WO2019081769A1 - Heat exchange unit and assembly - Google Patents

Heat exchange unit and assembly

Info

Publication number
WO2019081769A1
WO2019081769A1 PCT/EP2018/079510 EP2018079510W WO2019081769A1 WO 2019081769 A1 WO2019081769 A1 WO 2019081769A1 EP 2018079510 W EP2018079510 W EP 2018079510W WO 2019081769 A1 WO2019081769 A1 WO 2019081769A1
Authority
WO
WIPO (PCT)
Prior art keywords
heat exchange
thermo
flow
supporting plate
conducting sheet
Prior art date
Application number
PCT/EP2018/079510
Other languages
French (fr)
Inventor
Henrik Hjelmsmark
Original Assignee
Sani Membranes Aps
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sani Membranes Aps filed Critical Sani Membranes Aps
Publication of WO2019081769A1 publication Critical patent/WO2019081769A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0031Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other
    • F28D9/0043Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other the plates having openings therein for circulation of at least one heat-exchange medium from one conduit to another
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/12Elements constructed in the shape of a hollow panel, e.g. with channels
    • F28F3/14Elements constructed in the shape of a hollow panel, e.g. with channels by separating portions of a pair of joined sheets to form channels, e.g. by inflation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/03Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with plate-like or laminated conduits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0062Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by spaced plates with inserted elements
    • F28D9/0075Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by spaced plates with inserted elements the plates having openings therein for circulation of the heat-exchange medium from one conduit to another
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/08Elements constructed for building-up into stacks, e.g. capable of being taken apart for cleaning
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/026Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits
    • F28F9/0278Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits in the form of stacked distribution plates or perforated plates arranged over end plates

