WO2019120717A1 - Formulations de peroxyde d'hydrogène dans des feuilles à couche barrière - Google Patents

Formulations de peroxyde d'hydrogène dans des feuilles à couche barrière Download PDF

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Publication number
WO2019120717A1
WO2019120717A1 PCT/EP2018/079683 EP2018079683W WO2019120717A1 WO 2019120717 A1 WO2019120717 A1 WO 2019120717A1 EP 2018079683 W EP2018079683 W EP 2018079683W WO 2019120717 A1 WO2019120717 A1 WO 2019120717A1
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WO
WIPO (PCT)
Prior art keywords
layer
cosmetic composition
barrier layer
packaging
polymer layer
Prior art date
Application number
PCT/EP2018/079683
Other languages
German (de)
English (en)
Inventor
Marc NOWOTTNY
Torsten LECHNER
Wolfgang Barthel
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2019120717A1 publication Critical patent/WO2019120717A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7244—Oxygen barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7246—Water vapor barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/748—Releasability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/40—Closed containers
    • B32B2439/46—Bags

Definitions

  • the present invention is in the field of cosmetics and relates to a product for the oxidative color change of keratinic fibers, in particular human hair, which comprises a packaged in an oxidant-containing composition.
  • the oxidizing agent-containing composition comprises at least one Cs-Cso alcohol, at least one nonionic surfactant, at least one anionic surfactant and at least one complexing compound.
  • the packaging is a packaging made of a special multilayer composite film system, the wall of which comprises at least two polymeric layers and a Barierre layer.
  • the barrier layer has a natural detergents and water vapor.
  • the hair color can be changed temporarily.
  • already formed dyes diffuse from the colorant into the hair fiber.
  • the dyeing with substantive dyes is associated with little hair damage, but a disadvantage is the low durability and fast washability of the dyes obtained with substantive dyes.
  • oxidative color-change agents are usually employed.
  • oxidation colorants For permanent, intensive colorations with corresponding fastness properties, so-called oxidation colorants are used.
  • Such colorants usually contain oxidation dye precursors, so-called developer components and coupler components, which under the influence of oxidants - usually hydrogen peroxide - form the actual dyes among each other. Oxidation dyes are characterized by excellent, long-lasting staining results.
  • oxidizing agents without the addition of oxidation dye precursors.
  • oxidizing agents for a medium Blondier soap the use of hydrogen peroxide as the oxidant alone is sufficient, for the achievement of a stronger Blondier bines usually a mixture of hydrogen peroxide and Peroxidisulfatsalzen is used.
  • Oxidative color changing agents usually come on the market in the form of two-component compositions, in which two different preparations are packaged separately in two separate packages and are mixed together only shortly before use.
  • the first preparation is a - usually acidified for stability reasons - formulation containing as oxidizing agent, for example, hydrogen peroxide in concentrations of 1, 5 to 12 wt .-%.
  • the oxidizing agent formulation is usually in the form of an emulsion or dispersion and is usually provided in a plastic bottle with a reclosable outlet opening (developer bottle).
  • This oxidizer formulation is mixed with a second formulation before use.
  • This second preparation is an alkaline formulation which is often in the form of a cream or gel and which also contains at least one oxidation dye precursor if, at the same time as brightening, a color change is desired.
  • This second preparation can be provided for example in the form of a tube or in the form of a plastic or glass container.
  • the second preparation which contains the alkalizing agent and / or the oxidation dye precursors, transferred from the tube or container in the developer bottle and then mixed by shaking with the already in the developer bottle hydrogen peroxide preparation.
  • the application mixture is prepared in the developer bottle.
  • the application on the hair then takes place via a small nozzle or outlet opening on the head of the developer bottle.
  • the spout is opened after spillage, and the application mixture can be removed by squeezing the flexible developer bottle.
  • the use of the developer bottle requires a certain amount of routine from the user, so that some users prefer to make the application mixture in a mixing bowl and apply it with a brush.
  • the application mixture is then removed via the brush from the mixing bowl.
  • packages in the form of bags or pouches, which as a rule are made of plastic films or even metal foils, are suitable as inexpensive packaging forms with low material consumption.
  • Such a packaging can be produced, for example, by gluing or hot-pressing two superimposed plastic films, the adhesion taking place on all edges of the films.
  • the interior of the package i.e., plastic bag
  • the opening of the package can be done by tearing or cutting the plastic bag.
  • Oxidizing agents are highly reactive substances which, depending on the storage conditions and, if appropriate, the presence of decomposing impurities, decompose in small amounts to form oxygen (i.e., gas).
  • developer bottles known from the prior art are filled with the oxidizing agent composition only a maximum of half, usually only one third, of their internal volume.
  • developer bottles are made of polyethylene. Since polyethylene is permeable to both water vapor and gases, there is no or very little overpressure in the developer bottle.
  • developer bottles are usually provided with sturdy, thick walls and a sturdy screw cap, so that the diffusion of water vapor or gases through the thickness of the walls is reduced and a slight pressure increase within the bottle has no negative effects.
  • bag-shaped packages are, however, usually filled completely with the liquid preparation, and in the filled bag there is virtually no supernatant airspace.
  • packages should be flexible, and upon opening (e.g., tearing or slicing), there should be no uncontrolled discharge of the preparation. For this reason, in the packaging of liquid preparations, the emergence of overpressure in the packaging should be avoided as far as possible.
  • Oxidizing agent composition If an oxidizing agent composition is present in such a packaging, the gas (oxygen) produced during storage may cause the packaging to expand. Since the edges of the package are usually only glued, a strong swelling at worst leads to bursting of the packaging. For these reasons, during storage of Oxidizing agent-containing compositions of great importance in the choice of the film material that makes up the packaging.
  • Packaging made of pure plastic, such as polyethylene or polypropylene, is permeable to both water vapor and gases.
  • an oxidant-containing preparations in a package made of polyethylene or polypropylene therefore, no inflation of the packaging. Due to the high permeability of the relatively thin film of the packaging to water vapor, however, the water content of the preparation is reduced. If the preparation is stored in the packaging for a few weeks to months, the loss of water exceeds the maximum permitted for sufficient storage stability.
  • Completely airtight packages are made, for example, from plastic films having a lamination with a metal layer, for example, with an aluminum layer. These packages are impermeable to water vapor and gases. If these packages are filled with an oxidizing agent-containing preparation, the gas produced during the decomposition of the oxidizing agent can not escape, the package expands as described above and can delaminate or even burst.
  • the object of the present application was to pack hydrogen peroxide-containing formulations so that the mechanical strength of the packaging is sufficiently large to allow safe storage, but that easy accessibility to the ingredients is ensured.
  • oxidizer-containing compositions can be packaged in which the water vapor permeability is low and puffing can thereby be reduced by allowing the film oxygen permeability.
  • the films consist of a special composite film system and additionally have a barrier layer.
  • the oxidizing agent preparation must be thickened with special thickening agents and contain certain surfactants.
