc that has grown flows over the overflow weir 12 and is introduced into the sedimentation tank 4. The second flocculated water descends along the weir plate of the overflow weir 12, then rises, passes through the separator, and flows into the outflow chamber 15. In the sedimentation tank 4, flocculated flocs in the second flocculated water are precipitated.
 沈殿槽4内の上部には、複数の傾斜板13よりなるセパレータが設置されており、凝集フロックの沈殿分離が促進される。セパレータを通り抜けた処理水は、流出室15を経て流出配管16から取り出される。沈殿槽4にレーキ14が設けられている。 (4) A separator composed of a plurality of inclined plates 13 is provided at the upper part in the sedimentation tank 4 to promote sedimentation and separation of flocculated flocs. The treated water that has passed through the separator is taken out of the outflow pipe 16 through the outflow chamber 15. A rake 14 is provided in the settling tank 4.
 沈殿槽4の底部には、沈殿した凝集フロックを含むスラリーを抜き出すための引抜ライン17が接続されている。引抜ライン17には、抜き出したスラリーをサイクロン20に引抜ポンプ18が設けられている。サイクロン20は、軸心方向を鉛直方向として設置されている。 (4) A drawing line 17 for extracting a slurry containing precipitated flocculated flocs is connected to the bottom of the settling tank 4. In the drawing line 17, a drawing pump 18 is provided to the cyclone 20 for drawing the slurry. The cyclone 20 is installed such that the axial direction is a vertical direction.
 サイクロン20では、送られてきたスラリーを遠心分離により、サイクロン軸心部に集まる汚泥と、サイクロン側周面に集まる沈降促進材とに分離する。分離された沈降促進材は、サイクロン20の底部から、配管19によって再び第2凝集槽3内に戻されて循環使用される。 In the cyclone 20, the sent slurry is separated by centrifugation into sludge collected at the axis of the cyclone and sedimentation promoting material collected at the peripheral surface on the cyclone side. The separated sedimentation promoting material is returned from the bottom of the cyclone 20 to the second flocculation tank 3 again by the pipe 19 and is used for circulation.
 サイクロン20で軸心側に集められた分離汚泥は、サイクロン20の上面中央部の汚泥出口に接続された配管21(分離汚泥ライン)に流出する。該配管21は、配管22,25に分岐している。 分離 The separated sludge collected on the axis side in the cyclone 20 flows out to a pipe 21 (separated sludge line) connected to a sludge outlet at the center of the upper surface of the cyclone 20. The pipe 21 branches into pipes 22 and 25.
 配管22は、バルブ23を介して配管24に接続されている。配管22,24及びバルブ23によって汚泥排出ラインが構成されている。 Pipe 22 is connected to pipe 24 via valve 23. A sludge discharge line is constituted by the pipes 22, 24 and the valve 23.
 配管25は、バルブ26及び配管27を介して分離汚泥を第1凝集槽2に返送可能となっている。配管25,27及びバルブ26によって汚泥循環ラインが構成されている。バルブ23,26によって切替手段が構成されている。 The pipe 25 can return the separated sludge to the first flocculation tank 2 via the valve 26 and the pipe 27. A sludge circulation line is constituted by the pipes 25 and 27 and the valve 26. The valves 23 and 26 constitute switching means.
 この配管27に光学式濁度計などよりなるSS計28が設置されており、その検出信号が制御器30に入力される。制御器30によってバルブ23,26が制御され、ON/OFF切替または流量調整される。 SS An SS meter 28 such as an optical turbidity meter is installed in the pipe 27, and the detection signal is input to the controller 30. The valves 23 and 26 are controlled by the controller 30 to switch ON / OFF or adjust the flow rate.
