WO2019093267A1 - Absorbent article - Google Patents

Absorbent article Download PDF

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Publication number
WO2019093267A1
WO2019093267A1 PCT/JP2018/040997 JP2018040997W WO2019093267A1 WO 2019093267 A1 WO2019093267 A1 WO 2019093267A1 JP 2018040997 W JP2018040997 W JP 2018040997W WO 2019093267 A1 WO2019093267 A1 WO 2019093267A1
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WO
WIPO (PCT)
Prior art keywords
absorbent sheet
layer
absorbent
central
absorbent article
Prior art date
Application number
PCT/JP2018/040997
Other languages
French (fr)
Japanese (ja)
Inventor
奥田 富美子
木村 真由美
西川 綾
Original Assignee
花王株式会社
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Filing date
Publication date
Application filed by 花王株式会社 filed Critical 花王株式会社
Publication of WO2019093267A1 publication Critical patent/WO2019093267A1/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • A61F13/535Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad inhomogeneous in the plane of the pad, e.g. core absorbent layers being of different sizes

Definitions

  • the present invention relates to absorbent articles such as sanitary napkins, incontinence pads, diapers and the like.
  • the present invention comprises a front surface layer, a back surface layer, and an absorbent layer disposed between the front surface layer and the back surface layer, and a longitudinal direction corresponding to a direction connecting the belly side, crotch and back side of the wearer.
  • An absorbent article having a middle part, wherein the absorbent layer is a central absorbent sheet containing a cooling agent, and an outer packet absorbent sheet disposed on the skin side and the non-skin side of the central absorbent sheet.
  • the absorbent layer provides an absorbent article having a communicating part at least on the skin surface side in a region where the central absorbent sheet and the outer wrapping absorbent sheet overlap in plan view.
  • the present invention further comprises the steps of applying a cooling agent to a central absorbent sheet, sandwiching the skin side and non-skin side of the central absorbent sheet with an outer cover absorbent sheet, the central absorbent sheet and the outer cover Forming a communicating portion at least on the skin surface side in a region overlapping in plan view with the absorbent sheet.
  • FIG. 2 is a cross-sectional view schematically showing a cross section taken along line II-II of the sanitary napkin shown in FIG. It is a top view of an absorption layer. It is sectional drawing which shows the polymer rich area
  • (A) to (D) are cross-sectional views showing other preferred examples of the folded structure of the central absorbent sheet.
  • (A) to (D) are schematic views showing a specific example of the arrangement of the anti-slip portion with respect to the central absorbent sheet from the non-skin surface side.
  • the present invention relates to an absorbent article which effectively maintains a moderate cooling sensation effect on the skin of a wearer for a long time.
  • the content of the cooling agent in the absorbent article is generally reduced with time by volatilization, and the cooling effect is reduced. Therefore, conventionally, it has not been sufficient to maintain a proper cooling sensation effect. From the viewpoint of a moderate cooling effect, it is desirable that the effect be maintained for a long time without excessively increasing the cooling agent.
  • the absorbent article of the present invention can effectively maintain a suitable cooling effect on the wearer's skin for a long time.
  • a sanitary napkin (hereinafter also referred to as a napkin) 10 as a preferred embodiment of the absorbent article according to the present invention will be described with reference to the drawings.
  • the side in contact with the human body is referred to as the skin surface side or the skin contact surface side or the surface side, and the opposite side is the non-skin surface side or the non-skin contact surface side or the back surface side It is said.
  • These are used also as a term which shows relative physical relationship in member composition of an absorptive article also about a member which does not have a field which contacts a human body.
  • the direction which is located in the front side of a human body at the time of wear is called front, and the direction which is located in the rear side is called back.
  • the normal direction of the front surface or the back surface of the absorbent article is referred to as the thickness direction.
  • the napkin 10 is disposed between the surface layer 1 on the skin contact surface side, the back surface layer 2 on the non-skin contact surface side, and the surface layer 1 and the back surface layer 2.
  • the surface layer 1 has liquid permeability that can send the liquid to the absorbent layer 3, and the back surface layer 2 has leak resistance to the liquid.
  • the surface layer 1 and the back surface layer 2 have a size that extends outward of the outer edge of the absorption layer 3 while covering both surfaces of the absorption layer 3.
  • a liquid-permeable liquid diffusion layer 4 narrower than the absorption layer 3 is provided between the surface layer 1 and the absorption layer 3.
  • the liquid diffusion layer 4 has an effect of spreading the waste fluid transmitted from the surface layer 1 in the planar direction to widen the absorption area on the skin surface side of the absorbing layer 3.
  • the side sheets 5 are laminated on both sides of the skin contact surface side of the surface layer 1.
  • the side sheet 5 and the back surface layer 2 extend outward in the width direction of the absorbent layer 3 to form a wing portion 6 which is a fixing means to clothes and the like.
  • a displacement preventing adhesive portion 7 for fixing the napkin 10 to clothes is disposed on the non-skin-contacting surface side of the wing portion 6 and the back surface layer 2, a displacement preventing adhesive portion 7 for fixing the napkin 10 to clothes is disposed.
  • the outer peripheral edge of the napkin 10 is an outer peripheral seal portion 9 joined without the absorption layer 3 interposed.
  • the napkin 10 may include other components, and may have a form without the liquid diffusion layer 4 and the side sheet 5. Furthermore, it may have a leak-proof groove squeezed from the surface layer 1 to the absorbent layer 3, a plurality of embossments on the surface layer 1, and the like.
  • the side sheet 5 may be left at the free end inward of both sides of the surface layer 1 while being bonded to the surface layer 1, and an elastic member or the like may be provided at the free end to prevent A leak cuff may be configured.
  • the napkin 10 has a longitudinally long shape having a longitudinal direction (Y direction) and a width direction (X direction) orthogonal to the longitudinal direction in a plan view.
  • the surface layer 1, the back surface layer 2, and the absorption layer 3 are longitudinally long shapes like the napkin 10.
  • the longitudinal direction corresponds to the direction connecting the wearer's ventral side, crotch and dorsal side when the napkin 10 is worn.
  • the width direction corresponds to the direction in which the left and right feet in the crotch of the wearer are connected.
  • the longitudinal direction (Y direction) and the width direction (X direction) indicate the direction in plan view of the napkin 10 and at the same time indicate the direction in plan view of the surface layer 1, the back layer 2 and the absorbent layer 3 .
  • the napkin 10 has an intermediate portion C including an area corresponding to the wearer's excretion point in the longitudinal direction. Furthermore, it has a front portion F disposed on the abdomen side forward of the middle portion C and a rear portion R disposed on the rear buttock side. Further, in the middle part C, there is a liquid receiving area C1 which faces the excrement point and directly receives the excrement fluid at the central part in the width direction.
  • the "width direction central portion" where the liquid receiving area C1 is, as shown in FIG. 1, means a range of a predetermined width extending laterally from the center line L in the width direction, and is wider than the width direction both end edges 39 of the absorbing layer 3 Say the part of the inner range.
  • the middle part C, the liquid receiving area C1, the front part F and the rear part R indicate the divisions in the napkin 10 and also indicate the divisions in the surface layer 1, the absorption layer 3 and the back layer 2 corresponding thereto.
  • the division positions of the middle portion C, the front portion F and the rear portion R may be appropriately set according to the length of the absorbent article set according to the purpose of use and the like.
  • a region along the longitudinal direction in which the wing portion is present is the middle portion C.
  • the napkin 10 of the present embodiment shows an example of a shape set for daytime use, etc., and the length in the longitudinal direction is equally divided into three to set the front part F, middle part C and rear part R The midsection follows this setting, even in the case of a day napkin without the wings and wings.
  • the middle portion C can be set as a portion located at a certain distance from the front portion F. Furthermore, for adult or infant diapers and the like, and for urine collection pads and the like, the length in the longitudinal direction is equally divided into three, and the front part F, middle part C and rear part R are set.
  • the absorbent layer 3 has a laminated structure in which a central absorbent sheet 32 containing a cooling agent and an outer shell absorbent sheet 31 disposed on the skin side and the non-skin side of the central absorbent sheet 32 are layered. Have. In a region where the central absorbent sheet 32 and the outer shell absorbent sheet 31 overlap in plan view, at least the skin surface side is provided with a communicating portion 8 which is a ventilating means communicating the central absorbent sheet 32 and the outer shell absorbent sheet 31. . Due to the structure in which the envelope absorbent sheet 31 is disposed on the upper and lower sides (skin side and non-skin side) of the central absorbent sheet 32 containing a cooling agent, excessive volatilization of the cooling agent during use is suppressed, The sense of sustainability increases.
  • the volatilization of the cooling agent is not completely suppressed by the structure in which the communicating portion 8 of the central absorbent sheet 32 and the outer packaging absorbent sheet 31 is provided at least on the skin surface side, and the cooling agent An appropriate cooling sensation can be imparted via That is, when the napkin 10 is worn, the volatile component of the cooling agent accumulated between the layered sheets in the absorbent layer 3 can be positively moved to the skin surface side by the communication part 8.
  • the central absorbent sheet 32 has a folded structure in which both ends in the width direction are overlapped on the surface layer 1 side.
  • the central absorbent sheet 32 is disposed in the middle portion C.
  • the central absorbent sheet 32 is located at a middle portion C located between the front portion F and the rear portion R, including the liquid receiving area C1.
  • the arrangement of the central absorbent sheet 32 may have the same length as the middle portion C if it is arranged in the middle portion C, and the length from the middle portion C to the front portion F and the rear portion R May be included.
  • the outer packaging absorbent sheet 31 has a folded structure in which both ends in the width direction are overlapped on the back layer 2 side and folded in three.
  • the outer packaging absorbent sheet 31 has a length ranging from the middle part C to the front part F and the rear part R, and has an outer shape of the absorbent layer 3.
  • the outer packaging absorbent sheet 31 is wider in the folded state than the central absorbent sheet 32 in the folded state, and has a longer length in the longitudinal direction than the central absorbent sheet 32.
  • the central absorbent sheet 32 containing a cooling agent is housed inside the folded structure of the outer shell absorbent sheet 31.
  • the skin surface side portion 31A and the non-skin surface side portion 31B of the outer packaging absorbent sheet 31 are arranged so as to cover the skin surface side and the non-skin surface side of the central absorbent sheet 32.
  • the absorbent layer 3 has the central absorbent sheet 32 in the above-described laminated structure, and is provided with a high basis weight portion 33 thicker than the periphery at the center in the width direction of the middle portion C.
  • the ratio (H2 / H1) of the thickness (H1) of the high basis weight portion 33 to the thickness (H2) of the portion other than the high basis weight portion 33 in the absorbent layer 3 can be used without discomfort to the skin surface From the viewpoint, 1 ⁇ 5 or more is preferable, and 1 ⁇ 3 or more is preferable.
  • the ratio (H2 / H1) is preferably 4/5 or less, more preferably 2/3 or less, from the viewpoint of fit.
  • the central absorbent sheet 32 contains a cooling agent as described above.
  • the central absorbent sheet 32 may contain a cooling agent in the entire area of the central absorbent sheet 32 or may be contained in a partial area of the central absorbent sheet 32.
  • the central absorbent sheet 32 has a folded structure, it is preferable to contain a cooling agent in the region inside the folded structure. Further, when the central absorbent sheet 32 has a polymer rich region 35 and a fiber rich region 36 described later, it is more preferable to contain a cooling agent in the polymer rich region 35.
  • the cooling agent may be contained in other regions of the absorbent layer 3 as long as it is contained in the central absorbent sheet 32, and members other than the central absorbent sheet 32 (for example, the outer packaging absorbent sheet 31 or the liquid diffusion layer 4 and the surface layer 1).
  • the central absorbent sheet 32 has a region having the largest content of the cooling agent, from the viewpoint of effectively maintaining the appropriate cooling sensation effect on the wearer's skin for a long time.
  • region containing a cooling agent exists in the intermediate part C in planar view of the napkin 10.
  • the central absorbent sheet 32 contains a cooling agent, it is preferable to include an application part of the cooling agent, that is, an application part of the cooling agent-containing liquid.
  • a cooling agent containing liquid is a coating liquid which mixed the cooling agent and the solvent, and is a liquid used when making the napkin 10 contain a cooling agent.
  • the application part of the cooling agent containing liquid is a part to be initially contained in the manufacturing process, and in the napkin 10 as a product, it is a part having a large amount of cooling agent component (a part having a large content). This content can be measured by a method which is divided into the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 of the absorbent layer 3 and described later.
  • the central absorbent sheet 32 may further contain an antibacterial agent.
  • an antibacterial agent By containing the antibacterial agent, in addition to the suppression of mure and stickiness as a sensation due to a cooling agent, it is possible to suppress the proliferation of bacteria easily caused due to mure and stickiness, and can be used comfortably.
  • the communicating portion 8 is a ventilation means communicating at an overlapping portion of the central absorbent sheet 32 and the outer wrapping absorbent sheet 31.
  • the communicating portion 8 is disposed at least on the skin surface side of the absorbent layer 3 as a ventilation means for guiding the volatile component of the cooling agent to the skin surface.
  • the skin surface side portion 31A of the outer packaging absorbent sheet 31 and the central absorbent sheet 32 are arranged.
  • the depth of the communication part 8 is not limited to this. Preferred embodiments will be described later.
  • the communicating portion 8 functions as a moving path of the volatile component of the cooling agent, and a moving path of air due to the deformation of the absorbing layer 3 and the like.
  • the volatile component of the cooling agent accumulated between the sheets of the absorption layer which is a layered structure, is transferred to the skin surface even when the residual amount of the cooling agent decreases, particularly with time. It can be delivered enough.
  • the volatile component of the cooling agent can be positively fed from the inside of the absorption layer 3 to the skin surface by the presence of the communication portion 8.
  • the delivery of the cooling agent is more effective, for example, due to the deformation of the absorbent layer accompanying the movement of the wearer's body when wearing a napkin.
  • the communicating portion 8 may be a gap portion such as a slit portion cut into an elongated shape or a recessed portion space where a portion of the member is cut away, or a recessed portion space (squeezed portion) in which a portion of the member is pressed and depressed It may be a recess space in which the basis weight of the member is partially reduced.
  • the communication part 8 is a concave part space where a slit part or a part of a member is cut away, in the communication part 8, the central absorbent sheet 32 and the outer packaging absorbent sheet 31 are continuously cut at the same position.
  • the cutting end forms the wall of the communicating portion 8.
  • the communication portion 8 is preferably a communication hole.
  • a communicating hole is a hole which penetrates predetermined thickness from the skin surface side of absorption layer 3, and is the concept containing the slit part and crevice space which were mentioned above.
  • the communication hole portion can be opened and closed, and the volatile component of the cooling agent can be more effectively fed to the skin surface side while being accumulated in a fixed amount.
  • the communication portion 8 is disposed as a slit portion 81 obtained by cutting a part of the absorbent layer 3 (see FIGS. 1 to 3).
  • a plurality of slit parts 81 are dispersed and arranged in the plane region of the absorption layer 3.
  • the “slit portion” referred to here can be defined as a cut portion having a member cutting width of 0.5 mm or less, preferably 0.3 mm or less, more preferably 0.2 mm or less.
  • the “width” of the slit portion 81 refers to the distance (opening width) between the disconnected members in the direction orthogonal to the length direction in which the slit portion 81 extends in a plan view of the napkin 10.
  • the width of the slit portion 81 can be measured with a digital microscope VHX-1000 manufactured by Keyence Corporation in a natural state where the absorbent layer 3 is taken out of the napkin 10 and placed on a horizontal table and tension is not applied. At the time of measurement, measurement magnification is appropriately adjusted and measured.
  • the communication portion 8 is at least disposed in a region where the central absorbent sheet 32 and the skin surface side portion 31A of the outer packaging absorbent sheet 31 overlap in plan view on the skin surface side of the absorbent layer 3 (FIG. 1 and FIG. 3). reference).
  • the communicating portion 8 is preferably disposed in a region including at least the middle portion C in the longitudinal direction of the absorption layer 3 in plan view. Further, among the communicating portions 8, those located on the outermost side in the width direction are on the inner side than both end edges 39 in the width direction of the absorbing layer 3 and are arranged on the outer side in the width direction than the region containing the cooling agent. preferable. It is preferable that a plurality of communication portions 8 be dispersedly arranged in the above-described region in order to effectively exhibit the function as the air passage.
  • the communicating portion 8 may be formed at least on the surface layer 1 side (skin surface side) of the absorbing layer 3 in the thickness direction of the absorbing layer 3, and may extend to a predetermined depth from the surface layer 1 side. It may extend over the entire thickness direction of the layer 3. In consideration of the action of the communication part 8 on the cooling agent, it is preferable that the communication part 8 be as far as the predetermined depth from the surface layer 1 side. The depth is preferably about 50% to 70% of the thickness of the absorbing layer 3.
  • the communication portion 8 be disposed across the plurality of sheet layers in the thickness direction from the skin surface side of the absorbent layer 3, and the center from the skin surface side portion 31 A of the outer packaging absorbent sheet 31 It is more preferable to reach the portion of the absorbent sheet 32 where the cooling agent is disposed.
  • the outer wrapping absorbent sheet 31 (the non-skin surface side portion 31B) of the portion closest to the anti-displacement portion 7 does not exist.
  • the communicating portion 8 extends from the surface to the back surface of the absorbing layer 3 from the viewpoint of the cooling effect due to the movement of the air to the communicating portion 8 due to the deformation of the absorbing layer 3.
  • the plan view shape of the communication portion 8 is not particularly limited, and may be rectangular or circular. It is preferable that the length in one direction of the communicating portion 8 be wider on the skin surface side than the non-skin surface, considering the action on the cooling agent. With such a configuration, the diffusion of the cooling agent to the skin side can be further promoted, and the diffusion of the cooling agent to the non-skin side can be further suppressed.
  • the absorbent sheet which comprises the center absorbent sheet 32 and the outer shell absorbent sheet 31 contains a highly absorbent polymer material and hydrophilic fibers.
  • the water absorbing sheet is a thin sheet having a thickness in which a superabsorbent polymer material is sandwiched and fixed between two sheet-like fiber layers made of hydrophilic fibers.
  • the superabsorbent polymer material mentioned here is a surface-crosslinked polymer material called a so-called SAP (Superabsorbent polymer) (the same applies hereinafter).
  • SAP Superabsorbent polymer
  • the preparation can be performed by various methods commonly used, and may be either wet or dry. Since the absorbent sheet has a highly absorbent polymer material dispersed and arranged in the plane direction of the sheet, gel blocking (the absorption inhibition phenomenon of the liquid caused by the interaction between the absorbent polymers which are absorbed by swelling the aqueous liquid such as body fluid) Are difficult to cause, and have high absorbency. For this reason, the thickness of one water absorbing sheet layer can be suppressed to 1.0 mm or less. For example, those described in paragraphs [0019] to [0131] of JP-A-8-246395 can be mentioned.
  • the absorbent sheet preferably has a polymer rich region 35 and a fiber rich region 36 as shown in FIG. 4 in a cross sectional view.
