WO2019184731A1 - Method for controlling structure of solidified cast ingot in continuous casting process and control device thereof - Google Patents

Method for controlling structure of solidified cast ingot in continuous casting process and control device thereof Download PDF

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Publication number
WO2019184731A1
WO2019184731A1 PCT/CN2019/078326 CN2019078326W WO2019184731A1 WO 2019184731 A1 WO2019184731 A1 WO 2019184731A1 CN 2019078326 W CN2019078326 W CN 2019078326W WO 2019184731 A1 WO2019184731 A1 WO 2019184731A1
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Prior art keywords
cooling
heating
cooling zone
slab
continuous casting
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PCT/CN2019/078326
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French (fr)
Chinese (zh)
Inventor
乌力平
沈昶
孙彪
汪国才
陆强
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马鞍山钢铁股份有限公司
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Priority to JP2020550144A priority Critical patent/JP7111828B2/en
Priority to EP19777614.9A priority patent/EP3750649A4/en
Publication of WO2019184731A1 publication Critical patent/WO2019184731A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/124Accessories for subsequent treating or working cast stock in situ for cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/22Controlling or regulating processes or operations for cooling cast stock or mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/22Controlling or regulating processes or operations for cooling cast stock or mould
    • B22D11/225Controlling or regulating processes or operations for cooling cast stock or mould for secondary cooling

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  • the invention relates to the technical field of metallurgical continuous casting, and more particularly to a method for controlling the solidification structure of a slab during continuous casting and a control device thereof.
  • the molten steel in the liquid phase is separated by the “solidified crystal bridge”.
  • the molten steel in the lower part of the crystal bridge cannot be replenished by the upper metal to form loose or shrinkage holes, accompanied by central segregation and uneven composition. And other related issues.
  • low-temperature casting technology, electromagnetic stirring technology and coagulation end soft reduction or casting and rolling technology have been formed in this aspect for a long time, but the solidification structure of the surface layer, subsurface layer and core of the slab remains not ideal.
  • a method for producing high carbon chromium bearing steel by double slow cooling process (publication number: CN101412183A; publication date: 2009.04.22), which is slowly cooled by the high temperature of the casting blank through the slow cooling pit of the casting blank The hydrogen content and stress of the slab are then placed in a slow hood to further release hydrogen and stress in the slab.
  • the production method of high-carbon chromium bearing steel by two slow cooling can ensure the low-quality and non-white-point crack defects of the rolled material.
  • the slow cooling treatment of the cast slab in the prior art is often performed on the solidified slab, and it is difficult to effectively reduce the columnar crystal spacing and gap, especially in the near-surface columnar crystal of the slab. density.
  • the object of the present invention is to overcome the problem that the solidification structure of the surface layer, the subsurface layer and the core of the prior art is still not satisfactory, and to provide a method and a control device for controlling the solidification structure of the casting blank in the continuous casting process,
  • the invention provides a method for controlling the solidification structure of a slab during continuous casting, and a super-cooling zone and a heating slow-cooling zone are arranged in a section from the nozzle water nozzle to the end of the solidification end point, and the continuous casting slab is first in the super-cool zone.
  • Super-cooling, and then heating and cooling in the heating and cooling zone can reduce the columnar crystal spacing and gap, increase the density of the near-layer columnar crystal of the slab, and reduce the occurrence of internal cracks;
  • the utility model provides a device for controlling the solidification structure of a slab based on heating and slow cooling.
  • the lower part of the continuous casting mold is provided with a super-strong cooling zone and a heating slow cooling zone along the length direction of the continuous casting slab, and the super-cooling zone is used for Water spray cooling is provided on the surface of the slab, and the heating slow cooling zone is used to provide heat heating to the surface of the slab, which can reduce the columnar crystal spacing and gap, increase the density of the near columnar columnar crystal of the slab, and reduce the occurrence of internal cracks.
  • the invention discloses a method for controlling the solidification structure of a slab in a continuous casting process, wherein a super-strong cooling zone and a heating slow-cooling zone are arranged in a section from the nozzle water nozzle to the end of the solidification end point, and the continuous casting slab is first in the super-strong cooling zone.
  • the super cooling is performed, and then the heating and cooling in the heating slow cooling zone is performed, wherein the cooling intensity of the heating slow cooling is less than the cooling intensity of the air cooling.
  • a weak cooling zone is further disposed between the super-strong cooling zone and the heating slow cooling zone, and the weak cooling zone has a cooling intensity less than that of the super-cooling.
  • the super-cooling zone water flow density is Q L/m 2 and the weak cooling zone water flow density is q L/m 2 , Q ⁇ 2q.
  • the super-cooling starting point of the super-strong cooling zone is located at the crystallizer sewer, and the length of the super-cooling zone is greater than 12% L, wherein L is the total cooling length, and the total cooling length is from the crystallizer sewer to the solidification end point.
  • the distance between the heating slow cooling starting point of the heating slow cooling zone and the mold crystallizer water outlet is greater than 40% L, where L is the total cooling length.
  • the water flow density in the super-cooling zone of the round billet continuous casting billet is ⁇ 465 L/m 2
  • the water flow density in the super-cooling zone of the rectangular billet continuous casting billet is ⁇ 490 L/m 2
  • the super-cooling of the thick-plate continuous casting billet The water flow density in the area is ⁇ 255L/m 2 .
  • the surface of the slab is heated in the heating slow cooling zone, and the heat energy value of the heating is greater than 5 kW/m 2 .
  • the heating slow cooling end of the heating slow cooling zone is located before the solidification end point.
  • the invention relates to a device for controlling the solidification structure of a slab based on heating and slow cooling.
  • the lower part of the continuous casting mold is provided with a super-strong cooling zone and a heating slow cooling zone along the length direction of the continuous casting slab, and the super-cooling zone is used for Water spray cooling is provided to the surface of the slab, and the heating slow cooling zone is used to provide heat to the surface of the slab.
  • the surface of the continuous casting slab of the heating slow cooling zone is provided with an electromagnetic heating coil or a heating cover, wherein the heating cover is a steam heating cover or a flammable gas heating cover or a reflective heat insulation self-heating cover.
  • the front portion of the heating slow cooling zone is provided with a weak cooling zone.
  • a method for controlling the solidification structure of a slab in a continuous casting process wherein a super-cooling zone and a heating slow-cooling zone are arranged in a section from the nozzle water nozzle to the end of the solidification end point, and the continuous casting slab is first super Super-cooling in the strong cooling zone can effectively reduce the primary dendrite spacing and gap, increase the density of columnar crystals in the slab, reduce the columnar crystal loosening, and then heat the slow cooling zone to reduce the slab.
  • Temperature gradient reduces the temperature difference between the surface and the inside of the slab, inhibits the growth of columnar crystals, and avoids the occurrence of internal cracks in the slab; thereby reducing the columnar crystal spacing and gap, and improving the solidification structure of the subsurface and core of the slab , increasing the density of the columnar crystals in the near surface layer of the slab, and reducing the occurrence of internal cracks;
  • a method for controlling the solidification structure of a slab during continuous casting in the present invention wherein a weak cooling zone is provided between the super-cooling zone and the heating slow-cooling zone, and the cooling intensity of the weak cooling zone is less than that of the super-cooling cooling
  • the strength so as to ensure that the weak cooling zone has a sufficient range to ensure a good transition between the super-cooling zone and the heating and cooling zone during the continuous casting process, avoiding the direct transition of the continuous casting billet from the super-cooling zone to the heating slow-cooling zone, thereby avoiding Causes the surface temperature to rise too much, thereby reducing the internal cracks that are prone to occur in the solidified section;
  • a method for controlling the solidification structure of a slab during continuous casting wherein the distance between the heating slow cooling zone of the heating slow cooling zone and the crystallizer water outlet is greater than 40% of the total cooling length, and the heating is slow
  • the end point of the heating ring of the zone is located before the solidification end point, that is, the range of the heating slow cooling zone from 40% after the total cooling length to the end of the solidification end point, thereby ensuring sufficient weakness between the super-strong cooling zone and the heating slow cooling zone.
  • the cooling zone avoids the sudden temperature rise of the surface of the slab, and can reduce the internal cracks in the solidified section;
  • a device for controlling the solidification structure of a slab based on heating and slow cooling wherein a lower portion of the continuous casting mold is provided with a super-strong cooling zone and a heating slow-cooling zone along the length direction of the continuous casting slab, super-cooling
  • the zone is used for providing water spray cooling to the surface of the slab
  • the heating slow cooling zone is used for providing heat heating to the surface of the slab, reducing the columnar crystal spacing and gap, increasing the density of the near columnar columnar crystal of the slab, and reducing internal cracks.
  • FIG. 1 is a schematic structural view of an apparatus for controlling a solidification structure of a slab based on heating and slow cooling according to the present invention
  • Figure 2 is a heating and cooling zone of the present invention is an electromagnetic heating coil
  • FIG. 3 is a schematic view showing the microstructure of the slab of the embodiment 4;
  • a device for controlling the solidification structure of a slab based on heating and slow cooling the lower portion of the continuous casting mold 300 is provided with a super-strong cooling zone 210 along the longitudinal direction of the continuous casting slab 100.
  • the heating slow cooling zone 230 the exterior of the continuous casting blank 100 is a solidified shell 120, the inside of the solidified shell 120 is unsolidified molten steel 110, and the super-cooling zone 210 is used to provide water spray cooling to the surface of the solidified shell 120.