Definitions

  • the present invention relates to a planar, heat exchange unit for heat exchange between two liquid media, said unit having a thermo-conducting sheet or thin foil that is suitable for heat transfer bonded onto at least one external or outer surface of a supporting plate with integrated flow paths for a first liquid media inside the plate and the thermo-conducting sheet being in fluid contact with an outer second liquid media.
  • the heat exchange unit comprises a supporting plate having a first and a second planar, preferably rectangular, surface enclosing at least two connected exit openings, internal flow distribution channels, and at least one flow area or flow area for a first liquid media, said flow area being formed to enable fluid contact between said first liquid and the internal surface of a thermo-conducting sheet bonded at the perimeter onto the planar outer surface, said flow area being provided with perforations, preferably along opposite edges of the flow area, forming a fluid connection between flow area and internal channels, and said flow area being sealed at its periphery with the periphery of the thermo-conducting sheet, the external surface of which is in fluid contact with a second liquid media, thus enabling heat exchange.
  • the present invention relates to an assembly of at least one planar, rigid, heat exchange unit into a heat exchange module for heat exchange between two liquid media streams.
  • the heat exchange module may, e.g. be configured for counter flow or mixed flow liquid-to-liquid heat exchange.
  • the modules may be connected in series to serve any larger needs for heat exchange between liquid media.
  • the invention further relates to the use of the heat exchange unit and module for heat exchange of liquid media having sanitary requirements, e.g. heat exchange, including pasteurization, of liquid dairy products, and of highly viscous media, as well as liquid media having a content of suspended solids.
  • sanitary requirements e.g. heat exchange, including pasteurization, of liquid dairy products, and of highly viscous media, as well as liquid media having a content of suspended solids.
  • Apparatuses for heat exchange between two liquid media are generally composed of a thermo-conducting material, typically plates arranged in stacks of plates, and the apparatus is subjected to a liquid flow on both sides of the thermo-conducting plates, such as stainless-steel plates.
  • the heat exchange plates of the prior art are typically pressed plates of a sufficient thickness, such as 0.8 mm to 2 mm being able to withstand relatively high pressures without being deformed during manufacturing and operation.
  • the high plate thickness leads to decreased heat conduction and a large material consumption in the final product, which typically is very heavy and requiring considerable mechanical assembly and fastenings means.
  • gasket There are three typical configurations of plate heat exchangers: gasket, fused and welded.
  • the gasketed units are plate and frame types, where a very thick frame plate is used to squeeze a large number of gaskets positioned between plates. This
  • thermo-conducting metal sheets are easily corrodible when in contact with, e.g. even slightly acidic media.
  • thermo-conducting sheet which is fluid tight bonded at its edges to the surface of a hollow supporting plate comprising a flow area for a first liquid medium, the thermo-conducting sheet being in fluid contact with said first liquid medium at its internal surface and being in fluid contact with a second liquid medium at its external surface.
  • the flow area is connected through a flow path to at least two exit openings or fluid connections for the first liquid medium, and the flow path comprising internal flow distribution channels and spaced apart holes or perforations leading to the flow distribution area for liquid contact of the first medium with the internal surface of the thermo-conducting sheet, thus providing heat exchange between the two liquid media.
  • thermo-conducting sheet may be liquid tight bonded to the supporting plate at one or more additional points or lines.
  • the supporting plate of the heat exchange unit comprises two half- plates.
  • the half plates may be bonded together.
  • the supporting plate is typically formed by liquid tight bonding, such as edgewise bonding or heat-fusion of the two fitting half-plates.
  • the half plates may be made of a light material, such as plastics which allows for the half-plates to be formed by molding.
  • the supporting plat of the heat exchange unit comprising bonded first and a second half-plates, further comprises first and a second rigid outer surface.
  • the half plates encloses at least two internal flow distribution channels, being fluidly connected through perforations with a flow area positioned on one or both rigid outer surface(s) of the supporting plate.
  • the heat exchange unit comprises at least one thermo-conducting sheet positioned liquid tight bonded adjacent to and covering the flow distribution area on each of the surfaces of the supporting plate.
  • the supporting plate may further comprise at least two fluidly connected fluid connections or exit openings.
  • the fluid connections has protruding rims and extend perpendicular to the surface of the supporting plate.
  • the internal flow distribution channels extends from the fluid connections through the perforations and the flow area(s) thus defining an internal flow path for a first liquid medium through said heat exchange unit.
  • Each of the internal flow distribution channels is preferably formed as an elongate groove or depression in an inner surface of one or both of the half plates.
  • each internal flow distribution channel is formed from mating/cooperating grooves/depressions formed in each half plate.
  • Objects of the invention may further be achieved by a heat exchange module comprising a plurality of heat exchange units as mentioned above, wherein the at least two fluid connections comprises protruding rims, and where the supporting plates further comprises bonding points functioning as distance points together with the protruding rims thus forming a gap between the heat exchange units for passage of a second liquid medium in-between two adjacent heat exchange units when stacked.
  • the heat exchange units of the heat exchange module may be fluidly connected at the above mentioned fluid connections to allow passage of a first liquid medium between the heat exchange units of the heat exchange module.
  • the heat exchange units of the heat exchange module may further be bonded to each other at said bonding points functioning as distance points, such as through thermal bonding into a module.
  • the fluid connections with the protruding rims may be formed integral with the supporting plate.
  • the protruding rims are formed from insertion of loose inlet pieces.
  • the thermo-conducting sheet can be a thin foil of a thermo-conducting material, such as a metal, such as stainless steel, aluminium or die cast aluminium alloys; or of heat conducting plastics or a hybrid material, such as polysulfone or nylon having heat- conductive additives including graphite, carbon fibers, and ceramics such as aluminum nitride and boron nitride.
  • a thermo-conducting material such as a metal, such as stainless steel, aluminium or die cast aluminium alloys; or of heat conducting plastics or a hybrid material, such as polysulfone or nylon having heat- conductive additives including graphite, carbon fibers, and ceramics such as aluminum nitride and boron nitride.
  • the thermo-conducting sheet used for heat exchange is preferably impermeable to the type of liquid media to be cooled or heated.
  • thermo-conducting material is based on PP, Polypropylene, with an added thermal conductivity component is, e.g. TECACOMP ® TC (Ensinger, Ensinger Platz, Seewalchen am Attersee, Austria) whereby thermal conductivity can be up to 25 W/(m-K) depending on the filler used, and as thermoconducting sheet can be, e.g., only of 0.1 mm thickness for efficient heat exchange in a unit or module of the invention.
  • TECACOMP ® TC Ensinger, Ensinger Platz, Seewalchen am Attersee, Austria
  • thermo-conducting sheet is based high alloy stainless steel whereby thermal conductivity can be very high, and as thermo-conducting sheet can be as example only 0.05 mm of thickness, a very efficient heat exchange can be obtained, and at the same time consumption of high value material is minimal.
  • a preforming of the sheet may be used to secure improved bonding to the plastic base plate and at the same time this preforming can counteract problems caused by differences in thermal expansion between plastic and metal.
  • the thermo-conducting sheet is made from a woven or non-woven polypropylene sheet having a filler of thermo-conducting plastic material molded into and on top of the woven or non-woven sheet.
  • Types of useful polymeric mixed plastics materials may be formed into suitable liquid and/or gas impermeable, heat conducting thin sheets using the methods and combinations of materials, and methods for making membranes by forming a nanofibrous layer on a macroporous support layer and applying polymer to the nanofibrous layer, disclosed in US Pub. No.: US 2015/0059578 Al (Huizing et al.) the contents of which are hereby incorporated by reference.
  • the composite membranes taught by Huizing et al. may advantageously be given a final coating with an impermea ble polymer.
  • one first liquid medium to be heat exchanged can flow in the channels and flow distribution areas formed inside the supporting plates having one or more thermo-conducting sheets bonded to their planar outer surfaces, while a free flow of a second liquid medium is maintained on the outside and flowing through gaps between the stacked plates of the module.
  • the heat exchange second liquid media can be highly viscous and even contain larger particulate impurities, as long as the media does not block the free flow passage outside or between the heat exchange plates.
  • the present invention enables cleaning at both external surfaces of the heat exchange unit and in modular unit assemblies as well as at the internal surfaces inside the supporting plate(s) at the flow path for the first liquid medium in the heat exchange unit.
  • the heat exchange module of the invention is suita ble for applications, such as milk pasteurization, where sanitary requirements can be fulfilled with external flushing between module plates as well as with internal cleaning flushing of the flow paths of the supporting plate.
  • the heat exchange module is highly resistant to corrosion when having a polymer based thermo-conducting sheet.
  • heat exchange modules of the invention may be used for energy exchange of hot and cool flows in large scale district heating system based on hot or warm water.
  • thermo-conducting sheet shall mean a thin thermo- conducting foil or membrane capable of being bonded or sealed liquid tight to a supporting plate, typically a plastics plate.
  • a "thermo-conducting sheet” as used herein is relatively thin and can be flexible, typically made by rolling a metal or plastic sheet into thin foil or by casting of a hybrid polymeric or plastics material, e.g. such as highly rigid polypropylene having suitable thermo-conduction enhancing additives.
  • flow area shall mean a confined and optionally corrugated or mesh like surface area of a supporting plate.
  • the flow area may serve as a flow distribution area or heat exchange area for a first liquid medium in fluid contact with a thermo-conducting sheet.
  • the flow area defines the area available for heat exchange at the internal surface of the thermo-conducting sheet.
  • flow area flow distribution area
  • heat exchange area are used interchangeably herein, but where the term “heat exchange area” when used for a heat exchange unit of the invention preferably describes the combined flow distributions areas on both sides of said unit.
  • fluid connection or "exit opening” as used herein shall mean an opening for a flow of liquid media into and/or out of the support plate(s) of the planar heat exchange unit and heat exchange module of the invention.
  • each fluid connection/ exit opening t allows access to both sides of the unit or the module, and one or both sides can be connected to the flow of the first media.
  • At least two fluidly connected exits provide for functional flow operation of the unit.
  • the fluid connection/exit openings are connected through various internal flow distribution channels leading through perforations to the external flow areas on the supporting plate, thus allowing flow of liquid media from one exit opening to the other, such as through pumping.
  • the connected exits are located at opposite ends of the planar unit.
  • the terms "heat exchange module” and “heat exchange unit assembly” are used interchangeably herein and are used for the subject matter of Figure 5 as well as for modules and unit assemblies when integrated with various connecting parts in housings and systems for heat exchange.
  • first liquid medium and “first liquid media” (to be cooled or heated) are interchangeably used herein and are used for the media flowing internally in the hollow supporting plate and being in fluid contact with the internal surface of the heat exchange thermo-conducting sheet.
  • second liquid medium and “second liquid media” (to be cooled or heated) are interchangeably used herein and are used for the media flowing externally on the heat exchange unit and being in fluid contact with the external surface of the heat exchange thermo-conducting sheet.
  • Internal surface of the heat exchange thermo-conducting sheet shall herein mean the thermo-conducting sheet surface facing the outer surface of the supporting hollow plate and being in fluid contact with the first liquid medium.
  • External surface of the heat exchange thermo-conducting sheet shall herein mean the thermo-conducting sheet surface facing the external or second liquid cooling or heating medium.
  • liquid tight sealing means liquid tight sealing, fluid tight sealing, and liquid tight bonding, etc. are used interchangeably herein and may also specify gas tight sealing when the heat exchange unit of the invention is suitable for heat exchange of gas-to-gas (air-to-air) or gas-to-liquid.
  • viscous media or media having suspended solids shall mean liquid media, such as dairy products, fruit and vegetable juice, mineral and vegetable oil, waste water of many kinds, media streams having a corrosive effect and the like.
  • Fig. 1 is a perspective view of a heat exchange unit comprising the supporting plate (1) comprising two half-plates (2, 3), fluid connections (4, 5) with protruding cylindrical rims (4', 5'), flow area (6), thermoconducting sheet (7), bonding points (8), internal flow distribution channels (9A, 9B), perforations (10A, 10B) leading to the flow area (6).
  • Fig. 2 is an exploded perspective view of a heat exchange unit showing the various parts forming the unit as shown in Figure 1, and showing in detail an embodiment of internal features, such as a guided flow distribution with two opposite fluid connections (4, 5) having fluid connection to five channels (9A and 9B) with manifolding to/from multiple (twentyfive) perforations (10A, 10B) arranged in a line and leading flow to the flow area (6)of the two half-plates forming the supporting plate.
  • a guided flow distribution with two opposite fluid connections (4, 5) having fluid connection to five channels (9A and 9B) with manifolding to/from multiple (twentyfive) perforations (10A, 10B) arranged in a line and leading flow to the flow area (6)of the two half-plates forming the supporting plate.
  • Fig. 3 is a cross-sectional view perpendicular to the longitudinal extension of a heat exchange unit, showing the two half-plates (2, 3), an exemplary liquid media flow distribution channel (9A, 9B), perforations (10A, 10B), grid structure or mesh with groove (12) and ridge (13), thermo-conducting sheet (7) and inlet and outlet to and from the flow area,
