WO2020006691A1 - Aqueous polymer dispersion - Google Patents

Aqueous polymer dispersion Download PDF

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Publication number
WO2020006691A1
WO2020006691A1 PCT/CN2018/094427 CN2018094427W WO2020006691A1 WO 2020006691 A1 WO2020006691 A1 WO 2020006691A1 CN 2018094427 W CN2018094427 W CN 2018094427W WO 2020006691 A1 WO2020006691 A1 WO 2020006691A1
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WO
WIPO (PCT)
Prior art keywords
equal
ammonium
component
less
aqueous dispersion
Prior art date
Application number
PCT/CN2018/094427
Other languages
French (fr)
Inventor
Jin ZHENG (Jay)
Xiaohui JIA (Jesse)
Ping Zhang
Qian Chen
Lingyun HUANG (Roy)
Original Assignee
Wacker Chemie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie Ag filed Critical Wacker Chemie Ag
Priority to PCT/CN2018/094427 priority Critical patent/WO2020006691A1/en
Publication of WO2020006691A1 publication Critical patent/WO2020006691A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C08J5/127—Aqueous adhesives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C09D123/08—Copolymers of ethene
    • C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09D123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0246—Acrylic resin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/04—Cellulosic plastic fibres, e.g. rayon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0221—Vinyl resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0278—Polyurethane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B32B2437/02—Gloves, shoes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2331/00—Characterised by the use of copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, or carbonic acid, or of a haloformic acid
    • C08J2331/02—Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
    • C08J2331/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02—Homopolymers or copolymers of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2431/00—Characterised by the use of copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, or carbonic acid, or of a haloformic acid
    • C08J2431/02—Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/324—Alkali metal phosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/54—Aqueous solutions or dispersions

Definitions

  • the present invention relates to an aqueous polymer dispersion and use thereof for interfacial bonding between polymeric porous materials.
  • 192 CGN is a self-crosslinking aqueous polymer dispersion based on ethylene-vinyl acetate. This product can be crosslinked at 150°C for bonding in the production of nonwovens.
  • the recommended use of the product is: prior to use, adding 1%catalyst (based on the solids content of 192 CGN) to the product and mix well.
  • the catalyst is generally formulated as a 10%aqueous solution. Among the commonly used are ammonium chloride, citric acid and sodium bisulfate. If the time for mixing 192 CGN with the catalyst is too long and exceeds thirty minutes under room temperature, the mixture will gel, leading to a significantly increased viscosity that renders it unusable.
  • CN102650094A discloses a non-woven fibrous structure where the fibers are consolidated by crosslinking a binder based on an ethylene-vinyl acetate polymer emulsion.
  • the binder contains 1 to 5 wt%organic acidulant (based on the total weight of comonomers) , such as oxalic, succinic adipic, glutaric, tartaric and citric acids, and crosslinkable functional monomers such as N-methylol amide derived from acrylic acid and methacrylic acid.
  • the organic acidulant is a mono-or polycarboxylic acid having from about 2 to about 12 carbon atoms and a pKa value of from about 2 to 7 in water.
  • the organic acidulant can promote premature crosslinking of the copolymer of the binder and ultimately destabilize the latex binder composition. Therefore, the organic acidulant should be added in preferably within several hours, typically within 5 hours, or more preferably within 2 hours, before the latex binder composition is contacted with the non-woven fibrous structure.
  • VAE emulsion containing NMA This VAE emulsion is a system stabilized by an alkylphenol polyoxyethylene ether surfactant.
  • Run 9-15 contained a buffer system of sodium acetate and acetic acid, and adjusted the pH of the VAE emulsion to be approximately 4.4. After Preparation Run 9-15 was completed, no additional ammonium chloride was added.
  • the prior art adhesive products have the shortcomings of onsite preparation and short-term storage.
  • the present invention obtains a single-package polymer aqueous dispersion which has good adhesion after heating, has the advantages of long-term storage under room temperature conditions and good viscosity stability.
  • the single-package polymer aqueous dispersion is particularly suitable for the bonding between a fiber textile material and a polymer foam material, and has high wet bond strength and excellent water resistance.
  • aqueous polymer dispersion wherein the said polymer is obtained by the polymerization of a composition comprising Components A and B:
  • a –one or more monomers selected from the group consisting of C1-C15 vinyl alkyl carbonates having unbranched or branched chains, vinyl aromatics, olefins, diolefins and haloethene compounds; and
  • B -crosslinkable comonomers comprising crosslinkable N-methylol groups or their derivatives which are etherified with C1-C6 alkanols, preferably N-methylol amide derived from acrylic acid and methacrylic acid, more preferably one, or a combination, of N-methylolacrylamide and N- (N-butoxymethyl) acrylamide;
  • n is a positive integer, preferably selected from among 1, 2 and 3, and
  • X represents organic or inorganic acid radicals
  • organic or inorganic acids formed from X and hydrogen ions have a primary pK a of less than 4.74, preferably less than or equal to 3.5 and greater than or equal to 1, as measured at 25°C and 1 atm, in 1 mol/L aqueous solution
  • the pH value of the resultant aqueous dispersion is adjusted to greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5, more preferably greater than or equal to 5 and less than or equal to 5.5; pH value analyzed by Mettler Toledo S220 SevenCompact pH/Ion according to its Instruction book.
  • the pK a in the present invention represents the ability of an acid to dissociate hydrogen ions and refers to the negative logarithm of the acid dissociation constant K a , i.e.:
  • the pK a of common organic or inorganic acids can be obtained from LANGE'S HANDBOOK OF CHEMISTRY Science Press 1991 1 st edition.
  • the primary pK a of some organic or inorganic acids are listed in the following table 1: Source: Table 5-7 and Table 5-8 Proton transfer reaction in above handbook.
  • the primary pK a of these acids refers to the value when an organic acid or an inorganic acid loses the first hydrogen ion; if an organic or inorganic acid has multiple hydrogen ions, the value when it loses the second hydrogen ion is the secondary pK a .
  • aqueous dispersion as mentioned above, wherein the content of alkyl alcohol polyoxyethylene ethers and/or alkylphenol polyoxyethylene ethers and or polyoxyethylene ether-polyoxypropylene ethers is lower than 1wt%; preferably lower than 0.1wt%; based on the total weight of monomers of Component A.
  • aqueous dispersion as mentioned above, wherein the content of PVOH is greater than 2.5wt%; preferably greater than or equal to 2.5wt%and lower than or equal to 5wt%; preferably greater than or equal to 3wt%and lower than or equal to 5wt%; based on the total weight of monomers of Component A.
  • aqueous dispersion as mentioned above, wherein the organic or inorganic acids formed from X and hydrogen ions have a boiling point of greater than or equal to 120°C, preferably greater than or equal to 150°C, as measured at 25°C and 1 atm.
  • aqueous dispersion as mentioned above, wherein the ammonium salt according to formula (I) have a solubility in water of greater than or equal to 30 g/L, preferably greater than or equal to 50 g/L, as measured at 25°C and 1 atm.
