WO2019030089A1 - Mélanges herbicides comprenant du l-glufosinate ou son sel et au moins un inhibiteur de als - Google Patents

Mélanges herbicides comprenant du l-glufosinate ou son sel et au moins un inhibiteur de als Download PDF

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Publication number
WO2019030089A1
WO2019030089A1 PCT/EP2018/070931 EP2018070931W WO2019030089A1 WO 2019030089 A1 WO2019030089 A1 WO 2019030089A1 EP 2018070931 W EP2018070931 W EP 2018070931W WO 2019030089 A1 WO2019030089 A1 WO 2019030089A1
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methyl
gene
event code
pat
das
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PCT/EP2018/070931
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Christian Winter
Markus Gewehr
Ryan Louis NIELSON
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Basf Se
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Definitions

  • Herbicidal mixtures comprising L-glufosinate or its salt and at least one ALS inhibitor
  • the present invention relates to herbicidal mixtures comprising L-glufosinate or its salt and at least one ALS inhibitor.
  • the invention furthermore relates to a method for controlling undesirable vegetation in burndown programs, in industrial vegetation management and forestry, in vegetable and perennial crops and in turf and lawn.
  • Burndown i.e. the complete removal of weeds from the soil by application of herbicides prior to planting or emergence of a crop, is an important tool of modern weed management. Weeds present at planting will generally grow much quicker than crop plants and thus compete very early in the growing season thereby damaging the crop plants and reducing crop yield. Thus, it is desirable to plant the crop in a weed-free seed bed or to assure that essentially no weeds are present when the crop emerges. Burn-down may also entail weed control on fallow crop land.
  • Industrial weed management includes for example railway and right-of-way management, fence lines and non-crop land such as industrial and building sites, gravel areas, roads or sidewalks.
  • Forestry includes for example the clearing of existing forest or bushland, the removal of regrowth after mechanical forest cutting, or the management of weeds under forestry plantations. In the latter case, it may be desirable to shield desirable trees from contact with the spray solution that contains the herbicidal mixture according to the present in- vention.
  • Vegetable crops includes for example aubergine, beans, bell pepper, cabbage, chili, cucumber, eggplant, lettuce, melon, onion, potato, sweet potato, spinach and tomato.
  • weed control in vegetable crops it may be desirable to shield the crops from contact with the spray solution that contains the herbicidal mixture according to the present invention.
  • Perennial crops include trees, nuts and vine crops such as for example almond, apple, apricot, avocado, cashew nut, cherry, Christmas trees, durian, orange, dragon fruit, grapes, guava, lon- gan, mango, olive, papaya, peach, pear and other pome fruits, pistachio, plum, pomegranate, pomelo and quince and citrus crops including e. g. Clementine, grapefruit, lemon, lime, manda- rin and nectarine as well as nut crops including e. g.
  • hazelnut, macadamia nut and walnut; and plantation crops such as for example banana, cacao, coconut, coffee, oil palm, pepper and other spices, plantain, rubber, sugarcane and tea.
  • ornamentals such as, for example, azaleas, rhododendron, roses and nurseries. For weed control in perennial crops, it may be desirable to shield the crops from contact with the spray solution that contains the herbicidal mixture according to the present invention.
  • compositions according to the invention can also be used for weed control in turf and lawn provided the desirable grass species are tolerant to the herbicidal mixture.
  • such mixtures can be used in desirable grass that has been rendered tolerant to glufosinate by mutagenesis or genetic engineering.
  • Glufosinate and its salts are non-selective systemic herbicides having a good post-emergence activity against numerous weeds and thus can be used in burndown programs, in industrial vegetation management and forestry, in vegetable and perennial crops and in turf and lawn.
  • solo application of glufosinate often yields unsatisfactory weed control, and several applications and/or high dosage rates are often required.
  • the effectiveness of glufosinate against some weeds is not fully sufficient.
  • glufosinate in combination with at least one further herbicide.
  • the effectiveness of such combinations is often not satisfactory and high application rates are still required to achieve acceptable weed control.
  • the relia- bility and persistence of such combinations depends strongly on the weathering conditions and certain difficult to control weed species may escape.
