WO2020010182A1 - Réacteur pour liquide et gaz et procédé d'utilisation - Google Patents

Réacteur pour liquide et gaz et procédé d'utilisation Download PDF

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Publication number
WO2020010182A1
WO2020010182A1 PCT/US2019/040473 US2019040473W WO2020010182A1 WO 2020010182 A1 WO2020010182 A1 WO 2020010182A1 US 2019040473 W US2019040473 W US 2019040473W WO 2020010182 A1 WO2020010182 A1 WO 2020010182A1
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WIPO (PCT)
Prior art keywords
gas
liquid
reaction chamber
flow
electric field
Prior art date
Application number
PCT/US2019/040473
Other languages
English (en)
Inventor
Walter Riley Buchanan
Grant William Forsee
Original Assignee
Ion Inject Technology Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US16/027,005 external-priority patent/US10882021B2/en
Priority claimed from US16/205,844 external-priority patent/US11452982B2/en
Application filed by Ion Inject Technology Llc filed Critical Ion Inject Technology Llc
Priority to EP19830254.9A priority Critical patent/EP3818014A4/fr
Publication of WO2020010182A1 publication Critical patent/WO2020010182A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia
    • C02F2101/163—Nitrates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/32—Hydrocarbons, e.g. oil
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/002—Construction details of the apparatus
    • C02F2201/003—Coaxial constructions, e.g. a cartridge located coaxially within another
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4619—Supplying gas to the electrolyte

Definitions

  • Embodiments of the current invention relate to plasma reactors and methods and systems that utilize plasma reactors.
  • Plasma reactors may include at least two electrodes which are spaced apart.
  • a voltage difference is applied to the electrodes and an electric field is established between them.
  • a stream of gas may be introduced to the space between the electrodes such that it passes through the electric field. Exposure to the electric field generally ionizes the gas and creates a plasma. If a stream of liquid is also introduced to the space between the electrodes, the gas and liquid may form two layers flowing in parallel and a plasma may form in the gas and at the surface of the liquid and further, the ions resulting from the plasma may be injected into, or may otherwise enter into the liquid as it passes through the electric field.
  • Plasma injection into liquid may be utilized for applications such as: in-line liquid hydrocarbon fuel reforming for hydrogen enrichment to improve the fuel economy of internal combustion engines; nitrogen fixing by direct nitrogen ion injection into water; destruction of high molecular weight hydrocarbons (proteins and pharmaceuticals) in drinking water;
  • ammonia/nitrate sequestering for treatment of high nitrate content water; demineralization (water softening) for consumer and industrial markets; nitrification of water for agricultural use; pH modification of liquid streams; disinfection, oxygen and ozone injection; and other similar applications.
  • the second electrode in close proximity and directly in contact with the liquid.
  • the second electrode may contact the liquid but also may be placed in close proximity or further away from the first electrode.
  • the second electrode may be dielectrically isolated from the liquid by a non-conductive layer.
  • the ionization energy of a gas is the minimum amount of energy required to remove the most loosely bound electron, also known as the valence electron, of an isolated neutral atom, molecule, or ion of the gas.
  • the ionization energy varies for from gas to gas and the form of the gas, and these values are well-known to those skilled in the art.
  • the molar ionization energy of atomic nitrogen is approximately 1402.3 kJ mol-l
  • atomic oxygen is approximately 1313.9 kJ mol-l
  • atomic argon is approximately 1520.6 kJ mol-l.
  • producing ionized gases or plasmas generally requires dissociating molecules of the gas, stripping shared electrons so atoms dissociate, and holding the atoms in an ionized form.
  • Non-thermal plasmas which can be produced using a gas adjacent to a liquid in reactors such as those described in U.S. Patents Nos. 9,287,800, 10,010,854, and
  • oxygen levels of approximately 12 to 14 parts-per-million (PPM) are typically desirable. In some applications, levels as high as 50 PPM are desired.
  • PPM parts-per-million
  • Aquaponics which combines conventional aquaculture, raising aquatic organisms in tanks, with hydroponics, maintaining high oxygen levels is often required for growth and good health of the species being raised.
  • a first embodiment of the current invention provides a plasma laminar flow reactor comprising a housing, an electric field generator, an upper flow spreader, and a lower flow spreader.
  • the housing may include an internal reactor chamber, a gas inlet port, and liquid inlet and liquid outlet ports.
  • the electric field generator may include a first electrode, an optional pre-ionization electrode and a spaced apart second electrode and may generate an electric field or electric fields therebetween.
  • the first electrode and optional pre-ionization electrode may be composed of one or more concentric shapes.