  • Component C is an ammonium salt of organic acids and/or ammonium salt of an inorganic acid
  • organic acids are acidic organic compounds having from 2 to 8 carbon atoms and containing a carboxyl group (-COOH) and a sulfonyl group (-SO 3 H) ;
  • organic acids containing a carboxyl group preference is given to the organic acids containing a carboxyl group (-COOH) , and greater preference is given to one, or a combination, of mono-, di- and tri-carboxylic acids; or
  • organic acids containing a sulfonyl group (-SO 3 H) , and greater preference is given to one, or a combination, of p-toluenesulfonic, benzenesulfonic and methanesulfonic acids;
  • ammonium salt of organic acids is one or more preferably selected from among ammonium citrate, ammonium oxalate, ammonium tartrate, ammonium p-toluenesulfonate, ammonium succinate, ammonium adipate and ammonium glutarate;
  • ammonium salt of organic acids is one or more further preferably selected from among ammonium citrate, ammonium oxalate, ammonium tartrate and ammonium p-toluenesulfonate; further preferably one or more selected from among ammonium citrate, ammonium oxalate, ammonium tartrate;
  • the inorganic acid is an acidic inorganic compound
  • the inorganic acid is one or more selected from among sulfuric, hydrochloric and phosphoric acids;
  • the ammonium salt of the inorganic acid is one or more preferably selected from among ammonium chloride and ammonium hydrogen sulfate.
  • aqueous dispersion as mentioned above, further comprising a buffer solution.
  • aqueous dispersion as mentioned above, further comprising Component F1, a buffer solution containing sodium acetate and acetic acid.
  • aqueous dispersion as mentioned above, further comprising Component F2, a buffer solution containing sodium dihydrogen phosphate and disodium hydrogen phosphate.
  • aqueous dispersion as mentioned above, wherein the amount of vinyl acetate and ethylene in Component A is greater than or equal to 90 wt%, preferably greater than or equal to 95 wt%, more preferably greater than or equal to 98 wt%, based on the total weight of monomers of Component A.
  • aqueous dispersion as mentioned above, wherein the monomers of Component A are vinyl acetate and ethylene.
  • aqueous dispersions as mentioned above, wherein the amount of the ammonium salt as Component C is between 0.1 and 5 wt%, preferably between 0.5 and 3 wt%, based on the total weight of monomers of Component A.
  • aqueous dispersions as mentioned above, wherein the amount of the crosslinkable comonomer as Component B is between 0.1 and 5 wt%, preferably between 0.5 and 3 wt%, based on the total weight of monomers of Component A.
  • aqueous dispersion as mentioned above, further comprising other comonomers as Component D, which is one or more selected from among acrylic acid and acrylamide.
  • aqueous dispersion as mentioned above, wherein the aqueous polymer dispersion is an emulsion having a Brookfield viscosity between 5,000 and 12,000 mPa ⁇ s, preferably between 7,000 and 10,000 mPa ⁇ s, as measured according to the ST-2 Brookfield viscosity test method and having a rate of change in Brookfield viscosity of less than 100 wt%, preferably less than 30%, more preferably less than 10%, after 60 days of storage at 23°C; preferably a rate of change in Brookfield viscosity of less than 100 wt%, after 14 days of storage at 50°C.
  • Tg glass transition temperature
  • the pH value of the emulsion is greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5; preferably greater than or equal to 5 and less than or equal to 5.5.
  • aqueous dispersion as mentioned above, wherein the pH value of the Component C aqueous solution is greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5; preferably greater than or equal to 5 and less than or equal to 5.5 .
  • the pH value of the resultant aqueous dispersion is adjusted to greater than or equal to 4.5 and less than or equal to 8, preferably greater than or equal to 4.5 and less than or equal to 5.5, preferably greater than or equal to 5 and less than or equal to 5.5
  • the preparation method as mentioned above preferably using acetic acid and/or Sodium hydroxide as the pH adjuster.
  • interfacial bonding between polymeric porous materials is that between one type or more types of materials selected from among fiber textile materials and polymeric foamed materials, preferably that between one type or more types of materials selected from the group consisting of synthetic fiber textile materials, synthetic fiber non-woven materials, natural fiber textile materials, natural fiber non-woven materials, regenerated cellulose materials, ethylene-vinyl acetate (EVA) copolymer foams and polyurethane (PU) foams, more preferably that between that PU foams and synthetic fiber textile materials, or between PU foams and natural fiber textile materials, or between EVA copolymer foams and synthetic fiber textile materials, or between EVA copolymer foams and natural fiber textile materials.
  • EVA ethylene-vinyl acetate
  • a composite structure for insoles comprising an artificial fiber textile material and a polymeric foamed material, which are held in place by bonding with the aforesaid aqueous dispersion.
  • Composite products are obtained in such a way that polymeric porous materials are interfacially bonded. Some of them often come into contact with water during use, or frequently need to be cleaned. Use fields of these composites include, for example, shoe liners, shoe inserts and sportswear. Composite products with poor water resistance are prone to degumming in contact with water, that is, interface debonding, leading to a short service life.
  • the interfacial bonding between polymeric porous materials is preferably the lamination of an artificial fiber textile material onto a polymeric foamed material.
  • the interfacial bonding between polymeric porous materials is preferably that between polyester or acrylic or cotton textile materials and EVA copolymer foams.
  • the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded, the resulting product being exposed to a heat source for a period of time.
  • carpets comprise a primary backing with yarn tufts in the form of cut or uncut loops extending upwardly from the backing to form a pile surface.
  • yarn tufts in the form of cut or uncut loops extending upwardly from the backing to form a pile surface.
  • the yarn is inserted into a primary backing by tufting needles and a pre-coat or binder is applied thereto.
  • the fibers are embedded and actually held in place by the binder composition.
  • the interfacial bonding between polymeric porous materials does not include the production of polymeric porous materials themselves using a binder, which mainly refers to the bonding together of fibrous polymer materials less than 5 mm in diameter.
  • a binder is used to form non-woven fabrics by bonding together the fibrous materials such as wood pulp fibers, rayon, cottons, wools and acetate fibers; or in the process of paper making, a binder is used to form paper webs, papers or cardboards by bonding pulp fibers together.
  • the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded, the resulting product being exposed to a heat source, at between 150 and 200°C, for a period of time between 25 and 120 seconds to complete the drying step; or the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded, the resulting product being exposed to a heat source, at between 100 and 110°C, for a period of time between 20 and 30 minutes to complete the drying step.
  • the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded using a roll coater with a certain pressure, and simultaneously completing the drying step therein.
  • the coat weight of the aqueous polymer dispersion is between 120 and 210 g/m 2 .
  • the coating roller takes up a small amount of glue during the production, leading to a poor bonding effect of the product; while the viscosity of the aqueous polymer dispersion is too high, the coating roller takes up a large amount of glue, leading to excessive coat weight in the product and high consumption of the aqueous polymer dispersion and thus to diseconomy.
