WO2019208598A1

WO2019208598A1 - Pyrimidine compound and harmful arthropod-controlling composition containing same

Info

Publication number: WO2019208598A1
Application number: PCT/JP2019/017320
Authority: WO
Inventors: 康片桐
Original assignee: 住友化学株式会社
Priority date: 2018-04-25
Filing date: 2019-04-24
Publication date: 2019-10-31

Abstract

The present invention provides a compound having an excellent controlling effect on harmful arthropods. A compound represented by formula (I) (in the formula, R represents a methyl group or an ethyl group) has an excellent controlling effect on harmful arthropods.

Description

Pyrimidine compound and harmful arthropod control composition containing the same

This application claims priority and benefit to Japanese Patent Application No. 2018-083719 filed on Apr. 25, 2018, the entire contents of which are hereby incorporated by reference.
The present invention relates to a pyrimidine compound and a harmful arthropod control composition containing the same.

So far, various compounds have been studied for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that certain compounds have a pest control effect.

International Publication No. 93/019050

An object of the present invention is to provide a compound having an excellent control effect against harmful arthropods.

The present invention is as follows.
[1] Formula (I)

[Wherein, R represents a methyl group or an ethyl group. ]
(Hereinafter referred to as the present compound).
[2] A harmful arthropod control composition comprising the compound according to [1] and an inert carrier.
[3] A method for controlling harmful arthropods, which comprises applying an effective amount of the compound according to [1] to harmful arthropods or habitats of harmful arthropods.
[4] A composition comprising one or more components selected from the group consisting of group (a) and group (b), and the compound according to [1]:
Group (a): a group consisting of an insecticidal active ingredient, an acaricidal active ingredient and a nematicidal active ingredient;
Group (b): bactericidal active ingredient.
[5] A method for controlling harmful arthropods, which comprises applying an effective amount of the composition according to [4] to harmful arthropods or habitats of harmful arthropods.
[6] A seed or vegetative organ holding an effective amount of the compound according to [1] or the effective amount of the composition according to [4].

According to the present invention, harmful arthropods can be controlled.

The compound of the present invention is mixed with an acid such as hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, acetic acid or benzoic acid, thereby adding an acid addition salt such as hydrochloride, sulfate, nitrate, phosphate, acetate or benzoate. May form.

The compounds of the present invention include any active isomers and mixtures thereof. The isomer is represented by the formula (IA) in which the relative configuration of the substituent at the 1-position and the substituent at the 4-position of the cyclohexane ring is cis-coordinate.

And a compound of formula (IB) in which the relative configuration is trans coordination

The compound shown by these is mentioned.
In the compound of the present invention, the relative configuration of the substituent at the 1-position and the substituent at the 4-position of the cyclohexane ring is preferably cis-coordinate.

Examples of the compound of the present invention include the following compounds.
In the compound of the present invention, a compound in which the relative configuration of the substituent at the 1-position and the substituent at the 4-position of the cyclohexane ring is cis-coordinate.
A compound represented by formula (IA).
In the formula (IA), compounds wherein R is a methyl group (hereinafter referred to as the present compound 1).
In the formula (IA), a compound wherein R is an ethyl group (hereinafter referred to as the present compound 2).
A compound represented by formula (IB).
In the formula (IB), compounds wherein R is a methyl group (hereinafter referred to as the present compound 3).
In the formula (IB), compounds wherein R is an ethyl group (hereinafter referred to as the present compound 4).
In the formula (I), a compound wherein R is a methyl group (hereinafter referred to as the present compound 5).
In the formula (I), a compound wherein R is an ethyl group (hereinafter referred to as the present compound 6).

The compound of the present invention comprises the following group (a), group (b), group (c), group (d), group (e), group (f), group (g), and group (h). One or more selected components (hereinafter referred to as this component) can be used in combination or in combination.
The mixed use or combination means that the compound of the present invention and the present component are used simultaneously, separately or at intervals.
When the compound of the present invention and this component are used at the same time, the compound of the present invention and this component may be contained in separate preparations or may be contained in one preparation.
One aspect of the present invention is a composition (hereinafter referred to as composition A) containing one or more components selected from the group consisting of group (a) and group (b) and the compound of the present invention.

Group (a) includes acetylcholinesterase inhibitors (eg carbamate insecticides, organophosphorus insecticides), GABAergic chloride channel antagonists (eg phenylpyrazole insecticides), sodium channel modulators (eg pyrethroid insecticides) ), Nicotinic acetylcholine receptor antagonist modulators (eg neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamatergic chloride channel allosteric modulators (eg macrolide insecticides), juvenile hormone mimics , Multi-site inhibitor, chordal organ TRPV channel modulator, mite growth inhibitor, mitochondrial ATP biosynthesis enzyme inhibitor, oxidative phosphorylation uncoupler, nicotinic acetylcholine receptor Channel blockers (eg, nereistoxin insecticides), chitin synthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, inhibitors of mitochondrial electron transport complex I, II, III and IV, potential Dependent sodium channel blockers, acetyl CoA carboxylase inhibitors, ryanodine receptor modulators (eg diamide insecticides), stringed organ modulators, microbial insecticides active ingredients, and other insecticidal active ingredients, acaricidal active ingredients and A group consisting of nematicidal active ingredients. These are described in the classification based on the mechanism of action of IRAC.

Group (b) includes nucleic acid synthesis inhibitors (eg, phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (eg, MBC fungicides), respiratory inhibitors (eg, QoI fungicides) , QiI fungicides), amino acid synthesis and protein synthesis inhibitors (eg, anilinopyridine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (eg, triazole-based DMI) Bactericides), cell wall synthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-acting contact active bactericides, microbial bactericides, and other bactericidal active ingredients. These are described in the classification based on the mechanism of action of FRAC.

Group (c) is a group of plant growth regulating components (including mycorrhizal fungi and rhizobia).

Group (d) is a group of chemical damage reducing components.

Group (e) is a group of synergists.

Group (f) is a group of repellent components comprising bird repellent components, insect repellent components, and animal repellent components.

Group (g) is a group of mollusc component.

Group (h) is a group of insect pheromones.

Below, the example of the combination of this component and this invention compound is described. For example, alanycarb + SX means a combination of alanycarb and SX.
The abbreviation SX means any one of the compounds 1 to 6 of the present invention. In addition, all of the components described below are known components and can be obtained from commercially available preparations or produced by known methods. If this component is a microorganism, it can also be obtained from a fungus depository. The numbers in parentheses represent CAS RN (registered trademark).

Combination of the above component (a) and the compound of the present invention:
Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acrinathrin + SX, acynonapyr + SX, aphidopirofo sap (afoxolaner) + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, linylated Aluminum phosphide + SX, amitraz + SX, azadirachtin + SX, azamethiphos + SX, azinphos-ethyl + SX, azinphos-methyl + SX, azocyclotin ) + SX, Celastrus angulatus bark (bark of Celastrus angulatus) + SX, bendiocarb + SX, benfluthrin + SX, Benff Benfuracarb + SX, bensultap + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX, betacypermethrin (beta) -cypermethrin) + SX, bifenazate + SX, bifenthrin + SX, bioallethrin + SX, bioresmethrin + SX, bistrifluron + SX, borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butocarboxim + SX, butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, cartap hydrochlo ride) + SX, cartap + SX, chinomethionat + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX , Chlorfenvinphos + SX, Chlorfluazuron + SX, Chlormephos + SX, Chlorpicrin + SX, Chlorpyrifos + SX, Chlorpyrifos-methyl + SX, chromafenozide + SX, clofentezine + SX, clothianidin + SX, concanamycin A + SX, coumaphos + SX, cryolite + SX, Cyanophos + SX, Cyantraniliprole + SX, Cyclaniprole + SX, Cycloprothrin + SX, Cloxaprid + SX, cyenopyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + SX, cyhexatin SX, cyhexatin Permethrin + SX, cyphenothrin + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX , Diafenthiuron + SX, diazinon + SX, dichlorvos + SX, dicloromezotiaz + SX, dicofol + SX, dicrotophos + SX, diflovidazine (diflovidazin) + SX, diflubenzuron + SX, dimefluthrin + SX, dimethoate + SX, dimethylvinphos + SX, dinotefra (dinotefuran) + SX, disodium octaborate + SX, disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX, dried fern Leaf (dried leaves of Dryopteris filix-mas) + SX, emamectin-benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O- (4-nitrophenyl) ) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, etofenprox + SX, etoxazole + SX, extract of Artemisia absinthium + SX, Cassia nigricans extract extract of C assia nigricans) + SX, extract of clitoria ternatea + SX, extract of Symphytum officinale + SX, extract of simulated blend of Chenopodium ambrosioides + SX, tansy extract Extract of Tanacetum vulgare + SX, Atlantic nettle extract (extract of Urtica dioica) + SX, extract of Viscum album + SX, famphur + SX, fenamiphos + SX, Fenazaquin + SX, fenbutatin oxide + SX, fenitrothion + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate (fenpyroximate) ) + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, flometoquin + SX, flonicamide amid) + SX, fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, flubendiamide + SX, flucycloxuron + SX, flucitrinate (flucythrinate) + SX, fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupiradifuron ( flupyradifurone) + SX, fluprimin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formatenate + SX, fosthiazate + SX, flametine furamethrin) + SX, furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide (GS-omega / kappa HXTX- Hv1a peptide) + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox (hexythiazox) ) + SX, potassium salt of hop beta acid + SX, hydramethylnon + SX, hydroprene + SX, imiciaphos + SX, imidacloprid + SX , Imiprothrin + SX, indoxacarb + SX, isofenphos + SX, isoprocarb + SX, isopropyl O- (methoxyaminothiophosphoryl) salicylate (isopropyl-O- (methoxyaminothiophosphoryl) salicylate ) + SX, isoxathion + SX, ivermectin + SX, kadethrin + SX, kappa-tefluthrin + SX, kappa-bifenthrin + SX, kinoprene + SX, lambda-cyhalothrin + SX, lenoremycin + SX, lepimectin + SX, lime sulfur combination ( lime sulfur + SX, lufenuron + SX, machine oil + SX, malathion + SX, mecarbam + SX, meperfluthrin + SX, metaflumizone + SX, Metam + SX, methamidophos + SX, methidathion + SX, methiocarb + SX, metomyl + SX, metoprene + SX, methoxychlor + SX, methoxyphenozide (methoxyfenozide) + SX, methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin (milb) emectin) + SX, milbemycin oxime + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, nared + SX, neem oil ) + SX, nicotine + SX, nicotine-sulfate + SX, nitenpyram + SX, novaluron + SX, noviflumuron + SX,
Oil of the seeds of Chenopodium anthelminticum + SX, omethoate + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone ) + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX, pirimicarb + SX, pirimiphos-methyl + SX, plaretrin ( prallethrin) + SX, profenofos + SX, profluthrin + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene arginic acid Propylene glycol alginate + SX, prothiofos + SX, pyrflubumide + SX, pyrometrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, pyrinostrobin + SX, pyriprole proxy SX, pyriprole proxy + SX (pyriproxyfen) + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spinetoram + SX, spinosa Spinosad + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat + SX, sulfluramid + SX, sulfotep ( sulfotep) + SX, sulfoxaflor + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX, tau-fluvalinate + SX, Tebufenozide + SX, tebufenpyrad + SX, tebupirimfos + SX, teflubenzuron + SX, tefluthrin + SX, temephos + SX, fo tersfos ter Terpene constituents of the extract of chenopodium ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460) + SX, tetrachlorvinphos + SX, tetradiphone ( tetradifon) + SX, tetramethrin + SX, tetramethylfluthrin + SX, tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam (thiamethoxam) + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosultap-disodium + SX, thiosultap Sodium salt (thiosultap-monosodium) + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos (triazophos) ) + SX, trichlorfon + SX, triflumezopyrim + SX, triflumuron + SX, trime Carb (trimethacarb) + SX, ticlopyrazoflor + SX, bamidothion + SX, wood extract of Quassia amara + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, 3-bromo-N- [2,4-dichloro-6- (methylcarbamoyl) Phenyl] -1- (3,5-dichloropyridin-2-yl) -1H-pyrazole-5-carboxamide (1104384-14-6) + SX, N- [3-Chloro-1- (pyridin-3-yl) ) -1H-pyrazol-4-yl] -N-ethyl-3- (3,3,3-trifluoropropanesulfinyl) propanamide (1477923-37-7) + SX, 4- [5- (3,5 -Dichlorophenyl) -5- (trifluoromethyl) -4,5-di Hydro-1,2-oxazol-3-yl] -2-methyl-N- (1-oxothietan-3-yl) benzamide (1241050-20-3) + SX, 3-methoxy-N- (5- {5 -(Trifluoromethyl) -5- [3- (trifluoromethyl) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} indan-1-yl) propanamide (1118626-57-5 ) + SX, N- [2-Bromo-6-chloro-4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) phenyl] -3- {ethyl [(pyridine -4-yl) carbonyl] amino} -2-methoxybenzamide (1429513-53-0) + SX, N- [2-bromo-6-chloro-4- (1,1,1,2,3,3, 3-Heptafluoropropan-2-yl) phenyl] -3- [ethyl (4-cyanobenzoyl) a NO] -2-methoxybenzamide (1609007-65-9) + SX, N- [2-bromo-6-difluoromethoxy-4- (1,1,1,2,3,3,3-heptafluoropropane- 2-yl) phenyl] -3- {methyl [(pyridin-4-yl) carbonyl] amino} -2-methoxybenzamide (1630969-78-6) + SX, 1- {2-fluoro-4-methyl-5 -[(2,2,2-trifluoroethyl) sulfinyl] phenyl} -3- (trifluoromethyl) -1H-1,2,4-triazol-5-amine (885026-50-6) + SX,
BT crop protein Cry1Ab (BT crop protein Cry1Ab) + SX, BT crop protein Cry1Ac (BT crop protein Cry1Ac) + SX, BT crop protein Cry1Fa (BT crop protein Cry1Fa) + SX, BT crop protein Cry1A.105 ( BT crop protein Cry1A.105) + SX, BT crop protein Cry2Ab (BT crop protein Cry2Ab) + SX, BT crop protein Vip3A (BT crop protein Cry3A) + SX, BT crop protein Cry3A (BT crop protein Cry3A) + SX, BT crop protein Cry3Ab (BT crop protein Cry3Ab) + SX, BT crop protein Cry3Bb (BT crop protein Cry3Bb) + SX, BT crop protein Cry34Ab1 / Cry35Ab1 (BT crop protein Cry34Ab1 / Cry35Ab1) + SX, Orana granulosis virus BV-0001 (Adoxophyes orana granulosis virus BV-0001) + SX, Anticalcia gemmatalis mNPV + SX, Autographa californica mNPV ) + SX, Shijia Pomonella granule disease virus V15 (Cydia pomonella GV V15) + SX, Sidia pomonella granule disease virus V22 (Cydia pomonella GV V22) + SX, Cryptophlebia leucotreta granule disease virus (Cryptophlebia leucotreta GV) + SX, Cytoplasmic polyhedral virus (Dendrolimus punctatus cypovirus) + SX, Helicobelpa algera nuclear polyhedrosis virus BV-0003 (Helicoverpa armigera NPV BV-0003) + SX, Helicoberpa zea nuclear polyhedrosis virus (Helicoverpa zea NPV) + SX, Lymantria dispar nuclear polyhedrosis virus (Lymantria dispar NPV) + SX, Mamestra brassicae nuclear polyhedrosis virus (Mamestra brassicae NPV) + SX, Mamestra configurata nuclear polyhedrosis virus (Mamestra configurata NPV) + SX, Neo Diprion abietis nuclear polyhedrosis virus (Neodiprion abietis NPV) + SX, Neodiprion Reconte Neodiprion lecontei NPV + SX, Neodiprion sertifer NPV + SX, Nosema locustae + SX, Orgyia pseudotubata nuclear polyhedrosis virus (Orgyia pseudotsugata NPV) + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Spodoptera exigua mNPV + SX, Spodoptera littoralis mNPV + SX, Spodoptera litura NPV + SX, Arthrobotrys dactyloides + SX, Bacillus firmus GB-126 + SX, Bacillus firmus -1582 + SX, Bacillus megaterium + SX, Bacillus sp. AQ175 + SX, Bacillus sp. AQ177 + SX, Bacillus sp. AQ178 + SX, Bacillus sphaericus 2362 + SX, Bacillus sphaericus ABTS1743 + SX, Bacillus sphaericus Serotype H5a5b + SX, Bacillus thuringiensis AQ52 + SX, Bacillus thuringiensis BD # 32 + SX, Bacillus thuringiensis CR-371 + SX, Bacillus thuringiensis subsp. Aizawai GC-91 + SX, Bacillus thuringiensis subsp.Aizawai Serotype H-7 + SX, Bacillus thuringiensis subsp. Kurstaki ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki EG784 + SX, Bacillus thuringiensis subsp. Kurstaki EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki F810 + SX, Bacillus thuringiensis subsp. Kurstaki HD-1 + SX, Bacillus thuringiensis P + SX, Bacillus thuringiensis subsp. Kurstaki SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki SA-12 + SX, Bacillus thuringiensis subsp.Tenebriosis NB176 + SX, Bacillus thuringiensis subsp.Thuringiensis MPPL002 + SX, Bacillu s thuringiensis subsp.morrisoni + SX, Bacillus thuringiensis var.colmeri + SX, Bacillus thuringiensis var.darmstadiensis 24-91 + SX, Bacillus thuringiensis var.dendrolimus + SX, Bacillus thuringiensis var.galleriae + SX, Bacillus thuringien Israelensis serotype H-14 + SX, Bacillus thuringiensis var.san diego M-7 + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. , Bacillus thuringiensis var. T36 + SX, Beauveria bassiana ANT-03 + SX, Beauveria bassiana ATCC74040 + SX, Beauveria bassiana GHA + SX, Beauveria brongniartii + SX, Burkholderia rinojensis A396 + SX, Chromobacterium subtsugae PRAA4-1Tyl + SX, Dectylaria thaumasia + SX, Hirsutella minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 + SX, Lecanicillium lecanii conidia of s train DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX, Metarhizium anisopliae F52 + SX, Metarhizium anisopliae var.acridum + SX, Metarhizium flavoviride + SX, Monacrosporium phymatopagmy, SX, Paeciloces Paecilomyces tenuipes T1 + SX, Paenibacillus popilliae + SX, Pasteuria nishizawae Pn1 + SX, Pasteuria penetrans + SX, Pasteuria usgae + SX, Pasteuria thoynei + SX, Serratia entomophila + SX, Verticillium chlamydosporium + SX, IM (acetoprole) + SX, rotilaner + SX, sarolaner + SX, isocycloseram + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Lecanicillium muscarium Ve6 + SX, N-ethyl -5-methyl-1- (3-methylbutan-2-yl) -N- (pyridazin-4-yl) -1H-pyrazole-4-carboxamide (1403615-77-9) + SX, imidaclothiz + SX .