  • FIG. 4 shows an embodiment in which the polymer rich area 35 and the fiber rich area 36 are laminated on the thickness cross section of a part of the absorbent sheet constituting the central absorbent sheet 32 to form an integral structure.
  • the polymer rich area 35 and the fiber rich area 36 are the mass ratio of the superabsorbent polymer material 37 to the total mass of the mass of the superabsorbent polymer material 37 and the mass of the hydrophilic fiber (hereinafter referred to simply as “superabsorbent polymer material It is defined by "the mass ratio of 37".
  • the mass ratio of the superabsorbent polymer material 37 is relatively higher than that of the fiber rich region 36.
  • the mass ratio of the superabsorbent polymer material 37 to the polymer-rich region 35 is relatively low.
  • the absorbent sheet has a polymer-rich region 35 in which free water becomes relatively small after absorption of menstrual blood in the thickness direction of the absorbent layer 3 and a fiber-rich region 36 in which free water remains relatively between fibers.
  • the cooling agent is preferably contained in the polymer rich region 35 of the central absorbent sheet 32.
  • the cooling agent application part mentioned above is distribute
  • the superabsorbent polymer material 37 relatively reduces the free water in the periphery, so the cooling agent tends to evaporate.
  • the fiber-rich region 36 excessive diffusion of the volatile component of the cooling agent can be suppressed by the free water (body fluid) remaining relatively in a relatively large amount.
  • the central absorbent sheet 32 preferably has a cooling agent in the polymer rich area 35 and is folded with the fiber rich area 36 on the outer surface side.
  • the cooling agent is easily volatilized inside the laminated structure of the central absorbent sheet 32.
  • it has a structure which suppresses that the volatile component of a cooling agent spreads outside to the outer side of the central absorbent sheet 32 too much.
  • the central absorbent sheet 32 can effectively impart an appropriate cooling sensation effect longer in combination with the outer wrapping absorbent sheet 31.
  • diffusion of the cooling agent to the slippage prevention adhesion part 7 can be suppressed moderately, and degradation of the slippage prevention performance can be suppressed.
  • the formation of the polymer rich area 35 and the fiber rich area 36 in the absorbent sheet can be performed, for example, as follows. First, a wet fiber web made by wet papermaking of a water slurry containing hydrophilic fibers is produced.
  • the water slurry may contain a heat melting adhesive fiber, a paper reinforcing agent, and the like.
  • the superabsorbent polymer material is sprayed onto the fiber web in the wet state to create a state in which the superabsorbent polymer intercalates between the fibers. This portion becomes the polymer rich region 35 in the absorbent sheet.
  • the layer to which the high absorbent polymer material is dispersed may be paper making, dried paper, or non-woven fabric produced by various methods. From the viewpoint of facilitating penetration of the superabsorbent polymer material into fibers, bulky paper such as creped paper, air through non-woven fabric and the like are preferable.
  • a hot melt adhesive or the like is used for bonding the high-absorbent polymer material to the component fibers of the layer to be the polymer-rich region 35, and bonding to the layer to be the polymer-rich region 35 and the layer to be the fiber-rich region 36.
  • a water soluble adhesive or the like may be used.
  • the fiber rich area 36 may be formed by laminating or spraying hydrophilic fibers on the layer to be the polymer rich area 35.
  • the content of the cooling agent in the entire napkin 10 can be determined depending on the type of the cooling agent from the viewpoint of the appropriateness of the cooling feeling, the mure feeling and the sticky feeling.
  • the content is preferably 13.5 mg / 100 mm or less, more preferably 12.5 mg / 100 mm or less, and still more preferably 11.5 mg / 100 mm or less.
  • the cooling agent can be extracted with a solvent from the target member or target site of the absorbent article, and the extraction solution can be analyzed by gas chromatography (GC).
  • GC gas chromatography
  • the measurement is performed with a flame ionization detector (FID) attached to a gas chromatograph, and can be measured, for example, by 7890A manufactured by Agilent technologies.
  • FID flame ionization detector
  • the relationship between the concentration of the compound constituting the cooling agent and the peak area is previously converted to a calibration curve, and quantitative work is performed based on the calibration curve.
  • the case where the cooling agent contains menthyl lactate and / or menthol is described as an example.
  • Menthyl lactate and / or menthol is extracted from the target member or target site using methanol as a solvent.
  • methanol as a solvent
  • a standard curve is plotted where the peak area is plotted against the concentration of the standard sample.
  • the peak area obtained is applied to the calibration curve to calculate the amount of menthyl lactate and / or the amount of menthol.
  • the amount of cooling agent per unit area can be determined by dividing the amount of menthyl lactate and / or menthol obtained by the area of the target member or the target site.
  • the obtained menthyl lactate content and / or menthol content is divided by the length (mm) of the absorbent article in the length direction of the target member or target portion of the absorbent article, and multiplied by 100 to obtain the product length ( Absorbent layer length)
  • the amount of cooling agent per 100 m can be determined.
  • the central absorbent sheet 32 is not limited to the one having a folded structure as shown in FIG. 2 as long as it has a laminated structure with the outer wrapping absorbent sheet 31.
  • an unfolded embodiment is also possible.
  • the central absorbent sheet 32 preferably has a folding structure.
  • the folded structure of the central absorbent sheet 32 is not limited to the embodiment shown in FIG.
  • it may be folded as shown in FIGS. 5 (A) to 5 (D).
  • FIG. 5 (A) shows a mode in which both ends in the width direction of the central absorbent sheet 32 are folded back in the S-shape on the skin side and the non-skin side, respectively.
  • FIG. 5B shows an aspect in which the sheet is folded in half in the width direction.
  • FIGS. 5C and 5D show a mode in which the portions folded in three in the width direction are equal in length.
  • the outer packaging absorbent sheet 31 is not limited to one having a folded structure as shown in FIG.
  • the outer wrapping absorbent sheet 31 may be formed as a plurality of separate sheet parts, and these sheet parts may be arranged on the skin surface side and the non-skin surface side of the central absorbent sheet 32 to form a laminated structure.
  • the envelope absorbent sheet 31 is preferably folded.
  • the folded structure of the outer wrapping absorbent sheet 31 is not limited to the aspect shown in FIG. 2 and can be various. For example, it may be similar to those shown in FIGS. 5 (A) to 5 (D) shown as the folded structure of the central absorbent sheet 32.
  • seat of 2 sheets divided into the skin surface side and the non-skin surface side may be sufficient. Furthermore, it is not limited to the aspect which includes the central absorbent sheet 32 inside the folding structure of the outer packaging absorbent sheet 31, and the central absorbent sheet on the non-skin side of the folding structure of the outer packaging absorbent sheet 31 without including it. 32 may be laminated. However, if the central absorbent sheet 32 is contained in the inside of the folded structure of the outer packaging absorbent sheet 31, the volatile component of the cooling agent is more easily retained, which is preferable from the viewpoint of the action of the communication portion 8 described above.
  • the overlapping portions of the absorbent sheets are not joined except for the portion where the communication portion 8 is disposed.
  • the space between the layers of the absorption layer 3 is easily formed, and the opening and closing property between the above layers is enhanced.
  • the movement of the volatile component of the cooling agent to the skin can be more easily expressed.
  • the slip prevention adhesion part 7 is arrange
  • the anti-displacement portion 7 adheres to the clothes and has a function of reducing the displacement between the clothes and the napkin.
  • a cooling agent has been one of the factors that lower the anti-displacement performance, such as the decrease in the adhesive strength of the anti-displacement portion and the adhesive residue on the clothes.
  • the overlapping portion is an arrangement area of the central absorbent sheet 32 (an area occupied by the central absorbent sheet 32 in a plan view of the napkin 10 and when the central absorbent sheet 32 is in a folded state, It is preferable that it is 35% or less of arrangement
  • the overlapping portion is preferably 10% or more, more preferably 15% or more, and still more preferably 18% or more, from the viewpoint of effectively suppressing the difference from the clothes. Further, from the viewpoint of effectively suppressing the displacement with the clothes, it is preferable that a plurality of the displacement prevention adhesive portions 7 be dispersedly disposed.
  • the central area in the width direction of the middle portion C of the central absorbent sheet 32 has a small overlap with the anti-slip portion 7, and more preferably not.
  • the width direction central region of the middle portion C of the central absorbent sheet 32 means the central region of the central absorbent sheet 32 when the entire length in the width direction is divided into three.
  • FIGS. 6A to 6 (D) are schematic views showing a specific example of the arrangement of the anti-slip portion 7.
  • FIGS. 6A to 6D in order to show the positional relationship between the anti-slip portion 7 and the central absorbent sheet 32, the disposition of the anti-slip portion 7 on the central absorbent sheet 32 except for the other members. Is shown schematically.
  • FIG. 6A shows a mode in which a plurality of anti-slip adhesion portions 7 are arranged at positions on both sides of the central absorbent sheet 32 in the longitudinal direction.
  • FIG. 6 (B) shows a mode in which a pair of the shift preventing adhesive portions 7 continuous in the longitudinal direction are arranged along both sides in the longitudinal direction of the central absorbent sheet 32. In both FIGS.
  • the anti-slip adhesion portion 7 is disposed so as not to overlap the central region in the width direction of the central absorbent sheet 32.
  • FIG. 6C shows a mode in which a plurality of anti-slip adhesion portions 7 are arranged in parallel in the width direction of the central absorbent sheet 32.
  • FIG. 6D shows a mode in which a plurality of anti-slip adhesion portions 7 are arranged in parallel in the longitudinal direction of the central absorbent sheet 32.
  • the overlap between the anti-slip adhesive portion 7 and the central absorbent sheet 32 is 35% or less of the above-mentioned arrangement area so that the anti-slip adhesive portion 7 does not overlap with the central region in the width direction of the middle portion C of the central absorbent sheet 32
  • the overlapping portion of the central absorbent sheet 32 and the anti-slip portion 7 in plan view is sufficiently reduced, and the anti-slip portion 7 is present in the region of the central region in the width direction where body pressure is most applied.
  • the influence which a cooling agent has on a gap stop adhesion part can be reduced more effectively.
  • the side sheet 5 is preferably laminated on both sides of the skin contact surface side of the surface layer 1. It is more preferable that the side sheet 5 has lower air permeability than the surface layer 1.
  • thermoreceptor As a cooling agent, it can stimulate the wearer's skin and / or mucous membrane surface thermoreceptor to convey a feeling of exhilaration to the wearer without changing the temperature on the skin and / or mucous membrane surface
  • agents can be used. Examples thereof include cyclohexyl derivatives, cyclohexanol derivatives, carboxamides and the like, as described in paragraphs [0006] to [0086] of JP-A-2015-12918.
  • cyclohexyl derivatives include menthyl lactate, menthylethylaminooxalic acid, 3- (l-menthoxy) propane-1,2-diol, 3- (l-menthoxy) -2-methylpropane-1,2-diol, and succinic acid. Menthyl, 3- (l-menthoxy) ethan-1-ol, 3- (l-menthoxy) propan-1-ol, 3- (l-menthoxy) butan-1-ol, 1-menthyl-4-hydroxypentano And alt, l-menthyl 3-hydroxybutyrate and the like.
  • cyclohexanol derivatives examples include menthol, p-menthan-3,8-diol, isopulegol and the like.
  • carboxamides N-ethyl-p-menthane-3-carboxamide (N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide), N, 2,3-trimethyl-2- (l-methylethyl) And L) -butanamide, 1-menthylacetic acid N-ethylamide and the like.
  • One of these may be used, or two or more of them may be used in combination.
  • a water-insoluble or poorly water-soluble cooling agent is preferable from the viewpoint of refreshing feeling due to odor, quick action, and sustainability. Since the water-insoluble or poorly water-soluble cooling agent hardly migrates to the non-skin side with the body fluid, the cold feeling tends to be sustained. As water-insoluble substances, menthyl lactate and menthol are preferable.
  • the term "water-insoluble or poorly water-soluble” as used herein means that the solubility is 1 g or less in 1 L of water at 25 ° C, and particularly "water-insoluble” is 0.1 g or less in 1 L of water at 25 ° C Say that it is soluble in water.
  • a cooling agent can be contained in the napkin 10 by various methods.
  • the napkin 10 may be contained in the napkin 10 in a state of being dissolved in a solvent, or may be contained without using a solvent.
  • the cooling agent may be contained in the napkin 10 together with a delivery means such as encapsulation in microcapsules.
  • the cooling agent in particular, it is preferable to include menthol and menthyl lactate because the cooling effect can be felt quickly and gently after wearing, and the durability can be enhanced.
  • the content ratio of menthol and menthyl lactate is preferably 0.01 or more, more preferably 0.02 or more, and further preferably 0.2 or less, in the mass ratio of the former / the latter. The following are preferred.
  • antibacterial agent those usually used in the field of absorbent articles can be used.
  • hydrophilic fiber which comprises an absorptive sheet
  • hydrophilic fibers which carried out the hydrophilization treatment of the hydrophobic fiber, and the thing which itself is hydrophilic are mentioned.
  • those which themselves are hydrophilic and have water retention are preferred.
  • hydrophilic fibers natural fibers, regenerated cellulose fibers or semi-synthetic fibers are mentioned as preferable examples.
  • pulp and rayon are preferable, and pulp is more preferable.
  • crosslinked cellulose fibers obtained by crosslinking the intramolecular and / or intermolecular of cellulose fibers or bulky cellulose fibers obtained by mercerizing wood pulp may be used.
  • the pulp include wood pulp such as softwood kraft pulp and hardwood kraft pulp, and natural cellulose fibers such as cotton pulp and straw pulp, but not limited thereto. These pulps can be used alone or in combination of two or more.
  • the superabsorbent polymer material constituting the absorbent sheet can be obtained, for example, by polymerizing a water-soluble ethylenically unsaturated monomer which is mainly composed of acrylic acid or acrylate and optionally added with a crosslinking agent.
  • Hydrogel materials are included.
  • polyethylene oxide, polyvinyl pyrrolidone, crosslinked products of sulfonated polystyrene and polyvinyl pyridine, saponified starch-poly (meth) acrylonitrile graft copolymer, starch-poly (meth) acrylic acid graft copolymer, starch-poly ( The hydrolyzate of a (meth) acrylic ester graft copolymer etc. are mentioned.
  • These water-absorbing polymer materials can be used alone or in combination of two or more.
  • the superabsorbent polymer material a material capable of absorbing and retaining 20 times or more of its own weight and capable of gelation is preferable.
  • the shape of the superabsorbent polymer material various materials used for the absorbent layer can be used without particular limitation. For example, spherical shape, granular shape, fibrous shape, bowl shape, lump shape etc. are mentioned.
  • the surface layer 1 can use various materials having liquid permeability.
  • a hydrophilic non-woven fabric is preferable, a thermal bond non-woven fabric is more preferable, and an air-through non-woven fabric is particularly preferable.
  • it is a thermoplastic resin fiber subjected to hydrophilization treatment, and the fiber is a fiber subjected to a three-dimensional crimp such as a secondary crimp or a tertiary crimp.
  • polyethylene, polypropylene, polyester, nylon, and composite fibers thereof are prepared, and various hydrophilicizing agents are applied before cutting into a predetermined length to form staples.
  • hydrophilizing agent various alkyl sulfonates represented by ⁇ -olefin sulfonate, acrylate, acrylate / acrylamide copolymer, ester amide, ester amide salt, polyethylene glycol and derivatives thereof, water-soluble Hydrophilization treatment with a commonly used hydrophilizing agent can be used, such as polyester resin, various silicone derivatives, various saccharide derivatives, and mixtures thereof.
  • various materials having leak resistance can be used.
  • a non-moisture permeable or moisture-permeable film alone, or a combination of a film and a non-woven fabric, or a water-repellent non-woven fabric (SMS, SMMS, etc.) can be used. It is most preferable to use a non-moisture-permeable film alone as the leak-proof material from the viewpoint of cost and matching with the anti-slip adhesive.
  • the liquid diffusion layer 4 is preferably one having hydrophilicity and excellent in liquid diffusibility.
  • Non-woven fabrics containing thermoplastic fibers can be mentioned.
  • the non-woven fabric non-woven fabrics obtained by various manufacturing methods can be used. For example, an air through non-woven fabric in which heat fusion points of fibers are formed by air through method on fiber web obtained by card method or air laid method, heat fusion point of fibers is formed by heat roll method on fiber web obtained by card method
  • Various non-woven fabrics such as heat-roll non-woven fabric, heat-embossed non-woven fabric, spunlace non-woven fabric, needle punched non-woven fabric, resin-bonded non-woven fabric, etc. can be used.
  • the side sheet 5 is preferably a water repellent non-woven fabric, and non-woven fabric manufactured by the card method, spun bonded non-woven fabric, meltblown non-woven fabric, spun lace non-woven fabric, heat roll non-woven fabric, needle punched non-woven fabric etc.
  • Various non-woven fabrics treated with water can be used.
  • a spunbond nonwoven fabric, a spunbond-meltblown (SM) nonwoven fabric, a spunbond-meltblown-spunbond (SMS) nonwoven fabric and the like are used.
  • the absorbent article of the present invention is not limited to the sanitary napkin of the above embodiment, and can be applied to, for example, panty liners, incontinence pads, urine collecting pads, disposable diapers and the like. Moreover, it is effective not only to menstrual blood but also to other things such as urine, orimono, soft stools and the like. In addition to the components described above, members may be incorporated appropriately in accordance with the application and function.
  • the absorbent article of the present invention is a product such as a sanitary napkin or a panty liner which is carried in a bag for each product, it is preferable to be individually packaged. Specifically, it is preferable that the absorbent article packaging body is longitudinally folded so that the surface layer is inside, and is wrapped by the outer wrapping material for individual wrapping. By using the individual package, it is possible to make the article highly portable while protecting the hygiene of the surface layer (use side) that touches the skin, and it is possible to enhance the convenience of the user.
  • a preferred method for producing the absorbent layer 3 includes the following steps among commonly used methods for producing an absorbent article. That is, the step (S1) of applying a cooling agent to the central absorbent sheet 32, the step (S2) of sandwiching the skin side and the non-skin side of the central absorbent sheet 32 with the outer cover absorbent sheet 31, and central absorbent And a step (S3) of forming the communicating portion 8 at least on the skin surface side in a region where the sheet 32 and the outer wrapping absorbent sheet 31 overlap in plan view.
  • the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 may be laminated in the step (S2) without being folded, even if one or both of the both sheets are folded and laminated. Good.
  • the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 are folded, a sheet wider than the width of the absorbent layer is used on the assumption that the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 are folded.
  • the application of the cooling agent in the step (S1) is appropriately performed by assuming that the central absorbent sheet 32 is folded.
  • the width to which the cooling agent is applied is preferably a region which is inside the widthwise end edges 39 of the absorbent layer 3 (absorbent body) described above.
  • a region having a range of 75% or less with respect to the width of the absorbing layer 3 is more preferable, and a region having a range of 70% or less is further preferable.
  • the cooling agent is preferably prepared and applied as a cooling agent-containing coating solution in which a solvent is mixed.
  • the solvent those usually used can be used.