  • the present invention is a cosmetic product for changing the natural color of keratinous fibers, in particular human hair, comprising (i) at least one packaging (VP) comprising at least one multilayer film (F) which contains at least one first polymer layer (P1), at least one second polymer layer (P2) and at least one barrier layer (BS), and
  • the multilayer film (F) has an oxygen transmission rate (OTR) at 23 ° C and 50% relative humidity of 0, 1 to 5 cc / m 2 / d / bar, preferably from 0.2 to 3.5 cc / m 2 / d / bar, more preferably from 0.5 to 2.5 cc / m 2 / d / bar, and a water vapor permeability at 38 ° C and 100% relative humidity of 0, 1 to 5 g / m 2 d, preferably from 0, From 2 to 3.5 g / m 2 d, more preferably from 0.5 to 2.5 g / m 2 d.
  • OTR oxygen transmission rate
  • Keratinic fibers, keratin-containing fibers or keratin fibers are understood to mean furs, wool, feathers and, in particular, human hair.
  • compositions according to the invention are primarily suitable for lightening and dyeing keratin fibers, in principle, there is nothing to prevent their use in other fields as well.
  • the product of the invention is a product for the oxidative color change of keratinic fibers, i. a product used on the human head to achieve oxidative coloring, brightening, bleaching, bleaching or hair shading.
  • shade is understood to mean a coloring in which the color result is lighter than the original hair color.
  • That the product is to be used "to change the natural color” is intended to mean that the product either comprises only an oxidizing agent for bonding, or that the product comprises an oxidizing agent used with a non-invention coupler to cause a color change or that the product is used with a non-invention dye for further tinting.
  • the term "packaging” according to the invention is understood to mean a packaging which is preferably present in the form of a sachet.
  • a sachet is a small package in bag or bag form, which is often used in the packaging of cosmetics.
  • the capacity of the packaging, in particular of the sachet can be, for example, 5 to 1000 ml, preferably 10 to 200 ml and particularly preferably 20 to 50 ml.
  • a multilayer film (F) in the context of the present invention is understood to mean a thin, areal and windable web of the at least one polymer layer (P1) and the at least one polymer layer (P2). This multilayer film (F) forms the wall of the package (VP).
  • the polymer layers (P1) and (P2) preferably comprise polymers capable of forming films. Furthermore, the polymer layers (P1) and (P2) are preferably different polymer layers from each other.
  • the package additionally contains a barrier layer (BS), which prevents or reduces the passage of water vapor and other gases, such as oxygen, ie prevents or reduces the diffusion of these gases through the wall of the package.
  • BS barrier layer
  • the permeability values of the film (F) are advantageously adjusted.
  • the film (F) thus gives the package advantageous barrier properties, in particular with regard to the water vapor transmission rate (WVTR, measured in units of g / (m 2 d) or g / (m 2 24 h) ) measured according to the method ASTM F 1249 at 38 ° C ambient temperature and 100% relative Beerfeutmaschine, and for oxygen (English: Oxygen Transmission Rate, OTR, measured in cm 3 / (m 2 d bar) or cm 3 / ( m 2 24h) - where cm 3 is equivalent to cc - at an atmospheric pressure of 1 bar) measured by the method ASTM D 3985 at 23 ° C ambient temperature and 50% relative Heilfeutmaschine.
  • WVTR water vapor transmission rate
  • OTR oxygen Transmission Rate
  • anionic surfactant amphiphilic (bifunctional) compounds, which consist of at least one hydrophobic and at least one hydrophilic part of the molecule to understand.
  • the hydrophobic moiety is preferably a hydrocarbon chain of 8 to 28 carbon atoms, which may be saturated or unsaturated, linear or branched. Most preferably, this Cs-C28 alkyl chain is linear.
  • these surfactants contain at least one anionic group, in particular a carboxylate and / or sulfonate group.
  • nonionic surfactant means amphiphilic (bifunctional) compounds which have at least one hydrophobic and at least one hydrophilic moiety.
  • the hydrophobic moiety is preferably a hydrocarbon chain of 8 to 28 carbon atoms, which may be saturated or unsaturated, linear or branched. Most preferably, this Cs-C28 alkyl chain is linear.
  • anionic, cationic, zwitterionic and amphiphilic surfactants contain neither cationic nor anionic groups. In addition, these surfactants also have no cationizable and anionizable groups, which can form cationic or anionic groups depending on the pH.
  • the at least one first nonionic surfactant is inventively different from the at least one second nonionic surfactant.
  • complexing compounds in the context of the present invention means compounds which have at least one free electron pair and are capable of mono- or polyvalent ones. Complexing cations.
  • the cosmetic product according to the invention comprises as the first component a packaging (VP) which comprises at least one multilayer film (F).
  • This film contains at least one first polymer layer (P1), at least one second polymer layer (P2) and at least one barrier layer (BS).
  • VP packaging
  • BS barrier layer
  • such packaging is usually produced by gluing, pressing or welding two superposed pieces of film (the packaging (VP) being filled simultaneously with the cosmetic composition (KM) ), ie such a package is closed at all edges.
  • This packaging can be opened, for example, by tearing or cutting open.
  • the thickness of the multilayer film (F) should in this case be designed so that a sufficient mechanical stability is present, but at the same time the film (F) - and thus the packaging produced from the film (VP) - is so flexible that a complete removal the cosmetic composition (KM) from the opened package (VP) by pressing or pressing is made possible.
  • Preferred embodiments of the present invention are therefore characterized in that the at least one multilayer film has a total thickness of 21 pm to 2.0 mm, preferably from 30 pm to 1, 0 mm, preferably from 50 pm to 500 pm, in particular from 60 pm to 200 pm.
  • the total thickness of the film (F) is understood to be the sum of the thicknesses of all individual layers of which the film (F) consists.
  • the bond strength of the film is 0.1 to 10 N / 15mm, preferably 1 to 8 N / 15mm, more preferably 1.5 to 5 N / 15mm. This is measured by the method ASTM F-904.
  • Adhesive strength is a physical measure of adhesion between layers. The adhesive strength is related to the two layers of a film with the lowest adhesive strength between two layers of one and the same film. The adhesive strengths set according to the invention lead to an advantageous mechanical stability over the storage time of the packaged cosmetic product.
  • the seal strength of the package (VP) is 10 to 40 N / 15mm, preferably 15 to 35 N / 15mm, more preferably 20 to 30 N / 15mm under the conditions of 150 ° C, 2.54 cm () and 4 kg / cm 2 .
  • the seal seam strength is measured according to the method ASTM F-88 under the above Conditions. The challenge with packaging is always to ensure the mechanical durability of the packaging while at the same time allowing the user easy access to the contents. Setting the seal seam strength to these values enables these two goals to be achieved.
  • a sealed seam is understood to mean a seam through which the packaging is closed.
  • two films are superimposed, which are pressed together by a force perpendicular to the film surface.
  • parts of the compressed areas may fuse together so that the foils are welded together.
  • the arrangement of layers (P1), (P2) and (BS) within the multilayer film (F) may be different. Furthermore, it is also possible for the film (F) to comprise further layers in addition to the previously mentioned layers. In addition, it is advantageous according to the invention if all of the above-mentioned layers are each oriented parallel to the surfaces of the film (F), ie all layers have the same orientation.
