WO2019156246A1 - Composition for pest control - Google Patents

Composition for pest control Download PDF

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Publication number
WO2019156246A1
WO2019156246A1 PCT/JP2019/004747 JP2019004747W WO2019156246A1 WO 2019156246 A1 WO2019156246 A1 WO 2019156246A1 JP 2019004747 W JP2019004747 W JP 2019004747W WO 2019156246 A1 WO2019156246 A1 WO 2019156246A1
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WO
WIPO (PCT)
Prior art keywords
compound
group
pest control
agrochemical
dichloromesothiaz
Prior art date
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PCT/JP2019/004747
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French (fr)
Japanese (ja)
Inventor
岳史 山我
新太郎 阿部
Original Assignee
全国農業協同組合連合会
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Publication of WO2019156246A1 publication Critical patent/WO2019156246A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00—Stationary means for catching or killing insects
    • A01M1/20—Poisoning, narcotising, or burning insects
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Definitions

  • the present invention relates to a pest control composition containing dichloromezzothiaz and other agricultural chemical compounds.
  • Dichloromezothiaz is a mesoionic compound that exhibits a high effect on pests such as diamondback moth, blue caterpillar, mushroom, hornworm, hornbill beetle, and wasp.
  • patent document 1 the effect with respect to the pest of a dichloromezzothiaz is illustrated.
  • this document describes a method of use mixed with other pesticides, there are no specific use cases and no mention of synergistic effects.
  • the present invention provides a pesticidal composition containing dichloromesothiaz as an active ingredient and at least one other pesticidal agent, and a method of using the same.
  • the present invention relates to the following inventions: [1] Dichloromesothiaz (a) as an active ingredient, diamide, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, phenylpyrazole, nereistoxin analog, and diacyl-hydrazine
  • a pest control composition comprising at least one agrochemical compound selected from the group consisting of: or an agriculturally acceptable salt (b) thereof.
  • the agrochemical compound (b) is a diamide compound selected from the group consisting of cyantraniliprole, fulvendiamide, and chlorantraniliprole.
  • the agrochemical compound (b) is acrinatrin, imiprothrin, etofenprox, empentrin, cycloprotorin, cyhalothrin, ciphenothrin, cyfluthrin, cypermethrin, tefluthrin, teraretrin, bifenthrin, phenolate, fenvalerate, fenpropatrin, Phthalthrin, praretrin, flucitrinate, fulvalinate, flumethrin, profluthrin, permethrin, monfluorotrin, alpha-cypermethrin, alletrin, esfenvalerate, dimethylfluthrin, silafluophene, zeta-cypermethrin, tau-fulvalinate, tetramethrin, deltamethrin, Tralomethrin, transfluthrin, pyre
  • the composition for controlling pests according to Item 1 which is a pyrethroid compound selected from the group consisting of, lambda-cyhalothrin, and resmethrin.
  • the agrochemical compound (b) is a neonicotinoid compound selected from the group consisting of imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, thiacloprid, and thiamethoxam.
  • the agrochemical compound (b) is a spinosyn compound selected from the group consisting of spinetoram and spinosad.
  • the agrochemical compound (b) is a chitin biosynthesis inhibitor selected from the group consisting of teflubenzuron, buprofezin, chlorfluazuron, diflubenzuron, flufenoxuron, lufenuron, novallon, and polyoxins.
  • the composition for pest control as described.
  • the pest control composition according to item 1 wherein the agrochemical compound (b) is a nereistoxin analog compound selected from the group consisting of cartap, bensultap, thiocyclam, and thiosultap sodium.
  • the agrochemical compound (b) is a diacyl-hydrazine compound selected from the group consisting of tebufenozide, chromafenozide, halofenozide, and methoxyphenozide.
  • any of items 1 to 9, comprising the dichloromesothiaz (a) and the agrochemical compound (b) in a weight ratio of (a) / (b) of 1/1000 to 1000/1.
  • a composition for controlling pests according to claim 1. [11] The pest control composition as described in any one of items 1 to 10, which comprises an agriculturally acceptable carrier, a bulking agent and / or a surfactant.
  • a group consisting of dichloromezothiaz (a) and diamide, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, phenylpyrazole, nereistoxin analog, and diacyl-hydrazine A method for controlling pests, comprising applying at least one agrochemical compound selected from the above or an agriculturally acceptable salt (b) thereof.
  • agrochemical compound selected from the above or an agriculturally acceptable salt (b) thereof comprising applying at least one agrochemical compound selected from the above or an agriculturally acceptable salt (b) thereof.
  • the present invention relates to a pest control composition
  • a pest control composition comprising dichloromethozothiaz (a) as an active ingredient and at least one other agricultural chemical compound or agriculturally acceptable salt (b).
  • the other agrochemical compound (b) that can be mixed with dichloromesothiaz (a) may be any compound that can be used for agrochemicals.
  • agrochemical compounds include insecticides, fungicides, fungicides, bactericides, acaricides, nematicides, herbicides, plant growth regulators.
  • Specific examples of the agrochemical compound include those described in Shibuya Index (SHIBUYA INDEX 17th Edition, 2014, SHIBUYA INDEX RESEARCH GROUP issued).
  • diamide diamide, Na channel inhibitor, electron transport system I inhibitor, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, benzoylurea, carbamate, organophosphorus, phenylpyrazole And compounds included in nereistoxin analogs, sulfoximines, butenolides, mesoionics, avermectins, juvenile hormone analogs, nereistoxin analogs, diacyl-hydrazines.
  • diamide, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, phenylpyrazole, nereistoxin analogues from the viewpoint of exhibiting synergistic action in combination with dichloromesothiaz (a) And diacyl-hydrazine compounds are particularly preferred.
  • Agrochemical compounds can also be classified by the mechanism of action, such as acetylcholinesterase inhibitors, GABAergic chloride channel blockers, sodium channel modulators, nicotinic acetylcholine receptor competitive modulators, nicotinic acetylcholine allosteric modulators, glutamate agonists.
  • Chloride channel allosteric modulator juvenile hormone analog, other non-specific inhibitors, TRPV channel modulator, mite growth inhibitor, microbial insect midgut membrane disruptor, mitochondrial ATP synthase inhibitor, oxidative Phosphorylated uncoupler, nicotinic acetylcholine receptor channel blocker, chitin biosynthesis inhibitor, molting inhibitor, molting hormone receptor agonist, octopamine receptor Gonist, mitochondrial electron transport complex III inhibitor, mitochondrial electron transport complex I inhibitor (METI), voltage-gated sodium channel blocker, acetyl CoA carboxylase inhibitor, mitochondrial electron transport complex IV inhibitor, mitochondrial electron Examples thereof include a transmission system complex II inhibitor and a linoadin receptor modulator.
  • GABAergic chloride channel blockers GABAergic chloride channel blockers, linoadin receptor modulators, sodium channel modulators, nicotinic acetylcholine receptor competitive modulators, nicotinic properties, from the viewpoint of exerting synergistic action in combination with dichloromesothiaz (a)
  • Particularly preferred are compounds having the action of acetylcholine receptor allosteric modulators, nicotinic acetylcholine receptor channel blockers, and molting hormone receptor agonist chitin biosynthesis inhibitors.
  • examples of the diamide-based agricultural chemical compound include cyantraniliprole, fulvendiamide, chlorantraniliprole, cyclaniliprol and tetraniliprol.
  • cyantraniliprole and fulvendiamide can be used in particular.
  • examples of the compound having a voltage-dependent sodium channel inhibitory action include metaflumizone and indoxacarb.
  • metaflumizone can be used in particular.
  • examples of the compound having an electron transport system I inhibitory action include phenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, and tolfenpyrad.
  • tolfenpyrad can be used in particular.
  • pyrethroid-based agrochemical compounds include the following: acrinatrin, imiprotrine, etofenprox, empentrin, cycloprotorin, cyhalothrin, ciphenothrin, cyfluthrin, cypermethrin, teflutrin, teraretrin, bifenthrin, phenvalerate, fen Propatrin, phthalthrin, praretrin, flucitrinate, fulvalinate, flumethrin, profluthrin, permethrin, monfluorotrin, alpha-cypermethrin, alletrin, esfenvalerate, dimeflutrin, silafluophene, zeta-cypermethrin, tau-fulvalinate, tetramethrin , Deltamethrin, tralomethrin, transfluthrin, pyr
  • neonicotinoid-based agricultural chemical compounds include imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, thiacloprid, and thiamethoxam.
  • imidacloprid can be used in particular.
  • spinetoram and spinosad are mentioned as spinosyn-based agricultural chemical compounds.
  • spinetoram can be used in particular.
  • teflubenzuron bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, nobiflumuron, triflumuron are listed as benzoylurea-based agricultural chemical compounds.
  • teflubenzuron can be used in particular.
  • an organophosphorus agrochemical compound acephate, azamethiphos, azinephosethyl, azinephosmethyl, kazusafos, chloretiophos, chlorfenvinphos, chlormefos, chlorpyrifos, chlorpyrifosmethyl, coumaphos, cyanophos, dimethone-S-methyl, diazinon, dichlorvos, Dicrotophos, dimethoate, dimethylvinphos, ethylthiomethone (disulfoton), EPN, ethion, etoprophos, fanful, phenamiphos, fenitrothion, fenthion, phosthiazeto, heptenophos, imisiaphos, isofenphos, isoxathione, malathion, mecarbam, methamidophos, methidathione, vin , Ometo
  • phenylpyrazole-based agricultural chemical compounds include ethiprol, fipronil, pyrafluprolol, and pyriprolol.
  • sulfoxafluorol may be mentioned as a sulfoximine-based agricultural chemical compound.
  • flupiradiflon as a butenolide-based agrochemical compound, flupiradiflon may be mentioned.
  • triflumezopyrim may be mentioned as a mesoionic pesticide compound.
  • avermectin-based agrochemical compounds include abamectin, emamectin benzoate, lepimectin, and milbemectin.
  • pyriproxyfen, hydroprene, quinoprene, methoprene, and phenoxycarb are listed as agrochemical compounds having juvenile hormone-like activity.
  • examples of nereistoxin analogs include bensultap, cartap, thiocyclam, and thiosultap.
  • diacyl-hydrazine-based agricultural chemical compounds include tebufenozide, chromafenozide, halofenozide, and methoxyphenozide.
  • examples of the acetylcholinesterase inhibitor include the aforementioned carbamate compounds and organophosphorus compounds.
  • examples of the GABA-acting chloride channel blocker include the aforementioned phenylpyrazole compounds.
  • examples of the sodium channel modulator include the pyrethroid compounds described above.
  • nicotinic acetylcholine receptor competitive modulators include nicotine sulfate, sulfoxafurol, flupiradiflon, and triflumezopyrim in addition to the aforementioned neonicotinoid compounds.
  • nicotinic acetylcholine allosteric modulators examples include spinosyn compounds.
  • glutamate-acting chloride ion channel allosteric modulators include the avermectin-based compounds described above.
  • non-specific inhibitors include methyl bromide, chloropicrin, sulfuryl fluoride, borax, boric acid, disodium octaborate, sodium metaborate, tartar, tazomet, and carbam.
  • TRPI channel modulators include pymetrozine and pyrifluquinazone.
  • mite growth inhibitors examples include clofentedine, difluvidazine, hexythiazox, and etoxazole.
  • microorganism-derived insect midgut lining agents include Bacillus thuringiensis and Bacillus sphaericus, and insecticidal protein products derived from the microorganism.
  • mitochondrial ATP synthase inhibitors examples include diafenthiuron, azocyclotin, tricyclohexyltin hydroxide (cyhexatin), fenbutaine oxide, propargite, and tetradiphone.
  • Examples of oxidative phosphorylation uncouplers that disturb the proton gradient include chlorfenapyr, DNOC, and sulfuramide.
  • nicotinic acetylcholine receptor channel blockers examples include the aforementioned nereistoxin analogs.
  • chitin biosynthesis inhibitors include buprofezin and polyoxins in addition to the aforementioned benzoylurea compounds.
  • Ciromazine is mentioned as a molting inhibitor.
  • molting hormone receptor agonists examples include chromafenozide, halofenozide, methoxyphenozide, and tebufenozide.
  • An example of an octopamine receptor agonist is amitraz.
  • mitochondrial electron transport system complex III inhibitors examples include hydramethylnon, acequinosyl, fluacrylpyrim, and bifenazate.
  • I inhibitors include rotenone in addition to the above-mentioned METI agents.
  • acetyl CoA carboxylase inhibitors include spirodiclofen, spiromesifen, and spirotetramat.
  • mitochondrial electron transport system complex IV inhibitors examples include aluminum phosphide, calcium phosphide, hydrogen phosphide, zinc phosphide, calcium cyanide, sodium cyanide and potassium cyanide.
  • mitochondrial electron transport system complex II inhibitors examples include sienopyrafen, cyflumetofene, and pivlummid.
  • linoadin receptor modulators examples include chlorantraniliprole, cyantraniliprolol, and fulvendiamide.
  • Drugs relating to other mechanisms of action such as flonicamid, azadirachtin, benzoximate, bromopropyrate, quinomethionate, dicophore, GS- ⁇ / ⁇ HXTX-HV1a peptide, lime sulfur combination, pyridalyl, sulfur, etc. are also used as agrochemical compounds in the present invention. It can be used for a pest control composition.
  • other agrochemical compounds include, but are not limited to: Phenylamide type: Benalaxyl, Benalaxyl M, Furaraxyl, Metalaxyl, Metalaxyl M, oxadixyl, oflase, cyprofuran, etc .; Hydroxy- (2-amino-) pyrimidine series: bupilimate, dimethylylmol, ethylimol, etc .; Aromatic heterocyclic system: hydroxyisoxazole (himexazole), octirinone, etc .; Carboxylic acid type: Oxolinic acid, etc .; Methylbenzimidazole carbamates: benomyl, carbendazole (carbendazim), fuberidazole, thiabendazole, thiophanate, thiophanate methyl, etc .; N-phenyl carbamate type: dietofencarb, etc .; Benz
  • the agricultural chemical compound (b), which is an active ingredient used in the present invention, includes agriculturally acceptable salts.
  • agriculturally acceptable salts include: salts of alkali metals such as sodium or potassium; salts of alkaline earth metals such as calcium, magnesium or barium; salts of transition metals such as manganese, copper, zinc or iron; ammonium A salt (the nitrogen atom may be optionally substituted by 1-4 alkyl groups having 1-4 carbon atoms and / or one phenyl or benzyl substituent), preferably diisopropylammonium, tetramethyl Ammonium, tetrabutylammonium, trimethylbenzylammonium; salt with inorganic acid such as hydrochloric acid, hydrobromic acid, phosphoric acid or sulfuric acid; C 1 -C 4 alkylsulfonic acid such as methanesulfonic acid, benzenesulfonic acid or toluenesulfonic acid Aromatic sulfonic acid such
  • a pest control composition further comprising a suitable agriculturally and horticulturally acceptable carrier, the form of which is an emulsion, solution, suspension, wettable powder, granule. It is provided to be formulated into any dosage form such as a wettable powder, a flowable powder, a powder, a DL powder, a granule, a fine powder F, a tablet, an oil, an aerosol, a smoke, a microcapsule.