  • Fig. 4 is a top view of the grid or mesh with groove (12) and ridge (13) forming the flow area (6) available for heat exchange in fluid contact with the internal surface of the heat exchange thermo-conducting sheet.
  • Fig. 5 is a perspective view of a heat exchange unit assembly (20) built up as a heat exchange module with fluid connections for flow of first liquid media (C, D) and gaps between plates for flow of second liquid media (A, B).
  • Certain embodiments of the present invention relates to a rigid, planar heat exchange unit assembly, wherein said heat exchange plate comprises at least a first and a second exit (4, 5) opening for a liquid medium, and where internal channels extend from said first exit opening (4) to said second exit opening (5) and in between enters and exits through perforations (10A, 10B) to at least one flow area (6) sealingly covered by a thermo-conducting sheet (7), where said perforations may comprise slits or holes making fluid connection between the flow area and the internal channels (9A, 9B), said flow and flow area being formed as mesh like channels (12, 13) on and as a part of the outside of the supporting plate (1), said mesh formed to ensure a flow area between a covering thermo-conducting sheet and the heat exchange plate surface, said thermo- conducting sheet being bonded at the perimeter of the flow area.
  • thermo-conducting sheet may be needed to drive the flow and to keep the thermo- conducting sheet fixed during operation.
  • the supporting plate comprises at least one flow distribution area of the outer surface of the supporting plate, said area being available for heat exchange and being overlaid with and sealed at the perimeter by a thermo-conducting sheet, thus being positioned adjacent to said flow distribution area.
  • the thermo-conducting sheet is bonded along the perimeter of said flow area, which is available for heat exchange. The bonding provides liquid tight sealing of the internal surface of the heat exchange sheet from the outside of the heat exchange unit or module.
  • Said flow area (6) is formed as an integral part of the supporting plate (1) and comprises indents or channels (12, 13) forming a mesh like flow area that can lift up the thermo- conducting sheet to withstand a hydraulic pressure, while allowing a substantial flow between said internal surface of the thermo-conducting sheet and the supporting plate, even when a pressure being applied from the outside on the heat exchange unit compresses the thermo-conducting sheet towards the surface of the supporting plate.
  • the thermo-conducting sheet may partly take form from the supporting flow area due to the outside pressure, hereby forming a corrugated surface increasing heat exchange efficiency.
  • the flow area on the support plate is formed with at least one entry and at least one outlet and with the flow area between said entry and exit being formed by perforations leading to internal channels, said channels leading to the fluid connections, such as by connecting to the exit opening through a manifold.
  • Said entry and outlet may be formed by multiple perforations in either side of the flow area, hereby ensuring a uniform flow over the entire flow area available for heat exchange, and ensuring minimal pressure loss through an adequate number of perforations, said perforations still small enough to ensure the lifting function for the applied pressure on the thermo-conducting sheet on said mesh.
  • thermo-conducting sheet Said flow distribution area together with said channels and connected fluid connections allow for unimpeded and controlled flow of the first liquid medium through the supporting plate leading to enhanced turbulence conditions at the internal surface of the thermo-conducting sheet.
  • the unimpeded flow of the first and the second liquid media allows for a very homogenous pressure gradient over the thermo-conducting sheet, thus improving operational lifetime and making it possible to create a turbulence optimized over the entire sheet surface leading to a substantial turbulence and heat exchange improvement of the thermo-conducting sheet area.
  • said supporting plate of the heat exchange unit comprises two half- plates which are bonded together at the periphery, where the two half-plates are identical in shape keeping the number of different parts of the unit/module at a minimum.
  • the bonding at the perimeter of the plates seals the internal surface of the thermo-conducting sheet from the cooling or heating first liquid medium flowing past the external surface of the thermo-conducting sheet without any further need for a gasket. More bonding areas may be added inside the supporting plate edge or perimeter to make the planar unit more rigid.
  • the assembly of the heat exchange unit is comprised by fusing of a thermo-conducting sheet onto the outer surface of the supporting plate, which in turn is formed by bonding, such as by fusion or in molding, of two identically shaped half- plates, and where the fluid connections are formed by integrated parts of the two half- plates.
  • thermo-conducting sheet has a mesh structure, such as an overlaying fishbone like curve-shape similar to that seen in conventional plate heat exchangers. This overlaying shape is dimensioned to increase turbulence of the external flow of the second liquid medium, hereby optimizing heat exchange capacity at comparably lower external flow volumes.
  • said at least two fluid connections extend transversely to the planar surface of the supporting plate.
  • the exits being perpendicular to the horizontal plane of the supporting plate allow for a large access area to the internal flow distribution channels and flow distribution areas forming the heat exchange area, and, at the same time, the relatively large channels reduce counter pressure of flow to the exits.
  • high flow speeds between the two fluid connections during heat exchange flows or during cleaning operation are possible.
  • said supporting plate comprises on its planar sides two or more cylindrical rims or studs or protrusions surrounding the fluid connections.
  • the combined or stacked cylindrical protrusions when the heat exchange plates are stacked together, form the exit path for the first liquid medium while keeping the number of assembly parts to a minimum.
  • Said connected exits forming the exit manifold can be fused together at contact areas, hereby forming a manifold sealing the first internal media from the second external media.
  • the cylindrical, protruding rims may be in the form of loose inlet pieces, such as is preferably made of the same material as the supporting plate, e.g. a plastics, such as described herein below.
  • said heat exchange unit or heat exchange modular assembly comprises at least one heat exchange thermo-conducting sheet in fluid tight bonding or sealing onto a supporting hollow plate.
  • each heat exchange unit may comprise two layers of thermo-conducting sheets, i.e. provided on both sides of the supporting plate, such as where the internal surface is protected against the pressure exerted against the lifting points formed by the corrugated or fishbone-like contact points of the mesh like structure.
  • said supporting plate comprises, e.g. at its edge or perimeter, one or more bonding points for bonding two adjacent planar heat exchange units or bonding of a heat exchange unit to an overlaying unit in a stack of heat exchange units forming a module.
  • the bonding points together with the protruding exit opening rims define the distance between two planar heat exchange units in a stack or module.
  • Said protruding exits of adjacent heat exchange units are bonded, such as by heat fusion, to achieve sealing between fluid connections to provide an integrated flow path to the outside and external flow connections for liquid heat exchange media or for connections to a flow of cleaning liquid through the bonded plurality of planar heat exchange units forming the module.
  • the heat exchange units are planar and can be stacked together using a few plates to many dozens of plates forming one bonded rigid heat exchange module.
  • the heat exchange units are stacked with spacing for the external or second media to be heat exchanged, offering a gap outside for access or flow of media between the units and in contact with the external surface of the thermo-conducting sheets.
  • the gap between plates e.g. as illustrated in Fig. 5, can be dimensioned to secure a free and unimpeded flow of media (A, B) to be heat exchanged and allows for flow of viscous media or media having suspended solids.
  • an assembly of the heat exchange units of the invention comprises a plurality of planar heat exchange units, forming a rigid heat exchange module, said heat exchange plates are situated parallel juxtaposed having the heat exchange area facing the heat exchange area of an adjacent heat exchange plate.
  • Said plurality of heat exchange plates forming a square or rectangular entry for the second liquid media, such that said media is able to pass between the planar heat exchange units allowing for a large thermo-conducting sheet area (heat exchange area) on a small foot print.
  • the gap between the planar heat exchange units is filled with a spacer netting or mesh that creates turbulent flow over the heat exchange area even at low cross flow volumes of the liquid media and at the same time keeping the thermo-conducting sheet in place at low or negative pressures applied to the thermo-conducting sheet.
  • said plurality of planar heat exchange units forming a heat exchange module
  • said plurality of units is placed in a housing, said housing forming a square or rectangular inlet and outlet for the liquid media to be heat exchanged, thus guiding the external second liquid flow and the internal first liquid flow at inlets and outlets that in exemplary embodiments are provided transversely from the housing.
  • the bonded supporting plates with the attached thermo-conducting sheets each form a pressure vessel so that when a flow and a pressure are applied through an exit opening, a flushing of the plate may take place, between two exits, thereby cleaning, i.a. the internal surface of the bonded thermo-conducting sheet.
  • the invention provides a heat exchange plate unit which has, with respect to known liquid-to-liquid heat exchangers, such as plate heat exchangers, the advantages of having at the same time:
  • a flushable interior side such as for turbulent flow of a heat conducting media or for flushing with a cleaning liquid
  • the heat exchange modular assembly has a shortened length of the paths of the liquids to be heat exchanged (10 to 100 cm) and a non-impeding (5 to 100 cm long) but relatively large inside flow area available for heat exchange, combined with a large active area (up to about half of heat exchange plate thickness), a plurality of flow leading channels for the first liquid stream or discharge leading to at least two larger perpendicular fluid connections, and an overall structure with sufficient mechanical strength for it to keep a constant geometry at high cross flow rates and pressure gradients, guaranteeing the stability of the hydrodynamic conditions, under pressure, media and temperature constraints and at a satisfactory constructional cost.
  • the flow area used for heat exchange between the two liquid media may be in one embodiment formed with a mesh like channel structure where channels are 0.2-2.0 mm wide giving similar space between ridges (13) for lifting the thermo-conducting sheet, the ridge or lifting area formed without sharp points or ridges securing a sufficiently gentle carrier surface against outside pressure on the thermo-conducting sheet.
  • the heat exchange area flow distribution channels, perforations (slits and holes) as well as internal channels are formed hydrodynamically, securing that minimal blocking and pressure loss will take place in the internal liquid flow path from and through the fluid connections.
  • the slits or holes connecting the inside channels with flow area on the outer surface of the supporting plate are dimensioned to the needed flow and to physical size to needed lifting of thermo-conducting sheet, typically 0.2-2.0 mm wide.
  • the heat exchange units can be sized according to need for heat exchange area as well as to cost optimized production and are typically from 10 cm by 10 cm of heat exchange area up to 50 cm by 100 cm heat exchange area. The typical size for industrial applications is 20 cm by 20 cm up to 20 by 100 cm heat exchange area.
  • planar heat exchange units are typically made of 3-8 mm thick supporting plates made up by two half-plates.
  • the plate design, material and thickness are dimensioned to ensure a rigid construction of the unit and assembled modules under turbulent external and internal flow.
  • the inside flow distribution channels formed by the two half-plates can be of rounded cross section, and typically around half of the plate thickness in diameter as individual channels or be made up by mesh type volumes.
  • a mesh-like flow area may be formed as a fishbone structure that allows flow distribution while keeping distance to the internal surface of the thermo- conducting sheet at contact points.
  • the inside channels lead to plate fluid connections that can be designed to lead specific types of liquids from the stacked assembly of heat exchange units to the exit with negligible pressure loss.
  • the plate exits are 10-50 mm in diameter.
  • Materials used for the heat exchange unit plate parts are typically plastics, such as polymeric or co-polymeric thermoplastics, but can be of hybrid material or metallic origin or any other suitable material that can be bonded and withstand the liquid media to be heat exchanged, the temperature span needed, typically 5-95 degrees Celsius as well as the medias used for cleaning the units and modular assemblies. The choice of material must foresee thermal expansion and rigidity of the heat exchange unit/module.
  • Preferred execution is heat exchange plates in molded plastic material, such as polypropylene, and with, e.g., a polymeric based hybrid thermo-conducting sheet used for heat exchange.
  • Other executions can be as sintered parts or 3D printed versions in various materials.
  • thermo-conducting sheet to supporting plate liquid tight bonding and heat exchange units into stack bonding may be by laser welding, direct or indirect heat welding, in mold fabrication, ultrasonic welding, use of glue or hot-melt or solvents, or mechanically bonding with mechanical elements or connections designed into the parts.
  • plastic parts are welded together through heat applied melting of very specific areas of the designed parts, said heat exchange plate parts being molded by injection molding of polymer thermoplastic.
  • the thermo-conducting sheet may be bonded to the plate using a combination of hot-melt, in molding and welding to achieve liquid tight sealing.
  • thermoplastics such as polypropylene or polyethylene
  • the material of the supporting plate (or half-plates) can be recycled through re-melting of the plastic.
  • the second liquid medium is pumped at a speed of typically 1 to 5 meters per second across the external surface of the thermo-conducting sheet to keep a high heat conducting efficiency and to keep possible suspended solids from building up and depositing on the thermo- conducting sheet.
  • the first liquid medium is pumped at a speed of typically 0.5 to 2.5 meters per second through the flow distribution channels and flow distribution areas and heat exchange area in the supporting plate and across the internal surface of the thermo-conducting sheet to keep a high heat conducting efficiency and to keep the boundary layer on the internal thermo-conducting sheet surface as small as possible, hereby keeping the heat exchange efficiency high and functional in operation for a longer time.