  • a nozzle is arranged in the super-cooling zone 210, and the nozzle is used for water-cooling cooling on the surface of the slab, and the heating slow-cooling zone 230 is used for supplying heat to the surface of the slab, thereby heating and tempering the surface of the slab.
  • an electromagnetic heating coil 231 is disposed on the surface of the continuous casting blank 100 of the heating slow cooling zone 230.
  • the surface of the continuous casting blank 100 of the heating slow cooling zone 230 is provided with a heating cover 231, wherein the heating cover 231 is a steam heating cover or a combustible gas heating cover or a reflective heat insulation self-heating cover.
  • the front portion of the heating slow cooling zone 230 is provided with a weak cooling zone 220, that is, the weak cooling zone 220 is disposed between the super-strong cooling zone 210 and the heating slow cooling zone 230.
  • a nozzle is provided in the weak cooling zone 220 for performing water spray cooling on the surface of the slab. It is worth noting that the water spray cooling can also be water vapor mixed cooling.
  • the invention discloses a method for controlling the solidification structure of a slab during continuous casting, in which a super cooling, a weak cooling and a heating slow cooling measure are sequentially applied to a slab in a certain section of the casting direction in a continuous process of molten steel. Thereby, the secondary surface layer and the core solidification structure of the slab are improved, and the total energy release amount of the entire continuous casting process is ensured.
  • a super-strong cooling zone 210 and a heating slow cooling zone 230 are provided, and the continuous casting blank 100 is firstly cooled in the super-strong cooling zone 210, and then The heating slow cooling zone 230 performs heating and slow cooling, wherein the cooling intensity of the heating slow cooling is less than the cooling intensity of the air cooling; the cooling intensity of the super cooling is greater than the cooling intensity of the air cooling.
  • the super-cooling starting point of the super-strong cooling zone 210 is located at the lower nozzle of the continuous casting mold 300, and the length of the super-strong cooling zone 210 is greater than 12% L, wherein L is the total cooling length, wherein the total cooling length is from the crystallizer sewer
  • L is the total cooling length
  • the total cooling length is from the crystallizer sewer
  • the average cooling intensity of the super-cooling zone 210 is much larger than that of the existing continuous casting technology. This is because the amount of water in the early stage cooling is small, so that the cooling intensity is too low, so that the amount of heat released in the early stage of the slab is small, and the ideal cooling cannot be formed quickly. Thickness and density of the shell; therefore, it is necessary to strengthen the pre-cooling of the billet so that the total heat of the billet is released as much as possible in the early stage, so that the surface of the billet cannot quickly form the shell of the desired thickness and density. Therefore, the total heat of the slab is released as much as possible in the early stage, and the different types of slabs have super cooling strength, and the cooling strength can be expressed by the water flow density, and is different by Q L/m 2 .
  • the super-cooling zone 210 of the round billet continuous casting billet 100 has a water flow density Q 1 ⁇ 465 L/m 2 ;
  • the super-cooling zone 210 of the rectangular billet continuous casting billet 100 has a water flow density Q 2 ⁇ 490 L/m 2 ;
  • the super-cooling zone 210 of the thick slab continuous casting blank 100 has a water flow density Q 3 ⁇ 255 L/m 2 ; and the thickness of the slab continuous casting is required to be not less than 200 mm;
  • the continuous casting blank 100 starts from the continuous casting mold 300, and the super cooling is applied thereto, which can effectively reduce the primary dendrite spacing and gap, increase the density of the columnar crystals in the casting blank, and reduce the columnar crystal looseness.
  • a weak cooling zone 220 is further disposed between the super-cooling zone 210 and the heating slow cooling zone 230 of the embodiment, and the cooling intensity of the weak cooling zone 220 is less than the cooling intensity of the super-cooling. After super-cooling, the cooling strength of the slab transitions to the weak cooling zone 220, and then passes through the weak cooling zone 220 and then transitions to the heating slow cooling zone 230, wherein the weak cooling zone 220 adopts the conventional cooling intensity of continuous casting. It is worth noting that the cooling intensity of the weak cooling zone 220 is q 1 L/m 2 and the super cooling intensity Q L/m 2 is Q ⁇ 2q 1 .
  • the cooling intensity of the different types of slab weak cooling zone 220 is different, and it is worth noting that the cooling intensity of the weak cooling zone 220 is substantially the same as the conventional cooling intensity during the continuous casting process, and the cooling intensity can be expressed by the water flow density. , specific classification description:
  • the cooling strength (water flow density) of the region is required to be ⁇ 155 L/m 2 ;
  • the cooling strength (water flow density) of this area is ⁇ 85L/m 2 .
  • the slab is first cooled by the super-cooling zone 210, and then transitioned through the weak cooling zone 220, and then enters the heating chill zone 230 for heating and tempering, which may reduce the temperature transition difference and reduce the temperature gradient in the slab.
  • the temperature difference between the surface of the slab and the inside is reduced, and the growth of the columnar crystal is suppressed.
  • the distance between the heating slow cooling zone of the heating slow cooling zone 230 of the present embodiment and the water inlet of the continuous casting mold 300 is greater than 40% of the total cooling length, and the heating slow cooling end of the heating slow cooling zone 230 is located before the solidification end point. That is, the heating slow cooling zone 230 starts from a total cooling length extending from the lower nozzle of the continuous casting mold 300 in the drawing direction by more than 40%, and ends up not exceeding the end of the cooling length.
  • the heating slow cooling zone 230 starts at less than 40% of the total cooling length, it will easily lead to the conventional cooling zone being too short to perform a good transition and cause the slab surface. If the temperature rise is too large, the solidified section area is prone to internal cracks. For this reason, the applicant has creatively proposed that the heating slow cooling starting point is located at a total cooling length of more than 40%, and the heating slow cooling end point is before the solidification end point. In addition, it is worth noting that the heating slow cooling end of the heating slow cooling zone 230 is adapted to the performance of the final product.
  • the slow cooling zone 230 is heated while heating the slow cooling zone 230.
  • the total length should also match the length of the pre-cooling zone 210 to ensure that the total amount of energy released during the continuous casting process is constant.
  • the longer the length of the super-cool zone 210 the longer the length of the heating zone 230, that is, the heating zone.
  • the length of 230 is positively correlated with the length of the super-strong cold zone 210 and ensures a constant total energy release during the continuous casting process.
  • the method of heating and cooling is to provide heating measures to the surface of the slab, and the heating energy value is greater than 5 kW/m 2 kW/m 2 .
  • This embodiment is carried out on a 5 round round billet continuous casting machine of a steel mill.
  • the cross section diameter of the billet is 380 mm.
  • strong cold, weak cold and heating slow cooling measures are applied to the casting billet in the casting direction.
  • the length of the zone 210, the cooling water flow density of the super-cooling zone 210, the heating slow cooling zone 230 heating the slow cooling starting point, and the heating slow cooling zone 230 heating provide heat as shown in Table 1;
  • the super-strong cooling zone 210 is from the continuous casting mold 300 From the lower mouth to 22% L, the heating slow cooling zone 230 is at the 55% L position to the solidification end point.
  • the slab is taken at a low magnification, and the columnar crystal looseness of the slab is analyzed, and the surface temperature at the time of complete solidification of the slab is measured.
  • Table 1 The specific parameters and results of the examples are shown in Table 1.
  • the basic content of this embodiment is the same as that of the first embodiment.
  • the difference between the cooling water flow density of the super-strong cooling zone 210, the heating slow cooling starting point position and the heating slow cooling zone 230 is different.
  • the specific parameters are as shown in Table 1. After the casting is finished, the slab is taken at a low magnification, and the columnar crystal looseness of the slab is analyzed, and the surface temperature at the time when the slab is completely solidified is measured. The specific parameters and results of the examples are shown in Table 1.
  • This embodiment is carried out on a 5 round round billet continuous casting machine of a steel mill.
  • the cross section diameter of the billet is 700 mm.
  • strong cold, weak cold and heating slow cooling measures are applied to the casting billet in the casting direction.
  • the length of the zone 210, the cooling water flow density of the super-cooling zone 210, the heating slow cooling zone 230 heating the slow cooling starting point, and the heating slow cooling zone 230 heating provide heat as shown in Table 1;
  • the super-strong cooling zone 210 is from the continuous casting mold 300 From the lower mouth to 17% L, the heating slow cooling zone 230 is at the 55% L position to the solidification end point.
  • the slab is taken at a low magnification, and the columnar crystal looseness of the slab is analyzed, and the surface temperature at the time of complete solidification of the slab is measured.
  • Table 1 The specific parameters and results of the examples are shown in Table 1.
  • the basic content of this embodiment is the same as that of the third embodiment.
  • the difference between the cooling water flow density, the heating slow cooling starting point and the heating slow cooling zone 230 is different.
  • the specific parameters are as shown in Table 1. After the casting is finished, the casting blank is taken at a low magnification, and the columnar crystal looseness of the casting blank is analyzed, and the surface temperature when the casting blank is completely solidified is measured. The specific parameters and results of the examples are shown in Table 1.
  • a picture of the low magnification structure of the cast slab of Example 4 is shown in FIG.
  • the basic content of this embodiment is the same as that of Embodiment 4, except that the water flow density of the cooling strength of the surface of the slab is 200 L/m 2 .
  • After casting take a low-magnification sample of the slab, perform low-fold analysis, analyze the columnar crystal looseness of the slab, and measure the surface temperature when the slab is completely solidified.
  • the specific parameters and results of Comparative Example 1 are shown in Table 1.