  • the barrier layer (BS) is arranged on the side in contact with the cosmetic composition (KM).
  • the first polymer layer (P1) thus adjoins the barrier layer (BS) on the one hand and the second polymer layer (P2) on the outside of the packaging, on the other hand.
  • the polymer layer (P1) is different from the polymer layer (P2).
  • the barrier layer (BS) serves as a carrier layer onto which the first polymer layer (P1) is then applied.
  • the second polymer layer (P2) is then applied to this polymer layer (P1).
  • the three layers (BS), (P1) and (P2) together form a film (F) whose total thickness is preferably from 30 .mu.m to 1, 0 mm.
  • the multilayer film (F) consists of three layers, the layer (P1) being in the innermost position and in contact with the cosmetic composition (KM).
  • the layer (P1) is in contact with the barrier layer (BS), and the barrier layer (BS) in turn makes contact with the layer (P2).
  • the layers (P1) and (P2) do not adjoin one another but are separated by the barrier layer (BS).
  • the layers (P1) and (P2) may in principle be made of the same polymeric material, but it is preferred if the two layers (P1) and (P2) are made of different polymeric materials.
  • the particular advantage of this arrangement is that the - often very thin - barrier layer (BS) neither on the inner nor on the outer surface of the multilayer Foil (F), but is protected in the direction of the inside by the polymeric layer (P1) and in the direction of the outside by the polymeric layer (P2). In this way, in this arrangement, a mechanical abrasion or mechanical destruction of the barrier layer (BS) are best avoided.
  • the at least one multilayer film (F) is therefore advantageous in the context of the present invention for the at least one multilayer film (F) to contain the at least one barrier layer (BS) between the at least one first polymer layer (P1) and the at least one second polymer layer (P2).
  • BS barrier layer
  • a film (F) in which the first polymer layer (P1) is arranged on the side in contact with the cosmetic composition (KM).
  • the second polymer layer (P2) is adjacent to and different from the polymer layer (P1). Outside is the barrier layer (BS).
  • the layer (P1) can function as a polymeric carrier layer onto which the second polymeric layer (P2) is then applied. Subsequently, the side adjacent to (P2) (i.e., the outside) is provided with the barrier layer. It is therefore advantageous in the context of the present invention for the at least one multilayer film (F) to contain the at least one barrier layer (BS) on the outside of the packaging (VP).
  • the outer side of the packaging is understood to mean that side of the packaging which does not come into contact with the cosmetic composition (CM) but with the environment.
  • the three layers (P1), (P2) and (BS) in this case form a film (F) whose total thickness is preferably from 30 .mu.m to 1, 0 mm.
  • the use of such packages has been found to be particularly advantageous in terms of increased storage stability since this arrangement exhibits neither bloating nor delamination with prolonged contact time with an oxidizer-containing composition.
  • the multilayer film (F) contains the above-described three layers (P1), (P2) and (BS), suitable arrangements according to the invention of the layers are described below (from inside (in contact with the cosmetic composition (KM)) to the outside considered):
  • the first polymeric material of the first layer (P1) is according to the invention an organic polymeric material. This material may be a polymer type layer or a polymer blend layer.
  • This first layer (P1) can, for example, function as a polymeric carrier material, ie in the production of the film a layer or a film of the polymeric material (P1) can be initially charged and then sprayed, laminated or coated with the further inventive layers.
  • the at least one first polymer layer (P1) is formed from polypropylene, polyethylene, polyester, polyamide or polyvinyl alcohol, in particular from polypropylene.
  • the term "formed” is understood according to the invention that the polymer layer at least 70 wt .-%, preferably at least 80 wt .-%, preferably at least 90 wt .-%, in particular at least 99 wt .-%, jewiels based on the total weight the polymer layer (P1) containing previously mentioned compounds.
  • a particularly preferred product according to the invention is therefore characterized in that the multilayer film (F) comprises at least one first polymer layer (P1) which is formed from polypropylene.
  • Polypropylene is alternatively referred to as poly (1-methylethylene), and is a thermoplastic polymer belonging to the group of polyolefins.
  • Polypropylene is produced by polymerization of propylene (propene) using various catalysts.
  • polypropylene can be produced by stereospecific polymerization of propylene in the gas phase or in suspension according to Giulio Natta.
  • Polypropylenes of the invention may be isotactic and thus highly crystalline, but also syndiotactic or amorphous.
  • the regulation of the average relative molar mass can be effected, for example, by setting a specific hydrogen partial pressure during the polymerization of the propene.
  • polypropylene may have average relative molecular weights of about 150000 to 1500000 g / mol.
  • the processing of polypropylene can be done, for example, by extrusion and stretch blow molding, or by pressing, calendering, thermoforming, and cold forming.
  • the first polymer layer (P1) preferably has a specific layer thickness. It is therefore preferred in the context of the present invention if the at least one first polymer layer (P1) has a layer thickness of from 20.0 ⁇ m to 300 ⁇ m, preferably from 40.0 ⁇ m to 200 ⁇ m, preferably from 50.0 ⁇ m to 100 ⁇ m, in particular from 60.0 pm to 90.0 pm.
  • multilayer film (F) comprises at least one first polymer layer (P1), which is formed from polypropylene and has a layer thickness of 60.0 to 90.0 ⁇ m.
  • the multilayer film (F) from which the package is made comprises a second polymer layer (P2) of a second polymeric material.
  • the second polymeric material It may be a layer of a polymer type or a layer of a polymer mixture.
  • the second layer (P2) can be sprayed, applied or coated either before or after application of the barrier layer (BS) on the first polymer layer (P1) acting as a carrier layer.
  • the second polymer layer (P2) acts as a carrier layer, to which then the barrier layer (BS) and the first polymer layer (P1) are applied.
  • the first polymeric material of the first polymer layer (P1) and the second polymeric material of the second polymer layer (P2) may be the same (if both layers are not in contact with each other) or may be different.
  • the polymer layer (P2) can therefore be formed from the compounds previously mentioned in connection with the polymer layer (P1).
  • the layers (P1) and (P2) are made of different polymeric materials (i.e., different polymers or polymer blends). It is therefore preferred within the scope of the present invention for the at least one second polymer layer (P2) to be formed from polyethylene terephthalate or polyethylene naphthalate, in particular from polyethylene terephthalate.
  • polymer layer at least 70 wt .-%, preferably at least 80 wt .-%, preferably at least 90 wt .-%, in particular at least 99 wt .-%, jewiels based on the total weight the polymer layer (P2) containing previously mentioned compounds.
  • PET Polyethylene terephthalate
  • the production of polyethylene terephthalate can be carried out, for example, by transesterification of dimethyl terephthalate with ethylene glycol at higher temperatures. In this transesterification reaction, methanol is split off, which is removed by distillation.
  • the resulting bis (2-hydroxyethyl) terephthalate is converted by polycondensation to PET, which again produces ethylene glycol.