 この凝集沈殿装置1を運転開始する際は、まず各槽2,3,4に上水、井水、河川水、雨水、浄化処理水など比較的清澄度の高い清水が規定水位まで水張りされる。これは、各槽2~4や部材の破損がないか確認するためである。 When the coagulating sedimentation apparatus 1 is started to operate, first, fresh water having relatively high clarity such as clean water, well water, river water, rain water, and purified water is filled in each of the tanks 2, 3, and 4 to a specified water level. . This is to check whether the tanks 2 to 4 and the members are damaged.
 この凝集沈殿装置にヤード排水などの原水が流入開始すると、第1凝集槽2に無機凝集剤が添加されると共に、第2凝集槽3に高分子凝集剤(ポリマー)が添加される。また、第2凝集槽3には、所定量の沈降促進材が添加される。 (4) When raw water such as yard wastewater starts flowing into this coagulation sedimentation apparatus, an inorganic coagulant is added to the first coagulation tank 2 and a polymer coagulant (polymer) is added to the second coagulation tank 3. Further, a predetermined amount of a sedimentation promoting material is added to the second coagulation tank 3.
 原水は、第1凝集槽2内の清水と混ざり合い、希釈されて凝集処理され、第2凝集槽3を経て沈殿槽4に流入し、凝集フロックの沈降分離が行われ、処理水(清澄水)が配管16から排出される。 The raw water mixes with the fresh water in the first flocculation tank 2, is diluted and subjected to flocculation treatment, flows into the sedimentation tank 4 via the second flocculation tank 3, sedimentation and separation of flocculated floc, and the treated water (clear water) ) Is discharged from the pipe 16.
 このように、凝集沈殿装置1の起動時にあっては、原水が各凝集槽2,3内の清水で希釈されるので、各凝集槽2,3内のSS濃度が低く、沈殿槽4内で沈殿したスラリーのSS濃度も小さい。そのため、サイクロン20で分離された分離汚泥のSS濃度が低く、そのまま排出することは適切ではない。 As described above, when the coagulation and sedimentation apparatus 1 is started, since the raw water is diluted with the fresh water in each of the coagulation tanks 2 and 3, the SS concentration in each of the coagulation tanks 2 and 3 is low. The SS concentration of the precipitated slurry is also low. Therefore, the SS concentration of the separated sludge separated by the cyclone 20 is low, and it is not appropriate to discharge the sludge as it is.
 そこで、この実施の形態では、凝集沈殿装置1の起動時にはバルブ23を閉とし、バルブ26を開とし、サイクロン20からの分離汚泥の全量を配管27から第1凝集槽2に返送する。 Therefore, in this embodiment, the valve 23 is closed and the valve 26 is opened when the coagulation and sedimentation apparatus 1 is started, and the entire amount of the separated sludge from the cyclone 20 is returned from the pipe 27 to the first coagulation tank 2.
 この配管27内を流れる分離汚泥のSS濃度がSS計28で計測され、その検出信号が制御器30に入力される。制御器30は、SS計28の検出SS濃度が、予め設定した所定濃度(ヤード排水を処理する凝集沈殿装置の場合、10~50g/L特に15~30g/L程度)になるまで、バルブ23を閉、バルブ26を開とし、分離汚泥の全量を第1凝集槽2に返送する。 (4) The SS concentration of the separated sludge flowing in the pipe 27 is measured by the SS meter 28, and the detection signal is input to the controller 30. The controller 30 controls the valve 23 until the SS concentration detected by the SS meter 28 reaches a preset predetermined concentration (in the case of the coagulation sedimentation apparatus for treating yard wastewater, about 10 to 50 g / L, particularly about 15 to 30 g / L). Is closed and the valve 26 is opened to return the entire amount of the separated sludge to the first flocculation tank 2.
 この状態を維持すると、第1及び第2凝集槽2,3内のSS濃度が次第に上昇し、SS計28の検出SS濃度も次第に上昇する。SS計28の検出SS濃度が上記所定濃度にまで上昇すると、制御器30がバルブ23を開、バルブ26を閉とし、サイクロン20からの分離汚泥の全量を配管24から排出する。 す る と When this state is maintained, the SS concentration in the first and second coagulation tanks 2 and 3 gradually increases, and the SS concentration detected by the SS meter 28 also gradually increases. When the SS concentration detected by the SS meter 28 rises to the above-mentioned predetermined concentration, the controller 30 opens the valve 23 and closes the valve 26, and discharges the entire amount of the separated sludge from the cyclone 20 from the pipe 24.
