WO2019089505A3 - Zinc electrodes for batteries - Google Patents

Zinc electrodes for batteries Download PDF

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Publication number
WO2019089505A3
WO2019089505A3 PCT/US2018/058096 US2018058096W WO2019089505A3 WO 2019089505 A3 WO2019089505 A3 WO 2019089505A3 US 2018058096 W US2018058096 W US 2018058096W WO 2019089505 A3 WO2019089505 A3 WO 2019089505A3
Authority
WO
WIPO (PCT)
Prior art keywords
sponge
zinc
network
batteries
annealed
Prior art date
Application number
PCT/US2018/058096
Other languages
French (fr)
Other versions
WO2019089505A2 (en
Inventor
Debra R. Rolison
Joseph F. Parker
Jeffrey W. Long
Jesse S. Ko
Original Assignee
The Government Of The United States Of America As Represented By The Secretary Of The Navy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/797,181 external-priority patent/US10720635B2/en
Application filed by The Government Of The United States Of America As Represented By The Secretary Of The Navy filed Critical The Government Of The United States Of America As Represented By The Secretary Of The Navy
Priority to EP18873576.5A priority Critical patent/EP3704754A4/en
Priority to JP2020524107A priority patent/JP7275127B2/en
Priority to CN201880071313.2A priority patent/CN111406330B/en
Priority to KR1020207013482A priority patent/KR20200066695A/en
Publication of WO2019089505A2 publication Critical patent/WO2019089505A2/en
Publication of WO2019089505A3 publication Critical patent/WO2019089505A3/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/06—Electrodes for primary cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/244—Zinc electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/42—Alloys based on zinc
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/94—Non-porous diffusion electrodes, e.g. palladium membranes, ion exchange membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/30—Batteries in portable systems, e.g. mobile phone, laptop
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

An article having a continuous network of zinc and a continuous network of void space interpenetrating the zinc network. The zinc network is a fused, monolithic structure. A method of: providing an emulsion having a zinc powder and a liquid phase; drying the emulsion to form a sponge; annealing and/or sintering the sponge to form an annealed and/or sintered sponge; heating the annealed and/or sintered sponge in an oxidizing atmosphere to form an oxidized sponge having zinc oxide on the surface of the oxidized sponge; and electrochemically reducing the zinc oxide to form a zinc metal sponge.
PCT/US2018/058096 2017-10-30 2018-10-30 Zinc electrodes for batteries WO2019089505A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP18873576.5A EP3704754A4 (en) 2017-10-30 2018-10-30 Zinc electrodes for batteries
JP2020524107A JP7275127B2 (en) 2017-10-30 2018-10-30 Zinc electrode for batteries
CN201880071313.2A CN111406330B (en) 2017-10-30 2018-10-30 Zinc electrode for battery
KR1020207013482A KR20200066695A (en) 2017-10-30 2018-10-30 Zinc electrode for battery

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/797,181 2017-10-30
US15/797,181 US10720635B2 (en) 2012-11-28 2017-10-30 Zinc electrodes for batteries

Publications (2)

Publication Number Publication Date
WO2019089505A2 WO2019089505A2 (en) 2019-05-09
WO2019089505A3 true WO2019089505A3 (en) 2019-07-25

Family

ID=66332966

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2018/058096 WO2019089505A2 (en) 2017-10-30 2018-10-30 Zinc electrodes for batteries

Country Status (5)

Country Link
EP (1) EP3704754A4 (en)
JP (1) JP7275127B2 (en)
KR (1) KR20200066695A (en)
CN (1) CN111406330B (en)
WO (1) WO2019089505A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11069889B2 (en) * 2019-07-19 2021-07-20 The Government of the United Stales of America, as represented by the Secretare of the Navy Zinc electrode improvements
CN113972376B (en) * 2021-10-21 2023-06-02 中国石油天然气股份有限公司 Three-dimensional metal framework supported porous zinc anode material and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010009741A1 (en) * 1997-08-01 2001-07-26 Richard Edward Durkot Electrode having multi-modal distribution of zinc-based particles
US20050003271A1 (en) * 2003-07-03 2005-01-06 Zhiping Jiang Zinc/air cell with improved anode
US20110287307A1 (en) * 2004-06-28 2011-11-24 Eveready Battery Company, Inc. Alkaline Electrochemical Cell with a Blended Zinc Powder
US20140147757A1 (en) * 2012-11-28 2014-05-29 The Government of the United States of America, as represented by the Ssecretary of the Navy Zinc electrodes for batteries
CN104078682A (en) * 2013-03-27 2014-10-01 宋永江 Secondary zinc electrode additive
US20180130998A1 (en) * 2012-11-28 2018-05-10 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Zinc Electrodes for Batteries

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5780186A (en) * 1996-05-09 1998-07-14 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration High performance zinc anode for battery applications
US6300011B1 (en) * 2000-01-25 2001-10-09 The Gillete Company Zinc/air cell
US7273680B2 (en) * 2002-08-28 2007-09-25 The Gillette Company Alkaline battery including nickel oxyhydroxide cathode and zinc anode
US9802254B2 (en) 2014-09-30 2017-10-31 The United States Of America, As Represented By The Secretary Of The Navy Zinc electrodes for batteries
US9324993B2 (en) * 2013-09-06 2016-04-26 Lenovo (Singapore) Pte. Ltd. Lithium-ion cell and energy density thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010009741A1 (en) * 1997-08-01 2001-07-26 Richard Edward Durkot Electrode having multi-modal distribution of zinc-based particles
US20050003271A1 (en) * 2003-07-03 2005-01-06 Zhiping Jiang Zinc/air cell with improved anode
US20110287307A1 (en) * 2004-06-28 2011-11-24 Eveready Battery Company, Inc. Alkaline Electrochemical Cell with a Blended Zinc Powder
US20140147757A1 (en) * 2012-11-28 2014-05-29 The Government of the United States of America, as represented by the Ssecretary of the Navy Zinc electrodes for batteries
US20180130998A1 (en) * 2012-11-28 2018-05-10 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Zinc Electrodes for Batteries
CN104078682A (en) * 2013-03-27 2014-10-01 宋永江 Secondary zinc electrode additive

Also Published As

Publication number Publication date
JP7275127B2 (en) 2023-05-17
JP2021501446A (en) 2021-01-14
WO2019089505A2 (en) 2019-05-09
CN111406330B (en) 2024-02-23
KR20200066695A (en) 2020-06-10
EP3704754A4 (en) 2021-07-21
EP3704754A2 (en) 2020-09-09
CN111406330A (en) 2020-07-10

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