  • Another production method of polyethylene terephthalate is the direct polycondensation of ethylene glycol and terephthalic acid at high temperatures while distilling off the resulting water.
  • the second polymer layer (P2) has a smaller layer thickness than the polymer layer (P1). It is therefore advantageous in the context of the present invention for the at least one second polymer layer (P2) to have a layer thickness of from 1.00 ⁇ m to 100 ⁇ m, preferably from 2.50 ⁇ m to 50.0 ⁇ m, preferably from 5.00 ⁇ m to 25 ⁇ m , 0 pm, in particular from 10.0 pm to 20.0 pm.
  • a particularly preferred product according to the invention is therefore characterized in that multilayer film (F) comprises at least one second polymer layer (P2), which is formed from polyethylene terephthalate and has a layer thickness of 10.0 to 20.0 ⁇ m.
  • the polymer layers (P1) and (P2) of the multilayer film (F) consist of organic polymeric materials, which usually have only an insufficient barrier effect against gases and water vapor. If the oxidizing agent-containing composition (KM) in a package (VP) of a multilayer film (F) packed, which comprises only the two organic polymer layers (P1) and (P2), water vapor can escape unhindered, so that the Water content in the composition (KM) changed unacceptably during prolonged storage. In order to minimize the uncontrolled escape of water vapor from the packaging (VP), the organic polymer layers (P1) and (P2) are therefore used in conjunction with a barrier layer (BS).
  • BS barrier layer
  • the barrier layer (BS) has a natural detergent mitr für vapor.
  • the barrier layer (BS) reduces the permeation rate of water vapor and gases through the film.
  • a film (F) according to the invention which has a barrier layer (BS) in addition to the layers (P1) and (P2), thus has a comparison to a comparable film (with the same total thickness), which only the two layers (P1) and (P2), however, has no barrier layer (BS), reduced water vapor permeability and reduced gas permeability.
  • the barrier layer (BS) is, for example, a thin layer which comprises an inorganic material, the inorganic material being applied to the organic polymer layer by means of vacuum coating techniques (eg PVD "physical vapor deposition” or CVD “chemical vapor deposition”). P1) and / or (P2) can be applied.
  • vacuum coating techniques eg PVD "physical vapor deposition” or CVD “chemical vapor deposition”
  • the barrier layer (BS) is a layer comprising at least one inorganic material, aluminum, aluminum oxides, magnesium, magnesium oxides, silicon, silicon oxides, titanium, titanium oxides, tin, tin oxides, zirconium, zirconium oxide and / or or carbon in question.
  • oxides which can be selected from the group consisting of aluminum oxides, magnesium oxides, silicon oxides, titanium oxides, tin oxides and / or zirconium oxides.
  • the barrier layer (BS) of inorganic material is very particularly preferably between the two polymer layers (P1) and (P2). The production of films with barrier layers of inorganic material is described, for example, in document EP 1036813 A1, to which reference is made at this point in full.
  • the barrier layer (BS) may also comprise a thin layer of inorganic-organic hybrid polymers.
  • ORMOCER polymers are known in the literature under the technical term ORMOCER polymers.
  • a typical ORMOCER polymer can be prepared, for example, by hydrolytic polycondensation of an organofunctional silane with an aluminum compound and optionally with an inorganic oxide component. Corresponding syntheses are disclosed for example in the document EP 0792846 B1, to which reference is made at this point in full.
  • Inorganic-organic hybrid polymers (ORMOCER polymers) have both inorganic and organic network structures. The structure of the inorganic silicate network structure can be carried out in the sol-gel process via the controlled hydrolysis and condensation of alkoxysilanes.
  • the silicate network can be modified in a targeted manner.
  • organofunctional groups which are introduced by the organoalkoxylans in the material, an organic network is additionally built.
  • the ORMOCER polymers produced in this way can be applied to the layers (P1) and / or (P2), for example by means of conventional application techniques (spraying, brushing, etc.).
  • the at least one barrier layer (BS) consists of aluminum oxides, magnesium oxides, silicon oxides, titanium oxides, tin oxides, zirconium oxides, inorganic-organic hybrid polymers (ORMOCER polymers) or mixtures thereof, in particular of silicon oxides ,
  • the term "formed” is understood according to the invention that the polymer layer at least 70 wt .-%, preferably at least 80 wt .-%, preferably at least 90 wt .-%, in particular at least 99 wt .-%, jewiels based on the total weight the barrier layer (BS), which contains previously mentioned compounds.
  • Particularly preferred are multilayer films (F) according to the invention, in which the barrier layer (BS) is formed from silicon oxides or inorganic-organic hybrid polymers (ORMORCER polymers).
  • the multilayer film (F), which is the wall of the package (VP), has a barrier layer (BS) comprising both inorganic oxide components and inorganic-organic hybrid polymers (ORMOCER polymers).
  • the barrier layer (BS) may also comprise a further organic polymeric material which itself has no barrier effect, but for example increases the mechanical stability of the barrier layer, simplifies production or better bonding of the layers (BS) and (P1) and / or (P2) causes.
  • multilayer films (F) according to the invention in which the barrier layer (BS) is formed from aluminum oxides, magnesium oxides, silicon oxides, titanium oxides, tin oxides, zirconium oxides and mixtures thereof and additionally at least one inorganic-organic hybrid polymer (ORMORCER polymers).
  • the barrier layer (BS) is formed from aluminum oxides, magnesium oxides, silicon oxides, titanium oxides, tin oxides, zirconium oxides and mixtures thereof and additionally at least one inorganic-organic hybrid polymer (ORMORCER polymers).
  • the thickness of the barrier layer (BS) can therefore be chosen as a function of the desired barrier effect.
  • the barrier layer (BS) may have a layer thickness of 1 to 1000 nm (nanometers).
  • the barrier layer (BS) preferably has a layer thickness of 5 to 500 nm, more preferably of 10 to 250 nm, and particularly preferably from 10 to 150 nm (nanometers).
  • the at least one barrier layer has a layer thickness of from 1.00 nm to 1000 nm, preferably from 5.00 nm to 500 nm, preferably from 10.0 nm to 250 nm, in particular from 10.0 nm to 150 nm.
  • the multilayer film (F) may additionally comprise one or more further layers. These further layers may be, for example, intermediate layers and / or adhesive layers. It is therefore preferred according to the invention if the at least one multilayer film (F) additionally contains at least one further layer selected from the group of intermediate layers (SZ), adhesive layers (SK) and mixtures thereof.
  • the films (F) may have further intermediate layers (SZ) in order to increase the mechanical stability.
  • Interlayers may also prevent or minimize the permeation of polymers or residual monomers from a polymer layer into the cosmetic composition (CM).
  • the films may also include one or more adhesive layers (SK) to reduce or prevent delamination (i.e., peeling or air space buildup) between two layers.
  • SK adhesive layers
  • a particularly preferred product according to the invention is characterized in that the multilayer film (F) additionally contains, in addition to the first polymer layer (P1), the second polymer layer (P2) and the barrier layer (BS), one or more further layers which consist of intermediate layers (SZ ) and / or adhesive layers (SK) are selected.