  • Component A one or more monomers, selected from the group consisting of C1-C15 vinyl alkyl carbonates having unbranched or branched chains, vinyl aromatics, olefins, diolefins and haloethene compounds;
  • Preferred C1-C15 vinyl alkyl carbonates having unbranched or branched chains are selected from the group of vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, 1-methylvinyl acetate, vinyl pivalate and vinyl esters of ⁇ -branched monocarboxylic acids having up to 10 carbon atoms, for example VeoVa9 or VeoVa10, wherein vinyl acetate is particularly preferred.
  • the said component A can also be polymerized to form copolymers of vinyl acetate and ethylene, or copolymers of vinyl acetate and ethylene and one or more other vinyl monomers, such as vinyl acetate-ethylene-acrylate copolymers and vinyl acetate-ethylene-vinyl chloride copolymers.
  • Suitable comonomers are the esters of unbranched or branched alcohols having 1 to 15 atoms, for example methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate and norbornyl acrylate, wherein preference is given to methyl acrylate, methyl methacrylate, n-butyl acrylate and 2-ethylhexyl acrylate.
  • the polymers are prepared by the solution polymerization process, emulsion polymerization process or suspension polymerization process, preferably by the emulsion polymerization process, in which the polymerization temperature is generally from 20°C to 100°C, preferably from 45°C to 80°C.
  • the polymerization of gaseous monomers, such as ethylene, 1, 3-butadiene or vinyl chloride, can also be carried out under a pressure of generally from 5 bar to 100 bar (abs. ) .
  • the pH range desired for the polymerization which is in general between 2.5 and 10, preferably 3 and 8, can be established in a known manner by acids, bases or customary buffer salts, such as alkali metal phosphates or alkali metal carbonates.
  • the polymerization is initiated by a water-soluble or monomer-soluble initiator or redox initiator combinations customary for emulsion polymerization or suspension polymerization.
  • water-soluble initiators are the sodium, potassium and ammonium salts of peroxodisulfuric acid, hydrogen peroxide, t-butyl peroxide (e.g. t-butyl hydroperoxide) , potassium peroxodisulfate, t-butyl peroxypivalate and azobisisobutyronitrile. These initiators are generally used in an amount of 0.01 to 3%by weight in each case based on the total dry weight of the monomers.
  • Suitable reducing agents are the sulfites of alkali metals or of ammonium, the bisulfites of alkali metals or of ammonium, the derivatives of sulfoxylic acid of alkali metals or of ammonium, or sulfinates of alkali metals or of ammonium.
  • the amount of said reducing agent is generally from 0.01 to 3 %by weight in each case based on the total dry weight of the monomers of Component A.
  • regulators can be used during the polymerization. If regulators are used, they are usually employed in amounts of from 0.01 to 5.0%by weight, based on the total dry weight of the monomers of Component A, and are introduced separately or premixed with reaction components. Examples of such substances are n-dodecyl mercaptan, t-dodecyl mercaptan, mercaptopropionic acid, methyl mercaptopropionate, isopropanol and acetaldehyde.
  • Suitable protective colloids for the polymerization are polyvinyl alcohols; polyvinyl acetals; polyvinylpyrrolidones; polysaccharides in water-soluble form, e.g. starches (amylose and amylopectin) , celluloses and their carboxymethyl, methyl, hydroxyethyl, hydroxypropyl derivatives, dextrins and cyclodextrins.
  • the polymerization can be carried out successively or continuously.
  • an post-polymerization can be carried out to remove residual monomers using known methods, in general by means of an post-polymerization initiated by a redox catalyst. Volatile residual monomers can also be removed by means of distillation, preferably under reduced pressure, and, if appropriate, with inert entrainer gases such as air, nitrogen or steam being passed through or over the polymerization mixture.
  • the aqueous polymer dispersions obtainable in this way have a solids content of from 40 to 70%by weight.
  • Protective colloids used as spray additives
  • defoamers and anti-caking agents can be added to the aqueous polymer dispersions herein for subsequent preparation of water-redispersible polymer powders by means of a traditional process: fluidized-bed drying, freeze drying or spray drying.
  • Tg glass transition temperature
  • the viscosity of the sample is determined with a Brookfield RV/DV rotational viscometer according to GB/T 11175-2002 using spindle No. 4 at 20 rpm at 25°C.
  • a dry fabric sample mentioned above is soaked in water at 25°C for 1 hour and then taken out.
  • the resulting wet fabric is then tested for 180° peeling strength in reference to the method shown in Figure 1 of ISO11339-2010 on Shandong Labthink XLW (G) -PC smart electronic tensile tester.
  • the wet sample, with its width remaining 25.4mm (1 inch) is vertically stretched for a distance of 40mm. The stretches up to 2mm at both the beginning and end of the test are not taken into account. The stretching speed is 100mm/min.
  • the aqueous polymer dispersions in Examples and Comparative Examples were prepared according to the basic formulation in Table 2.
  • the basic formulation in Table 2 contains the type of monomers, amount of monomers, type of protective colloid, initiator system, initial charge and subsequent feed of each raw material, and the like.
  • the concentration of a solution is the weight of solute divided by the weight of solution, in the form of percent by weight.
  • pH value in present invention is analyzed by Mettler Toledo S220 SevenCompact pH/Ion according to its Instruction book.
  • NMA refers to N-Methylolacrylamide.
  • Ammonium citrate, sodium citrate, ammonium acetate, ammonium chloride, ammonium oxalate, ammonium p-toluenesulfonate, and ammonium tartrate are all commercially available products.
  • PVOH 04/88 20 wt%aqueous solution having an alcoholysis degree of 88 wt%, 4 wt%aqueous solution of which has a viscosity of 4 mPa ⁇ sat 20°C according to DIN 53015, is prepared into a 20 wt%aqueous solution before use.
  • PVOH 25/88 10.3 wt%aqueous solution having an alcoholysis degree of 88 wt%, 4 wt%aqueous solution of which has a viscosity of 25 mPa ⁇ sat 20°C according to DIN 53015, is prepared into a 10.3 wt%aqueous solution before use.
  • tBHP 10 wt%aqueous solution refers to t-butyl hydroperoxide, which is prepared into a 10 wt%aqueous solution before use.
  • FF6M 5 wt%aqueous solution refers to disodium hydroxysulfinoacetate (purchased from Brüggemann Chemical Incorporates) , which is prepared into a 5 wt%aqueous solution before use.
  • FAS 1wt%aqueous solution refers to ferrous ammonium sulfate, which is prepared into a 1 wt%aqueous solution before use.
  • the amount of ethylene used in Table 2 refers to the amount of ethylene gas fed in each example
  • Step 1 A premix of 700g of deionized water, 114g of PVOH 04/88 20 wt%aqueous solution, 625g of PVOH 25/88 10.3wt%aqueous solution and 9g of sodium acetate was added into a 5-liter reactor. The premix was mixed well and its pH was adjusted to 5 with acetic acid before 7g of FAS was added.