  • dipropylene glycol and the like can be mentioned.
  • the communicating portions 8 in the step (S3) are provided in a distributed manner in the surface direction. As shown in FIG. 3, it is preferable that a plurality of communicating portions 8 provided in the absorbent sheet have a length extending in the longitudinal direction of the absorbent layer, and a plurality of the communicating portions 8 be arranged in the longitudinal direction. It is more preferable to arrange multiple arrays in the width direction of the absorbing layer.
  • the formation of the communicating portion 8 can be performed by various methods used for this kind of article depending on the form of the communicating portion 8.
  • a cutting blade extending in the circumferential direction on the roll circumferential surface is provided with a cutter roll distributed and arranged in the roll circumferential direction and the roll axis direction, and an anvil roll correspondingly disposed.
  • the cutting device can be used to form cuts (not shown).
  • the cutting blade has a circumferential length corresponding to the longitudinal length of the cut (slit portion).
  • the cutting blades are distributed at the peripheral surface of the roll in correspondence with the desired arrangement of the notches (slits). Further, the depth of the cut can be set by the clearance between the cutter roll and the anvil roll, the size of the cutting blade, and the like.
  • the communication part 8 when the communication part 8 is the recessed space which a part of member cut away, it can change the setting of the cutting blade of said roll, etc., and can form. Moreover, when the communication part 8 is the recessed space (pressing part) which a part of member was pressed down and was dented, it can form by various embossing processes.
  • the width of the region forming the communication portion 8 is preferably a region which is wider than the cooling agent application width and which is inside the width direction both end edges 39 of the absorbent layer 3 described above. It is more preferable that the region be in a range of, for example, 85% or less with respect to the width of the absorption layer 3.
  • the manufacturing method of the absorbent article of this invention has the following processes performed using the absorption layer 3 obtained by said manufacturing method.
  • S4 Step of disposing the absorbing layer 3 between the surface layer 1 and the back layer 2
  • S5 step of disposing the anti-slip portion 7 on the non-skin side of the back layer 2
  • the front surface layer 1 and the back surface layer 2 which are cut into a predetermined size are laminated and bonded on both surfaces of the absorbent layer 3 obtained as described above.
  • the liquid diffusion layer 4 and the side sheet 5 may be formed into a predetermined size and shape and laminated.
  • various squeezing treatments such as leak prevention grooves may be performed.
  • step (S5) is performed as necessary.
  • the anti-displacement portion 7 is disposed.
  • the overlapping portion of the anti-slip portion 7 and the central absorbent sheet 32 in plan view is 35% or less of the arrangement area of the central absorbent sheet 32, and the widthwise center of the central portion C of the central absorbent sheet 32 It is preferable to arrange the area so as not to overlap with the anti-slip portion.
  • the present invention further discloses the following absorbent article and method of manufacturing the absorbent article.
  • a longitudinal direction corresponding to a direction connecting a belly side, a crotch and a dorsal side of a wearer comprising a front layer, a back layer, and an absorbent layer disposed between the front layer and the back layer; It has a width direction orthogonal to the longitudinal direction, and has a front portion, a rear portion, and an intermediate portion located between the front and rear portions and including a region corresponding to a discharge point along the longitudinal direction.
  • An absorbent article, wherein the absorbent layer includes a central absorbent sheet containing a cooling agent, and an envelope absorbent sheet disposed on the skin side and the non-skin side of the central absorbent sheet.
  • the central absorbent sheet includes a superabsorbent polymer material and a hydrophilic fiber, and in cross section, the superabsorbent polymer material in the total mass of the mass of the superabsorbent polymer material and the mass of the hydrophilic fiber
  • ⁇ 3> The absorbent article according to ⁇ 1> or ⁇ 2>, wherein the central absorbent sheet is disposed in the middle part of the absorbent article, and the communication part is a communication hole connected in a thickness direction.
  • ⁇ 4> The absorbent article according to ⁇ 3>, wherein a length in one direction of the communication hole is wider on the skin surface side than on a non-skin surface.
  • ⁇ 5> The absorbent article as described in said ⁇ 3> or ⁇ 4> whose said communicating hole is a slit part by a cut
  • the anti-slip adhesion portion is disposed on the non-skin surface side of the back surface layer, and the overlapping portion of the anti-slip adhesion portion and the central absorbent sheet in a plan view is 35% of the arrangement area of the central absorbent sheet.
  • the cooling agent is a water-insoluble or poorly water-soluble agent.
  • the absorbent article as described in said ⁇ 7> which contains a menthyl lactate as said cooling agent.
  • ⁇ 9> The absorbent article as described in said ⁇ 8> which contains menthol as said cooling agent.
  • ⁇ 10> The absorbent article as described in said ⁇ 9> whose mass ratio of the said menthol and menthyl lactate is 0.01 or more and 0.2 or less as the former / latter.
  • ⁇ 11> The absorbent article according to any one of ⁇ 1> to ⁇ 10>, wherein a side sheet having air permeability smaller than that of the surface layer is laminated on both sides of the skin contact surface side of the surface layer.
  • ⁇ 12> The absorbent article according to any one of ⁇ 1> to ⁇ 11>, including a wing portion extended outward in the width direction of the absorbent layer.
  • ⁇ 13> The absorbent article according to any one of the above ⁇ 1> to ⁇ 12>, which is a sanitary napkin.
  • S3 The manufacturing method of the absorption layer as described in said ⁇ 14> which performs said process (S3) after said process (S1) and (S2).
  • ⁇ 16> The manufacturing method of the absorbent article provided with the process of arranging the absorption layer obtained by the manufacturing method as described in said ⁇ 15> between a surface layer and a back surface layer. ⁇ 17> And a step of arranging the anti-slip portion on the non-skin side of the back layer, wherein the overlapping portion of the anti-slip portion and the central absorbent sheet in plan view corresponds to the arrangement area of the central absorbent sheet.
  • the absorbent article according to ⁇ 16> wherein the width is not more than 35%, and the width direction central region perpendicular to the longitudinal direction in the middle portion of the central absorbent sheet does not overlap with the anti-slip portion. Production method.

Abstract

An absorbent article is provided with an obverse surface layer 1, a reverse surface layer 2, and an absorbent layer 3, has a longitudinal direction corresponding to a direction connecting a wearer's ventral part, groin part, and dorsal part and a width direction intersecting the longitudinal direction, and has, along the longitudinal direction, a front part F, a rear part R, and a central part C that is between the front part and the rear part and includes a region corresponding to an elimination orifice. The absorbent layer 3 comprises a layered stack of a central absorbent sheet 32 that contains a cooling sensation agent and encapsulating absorbent sheets 31 disposed on the skin side and the non-skin side of the central absorbent sheet 32. The absorbent layer 3 has, in an overlap region (as seen in plan view) between the central absorbent sheet 32 and the encapsulating absorbent sheets 31, a communicating part 8 on at least the skin side.

Description

吸収性物品Absorbent articles
 本発明は、生理用ナプキンや失禁パッド、おむつなどの吸収性物品に関する。 The present invention relates to absorbent articles such as sanitary napkins, incontinence pads, diapers and the like.
 生理用ナプキン等の吸収性物品において、排泄液が多いときや長時間使用するときなどにべたつきが生じて着用者が不快に感じることがある。これに対し、従来、清涼剤等の冷感材料を吸収性物品に含有させることによって、着用感の向上をはかろうとする技術があった(例えば特許文献1及び2)。冷感材料は揮発して、着用者の肌の感覚神経細胞のTRPM8やTRPA1などを刺激して受容器のしきい値を変化させることで清涼感が感じられる。 In an absorbent article such as a sanitary napkin, the wearer may feel uncomfortable due to stickiness when there is a large amount of excrement fluid or when used for a long time. On the other hand, conventionally, there has been a technique for improving the feeling of wearing by incorporating a cooling sensation material such as a refreshing agent into the absorbent article (for example, Patent Documents 1 and 2). The cold sensation material is volatilized and stimulates TRPM8 or TRPA1 of the sensory nerve cells of the wearer's skin to change the receptor threshold, thereby giving a refreshing sensation.
特表2004-528090号公報Japanese Patent Publication No. 2004-528090 特開2010-234028号公報JP, 2010-234028, A
 本発明は、表面層、裏面層、及び前記表面層と前記裏面層との間に配された吸収層を備え、着用者の腹側部、股下部及び背側部を繋ぐ方向に対応する縦方向と、該縦方向と直交する幅方向とを有し、該縦方向に沿って、前方部、後方部、及び該前方部と後方部の間に位置し、排泄ポイントに対応する領域を含む中間部を有する吸収性物品であって、前記吸収層は、冷感剤を含有する中央吸収性シートと、該中央吸収性シートの肌面側及び非肌面側に配された外包吸収性シートとを、層状に重ねてなり、前記吸収層は、前記中央吸収性シートと前記外包吸収性シートとの平面視重なる領域において、少なくとも肌面側に連通部を有する、吸収性物品を提供する。
 また、本発明は、中央吸収性シートに冷感剤を塗布する工程と、前記中央吸収性シートの肌側面及び非肌側面を外包吸収性シートで挟む工程と、前記中央吸収性シートと前記外包吸収性シートとの平面視重なる領域において、少なくとも肌面側に連通部を形成する工程と、を備える吸収層の製造方法を提供する。
The present invention comprises a front surface layer, a back surface layer, and an absorbent layer disposed between the front surface layer and the back surface layer, and a longitudinal direction corresponding to a direction connecting the belly side, crotch and back side of the wearer. Has a direction and a width direction orthogonal to the longitudinal direction, and includes a region corresponding to a discharge point, which is located along the longitudinal direction between the front portion, the rear portion, and the front portion and the rear portion An absorbent article having a middle part, wherein the absorbent layer is a central absorbent sheet containing a cooling agent, and an outer packet absorbent sheet disposed on the skin side and the non-skin side of the central absorbent sheet. In a layered manner, and the absorbent layer provides an absorbent article having a communicating part at least on the skin surface side in a region where the central absorbent sheet and the outer wrapping absorbent sheet overlap in plan view.
The present invention further comprises the steps of applying a cooling agent to a central absorbent sheet, sandwiching the skin side and non-skin side of the central absorbent sheet with an outer cover absorbent sheet, the central absorbent sheet and the outer cover Forming a communicating portion at least on the skin surface side in a region overlapping in plan view with the absorbent sheet.
 本発明の上記及び他の特徴及び利点は、適宜添付の図面を参照して、下記の記載からより明らかになるであろう。 The above and other features and advantages of the present invention will become more apparent from the following description with reference to the accompanying drawings as appropriate.
本発明における吸収性物品の好ましい一実施形態としての生理用ナプキンを伸長した状態で肌当接面側から模式的に示す一部切欠斜視図である。BRIEF DESCRIPTION OF THE DRAWINGS It is a partially notched perspective view shown typically from the skin contact surface side in the state which expand | extended the sanitary napkin as one preferable embodiment of the absorbent article in this invention. 図1に示す生理用ナプキンのII-II線断面を模式的に示す断面図である。FIG. 2 is a cross-sectional view schematically showing a cross section taken along line II-II of the sanitary napkin shown in FIG. 吸収層の平面図である。It is a top view of an absorption layer. 中央吸収性シートにおけるポリマーリッチ領域と繊維リッチ領域とを部分的に拡大して示す断面図である。It is sectional drawing which shows the polymer rich area | region and the fiber rich area | region in a center absorptive sheet in partial enlargement. (A)~(D)は、中央吸収性シートの折り畳み構造の他の好ましい例を示す断面図である。(A) to (D) are cross-sectional views showing other preferred examples of the folded structure of the central absorbent sheet. (A)~(D)は、ズレ止粘着部の中央吸収性シートに対する配置の具体例を非肌面側から示す模式図である。(A) to (D) are schematic views showing a specific example of the arrangement of the anti-slip portion with respect to the central absorbent sheet from the non-skin surface side.
発明の詳細な説明Detailed Description of the Invention
 本発明は、着用者の肌に対する適度な冷感効果を長く効果的に維持する吸収性物品に関する。 TECHNICAL FIELD The present invention relates to an absorbent article which effectively maintains a moderate cooling sensation effect on the skin of a wearer for a long time.
 吸収性物品における冷感剤の含有量は、通常、揮発によって時間の経過とともに低減し、清涼効果は薄らいでいく。そのため、従来、適度な冷感効果の維持が十分とはいえなかった。適度な冷感効果の観点から、冷感剤を過度に増やさなくとも、効果が長く維持されることが望まれる。 The content of the cooling agent in the absorbent article is generally reduced with time by volatilization, and the cooling effect is reduced. Therefore, conventionally, it has not been sufficient to maintain a proper cooling sensation effect. From the viewpoint of a moderate cooling effect, it is desirable that the effect be maintained for a long time without excessively increasing the cooling agent.
 これに対し、本発明の吸収性物品は、着用者の肌に対する適度な冷感効果を長く効果的に維持することができる。 On the other hand, the absorbent article of the present invention can effectively maintain a suitable cooling effect on the wearer's skin for a long time.
 以下、本発明に係る吸収性物品の好ましい一実施形態としての生理用ナプキン(以下、ナプキンとも言う)10について、図面を参照しながら説明する。
 本発明においては、特に断らない限り、人体に接触する側を肌面側ないし肌当接面側あるいは表面側といい、これと反対側を非肌面側ないし非肌当接面側あるいは裏面側という。これらは、人体に接触する面を有さない部材に関しても、吸収性物品の部材構成における相対的な位置関係を示す用語として用いる。また、着用時に人体の前側に位置する方向を前方といい、後側に位置する方向を後方という。吸収性物品の表面又は裏面の法線方向を厚み方向という。
Hereinafter, a sanitary napkin (hereinafter also referred to as a napkin) 10 as a preferred embodiment of the absorbent article according to the present invention will be described with reference to the drawings.
In the present invention, unless otherwise stated, the side in contact with the human body is referred to as the skin surface side or the skin contact surface side or the surface side, and the opposite side is the non-skin surface side or the non-skin contact surface side or the back surface side It is said. These are used also as a term which shows relative physical relationship in member composition of an absorptive article also about a member which does not have a field which contacts a human body. Moreover, the direction which is located in the front side of a human body at the time of wear is called front, and the direction which is located in the rear side is called back. The normal direction of the front surface or the back surface of the absorbent article is referred to as the thickness direction.
 ナプキン10は、図1及び2に示すように、肌当接面側の表面層1と、非肌当接面側の裏面層2と、表面層1と裏面層2との間に配された液保持性の吸収層(吸収体)3とを有する。表面層1は液を吸収層3へと送り込める液透過性を備え、裏面層2は液に対する防漏性を備える。表面層1及び裏面層2は吸収層3の両面を覆いつつ、吸収層3の外縁外方へと延出する大きさを有する。
 本実施形態においては、表面層1と吸収層3との間に、吸収層3よりも幅狭の液透過性の液拡散層4を有する。液拡散層4は、表面層1から透過される排泄液を平面方向に広げて、吸収層3の肌面側の吸収面積を広げる作用を有する。また、表面層1の肌当接面側の両側にサイドシート5が積層されている。サイドシート5と裏面層2とが吸収層3の幅方向外方に延出して、着衣等への固定手段であるウイング部6を形成している。ウイング部6及び裏面層2の非肌当接面側には、ナプキン10を着衣に固定するためのズレ止粘着部7が配されている。このシートの積層構造において、ナプキン10の外周縁は、吸収層3を介在させずに接合された外周シール部9となっている。
As shown in FIGS. 1 and 2, the napkin 10 is disposed between the surface layer 1 on the skin contact surface side, the back surface layer 2 on the non-skin contact surface side, and the surface layer 1 and the back surface layer 2. And a liquid-retaining absorption layer (absorber) 3. The surface layer 1 has liquid permeability that can send the liquid to the absorbent layer 3, and the back surface layer 2 has leak resistance to the liquid. The surface layer 1 and the back surface layer 2 have a size that extends outward of the outer edge of the absorption layer 3 while covering both surfaces of the absorption layer 3.
In the present embodiment, a liquid-permeable liquid diffusion layer 4 narrower than the absorption layer 3 is provided between the surface layer 1 and the absorption layer 3. The liquid diffusion layer 4 has an effect of spreading the waste fluid transmitted from the surface layer 1 in the planar direction to widen the absorption area on the skin surface side of the absorbing layer 3. Further, the side sheets 5 are laminated on both sides of the skin contact surface side of the surface layer 1. The side sheet 5 and the back surface layer 2 extend outward in the width direction of the absorbent layer 3 to form a wing portion 6 which is a fixing means to clothes and the like. On the non-skin-contacting surface side of the wing portion 6 and the back surface layer 2, a displacement preventing adhesive portion 7 for fixing the napkin 10 to clothes is disposed. In the laminated structure of this sheet, the outer peripheral edge of the napkin 10 is an outer peripheral seal portion 9 joined without the absorption layer 3 interposed.
 ナプキン10は、他の構成部材を含んでいてもよく、また液拡散層4、サイドシート5を有さない形態であってもよい。さらに表面層1から吸収層3にかけて圧搾した防漏溝、表面層1上の複数のエンボスなどを有していてもよい。また、サイドシート5は、表面層1と接合されながら、表面層1の両側よりも内方側に自由端部を残すようにしてもよく、前記自由端部に弾性部材等を配して防漏カフを構成してもよい。 The napkin 10 may include other components, and may have a form without the liquid diffusion layer 4 and the side sheet 5. Furthermore, it may have a leak-proof groove squeezed from the surface layer 1 to the absorbent layer 3, a plurality of embossments on the surface layer 1, and the like. In addition, the side sheet 5 may be left at the free end inward of both sides of the surface layer 1 while being bonded to the surface layer 1, and an elastic member or the like may be provided at the free end to prevent A leak cuff may be configured.
 ナプキン10は、平面視において、縦方向(Y方向)と、該縦方向と直交する幅方向(X方向)とを有する、縦長形状である。また表面層1、裏面層2及び吸収層3は、ナプキン10と同様に、縦長形状である。縦方向は、ナプキン10の装着時における、着用者の腹側部、股下部及び背側部を繋ぐ方向に対応する。幅方向は、着用者の股下における左右の足を繋ぐ方向に対応する。本明細書において、縦方向(Y方向)及び幅方向(X方向)は、ナプキン10の平面視における方向を示すと同時に、表面層1、裏面層2及び吸収層3の平面視における方向を示す。 The napkin 10 has a longitudinally long shape having a longitudinal direction (Y direction) and a width direction (X direction) orthogonal to the longitudinal direction in a plan view. Moreover, the surface layer 1, the back surface layer 2, and the absorption layer 3 are longitudinally long shapes like the napkin 10. The longitudinal direction corresponds to the direction connecting the wearer's ventral side, crotch and dorsal side when the napkin 10 is worn. The width direction corresponds to the direction in which the left and right feet in the crotch of the wearer are connected. In the present specification, the longitudinal direction (Y direction) and the width direction (X direction) indicate the direction in plan view of the napkin 10 and at the same time indicate the direction in plan view of the surface layer 1, the back layer 2 and the absorbent layer 3 .