  • the multilayer film (F) additionally contains, in addition to the first polymer layer (P1), the second polymer layer (P2) and the barrier layer (BS), one or more further layers which consist of intermediate layers (SZ ) and / or adhesive layers (SK) are selected.
  • the multilayer film (F) also contains further layers in addition to the layers (P1), (P2) and (BS), suitable arrangements according to the invention of the layers are described below (of interior space (in contact with the cosmetic composition (KM)). ) to the outside):
  • the product according to the invention comprises as a second constituent a cosmetic composition (KM) packaged in the packaging (VP) and comprising at least one oxidizing agent, a Cs-Cso alcohol, a nonionic surfactant, an anionic surfactant and a complexing compound.
  • a cosmetic composition KM packaged in the packaging (VP) and comprising at least one oxidizing agent, a Cs-Cso alcohol, a nonionic surfactant, an anionic surfactant and a complexing compound.
  • the preparation (B) may contain various ingredients. If a pure lightening or bleaching is to be achieved, the preparation contains (B) at least one alkalizing agent. If an oxidative dyeing is desired, in the preparation (B) in addition to the alkalizing often Oxidationsfarbstoffvorpodukte included.
  • CM Cosmetic composition
  • B a cosmetic composition
  • CM oxidizing agent
  • the preparation (KM) according to the invention is an aqueous preparation.
  • the cosmetic composition (KM) contains as the first essential ingredient a) at least one oxidizing agent. Preference is given to using certain oxidizing agents. It is therefore in the context of the present invention, when the cosmetic composition (KM) at least one oxidizing compound selected from the group of persulfates, chlorites, hydrogen peroxide and addition products of hydrogen peroxide to urea, melamine and sodium borate, in particular hydrogen peroxide.
  • the cosmetic composition (KM) at least one oxidizing compound selected from the group of persulfates, chlorites, hydrogen peroxide and addition products of hydrogen peroxide to urea, melamine and sodium borate, in particular hydrogen peroxide.
  • the use of hydrogen peroxide has proved to be particularly advantageous according to the invention.
  • the concentration of the oxidizing agent in the composition (KM) is determined on the one hand by the legal requirements and on the other hand by the desired effect; preferably 0.5 to 20.0 wt .-% solutions are used in water. It is therefore preferred according to the invention for the cosmetic composition (KM) to contain the at least one oxidizing compound, in particular hydrogen peroxide, in a total amount of from 0.5 to 20% by weight, preferably from 1.0 to 18% by weight, preferably from 1, 2 to 16 wt .-%, in particular from 1, 5 to 15 wt .-%, based on the total weight of the cosmetic composition (KM) contains.
  • the amount of hydrogen peroxide refers to 100% hydrogen peroxide.
  • packages (VP) according to the invention which contained preparations (KM) with 9 to 12% by weight of hydrogen peroxide showed no volume changes even after several weeks storage at elevated temperature (ie no swelling) and no unscheduled openings (ie the packages did not burst).
  • the cosmetic composition (KM) contains as second essential ingredient b) at least one Cs-Cso-alcohol.
  • mixtures of linear Ci 4 -Ci8 alcohols have proven particularly useful.
  • the cosmetic composition (KM) at least one linear Cio-C3o-alcohol selected from the group of linear C10-C28 alcohols, linear Ci2-C26 alcohols, linear Ci 4 -C 20 Alcohols, linear Ci 4 -Ci8 alcohols and mixtures of the aforementioned alcohols, in particular a mixture of linear C14-C18 alcohols containing.
  • the mixture of cetyl alcohol and stearyl alcohol known under the name cetearyl alcohol in particular a mixture of 50% by weight of cetyl alcohol and 50% by weight of stearyl alcohol, based on the total weight of the mixture, has proven to be particularly advantageous.
  • the at least one Cs-Cso-alcohol is preferably used in certain quantitative ranges.
  • Preferred embodiments of the present invention are therefore characterized in that the cosmetic composition (KM) the at least one linear Cs-Cso-alcohol, in particular a mixture of linear C 4 -C 18 -alcohols, in a total amount of 0.10 to 7.0 Wt .-%, preferably from 0.50 to 6.5 wt .-%, preferably from 1, 0 to 6.0 wt .-%, in particular from 1, 0 to 5.0 wt .-%, based on the Total weight of the cosmetic composition (KM).
  • the cosmetic composition (KM) contains at least one anionic surfactant.
  • anionic surfactants ensures a sufficient miscibility of the cosmetic (KM) with the preparation (B), which contains the oxidation dye precursors, and also ensures a high storage stability, since precipitation of components of the cosmetic composition (KM) is avoided.
  • the cosmetic composition (KM) at least one anionic surfactant selected from the group of (i) Cs-Ci8-Alkylethersulfaten with 1 to 10 moles of ethylene oxide per mole of Cs-C-is-alkyl ether sulfate and salts thereof, in particular of sodium salts of C 2 -C 4 -alkyl ether sulfates with 2 moles of ethylene oxide per mole of C 2 -C 4 -alkyl ether sulfate, (c) C 2 -C 4 -alkyl sulfates, (iii) salts of linear and branched C 8 - C30 carboxylic acids, (iv) acyl sarcosides having 8 to 24 carbon atoms in the acyl group, (v) acyl taurides having 8 to 24 carbon atoms in the acyl group, (vi) acyl isethionates having 8 to
  • Sodium salts of Ci 4 -Ci8 alkyl sulfates contains.
  • An anionic surfactant which is particularly suitable for the purposes of the present invention is the compound Sodium Cetearyl Sulfate known under the INCI name (CAS No .: 59186-41-3).
  • the at least one anionic surfactant is preferred in certain Total quantities used. It is therefore preferred in the context of the present invention, when the cosmetic composition (KM), the at least one anionic surfactant, in particular sodium salts of CwC-is-alkyl sulfates, in a total amount of 0, 10 to 7.0 wt .-%, preferably from 0.10 to 5.5% by weight, preferably from 0.10 to 4.0% by weight, in particular from 0.10 to 3.5% by weight, based on the total weight of the cosmetic composition (KM) , contains.
  • the at least one anionic surfactant in particular sodium salts of CwC-is-alkyl sulfates
  • the cosmetic composition (KM) contains at least one nonionic surfactant.
  • the combination of at least one anionic and at least one nonionic surfactant achieves excellent dispersion of the constituents of the cosmetic composition (KM) and thus high storage stability.
  • the cosmetic composition (KM) at least one nonionic surfactant selected from the group of (i) ethoxylated and / or propoxylated alcohols and carboxylic acids having 8 to 30 carbon atoms and 2 to 30 ethylene oxide and (ii) addition products of 30 to 50 moles of ethylene oxide with castor oil and hydrogenated castor oil, (iii) alkyl polyglucosides of the formula R 1 0- [G] P in which R 1 is an alkyl and / or alkenyl radical with 4 to 22 carbon atoms, G stands for a sugar residue with 5 or 6 carbon atoms and p stands for numbers from 1 to 10, (iv) monoethanolamides of carboxylic acids having 8 to 30 carbon atoms and (v) mixtures thereof, in particular adducts of 40 moles of ethylene oxide hydrogenated castor oil.