  • the reactor was heated to 70°C, into which 1514g of vinyl acetate and 291g of ethylene were added, and the pressure in the reactor was maintained below 45 bar.
  • the temperature was raised to 70°C while 10 wt%t-butyl hydroperoxide aqueous solution and 5 wt%FF6M aqueous solution were added dropwisely with a pump to initiate reaction and the dropwise addition continued until the reaction was completed.
  • 440 g of vinyl acetate and a mixed solution of 144g of deionized water and 36 g of N-Methylolacrylamide were added.
  • Step 2 After reaction for 4 hours, the mixture was transferred to a degassing tank, where 1 g of mineral oil-based defoamer and 28 g of ammonium citrate (as aqueous solution) were added, and after degassing for 30 minutes, the aqueous polymer dispersion was obtained.
  • the product’s Tg is 0°C; solid content is 56wt%.
  • Comparative Example C Comparative Example C.
  • Ex. 0 was prepared in the same manner as in Ex. 1 and also contained 28 g of citric acid. However, after Step 2, acetic acid was additionally added to adjust the pH of aqueous polymer dispersion to 4.4.
  • Table 3.2 shows the performance test results of Examples 1, 4-7 and Comparative Examples 2, 3 and 8.
  • Table 3.2 shows that three samples having a wet-bonding strength of greater than 11 N/inch in a short time (within 3 minutes) were obtained with Examples 1 and 4-7.
  • Table 3.2 shows that three samples having a wet-bonding strength of greater than 11 N/inch in a short time (within 3 minutes) were obtained with Examples 1 and 4-7.
  • the wet-bond strength of these Examples was high and built up fast.
  • Comparative Example 2 which used sodium citrate, had a wet-bond strength and a build-up speed close to those of the blank C. Ex. 8, and was not effective.
  • Example 1 of the present invention The stability of Example 1 of the present invention is shown in Table 4: the aqueous polymer dispersion containing ammonium citrate had very little change in viscosity without gelling when stored under higher temperature for a long period of time and could be used in actual applications.

Abstract

A single-package polymer aqueous dispersion which has good adhesion after heating, has the advantages of long-term storage under room temperature conditions and good viscosity stability. The single-package polymer aqueous dispersion is particularly suitable for the bonding between a fiber textile material and a polymer foam material, and has high wet adhesion strength and excellent water resistance.

Description

[Title established by the ISA under Rule 37.2] AQUEOUS POLYMER DISPERSION Field of the Invention
The present invention relates to an aqueous polymer dispersion and use thereof for interfacial bonding between polymeric porous materials.
Background of the Invention
Commercial
Figure PCTCN2018094427-appb-000001
192 CGN is a self-crosslinking aqueous polymer dispersion based on ethylene-vinyl acetate. This product can be crosslinked at 150℃ for bonding in the production of nonwovens. The recommended use of the product is: prior to use, adding 1%catalyst (based on the solids content of
Figure PCTCN2018094427-appb-000002
192 CGN) to the product and mix well. The catalyst is generally formulated as a 10%aqueous solution. Among the commonly used are ammonium chloride, citric acid and sodium bisulfate. If the time for mixing
Figure PCTCN2018094427-appb-000003
192 CGN with the catalyst is too long and exceeds thirty minutes under room temperature, the mixture will gel, leading to a significantly increased viscosity that renders it unusable.
CN102650094A discloses a non-woven fibrous structure where the fibers are consolidated by crosslinking a binder based on an ethylene-vinyl acetate polymer emulsion. The binder contains 1 to 5 wt%organic acidulant (based on the total weight of comonomers) , such as oxalic, succinic adipic, glutaric, tartaric and citric acids, and crosslinkable functional monomers such as N-methylol amide derived from acrylic acid and methacrylic acid. The organic acidulant is a mono-or polycarboxylic acid having from about 2 to about 12 carbon atoms and a pKa value of from about 2 to 7 in water. The patent also indicates that the organic acidulant can promote premature crosslinking of the copolymer of the binder and ultimately destabilize the latex binder composition. Therefore, the organic acidulant should be added in preferably within several hours, typically within 5 hours, or more preferably within 2 hours, before the latex binder composition is contacted with the non-woven fibrous structure.
US4,449,978 discloses a VAE emulsion containing NMA. This VAE emulsion is a system stabilized by an alkylphenol polyoxyethylene ether surfactant. Among them, Run 9-15 contained a buffer system of sodium acetate and acetic acid, and adjusted the pH  of the VAE emulsion to be approximately 4.4. After Preparation Run 9-15 was completed, no additional ammonium chloride was added.
Summary of the Invention
The prior art adhesive products have the shortcomings of onsite preparation and short-term storage.
The present invention obtains a single-package polymer aqueous dispersion which has good adhesion after heating, has the advantages of long-term storage under room temperature conditions and good viscosity stability. The single-package polymer aqueous dispersion is particularly suitable for the bonding between a fiber textile material and a polymer foam material, and has high wet bond strength and excellent water resistance.
In present invention, we would like to provide an aqueous polymer dispersion, wherein the said polymer is obtained by the polymerization of a composition comprising Components A and B:
A –one or more monomers, selected from the group consisting of C1-C15 vinyl alkyl carbonates having unbranched or branched chains, vinyl aromatics, olefins, diolefins and haloethene compounds; and
B -crosslinkable comonomers, comprising crosslinkable N-methylol groups or their derivatives which are etherified with C1-C6 alkanols, preferably N-methylol amide derived from acrylic acid and methacrylic acid, more preferably one, or a combination, of N-methylolacrylamide and N- (N-butoxymethyl) acrylamide;
and wherein it also contains Component C, an ammonium salt having the following formula (I) :
X (NH 4)  m      (I)
where m is a positive integer, preferably selected from among 1, 2 and 3, and
X represents organic or inorganic acid radicals,
wherein the organic or inorganic acids formed from X and hydrogen ions have a primary pK a of less than 4.74, preferably less than or equal to 3.5 and greater than or equal to 1, as measured at 25℃ and 1 atm, in 1 mol/L aqueous solution
the pH value of the resultant aqueous dispersion is adjusted to greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than  or equal to 5.5, more preferably greater than or equal to 5 and less than or equal to 5.5; pH value analyzed by Mettler Toledo S220 SevenCompact pH/Ion according to its Instruction book.
The pK a in the present invention represents the ability of an acid to dissociate hydrogen ions and refers to the negative logarithm of the acid dissociation constant K a, i.e.:
pK a = -log 10K a
the pK a of common organic or inorganic acids can be obtained from LANGE'S HANDBOOK OF CHEMISTRY Science Press 1991 1 st edition. For example, the primary pK a of some organic or inorganic acids are listed in the following table 1: Source: Table 5-7 and Table 5-8 Proton transfer reaction in above handbook.
Table 1
Citric acid 3.128
Acetic Acid 4.76
Hydrochloric acid -6.1
Oxalic acid 1.27
Benzenesulfonic acid 0.7
Tartaric acid 3.04
The primary pK a of these acids refers to the value when an organic acid or an inorganic acid loses the first hydrogen ion; if an organic or inorganic acid has multiple hydrogen ions, the value when it loses the second hydrogen ion is the secondary pK a.