 ナプキン10は、縦方向に関して、着用者の排泄ポイントに対応する領域を含む中間部Cを有する。さらに中間部Cよりも前方の腹部側に配置される前方部F、後方の臀部側に配置される後方部Rを有する。また、中間部Cには、幅方向中央部分に、前記排泄ポイントに対向し、排泄液を直接受け止める受液領域C1がある。受液領域C1がある「幅方向中央部分」とは、図1に示すように、幅方向の中心線Lから左右に広がる所定幅の範囲をいい、吸収層3の幅方向両端縁39よりも内側の範囲の部分を言う。具体的には、ナプキン10の幅方向の中心線Lから左右に広がる領域であって、吸収層幅に対して40%以上50%以下の範囲の部分をいう。なお、中間部C、受液領域C1、前方部F及び後方部Rは、ナプキン10における区分を示すと同時に、これに対応する表面層1、吸収層3及び裏面層2における区分をも示す。 The napkin 10 has an intermediate portion C including an area corresponding to the wearer's excretion point in the longitudinal direction. Furthermore, it has a front portion F disposed on the abdomen side forward of the middle portion C and a rear portion R disposed on the rear buttock side. Further, in the middle part C, there is a liquid receiving area C1 which faces the excrement point and directly receives the excrement fluid at the central part in the width direction. The "width direction central portion" where the liquid receiving area C1 is, as shown in FIG. 1, means a range of a predetermined width extending laterally from the center line L in the width direction, and is wider than the width direction both end edges 39 of the absorbing layer 3 Say the part of the inner range. Specifically, it is a region that spreads laterally from the center line L in the width direction of the napkin 10, and is a portion in the range of 40% to 50% with respect to the width of the absorbent layer. The middle part C, the liquid receiving area C1, the front part F and the rear part R indicate the divisions in the napkin 10 and also indicate the divisions in the surface layer 1, the absorption layer 3 and the back layer 2 corresponding thereto.
 中間部C、前方部F及び後方部Rの区分位置は、使用目的等によって設定される吸収性物品の長さに応じて適宜設定され得る。ショーツの股下部に折り曲げて固定するウイング部を備える場合は、該ウイング部の存在する縦方向に沿った領域が中間部Cとなる。本実施形態のナプキン10は、昼用などとして設定される形状の例を示しており、縦方向の長さを3等分して、前方部F、中間部C及び後方部Rが設定されており、ウイング部を備えない昼用のナプキンの場合にも、中間部はこの設定に従う。ナプキン10がどのような形状であっても一般的には、中間部Cは、前方部Fからの一定の距離の位置にある部位として設定され得る。さらに大人用若しくは幼児用のおむつなど、また、尿取りパッドなどについては、縦方向の長さを3等分して、前方部F、中間部C及び後方部Rが設定される。 The division positions of the middle portion C, the front portion F and the rear portion R may be appropriately set according to the length of the absorbent article set according to the purpose of use and the like. In the case of providing a wing portion that is bent and fixed to the crotch portion of the shorts, a region along the longitudinal direction in which the wing portion is present is the middle portion C. The napkin 10 of the present embodiment shows an example of a shape set for daytime use, etc., and the length in the longitudinal direction is equally divided into three to set the front part F, middle part C and rear part R The midsection follows this setting, even in the case of a day napkin without the wings and wings. In general, regardless of the shape of the napkin 10, the middle portion C can be set as a portion located at a certain distance from the front portion F. Furthermore, for adult or infant diapers and the like, and for urine collection pads and the like, the length in the longitudinal direction is equally divided into three, and the front part F, middle part C and rear part R are set.
 次に、吸収層3の好ましい層構造、吸収層3における冷感剤を含有する領域、及び連通部8について説明する。 Next, the preferable layer structure of the absorption layer 3, the area | region containing the cooling agent in the absorption layer 3, and the communication part 8 are demonstrated.
 吸収層3は、冷感剤を含有する中央吸収性シート32と、中央吸収性シート32の肌面側及び非肌側面に配された外包吸収性シート31とを、層状に重ねた積層構造を有する。中央吸収性シート32と外包吸収性シート31との平面視重なる領域において、少なくとも肌面側に中央吸収性シート32と外包吸収性シート31を連通する通気手段である連通部8が配されている。
 冷感剤を含有する中央吸収性シート32の上下(肌面側及び非肌面側)に外包吸収性シート31を配置した構造により、使用時の冷感剤の過度の揮発が抑制され、冷感の持続性が高まる。また、少なくとも肌面側に中央吸収性シート32と外包吸収性シート31との連通部8を設けた構造により、冷感剤の揮発が完全には抑制されず、冷感剤が連通部8を介して適度な冷感を付与することができる。すなわち、ナプキン10の着用時において、吸収層3内の層状にされたシート間に溜まる冷感剤の揮発成分を、連通部8により肌面側へ積極的に移動させることができる。
The absorbent layer 3 has a laminated structure in which a central absorbent sheet 32 containing a cooling agent and an outer shell absorbent sheet 31 disposed on the skin side and the non-skin side of the central absorbent sheet 32 are layered. Have. In a region where the central absorbent sheet 32 and the outer shell absorbent sheet 31 overlap in plan view, at least the skin surface side is provided with a communicating portion 8 which is a ventilating means communicating the central absorbent sheet 32 and the outer shell absorbent sheet 31. .
Due to the structure in which the envelope absorbent sheet 31 is disposed on the upper and lower sides (skin side and non-skin side) of the central absorbent sheet 32 containing a cooling agent, excessive volatilization of the cooling agent during use is suppressed, The sense of sustainability increases. In addition, the volatilization of the cooling agent is not completely suppressed by the structure in which the communicating portion 8 of the central absorbent sheet 32 and the outer packaging absorbent sheet 31 is provided at least on the skin surface side, and the cooling agent An appropriate cooling sensation can be imparted via That is, when the napkin 10 is worn, the volatile component of the cooling agent accumulated between the layered sheets in the absorbent layer 3 can be positively moved to the skin surface side by the communication part 8.
 本実施形態において、吸収層3の層構造をなす中央吸収性シート32と外包吸収性シート31の好ましい態様について詳述する。
 図2において、中央吸収性シート32は、表面層1側で幅方向の両端部を重ね合わせて三つ折りされた、折り畳み構造を有する。中央吸収性シート32は、中間部Cに配されている。中央吸収性シート32は、前方部Fと後方部Rとの間に位置する中間部Cにおいて、受液領域C1を含む位置にある。中央吸収性シート32の配置は、中間部Cに配置されていれば、中間部Cと同等の長さを有していてもよく、中間部Cから前方部F及び後方部Rに亘る長さを有していてもよい。
 図2において、外包吸収性シート31は、裏面層2側で幅方向の両端部を重ね合わせて三つ折りされた、折り畳み構造を有する。外包吸収性シート31は、中間部Cから前方部F及び後方部Rに及ぶ長さを有し、吸収層3の外形形状をなしている。外包吸収性シート31は、折り畳まれた状態において、折り畳まれた状態の中央吸収性シート32よりも幅広であり、中央吸収性シート32よりも縦方向の長さが長い。
 吸収層3において、冷感剤を含有する中央吸収性シート32は、外包吸収性シート31の折り畳み構造の内部に収められている。この配置において、外包吸収性シート31の肌面側部分31Aと非肌面側部分31Bとが、中央吸収性シート32の肌面側及び非肌面側を覆って配されている。
 吸収層3は、上記の積層構造において、中央吸収性シート32を有することによって、中間部Cの幅方向中央に、周辺より厚い高坪量部33を備える。
 吸収層3において、高坪量部33の厚さ(H1)の、高坪量部33以外の部分の厚さ(H2)に対する比(H2/H1)は、肌面に対して違和感なく使用できる観点から、1/5以上が好ましく、1/3以上が好ましい。前記比(H2/H1)は、フィット性の観点から、4/5以下が好ましく、2/3以下がより好ましい。
In the present embodiment, preferable aspects of the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 having the layer structure of the absorbent layer 3 will be described in detail.
In FIG. 2, the central absorbent sheet 32 has a folded structure in which both ends in the width direction are overlapped on the surface layer 1 side. The central absorbent sheet 32 is disposed in the middle portion C. The central absorbent sheet 32 is located at a middle portion C located between the front portion F and the rear portion R, including the liquid receiving area C1. The arrangement of the central absorbent sheet 32 may have the same length as the middle portion C if it is arranged in the middle portion C, and the length from the middle portion C to the front portion F and the rear portion R May be included.
In FIG. 2, the outer packaging absorbent sheet 31 has a folded structure in which both ends in the width direction are overlapped on the back layer 2 side and folded in three. The outer packaging absorbent sheet 31 has a length ranging from the middle part C to the front part F and the rear part R, and has an outer shape of the absorbent layer 3. The outer packaging absorbent sheet 31 is wider in the folded state than the central absorbent sheet 32 in the folded state, and has a longer length in the longitudinal direction than the central absorbent sheet 32.
In the absorbent layer 3, the central absorbent sheet 32 containing a cooling agent is housed inside the folded structure of the outer shell absorbent sheet 31. In this arrangement, the skin surface side portion 31A and the non-skin surface side portion 31B of the outer packaging absorbent sheet 31 are arranged so as to cover the skin surface side and the non-skin surface side of the central absorbent sheet 32.
The absorbent layer 3 has the central absorbent sheet 32 in the above-described laminated structure, and is provided with a high basis weight portion 33 thicker than the periphery at the center in the width direction of the middle portion C.
The ratio (H2 / H1) of the thickness (H1) of the high basis weight portion 33 to the thickness (H2) of the portion other than the high basis weight portion 33 in the absorbent layer 3 can be used without discomfort to the skin surface From the viewpoint, 1⁄5 or more is preferable, and 1⁄3 or more is preferable. The ratio (H2 / H1) is preferably 4/5 or less, more preferably 2/3 or less, from the viewpoint of fit.
 中央吸収性シート32は前述のとおり冷感剤を含有している。中央吸収性シート32は、中央吸収性シート32の全領域に冷感剤を含有していてもよいし、中央吸収性シート32の一部の領域に含有していてもよい。
 中央吸収性シート32が折り畳み構造を有する場合には、冷感剤を折り畳み構造の内側の領域に含有していることが好ましい。また、中央吸収性シート32が後述するポリマーリッチ領域35及び繊維リッチ領域36を有する場合には、冷感剤をポリマーリッチ領域35に含有していることがより好ましい。
 冷感剤は、中央吸収性シート32に含まれる限り、吸収層3の他の領域に含まれていてもよく、中央吸収性シート32以外の部材(例えば、外包吸収性シート31や液拡散層4や表面層1)に含まれていてもよい。ただし、着用者の肌に対する適度な冷感効果を長く効果的に維持させる観点から、冷感剤の含有量が最も多い領域が、中央吸収性シート32にあることが好ましい。また、冷感剤を含む領域は、ナプキン10の平面視において、中間部Cにあることが好ましい。
 中央吸収性シート32が、冷感剤を含有するとき、冷感剤の塗布部、すなわち冷感剤含有液の塗布部を含むことが好ましい。ここで、冷感剤含有液とは、冷感剤と溶媒とを混合した塗布液のことであり、冷感剤をナプキン10に含有させる際に用いられる液である。この冷感剤含有液の塗布部は製造工程において最初に含有させられる部位であり、製品としてのナプキン10においては、冷感剤成分が最も多い部位(含有量が多い部分)である。この含有量は、吸収層3の中央吸収性シート32と外包吸収性シート31とに分けて後述する方法により測定することができる。
The central absorbent sheet 32 contains a cooling agent as described above. The central absorbent sheet 32 may contain a cooling agent in the entire area of the central absorbent sheet 32 or may be contained in a partial area of the central absorbent sheet 32.
When the central absorbent sheet 32 has a folded structure, it is preferable to contain a cooling agent in the region inside the folded structure. Further, when the central absorbent sheet 32 has a polymer rich region 35 and a fiber rich region 36 described later, it is more preferable to contain a cooling agent in the polymer rich region 35.
The cooling agent may be contained in other regions of the absorbent layer 3 as long as it is contained in the central absorbent sheet 32, and members other than the central absorbent sheet 32 (for example, the outer packaging absorbent sheet 31 or the liquid diffusion layer 4 and the surface layer 1). However, it is preferable that the central absorbent sheet 32 has a region having the largest content of the cooling agent, from the viewpoint of effectively maintaining the appropriate cooling sensation effect on the wearer's skin for a long time. Moreover, it is preferable that the area | region containing a cooling agent exists in the intermediate part C in planar view of the napkin 10. FIG.
When the central absorbent sheet 32 contains a cooling agent, it is preferable to include an application part of the cooling agent, that is, an application part of the cooling agent-containing liquid. Here, a cooling agent containing liquid is a coating liquid which mixed the cooling agent and the solvent, and is a liquid used when making the napkin 10 contain a cooling agent. The application part of the cooling agent containing liquid is a part to be initially contained in the manufacturing process, and in the napkin 10 as a product, it is a part having a large amount of cooling agent component (a part having a large content). This content can be measured by a method which is divided into the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 of the absorbent layer 3 and described later.
 中央吸収性シート32は、さらに抗菌剤を含有していてもよい。抗菌剤を含有することで、冷感剤による感覚としてのムレやべたつきの抑制に加えて、ムレやべたつきが原因で引き起こされやすい菌の繁殖を抑制でき、快適に使用することができる。 The central absorbent sheet 32 may further contain an antibacterial agent. By containing the antibacterial agent, in addition to the suppression of mure and stickiness as a sensation due to a cooling agent, it is possible to suppress the proliferation of bacteria easily caused due to mure and stickiness, and can be used comfortably.
 連通部8は、中央吸収性シート32と外包吸収性シート31との重なり部分において連通する通気手段である。連通部8は、冷感剤の揮発成分を肌面へ誘導する通気手段として、少なくとも吸収層3の肌面側に配されている。本実施形態においては、外包吸収性シート31の肌面側部分31Aと中央吸収性シート32とに亘って配されている。ただし、連通部8の深さはこれに限定されるものでない。好ましい態様については後述する。
 連通部8は、冷感剤の揮発成分の移動経路、吸収層3等の変形による空気の移動経路として作用する。これらの作用により、特に時間が経って冷感剤の含有残存量が少なくなってきたときにおいても、層状構造である吸収層のシート間に溜まった冷感剤の揮発成分を、肌面へと十分に送り込むことができる。例えば、冷感剤が吸収層3の奥に残存する場合には、連通部8の存在によって吸収層3内部から肌面へと冷感剤の揮発成分を積極的に送り込むことができる。冷感剤の送り込みは、例えば、ナプキン着用時の着用者の体の動きに伴う、吸収層の変形などによって、より効果が高まる。
The communicating portion 8 is a ventilation means communicating at an overlapping portion of the central absorbent sheet 32 and the outer wrapping absorbent sheet 31. The communicating portion 8 is disposed at least on the skin surface side of the absorbent layer 3 as a ventilation means for guiding the volatile component of the cooling agent to the skin surface. In the present embodiment, the skin surface side portion 31A of the outer packaging absorbent sheet 31 and the central absorbent sheet 32 are arranged. However, the depth of the communication part 8 is not limited to this. Preferred embodiments will be described later.
The communicating portion 8 functions as a moving path of the volatile component of the cooling agent, and a moving path of air due to the deformation of the absorbing layer 3 and the like. Due to these actions, the volatile component of the cooling agent accumulated between the sheets of the absorption layer, which is a layered structure, is transferred to the skin surface even when the residual amount of the cooling agent decreases, particularly with time. It can be delivered enough. For example, when the cooling agent remains behind the absorption layer 3, the volatile component of the cooling agent can be positively fed from the inside of the absorption layer 3 to the skin surface by the presence of the communication portion 8. The delivery of the cooling agent is more effective, for example, due to the deformation of the absorbent layer accompanying the movement of the wearer's body when wearing a napkin.
 連通部8は、細長く切り込まれたスリット部又は部材の一部が切り欠かれた凹部空間等の隙間部分でもよく、部材の一部が押圧されて窪んだ凹部空間(圧搾部)であってもよく、部材の坪量が部分的に小さくされた凹部空間であってもよい。
 連通部8がスリット部又は部材の一部が切り欠かれた凹部空間である場合、連通部8において中央吸収性シート32及び外包吸収性シート31が同じ位置において連続的に切断されており、シート切断端部が連通部8の壁を形成することとなる。この壁において、中央吸収性シート32及び外包吸収性シート31の切断端部の一部が結合していることが好ましい。このような構成とすることにより、冷感剤が含有されている部分から吸収層3の肌面側表面への距離が短くなり、冷感剤の肌面側への移動をより効果的に行うことができる。圧搾部においても同等の効果が得られると考えられる。
The communicating portion 8 may be a gap portion such as a slit portion cut into an elongated shape or a recessed portion space where a portion of the member is cut away, or a recessed portion space (squeezed portion) in which a portion of the member is pressed and depressed It may be a recess space in which the basis weight of the member is partially reduced.
When the communication part 8 is a concave part space where a slit part or a part of a member is cut away, in the communication part 8, the central absorbent sheet 32 and the outer packaging absorbent sheet 31 are continuously cut at the same position. The cutting end forms the wall of the communicating portion 8. In this wall, it is preferable that a part of the cut ends of the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 be joined. With such a configuration, the distance from the portion containing the cooling agent to the surface on the skin surface side of the absorbent layer 3 becomes short, and the movement of the cooling agent to the skin surface side is performed more effectively. be able to. It is considered that the same effect can be obtained in the pressing section.
 連通部8は好ましくは、連通孔である。連通孔とは、吸収層3の肌面側から所定の厚みを貫通する孔のことであり、上述したスリット部や凹部空間を含む概念である。連通部8が連通孔であると、ナプキン10の着用時の着用者の体の動きに伴って、ナプキン10の幅方向内方への押圧や、前後方向のせん断力等の外力が加わった時に、連通孔部分が開閉して、冷感剤の揮発成分を一定量溜めながら肌面側へと、より効果的に送り込むことができる。 The communication portion 8 is preferably a communication hole. A communicating hole is a hole which penetrates predetermined thickness from the skin surface side of absorption layer 3, and is the concept containing the slit part and crevice space which were mentioned above. When the communication portion 8 is a communication hole, when an external force such as a pressure inward in the width direction of the napkin 10 or a shearing force in the front-rear direction is applied with the movement of the wearer's body when wearing the napkin 10 The communication hole portion can be opened and closed, and the volatile component of the cooling agent can be more effectively fed to the skin surface side while being accumulated in a fixed amount.
