WO2019056537A1 - Composition herbicide contenant du triazole-sulcotrione et application de celle-ci - Google Patents

Composition herbicide contenant du triazole-sulcotrione et application de celle-ci Download PDF

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Publication number
WO2019056537A1
WO2019056537A1 PCT/CN2017/112021 CN2017112021W WO2019056537A1 WO 2019056537 A1 WO2019056537 A1 WO 2019056537A1 CN 2017112021 W CN2017112021 W CN 2017112021W WO 2019056537 A1 WO2019056537 A1 WO 2019056537A1
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Prior art keywords
weight ratio
herbicidal composition
composition
triazosulfone
composition containing
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PCT/CN2017/112021
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English (en)
Chinese (zh)
Inventor
张景远
彭学岗
金涛
陈小奇
崔琦
Original Assignee
青岛清原抗性杂草防治有限公司
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Publication of WO2019056537A1 publication Critical patent/WO2019056537A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
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    • A01N43/18—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
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    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals

Definitions

  • the invention belongs to the field of pesticides, and in particular relates to a herbicidal composition containing triazosulfone and application thereof.
  • Chemical weeding is the most economical and effective means of controlling weeds in farmland.
  • long-term continuous high-dose use of single-species or single-acting chemical herbicides is prone to problems such as weed resistance and resistance evolution.
  • Rational compounding or compounding of herbicide compounds has the advantages of expanding weed spectrum, improving control effect, delaying the occurrence and development of weed resistance and drug resistance, and is one of the most effective methods to solve the above problems.
  • Patent CN105724390A discloses a plurality of herbicidal compositions containing pyrazole compounds, including the active component triazosulfone, which has a chemical structural formula of It is a newly developed HPPD inhibitor herbicide for post-emergence stem and leaf treatment of rice fields. It has excellent biological activity and can effectively control a variety of malignant weeds in rice fields, but it is not recorded that all combinations can produce synergistic effects.
  • the present invention provides a herbicidal composition containing triazosulfone and an application thereof, which can effectively prevent weeds such as valerian, rice bran, and gold in crops.
  • the problem is that it has the characteristics of expanding herbicidal spectrum, reducing application rate, safety to crops, synergy and solving resistant weeds.
  • a herbicidal composition containing trioxacillin comprising a herbicidally effective amount of active ingredient A and active ingredient B, wherein active ingredient A is triazosulfone, and active ingredient B is selected from one of the following compounds or Variety: oxadiazon, piperacine, tetrazolidylamine, herbicide, sassafras, 2, 4, 4, sodium, sodium, chlorpyrifos, chlorpyrifos, grass, and grass Caudadan, oxazolamide, benzofenone, phenothanil, dicyclohexanone, cyclopentaloxone, isoproturon, pyrazosulfuron, furanone, penoxsulam .
  • the weight ratio of the active ingredients A and B is 1:60-60:1, preferably 1:50-50:1 and 1:40-40:1, more preferably 1:30-30:1 and 1:20- 20:1, further preferably 1:10-10:1.
  • the weight ratio of A to humulones is 1:30-12:1
  • the weight ratio of A to piperacin is 1:40-12:1
  • the weight ratio of A to tetrazolyl is 1:30-12:1
  • the weight ratio of A to herbicide is 1:30-12:1
  • the weight ratio of A to Shakespeare is 1:36-12:1
  • the weight ratio of A and 2 methyl 4-chlorosodium salt is 1:32-32:1
  • the weight ratio of A to chlorpyrifos is 1:30-6:1
  • the weight ratio of A to Xicaojing is 1:12-12:1
  • the weight ratio of A to chlorpyrifos is 1:4-24:1
  • the weight ratio of A to grass and grass is 1:24-4:1
  • the weight ratio of A to grass is 1:24-1:1
  • the weight ratio of A to oxazolamide is 1:12-12:1
  • the weight ratio of A to benzophenone is 1:4-20:1
  • the weight ratio of A to benzilamide is 1:24-2:3
  • the weight ratio of A to dicyclosulfone is 1:24-18:1
  • the weight ratio of A to cyclopentazone is 1:24-36:1
  • the weight ratio of A to isoproturon is 1:36-24:1
  • the weight ratio of A to pyrazosulfuron is 2:1-16:1
  • the weight ratio of A to furanone is 1:16-12:1
  • the weight ratio of A to penoxsulam is 1:8-48:1.
  • the mass percentage of A and B in the herbicidal composition is from 1 to 95%, preferably from 10 to 80%, based on the total amount.
  • the herbicidal composition further comprises a safener C selected from one or more of the following compounds:
  • the herbicidal composition further comprises a conventional auxiliary agent comprising a carrier and a surfactant.
  • carrier refers to an organic or inorganic, natural or synthetic material. They contribute to the active ingredients For administration, the carrier is generally inert and must be agriculturally acceptable, especially for the treated plant.
  • the carrier may be solid, such as clay, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, etc.; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or waxy hydrocarbons, chlorine Hydrocarbons, liquefied gases, etc.
  • Surfactants may include emulsifiers, dispersants or wetting agents, which may be ionic or nonionic. Examples which may be mentioned are salts of polyacrylic acid, lignosulfonates, salts of phenolsulfonic or naphthalenesulfonic acid, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (especially a polymer of an alkylphenol or an arylphenol, a sulfosuccinate, a taurine derivative (especially a taurine alkyl ester), a phosphate ester of an alcohol or a phosphate of a polyhydroxyethylated phenol, Alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated hexadecane, hepta-
  • compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
  • compositions of the present invention may be diluted or used directly by the user prior to use.
  • the preparation can be prepared by a usual processing method, that is, after mixing the active material with a liquid solvent or a solid carrier, and then adding one or more of a surfactant such as a dispersing agent, a stabilizer, a wetting agent, a binder, an antifoaming agent, and the like.
  • a surfactant such as a dispersing agent, a stabilizer, a wetting agent, a binder, an antifoaming agent, and the like.
  • Specific formulations of the herbicidal compositions are dispersible oil suspensions, aqueous suspensions, suspoemulsions, emulsifiable concentrates, water-dispersible granules (dry suspensions), aqueous emulsions, microemulsions.
  • compositions of the present invention can be combined with solid and liquid additives conventionally used in prior art formulations.
  • composition of the active ingredient A and the active ingredient B may be mixed with the following active substances, for example, "World Pesticide New Variety Technology Encyclopedia", China Agricultural Science and Technology Press, 2010.9 and known materials in the literature cited herein.
  • the herbicide active substance mentioned below (remark: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, when appropriate, the code name): acetochlor, butachlor, Alachlor, propisochlor, metolachlor, dimethoprim, pretilachlor, chlorfenapyr, acetochlor, naproxil, R-L-naproxil, enemies ,benzilin, dibenzoylamine, flufenacetamide, herbicide, flufenic acid, bromobutyramide, dimethoprim, high-performance metolachlor, ethoxy Bentochlor, flufenacet, methoxymethafen, metazachlor, isoxacillin, high-efficiency
  • composition of the present invention can be applied to the leaves of the plants to be treated by spraying, i.e., to the weeds, particularly on the surface which is infested or susceptible to weeds which are harmful to the growth of the crop.
  • composition of the present invention is environmentally friendly, is easily degraded in the environment, and is safe for crops.
  • the herbicidal composition of the invention has low cost and convenient use, and has great economic and social benefits for its popularization and application.
  • the herbicidal composition of the present invention can prevent the herbaceous weeds, the weeds, the sedge and the ACCase inhibitors which are resistant to ALS inhibitors.
  • Gramineous weeds such as Thousand Gold, which are resistant, are effective solutions for weed resistance management in paddy fields.
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • chloropyrazine 6% calcium dodecylbenzenesulfonate + 7% fatty acid polyoxyethylene ether + 5% castor oil polyoxyethylene ether + 2.5% organic bentonite + 2.5% gas phase two Silica +5% 150 #solvent oil + methyl oleate to make up.
  • composition of the wettable powder is:
  • composition of the water dispersible granules is:
  • composition of the cream formulation is:
  • composition of the microemulsion is:
  • composition of the water emulsion is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water dispersible granules is:
  • composition of the cream formulation is:
  • composition of the microemulsion is:
  • composition of the water emulsion is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the cream formulation is:
  • composition of the microemulsion is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the cream formulation is:
  • composition of the microemulsion is:
  • composition of the water emulsion is:
  • composition of the dispersible oil suspension formulation is:
  • composition of the cream formulation is:
  • composition of the microemulsion is:
  • composition of the water emulsion is:
  • composition of the dispersible oil suspension agent is:
  • composition of the water-dispersible granules is:
  • composition of the cream formulation is:
  • composition of the water emulsion is:
  • composition of the water suspension agent is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the microemulsion is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension formulation is:
  • composition of the cream formulation is:
  • composition of the water suspension formulation is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water dispersible granules is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water dispersible granules is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the water suspension formulation is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the cream formulation is:
  • composition of the microemulsion is:
  • composition of the water emulsion is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • composition of the water dispersible granules is:
  • composition of the cream formulation is:
  • composition of the aqueous suspension formulation is:
  • composition of the wettable powder is:
  • composition of the water-dispersible granules is:
  • composition of the water suspension formulation is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • A+10% herbicidal +8% sodium lignin sulfonate dispersant +4% pull-up powder +10% precipitation method white carbon black + diatomaceous earth to make up 85) water-dispersible granules are composed of:
  • composition of the cream formulation is:
  • composition of the water suspension agent is:
  • composition of the dispersible oil suspension agent is:
  • composition of the wettable powder is:
  • water dispersible granules are composed of:
  • Echinochloa crusgalli is collected from the rice paddy field of Hanshou County, Hunan province.
  • Leptochloa chinensis is collected from Jiashan, Zhejiang province.
  • Cyperus difformis is collected from Jingzhou, Sagittaria trifolia L., and rice blast ( Echinochloa phyllopogon (stapf) Koss.) was collected from Yingkou, Liaoning province.
  • the above weeds were cultivated by pot culture. They were placed in an enamel pan with 180 ⁇ 140mm plastic nutrient bowl, and the surface soil was collected from the farmland and air-dried through the farmland (4/5 At the beginning, the soil moisture is controlled at 20% at the beginning.