  • a suitable agriculturally and horticulturally acceptable carrier the form of which is an emulsion, solution, suspension, wettable powder, granule. It is provided to be formulated into any dosage form such as a wettable powder, a flowable powder, a powder, a DL powder, a granule, a fine powder F, a tablet, an oil, an aerosol, a smoke, a microcapsule.
  • a suitable agriculturally and horticulturally acceptable carrier the form of which is an emulsion, solution
  • the pest control composition of the present invention is applied in any form that exhibits a synergistic action.
  • dichloromezzothiaz (a) which is an active ingredient contained in the composition for controlling pests of the present invention, and other agricultural chemical compounds or agriculturally acceptable salts (b) thereof are the above-mentioned 1 It is applied directly or after dilution with an appropriate diluent as a pre-formulated preparation in this dosage form.
  • the dichloromesothiaz (a) which is an active ingredient contained in the pest control composition of the present invention, and other agricultural chemical compounds or agriculturally acceptable salts (b) thereof are used.
  • dichloromesothiaz (a) and other pesticidal compounds or agriculturally acceptable salts (b) thereof may be applied separately and sequentially in the same area. When applied sequentially, the order is arbitrary, and after applying one, the other can be applied after an arbitrary time.
  • the application interval can be arbitrarily selected within a range in which a synergistic effect is exhibited. For example, the application interval can be applied for 1 hour to several hours, and in some cases, several days.
  • Pesticides in which dichloromesothiaz (a) and other agricultural chemical compounds or agriculturally acceptable salts (b) thereof are not mixed in advance can be referred to as combined agricultural chemicals, kit agricultural chemicals, and the like.
  • the carrier that can be used can be appropriately selected depending on the dosage form of the composition.
  • the carrier include a solid carrier, a liquid carrier, a gaseous carrier, a surfactant, a dispersant, and other formulation adjuvants. .
  • solid carrier examples include talc, bennite, clay, kaolin, diatomaceous earth, vermiculite, white carbon, calcium carbonate and the like.
  • liquid carrier examples include alcohols such as methanol, n-hexanol and ethylene glycol, ketones such as acetone, methyl ethyl ketone and cyclohexanone, aliphatic hydrocarbons such as n-hexane, kerosene and kerosene, toluene, xylene and methyl Aromatic hydrocarbons such as naphthalene, ethers such as diethyl ether, dioxane and tetrahydrofuran, esters such as ethyl acetate, nitriles such as acetonitrile and isobutyronitrile, acid amides such as dimethylformamide and dimethylacetamide, soybean Examples include oils, vegetable oils such as cotton seed drops, dimethyl sulfoxide, and water.
  • alcohols such as methanol, n-hexanol and ethylene glycol
  • ketones such as acetone, methyl ethyl ket
  • gaseous carrier examples include LPG, air, nitrogen, carbon dioxide gas, dimethyl ether and the like.
  • Surfactants and dispersants for emulsification, dispersion, spreading, etc. include, for example, alkyl sulfates, alkyl (aryl) sulfonates, polyoxyalkylene alkyl (aryl) ethers, polyhydric alcohol esters, Lignin sulfonate and the like are used.
  • auxiliary agent for improving the properties of the preparation for example, carboxymethyl cellulose, gum arabic, polyethylene glycol, calcium stearate and the like are used.
  • the above carriers, surfactants, dispersants, and adjuvants may be used alone or in combination as necessary.
  • the total amount of active ingredients in the composition of the invention is 0.1 to 99.9% by weight, preferably 0.4 to 80% by weight, and more preferably 2 to 80%.
  • the mixing ratio of the dichloromesothiaz (a) and the other agrochemical compound (b) can be varied over a wide range, but the dichloromezothiaz (a) is usually 0.1 to 80%, preferably 0 2 to 40%, more preferably 1 to 40%, and other agrochemical compounds 0.1 to 80%, preferably 0.2 to 40%, more preferably 1 to 40%.
  • the mixing ratio of dichloromesothiaz (a) and other agrochemical compound (b) may be arbitrarily determined by those skilled in the art within a range in which a desired effect is exhibited. From the viewpoint of exhibiting a desired effect, the mass ratio of (a) / (b) can be set to 1/1000 to 1000/1, more preferably 1/100 to 100/1.
  • the pest control composition further comprising an agriculturally and horticulturally acceptable carrier in a preferred embodiment includes the following: (1) 0.1 to 80% by weight of dichloromesothiaz (a), 0.1 to 80% by weight of other agrochemical compound (b), 0.6 to 30% by weight of wetting agent and dispersant, A composition in wettable powder form containing 20-95% by weight of a bulking agent; (2) 0.1 to 80% by weight of dichloromezzothiaz (a), 0.1 to 80% by weight of other agrochemical compound (b), 0.6 to 30% of wetting agent, dispersant and binder %, A composition in the form of a water dispersible granule containing 20-95% by weight of a bulking agent, (3) Dichloromesothiaz (a) 0.1-80% by weight, other agrochemical compound (b) 0.1-80% by weight, dispersant, thickener, antifreezing agent, preservative and antifoam A composition in the form of a suspension concentrate containing 5
  • the composition of the present invention is left as it is or diluted, and an effective amount of the target pest, the target useful plant, the propagation material of the target useful plant, such as seeds, tuberous root, soil, etc.
  • the present invention provides a method for using a pest control composition, characterized by being applied to a region where a cultivation carrier and a target useful plant grow.
  • an effective amount of dichloromesothiaz (a) and other agrochemical compound or agriculturally acceptable salt thereof (b) is used as a target pest, target useful plant, target useful plant propagation material,
  • a method for controlling pests including application to an area where seeds, tuberous roots, etc., soil, a cultivation carrier, or a target useful plant grows, for example, a field.
  • examples of the method for treating the composition of the present invention with the target pest, the target useful plant, the seed of the target useful plant, the soil, or the cultivation carrier include spraying treatment, soil treatment, surface treatment, or fumigation treatment.
  • examples of the spraying treatment include spraying, spraying, misting, atomizing, dusting, and water surface application.
  • examples of soil treatment include soil irrigation and soil mixing.
  • examples of the surface treatment include application, powder coating, and coating.
  • fumigation processing covering soil with a poly film after soil injection
  • the composition for controlling pests of the present invention can be used for any application using dichloromesothiaz. That is, the pest control composition of the present invention can be used for controlling pests such as insects, ticks, aphids, spiders, nematodes, snails, fungi, bacteria, and viruses. Therefore, the composition of the present invention can be used as an insecticidal composition, a bactericidal composition, an acaricidal composition, a nematicidal composition, a molluscicidal composition, a bactericidal composition, and an antiviral composition.
  • Pests that exhibit the control effect of the composition of the present invention include the following: Lepidopterous pests (for example, moths such as Spodoptera spp. , White butterflies such as white butterflies, striped moths such as genus Adoxofies, prickly moths, codling moths, sink moths such as peaches moths, leaf moths such as Rionetia genus, dogas moths such as Limantria genus, sugas such as cotton squirrels , Higgaris such as white-spotted starfish, Hirokosukaga such as igai and koiga, Bokutoga such as Himebokuto, Akaeguriba, Himeiguriba, Akebikono ⁇ such as, etc.), Hemiptera (for example, silver leaf whitefly, tobacco whitefly, whitefly whitefly) such as whitefly (Aleyrodidae), peach aphid, cotton aphid, etc
  • Leafhoppers such as Japanese beetle, planthoppers (Cixididae), such as Japanese brown planthopper, Japanese brown planthopper, white-headed beetle, white-headed beetle, white-headed beetle, white-tailed beetle (Mididaidae), , lataspidae, Scutelleridae, Urostylidae, Berytidae, Lygaeidae, Malcidae, Largidae, Pyrrhocoridae, Alydidae, Coreidae, Rhopalidae), mulberry mealybugs, scale insects such as oranges mealybugs (Diaspididae, Margarodidae, Ortheziidae, Aclerdiae, Dactylopiidae, Kerridae, Pseudococcidae, Coccidae , Eriococcidae, Astero
  • weevil such as maize weevil, rice weevil, azuki beetle
  • worm beetle such as chalcedoridae, scarab beetle such as stag beetle, scallop, potato beetle, cucumber potato beetle, Colorado western corn Worms such as worms, paddy beetles, blue-spotted beetles, sinkworms, epilacunas such as scallops, and longhorn beetles;
  • Dust mites (Tarsonmididae) such as chano dust mites, fusida such as tomato rust mites and citrus mites S (Eriophyidae), such as grain mites), Hymenopteran pests (for example, wasps such as wasp (Tenthredinidae, Pamphiidae, Argidae, Cimbicidae, Diplionidae)) Diptera pests (for example, grasshoppers),
  • Test Example 1 Lobster Pest Control Test Cut leaves of about 9 cm in diameter from pot-grown cabbage, and water (0.02% neoesterin) so that dichloromesothiaz and other pesticide compounds have a predetermined concentration as shown in Table 1.
  • the cabbage leaf was immersed in the composition of the present invention prepared in (Additional) for 1 minute. After air drying, this was transferred to a 9 cm diameter plastic cup with filter paper. Thereafter, 10 third-instar larvae were released per cup, covered with a cup, and left in a constant temperature room at 25 ° C. (16 hours light period-8 hours dark period). Three days after the release, the mortality of the insects was observed, the corrected death rate was calculated according to the following formula, and the results are shown in Table 1.
  • Corrected death rate (%) ⁇ (untreated group survival rate ⁇ treated group survival rate) / untreated group survival rate ⁇ ⁇ 100
  • the theoretical value when there is no synergistic effect is calculated according to the following Colby equation, and the results are shown in Table 1 (Calculation of the synergistic and antagonistic responses of herbicide combinations Weeds, (1967), vol. 15, pages 20-22: Non-Patent Document 1).
  • Colby's formula: Theoretical value (%) (A + B) ⁇ (A ⁇ B) / 100 (A: 100- (rate of death when compound A alone is treated) B: 100- (Death rate when only compound B is treated)
  • Test Example 2 Sweet potato control test A leaf of about 9 cm in diameter was cut from a pot-grown cabbage, and water (0.02% neoesterin was added to a predetermined concentration of dichloromezzothiaz and other insecticides as shown in Table 1.
  • the cabbage leaf was immersed in the composition of the present invention prepared in (Additional) for 1 minute. After air drying, this was transferred to a 9 cm diameter plastic cup with filter paper. Thereafter, 10 third instar larvae were released per cup, the cup was covered, and left in a constant temperature room at 25 ° C. (16 hours light period-8 hours dark period). Three days after the release, the mortality of the insects was observed, the corrected death rate was calculated according to the following formula, and the results are shown in Table 1.

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Abstract

The present invention provides a composition for pest control, which exhibits a reliable controlling effect on a wide variety of pests at lower doses by using dicloromezotiaz in combination with another chemical agent. The present invention provides a composition for pest control, which contains dicloromezotiaz and at least one other agrochemical compound as active ingredients.

Description

有害生物防除用組成物Pest control composition
　本発明はジクロロメゾチアズと他の農薬化合物を含有する、有害生物防除用組成物に関する。 The present invention relates to a pest control composition containing dichloromezzothiaz and other agricultural chemical compounds.
　従来から数多くの農薬が、有害生物防除のために使用されている。発生する種々の有害生物を防除するため、複数の薬剤を使用することは一般的であるが、使用者の作業省力化などの理由から、タンクミックス法により施用前に混合する混合農薬や、２種類以上の活性成分をあらかじめ含有する農薬が販売されている。シブヤインデックス（SHIBUYA INDEX　第１７版、２０１４年、ＳＨＩＢＵＹＡ　ＩＮＤＥＸ　ＲＥＳＥＡＲＣＨ　ＧＲＯＵＰ発行、非特許文献２）には、これまでに開発された多くの有害生物防除用組成物に関する記載がある。ジクロロメゾチアズに関しても、特許文献１（特許５７７７６１９号公報）によりその使用事例を開示している。 A lot of pesticides have been used for pest control. In order to control various pests that occur, it is common to use multiple chemicals. However, for reasons such as saving labor for users, mixed agricultural chemicals that are mixed before application by the tank mix method, 2 Agricultural chemicals containing more than one kind of active ingredient in advance are sold. The Shibuya Index (SHIBUYA INDEX 17th edition, 2014, published by SHIBUYA INDEX RESEARCH GROUP, Non-Patent Document 2) describes many pest control compositions that have been developed so far. Regarding dichloromesothiaz, use cases thereof are disclosed in Patent Document 1 (Japanese Patent No. 5777619).
　ジクロロメゾチアズは、コナガ、アオムシ、ヨトウガ、ハスモンヨトウ、キスジノミハムシ、カブラハバチなどの害虫に高い効果を示すメソイオン系化合物である。特許文献１においては、ジクロロメゾチアズの有害生物に対する効果が例示されている。この文献において、他の農薬と混合する使用方法について記載されているものの、具体的な使用事例はなく、相乗効果についてもなんら言及されていない。 Dichloromezothiaz is a mesoionic compound that exhibits a high effect on pests such as diamondback moth, blue caterpillar, mushroom, hornworm, hornbill beetle, and wasp. In patent document 1, the effect with respect to the pest of a dichloromezzothiaz is illustrated. Although this document describes a method of use mixed with other pesticides, there are no specific use cases and no mention of synergistic effects.
特許５７７７６１９号公報Japanese Patent No. 5777619
　農業においては、環境への配慮、作業者の暴露影響、処理コスト低減の目的から、より低薬量での有害生物防除が望まれている。とりわけ、薬剤感受性の低い害虫種や薬剤抵抗性が発達した害虫種について、より確実に防除するための手段について高い関心が持たれている。 In agriculture, pest control at lower doses is desired for environmental considerations, exposure effects of workers, and processing cost reduction. In particular, there is a high interest in means for more reliably controlling pest species with low drug sensitivity and pest species with developed drug resistance.
　本発明者らは、ジクロロメゾチアズと他の有害生物防除組成物との組み合わせを鋭意検討した結果、害虫に対し、単独成分から予想できない、優れた防除効果（相乗的な効果）を見出し、本発明を完成した。 As a result of earnestly examining the combination of dichloromesothiaz and other pest control compositions, the present inventors have found an excellent control effect (synergistic effect) that cannot be expected from a single component against pests, The present invention has been completed.
　すなわち、本発明は、有効成分としてジクロロメゾチアズと、他の有害生物防除剤のすくなくとも１種とを含有する有害生物防除組成物およびその使用方法を提供するものである。 That is, the present invention provides a pesticidal composition containing dichloromesothiaz as an active ingredient and at least one other pesticidal agent, and a method of using the same.