  • a picture of the low-magnification structure of the proportion 1 slab is shown in Fig. 4.
  • the length of the super cold zone 210 and the length of the heating slow zone 230 in the table are L, and L represents the total cooling length.
  • the columnar crystal structure in the solidification structure of the slab in Example 1-4 is relatively loose, the average columnar crystal looseness is less than 26.0 um, and the surface temperature of the slab is increased, which can effectively reduce the occurrence of internal cracks. Improve the quality of the slab to meet the demand for solidification structure of different products.
  • FIG. 3 is a schematic view showing the morphology of the microstructure of the slab of Example 4;
  • FIG. 4 is a schematic view showing the microstructure of the slab of Comparative Example 1; wherein, FIG. 3 and FIG. 4 include a columnar crystal region 410, The equiaxed crystal region 420 and the loose pores 430, the slab columnar crystal region 410 in FIG. 4 has a relatively loose domain structure, and the columnar crystal region 410 has a loose pore 430, and the slab columnar crystal region 410 of FIG. 3 is densely organized and dendritic. Finely compact, the loose holes 430 of the columnar crystal regions 410 are substantially eliminated. Moreover, the average columnar grain looseness is reduced from 37.2 um to 26.0 um.
  • Example 4 not only reduces the columnar crystal spacing and gap, improves the secondary surface layer and core solidification structure of the cast strand, but also enlarges the proportion of equiaxed crystal regions 420, thereby improving The quality of the slab.

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Abstract

A method for controlling the structure of a solidified cast ingot in a continuous casting process comprises: arranging a high-intensity cooling region (210) and a heating and slow-cooling region (230) in a space between a water drain port of a crystallizer and a solidification end point; performing high-intensity cooling on a continuously cast ingot (100) in the high-intensity cooling region; and then performing heating and slow-cooling on the continuously cast ingot (100) in the heating and slow-cooling region, wherein a cooling intensity of the heating and slow-cooling is less than a cooling intensity of air-based cooling. A device for employing heating and slow-cooling to control the structure of a solidified cast ingot is further disclosed, comprising a high-intensity cooling region and a heating and slow-cooling region arranged in a lengthwise direction of a continuously cast ingot at a lower portion of a continuous casting crystallizer, wherein the high-intensity cooling region is used to spray water to a surface of the cast ingot so as to perform cooling, and the heating and slow-cooling region is used to heat the surface of the cast ingot. In the method and device, a continuously cast ingot is firstly cooled in the high-intensity cooling region, and then undergoes heating and slow-cooling in the heating and slow-cooling region, thereby reducing spacing and gaps among columnar crystals, increasing efficiency of space-filling of near-surface columnar crystals on a cast ingot, and improving quality of the cast ingot.

Description

一种控制连铸过程中铸坯凝固组织结构的方法及其控制装置Method for controlling solidification structure of casting blank in continuous casting process and control device thereof 技术领域Technical field
本发明涉及冶金连铸技术领域,更具体地说,涉及一种控制连铸过程中铸坯凝固组织结构的方法及其控制装置。The invention relates to the technical field of metallurgical continuous casting, and more particularly to a method for controlling the solidification structure of a slab during continuous casting and a control device thereof.
背景技术Background technique
在现代钢铁连铸生产技术中,铸坯组织的结构和缺陷一直严重影响铸坯质量,由于在传统连铸技术中的冷却模式条件下,钢水凝固过程中铸坯结构对铸材及零件的性能适应性往往不足,调控方式和程度的不足使得凝固结构的可控性也不好,不能满足日益提高的对材料使用性能,特别是具体的个性化要求。比如,对有些情况下过度生长的柱状晶发达,使得中心偏析严重;另一些情况下冷却不当又使得晶粒和晶界粗大;又比如,凝固后期优先生长的柱状晶控制不住而在铸坯中心相遇形成“搭桥”,液相穴内钢液被“凝固晶桥”分开,晶桥下部钢液在凝固收缩时得不到上部金属补充而形成疏松或缩孔,并伴随中心偏析、成分不均匀等相关问题。为了解决上述问题,长期以来在该方面形成了低温浇铸技术、电磁搅拌技术和凝固末端轻压下或铸轧技术等,但其这些技术对铸坯表层、次表层和心部的凝固组织结构仍然不理想。In the modern steel continuous casting production technology, the structure and defects of the slab structure have seriously affected the quality of the slab. Due to the cooling mode in the traditional continuous casting technology, the performance of the slab structure on the castings and parts during the solidification process of the molten steel Adaptability is often insufficient, and the lack of regulation and degree makes the controllability of the solidification structure not good, and can not meet the increasing performance of materials, especially the specific individual requirements. For example, in some cases, excessive growth of columnar crystals makes the center segregation severe; in other cases, improper cooling causes grain and grain boundaries to be coarse; for example, columnar crystals that preferentially grow in the late stage of solidification cannot be controlled in the slab The center meets to form a “bridge”. The molten steel in the liquid phase is separated by the “solidified crystal bridge”. The molten steel in the lower part of the crystal bridge cannot be replenished by the upper metal to form loose or shrinkage holes, accompanied by central segregation and uneven composition. And other related issues. In order to solve the above problems, low-temperature casting technology, electromagnetic stirring technology and coagulation end soft reduction or casting and rolling technology have been formed in this aspect for a long time, but the solidification structure of the surface layer, subsurface layer and core of the slab remains not ideal.
经检索,一种双缓冷工艺生产高碳铬轴承钢的方法(公开号:CN101412183A;公开日:2009.04.22),该技术通过对铸坯缓冷坑中,利用铸坯高温缓慢冷却,释放铸坯的氢含量及应力,而后再将轧材放入缓冷罩中,以进一步释放轧材中的氢和应力。通过两次缓冷生产高碳铬轴承钢的生产方法可以保证轧材低倍质量无白点裂纹缺陷存在。但是,值得注意的是,现有技术对铸坯的缓冷处理往往是针对凝固完成的铸坯进行处理,难以有效的降低柱状晶间距和间隙,特别是难以有效提高铸坯近表层柱状晶的致密度。A method for producing high carbon chromium bearing steel by double slow cooling process (publication number: CN101412183A; publication date: 2009.04.22), which is slowly cooled by the high temperature of the casting blank through the slow cooling pit of the casting blank The hydrogen content and stress of the slab are then placed in a slow hood to further release hydrogen and stress in the slab. The production method of high-carbon chromium bearing steel by two slow cooling can ensure the low-quality and non-white-point crack defects of the rolled material. However, it is worth noting that the slow cooling treatment of the cast slab in the prior art is often performed on the solidified slab, and it is difficult to effectively reduce the columnar crystal spacing and gap, especially in the near-surface columnar crystal of the slab. density.
发明内容Summary of the invention
1.发明要解决的技术问题1. The technical problem to be solved by the invention
本发明的目的克服现有技术铸坯表层、次表层和心部的凝固组织结构仍然不理想的问题,提供一种控制连铸过程中铸坯凝固组织结构的方法及其控制装置,The object of the present invention is to overcome the problem that the solidification structure of the surface layer, the subsurface layer and the core of the prior art is still not satisfactory, and to provide a method and a control device for controlling the solidification structure of the casting blank in the continuous casting process,
其中提供的一种控制连铸过程中铸坯凝固组织结构的方法,在结晶器下水口至凝固终点结束的区间设置有超强冷区和加热缓冷区,连铸坯先在超强冷区进行超强冷却,而后在加热缓冷区进行加热缓冷,可以降低柱状晶间距和间隙,提高铸坯近表层柱状晶的致密度,同时减少内部裂纹的产生;The invention provides a method for controlling the solidification structure of a slab during continuous casting, and a super-cooling zone and a heating slow-cooling zone are arranged in a section from the nozzle water nozzle to the end of the solidification end point, and the continuous casting slab is first in the super-cool zone. Super-cooling, and then heating and cooling in the heating and cooling zone can reduce the columnar crystal spacing and gap, increase the density of the near-layer columnar crystal of the slab, and reduce the occurrence of internal cracks;
其中提供的一种基于加热缓冷控制铸坯凝固组织结构的装置,连铸结晶器的下部沿着连铸坯的长度方向设置有超强冷区和加热缓冷区,超强冷区用于向铸坯表面提供喷水冷却,加热缓冷区用于向铸坯表面提供热量加热,可以降低柱状晶间距和间隙,提高铸坯近表层柱状晶的致密度,并减少内部裂纹的产生。The utility model provides a device for controlling the solidification structure of a slab based on heating and slow cooling. The lower part of the continuous casting mold is provided with a super-strong cooling zone and a heating slow cooling zone along the length direction of the continuous casting slab, and the super-cooling zone is used for Water spray cooling is provided on the surface of the slab, and the heating slow cooling zone is used to provide heat heating to the surface of the slab, which can reduce the columnar crystal spacing and gap, increase the density of the near columnar columnar crystal of the slab, and reduce the occurrence of internal cracks.
2.技术方案2. Technical solutions
为达到上述目的,本发明提供的技术方案为:In order to achieve the above object, the technical solution provided by the present invention is:
本发明的一种控制连铸过程中铸坯凝固组织结构的方法,在结晶器下水口至凝固终点结束的区间设置有超强冷区和加热缓冷区,连铸坯先在超强冷区进行超强冷却,而后在加热缓冷区进行加热缓冷,其中加热缓冷的冷却强度小于空冷的冷却强度。The invention discloses a method for controlling the solidification structure of a slab in a continuous casting process, wherein a super-strong cooling zone and a heating slow-cooling zone are arranged in a section from the nozzle water nozzle to the end of the solidification end point, and the continuous casting slab is first in the super-strong cooling zone. The super cooling is performed, and then the heating and cooling in the heating slow cooling zone is performed, wherein the cooling intensity of the heating slow cooling is less than the cooling intensity of the air cooling.