  • a second electrode may have a shape similar to the first electrode or another shape depending on the application and the electrical nature of the liquid passing through the reactor. The second electrode may be spaced close to or spaced farther from the first electrode.
  • the second electrode may have any shape convenient to the design. Together, the first and second electrodes may produce a cylindrical electrical field close to the first electrode.
  • the optional pre-ionization electrode may produce an electric field in close proximity to the field produced by the first electrode and second electrode.
  • the plasma laminar flow reactor may also include a dielectric element positioned between the first electrode, the optional pre-ionization electrode, and the second electrode adjacent to the first electrode and optional pre-ionization electrode.
  • the upper flow spreader may supply a stream of gas and liquid to the reactor chamber and may be positioned within the reactor chamber concentrically with the first electrode and the optional pre-ionization electrode.
  • the lower flow spreader may supply a base for the stream of liquid as it flows to the reactor chamber and may be positioned within the reactor chamber concentrically with the first electrode and the upper flow spreader.
  • the gas may create a gas zone inside the reactor chamber.
  • the stream of liquid and the stream of gas may flow adjacent one another radially outward from the center of the reactor chamber and pass through the electric field. This may allow the gas and liquid to create and maintain two layers (gas over liquid) as the gas and liquid pass through the electric field.
  • the gas may be injected from a relatively higher pressure gas source than the liquid through a flow limiting valve, small pump either as a steady flow or pulsed on and off, or other means well known to those familiar with gas control systems, such that the gas zone above the liquid is maintained.
  • a second embodiment of the current invention provides for an alteration of the second electrode by adding a dielectric isolation between the second electrode and the liquid. This may enable complete electrical isolation of the drive electronics and the liquid and gases to be used in the reactor. In addition, this may allow for plasma reactors without any conductive elements contacting the liquid.
  • a third embodiment of the current invention provides an alteration to the first electrode, the pre-ionization electrode, and/or the second electrode that can be used to modify the electrical characteristics of the reactor. This may enable larger reactors and more flexibility in design.
  • the electrode is broken into several smaller electrodes. This may allow the plasma area to be larger without a proportional increase in the capacitance of the first electrode. This may be desirable for the voltage generator.
  • the number of first or second electrodes may depend on the needs of the reactor and the reaction desired.
  • the present invention includes plasma reactor systems having a housing with an internal reaction chamber; at least one electric field generator configured for generating one or more electric fields between electrodes, with at least a portion of an electric field within the reaction chamber; a dielectric element; a gas source; a liquid source; a gas inlet path to the reaction chamber; and a liquid inlet path to the reaction chamber, where the stream of gas and stream of liquid within the reaction chamber are configured to flow adjacent one another and to pass through the electric field to produce an effluent.
  • Creating a plasma zone using a gas adjacent to a liquid accommodates many novel uses. These uses may include, but are not limited to, ionizing a gas and injecting the ionized particles into a liquid to create a new liquid; ionizing a gas and injecting ionized particles into a liquid to disinfect, oxidize, or otherwise modify the liquid in a desirable manner; ionizing a gas in order to dissociate molecules into their constituent atoms or different molecules in the gas to allow for undesirable atoms and/or molecules to enter a liquid and be removed from the gas stream; and ionizing a gas which modifies the molecules of the liquid in a desirable manner.
  • a reactor system and method is configured for injecting or infusing ionized molecular particles, ionized monatomic particles, and/or non-ionized particles of a gas into a flowing or non-flowing liquid.
  • the reactor includes a reaction chamber configured for holding a liquid and a gas adjacent to the liquid.
  • a high intensity alternating current (AC) electric field is connected and applied to the reaction chamber, configured for making contact with the gas and/or the liquid.
  • the voltage power level of the AC electric field is configured for adjustment as desired for optimizing desired gas particle injection, infusion, or diffusion into liquid. By varying the electrical field strength of these systems, the ratio of molecular infusion and ionic injection can be controlled.
  • the AC electric field may or may not ionize molecules in a gas or liquid and may terminate in a liquid.
  • the electric field may pass through a gas to be infused into a liquid while the gas is adjacent to the liquid and/or pass through the liquid.
  • the present invention is configured for adjustment of the electric field to enhance the infusion of gas particles into liquid.
  • Fig. 1 is an isometric view of a plasma reactor constructed in accordance with various embodiments of the current invention.
  • Fig. 2 is an exploded view of the plasma reactor of Fig. 1.
  • Fig. 3 is a cross sectional view of the plasma reactor of Fig. 1 cut along the line 3 - 3 of Fig. 1.
