WO2020019544A1 - 一种测量铝电解槽阳极电流的系统及方法 - Google Patents
一种测量铝电解槽阳极电流的系统及方法 Download PDFInfo
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- WO2020019544A1 WO2020019544A1 PCT/CN2018/111315 CN2018111315W WO2020019544A1 WO 2020019544 A1 WO2020019544 A1 WO 2020019544A1 CN 2018111315 W CN2018111315 W CN 2018111315W WO 2020019544 A1 WO2020019544 A1 WO 2020019544A1
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/20—Automatic control or regulation of cells
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R19/00—Arrangements for measuring currents or voltages or for indicating presence or sign thereof
- G01R19/0092—Arrangements for measuring currents or voltages or for indicating presence or sign thereof measuring current only
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R19/00—Arrangements for measuring currents or voltages or for indicating presence or sign thereof
- G01R19/165—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values
- G01R19/16533—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values characterised by the application
- G01R19/16538—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values characterised by the application in AC or DC supplies
- G01R19/16542—Indicating that current or voltage is either above or below a predetermined value or within or outside a predetermined range of values characterised by the application in AC or DC supplies for batteries
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/364—Battery terminal connectors with integrated measuring arrangements
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
- G01R31/396—Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R15/00—Details of measuring arrangements of the types provided for in groups G01R17/00 - G01R29/00, G01R33/00 - G01R33/26 or G01R35/00
- G01R15/14—Adaptations providing voltage or current isolation, e.g. for high-voltage or high-current networks
- G01R15/24—Adaptations providing voltage or current isolation, e.g. for high-voltage or high-current networks using light-modulating devices
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the invention relates to the technical field of current measurement, in particular to a system and method for measuring anode current of an aluminum electrolytic cell.
- the electrolytic cell control system determines the electrolyte pseudo-resistance change according to the anode current, and then controls the thermal balance and cell stability. Especially in the electrolytic cell, the magnitude of the anode current on each anode directly determines the amount of alumina participating in the reaction in the anode area, that is, the amount of alumina consumed. Therefore, how to accurately measure the anode current has become a top priority in this field.
- independent anode current measurement mainly adopts two methods: equidistant voltage drop method and Hall magnetic effect measurement method.
- the former is estimated based on the voltage drop caused by the current passing through the horizontal bus bar or the anode guide bar. Because the horizontal bus bar and the anode guide bar have a large geometric size, the distribution of the current on the cross section has uncertainty and non-uniformity. And the difference in conductor temperature, it is only possible to measure the trend of change and it is difficult to give an accurate current value; the latter has a very complicated background magnetic field due to the staggered arrangement of the conductors on the electrolytic cell, and it is difficult to measure and obtain an accurate current value .
- the purpose of the present invention is to provide a system and method for measuring anode current of an aluminum electrolytic cell, so as to achieve accurate measurement of each anode current.
- the present invention provides a system for measuring anode current of an aluminum electrolytic cell, the system includes: a plurality of electrolytic cell units;
- the electrolytic cell unit includes: one column bus, two horizontal buses, m anodes, m anode guide rods, one or one pair of jumper buses, and multiple optical fiber current sensors;
- the m anode guides and the m anodes are evenly divided into two rows of A and B.
- One end of the anode guides of each row is respectively overlapped with each horizontal bus.
- the anode guides of each row are The other end is respectively connected to the anodes of each row, and each of the anodes and each anode guide rod are arranged one by one, and the jumper bus bar is disposed on one side or both sides of the feeding port, and two of the horizontal bus bars are provided.
- the jumper bus Connected by the jumper bus, one end of the pillar bus is connected to the first horizontal bus;
- one optical fiber current sensor is provided on the horizontal bus bar between the two anode guide rods;
- one of the anode guide bars and the pillar bus bar or jumper bus bar is provided with one of the horizontal bus bars.
- system further includes:
- An optical fiber protection tube is used to transmit the current information detected by each optical fiber current sensor to a measurement box for analysis and processing through a polarization maintaining fiber concentrated in the optical fiber protection tube.