  • An embodiment of the invention is a heat exchange unit, which provides a planar, rigid heat exchange unit for cooling or heating of liquid media, wherein a planar thermo- conducting sheet, which is fluid tight bonded at its edges to the surface of a hollow supporting plate comprising a flow area for a first liquid medium, the thermo- conducting sheet being in fluid contact with said first liquid medium at its internal surface and being in fluid contact with a second liquid medium at its external surface.
  • the flow area is connected through a flow path to at least two fluid connections for the first liquid medium, and the flow path comprising internal flow distribution channels and holes or perforations leading to the flow area for liquid contact of the first medium with the internal surface of the thermo-conducting sheet, thus providing heat exchange between the two liquid media.
  • An additional embodiment of the invention is a heat exchange module as disclosed herein comprising a plurality of heat exchange units each comprising a rigid, planar and partly internally channeled supporting plate (1) formed by liquid tight bonding of two planar, essentially identical, half-plates (2, 3) and a thermo-conducting membrane (7) in fluid contact with a first and a second liquid media having different temperatures, and where the thermo-conducting membrane (7) is at least peripherally bonded to and covering a flow distribution area (6) for the first liquid medium on the supporting plate (1), where the flow area (6) is formed as a grid having drainage grooves (12) and raised contact points (13) supporting the internal surface of the membrane (7); while at the same time allowing the second liquid medium to be in fluid contact with the external membrane surface; the supporting plate (1) having perforation slits or holes (10A, 10B) connecting the flow area (6) and the at least one channel (9A, 9B).
  • An additional embodiment of the invention is a heat exchange module as disclosed herein comprising two or more planar heat exchange units being situated parallel juxtaposed having the external surface of the membrane (7) on one unit facing the external surface of the membrane of an adjacent unit, said plurality of units forming a stack of square or rectangular entry geometry for a liquid media (A), such that said media is able to pass between the planar heat exchange units, and where the at least two perpendicular fluid connections (C, D) are formed by discrete inlet pieces, such as cylindrical or ring-shaped inlet pieces, or formed as integrated parts of said half-plates (2, 3), and where the distance between the planar units is defined by the height of the rims of the fluid connections (4, 5) and of the bonding points (8), cf. Fig. 5.
  • Figure 1 Illustrates one embodiment of the heat exchange unit which may be formed by a) bonding at least one thermo-conducting sheet (7) onto a supporting plate (1) having internal preformed flow distribution channels (9A, 9B) in fluid connection (not shown) with a plurality of perforations (10A, 10B) opening onto a flow area (6) on at least one outer side, where the bonding provides liquid tight sealing along the edges or periphery of the flow area (6); and
  • the supporting plate being formed by bonding of two equal-size half-plates (2, 3) along their edges, where the bonding provides liquid tight sealing, and the supporting plate (1) being provided with two fluid connections (4, 5) are provided with a cylindrical rim and internal fluid connection with the flow distribution channels (9A, 9B).
  • the supporting plate (1) may be provided with protrusions (8) distributed spaced apart along the edges of both sides of the plate.
  • the protrusions (8) function as bonding points when two or more heat exchange units are stacked into a heat exchange module.
  • the fluid connections (4, 5) of the heat exchange unit is on opposite ends of the heat exchange area (6) and the heat exchange area is covered with an adjacent thermo-conducting sheet with a cut out showing the corrugated or mesh like flow area (6) below the thermo-conducting sheet.
  • multiple internal channels (9A and 9B) connect the two fluid connections on the plate (1) to the flow area via the perforations (10A, 10B) in either end of the flow area hereby forming a flow path under the thermo-conducting sheet from exit (4) to exit (5).
  • Bonding points (8) used when staking the plates into a module are also indicated. Said bonding points (8) together with the cylindrical, protruding fluid connections (4, 5) define the distance between two plates (1).
  • the two half-plates (2, 3) are identical or laterally reversed.
  • the perforations (10A, 10B) constitutes of slits and/or holes.
  • An embodiment of the invention provides a rigid, planar heat exchange unit, comprising an internally channeled planar supporting plate (1) formed by liquid tight bonding of two planar, typically identical, half-plates (2, 3), the heat exchange effect obtained through a thermo-conducting sheet (7) in fluid contact with a first and a second liquid media having different temperatures, and where the thermo-conducting sheet (7) is peripherally bonded to and covering a flow area (6) for the first liquid medium on the supporting plate (1), where the area (6) is formed as a grid having raised contact points (13) supporting the internal surface of the thermo-conducting sheet (7); while at the same time having the second liquid media in fluid contact with the external thermo- conducting sheet surface; the supporting plate (1) having perforation slits or holes (10A, 10B) connecting the distribution area (6) and the at least one channel (9A, 9B).
  • the channels (9A, 9B) inside the plates are for leading the first liquid media in the flow area through perforations (10A, 10B) to at least two or more paired fluid connections (4, 5) being perpendicular to the horizontal plane of the supporting plate, the combined fluid connections forming integral exit channels when stacking multiple heat exchange plates into an assembly of heat exchange units.
  • thermo-conducting sheet In a configuration of the invention with at least two fluid connections in fluid connection, it is possible to lead a media stream contacting the internal surface of the thermo-conducting sheet to ensure optimal heat exchange or optimal flushing with liquid cleaning media from one exit (4 or 5) to the other exit (4 or 5).
  • the flow area surface (6) is covered by liquid tight bonding of a flat thermo-conducting sheet (7) along its perimeter whereby heat exchange can be achieved.
  • Figure 2 Illustrates an exploded perspective view of a heat exchange unit assembly with two half-plates (2, 3) and two thermo-conducting sheets (7).
  • the upper half-plate (2) shows the outside surface (2s) of the supporting plate (1) with the flow area (6) being in each end or positioned just inside opposite ends of the flow path perforated with holes (10A, 10B), peripheral bonding points (8) and protruding fluid connections (4, 5).
  • the lower half-plate (3) shows the internal half flow distribution channels (9A, 9B) forming full channels when half-plates (2, 3) are bonded together, the flow distribution channels connecting the plate fluid connections (4, 5) with the perforations (10A, 10B).
  • the embodiment shows a variation in layout of the inside channels (9A, 9B) forming a manifold for the flow distribution channels (9A, 9B).
  • the shown manifold may in another embodiment be replaced with an internal flow volume, for example being fish-bone shaped, to keep spacing between the half-plates (2, 3).
  • the fluid connections (4, 5) can be placed as convenient, for example in opposite plate ends or corners or side by side, considering efficient flow or flow distribution of the channels (9A, 9B) as well as uniform flow distribution over the flow and heat exchange area (6).
  • the supporting plate comprises bonding points (8), the bonding points also functioning as distance points together with the protruding exit rims (4', 5') such that the second liquid medium can pass through the gap thus formed between the thermo-conducting sheet(s) in-between two adjacent heat exchange units in a module.
  • the bonding points (8) are here illustrated as a solid cylinder shaped protrusion extending transversely to the surface of the supporting plates (1).
  • the distance between the plates can be supported by a mechanical member or bar positioned at the edge of the heat exchange unit.
  • Figure 3 Illustrates a cross-sectional view of a detail of a heat exchange plate unit, showing an example of a flow distribution channel (9A/9B), perforations (10A/10B), the grid structure of the flow area (6) and the adjacent thermo-conducting sheet (7).
  • the grid or mesh like structure of the flow area (6) is formed as an integral part of the half- plates (2, 3) and may be formed with indentions, protrusions (13) and grooves (12), the grooves forming channels for flow and the protrusions forming support areas for the thermo-conducting sheet (7).
  • the heat exchange area grooves or channels are connected to the internal channels via the perforations (10A, 10B).
  • the openness of the flow area (6) is designed to support the thermo-conducting sheet, which again depends on the applied pressure on the thermo-conducting sheet during various operation types and the type of thermo-conducting sheet, as may be needed during operations using a relatively high pressure across the thermo-conducting sheet and a relatively thin or brittle thermo-conducting sheet may need several support points, protrusions or ridges (13), to ensure a free flow area in the grooves (12) facing the internal surface of the thermo-conducting sheet.
  • Figure 4 Illustrates a top view of an example of the grid forming the corrugated flow or heat exchange area (6) below the thermo-conducting sheet or facing the internal surface of the thermo-conducting sheet.
  • the grooves (12) form a grid of flow channels and the protrusions or ridges (13) can be formed in a symmetrical mesh as shown.
  • the groove (12) and protrusion (13) construction can be prepared to direct the liquid flow with more open groove areas and/or be made with narrow grooves forming a relatively more flow impeding area in order to secure a uniform turbulent flow speed in fluid contact with the internal surface of the thermo-conducting sheet.
  • FIG. 5 shows a stack of heat exchange units forming a heat exchange module.
  • This example shows a heat exchange module (20) built up by a plurality of planar heat exchange units and also shown are the flows of first liquid media (C, D) and second liquid media (A, B) providing counter flow like heat exchange operation.
  • first liquid media C, D
  • second liquid media A, B
  • thermo-conducting sheet a heat exchange unit with more than one flow area section or heat exchange area, where each flow area is in fluid connection and edgewise liquid tight sealed by bonding of a thermo-conducting sheet.
  • This embodiment might provide multiple, such as 4, 5, 6 or more separate flow areas (6) on either side of the supporting plate, each area being fluidly connected consecutively to the next, so that a flow path from exit (5) to exit (4) is formed.
  • Heat exchange areas may be connected with multiple internal flow distribution channels (9A/9B) and fluid connecting perforations (10A, 10B) in either end of the channels, forming an outlet from one flow area and an inlet to the next flow area. Perforations and internal channels are positioned to give a uniform flow over the flow area (6) below the thermo-conducting sheet(s) (7, not shown here).
  • Reasons for selecting multiple, such as more than one, heat exchange areas can be many, such as directing the flow or cleaning media flow path, bonding method for thermo-conducting sheet, size of thermo-conducting sheet area, stiffness of supporting plate and fabrication method of supporting plate.
  • the bonded assembly of a plurality of heat exchange units shall have a sufficiently rigid structure to provide good dimensional stability under mechanical, thermal and chemical stress.
  • All unit parts can be of food and pharmaceutical grade material with traceable origins, making the heat exchange unit and modular assembly suitable for heat exchange operations of liquid human food, consumables, pharmaceuticals, and the likes.
  • the plate materials used are preferably of a plastics material that can be reused by re-melting, or be burned as a clean fossil-like fuel.
  • thermo-conducting sheet All plastics parts of the unit can be produced by 3D printing or sintering of other means.
  • the skilled person in thermal processes will know that the heat exchangers described herein can also be used in heat exchange for gas-to-gas as well as for gas-to-liquid media, where gas tight conditions are required, such as for evaporation and or condensation on either one or both sides of the thermo-conducting sheet.
  • the first and the second liquid media exhibit a temperature difference
  • the second liquid medium may be the process medium in typical industrial applications, such as dairy, e.g. milk for pasteurization, and the first liquid medium typically being water.
  • the supporting plate (1) comprises at least two fluid connections (4, 5) and at least two internal flow distribution channels (9A, 9B), defining at least two independent sets of flow paths through said supporting plate which are in fluid connection with the at least one flow area (6), each set of flow paths comprising at least two fluid connections (4, 5) being in fluid connection, and at least one internal flow distribution channel (9A
  • thermo-conducting sheet (7) comprises an additional open mesh between opposite juxtaposed heat exchange units (7), said additional open mesh being configured for flow of second liquid media and creating a turbulent flow between said planar heat exchange units at low flow volume, while also keeping the thermo-conducting sheets (7) fixed, hereby allowing for flush of the thermo-conducting sheets with a negative pressure across the thermo-conducting sheet.
  • Example 1 Manufacture of a heat exchange unit and module prototypes.
  • planar heat exchange units are built up into a rigid stack of 33 plates forming a heat exchange module of 2.5 square meter of heat exchange surface.
  • each protruding exit is heat-bonded to the exit of the juxtaposed plates, and the bonding points on the perimeter are also heat-bonded together so that these together with the exits secure a uniform distance of 1.6 mm of free gap between the plates.
  • the protruding exits have an internal diameter of 16 mm, and in the built up module there are 4 exits where in operation 2 of these are entries for the first media and 2 are exits for said first media.
  • the exits each connect to the internal manifold in the plates and said manifold is formed by 2 mm channels in the plate formed when the 2 half plates are connected.
  • the internal channels lead to the first flow area connecting to this through slits in the plate and same design I used between consecutive flow areas, and from last flow area to the other protruding exit.
  • the heat exchanger module is then positioned into a pressure withstanding molded polypropylene flow housing where there are four 16 mm fluid connections for the first media: 2 openings for inlet and 2 openings for outlet, where said exits are sealingly connected to the heat exchanger module as well as sealed in towards the flow housing.
  • the second media can enter the heat exchanger module through a 200 mm x 200 mm opening in each end of the housing giving access to the gaps between the stacked heat exchanger plates.
  • the flow housing allows for several heat exchange modules in flow housings to be stacked forming large, longer heat exchangers. In given example 4 housings are stacked making an assembled unit with 10 sqm heat exchange surface. Results achieved.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