 このようにして、凝集沈殿装置1の起動時に配管24から低SS濃度の汚泥が排出されることが防止される。 Thus, when the flocculation and settling apparatus 1 is started, sludge having a low SS concentration is prevented from being discharged from the pipe 24.
 上記説明では、SS計28の検出SS濃度が所定値にまで上昇した後は、汚泥の全量を配管24から排出するものとしたが、サイクロン20からの分離汚泥の一部を配管27から第1凝集槽2に返送してもよい。また、分離汚泥の排出を連続的でなく間欠的に行ってもよい。 In the above description, after the detected SS concentration of the SS meter 28 has risen to a predetermined value, the entire amount of sludge is discharged from the pipe 24, but a part of the separated sludge from the cyclone 20 is discharged from the pipe 27 to the first pipe 27. It may be returned to the coagulation tank 2. Further, the separation sludge may be discharged intermittently instead of continuously.
 この第1の実施の形態では、第1及び第2薬注装置6,9による凝集剤添加量は一定とされている(定量添加方式)。ただし、原水のSS濃度を検出し、その検出結果に応じて凝集剤添加量を制御するようにしてもよい。 In the first embodiment, the amount of the coagulant added by the first and second chemical infusion devices 6 and 9 is fixed (quantitative addition method). However, the SS concentration of the raw water may be detected, and the added amount of the flocculant may be controlled according to the detection result.
 図2は、第2の実施の形態に係る凝集沈殿装置1Aを示している。この凝集沈殿装置1Aでは、制御器30は第1及び第2薬注装置6,9も後述のように制御するよう構成されている。凝集沈殿装置1Aのその他の構成は凝集沈殿装置1と同じであり、同一符号は同一部分を示している。 FIG. 2 shows an aggregating and settling apparatus 1A according to a second embodiment. In the coagulation and sedimentation apparatus 1A, the controller 30 is configured to control the first and second chemical injection devices 6 and 9 as described later. Other configurations of the coagulation and sedimentation apparatus 1A are the same as those of the coagulation and sedimentation apparatus 1, and the same reference numerals indicate the same parts.
 制御器30は、凝集沈殿装置1Aの起動時に、SS計28の検出濃度が所定値にまで上昇するまでは第1の実施の形態と同一の起動方法に従って、バルブ23,26の開閉を制御する。この実施の形態にあっては、制御器30は、さらに、SS計28の検出濃度が所定値にまで上昇するまでは、第1及び第2薬注装置6,9による無機凝集剤及び高分子凝集剤の添加量を定常運転時の標準添加量よりも多く(例えばそれぞれ標準添加量の1.5~5倍量特に2~5倍量)する。これにより、第1及び第2凝集槽2,3での凝集効果が増大し、沈殿槽4で沈殿したスラリーのSS濃度が高くなる。これにより、サイクロン20で分離される汚泥濃度が早期に所定値まで上昇する。 The controller 30 controls opening and closing of the valves 23 and 26 according to the same starting method as in the first embodiment until the detected concentration of the SS meter 28 rises to a predetermined value when the coagulating sedimentation apparatus 1A is started. . In this embodiment, the controller 30 further controls the inorganic coagulant and the polymer by the first and second dispensing devices 6 and 9 until the concentration detected by the SS meter 28 increases to a predetermined value. The addition amount of the flocculant is larger than the standard addition amount during the steady operation (for example, 1.5 to 5 times the standard addition amount, particularly 2 to 5 times the standard addition amount). Thereby, the aggregation effect in the first and second aggregation tanks 2 and 3 is increased, and the SS concentration of the slurry precipitated in the precipitation tank 4 is increased. As a result, the concentration of sludge separated by the cyclone 20 quickly increases to a predetermined value.