The aqueous dispersion as mentioned above, it is a single package product.
The aqueous dispersion as mentioned above, wherein the content of alkyl alcohol polyoxyethylene ethers and/or alkylphenol polyoxyethylene ethers and or polyoxyethylene ether-polyoxypropylene ethers is lower than 1wt%; preferably lower than 0.1wt%; based on the total weight of monomers of Component A.
The aqueous dispersion as mentioned above, wherein the content of PVOH is greater than 2.5wt%; preferably greater than or equal to 2.5wt%and lower than or equal  to 5wt%; preferably greater than or equal to 3wt%and lower than or equal to 5wt%; based on the total weight of monomers of Component A.
The aqueous dispersion as mentioned above, wherein the organic or inorganic acids formed from X and hydrogen ions have a boiling point of greater than or equal to 120℃, preferably greater than or equal to 150℃, as measured at 25℃ and 1 atm.
The aqueous dispersion as mentioned above, wherein the ammonium salt according to formula (I) have a solubility in water of greater than or equal to 30 g/L, preferably greater than or equal to 50 g/L, as measured at 25℃ and 1 atm.
The aqueous dispersion as mentioned above, wherein Component C is an ammonium salt of organic acids and/or ammonium salt of an inorganic acid,
wherein the organic acids are acidic organic compounds having from 2 to 8 carbon atoms and containing a carboxyl group (-COOH) and a sulfonyl group (-SO 3H) ;
preference is given to the organic acids containing a carboxyl group (-COOH) , and greater preference is given to one, or a combination, of mono-, di- and tri-carboxylic acids; or
preference is given to the organic acids containing a sulfonyl group (-SO 3H) , and greater preference is given to one, or a combination, of p-toluenesulfonic, benzenesulfonic and methanesulfonic acids;
the ammonium salt of organic acids is one or more preferably selected from among ammonium citrate, ammonium oxalate, ammonium tartrate, ammonium p-toluenesulfonate, ammonium succinate, ammonium adipate and ammonium glutarate;
the ammonium salt of organic acids is one or more further preferably selected from among ammonium citrate, ammonium oxalate, ammonium tartrate and ammonium p-toluenesulfonate; further preferably one or more selected from among ammonium citrate, ammonium oxalate, ammonium tartrate;
the inorganic acid is an acidic inorganic compound;
the inorganic acid is one or more selected from among sulfuric, hydrochloric and phosphoric acids;
The ammonium salt of the inorganic acid is one or more preferably selected from among ammonium chloride and ammonium hydrogen sulfate.
The aqueous dispersion as mentioned above, further comprising a buffer solution.
The aqueous dispersion as mentioned above, further comprising Component F1, a buffer solution containing sodium acetate and acetic acid.
The aqueous dispersion as mentioned above, further comprising Component F2, a buffer solution containing sodium dihydrogen phosphate and disodium hydrogen phosphate.
The aqueous dispersion as mentioned above, wherein the amount of vinyl acetate and ethylene in Component A is greater than or equal to 90 wt%, preferably greater than or equal to 95 wt%, more preferably greater than or equal to 98 wt%, based on the total weight of monomers of Component A.
The aqueous dispersion as mentioned above, wherein the monomers of Component A are vinyl acetate and ethylene.
The aqueous dispersions as mentioned above, wherein the amount of the ammonium salt as Component C is between 0.1 and 5 wt%, preferably between 0.5 and 3 wt%, based on the total weight of monomers of Component A.
The aqueous dispersions as mentioned above, wherein the amount of the crosslinkable comonomer as Component B is between 0.1 and 5 wt%, preferably between 0.5 and 3 wt%, based on the total weight of monomers of Component A.
The aqueous dispersion as mentioned above, further comprising other comonomers as Component D, which is one or more selected from among acrylic acid and acrylamide.
The aqueous dispersion as mentioned above, wherein the aqueous polymer dispersion is an emulsion having a Brookfield viscosity between 5,000 and 12,000 mPa·s, preferably between 7,000 and 10,000 mPa·s, as measured according to the ST-2 Brookfield viscosity test method and having a rate of change in Brookfield viscosity of less than 100 wt%, preferably less than 30%, more preferably less than 10%, after 60 days of storage at 23℃; preferably a rate of change in Brookfield viscosity of less than 100 wt%, after 14 days of storage at 50℃.
The aqueous dispersion as mentioned above, wherein the glass transition temperature (Tg) of the dried product of the aqueous polymer dispersion ranges from-2℃ to 10℃, preferably from 0℃ to 5℃ as measured according to ST-1.
A method for preparing the aqueous dispersion as mentioned above, wherein after the emulsion polymerization of Components containing A and B is completed,  Component C and/or Component C aqueous solution is added to obtain the aqueous dispersion.
The aqueous dispersion as mentioned above, wherein after the emulsion polymerization of Components containing A and B is completed, the pH value of the emulsion is greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5; preferably greater than or equal to 5 and less than or equal to 5.5.
The preparation method as mentioned above, wherein Component C is dissolved in water in advance.
The aqueous dispersion as mentioned above, wherein the pH value of the Component C aqueous solution is greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5; preferably greater than or equal to 5 and less than or equal to 5.5 .
The preparation method as mentioned above, wherein after the emulsion polymerization of Components containing A and B is completed, Component C and/or Component C aqueous solution is added in when the system temperature is lower than or equal to 70℃, preferably lower than or equal to 40℃.
The preparation method as mentioned above, after the addition of Component C and/or Component C aqueous solution, the pH value of the resultant aqueous dispersion is adjusted to greater than or equal to 4.5 and less than or equal to 8, preferably greater than or equal to 4.5 and less than or equal to 5.5, preferably greater than or equal to 5 and less than or equal to 5.5
The preparation method as mentioned above, preferably using acetic acid and/or Sodium hydroxide as the pH adjuster.
Use of the aqueous dispersion as mentioned above for interfacial bonding between polymeric porous materials
wherein the interfacial bonding between polymeric porous materials is that between one type or more types of materials selected from among fiber textile materials and polymeric foamed materials, preferably that between one type or more types of materials selected from the group consisting of synthetic fiber textile materials, synthetic fiber non-woven materials, natural fiber textile materials, natural fiber non-woven materials, regenerated cellulose materials, ethylene-vinyl acetate (EVA) copolymer foams and  polyurethane (PU) foams, more preferably that between that PU foams and synthetic fiber textile materials, or between PU foams and natural fiber textile materials, or between EVA copolymer foams and synthetic fiber textile materials, or between EVA copolymer foams and natural fiber textile materials.
Use of the aqueous dispersion as mentioned above for structural bonding between textile materials and non-woven materials.
A composite structure for insoles, comprising an artificial fiber textile material and a polymeric foamed material, which are held in place by bonding with the aforesaid aqueous dispersion.