The invention relates to a liquid-to-liquid heat exchange unit, which provides a planar, rigid heat exchange plate for cooling or heating of liquid media, said plate having a planar thermo-conducting sheet, which is fluid tight bonded at its edges to the surface of a hollow supporting plate comprising fluid connections, internal flow distribution channels, and a flow area for a first liquid medium, and the thermo-conducting sheet being in fluid contact with said first liquid medium at its internal surface and being in fluid contact with a second liquid medium at its external surface.

Description

HEAT EXCHANGE UNIT AND ASSEMBLY
Field of the Invention
The present invention relates to a planar, heat exchange unit for heat exchange between two liquid media, said unit having a thermo-conducting sheet or thin foil that is suitable for heat transfer bonded onto at least one external or outer surface of a supporting plate with integrated flow paths for a first liquid media inside the plate and the thermo-conducting sheet being in fluid contact with an outer second liquid media. The heat exchange unit comprises a supporting plate having a first and a second planar, preferably rectangular, surface enclosing at least two connected exit openings, internal flow distribution channels, and at least one flow area or flow area for a first liquid media, said flow area being formed to enable fluid contact between said first liquid and the internal surface of a thermo-conducting sheet bonded at the perimeter onto the planar outer surface, said flow area being provided with perforations, preferably along opposite edges of the flow area, forming a fluid connection between flow area and internal channels, and said flow area being sealed at its periphery with the periphery of the thermo-conducting sheet, the external surface of which is in fluid contact with a second liquid media, thus enabling heat exchange.
In addition, the present invention relates to an assembly of at least one planar, rigid, heat exchange unit into a heat exchange module for heat exchange between two liquid media streams. The heat exchange module may, e.g. be configured for counter flow or mixed flow liquid-to-liquid heat exchange. The modules may be connected in series to serve any larger needs for heat exchange between liquid media.
The invention further relates to the use of the heat exchange unit and module for heat exchange of liquid media having sanitary requirements, e.g. heat exchange, including pasteurization, of liquid dairy products, and of highly viscous media, as well as liquid media having a content of suspended solids.
Description of the Prior Art
Apparatuses for heat exchange between two liquid media are generally composed of a thermo-conducting material, typically plates arranged in stacks of plates, and the apparatus is subjected to a liquid flow on both sides of the thermo-conducting plates, such as stainless-steel plates. The heat exchange plates of the prior art are typically pressed plates of a sufficient thickness, such as 0.8 mm to 2 mm being able to withstand relatively high pressures without being deformed during manufacturing and operation. The high plate thickness leads to decreased heat conduction and a large material consumption in the final product, which typically is very heavy and requiring considerable mechanical assembly and fastenings means.
There are three typical configurations of plate heat exchangers: gasket, fused and welded. The gasketed units are plate and frame types, where a very thick frame plate is used to squeeze a large number of gaskets positioned between plates. This
configuration may be disassembled and cleaned, however the gaskets often leak. The fused or solded units, as well as the welded units cannot be cleaned, so if the heat surface becomes dysfunctional or the flow path is blocked, the unit has to be scrapped. A disadvantage of thermo-conducting metal sheets is that they are easily corrodible when in contact with, e.g. even slightly acidic media.
It is a purpose of the present invention to provide a heat exchange unit which is lighter than the prior art heat exchange units; which has improved flow turbulence for increased heat exchange; which allows for simple cleaning operation; and, among other advantages, is easily scalable. In addition, it is an object of the present invention to provide a planar heat exchange unit having a simple plate-like construction, with optimized internal flow path in a supporting plate for a first liquid medium to be cooled or heated, where the medium is in fluid contact with the internal surface of a thermo- conducting sheet being bonded to at least one surface of the supporting plate, and being optimized for reduced pressure loss of a second medium to be cooled or heated while flowing past the external surface of the thermo-conducting sheet.
Summary of the invention
This is achieved with a heat exchange unit, which provides a planar, rigid heat exchange unit for cooling or heating of liquid media, wherein a planar thermo-conducting sheet, which is fluid tight bonded at its edges to the surface of a hollow supporting plate comprising a flow area for a first liquid medium, the thermo-conducting sheet being in fluid contact with said first liquid medium at its internal surface and being in fluid contact with a second liquid medium at its external surface. The flow area is connected through a flow path to at least two exit openings or fluid connections for the first liquid medium, and the flow path comprising internal flow distribution channels and spaced apart holes or perforations leading to the flow distribution area for liquid contact of the first medium with the internal surface of the thermo-conducting sheet, thus providing heat exchange between the two liquid media.
In addition, the thermo-conducting sheet may be liquid tight bonded to the supporting plate at one or more additional points or lines.
In an embodiment, the supporting plate of the heat exchange unit comprises two half- plates. The half plates may be bonded together.
The supporting plate is typically formed by liquid tight bonding, such as edgewise bonding or heat-fusion of the two fitting half-plates. The half plates may be made of a light material, such as plastics which allows for the half-plates to be formed by molding. The supporting plat of the heat exchange unit, comprising bonded first and a second half-plates, further comprises first and a second rigid outer surface. The half plates encloses at least two internal flow distribution channels, being fluidly connected through perforations with a flow area positioned on one or both rigid outer surface(s) of the supporting plate. The heat exchange unit comprises at least one thermo-conducting sheet positioned liquid tight bonded adjacent to and covering the flow distribution area on each of the surfaces of the supporting plate. The supporting plate may further comprise at least two fluidly connected fluid connections or exit openings. The fluid connections has protruding rims and extend perpendicular to the surface of the supporting plate. The internal flow distribution channels extends from the fluid connections through the perforations and the flow area(s) thus defining an internal flow path for a first liquid medium through said heat exchange unit.
Each of the internal flow distribution channels is preferably formed as an elongate groove or depression in an inner surface of one or both of the half plates. In
embodiments, where the internal flow distribution channels are formed as elongate grooves or depressions in an inner surfaces of both of the half plates, each internal flow distribution channel is formed from mating/cooperating grooves/depressions formed in each half plate.
Objects of the invention may further be achieved by a heat exchange module comprising a plurality of heat exchange units as mentioned above, wherein the at least two fluid connections comprises protruding rims, and where the supporting plates further comprises bonding points functioning as distance points together with the protruding rims thus forming a gap between the heat exchange units for passage of a second liquid medium in-between two adjacent heat exchange units when stacked.
The heat exchange units of the heat exchange module may be fluidly connected at the above mentioned fluid connections to allow passage of a first liquid medium between the heat exchange units of the heat exchange module.
The heat exchange units of the heat exchange module may further be bonded to each other at said bonding points functioning as distance points, such as through thermal bonding into a module.
In an embodiment of the heat exchange module, the fluid connections with the protruding rims may be formed integral with the supporting plate. Alternatively, the protruding rims are formed from insertion of loose inlet pieces.
The thermo-conducting sheet can be a thin foil of a thermo-conducting material, such as a metal, such as stainless steel, aluminium or die cast aluminium alloys; or of heat conducting plastics or a hybrid material, such as polysulfone or nylon having heat- conductive additives including graphite, carbon fibers, and ceramics such as aluminum nitride and boron nitride. The thermo-conducting sheet used for heat exchange is preferably impermeable to the type of liquid media to be cooled or heated.
A useful thin foil of a thermo-conducting material is based on PP, Polypropylene, with an added thermal conductivity component is, e.g. TECACOMP® TC (Ensinger, Ensinger Platz, Seewalchen am Attersee, Austria) whereby thermal conductivity can be up to 25 W/(m-K) depending on the filler used, and as thermoconducting sheet can be, e.g., only of 0.1 mm thickness for efficient heat exchange in a unit or module of the invention. An alternative thin foil of a thermo-conducting material is based high alloy stainless steel whereby thermal conductivity can be very high, and as thermo-conducting sheet can be as example only 0.05 mm of thickness, a very efficient heat exchange can be obtained, and at the same time consumption of high value material is minimal. In some executions of the foil, a preforming of the sheet may be used to secure improved bonding to the plastic base plate and at the same time this preforming can counteract problems caused by differences in thermal expansion between plastic and metal. In certain embodiments of the units and modules of the invention the thermo-conducting sheet is made from a woven or non-woven polypropylene sheet having a filler of thermo-conducting plastic material molded into and on top of the woven or non-woven sheet. Types of useful polymeric mixed plastics materials may be formed into suitable liquid and/or gas impermeable, heat conducting thin sheets using the methods and combinations of materials, and methods for making membranes by forming a nanofibrous layer on a macroporous support layer and applying polymer to the nanofibrous layer, disclosed in US Pub. No.: US 2015/0059578 Al (Huizing et al.) the contents of which are hereby incorporated by reference. For use in embodiments of the present invention the composite membranes taught by Huizing et al. may advantageously be given a final coating with an impermea ble polymer.
In an embodiment of the heat exchange module of the invention one first liquid medium to be heat exchanged can flow in the channels and flow distribution areas formed inside the supporting plates having one or more thermo-conducting sheets bonded to their planar outer surfaces, while a free flow of a second liquid medium is maintained on the outside and flowing through gaps between the stacked plates of the module. The heat exchange second liquid media can be highly viscous and even contain larger particulate impurities, as long as the media does not block the free flow passage outside or between the heat exchange plates.
Surprisingly, the present invention enables cleaning at both external surfaces of the heat exchange unit and in modular unit assemblies as well as at the internal surfaces inside the supporting plate(s) at the flow path for the first liquid medium in the heat exchange unit.
The heat exchange module of the invention is suita ble for applications, such as milk pasteurization, where sanitary requirements can be fulfilled with external flushing between module plates as well as with internal cleaning flushing of the flow paths of the supporting plate. In addition, the heat exchange module is highly resistant to corrosion when having a polymer based thermo-conducting sheet.
Furthermore, the heat exchange modules of the invention may be used for energy exchange of hot and cool flows in large scale district heating system based on hot or warm water.
Definitions
The term "thermo-conducting sheet" as used herein shall mean a thin thermo- conducting foil or membrane capable of being bonded or sealed liquid tight to a supporting plate, typically a plastics plate. A "thermo-conducting sheet" as used herein is relatively thin and can be flexible, typically made by rolling a metal or plastic sheet into thin foil or by casting of a hybrid polymeric or plastics material, e.g. such as highly rigid polypropylene having suitable thermo-conduction enhancing additives.
The term "flow area" as used herein shall mean a confined and optionally corrugated or mesh like surface area of a supporting plate. The flow area may serve as a flow distribution area or heat exchange area for a first liquid medium in fluid contact with a thermo-conducting sheet. The flow area defines the area available for heat exchange at the internal surface of the thermo-conducting sheet. The terms "flow area", "flow distribution area" and "heat exchange area" are used interchangeably herein, but where the term "heat exchange area" when used for a heat exchange unit of the invention preferably describes the combined flow distributions areas on both sides of said unit. The term "fluid connection" or "exit opening" as used herein shall mean an opening for a flow of liquid media into and/or out of the support plate(s) of the planar heat exchange unit and heat exchange module of the invention. Thus, each fluid connection/ exit opening t allows access to both sides of the unit or the module, and one or both sides can be connected to the flow of the first media. At least two fluidly connected exits provide for functional flow operation of the unit. The fluid connection/exit openings are connected through various internal flow distribution channels leading through perforations to the external flow areas on the supporting plate, thus allowing flow of liquid media from one exit opening to the other, such as through pumping. In certain embodiments the connected exits are located at opposite ends of the planar unit. The terms "heat exchange module" and "heat exchange unit assembly" are used interchangeably herein and are used for the subject matter of Figure 5 as well as for modules and unit assemblies when integrated with various connecting parts in housings and systems for heat exchange.
The terms "first liquid medium" and "first liquid media" (to be cooled or heated) are interchangeably used herein and are used for the media flowing internally in the hollow supporting plate and being in fluid contact with the internal surface of the heat exchange thermo-conducting sheet.
The terms "second liquid medium" and "second liquid media" (to be cooled or heated) are interchangeably used herein and are used for the media flowing externally on the heat exchange unit and being in fluid contact with the external surface of the heat exchange thermo-conducting sheet.
The terms "to be cooled or heated" and "to be heat exchanged" are used
interchangeably herein and used to characterize a liquid medium or media flowing internally in a hollow supporting plate of the heat exchange unit of the invention or externally in fluid contact with the heat exchange unit.
"Internal surface" of the heat exchange thermo-conducting sheet shall herein mean the thermo-conducting sheet surface facing the outer surface of the supporting hollow plate and being in fluid contact with the first liquid medium.
"External surface" of the heat exchange thermo-conducting sheet shall herein mean the thermo-conducting sheet surface facing the external or second liquid cooling or heating medium.
The terms "liquid tight sealing", "fluid tight sealing", and "liquid tight bonding", etc. are used interchangeably herein and may also specify gas tight sealing when the heat exchange unit of the invention is suitable for heat exchange of gas-to-gas (air-to-air) or gas-to-liquid.
The term "viscous media or media having suspended solids" as used herein shall mean liquid media, such as dairy products, fruit and vegetable juice, mineral and vegetable oil, waste water of many kinds, media streams having a corrosive effect and the like. Brief description of the drawings
Fig. 1 is a perspective view of a heat exchange unit comprising the supporting plate (1) comprising two half-plates (2, 3), fluid connections (4, 5) with protruding cylindrical rims (4', 5'), flow area (6), thermoconducting sheet (7), bonding points (8), internal flow distribution channels (9A, 9B), perforations (10A, 10B) leading to the flow area (6).
Fig. 2 is an exploded perspective view of a heat exchange unit showing the various parts forming the unit as shown in Figure 1, and showing in detail an embodiment of internal features, such as a guided flow distribution with two opposite fluid connections (4, 5) having fluid connection to five channels (9A and 9B) with manifolding to/from multiple (twentyfive) perforations (10A, 10B) arranged in a line and leading flow to the flow area (6)of the two half-plates forming the supporting plate.
Fig. 3 is a cross-sectional view perpendicular to the longitudinal extension of a heat exchange unit, showing the two half-plates (2, 3), an exemplary liquid media flow distribution channel (9A, 9B), perforations (10A, 10B), grid structure or mesh with groove (12) and ridge (13), thermo-conducting sheet (7) and inlet and outlet to and from the flow area,
Fig. 4 is a top view of the grid or mesh with groove (12) and ridge (13) forming the flow area (6) available for heat exchange in fluid contact with the internal surface of the heat exchange thermo-conducting sheet.
Fig. 5 is a perspective view of a heat exchange unit assembly (20) built up as a heat exchange module with fluid connections for flow of first liquid media (C, D) and gaps between plates for flow of second liquid media (A, B).
Detailed description of the invention
Certain embodiments of the present invention relates to a rigid, planar heat exchange unit assembly, wherein said heat exchange plate comprises at least a first and a second exit (4, 5) opening for a liquid medium, and where internal channels extend from said first exit opening (4) to said second exit opening (5) and in between enters and exits through perforations (10A, 10B) to at least one flow area (6) sealingly covered by a thermo-conducting sheet (7), where said perforations may comprise slits or holes making fluid connection between the flow area and the internal channels (9A, 9B), said flow and flow area being formed as mesh like channels (12, 13) on and as a part of the outside of the supporting plate (1), said mesh formed to ensure a flow area between a covering thermo-conducting sheet and the heat exchange plate surface, said thermo- conducting sheet being bonded at the perimeter of the flow area.