优选地,超强冷区和加热缓冷区之间还设置有弱冷却区,所述的弱冷却区冷却强度小于超强冷却的冷却强度。Preferably, a weak cooling zone is further disposed between the super-strong cooling zone and the heating slow cooling zone, and the weak cooling zone has a cooling intensity less than that of the super-cooling.
优选地,超强冷区水流密度为Q L/m 2弱冷却区水流密度为q L/m 2,Q≥2q。 Preferably, the super-cooling zone water flow density is Q L/m 2 and the weak cooling zone water flow density is q L/m 2 , Q ≥ 2q.
优选地,超强冷区的超强冷却起点位于结晶器下水口,超强冷区的长度大于12%L,其中L为总冷却长度,总冷却长度为从结晶器下水口到凝固终点。Preferably, the super-cooling starting point of the super-strong cooling zone is located at the crystallizer sewer, and the length of the super-cooling zone is greater than 12% L, wherein L is the total cooling length, and the total cooling length is from the crystallizer sewer to the solidification end point.
优选地,加热缓冷区的加热缓冷起点与结晶器结晶器下水口之间的距离大于40%L,其中L为总冷却长度。Preferably, the distance between the heating slow cooling starting point of the heating slow cooling zone and the mold crystallizer water outlet is greater than 40% L, where L is the total cooling length.
优选地,圆坯连铸坯的超强冷区水流密度≥465L/m 2,或者矩形坯连铸坯的超强冷区水流密度≥490L/m 2,或者厚板连铸坯的超强冷区水流密度≥255L/m 2Preferably, the water flow density in the super-cooling zone of the round billet continuous casting billet is ≥ 465 L/m 2 , or the water flow density in the super-cooling zone of the rectangular billet continuous casting billet is ≥ 490 L/m 2 , or the super-cooling of the thick-plate continuous casting billet The water flow density in the area is ≥255L/m 2 .
优选地,在加热缓冷区向铸坯表面进行加热,加热的热能量值大于5kW/m 2Preferably, the surface of the slab is heated in the heating slow cooling zone, and the heat energy value of the heating is greater than 5 kW/m 2 .
优选地,所述的加热缓冷区的加热缓冷终点位于凝固终点之前。Preferably, the heating slow cooling end of the heating slow cooling zone is located before the solidification end point.
本发明的一种基于加热缓冷控制铸坯凝固组织结构的装置,连铸结晶器的下部沿着连铸坯的长度方向设置有超强冷区和加热缓冷区,超强冷区用于向铸坯表面提供喷水冷却,加热缓冷区用于向铸坯表面提供热量加热。The invention relates to a device for controlling the solidification structure of a slab based on heating and slow cooling. The lower part of the continuous casting mold is provided with a super-strong cooling zone and a heating slow cooling zone along the length direction of the continuous casting slab, and the super-cooling zone is used for Water spray cooling is provided to the surface of the slab, and the heating slow cooling zone is used to provide heat to the surface of the slab.
优选地,加热缓冷区的连铸坯表面设置有电磁加热线圈或者加热罩,其中加热罩为蒸汽加热罩或者可燃性气体加热罩或者反射绝热自加热罩。Preferably, the surface of the continuous casting slab of the heating slow cooling zone is provided with an electromagnetic heating coil or a heating cover, wherein the heating cover is a steam heating cover or a flammable gas heating cover or a reflective heat insulation self-heating cover.
优选地,加热缓冷区的前部设置有弱冷却区。Preferably, the front portion of the heating slow cooling zone is provided with a weak cooling zone.
3.有益效果3. Beneficial effects
采用本发明提供的技术方案,与已有的公知技术相比,具有如下显著效果:Compared with the prior art, the technical solution provided by the invention has the following remarkable effects:
(1)本发明的一种控制连铸过程中铸坯凝固组织结构的方法,在结晶器下水口至凝固终点结束的区间设置有超强冷区和加热缓冷区,连铸坯先在超强冷区进行超强冷却,可以有效的降低一次枝晶间距和间隙,提高铸坯中柱状晶的致密度,减少柱状晶疏松,而后在加热缓 冷区进行加热缓冷,降低铸坯中的温度梯度,减少铸坯表面与内部的温度差,抑制柱状晶的生长,还避免出现铸坯内部裂纹的产生;从而降低了柱状晶间距和间隙,改善铸坯次表层和心部的凝固组织结构,提高铸坯近表层柱状晶的致密度,同时减少内部裂纹的产生;(1) A method for controlling the solidification structure of a slab in a continuous casting process according to the present invention, wherein a super-cooling zone and a heating slow-cooling zone are arranged in a section from the nozzle water nozzle to the end of the solidification end point, and the continuous casting slab is first super Super-cooling in the strong cooling zone can effectively reduce the primary dendrite spacing and gap, increase the density of columnar crystals in the slab, reduce the columnar crystal loosening, and then heat the slow cooling zone to reduce the slab. Temperature gradient reduces the temperature difference between the surface and the inside of the slab, inhibits the growth of columnar crystals, and avoids the occurrence of internal cracks in the slab; thereby reducing the columnar crystal spacing and gap, and improving the solidification structure of the subsurface and core of the slab , increasing the density of the columnar crystals in the near surface layer of the slab, and reducing the occurrence of internal cracks;
(2)本发明的一种控制连铸过程中铸坯凝固组织结构的方法,超强冷区的超强冷却起点位于结晶器下水口,超强冷区的长度大于度12%的总冷却长度,如果冷却长度过短则无法形成足够致密的柱状晶和尽可能厚的坯壳厚度,不利于凝固后期实施所希望的弱冷却控制;(2) A method for controlling the solidification structure of a slab during continuous casting, the super-cooling starting point of the super-cooling zone is located at the nozzle of the crystallizer, and the length of the super-cooling zone is greater than 12% of the total cooling length If the cooling length is too short, sufficient dense columnar crystals and as thick a shell thickness as possible are not formed, which is disadvantageous for implementing the desired weak cooling control in the late solidification stage;
(3)本发明的一种控制连铸过程中铸坯凝固组织结构的方法,超强冷区和加热缓冷区之间还设置有弱冷却区,弱冷却区冷却强度小于超强冷却的冷却强度,从而保证弱冷却区具有足够的范围,保证连铸过程中超强冷区与加热缓冷区之间的良好过渡,避免连铸坯由超强冷区直接过渡到加热缓冷区,进而避免造成表面温升过大,从而减小凝固截面区易出现的内部裂纹;(3) A method for controlling the solidification structure of a slab during continuous casting in the present invention, wherein a weak cooling zone is provided between the super-cooling zone and the heating slow-cooling zone, and the cooling intensity of the weak cooling zone is less than that of the super-cooling cooling The strength, so as to ensure that the weak cooling zone has a sufficient range to ensure a good transition between the super-cooling zone and the heating and cooling zone during the continuous casting process, avoiding the direct transition of the continuous casting billet from the super-cooling zone to the heating slow-cooling zone, thereby avoiding Causes the surface temperature to rise too much, thereby reducing the internal cracks that are prone to occur in the solidified section;
(4)本发明的一种控制连铸过程中铸坯凝固组织结构的方法,加热缓冷区的加热缓冷起点与结晶器下水口之间的距离大于40%的总冷却长度,加热缓冷区的加热环冷的终点位于凝固终点之前,即加热缓冷区位于总冷却长度40%之后的位置到凝固终点之前的范围,从而保证超强冷区与加热缓冷区之间有充分的弱冷却区,避免铸坯表面的突然温度升高,可以减小凝固截面区易出现内部裂纹;(4) A method for controlling the solidification structure of a slab during continuous casting, wherein the distance between the heating slow cooling zone of the heating slow cooling zone and the crystallizer water outlet is greater than 40% of the total cooling length, and the heating is slow The end point of the heating ring of the zone is located before the solidification end point, that is, the range of the heating slow cooling zone from 40% after the total cooling length to the end of the solidification end point, thereby ensuring sufficient weakness between the super-strong cooling zone and the heating slow cooling zone. The cooling zone avoids the sudden temperature rise of the surface of the slab, and can reduce the internal cracks in the solidified section;
(5)本发明的一种基于加热缓冷控制铸坯凝固组织结构的装置,连铸结晶器的下部沿着连铸坯的长度方向设置有超强冷区和加热缓冷区,超强冷区用于向铸坯表面提供喷水冷却,加热缓冷区用于向铸坯表面提供热量加热,降低了柱状晶间距和间隙,提高铸坯近表层柱状晶的致密度,同时减少内部裂纹的产生,以达到获得与不同最终产品性能要求相应的铸坯凝固组织结构的目的。(5) A device for controlling the solidification structure of a slab based on heating and slow cooling according to the present invention, wherein a lower portion of the continuous casting mold is provided with a super-strong cooling zone and a heating slow-cooling zone along the length direction of the continuous casting slab, super-cooling The zone is used for providing water spray cooling to the surface of the slab, and the heating slow cooling zone is used for providing heat heating to the surface of the slab, reducing the columnar crystal spacing and gap, increasing the density of the near columnar columnar crystal of the slab, and reducing internal cracks. Produced to achieve the purpose of obtaining the solidification structure of the slab corresponding to the performance requirements of different final products.