Combination of the above component (b) and the compound of the present invention:
Acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, Azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, benthivalicarb-isopropyl + SX, benzovindiflupyr + SX, binapacryl + SX, Biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin-S + SX, Bordeaux mixture + SX, boscalid + SX, bromotalonyl ( b romothalonil) + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, carpropamid + SX, chinomethionat + SX, chitin + SX, chloroneb + SX, chlorothalonil + SX, chlozolinate + SX, collochlorin B (colltochlorin B) ) + SX, copper (II) acetate + SX, copper (II) hydroxide + SX, copper oxychloride + SX, copper sulfate (II) ) (copper (II) sulfate) + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX , Cyprodinil + SX, Diclobentiazox ) + SX, dichlofluanid + SX, dilocymet + SX, diclomezine + SX, dicloran + SX, dietofencarb + SX, difenoconazole + SX, difenoconazole diflumetorim) + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diiconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX, dodecylbenzenesulphonic bisethylenediamine copper (II) dodecylbenzenesulphonic acid bisethylenediamine copper (II) salt) + SX, dodemorph + SX, dodine + SX, edifenphos + SX, e Xenostrobin + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, tea tree extract from Melaleuca alternifolia) + SX, extract of reedoutria sachalinensis + SX, extract from cotyledons of lupine plantlets ("BLAD") + SX, extract of garlic Allium sativum) + SX, extract of Equisetum arvense + SX, extract of Tropaeolum majus + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin ) + SX, fenarimol + SX, fenbuconazole + SX, fenfuram + SX, fenhexamid + SX, phenoxa Fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, acetic acid Fentin acetate + SX, fentin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpico Xylamide (florylpicoxamid) + SX, fluazinam + SX, fludioxonil + SX, flufenoxystrobin + SX, fluindapyr + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxastrobin + SX, fluquinconazole + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, Folpet + SX, fosetyl + SX, fosetyl-aluminium + SX, fuberidazole + SX, furalaxyl + SX, furametpyr + SX, guazatine + SX, hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate + SX , Impyrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + SX, ipflufe Quin (ipflufenoquin) + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX, isofetamid + SX, isoflucypram + SX, isoprothiolane + SX , Isopyrazam + SX, Isotianil + SX, kasugamycin + SX, kresoxim-methyl + SX, laminarin + SX, oak leaves and bark of Quercus + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, maneb + SX, mefentrifluconazole + SX, mepanipyrim + SX, Mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metconazole + SX, meta Sulfocarb (methasulfocarb) + SX, metiram + SX, metomiminostrobin + SX, metrafenone + SX, methyltetraprole + SX, machine oil + SX, microbutanyl ( myclobutanil) + SX, naftifine + SX, nuarimol + SX, octhilinone + SX, ofurace + SX, orysastrobin + SX, oxadixyl + SX, oxathiapi Oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin ( oxycarboxin) + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen fen) + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin (picoxystrobin) + SX, piperalin + SX, polyoxins + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, Prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, propineb + SX, proquinazid + SX , Prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, pyraclostrobin + SX, pyrametostrobin ostrobin) + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, pyribencarb + SX, pyributicarb + pyributicarb Pyridachlometyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, Quillaja extract + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, Saponins of quinoa Chenopodium quinoa) + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium hydrogencarbonate + SX, Spiroxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine (terbinafine) + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, thymol + SX, thiazinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triazime (triadimefon) + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole (tricyclazole) + SX, triridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, validamycin ( validamycin) + SX, valifenalate + SX, vinclozolin + SX, yellow mustard powder + SX, zinc thiazole + SX, zineb + SX, ziram + SX, Zoxamide + SX,
3- (Difluoromethyl) -N-methoxy-1-methyl-N-[(1R) -1-methyl-2- (2,4,6-trichlorophenyl) ethyl] pyrazole-4-carboxamide (1639015-48- 7) + SX, 3- (Difluoromethyl) -N-methoxy-1-methyl-N-[(1S) -1-methyl-2- (2,4,6-trichlorophenyl) ethyl] pyrazole-4-carboxamide (1639015-49-8) + SX, 3- (Difluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide (141573-94-6) + SX, 3- (difluoromethyl) -N-[(3R) -7-fluoro-1,1,3-trimethylindan-4-yl] -1-methylpyrazole-4-carboxamide (1513466-73-3) + SX, N ′-[4-({3-[(4-chlorophenyl) Til] -1,2,4-thiadiazol-5-yl} oxy) -2,5-dimethylphenyl] -N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, 2- {3 -[2- (1-{[3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5 -Dihydro-1,2-oxazol-5-yl} -3-chlorophenyl methanesulfonate (1360819-11-9) + SX, 4- (2-bromo-4-fluorophenyl) -N- (2-chloro -6-Fluorophenyl) -1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2- [6- (3-Fluoro-4-methoxyphenyl) -5-methylpyridine -2-yl] quinazoline (1257056-97-5) + SX, 5-fluoro-2-[(4 -Methylphenyl) methoxy] -4-pyrimidinamine (1174376-25-0) + SX, 5-fluoro-4-imino-3-methyl-1-tosyl-3,4-dihydropyrimidin-2 (1H) -one (1616664-98-2) + SX, N '-(2,5-Dimethyl-4-phenoxyphenyl) -N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-{ 4-[(4,5-Dichlorothiazol-2-yl) oxy] -2,5-dimethylphenyl} -N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, (2Z)- Ethyl 3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl) methyl] -N-ethyl-6-methoxy-3- Nitropyridin-2-amine (1446247-98-8) + SX, α- [3- (4-Chloro-2-fluorophenyl) -5 (2,4-difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229605-96-2) + SX, (αS)-[3- (4-chloro-2-fluorophenyl) -5- (2 , 4-Difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229606-46-5) + SX, (αR)-[3- (4-chloro-2-fluorophenyl) -5- (2,4 -Difluorophenyl) -4-isoxazolyl] -3-pyridinemethanol (1229606-02-3) + SX, 2-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2- Yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1342260-19-8) + SX, 2-{[(2R, 3S) -3- (2-chlorophenyl) ) -2- (2,4-Difluorophenyl) oxiran-2-yl ] Methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-70-7) + SX, 2-{[(2S, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-71-8) + SX, 2 -{[(2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4- Triazole-3-thione (1638897-72-9) + SX, 2-{[(2S, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxilan-2-yl] methyl } -2,4-dihydro-3H-1,2,4-triazole-3-thione (1638897-73-0) + SX, 1- [3- (2-Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-yl thiocyanate (1342260-26-7) + SX, 1-{[(2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole-5 -Yl thiocyanato (1638897-82-1) + SX, 1-{[(2S, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxilan-2-yl] methyl}- 1H-1,2,4-triazol-5-yl thiocyanate (1638897-84-3) + SX, 1-{[(2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluoro Phenyl) oxiran-2-yl] methyl} -1H-1,2, -Triazol-5-yl thiocyanato (1638897-86-5) + SX, 1-{[(2S, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2-yl ] Methyl} -1H-1,2,4-triazol-5-yl thiocyanato (1638897-89-8) + SX, 5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H -1,2,4-triazol-1-ylmethyl) cyclopentanol (1394057-11-4) + SX, (1R, 2S, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2- Methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801930-06-2) + SX, (1S, 2R, 5R) -5- (4-chlorobenzyl) -2 -Chloromethyl-2-methyl-1- (1H-1,2,4-triazole-1 Ylmethyl) cyclopentanol (1801930-07-3) + SX, (1R, 2R, 5R) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2, 4-Triazol-1-ylmethyl) cyclopentanol (1801919-53-8) + SX, (1S, 2S, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- ( 1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801919-54-9) + SX, (1R, 2R, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2 -Methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801919-55-0) + SX, (1S, 2S, 5R) -5- (4-chlorobenzyl)- 2-Chloromethyl-2-methyl-1- (1H-1,2,4-triazole-1- Rumethyl) cyclopentanol (1801919-56-1) + SX, (1R, 2S, 5R) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- (1H-1,2, 4-Triazol-1-ylmethyl) cyclopentanol (1801919-57-2) + SX, (1S, 2R, 5S) -5- (4-chlorobenzyl) -2-chloromethyl-2-methyl-1- ( 1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801919-58-3) + SX, methyl = 3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (1791398-02-1) + SX, methyl = (1R, 2S, 3S) -3-[(4-chlorophenyl) methyl]- 2-hydroxy-1-methyl-2- (1H-1,2,4- Triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-90-2) + SX, methyl = (1S, 2R, 3R) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2 -(1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-91-3) + SX, methyl = (1R, 2R, 3R) -3-[(4-chlorophenyl) methyl] -2-Hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-92-4) + SX, methyl = (1S, 2S, 3S)- 3-[(4-Chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743-93-5) + SX, Methyl = ( R, 2R, 3S) -3-[(4-Chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2080743- 94-6) + SX, methyl = (1S, 2S, 3R) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H-1,2,4-triazole-1 -Ylmethyl) cyclopentanecarboxylate (2080743-95-7) + SX, methyl = (1R, 2S, 3R) -3-[(4-chlorophenyl) methyl] -2-hydroxy-1-methyl-2- (1H -1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2081061-22-3) + SX, methyl = (1S, 2R, 3S) -3-[(4-chlorophenyl) methyl] -2- Hydroxy-1-methyl 2- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanecarboxylate (2081061-23-4) + SX, 2-chloromethyl-5- (4-fluorobenzyl) -2-methyl-1 -(1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1394057-13-6) + SX, (1R, 2S, 5S) -2-chloromethyl-5- (4-fluorobenzyl) -2-Methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801930-08-4) + SX, (1S, 2R, 5R) -2-chloromethyl-5 (4-Fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1801930-09-5) + SX, (1R, 2R, 5R) -2 -Chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-08-4) + SX, (1S, 2S, 5S) -2-chloromethyl-5- (4-fluorobenzyl)- 2-Methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-10-8) + SX, (1R, 2R, 5S) -2-chloromethyl-5- ( 4-Fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-13-1) + SX, (1S, 2S, 5R) -2- Chloromethyl-5- (4-fluorobenzyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-16-4) + SX, (1R, 2S , 5R) -2-Chloromethyl-5- (4-fluorobenzyl) -2-methyl 1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-20-0) + SX, (1S, 2R, 5S) -2-chloromethyl-5- (4-fluorobenzyl ) -2-Methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol (1638898-24-4) + SX, (R) -2- [2-chloro-4- ( 4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) pent-3-in-2-ol (1801919-59-4) + SX, (R) -2- [4 -(4-Chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol (1616236-94-2) + SX, (R ) -1- [4- (4-Chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl- -(1,2,4-triazol-1-yl) ethanol (1801919-60-7) + SX, (R) -2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -3-Methyl-1- (1,2,4-triazol-1-yl) butan-2-ol (1801919-61-8) + SX, 3- [5- (4-chlorophenyl) -2,3- Dimethyl-1,2-oxazolidine-3-yl] pyridine (847749-37-5) + SX,
Agrobacterium radiobactor K1026 + SX, Agrobacterium radiobactor K84 + SX, Bacillus amyloliquefaciens AT332 + SX, Bacillus amyloliquefaciens B3 + SX, Bacillus amyloliquefaciens D747 + SX, Bacillus amyloliquefaciens DB101 + SX, Baciliens amyls FZB24 + SX, Bacillus amyloliquefaciens FZB42 + SX, Bacillus amyloliquefaciens IN937a + SX, Bacillus amyloliquefaciens MBI600 + SX, Bacillus amyloliquefaciens QST713 + SX, Bacillus amyloliquefaciens isolate B246 + SXo Bacils SX + Bacillus amyloliquefaciens isolate B246 + SX + Bacillus SX + Bacillus amyloliquefaciens licheniformis SB3086 + SX, Bacillus pumilus AQ717 + SX, Bacillus pumilus BUF-33 + SX, Bacillus pumilus GB34 + SX, Bacillus pumilus QST2808 + SX, Bacillus simplex CGF2856 + SX, Bacillus subtilis AQ153 + SX, Bacillus subtilis SX, BaQ subtilis BU1814 + SX, Bacillus subtilis D747 + SX, Bacillus subtilis DB101 + SX, Bacillus subtilis FZB24 + SX, Bacillus subtili s GB03 + SX, Bacillus subtilis HAI0404 + SX, Bacillus subtilis IAB / BS03 + SX, Bacillus subtilis MBI600 + SX, Bacillus subtilis QST30002 / AQ30002 + SX, Bacillus subtilis QST30004 / AQ30004 + SX, Bacillus subtilis QST713 + + SX, Bacillus subtilis var. Amyloliquefaciens FZB24 + SX, Bacillus subtilis Y1336 + SX, Burkholderia cepacia + SX, Burkholderia cepacia type Wisconsin J82 + SX, Burkholderia cepacia type Wisconsin M54 + SX, Octo Chaetomium cupreum + SX, Clonostachys rosea + SX, Coniothyrium minitans CGMCC8325 + SX, Coniothyrium minitans CON / M / 91-8 + SX, cryptococcus albidus + SX, Erwinia carotovora subsp. Carotovora CGE234M403 + SX, Fusarium 47 J1446 + SX, Paenibacillus polymyxa AC-1 + SX, Paenibacillus polymyxa BS-0105 + SX, Pantoea agglomerans E325 + SX, Phlebiopsis gigantea VRA1992 + SX, Pseudomonas aureofaciens TX-1 + SX, Pseudomonas chlororaphiSX 63-28 + chlororaphis MA342 + SX, Pseudomonas fluorescens 1629RS + SX, Pseudomonas fluorescens A506 + SX, Pseudomonas fluorescens CL145A + SX, Pseudomonas fluorescens G7090 + SX, Pseudomonas sp. CAB-02 + SX, Pseudomonae SX, Pseudozyma flocculosa PF-A22UL + SX, Pseudomonas rhodesiae HAI-0804 + SX, Pythium oligandrum DV74 + SX, Streptomyces griseoviridis K61 + SX, Streptomyces lydicus WYCD108US + SX, Streptomyces lydicus SX-YY-108-mydicus SX 01 + SX, Talaromyces flavus V117b + SX, Trichoderma asperellum ICC012 + SX, Trichoderma asperellum SKT-1 + SX, Trichoderma asperellum T34 + SX, Trichoderma atroviride CNCM 1-1237 + SX, Trichoderma atroviride LC52 + SXtro Trider , Trichoderma atroviride SKT-1 + SX, Trichoderma gamsii ICC080 + SX, Trichoderma harzianum 21 + SX, Trichoderma harzianum DB104 + SX, Trichoderma harzianum DSM 14944 + SX, Trichoderma harzianum ESALQ-1303 + SXharcho SX, Trichoderma harzianum IIHR-Th-2 + SX, Trichoderma harzianum kd + SX, Trichoderma harzianum MO1 + SX, Trichoderma harzianum SF + SX, Trichoderma harzianum T22 + SX, Trichoderma harzianum T39 + TEMharz T TH35 + SX, Trichoderma polysporum IMI206039 + SX, trichoderma stromaticum + SX, Trichoderma virens G-41 + SX, Trichoderma virens GL-21 + SX, Trichoderma viride + SX, Variovorax paradoxus CGF4526 + SX, Harpin protein + SX, methyl { 2-methyl-5- [1- (4-methoxy-2-methylphenyl) -1H-pyrazol-3-yl] phenyl} methyl) carbamate (1605879-98-8) + SX, 2- (difluoromethyl) -N- [1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1616239-21-4) + SX, 2- (difluoromethyl) -N- [3-ethyl -1,1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1847460-02-9) + SX, 2- (difluoromethyl) -N- [3-propyl-1 , 1-dimethyl-2,3-dihydro-1H-inden-4-yl] pyridine-3-carboxamide (1847460-05-2) + SX, (2E, 3Z) -5-{[1- (4-chlorophenyl ) -1H-pyrazol-3-yl] oxy} -2- (methoxyimino) -N, 3-d imethylpent-3-enamide (1445331-27-0) + SX, Bacillus amyloliquefaciens subsp.plantarum D747 + SX, Pythium oligandrum M1 + SX, Trichoderma asperellum T25 + SX, Trichoderma asperellum TV1 + SX, Trichoderma atroviride IMI 206der atroviride T11 + SX, Bacillus amyloliquefaciens (Aveo ™ EZ Nematicide) + SX.