  • nonionic surfactant selected from the group of (i) ethoxylated and / or propoxylated alcohols and carboxylic acids having 8 to 30
  • the index number p indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglucosides, and stands for a number between 1 and 10.
  • DP degree of oligomerization
  • alkyl and / or alkenyl oligoglucosides are preferred whose degree of oligomerization is less than 1.7, and in particular between 1.2 and 1.7.
  • the alkyl or alkenyl radical R 1 can be derived from primary alcohols having 4 to 20, preferably 8 to 16 carbon atoms.
  • alkyl oligoglucosides based on hydrogenated C 2 / i4 cocoalcohol with a DP of 1-3 as they are commercially available for example under the INCI name "Coco-glucoside”.
  • nonionic surfactants are ethoxylated alcohols having 14 to 18 carbon atoms and 20 to 30 moles of ethylene oxide per mole of alcohol, especially those under the INCI name ceteareth-20 (CAS No .: 68439-49-6) known compound.
  • the at least one nonionic surfactant is preferably used in certain total amounts.
  • the cosmetic composition (KM) comprises the at least one nonionic surfactant, in particular adducts of 40 moles of ethylene oxide and hydrogenated castor oil, in a total amount of 0.10 to 4.0% by weight, preferably from 0, 12 to 3.0 wt .-%, preferably from 0, 15 to 2.5 wt .-%, in particular from 0.20 to 2.0 wt .-%, based on the total weight of the cosmetic composition (KM ) contains.
  • the cosmetic composition (KM) contains as fifth essential ingredient e) at least one complexing compound.
  • This complexing compound leads to an improved stabilization of the oxidizing agent, in particular the hydrogen peroxide, since this is protected from decomposition as a result of the reaction with metal ions of the cosmetic composition (KM).
  • certain complexing compounds are preferably used. It is therefore advantageous according to the invention if the cosmetic composition (KM) comprises at least one complexing compound selected from the group of ⁇ -alaninediacetic acid, cyclodextrin,
  • Diethylenetriaminepentamethylenephosphonic acid ethylenediaminetetraacetic acid (EDTA) and salts thereof, etidronic acid, hydroxyethylethylenediaminetetraacetic acid (HEDTA) and its sodium salts, sodium salts of nitrilotriacetic acid (NTA), diethylenetriaminepentaacetic acid, phytic acid, hydroxypropyl cyclodextrin, methylcyclodextrin, Aminotrimethylenphosphonat pentasodium, ethylenediamine pentasodium, diethylenetriamine pentaacetate pentasodium, pentasodium triphosphate , Potassium EDTMP, sodium EDTMP, sodium dihydroxyethylglycinate, sodium phytate, sodium polydimethylglycinophenolsulphonate, tetrahydroxyethylethylenediamine, tetrahydroxypropylethylenediamine, tetrapot
  • Tetrasodiumiminodisuccinate trisodium ethylenediamine disuccinate, tetrasodium N, N-bis (carboxymethyl) glutamate, tetrasodium DL-alanine-N, N-diacetate and desferrioxamine, especially ethylenediaminetetraacetic acid.
  • ethylenediaminetetraacetic acid CAS No. xxxx
  • the use of ethylenediaminetetraacetic acid has proved to be particularly advantageous with regard to the stabilization of the oxidizing agent, in particular the hydrogen peroxide.
  • the at least one complexing compound, in particular ethylenediaminetetraacetic acid is preferably present in the cosmetic compositions (KM) in specific total amounts.
  • the cosmetic composition (KM) contains the at least one complexing compound, in particular ethylenediaminetretraacetic acid, in a total amount of 0, 10 to 1, 0% by weight, preferably from 0, 10 to 0, 80 wt.%, Preferably from 0.10 to 0.60 wt. %, in particular from 0, 10 to 0.50 wt .-%, based on the total weight of the cosmetic composition (KM) contains.
  • the product according to the invention is therefore characterized in that the cosmetic composition (KM) hydrogen peroxide, a mixture of linear Cw-Ci8 alcohols, a sodium salt of a Ci6-Ci8-alkyl sulfate, an adduct of 40 moles of ethylene oxide hydrogenated castor oil and Contains ethylenediaminetetraacetic acid.
  • the cosmetic composition (KM) hydrogen peroxide, a mixture of linear Cw-Ci8 alcohols, a sodium salt of a Ci6-Ci8-alkyl sulfate, an adduct of 40 moles of ethylene oxide hydrogenated castor oil and Contains ethylenediaminetetraacetic acid.
  • the abovementioned compounds are preferably used in specific amounts in the preparation (KM). Particularly preferred embodiments are therefore characterized in that the cosmetic composition (KM)
  • the cosmetic composition (KM) preferably has an acidic pH in order to avoid or reduce decomposition of the oxidizing agent used, in particular of the hydrogen peroxide. It is therefore preferred in the context of the present invention if the cosmetic composition (KM) has a pH (measured at 20 ° C.) of from pH 1.5 to 5.0, preferably from pH 2.0 to pH 4.6 , preferably from pH 2.3 to pH 4.5, in particular from pH 3 to pH 4, having.
  • the preparation (CM) present in the packaging (VP) contains the essential ingredients in an aqueous or aqueous-alcoholic carrier, which is, for example, a cream, an emulsion, a gel or a surfactant-containing foaming solution can act.
  • an aqueous or aqueous-alcoholic carrier which is, for example, a cream, an emulsion, a gel or a surfactant-containing foaming solution can act.
  • the preparation (KM) may continue to contain additional active ingredients, auxiliaries and additives.
  • the preparation (KM) may, for example, additionally contain one or more acids for stabilizing the oxidizing agent used, in particular the hydrogen peroxide. It is therefore within the scope of the present invention preferred if the cosmetic composition (KM) additionally at least one acid selected from the group of dipicolinic acid, citric acid, acetic acid, malic acid, lactic acid, tartaric acid, hydrochloric acid, phosphoric acid, pyrophosphoric acid and its salts, benzoic acid and their salts, 1-hydroxyethane-1, 1-diphosphonic acid, ethylenediaminetetraacetic acid and its salts, sulfuric acid and mixtures, in particular a mixture of disodium pyrophosphate and benzoic acid and salts thereof.
  • the cosmetic composition (KM) additionally at least one acid selected from the group of dipicolinic acid, citric acid, acetic acid, malic acid, lactic acid, tartaric acid, hydrochloric acid, phosphoric acid, pyrophosphoric acid and its salts, benzoic
  • a particularly high stabilization of the oxidizing agent, in particular the hydrogen peroxide, is achieved when the abovementioned acids are used in certain quantitative ranges. It is therefore advantageous in this context if the at least one acid, in particular the mixture of disodium pyrophosphate and benzoic acid and salts thereof, in a total amount of 0, 1 to 3.0 wt .-%, preferably from 0.5 to 2.5 Wt .-%, preferably from 0.8 to 2.0 wt .-%, in particular from 0.9 to 1, 5 wt .-%, based on the total weight of the cosmetic composition (KM), is included.
