WO2019168249A8 - Ligand, oligomerization catalyst comprising same, and method for producing ethylene oligomer by using oligomerization catalyst - Google Patents

Ligand, oligomerization catalyst comprising same, and method for producing ethylene oligomer by using oligomerization catalyst Download PDF

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Publication number
WO2019168249A8
WO2019168249A8 PCT/KR2018/012025 KR2018012025W WO2019168249A8 WO 2019168249 A8 WO2019168249 A8 WO 2019168249A8 KR 2018012025 W KR2018012025 W KR 2018012025W WO 2019168249 A8 WO2019168249 A8 WO 2019168249A8
Authority
WO
WIPO (PCT)
Prior art keywords
oligomerization catalyst
ligand
same
catalyst
producing ethylene
Prior art date
Application number
PCT/KR2018/012025
Other languages
French (fr)
Korean (ko)
Other versions
WO2019168249A1 (en
Inventor
이호성
조용남
Original Assignee
에스케이이노베이션 주식회사
에스케이종합화학 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020180119906A external-priority patent/KR102605188B1/en
Application filed by 에스케이이노베이션 주식회사, 에스케이종합화학 주식회사 filed Critical 에스케이이노베이션 주식회사
Priority to CN201880057196.4A priority Critical patent/CN111094308B/en
Priority to US16/771,857 priority patent/US11224870B2/en
Priority to JP2020512872A priority patent/JP7210552B2/en
Priority to EP18907972.6A priority patent/EP3760634A4/en
Publication of WO2019168249A1 publication Critical patent/WO2019168249A1/en
Publication of WO2019168249A8 publication Critical patent/WO2019168249A8/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

The present invention relates to a ligand, an ethylene oligomerization catalyst comprising same, and a method for selectively producing 1-hexene or 1-octene from ethylene by using the catalyst. The ligand according to the present invention is a bis (diphenylphosphino) ethene with a phosphorus atom substituted with a fluoro-substituted phenyl, and when the ligand is used for ethylene oligomerization, the high temperature activity of the catalyst can be increased.
PCT/KR2018/012025 2018-02-27 2018-10-12 Ligand, oligomerization catalyst comprising same, and method for producing ethylene oligomer by using oligomerization catalyst WO2019168249A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201880057196.4A CN111094308B (en) 2018-02-27 2018-10-12 Ligand, oligomerization catalyst comprising the same, and method for preparing ethylene oligomer using the oligomerization catalyst
US16/771,857 US11224870B2 (en) 2018-02-27 2018-10-12 Ligand, oligomerization catalyst comprising same, and method for producing ethylene oligomer by using oligomerization catalyst
JP2020512872A JP7210552B2 (en) 2018-02-27 2018-10-12 Ligand, oligomerization catalyst containing the same, and method for producing ethylene oligomer using the same
EP18907972.6A EP3760634A4 (en) 2018-02-27 2018-10-12 Ligand, oligomerization catalyst comprising same, and method for producing ethylene oligomer by using oligomerization catalyst

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2018-0023819 2018-02-27
KR20180023819 2018-02-27
KR1020180119906A KR102605188B1 (en) 2018-02-27 2018-10-08 Ligand, Oligomerization Catalyst And Process For Preparing Ethylene Oligomer Using Thereof
KR10-2018-0119906 2018-10-08

Publications (2)

Publication Number Publication Date
WO2019168249A1 WO2019168249A1 (en) 2019-09-06
WO2019168249A8 true WO2019168249A8 (en) 2020-02-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2018/012025 WO2019168249A1 (en) 2018-02-27 2018-10-12 Ligand, oligomerization catalyst comprising same, and method for producing ethylene oligomer by using oligomerization catalyst

Country Status (1)

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WO (1) WO2019168249A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111905832B (en) * 2020-07-23 2023-02-03 天津科技大学 Catalyst system for selective oligomerization of ethylene, reaction method and application thereof
CN114163475B (en) * 2021-12-01 2023-07-28 浙江智英石化技术有限公司 Catalyst system containing pyrrole rigid structure multi-site ligand, preparation method and application
CN116328832A (en) * 2021-12-24 2023-06-27 中国石油化工股份有限公司 Organic polymer carrier, main catalyst, ethylene polymerization catalyst composition and application thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
DE60331252D1 (en) 2002-12-20 2010-03-25 Sasol Tech Pty Ltd TRIMERIZATION OF OLEFINES
CN1566041A (en) * 2003-06-13 2005-01-19 中国科学院化学研究所 Ethylene oligomerization catalysis system and preparation method and application thereof
US8003839B2 (en) * 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
KR101846031B1 (en) * 2012-03-16 2018-04-05 에스케이이노베이션 주식회사 Catalyst Systems for Preparing 1-Hexene and/or 1-Octene from Ethylene

Also Published As

Publication number Publication date
WO2019168249A1 (en) 2019-09-06

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