Combination of the above component (c) and the compound of the present invention:
1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX , IAA ((1H-indol-3-yl) acetic acid) + SX, IBA (4- (1H-indol-3-yl) butyric acid) + SX, MCPA (2- (4-chloro-2-methylphenoxy) acetic acid) + SX, MCPB (4- (4-chloro-2-methylphenoxy) butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anancymidol + SX, butralin + SX, calcium carbonate (calcium carbonate) + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + S X, chlormequat-chloride + SX, chloropropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide ) + SX, daminozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat ( diquat) + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, gibberellin A + SX, Gibberellin A3 + SX, inabenfide + SX, kinetin + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat chloride chloride) + SX, oxidation Glutathione + SX, pacrobutrazol + SX, pendimethalin + SX, prohexandione-calcium + SX, prohydrojasmon + SX, pyraflu Phenethyl (pyraflufen-ethyl) + SX, sintofen + SX, 1-sodium naphthalene acetate (sodium 1-naphthaleneacetate) + SX, sodium cyanate + SX, streptmycin + SX, thidiazuron ( thidiazuron) + SX, triapenthenol + SX, Tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2- (naphthalene-1- Yl) acetamide (2- (naphthalene-1-yl) acetamide) + SX, [4-oxo-4- (2-phenylethyl) amino] butyric acid + SX, 5- (trifluoromethyl) benzo [b] thiol 2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl) amino] -1-propanol + SX, formononetin + SX, Claroideoglomus etunicatum + SX, Funneliformis mosseae + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus monosporum + SX, Paraglomus brasillianum + SX, Rhizophagus clarus + SX, Rhizophagus intraradices RTI-801 + SX, Rhizophagus irregular + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum brasilense XOH + SX, Azospirillum brasilense Ab-V5 + SX, Azospirillum brasilense Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillens + SX Azospirillum lipoferum + SX, Bradyrhizobium elkanii SEMIA 587 + SX, Bradyrhizobium elkanii SEMIA 5019 + SX, Bradyrhizobium japonicum TA-11 + SX, Bradyrhizobium japonicum USDA 110 + SX, Bradyrhizobium liaoningen se + SX, Bradyrhizobium lupini + SX, Delftia acidovorans RAY209 + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Rhizobium etli + SX, Rhizobium rum Rumzoumum SX Trivolii + SX, Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, lipochitooligosaccharide SP104 + SX MZ

Combination of the above component (d) and the compound of the present invention:
Allidochlor + SX, Benoxacor + SX, Cloquintocet + SX, Cloquintocet-mexyl + SX, Ciometrinil + SX, Cyprosulfamide + SX, dichlormid + SX, dicyclonone + SX, dimepiperate + SX, disulfoton + SX, dymron + SX, fenchlorazole + SX, fenchlorazole Fenchlorazole-ethyl + SX, fenclorim + SX, flurazole + SX, furilazole + SX, flxofenim + SX, hexim + SX, isoxadifen + SX , Isoxadifen-ethyl + SX, mecoprop + SX, mefenpyr + SX, mefenpyr-ethyl + SX, mefenpyrdi Chill (mefenpyr-diethyl) + SX, mephenate + SX, meetcamifen + SX, oxabetrinil + SX, 1,8-naphthalic anhydride + SX, 1 , 8-octamethylenediamine + SX, AD-67 (4- (dichloroacetyl) -1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy- 3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl) sulfonyl] benzene) + SX, DKA-24 (2,2-dichloro-N -[2-oxo-2- (2-propenylamino) ethyl] -N- (2-propenyl) acetamide) + SX, MG191 (2- (dichloromethyl) -2-methyl-1,3-dioxolane) + SX, MG -838 (2-propenyl 1-oxa-4-azaspiro [4.5] decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N- (1,3-dioxan-2-ylmethyl) -N -(2-propenyl) acetamide) + SX, R-28725 (3- (dichloroacetyl) -2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3- (dichloroacetyl) -2,2, 5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1- (dichloroacetyl) azepane) + SX.