  • Fig. 4 is an enlarged cross sectional view of a plasma reactor from Fig. 3 highlighting the upper portion of a reactor chamber.
  • FIG. 5 is an enlarged cross sectional view of a plasma reactor showing gas and liquid flow paths.
  • Fig. 6 is the enlarged cross sectional view of a plasma reactor of Fig. 5 showing the second embodiment of the plasma reactor showing a dielectrically isolated second electrode.
  • Fig. 7 is the enlarged cross sectional view of a plasma reactor of Fig. 5 showing a reactor with multiple electrodes on the pre-ionizer and first electrode.
  • Fig. 8 is a graph of Methylene Blue reduction in reactor effluent water vs. reactor power using oxygen as a feed gas.
  • Fig. 9 is a chart of residual dissolved oxygen in effluent water after treatment with an oxygen feed gas.
  • Fig. 10 is a chart of Oxidization Reduction Potential of an effluent gas after treatment with an oxygen feed gas.
  • Fig. 11 is a graph using pH to monitor the reactor effluent water vs. % nitrogen in the gas (feed gas) fed into the plasma reactor.
  • Fig. 12 is a confirmation by ultraviolet-visible spectroscopy (UV/VIS) that levels of nitrogen in the effluent water are increased in the effluent water.
  • UV/VIS ultraviolet-visible spectroscopy
  • Fig. 13 is a confirmation by graph of ultraviolet- visible spectroscopy
  • UV/VIS UV/VIS
  • Fig. 14 is a graph of the ratio of hydrogen peroxide (H202) to dissolved ozone
  • Fig. 15 is a chart of production rates of hydrogen peroxide and hydrogen as a gas or as dissolved hydrogen in the water using argon and argon/hydrogen mixtures as feed gases vs. reactor power.
  • Fig. 16 is a graph showing dissolved oxygen (DO2) and Oxidation Reduction
  • ORP ORP in effluent water vs. power using a reactor of the present invention.
  • DO2 is monitored using a dissolved oxygen meter, and ORP is used to monitor oxidization radicals such as dissolved ozone formation after initiation of plasma in the reactor.
  • This embodiment of the reactor is using water as a liquid and oxygen as a feed gas.
  • Fig. 17 shows the infusion of oxygen into the liquid at voltage generator power levels below the power required to ionize the gas and inject oxygen radicals into the liquid.
  • “embodiments” mean that the feature or features being referred to are included in at least one embodiment of the technology.
  • references to“one embodiment”,“an embodiment”, or“embodiments” in this description do not necessarily refer to the same embodiment and are also not mutually exclusive unless so stated and/or except as will be readily apparent to those skilled in the art from the description.
  • a feature, structure, act, etc. described in one embodiment may also be included in other embodiments, but is not necessarily included.
  • the current technology can include a variety of combinations and/or integrations of the embodiments described herein.
  • a plasma reactor 10 constructed in accordance with at least a first embodiment of the current invention, is shown.
  • the reactor 10 generally receives a gas, a liquid, and electrical stimulus as inputs.
  • the gas may be ionized to form a plasma over the liquid which is in contact with the liquid.
  • the ionized gas interacts with the liquid to create an effluent or product.
  • the plasma reactor 10 broadly comprises a lower housing 18, a housing wall 45, an upper housing 17, at least one dielectric element 23, an upper flow spreader 25, a lower flow spreader 34, first electrode(s) 24, a second electrode which may be the lower flow spreader 34 or another second electrode configuration herein described, and a reaction or effluent chamber 26.
  • the reactor may also include an optional pre-ionization electrode 36.
  • An electric field generator may be attached to the first and second electrodes. In cases where an optional pre-ionization electrode is utilized, an electric field generator may be attached to the pre-ionization electrode.
  • the plasma reactor 10 may also include a plurality of gaskets or seals, such as O-ring seals, that are positioned at the interfaces between various components of the reactor 10.
  • the housings 17, 18, and 45 generally retain the components of the plasma reactor 10, and its shape may be adapted to the system in which it is implemented.
  • the housings may include additional components that adapt the plasma reactor 10 to the system in which it is implemented.
  • the housing may have a rounded shape with a plurality of sidewalls.
  • the housings 17, 18, and 45 may also include aligned threaded and non-threaded holes 37 to allow for fasteners to assemble the housings 17 and 45 to the lower housing 18.
  • the lower housing 18 may include a liquid inlet port 20 and a liquid outlet port 21 which may be connected to the liquid inlet tube 19 and liquid outlet tube 22 respectively.
  • the housings and other components may be constructed from metals, plastics, ceramics, or the like.