- the invention also provides a method for measuring the anode current of an aluminum electrolytic cell, the method comprising:
- the current of the j-th anode in the i-th row is or among them, Is the current detected by the fiber-optic current sensor between the column bus bar or jumper bus bar and the i-th row and j-th anode guide rod, Is the current detected by the fiber-optic current sensor between the j-1th anode guide in the i-th row and the j-th anode guide in the i-th row, The current detected by the fiber-optic current sensor between the i-th row of the j-th anode guide rod and the i-th row of the j + 1-th anode guide rod;
- the current of the j-th anode in the i-th row is or
- the current of the i-th and j-th anodes is or These include:
- the third judgment result has an anode guide rod at the other end of the j-th anode guide rod in the i-th row, it is judged whether its number is the j-1th row in the i-th row and a fourth judgment result is obtained;
- the fourth judgment result is on the other end of the j-th anode guide in the i-th row, the number of the anode guide is i-th in the i-th row, the current of the j-th anode in the i-th row is
- the fourth judgment result is on the other end of the j-th anode rod in the i-th row, the anode rod number is not the j-1th in the i-th row, the current of the j-th anode in the i-th row is
- the current of the i-th and j-th anodes is or These include:
- the fifth judgment result is that the number of the anode guide rod is the j-1th row of the i-th row, the current of the jth anode of the i-th row is
- the current value flowing in the direction of the anode guide is positive, and the current value leaving the direction of the anode guide is negative.
- the present invention discloses the following technical effects:
- an optical fiber current sensor is installed between two adjacent anode guide rods and between the anode guide rod and the column bus bar or the jumper bus bar to measure the current, and the anode current can be accurately measured with a measurement error within 1%. It can realize the on-demand addition of the regional alumina feed amount, diagnose the anode status of the electrolytic cell, realize stable and efficient production of the electrolytic cell, significantly improve the current efficiency, reduce energy consumption, and realize further energy saving and emission reduction of the aluminum electrolytic cell.
- FIG. 1 is a structural diagram of an electrolytic cell unit according to an embodiment of the present invention.
- FIG. 2 is a flowchart of a method for measuring anode current of an aluminum electrolytic cell according to an embodiment of the present invention
- the object of the present invention is to provide a system and method for measuring anode current of an aluminum electrolytic cell, so as to realize accurate measurement of each anode current.
- the invention provides a system for measuring anode current of an aluminum electrolytic cell, the system includes: a plurality of electrolytic cell units;
- the electrolytic cell unit includes: one column bus bar 1, two horizontal bus bars 4, m anodes 2, m anode guide bars 3, one or one pair of jumper bus bars 6, and a plurality of optical fiber current sensors 5;
- the m anode guides 3 and the m anodes 2 are evenly divided into two rows of A and B. One end of the anode guides 3 of each row is respectively overlapped with each of the horizontal bus bars 4. The other end of the anode guide rod 3 is respectively connected to the anodes 2 of each row.
- Each of the anodes 2 and the anode guide rods 3 are arranged one-to-one correspondingly, and the jumper bus 6 is disposed on one side or two sides of the feed inlet.
- two horizontal bus bars 4 are connected through the jumper bus bar 6, and one end of the column bus bar 1 is connected to the first horizontal bus bar 4; the current is supplied by the column bus bar 1 and the jumper bus bar. It is delivered to each of the horizontal busbars 4 and then passes through each of the horizontal busbars 4 to transmit the current to the corresponding anodes 2 through the anode guide rods 3 overlapped with the horizontal busbars 4.
- one optical fiber current sensor 5 is provided on the horizontal bus bar 4 between the two anode guide rods 3. ;
- system according to the present invention further includes:
- An optical fiber protection tube is used to transmit the current information detected by each optical fiber current sensor 5 to a measurement box for analysis and processing through a polarization maintaining fiber concentrated in the optical fiber protection tube.
- the present invention divides m of the anode guide rods 3 and m of the anodes 2 into two rows, A and B, on average.
- the current value flowing in the direction of the anode guide rod 3 is positive, and the current value leaving the anode guide rod 3 is negative.