　すなわち、本発明は、以下の発明に関する：
［１］　有効成分としてジクロロメゾチアズ（ａ）と、ジアミド系、ピレスロイド系、ネオニコチノイド系、スピノシン系、キチン生合成阻害剤、フェニルピラゾール系、ネライストキシン類縁体、及びジアシル－ヒドラジン系からなる群から選ばれる少なくとも１の農薬化合物又はその農業上許容される塩（ｂ）を含有する有害生物防除用組成物。
［２］　前記農薬化合物（ｂ）が、シアントラニリプロール、フルベンジアミド、及びクロラントラニリプロールからなる群から選ばれるジアミド系化合物である、項目１に記載の有害生物防除用組成物。
［３］　前記農薬化合物（ｂ）が、アクリナトリン、イミプロトリン、エトフェンプロックス、エムペントリン、シクロプロトリン、シハロトリン、シフェノトリン、シフルトリン、シペルメトリン、テフルトリン、テラレトリン、ビフェントリン、フェノトリン、フェンバレレート、フェンプロパトリン、フタルスリン、プラレトリン、フルシトリネート、フルバリネート、フルメトリン、プロフルトリン、ペルメトリン、モンフルオロトリン、アルファ－シペルメトリン、アレトリン、エスフェンバレレート、ジメフルトリン、シラフルオフェン、ゼータ－シペルメトリン、タウ－フルバリナート、テトラメトリン、デルタメトリン、トラロメトリン、トランスフルトリン、ピレトリン、ピレトリンＩおよびＩＩ、ベータ－シペルメトリン、ラムダ－シハロトリン、及びレスメトリンからなる群から選ばれるピレスロイド系化合物である、項目１に記載の有害生物防除用組成物。
［４］　前記農薬化合物（ｂ）が、イミダクロプリド、アセタミプリド、クロチアニジン、ジノテフラン、ニテンピラム、チアクロプリド、及びチアメトキサムからなる群から選ばれるネオニコチノイド系化合物である、項目１に記載の有害生物防除用組成物。
［５］　前記農薬化合物（ｂ）が、スピネトラム、及びスピノサドからなる群から選ばれるスピノシン系化合物である、項目１に記載の有害生物防除用組成物。
［６］　前記農薬化合物（ｂ）が、テフルベンズロン、ブプロフェジン、クロルフルアズロン、ジフルベンズロン、フルフェノクスロン、ルフェヌロン、ノバルロン、及びポリオキシン類からなる群から選ばれるキチン生合成阻害剤である、項目１に記載の有害生物防除用組成物。
［７］　前記農薬化合物（ｂ）が、フィプロニル及びエチプロールからなる群から選ばれるフェニルピラゾール系化合物である、項目１に記載の有害生物防除用組成物。
［８］　前記農薬化合物（ｂ）が、カルタップ、ベンスルタップ、チオシクラム、及びチオスルタップナトリウムからなる群から選ばれる、ネライストキシン類縁体化合物である、項目１に記載の有害生物防除用組成物。
［９］　前記農薬化合物（ｂ）が、テブフェノジド、クロマフェノジド、ハロフェノジド、及びメトキシフェノジドからなる群から選ばれるジアシル－ヒドラジン系化合物である、項目１に記載の有害生物防除用組成物。
［１０］　前記ジクロロメゾチアズ（ａ）と、前記農薬化合物（ｂ）とを、１／１０００～１０００／１の（ａ）／（ｂ）の重量比で含有する、項目１～９のいずれか一項に記載の有害生物防除用組成物。
［１１］　農業上許容される担体、増量剤および／または界面活性剤を含んでいることを特徴とする、項目１～１０のいずれか一項に記載の有害生物防除用組成物。
［１２］　ジクロロメゾチアズ（ａ）と、ジアミド系、ピレスロイド系、ネオニコチノイド系、スピノシン系、キチン生合成阻害剤、フェニルピラゾール系、ネライストキシン類縁体、及びジアシル－ヒドラジン系からなる群から選ばれる少なくとも１の農薬化合物又はその農業上許容される塩（ｂ）とを施用することを含む、有害生物を防除する方法。
［１３］　前記ジクロロメゾチアズ（ａ）と、前記農薬化合物（ｂ）とを、１／１０００～１０００／１の（ａ）／（ｂ）の重量比で施用する、項目１２に記載の方法。
［１４］　ジクロロメゾチアズ（ａ）と、農薬化合物又はその農業上許容される塩（ｂ）とが、混合状態で施用される、項目１２又は１３に記載の方法。
［１５］　ジクロロメゾチアズ（ａ）と、農薬化合物又はその農業上許容される塩（ｂ）とが、逐次施用される、項目１２又は１３に記載の方法。 That is, the present invention relates to the following inventions:
[1] Dichloromesothiaz (a) as an active ingredient, diamide, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, phenylpyrazole, nereistoxin analog, and diacyl-hydrazine A pest control composition comprising at least one agrochemical compound selected from the group consisting of: or an agriculturally acceptable salt (b) thereof.
[2] The pest control composition according to Item 1, wherein the agrochemical compound (b) is a diamide compound selected from the group consisting of cyantraniliprole, fulvendiamide, and chlorantraniliprole.
[3] The agrochemical compound (b) is acrinatrin, imiprothrin, etofenprox, empentrin, cycloprotorin, cyhalothrin, ciphenothrin, cyfluthrin, cypermethrin, tefluthrin, teraretrin, bifenthrin, phenolate, fenvalerate, fenpropatrin, Phthalthrin, praretrin, flucitrinate, fulvalinate, flumethrin, profluthrin, permethrin, monfluorotrin, alpha-cypermethrin, alletrin, esfenvalerate, dimethylfluthrin, silafluophene, zeta-cypermethrin, tau-fulvalinate, tetramethrin, deltamethrin, Tralomethrin, transfluthrin, pyrethrin, pyrethrin I and II, beta-cypermethrin Item 2. The composition for controlling pests according to Item 1, which is a pyrethroid compound selected from the group consisting of, lambda-cyhalothrin, and resmethrin.
[4] The pest control composition according to item 1, wherein the agrochemical compound (b) is a neonicotinoid compound selected from the group consisting of imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, thiacloprid, and thiamethoxam. .
[5] The pest control composition according to item 1, wherein the agrochemical compound (b) is a spinosyn compound selected from the group consisting of spinetoram and spinosad.
[6] In item 1, the agrochemical compound (b) is a chitin biosynthesis inhibitor selected from the group consisting of teflubenzuron, buprofezin, chlorfluazuron, diflubenzuron, flufenoxuron, lufenuron, novallon, and polyoxins. The composition for pest control as described.
[7] The pest control composition according to Item 1, wherein the agrochemical compound (b) is a phenylpyrazole compound selected from the group consisting of fipronil and ethiprol.
[8] The pest control composition according to item 1, wherein the agrochemical compound (b) is a nereistoxin analog compound selected from the group consisting of cartap, bensultap, thiocyclam, and thiosultap sodium.
[9] The pest control composition according to Item 1, wherein the agrochemical compound (b) is a diacyl-hydrazine compound selected from the group consisting of tebufenozide, chromafenozide, halofenozide, and methoxyphenozide.
[10] Any of items 1 to 9, comprising the dichloromesothiaz (a) and the agrochemical compound (b) in a weight ratio of (a) / (b) of 1/1000 to 1000/1. A composition for controlling pests according to claim 1.
[11] The pest control composition as described in any one of items 1 to 10, which comprises an agriculturally acceptable carrier, a bulking agent and / or a surfactant.
[12] A group consisting of dichloromezothiaz (a) and diamide, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, phenylpyrazole, nereistoxin analog, and diacyl-hydrazine A method for controlling pests, comprising applying at least one agrochemical compound selected from the above or an agriculturally acceptable salt (b) thereof.
[13] The method according to item 12, wherein the dichloromesothiaz (a) and the agrochemical compound (b) are applied at a weight ratio of (a) / (b) of 1/1000 to 1000/1. .
[14] The method according to item 12 or 13, wherein the dichloromezzothiaz (a) and the agricultural chemical compound or the agriculturally acceptable salt (b) thereof are applied in a mixed state.
[15] The method according to item 12 or 13, wherein the dichloromezzothiaz (a) and the agricultural chemical compound or the agriculturally acceptable salt (b) thereof are applied sequentially.
　本発明は、有効成分としてジクロロメゾチアズ（ａ）と、他の少なくとも１の農薬化合物又は農業上許容される塩（ｂ）を含有する有害生物防除用組成物に関する。 The present invention relates to a pest control composition comprising dichloromethozothiaz (a) as an active ingredient and at least one other agricultural chemical compound or agriculturally acceptable salt (b).
　本発明において、ジクロロメゾチアズ（ａ）に混合可能な他の農薬化合物（ｂ）とは、農薬に使用しうる任意の化合物あってよい。かかる農薬化合物として、例えば殺虫剤、殺菌剤、殺真菌剤、殺細菌剤、殺ダニ剤、殺線虫剤、除草剤、植物成長調節剤が挙げられる。具体的な農薬化合物としては、例えば、シブヤインデックス（ＳＨＩＢＵＹＡ　ＩＮＤＥＸ　第１７版、２０１４年、ＳＨＩＢＵＹＡ　ＩＮＤＥＸ　ＲＥＳＥＡＲＣＨ　ＧＲＯＵＰ　発行）に記載のものが挙げられる。 In the present invention, the other agrochemical compound (b) that can be mixed with dichloromesothiaz (a) may be any compound that can be used for agrochemicals. Examples of such agrochemical compounds include insecticides, fungicides, fungicides, bactericides, acaricides, nematicides, herbicides, plant growth regulators. Specific examples of the agrochemical compound include those described in Shibuya Index (SHIBUYA INDEX 17th Edition, 2014, SHIBUYA INDEX RESEARCH GROUP issued).
　農薬化合物として、ジアミド系、Ｎａチャンネル阻害剤、電子伝達系Ｉ阻害剤、ピレスロイド系、ネオニコチノイド系、スピノシン系、キチン生合成阻害剤、ベンゾイル尿素系、カーバメート系、有機リン系、フェニルピラゾール系、ネライストキシン類縁体、スルホキシミン系、ブテノライド系、メソイオン系、アベルメクチン系、幼若ホルモン類似剤、ネライストキシン類縁体、ジアシル－ヒドラジン系に含められる化合物が挙げられる。本発明では、ジクロロメゾチアズ（ａ）と組み合わせて相乗作用を発揮する観点から、ジアミド系、ピレスロイド系、ネオニコチノイド系、スピノシン系、キチン生合成阻害剤、フェニルピラゾール系、ネライストキシン類縁体、及びジアシル－ヒドラジン系の化合物が特に好ましい。 As agrochemical compounds, diamide, Na channel inhibitor, electron transport system I inhibitor, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, benzoylurea, carbamate, organophosphorus, phenylpyrazole And compounds included in nereistoxin analogs, sulfoximines, butenolides, mesoionics, avermectins, juvenile hormone analogs, nereistoxin analogs, diacyl-hydrazines. In the present invention, diamide, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, phenylpyrazole, nereistoxin analogues from the viewpoint of exhibiting synergistic action in combination with dichloromesothiaz (a) And diacyl-hydrazine compounds are particularly preferred.
　また、農薬化合物は、作用メカニズムにより分類することができ、例えばアセチルコリンエステラーゼ阻害剤、ＧＡＢＡ作動性塩素イオンチャネルブロッカー、ナトリウムチャネルモジュレーター、ニコチン性アセチルコリン受容体競合的モジュレーター、ニコチン性アセチルコリンアロステリックモジュレーター、グルタミン酸作動性塩素イオンチャネルアロステリックモジュレーター、幼若ホルモン類似剤、その他の非特異的阻害剤、ＴＲＰＶチャネルモジュレーター、ダニ類成長阻害剤、微生物由来昆虫中腸内膜破壊剤、ミトコンドリアＡＴＰ合成酵素阻害剤、酸化的リン酸化脱共役剤、ニコチン性アセチルコリン受容体チャネルブロッカー、キチン生合性阻害剤、脱皮阻害剤、脱皮ホルモン受容体アゴニスト、オクトパミン受容体アゴニスト、ミトコンドリア電子伝達系複合体ＩＩＩ阻害剤、ミトコンドリア電子伝達系複合体Ｉ阻害剤（ＭＥＴＩ）、電位依存性ナトリウムチャネルブロッカー、アセチルＣｏＡカルボキシラーゼ阻害剤、ミトコンドリア電子伝達系複合体ＩＶ阻害剤、ミトコンドリア電子伝達系複合体ＩＩ阻害剤、リノアジン受容体モジュレーターなどが挙げられる。本発明では、ジクロロメゾチアズ（ａ）と組み合わせて相乗作用を発揮する観点から、ＧＡＢＡ作動性塩素イオンチャネルブロッカー、リノアジン受容体モジュレーター、ナトリウムチャネルモジュレーター、ニコチン性アセチルコリン受容体競合的モジュレーター、ニコチン性アセチルコリン受容体アロステリックモジュレーター、ニコチン性アセチルコリン受容体チャネルブロッカー、脱皮ホルモン受容体アゴニストキチン生合性阻害剤の作用を有する化合物が特に好ましい。 Agrochemical compounds can also be classified by the mechanism of action, such as acetylcholinesterase inhibitors, GABAergic chloride channel blockers, sodium channel modulators, nicotinic acetylcholine receptor competitive modulators, nicotinic acetylcholine allosteric modulators, glutamate agonists. Chloride channel allosteric modulator, juvenile hormone analog, other non-specific inhibitors, TRPV channel modulator, mite growth inhibitor, microbial insect midgut membrane disruptor, mitochondrial ATP synthase inhibitor, oxidative Phosphorylated uncoupler, nicotinic acetylcholine receptor channel blocker, chitin biosynthesis inhibitor, molting inhibitor, molting hormone receptor agonist, octopamine receptor Gonist, mitochondrial electron transport complex III inhibitor, mitochondrial electron transport complex I inhibitor (METI), voltage-gated sodium channel blocker, acetyl CoA carboxylase inhibitor, mitochondrial electron transport complex IV inhibitor, mitochondrial electron Examples thereof include a transmission system complex II inhibitor and a linoadin receptor modulator. In the present invention, GABAergic chloride channel blockers, linoadin receptor modulators, sodium channel modulators, nicotinic acetylcholine receptor competitive modulators, nicotinic properties, from the viewpoint of exerting synergistic action in combination with dichloromesothiaz (a) Particularly preferred are compounds having the action of acetylcholine receptor allosteric modulators, nicotinic acetylcholine receptor channel blockers, and molting hormone receptor agonist chitin biosynthesis inhibitors.
　本発明において、ジアミド系の農薬化合物として、シアントラニリプロール、フルベンジアミド、クロラントラニリプロール、シクラニリプロールおよびテトラニリプロールが挙げられる。なかでも、シアントラニリプロール及びフルベンジアミドが特に使用されうる。 In the present invention, examples of the diamide-based agricultural chemical compound include cyantraniliprole, fulvendiamide, chlorantraniliprole, cyclaniliprol and tetraniliprol. Among these, cyantraniliprole and fulvendiamide can be used in particular.
　本発明において、電位依存性ナトリウムチャンネル阻害作用を有する化合物としてメタフルミゾン、インドキサカルブが挙げられる。なかでも、メタフルミゾンが特に使用されうる。 In the present invention, examples of the compound having a voltage-dependent sodium channel inhibitory action include metaflumizone and indoxacarb. Among these, metaflumizone can be used in particular.
　本発明において、電子伝達系Ｉ阻害作用を有する化合物として、フェナザキン、フェンピロキシメート、ピリミジフェン、ピリダベン、テブフェンピラド、トルフェンピラドが挙げられる。なかでも、トルフェンピラドが特に使用されうる。 In the present invention, examples of the compound having an electron transport system I inhibitory action include phenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, and tolfenpyrad. Among these, tolfenpyrad can be used in particular.