 本実施形態においては、連通部8は吸収層3の一部を切り込んだスリット部81として配されている(図1~3参照)。スリット部81は吸収層3の平面領域において複数分散して配列されている。ここで言う「スリット部」は、部材断絶の幅が0.5mm以下の切り込み部分として定義でき、好ましくは0.3mm以下であり、より好ましくは0.2mm以下である。スリット部81の「幅」とは、ナプキン10の平面視において、スリット部81の延出する長さ方向に直交する方向の、断絶された部材間の距離(開口幅)をいう。スリット部81の幅は、ナプキン10から吸収層3を取り出して水平な台に静置し、張力を加えない自然状態において、株式会社キーエンス製のデジタルマイクロスコープVHX-1000によって測定することができる。測定に際し、測定倍率は適宜調整して測定する。 In the present embodiment, the communication portion 8 is disposed as a slit portion 81 obtained by cutting a part of the absorbent layer 3 (see FIGS. 1 to 3). A plurality of slit parts 81 are dispersed and arranged in the plane region of the absorption layer 3. The “slit portion” referred to here can be defined as a cut portion having a member cutting width of 0.5 mm or less, preferably 0.3 mm or less, more preferably 0.2 mm or less. The “width” of the slit portion 81 refers to the distance (opening width) between the disconnected members in the direction orthogonal to the length direction in which the slit portion 81 extends in a plan view of the napkin 10. The width of the slit portion 81 can be measured with a digital microscope VHX-1000 manufactured by Keyence Corporation in a natural state where the absorbent layer 3 is taken out of the napkin 10 and placed on a horizontal table and tension is not applied. At the time of measurement, measurement magnification is appropriately adjusted and measured.
 連通部8は、吸収層3の肌面側において、中央吸収性シート32と外包吸収性シート31の肌面側部分31Aとの平面視において重なる領域に少なくとも配されている(図1及び図3参照)。連通部8は、吸収層3を平面視した縦方向において、少なくとも中間部Cを含む領域に配されることが好ましい。また、連通部8のうち最も幅方向外側に位置するものは、吸収層3の幅方向両端縁39よりも内側にあり、冷感剤が含まれる領域よりも幅方向外側に配されることが好ましい。
 連通部8は、通気路としての作用を効果的に発現させる観点から、上記領域に、複数、分散配置されていることが好ましい。
The communication portion 8 is at least disposed in a region where the central absorbent sheet 32 and the skin surface side portion 31A of the outer packaging absorbent sheet 31 overlap in plan view on the skin surface side of the absorbent layer 3 (FIG. 1 and FIG. 3). reference). The communicating portion 8 is preferably disposed in a region including at least the middle portion C in the longitudinal direction of the absorption layer 3 in plan view. Further, among the communicating portions 8, those located on the outermost side in the width direction are on the inner side than both end edges 39 in the width direction of the absorbing layer 3 and are arranged on the outer side in the width direction than the region containing the cooling agent. preferable.
It is preferable that a plurality of communication portions 8 be dispersedly arranged in the above-described region in order to effectively exhibit the function as the air passage.
 連通部8は、吸収層3の厚み方向において少なくとも吸収層3の表面層1側(肌面側)に形成されていればよく、表面層1側から所定深さにまであってもよく、吸収層3の厚み方向全体に亘ってあってもよい。連通部8の冷感剤に対する作用を考慮すると、連通部8は表面層1側から所定深さにまであることが好ましい。深さとしては、吸収層3の厚みの50%以上70%以下程度が好ましい。より具体的には、連通部8は、吸収層3の肌面側から厚み方向に複数のシート層に亘って配されていることが好ましく、外包吸収性シート31の肌面側部分31Aから中央吸収性シート32の冷感剤が配されている部位まで到達していることがより好ましい。また、ズレ止粘着部7に最も近い部位の外包吸収性シート31(非肌面側部分31B)には存在していないことが好ましい。このような構成とすることにより、冷感剤の肌面側への拡散を促進して適度な冷感を付与でき、また、冷感剤の非肌面側への拡散を抑制して、ズレ止粘着部の粘着力の低下、着衣への糊残り等のズレ止性能の低下をより効果的に抑制できる。
 一方で、吸収層3の変形による連通部8への空気の移動による冷感効果の観点からは、連通部8は吸収層3の表面から裏面まで至っていることが好ましい。
The communicating portion 8 may be formed at least on the surface layer 1 side (skin surface side) of the absorbing layer 3 in the thickness direction of the absorbing layer 3, and may extend to a predetermined depth from the surface layer 1 side. It may extend over the entire thickness direction of the layer 3. In consideration of the action of the communication part 8 on the cooling agent, it is preferable that the communication part 8 be as far as the predetermined depth from the surface layer 1 side. The depth is preferably about 50% to 70% of the thickness of the absorbing layer 3. More specifically, it is preferable that the communication portion 8 be disposed across the plurality of sheet layers in the thickness direction from the skin surface side of the absorbent layer 3, and the center from the skin surface side portion 31 A of the outer packaging absorbent sheet 31 It is more preferable to reach the portion of the absorbent sheet 32 where the cooling agent is disposed. In addition, it is preferable that the outer wrapping absorbent sheet 31 (the non-skin surface side portion 31B) of the portion closest to the anti-displacement portion 7 does not exist. With such a configuration, it is possible to promote the diffusion of the cooling agent to the skin side to give an appropriate cooling sensation, and also suppress the diffusion of the cooling agent to the non-skin side to shift It is possible to more effectively suppress the decrease in the adhesive strength of the anti-adhesive portion, and the decrease in the anti-displacement performance such as the adhesive residue on the clothes.
On the other hand, it is preferable that the communicating portion 8 extends from the surface to the back surface of the absorbing layer 3 from the viewpoint of the cooling effect due to the movement of the air to the communicating portion 8 due to the deformation of the absorbing layer 3.
 連通部8の平面視形状は特に限定されず、矩形でもよく、円形でもよい。連通部8は、冷感剤に対する作用を考慮すると、連通部8の一方向の長さが非肌面より肌面側において広いことが好ましい。このような構成とすることにより、冷感剤の肌面側への拡散をより促進でき、また、冷感剤の非肌面側への拡散をより抑制できる。 The plan view shape of the communication portion 8 is not particularly limited, and may be rectangular or circular. It is preferable that the length in one direction of the communicating portion 8 be wider on the skin surface side than the non-skin surface, considering the action on the cooling agent. With such a configuration, the diffusion of the cooling agent to the skin side can be further promoted, and the diffusion of the cooling agent to the non-skin side can be further suppressed.
 中央吸収性シート32及び外包吸収性シート31を構成する吸収性シートは、高吸収性ポリマー材と親水性繊維とを含む。吸水性シートは、親水性繊維からなる2つのシート状の繊維層間に高吸収性ポリマー材を挟持して固定した厚みの薄いシート体である。ここでいう高吸収性ポリマー材はいわゆるSAP(Superabsorbent polymer)と呼ばれる表面架橋された高分子材料である(以下、同様)。吸収性シートの形成にあたっては、高吸収性ポリマーが湿潤によって発現する粘着力や、別に添加した接着剤や接着性繊維等のバインダーを利用して一体化することができる。作製は通常用いられる種々の方法によって行うことができ、湿式、乾式いずれの方式によってもよい。
 吸収性シートは高吸収性ポリマー材をシートの平面方向に分散配置させているためゲルブロッキング(体液等の水性液体を吸収して膨潤した吸収性ポリマー同士の相互作用により生じる液体の吸収阻害現象)を起こし難く、高い吸収力を有する。このため、吸水性シート1層の厚みを1.0mm以下に抑えることができる。例えば、特開平8-246395号公報の段落[0019]~[0131]に記載のものなどが挙げられる。
The absorbent sheet which comprises the center absorbent sheet 32 and the outer shell absorbent sheet 31 contains a highly absorbent polymer material and hydrophilic fibers. The water absorbing sheet is a thin sheet having a thickness in which a superabsorbent polymer material is sandwiched and fixed between two sheet-like fiber layers made of hydrophilic fibers. The superabsorbent polymer material mentioned here is a surface-crosslinked polymer material called a so-called SAP (Superabsorbent polymer) (the same applies hereinafter). In forming the absorbent sheet, it can be integrated using the adhesive strength of the superabsorbent polymer when it is wetted, or a binder such as an adhesive or adhesive fiber added separately. The preparation can be performed by various methods commonly used, and may be either wet or dry.
Since the absorbent sheet has a highly absorbent polymer material dispersed and arranged in the plane direction of the sheet, gel blocking (the absorption inhibition phenomenon of the liquid caused by the interaction between the absorbent polymers which are absorbed by swelling the aqueous liquid such as body fluid) Are difficult to cause, and have high absorbency. For this reason, the thickness of one water absorbing sheet layer can be suppressed to 1.0 mm or less. For example, those described in paragraphs [0019] to [0131] of JP-A-8-246395 can be mentioned.
 吸収性シートは、断面視において、図4に示すように、ポリマーリッチ領域35と繊維リッチ領域36とを備えることが好ましい。具体的には、図4は、中央吸収性シート32を構成する吸収性シートの一部の厚み断面にポリマーリッチ領域35と繊維リッチ領域36とが積層され一体構造になっている態様を示している。
 ポリマーリッチ領域35と繊維リッチ領域36とは、高吸収性ポリマー材37の質量と親水性繊維の質量との合計質量に対する高吸収性ポリマー材37の質量比率(以下、単に「高吸収性ポリマー材37の質量比率」と言う。)によって規定される。ポリマーリッチ領域35は繊維リッチ領域36よりも前記高吸収性ポリマー材37の質量比率が相対的に高くされている。一方、繊維リッチ領域36は、ポリマーリッチ領域35に対して高吸収性ポリマー材37の質量比率が相対的に低い。
The absorbent sheet preferably has a polymer rich region 35 and a fiber rich region 36 as shown in FIG. 4 in a cross sectional view. Specifically, FIG. 4 shows an embodiment in which the polymer rich area 35 and the fiber rich area 36 are laminated on the thickness cross section of a part of the absorbent sheet constituting the central absorbent sheet 32 to form an integral structure. There is.
The polymer rich area 35 and the fiber rich area 36 are the mass ratio of the superabsorbent polymer material 37 to the total mass of the mass of the superabsorbent polymer material 37 and the mass of the hydrophilic fiber (hereinafter referred to simply as “superabsorbent polymer material It is defined by "the mass ratio of 37". In the polymer rich region 35, the mass ratio of the superabsorbent polymer material 37 is relatively higher than that of the fiber rich region 36. On the other hand, in the fiber-rich region 36, the mass ratio of the superabsorbent polymer material 37 to the polymer-rich region 35 is relatively low.
 吸収性シートは上記構成により、吸収層3の厚み方向において、経血吸収後に自由水が相対的に少なくなるポリマーリッチ領域35と自由水が相対的に多く繊維間に残る繊維リッチ領域36とを備える。 With the above configuration, the absorbent sheet has a polymer-rich region 35 in which free water becomes relatively small after absorption of menstrual blood in the thickness direction of the absorbent layer 3 and a fiber-rich region 36 in which free water remains relatively between fibers. Prepare.
 冷感剤は、中央吸収性シート32のポリマーリッチ領域35に含まれていることが好ましい。このとき、前述した冷感剤塗布部がポリマーリッチ領域35に配されていることが好ましい。ポリマーリッチ領域35においては高吸収性ポリマー材37により周辺の自由水が相対的に低減されるため、冷感剤が揮発しやすい。一方で、繊維リッチ領域36においては、相対的に多く残る自由水(体液)により、冷感剤の揮発成分が過度に拡散することを抑制することができる。
 中央吸収性シート32は、ポリマーリッチ領域35に冷感剤を有し、繊維リッチ領域36を外面側にして折り畳んだ構成であることが好ましい。これにより、中央吸収性シート32の積層構造の内部に冷感剤が揮発しやすい構造を備える。加えて、中央吸収性シート32の外側に冷感剤の揮発成分が外側に拡散しすぎるのを抑制する構造を備える。これにより、中央吸収性シート32は、外包吸収性シート31との組合せにおいて、適度な冷感効果をより長く効果的に付与することができる。
 また、このような構成とすることにより、ズレ止粘着部7への冷感剤の拡散を適度に抑えることができ、ズレ止性能の劣化を抑制できる。
The cooling agent is preferably contained in the polymer rich region 35 of the central absorbent sheet 32. At this time, it is preferable that the cooling agent application part mentioned above is distribute | arranged to the polymer rich area | region 35. As shown in FIG. In the polymer-rich region 35, the superabsorbent polymer material 37 relatively reduces the free water in the periphery, so the cooling agent tends to evaporate. On the other hand, in the fiber-rich region 36, excessive diffusion of the volatile component of the cooling agent can be suppressed by the free water (body fluid) remaining relatively in a relatively large amount.
The central absorbent sheet 32 preferably has a cooling agent in the polymer rich area 35 and is folded with the fiber rich area 36 on the outer surface side. Thus, the cooling agent is easily volatilized inside the laminated structure of the central absorbent sheet 32. In addition, it has a structure which suppresses that the volatile component of a cooling agent spreads outside to the outer side of the central absorbent sheet 32 too much. As a result, the central absorbent sheet 32 can effectively impart an appropriate cooling sensation effect longer in combination with the outer wrapping absorbent sheet 31.
Moreover, by setting it as such a structure, the spreading | diffusion of the cooling agent to the slippage prevention adhesion part 7 can be suppressed moderately, and degradation of the slippage prevention performance can be suppressed.
 吸収性シートにおけるポリマーリッチ領域35と繊維リッチ領域36の形成は、例えば次のようにして行うことができる。
 まず、親水性繊維を含む水スラリーを湿式抄紙して抄造された、湿潤した繊維ウエブを作製する。水スラリーには熱溶融性接着繊維、紙力補強剤などを含ませてもよい。湿潤した状態にある繊維ウエブに対して、高吸収性ポリマー材を散布し、高吸収性ポリマーが繊維間に入り込んだ状態を作り出す。この部分が、吸収性シートにおけるポリマーリッチ領域35となる。次いで、高吸収性ポリマー材を散布した面の上から、親水性繊維及び熱溶融性接着繊維又は紙力補強剤を含む繊維集合体を積層して乾燥、一体化処理をして吸収性シートを得る。後から積層した繊維集合体の部分が繊維リッチ領域36となる。
 また、吸収性シートを乾式で作製する場合は、高吸収性ポリマー材を散布する層は、抄紙、乾燥した紙、種々の方法により作製された不織布であってもよい。高吸収性ポリマー材を繊維間に入り込ませやすくするとう観点から、クレープ処理されたような嵩高な紙、エアースルー不織布などが好ましい。この場合、高吸収性ポリマー材とポリマーリッチ領域35となる層の構成繊維との接合、ポリマーリッチ領域35となる層と繊維リッチ領域36となる層との接合には、ホットメルト型接着剤や水溶性接着剤などを用いてもよい。さらに、ポリマーリッチ領域35となる層に対し、親水性繊維を積層する又は吹き付けることで繊維リッチ領域36を形成してもよい。
The formation of the polymer rich area 35 and the fiber rich area 36 in the absorbent sheet can be performed, for example, as follows.
First, a wet fiber web made by wet papermaking of a water slurry containing hydrophilic fibers is produced. The water slurry may contain a heat melting adhesive fiber, a paper reinforcing agent, and the like. The superabsorbent polymer material is sprayed onto the fiber web in the wet state to create a state in which the superabsorbent polymer intercalates between the fibers. This portion becomes the polymer rich region 35 in the absorbent sheet. Then, on the surface to which the superabsorbent polymer material has been dispersed, a fiber assembly containing hydrophilic fibers and a heat melting adhesive fiber or a paper strength reinforcing agent is laminated, dried and integrated to obtain an absorbent sheet. obtain. The portion of the fiber assembly laminated later becomes the fiber rich region 36.
When the absorbent sheet is produced dry, the layer to which the high absorbent polymer material is dispersed may be paper making, dried paper, or non-woven fabric produced by various methods. From the viewpoint of facilitating penetration of the superabsorbent polymer material into fibers, bulky paper such as creped paper, air through non-woven fabric and the like are preferable. In this case, a hot melt adhesive or the like is used for bonding the high-absorbent polymer material to the component fibers of the layer to be the polymer-rich region 35, and bonding to the layer to be the polymer-rich region 35 and the layer to be the fiber-rich region 36. A water soluble adhesive or the like may be used. Furthermore, the fiber rich area 36 may be formed by laminating or spraying hydrophilic fibers on the layer to be the polymer rich area 35.
 冷感剤は、上記のとおり長持ちするため、過度に含有量を増量する必要がない。そのため従来と同様の含有量でありながら、肌への刺激を抑え、適度な冷感効果を長く効果的に維持することができる。
 具体的には、ナプキン10全体における冷感剤の含有量は、冷感の適度さと、ムレ感やべたつき感の観点から、冷感剤の種類によって決めることができる。
 例えば、乳酸メンチルの場合であれば、製品長に対して4mg/100mm以上が好ましく、5mg/100mm以上がより好ましく、6.5mg/100mm以上がさらに好ましい。前記含有量は、肌への刺激を抑制する観点から、13.5mg/100mm以下が好ましく、12.5mg/100mm以下がより好ましく、11.5mg/100mm以下がさらに好ましい。
Since the cooling agent lasts as described above, there is no need to increase the content excessively. Therefore, while having the same content as in the prior art, it is possible to suppress the stimulation on the skin and maintain the appropriate cooling sensation effect effectively for a long time.
Specifically, the content of the cooling agent in the entire napkin 10 can be determined depending on the type of the cooling agent from the viewpoint of the appropriateness of the cooling feeling, the mure feeling and the sticky feeling.
For example, in the case of menthyl lactate, 4 mg / 100 mm or more is preferable, 5 mg / 100 mm or more is more preferable, and 6.5 mg / 100 mm or more is more preferable. From the viewpoint of suppressing skin irritation, the content is preferably 13.5 mg / 100 mm or less, more preferably 12.5 mg / 100 mm or less, and still more preferably 11.5 mg / 100 mm or less.
(冷感剤の含有の有無、含有量の測定方法)
 吸収性物品の対象部材又は対象部位から冷感剤を溶媒で抽出し、抽出溶液をガスクロマトグラフィ法(GC)で分析することができる。測定は、ガスクロマトグラフに取り付けた水素炎イオン化型検出器(FID)で行い、例えば、Agilent technologies製7890Aにより測定することができる。予め冷感剤を構成する化合物の濃度とピーク面積の関係を検量線化しておき、当該検量線を元に定量作業を行う。
 冷感剤が乳酸メンチル及び/又はメントールを含む場合を例に説明する。溶媒としてメタノールを使用して対象部材又は対象部位から乳酸メンチル及び/又はメントールを抽出する。メタノールを溶媒として、予め濃度の異なる3~5段階程度の乳酸メンチル溶液及び/又はメントール溶液を準備し、GCのクロマトグラムからそれぞれの濃度のピーク面積を算出し、標準試料として、n-ペンチルアルコールを用い、標準試料の濃度に対してそのピーク面積をプロットした検量線を作成する。検量線を作成した分析と同じ条件で抽出液の分析を行うことで、得られたピーク面積を検量線にあてはめて乳酸メンチル量及び/又はメントール量を算出する。また、得られた乳酸メンチル量及び/又はメントール量を、対象部材又は対象部位の面積で除することにより、単位面積当たりの冷感剤量(冷感剤坪量)を求めることができる。また、得られた乳酸メンチル量及び/又はメントール量を、吸収性物品の対象部材又は対象部位の吸収性物品長さ方向の長さ(mm)で除し、100倍することで、製品長(吸収層長さ)100m当りの冷感剤量を求めることができる。
 製品の構成部材又は部位ごとの冷感剤量を知るには、5℃のチャンバー内で製品を分解し、測定する材料部位を取り出すことで分析可能となる。
(Presence or absence of content of cooling agent, measuring method of content)
The cooling agent can be extracted with a solvent from the target member or target site of the absorbent article, and the extraction solution can be analyzed by gas chromatography (GC). The measurement is performed with a flame ionization detector (FID) attached to a gas chromatograph, and can be measured, for example, by 7890A manufactured by Agilent technologies. The relationship between the concentration of the compound constituting the cooling agent and the peak area is previously converted to a calibration curve, and quantitative work is performed based on the calibration curve.