Composite products are obtained in such a way that polymeric porous materials are interfacially bonded. Some of them often come into contact with water during use, or frequently need to be cleaned. Use fields of these composites include, for example, shoe liners, shoe inserts and sportswear. Composite products with poor water resistance are prone to degumming in contact with water, that is, interface debonding, leading to a short service life.
According to the use as described above, the interfacial bonding between polymeric porous materials is preferably the lamination of an artificial fiber textile material onto a polymeric foamed material.
According to the use as described above, the interfacial bonding between polymeric porous materials is preferably that between polyester or acrylic or cotton textile materials and EVA copolymer foams.
According to the use as described above, the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded, the resulting product being exposed to a heat source for a period of time.
According to the use as described above, uses in carpet area are excluded. Most conventional carpets comprise a primary backing with yarn tufts in the form of cut or uncut loops extending upwardly from the backing to form a pile surface. In the case of tufted carpets, the yarn is inserted into a primary backing by tufting needles and a pre-coat or binder is applied thereto. In the case of non-tufted or bonded pile carpets, the fibers are embedded and actually held in place by the binder composition.
According to the use as described above, the interfacial bonding between polymeric porous materials does not include the production of polymeric porous materials themselves using a binder, which mainly refers to the bonding together of fibrous polymer materials less than 5 mm in diameter. For example, in the process of manufacturing non-woven, a binder is used to form non-woven fabrics by bonding together the fibrous materials such as wood pulp fibers, rayon, cottons, wools and acetate fibers; or in the process of paper making, a binder is used to form paper webs, papers or cardboards by bonding pulp fibers together.
According to the use as described above, the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded, the resulting product being exposed to a heat source, at between 150 and 200℃, for a period of time between 25 and 120 seconds to complete the drying step; or the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded, the resulting product being exposed to a heat source, at between 100 and 110℃, for a period of time between 20 and 30 minutes to complete the drying step.
According to the use as described above, the aqueous polymer dispersion is applied onto the surfaces of the polymeric porous materials to be bonded using a roll coater with a certain pressure, and simultaneously completing the drying step therein.
According to the use as described above, after the drying step is completed using the roll coater, no further hot press treatment is required.
According to the use as described above, the coat weight of the aqueous polymer dispersion is between 120 and 210 g/m 2.
When the viscosity of the aqueous polymer dispersion is too low, the coating roller takes up a small amount of glue during the production, leading to a poor bonding effect of the product; while the viscosity of the aqueous polymer dispersion is too high, the coating roller takes up a large amount of glue, leading to excessive coat weight in the product and high consumption of the aqueous polymer dispersion and thus to diseconomy.
Component A –one or more monomers, selected from the group consisting of C1-C15 vinyl alkyl carbonates having unbranched or branched chains, vinyl aromatics, olefins, diolefins and haloethene compounds;
Preferred C1-C15 vinyl alkyl carbonates having unbranched or branched chains are selected from the group of vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, 1-methylvinyl acetate, vinyl pivalate and vinyl esters of α-branched monocarboxylic acids having up to 10 carbon atoms, for example VeoVa9 or VeoVa10, wherein vinyl acetate is particularly preferred.
The said component A can also be polymerized to form copolymers of vinyl acetate and ethylene, or copolymers of vinyl acetate and ethylene and one or more other vinyl monomers, such as vinyl acetate-ethylene-acrylate copolymers and vinyl acetate-ethylene-vinyl chloride copolymers.
Component D. Suitable comonomers, i.e. methacrylates or acrylates, are the esters of unbranched or branched alcohols having 1 to 15 atoms, for example methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate and norbornyl acrylate, wherein preference is given to methyl acrylate, methyl methacrylate, n-butyl acrylate and 2-ethylhexyl acrylate.
The polymers are prepared by the solution polymerization process, emulsion polymerization process or suspension polymerization process, preferably by the emulsion polymerization process, in which the polymerization temperature is generally from 20℃ to 100℃, preferably from 45℃ to 80℃. The polymerization of gaseous monomers, such as ethylene, 1, 3-butadiene or vinyl chloride, can also be carried out under a pressure of generally from 5 bar to 100 bar (abs. ) . The pH range desired for the polymerization, which is in general between 2.5 and 10, preferably 3 and 8, can be established in a known manner by acids, bases or customary buffer salts, such as alkali metal phosphates or alkali metal carbonates.
The polymerization is initiated by a water-soluble or monomer-soluble initiator or redox initiator combinations customary for emulsion polymerization or suspension polymerization. Examples of water-soluble initiators are the sodium, potassium and ammonium salts of peroxodisulfuric acid, hydrogen peroxide, t-butyl peroxide (e.g. t-butyl hydroperoxide) , potassium peroxodisulfate, t-butyl peroxypivalate and azobisisobutyronitrile. These initiators are generally used in an amount of 0.01 to 3%by weight in each case based on the total dry weight of the monomers.
As redox initiators, use is made of combinations of the initiators above-mentioned in combination with reducing agents. Suitable reducing agents are the sulfites of alkali metals or of ammonium, the bisulfites of alkali metals or of ammonium, the derivatives of sulfoxylic acid of alkali metals or of ammonium, or sulfinates of alkali metals or of ammonium. The amount of said reducing agent is generally from 0.01 to 3 %by weight in each case based on the total dry weight of the monomers of Component A.
To control the molecular weight, regulating substances can be used during the polymerization. If regulators are used, they are usually employed in amounts of from 0.01 to 5.0%by weight, based on the total dry weight of the monomers of Component A, and are introduced separately or premixed with reaction components. Examples of such substances are n-dodecyl mercaptan, t-dodecyl mercaptan, mercaptopropionic acid, methyl mercaptopropionate, isopropanol and acetaldehyde.
Suitable protective colloids for the polymerization are polyvinyl alcohols; polyvinyl acetals; polyvinylpyrrolidones; polysaccharides in water-soluble form, e.g. starches (amylose and amylopectin) , celluloses and their carboxymethyl, methyl, hydroxyethyl, hydroxypropyl derivatives, dextrins and cyclodextrins.
The polymerization can be carried out successively or continuously.
After conclusion of the polymerization, an post-polymerization can be carried out to remove residual monomers using known methods, in general by means of an post-polymerization initiated by a redox catalyst. Volatile residual monomers can also be removed by means of distillation, preferably under reduced pressure, and, if appropriate, with inert entrainer gases such as air, nitrogen or steam being passed through or over the polymerization mixture. The aqueous polymer dispersions obtainable in this way have a solids content of from 40 to 70%by weight.
Protective colloids (used as spray additives) , defoamers and anti-caking agents can be added to the aqueous polymer dispersions herein for subsequent preparation of water-redispersible polymer powders by means of a traditional process: fluidized-bed drying, freeze drying or spray drying.
Sample Preparation and Test Method
Sample preparation and method ST-1 for glass transition temperature measurement:
sample a certain amount of the aqueous polymer dispersion and dry at 25℃ overnight and then let stand in a vacuum oven at 40℃ for 24 hours to obtain an dried polymer product.