附图说明DRAWINGS
图1为本发明的一种基于加热缓冷控制铸坯凝固组织结构的装置的结构示意图;1 is a schematic structural view of an apparatus for controlling a solidification structure of a slab based on heating and slow cooling according to the present invention;
图2为本发明的加热缓冷区为电磁加热线圈;Figure 2 is a heating and cooling zone of the present invention is an electromagnetic heating coil;
图3为实施例4的铸坯微观组织的形貌示意图;3 is a schematic view showing the microstructure of the slab of the embodiment 4;
图4为对比例1的铸坯微观组织的形貌示意图。4 is a schematic view showing the morphology of the microstructure of the slab of Comparative Example 1.
附图中的标号说明:The reference numerals in the drawings indicate:
100、连铸坯;110、未凝固钢水;120、凝固坯壳;100, continuous casting billet; 110, unsolidified molten steel; 120, solidified shell;
210、超强冷区;220、弱冷却区;230、加热缓冷区;210, super strong cold zone; 220, weak cooling zone; 230, heating slow cooling zone;
300、连铸结晶器;300, continuous casting mold;
410、柱状晶区;420、等轴晶区;430、疏松孔。410, columnar crystal region; 420, equiaxed crystal region; 430, loose pores.
具体实施方式detailed description
为进一步了解本实用新型的内容,结合附图和实施例对本实用新型作详细描述。In order to further understand the contents of the present invention, the present invention will be described in detail with reference to the accompanying drawings and embodiments.
本说明书附图所绘示的结构、比例、大小等,均仅用以配合说明书所揭示的内容,以供熟悉此技术的人士了解与阅读,并非用以限定本发明可实施的限定条件,故不具技术上的实质意义,任何结构的修饰、比例关系的改变或大小的调整,在不影响本发明所能产生的功效及所能达成的目的下,均应仍落在本发明所揭示的技术内容得能涵盖的范围内。同时,本说明书中所引用的如“上”、“下”、“左”、“右”、“中间”等用语,亦仅为便于叙述的明了,而非用以限定可实施的范围,其相对关系的改变或调整,在无实质变更技术内容下,当亦视为本发明可实施的范畴。The structures, the proportions, the sizes, and the like of the drawings are only used to clarify the contents disclosed in the specification for understanding and reading by those skilled in the art, and are not intended to limit the conditions that can be implemented by the present invention. Without technical significance, the modification of any structure, the change of the proportional relationship or the adjustment of the size should still fall within the technology disclosed by the present invention without affecting the effects and the achievable objectives of the present invention. The content can be covered. In the meantime, the terms "upper", "lower", "left", "right", "intermediate", etc., as used in this specification, are merely for convenience of description, and are not intended to limit the scope of implementation. Changes or adjustments in relative relationships are considered to be within the scope of the invention, without departing from the scope of the invention.
如图1-图3所示,本发明的一种基于加热缓冷控制铸坯凝固组织结构的装置,连铸结晶器300的下部沿着连铸坯100的长度方向设置有超强冷区210和加热缓冷区230,连铸坯100的外部为凝固坯壳120,凝固坯壳120内部为未凝固钢水110,超强冷区210用于向凝固坯壳120的铸坯表面提供喷水冷却,即在超强冷区210内设置有喷嘴,喷嘴用于向铸坯表面进行喷水冷却,加热缓冷区230用于向铸坯表面提供热量加热,进而对铸坯表面进行加热缓冷。如图2所示,加热缓冷区230的连铸坯100表面设置有电磁加热线圈231。As shown in FIG. 1 to FIG. 3, a device for controlling the solidification structure of a slab based on heating and slow cooling, the lower portion of the continuous casting mold 300 is provided with a super-strong cooling zone 210 along the longitudinal direction of the continuous casting slab 100. And the heating slow cooling zone 230, the exterior of the continuous casting blank 100 is a solidified shell 120, the inside of the solidified shell 120 is unsolidified molten steel 110, and the super-cooling zone 210 is used to provide water spray cooling to the surface of the solidified shell 120. That is, a nozzle is arranged in the super-cooling zone 210, and the nozzle is used for water-cooling cooling on the surface of the slab, and the heating slow-cooling zone 230 is used for supplying heat to the surface of the slab, thereby heating and tempering the surface of the slab. As shown in FIG. 2, an electromagnetic heating coil 231 is disposed on the surface of the continuous casting blank 100 of the heating slow cooling zone 230.
或者如图3所示,加热缓冷区230的连铸坯100表面设置有加热罩231,其中加热罩231为蒸汽加热罩或者可燃性气体加热罩或者反射绝热自加热罩。Alternatively, as shown in FIG. 3, the surface of the continuous casting blank 100 of the heating slow cooling zone 230 is provided with a heating cover 231, wherein the heating cover 231 is a steam heating cover or a combustible gas heating cover or a reflective heat insulation self-heating cover.
如图3所示,加热缓冷区230的前部设置有弱冷却区220,即弱冷却区220设置于超强冷区210与加热缓冷区230之间。在弱冷却区220内设置有喷嘴,喷嘴用于向铸坯表面进行喷水冷却。值得说明的是喷水冷却也可以是水汽混合冷却。As shown in FIG. 3, the front portion of the heating slow cooling zone 230 is provided with a weak cooling zone 220, that is, the weak cooling zone 220 is disposed between the super-strong cooling zone 210 and the heating slow cooling zone 230. A nozzle is provided in the weak cooling zone 220 for performing water spray cooling on the surface of the slab. It is worth noting that the water spray cooling can also be water vapor mixed cooling.
本发明的一种控制连铸过程中铸坯凝固组织结构的方法,通过在钢水连铸过程中对铸坯沿浇铸方向一定区域段内依次分别施加超强冷却、弱冷却和加热缓冷措施,从而改善铸坯次表层和心部凝固组织结构,同时保证整个连铸过程能量释放总量一定。详细的说明是:在连铸结晶器300下水口至凝固终点结束的区间设置有超强冷区210和加热缓冷区230,连铸坯100先在超强冷区210进行超强冷却,而后在加热缓冷区230进行加热缓冷,其中加热缓冷的冷却强度小于空冷的冷却强度;超强冷却的冷却强度大于空冷的冷却强度。The invention discloses a method for controlling the solidification structure of a slab during continuous casting, in which a super cooling, a weak cooling and a heating slow cooling measure are sequentially applied to a slab in a certain section of the casting direction in a continuous process of molten steel. Thereby, the secondary surface layer and the core solidification structure of the slab are improved, and the total energy release amount of the entire continuous casting process is ensured. The detailed description is: in the section from the lower nozzle of the continuous casting mold 300 to the end of the solidification end point, a super-strong cooling zone 210 and a heating slow cooling zone 230 are provided, and the continuous casting blank 100 is firstly cooled in the super-strong cooling zone 210, and then The heating slow cooling zone 230 performs heating and slow cooling, wherein the cooling intensity of the heating slow cooling is less than the cooling intensity of the air cooling; the cooling intensity of the super cooling is greater than the cooling intensity of the air cooling.
即超强冷区210的超强冷却起点位于连铸结晶器300下水口,超强冷区210的长度大于度12%L,其中L为总冷却长度,其中总冷却长度为从结晶器下水口到凝固终点的距离,即超强冷区210由连铸结晶器300下水口一直沿浇铸方向延伸到大于12%的总冷却长度。这是由于超强冷区210长度低于12%的总冷却长度时,使得超强冷区210的区间太短,使得连铸坯100无法形成足够致密的柱状晶和尽可能厚的坯壳厚度,不利于凝固后期实施所希望的弱 冷却控制。超强冷区210的平均冷却强度远大于现有连铸技术冷却强度,这是由于前期冷却的比水量小,则使得冷却强度过低,则使得铸坯前期释放的热量少,无法迅速形成理想厚度和致密度的坯壳;因此,必须加强铸坯的前期冷却,使得铸坯总热量尽量在前期多释放,进而使得铸坯表面无法迅速形成理想厚度和致密度的坯壳。从而使铸坯总热量尽量在前期多释放,并且使得不同类型的铸坯超强冷却强度,且冷却强度可以用水流密度来表示,并用Q L/m 2有所不同,具体分类描述: That is, the super-cooling starting point of the super-strong cooling zone 210 is located at the lower nozzle of the continuous casting mold 300, and the length of the super-strong cooling zone 210 is greater than 12% L, wherein L is the total cooling length, wherein the total cooling length is from the crystallizer sewer The distance to the end of solidification, i.e., the super-cooling zone 210, is extended from the spout of the continuous casting mold 300 in the casting direction to a total cooling length of greater than 12%. This is because the length of the super-cold zone 210 is less than 12% of the total cooling length, so that the section of the super-cold zone 210 is too short, so that the continuous casting blank 100 cannot form a sufficiently dense columnar crystal and as thick as possible. It is not conducive to the implementation of the desired weak cooling control in the late stage of solidification. The average cooling intensity of the super-cooling zone 210 is much larger than that of the existing continuous casting technology. This is because the amount of water in the early stage cooling is small, so that the cooling intensity is too low, so that the amount of heat released in the early stage of the slab is small, and the ideal cooling cannot be formed quickly. Thickness and density of the shell; therefore, it is necessary to strengthen the pre-cooling of the billet so that the total heat of the billet is released as much as possible in the early stage, so that the surface of the billet cannot quickly form the shell of the desired thickness and density. Therefore, the total heat of the slab is released as much as possible in the early stage, and the different types of slabs have super cooling strength, and the cooling strength can be expressed by the water flow density, and is different by Q L/m 2 .