 図3は、第3の実施の形態に係る凝集沈殿装置1Bを示している。 FIG. 3 shows a coagulation-sedimentation apparatus 1B according to a third embodiment.
 この実施の形態にあっては、バルブ23,26の開閉を制御するために、制御器30の代りにタイマー31が設置されている。また、SS計28は省略されている。その他の構成は図1の凝集沈殿装置1と同一であり、同一符号は同一部分を示している。 In this embodiment, a timer 31 is provided instead of the controller 30 to control the opening and closing of the valves 23 and 26. Also, the SS meter 28 is omitted. Other configurations are the same as those of the coagulation and sedimentation apparatus 1 of FIG. 1, and the same reference numerals indicate the same parts.
 この実施の形態にあっては、凝集沈殿装置1Bの起動時に、凝集沈殿装置1Bへの原水流入開始から所定時間が経過するまでは、バルブ26を開、バルブ23を閉とし、サイクロン20からの分離汚泥の全量を第1凝集槽2に返送する。そして、所定時間が経過した後は、バルブ26を閉、バルブ23を開とし、サイクロン20からの分離汚泥の全量を配管24から排出する。なお、この場合も、サイクロン20からの分離汚泥の一部を配管27から第1凝集槽2に返送してもよいし、連続処理でなく間欠処理としてもよい。所定時間は凝集沈殿装置1BのHRTの0.5~4倍程度が好ましい。 In this embodiment, the valve 26 is opened and the valve 23 is closed until a predetermined time has elapsed from the start of the flow of raw water into the coagulation and sedimentation device 1B when the coagulation and sedimentation device 1B is started. The entire amount of the separated sludge is returned to the first flocculation tank 2. After a lapse of a predetermined time, the valve 26 is closed and the valve 23 is opened, and the entire amount of the separated sludge from the cyclone 20 is discharged from the pipe 24. Also in this case, a part of the separated sludge from the cyclone 20 may be returned to the first flocculation tank 2 from the pipe 27, or may be intermittent treatment instead of continuous treatment. The predetermined time is preferably about 0.5 to 4 times the HRT of the coagulation sedimentation apparatus 1B.
 この実施の形態においても、沈殿槽4で沈殿したスラリーのSS濃度が早期に上昇する。これにより、サイクロン20で分離される汚泥濃度が早期に上昇する。 も Also in this embodiment, the SS concentration of the slurry precipitated in the precipitation tank 4 increases early. As a result, the concentration of sludge separated by the cyclone 20 increases early.
 図4は、第4の実施の形態に係る凝集沈殿装置1Cを示している。この凝集沈殿装置1Cは、図3の凝集沈殿装置1Bと同じくタイマー31を備えていると共に、さらに第1及び第2薬注装置6,9による凝集剤添加量を制御する制御器32を備えている。 FIG. 4 shows a coagulating sedimentation apparatus 1C according to a fourth embodiment. The coagulation and sedimentation device 1C includes a timer 31 as in the coagulation and sedimentation device 1B of FIG. 3, and further includes a controller 32 that controls the amount of coagulant added by the first and second chemical injection devices 6, 9. I have.
 タイマー31は、図3の凝集沈殿装置1Bと同じく、凝集沈殿装置1Cへの原水流入開始(原水ポンプの運転開始)から所定時間が経過するまでは、バルブ26を開、バルブ23を閉とし、サイクロン20からの分離汚泥の全量を第1凝集槽2に返送する。そして、所定時間が経過した後は、バルブ26を閉、バルブ23を開とし、サイクロン20からの分離汚泥の全量を配管24から排出する。なお、この場合も、サイクロン20からの分離汚泥の一部を配管27から第1凝集槽2に返送してもよいし、連続処理でなく間欠処理としてもよい。 The timer 31 opens the valve 26 and closes the valve 23 until a predetermined time elapses from the start of inflow of raw water into the coagulation and sedimentation apparatus 1C (start of operation of the raw water pump), similarly to the coagulation and sedimentation apparatus 1B of FIG. The entire amount of the separated sludge from the cyclone 20 is returned to the first flocculation tank 2. After a lapse of a predetermined time, the valve 26 is closed and the valve 23 is opened, and the entire amount of the separated sludge from the cyclone 20 is discharged from the pipe 24. Also in this case, a part of the separated sludge from the cyclone 20 may be returned to the first flocculation tank 2 from the pipe 27, or may be intermittent treatment instead of continuous treatment.