Hereby is achieved the possibility, with very minute pressure loss, to flush or create a cross flow over all areas of the inside of the supporting plate with a turbulent stream from one exit opening being in fluid connection to another exit opening, or the possibility to flow from one or both exit openings while at the same time having the possibility of applying a hydraulic pressure on the external surface of the thermo- conducting sheet from an unimpeded cross flow of cooling or heating liquid media outside the heat exchange unit. An applied pressure on the external surface of the thermo-conducting sheet may be needed to drive the flow and to keep the thermo- conducting sheet fixed during operation.
The supporting plate comprises at least one flow distribution area of the outer surface of the supporting plate, said area being available for heat exchange and being overlaid with and sealed at the perimeter by a thermo-conducting sheet, thus being positioned adjacent to said flow distribution area. The thermo-conducting sheet is bonded along the perimeter of said flow area, which is available for heat exchange. The bonding provides liquid tight sealing of the internal surface of the heat exchange sheet from the outside of the heat exchange unit or module.
Said flow area (6) is formed as an integral part of the supporting plate (1) and comprises indents or channels (12, 13) forming a mesh like flow area that can lift up the thermo- conducting sheet to withstand a hydraulic pressure, while allowing a substantial flow between said internal surface of the thermo-conducting sheet and the supporting plate, even when a pressure being applied from the outside on the heat exchange unit compresses the thermo-conducting sheet towards the surface of the supporting plate. The thermo-conducting sheet may partly take form from the supporting flow area due to the outside pressure, hereby forming a corrugated surface increasing heat exchange efficiency.
The flow area on the support plate is formed with at least one entry and at least one outlet and with the flow area between said entry and exit being formed by perforations leading to internal channels, said channels leading to the fluid connections, such as by connecting to the exit opening through a manifold. Said entry and outlet may be formed by multiple perforations in either side of the flow area, hereby ensuring a uniform flow over the entire flow area available for heat exchange, and ensuring minimal pressure loss through an adequate number of perforations, said perforations still small enough to ensure the lifting function for the applied pressure on the thermo-conducting sheet on said mesh.
Said flow distribution area together with said channels and connected fluid connections allow for unimpeded and controlled flow of the first liquid medium through the supporting plate leading to enhanced turbulence conditions at the internal surface of the thermo-conducting sheet. The unimpeded flow of the first and the second liquid media allows for a very homogenous pressure gradient over the thermo-conducting sheet, thus improving operational lifetime and making it possible to create a turbulence optimized over the entire sheet surface leading to a substantial turbulence and heat exchange improvement of the thermo-conducting sheet area.
In an embodiment, said supporting plate of the heat exchange unit comprises two half- plates which are bonded together at the periphery, where the two half-plates are identical in shape keeping the number of different parts of the unit/module at a minimum. The bonding at the perimeter of the plates seals the internal surface of the thermo-conducting sheet from the cooling or heating first liquid medium flowing past the external surface of the thermo-conducting sheet without any further need for a gasket. More bonding areas may be added inside the supporting plate edge or perimeter to make the planar unit more rigid.
In an embodiment, the assembly of the heat exchange unit is comprised by fusing of a thermo-conducting sheet onto the outer surface of the supporting plate, which in turn is formed by bonding, such as by fusion or in molding, of two identically shaped half- plates, and where the fluid connections are formed by integrated parts of the two half- plates.
In an embodiment, said at least two fluid connections for the first liquid medium are positioned at a distance from each other, whereby it is possible to clean the flow distribution channels and area of the heat exchange unit effectively by flushing from one exit to the other exit by flushing with a cleaning liquid. In an embodiment, the external surface of the thermo-conducting sheet has a mesh structure, such as an overlaying fishbone like curve-shape similar to that seen in conventional plate heat exchangers. This overlaying shape is dimensioned to increase turbulence of the external flow of the second liquid medium, hereby optimizing heat exchange capacity at comparably lower external flow volumes.
In an embodiment, said at least two fluid connections extend transversely to the planar surface of the supporting plate. The exits being perpendicular to the horizontal plane of the supporting plate allow for a large access area to the internal flow distribution channels and flow distribution areas forming the heat exchange area, and, at the same time, the relatively large channels reduce counter pressure of flow to the exits. Thus, high flow speeds between the two fluid connections during heat exchange flows or during cleaning operation are possible.
In an embodiment, said supporting plate comprises on its planar sides two or more cylindrical rims or studs or protrusions surrounding the fluid connections. The combined or stacked cylindrical protrusions, when the heat exchange plates are stacked together, form the exit path for the first liquid medium while keeping the number of assembly parts to a minimum. Said connected exits forming the exit manifold can be fused together at contact areas, hereby forming a manifold sealing the first internal media from the second external media. Alternatively, the cylindrical, protruding rims may be in the form of loose inlet pieces, such as is preferably made of the same material as the supporting plate, e.g. a plastics, such as described herein below.
In an embodiment, said heat exchange unit or heat exchange modular assembly comprises at least one heat exchange thermo-conducting sheet in fluid tight bonding or sealing onto a supporting hollow plate. Hereby, each heat exchange unit may comprise two layers of thermo-conducting sheets, i.e. provided on both sides of the supporting plate, such as where the internal surface is protected against the pressure exerted against the lifting points formed by the corrugated or fishbone-like contact points of the mesh like structure.
In an embodiment, said supporting plate comprises, e.g. at its edge or perimeter, one or more bonding points for bonding two adjacent planar heat exchange units or bonding of a heat exchange unit to an overlaying unit in a stack of heat exchange units forming a module. The bonding points together with the protruding exit opening rims define the distance between two planar heat exchange units in a stack or module. Said protruding exits of adjacent heat exchange units are bonded, such as by heat fusion, to achieve sealing between fluid connections to provide an integrated flow path to the outside and external flow connections for liquid heat exchange media or for connections to a flow of cleaning liquid through the bonded plurality of planar heat exchange units forming the module.
The heat exchange units are planar and can be stacked together using a few plates to many dozens of plates forming one bonded rigid heat exchange module. The heat exchange units are stacked with spacing for the external or second media to be heat exchanged, offering a gap outside for access or flow of media between the units and in contact with the external surface of the thermo-conducting sheets. The gap between plates, e.g. as illustrated in Fig. 5, can be dimensioned to secure a free and unimpeded flow of media (A, B) to be heat exchanged and allows for flow of viscous media or media having suspended solids.
The free gaps between heat exchange plates or planar heat exchange units allow for inspection of the thermo-conducting sheet and other parts being in touch with the liquid media thus making visual inspection of cleaning operation and heat exchange process possible.
In one embodiment, an assembly of the heat exchange units of the invention comprises a plurality of planar heat exchange units, forming a rigid heat exchange module, said heat exchange plates are situated parallel juxtaposed having the heat exchange area facing the heat exchange area of an adjacent heat exchange plate. Said plurality of heat exchange plates forming a square or rectangular entry for the second liquid media, such that said media is able to pass between the planar heat exchange units allowing for a large thermo-conducting sheet area (heat exchange area) on a small foot print. The protruding exits of each supporting plate of the heat exchange unit combined, such as bonded together by, e.g., welding or melting, form two or more combined exits extending transversely to the surface of said heat exchange module.
In one embodiment of said plurality of heat exchange units forming a heat exchange module, the gap between the planar heat exchange units is filled with a spacer netting or mesh that creates turbulent flow over the heat exchange area even at low cross flow volumes of the liquid media and at the same time keeping the thermo-conducting sheet in place at low or negative pressures applied to the thermo-conducting sheet.
In one embodiment of said plurality of planar heat exchange units forming a heat exchange module, said plurality of units is placed in a housing, said housing forming a square or rectangular inlet and outlet for the liquid media to be heat exchanged, thus guiding the external second liquid flow and the internal first liquid flow at inlets and outlets that in exemplary embodiments are provided transversely from the housing. The bonded supporting plates with the attached thermo-conducting sheets each form a pressure vessel so that when a flow and a pressure are applied through an exit opening, a flushing of the plate may take place, between two exits, thereby cleaning, i.a. the internal surface of the bonded thermo-conducting sheet.
The invention provides a heat exchange plate unit which has, with respect to known liquid-to-liquid heat exchangers, such as plate heat exchangers, the advantages of having at the same time:
1) a flushable interior side, such as for turbulent flow of a heat conducting media or for flushing with a cleaning liquid,
2) an external free flow of a second liquid stream to be heat exchanged,
3) a varied free-flow gap being defined by the possibility for variation of gap distance between heat exchange plates (1 to 6 mm) when stacked,
4) a possibility to use a very thin thermal conducting sheet improving heat transfer through short thermal path,
5) a possibility to use a very thin thermal conducting sheet reducing the need for thermal conductive material to an absolute minimum,
while having the individual planar heat exchange units manufactured of relatively small thickness, however still rigid (3-8 mm thick supporting plate consisting of 2 bonded half- plates), all of which making a very compact and light heat exchange unit possible.
The heat exchange modular assembly has a shortened length of the paths of the liquids to be heat exchanged (10 to 100 cm) and a non-impeding (5 to 100 cm long) but relatively large inside flow area available for heat exchange, combined with a large active area (up to about half of heat exchange plate thickness), a plurality of flow leading channels for the first liquid stream or discharge leading to at least two larger perpendicular fluid connections, and an overall structure with sufficient mechanical strength for it to keep a constant geometry at high cross flow rates and pressure gradients, guaranteeing the stability of the hydrodynamic conditions, under pressure, media and temperature constraints and at a satisfactory constructional cost.
The flow area used for heat exchange between the two liquid media may be in one embodiment formed with a mesh like channel structure where channels are 0.2-2.0 mm wide giving similar space between ridges (13) for lifting the thermo-conducting sheet, the ridge or lifting area formed without sharp points or ridges securing a sufficiently gentle carrier surface against outside pressure on the thermo-conducting sheet. The heat exchange area flow distribution channels, perforations (slits and holes) as well as internal channels are formed hydrodynamically, securing that minimal blocking and pressure loss will take place in the internal liquid flow path from and through the fluid connections. The slits or holes connecting the inside channels with flow area on the outer surface of the supporting plate are dimensioned to the needed flow and to physical size to needed lifting of thermo-conducting sheet, typically 0.2-2.0 mm wide. The heat exchange units can be sized according to need for heat exchange area as well as to cost optimized production and are typically from 10 cm by 10 cm of heat exchange area up to 50 cm by 100 cm heat exchange area. The typical size for industrial applications is 20 cm by 20 cm up to 20 by 100 cm heat exchange area.
The planar heat exchange units are typically made of 3-8 mm thick supporting plates made up by two half-plates. The plate design, material and thickness are dimensioned to ensure a rigid construction of the unit and assembled modules under turbulent external and internal flow.
The inside flow distribution channels formed by the two half-plates can be of rounded cross section, and typically around half of the plate thickness in diameter as individual channels or be made up by mesh type volumes. However, in either case, the design must consider flow and pressure losses, avoiding very low or very high flow speed areas. For example, a mesh-like flow area may be formed as a fishbone structure that allows flow distribution while keeping distance to the internal surface of the thermo- conducting sheet at contact points.
The inside channels lead to plate fluid connections that can be designed to lead specific types of liquids from the stacked assembly of heat exchange units to the exit with negligible pressure loss. Typically, the plate exits are 10-50 mm in diameter. Materials used for the heat exchange unit plate parts are typically plastics, such as polymeric or co-polymeric thermoplastics, but can be of hybrid material or metallic origin or any other suitable material that can be bonded and withstand the liquid media to be heat exchanged, the temperature span needed, typically 5-95 degrees Celsius as well as the medias used for cleaning the units and modular assemblies. The choice of material must foresee thermal expansion and rigidity of the heat exchange unit/module. Preferred execution is heat exchange plates in molded plastic material, such as polypropylene, and with, e.g., a polymeric based hybrid thermo-conducting sheet used for heat exchange. Other executions can be as sintered parts or 3D printed versions in various materials.
Bonding of the various parts into one unit including half-plate to half-plate liquid tight bonding, thermo-conducting sheet to supporting plate liquid tight bonding and heat exchange units into stack bonding may be by laser welding, direct or indirect heat welding, in mold fabrication, ultrasonic welding, use of glue or hot-melt or solvents, or mechanically bonding with mechanical elements or connections designed into the parts. In the preferred execution, plastic parts are welded together through heat applied melting of very specific areas of the designed parts, said heat exchange plate parts being molded by injection molding of polymer thermoplastic. The thermo-conducting sheet may be bonded to the plate using a combination of hot-melt, in molding and welding to achieve liquid tight sealing.
By using thermoplastics such as polypropylene or polyethylene, the material of the supporting plate (or half-plates) can be recycled through re-melting of the plastic.
In an embodiment of the heat exchange assembly of the invention, the second liquid medium is pumped at a speed of typically 1 to 5 meters per second across the external surface of the thermo-conducting sheet to keep a high heat conducting efficiency and to keep possible suspended solids from building up and depositing on the thermo- conducting sheet. The first liquid medium is pumped at a speed of typically 0.5 to 2.5 meters per second through the flow distribution channels and flow distribution areas and heat exchange area in the supporting plate and across the internal surface of the thermo-conducting sheet to keep a high heat conducting efficiency and to keep the boundary layer on the internal thermo-conducting sheet surface as small as possible, hereby keeping the heat exchange efficiency high and functional in operation for a longer time.
An embodiment of the invention is a heat exchange unit, which provides a planar, rigid heat exchange unit for cooling or heating of liquid media, wherein a planar thermo- conducting sheet, which is fluid tight bonded at its edges to the surface of a hollow supporting plate comprising a flow area for a first liquid medium, the thermo- conducting sheet being in fluid contact with said first liquid medium at its internal surface and being in fluid contact with a second liquid medium at its external surface. And in this embodiment the flow area is connected through a flow path to at least two fluid connections for the first liquid medium, and the flow path comprising internal flow distribution channels and holes or perforations leading to the flow area for liquid contact of the first medium with the internal surface of the thermo-conducting sheet, thus providing heat exchange between the two liquid media. An additional embodiment of the invention is a heat exchange module as disclosed herein comprising a plurality of heat exchange units each comprising a rigid, planar and partly internally channeled supporting plate (1) formed by liquid tight bonding of two planar, essentially identical, half-plates (2, 3) and a thermo-conducting membrane (7) in fluid contact with a first and a second liquid media having different temperatures, and where the thermo-conducting membrane (7) is at least peripherally bonded to and covering a flow distribution area (6) for the first liquid medium on the supporting plate (1), where the flow area (6) is formed as a grid having drainage grooves (12) and raised contact points (13) supporting the internal surface of the membrane (7); while at the same time allowing the second liquid medium to be in fluid contact with the external membrane surface; the supporting plate (1) having perforation slits or holes (10A, 10B) connecting the flow area (6) and the at least one channel (9A, 9B).