The case where the cooling agent contains menthyl lactate and / or menthol is described as an example. Menthyl lactate and / or menthol is extracted from the target member or target site using methanol as a solvent. Using methanol as a solvent, prepare in advance 3 to 5 steps of menthyl lactate solution and / or menthol solution with different concentrations, calculate peak areas of each concentration from the chromatogram of GC, and use n-pentyl alcohol as a standard sample A standard curve is plotted where the peak area is plotted against the concentration of the standard sample. By analyzing the extract under the same conditions as the analysis for which the calibration curve was prepared, the peak area obtained is applied to the calibration curve to calculate the amount of menthyl lactate and / or the amount of menthol. Further, the amount of cooling agent per unit area (cooling agent basis weight) can be determined by dividing the amount of menthyl lactate and / or menthol obtained by the area of the target member or the target site. In addition, the obtained menthyl lactate content and / or menthol content is divided by the length (mm) of the absorbent article in the length direction of the target member or target portion of the absorbent article, and multiplied by 100 to obtain the product length ( Absorbent layer length) The amount of cooling agent per 100 m can be determined.
In order to know the amount of cooling agent for each component or part of the product, it is possible to analyze by decomposing the product in a chamber at 5 ° C. and taking out the material part to be measured.
 本実施形態の吸収層3の積層構造において、中央吸収性シート32は、外包吸収性シート31と層状の積層構造を有する限り、図2のような折り畳み構造を有するものに限られない。例えば、折り畳まれていない態様も可能である。ただし、冷感剤の揮発を制御する観点から、中央吸収性シート32は折り畳み構造を有することが好ましい。中央吸収性シート32の折り畳み構造は、図2に示す態様に限らず、種々のものとすることができる。例えば、図5(A)~(D)に示すような折り畳みであってもよい。図5(A)は、中央吸収性シート32の幅方向の両端部をそれぞれ肌面側と非肌面側とに折り返しS字状に折り畳んだ態様を示している。図5(B)は幅方向に二つ折りした態様を示している。図5(C)及び(D)は、幅方向に三つ折りした各部分の長さが等しくなるように折り畳んだ態様を示している。 In the laminated structure of the absorbent layer 3 of the present embodiment, the central absorbent sheet 32 is not limited to the one having a folded structure as shown in FIG. 2 as long as it has a laminated structure with the outer wrapping absorbent sheet 31. For example, an unfolded embodiment is also possible. However, from the viewpoint of controlling the volatilization of the cooling agent, the central absorbent sheet 32 preferably has a folding structure. The folded structure of the central absorbent sheet 32 is not limited to the embodiment shown in FIG. For example, it may be folded as shown in FIGS. 5 (A) to 5 (D). FIG. 5 (A) shows a mode in which both ends in the width direction of the central absorbent sheet 32 are folded back in the S-shape on the skin side and the non-skin side, respectively. FIG. 5B shows an aspect in which the sheet is folded in half in the width direction. FIGS. 5C and 5D show a mode in which the portions folded in three in the width direction are equal in length.
 本実施形態の吸収層3の積層構造において、外包吸収性シート31は、図2のような折り畳み構造を有するものに限られない。例えば、外包吸収性シート31を複数の別々のシート部にし、これらシート部を中央吸収性シート32の肌面側と非肌面側に配して積層構造を形成してもよい。冷感剤の揮発を制御する観点から、外包吸収性シート31は折り畳まれていることが好ましい。
 外包吸収性シート31の折り畳み構造は、図2に示す態様に限らず、種々のものとすることができる。例えば、中央吸収性シート32の折り畳み構造として示した図5(A)~(D)と同様のものとしてもよい。また肌面側と非肌面側とに分かれた2枚のシートを積層した構造であってもよい。さらに、外包吸収性シート31の折り畳み構造の内部に中央吸収性シート32を内包する態様に限定されず、内包せずに、外包吸収性シート31の折り畳み構造の非肌面側に中央吸収性シート32を積層する態様であってもよい。
 ただし、外包吸収性シート31の折り畳み構造の内部に中央吸収性シート32を内包する態様であると、冷感剤の揮発成分をより溜めやすくなり、前述した連通部8の作用の観点から好ましい。
In the laminated structure of the absorbent layer 3 of the present embodiment, the outer packaging absorbent sheet 31 is not limited to one having a folded structure as shown in FIG. For example, the outer wrapping absorbent sheet 31 may be formed as a plurality of separate sheet parts, and these sheet parts may be arranged on the skin surface side and the non-skin surface side of the central absorbent sheet 32 to form a laminated structure. From the viewpoint of controlling the volatilization of the cooling agent, the envelope absorbent sheet 31 is preferably folded.
The folded structure of the outer wrapping absorbent sheet 31 is not limited to the aspect shown in FIG. 2 and can be various. For example, it may be similar to those shown in FIGS. 5 (A) to 5 (D) shown as the folded structure of the central absorbent sheet 32. Moreover, the structure which laminated | stacked the sheet | seat of 2 sheets divided into the skin surface side and the non-skin surface side may be sufficient. Furthermore, it is not limited to the aspect which includes the central absorbent sheet 32 inside the folding structure of the outer packaging absorbent sheet 31, and the central absorbent sheet on the non-skin side of the folding structure of the outer packaging absorbent sheet 31 without including it. 32 may be laminated.
However, if the central absorbent sheet 32 is contained in the inside of the folded structure of the outer packaging absorbent sheet 31, the volatile component of the cooling agent is more easily retained, which is preferable from the viewpoint of the action of the communication portion 8 described above.
 吸収層3がどのような積層構造を有していても、連通部8の配された部分を除いて、吸収性シートの重なり部分が接合されないことが好ましい。これにより、吸収層3の層間の空間が形成されやすく、前述の層間の開閉性が高まる。その結果、冷感剤の揮発成分の肌への移動をより発現させやすくすることができる。 Regardless of the laminated structure of the absorbent layer 3, it is preferable that the overlapping portions of the absorbent sheets are not joined except for the portion where the communication portion 8 is disposed. Thereby, the space between the layers of the absorption layer 3 is easily formed, and the opening and closing property between the above layers is enhanced. As a result, the movement of the volatile component of the cooling agent to the skin can be more easily expressed.
 次に、冷感剤のズレ止粘着部7に対する影響を考慮した、ズレ止め粘着部7と中央吸収性シート32との好ましい配置関係について説明する。
 ズレ止粘着部7は、前述のとおり、裏面層2の非肌面側に配置される。ズレ止粘着部7は、着衣に粘着し、着衣とナプキンとの装着固定位置のズレを低減する機能を有する。従来、冷感剤は、ズレ止粘着部の粘着力低下や着衣への糊残りといったズレ止性能を低下させる要因の一つとなっていた。
 これに対し、本実施形態においては、ズレ止粘着部7と冷感剤を含有する中央吸収性シート32との平面視における重なりをできるだけ少なくすることが好ましい。この観点から、上記重なり部分は、中央吸収性シート32の配置面積(ナプキン10の平面視において、中央吸収性シート32が占める面積であり、中央吸収性シート32が折り畳まれた状態である時には、折り畳まれた状態での平面視における面積)を100%とした場合に、配置面積の35%以下であることが好ましく、30%以下であることがより好ましく、25%以下であることがさらに好ましい。このような配置とすることにより、ズレ止粘着部7の粘着剤に対する冷感剤の影響を低減して、粘着力の低下、着衣への糊残り等のズレ止性能の低下を抑制することができる。また、上記重なり部分は、着衣とのズレを効果的に抑制する観点から、10%以上であることが好ましく、15%以上であることがより好ましく、18%以上であることがさらに好ましい。また、ズレ止粘着部7は、着衣とのズレを効果的に抑制する観点から、複数、分散配置されていることが好ましい。
Next, a preferred positional relationship between the anti-deviation adhesive portion 7 and the central absorbent sheet 32 in consideration of the influence of the cooling agent on the anti-deviation adhesive portion 7 will be described.
The slip prevention adhesion part 7 is arrange | positioned at the non-skin surface side of the back surface layer 2 as mentioned above. The anti-displacement portion 7 adheres to the clothes and has a function of reducing the displacement between the clothes and the napkin. Heretofore, a cooling agent has been one of the factors that lower the anti-displacement performance, such as the decrease in the adhesive strength of the anti-displacement portion and the adhesive residue on the clothes.
On the other hand, in the present embodiment, it is preferable to reduce the overlap between the anti-slip portion 7 and the central absorbent sheet 32 containing a cooling agent in a plan view as much as possible. From this point of view, the overlapping portion is an arrangement area of the central absorbent sheet 32 (an area occupied by the central absorbent sheet 32 in a plan view of the napkin 10 and when the central absorbent sheet 32 is in a folded state, It is preferable that it is 35% or less of arrangement | positioning area when the area in planar view in the folded state is 100%, It is more preferable that it is 30% or less, It is more preferable that it is 25% or less . With such an arrangement, the influence of the cooling agent on the pressure-sensitive adhesive of the anti-displacement portion 7 is reduced to suppress the decrease in the adhesive strength and the anti-displacement performance such as the adhesive residue on the clothes. it can. The overlapping portion is preferably 10% or more, more preferably 15% or more, and still more preferably 18% or more, from the viewpoint of effectively suppressing the difference from the clothes. Further, from the viewpoint of effectively suppressing the displacement with the clothes, it is preferable that a plurality of the displacement prevention adhesive portions 7 be dispersedly disposed.
 加えて、中央吸収性シート32の中間部Cにおける幅方向中央領域が、ズレ止粘着部7との重なりを少なくしていることが好ましく、重ならないことがより好ましい。最も体圧のかかる、中央吸収性シート32の幅方向中央領域の領域にズレ止粘着部7が少ないことにより、冷感剤がズレ止粘着部7に与える影響を低減することができる。ここでいう、中央吸収性シート32の中間部Cにおける幅方向中央領域とは、中央吸収性シート32における、幅方向全長を3分割した際の中央の領域を意味する。 In addition, it is preferable that the central area in the width direction of the middle portion C of the central absorbent sheet 32 has a small overlap with the anti-slip portion 7, and more preferably not. By reducing the amount of the anti-slip portion 7 in the region of the central region in the width direction of the central absorbent sheet 32 to which the body pressure is most applied, the influence of the cooling agent on the anti-slip portion 7 can be reduced. Here, the width direction central region of the middle portion C of the central absorbent sheet 32 means the central region of the central absorbent sheet 32 when the entire length in the width direction is divided into three.
 図6(A)~(D)は、ズレ止粘着部7の配置の具体例を示す模式図である。図6(A)~(D)においては、ズレ止粘着部7と中央吸収性シート32との配置関係を示すため、他の部材を除き、中央吸収性シート32にズレ止粘着部7の配置を投影させて模式的に示した。
 図6(A)は、複数のズレ止粘着部7を、中央吸収性シート32の縦方向の両側にかかる位置に複数配列した態様を示す。図6(B)は、縦方向に連続したズレ止粘着部7を一対、中央吸収性シート32の縦方向の両側に沿って配置した態様を示す。図6(A)及び(B)はいずれも、ズレ止粘着部7が中央吸収性シート32の幅方向中央領域と重ならない配置としている。図6(C)は、ズレ止粘着部7を、中央吸収性シート32の幅方向に平行に複数配置した態様を示す。図6(D)は、ズレ止粘着部7を、中央吸収性シート32の縦方向に平行に複数配置した態様を示す。
6 (A) to 6 (D) are schematic views showing a specific example of the arrangement of the anti-slip portion 7. As shown in FIG. In FIGS. 6A to 6D, in order to show the positional relationship between the anti-slip portion 7 and the central absorbent sheet 32, the disposition of the anti-slip portion 7 on the central absorbent sheet 32 except for the other members. Is shown schematically.
FIG. 6A shows a mode in which a plurality of anti-slip adhesion portions 7 are arranged at positions on both sides of the central absorbent sheet 32 in the longitudinal direction. FIG. 6 (B) shows a mode in which a pair of the shift preventing adhesive portions 7 continuous in the longitudinal direction are arranged along both sides in the longitudinal direction of the central absorbent sheet 32. In both FIGS. 6A and 6B, the anti-slip adhesion portion 7 is disposed so as not to overlap the central region in the width direction of the central absorbent sheet 32. FIG. 6C shows a mode in which a plurality of anti-slip adhesion portions 7 are arranged in parallel in the width direction of the central absorbent sheet 32. FIG. 6D shows a mode in which a plurality of anti-slip adhesion portions 7 are arranged in parallel in the longitudinal direction of the central absorbent sheet 32.
 ズレ止粘着部7と中央吸収性シート32との重なりを、上記配置面積の35%以下とし、ズレ止粘着部7を中央吸収性シート32の中間部Cにおける幅方向中央領域と重ならないように配置する構成とすることにより、中央吸収性シート32とズレ止粘着部7の平面視における重なり部が十分に少なくなり、最も体圧のかかる幅方向中央領域の領域にズレ止粘着部7が存在しないことにより冷感剤がズレ止め粘着部に与える影響をより効果的に低減することができる。 The overlap between the anti-slip adhesive portion 7 and the central absorbent sheet 32 is 35% or less of the above-mentioned arrangement area so that the anti-slip adhesive portion 7 does not overlap with the central region in the width direction of the middle portion C of the central absorbent sheet 32 By arranging it, the overlapping portion of the central absorbent sheet 32 and the anti-slip portion 7 in plan view is sufficiently reduced, and the anti-slip portion 7 is present in the region of the central region in the width direction where body pressure is most applied. By not carrying out, the influence which a cooling agent has on a gap stop adhesion part can be reduced more effectively.
 吸収性物品がサイドシート5を備える場合、サイドシート5は、表面層1の肌当接面側の両側に積層されていることが好ましい。サイドシート5は表面層1よりも通気性が小さいことがより好ましい。 When the absorbent article includes the side sheet 5, the side sheet 5 is preferably laminated on both sides of the skin contact surface side of the surface layer 1. It is more preferable that the side sheet 5 has lower air permeability than the surface layer 1.
 ナプキン10を構成する部材の形成材料は、この種の物品に用いられるものを特に制限なく用いることができる。 What is used for the article of this kind can be used without particular limitation as a forming material of the member constituting the napkin 10.
 冷感剤としては、着用者の皮膚及び/又は粘膜表面の温度受容器を刺激して、皮膚及び/又は粘膜表面上の温度を変化させることなしに、着用者に爽快感を伝えることのできる種々の剤を用いることができる。例えば、シクロヘキシル誘導体、シクロヘキサノール誘導体、カルボキサミド類など、特開2015-12918号公報の段落[0006]~[0086]に記載のものが挙げられる。シクロヘキシル誘導体としては、 乳酸メンチル、メンチルエチルアミノシュウ酸、3-(l-メントキシ)プロパン-1,2-ジオール、3-(l-メントキシ)-2-メチルプロパン-1,2-ジオール、コハク酸メンチル、3-(l-メントキシ)エタン-1-オール、3-(l-メントキシ)プロパン-1-オール、3-(l-メントキシ)ブタン-1-オール、l-メンチル-4-ヒドロキシペンタノエート、l-メンチル-3-ヒドロキシブチレート等が挙げられる。シクロヘキサノール誘導体としては、メントール、p-メンタン-3,8-ジオール、イソプレゴール等が挙げられる。カルボキサミド類としては、N-エチル-p-メンタン-3-カルボキサミド(N-エチル-2-イソプロピル-5-メチルシクロヘキサン-1-カルボキサミド)、N,2,3-トリメチル-2-(l-メチルエチル)-ブタンアミド、l-メンチル酢酸N-エチルアミド等が挙げられる。これらは1種を用いてもよく、2種以上を組合せて用いてもよい。
 その中でも、匂いによる爽快感と速効性、持続性の観点から、水不溶性又は水難溶性の冷感剤が好ましい。水不溶性又は水難溶性の冷感剤は体液とともに非肌面側へ移行しにくいことから、冷感は持続しやすい。水不溶性のものとしては、乳酸メンチル、メントールが好ましい。ここで言う「水不溶性又は水難溶性」とは、25℃の水1Lに対して1g以下の溶解性であることを言い、特に「水不溶性」は25℃の水1Lに対して0.1g以下の溶解性であることを言う。
 冷感剤は、種々の方法によってナプキン10に含ませることができる。例えば、溶媒に溶解させた状態でナプキン10に含ませてもよく、溶媒を用いずに含ませてもよい。また冷感剤はマイクロカプセルに包むなどデリバリー手段を伴ってナプキン10に含ませてもよい。
As a cooling agent, it can stimulate the wearer's skin and / or mucous membrane surface thermoreceptor to convey a feeling of exhilaration to the wearer without changing the temperature on the skin and / or mucous membrane surface Various agents can be used. Examples thereof include cyclohexyl derivatives, cyclohexanol derivatives, carboxamides and the like, as described in paragraphs [0006] to [0086] of JP-A-2015-12918. Examples of cyclohexyl derivatives include menthyl lactate, menthylethylaminooxalic acid, 3- (l-menthoxy) propane-1,2-diol, 3- (l-menthoxy) -2-methylpropane-1,2-diol, and succinic acid. Menthyl, 3- (l-menthoxy) ethan-1-ol, 3- (l-menthoxy) propan-1-ol, 3- (l-menthoxy) butan-1-ol, 1-menthyl-4-hydroxypentano And alt, l-menthyl 3-hydroxybutyrate and the like. Examples of cyclohexanol derivatives include menthol, p-menthan-3,8-diol, isopulegol and the like. As carboxamides, N-ethyl-p-menthane-3-carboxamide (N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide), N, 2,3-trimethyl-2- (l-methylethyl) And L) -butanamide, 1-menthylacetic acid N-ethylamide and the like. One of these may be used, or two or more of them may be used in combination.
Among them, a water-insoluble or poorly water-soluble cooling agent is preferable from the viewpoint of refreshing feeling due to odor, quick action, and sustainability. Since the water-insoluble or poorly water-soluble cooling agent hardly migrates to the non-skin side with the body fluid, the cold feeling tends to be sustained. As water-insoluble substances, menthyl lactate and menthol are preferable. The term "water-insoluble or poorly water-soluble" as used herein means that the solubility is 1 g or less in 1 L of water at 25 ° C, and particularly "water-insoluble" is 0.1 g or less in 1 L of water at 25 ° C Say that it is soluble in water.