  • the upper housing 17 generally retains the first electrode 24, optional pre ionization electrode 36, high dielectric element 23, and alignment rod 12.
  • the upper housing 17 may have a box shape with a plurality of sidewalls and an internal cavity 38 bounded by the sidewalls.
  • the internal cavity 38 may be filled with dielectric materials, ceramics, polymers, gases, or the like to provide electrical isolation and suppress undesirable corona discharge from the first electrode 24 to the upper housing 17 and alignment rod 12.
  • the upper housing lid 17 may also have a second opening roughly centered on the housing to allow for a central alignment rod 12 to which the housing lid 17, dielectric element 23, upper flow spreader 25, and second lower flow spreader 34 may be connected, thereby facilitating good alignment between the various reactor components.
  • the alignment rod 12 may have a gas inlet hole 13 roughly centered in the rod which continues through the rod to the gas inlet port 14 which may allow gas to pass through the port into the gas inlet chamber 15.
  • the alignment rod 12 may be made of electrically conductive material which may allow the use of the alignment rod 12 to electrically contact the lower spreader 34.
  • the lower spreader 34 may be made of conductive material and act as the second electrode or may be made from electrically nonconductive materials which may require an alternate second electrode configuration described herein.
  • the use of the lower spreader 34 as an electrode, or an alternate second electrode configuration may depend on the type of liquid and gas reaction desired or other design considerations.
  • An optional gas pre-ionization electrode 36 may be included to enable the gas entering the reactor to be ionized prior to entering the reactor chamber 26. This may result in a greater degree of gas ionization.
  • the upper flow spreader 25 may be made of material such as ceramics or metals that pass the electric field to the area generally under the pre-ionization electrode 36.
  • the pre-ionization electrode 36 may be connected to a second electrical source or use the same source as the first electrode 24. In some cases the first electrode may simply be extended over the upper flow spreader 25 to facilitate this function. This pre-ionization electrode 36 may not be required in all reactors and is optional depending on the reactor requirements.
  • the first electrode 24 and lower flow spreader 34 or alternate second electrodes may be spaced apart, and the electric field may exist between the two components. Both components 24 and 34 or alternate second electrode may be connected to an external voltage supply which controls the characteristics of the electric field.
  • the voltage supply may provide a plasma generating voltage up to 150 kV of pulsed DC, AC, or other wave form used to create a plasma.
  • the first electrode 24 and optional pre ionization electrode 36 may be connected to a variable voltage through the wire 11 and 44 respectively, while the lower flow spreader 34 may be connected as a second electrode or alternate second electrode may be connected to an electrical ground or neutral through the alignment rod.
  • the first electrode 24 may be annular or ring-shaped, although other shapes are possible, and may be constructed from a metal, such as iron, nickel, gold, copper, alloys thereof, or the like.
  • the first electrode 24 may be located in the internal cavity 38 and may be isolated from the reactor chamber 26 by the dielectric element 23.
  • the lower flow spreader 34 or alternate second electrode may be generally cylindrically shaped and attached to the alignment rod. In some applications the location of the second electrode may not be critical, and the second electrode may be placed as convenient for the design of the reactor farther away from the first electrode 24.
  • the second electrode may be shaped the same as the first electrode 24 and positioned to align with the first electrode within the body of a nonconductive lower spreader 34, as described in more detail below.
  • the electric field generated may be roughly cylindrical in shape and positioned roughly below the respective electrode.
  • the dielectric element 23 generally provides an insulating gap across which at least a portion of the electric field is established.
  • the dielectric element 23 may be planar and disc-shaped, although other shapes are possible, and may be constructed from insulating dielectric material well known in this field such as ceramics, polymers, or the like.
  • the first electrode 24 and optional pre-ionization electrode 36 may be plated, deposited, bonded, glued, or otherwise affixed to the upper surface of the dielectric element 23.
  • the upper flow spreader 25 generally allows the gas to enter the reactor chamber 26 through gas inlet port 13, alignment rod 12, gas inlet port 14, and gas inlet chamber 15 in a roughly radial pattern between the upper flow spreader and the dielectric element 23 and allows liquid to flow roughly evenly in a radial pattern over the lower flow spreader into the reactor chamber 26.
  • the upper flow spreader 25 may have a generally conical shape with a center hole which may allow the upper flow spreader to be mounted on the alignment rod 12.
  • the lower surface of the upper spreader 25 and upper surface of the lower spreader 36 may create a liquid inlet chamber 27 and may be shaped such that the liquid entering the liquid inlet chamber from the inlet coupler 48 through the water inlet opening 46 exits the inlet chamber 27 radially outward on the surface of the lower spreader 34 into the reactor chamber 26.