　本発明において、ピレスロイド系の農薬化合物として、以下の：アクリナトリン、イミプロトリン、エトフェンプロックス、エムペントリン、シクロプロトリン、シハロトリン、シフェノトリン、シフルトリン、シペルメトリン、テフルトリン、テラレトリン、ビフェントリン、フェノトリン、フェンバレレート、フェンプロパトリン、フタルスリン、プラレトリン、フルシトリネート、フルバリネート、フルメトリン、プロフルトリン、ペルメトリン、モンフルオロトリン、アルファ－シペルメトリン、アレトリン、エスフェンバレレート、ジメフルトリン、シラフルオフェン、ゼータ－シペルメトリン、タウ－フルバリネート、テトラメトリン、デルタメトリン、トラロメトリン、トランスフルトリン、ピレトリン、ピレトリンＩおよびＩＩ、ベータ－シペルメトリン、ラムダ－シハロトリン、及びレスメトリンが挙げられる。なかでも、アクリナトリンが特に使用されうる。 In the present invention, pyrethroid-based agrochemical compounds include the following: acrinatrin, imiprotrine, etofenprox, empentrin, cycloprotorin, cyhalothrin, ciphenothrin, cyfluthrin, cypermethrin, teflutrin, teraretrin, bifenthrin, phenvalerate, fen Propatrin, phthalthrin, praretrin, flucitrinate, fulvalinate, flumethrin, profluthrin, permethrin, monfluorotrin, alpha-cypermethrin, alletrin, esfenvalerate, dimeflutrin, silafluophene, zeta-cypermethrin, tau-fulvalinate, tetramethrin , Deltamethrin, tralomethrin, transfluthrin, pyrethrin, pyrethrin I and II, beta - cypermethrin, lambda - cyhalothrin, and resmethrin are mentioned. Among these, acrinatrin can be used in particular.
　本発明において、ネオニコチノイド系の農薬化合物として、イミダクロプリド、アセタミプリド、クロチアニジン、ジノテフラン、ニテンピラム、チアクロプリド、及びチアメトキサムが挙げられる。なかでも、イミダクロプリドが特に使用されうる。 In the present invention, neonicotinoid-based agricultural chemical compounds include imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, thiacloprid, and thiamethoxam. Among these, imidacloprid can be used in particular.
　本発明において、スピノシン系の農薬化合物として、スピネトラム、スピノサドが挙げられる。なかでも、スピネトラムが特に使用されうる。 In the present invention, spinetoram and spinosad are mentioned as spinosyn-based agricultural chemical compounds. Among these, spinetoram can be used in particular.
　本発明において、ベンゾイル尿素系の農薬化合物として、テフルベンズロン、ビストリフルロン、クロルフルアズロン、ジフルベンズロン、フルシクロクスロン、フルフェノクスロン、ヘキサフルムロン、ルフェヌロン、ノバルロン、ノビフルムロン、トリフルムロンが挙げられる。なかでも、テフルベンズロンが特に使用されうる。 In the present invention, teflubenzuron, bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, nobiflumuron, triflumuron are listed as benzoylurea-based agricultural chemical compounds. Among these, teflubenzuron can be used in particular.
　本発明において、カーバメート系の農薬化合物として、アラニカルブ、アルジカルブ、ベンジオカルブ、ベンフラカルブ、ブトカルボキシム、ブトキシカルボキシム、カルバリル、カルボフラン、カルボスルファン、エチオフェンカルブ、フェノブカルブ、ホルメタネート、フラチオカルブ、イソプロカルブ、メチオカルブ、メソミル、メトルカルブ、オキサミル、ピリミカーブ、プロポクスル、チオジカルブ、チオファノックス、トリアザメート、トリメタカルブ、ＸＭＣ、キシリルカルブが挙げられる。 In the present invention, as a carbamate-based agricultural chemical compound, alanicarb, aldicarb, bendiocarb, benfuracarb, butocarboxym, butoxycarboxym, carbaryl, carbofuran, carbosulfan, etiofencarb, fenobucarb, formethanate, furiocarb, isoprocarb, methiocarb, mesomil, metolcarb , Oxamyl, pyrimicarb, propoxur, thiodicarb, thiophanox, triazamate, trimetacarb, XMC, and xylylcarb.
　本発明において、有機リン系の農薬化合物として、アセフェート、アザメチホス、アジンホスエチル、アジンホスメチル、カズサホス、クロレトキシホス、クロルフェンビンホス、クロルメホス、クロルピリホス、クロルピリホスメチル、クマホス、シアノホス、ジメトン－Ｓ－メチル、ダイアジノン、ジクロルボス、ジクロトホス、ジメトエート、ジメチルビンホス、エチルチオメトン（ジスルホトン）、ＥＰＮ、エチオン、エトプロホス、ファンフル、フェナミホス、フェニトロチオン、フェンチオン、ホスチアゼート、ヘプテノホス、イミシアホス、イソフェンホス、イソキサチオン、マラチオン、メカルバム、メタミドホス、メチダチオン、メビンホス、モノクロトホス、オメトエート、オキシジメトンメチル、パラチオン、メチルパラチオン、フェントエート、ホレート、ホサロン、ホスメット、ホスファミドン、ホキシム、ピリミホスメチル、プロフェノホス、プロペタムホス、プロチオホス、ピラクロホス、ピリダフェンチオン、キナルホス、スルホテップ、テブピリムホス、テメホス、テルブホス、テトラクロルビンホス、チオメトン、トリアゾホス、トリクロルホン、バミドチオン、スルプロホス、パラオキソン、ホセチルアルミニウム、トルクロホス－メチル、クロルエトキシホス、ファムフール、ナレドが挙げられる。 In the present invention, as an organophosphorus agrochemical compound, acephate, azamethiphos, azinephosethyl, azinephosmethyl, kazusafos, chloretiophos, chlorfenvinphos, chlormefos, chlorpyrifos, chlorpyrifosmethyl, coumaphos, cyanophos, dimethone-S-methyl, diazinon, dichlorvos, Dicrotophos, dimethoate, dimethylvinphos, ethylthiomethone (disulfoton), EPN, ethion, etoprophos, fanful, phenamiphos, fenitrothion, fenthion, phosthiazeto, heptenophos, imisiaphos, isofenphos, isoxathione, malathion, mecarbam, methamidophos, methidathione, vin , Ometoate, oxydimethone methyl, parathion, meth Parathion, phentoate, folate, hosalon, phosmet, phosphamidone, phoxime, pirimiphosmethyl, propenofos, propetamphos, prothiophos, pyracrofos, pyridafenthion, quinalphos, sulfotep, tebupyrimphos, temefos, terbufos, tetrachlorbinphos, thiomethone, triazophos, trichlorfones, trichlorfones, trichlorfone , Paraoxon, fosetyl aluminum, tolcrofos-methyl, chloroethoxyphos, famfur, and nared.
　本発明において、フェニルピラゾール系の農薬化合物として、エチプロール、フィプロニル、ピラフルプロール、及び、ピリプロールが挙げられる。 In the present invention, phenylpyrazole-based agricultural chemical compounds include ethiprol, fipronil, pyrafluprolol, and pyriprolol.
　本発明において、スルホキシミン系の農薬化合物として、スルホキサフロルが挙げられる。 In the present invention, sulfoxafluorol may be mentioned as a sulfoximine-based agricultural chemical compound.
　本発明において、ブテノライド系の農薬化合物として、フルピラジフロンが挙げられる。 In the present invention, as a butenolide-based agrochemical compound, flupiradiflon may be mentioned.
　本発明において、メソイオン系の農薬化合物として、トリフルメゾピリムが挙げられる。 In the present invention, triflumezopyrim may be mentioned as a mesoionic pesticide compound.
　本発明において、アベルメクチン系の農薬化合物として、アバメクチン、エマメクチン安息香酸塩、レピメクチン、及びミルベメクチンが挙げられる。 In the present invention, avermectin-based agrochemical compounds include abamectin, emamectin benzoate, lepimectin, and milbemectin.
　本発明において、幼若ホルモン類似作用を有する農薬化合物として、ピリプロキシフェン、ハイドロプレン、キノプレン、メトプレン、フェノキシカルブが挙げられる。 In the present invention, pyriproxyfen, hydroprene, quinoprene, methoprene, and phenoxycarb are listed as agrochemical compounds having juvenile hormone-like activity.
　本発明において、ネライストキシン類縁体として、ベンスルタップ、カルタップ、チオシクラム、チオスルタップが挙げられる。 In the present invention, examples of nereistoxin analogs include bensultap, cartap, thiocyclam, and thiosultap.
　本発明において、ジアシル－ヒドラジン系の農薬化合物として、テブフェノジド、クロマフェノジド、ハロフェノジド、及びメトキシフェノジドが挙げられる。 In the present invention, diacyl-hydrazine-based agricultural chemical compounds include tebufenozide, chromafenozide, halofenozide, and methoxyphenozide.
　本発明において、アセチルコリンエステラーゼ阻害剤としては、前述のカーバメート系化合物、有機リン系化合物が挙げられる。 In the present invention, examples of the acetylcholinesterase inhibitor include the aforementioned carbamate compounds and organophosphorus compounds.
　本発明において、ＧＡＢＡ作動性塩素イオンチャネルブロッカーとしては、前述のフェニルピラゾール系の化合物が挙げられる。 In the present invention, examples of the GABA-acting chloride channel blocker include the aforementioned phenylpyrazole compounds.
　本発明において、ナトリウムチャネルモジュレーターとしては、前述のピレスロイド系化合物などが挙げられる。 In the present invention, examples of the sodium channel modulator include the pyrethroid compounds described above.
　本発明においてニコチン性アセチルコリン受容体競合的モジュレーターとしては、前述のネオニコチノイド系化合物の他、硫酸ニコチン、スルホキサフロル、フルピラジフロン、トリフルメゾピリムが挙げられる。 In the present invention, nicotinic acetylcholine receptor competitive modulators include nicotine sulfate, sulfoxafurol, flupiradiflon, and triflumezopyrim in addition to the aforementioned neonicotinoid compounds.
　ニコチン性アセチルコリンアロステリックモジュレーターとしては、スピノシン系の化合物が挙げられる。 Examples of nicotinic acetylcholine allosteric modulators include spinosyn compounds.
　グルタミン酸作動性塩素イオンチャネルアロステリックモジュレーターとしては、前述のアベルメクチン系の化合物が挙げられる。 Examples of glutamate-acting chloride ion channel allosteric modulators include the avermectin-based compounds described above.
　その他の非特異的阻害剤として、臭化メチル、クロルピクリン、フッ化スルフリル、ホウ砂、ホウ酸、オクタホウ酸二ナトリウム、メタホウ酸ナトリウム、吐酒石、タゾメット、カーバムが挙げられる。 Other non-specific inhibitors include methyl bromide, chloropicrin, sulfuryl fluoride, borax, boric acid, disodium octaborate, sodium metaborate, tartar, tazomet, and carbam.
　ＴＲＰＶチャネルモジュレーターとして、ピメトロジン、ピリフルキナゾンが挙げられる。 TRPI channel modulators include pymetrozine and pyrifluquinazone.
　ダニ類成長阻害剤として、クロフェンテジン、ジフロビダジン、ヘキシチアゾクス、及びエトキサゾールが挙げられる。 Examples of mite growth inhibitors include clofentedine, difluvidazine, hexythiazox, and etoxazole.
　微生物由来昆虫中腸内膜破壊剤として、Bacillus thuringiensisやBacillus sphaericus、並びに当該微生物由来の殺虫タンパク質生産物が挙げられる。 Examples of microorganism-derived insect midgut lining agents include Bacillus thuringiensis and Bacillus sphaericus, and insecticidal protein products derived from the microorganism.
　ミトコンドリアATP合成酵素阻害剤として、ジアフェンチウロン、アゾシクロチン、水酸化トリシクロヘキシルスズ（シヘキサチン）、酸化フェンブタスズ、プロパルギット、テトラジホンが挙げられる。 Examples of mitochondrial ATP synthase inhibitors include diafenthiuron, azocyclotin, tricyclohexyltin hydroxide (cyhexatin), fenbutaine oxide, propargite, and tetradiphone.
　プロトン勾配をかく乱する酸化的リン酸化脱共役剤としては、クロルフェナピル、DNOC、スルフルラミドが挙げられる。 Examples of oxidative phosphorylation uncouplers that disturb the proton gradient include chlorfenapyr, DNOC, and sulfuramide.
　ニコチン性アセチルコリン受容体チャネルブロッカーとして、前述のネライストキシン類縁体が挙げられる。 Examples of nicotinic acetylcholine receptor channel blockers include the aforementioned nereistoxin analogs.
　キチン生合成阻害剤として、前述のベンゾイル尿素系化合物の他に、ブプロフェジン、並びにポリオキシン類が挙げられる。 Examples of chitin biosynthesis inhibitors include buprofezin and polyoxins in addition to the aforementioned benzoylurea compounds.
　脱皮阻害剤として、シロマジンが挙げられる。 Ciromazine is mentioned as a molting inhibitor.
　脱皮ホルモン受容体アゴニストとして、クロマフェノジド、ハロフェノジド、メトキシフェノジド、テブフェノジドが挙げられる。 Examples of molting hormone receptor agonists include chromafenozide, halofenozide, methoxyphenozide, and tebufenozide.
　オクトパミン受容体アゴニストとして、アミトラズが挙げられる。 An example of an octopamine receptor agonist is amitraz.
　ミトコンドリア電子伝達系複合体ＩＩＩ阻害剤として、ヒドラメチルノン、アセキノシル、フルアクリピリム、ビフェナゼートが挙げられる。 Examples of mitochondrial electron transport system complex III inhibitors include hydramethylnon, acequinosyl, fluacrylpyrim, and bifenazate.
　ミトコンドリア電子伝達系複合体）Ｉ阻害剤として、前述のＭＥＴＩ剤の他に、ロテノンが挙げられる。 (Mitochondrial electron transport system complex) I inhibitors include rotenone in addition to the above-mentioned METI agents.
　アセチルＣｏＡカルボキシラーゼ阻害剤として、スピロジクロフェン、スピロメシフェン、スピロテトラマトが挙げられる。 Examples of acetyl CoA carboxylase inhibitors include spirodiclofen, spiromesifen, and spirotetramat.
　ミトコンドリア電子伝達系複合体ＩＶ阻害剤として、リン化アルミニウム、リン化カルシウム、リン化水素、リン化亜鉛、シアン化カルシウム、シアン化ナトリウム、シアン化カリウムが挙げられる。 Examples of mitochondrial electron transport system complex IV inhibitors include aluminum phosphide, calcium phosphide, hydrogen phosphide, zinc phosphide, calcium cyanide, sodium cyanide and potassium cyanide.
　ミトコンドリア電子伝達系複合体ＩＩ阻害剤として、シエノピラフェン、シフルメトフェン、ピフルブミドが挙げられる。 Examples of mitochondrial electron transport system complex II inhibitors include sienopyrafen, cyflumetofene, and pivlummid.
　リノアジン受容体モジュレーターとして、クロラントラニリプロール、シアントラニリプロール、フルベンジアミドが挙げられる。 Examples of linoadin receptor modulators include chlorantraniliprole, cyantraniliprolol, and fulvendiamide.