(1)圆坯连铸坯100的超强冷区210水流密度Q 1≥465L/m 2(1) The super-cooling zone 210 of the round billet continuous casting billet 100 has a water flow density Q 1 ≥ 465 L/m 2 ;
(2)矩形坯连铸坯100的超强冷区210水流密度Q 2≥490L/m 2(2) The super-cooling zone 210 of the rectangular billet continuous casting billet 100 has a water flow density Q 2 ≥ 490 L/m 2 ;
(3)厚板连铸坯100的超强冷区210水流密度Q 3≥255L/m 2;且要求板坯连铸的厚度不小于200mm; (3) The super-cooling zone 210 of the thick slab continuous casting blank 100 has a water flow density Q 3 ≥ 255 L/m 2 ; and the thickness of the slab continuous casting is required to be not less than 200 mm;
连铸坯100出连铸结晶器300开始,对其施加超强冷却,可以有效地降低一次枝晶间距和间隙,提高铸坯中柱状晶的致密度,减少柱状晶疏松。The continuous casting blank 100 starts from the continuous casting mold 300, and the super cooling is applied thereto, which can effectively reduce the primary dendrite spacing and gap, increase the density of the columnar crystals in the casting blank, and reduce the columnar crystal looseness.
本实施例的超强冷区210和加热缓冷区230之间还设置有弱冷却区220,弱冷却区220冷却强度小于超强冷却的冷却强度。经过超强冷后,铸坯冷却强度过渡到弱冷却区220,经弱冷却区220后再过渡到加热缓冷区230,其中弱冷却区220即采用连铸常规的冷却强度。值得说明的是,弱冷却区220的冷却强度为q 1L/m 2,且超强冷却强度Q L/m 2,则Q≥2q 1。且对于不同类型的铸坯弱冷却区220的冷却强度有所不同,且值得说明的是弱冷却区220的冷却强度与连铸过程中的常规冷却强度基本相同,冷却强度可以用水流密度来表示,具体分类描述: A weak cooling zone 220 is further disposed between the super-cooling zone 210 and the heating slow cooling zone 230 of the embodiment, and the cooling intensity of the weak cooling zone 220 is less than the cooling intensity of the super-cooling. After super-cooling, the cooling strength of the slab transitions to the weak cooling zone 220, and then passes through the weak cooling zone 220 and then transitions to the heating slow cooling zone 230, wherein the weak cooling zone 220 adopts the conventional cooling intensity of continuous casting. It is worth noting that the cooling intensity of the weak cooling zone 220 is q 1 L/m 2 and the super cooling intensity Q L/m 2 is Q ≥ 2q 1 . The cooling intensity of the different types of slab weak cooling zone 220 is different, and it is worth noting that the cooling intensity of the weak cooling zone 220 is substantially the same as the conventional cooling intensity during the continuous casting process, and the cooling intensity can be expressed by the water flow density. , specific classification description:
(1)对于圆坯连铸要求该区域冷却强度(水流密度)≥155L/m 2(1) For round billet continuous casting, the cooling strength (water flow density) of the region is required to be ≥ 155 L/m 2 ;
(2)对于矩形坯连铸要求该区域冷却强度(水流密度)≥245L/m 2(2) For rectangular billet continuous casting, the cooling strength (water flow density) of this area is ≥245L/m 2 ;
(2)对于板坯连铸要求该区域冷却强度(水流密度)≥85L/m 2。铸坯先经过超强冷区210进行冷却,再经过弱冷却区220进行过渡后,进入加热缓冷区230进行加热缓冷,可有减小温度过渡的差值,降低铸坯中的温度梯度,减少铸坯表面与内部的温度差,抑制柱状晶的生长。 (2) For slab continuous casting, the cooling strength (water flow density) of this area is ≥85L/m 2 . The slab is first cooled by the super-cooling zone 210, and then transitioned through the weak cooling zone 220, and then enters the heating chill zone 230 for heating and tempering, which may reduce the temperature transition difference and reduce the temperature gradient in the slab. The temperature difference between the surface of the slab and the inside is reduced, and the growth of the columnar crystal is suppressed.
本实施例的加热缓冷区230的加热缓冷起点与连铸结晶器300下水口之间的距离大于40%的总冷却长度,加热缓冷区230的加热缓冷终点位于凝固终点之前。即加热缓冷区230为从连铸结晶器300下水口沿拉坯方向延伸大于40%的总冷却长度开始,到不超过冷却长度终点结束。通过对铸坯施加加热缓冷措施,降低铸坯中的温度梯度,减少铸坯表面与内部的温度差,抑制柱状晶的生长,还避免出现铸坯内部裂纹的产生。申请人研发团队,通过长时间的研发发现,如果加热缓冷区230在小于40%的总冷却长度开始,则易导致常规冷却区过 短,无法起到良好的过渡作用,并造成铸坯表面温升过大,致使凝固截面区易出现内部裂纹,为此申请人创造性的提出了加热缓冷起点位于大于40%的总冷却长度处,加热缓冷终点位于凝固终点之前。此外,值得注意的是加热缓冷区230的加热缓冷终点与最终产品的性能相适应,如最终产品对铸坯芯部要求较高,则加热缓冷区230,同时加热缓冷区230的总长度也要和前期超强冷区210长度相匹配,保证整个连铸过程能量释放总量一定,如超强冷区210长度越长则加热缓冷区230长度越长,即加热缓冷区230的长度与超强冷区210的长度呈正相关,并保证连铸过程能量释放总量一定。加热缓冷的方式为向铸坯表面提供加热措施,加热的热能量值大于5kW/m 2千瓦/平方米。 The distance between the heating slow cooling zone of the heating slow cooling zone 230 of the present embodiment and the water inlet of the continuous casting mold 300 is greater than 40% of the total cooling length, and the heating slow cooling end of the heating slow cooling zone 230 is located before the solidification end point. That is, the heating slow cooling zone 230 starts from a total cooling length extending from the lower nozzle of the continuous casting mold 300 in the drawing direction by more than 40%, and ends up not exceeding the end of the cooling length. By applying heat and slow cooling measures to the slab, the temperature gradient in the slab is reduced, the temperature difference between the surface of the slab and the inside is reduced, the growth of the columnar crystals is suppressed, and the occurrence of internal cracks in the slab is also avoided. Applicant's R&D team found through long-term research and development that if the heating slow cooling zone 230 starts at less than 40% of the total cooling length, it will easily lead to the conventional cooling zone being too short to perform a good transition and cause the slab surface. If the temperature rise is too large, the solidified section area is prone to internal cracks. For this reason, the applicant has creatively proposed that the heating slow cooling starting point is located at a total cooling length of more than 40%, and the heating slow cooling end point is before the solidification end point. In addition, it is worth noting that the heating slow cooling end of the heating slow cooling zone 230 is adapted to the performance of the final product. If the final product has a higher requirement on the core of the casting blank, the slow cooling zone 230 is heated while heating the slow cooling zone 230. The total length should also match the length of the pre-cooling zone 210 to ensure that the total amount of energy released during the continuous casting process is constant. For example, the longer the length of the super-cool zone 210, the longer the length of the heating zone 230, that is, the heating zone. The length of 230 is positively correlated with the length of the super-strong cold zone 210 and ensures a constant total energy release during the continuous casting process. The method of heating and cooling is to provide heating measures to the surface of the slab, and the heating energy value is greater than 5 kW/m 2 kW/m 2 .
实施例1Example 1
本实施例在某钢厂5流圆坯连铸机上进行,铸坯截面直径为380mm,在浇铸过程中对铸坯沿浇铸方向依次分别施加强冷、弱冷和加热缓冷措施,超强冷区210长度、超强冷区210冷却水流密度、加热缓冷区230加热缓冷起点、加热缓冷区230加热提供热量如表1所示;超强冷区210为从连铸结晶器300的下口至22%L,加热缓冷区230为55%L位置至凝固终点。浇铸结束后取铸坯低倍样一块,分析铸坯的柱状晶疏松情况,同时测量铸坯完全凝固时的表面温度,实施例具体参数及结果如表1所示。This embodiment is carried out on a 5 round round billet continuous casting machine of a steel mill. The cross section diameter of the billet is 380 mm. During the casting process, strong cold, weak cold and heating slow cooling measures are applied to the casting billet in the casting direction. The length of the zone 210, the cooling water flow density of the super-cooling zone 210, the heating slow cooling zone 230 heating the slow cooling starting point, and the heating slow cooling zone 230 heating provide heat as shown in Table 1; the super-strong cooling zone 210 is from the continuous casting mold 300 From the lower mouth to 22% L, the heating slow cooling zone 230 is at the 55% L position to the solidification end point. After the casting is finished, the slab is taken at a low magnification, and the columnar crystal looseness of the slab is analyzed, and the surface temperature at the time of complete solidification of the slab is measured. The specific parameters and results of the examples are shown in Table 1.
实施例2Example 2
本实施例的基本内容同实施例1,不同之处在于:超强冷区210冷却水流密度、加热缓冷起点位置和加热缓冷区230加热提供热量参数有所不同,具体参数如表1所示;浇铸结束后取铸坯低倍样一块,分析铸坯的柱状晶疏松情况,同时测量铸坯完全凝固时的表面温度,实施例具体参数及结果如表1所示。The basic content of this embodiment is the same as that of the first embodiment. The difference between the cooling water flow density of the super-strong cooling zone 210, the heating slow cooling starting point position and the heating slow cooling zone 230 is different. The specific parameters are as shown in Table 1. After the casting is finished, the slab is taken at a low magnification, and the columnar crystal looseness of the slab is analyzed, and the surface temperature at the time when the slab is completely solidified is measured. The specific parameters and results of the examples are shown in Table 1.