- the electrolytic cell unit includes: 1 column bus bar 1, 2 horizontal bus bars 4, 10 Anodes 2, 10 anode guides 3, 1 pair of jumper busbars 6, 12 fiber-optic current sensors 5;
- the 10 anode rods 3 and 10 the anode 2 are evenly divided into 2 rows, namely A and B rows, the first anode 2 in the first row is represented by A1, and the first in the second row Each anode 2 is represented by B1, and other similar reasons will not be discussed one by one here.
- One end of the anode guide rods 3 in each row is overlapped with each of the horizontal bus bars 4, and the anode guide rods 3 in each row.
- each anode 2 and each anode guide rod 3 are arranged one-to-one correspondingly, and the jumper busbars 6 are respectively disposed on both sides of the inlet, two
- the horizontal busbars 4 are connected through the jumper busbars 6, and one end of the column busbars 1 is connected to the first horizontal busbar 4.
- the current is transmitted from the column bus 1 to the horizontal bus 4 connected to the column bus 1, and is transmitted to the horizontal bus 4 on the B side through the jumper bus 6, and then the current is passed through the horizontal bus 4
- the anode guide rods 3 overlapped with the horizontal bus bar 4 are conveyed to the corresponding anodes 2.
- the optical fiber current sensor 5 uses the Faraday magneto-optical effect principle that light can deflect in a magnetic field, and uses a closed-loop optical path method to effectively overcome the interference of the background magnetic field and contact, and has high measurement accuracy.
- the optical fiber current sensor 5 transmits an optical signal
- the conductive medium is an optical fiber. Natural electrical insulation is safe, reliable, flexible, and easy to install.
- the present invention can install a fiber-optic current sensor 5 between two adjacent anode guides 3 and between the anode guide 3 and the column bus 1 or the jumper bus 6 to measure the current. Accurately measure the current of each anode, and the measurement error is within 1%. It can realize the on-demand addition of regional alumina feeding amount, diagnose the anode state of the electrolytic cell, realize stable and efficient production of the electrolytic cell, significantly improve the current efficiency and reduce Energy consumption, to achieve further energy saving and emission reduction of aluminum electrolytic cells.
- the present invention can add the amount of alumina according to needs, thereby avoiding imbalance in anode current distribution and imbalance in alumina demand caused by the conventional pole changing operation.
- the status information of each anode and each feeding point area can be obtained, including alumina concentration, local pole distance and local fault.
- Accurate detection of independent anode current can predict the trend and failure of local conditions, and then realize the health management of the entire electrolytic cell.
- Accurate detection of independent anode current to obtain higher current efficiency, and electrolysis can be performed at lower voltages.
- Accurate detection of independent anode currents can predict and diagnose faults that occur on each anode / area.
- Accurate detection of independent anode current can judge and process local effects in time, thereby eliminating anode effects and reducing greenhouse gas emissions.
- FIG. 2 is a flowchart of a method for measuring anode current in an aluminum electrolytic cell according to an embodiment of the present invention. As shown in FIG. 2, the present invention also provides a method for measuring anode current in an aluminum electrolytic cell. The method includes:
- Step S1 Determine the i-th row of the j-th anode 2 and the i-th row of the j-th anode guide rod 3 corresponding to the i-th row of the j-th anode 2; where i is equal to A or B, and j is A positive integer greater than or equal to 2 and less than or equal to m / 2.
- Step S2 It is determined whether there is a column bus bar 1 or a jumper bus bar 6 at both ends of the i-th and j-th anode guide bars 3 to obtain a first judgment result.
- Step S3 If there is a pillar bus 1 or a jump bus 6 in the first judgment result, the current of the i-th and j-th anode 2 is or among them, Is the current detected by the optical fiber current sensor 5 between the column bus 1 or the jump bus 6 and the i-th j-th anode guide rod 3, Is the current detected by the fiber-optic current sensor 5 between the i-th row of the j-1th anode guide rod 3 and the i-th row of the j-th anode guide rod 3, The current detected by the optical fiber current sensor 5 between the i-th row of the j-th anode guide rod 3 and the i-th row of the j + 1-th anode guide rod 3.