Combination of the above component (e) and the compound of the present invention:
1-dodecyl-1H-imidazole + SX, N- (2-ethylhexyl) -8,9,10-trinorborn-5-ene-2,3-dicarboximide (N -(2-ethylhexyl) -8,9,10-trinorborn-5-ene-2,3-dicarboximide) + SX, bucarpolate + SX, N, N-dibutyl-4-chlorobenzenesulfonamide (N, N -dibutyl-4-chlorobenzenesulfonamide) + SX, dietholate + SX, diethylmaleate + SX, piperonyl butoxide + SX, piperonylcyclonene + SX, piperotal + SX, propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, Verbutin + SX, DMC (1, 1-bis (4-chlorophenyl) ethanol) + SX, FDMC (1,1-bis (4-chlorophenyl) -2,2,2-trifluoroethanol) + SX, ETN (1,2- epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S, S, S -tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX.

Combination of the above component (f) and the compound of the present invention:
Anthraquinone + SX, chloralose + SX, acrep + SX, butopyronoxyl + SX, camphor + SX, d-camphor + SX, carboxide ) + SX, dibutyl phthalate + SX, deet + SX, dimethyl carbate + SX, dimethyl phthalate + SX, dibutyl succinate + SX , Dibutyl adipate + SX, ethohexadiol + SX, hexamid + SX, icaridin + SX, methoquin-butyl + SX, methyl neodecanamide (methylneodecanamide) + SX, 2- (octylthio) ethanol + SX, butoxypolypropylene glycol + SX, oxamate + SX, quwenzhi + SX, quyingding + SX, zengxiaon + SX, Les Rebemide + SX, copper naphthenate + SX, zinc naphthenate + SX.

Combination of the above component (g) and the compound of the present invention:
Bis (tributyltin) oxide + SX, allicin + SX, bromoacetamide + SX, cloethocarb + SX, copper sulfate + SX, fentin ) + SX, ferric phosphate + SX, metaldehyde + SX, niclosamide + SX, pentachlorophenol + SX, sodium pentachlorophenoxide + SX, tazimcarb + SX, tralopyril + SX, trifenmorph + SX.

Combination of the above component (h) and the compound of the present invention:
(E) -2-hexenal + SX, (E) -2-octadecenal + SX, (E) -4-tridecen-1-yl acetate + SX, (E) -5-decen-1-yl acetate + SX, (E) -5-decen-1-ol + SX, (E) -3,3-dimethylcyclohexylideneacetaldehyde + SX, (E) -7-dodecen-1-yl acetate + SX, (E) -8-dodecen-1 -yl acetate + SX, (E) -9-dodecen-1-yl acetate + SX, (E) -10-hexadecenal + SX, (E) -11-hexadecen-1-yl acetate + SX, (E)- 11-tetradecen-1-yl acetate + SX, (E) -11-tetradecen-1-ol + SX, (E) -4-tridecen-1-yl acetate + SX, (E) -6-methylhept-2- en-4-ol + SX, (Z) -2- (3,3-dimethylcyclohexylidene) ethanol + SX, (Z) -4-decen-1-yl acetate + SX, (Z) -4-tridecen-1- yl acetate + SX, (Z) -5-decen-1-yl acetate + SX, (Z) -5-decen-1-ol + SX, (Z) -7-tetradecenal + SX, (Z) -7- dodecen-1-yl acetate + SX, (Z) -8-dodecen-1-yl acetate + SX, (Z) -9-dodecen-1-yl acetate + SX, (Z) -8-dodecen-1-ol + SX, (Z) -9-hexadecenal + SX, (Z) -10-hexadecen-1-yl acetate + SX, (Z) -11-hexadecen-1-ol + SX, (Z) -11-hexadecenal + SX, (Z) -11-hexadecen-1-yl acetate + SX, (Z) -11-octadecenal + SX, (Z) -13-octadecenal + SX, (Z) -hexad ec-13-en-11-yn-1-yl acetate + SX, (Z) -13-octadecenal + SX, (Z) -icos-13-en-10-one + SX, (Z) -7-tetradecenal + SX, (Z) -tetradec-9-en-1-ol + SX, (Z) -9-tetradecen-1-yl acetate + SX, (Z) -11-tetradecen-1-yl acetate + SX, ( Z) -13-icosen-10-one + SX, (Z, E) -7,11-hexadecadien-1-yl acetate + SX, (Z, E) -9,12-tetradecadien-1-yl acetate + SX , (E, Z) -4,10-tetradecadien-1-yl acetate + SX, (E, E) -8,10-dodecadien-1-ol + SX, (E, E) -10,12-hexadecadienal + SX, (E, E) -9,11-tetradecadien-1-yl acetate + SX, (E, Z) -2,13-octadecadien-1-ol + SX, (E, Z) -3,13-octadecadien -1-ol + SX, (E, Z) -2,13-octadecadien-1-yl acetate + SX, (E, Z) -3,13-octadecadien-1-yl acetate + SX, (E, Z) -7,9-dodecadien-1-yl acetate + SX, (E, E) -7,9-dodecadien-1-yl acetate + SX, (Z, E) -9,12-tetradecadien-1-yl acetate + SX, (Z, E) -9,11-tetradecadien-1-yl acetate + SX, (Z, E) -7,11-hexadecadien-1-yl acetate + SX, (Z, Z) -3,13- octadecadien-1-ol + SX, (Z, Z) -4,7-decadien-1-yl acetate + SX, (Z, Z) -3,13-octadecadien-1-yl acetate + SX, (Z, Z ) -7,11-hexadecadien-1-yl acetat e + SX, (Z, Z, E) -7,11,13-hexadecatrienal + SX, (5R) -5-[(1Z) -1-decen-1-yl] dihydro-2 (3H) -furanone + SX, (2R, 5R) -ethyl-1,6-dioxaspiro [4,4] nonane + SX, (2R, 5S) -ethyl-1,6-dioxaspiro [4,4] nonane + SX, (4R, 8R ) -4,8-dimethyldecanal + SX, (4R, 8S) -4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo [3,2,1] octane + SX, (-)-4-methyl-3-heptanol + SX, 1,7-dioxaspiro [5,5] undecane + SX, 3-carene + SX, 3-methylcyclohex-2-en-1-one + SX, 14- methyloctadec-1-ene + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 4- (3-oxobutyl) phenyl acetate + SX, dodecyl acetate + SX, dodeca-8,10 -dien-1-yl acetate + SX, ethyl (2E, 4Z) -decadienoate + SX, ethyl 4-methyloctanoate + SX, methyl 2,6,10-trimethyldodecanoate + SX, tetradecan-1-ol + SX, tetradec-11 -en-1-ol + SX, tetradec-11-en-1-yl acetate + SX, tridec-4-en-1-yl acetate + SX, (3S, 6R) -3-methyl-6-isopropenyl-9 -decen-1-yl acetate + SX, (3S, 6S) -3-methyl-6-isopropenyl-9-decen-1-yl acetate + SX, alpha-multistriatin + SX, alpha-pinene + SX, endo-brevicomin + SX, exo-brevicomin + SX, camphene + SX, codlelure + SX, Codlemone + SX, cuelure + SX, disparlure + SX, dominicalure + SX, eugenol + SX, farnesol + SX, ferrolure + SX, Frontalin + SX, Gossyplure + SX, Grandlure + SX, Grandlure I + SX, Grandlure II + SX, Grandlure III + SX, grandlure IV + SX, hexalure + SX, ipsdienol + SX, ipsenol + SX, japonilure + SX, lineatin + SX, little a (litlue) + SX, looplure + SX, medlur e) + SX, megatomoic acid + SX, methyl eugenol + SX, muscalure + SX, nerolidol + SX, orfralure + SX, oryctalure + SX, ostramone + SX, rhyncolure + SX, siglure + SX, sordidin + SX, sulcatol + SX, trimedure + SX, trimedure A + SX, Trimedlure B1 + SX, Trimedlure B2 + SX, Trimedlure C + SX, Trunk-call + SX, (E)-Verbenol ((E) -verbenol) + SX, (Z) -verbenol ((Z) -verbenol) + SX, trans-verbenol + SX, S-verbenone ((S) -verbenone) + SX.

The ratio of the compound of the present invention to this component is not particularly limited, but is 1000: 1 to 1: 1000, 500: 1 to 1: 500, 100: 1 in weight ratio (the compound of the present invention: this component). ~ 1: 100, 50: 1, 20: 1, 10: 1, 9: 1, 8: 1, 7: 1, 6: 1, 5: 1, 4: 1, 3: 1, 2: 1, 1 : 1, 1: 2, 1: 3, 1: 4, 1: 5, 1: 6, 1: 7, 1: 8, 1: 9, 1:10, 1:20, 1:50, etc. .

The compound of the present invention is effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful molluscs. Examples of harmful arthropods, harmful nematodes, and harmful molluscs include the following.

Hemiptera: Japanese green planthopper (Laodelphax striatellus), Japanese brown planthopper (Nilaparvata lugens), white-tailed planthopper (Sogatella furcifera), corn planter (Peregrinus maidis), yellow-spotted fish (Javesella pellucida), Perukinsiori Leafhopper (Delphacidae); Nephotettixepscincticeps, Nephotettix virescens, Nephotettix nigropictus, Recilia dorsalis, Eaca Corn leaf hopper (Dalbulus maidis), leafhopper (Cicadellidae) such as Cofanaofspectra; Mahanarva posticata, Mahanarva fimbriolata, etc. Bean aphids (Aphis fabae), soybean aphids (Aphis glycines), cotton aphids (Aphis gossypii), European apple aphids (Aphis pomi), snowy aphids (Aphis spiraecola), peach aphids (Myzus persicae), barley aphids helichrysi), radish aphids (Brevicoryne brassicae), Rosy apple aphid (Dysaphis plantaginea), black pea aphids (Lipaphis erysimi), tulip beetles (Macrosiphum euphorbiae), potato beetles Barley beetle (Rhopalosiphum padi), corn aphid (Rhopalosiphum maidis), citrus aphid (Toxoptera citricida), peach beetle (Hyalopterus pruni), baboon Aphididae such as scotch aphids (Melanaphis sacchari), black aphids (Tetraneura nigriabdominalis), peanut aphids (Ceratovacuna lanigera), Eriosoma lanigerum; ), Pecan leaf phylloxera (Phylloxera notabilis), Southern pecan leaf phylloxera (Phylloxera russellae), etc .; Aphidoxeridae; (Adelgidae); Rice beetle (Scotinophara lurida), Malayan rice black bug (Scotinophara coarctata), Blue-headed beetle (Nezara antennata), White-headed beetle (Eysarcoris aeneus), Japanese beetle E-is Larva stink bug (Eysarcoris ventralis), Murasakila stink bug (Eysarcoris annamita), Haremorpha halys, Southern stink bug (Nezara viridula), Brown stink bug (Euschistus heros) Melacanthus and other stink bugs (Pentatomidae); Burrower brown bug (Scaptocoris castanea) and other stink bugs (Cydnidae); Alydidae; Cletus punctiger, Leptoglossus australis, etc. (Coreidae); Caverelius saccharivorus, Ameri Lygaeidae, such as Blisssus leucopterus; Trigonotylus caelestialium, Stenotus rubrovittatus, L Streptomyces (Miridae); whitefly (Trialeurodes vaporariorum), tobacco whitefly (Bemisia tabaci), citrus whitefly (Dialeurodes citri), citrus whitefly (Aleurocanthus チャ spiniferus), chalet genius (Aleurocanthus spiniferus), Aleyrodidae, etc .; Blue-footed scale (Abgrallaspis cyanophylli), Red-footed scale (Aonidiella aurantii), Nymphalid scale (Diaspidiotus perniciosus), Blue-scale scale Pseudaulacaspis pentagona, Unaspis yanonensis, Nymphaensis scales (Unaspis citri), etc. (Diaspididae); Ruby beetles (Ceroplastes rubens), etc. ), Scotsidae (Margarodidae), such as Iceryachseychellarum; comstocki), PtereusococcusPlancitri, Pseudococcus ガ calceolariae, Pseudococcus longispinus, and turtleremy bugs such as Brevennia rehi (Pseudococcidae); Cigarette lice (Diaphorina citri), Cigarette lice (Trioza erytreae), Pepper lice (Cacopsylla pyrisuga), Cacosylla chinensis, potato Pteris cerica (Psyllidae); Platanus gumbai (Corythucha ciliata), Awadachisougunbai (Corythucha marmorata), Nashigunbui (Stephanitis nrio), Stephanitis pyrioides, etc. (Tingidae); ) Such as Giant Cicada (Quesada gigas); Cicadidae; Brazilian turtle (Triatoma infestans); Venezuelan turtle (Rhodonius prolixus) and other genus Reduviidae; Triatoma spp.).