实施例3Example 3
本实施例在某钢厂5流圆坯连铸机上进行,铸坯截面直径为700mm,在浇铸过程中对铸坯沿浇铸方向依次分别施加强冷、弱冷和加热缓冷措施,超强冷区210长度、超强冷区210冷却水流密度、加热缓冷区230加热缓冷起点、加热缓冷区230加热提供热量如表1所示;超强冷区210为从连铸结晶器300的下口至17%L,加热缓冷区230为55%L位置至凝固终点。浇铸结束后取铸坯低倍样一块,分析铸坯的柱状晶疏松情况,同时测量铸坯完全凝固时的表面温度,实施例具体参数及结果如表1所示。This embodiment is carried out on a 5 round round billet continuous casting machine of a steel mill. The cross section diameter of the billet is 700 mm. During the casting process, strong cold, weak cold and heating slow cooling measures are applied to the casting billet in the casting direction. The length of the zone 210, the cooling water flow density of the super-cooling zone 210, the heating slow cooling zone 230 heating the slow cooling starting point, and the heating slow cooling zone 230 heating provide heat as shown in Table 1; the super-strong cooling zone 210 is from the continuous casting mold 300 From the lower mouth to 17% L, the heating slow cooling zone 230 is at the 55% L position to the solidification end point. After the casting is finished, the slab is taken at a low magnification, and the columnar crystal looseness of the slab is analyzed, and the surface temperature at the time of complete solidification of the slab is measured. The specific parameters and results of the examples are shown in Table 1.
实施例4Example 4
本实施例的基本内容同实施例3,不同之处在于:超超强冷区210冷却水流密度、加热缓冷起点位置和加热缓冷区230加热提供热量参数有所不同,具体参数如表1所示;浇铸结束后取铸坯低倍样一块,分析铸坯的柱状晶疏松情况,同时测量铸坯完全凝固时的表面温度, 实施例具体参数及结果如表1所示。实施例4铸坯低倍组织的图片如图4所示。The basic content of this embodiment is the same as that of the third embodiment. The difference between the cooling water flow density, the heating slow cooling starting point and the heating slow cooling zone 230 is different. The specific parameters are as shown in Table 1. After the casting is finished, the casting blank is taken at a low magnification, and the columnar crystal looseness of the casting blank is analyzed, and the surface temperature when the casting blank is completely solidified is measured. The specific parameters and results of the examples are shown in Table 1. A picture of the low magnification structure of the cast slab of Example 4 is shown in FIG.
对比例1Comparative example 1
本实施例的基本内容同实施例4,不同之处在于:铸坯表面的冷却强度的水流密度为200L/m 2。浇铸结束后取铸坯低倍样一块,进行低倍分析,分析铸坯的柱状晶疏松情况,同时测量铸坯完全凝固时的表面温度,对比例1具体参数及结果如表1所示,对比例1铸坯低倍组织的图片如图4所示。 The basic content of this embodiment is the same as that of Embodiment 4, except that the water flow density of the cooling strength of the surface of the slab is 200 L/m 2 . After casting, take a low-magnification sample of the slab, perform low-fold analysis, analyze the columnar crystal looseness of the slab, and measure the surface temperature when the slab is completely solidified. The specific parameters and results of Comparative Example 1 are shown in Table 1. A picture of the low-magnification structure of the proportion 1 slab is shown in Fig. 4.
表1Table 1
Figure PCTCN2019078326-appb-000001
Figure PCTCN2019078326-appb-000001
备注:表中超强冷区210长度、加热缓冷区230长度单位为L,L表示总冷却长度。Remarks: The length of the super cold zone 210 and the length of the heating slow zone 230 in the table are L, and L represents the total cooling length.
由实施结果可以看出,实施例1-4中铸坯凝固组织中柱状晶组织疏松较小,平均柱状晶疏松大小小于26.0um,且铸坯表面温度有所提高,可以效减少内部裂纹的产生,提高铸坯质量,以满足不同产品对凝固组织的需求。It can be seen from the implementation results that the columnar crystal structure in the solidification structure of the slab in Example 1-4 is relatively loose, the average columnar crystal looseness is less than 26.0 um, and the surface temperature of the slab is increased, which can effectively reduce the occurrence of internal cracks. Improve the quality of the slab to meet the demand for solidification structure of different products.
进一步的分析,图3为实施例4的铸坯微观组织的形貌示意图;图4为对比例1的铸坯微观组织的形貌示意图;其中,图3和图4中包括柱状晶区410、等轴晶区420和疏松孔430,图4中铸坯柱状晶区410域组织相对疏松,且柱状晶区410具有疏松孔430,而图3的铸坯柱状晶区410域组织致密、枝晶细致紧密,柱状晶区410的疏松孔430基本消除。而且,平均柱状晶疏松大小由37.2um降低到26.0um以下。降低了柱状晶间距和间隙,改善铸坯次表层和心部凝固组织结构,提高铸坯近表层柱状晶的致密度,同时减少内部裂纹的产生。进一步的对比可以发现,相比对比例1,实施例4不仅降低了柱状晶间距和间隙,改善铸坯次表层和心部凝固组织结构,而且扩大时等轴晶区420的比例,从而改善了铸坯的质量。For further analysis, FIG. 3 is a schematic view showing the morphology of the microstructure of the slab of Example 4; FIG. 4 is a schematic view showing the microstructure of the slab of Comparative Example 1; wherein, FIG. 3 and FIG. 4 include a columnar crystal region 410, The equiaxed crystal region 420 and the loose pores 430, the slab columnar crystal region 410 in FIG. 4 has a relatively loose domain structure, and the columnar crystal region 410 has a loose pore 430, and the slab columnar crystal region 410 of FIG. 3 is densely organized and dendritic. Finely compact, the loose holes 430 of the columnar crystal regions 410 are substantially eliminated. Moreover, the average columnar grain looseness is reduced from 37.2 um to 26.0 um. The columnar crystal spacing and gap are reduced, the secondary surface layer and the core solidification structure of the slab are improved, the density of the near-layer columnar crystal of the slab is improved, and the internal crack is reduced. Further comparison can be found that, compared with Comparative Example 1, Example 4 not only reduces the columnar crystal spacing and gap, improves the secondary surface layer and core solidification structure of the cast strand, but also enlarges the proportion of equiaxed crystal regions 420, thereby improving The quality of the slab.
在上文中结合具体的示例性实施例详细描述了本发明。但是,应当理解,可在不脱离由所附权利要求限定的本发明的范围的情况下进行各种修改和变型。详细的描述和附图应仅被认为是说明性的,而不是限制性的,如果存在任何这样的修改和变型,那么它们都将落入在此描述的本发明的范围内。此外,背景技术旨在为了说明本技术的研发现状和意义,并不旨在限制本发明或本申请和本发明的应用领域。The invention has been described in detail above with reference to specific exemplary embodiments. It should be understood, however, that various modifications and changes can be made without departing from the scope of the invention as defined by the appended claims. The detailed description and drawings are to be regarded as illustrative and not restrictive In addition, the background art is intended to illustrate the state of the art and the meaning of the present invention, and is not intended to limit the invention or the application field of the present application and the present invention.

Claims (11)

  1. 一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,在结晶器下水口至凝固终点结束的区间设置有超强冷区(210)和加热缓冷区(230),连铸坯(100)先在超强冷区(210)进行超强冷却,而后在加热缓冷区(230)进行加热缓冷,其中加热缓冷的冷却强度小于空冷的冷却强度。A method for controlling solidification structure of a slab during continuous casting, characterized in that a super-cooling zone (210) and a heating slow-cooling zone (230) are arranged in a section from the nozzle water nozzle to the end of the solidification end point, continuous casting The billet (100) is first subjected to super cooling in the super-cooling zone (210), and then heated and cooled in the heating slow cooling zone (230), wherein the cooling intensity of the heating slow cooling is less than the cooling intensity of the air cooling.
  2. 根据权利要求1所述的一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,超强冷区(210)和加热缓冷区(230)之间还设置有弱冷却区(220),所述的弱冷却区(220)冷却强度小于超强冷却的冷却强度。A method for controlling solidification structure of a slab during continuous casting according to claim 1, wherein a weak cooling zone is further disposed between the super-cooling zone (210) and the heating slow zone (230) ( 220), the weak cooling zone (220) has a cooling intensity that is less than a cooling intensity of the super-cooling.
  3. 根据权利要求2所述的一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,超强冷区(210)水流密度为Q L/m 2,弱冷却区(220)水流密度为q L/m 2,Q≥2q。 A method for controlling solidification structure of a slab during continuous casting according to claim 2, wherein the super-cooling zone (210) has a water flow density of Q L/m 2 and the weak cooling zone (220) has a water flow density of q L/m 2 , Q ≥ 2q.
  4. 根据权利要求1所述的一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,超强冷区(210)的超强冷却起点位于结晶器下水口,超强冷区(210)的长度大于12%L,其中L为总冷却长度。A method for controlling solidification structure of a slab during continuous casting according to claim 1, wherein the super-cooling starting point of the super-cooling zone (210) is located at the nozzle of the crystallizer, and the super-cool zone (210) The length of the ) is greater than 12% L, where L is the total cooling length.