- Step S4 if there is no pillar busbar 1 or jumper busbar 6 in the first judgment result, it is judged whether the anode guide rods 3 exist at both ends of the i-th row and the j-th anode guide rod 3, and a second judgment result is obtained.
- Step S5 If the anode guide rod 3 exists in the second judgment result, the current of the i-th and j-th anode 2 is For example, the current on the anode 2A4 is measured by the optical fiber current sensor 5 between A3 and A4. Current measured by fiber-optic current sensor 5 between A4 and A5 Size and direction are determined together.
- the current of the anode 2A4 when with When flowing to the anode guide 3 corresponding to the anode 2A4, the direction is positive, and when leaving the anode guide 3 corresponding to the anode 2A4, the direction is negative. Therefore, the current of the anode 2A4 is
- Step S6 If there is only one anode guide rod 3 in the second judgment result, the current of the i-th row and the j-th anode 2 is or
- Step S3 if there is a pillar bus 1 or a jumper bus 6 in the first judgment result, the current of the i-th and j-th anode 2 is or This includes:
- Step S31 If the pillar bus 1 or the jump bus 6 is present in the first judgment result, it is judged whether the anode guide 3 exists in the other end of the i-th row and the j-th anode guide 3, and a third judgment result is obtained.
- Step S32 If the third judgment result does not exist on the other end of the j-th anode guide rod 3 in the i-th row, the current of the j-th anode electrode 2 in the i-th row is
- Step S33 If the third judgment result exists in the anode guide rod 3 at the other end of the j-th anode guide rod 3 in the i-th row, it is judged whether its number is the j-1th member in the i-th row and a fourth judgment result is obtained.
- Step S34 If the fourth judgment result is that the anode rod 3 on the other end of the i-th row of the j-th anode guide rod 3 is the i-th row of the j-1th anode, the current of the i-th row of the j-th anode 2
- the current on the anode 2B2 is measured by the optical fiber current sensor 5 between B1 and B2.
- Current measured by fiber-optic current sensor 5 between B2 and jumper bus 6 Size and direction are determined together.
- Step S35 If the fourth judgment result is that the anode rod 3 on the other end of the i-th row of the j-th anode guide rod 3 is not the i-th row of the j-1th anode, the current of the i-th row of the j-th anode 2 is For example, the current on the anode 2B3 is measured by the optical fiber current sensor 5 between B3 and B4. Current measured by fiber-optic current sensor 5 between B3 and jumper bus 6 Size and direction are determined together.
- Step S6 if there is only one anode guide rod 3 in the second judgment result, the current of the i-th and j-th anode 2 is or These include:
- Step S61 if there is only one anode guide rod 3 in the second judgment result, it is judged whether the number of the anode guide rod 3 is the j-1th row in the i-th row, and a fifth judgment result is obtained.