 制御器32は、凝集沈殿装置1Cの起動(タイマー31のスタート(原水ポンプの運転開始))から所定時間経過するまでは、第1及び第2薬注装置6,9による無機凝集剤及び高分子凝集剤の添加量を定常運転時の標準添加量よりも多く(例えばそれぞれ標準添加量の1.5~5倍量)する。これにより、凝集槽2,3での凝集効果が増大し、沈殿槽4で沈殿したスラリーのSS濃度が上昇する。これにより、サイクロン20で分離される汚泥濃度が早期に所定値まで上昇する。 The controller 32 controls the inorganic coagulant and the polymer by the first and second chemical injection devices 6 and 9 until a predetermined time elapses from the start of the coagulation and sedimentation device 1C (start of the timer 31 (start of operation of the raw water pump)). The addition amount of the flocculant is made larger than the standard addition amount in the steady operation (for example, 1.5 to 5 times the standard addition amount, respectively). Thereby, the aggregation effect in the aggregation tanks 2 and 3 increases, and the SS concentration of the slurry precipitated in the precipitation tank 4 increases. As a result, the concentration of sludge separated by the cyclone 20 increases to a predetermined value at an early stage.
 第3,4の実施の形態のようなタイマーによる制御は、特に原水中のSS濃度が安定している(変動幅が比較的小さい)場合に有効である。 The control by the timer as in the third and fourth embodiments is particularly effective when the SS concentration in the raw water is stable (the fluctuation width is relatively small).
 本発明に係る凝集沈殿装置およびその起動方法は、ヤード排水の処理に好適であるが、その他の各種排水の処理にも適用可能である。 凝集 The coagulation sedimentation apparatus and its activation method according to the present invention are suitable for treating yard wastewater, but can also be applied to other various wastewater treatments.
 本発明における凝集沈殿装置の「起動」とは、新設装置の運転開始時だけでなく、メンテナンスや搬送など各槽の水を一旦抜いた後の初回の運転開始時も含まれる。 「“ Starting up ”of the coagulation sedimentation apparatus in the present invention includes not only the start of operation of the newly installed apparatus but also the first start of operation after draining water from each tank, such as for maintenance and transportation.
 本発明において使用する無機凝集剤や高分子凝集剤の種類はとくに限定されず、無機凝集剤としては、たとえばポリ塩化アルミニウム(PAC)、塩化第二鉄、硫酸第二鉄、ポリ硫酸鉄などを使用できる。高分子凝集剤としては、たとえばノニオン性、カチオン性、アニオン性あるいは両性の高分子凝集剤を用いることができる。 The kind of the inorganic flocculant and the polymer flocculant used in the present invention is not particularly limited, and examples of the inorganic flocculant include polyaluminum chloride (PAC), ferric chloride, ferric sulfate, and polyiron sulfate. Can be used. As the polymer flocculant, for example, a nonionic, cationic, anionic or amphoteric polymer flocculant can be used.