Take 8-15 mg of the dry product and heat from -80℃ to 100℃ at a heating rate of 10K/min using NETZSCH F203 analyzer in a closed sample cell in protective nitrogen atmosphere, according to ISO11357-1 2014, to determine the glass transition temperature (Tg) of the dried polymer product.
Method ST-2 for viscosity inspection:
The viscosity of the sample is determined with a Brookfield RV/DV rotational viscometer according to GB/T 11175-2002 using spindle No. 4 at 20 rpm at 25℃.
Lab-scale sample preparation method for peeling strength test:
Cut a piece of polyester fabric and a pice of Polyurethane foam to size 20 × 15 cm in reference to the test method improved as per ISO11339-2010. Lay the Polyurethane foam on the glass, the upper and lower ends being fixed with 1.8cm wide 3M electrical tape. Spread the aqueous polymer dispersion over the foam using a doctor blade, scraped tight with a 300-μm scraper bar. Place the foam sample in an oven for heat treatment at 160℃ for 30s before removing.
Spread another layer of aqueous polymer dispersion on the glass by a 300-μm scraper bar. The polyester fabric is layed on the glass, and pressed twice by a glass rod before removing.
Lay Polyurethane foam on the polyester fabric and press it twice with a 2-kg pressure roller. Place the fabric sample in an oven for heat treatment at 160℃ for a while before removing. The dry fabric sample is prepared.
Method ST-4 for wet bonding strength test:
A dry fabric sample mentioned above is soaked in water at 25℃ for 1 hour and then taken out. The resulting wet fabric is then tested for 180° peeling strength in reference to the method shown in Figure 1 of ISO11339-2010 on Shandong Labthink XLW (G) -PC smart electronic tensile tester. The wet sample, with its width remaining 25.4mm (1 inch) , is vertically stretched for a distance of 40mm. The stretches up to 2mm at both the  beginning and end of the test are not taken into account. The stretching speed is 100mm/min.
Detailed Description of the Preferred Embodiments
The aqueous polymer dispersions in Examples and Comparative Examples were prepared according to the basic formulation in Table 2. The basic formulation in Table 2 contains the type of monomers, amount of monomers, type of protective colloid, initiator system, initial charge and subsequent feed of each raw material, and the like.
The amounts in the present invention are, unless otherwise specified, in parts by weight.
In Tables 2, unless otherwise specified, the part by weight of each raw material are calculated on the basis of 100 parts by weight of the vinyl acetate and ethylene monomers.
In Tables 2, the concentration of a solution is the weight of solute divided by the weight of solution, in the form of percent by weight.
Unless otherwise specified, pH value in present invention is analyzed by Mettler Toledo S220 SevenCompact pH/Ion according to its Instruction book.
NMA refers to N-Methylolacrylamide.
Ammonium citrate, sodium citrate, ammonium acetate, ammonium chloride, ammonium oxalate, ammonium p-toluenesulfonate, and ammonium tartrate are all commercially available products.
PVOH 04/88 20 wt%aqueous solution, having an alcoholysis degree of 88 wt%, 4 wt%aqueous solution of which has a viscosity of 4 mPa·sat 20℃ according to DIN 53015, is prepared into a 20 wt%aqueous solution before use.
PVOH 25/88 10.3 wt%aqueous solution, having an alcoholysis degree of 88 wt%, 4 wt%aqueous solution of which has a viscosity of 25 mPa·sat 20℃ according to DIN 53015, is prepared into a 10.3 wt%aqueous solution before use.
tBHP 10 wt%aqueous solution refers to t-butyl hydroperoxide, which is prepared into a 10 wt%aqueous solution before use.
FF6M 5 wt%aqueous solution refers to disodium hydroxysulfinoacetate (purchased from Brüggemann Chemical Incorporates) , which is prepared into a 5 wt%aqueous solution before use.
FAS 1wt%aqueous solution refers to ferrous ammonium sulfate, which is prepared into a 1 wt%aqueous solution before use.
The raw materials primarily adjusted in Examples and Comparative Examples were referred to Table 2. The procedure was similar to that of Example 1.
Table 2
Figure PCTCN2018094427-appb-000004
Figure PCTCN2018094427-appb-000005
Figure PCTCN2018094427-appb-000006
*The amount of ethylene used in Table 2 refers to the amount of ethylene gas fed in each example
Example Ex. 1
Step 1. A premix of 700g of deionized water, 114g of PVOH 04/88 20 wt%aqueous solution, 625g of PVOH 25/88 10.3wt%aqueous solution and 9g of sodium acetate was added into a 5-liter reactor. The premix was mixed well and its pH was adjusted to 5 with acetic acid before 7g of FAS was added.
The reactor was heated to 70℃, into which 1514g of vinyl acetate and 291g of ethylene were added, and the pressure in the reactor was maintained below 45 bar.
The temperature was raised to 70℃ while 10 wt%t-butyl hydroperoxide aqueous solution and 5 wt%FF6M aqueous solution were added dropwisely with a pump to initiate reaction and the dropwise addition continued until the reaction was completed. After the initiation reaction, 440 g of vinyl acetate and a mixed solution of 144g of deionized water and 36 g of N-Methylolacrylamide were added.
Step 2. After reaction for 4 hours, the mixture was transferred to a degassing tank, where 1 g of mineral oil-based defoamer and 28 g of ammonium citrate (as aqueous solution) were added, and after degassing for 30 minutes, the aqueous polymer dispersion was obtained. The product’s Tg is 0℃; solid content is 56wt%.
The other examples and comparative examples were prepared in the same manner as in Ex. 1, except that ammonium citrate was replaced with the corresponding other ammonium salts in Table 2.
Comparative Example C. Ex. 0 was prepared in the same manner as in Ex. 1 and also contained 28 g of citric acid. However, after Step 2, acetic acid was additionally added to adjust the pH of aqueous polymer dispersion to 4.4.
Table 3.1
Figure PCTCN2018094427-appb-000007
Test wet bonding strength as per ST-4 conditions after the products have been stored at 25℃ for more than a week. Table 3.2 shows the performance test results of Examples 1, 4-7 and Comparative Examples 2, 3 and 8.
Table 3.2
Figure PCTCN2018094427-appb-000008
Table 3.2 shows that three samples having a wet-bonding strength of greater than 11 N/inch in a short time (within 3 minutes) were obtained with Examples 1 and 4-7. In particular, by using the examples containing ammonium oxalate and ammonium p-toluenesulfonate, two samples having a wet bonding strength of more than 17 N/inch within 10 minutes, exhibiting particularly excellent performance. The wet-bond strength of these Examples was high and built up fast.
Comparative Example 2, which used sodium citrate, had a wet-bond strength and a build-up speed close to those of the blank C. Ex. 8, and was not effective.
In Comparative Example 3, due to ammonium acetate, the organic acid formed by acetate radicals and hydrogen ions had a primary pKa of 4.73, resulting in a poor wet-bond strength.