- Step S62 If the fifth judgment result is that the number of the anode guide rod 3 is the i-1th row and the j-1th row, the current of the ith row and the jth anode 2 is For example, the current on the anode 2A5 is measured by the optical fiber current sensor 5 between A4 and A5. Size and direction are determined together. When calculating the current of anode 2A5, when When flowing to the anode guide rod 3 corresponding to the anode 2A5, the direction is positive, and when leaving the anode guide rod 3 corresponding to the anode 2A5, the direction is negative. Therefore, the current of the anode 2A5 is
- Step S63 If the result of the fifth judgment is that the number of the anode guide rod 3 is not the j-1th row of the i-th row, the current of the jth anode 2 of the i-th row is For example, the current on the anode 2A1 is measured by the optical fiber current sensor 5 between A1 and A2. Size and direction are determined together. When calculating the current of anode 2A1, when When flowing to the anode guide rod 3 corresponding to the anode 2A1, the direction is positive, and when leaving the anode guide rod 3 corresponding to the anode 2A1, the direction is negative. Therefore, the current of the anode 2A1 is
Abstract
Description
Claims (6)
- 一种测量铝电解槽阳极电流的系统,其特征在于,所述系统包括:多个电解槽单元;所述电解槽单元包括:1个立柱母线、2个水平母线、m个阳极、m个阳极导杆、1个或1对跨接母线和多个光纤电流传感器;将m个所述阳极导杆以及m个所述阳极平均分成A、B两排,各排的所述阳极导杆的一端分别搭接在各水平母线上,各排的所述阳极导杆的另一端分别连接各排的所述阳极上,各所述阳极与各阳极导杆一一对应设置,所述跨接母线设置在进料口的一侧或两侧,两个所述水平母线之间通过所述跨接母线连接,所述立柱母线的一端连接到第一个水平母线上;当所述阳极导杆的一侧与另一个所述阳极导杆相邻时,则在两个所述阳极导杆之间的所述水平母线上设置一个所述光纤电流传感器;当所述阳极导杆的任意一侧相邻所述立柱母线或跨接母线时,则在所述阳极导杆与所述立柱母线或跨接母线之间的所述水平母线上设置一个所述光纤电流传感器;当所述阳极导杆的任意一侧既没有与所述阳极导杆相邻,也没有与所述立柱母线或跨接母线相邻时,则在该侧的所述水平母线上无需设置所述光纤电流传感器。
- 根据权利要求1所述的系统,其特征在于,所述系统还包括:光纤保护管,用于将各光纤电流传感器检测的电流信息通过集中在光纤保护管内的保偏光纤传递到测量盒中进行分析处理。
- 一种测量铝电解槽阳极电流的方法,其特征在于,所述方法应用于根据权利要求1至权利要求2任一项所述的系统,所述方法包括:确定待检测电流的第i排第j个阳极,以及与第i排第j个阳极对应的第i排第j个阳极导杆;其中,i等于A或B,j为大于等于2小于等于m/2的正整数;判断第i排第j个阳极导杆的两端是否存在立柱母线或跨接母线,获 得第一判断结果;如果第一判断结果存在立柱母线或跨接母线,则第i排第j个阳极的电流为 或 其中, 为立柱母线或跨接母线与第i排第j个阳极导杆之间的光纤电流传感器检测的电流, 为第i排第j-1个阳极导杆与第i排第j个阳极导杆之间的光纤电流传感器检测的电流, 为第i排第j个阳极导杆与第i排第j+1个阳极导杆之间的光纤电流传感器检测的电流;如果第一判断结果不存在立柱母线或跨接母线,则判断第i排第j个阳极导杆的两端是否均存在阳极导杆,获得第二判断结果;
- 如果第一判断结果存在立柱母线或跨接母线,则判断第i排第j个阳极导杆的另一端是否存在阳极导杆,获得第三判断结果;如果第三判断结果在第i排第j个阳极导杆的另一端存在阳极导杆,则判断其编号是否为第i排第j-1个,获得第四判断结果;
- 根据权利要求3所述的方法,其特征在于,对于第i排第j个阳极导杆,流向该阳极导杆方向的电流值为正,离开该阳极导杆方向的电流值为负。
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CN112725840B (zh) * | 2020-12-29 | 2021-11-30 | 北方工业大学 | 一种铝电解槽数字孪生控制系统 |
CN116752193B (zh) * | 2023-06-09 | 2024-02-02 | 北京世维通光智能科技有限公司 | 一种测量铝电解槽区域阳极电流的系统及方法、电子设备 |
CN116660613B (zh) * | 2023-07-31 | 2023-10-31 | 北京世维通光智能科技有限公司 | 基于单光纤环的区域阳极电流测量系统及电解槽测量系统 |
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2018
- 2018-07-25 CN CN201810823925.4A patent/CN108998813A/zh active Pending
- 2018-10-23 WO PCT/CN2018/111315 patent/WO2020019544A1/zh active Application Filing
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2019
- 2019-07-12 US US16/510,284 patent/US20200032408A1/en not_active Abandoned
- 2019-07-24 AU AU2019208191A patent/AU2019208191A1/en not_active Abandoned
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CN104278295A (zh) * | 2013-07-04 | 2015-01-14 | 贵阳铝镁设计研究院有限公司 | 一种铝电解槽阳极电流分布测量系统及其测量方法 |
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AU2019208191A1 (en) | 2020-02-13 |
US20200032408A1 (en) | 2020-01-30 |
CN108998813A (zh) | 2018-12-14 |
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