Lepidoptera: Green moth (Chilo suppressalis), Darkheaded stem borer (Chilo polychrysus), White stem borer (Scirpophaga innotata), Itteno moth (Scirpophaga incertulas), Rupela albina cis martialis cis Casino maiga (Marasmia exigua), cotton moth (Notarcha derogata), yellow corn borer (Ostrinia furnacalis), European corn borer (Ostrinia nubilalis), yellow-tailed moth (Hellula undalis), Monkikuro moth terrel Caseworms (Nymphula depunctalis), Sugarcane borer (Diatraea saccharalis), etc. (Crambidae); Pyralidae, such as Cadra cautella; Spodoptera litura, Spodoptera exigua, Mythimna separata, Mamestra brassicae, pods (Naranga aenescens), Spodoptera frugiperda, African white scallop (Spodoptera exempta), Tamanayaga (Agrotis ギ ipsilon), Tamanaginobaia (Autographa nigrisigna), Inekin oyfest ix (Trichoplusia spp.), Heliothis ppvirscens, and other Heliotis genus (Heliothis spp.), Helicoverpa armigera, Helicoverpa zea, and other Helicobelpa genus (Helicoverpa spp.) , Velvetbean caterpillar (Anticarsia gemmatalis), Cotton leafworm (Alabama argillacea), Hop vine borer (Hydraecia immanis), etc. (Noctuidae); Diantha (Grapholita dimorpha), Leguminivora メ glycinivorella, Matsumuraeses azukivora, Adoxophyes orana fasciata, Adoxophyes nanima, Monakiki Archips fuscocupreanus), Cydia リン pomonella, Tetramoera schistaceana, Bean Shoot Borer (Epinotia aporema), Citrus fruit borer (Ecdytolopha aurantiana), etc. Grapillariidae such as Phyllonorycter 等 ringoniella; Carposinidae such as Carposina sasakii; Coffee Leaf miner (Leucoptera coffeella), Lyonetiapella Lymantiidae; Lymantriidae such as Lymantria dispar, Euproctis spp. Such as Euproctis spp. Lymantriidae; Plutellidae (Plutellidae); American mosquitoes (Anarsia lineatella), Japanese moth (Helcystogramma triannulella), Cotton moth (Pectinophora gossypiella), Potato moth (Phthorimaea operculella), American horridae (Cu) Hi Arctiidae; Castiidae such as Giant Sugarcane borer (Telchin licus); Boletinaceae such as Cossus insularis; Cossus insularis; Limacodidae, such as Parasa lepida; Staphymopodidae, such as Stahmopoda masinissa; Sphingidae, such as Acherontia lachesis; hector), Sesiidae such as Synanthedon tenuis; Parsaraceae (Parnara guttata); Hesperiidae; Tinea translucens; Tineola bisselliella

Thysanoptera: Citrus thrips (Frankliniella occidentalis), Thrips palmi, Scirtothrips dorsalis, Thrips Thripidae such as Echinothrips americanus; Thripidae such as Haplothrips aculeatus.

Diptera: Anthomyiidae such as Dela platura, Delia antiqua, Pegomya cunicularia; Udidiidae such as sugar beet root mygot Agromyza oryzae, tomato leaffly (Liriomyza sativae), beetle leaflet (Liriomyza trifolii), leafhopper (Chromatomyia horticola), etc. Bactrocera cucurbitae), citrus fruit fly (Bactrocera ナス dorsalis), nasal fly (Bactrocera ミ latifrons), olive fruit fly (Bactrocera oleae), quinceland fruit fly (Bactrocera tryoni), Ceratitis golet pomonella, Rhacochlaena japonica, etc. (Tephritidae); Hydrellia griseola, Hydrellia philippina, Hydrellia philippina, Hydrelliae ); Drosophila の suzukii and other Drosophilidae (Drosophilidae); Drosophilidae (Megaselia spiracularis) and other flies (Phoridae); difformis, etc. (Sciaridae); Hessian flies (Mayetiola destructor), Inseolia oryzae, etc., Cecidomyiidae; Diopsis macrophthalma, etc .; , Common cranefly (Tipula oleracea), European cranefly (Tipula paludosa), etc. (Tipulidae); Culex pipiens pallens; Acer moth (Culex pipiens pipiens), Alaska spider mosquito (Culex vishnui), Aedes albopictus, Aedes tiaegypti, Sophia swan (Anopheles sinensis), Gambie opheles ele Anopheles coluzzii, Anopheles albimanus, Anopheles sundaicus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus and other mosquitoes (Culicidae); Family (Simulidae); Abidae (Tabanus trigonus), etc. (Tabanidae); House fly (Musca Calliphoridae; Sarcophagidae; Chironomus plumosus, Chironomus yoshimatsui, Glyptotendipes tokunagai, etc. Chironomidae;

Coleoptera: Western corn root worm (Diabrotica virgifera virgifera), Southern corn root worm (Diabrotica undecimpunctata howardi), Northern corn root worm (Diabrotica barberi), Mexican corn root worm (Diabrotica virgifera zeae), Banded cub amber beetle balteata), Cucurbit Beetle (Diabrotica speciosa), Bean Leaf Beetle (Cerotoma trifurcata), Bark beetle beetle (Oulema melanopus), Root beetle (Aulacophora femoralis), Phyllotreta striolata a p flea beetle (Phyllotreta pusilla), Cabbage stem flea beetle (Psylliodes chrysocephala), Colorado beetle (Leptinotarsa decemlineata), rice beetle (Oulema oryzae), grape colaspis (Colaspis brunnea), Corn flare beetle (Chaetocnema pulicaria), sweet potato beetle (Chaetocnema confinis), potato flare beetle (Epitrix cucumeris), rice beetle (Dicladispa armigera), southern corn leaf beetle (Myochrousata dentistry) Chrysomelidae such as tobacco flea beetle (EpitrixEhirtipennis); Carabidae such as Seedcorn beetle (Stenolophus lecontei) and Slender 、 seedcorn beetle (Clivina impressifrons); AnomalaAcupru, Anomala (Anomala albopilosa), bean squirrel (Popilliaonicajaponica), nagachakogane (Heptophylla picea), European Chafer (Rhizotrogus majalis), black marsh (Tomarus gibbosus), Holotrichia genus (Holotrichia spp.), Pune crinita) etc. (Phyllophaga spp.), Diloboderus 等 abderus etc. Diloboderus genus (Diloboderus spp.), etc. postfasciatus, alfalfa weevil (Hypera postica), weevil (Sitophilus zeamais), weevil (Sitophilus oryzae), granary weevil (Sitophilus granarius), green weevil (Echinocnemus sormez worm) ), Cottontail weevil (Anthonomus grandis), Shibao Weevil (Sphenophorus venatus), Southern Corn Billbug (Sphenophorus callosus), Soybean stalk weevil (Sternechus subsignatus), Sugarcane weevil (Sphenophorus yo) Weevil (Scepticus griseus), flying white leopard weevil (Scepticus uniformis), Brazilian weevil (Zabrotes subfasciatus), pine beetle (Tomicus piniperda), Coffee Berry Borer (Hypothenemus hampeus) Weevilidae (Curculionidae) such as cotton root borer (Eutinobothrus ； brasiliensis); Epilachna vigintioctopunctata, etc., Coccinellidae; Lyctus brunneus, Rhizopertha dominica, etc., Bostrychidae; lophora malasiaca), Migdolus fryanus, etc. Cerambycidae; Genus (Conoderus spp.), Ktenicera spp., Limonius spp., Aeolus genus (Aeolus spp.), Etc. (Elateridae); Staphylinidae); Anthrenus verbasci, Dermestes maculates, Trogoderma granarium, etc. Dermestidae; (Anobida e); Laemophloeidae, such as Cryptolestes ferrigineus; Silvanidae, such as Oryzaephilus surinamensis.

Orthoptera: Moroccan grasshopper (Locusta migratoria), Moroccan grasshopper (Dociostaurus maroccanus), Australian flying grasshopper (Chortoicetes terminifera), Red-footed grasshopper (Nomadacris septemfasciata, Brown Locust (Locustana Pardal), Brown Locust (Locustana pardal) Locust (Calliptamus italicus), Differential grasshopper (Melanoplus differentialis), Two striped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-Legged grasshopper (Melanoula femurwing) ), Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris guttulosa), Cobainago (Oxya yezoensis), Species (Oxya japonica), Thai winged chinook (Patanga succincta) rid e); Ceratoaceae (Gryllotalpa orientalis), etc. (Gryllotalpidae); European crickets (Acheta domestica), crickets (Gryllidae), such as Teleogryllus emma;

Hymenoptera: Tenthedinidae, such as Athalia rosae, Athalia japonica; Tenthredinidae, Solenopsis geminata, and other genus Toppisari (Solenopsis geminata) leaf-cutting ant (Atta capiguara) and other species of genus Atta spp., genus Acromyrmex spp., scorpionary (Paraponera clavata), rugliari (Ochetellus glaber), common ants (Monomorium pileonis), Argentina ), Black ants (Formica fusca japonica), red ants (Pristomyrmex punctutus), giant ants (Pheidole noda), crested ants (Pheidole megacephala), black ants (Camponotus japonicus), red-tailed ants (Camponotus Shu (Pogonomyrmex occidentalis) Pogonomyrmex, Wasmania auropunctata, and other species (Wasmania), Anoplolepis gracilipes, and other antaceae (Formicidae); Giant hornet Vespa analis Fabriciusi), Vespa velutina, Polistes jokahamae and other hornets (Vespidae);

Cockroach (Blattodea): German cockroach (Blattellidae) such as Blattella germanica; Black cockroach (Periplaneta fuliginosa), Greater cockroach (Periplaneta americana), Greater cockroach (Periplaneta brunnea), ali (Blattidae); Yamato termite (Reticulitermes speratus), house termite (Coptotermes formosanus), American ant termite (Incisitermes コ minor), daiko termite (Cryptotermes domesticus), taiwan termite (Odontotermes N ant hunter) Glyptotermes satsumensis), Glyptotermes nakajimai, Caterpillars (Glyptotermes fuscus), Termites (Hodotermopsis sjostedti), Coptotermes guangzhouensis , Amami Termites (Reticulitermes amamianus), Miyatake Termites (Reticulitermes miyatakei), Camellia Termites (Reticulitermes kanmonensis), Takashi Termites (Nasutitermes ニ(Termitidae).

Fleas (Siphonaptera): Pulex genus such as human flea (Pulex irritans), Ctenocephalides genus such as cat flea (Ctenocephalides canis), Xenopsylla genus Xenopsyllaung such as Xenopsylla cheopis, Tunga genus, Echidnophaga genus such as chicken flea (Echidnophaga gallinacea), and Nosopsyllus genus such as European rat minnow (Nosopsyllus fasciatus).

Psocodae: genus Pediculus such as head lice (Pediculus humanus capitis); genus Phtirus such as pheasant lice (Pthirus pubis); Damalinia genus such as Damalinia bovis; Bovine white lice (Linognathus vituli), sheep trunk parasitic lice (Linognathus ovillus) genus Linognathus genus; Menopon genus; Trimenopon spp .; Trinoton spp .; Trichodectes genus such as dog lice (Trichodectes canis); Felicola genus such as cat lice (Felicola subrostratus); Men, such as the great wolf (Menacanthus stramineus) Acanthus; Werneckiella spp .; Lepikentron spp .; Liscelis subfuscas, Liposcelis bostrychophilus, Liposcelis simulans, Liposcelis simulans, Liposcelis Liposcelididae such as Liposcelis entomophila.

目 Thysanura: Lepismatidae such as Ctenoepisma villosa, Lepisma saccharina.