The stability of Example 1 of the present invention is shown in Table 4: the aqueous polymer dispersion containing ammonium citrate had very little change in viscosity without gelling when stored under higher temperature for a long period of time and could be used in actual applications.
Table 4
Figure PCTCN2018094427-appb-000009

Claims (15)

  1. An aqueous polymer dispersion, wherein the said polymer is obtained by the polymerization of a composition comprising Components A and B:
    A –one or more monomers, selected from the group consisting of C1-C15 vinyl alkyl carbonates having unbranched or branched chains, vinyl aromatics, olefins, diolefins and haloethene compounds; and
    B -crosslinkable comonomers, comprising crosslinkable N-methylol groups or their derivatives which are etherified with C1-C6 alkanols, preferably N-methylol amide derived from acrylic acid and methacrylic acid, more preferably one, or a combination, of N-methylolacrylamide and N- (N-butoxymethyl) acrylamide;
    and wherein it also contains Component C, an ammonium salt having the following formula (I) :
    X (NH 4)  m            (I)
    where m is a positive integer, preferably selected from among 1, 2 and 3, and
    X represents organic or inorganic acid radicals,
    wherein the organic or inorganic acids formed from X and hydrogen ions have a primary pK a of less than 4.74, preferably less than or equal to 3.5 and greater than or equal to 1, as measured at 25℃ and 1 atm, in 1 mol/L aqueous solution
    the pH value of the resultant aqueous dispersion is adjusted to greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5, more preferably greater than or equal to 5 and less than or equal to 5.5; pH value analyzed by Mettler Toledo S220 SevenCompact pH/Ion according to its Instruction book.
  2. The aqueous dispersion as mentioned in Claim 1, it is a single-package product.
  3. The aqueous dispersion as mentioned in Claim 1 or 2, further comprising a buffer solution; preferable comprising Component F1 or F2, F1 is a buffer solution containing sodium acetate and acetic acid; F2 is a buffer solution containing sodium dihydrogen phosphate and disodium hydrogen phosphate.
  4. The aqueous dispersion as mentioned in any of Claim 1-3, wherein Component C is an ammonium salt of organic acids and/or ammonium salt of an inorganic acid,
    wherein the organic acids are acidic organic compounds having from 2 to 8 carbon atoms and containing a carboxyl group (-COOH) and a sulfonyl group (-SO 3H) ;
    preference is given to the organic acids containing a carboxyl group (-COOH) , and greater preference is given to one, or a combination, of mono-, di-and tri-carboxylic acids; or
    preference is given to the organic acids containing a sulfonyl group (-SO 3H) , and greater preference is given to one, or a combination, of p-toluenesulfonic, benzenesulfonic and methanesulfonic acids;
    the ammonium salt of organic acids is one or more preferably selected from among ammonium citrate, ammonium oxalate, ammonium tartrate, ammonium p-toluenesulfonate, ammonium succinate, ammonium adipate and ammonium glutarate;
    the ammonium salt of organic acids is one or more further preferably selected from among ammonium citrate, ammonium oxalate, ammonium tartrate and ammonium p-toluenesulfonate; further preferably one or more selected from among ammonium citrate, ammonium oxalate, ammonium tartrate;
    the inorganic acid is an acidic inorganic compound;
    the inorganic acid is one or more selected from among sulfuric, hydrochloric and phosphoric acids;
    The ammonium salt of the inorganic acid is one or more preferably selected from among ammonium chloride and ammonium hydrogen sulfate.
  5. The aqueous dispersion as mentioned in any of Claim 1-4, wherein the amount of vinyl acetate and ethylene in Component A is greater than or equal to 90 wt%, preferably greater than or equal to 95 wt%, more preferably greater than or equal to 98 wt%, based on the total weight of monomers of Component A.
  6. The aqueous dispersions as mentioned in any of Claim 1-5, wherein the amount of the ammonium salt as Component C is between 0.1 and 5 wt%, preferably between 0.5 and 3 wt%, based on the total weight of monomers of Component A.
  7. The aqueous dispersions as mentioned in any of Claim 1-6, wherein the amount of the crosslinkable comonomer as Component B is between 0.1 and 5 wt%, preferably between 0.5 and 3 wt%, based on the total weight of monomers of Component A.
  8. The aqueous dispersion as mentioned in any of Claim 1-7, wherein the aqueous polymer dispersion is an emulsion having a Brookfield viscosity between 5,000 and 12,000 mPa·s, preferably between 7,000 and 10,000 mPa·s, as measured according to the ST-2 Brookfield viscosity test method and having a rate of change in Brookfield viscosity of less than 100 wt%, preferably less than 30%, more preferably less than 10%, after 60 days of storage at 23℃; preferably a rate of change in Brookfield viscosity of less than 100 wt%, after 14 days of storage at 50℃.
  9. The aqueous dispersion as mentioned in any of Claim 1-8, wherein the glass transition temperature (Tg) of the dried product of the aqueous polymer dispersion ranges from-2℃ to 10℃, preferably from 0℃ to 5℃ as measured according to ST-1.
  10. A method for preparing the aqueous dispersion as mentioned in any of Claim 1-9, wherein after the emulsion polymerization of Components containing A and B is completed, Component C and/or Component C aqueous solution is added to obtain the aqueous dispersion.
  11. The aqueous dispersion as mentioned in Claim 10, wherein after the emulsion polymerization of Components containing A and B is completed, the pH value of the emulsion is greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5; preferably greater than or equal to 5 and less than or equal to 5.5.
  12. The aqueous dispersion as mentioned in Claim 10 or 11, wherein the pH value of the Component C aqueous solution is greater than or equal to 4.7 and less than or equal to 8, preferably greater than or equal to 4.7 and less than or equal to 5.5; preferably greater than or equal to 5 and less than or equal to 5.5.
  13. The preparation method as mentioned in any of Claim 10-12, wherein after the emulsion polymerization of Components containing A and B is completed, Component C and/or Component C aqueous solution is added in when the system temperature is lower than or equal to 70℃, preferably lower than or equal to 40℃.
  14. Use of the aqueous dispersion as mentioned in any of Claim 1-9 for interfacial bonding between polymeric porous materials,
    wherein the interfacial bonding between polymeric porous materials is that between one type or more types of materials selected from among fiber textile materials and polymeric foamed materials, preferably that between one type or more types of materials selected from the group consisting of synthetic fiber textile materials, synthetic fiber non-woven materials, natural fiber textile materials, natural fiber non-woven materials, regenerated cellulose materials, ethylene-vinyl acetate (EVA) copolymer foams and polyurethane (PU) foams, more preferably that between that PU foams and synthetic fiber textile materials, or between PU foams and natural fiber textile materials, or between EVA copolymer foams and synthetic fiber textile materials, or between EVA copolymer foams and natural fiber textile materials.
  15. A composite structure for insoles, comprising an artificial fiber textile material and a polymeric foamed material, which are held in place by bonding with the aforesaid aqueous dispersion in any of Claim 1-9.
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