  • Hydrogen peroxide amount calculated on 100% hydrogen peroxide,) mixture of linear C 4 -C 18 -alcohols, in particular cetearyl alcohol,) sodium salts of C 16 -C 18 -alkyl sulfates, in particular sodium cetearyl sulfate,) addition products of 40 mol of ethylene oxide onto hydrogenated castor oil,) ethylenediaminetetraacetic acid .
  • the products according to the invention obtainable in this way have a high storage stability and a water loss within the acceptable range during storage. No bloating or delamination of the package (VP) was observed during storage of these cosmetic products according to the invention.
  • the product according to the invention is used for the purpose of oxidative color change.
  • the preparation (KM) packaged in the packaging (VP), which is the oxidizing agent preparation is mixed with at least one further preparation (B) to produce the ready-to-use color-changing agent.
  • the preparations (KM) and (B) are made up separately from each other.
  • a particularly preferred product according to the invention is characterized in that it comprises a preparation (B) prepared separately from the preparation (KM), wherein the preparation (B) contains at least one compound selected from oxidation dye precursors, substantive dyes, alkalizing agents and mixtures thereof.
  • Preferred products of the present invention are therefore characterized by additionally comprising at least one second cosmetic composition (KM2) comprising at least one compound selected from oxidation dye precursors, substantive dyes, alkalizing agents and mixtures thereof and which are separate from the cosmetic composition (KM). is made up.
  • the preparation (B) contains at least one oxidation dye precursor.
  • Oxidation dye precursors can be subdivided into developers and couplers, the developers being mostly used in the form of their physiologically acceptable salts (for example in the form of their hydrochlorides, hydrobromides, hydrogen sulfates or sulfates) because of their greater sensitivity to oxygen.
  • Coupler components do not form a significant color within the framework of the oxidative dyeing alone, but always require the presence of developer components.
  • such agents include at least one developer-type oxidation dye precursor and at least one coupler-type oxidation dye precursor.
  • Particularly suitable developer-type oxidation dye precursors are selected from at least one compound from the group formed from p-phenylenediamine, p-toluenediamine, 2- (2-hydroxyethyl) -p-phenylenediamine, 2- (1,2-dihydroxyethyl ) -p-phenylenediamine, N, N-bis (2-hydroxyethyl) -p-phenylenediamine, 2-methoxymethyl-p-phenylenediamine, N- (4-amino-3-methylphenyl) -N- [3- (1H -imidazol-1-yl) propyl] amine, N, N'-bis (2-hydroxyethyl) -N, N'-bis (4-aminophenyl) -1, 3-diamino-propan-2-ol, bis (2-hydroxy-5-aminophenyl) methane, 1, 3-bis (2,5-diaminophenoxy) propan-2-ol
  • coupler-type oxidation dye precursors are selected from the group formed from 3-aminophenol, 5-amino-2-methylphenol, 3-amino-2-chloro-6-methylphenol, 2-hydroxy-4-aminophenoxyethanol, 5-Amino-4-chloro-2-methylphenol, 5- (2-hydroxyethyl) amino-2-methylphenol, 2,4-dichloro-3-aminophenol, 2-aminophenol, 3-phenylenediamine, 2- (2,4 - diaminophenoxy) ethanol, 1, 3-bis (2,4-diaminophenoxy) propane, 1-methoxy-2-amino-4- (2- hydroxyethylamino) benzene, 1, 3-bis (2,4-diaminophenyl) propane, 2,6-bis (2'-hydroxyethylamino) -1-methylbenzene, 2 - ( ⁇ 3 - [(2-hydroxyethyl) amino] -4 -methoxy-5-methylphenyl ⁇ amino) ethanol
  • the preparation (B) may also contain one or more substantive dyes.
  • Suitable nonionic substantive dyes may be selected from the group HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, HC Orange 1, Disperse Orange 3, HC Red 1, HC Red 3, HC Red 7 , HC Red 10, HC Red 1, HC Red 13, HC Red BN, HC Blue 2, HC Blue 1 1, HC Blue 12, Disperse Blue 3, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Disperse Black 9 , 1, 4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1, 4-bis (2-hydroxyethyl) amino-2-nitrobenzene, 3-nitro-4- (2-hydroxyethyl) aminophenol, 2- (2-hydroxyethyl) amino-4,6-dinitrophenol, 4 - [(2-hydroxyethyl) amino] -3-nitro-1-methylbenzene, 1-amino-4- (2-hydroxyethyl) amino-5 - chloro-2-
  • Suitable anionic direct dyes may be selected from the group Acid Yellow 1, Yellow 10, Acid Yellow 23, Acid Yellow 36, Acid Orange 7, Acid Red 33, Acid Red 52, Pigment Red 57: 1, Acid Blue 7, Acid Green 50, Acid Violet 43, Acid Black 1, Acid Black 52, bromophenol blue and tetrabromophenol blue.
  • Suitable cationic substantive dyes are cationic triphenylmethane dyes such as Basic Blue 7, Basic Blue 26, Basic Violet 2 and Basic Violet 14, aromatic systems substituted with a quaternary nitrogen group such as Basic Yellow 57, Basic Red 76, Basic Blue 99 , Basic Brown 16 and Basic Brown 17, cationic anthraquinone dyes such as HC Blue 16 (Bluequat B) and direct dyes containing a heterocycle having at least one quaternary nitrogen atom, in particular Basic Yellow 87, Basic Orange 31 and Basic Red 51 ,
  • the cationic substantive dyes which are sold under the trademark Arianor, according to the invention are also suitable cationic substantive dyes.
  • the pH of the agent (B) is between 7 and 11, in particular between 8 and 10.5.
  • the pH values are pH values which were measured at a temperature of 22 ° C.
  • the preparation (B) may contain at least one alkalizing agent.
  • the alkalizing agents which can be used according to the invention for adjusting the preferred pH can be selected from the group consisting of ammonia, alkanolamines, basic amino acids and inorganic alkalizing agents such as (earth) alkali metal hydroxides, (earth) alkali metal metasilicates, (alkaline) alkaline metal phosphates and ( Earth) alkali metal hydrogen phosphates.
  • Preferred inorganic alkalizing agents are magnesium carbonate, sodium hydroxide, potassium hydroxide, sodium silicate and sodium metasilicate.
  • Organic alkalizing agents which can be used according to the invention are preferably selected from monoethanolamine, 2-amino-2-methylpropanol and triethanolamine.
  • the basic amino acids which can be used as alkalizing agents according to the invention are preferably selected from the group formed from arginine, lysine, ornithine and histidine, more preferably arginine.
  • further preferred agents according to the invention are characterized in that they additionally contain an organic alkalizing agent.
  • An embodiment of the first subject of the invention is characterized in that the agent additionally contains at least one alkalizing agent which is selected from the group consisting of ammonia, alkanolamines and basic amino acids, in particular ammonia, monoethanolamine and arginine or its compatible salts.
  • the preparation (B) may further comprise additional active ingredients, auxiliaries and additives.