  • the weed seeds with full and uniform grain are selected, soaked in warm water at 25 °C for 6 hours, and germinated in a 28 °C biochemical incubator (dark) to evenly spread the weed seeds that have just been exposed. Place on the surface of the soil, and then cover the soil by 0.5-1cm according to the particle size.
  • the required active ingredient B is a commercially available original drug, and A is produced by the company.
  • the original drugs were all treated with acetone as a solvent, diluted with 0.1% emulsifier T-80 aqueous solution, and now diluted.
  • each group of A and active ingredient B When determining the distribution ratio or content of each group of A and active ingredient B, it should be measured from the characteristics and virulence of the two agents, and the main purpose of the formulation should be considered. On the basis of the preliminary pre-test, the A and B active ingredients used alone and mixed dosages are shown in the table. Water containing no drug, the same solvent and an emulsifier was used as a blank control.
  • Each treatment was repeated 4 times, and each time 3 pots were treated, 20 seeds of weed seeds were planted per pot, and 60 plants per treatment.
  • the cultured test materials were evenly placed on a platform with an area of 0.5 m 2 , and sprayed with a 3WP-2000 type walking spray tower, and the spray amount was 30 kg/ha.
  • the spray pressure was 0.3 MPa. After all the liquid medicines have been sprayed, close the air valve. After 30 seconds, open the spray tower door and take out the nutrient bowl. Then open the air valve, spray 50ml of water, and clean the spray tube.
  • the whole seedlings of the living weeds were cut along the surface of the soil with a blade, and the fresh weight of the weeds was weighed by an analytical balance. For dead weeds, the fresh weight is zero.
  • the investigation was conducted 20 days after the treatment, and a total of 1 investigation was conducted.
  • E measured inhibition rate
  • the E-E0 value is greater than 10% for synergism, less than -10% for antagonism, and between -10% and 10% for additive effect. According to the actual control effect and the characteristics of the herbicide, the balance of the formula and other factors determine the best ratio.
  • X is the fresh weight inhibition rate when A is used as P
  • Y is the fresh weight inhibition rate when the amount of active ingredient B is Q.
  • Echinochloa crusgalli is collected from Hunan Hanshou paddy field; Leptochloa chinensis is collected from Huangmei County, Hubei Province, and Cyperus iria L. is collected from Jingzhou, Hubei, and Monochoria vaginalis. Heilongjiang Hulin was collected from Yingkou, Liaoning, and Echinochloa phyllopogon (stapf) Koss. and Scirpus juncoides Roxb.
  • the test soil was dosed to 3/4 of the pots and then watered from the bottom of the pots to completely wet the soil to saturation.
  • the pretreated weed seeds were uniformly distributed on the surface, and the soil was covered by 0.5-2 cm according to the seed size, and was used 24 hours after sowing.
  • GA10 type one ten thousand electronic balance Germany
  • ZDR2000 intelligent data recorder Hagzhou Zeda Instrument Co., Ltd.
  • SPX type intelligent biochemical incubator Naingbo Jiangnan Instrument Factory
  • the required active ingredient B is a commercially available original drug, and A is produced by the company.
  • the original drugs were all treated with acetone as a solvent, diluted with 0.1% emulsifier T-80 aqueous solution, and now diluted.
  • Each treatment was repeated 4 times, 3 pots per treatment, and 30 seeds of weed seeds were seeded per pot.
  • the whole seedlings of the living weeds were cut along the surface of the soil with a blade, and the fresh weight of the weeds was weighed by an analytical balance. For dead weeds, the fresh weight is zero.
  • the investigation was conducted 20 days after the treatment, and a total of 1 investigation was conducted.
  • E measured inhibition rate
  • the E-E0 value is greater than 10% for synergism, less than -10% for antagonism, and between -10% and 10% for additive effect. According to the actual control effect and the characteristics of the herbicide, the balance of the formula and other factors determine the best ratio. In general, mutual synergism is evaluated at low doses. With the increase of the dosage, when a certain component exceeds a certain dose, the individual components achieve higher control effect, and the synergistic effect is no longer meaningful.
  • X is the fresh weight inhibition rate when A is used as P
  • Y is the fresh weight inhibition rate when the amount of active ingredient B is Q.
  • Table 14A is combined with pyrazosulfuron-methyl to control the actual control effect of the ragweed (soil closure) and the combined effect evaluation (Gowing)
  • the herbicide composition prepared in Examples 1) to 90) was used to control the weed test in paddy fields.
  • Test method rice 3 leaves 1 heart, weed 3-4 leaf stage, manual sprayer, water volume 30 kg / 667 m 2 , spray evenly with stem and leaf spray, the specific test agent and dosage are shown in Table 22, the plot area is 50 square Rice, repeated 4 times per treatment. See Table 22 for the investigation of the control effect 45 days after application.
  • the composition is useful for controlling grass weeds in rice fields after emergence, and has surprising and unexpected synergistic effects, especially for alfalfa, rice bran, and gold.
  • the broad-leaved weeds such as the weeds of the grasses and the broadleaf weeds such as the ragweed and the wild sage have a particularly significant synergistic effect.
  • This synergistic effect is more pronounced at low doses, which can reduce the dosage and safety of rice. It reduces the pollution to the environment, and the reasonable compounding reduces the agricultural cost, and is effective for the resistance of ALS and ACCase inhibitors to weeds, and has a good application prospect.