 上記実施の形態は本発明の一例であり、本発明は上記以外の態様とされてもよい。例えば、図1,2の実施の形態では、SS計は配管27に設けられているが、配管21又は25に設けられてもよい。また、図2、図4の態様において、各種凝集剤の添加量を増大させる期間は、バルブ26を開としている期間の一部であってもよい。 The above embodiment is an example of the present invention, and the present invention may be applied to other modes. For example, in the embodiments of FIGS. 1 and 2, the SS meter is provided on the pipe 27, but may be provided on the pipe 21 or 25. In addition, in the embodiments of FIGS. 2 and 4, the period in which the amount of addition of various coagulants is increased may be a part of the period in which the valve 26 is open.
 本発明を特定の態様を用いて詳細に説明したが、本発明の意図と範囲を離れることなく様々な変更が可能であることは当業者に明らかである。
 本出願は、2018年8月10日付で出願された日本特許出願2018-151718に基づいており、その全体が引用により援用される。
Although the invention has been described in detail using specific embodiments, it will be apparent to those skilled in the art that various modifications can be made without departing from the spirit and scope of the invention.
This application is based on Japanese Patent Application No. 2018-151718 filed on August 10, 2018, which is incorporated by reference in its entirety.
 1,1A,1B,1C 凝集沈殿装置
 2 第1凝集槽
 3 第2凝集槽
 4 沈殿槽
 6 第1薬注装置
 9 第2薬注装置
 20 サイクロン
 23,26 バルブ
 28 SS計
 30,32 制御器
 31 タイマー

 
1, 1A, 1B, 1C Coagulation and sedimentation apparatus 2 First coagulation tank 3 Second coagulation tank 4 Sedimentation tank 6 First chemical injection device 9 Second chemical injection device 20 Cyclone 23, 26 Valve 28 SS meter 30, 32 Controller 31 timer

Claims (8)

  1.  原水が導入され、第1凝集剤により凝集処理する第1凝集槽と、
     該第1凝集槽から排出された第1凝集処理水が導入され、第2凝集剤と沈降促進材により凝集処理する第2凝集槽と、
     該第2凝集槽から排出された第2凝集処理水が導入され、処理水とスラリーとに沈降分離する沈殿槽と、
     該沈殿槽から抜き出したスラリーを分離汚泥と沈降促進材とに分離し、分離した沈降促進材を該第2凝集槽に戻すサイクロンと
    を備え、
     該サイクロンの汚泥出口からの分離汚泥ラインが汚泥排出ラインと汚泥循環ラインとに分岐され、
     該汚泥循環ラインが前記第1凝集槽に接続されており、
     該汚泥循環ラインと汚泥排出ラインとの切替手段を有する
    凝集沈殿装置において、
     該凝集沈殿装置の起動時には該分離汚泥ラインを該汚泥循環ラインに接続して該サイクロンからの分離汚泥を該汚泥循環ラインを通じて該第1凝集槽に返送し、
     該凝集沈殿装置の起動終了後には連続的または間欠的に該分離汚泥ラインを該汚泥排出ラインに接続するかまたは該汚泥排出ライン及び汚泥循環ラインに分岐して該サイクロンからの分離汚泥の少なくとも一部を連続的又は間欠的に系外排出する
    ように前記切替手段を制御する制御手段を備えた
    ことを特徴とする凝集沈殿装置。
    A first coagulation tank into which raw water is introduced and coagulation treatment is performed with a first coagulant;
    A second coagulation tank into which the first coagulation treatment water discharged from the first coagulation tank is introduced and coagulated by a second coagulant and a sedimentation promoting material;
    A second coagulation treatment water discharged from the second coagulation tank is introduced, and the sedimentation tank sediments and separates into treated water and slurry;
    A cyclone for separating the slurry extracted from the sedimentation tank into separated sludge and a sedimentation promoting material, and returning the separated sedimentation promoting material to the second flocculation tank;
    A separated sludge line from the sludge outlet of the cyclone is branched into a sludge discharge line and a sludge circulation line,
    The sludge circulation line is connected to the first flocculation tank,
    In the coagulation sedimentation apparatus having switching means for the sludge circulation line and the sludge discharge line,
    When the coagulation settling apparatus is started, the separated sludge line is connected to the sludge circulation line, and the separated sludge from the cyclone is returned to the first coagulation tank through the sludge circulation line,
    After the start of the coagulation sedimentation apparatus, the separated sludge line is connected to the sludge discharge line continuously or intermittently or branched into the sludge discharge line and the sludge circulation line to separate at least one of the separated sludge from the cyclone. A coagulating sedimentation apparatus comprising: a control unit that controls the switching unit so that the unit is continuously or intermittently discharged from the system.