　その他の作用機構に関する薬剤、例えばフロニカミド、アザジラクチン、ベンゾキシメート、ブロモプロピレート、キノメチオナート、ジコホル、ＧＳ－ω／κＨＸＴＸ－ＨＶ１ａペプチド、石灰硫黄合剤、ピリダリル、硫黄なども、農薬化合物として、本発明の有害生物防除用組成物に使用しうる。 Drugs relating to other mechanisms of action, such as flonicamid, azadirachtin, benzoximate, bromopropyrate, quinomethionate, dicophore, GS-ω / κHXTX-HV1a peptide, lime sulfur combination, pyridalyl, sulfur, etc. are also used as agrochemical compounds in the present invention. It can be used for a pest control composition.
　本発明の別の態様では、その他の農薬化合物として、非限定的に下記の化合物：
　　フェニルアミド系：ベナラキシル、ベナラキシルＭ、フララキシル、メタラキシル、
　メタラキシルＭ、オキサジキシル、オフラセ、シプロフラン等；
　　ヒドロキシ－（２－アミノ－）ピリミジン系：ブピリメート、ジメチリモール、エチ
　リモール等；
　　芳香族ヘテロ環系：ヒドロキシイソキサゾール（ヒメキサゾール）、オクチリノン等　；
　　カルボン酸系：オキソリニック酸等；
　　メチルベンゾイミダゾールカーバメート系：ベノミル、カルベンダゾール（カルベン
　ダジム）、フベリダゾール、チアベンダゾール、チオファネート、チオファネートメチ
　ル等；
　　Ｎ－フェニルカーバメート系：ジエトフェンカルブ等；
　　ベンズアミド系：ゾキサミド、フルオピコリド等；
　　チアゾールカルボキサミド系：エタボキサム等；
　　フェニルウレア系：ペンシクロン等；
　　シアノアクリレート系：フェナマクリル等；
　　ピリミジンアミン系：ジフルメトリム等；
　　ピラゾールカルボキサミド系：トルフェンピラド等；
　　ＳＤＨＩ：ベノダニル、フルトラニル、メプロニル、イソフェタミド、フルオピラム、フェンフラム、カルボキシン、オキシカルボキシン、チフルザミド、ベンゾビンジフルピル、ビキサフェン、フルキサピロキサド、フラメトピル、インピルフルキサム、イソピラザム、ペンフルフェン、ペンチオピラド、セダキサン、ピジフルメトフェン、ボスカリド、ピラジフルミド等；
　　ＱｏＩ：アゾキシストロビン、クモキシストロビン、エノキサストロビン、フルフェノキシストロビン、ピコキシストロビン、ピラオキシストロビン、マンデストロビン、ピラクロストロビン、ピラメトストロビン、トリクロピリカルブ、クレソキシムメチル、トリフロキシストロビン、ジモキシストロビン、フェナミンストロビン、メトミノストロビン、オリサストロビン、ファモキサドン、フルオキサストロビン、フェンアミドン、ピリベンカルブ等；
　　ＱｉＩ：シアゾファミド、アミスルブロム等；
　　脱共役剤として作用しうる化合物：ビナパクリル、メプチルジノカップ、ＤＰＣ（ジ
　ノカップ）、フルアジナム等；
　　有機スズ化合物：酢酸トリフェニルスズ、塩化トリフェニルスズ、水酸化トリフェニ
　ルスズ等；
　　チオフェンカルボキサミド系：シルチオファム等；
　　ＱｏＳＩ：アメトクトラジン等；
　　アニリノピリミジン系：シプロジニル、メパニピリム、ピリメタニル等；
　　エノピラヌロン酸抗生物質：ブラストサイジンＳ等；
　　ヘキソピラノシル抗生物質：カスガマイシン等；
　　グルコピラノシル抗生物質：ストレプトマイシン等；
　　テトラサイクリン抗生物質：オキシテトラサイクリン等；
　　アザ－ナフタレン系：キノキシフェン、プロキナジド等；
　　フェニルピロール系：フェンピクロニル、フルジオキソニル等；
　　ジカルボキシイミド系：クロゾリネート、ジメタクロン、イプロジオン、プロシミドン、ビンクロゾリン等；
　　ホスホロチオレート系：ＥＤＤＰ（エジフェンホス）、ＩＢＰ（イプロベンホス）、ピラゾホス等；
　　ジチオラン系：イソプロチオラン等；
　　芳香族炭化水素：ビフェニル、クロロネブ、ＣＮＡ（ジクロラン）、ＰＣＮＢ（キントゼン）、テクナゼン、トルクロホスメチル等；
　　複素芳香族：エクロメゾール（エトリジアゾール）等；
　　カーバメート系：ヨードカルブ、プロパモカルブ、プロチオカルブ等；
　　微生物（Ｂａｃｉｌｌｕｓ属）：バチルス　ズブチリスＱＳＴ７１３株、バチルス　
ズブチリスＦＺＢ２４株、バチルス　ズブチリスＭＢＩ６００株、バチルス　ズブチリスＤ７４７株等；
　　微生物（トリコデルマ属）：トリコデルマ・アトロビリデＳＣ１株等；
　　微生物（シュードモナス属）：シュードモナス　ロデシアＨＡＩ－０８０４株
　　植物抽出物：ゴセイカユプテ（ティーツリー）の抽出物、植物油類（混合物）オイゲ
　ノール、ゲラニオール、チモール等；
　　ポリエン：ナタマイシン（ピマリシン）等；
　　オキシステロール結合蛋白質阻害：オキサチアピプロリン等；
　　ＤＭＩ：トリホリン、ピリフェノックス、ピリソキサゾール、フェナリモル、ヌアリモール、イマザリル、オキスポコナゾール、ペフラゾエート、プロクロラズ、トリフルミゾール、アザコナゾール、ビテルタノール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、ジニコナゾール、エポキシコナゾール、エタコナゾール、フェンブコナゾール、フルキンコナゾール、フルシラゾール、フルトリアホール、ヘキサコナゾール、イミベンコナゾール、イプコナゾール、メトコナゾール、ミクロブタニル、ペンコナゾール、プロピコナゾール、シメコナゾール、テブコナゾール、テトラコナゾール、トリアジメホン、トリアジメノール、トリチコナゾール、プロチオコナゾール等；
　　ＳＢＩクラスII：アルジモルフ、ドデモルフ、フェンプロピモルフ、トリデモルフ、フェンプロピジン、ピペラリン、スピロキサミン等；
　　ＳＢＩクラスIII：フェンヘキサミド、フェンピラザミン等；
　　ＳＢＩクラスIV：ピリブチカルブ、ナフチフィン、テルビナフィン等；
　　カルボン酸アミド系：ジメトモルフ、フルモルフ、ピリモルフ、ベンチアバリカルブ
　イソプロピル、イプロバリカルブ、バリフェナレート、マンジプロパミド等；
　　ＭＢＩ－Ｒ：フサライド、ピロキロン、トリシクラゾール等；
　　ＭＢＩ－Ｄ：カルプロパミド、ジクロシメット、フェノキサニル等；
　　ＭＢＩ－Ｐ：トルプロカルブ等；
　　ベンゾチアジアゾール系：アシベンゾラルＳメチル等；
　　ベンゾイソチアゾール系：プロベナゾール等；
　　チアジアゾールカルボキサミド系：チアジニル、イソチアニル等；
　　天然物：ラミナリン等；
　　植物抽出物：オオイタドリ抽出液等；
　　微生物：バチルス・マイコイデス分離株Ｊ等；
　　無機化合物：水酸化第二銅、オキシキノリン銅等；
　　ジチオカーバメート系：ファーバム、マンゼブ、マンネブ、メチラム、プロピネブ、
　チウラム、チアゾール亜鉛、ジネブ、ジラム、ポリカーバメート等；
　　フタルイミド系：キャプタン、ダイホルタン（カプタホール）、ホルペット等；
　　クロロニトリル系：ＴＰＮ（クロロタロニル）等；
　　スルファミド系：スルフェン酸系（ジクロフルアニド）、トリルフルアニド等；
　　ビスグアニジン系：グアザチン、イミノクタジン酢酸塩、イミノクタジンアルベシル酸塩等；
　　トリアジン系：トリアジン（アニラジン）等；
　　キノン系：ジチアノン等；
　　キノキサリン系：キノキサリン系（キノメチオナート）等；
　　マレイミド：フルオルイミド等；
　その他の有効成分：トジカルブ、ピリミカルブ、プロポキスル、シラマジン（ｃｙｒａｍａｚｉｎ）、ジオフェノラン、クロフェンタジン、グアジフィル（ｇｕａｄｉｐｙｒ）、エンドスルファン、バニリプロール、ピラフルプロール、クリオマジン（ｃｒｙｏｍａｚｉｎｅ）、ピペロニルブトキシド、ベンクロチアズ、フルピラゾホス、アミドフルメト、ペラミン、タスマノン（ｔａｓｍａｎｏｎｅ）、ヴェサミコール（ｖｅｓａｍｉｃｏｌ）、アストロマイシン（ａｓｔｒｏｍｉｃｉｎ）、ブロムクロルフェナピル（ｂｒｏｍｃｈｌｏｒｆｅｎａｐｙｒ）、スルホキサム（ｓｕｌｆｏｘｉｍｅ）、ジシクラニル（ｄｉｃｙｃｌａｎｉｌ）、フランフェノジド（ｆｕｒａｎｆｅｎｏｚｉｄｅ）、ヘプタフルスリン（ｈｅｐｔａｆｌｕｔｈｒｉｎ）、メイリンマイシン（ｍｅｉｌｉｎｇｍｙｃｉｎ）、ヴァーティシライド（ｖｅｒｔｉｃｉｌｉｄｅ）、ジエタシン（ｊｉｅｔａｃｉｎ）、フルエンスルホン（ｆｌｕｅｎｓｕｌｆｏｎｅ）、オキシマトリン（ｏｘｙｍａｔｒｉｎｅ）、アフィドピロペン（ａｆｉｄｏｐｙｒｏｐｅｎ）、チオキサザフェン（ｔｉｏｘａｚａｆｅｎ）、フルララナー（ｆｌｕｒａｌａｎｅｒ）、アホクソラナー（ａｆｏｘｏｌａｎｅｒ）、ピリミノストロビン（ｐｙｒｉｍｉｎｏｓｔｒｏｂｉｎ）、モンフルオロスリン（ｍｏｍｆｌｕｏｒｏｔｈｒｉｎ）、シクロサプリド（ｃｙｃｌｏｘａｐｒｉｄ）、シクロキシリジン（ｃｙｃｌｏｘｙｌｉｄｉｎ）、フルキサメタミド（ｆｌｕｘａｍｅｔａｍｉｄｅ）、フルピリミン（ｆｌｕｐｙｒｉｍｉｎｅ）、チクロピラゾフロール（ｔｙｃｌｏｐｙｒａｚｏｆｌｏｒ）、ブロフラニリド（ｂｒｏｆｌａｎｉｌｉｄｅ）、オキサゾスルフィル（ｏｘａｚｏｓｕｌｆｙｌ）、シモキサニル、ホセチル、亜リン酸および塩、テクロフタラム、トリアゾキシド、フルスルファミド、ジクロメジン、メタスルホカルブ、シフルフェナミド、メトラフェノン、ピリオフェノン、グアニジン（ドジン）、フルチアニル、フェリムゾン、テブフロキン、ピカルブトラゾクス、バリダマイシン、メチルテトラプロール、ピリダクロメチル、ジクロベンチアゾクス、コニオチリウムミニタンスが挙げられる。 In another aspect of the invention, other agrochemical compounds include, but are not limited to:
Phenylamide type: Benalaxyl, Benalaxyl M, Furaraxyl, Metalaxyl,
Metalaxyl M, oxadixyl, oflase, cyprofuran, etc .;
Hydroxy- (2-amino-) pyrimidine series: bupilimate, dimethylylmol, ethylimol, etc .;
Aromatic heterocyclic system: hydroxyisoxazole (himexazole), octirinone, etc .;
Carboxylic acid type: Oxolinic acid, etc .;
Methylbenzimidazole carbamates: benomyl, carbendazole (carbendazim), fuberidazole, thiabendazole, thiophanate, thiophanate methyl, etc .;
N-phenyl carbamate type: dietofencarb, etc .;
Benzamide series: zoxamide, fluopicolide, etc .;
Thiazole carboxamides: ethaboxam, etc .;
Phenylurea type: Pencyclone, etc .;
Cyanoacrylate type: Phenacryl etc .;
Pyrimidineamine type: diflumetrim, etc .;
Pyrazole carboxamide series: tolfenpyrad and the like;
SDHI: benodanyl, flutolanil, mepronil, isophetamide, fluopyram, fenfram, carboxin, oxycarboxin, tifluzamide, benzovindiflupyr, bixaphene, floxapyroxad, flametopyr, impylfluxam, isopyrazam, penflufen, pentiopyrad, sedaxane, Pidiflumethophene, boscalid, pyraziflumide, etc .;
QoI: azoxystrobin, cumoxystrobin, enoxastrobin, fluphenoxystrobin, picoxystrobin, pyroxystrobin, mandestrobin, pyraclostrobin, pyramethostrobin, triclopyricarb, cresoxime methyl, trif Roxistrobin, dimoxystrobin, phenaminestrobin, metminostrobin, orissastrobin, famoxadone, floxastrobin, fenamidone, pyribencarb, etc .;
QiI: cyazofamide, amisulbrom, etc.