Acari: Nite spider mite (Tetranychus urticae), Kanzawa spider mite (Tetranychus kanzawai), honey spider mite (Tetranychus evansi), citrus spider mite (Panonychus citri), apple spider mite (Panonychus ulmi), Ony s genus (Opp. ); Citrus mite (Aculops pelekassi), Ryu citrus rust mite (Phyllocoptruta citri), tomato rust mite (Aculops lycopersici), green rust mite (Calacarus carinatus), green moth mite (Acaphylla therio physis), tick (Eca Aculus schlechtendali), Aceria カ diospyri, Aceria tosichella, Sheevtchenkella sp., Etc., Eriophyidae; (Tenuipalpidae) such as (Brevipalpus phoenicis); Tuckerellidae; Ixodidae, for example, Haemaphysalis longicornis, Haemaphysalis flavs, tick Haemaphys American dock ticks (Dermacentor variabilis), Dermacentor taiwanicus, Dermacentor andersoni, etc. , Ixodes pacificus, Ixodes holocyclus and other Ixodes genus, Amblyomma americanum, Amblyomma maculatum and other Amblyomma maculatum genus Tick (Rhipicephalus microplus), Boophilus genus Boophilus annulatus (Boophilus annulatus), Rhipicephalus sanguineus, Rhipicephalus ダニ tick (Rhipicephalus appendiculatus) TRhipicephalus 属 (Rhipicephalus appendiculatus) Acaridae, such as spinach, Tyrophagus similis; Dermatophagoides farinae, Dermatophagoides sinpteronyssinus, hey Clet, hey Cheyletus moorei), larvae (Cheyletiella yasguri), etc. (Cheyletidae); Argas persicus (Argas persicus), etc. Ornithodorus genus such as Ornithodorus turicata, Psoroptes ovis, Psoroptes genus Psoroptes cati), the genus Notoedres, such as the mud shrimp mite (Notoedres muris), the genus Sarcoptes, such as Sarcoptes scabiei, the genus Otodectes, such as the octodectes cynotis, and the genus Listrophorus girobus, etc. Hymenoptera (Chorioptes spp.), Hypodectes spp., Pterolichus spp., Cytodites ジ spp., Laminosioptes spp., Dermanyssus gallinae, etc. Torisashi Ornithonyssus sylviarum, Ornithonyssus bacoti, etc., Varroa jacobsoni, Varroa, Cattle ticks (Ornithocheyletia spp.), Inodex mite (Demodex canis), Feline mite (Demodex cati) and other Demodex genera, Myobia spp. (Trombicula pallida), Trombiculaascutellaris, etc.

Araneae: Eutrichuridae such as Cheracanthium japonicum; Theridiidae such as Latrodectus hasseltii.
Polydesmida: Paradoxosomatidae such as Oxidus gracilis and Nedyopus tambanus.
Isopoda: Armadillidiidae, such as Armadillidium vulgare.
Chiropoda: Scutigeridae, such as Thereuonema hilgendorfi; Scolopendridae, such as Scolopendra subspinipes;

Gastropoda: Limax marginatus, Limax flavus, and other scallops (Limacidae); Ampullariidae; Austropepleaeollula, etc.

Nematoda: Aphelenchoididae, such as Aphelenchoides besseyi; Pratylenchulus coffeae, Pratylenchus brachyurus, Pratilenchus simulis Pratylenenchidae (Pratylenchidae); Java root-knot nematode (Meloidogyne javanica); Heteroderidae such as Cyst nematode (Globodera pallida); Hoplolymidae (Hoplolaimidae) such as Rotilenchulus reniformis; Strawberry nematode (Nothotylenchus acris) Anguinidae such as Ditylenchus dipsaci; Tylenchulidae such as Tylenchulus semipenetrans; Longidoride such as Xiphinema index; Parasitaphelenchidae, such as pine wood nematode (Bursaphelenchus xylophilus);

The compounds of the present invention are harmful arthropods such as harmful insects, harmful mites, harmful molluscs, and the like that have reduced sensitivity to insecticides, acaricides, molluscicides and nematicides, or have developed resistance. It can also be used against harmful nematodes.

The compound of the present invention can also be used to protect plants from plant diseases caused by insect-borne viruses or insect-borne bacteria.

Examples of such insect-borne viruses include the following.

Rice tungro spherical virus, Rice tungro bacilliform virus, Rice grassy stunt virus, Rice ragged stunt virus, Rice stripe virus ( Rice stripe virus, Rice black streaked dwarf virus, Southern rice black-streaked dwarf virus, Rice gall dwarf virus, Rice hoja blanca virus), Rice yellow stunt virus, Rice yellow mottle virus, Rice dwarf virus, Northern cereal mosaic virus, Barley yellow dwarf virus , Barley mild mosaic virus, barley yellow dwarf virus-PAV, Formic acids Yellow Fusarium RPS virus (Cereal yellow dwarf virus-RPS), wheat yellow leaves virus (Wheat yellow leaf virus), Oat sterile dwarf virus, Wheat streak mosaic virus,
Maize dwarf mosaic virus, Maize stripe virus, Maize chlorotic mottle virus, Maize chlorotic dwarf virus, Maize rayado fino virus, sugar cane mosaic virus (Sugarcane mosaic virus), Fiji disease virus, Sugarcane yellow leaf virus, soybean fine Spotted mosaic virus, Cycas necrotic stunt virus, Soybean dwarf virus, Milk vetch dwarf virus, Soybean mosaic virus , Alfalfa mosaic virus, Bean yellow mosaic virus, Bean common mosaic virus, Southern bean mosaic virus, Peanut stunt virus ), Broad bean wilt virus 1 (Broad bean wilt virus 2), Broad bean necrosis virus, Broad bean yellow vein virus (Broad bean yellow vein virus) ), Clover yellow vein virus, Peanut mottle virus, Tobacco streak virus, Bean pod mottle virus, Cowpea chlorotic mottle virus, Mung bean yellow mosaic virus, Soybean crinkle leaf virus, tomato chlorosis virus, tomato spotted wilt virus, tomato yellow leaf curl virus, tomato aspermy virus, Tomato infectious chlorosis virus, Potato cigar virus (Potat o leafroll virus, Potato virus Y, Melon yellow spot virus, Melon necrotic spot virus, Watermelon mosaic virus, Cucumber mosaic Virus (Cucumber mosaic virus), Zucchini yellow mosaic virus, Turnip mosaic virus, Turnip yellow mosaic virus, Cauliflower mosaic virus, Lettuce mosaic Virus (Lettuce mosaic virus), Celery mosaic virus, Beet mosaic virus, Cucurbit chlorotic yellows virus, Capsicum chlorosis virus, Beet Pseudo Yellows virus ( Beet pseudo yellows virus, Leak yellow stripe virus, Onion yellow dwarf virus, Sweet potato feathery mottle virus, Sweet potato shukuyo mosaic virus), Strawberry mottle virus, Strawberry mild yellow edge virus, Strawberry pseudo mild yellow edge virus, Strawberry crinkle virus, Strawberry crinkle virus Strawberry vein banding virus, plum pox virus, chrysanthemum stem necrosis virus, impatiens necrotic spot virus, iris yellow virus (Iris) yellow spot virus) Lily mild mottle virus (Lily mottle virus), lily latent virus (Lilly symptomless virus), tulip mosaic virus (Tulip mosaic virus) and the like.

Examples of insect-borne bacteria include the following.

Rice yellow dwarf phytoplasma (Candidatus Phytoplasma oryzae), Candidatus Phytoplasma asteris, Maize bushy stunt phytoplasma, citrus greening fungus Asian type (Candidatus Liberbacter 病 asiaticus), citrus greening fungus African type (Candidatus cricket) Type (Candidatus Liberbacter americanus).

The harmful arthropod control composition of the present invention contains the compound or composition A of the present invention and an inert carrier. The arthropod pest control composition of the present invention is usually prepared by mixing the compound of the present invention or the composition A with an inert carrier such as a solid carrier, liquid carrier, gaseous carrier, etc. Emulsions, oils, powders, granules, wettable powders, granule wettable powders, flowables, dry flowables, microcapsules, aerosols, poison baits, resin preparations, shampoos It is formulated into paste preparations, foams, carbon dioxide preparations, tablets and the like. These preparations may be used after being processed into mosquito coils, electric mosquito mats, liquid mosquito traps, fumigants, fumigants, sheet preparations, spot-on agents, or oral treatments. The harmful arthropod control composition of the present invention usually contains 0.0001 to 95% by weight of the compound or composition A of the present invention.

Examples of solid carriers used for formulation include clays (kaolin clay, diatomaceous earth, bentonite, fusami clay, acidic clay), dry silica, wet silica, talc, ceramic, and other inorganic minerals (sericite, quartz, Sulfur, activated carbon, calcium carbonate, etc.), fine powders and granules of chemical fertilizers (ammonium sulfate, phosphoric acid, ammonium nitrate, urea, ammonium chloride, etc.), etc., and synthetic resins (polypropylene, polyacrylonitrile, polymethyl methacrylate, polyethylene terephthalate) Polyester resins such as nylon-6, nylon-11, nylon-66, polyamide resin, polyvinyl chloride, polyvinylidene chloride, vinyl chloride-propylene copolymer, etc.).

Examples of the liquid carrier include water, alcohols (methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, propylene glycol, phenoxyethanol, etc.), ketones (acetone, methyl ethyl ketone, cyclohexanone, etc.), aromatic hydrocarbons (Toluene, xylene, ethylbenzene, dodecylbenzene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, kerosene, light oil, etc.), esters (ethyl acetate, butyl acetate, isopropyl myristate, Ethyl oleate, diisopropyl adipate, diisobutyl adipate, propylene glycol monomethyl ether acetate, etc.), nitriles (acetonitrile, isobutyrate) Nitriles), ethers (diisopropyl ether, 1,4-dioxane, 1,2-dimethoxyethane, diethylene glycol dimethyl ether, diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, 3-methoxy-3-methyl-1 -Butanol, etc.), amides (N, N-dimethylformamide (hereinafter referred to as DMF), N, N-dimethylacetamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), propylene carbonate and vegetable oils (soybean oil, cottonseed oil, etc.) Is mentioned.

Examples of the gaseous carrier include fluorocarbon, butane gas, LPG (liquefied petroleum gas), dimethyl ether, and carbon dioxide gas.

Examples of the surfactant include nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, and polyethylene glycol fatty acid ester, and anions such as alkyl sulfonate, alkyl benzene sulfonate, and alkyl sulfate. Surfactant is mentioned.

Examples of other adjuvants for preparation include fixing agents, dispersants, colorants and stabilizers, such as casein, gelatin, saccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, Synthetic water-soluble polymers (polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids, etc.), acidic isopropyl phosphate, 2,6-di-tert-butyl-4-methylphenol, BHA (2-tert-butyl-4-methoxyphenol) And a mixture of 3-tert-butyl-4-methoxyphenol).

Examples of the base material of the resin preparation include vinyl chloride polymers, polyurethanes, etc., and these base materials include phthalic acid esters (dimethyl phthalate, dioctyl phthalate, etc.), adipic acid esters as necessary. Further, a plasticizer such as stearic acid may be added. The resin formulation is obtained by kneading the compound in the base material using a normal kneading apparatus, and then molding by injection molding, extrusion molding, press molding, etc., and if necessary, through further steps such as molding, cutting, It can be processed into resin preparations such as plates, films, tapes, nets, and strings. These resin preparations are processed, for example, as animal collars, animal ear tags, sheet preparations, attracting strings, or gardening supports.
Examples of the base material of the poison bait include cereal flour, vegetable oil, sugar, crystalline cellulose and the like, and further, if necessary, preservation of antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, dehydroacetic acid and the like Ingredients, anti-fouling preventives for children and pets such as pepper powder, cheese flavoring, onion flavoring, pest-attracting flavoring such as peanut oil, and the like are added.

The method for controlling harmful arthropods according to the present invention comprises an effective amount of the compound or composition A of the present invention directly on the harmful arthropods and / or habitats of harmful arthropods (plants, soil, households, animals). Etc.). It can also be processed into seeds. Examples of the method for controlling harmful arthropods of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, smoke treatment, water surface treatment and seed treatment.

In the present invention, examples of plants include whole plants, foliage, flowers, ears, fruits, trunks, branches, crowns, seeds, vegetative organs and seedlings.

Nutritional reproductive organ means plant roots, stems, leaves, etc. that have the ability to grow when their parts are separated from the body and placed in the soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms or solid bulbs, tubers, rhizomes, and stolons. , Rhizophore, cane-cuttings, propagule and vine-cutting. In addition, a toothpick is sometimes called a runner, and a basket is also called a pearl bud, and is divided into a granule (broad bud) and a scale bud (bulbil). The vine means shoots (a general term for leaves and stems, shoot) such as sweet potatoes and yams. A bulb, a bulb, a tuber, a rhizome, a stem fragment, a root bearing body or a tuberous root is collectively called a bulb. Potato cultivation begins with planting tubers in the soil, but the tubers used are commonly referred to as seed pods.

The seed or vegetative reproductive organ holding the present compound or composition A in the present invention means a state where the present compound or composition A is attached to the surface of the seed or vegetative reproductive organ. . Moreover, this invention compound or composition A adhering to the surface may osmose | permeate the inside from the surface.
When composition A is attached to the surface of seeds or vegetative organs, a plurality of single active ingredient layers may be overlapped, or a single layer in which a plurality of active ingredients are mixed is formed. Alternatively, a single active ingredient layer and a plurality of active ingredient layers may overlap, or a plurality of active ingredient layers may overlap.
The seed or vegetative organ used for seed treatment may be used as it is, and materials other than the present compound or composition A may be attached before and after the present compound or composition A is treated. .

Examples of the seed treatment include a method in which a suspension of the compound or composition A of the present invention is atomized and sprayed on the seed surface or the surface of the vegetative reproductive organ, and the compound or composition A of the present invention is applied to the seed or the vegetative reproductive organ. A method of immersing seeds or vegetative reproductive organs in a solution of the compound or composition A of the present invention for a certain period of time, coating seeds or vegetative reproductive organs with a carrier (film, pellet, etc.) containing the compound or composition A of the present invention The method of doing is mentioned.