  • the inner surface may be enlarged away from the alignment rod 12 and may create a gas inlet chamber 15.
  • the alignment rod may be hollow to facilitate the passage of gas from the inlet port and may have an opening forming a gas outlet port 14 near the gas inlet chamber 15 which may allow gas to flow through the alignment rod into the gas inlet chamber 15.
  • the lower end of the alignment rod 12 may have the gas blocked with a cap nut 47 or other means such that the gas may not pass through the alignment rod to the inlet coupler 48.
  • the upper flow spreader 25 may be positioned opposite the dielectric element
  • the upper flow spreader 25 may also be positioned concentrically with the first electrodes 24 and optional pre-ionization electrode 36. Gas may flow into gas chamber 15 and may flow radially out to the reactor chamber 26.
  • the combination of the upper flow spreader 25 and the lower flow spreader may also facilitate the flow of liquid from the liquid inlet chamber 27 to the reactor chamber 26.
  • the inner area of the lower flow spreader 34, in combination with the lower surface of the upper flow spreader 25, may generally establish a radial flow pattern for the liquid before entering the reaction chamber 26.
  • the lower flow spreader 34 may have a generally cylindrical shape with a circumferential sidewall.
  • the upper flow spreader 25 may be positioned within the hollow interior of the housing wall 45, such that the upper flow spreader 25 is concentric with the lower flow spreader 34. There may be a space between the outer surface of the upper flow spreader 25 and the lower flow spreader 34 which forms a liquid passageway.
  • this liquid passageway may allow the liquid to flow from the liquid inlet chamber 27 to the reactor chamber 26.
  • the top edge of the lower flow spreader 34 may be flat, rounded, arcuate, or curved between the inner surface and the outer surface, or tapered from the inner surface to the outer surface.
  • the bottom edge of the lower flow spreader 34 may be closed except for one or more liquid inlet openings 46 which may facilitate the flow of a liquid from the liquid inlet port 19 through the inlet port 20 and inlet connection tube 48 into the liquid inlet chamber 27.
  • the lower housing 18 may further include one or more liquid inlets 20 and liquid inlet tubes 19 that supply liquid to the reactor 10.
  • the combination of the dielectric element 23, the upper flow spreader 25, and the lower flow spreader 34 may create a gas flow and a parallel liquid flow where the gas is maintained at slightly greater pressure than the liquid thereby maintaining a gas zone between the high voltage dielectric and the liquid.
  • the area of plasma generation may be extended significantly over previous designs.
  • the lower flow spreader 34 only may be constructed from electrically conductive materials, such as metals. In such embodiments, the lower flow spreader 34, particularly the upper edge, may form the second electrode. In other
  • the lower flow spreader 34 may be constructed from non-conductive materials, such as plastics or ceramics.
  • the second electrode may be formed either by the alignment rod 12, the cap nut 47, or a second annular electrode made of electrically conductive material located at the top of the lower spreader generally below the first electrode or electrically isolated by a second electrode dielectric from the liquid.
  • the location of the second electrode may be remote and even outside the reactor 10 using such things as a conductive liquid outlet or inlet tube 19 and 22 connected to ground or neutral.
  • the reactor chamber 26 generally provides a setting for the gas to be ionized while in the general area under the dielectric element 23 and first electrode 24 and to react with the liquid.
  • the reactor chamber 26 may include an outer surface and an inner surface.
  • the outer surface may be bounded by the lower surface of the dielectric element 25, the lower surface of the upper housing 17, the inner surface of the housing wall 45, and the upper surface of the lower housing 18.
  • the inner surface may be bounded by the outer edge of the upper flow spreader, the outer edge of the lower flow spreader 34, and the outer surface of the inlet coupler 48.
  • the plasma reactor 10 may operate as follows: the liquid inlet tube 19 may be coupled to an external pressurized liquid source which may be pressurized between 2 and 300 pounds per square inch gauge (psig).
  • the gas inlet 13 in the alignment rod 12 may be coupled to an external pressurized gas source, the gas may be supplied at a positive pressure relative to the liquid source pressure, and the gas flow rate into the gas inlet 13 may be somewhat controlled.
  • the gas may flow from the gas inlet 13 into the alignment rod 12 and through the alignment rod 12 through the gas inlet port 14 into the gas inlet chamber 15. From here the gas may flow from the gas inlet chamber 15 between the upper flow spreader 25 and the high voltage dielectric element 23 radially outward into the reaction chamber 26, thereby creating a gas layer.
  • a plasma may be created which ionizes the gas and converts it into a stream of plasma with roughly laminar flow with the liquid.