  2.  前記制御手段として、前記分離汚泥ラインまたは前記汚泥循環ラインに設けられたSS計と、該SS計の検出SS濃度が所定濃度に上昇するまで前記サイクロンからの分離汚泥を前記第1凝集槽に返送するように前記切替手段を制御する制御器とを備えた、請求項1に記載の凝集沈殿装置。 As the control means, an SS meter provided in the separated sludge line or the sludge circulation line, and the separated sludge from the cyclone is returned to the first flocculation tank until the detected SS concentration of the SS meter rises to a predetermined concentration. The coagulating sedimentation apparatus according to claim 1, further comprising: a controller that controls the switching unit so as to perform the switching.
  3.  前記SS計の検出SS濃度が所定濃度に上昇するまでの期間の少なくとも一部において、前記第1凝集槽への第1凝集剤の添加量および第2凝集槽への第2凝集剤の添加量を増大させる凝集剤添加量制御部が設けられている、請求項2に記載の凝集沈殿装置。 The amount of the first flocculant added to the first flocculating tank and the amount of the second flocculant added to the second flocculating tank during at least a part of the period until the SS concentration detected by the SS meter rises to the predetermined concentration. The coagulation sedimentation apparatus according to claim 2, further comprising a coagulant addition amount control unit for increasing the amount of coagulant.
  4.  前記制御手段として、前記第1凝集槽への原水供給開始後、所定時間、前記サイクロンからの分離汚泥を前記第1凝集槽に返送するように前記切替手段を制御するタイマーを備えた、請求項1に記載の凝集沈殿装置。 A timer for controlling the switching means so that the separated sludge from the cyclone is returned to the first flocculation tank for a predetermined time after starting supply of raw water to the first flocculation tank, as the control means. 2. The coagulation sedimentation apparatus according to 1.
  5.  前記第1凝集槽への原水供給開始後、所定時間が経過するまでの期間の少なくとも一部において、前記第1凝集槽への第1凝集剤の添加量および第2凝集槽への第2凝集剤の添加量を増大させる凝集剤添加量制御部が設けられている、請求項4に記載の凝集沈殿装置。 In at least a part of a period from the start of supply of raw water to the first coagulation tank until a predetermined time elapses, the amount of the first coagulant added to the first coagulation tank and the second coagulation to the second coagulation tank The coagulation sedimentation apparatus according to claim 4, further comprising a coagulant addition amount control unit for increasing the addition amount of the agent.