When the harmful arthropod control composition of the present invention is used for pest control in the agricultural field, the application amount is usually 1 to 10,000 g as the amount of the compound of the present invention per 10,000 m ² . When treating seeds, the amount of the compound of the present invention is usually applied in the range of 0.001 to 100 g per 1 kg of seeds. When the harmful arthropod control composition of the present invention is formulated into an emulsion, a wettable powder, a flowable agent, etc., it is usually applied after diluting with water so that the active ingredient concentration is 0.01 to 10,000 ppm. The granules, powders, etc. are usually applied as they are.

These preparations and water dilutions of these preparations may be sprayed directly onto harmful arthropods or plants such as crops to be protected from harmful arthropods, and also control pests that inhabit cultivated soil Therefore, the soil may be treated.

Also, it can be treated by methods such as wrapping a resin preparation processed into a sheet or string around the crop, stretching it around the crop, or laying it on the stock soil.

When the harmful arthropod control composition of the present invention is used for controlling pests inhabiting in a house, the application amount is the amount of the compound of the present invention per 1 m ² of treatment area when treated on the surface. The amount of the compound of the present invention per 1 m ³ of treatment space is usually 0.001 to 500 mg when treated in a space. When the harmful arthropod control composition of the present invention is formulated into an emulsion, a wettable powder, a flowable, etc., it is usually diluted with water so that the active ingredient concentration is 0.01 to 10,000 ppm. Apply oil, aerosol, smoke, poison bait, etc. as they are.

When the harmful arthropod control composition of the present invention is used for controlling ectoparasites of domestic animals such as cattle, horses, pigs, sheep, goats and chickens, and small animals such as dogs, cats, rats and mice, veterinary It can be used for animals by known methods. As a specific method of use, for the purpose of systemic suppression, for example, administration by tablet, feed mixing, suppository, injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) is intended for non-systemic suppression. In this case, for example, an oil agent or an aqueous liquid is sprayed, a pour-on treatment or a spot-on treatment is performed, the animal is washed with a shampoo preparation, or a resin preparation is attached to the animal with a collar or ear tag. When administered to animals, the amount of the compound of the present invention is usually in the range of 0.1 to 1000 mg per kg of animal body weight.

Further, the compound or composition A of the present invention can be used as a control agent for harmful arthropods in agricultural land such as fields, paddy fields, lawns, orchards. The compound of the present invention can control harmful arthropods such as cultivated land in cultivated lands where the following plants are cultivated.

Corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugar cane, tobacco, solanaceous vegetables (eggplant, tomato, pepper, capsicum, potato), cucurbitaceae Vegetables (cucumber, pumpkin, zucchini, watermelon, melon, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard, broccoli, cauliflower, etc.), asteraceae vegetables (burdock, sangiku, artichoke, lettuce) ), Liliaceae vegetables (leek, onion, garlic, asparagus, etc.), celery family vegetables (carrot, parsley, celery, red burdock, etc.), red crustacean vegetables (spinach, chard, etc.), perilla (vegetables, mint) , Basil, etc.), strawberry Sweet potato, wild yam, taro, pears (apple, pear, Japanese pear, quince, quince, etc.), nuclear fruit (peach, plum, nectarine, ume, sweet cherry, apricot, prunes, etc.), citrus (Satsuma mandarin, orange, lemon) , Lime, grapefruit, etc.), nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, Banana, coffee, date palm, coconut palm, tea, mulberry, ornamental plant, forest plant, fern, pasture, etc.

The above plants include plants that can be produced by natural mating, plants that can be generated by mutation, F1 hybrid plants, and genetically modified crops. Examples of genetically modified crops include HPPD (4-hydroxyphenylpyruvate dioxygenase enzyme) inhibitors such as isoxaflutole, ALS (acetolactic acid synthase) inhibitors such as imazetapyr and thifensulfuron methyl, EPSP (5 -Plants that have been given tolerance to herbicides such as enolpyruvylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, bromoxynil, or dicamba Plants capable of synthesizing selective toxins known in the genus Bacillus such as Bacillus thuringiensis; gene fragments that partially match endogenous genes derived from harmful insects, etc. It is synthesized by inducing gene silencing (RNAi) in the target harmful insect body. Plants that can impart an unusual insecticidal activity can be mentioned.

Hereinafter, the present invention will be described in more detail with reference to production examples, formulation examples, test examples, and the like, but the present invention is not limited only to these examples.

4,5-dichloro-6-ethylpyrimidine, cis-4-methylcyclohexane-1-amine and cis-4-ethylcyclohexane-1-amine are commercially available compounds.

Production Example 1
Under a nitrogen atmosphere, 0.43 g of cis-4-methylcyclohexane-1-amine and 0.53 g of potassium carbonate were sequentially added to a mixture of 0.45 g of 4,5-dichloro-6-ethylpyrimidine and 10 mL of DMF. The resulting mixture was stirred at 100 ° C. for 4 hours. Water was added to the resulting mixture and extracted with methyl tert-butyl ether. The obtained organic layer was dried over magnesium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography (hexane: ethyl acetate = 80: 20) to obtain 0.62 g of the present compound 1 represented by the following formula.

Compound of the present invention 1: ¹ H-NMR (CDCl ₃ ) δ: 8.41 (1H, s), 5.57-5.46 (1H, m), 4.27-4.19 (1H, m), 2.78 (2H, q, J = 7.6 Hz ), 1.84-1.53 (7H, m), 1.31-1.15 (5H, m), 0.97 (3H, d, J = 6.8 Hz).

Production Example 2
Under a nitrogen atmosphere, 1.01 g of cis-4-ethylcyclohexane-1-amine and 1.10 g of potassium carbonate were sequentially added to a mixture of 0.94 g of 4,5-dichloro-6-ethylpyrimidine and 20 mL of DMF. The resulting mixture was stirred at 100 ° C. for 3 hours. Water was added to the resulting mixture and extracted with methyl tert-butyl ether. The obtained organic layer was dried over magnesium sulfate and concentrated under reduced pressure. The obtained residue was subjected to silica gel column chromatography (hexane: ethyl acetate = 80: 20) to obtain 1.07 g of the present compound 2 represented by the following formula.

Compound 2 of the present invention: ¹ H-NMR (CDCl ₃ ) δ: 8.41 (1H, s), 5.58-5.45 (1H, m), 4.29-4.20 (1H, m), 2.78 (2H, q, J = 7.6 Hz ), 1.87-1.63 (6H, m), 1.38-1.15 (8H, m), 0.91 (3H, d, J = 7.2 Hz).

Next, formulation examples of the compound of the present invention are shown. In addition, a part represents a weight part.

Formulation Example 1
10 parts of any one of the compounds SX of the present invention are mixed with a mixture of 35 parts of xylene and 35 parts of DMF, and 14 parts of polyoxyethylene styryl phenyl ether and 6 parts of calcium dodecylbenzenesulfonate are added and mixed. A formulation is obtained.

Formulation Example 2
4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of wet silica and 54 parts of diatomaceous earth are mixed, and 20 parts of any one of the compounds SX of the present invention are added and mixed to obtain a preparation.

Formulation Example 3
1 part of wet silica, 2 parts of calcium lignin sulfonate, 30 parts of bentonite and 65 parts of kaolin clay are mixed with 2 parts of any one of the compounds SX of the present invention. Next, an appropriate amount of water is added to the mixture, and the mixture is further stirred, granulated with a granulator, and dried by ventilation to obtain a preparation.

Formulation Example 4
1 part of any one of the compounds SX of the present invention is mixed with an appropriate amount of acetone, and 5 parts of wet silica, 0.3 part of isopropyl acid phosphate and 93.7 parts of kaolin clay are added, and the mixture is sufficiently stirred and mixed. Acetone is removed by evaporation to obtain a preparation.

Formulation Example 5
35 parts of a mixture of polyoxyethylene alkyl ether sulfate ammonium salt and wet silica (weight ratio 1: 1), 20 parts of any one of the compounds SX of the present invention, and 45 parts of water are sufficiently mixed to obtain a preparation. .

Formulation Example 6
0.1 part of any one of the compounds SX of the present invention is mixed with a mixture of 5 parts of xylene and 5 parts of trichloroethane, and this is mixed with 89.9 parts of kerosene to obtain a preparation.

Formulation Example 7
10 mg of any one of the compounds SX of the present invention is mixed with 0.5 mL of acetone, and this solution is added dropwise to 5 g of animal solid feed powder (bred breeding solid feed powder CE-2, Nippon Claire Co., Ltd.), Mix evenly. The acetone is then evaporated to dryness to obtain a poisonous bait.

Formulation Example 8
0.1 part of any one of the compounds SX of the present invention and 49.9 parts of neothiozole (manufactured by Chuo Kasei Co., Ltd.) are placed in an aerosol can, and after mounting an aerosol valve, 25 parts of dimethyl ether and 25 parts of LPG are filled and shaken. And an oil aerosol is obtained by mounting the actuator.

Formulation Example 9
0.6 part of any one of the compounds SX of the present invention, 0.01 part of 2,6-di-tert-butyl-4-methylphenol, 5 parts of xylene, 3.39 parts of kerosene and 1 part of rhodol (registered trademark) ) A mixture of MO-60 and 50 parts of distilled water are filled into an aerosol container, a valve is attached, and then 40 parts of LPG is filled through the valve to obtain an aqueous aerosol.

Formulation Example 10
0.1 g of any one of the compounds SX of the present invention is mixed with 2 mL of propylene glycol and impregnated into a ceramic plate having a size of 4.0 cm × 4.0 cm and a thickness of 1.2 cm to obtain a heating smoke.

Formulation Example 11
5 parts of any one of the compounds SX of the present invention and 95 parts of an ethylene-methyl methacrylate copolymer (ratio of methyl methacrylate to the total weight of the copolymer: 10% by weight) are melt-kneaded, and the resulting kneading The product is extruded from an extrusion molding machine to obtain a rod-shaped molded body having a length of 15 cm and a diameter of 3 mm.

Formulation Example 12
5 parts of any one of the compounds SX of the present invention and 95 parts of a soft vinyl chloride resin are melt-kneaded, and the obtained kneaded product is extruded from an extrusion molding machine to obtain a rod-shaped molded body having a length of 15 cm and a diameter of 3 mm.

Formulation Example 13
100 mg of any one of the compounds SX of the present invention, 68.75 mg of lactose, 237.5 mg of corn starch, 43.75 mg of microcrystalline cellulose, 18.75 mg of polyvinylpyrrolidone, 28.75 mg of sodium carboxymethyl starch, and magnesium stearate 2. 5 mg is mixed and the resulting mixture is compressed to an appropriate size to obtain tablets.

Formulation Example 14
One of the compounds SX of the present invention, 25 mg, lactose 60 mg, corn starch 25 mg, carmellose calcium 6 mg, and 5% hydroxypropylmethylcellulose are mixed in an appropriate amount, and the resulting mixture is filled into a hard shell gelatin capsule or hydroxypropylmethylcellulose capsule And a capsule is obtained.

Formulation Example 15
Any one of the present compounds SX 100 mg, fumaric acid 500 mg, sodium chloride 2000 mg, methylparaben 150 mg, propylparaben 50 mg, granule sugar 25000 mg, sorbitol (70% solution) 13000 mg, Veegum (registered trademark) K100 mg, flavor 35 mg, and coloring Distilled water is added to 500 mg of the preparation so that the final volume becomes 100 mL, and mixed to obtain a suspension for oral administration.

Formulation Example 16
5 parts of any one of the compounds SX of the present invention are mixed with 5 parts of an emulsifier, 3 parts of benzyl alcohol, and 30 parts of propylene glycol, and the phosphate is adjusted so that the pH of this solution is 6.0 to 6.5. After adding a buffer solution, water is added as the balance to obtain a solution for oral administration.

Formulation Example 17
5 parts of aluminum distearate is added to 57 parts of fractionated coconut oil and 3 parts of polysorbate 85 and dispersed by heating. This is cooled to room temperature and 25 parts of saccharin is dispersed in the oily vehicle. To this, 10 parts of any one of the compounds SX of the present invention are allocated to obtain a paste preparation for oral administration.

Formulation Example 18
5 parts of any one of the compounds SX of the present invention are mixed with 95 parts of limestone powder to obtain granules for oral administration using a wet granulation method.

Formulation Example 19
5 parts of any one of the compounds SX of the present invention are mixed with 80 parts of diethylene glycol monoethyl ether, and 15 parts of propylene carbonate is mixed therewith to obtain a spot-on solution.

Formulation Example 20
10 parts of any one of the compounds SX of the present invention are mixed with 70 parts of diethylene glycol monoethyl ether, and 20 parts of 2-octyldodecanol is mixed with this to obtain a pour-on solution.