  • the characteristics of the electric field may be controlled by the external voltage supply which may provide a plasma generation voltage of up to 150 kV AC, pulsed DC, or 43- other electrical plasma generating sources familiar to those in the industry.
  • the strength of the electric field is generally the greatest at the shortest distance between the first electrode 24 and the surface, slightly below the surface of the liquid, or the second electrode 29, which may be generally below the first electrode 24.
  • the liquid may flow from the liquid inlet tube 19 through inlet 20 and inlet coupler 48 through the liquid inlet openings 46 in the lower spreader into the liquid inlet chamber 27. Given the curvature of the bottom of the flange 39 and the curvature of the top edge of the lower flow spreader 34, the liquid may exit the liquid inlet flow chamber 27 and flow radially outward in the channel formed by the upper flow spreader 25 and the lower flow spreader 34 into the reactor chamber 26. The liquid may then flow through the electric field with the gas as a stream with roughly laminar flow. The gas may flow on top of the liquid stream through the electric field forming a plasma.
  • some of the ions created in the plasma and some other non-ionized gas may react or otherwise enter the liquid to create a stream of effluent.
  • the effluent flows outward from the center of the reactor 10 and is collected toward the bottom of the reactor chamber 26.
  • the effluent may exit the plasma reactor 10 through the liquid outlet port 21 located at the bottom of the reactor chamber 26 and into the liquid outlet tube 22.
  • a second embodiment of the reactor utilizes a dielectrically isolated second electrode 29.
  • the second electrode may be dielectrically isolated from the liquid by using a second electrode 29. This electrode may be placed in the lower flow spreader 34 and covered with a material such as ceramic, polymer, or other materials known by those familiar with the art to isolate the alternate electrode 29 from the liquid stream. In these cases the electrical field will be shared by the dielectric element 23, the gas flow below the dielectric element, the liquid above the lower flow spreader 34, and the material used to isolate the alternate second electrode 29.
  • a third embodiment of this reactor may split the first electrode into several alternate first electrodes 41.
  • These alternate first electrodes 41 may be annular or other shapes, may be located in the internal cavity 38, and may be isolated from the reactor chamber 26 by the dielectric element 23.
  • this type of electrode may be used for alternate optional pre-ionization electrodes 49.
  • the electrical characteristic of a reactor of a given size may be altered thereby enabling a greater plasma area without a corresponding increase in electrode capacitance and simplifying the design of the electrical source to drive the electric field required to generate a plasma.
  • One or more first electrodes may be used in a given reactor.
  • One or more optional pre-ionization electrodes may be used in a reactor.
  • first electrodes in a given reactor may depend on the reactor size, type of reaction desired, and/or other considerations.
  • the use of an optional pre-ionization electrode and the configuration of said optional pre-ionization electrodes also may depend on the type of reaction and other design considerations.
  • the use of various configurations of first electrodes and configurations of optional pre-ionization electrodes are interchangeable.
  • the present invention includes plasma reactor systems having a housing with an internal reaction chamber; at least one electric field generator configured for generating one or more electric fields between electrodes, with at least a portion of an electric field within the reaction chamber; a dielectric element; a gas source; a liquid source; a gas inlet path to the reaction chamber; and a liquid inlet path to the reaction chamber, where the stream of gas and stream of liquid within the reaction chamber are configured to flow adjacent one another and to pass through the electric field to produce an effluent. It is understood that systems embodying the present invention may further include any one, all, or any combination of additional features described herein.
  • Such optional features include, but are not limited to, a pre-ionization electrode for pre-ionizing a gas prior to entry into the reaction chamber, multiple electrodes in series, flow spreaders, an alignment rod, and an effluent outlet path, as described above. Creating a plasma area in a gas adjacent to a liquid accommodates a number of novel uses.
  • an exemplary use of a plasma reactor for creating a plasma area in a gas adjacent to a liquid includes using oxygen as a feed gas and water as a feed liquid.
  • the oxygen can be pre-ionized prior to entering a reaction chamber 26 via a pre-ionization electric field created by an electric field generator between a pre-ionization electrode 36 and a second electrode 29.
  • ionized oxygen particles are driven into the water via a primary electric field between a first electrode 24 and a second electrode 29 to either disinfect or oxidize undesirable particles in the water, oxygenate the water, or leave a residual level of hydroxyls, ozone, hydrogen peroxide, or other particles in the water.
  • Methylene Blue also known as methylthioninium chloride
  • Fig. 8 shows the effect of treatment of water doped with Methylene Blue with a plasma reactor of the present invention, using oxygen as a feed gas.