  5. 根据权利要求1所述的一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,加热缓冷区(230)的加热缓冷起点与结晶器结晶器下水口之间的距离大于40%L,其中L为总冷却长度。A method for controlling solidification structure of a slab during continuous casting according to claim 1, wherein the distance between the heating slow cooling zone of the heating slow cooling zone (230) and the nozzle of the crystallizer crystallizer is greater than 40% L, where L is the total cooling length.
  6. 根据权利要求1所述的一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,圆坯连铸坯(100)的超强冷区(210)水流密度≥465L/m 2,或者矩形坯连铸坯(100)的超强冷区(210)水流密度≥490L/m 2,或者厚板连铸坯(100)的超强冷区(210)水流密度≥255L/m 2A method for controlling solidification structure of a slab during continuous casting according to claim 1, wherein the super-cooling zone (210) of the round billet continuous casting billet (100) has a water flow density of ≥ 465 L/m 2 , Or the super-cooling zone (210) of the rectangular billet continuous casting billet (100) has a water flow density of ≥ 490 L/m 2 , or the super-cooling zone (210) of the thick-plate continuous casting billet (100) has a water flow density of ≥ 255 L/m 2 .
  7. 根据权利要求1所述的一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,在加热缓冷区(230)向铸坯表面进行加热,加热的热能量值大于5kW/m 2A method for controlling solidification structure of a slab during continuous casting according to claim 1, characterized in that the surface of the slab is heated in a heating slow cooling zone (230), and the heating energy value is greater than 5 kW/m. 2 .
  8. 根据权利要求1-6任一项所述的一种控制连铸过程中铸坯凝固组织结构的方法,其特征在于,所述的加热缓冷区(230)的加热缓冷终点位于凝固终点之前。A method for controlling solidification structure of a slab during continuous casting according to any one of claims 1 to 6, characterized in that the heating slow cooling end of the heating slow cooling zone (230) is located before the solidification end point. .
  9. 一种基于加热缓冷控制铸坯凝固组织结构的装置,其特征在于:连铸结晶器(300)的下部沿着连铸坯(100)的长度方向设置有超强冷区(210)和加热缓冷区(230),超强冷区(210)用于向铸坯表面提供喷水冷却,加热缓冷区(230)用于向铸坯表面提供热量加热。A device for controlling solidification structure of a slab based on heating and slow cooling, characterized in that: a lower portion of the continuous casting mold (300) is provided with a super-strong cooling zone (210) and heating along the length direction of the continuous casting slab (100) The slow cooling zone (230), the super-cooling zone (210) is used to provide water spray cooling to the surface of the slab, and the heating slow cooling zone (230) is used to provide heat heating to the surface of the slab.
  10. 根据权利要求8所述的一种基于加热缓冷控制铸坯凝固组织结构的装置,其特征在于:加热缓冷区(230)的连铸坯(100)表面设置有电磁加热线圈(231)或者加热罩(231),其中加热罩(231)为蒸汽加热罩或者可燃性气体加热罩或者反射绝热自加热罩。The apparatus for controlling the solidification structure of a slab based on heating slow cooling according to claim 8, wherein the surface of the continuous casting slab (100) of the heating slow cooling zone (230) is provided with an electromagnetic heating coil (231) or The heating cover (231), wherein the heating cover (231) is a steam heating cover or a combustible gas heating cover or a reflective heat insulation self-heating cover.
  11. 根据权利要求8-9所述的一种基于加热缓冷控制铸坯凝固组织结构的装置,其特征在于:加热缓冷区(230)的前部设置有弱冷却区(220)。A device for controlling solidification structure of a slab based on heating slow cooling according to claims 8-9, characterized in that the front portion of the heating slow cooling zone (230) is provided with a weak cooling zone (220).
PCT/CN2019/078326 2018-03-29 2019-03-15 Method for controlling structure of solidified cast ingot in continuous casting process and control device thereof WO2019184731A1 (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108672668A (en) * 2018-03-29 2018-10-19 马鞍山钢铁股份有限公司 The method and its control device of casting blank solidification institutional framework in a kind of control casting process
CN109317631B (en) * 2018-10-30 2020-08-07 武汉钢铁有限公司 Production method for improving texture uniformity of continuous casting square billet
CN111707799A (en) * 2020-06-03 2020-09-25 攀钢集团攀枝花钢铁研究院有限公司 Heavy rail rolling region genetic characterization method based on solidification structure region correspondence
CN115383068B (en) * 2022-09-01 2024-02-27 一重集团大连工程技术有限公司 Blank tail on-line heat preservation device and method

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60130457A (en) * 1983-12-19 1985-07-11 Nippon Steel Corp Continuous casting method of steel
CN101412183A (en) 2008-11-28 2009-04-22 首钢总公司 Method for producing high-carbon chromium bearing steel by double retarded cooling process
JP2011161476A (en) * 2010-02-08 2011-08-25 Sanyo Special Steel Co Ltd Method for secondary cooling of cast slab in vertical type continuous casting
CN102586683A (en) * 2012-02-13 2012-07-18 钢铁研究总院 Ni-series low-temperature steel, manufacture method thereof, liquefied natural gas storage tank and ship body for transportation ship
CN104308111A (en) * 2014-11-19 2015-01-28 河北工程大学 Method for reducing macro segregation at 1/2R position of bearing steel wire rod
CN105583383A (en) * 2016-01-28 2016-05-18 北京科技大学 Cooling device for preventing surface of continuous cast billet from being cracked
CN108672668A (en) * 2018-03-29 2018-10-19 马鞍山钢铁股份有限公司 The method and its control device of casting blank solidification institutional framework in a kind of control casting process
CN208374145U (en) * 2018-03-29 2019-01-15 马鞍山钢铁股份有限公司 A kind of device based on heating slow cooling control casting blank solidification institutional framework

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT266362B (en) * 1966-04-22 1968-11-11 Boehler & Co Ag Geb Method and device for the production of stretch-formed products from refractory metals, in particular from unalloyed or alloyed steels with improved quality properties
AT279072B (en) * 1968-05-29 1970-02-25 Voest Ag Process for the treatment of cast strands in continuous casting plants outside the mold
GB1326635A (en) * 1970-09-18 1973-08-15 Tsnii Chernoj Metallurg Apparatus for and a method of continuous casting of metal
US3771584A (en) * 1971-01-08 1973-11-13 Roblin Industries Method for continuously casting steel billet strands to minimize the porosity and chemical segregation along the center line of the strand
JPS60257957A (en) * 1984-06-05 1985-12-19 Mitsubishi Heavy Ind Ltd Secondary cooling zone device for continuous casting device
JP2727205B2 (en) * 1988-12-02 1998-03-11 新日本製鐵株式会社 Method for improving segregation of continuous cast slab
JPH0660308B2 (en) * 1989-04-28 1994-08-10 株式会社クボタ Heat storage material
JPH0569099A (en) * 1991-09-12 1993-03-23 Nippon Steel Corp Method for improving internal quality in cast slab
JP3161917B2 (en) * 1994-09-30 2001-04-25 株式会社日立製作所 Thin slab continuous casting machine and thin slab continuous casting method
JP4055440B2 (en) * 2001-06-13 2008-03-05 Jfeスチール株式会社 Direct-rolling method for continuous cast slabs
DE102006056683A1 (en) * 2006-01-11 2007-07-12 Sms Demag Ag Continuous casting of metal profiles, first cools cast strip then permits thermal redistribution to re-heat surface before mechanical deformation
JP4899629B2 (en) * 2006-05-17 2012-03-21 住友金属工業株式会社 Billet continuous casting method
JP4690995B2 (en) * 2006-10-18 2011-06-01 新日本製鐵株式会社 Steel continuous casting method and continuous casting equipment
EP2551037A1 (en) * 2011-07-28 2013-01-30 Siemens Aktiengesellschaft Apparatus and method for temperature control of cast products
KR101511723B1 (en) * 2013-03-15 2015-04-13 주식회사 포스코 Casting apparatus and method using it
JP6452037B2 (en) * 2014-02-04 2019-01-16 日立金属株式会社 Casting method and casting apparatus
JP6608291B2 (en) * 2016-01-13 2019-11-20 日鉄エンジニアリング株式会社 Continuous casting method and continuous casting equipment

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60130457A (en) * 1983-12-19 1985-07-11 Nippon Steel Corp Continuous casting method of steel
CN101412183A (en) 2008-11-28 2009-04-22 首钢总公司 Method for producing high-carbon chromium bearing steel by double retarded cooling process
JP2011161476A (en) * 2010-02-08 2011-08-25 Sanyo Special Steel Co Ltd Method for secondary cooling of cast slab in vertical type continuous casting
CN102586683A (en) * 2012-02-13 2012-07-18 钢铁研究总院 Ni-series low-temperature steel, manufacture method thereof, liquefied natural gas storage tank and ship body for transportation ship
CN104308111A (en) * 2014-11-19 2015-01-28 河北工程大学 Method for reducing macro segregation at 1/2R position of bearing steel wire rod
CN105583383A (en) * 2016-01-28 2016-05-18 北京科技大学 Cooling device for preventing surface of continuous cast billet from being cracked
CN108672668A (en) * 2018-03-29 2018-10-19 马鞍山钢铁股份有限公司 The method and its control device of casting blank solidification institutional framework in a kind of control casting process
CN208374145U (en) * 2018-03-29 2019-01-15 马鞍山钢铁股份有限公司 A kind of device based on heating slow cooling control casting blank solidification institutional framework

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3750649A4

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