A cooling agent can be contained in the napkin 10 by various methods. For example, they may be contained in the napkin 10 in a state of being dissolved in a solvent, or may be contained without using a solvent. In addition, the cooling agent may be contained in the napkin 10 together with a delivery means such as encapsulation in microcapsules.
 冷感剤としては、特に、メントール及び乳酸メンチルを含むことが、冷感効果を着用後素早く感じられると共に穏やかなものとし、持続性を高めることから好ましい。同様の観点から、メントールと乳酸メンチルの含有量は、前者/後者の質量比で、0.01以上が好ましく、更に0.02以上が好ましく、また、0.2以下が好ましく、更に0.15以下が好ましい。 As a cooling agent, in particular, it is preferable to include menthol and menthyl lactate because the cooling effect can be felt quickly and gently after wearing, and the durability can be enhanced. From the same viewpoint, the content ratio of menthol and menthyl lactate is preferably 0.01 or more, more preferably 0.02 or more, and further preferably 0.2 or less, in the mass ratio of the former / the latter. The following are preferred.
 抗菌剤としては、吸収性物品の分野に通常使用されるものを使用することができる。 As the antibacterial agent, those usually used in the field of absorbent articles can be used.
 吸収性シートを構成する親水性繊維としては、疎水性の繊維を親水化処理したもの、それ自体が親水性であるものが挙げられる。特に、それ自体が親水性でかつ保水性を有するものが好ましい。後者の親水性繊維としては、天然系の繊維、セルロース系の再生繊維又は半合成繊維が好ましい例として挙げられる。親水性繊維としては、特にパルプ、レーヨンが好ましく、パルプが一層好ましい。さらにセルロース繊維の分子内及び/又は分子間を架橋させた架橋セルロース繊維や木材パルプをマーセル化処理して得られるような嵩高性のセルロース繊維を用いてもよい。パルプとしては、針葉樹クラフトパルプ或いは広葉樹クラフトパルプのような木材パルプ、木綿パルプ或いはワラパルプ等の天然セルロース繊維等が挙げられるが、それらに限定されるものではない。これらのパルプは1種又は2種以上を用いることができる。 As a hydrophilic fiber which comprises an absorptive sheet, what carried out the hydrophilization treatment of the hydrophobic fiber, and the thing which itself is hydrophilic are mentioned. In particular, those which themselves are hydrophilic and have water retention are preferred. As the latter hydrophilic fibers, natural fibers, regenerated cellulose fibers or semi-synthetic fibers are mentioned as preferable examples. As the hydrophilic fiber, in particular, pulp and rayon are preferable, and pulp is more preferable. Further, crosslinked cellulose fibers obtained by crosslinking the intramolecular and / or intermolecular of cellulose fibers or bulky cellulose fibers obtained by mercerizing wood pulp may be used. Examples of the pulp include wood pulp such as softwood kraft pulp and hardwood kraft pulp, and natural cellulose fibers such as cotton pulp and straw pulp, but not limited thereto. These pulps can be used alone or in combination of two or more.
 吸収性シートを構成する高吸収性ポリマー材としては、例えば、アクリル酸又はアクリル酸塩を主成分とし、場合によって架橋剤を添加してなる水溶性のエチレン性不飽和モノマーを重合させて得られるヒドロゲル材料が挙げられる。また、ポリエチレンオキサイド、ポリビニルピロリドン、スルホン化ポリスチレン及びポリビニルピリジンの架橋物、デンプン-ポリ(メタ)アクリロニトリルグラフト共重合物のケン化物、デンプン-ポリ(メタ)アクリル酸グラフト共重合物、デンプン-ポリ(メタ)アクリルエステルグラフト共重合物の加水分解物などが挙げられる。これらの吸水性ポリマー材は1種を単独で、又は2種以上を組み合わせて用いることができる。高吸収性ポリマー材としては、自重の20倍以上の液を吸収・保持できゲル化し得るものが好ましい。
 高吸収性ポリマー材の形状は、吸収層に用いられる種々ものを特に制限なく用いることができる。例えば、球状、粒状、繊維状、俵状、塊状などが挙げられる。
The superabsorbent polymer material constituting the absorbent sheet can be obtained, for example, by polymerizing a water-soluble ethylenically unsaturated monomer which is mainly composed of acrylic acid or acrylate and optionally added with a crosslinking agent. Hydrogel materials are included. Also, polyethylene oxide, polyvinyl pyrrolidone, crosslinked products of sulfonated polystyrene and polyvinyl pyridine, saponified starch-poly (meth) acrylonitrile graft copolymer, starch-poly (meth) acrylic acid graft copolymer, starch-poly ( The hydrolyzate of a (meth) acrylic ester graft copolymer etc. are mentioned. These water-absorbing polymer materials can be used alone or in combination of two or more. As the superabsorbent polymer material, a material capable of absorbing and retaining 20 times or more of its own weight and capable of gelation is preferable.
As the shape of the superabsorbent polymer material, various materials used for the absorbent layer can be used without particular limitation. For example, spherical shape, granular shape, fibrous shape, bowl shape, lump shape etc. are mentioned.
 表面層1は、液透過性を有する種々のものを用いることができる。肌触りの良さを考慮すると、親水性の不織布が好ましく、サーマルボンド不織布がより好ましく、エアスルー不織布が特に好ましい。親水化処理された熱可塑性樹脂繊維であり、かつ、該繊維が2次クリンプ又は3次クリンプのような立体捲縮がなされた繊維であることが好ましい。具体的には、ポリエチレン、ポリプロピレン、ポリエステル、ナイロン、及びこれらの複合繊維を作成し、所定の長さにカットしてステープルを形成する前の段階で、各種親水化剤を塗工する。親水化剤としては、αオレフィンスルホン酸塩に代表される各種アルキルスルホン酸塩、アクリル酸塩、アクリル酸塩/アクリルアミド共重合体、エステルアミド、エステルアミドの塩、ポリエチレングリコール及びその誘導物、水溶性ポリエステル樹脂、各種シリコーン誘導物、各種糖類誘導物、及びこれらの混合物など、通常用いられる親水化剤による親水化処理を用いることができる。 The surface layer 1 can use various materials having liquid permeability. In consideration of the goodness of the touch, a hydrophilic non-woven fabric is preferable, a thermal bond non-woven fabric is more preferable, and an air-through non-woven fabric is particularly preferable. It is preferable that it is a thermoplastic resin fiber subjected to hydrophilization treatment, and the fiber is a fiber subjected to a three-dimensional crimp such as a secondary crimp or a tertiary crimp. Specifically, polyethylene, polypropylene, polyester, nylon, and composite fibers thereof are prepared, and various hydrophilicizing agents are applied before cutting into a predetermined length to form staples. As the hydrophilizing agent, various alkyl sulfonates represented by α-olefin sulfonate, acrylate, acrylate / acrylamide copolymer, ester amide, ester amide salt, polyethylene glycol and derivatives thereof, water-soluble Hydrophilization treatment with a commonly used hydrophilizing agent can be used, such as polyester resin, various silicone derivatives, various saccharide derivatives, and mixtures thereof.
 裏面層2としては、防漏性を有する種々のものを用いることができる。例えば、非透湿性若しくは透湿性フィルム単独、又はフィルムと不織布とを貼り合わせたもの、撥水性の不織布(SMSやSMMS等)を用いることができる。コスト面やズレ止め粘着剤とのマッチングなどから、非透湿性フィルム単独を防漏材として用いることが最も好ましい。  As the back surface layer 2, various materials having leak resistance can be used. For example, a non-moisture permeable or moisture-permeable film alone, or a combination of a film and a non-woven fabric, or a water-repellent non-woven fabric (SMS, SMMS, etc.) can be used. It is most preferable to use a non-moisture-permeable film alone as the leak-proof material from the viewpoint of cost and matching with the anti-slip adhesive.
 液拡散層4としては、親水性を有し液拡散性に優れているものが好ましい。熱可塑性繊維を含む不織布などが挙げられる。不織布としては、各種の製法によって得られた不織布を用いることができる。例えば、カード法又はエアレイド法により得た繊維ウエブにエアスルー法で繊維どうしの熱融着点を形成したエアスルー不織布、カード法により得た繊維ウエブにヒートロール法で繊維同士の熱融着点を形成したヒートロール不織布、ヒートエンボス不織布、スパンレース不織布、ニードルパンチ不織布、レジンボンド不織布等の種々の不織布を用いることができる。 The liquid diffusion layer 4 is preferably one having hydrophilicity and excellent in liquid diffusibility. Non-woven fabrics containing thermoplastic fibers can be mentioned. As the non-woven fabric, non-woven fabrics obtained by various manufacturing methods can be used. For example, an air through non-woven fabric in which heat fusion points of fibers are formed by air through method on fiber web obtained by card method or air laid method, heat fusion point of fibers is formed by heat roll method on fiber web obtained by card method Various non-woven fabrics such as heat-roll non-woven fabric, heat-embossed non-woven fabric, spunlace non-woven fabric, needle punched non-woven fabric, resin-bonded non-woven fabric, etc. can be used.
 サイドシート5としては、撥水性の不織布が好ましく、カード法により製造された不織布、スパンボンド不織布、メルトブローン不織布、スパンレース不織布、ヒートロール不織布、ニードルパンチ不織布等の中から撥水性の物、又は撥水処理した種々の不織布を用いることができる。特に好ましくは、例えば、スパンボンド不織布、スパンボンド-メルトブローン(SM)不織布、スパンボンド-メルトブローン-スパンボンド(SMS)不織布等が用いられる。 The side sheet 5 is preferably a water repellent non-woven fabric, and non-woven fabric manufactured by the card method, spun bonded non-woven fabric, meltblown non-woven fabric, spun lace non-woven fabric, heat roll non-woven fabric, needle punched non-woven fabric etc. Various non-woven fabrics treated with water can be used. Particularly preferably, for example, a spunbond nonwoven fabric, a spunbond-meltblown (SM) nonwoven fabric, a spunbond-meltblown-spunbond (SMS) nonwoven fabric and the like are used.
 本発明の吸収性物品は、上記の実施形態の生理用ナプキンに制限されるものではなく、例えばパンティライナー、失禁パッド、尿とりパッド、使い捨ておむつ等に適応することができる。また、経血に限らずその他、尿、オリモノ、軟便等に対しても効果的である。また、上記構成部材の他、用途や機能に合わせ適宜部材を組み込んでもよい。 The absorbent article of the present invention is not limited to the sanitary napkin of the above embodiment, and can be applied to, for example, panty liners, incontinence pads, urine collecting pads, disposable diapers and the like. Moreover, it is effective not only to menstrual blood but also to other things such as urine, orimono, soft stools and the like. In addition to the components described above, members may be incorporated appropriately in accordance with the application and function.
 また、本発明の吸収性物品は、生理用ナプキンやパンティライナーなど1製品毎にカバンなどに入れて持ち運びされる物である場合、個包装されていることが好ましい。具体的には、表面層が内側になるよう縦方向に折り畳まれて、個包装用の外包材によって包まれた吸収性物品個包装体とされていることが好ましい。個包装体とすることで、肌に触れる表面層(使用面)の衛生を守りつつ、携帯性の高い物品することこができ、使用者の利便性を高めることができる。 When the absorbent article of the present invention is a product such as a sanitary napkin or a panty liner which is carried in a bag for each product, it is preferable to be individually packaged. Specifically, it is preferable that the absorbent article packaging body is longitudinally folded so that the surface layer is inside, and is wrapped by the outer wrapping material for individual wrapping. By using the individual package, it is possible to make the article highly portable while protecting the hygiene of the surface layer (use side) that touches the skin, and it is possible to enhance the convenience of the user.
 次に、本発明の吸収性物品に用いる吸収層の好ましい製造方法、本発明の吸収性物品の好ましい製造方法について説明する。
 吸収層3の好ましい製造方法としては、通常用いられる吸収性物品の製造方法の中で、次の工程を有する。
 すなわち、中央吸収性シート32に冷感剤を塗布する工程(S1)と、前記中央吸収性シート32の肌側面及び非肌側面を外包吸収性シート31で挟む工程(S2)、及び中央吸収性シート32と外包吸収性シート31との平面視重なる領域において、少なくとも肌面側に連通部8を形成する工程(S3)とを備える。
Next, the preferable manufacturing method of the absorbent layer used for the absorbent article of this invention, and the preferable manufacturing method of the absorbent article of this invention are demonstrated.
A preferred method for producing the absorbent layer 3 includes the following steps among commonly used methods for producing an absorbent article.
That is, the step (S1) of applying a cooling agent to the central absorbent sheet 32, the step (S2) of sandwiching the skin side and the non-skin side of the central absorbent sheet 32 with the outer cover absorbent sheet 31, and central absorbent And a step (S3) of forming the communicating portion 8 at least on the skin surface side in a region where the sheet 32 and the outer wrapping absorbent sheet 31 overlap in plan view.
 吸収層3の製造方法において、中央吸収性シート32及び外包吸収性シート31が折り畳まれずに工程(S2)において積層されてもよく、両シートのいずれか一方又は両方が折り畳まれて積層されてもよい。中央吸収性シート32及び外包吸収性シート31が折り畳まれる場合は、折り畳まれることを想定して吸収層の幅よりも幅広のものを用いる。工程(S1)の冷感剤の塗布は、中央吸収性シート32が折り畳まれることを想定して適宜位置決めして行われる。 In the method of manufacturing the absorbent layer 3, the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 may be laminated in the step (S2) without being folded, even if one or both of the both sheets are folded and laminated. Good. When the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 are folded, a sheet wider than the width of the absorbent layer is used on the assumption that the central absorbent sheet 32 and the outer wrapping absorbent sheet 31 are folded. The application of the cooling agent in the step (S1) is appropriately performed by assuming that the central absorbent sheet 32 is folded.
 工程(S1)において、冷感剤を塗布する幅は、前述した吸収層3(吸収体)の幅方向両端縁39よりも内側となる領域であることが好ましい。吸収層3の幅に対して例えば75%以下の範囲となる領域がより好ましく、70%以下の範囲となる領域がさらに好ましい。冷感剤は前述のとおり、溶媒を混合した冷感剤含有塗布液として調製し、塗布することが好ましい。溶媒としては、通常用いるものを用いることができる。例えば、ジプロピレングリコールなどが挙げられる。
 工程(S2)において、中央吸収性シート32を折り畳んだ後に外包吸収性シート31で挟む工程を行うことが好ましい。また、中央吸収性シート32が、ポリマーリッチ領域35と繊維リッチ領域36を有する場合には、中央吸収性シート32を繊維リッチ領域36を外側にして折り畳んだ後に、外包吸収性シート31で挟むことがより好ましい。
In the step (S1), the width to which the cooling agent is applied is preferably a region which is inside the widthwise end edges 39 of the absorbent layer 3 (absorbent body) described above. For example, a region having a range of 75% or less with respect to the width of the absorbing layer 3 is more preferable, and a region having a range of 70% or less is further preferable. As described above, the cooling agent is preferably prepared and applied as a cooling agent-containing coating solution in which a solvent is mixed. As the solvent, those usually used can be used. For example, dipropylene glycol and the like can be mentioned.
In the step (S2), it is preferable to perform the step of sandwiching the central absorbent sheet 32 with the outer wrapping absorbent sheet 31 after folding. When the central absorbent sheet 32 has the polymer rich area 35 and the fiber rich area 36, the central absorbent sheet 32 is folded with the fiber rich area 36 outside and then sandwiched by the outer absorbent sheet 31. Is more preferred.
 工程(S3)の連通部8は、面方向に分散配置して設ける。吸収性シートに設ける連通部8は、図3に示すように、吸収層の縦方向に延びる長さを有して、該縦方向に複数配列されることが好ましく、連通部8の縦方向の配列を吸収層の幅方向に複数配列することがより好ましい。連通部8の形成は、連通部8の形態に応じてこの種の物品に用いられる種々の方法によって行うことができる。
 例えば、連通部8がスリット部である場合、ロール周面に、周方向に延びる切断刃が、ロール周方向及びロール軸方向に分散配置されたカッターロールと、対応配置されるアンビルロールとを備えた切断装置を用いて切り込みを形成することができる(図示せず)。前記切断刃は、切り込み(スリット部)の縦方向の長さに対応する周方向の長さを有する。この切断刃は、ロール周面において、切り込み(スリット部)の所望の配置に対応して分散配置される。また、切り込みの深さは、カッターロールとアンビルロールとのクリアランスや切断刃の大きさ等によって設定することができる。また連通部8が、部材の一部が切り欠かれた凹部空間である場合、上記のロールの切断刃の設定を変更するなどして形成することができる。また、連通部8が、部材の一部が押圧されて窪んだ凹部空間(圧搾部)である場合、種々のエンボス処理によって形成することができる。
The communicating portions 8 in the step (S3) are provided in a distributed manner in the surface direction. As shown in FIG. 3, it is preferable that a plurality of communicating portions 8 provided in the absorbent sheet have a length extending in the longitudinal direction of the absorbent layer, and a plurality of the communicating portions 8 be arranged in the longitudinal direction. It is more preferable to arrange multiple arrays in the width direction of the absorbing layer. The formation of the communicating portion 8 can be performed by various methods used for this kind of article depending on the form of the communicating portion 8.
For example, when the communication portion 8 is a slit portion, a cutting blade extending in the circumferential direction on the roll circumferential surface is provided with a cutter roll distributed and arranged in the roll circumferential direction and the roll axis direction, and an anvil roll correspondingly disposed. The cutting device can be used to form cuts (not shown). The cutting blade has a circumferential length corresponding to the longitudinal length of the cut (slit portion). The cutting blades are distributed at the peripheral surface of the roll in correspondence with the desired arrangement of the notches (slits). Further, the depth of the cut can be set by the clearance between the cutter roll and the anvil roll, the size of the cutting blade, and the like. Moreover, when the communication part 8 is the recessed space which a part of member cut away, it can change the setting of the cutting blade of said roll, etc., and can form. Moreover, when the communication part 8 is the recessed space (pressing part) which a part of member was pressed down and was dented, it can form by various embossing processes.
 工程(S3)において、連通部8を形成する領域の幅は、冷感剤塗布幅よりも広く、かつ、前述した吸収層3の幅方向両端縁39よりも内側となる領域であることが好ましい。吸収層3の幅に対して例えば85%以下の範囲となる領域であることがより好ましい。 In the step (S3), the width of the region forming the communication portion 8 is preferably a region which is wider than the cooling agent application width and which is inside the width direction both end edges 39 of the absorbent layer 3 described above. . It is more preferable that the region be in a range of, for example, 85% or less with respect to the width of the absorption layer 3.
 吸収層3の製造方法としては、工程(C1)及び(C2)の後に前記工程(C3)を行うことが好ましい。 As a manufacturing method of the absorption layer 3, it is preferable to perform the said process (C3) after process (C1) and (C2).