  6.  原水が導入され、第1凝集剤により凝集処理する第1凝集槽と、
     該第1凝集槽から排出された第1凝集処理水が導入され、第2凝集剤と沈降促進材により凝集処理する第2凝集槽と、
     該第2凝集槽から排出された第2凝集処理水が導入され、処理水とスラリーとに沈降分離する沈殿槽と、
     該沈殿槽から抜き出したスラリーを分離汚泥と沈降促進材とに分離し、分離した沈降促進材を該第2凝集槽に戻すサイクロンと
    を備え、
     該サイクロンの汚泥出口からの分離汚泥ラインが汚泥排出ラインと汚泥循環ラインとに分岐され、
     該汚泥循環ラインが前記第1凝集槽に接続されている
    凝集沈殿装置の起動方法において、
     該凝集沈殿装置の起動時には該サイクロンからの分離汚泥を該汚泥循環ラインを通じて該第1凝集槽に返送し、
     該凝集沈殿装置の起動終了後には該サイクロンからの分離汚泥の少なくとも一部を連続的又は間欠的に系外排出するように切り替える
    ことを特徴とする凝集沈殿装置の起動方法。
    A first coagulation tank into which raw water is introduced and coagulation treatment is performed with a first coagulant;
    A second coagulation tank into which the first coagulation treatment water discharged from the first coagulation tank is introduced and coagulated by a second coagulant and a sedimentation promoting material;
    A second coagulation treatment water discharged from the second coagulation tank is introduced, and the sedimentation tank sediments and separates into treated water and slurry;
    A cyclone for separating the slurry extracted from the sedimentation tank into separated sludge and a sedimentation promoting material, and returning the separated sedimentation promoting material to the second flocculation tank;
    A separated sludge line from the sludge outlet of the cyclone is branched into a sludge discharge line and a sludge circulation line,
    In the method for starting a coagulation settling apparatus in which the sludge circulation line is connected to the first coagulation tank,
    When the coagulation settling apparatus is started, the separated sludge from the cyclone is returned to the first coagulation tank through the sludge circulation line,
    A method for activating a coagulation sedimentation device, comprising switching at least part of the separated sludge from the cyclone to be continuously or intermittently discharged from the system after the start of the coagulation sedimentation device.
  7.  前記凝集沈殿装置の起動時に、前記第1凝集槽への第1凝集剤添加量および第2凝集槽への第2凝集剤の添加量を増加させる、請求項6に記載の凝集沈殿装置の起動方法。 The start-up of the coagulation-sedimentation apparatus according to claim 6, wherein when the coagulation-sedimentation apparatus is started, the amount of the first coagulant added to the first coagulation tank and the amount of the second coagulant added to the second coagulation tank are increased. Method.
  8.  前記原水がヤード排水である、請求項6又は7に記載の凝集沈殿装置の起動方法。

     
    The method according to claim 6 or 7, wherein the raw water is yard drainage.

PCT/JP2019/026497 2018-08-10 2019-07-03 Flocculation and sedimentation device, and startup method thereof WO2020031567A1 (en)

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JP2000317220A (en) * 1999-05-12 2000-11-21 Japan Organo Co Ltd Flocculating and settling device
US20110036772A1 (en) * 2007-06-22 2011-02-17 I. Kruger Inc. Method of Removing Phosphorus from Wastewater
US20110127220A1 (en) * 2007-12-20 2011-06-02 Otv Sa Method for Treating Water by Advanced Oxidation and Ballasted Flocculation, and Corresponding Treatment Plant
JP2013078715A (en) * 2011-10-03 2013-05-02 Japan Organo Co Ltd Flocculation and sedimentation apparatus
US20140339158A1 (en) * 2013-05-20 2014-11-20 Veolia Water Solutions & Technologies Support System and Process for Removing Ammonium, Soluble BOD and Suspended Solids from a Wastewater Stream
JP2014237122A (en) * 2013-05-07 2014-12-18 新日鐵住金株式会社 Coagulation sedimentation equipment and method

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JP2000317220A (en) * 1999-05-12 2000-11-21 Japan Organo Co Ltd Flocculating and settling device
US20110036772A1 (en) * 2007-06-22 2011-02-17 I. Kruger Inc. Method of Removing Phosphorus from Wastewater
US20110127220A1 (en) * 2007-12-20 2011-06-02 Otv Sa Method for Treating Water by Advanced Oxidation and Ballasted Flocculation, and Corresponding Treatment Plant
JP2013078715A (en) * 2011-10-03 2013-05-02 Japan Organo Co Ltd Flocculation and sedimentation apparatus
JP2014237122A (en) * 2013-05-07 2014-12-18 新日鐵住金株式会社 Coagulation sedimentation equipment and method
US20140339158A1 (en) * 2013-05-20 2014-11-20 Veolia Water Solutions & Technologies Support System and Process for Removing Ammonium, Soluble BOD and Suspended Solids from a Wastewater Stream

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