An additional embodiment of the invention is a heat exchange module as disclosed herein comprising two or more planar heat exchange units being situated parallel juxtaposed having the external surface of the membrane (7) on one unit facing the external surface of the membrane of an adjacent unit, said plurality of units forming a stack of square or rectangular entry geometry for a liquid media (A), such that said media is able to pass between the planar heat exchange units, and where the at least two perpendicular fluid connections (C, D) are formed by discrete inlet pieces, such as cylindrical or ring-shaped inlet pieces, or formed as integrated parts of said half-plates (2, 3), and where the distance between the planar units is defined by the height of the rims of the fluid connections (4, 5) and of the bonding points (8), cf. Fig. 5.
Detailed description of the drawings
Other features and advantages of the invention are disclosed in the following description and examples of drawings, embodiments, working examples, and applications within cooling and heating of liquid media, with reference to the accompanying drawings and reference numbers therein.
Figure 1 Illustrates one embodiment of the heat exchange unit which may be formed by a) bonding at least one thermo-conducting sheet (7) onto a supporting plate (1) having internal preformed flow distribution channels (9A, 9B) in fluid connection (not shown) with a plurality of perforations (10A, 10B) opening onto a flow area (6) on at least one outer side, where the bonding provides liquid tight sealing along the edges or periphery of the flow area (6); and
b) the supporting plate being formed by bonding of two equal-size half-plates (2, 3) along their edges, where the bonding provides liquid tight sealing, and the supporting plate (1) being provided with two fluid connections (4, 5) are provided with a cylindrical rim and internal fluid connection with the flow distribution channels (9A, 9B).
In addition, the supporting plate (1) may be provided with protrusions (8) distributed spaced apart along the edges of both sides of the plate. The protrusions (8) function as bonding points when two or more heat exchange units are stacked into a heat exchange module.
In the illustrated embodiment, the fluid connections (4, 5) of the heat exchange unit is on opposite ends of the heat exchange area (6) and the heat exchange area is covered with an adjacent thermo-conducting sheet with a cut out showing the corrugated or mesh like flow area (6) below the thermo-conducting sheet. As indicated, multiple internal channels (9A and 9B) connect the two fluid connections on the plate (1) to the flow area via the perforations (10A, 10B) in either end of the flow area hereby forming a flow path under the thermo-conducting sheet from exit (4) to exit (5). Bonding points (8) used when staking the plates into a module are also indicated. Said bonding points (8) together with the cylindrical, protruding fluid connections (4, 5) define the distance between two plates (1). In the shown embodiment, the two half-plates (2, 3) are identical or laterally reversed. In some embodiments, the perforations (10A, 10B) constitutes of slits and/or holes.
An embodiment of the invention provides a rigid, planar heat exchange unit, comprising an internally channeled planar supporting plate (1) formed by liquid tight bonding of two planar, typically identical, half-plates (2, 3), the heat exchange effect obtained through a thermo-conducting sheet (7) in fluid contact with a first and a second liquid media having different temperatures, and where the thermo-conducting sheet (7) is peripherally bonded to and covering a flow area (6) for the first liquid medium on the supporting plate (1), where the area (6) is formed as a grid having raised contact points (13) supporting the internal surface of the thermo-conducting sheet (7); while at the same time having the second liquid media in fluid contact with the external thermo- conducting sheet surface; the supporting plate (1) having perforation slits or holes (10A, 10B) connecting the distribution area (6) and the at least one channel (9A, 9B).
The channels (9A, 9B) inside the plates are for leading the first liquid media in the flow area through perforations (10A, 10B) to at least two or more paired fluid connections (4, 5) being perpendicular to the horizontal plane of the supporting plate, the combined fluid connections forming integral exit channels when stacking multiple heat exchange plates into an assembly of heat exchange units.
In a configuration of the invention with at least two fluid connections in fluid connection, it is possible to lead a media stream contacting the internal surface of the thermo-conducting sheet to ensure optimal heat exchange or optimal flushing with liquid cleaning media from one exit (4 or 5) to the other exit (4 or 5).
The flow area surface (6) is covered by liquid tight bonding of a flat thermo-conducting sheet (7) along its perimeter whereby heat exchange can be achieved.
Figure 2 Illustrates an exploded perspective view of a heat exchange unit assembly with two half-plates (2, 3) and two thermo-conducting sheets (7). The upper half-plate (2) shows the outside surface (2s) of the supporting plate (1) with the flow area (6) being in each end or positioned just inside opposite ends of the flow path perforated with holes (10A, 10B), peripheral bonding points (8) and protruding fluid connections (4, 5). The lower half-plate (3) shows the internal half flow distribution channels (9A, 9B) forming full channels when half-plates (2, 3) are bonded together, the flow distribution channels connecting the plate fluid connections (4, 5) with the perforations (10A, 10B).
The embodiment shows a variation in layout of the inside channels (9A, 9B) forming a manifold for the flow distribution channels (9A, 9B). The shown manifold may in another embodiment be replaced with an internal flow volume, for example being fish-bone shaped, to keep spacing between the half-plates (2, 3).
The fluid connections (4, 5) can be placed as convenient, for example in opposite plate ends or corners or side by side, considering efficient flow or flow distribution of the channels (9A, 9B) as well as uniform flow distribution over the flow and heat exchange area (6).
In a larger plate, more fluidly connected fluid connections may be needed to secure flow and distribution of the first liquid medium.
The supporting plate comprises bonding points (8), the bonding points also functioning as distance points together with the protruding exit rims (4', 5') such that the second liquid medium can pass through the gap thus formed between the thermo-conducting sheet(s) in-between two adjacent heat exchange units in a module.
The bonding points (8) are here illustrated as a solid cylinder shaped protrusion extending transversely to the surface of the supporting plates (1). Alternatively, the distance between the plates can be supported by a mechanical member or bar positioned at the edge of the heat exchange unit.
Figure 3 Illustrates a cross-sectional view of a detail of a heat exchange plate unit, showing an example of a flow distribution channel (9A/9B), perforations (10A/10B), the grid structure of the flow area (6) and the adjacent thermo-conducting sheet (7). The grid or mesh like structure of the flow area (6) is formed as an integral part of the half- plates (2, 3) and may be formed with indentions, protrusions (13) and grooves (12), the grooves forming channels for flow and the protrusions forming support areas for the thermo-conducting sheet (7). The heat exchange area grooves or channels are connected to the internal channels via the perforations (10A, 10B). The openness of the flow area (6) is designed to support the thermo-conducting sheet, which again depends on the applied pressure on the thermo-conducting sheet during various operation types and the type of thermo-conducting sheet, as may be needed during operations using a relatively high pressure across the thermo-conducting sheet and a relatively thin or brittle thermo-conducting sheet may need several support points, protrusions or ridges (13), to ensure a free flow area in the grooves (12) facing the internal surface of the thermo-conducting sheet.
Figure 4 Illustrates a top view of an example of the grid forming the corrugated flow or heat exchange area (6) below the thermo-conducting sheet or facing the internal surface of the thermo-conducting sheet. The grooves (12) form a grid of flow channels and the protrusions or ridges (13) can be formed in a symmetrical mesh as shown. The groove (12) and protrusion (13) construction can be prepared to direct the liquid flow with more open groove areas and/or be made with narrow grooves forming a relatively more flow impeding area in order to secure a uniform turbulent flow speed in fluid contact with the internal surface of the thermo-conducting sheet.
Figure 5 shows a stack of heat exchange units forming a heat exchange module. This example shows a heat exchange module (20) built up by a plurality of planar heat exchange units and also shown are the flows of first liquid media (C, D) and second liquid media (A, B) providing counter flow like heat exchange operation. When the heat exchange module is in use, a first liquid flow enters at (A) and leaves at (B) and a second liquid flow enters at (C) and exits at (D).
During CIP cleaning - Cleaning In Place - liquid cleaning media are most often only used on the external or outer surface of the heat exchange units in a modular assembly, the cleaning liquid entering at (A) and leaving at (B), and often at high flow rates to ensure cleaning of all surfaces. The embodiment shown enables cleaning at the internal surfaces inside the supporting plates (1) at the flow path for the first liquid medium in a heat exchange unit and in modular unit assemblies. When this is needed, a cleaning flow may enter at (C) and leave at (D) (or vice versa), and at the same time a cleaning flow can enter at (A) and exit at (B) to ensure a sufficient pressure to keep the thermo- conducting sheet in place.
In addition, a heat exchange unit with more than one flow area section or heat exchange area is possible, where each flow area is in fluid connection and edgewise liquid tight sealed by bonding of a thermo-conducting sheet. This embodiment might provide multiple, such as 4, 5, 6 or more separate flow areas (6) on either side of the supporting plate, each area being fluidly connected consecutively to the next, so that a flow path from exit (5) to exit (4) is formed. Heat exchange areas may be connected with multiple internal flow distribution channels (9A/9B) and fluid connecting perforations (10A, 10B) in either end of the channels, forming an outlet from one flow area and an inlet to the next flow area. Perforations and internal channels are positioned to give a uniform flow over the flow area (6) below the thermo-conducting sheet(s) (7, not shown here).
Reasons for selecting multiple, such as more than one, heat exchange areas can be many, such as directing the flow or cleaning media flow path, bonding method for thermo-conducting sheet, size of thermo-conducting sheet area, stiffness of supporting plate and fabrication method of supporting plate.
Not shown in the presented illustrations are examples of internal channels (9A, 9B) formed as individual flow volumes instead of separate channels in a manifold. Also not shown are examples of a separate mesh positioned in between the planar heat exchange units when assembled into a heat exchange module. An open structured mesh squeezed in between heat exchange plates will further increase turbulence of the flow of the second liquid medium and protect the thermo-conducting sheet from hydraulic pressure differences.
The bonded assembly of a plurality of heat exchange units shall have a sufficiently rigid structure to provide good dimensional stability under mechanical, thermal and chemical stress.
All unit parts can be of food and pharmaceutical grade material with traceable origins, making the heat exchange unit and modular assembly suitable for heat exchange operations of liquid human food, consumables, pharmaceuticals, and the likes. The plate materials used are preferably of a plastics material that can be reused by re-melting, or be burned as a clean fossil-like fuel.
All plastics parts of the unit can be produced by 3D printing or sintering of other means. The skilled person in thermal processes will know that the heat exchangers described herein can also be used in heat exchange for gas-to-gas as well as for gas-to-liquid media, where gas tight conditions are required, such as for evaporation and or condensation on either one or both sides of the thermo-conducting sheet.
In preferred uses of the heat exchange module of the invention the first and the second liquid media exhibit a temperature difference, where the second liquid medium may be the process medium in typical industrial applications, such as dairy, e.g. milk for pasteurization, and the first liquid medium typically being water.
Additional embodiments of the invention are described below:
A heat exchange module (20), wherein said heat exchange unit assembly (20) comprises a plurality of planar heat exchange units, said units being situated parallel juxtaposed having the external surface of the thermo-conducting sheet on one unit facing the external surface of the thermo-conducting sheet of an adjacent heat exchange unit, said plurality of heat exchange plates forming a square or rectangular entry for a liquid media (A) such that said media is able to pass between the planar heat exchange units, and where the at least two perpendicular fluid connections (4, 5) are formed by integrated parts of said half-plates (2, 3), and where the distance between the planar units is defined by the height of the rims of the fluid connections (4, 5) and of the bonding points (8).
A heat exchange module (20), wherein the supporting plate (1) comprises at least two fluid connections (4, 5) and at least two internal flow distribution channels (9A, 9B), defining at least two independent sets of flow paths through said supporting plate which are in fluid connection with the at least one flow area (6), each set of flow paths comprising at least two fluid connections (4, 5) being in fluid connection, and at least one internal flow distribution channel (9A,9B), such that said heat exchange module (20) is configured for allowing liquid media (C, D) to pass from a first exit opening (4) through one or more internal flow distribution channels to said at least one flow area (6) and through one or more internal flow distribution channels to a second exit opening (5). A heat exchange unit module (20), wherein said heat exchange unit assembly (20) comprises an additional open mesh between opposite juxtaposed heat exchange units (7), said additional open mesh being configured for flow of second liquid media and creating a turbulent flow between said planar heat exchange units at low flow volume, while also keeping the thermo-conducting sheets (7) fixed, hereby allowing for flush of the thermo-conducting sheets with a negative pressure across the thermo-conducting sheet.
The skilled person of the art will be aware that different modifications can be made to the embodiments described above as well as the working example described below, without departing from the scope and spirit of the invention. Working examples
Example 1. Manufacture of a heat exchange unit and module prototypes.
The manufacture of a heat exchange unit of the invention having five flow areas in fluid connection on both sides of the supporting plate follows the steps below.
Injection molding of half-plates using a semi-crystalline homopolymer of polypropylene, to outer dimensions of these being 240 x 200 x 2 mm, making the bonded supporting plate 4 mm thick. These dimensions lead to a very rigid base plate with two protruding exits, connected to the internal manifold channels, that lead to five individual, but successively interconnected flow areas on the outside of the plate. The flow areas together cover approximately 190 x 190 mm on both side of the supporting plate, and a 0.2 mm thermo-conducting polypropylene based completely tight membrane on a non- woven mesh covers the five flow areas and is sealingly heat-bonded around each flow area. Hereby an effective, rigid heat exchanger plate, with high chemical and thermal span of operation, is made out of plastics only.
The planar heat exchange units are built up into a rigid stack of 33 plates forming a heat exchange module of 2.5 square meter of heat exchange surface. In building up the stack of plates, each protruding exit is heat-bonded to the exit of the juxtaposed plates, and the bonding points on the perimeter are also heat-bonded together so that these together with the exits secure a uniform distance of 1.6 mm of free gap between the plates.
The protruding exits have an internal diameter of 16 mm, and in the built up module there are 4 exits where in operation 2 of these are entries for the first media and 2 are exits for said first media. The exits each connect to the internal manifold in the plates and said manifold is formed by 2 mm channels in the plate formed when the 2 half plates are connected. The internal channels lead to the first flow area connecting to this through slits in the plate and same design I used between consecutive flow areas, and from last flow area to the other protruding exit.
The heat exchanger module is then positioned into a pressure withstanding molded polypropylene flow housing where there are four 16 mm fluid connections for the first media: 2 openings for inlet and 2 openings for outlet, where said exits are sealingly connected to the heat exchanger module as well as sealed in towards the flow housing. The second media can enter the heat exchanger module through a 200 mm x 200 mm opening in each end of the housing giving access to the gaps between the stacked heat exchanger plates. The flow housing allows for several heat exchange modules in flow housings to be stacked forming large, longer heat exchangers. In given example 4 housings are stacked making an assembled unit with 10 sqm heat exchange surface. Results achieved.
By leading a relatively large flow of 600 L/min of a second media through the flow distribution channel and a flow of 60 L/min of a first media through the heat exchanger module and through the 2.5 m2 flow areas, we measured a resulting heat exchange similar to that of similar size traditional heat exchanges.