Compounds that can act as uncouplers: Binapacryl, meptyldinocup, DPC (dinocup), fluazinam, etc .;
Organotin compounds: triphenyltin acetate, triphenyltin chloride, triphenyltin hydroxide, etc .;
Thiophenecarboxamide series: silthiofam, etc .;
QoSI: Ametoctrazine, etc .;
Anilinopyrimidines: cyprodinil, mepanipyrim, pyrimethanil, etc .;
Enopyranuronic acid antibiotics: blasticidin S and the like;
Hexopyranosyl antibiotics: kasugamycin, etc .;
Glucopyranosyl antibiotics: streptomycin, etc .;
Tetracycline antibiotics: oxytetracycline, etc .;
Aza-naphthalene series: quinoxyphene, proquinazide, etc .;
Phenylpyrrole type: fenpiclonyl, fludioxonil, etc .;
Dicarboximide series: Clozolinate, dimethaclone, iprodione, procymidone, vinclozoline, etc .;
Phosphorothiolate system: EDDP (edifenphos), IBP (iprobenphos), pyrazophos, etc .;
Dithiolane series: isoprothiolane, etc .;
Aromatic hydrocarbons: biphenyl, chloronebu, CNA (dichlorane), PCNB (kintozene), technazen, tolcrophos methyl, etc .;
Heteroaromatic: Echromesol (etridiazole) etc .;
Carbamates: iodocarb, propamocarb, prothiocarb, etc .;
Microorganisms (genus Bacillus): Bacillus subtilis QST713 strain, Bacillus
Subtilis FZB24 strain, Bacillus subtilis MBI600 strain, Bacillus subtilis D747 strain, etc .;
Microorganism (Trichoderma sp.): Trichoderma atrobide SC1 strain, etc .;
Microorganism (Pseudomonas genus): Pseudomonas Rhodesia HAI-0804 plant extract: Extract of Goseika Yupte (Tea Tree), vegetable oil (mixture) Eugenol, Geraniol, Thymol, etc .;
Polyene: natamycin (pimaricin), etc .;
Oxysterol binding protein inhibition: oxathiapiproline etc .;
DMI: trifolin, pyrifenox, pyrisoxazole, phenalimol, nuarimol, imazalyl, oxpoconazole, pefrazoate, prochloraz, triflumizole, azaconazole, viteltanol, bromconazole, cyproconazole, diphenoconazole, dinicoconazole, epoxiconazole, etaconazole , Fenbuconazole, fluquinconazole, flusilazole, flutriazole, hexaconazole, imibenconazole, ipconazole, metconazole, microbutanyl, penconazole, propiconazole, cimeconazole, tebuconazole, tetraconazole, triadimethone, triadimenol, tri Ticonazole, prothioconazole, etc .;
SBI class II: aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, piperalin, spiroxamine and the like;
SBI class III: phenhexamide, fenpyrazamine, etc .;
SBI class IV: piributicalbu, naphthifine, terbinafine, etc .;
Carboxylic acid amide system: dimethomorph, furmorph, pyrimorph, benchavaricarb isopropyl, iprovaricarb, varifenalate, mandipropamide, etc .;
MBI-R: fusaride, pyrokilone, tricyclazole, etc .;
MBI-D: carpropamide, diclocimet, phenoxanyl, etc .;
MBI-P: Tolprocarb, etc .;
Benzothiadiazole series: acibenzoral S methyl and the like;
Benzoisothiazole series: probenazole, etc .;
Thiadiazole carboxamides: thiazinyl, isothianyl, etc .;
Natural products: laminarin, etc .;
Plant extract: giant redbird extract, etc .;
Microorganisms: Bacillus mycoides isolate J etc .;
Inorganic compounds: cupric hydroxide, oxyquinoline copper, etc .;
Dithiocarbamate: Farbum, Manzeb, Mannebu, Methylam, Propineb,
Thiuram, thiazole zinc, dineb, ziram, polycarbamate, etc .;
Phthalimide: Captan, Daihortan (Captahol), Holpet, etc .;
Chloronitrile type: TPN (chlorothalonil), etc .;
Sulfamide type: sulfenic acid type (dichrofluanid), tolyl fluanide, etc .;
Bisguanidine series: guazatine, iminoctadine acetate, iminoctadine arbesylate, etc .;
Triazine series: Triazine (anilazin), etc .;
Quinone series: dithianon, etc .;
Quinoxaline: quinoxaline (quinomethionate), etc .;
Maleimide: fluorimide, etc .;
Other active ingredients: todicarb, pirimicarb, propoxur, cyramazine, diophenolane, clofentadine, guadiphyr, endosulfan, vaniliprole, pyrafluprole, cryomazine (cryomazine), piperonyl butopirazole benzotropiafluzide Tasmanone, vesamicol, astromicin, bromchlorfenapyr, sulfoxime, dicyclanil, furfurenide, furfenozide n), meilingmycin, verticylide, dietacin, fluensulfone, oxymatrine, afidopyropen, fluoxafen, fluoxafen afoxolaner, pyriminostrobin, monfluorothrin, cyclosupride, cycloxylidin, fluxamemidide, minpy, flupyrimine Clopyrazofurol, brofuranilide, oxazosulfyl, simoxanyl, fosetyl, phosphorous acid and salt, teclophthalam, triazoxide, flusulfamide, dichromedin, metasulfocarbion, ciflunazine, metafluridine (Dodin), fluthianyl, ferrimzone, tebufloquine, picarbutrazox, validamycin, methyltetraprole, pyridacromethyl, diclobenchazox, and coniotylium minitance.
　本発明において用いられる有効成分である農薬化合物（ｂ）には、農業上許容される塩を含む。農業上許容される塩としては、例えば、ナトリウム又はカリウム等のアルカリ金属の塩；カルシウム、マグネシウム又はバリウム等のアルカリ土類金属の塩；マンガン、銅、亜鉛又は鉄等の遷移金属の塩；アンモニウム塩（窒素原子は必要に応じて、１－４個の炭素数が１－４のアルキル基及び／又は１個のフェニル若しくはベンジル置換基で置換されてもよい）、好ましくはジイソプロピルアンモニウム、テトラメチルアンモニウム、テトラブチルアンモニウム、トリメチルベンジルアンモニウム；塩酸、臭化水素酸、リン酸又は硫酸等の無機酸との塩；メタンスルホン酸等のＣ１～Ｃ４アルキルスルホン酸、ベンゼンスルホン酸若しくはトルエンスルホン酸等の芳香族スルホン酸、シュウ酸、マレイン酸、フマル酸、乳酸、酒石酸、アジピン酸又は安息香酸等の有機酸との塩を挙げることができる。 The agricultural chemical compound (b), which is an active ingredient used in the present invention, includes agriculturally acceptable salts. Examples of agriculturally acceptable salts include: salts of alkali metals such as sodium or potassium; salts of alkaline earth metals such as calcium, magnesium or barium; salts of transition metals such as manganese, copper, zinc or iron; ammonium A salt (the nitrogen atom may be optionally substituted by 1-4 alkyl groups having 1-4 carbon atoms and / or one phenyl or benzyl substituent), preferably diisopropylammonium, tetramethyl Ammonium, tetrabutylammonium, trimethylbenzylammonium; salt with inorganic acid such as hydrochloric acid, hydrobromic acid, phosphoric acid or sulfuric acid; C 1 -C 4 alkylsulfonic acid such as methanesulfonic acid, benzenesulfonic acid or toluenesulfonic acid Aromatic sulfonic acid such as oxalic acid, maleic acid, fumaric acid, lactic acid, tartaric acid, Salts with pins or organic acids such as benzoic acid.
　本発明の別の態様によれば、適当な農園芸上許容可能な担体をさらに含む有害生物防除用組成物が提供され、その形態としては、乳剤、液剤、懸濁剤、水和剤、顆粒状水和剤、フロアブル剤、粉剤、ＤＬ粉剤、粒剤、微粒剤Ｆ、錠剤、油剤、エアゾール、くん煙剤、マイクロカプセル剤等の任意の剤型に処方することが提供される。これら各種の剤型は、例えば「農薬製剤ガイド」（日本農薬学会・施用法研究会　編、社団法人日本植物防疫協会発行、平成９年）に記載される方法によって製造することができる。 According to another aspect of the present invention, there is provided a pest control composition further comprising a suitable agriculturally and horticulturally acceptable carrier, the form of which is an emulsion, solution, suspension, wettable powder, granule. It is provided to be formulated into any dosage form such as a wettable powder, a flowable powder, a powder, a DL powder, a granule, a fine powder F, a tablet, an oil, an aerosol, a smoke, a microcapsule. These various dosage forms can be produced by a method described in, for example, “Agricultural Chemicals Formulation Guide” (edited by the Japanese Agricultural Chemical Society / Application Method Research Group, published by the Japan Plant Protection Association, 1997).
　本発明の有害生物防除用組成物は、相乗的な作用が発揮される任意の形態で施用される。具体的に、本発明の有害生物防除用組成物に含まれる有効成分であるジクロロメゾチアズ（ａ）と、その他の農薬化合物又はその農業上許容される塩（ｂ）とは、上述の１の剤型にあらかじめ処方された製剤として、直接、又は適切な希釈液による希釈後に施用される。さらに別の態様では、本発明の有害生物防除用組成物に含まれる有効成分であるジクロロメゾチアズ（ａ）と、その他の農薬化合物又はその農業上許容される塩（ｂ）とは、使用前に混合される組み合わせ農薬として販売され、使用前に使用者により混合されて、直接又は希釈液で希釈して施用されてもよい。さらに別の態様では、ジクロロメゾチアズ（ａ）と、その他の農薬化合物又はその農業上許容される塩（ｂ）とは、同じ領域に別々に逐次施用されてもよい。逐次施用される場合、その順番は任意であり、一方を施用後、任意の時間をおいてもう一方を施用することができる。施用の間隔は、相乗的な作用が発揮される範囲で任意に選択することができ、例えば１時間から数時間の間、場合により数日の間をあけて施用することができる。ジクロロメゾチアズ（ａ）と、その他の農薬化合物又はその農業上許容される塩（ｂ）とがあらかじめ混合されていない農薬を、組み合わせ農薬、キット農薬などということができる。 The pest control composition of the present invention is applied in any form that exhibits a synergistic action. Specifically, dichloromezzothiaz (a), which is an active ingredient contained in the composition for controlling pests of the present invention, and other agricultural chemical compounds or agriculturally acceptable salts (b) thereof are the above-mentioned 1 It is applied directly or after dilution with an appropriate diluent as a pre-formulated preparation in this dosage form. In yet another aspect, the dichloromesothiaz (a), which is an active ingredient contained in the pest control composition of the present invention, and other agricultural chemical compounds or agriculturally acceptable salts (b) thereof are used. It may be sold as a combination pesticide to be mixed before, mixed by the user before use, and applied directly or diluted with a diluent. In yet another aspect, dichloromesothiaz (a) and other pesticidal compounds or agriculturally acceptable salts (b) thereof may be applied separately and sequentially in the same area. When applied sequentially, the order is arbitrary, and after applying one, the other can be applied after an arbitrary time. The application interval can be arbitrarily selected within a range in which a synergistic effect is exhibited. For example, the application interval can be applied for 1 hour to several hours, and in some cases, several days. Pesticides in which dichloromesothiaz (a) and other agricultural chemical compounds or agriculturally acceptable salts (b) thereof are not mixed in advance can be referred to as combined agricultural chemicals, kit agricultural chemicals, and the like.
　使用可能な担体としては、組成物の剤形に応じて適宜選択することができ、一例として固体担体、液体担体、ガス状担体、界面活性剤、分散剤その他の製剤用補助剤等が挙げられる。 The carrier that can be used can be appropriately selected depending on the dosage form of the composition. Examples of the carrier include a solid carrier, a liquid carrier, a gaseous carrier, a surfactant, a dispersant, and other formulation adjuvants. .
　固体担体としては、例えば、タルク、ベンナイト、クレー、カオリン、ケイソウ土、バーミキュライト、ホワイトカーボン、炭酸カルシウム等があげられる。 Examples of the solid carrier include talc, bennite, clay, kaolin, diatomaceous earth, vermiculite, white carbon, calcium carbonate and the like.
　液体担体としては、例えば、メタノール、ｎ－ヘキサノール、エチレングリコール等のアルコール類、アセトン、メチルエチルケトン、シクロヘキサノン等のケトン類、ｎ－ヘキサン、ケロシン、灯油等の脂肪族炭化水素類、トルエン、キシレン、メチルナフタレンなどの芳香族炭化水素類、ジエチルエーテル、ジオキサン、テトラヒドロフランなどのエーテル類、酢酸エチルなどのエステル類、アセトニトリル、イソブチロニトリルなどのニトリル類、ジメチルホルムアミド、ジメチルアセトアミドなどの酸アミド類、ダイズ油、綿実滴等の植物油類、ジメチルスルホキシド、水などがあげられる。 Examples of the liquid carrier include alcohols such as methanol, n-hexanol and ethylene glycol, ketones such as acetone, methyl ethyl ketone and cyclohexanone, aliphatic hydrocarbons such as n-hexane, kerosene and kerosene, toluene, xylene and methyl Aromatic hydrocarbons such as naphthalene, ethers such as diethyl ether, dioxane and tetrahydrofuran, esters such as ethyl acetate, nitriles such as acetonitrile and isobutyronitrile, acid amides such as dimethylformamide and dimethylacetamide, soybean Examples include oils, vegetable oils such as cotton seed drops, dimethyl sulfoxide, and water.
　また、ガス状担体としてはＬＰＧ、空気、窒素、炭酸ガス、ジメチルエーテルなどがあげられる。 Further, examples of the gaseous carrier include LPG, air, nitrogen, carbon dioxide gas, dimethyl ether and the like.
　乳化、分散、展着などのための界面活性剤、分散剤としては、例えば、アルキル硫酸エステル類、アルキル（アリール）スルホン酸塩類、ポリオキシアルキレンアルキル（アリール）エーテル類、多価アルコールエステル類、リグニンスルホン酸塩などが用いられる。 Surfactants and dispersants for emulsification, dispersion, spreading, etc. include, for example, alkyl sulfates, alkyl (aryl) sulfonates, polyoxyalkylene alkyl (aryl) ethers, polyhydric alcohol esters, Lignin sulfonate and the like are used.
　また、製剤の性状を改善するための補助剤としては、例えば、カルボキシメチルセルロース、アラビアガム、ポリエチレングリコール、ステアリン酸カルシウム等が用いられる。 Further, as an auxiliary agent for improving the properties of the preparation, for example, carboxymethyl cellulose, gum arabic, polyethylene glycol, calcium stearate and the like are used.
　上記の担体、界面活性剤、分散剤、及び補助剤は、必要に応じて各々単独で、あるいは組み合わせて用いられる。 The above carriers, surfactants, dispersants, and adjuvants may be used alone or in combination as necessary.
　発明の組成物中の有効成分量は、その合計量で０．１～９９．９重量％、好ましくは０．４～８０重量％、さらにより好ましくは２～８０％である。ジクロロメゾチアズ（ａ）と、他の農薬化合物（ｂ）との混合割合は広範囲に渡って変えることができるが、通常ジクロロメゾチアズ（ａ）を０．１～８０％、好ましくは０．２～４０％、より好ましくは１～４０％含有し、他の農薬化合物を０．１～８０％、好ましくは０．２～４０％、より好ましくは１～４０％含有する。ジクロロメゾチアズ（ａ）と、他の農薬化合物（ｂ）の混合比は、所望の効果が発揮される範囲で当業者により任意に決定されてよい。所望の効果が発揮される観点から、（ａ）／（ｂ）の質量比を、１／１０００～１０００／１、より好ましくは１／１００～１００／１と設定することができる。 The total amount of active ingredients in the composition of the invention is 0.1 to 99.9% by weight, preferably 0.4 to 80% by weight, and more preferably 2 to 80%. The mixing ratio of the dichloromesothiaz (a) and the other agrochemical compound (b) can be varied over a wide range, but the dichloromezothiaz (a) is usually 0.1 to 80%, preferably 0 2 to 40%, more preferably 1 to 40%, and other agrochemical compounds 0.1 to 80%, preferably 0.2 to 40%, more preferably 1 to 40%. The mixing ratio of dichloromesothiaz (a) and other agrochemical compound (b) may be arbitrarily determined by those skilled in the art within a range in which a desired effect is exhibited. From the viewpoint of exhibiting a desired effect, the mass ratio of (a) / (b) can be set to 1/1000 to 1000/1, more preferably 1/100 to 100/1.