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  • Life Sciences & Earth Sciences (AREA)
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  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

L'invention concerne une composition herbicide contenant du triazole-sulcotrione et une application de celle-ci. La composition herbicide comprend une quantité herbicide efficace d'ingrédient actif A et d'ingrédients actifs B, l'ingrédient actif A étant du triazole-sulcotrione, et les ingrédients actifs B étant choisis parmi un ou plusieurs des composés suivants : indanofan, pipérophos, fentrazamide, bromacil, anilofos, sel de sodium de MCPA, prométryne, simétryne, halosulfuron-méthyle, molinate, benthiocarb, métamifop, clefoxidim, méfénacet, benzobicylon, pentoxazone, isoproturon, pyrazosulfuron-éthyle, téfuryltrione et pénoxsulam. La composition peut lutter efficacement contre les mauvaises herbes dans des cultures, telles que l'échinochloa pied-de-coq, l'échinochloa pied-de-coq de rizière et l'euphorbe épurge, et présente les avantages d'une plage herbicide étendue et d'une quantité d'application réduite, tandis que la composition herbicide est sans danger pour les cultures, peut générer un effet synergique et peut éliminer des mauvaises herbes résistantes.
PCT/CN2017/112021 2017-09-19 2017-11-21 Composition herbicide contenant du triazole-sulcotrione et application de celle-ci WO2019056537A1 (fr)

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CN108157374B (zh) * 2018-02-01 2022-03-15 青岛清原化合物有限公司 一种三元除草组合物及其应用
CN109042675B (zh) * 2018-07-21 2021-05-28 青岛清原化合物有限公司 包含hppd抑制剂类除草剂的三元除草组合物及其应用
CN109479888A (zh) * 2018-12-19 2019-03-19 青岛清原化合物有限公司 包含cyclopyrimorate的三元除草组合物及其应用
CN109497075B (zh) * 2018-12-19 2021-12-07 青岛清原化合物有限公司 包含trifludimoxazin的三元除草组合物及其应用
CN109452300B (zh) * 2019-01-11 2020-08-18 安徽省农业科学院植物保护与农产品质量安全研究所 一种含氯吡嘧磺隆的三元除草组合物及其应用
CN113387926B (zh) * 2020-03-13 2023-12-12 沈阳中化农药化工研发有限公司 一种杂环羧酸酯类化合物及其作为除草剂的用途
CN115363031B (zh) * 2022-09-30 2024-02-02 北京金泰毅农作物科技有限公司 一种含有Lancotrione-钠盐和敌稗的除草剂组合物

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