  • additional active ingredients for example, one or more fatty constituents from the group of C 2 -C 30 fatty alcohols, C 12 -C 30 fatty acid triglycerides, C 2 -C 30 fatty acid monoglycerides, C 2 -C 30 fatty acid diglycerides and / or hydrocarbons may be present.
  • a surface-active substance may additionally be added, such surface-active substances being referred to as surfactants or as emulsifiers, depending on the field of application. They are preferably selected from anionic, zwitterionic, amphoteric and nonionic surfactants and emulsifiers.
  • the preparation (B) contains at least one anionic surfactant.
  • anionic surfactants are fatty acids, alkyl sulfates, alkyl ether sulfates and ether carboxylic acids having 10 to 20 carbon atoms in the alkyl group and up to 16 glycol ether groups in the molecule.
  • the preparation (B) additionally contain at least one zwitterionic surfactant.
  • Preferred zwitterionic surfactants are betaines, N-alkyl-N, N-dimethylammonium glycinates, N-acylaminopropyl-N, N-dimethylammonium glycinates, and 2-alkyl-3-carboxymethyl-3-hydroxyethylimidazolines.
  • a preferred zwitterionic surfactant is known by the INCI name Cocamidopropyl Betaine.
  • the preparation (B) contains at least one amphoteric surfactant.
  • amphoteric surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids.
  • Particularly preferred amphoteric surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C 12 -C 18 -acylsarcosine.
  • the preparation (B) contain other nonionic surfactants.
  • Preferred nonionic surfactants are alkyl polyglycosides and alkylene oxide adducts of fatty alcohols and fatty acids with in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Preparations having excellent properties are also obtained if they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
  • the nonionic, zwitterionic or amphoteric surfactants are used in proportions of 0, 1 to 45 wt.%, Preferably 1 to 30 wt.% And most preferably from 1 to 15 wt.%, Based on the total weight of the preparation (B), used.
  • the preparation (B) may additionally contain at least one thickener.
  • thickeners there are no fundamental restrictions. Both organic and purely inorganic thickening agents can be used. Suitable thickening agents are anionic, synthetic polymers, cationic synthetic polymers, naturally occurring thickeners such as nonionic guar gums, scleroglucan gums or xanthan gums, gum arabic, ghatti gum, karaya gum, tragacanth gum, carrageen gum, agar-agar, locust bean gum, Pectins, alginates, starch fractions and derivatives such as amylose, amylopectin and dextrins, as well as cellulose derivatives such as methylcellulose, carboxyalkylcelluloses and hydroxyalkylcelluloses, nonionic fully synthetic polymers such as polyvinyl alcohol or polyvinylpyrrolidinone; and inorganic thickening agents, in particular phyllosilicates such as bentonite,
  • the preparation (B) may contain other active ingredients, auxiliaries and additives, such as nonionic polymers such as vinylpyrrolidinone / vinyl acrylate copolymers, polyvinylpyrrolidinone, vinylpyrrolidinone / vinyl acetate copolymers, polyethylene glycols and polysiloxanes; additional silicones, such as volatile or nonvolatile, straight-chain, branched or cyclic, crosslinked or uncrosslinked polyalkylsiloxanes (such as dimethicones or cyclomethicones), polyarylsiloxanes and / or polyalkylarylsiloxanes, in particular polysiloxanes with organofunctional groups, such as substituted or unsubstituted amines (amodimethicones), carboxyl, Alkoxy and / or hydroxyl groups (dimethicone copolyols), linear polysiloxane (A) polyoxyalkylene (B) block copolymers, graft
  • a 100 nm thick layer of silicon dioxide SiOx was vapor-deposited. Subsequently, the SiOx layer was overcoated with about 3 g / m2 ORMOCER polymer and cured. A 70 ⁇ m (microns) thick layer of polypropylene was then applied to the ORMOCER layer. From the film, a packaging (VP) was produced.
  • VP packaging
  • the following cosmetic composition (KM) was used (all data in% by weight).
  • the cosmetic composition KM filled into the previously described packaging (VP). Then the packages were stored at 40 ° C for 24 weeks. The packages were not bloated or delaminated.

Abstract

La présente invention concerne un produit cosmétique destiné à modifier la couleur naturelle de fibres kératiniques, en particulier des cheveux, ce produit comprenant au moins un emballage (VP) ainsi qu'une composition cosmétique (KM) contenue dans cet emballage (VP). L'emballage est constitué d'une feuille multicouche (F) comprenant au moins deux couches de polymère (P1) et (P2) et au moins une couche barrière (BS). La composition cosmétique comprend au moins un agent oxydant, au moins un alcool C8-C30, au moins un tensioactif anionique, au moins un tensioactif non ionique, ainsi qu'au moins un composant complexant. De manière surprenante, l'utilisation de cet emballage (VP) en combinaison avec la composition cosmétique (KM) n'entraîne pas de gonflement de l'emballage, ni une perte d'eau excessive du produit (KM) au cours du stockage.
PCT/EP2018/079683 2017-12-18 2018-10-30 Formulations de peroxyde d'hydrogène dans des feuilles à couche barrière WO2019120717A1 (fr)

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DE102017223053.3 2017-12-18
DE102017223053.3A DE102017223053A1 (de) 2017-12-18 2017-12-18 Wasserstoffperoxid-Formulierungen in Sperrschicht-Folien

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991001127A1 (fr) * 1989-07-21 1991-02-07 Brooks Geoffrey J Procede de decoloration et de traitement des cheveux, formule de decoloration et ses solutions
EP0792846A1 (fr) * 1996-02-28 1997-09-03 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Couches d'étanchéité
EP1036813A1 (fr) 1999-03-18 2000-09-20 Danisco Flexible Schüpbach AG Films à couches barrières
DE102014218006A1 (de) * 2014-09-09 2016-03-10 Henkel Ag & Co. Kgaa Verpackungseinheit (Kit-of-parts) mit speziellen aminierten Siliconpolymeren
DE102015223838A1 (de) * 2015-12-01 2017-06-01 Henkel Ag & Co. Kgaa Stabilisierte Wasserstoffperoxid-Formulierungen in Sachets aus Sperrschicht-Folien

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991001127A1 (fr) * 1989-07-21 1991-02-07 Brooks Geoffrey J Procede de decoloration et de traitement des cheveux, formule de decoloration et ses solutions
EP0792846A1 (fr) * 1996-02-28 1997-09-03 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Couches d'étanchéité
EP0792846B1 (fr) 1996-02-28 2004-08-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Couches d'étanchéité
EP1036813A1 (fr) 1999-03-18 2000-09-20 Danisco Flexible Schüpbach AG Films à couches barrières
DE102014218006A1 (de) * 2014-09-09 2016-03-10 Henkel Ag & Co. Kgaa Verpackungseinheit (Kit-of-parts) mit speziellen aminierten Siliconpolymeren
DE102015223838A1 (de) * 2015-12-01 2017-06-01 Henkel Ag & Co. Kgaa Stabilisierte Wasserstoffperoxid-Formulierungen in Sachets aus Sperrschicht-Folien

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