Formulation Example 21
0.1 part of any one of the compounds SX of the present invention, 40 parts of sodium polyoxyethylene lauryl ether sulfate (25% aqueous solution), 5 parts of amidopropyl betaine laurate, 5 parts of coconut oil fatty acid ethanolamide, carboxyvinyl polymer Add 5 parts and 49.4 parts of purified water and mix well to obtain a shampoo.

Formulation Example 22
0.15 part of any one of the compounds SX of the present invention, 95 parts of animal feed, and 4.85 parts of a mixture comprising calcium hydrogen phosphate, diatomaceous earth, Aerosil (registered trademark), and carbonate (or chalk) are sufficiently stirred. Mix to obtain animal feed premix.

Formulation Example 23
7.2 g of any one of the compounds SX of the present invention and 92.8 g of Phosco® S-55 are mixed at 100 ° C., poured into a suppository form, cooled and solidified to obtain a suppository.

Next, the efficacy of the compound of the present invention against harmful arthropods is shown by test examples. In the following test examples, the test was performed at 25 ° C.

Test method 1
A test compound is prepared in accordance with the method described in Formulation Example 5, and water containing 0.03% by volume of Cyndine (registered trademark) is added thereto to prepare a diluted solution containing the test compound at a predetermined concentration.
Approximately 30 cotton aphids (all stages) are inoculated into Cucuis sativus seedlings (second true leaf development stage) planted in a container. After 1 day, the diluted solution is sprayed on the seedlings at a rate of 10 mL / seedling. After 5 days, the number of live insects is examined, and the control value is obtained by the following formula.
Control value (%) = {1− (Cb × Tai) / (Cai × Tb)} × 100
In addition, the character in a formula represents the following meaning.
Cb: Number of test insects in the untreated group Cai: Number of live insects at the time of survey in the untreated group Tb: Number of test insects in the treated group Tai: Number of live insects at the time of survey in the treated group It means a group that operates in the same manner as the treatment group except that the test compound is not used.

Test Example 1-1
As a result of testing according to Test Method 1 using the following present compound as a test compound at a predetermined concentration of 500 ppm, all of the following present compounds exhibited a control value of 90% or more.
Compounds of the present invention: 1 and 2

Test Example 1-2
As a result of performing the test according to Test Method 1 using the following present compound as a test compound at a predetermined concentration of 200 ppm, all of the following present compounds exhibited a control value of 90% or more.
Compounds of the present invention: 1 and 2

Test method 2
A test compound is prepared in accordance with the method described in Formulation Example 5, and water containing 0.03% by volume of Cyndine (registered trademark) is added thereto to prepare a diluted solution containing the test compound at a predetermined concentration.
The diluted solution is sprayed onto a cabbage (Brassicae oleracea) seedling (second to third leaf development stage) planted in a container at a rate of 20 mL / seedling. Thereafter, the stems and leaves of this seedling are cut out and placed in a container with filter paper. Release 5 5th-instar larvae of Spodoptera litura. Five days later, the number of live insects is counted, and the death rate is obtained from the following formula.
Death rate% = (1−Number of surviving insects / 5) × 100

Test example 2
As a result of testing according to Test Method 2 using the following present compound as a test compound at a predetermined concentration of 500 ppm, the following present compound showed a mortality rate of 100%.
Compound of the present invention: 2

Test method 3
A test compound is prepared in accordance with the method described in Formulation Example 5, and water containing 0.03% by volume of Cyndine (registered trademark) is added thereto to prepare a diluted solution containing the test compound at a predetermined concentration.
The diluted solution is sprayed at a rate of 20 mL / seedling onto cabbage seedlings planted in the container (second to third true leaf development stage). Thereafter, the stems and leaves of this seedling are cut out and placed in a container with filter paper. Release 5 5th instar larvae. Five days later, the number of live insects is counted, and the death rate is obtained from the following formula.
Death rate% = (1−Number of surviving insects / 5) × 100

Test example 3
As a result of testing according to Test Method 3 using the following present compound as a test compound at a predetermined concentration of 500 ppm, all of the following present compounds showed a mortality rate of 80% or more.
Compounds of the present invention: 1 and 2

Test method 4
A test compound is prepared in accordance with the method described in Formulation Example 5, and water containing 0.03% by volume of Cyndine (registered trademark) is added thereto to prepare a diluted solution containing the test compound at a predetermined concentration.
The diluted solution is sprayed at a rate of 10 mL / seedling on rice (Oryza sativa) seedlings (second leaf development stage) planted in a container. Then, 20 3rd instar larvae are released. After 6 days, the number of surviving insects is examined, and the death rate is obtained by the following formula.
Death rate (%) = {1−number of surviving insects / 20} × 100

Test example 4
As a result of testing according to Test Method 4 using the following present compound as a test compound at a predetermined concentration of 500 ppm, all of the following present compounds showed a mortality rate of 90% or more.
Compounds of the present invention: 1 and 2

Test method 5
A test compound is prepared in accordance with the method described in Formulation Example 5, and water containing 0.03% by volume of Cyndine (registered trademark) is added thereto to prepare a diluted solution containing the test compound at a predetermined concentration.
Tomato (Lycopersicon esculentum) seedlings planted in a container are allowed to lay eggs for about 24 hours by releasing adult tobacco whitefly. This seedling is stored for 8 days, and the larvae are hatched from the delivered eggs. The diluted solution is sprayed on the seedlings at a rate of 10 mL / seedling. After 7 days, the number of surviving insects is examined, and the control value is obtained by the following formula.
Control value (%) = {1− (Cb × Tai) / (Cai × Tb)} × 100
In addition, the character in a formula represents the following meaning.
Cb: number of insects immediately before treatment in the untreated group Cai: number of live insects at the time of investigation in the untreated group Tb: number of insects just before the treatment in the treated group Tai: number of live insects at the time of investigation in the treated group Means a group that performs the same operation as the treatment group except that the test compound is not used.

Test Example 5
As a result of conducting the test according to Test Method 5 using the following present compound as a test compound at a predetermined concentration of 500 ppm, all of the following present compounds showed a control value of 90% or more.
Compounds of the present invention: 1 and 2

Test method 6
A test compound is prepared in accordance with the method described in Formulation Example 5, and water containing 0.03% by volume of Cyndine (registered trademark) is added thereto to prepare a diluted solution containing the test compound at a predetermined concentration.
The diluted solution is sprayed on the cucumber seedling planted in the container (second leaf development stage) at a rate of 10 mL / seedling. Thereafter, the first true leaf is cut out and accommodated in a container, to which about 20 larvae of Citrus thrips are released. After 7 days, the number of surviving insects is examined, and the death rate is obtained by the following formula.
Death rate (%) = {1−number of surviving insects / 20} × 100

Test Example 6
As a result of testing according to Test Method 6 using the following present compound as a test compound at a predetermined concentration of 500 ppm, all of the following present compounds showed a mortality rate of 90% or more.
Compounds of the present invention: 1 and 2

Test method 7
A test compound is prepared in accordance with the method described in Formulation Example 5, and water containing 0.03% by volume of Cyndine (registered trademark) is added thereto to prepare a diluted solution containing the test compound at a predetermined concentration.
About 40 adult spider mites are released on kidney bean (Phaseolus vulgaris) seedlings (first true leaf development stage) planted in a container. After 1 day, the diluted solution is sprayed on the seedlings at a rate of 10 mL / seedling. After 7 days, the number of live insects is examined, and the control value is calculated by the following formula.
Control value (%) = {1− (Cb × Tai) / (Cai × Tb)} × 100
In addition, the character in a formula represents the following meaning.
Cb: Number of test insects in the untreated group Cai: Number of live insects at the time of survey in the untreated group Tb: Number of test insects in the treated group Tai: Number of live insects at the time of survey in the treated group It means a group that operates in the same manner as the treatment group except that the test compound is not used.

Test Example 7
As a result of conducting a test according to Test Method 7 using the following present compound as a test compound at a predetermined concentration of 500 ppm, the following present compound showed a control value of 90% or more.
Compound of the present invention: 2

Test method 8
A test compound is prepared according to the method described in Formulation Example 5, water is added thereto, and a diluted solution containing the test compound at a predetermined concentration is prepared.
30 larvae of Culex pipiens larvae are released into the diluted solution, and after 1 day, the life and death are examined to determine the mortality. The death rate is calculated by the following formula.
Death rate (%) = (Number of dead insects / number of test insects) × 100

Test Example 8
As a result of testing according to Test Method 8 using the following present compound as a test compound at a predetermined concentration of 3.5 ppm, all of the following present compounds showed a mortality rate of 91% or more.
Compounds of the present invention: 1 and 2

Test method 9
A test compound is prepared according to the method described in Formulation Example 5, water is added thereto, and a diluted solution containing the test compound at a predetermined concentration is prepared. The predetermined concentration is either 500 ppm, 125 ppm, 31 ppm or 7.8 ppm.
A filter paper of the same size is laid on the inner bottom of a 5.5 cm diameter cup, and 0.7 mL of the diluted solution is dropped on the filter paper, and 30 mg of sucrose is uniformly added to the cup as food. Release 10 adult houseflies into the cup and cap. After 24 hours, the life of the house fly is examined to determine the death rate. The death rate is calculated by the following formula.
Death rate (%) = (Number of dead insects / number of test insects) × 100

Test Example 9
As a result of testing according to Test Method 9 using the following present compound as a test compound at a predetermined concentration of 500 ppm, all of the following present compounds showed a mortality rate of 80% or more.
Compounds of the present invention: 1 and 2

Test method 10
A test compound is prepared according to the method described in Formulation Example 5, water is added thereto, and a diluted solution containing the test compound at a predetermined concentration is prepared. The predetermined concentration is either 500 ppm, 125 ppm, 31 ppm or 7.8 ppm.
A filter paper of the same size is laid on the inner bottom of a 5.5 cm diameter cup, and 0.7 mL of the diluted solution is dropped on the filter paper, and 30 mg of sucrose is uniformly added to the cup as food. Release 2 adult German cockroaches into the cup and cap. Six days later, the survival and death of German cockroaches are investigated, the number of dead insects is counted, and the death rate is obtained by the following formula.
Death rate (%) = (Number of dead insects / number of test insects) × 100

Test Example 10
As a result of testing according to Test Method 10 using the following present compound as a test compound at a predetermined concentration of 500 ppm, all of the following present compounds showed a mortality rate of 100%.
Compounds of the present invention: 1 and 2

Test method 11
An acetone solution prepared so that the test compound is 200 ppm is poured into a container having an internal volume of 20 mL, and the inner surface of the container is uniformly coated so that the test compound has a predetermined concentration, and then dried. Predetermined concentration ^{10mg / m 2, 2.5mg / m} 2, 0.63mg / m 2, 0.16mg / m 2, is either 0.039mg / m ² or 0.0098mg / m ^2.
Place 5 adult female mosquitoes in the container and close the lid. One hour later, the sum of the number of knockdown insects and the number of dead insects (the number of dead insects) is investigated, and the percentage of the dead insects is determined by the following formula.
The percentage of moribund insects (%) = (number of moribund insects / number of test insects) x 100

Test Example 11
As a result of performing the test according to Test Method 11 using the following present compound as a test compound at a predetermined concentration of 10 mg / m ² , all of the following present compounds showed a mortality rate of 80% or more.
Compounds of the present invention: 1 and 2

Test method 12
An acetone solution prepared so that the test compound is 200 ppm is poured into a container having an internal volume of 20 mL, and the inner surface of the container is uniformly coated so that the test compound has a predetermined concentration, and then dried. Predetermined concentration ^{10mg / m 2, 2.5mg / m} 2, 0.63mg / m 2, 0.16mg / m 2, is either 0.039mg / m ² or 0.0098mg / m ^2.
Place 5 adult female mosquitoes in the container and close the lid. One day later, the total of the number of knockdown insects and the number of dead insects (the number of dead insects) is investigated, and the percentage of the dead insects is obtained by the following formula.
The percentage of moribund insects (%) = (number of moribund insects / number of test insects) x 100

Test Example 12
As a result of conducting the test according to Test Method 12 using the following present compound as a test compound at a predetermined concentration of 10 mg / m ² , all of the following present compounds showed a mortality rate of 80% or more.
Compounds of the present invention: 1 and 2

The compound of the present invention exhibits an excellent control effect against harmful arthropods.

Claims

Formula (I)

[Wherein, R represents a methyl group or an ethyl group. ]
A compound represented by
A harmful arthropod control composition comprising the compound according to claim 1 and an inert carrier.
A method for controlling harmful arthropods, which comprises applying an effective amount of the compound according to claim 1 to harmful arthropods or habitats of harmful arthropods.
A composition comprising one or more components selected from the group consisting of group (a) and group (b), and the compound according to claim 1:
Group (a): a group consisting of an insecticidal active ingredient, an acaricidal active ingredient and a nematicidal active ingredient;
Group (b): bactericidal active ingredient.
A method for controlling harmful arthropods, which comprises applying an effective amount of the composition according to claim 4 to harmful arthropods or habitats of harmful arthropods.
A seed or vegetative organ holding an effective amount of the compound according to claim 1 or an effective amount of the composition according to claim 4.