　好ましい態様における農園芸上許容可能な担体をさらに含む有害生物防除用組成物としては、以下の：
（１）ジクロロメゾチアズ（ａ）を０．１～８０重量％、他の農薬化合物（ｂ）を０．１～８０重量％、濡れ剤、および分散剤を０．６～３０重量％、増量剤を２０～９５重量％を含有する水和剤形態（ｗｅｔｔａｂｌｅ　　ｐｏｗｄｅｒ）である組成物、
（２）ジクロロメゾチアズ（ａ）を０．１～８０重量％、他の農薬化合物（ｂ）を０．１～８０重量％、濡れ剤、分散剤および結合剤を０．６～３０重量％、増量剤を２０～９５重量％を含有する顆粒状水和剤形態（ｗａｔｅｒ　　ｄｉｓｐｅｒｓｉｂｌｅ　　ｇｒａｎｕｌｅ）である組成物、
（３）ジクロロメゾチアズ（ａ）０．１～８０重量％、他の農薬化合物（ｂ）を０．１～８０重量％、分散剤、増粘剤、凍結防止剤、防腐剤および消泡剤を５～４０重量％、水を２０～９４重量％を含有するフロアブル剤形態（ｓｕｓｐｅｎｓｉｏｎ　　ｃｏｎｃｅｎｔｒａｔｅ）である組成物、
（４）ジクロロメゾチアズ（ａ）を０．１～８０重量％、他の有害生物防除剤として農薬化合物（ｂ）を０．１～８０重量％、乳化剤、および乳化安定剤を１～３０重量％、有機溶媒を２０～９７重量％　を含有する乳剤形態（ｅｍｕｌｓｉｆｉａｂｌｅ　　ｃｏｎｃｅｎｔｒａｔｅ）である組成物、
（５）ジクロロメゾチアズ（ａ）を０．１～８０重量％、他の農薬化合物（ｂ）を０．１～８０重量％、造粒助剤（界面活性剤）および結合剤を０．５～３０重量％、増量剤を２０～９８重量％を含有する粒剤形態（ｇｒａｎｕｌｅ）である組成物
が、挙げられる。 The pest control composition further comprising an agriculturally and horticulturally acceptable carrier in a preferred embodiment includes the following:
(1) 0.1 to 80% by weight of dichloromesothiaz (a), 0.1 to 80% by weight of other agrochemical compound (b), 0.6 to 30% by weight of wetting agent and dispersant, A composition in wettable powder form containing 20-95% by weight of a bulking agent;
(2) 0.1 to 80% by weight of dichloromezzothiaz (a), 0.1 to 80% by weight of other agrochemical compound (b), 0.6 to 30% of wetting agent, dispersant and binder %, A composition in the form of a water dispersible granule containing 20-95% by weight of a bulking agent,
(3) Dichloromesothiaz (a) 0.1-80% by weight, other agrochemical compound (b) 0.1-80% by weight, dispersant, thickener, antifreezing agent, preservative and antifoam A composition in the form of a suspension concentrate containing 5-40% by weight of the agent and 20-94% by weight of water,
(4) 0.1 to 80% by weight of dichloromesothiaz (a), 0.1 to 80% by weight of agrochemical compound (b) as other pest control agent, 1 to 30 of emulsifier and emulsion stabilizer A composition in the form of an emulsion containing 1% by weight, 20-97% by weight of an organic solvent,
(5) 0.1 to 80% by weight of dichloromesothiaz (a), 0.1 to 80% by weight of other agrochemical compound (b), 0.1% of granulation aid (surfactant) and binder. Mention may be made of compositions in the form of granules containing 5 to 30% by weight and 20 to 98% by weight of extenders.
　本発明の別の態様によれば、本発明の組成物を、そのままで、あるいは希釈して、有効量を対象有害生物、対象有用植物、対象有用植物の繁殖材料、例えば種子、塊根など、土壌、栽培担体、対象有用植物が生育する領域に適用することを特徴とする、有害生物防除用組成物の使用方法が提供される。さらに別の態様では、ジクロロメゾチアズ（ａ）と、その他の農薬化合物又はその農業上許容される塩（ｂ）の有効量を、対象有害生物、対象有用植物、対象有用植物の繁殖材料、例えば種子、塊根など、土壌、栽培担体、又は対象有用植物が生育する領域、例えば圃場に適用することを含む、有害生物の防除方法が提供される。 According to another aspect of the present invention, the composition of the present invention is left as it is or diluted, and an effective amount of the target pest, the target useful plant, the propagation material of the target useful plant, such as seeds, tuberous root, soil, etc. The present invention provides a method for using a pest control composition, characterized by being applied to a region where a cultivation carrier and a target useful plant grow. In yet another aspect, an effective amount of dichloromesothiaz (a) and other agrochemical compound or agriculturally acceptable salt thereof (b) is used as a target pest, target useful plant, target useful plant propagation material, There is provided a method for controlling pests, including application to an area where seeds, tuberous roots, etc., soil, a cultivation carrier, or a target useful plant grows, for example, a field.
　また、本発明の組成物を対象有害生物、対象有用植物、対象有用植物の種子、土壌又は栽培担体に処理する手法としては、散布処理、土壌処理、表面処理またはくん蒸処理などが挙げられる。散布処理としては、例えば、散布、噴霧、ミスティング、アトマイジング、散粒、水面施用が挙げられる。また、土壌処理としては、例えば、土壌潅注、土壌混和が挙げられる。また、表面処理としては、例えば、塗布、粉衣、被覆することが挙げられる。また、くん蒸処理としては、例えば、土壌注入後、ポリフィルムで土壌を覆うことが挙げられる。したがって、本発明の組成物の使用方法には、密閉された空間においてくん蒸処理によって適用する方法も含まれる。 In addition, examples of the method for treating the composition of the present invention with the target pest, the target useful plant, the seed of the target useful plant, the soil, or the cultivation carrier include spraying treatment, soil treatment, surface treatment, or fumigation treatment. Examples of the spraying treatment include spraying, spraying, misting, atomizing, dusting, and water surface application. Examples of soil treatment include soil irrigation and soil mixing. Examples of the surface treatment include application, powder coating, and coating. Moreover, as fumigation processing, covering soil with a poly film after soil injection | pouring is mentioned, for example. Accordingly, the method of using the composition of the present invention includes a method of applying by fumigation treatment in a sealed space.
　本発明の有害生物防除用組成物は、ジクロロメゾチアズを用いる任意の用途に用いることができる。すなわち、本発明の有害生物防除用組成物は、有害生物、例えば、昆虫、ダニ、アブラムシ、クモ、線虫、カタツムリ、真菌、細菌、及びウイルスの防除用に用いることができる。したがって、本発明の組成物は、殺虫組成物、殺菌組成物、殺ダニ組成物、殺線虫組成物、殺軟体動物組成物、殺細菌組成物、抗ウイルス組成物として用いることができる。 The composition for controlling pests of the present invention can be used for any application using dichloromesothiaz. That is, the pest control composition of the present invention can be used for controlling pests such as insects, ticks, aphids, spiders, nematodes, snails, fungi, bacteria, and viruses. Therefore, the composition of the present invention can be used as an insecticidal composition, a bactericidal composition, an acaricidal composition, a nematicidal composition, a molluscicidal composition, a bactericidal composition, and an antiviral composition.
　本発明の組成物が防除効果を示す害虫としては、以下の：
　鱗翅目害虫（例えば、ハスモンヨトウ、シロイチモンジヨトウ、アワヨトウ、タマナヤガ、トリコプルシア属、ヘリコベルパ属害虫（Ｈｅｌｉｃｏｖｅｒｐａ　ｓｐｐ）、ヘリオティス属害虫（Ｈｅｌｉｏｔｈｉｓ　ｓｐｐ）などのヤガ類、ニカメイガ、コブノメイガ、ヨーロピアンコーンボーラーなどのメイガ類、モンシロチョウ等のシロチョウ類、アドキソフィエス属、ナシヒメシンクイ、コドリンガなどのハマキガ類、モモシンクイガなどのシンクイガ類、リオネティア属などのハモグリガ類、リマントリア属などのドクガ類、コナガなどのスガ類、ワタアカミムシなどのキバガ類、アメリカシロヒトリなどのヒトリガ類、イガ、コイガなどのヒロズコガ類、ヒメボクトウなどのボクトウガ類、アカエグリバ、ヒメエグリバ、アケビコノハなどの吸蛾類など）、
　半翅目害虫（例えば、シルバーリーフコナジラミ、タバココナジラミ、オンシツコナジラミなどのコナジラミ類（Ａｌｅｙｒｏｄｉｄａｅ）、モモアカアブラムシ、ワタアブラムシなどのアブラムシ類（Ａｐｈｉｄｉｄａｅ，Ａｄｅｌｇｉｄａｅ，Ｐｈｙｌｌｏｘｅｒｉｄａｅ）、ツマグロヨコバイ、チャノミドリヒメヨコバイ、フタテンヒメヨコバイなどのヨコバイ類（Ｃｉｃａｄｅｌｌｉｄａｅ）、ヒメトビウンカ、トビイロウンカ、セジロウンカなどのウンカ類（Ｃｉｘｉｉｄａｅ）、シラホシカメムシ、ミナミアオカメムシ、アカヒゲホソミドリカスミカメなどのカメムシ類（Ｍｉｒｉｄａｅ，　Ｔｉｎｇｉｄａｅ，　Ａｃａｎｔｈｏｓｏｍａｔｉｄａｅ，　Ｃｙｄｎｉｄａｅ，　Ｄｉｎｉｄｏｒｉｄａｅ，　Ｐｅｎｔａｔｏｍｉｄａｅ，　Ｐｌａｔａｓｐｉｄａｅ，　Ｓｃｕｔｅｌｌｅｒｉｄａｅ，　Ｕｒｏｓｔｙｌｉｄａｅ，　Ｂｅｒｙｔｉｄａｅ，　Ｌｙｇａｅｉｄａｅ，　Ｍａｌｃｉｄａｅ，　Ｌａｒｇｉｄａｅ，　Ｐｙｒｒｈｏｃｏｒｉｄａｅ，　Ａｌｙｄｉｄａｅ，　Ｃｏｒｅｉｄａｅ，　Ｒｈｏｐａｌｉｄａｅ）、クワコナカイガラムシ、ミカンコナカイガラムシなどのカイガラムシ類（Ｄｉａｓｐｉｄｉｄａｅ，Ｍａｒｇａｒｏｄｉｄａｅ，Ｏｒｔｈｅｚｉｉｄａｅ，Ａｃｌｅｒｄｉａｅ，Ｄａｃｔｙｌｏｐｉｉｄａｅ，Ｋｅｒｒｉｄａｅ，Ｐｓｅｕｄｏｃｏｃｃｉｄａｅ，Ｃｏｃｃｉｄａｅ，Ｅｒｉｏｃｏｃｃｉｄａｅ，Ａｓｔｅｒｏｌｅｃａｎｉｉｄａｅ，Ｂｅｅｓｏｎｉｄａｅ，Ｌｅｃａｎｏｄｉａｓｐｉｄｉｄａｅ，Ｃｅｒｏｃｏｃｃｉｄａｅ）、グンバイムシ類、キジラミ類など）、
　総翅目害虫（例えば、ミカンキイロアザミウマ、ミナミキイロアザミウマ、ヒラズハナアザミウマ、ハナアザミウマ、クロトンアザミウマ、ネギアザミウマ、チャノキイロアザミウマ、カキクダアザミウマなどのアザミウマ類（Ｔｈｒｉｐｉｄａｅ，　　Ｐｈｌａｅｏｔｈｒｉｐｉｄａｅ，　　Ａｅｏｌｏｔｈｒｉｐｉｄａｅ））、
　鞘翅目害虫（例えば、メイズウィービル、イネミズゾウムシ、アズキゾウムシなどのゾウムシ類、チャイロゴミムシダマシなどのゴミムシダマシ類、ドウガネブイブイ、ヒメコガネなどのコガネムシ類、キスジノミハムシ、ウリハムシ、コロラドポテトハムシ、ウェスタンコーンルートワーム、サザンコーンルートワームなどのハムシ類、イネドロオイムシ、アオバアリガタハネカクシ、シンクイムシ類、ニジュウヤホシテントウなどのエピラクナ類、カミキリムシ類など）、ダニ目（例えば、ナミハダニ、カンザワハダニ、ミカンハダニ、リンゴハダニ、オリゴニカス属などのハダニ類（Ｔｅｔｒａｎｙｃｈｉｄａｅ）、チャノホコリダニなどのホコリダニ類（Ｔａｒｓｏｎｅｍｉｄａｅ）、トマトサビダニ、ミカンサビダニなどのフシダニ類（Ｅｒｉｏｐｈｙｉｄａｅ）、コナダニ類など）、
　膜翅目害虫（例えばカブラハバチなどのハバチ類（Ｔｅｎｔｈｒｅｄｉｎｉｄａｅ，　　Ｐａｍｐｈｉｌｉｉｄａｅ，　　Ａｒｇｉｄａｅ，　　Ｃｉｍｂｉｃｉｄａｅ，　　Ｄｉｐｒｉｏｎｉｄａｅ）など）、
　直翅目害虫（例えば、バッタ類など）、双翅目害虫（例えば、トマトハモグリバエ、マメハモグリバエ、ネギハモグリバエ、ミカンハモグリバエ、ナモグリバエなどのハモグリバエ類（Ａｇｒｏｍｙｚｉｄａｅ）、イエバエ類、イエカ類、ハマダラカ類、ユスリカ類、クロバエ類、ニクバエ類、ヒメイエバエ類、ハナバエ類、ミバエ類など）、
　網翅目害虫（例えば、ゴキブリ類など）、
　等翅目害虫（例えば、シロアリ類など）、
　植物寄生性線虫（例えば、ネコブセンチュウ、ネグサレセンチュウ、イネシンガレセンチュウ、マツノザイセンチュウ等のアフェレンコイデス類、マツノザイセンチュウなど）、などが挙げられる。 Pests that exhibit the control effect of the composition of the present invention include the following:
Lepidopterous pests (for example, moths such as Spodoptera spp. , White butterflies such as white butterflies, striped moths such as genus Adoxofies, prickly moths, codling moths, sink moths such as peaches moths, leaf moths such as Rionetia genus, dogas moths such as Limantria genus, sugas such as cotton squirrels , Higgaris such as white-spotted starfish, Hirokosukaga such as igai and koiga, Bokutoga such as Himebokuto, Akaeguriba, Himeiguriba, Akebikono吸蛾 such as, etc.),
Hemiptera (for example, silver leaf whitefly, tobacco whitefly, whitefly whitefly) such as whitefly (Aleyrodidae), peach aphid, cotton aphid, etc. Leafhoppers (Cicadellidae), such as Japanese beetle, planthoppers (Cixididae), such as Japanese brown planthopper, Japanese brown planthopper, white-headed beetle, white-headed beetle, white-headed beetle, white-tailed beetle (Mididaidae), , lataspidae, Scutelleridae, Urostylidae, Berytidae, Lygaeidae, Malcidae, Largidae, Pyrrhocoridae, Alydidae, Coreidae, Rhopalidae), mulberry mealybugs, scale insects such as oranges mealybugs (Diaspididae, Margarodidae, Ortheziidae, Aclerdiae, Dactylopiidae, Kerridae, Pseudococcidae, Coccidae , Eriococcidae, Asterolecaniidae, Beesonidae, Lecanodiaspididae, Cerococcidae), Crested Beetle, Pheasant Such as Mi acids),
Pests (eg, thrips of thrips such as citrus thrips, thrips of thrips, thrips of thrips, thrips of thrips, thrips of thrips, thrips of thrips, thrips of thrips)
Coleopterous pests (e.g. weevil such as maize weevil, rice weevil, azuki beetle), worm beetle such as chalcedoridae, scarab beetle such as stag beetle, scallop, potato beetle, cucumber potato beetle, Colorado western corn Worms such as worms, paddy beetles, blue-spotted beetles, sinkworms, epilacunas such as scallops, and longhorn beetles; ), Dust mites (Tarsonmididae) such as chano dust mites, fusida such as tomato rust mites and citrus mites S (Eriophyidae), such as grain mites),
Hymenopteran pests (for example, wasps such as wasp (Tenthredinidae, Pamphiidae, Argidae, Cimbicidae, Diplionidae))
Diptera pests (for example, grasshoppers), Diptera pests (for example, tomato leafhopper, legume leaf fly, leek leaf fly, citrus leaf fly, leaf leaf fly, etc.), house fly, house fly, sea moth, , Black flies, sphagnum flies, flies flies, flies, fruit flies, etc.),
Reticulate pests (eg cockroaches),
Isopods (eg, termites),
Plant parasitic nematodes (for example, aferencoides such as root-knot nematode, papaver nematode, rice scallop nematode, pine wood nematode, pine wood nematode, etc.).