 本発明の吸収性物品の製造方法は、上記の製造方法により得られた吸収層3を用いて行う以下の工程を有していることが好ましい。
(S4)吸収層3を、表面層1と裏面層2との間に配する工程
(S5)裏面層2の非肌側面にズレ止粘着部7を配する工程
 工程(S4)においては、上記のようにして得られた吸収層3の両面に、所定の大きさに裁断された表面層1及び裏面層2を積層し接合する。その際、必要により液拡散層4、サイドシート5を所定の大きさ及び形状に成形して積層してもよい。また防漏溝など種々の圧搾処理を施してもよい。
 次いで、必要により工程(S5)を行う。工程(S5)においては、裏面層2を設けた後に、ズレ止粘着部7を配する。その場合、ズレ止粘着部7と中央吸収性シート32との平面視における重なり部分を、中央吸収性シート32の配置面積の35%以下とし、中央吸収性シート32の中間部Cにおける幅方向中央領域が前記ズレ止粘着部と重ならないように配置するようにすることが好ましい。
It is preferable that the manufacturing method of the absorbent article of this invention has the following processes performed using the absorption layer 3 obtained by said manufacturing method.
(S4) Step of disposing the absorbing layer 3 between the surface layer 1 and the back layer 2 (S5) step of disposing the anti-slip portion 7 on the non-skin side of the back layer 2 In the step (S4), The front surface layer 1 and the back surface layer 2 which are cut into a predetermined size are laminated and bonded on both surfaces of the absorbent layer 3 obtained as described above. At that time, if necessary, the liquid diffusion layer 4 and the side sheet 5 may be formed into a predetermined size and shape and laminated. In addition, various squeezing treatments such as leak prevention grooves may be performed.
Next, step (S5) is performed as necessary. In the step (S5), after providing the back surface layer 2, the anti-displacement portion 7 is disposed. In that case, the overlapping portion of the anti-slip portion 7 and the central absorbent sheet 32 in plan view is 35% or less of the arrangement area of the central absorbent sheet 32, and the widthwise center of the central portion C of the central absorbent sheet 32 It is preferable to arrange the area so as not to overlap with the anti-slip portion.
 上述した実施形態に関し、本発明はさらに以下の吸収性物品及び吸収性物品の製造方法を開示する。 With respect to the embodiments described above, the present invention further discloses the following absorbent article and method of manufacturing the absorbent article.
<1>
 表面層、裏面層、及び前記表面層と前記裏面層との間に配された吸収層を備え、着用者の腹側部、股下部及び背側部を繋ぐ方向に対応する縦方向と、該縦方向と直交する幅方向とを有し、該縦方向に沿って、前方部、後方部、及び該前方部と後方部の間に位置し、排泄ポイントに対応する領域を含む中間部を有する吸収性物品であって、前記吸収層は、冷感剤を含有する中央吸収性シートと、該中央吸収性シートの肌面側及び非肌面側に配された外包吸収性シートとを、層状に重ねてなり、前記吸収層は、前記中央吸収性シートと前記外包吸収性シートとの平面視重なる領域において、少なくとも肌面側に連通部を有する、吸収性物品。
<2>
 前記中央吸収性シートは、高吸収性ポリマー材と親水性繊維とを含み、断面視において、前記高吸収性ポリマー材の質量と前記親水性繊維の質量との合計質量における前記高吸収性ポリマー材の質量比率が相対的に高いポリマーリッチ領域と、前記質量比率が前記ポリマーリッチ領域に対し相対的に低い繊維リッチ領域とを有しており、前記ポリマーリッチ領域に前記冷感剤が含まれており、前記繊維リッチ領域を外面側にして折り畳まれている、前記<1>に記載の吸収性物品。
<3>
 前記中央吸収性シートが前記吸収性物品の前記中間部に配置され、前記連通部が厚さ方向につながる連通孔である、前記<1>又は<2>に記載の吸収性物品。
<4>
 前記連通孔の一方向の長さが非肌面より肌面側において広い、前記<3>に記載の吸収性物品。
<5>
 前記連通孔が切り込みによるスリット部である、前記<3>又は<4>に記載の吸収性物品。
<6>
 前記裏面層の非肌面側にズレ止粘着部が配されており、該ズレ止粘着部と前記中央吸収性シートとの平面視における重なり部分は、前記中央吸収性シートの配置面積の35%以下であり、該中央吸収性シートの前記中間部における幅方向中央領域が前記ズレ止粘着部と重ならない、前記<1>~<5>のいずれか1に記載の吸収性物品。
<7>
 前記冷感剤は、水不溶性又は水難溶性の剤である、前記<1>~<6>のいずれか1に記載の吸収性物品。
<8>
前記冷感剤として乳酸メンチルを含む、前記<7>に記載の吸収性物品。
<9>
 前記冷感剤としてメントールを含む、前記<8>に記載の吸収性物品。
<10>
 前記メントールと乳酸メンチルの質量比が、前者/後者として、0.01以上、0.2以下である、前記<9>に記載の吸収性物品。
<11>
 前記表面層の肌当接面側の両側に、該表面層より通気性が小さいサイドシートが積層されている前記<1>~<10>のいずれか1に記載の吸収性物品。
<12>
 前記吸収層の幅方向外方に延出したウイング部を備えている前記<1>~<11>のいずれか1に記載の吸収性物品。
<13>
 生理用ナプキンである、前記<1>~<12>のいずれか1に記載の吸収性物品。
<14>
 中央吸収性シートに冷感剤を塗布する工程(S1)と、前記中央吸収性シートの肌側面及び非肌側面を外包吸収性シートで挟む工程(S2)と、前記中央吸収性シートと前記外包吸収性シートとの平面視重なる領域において、少なくとも肌面側に連通部を形成する工程(S3)と、を備える吸収層の製造方法。
<15>
 前記工程(S1)及び(S2)の後に前記工程(S3)を行う、前記<14>に記載の吸収層の製造方法。
<16>
 前記<15>に記載の製造方法により得られた吸収層を、表面層と裏面層との間に配する工程を備える吸収性物品の製造方法。
<17>
 前記裏面層の非肌側面にズレ止粘着部を配する工程を備えており、前記ズレ止粘着部と前記中央吸収性シートとの平面視における重なり部分を、前記中央吸収性シートの配置面積の35%以下であり、該中央吸収性シートの中間部における、前記縦方向と直交する幅方向中央領域が前記ズレ止粘着部と重ならないようになす、前記<16>に記載の吸収性物品の製造方法。
<1>
A longitudinal direction corresponding to a direction connecting a belly side, a crotch and a dorsal side of a wearer, comprising a front layer, a back layer, and an absorbent layer disposed between the front layer and the back layer; It has a width direction orthogonal to the longitudinal direction, and has a front portion, a rear portion, and an intermediate portion located between the front and rear portions and including a region corresponding to a discharge point along the longitudinal direction. An absorbent article, wherein the absorbent layer includes a central absorbent sheet containing a cooling agent, and an envelope absorbent sheet disposed on the skin side and the non-skin side of the central absorbent sheet. An absorbent article, wherein the absorbent layer has a communicating portion at least on the skin surface side in a region where the central absorbent sheet and the outer wrapping absorbent sheet overlap in plan view.
<2>
The central absorbent sheet includes a superabsorbent polymer material and a hydrophilic fiber, and in cross section, the superabsorbent polymer material in the total mass of the mass of the superabsorbent polymer material and the mass of the hydrophilic fiber A polymer-rich region having a relatively high mass ratio, and a fiber-rich region having a relatively low mass ratio relative to the polymer-rich region, wherein the polymer-rich region includes the cooling agent. The absorbent article according to <1>, which is folded with the fiber-rich region on the outer surface side.
<3>
The absorbent article according to <1> or <2>, wherein the central absorbent sheet is disposed in the middle part of the absorbent article, and the communication part is a communication hole connected in a thickness direction.
<4>
The absorbent article according to <3>, wherein a length in one direction of the communication hole is wider on the skin surface side than on a non-skin surface.
<5>
The absorbent article as described in said <3> or <4> whose said communicating hole is a slit part by a cut | notch.
<6>
The anti-slip adhesion portion is disposed on the non-skin surface side of the back surface layer, and the overlapping portion of the anti-slip adhesion portion and the central absorbent sheet in a plan view is 35% of the arrangement area of the central absorbent sheet The absorbent article according to any one of <1> to <5>, in which the widthwise center region of the middle portion of the center absorbent sheet does not overlap the anti-slip portion.
<7>
The absorbent article according to any one of <1> to <6>, wherein the cooling agent is a water-insoluble or poorly water-soluble agent.
<8>
The absorbent article as described in said <7> which contains a menthyl lactate as said cooling agent.
<9>
The absorbent article as described in said <8> which contains menthol as said cooling agent.
<10>
The absorbent article as described in said <9> whose mass ratio of the said menthol and menthyl lactate is 0.01 or more and 0.2 or less as the former / latter.
<11>
The absorbent article according to any one of <1> to <10>, wherein a side sheet having air permeability smaller than that of the surface layer is laminated on both sides of the skin contact surface side of the surface layer.
<12>
The absorbent article according to any one of <1> to <11>, including a wing portion extended outward in the width direction of the absorbent layer.
<13>
The absorbent article according to any one of the above <1> to <12>, which is a sanitary napkin.
<14>
A step (S1) of applying a cooling agent to a central absorbent sheet, a step (S2) of sandwiching the skin side and the non-skin side of the central absorbent sheet with an outer shell absorbent sheet, the central absorbent sheet and the outer shell Forming a communicating portion at least on the skin surface side in a region overlapping in plan view with the absorbent sheet (S3).
<15>
The manufacturing method of the absorption layer as described in said <14> which performs said process (S3) after said process (S1) and (S2).
<16>
The manufacturing method of the absorbent article provided with the process of arranging the absorption layer obtained by the manufacturing method as described in said <15> between a surface layer and a back surface layer.
<17>
And a step of arranging the anti-slip portion on the non-skin side of the back layer, wherein the overlapping portion of the anti-slip portion and the central absorbent sheet in plan view corresponds to the arrangement area of the central absorbent sheet. The absorbent article according to <16>, wherein the width is not more than 35%, and the width direction central region perpendicular to the longitudinal direction in the middle portion of the central absorbent sheet does not overlap with the anti-slip portion. Production method.
 本発明をその実施形態および実施例とともに説明したが、我々は特に指定しない限り我々の発明を説明のどの細部においても限定しようとするものではなく、添付の請求の範囲に示した発明の精神と範囲に反することなく幅広く解釈されるべきであると考える。 While the present invention has been described in conjunction with its embodiments and examples, it is not intended to limit our invention in any detail of the description unless otherwise specified, and the spirit of the invention as set forth in the appended claims. We believe that it should be interpreted broadly without violating the scope.
 本願は、2017年11月8日に日本国で特許出願された特願2017-215614に基づく優先権を主張するものであり、これらはここに参照してその内容を本明細書の記載の一部として取り込む。 The present application claims priority based on Japanese Patent Application No. 2017-215614 filed in Japan on November 8, 2017, which is incorporated herein by reference in its entirety. Capture as part.
1 表面層
2 裏面層
3 吸収層
4 液拡散層
5 サイドシート
6 ウイング部
7 ズレ止粘着部
8 連通部
10 生理用ナプキン
DESCRIPTION OF SYMBOLS 1 surface layer 2 back layer 3 absorption layer 4 liquid diffusion layer 5 side sheet 6 wing part 7 shift | offset | difference adhesive part 8 communication part 10 sanitary napkin

Claims (17)

  1.  表面層、裏面層、及び前記表面層と前記裏面層との間に配された吸収層を備え、着用者の腹側部、股下部及び背側部を繋ぐ方向に対応する縦方向と、該縦方向と直交する幅方向とを有し、該縦方向に沿って、前方部、後方部、及び該前方部と後方部の間に位置し、排泄ポイントに対応する領域を含む中間部を有する吸収性物品であって、前記吸収層は、冷感剤を含有する中央吸収性シートと、該中央吸収性シートの肌面側及び非肌面側に配された外包吸収性シートとを、層状に重ねてなり、前記吸収層は、前記中央吸収性シートと前記外包吸収性シートとの平面視重なる領域において、少なくとも肌面側に連通部を有する、吸収性物品。 A longitudinal direction corresponding to a direction connecting a belly side, a crotch and a dorsal side of a wearer, comprising a front layer, a back layer, and an absorbent layer disposed between the front layer and the back layer; It has a width direction orthogonal to the longitudinal direction, and has a front portion, a rear portion, and an intermediate portion located between the front and rear portions and including a region corresponding to a discharge point along the longitudinal direction. An absorbent article, wherein the absorbent layer includes a central absorbent sheet containing a cooling agent, and an envelope absorbent sheet disposed on the skin side and the non-skin side of the central absorbent sheet. An absorbent article, wherein the absorbent layer has a communicating portion at least on the skin surface side in a region where the central absorbent sheet and the outer wrapping absorbent sheet overlap in plan view.
  2.  前記中央吸収性シートは、高吸収性ポリマー材と親水性繊維とを含み、断面視において、前記高吸収性ポリマー材の質量と前記親水性繊維の質量との合計質量における前記高吸収性ポリマー材の質量比率が相対的に高いポリマーリッチ領域と、前記質量比率が前記ポリマーリッチ領域に対し相対的に低い繊維リッチ領域とを有しており、前記ポリマーリッチ領域に前記冷感剤が含まれており、前記繊維リッチ領域を外面側にして折り畳まれている、請求項1に記載の吸収性物品。 The central absorbent sheet includes a superabsorbent polymer material and a hydrophilic fiber, and in cross section, the superabsorbent polymer material in the total mass of the mass of the superabsorbent polymer material and the mass of the hydrophilic fiber A polymer-rich region having a relatively high mass ratio, and a fiber-rich region having a relatively low mass ratio relative to the polymer-rich region, wherein the polymer-rich region includes the cooling agent. The absorbent article according to claim 1, which is folded with the fiber-rich region on the outer surface side.
  3.  前記中央吸収性シートが前記吸収性物品の前記中間部に配置され、前記連通部が厚さ方向につながる連通孔である、請求項1又は2に記載の吸収性物品。 The absorbent article according to claim 1 or 2, wherein the central absorbent sheet is disposed in the middle portion of the absorbent article, and the communication portion is a communication hole connecting in a thickness direction.
  4.  前記連通孔の一方向の長さが非肌面より肌面側において広い、請求項3に記載の吸収性物品。 The absorbent article according to claim 3, wherein a length in one direction of the communication hole is wider on a skin surface side than a non-skin surface.
  5.  前記連通孔が切り込みによるスリット部である、請求項3又は4に記載の吸収性物品。 The absorbent article according to claim 3 or 4, wherein the communication hole is a slit portion by cutting.
  6.  前記裏面層の非肌面側にズレ止粘着部が配されており、該ズレ止粘着部と前記中央吸収性シートとの平面視における重なり部分は、前記中央吸収性シートの配置面積の35%以下であり、該中央吸収性シートの前記中間部における幅方向中央領域が前記ズレ止粘着部と重ならない、請求項1~5のいずれか1項に記載の吸収性物品。 The anti-slip adhesion portion is disposed on the non-skin surface side of the back surface layer, and the overlapping portion of the anti-slip adhesion portion and the central absorbent sheet in a plan view is 35% of the arrangement area of the central absorbent sheet The absorbent article according to any one of claims 1 to 5, wherein the widthwise central region in the middle portion of the central absorbent sheet does not overlap with the anti-slip portion.
  7.  前記冷感剤は、水不溶性又は水難溶性の剤である、請求項1~6のいずれか1項に記載の吸収性物品。 The absorbent article according to any one of claims 1 to 6, wherein the cooling agent is a water insoluble or poorly water soluble agent.
  8. 前記冷感剤として乳酸メンチルを含む、請求項7に記載の吸収性物品。 The absorbent article according to claim 7, comprising menthyl lactate as the cooling agent.
  9.  前記冷感剤としてメントールを含む、請求項8に記載の吸収性物品。 The absorbent article according to claim 8, comprising menthol as the cooling agent.
  10.  前記メントールと乳酸メンチルの質量比が、前者/後者として、0.01以上、0.2以下である、請求項9に記載の吸収性物品。 The absorbent article according to claim 9, wherein the mass ratio of menthol to menthyl lactate is 0.01 or more and 0.2 or less as the former / the latter.
  11.  前記表面層の肌当接面側の両側に、該表面層より通気性が小さいサイドシートが積層されている請求項1~10のいずれか1項に記載の吸収性物品。 The absorbent article according to any one of claims 1 to 10, wherein side sheets having lower air permeability than the surface layer are laminated on both sides of the skin contact surface side of the surface layer.
  12.  前記吸収層の幅方向外方に延出したウイング部を備えている請求項1~11のいずれか1項に記載の吸収性物品。 The absorbent article according to any one of claims 1 to 11, further comprising a wing portion extending outward in the width direction of the absorbent layer.
  13.  生理用ナプキンである、請求項1~12のいずれか1項に記載の吸収性物品。 The absorbent article according to any one of claims 1 to 12, which is a sanitary napkin.
  14.  中央吸収性シートに冷感剤を塗布する工程(S1)と、前記中央吸収性シートの肌側面及び非肌側面を外包吸収性シートで挟む工程(S2)と、前記中央吸収性シートと前記外包吸収性シートとの平面視重なる領域において、少なくとも肌面側に連通部を形成する工程(S3)と、を備える吸収層の製造方法。 A step (S1) of applying a cooling agent to a central absorbent sheet, a step (S2) of sandwiching the skin side and the non-skin side of the central absorbent sheet with an outer shell absorbent sheet, the central absorbent sheet and the outer shell Forming a communicating portion at least on the skin surface side in a region overlapping in plan view with the absorbent sheet (S3).
  15.  前記工程(S1)及び(S2)の後に前記工程(S3)を行う、請求項14に記載の吸収層の製造方法。 The manufacturing method of the absorption layer of Claim 14 which performs the said process (S3) after the said processes (S1) and (S2).
  16.  請求項15に記載の製造方法により得られた吸収層を、表面層と裏面層との間に配する工程を備える吸収性物品の製造方法。 The manufacturing method of the absorbent article provided with the process of arranging the absorption layer obtained by the manufacturing method of Claim 15 between a surface layer and a back surface layer.
  17.  前記裏面層の非肌側面にズレ止粘着部を配する工程を備えており、前記ズレ止粘着部と前記中央吸収性シートとの平面視における重なり部分を、前記中央吸収性シートの配置面積の35%以下であり、該中央吸収性シートの中間部における、前記縦方向と直交する幅方向中央領域が前記ズレ止粘着部と重ならないようになす、請求項16に記載の吸収性物品の製造方法。 And a step of arranging the anti-slip portion on the non-skin side of the back layer, wherein the overlapping portion of the anti-slip portion and the central absorbent sheet in plan view corresponds to the arrangement area of the central absorbent sheet. The manufacturing of the absorbent article according to claim 16, which is 35% or less, and in the middle portion of the central absorbent sheet, the width direction central region orthogonal to the longitudinal direction does not overlap the anti-slip portion. Method.
PCT/JP2018/040997 2017-11-08 2018-11-05 Absorbent article WO2019093267A1 (en)

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