Claims

Claims
1. A heat exchange unit (100) for heat exchange between a first liquid medium and a second liquid medium, comprising a planar and rigid supporting plate (1) having outer surfaces (2s, 3s) and a flow area (6) formed in at least one of the outer surfaces (2s, 3s) of the supporting plate (1),
wherein a thermo-conducting sheet (7) is bonded to the supporting plate (1) and fluid tightly sealed to a perimeter of the flow area (6), said thermo-conducting sheet (7) comprising an internal surface and an external surface,
wherein the supporting plate (1) further comprises
- at least two fluid connections (4, 5) for the first liquid medium,
- internal flow distribution channels (9A, 9B); and
- perforations (10A, 10B),
wherein the internal flow distribution channels (9A, 9B) fluidly connects said at least two fluid connections (4, 5) for the first liquid medium with said perforations (10A, 10B), wherein the perforations (10A, 10B) fluidly connects the flow distribution channels
(9A, 9B) to the flow area (6) to provide fluid contact between the at least two fluid connections (4, 5) and the internal surface of the thermo-conducting sheet (7),
wherein said fluid connections (4, 5) extends perpendicularly from the supporting plate (1),
wherein the external surface of the thermo-conducting sheet is in fluid contact with a flow of a second liquid medium, thus providing heat exchange between the first liquid media and the second liquid media, and
wherein said at least one flow area (6) is formed by a grooved or corrugated surface on at least one of said first and second rigid outer surfaces (2s, 3s).
2. The heat exchange unit (100) according to claim 1, wherein the supporting plate (1) comprises two half-plates bonded to each other.
3. A heat exchange unit (100) according to claim 1 or 2, wherein said at least one flow area (6) is formed by grooves (12) and protrusions (13), said protrusions (13) being configured for supporting said overlying thermo-conducting sheet (7), and said grooves (12) defining a flow path configured for flow distribution in the flow area (6) between the internal surface of the thermo-conducting sheet (7) and an outer surface (2s, 3s) of the supporting plate (1).
4. The heat exchange unit (100)) according to any one of the claims 1-3, wherein said at least one flow area (6) is an integral part of the rigid outer surface (2s, 3s) of the supporting plate (1).
5. A heat exchange according to claim 4, wherein the at least one flow area (6) forms a corrugated ridge and groove structure or mesh like structure on the surface (2s, 3s), where the structure forms a curved surface in fluid contact with the covering internal surface of the thermo-conducting sheet, and the curved surface being configured to create a turbulent flow inside and outside the supporting plate (1) at low liquid media flow speeds.
6. The heat exchange unit (100) according to any one of the claims 1-5, wherein said supporting plate (1) has an outer periphery being square or rectangular.
7. The heat exchange unit (100) according to any one of the claims 2-6, wherein said two half-plates (2, 3) each comprises at least one external flow area (6) and at least one perpendicular fluid connecting perforation (10A, 10B) leading into an internal half part of a flow distribution channel (9A, 9B), wherein the half-plates are bonded together at least at the periphery, and wherein the two half-plates (2, 3) are symmetrical or identical in shape.
8. The heat exchange unit (100) according to any one of the claims 2-8, wherein the supporting plate (1) is formed by liquid tight bonding, such as edgewise bonding or heat- fusion of two fitting half-plates made of a light material, such as plastics.
9. The heat exchange unit (100) according to claims 9 or 10, wherein the half-plates (2, 3) are formed by molding.
10. The heat exchange unit (lOO)according to any one of the claims 1-9, wherein the thermo-conducting sheet (7) is selected from a thin foil of a thermo-conducting material, such as a metal, such as stainless steel, aluminium or die cast aluminum alloys; or is made of a heat conducting plastics or a hybrid material, such as polypropylene, polysulfone or nylon having heat-conductive additives including graphite carbon fibers and ceramics, such as aluminum nitride and boron nitride; where the thermo- conducting sheet is impermeable to the type of liquid media to be cooled or heated.
11. The heat exchange unit (100) according to any one of the claims 1-10, wherein the external surface of the thermo-conducting sheet (7) has a mesh structure, such as an overlaying fishbone like curve-shape.
12. A heat exchange unit (100) according to any one of the claims 1-11, wherein said at least two fluid connections (4, 5) with their protruding rims (4', 5') extend transversely from the planar surface of said first and second rigid outer surface (2s,3s) of the supporting plate (1).
13. A heat exchange unit (100) according to any one of the claims 1-12, wherein said internal flow distribution channels (9A, 9B) comprise multiple separate channels or flow volumes formed by the inside of said half-plates (2, 3) and where the separate channels form a manifold leading to the fluid connections (4, 5).
14. A heat exchange module (20) comprising a plurality of planar heat exchange units (100) according to any one of the claims 1-13, wherein the at least two fluidly connected fluid connections (4, 5) comprises protruding rims (4', 5'), and where the supporting plates (1) further comprises bonding points (8) functioning as distance points together with the protruding rims (4, 5) thus forming a gap between the heat exchange units (100) for passage of a second liquid medium in-between two adjacent heat exchange units (100) when stacked.
15. The heat exchange module (20) according to claim 2 wherein the fluid connections (4, 5) with the protruding rims (4', 5')are integral with the supporting plate (1) or the protruding rims (4', 5') are formed from insertion of loose inlet pieces.
PCT/EP2018/079510 2017-10-26 2018-10-26 Heat exchange unit and assembly WO2019081769A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201770808A DK180373B1 (en) 2017-10-26 2017-10-26 Heat exchange unit and assembly
DKPA201770808 2017-10-26

Publications (1)

Publication Number Publication Date
WO2019081769A1 true WO2019081769A1 (en) 2019-05-02

Family

ID=64184047

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2018/079510 WO2019081769A1 (en) 2017-10-26 2018-10-26 Heat exchange unit and assembly

Country Status (2)

Country Link
DK (1) DK180373B1 (en)
WO (1) WO2019081769A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112674614A (en) * 2019-10-18 2021-04-20 广东美的白色家电技术创新中心有限公司 Cooking utensil
IT201900020376A1 (en) * 2019-11-05 2021-05-05 Microchannel Devices S R L METHOD FOR MANUFACTURING MONOLITHIC MULTI-PIPE HYDRAULIC DEVICES, IN PARTICULAR HEAT EXCHANGERS

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160025007A1 (en) * 2014-07-25 2016-01-28 Airbus Helicopters Plate heat exchanger of improved thermal efficiency for a turboshaft engine
US20170182463A1 (en) * 2014-02-03 2017-06-29 Sani Membranes Aps Filter plate assembly

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170182463A1 (en) * 2014-02-03 2017-06-29 Sani Membranes Aps Filter plate assembly
US20160025007A1 (en) * 2014-07-25 2016-01-28 Airbus Helicopters Plate heat exchanger of improved thermal efficiency for a turboshaft engine

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112674614A (en) * 2019-10-18 2021-04-20 广东美的白色家电技术创新中心有限公司 Cooking utensil
CN112674614B (en) * 2019-10-18 2022-12-09 广东美的白色家电技术创新中心有限公司 Cooking utensil
IT201900020376A1 (en) * 2019-11-05 2021-05-05 Microchannel Devices S R L METHOD FOR MANUFACTURING MONOLITHIC MULTI-PIPE HYDRAULIC DEVICES, IN PARTICULAR HEAT EXCHANGERS
EP3819064A1 (en) * 2019-11-05 2021-05-12 Microchannel Devices S.r.l. Method for the manufacture of monolithic multi-tube hydraulic devices, in particular heat exchangers

Also Published As

Publication number Publication date
DK180373B1 (en) 2021-02-12
DK201770808A1 (en) 2019-05-08

Similar Documents

Publication Publication Date Title
US11813576B2 (en) Filter-plate assembly with external flow areas and attached membranes
US9217608B2 (en) Heat exchanger
EP0526679B1 (en) Heat exchanger with multi-walled plate elements
US20100258284A1 (en) Heat Exchanger
KR101667133B1 (en) Plate heat exchanger
JP2008528927A (en) Gasket assembly for plate heat exchanger
JP3394521B2 (en) Heat exchange equipment
WO2019081769A1 (en) Heat exchange unit and assembly
EP1986758A1 (en) A filter plate for use in a filter stack
WO2013072566A1 (en) Plate heat exchanger and method for manufacturing of a plate heat exchanger
US20080190594A1 (en) Heat Exchanger Device for Rapid Heating or Cooling of Fluids
EP3102315A1 (en) Filter plate assembly
WO2022148148A1 (en) Parallel-type heat exchanger
US7690420B2 (en) Plate heat exchanger
KR20140025299A (en) Heat exchanger
EP4045863B1 (en) Heat exchanger
WO2003071198A1 (en) A heat transfer apparatus
DK178159B1 (en) Filter plate assembly
KR101468607B1 (en) Hybrid half welded primary surface heat exchanger
KR100829801B1 (en) Heat exchanger for waste water
EP0458786A1 (en) Heat exchanger.
WO2002023645A2 (en) Bipolar separator plate assembly for a fuel cell
CN217236592U (en) Plate for plate heat exchanger
EP4303519A1 (en) A gas-liquid plate heat exchanger and method of assembling same
US20230339746A1 (en) Apparatus comprising a reactor for dehydrogenating a hydrogen-enriched liquid hydrogen carrier

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18799687

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18799687

Country of ref document: EP

Kind code of ref document: A1