  • Methylene Blue also known as methylthioninium chloride
  • UV/VIS ultraviolet- visible spectroscopy
  • Fig. 8 shows the capability of a plasma reaction of the present invention to reduce or eliminate contaminates in the effluent liquid. Additionally, it demonstrates that the level of disinfection may be altered or controlled by the power supplied to the reactor via the plasma voltage generator.
  • FIG. 9 shows an example of the residual dissolved oxygen in effluent water after treatment with oxygen as a feed gas to the plasma reactor.
  • Fig. 10 shows an example of the residual Oxygen Reduction Potential (ORP) of effluent water using oxygen as a feed gas.
  • ORP Oxygen Reduction Potential
  • a further embodiment of creating a plasma area in a gas adjacent to a liquid includes using nitrogen as a feed gas and water as a feed liquid in order to drive monatomic and non-monatomic nitrogen from the gas into the water. This process creates a nitrogen- containing effluent water.
  • Fig. 11 and Fig. 12 show the effect of water treated with a plasma reactor system of the present invention, using nitrogen as a feed gas.
  • the pH of the effluent water is measured for various mixtures of nitrogen and oxygen. This shows that as the percentage of nitrogen in the reactor feed gas is increased, the pH of the effluent water is decreased.
  • Fig. 12 shows the UV/VIS absorbance spectrum of the effluent water after treatment with nitrogen, showing an increased level of nitrogen in the effluent water.
  • FIG. 13 shows the UV/VIS absorbance spectrum of water containing nitrogen before and after treatment with an oxygen feed gas.
  • Fig. 13 illustrates the capability of using the present invention to control nitrogen levels in effluent liquid to desirable levels for various uses.
  • An additional exemplary use of a system for creating a plasma area in a gas adjacent to a liquid includes the dissociation of particular components within a gas. For instance, natural gas, methane, and associated fuel gases contain carbon and other unwanted elements and compounds.
  • Such gases can be used as a feed gas in a plasma reactor of the present invention with water or other liquids as a feed liquid to dissociate part or all of the carbon from the feed gas.
  • the plasma reaction within the reaction chamber can further result in the dissociated carbon becoming associated with the water or other liquid allowing for removal from the reactor. Using this technique results in lower levels of carbon dioxide (C02) emissions when the fuel is subsequently used.
  • C02 carbon dioxide
  • a further embodiment of a use of a plasma reactor system for creating a plasma area in a gas adjacent to a liquid includes use of a gas which may be ionized, causing the liquid to be modified or re-form desirable molecular structures.
  • Fig. 14 shows the use of argon and argon and oxygen mixtures as feed gases and the resulting hydrogen peroxide (H202) to ozone (03) ratio in the effluent water. In this manner, the latent disinfection capabilities of the effluent water may be modified.
  • FIG. 15 shows the results of the rate of production of hydrogen peroxide and hydrogen using a plasma reaction of the present invention using argon and argon and hydrogen mixtures as feed gases vs.
  • the hydrogen produced may be dissolved hydrogen in the water, hydrogen gas, or a combination of both.
  • a gaseous particle injection system and method is configured for injecting or infusing gaseous particles into a liquid.
  • the reactor includes a reaction chamber for holding a liquid and a gas adjacent to the liquid.
  • the reactor further includes first and second electrodes configured for forming an electric field between them, at least a portion of the electric field being positioned within the reaction chamber.
  • a desired feed liquid is inserted into the reaction chamber through an inlet path, and a desired feed gas is inserted into the reaction chamber adjacent to the liquid through an inlet path.
  • the feed liquid(s) and feed gas(es) may be flowing or non-flowing during a reaction in a reactor embodying the present invention.
  • the reactor is connected to a power source, and a voltage is applied between the first and second electrodes, forming an electric field at least partially positioned within the reaction chamber.
  • the connected power source is configured for producing an alternating current (AC), however, alternatively, pulse direct current (DC) or another wave form can be used.
  • the electric field makes contact with the gas and liquid within the reaction chamber, injecting or infusing particles from the feed gas into the liquid, forming a desired effluent with injected or infused gaseous particles.
  • the power of the electric field can be adjusted to optimize production of the desired effluent. For instance, utilizing voltages below the ionization energy or minimum power required to ionize the feed gas may result in increased ratios of molecular gas being injected or infused into the liquid. Utilizing higher voltages may result in higher levels of ionic gas injection. By varying electrical field strength of these systems, the ratio of molecular injection or infusion to ionic injection into the feed liquid can be controlled.
  • water is the feed liquid and molecular oxygen is the feed gas to a reactor of the present invention.