　以下、実施例を挙げて本発明を具体的に説明するが、本発明はこれらの実施例に限定されるものではない。本明細書において言及される全ての文献はその全体が引用により本明細書に取り込まれる。 Hereinafter, the present invention will be specifically described by way of examples, but the present invention is not limited to these examples. All documents mentioned herein are hereby incorporated by reference in their entirety.
試験例１　ハスモンヨトウ防除試験
　ポット栽培したキャベツから直径約９ｃｍの葉を切り取り、表１に示したようにジクロロメゾチアズと他の農薬化合物が所定濃度になるよう水（０．０２％ネオエステリン加用）で調整した本発明組成物にキャベツ葉を１分間浸漬した。風乾後、これをろ紙を敷いた直径９ｃｍのプラスチックカップに移した。その後、ハスモンヨトウ３齢幼虫をカップあたり１０頭放虫し、カップに蓋をして、２５℃恒温室（１６時間明期－８時間暗期）に放置した。放飼３日後に虫の生死を観察し、次式に従って補正死虫率を算出し、結果を表１に示した。

補正死虫率（％）＝｛（無処理区生存率－処理区生存率）／無処理区生存率｝×１００
　また、以下に示すコルビーの式のよって相乗効果がない場合の理論値を算出し、結果を表１に示した（Calculation　of　the　synergistic　and　antagonistic　responses　of　herbicide　combinations　Weeds,(1967), vol. 15, pages 20-22：非特許文献１）。
　コルビーの式：理論値（％）＝（Ａ＋Ｂ）－（Ａ×Ｂ）／１００
　　　（Ａ：１００－（化合物Ａのみを処理した場合の死虫率）
　　　　Ｂ：１００－（化合物Ｂのみを処理した場合の死虫率）） Test Example 1 Lobster Pest Control Test Cut leaves of about 9 cm in diameter from pot-grown cabbage, and water (0.02% neoesterin) so that dichloromesothiaz and other pesticide compounds have a predetermined concentration as shown in Table 1. The cabbage leaf was immersed in the composition of the present invention prepared in (Additional) for 1 minute. After air drying, this was transferred to a 9 cm diameter plastic cup with filter paper. Thereafter, 10 third-instar larvae were released per cup, covered with a cup, and left in a constant temperature room at 25 ° C. (16 hours light period-8 hours dark period). Three days after the release, the mortality of the insects was observed, the corrected death rate was calculated according to the following formula, and the results are shown in Table 1.

Corrected death rate (%) = {(untreated group survival rate−treated group survival rate) / untreated group survival rate} × 100
In addition, the theoretical value when there is no synergistic effect is calculated according to the following Colby equation, and the results are shown in Table 1 (Calculation of the synergistic and antagonistic responses of herbicide combinations Weeds, (1967), vol. 15, pages 20-22: Non-Patent Document 1).
Colby's formula: Theoretical value (%) = (A + B) − (A × B) / 100
(A: 100- (rate of death when compound A alone is treated)
B: 100- (Death rate when only compound B is treated)
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
　試験に供試した混合剤は、いずれも理論値を超えた補正死虫率を示しており、相乗効果が観察された。 All the mixed agents used in the test showed a corrected mortality rate exceeding the theoretical value, and a synergistic effect was observed.
試験例２　ヨトウガ防除試験
　ポット栽培したキャベツから直径約９ｃｍの葉を切り取り、表１に示したようにジクロロメゾチアズと他の殺虫剤が所定濃度になるよう水（０．０２％ネオエステリン加用）で調整した本発明組成物にキャベツ葉を１分間浸漬した。風乾後、これをろ紙を敷いた直径９ｃｍのプラスチックカップに移した。その後、ヨトウガ３齢幼虫をカップあたり１０頭放虫し、カップに蓋をして、２５℃恒温室（１６時間明期－８時間暗期）に放置した。放飼３日後に虫の生死を観察し、次式に従って補正死虫率を算出し、結果を表１に示した。

補正死虫率（％）＝｛（無処理区生存率－処理区生存率）／無処理区生存率｝×１００
　また、以下に示すコルビーの式のよって相乗効果がない場合の理論値を算出し、結果を表２に示した。
　コルビーの式：理論値（％）＝（Ａ＋Ｂ）－（Ａ×Ｂ）／１００
　　　（Ａ：１００－（化合物Ａのみを処理した場合の死虫率）
　　　　Ｂ：１００－（化合物Ｂのみを処理した場合の死虫率））
Figure JPOXMLDOC01-appb-T000002
　試験に供試した混合剤は、いずれも理論値を超えた補正死虫率を示しており、相乗効果が観察された。 Test Example 2 Sweet potato control test A leaf of about 9 cm in diameter was cut from a pot-grown cabbage, and water (0.02% neoesterin was added to a predetermined concentration of dichloromezzothiaz and other insecticides as shown in Table 1. The cabbage leaf was immersed in the composition of the present invention prepared in (Additional) for 1 minute. After air drying, this was transferred to a 9 cm diameter plastic cup with filter paper. Thereafter, 10 third instar larvae were released per cup, the cup was covered, and left in a constant temperature room at 25 ° C. (16 hours light period-8 hours dark period). Three days after the release, the mortality of the insects was observed, the corrected death rate was calculated according to the following formula, and the results are shown in Table 1.

Corrected death rate (%) = {(untreated group survival rate−treated group survival rate) / untreated group survival rate} × 100
Further, the theoretical values in the case where there is no synergistic effect according to the following Colby equation were calculated, and the results are shown in Table 2.
Colby's formula: Theoretical value (%) = (A + B) − (A × B) / 100
(A: 100- (rate of death when compound A alone is treated)
B: 100- (Death rate when only compound B is treated)
Figure JPOXMLDOC01-appb-T000002
All of the admixtures used in the test showed corrected mortality exceeding the theoretical value, and a synergistic effect was observed.

Claims (15)

  1. 　有効成分としてジクロロメゾチアズ（ａ）と、ジアミド系、ピレスロイド系、ネオニコチノイド系、スピノシン系、キチン生合成阻害剤、フェニルピラゾール系、ネライストキシン類縁体、及びジアシル－ヒドラジン系からなる群から選ばれる少なくとも１の農薬化合物又はその農業上許容される塩（ｂ）を含有する有害生物防除用組成物。 A group consisting of dichloromesothiaz (a) as an active ingredient and diamide, pyrethroid, neonicotinoid, spinosyn, chitin biosynthesis inhibitor, phenylpyrazole, nereistoxin analog, and diacyl-hydrazine A pest control composition containing at least one agrochemical compound selected from the above or an agriculturally acceptable salt (b) thereof.
  2. 　前記農薬化合物（ｂ）が、シアントラニリプロール、フルベンジアミド、及びクロラントラニリプロールからなる群から選ばれるジアミド系化合物である、請求項１に記載の有害生物防除用組成物。 The pest control composition according to claim 1, wherein the agricultural chemical compound (b) is a diamide compound selected from the group consisting of cyantraniliprole, fulvendiamide, and chlorantraniliprole.
  3. 　前記農薬化合物（ｂ）が、アクリナトリン、イミプロトリン、エトフェンプロックス、エムペントリン、シクロプロトリン、シハロトリン、シフェノトリン、シフルトリン、シペルメトリン、テフルトリン、テラレトリン、ビフェントリン、フェノトリン、フェンバレレート、フェンプロパトリン、フタルスリン、プラレトリン、フルシトリネート、フルバリネート、フルメトリン、プロフルトリン、ペルメトリン、モンフルオロトリン、アルファ－シペルメトリン、アレトリン、エスフェンバレレート、ジメフルトリン、シラフルオフェン、ゼータ－シペルメトリン、タウ－フルバリナート、テトラメトリン、デルタメトリン、トラロメトリン、トランスフルトリン、ピレトリン、ピレトリンＩ及びＩＩ、ベータ－シペルメトリン、ラムダ－シハロトリン、及びレスメトリンからなる群から選ばれるピレスロイド系化合物である、請求項１に記載の有害生物防除用組成物。 The agrochemical compound (b) is acrinathrin, imiprotorin, etofenprox, empentrin, cycloprotorin, cyhalothrin, ciphenothrin, cyfluthrin, cypermethrin, tefluthrin, teraretrin, bifenthrin, phenothrin, fenvalerate, phenpropatrin, phthalthrin, praretrin. , Flucitrinate, fulvalinate, flumethrin, profluthrin, permethrin, monfluorotrin, alpha-cypermethrin, allethrin, esfenvalerate, dimeflutrin, silafluophene, zeta-cypermethrin, tau-fluvalinate, tetramethrin, deltamethrin, tralomethrin, trans Flutrin, pyrethrin, pyrethrin I and II, beta-cypermethrin, ram - cyhalothrin, and a pyrethroid compound selected from the group consisting of resmethrin, pest controlling composition according to claim 1.
  4. 　前記農薬化合物（ｂ）が、イミダクロプリド、アセタミプリド、クロチアニジン、ジノテフラン、ニテンピラム、チアクロプリド、及びチアメトキサムからなる群から選ばれるネオニコチノイド系化合物である、請求項１に記載の有害生物防除用組成物。 The pest control composition according to claim 1, wherein the agrochemical compound (b) is a neonicotinoid compound selected from the group consisting of imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, thiacloprid, and thiamethoxam.
  5. 　前記農薬化合物（ｂ）が、スピネトラム、及びスピノサドからなる群から選ばれるスピノシン系化合物である、請求項１に記載の有害生物防除用組成物。 The pesticidal composition according to claim 1, wherein the agrochemical compound (b) is a spinosyn compound selected from the group consisting of spinetoram and spinosad.
  6. 　前記農薬化合物（ｂ）が、テフルベンズロン、ブプロフェジン、クロルフルアズロン、ジフルベンズロン、フルフェノクスロン、ルフェヌロン、ノバルロン、及びポリオキシン類からなる群から選ばれるキチン生合成阻害剤である、請求項１に記載の有害生物防除用組成物。 The said pesticide compound (b) is a chitin biosynthesis inhibitor selected from the group consisting of teflubenzuron, buprofezin, chlorfluazuron, diflubenzuron, flufenoxuron, lufenuron, novallon, and polyoxins. A composition for controlling pests.
  7. 　前記農薬化合物（ｂ）が、フィプロニル及びエチプロールからなる群から選ばれるフェニルピラゾール系化合物である、請求項１に記載の有害生物防除用組成物。 The pest control composition according to claim 1, wherein the agrochemical compound (b) is a phenylpyrazole compound selected from the group consisting of fipronil and ethiprol.
  8. 　前記農薬化合物（ｂ）が、カルタップ、ベンスルタップ、チオシクラム、及びチオスルタップナトリウムからなる群から選ばれる、ネライストキシン類縁体化合物である、請求項１に記載の有害生物防除用組成物。 The pest control composition according to claim 1, wherein the agrochemical compound (b) is a nereistoxin analog compound selected from the group consisting of cartap, bensultap, thiocyclam, and thiosultap sodium.
  9. 　前記農薬化合物（ｂ）が、テブフェノジド、クロマフェノジド、ハロフェノジド、及びメトキシフェノジドからなる群から選ばれるジアシル－ヒドラジン系化合物である、請求項１に記載の有害生物防除用組成物。 The pesticidal composition according to claim 1, wherein the agrochemical compound (b) is a diacyl-hydrazine compound selected from the group consisting of tebufenozide, chromafenozide, halofenozide, and methoxyphenozide.
  10. 　前記ジクロロメゾチアズ（ａ）と、前記農薬化合物（ｂ）とを、１／１０００～１０００／１の（ａ）／（ｂ）の重量比で含有する、請求項１～９のいずれか一項に記載の有害生物防除用組成物。 The dichloromesothiaz (a) and the agrochemical compound (b) are contained in a weight ratio of (a) / (b) of 1/1000 to 1000/1. The composition for pest control according to Item.
  11. 　農業上許容される担体、増量剤および／または界面活性剤を含んでいることを特徴とする、請求項１～１０のいずれか一項に記載の有害生物防除用組成物。 The pest control composition according to any one of claims 1 to 10, comprising an agriculturally acceptable carrier, a bulking agent and / or a surfactant.
  12. 　ジクロロメゾチアズ（ａ）と、ジアミド系、ピレスロイド系、ネオニコチノイド系、スピノシン系、キチン生合成阻害剤、フェニルピラゾール系、ネライストキシン類縁体、及びジアシル－ヒドラジン系からなる群から選ばれる少なくとも１の農薬化合物又はその農業上許容される塩（ｂ）とを施用することを含む、有害生物を防除する方法。 Selected from the group consisting of dichloromesothiaz (a) and diamides, pyrethroids, neonicotinoids, spinosyns, chitin biosynthesis inhibitors, phenylpyrazoles, nereistoxin analogs, and diacyl-hydrazines A method for controlling pests, comprising applying at least one agrochemical compound or an agriculturally acceptable salt thereof (b).
  13. 　前記ジクロロメゾチアズ（ａ）と、前記農薬化合物（ｂ）とを、１／１０００～１０００／１の（ａ）／（ｂ）の重量比で施用する、請求項１２に記載の方法。 The method according to claim 12, wherein the dichloromesothiaz (a) and the agrochemical compound (b) are applied at a weight ratio of (a) / (b) of 1/1000 to 1000/1.
  14. 　ジクロロメゾチアズ（ａ）と、農薬化合物又はその農業上許容される塩（ｂ）とが、混合状態で施用される、請求項１２又は１３に記載の方法。 The method according to claim 12 or 13, wherein the dichloromethozothiaz (a) and the agricultural chemical compound or an agriculturally acceptable salt (b) thereof are applied in a mixed state.
  15. 　ジクロロメゾチアズ（ａ）と、農薬化合物又はその農業上許容される塩（ｂ）とが、逐次施用される、請求項１２又は１３に記載の方法。 The method according to claim 12 or 13, wherein the dichloromesothiaz (a) and the agricultural chemical compound or the agriculturally acceptable salt (b) thereof are applied sequentially.
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