  • levels of Oxidation Reduction Potential (ORP) and dissolved oxygen in the effluent can be independently controlled to some extent, as desired for the particular intended use of the effluent.
  • ORP Oxidation Reduction Potential
  • other feed gases and feed liquids may be used in reactors and reactions embodying the present invention.
  • nitrogen or argon may be used as a feed gas for reactions of the present invention.
  • combinations of multiple gases and/or combinations of multiple liquids could be used as feed gases and/or feed liquids, respectively.
  • Figs. 16 and 17 An embodiment of use of a reactor of the present invention with a gas adjacent to a liquid and an electrical field is demonstrated by Figs. 16 and 17, with water being the feed liquid and oxygen being the feed gas.
  • dissolved oxygen DO2 was monitored using a dissolved oxygen meter and ORP was used to monitor oxidation of radicals, such as dissolved ozone formation, at power levels higher than voltage to initiate plasma in the reactor.
  • Fig. 16 shows that dissolved oxygen is infused into the liquid at power levels both below and above the power levels required for initiation of plasma.
  • O2 molecular oxygen
  • oxygen radicals which increase the ORP, are infused at power levels above the power levels required for initiation of plasma.
  • Fig. 17 shows a graph displaying oxygen infusion at power levels below the electrical field intensity required for initiation of a plasma.
  • the embodiment of the present invention shown in Figs. 16 and 17 accommodates a method of infusing oxygen into a liquid without ionizing the gas such that oxygen radicals are not injected into the liquid.
  • oxygen was infused at low power levels to increase the dissolved oxygen content in a stream of water. This allows dissolved oxygen levels to be increased in the water independently of increases in ionic injection.

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Abstract

L'invention concerne un système et un procédé pour effectuer des réactions à plasma créant une zone de plasma dans un gaz adjacent à un liquide. Un mode de réalisation du réacteur à plasma comprend un boîtier avec une chambre de réaction interne, des premier et second trajets d'entrée vers la chambre de réaction et des électrodes servant à produire un champ électrique. Le système peut en outre comprendre une électrode de préionisation et un champ électrique de préionisation pour préioniser un gaz d'alimentation avant son entrée dans une chambre de réaction. Le réacteur utilise un plasma pour ioniser le gaz adjacent au liquide. Le gaz ionisé réagit avec le liquide pour former un effluent. Des exemples d'utilisations du réacteur à plasma comprennent une injection ionique, une dissociation de gaz, une reformation de liquide et une dissociation de liquide. Dans un autre mode de réalisation, l'invention concerne un système et un procédé d'infusion de particules gazeuses dans un liquide par application d'un champ électrique à des degrés de puissance inférieurs à la tension requise pour former un plasma dans un gaz adjacent à un liquide.
PCT/US2019/040473 2018-07-03 2019-07-03 Réacteur pour liquide et gaz et procédé d'utilisation WO2020010182A1 (fr)

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US16/027,005 US10882021B2 (en) 2015-10-01 2018-07-03 Plasma reactor for liquid and gas and method of use
US16/027,005 2018-07-03
US16/205,844 2018-11-30
US16/205,844 US11452982B2 (en) 2015-10-01 2018-11-30 Reactor for liquid and gas and method of use

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100310434A1 (en) * 2009-06-05 2010-12-09 Eon Labs, Llc Distributed Dielectric Barrier Discharge Reactor
US20160194224A1 (en) * 2013-03-01 2016-07-07 Walter Buchanan Systems and methods for non-thermal plasma over liquid direct ion injection
US20170095788A1 (en) * 2015-10-01 2017-04-06 Walter Riley Buchanan Plasma reactor for liquid and gas
US20180311639A1 (en) * 2015-10-01 2018-11-01 Ion Inject Technology Llc Plasma reactor for liquid and gas and method of use

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9394189B2 (en) * 2013-03-01 2016-07-19 Walter Buchanan Methods, systems, and reactors for non-thermal plasma over liquid direct ion injection

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100310434A1 (en) * 2009-06-05 2010-12-09 Eon Labs, Llc Distributed Dielectric Barrier Discharge Reactor
US20160194224A1 (en) * 2013-03-01 2016-07-07 Walter Buchanan Systems and methods for non-thermal plasma over liquid direct ion injection
US20170095788A1 (en) * 2015-10-01 2017-04-06 Walter Riley Buchanan Plasma reactor for liquid and gas
US20180311639A1 (en) * 2015-10-01 2018-11-01 Ion Inject Technology Llc Plasma reactor for liquid and gas and method of use

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3818014A4 *

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