  • the herbicidal activity of these mixtures persists only for a short time, which allows effective burndown only within a small timeframe prior to planting a crop.
  • the persistence of the herbicidal activity of the mixture should be sufficiently long in order to achieve control of the weeds over a sufficient long time period thus allowing a more flexible application.
  • the mixture should also have a low toxicity to humans or other mammals.
  • the mixtures should also show an accelerated action on harmful plants, i.e. they should affect damaging of the harmful plants more quickly in comparison with application of the individual herbicides.
  • Glufosinate is a racemate of two enantiomers, out of which only one shows sufficient herbicidal activity (see e.g. US 4265654 and JP92448/83).
  • mixtures of L-glufosinate or its salt and at least one ALS inhibitor show a higher activity in burndown programms, in industrial vegetation management and forestry, in vegetable and perennial crops and in turf and lawn, if compared to mixtures of racemic glufosinate and at least one ALS inhibitor.
  • the present invention relates to herbicidal mixtures of
  • the abovementioned invention relates to herbicidal mixtures as de- scribed above, wherein L-glufosinate comprises more than 70% by weight of the L-enantiomer.
  • Glufosinate [common name of DL-4-[hydroxyl(methyl)phosphinoyl]-DL-homoalaninate] and its salts such as glufosinate ammonium and its herbicidal acitivity have been described e.g. by F. Schwerdtle et al. Z. Chakr. Wunsch, 1981 , Sonderheft IX, pp. 431 -440.
  • Glufosinate as racemate and its salts are commercially available, e.g. from Bayer CropScience under the tradenames BastaTM and LibertyTM.
  • L-Glufosinate as used in the present invention comprises more than 70% by weight of the L- enantiomer; preferably more than 80% by weight of the L-enantiomer; more preferably more than 90% of the L-entantiomer, most preferably more than 95% of the L-enantiomer and can be prepared as referred to above.
  • L-Glufosinate can be prepared according to methods known in the art, e.g. as described in WO2006/104120, US5530142, EP0127429 and J. Chem. Soc. Per- kin Trans. 1 , 1992, 1525-1529.
  • L-Glufosinate also called glufosinate-P
  • (2S)-2-amino-4-[hydroxy(methyl)phosphinoyl]butyric acid (CAS Reg. No. 35597-44-5).
  • Relevant salts of L-glufosinate are L-glufosinate-ammonium (also called glufosinate-P-ammonium), which is ammonium (2S)-2-amino-4- (methylphosphinato)butyric acid (CAS Reg. No.
  • L-glufosinate-sodium also called glufosinate-P-sodium
  • (2S)-2-amino-4-(methylphosphinato)butyric acid CAS Reg. No. 70033-13-5
  • L-glufosinate-potassium also called glufosinate-P-potassium
  • the weight ratio of compound I to compound II is preferably from 1000: 1 to 1 : 500, 400:1 to 1 :40, more preferably 500:1 to 1 :250, in particular from 200:1 to 1 :20, even more preferably from 100:1 to 1 :10, most preferrably 50:1 to 1 :5.
  • mixtures are preferred, which contain L-glufosinate-ammonium or L-glufosinate- sodium as L-glufosinate salts or L-glufosinate as free acid.
  • mixtures which contain L-glufosinate-ammonium as L-glufosinate salt.
  • the invention relates to herbicidal mixtures of
  • L-glufosinate or its salt as compound I preferably L-glufosinate-ammonium, L-glufosinate- sodium or L-glufosinate free acid
  • ALS inhibitor as compound II, preferably selected from the group consisting of amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlorimuron, chlorimuron- ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethametsulfuron- methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, flupyrsulfuron-methyl- sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazosulfuron, iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, mesosulfuron, metazosul- furon, metsulfuron, metsulfuron, met
  • Preferred compounds II are chlorimuron, chlorimuron-ethyl, flazasulfuron, iodosulfuron, iodosulfuron-methyl-sodium, mesosulfuron, metsulfuron, metsulfuron-methyl, nicosulfuron, sulfometuron, sulfometuron-methyl, tritosulfuron, imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr, imazapyr ammonium, imazethapyr, imazethapyr ammonium, florasulam, penoxsulam, pyroxsulam, bispyribac, bispyribac-sodium, thiencarbazone, thiencarbazone- methyl, rimsulfuron diclosulam, thifensulfuron, thifensulfuron-methyl and triasulfuron.
  • More preferred compounds II are chlorimuron, chlorimuron-ethyl, flazasulfuron, iodosulfuron, iodosulfuron-methyl-sodium, mesosulfuron, metsulfuron, metsulfuron-methyl, nicosulfuron, sul- fometuron, sulfometuron-methyl, tritosulfuron, imazamox, imazamox ammonium, imazapic, ima- zapic ammonium, imazapyr, imazapyr ammonium, imazethapyr, imazethapyr ammonium, flo- rasulam, penoxsulam, pyroxsulam, bispyribac and bispyribac-sodium.
  • More preferred compounds II are chlorimuron, foramsulfuron, halosulfuron, iodosulfuron, prosul- furon, rimsulfuron, thifensulfuron, imazamox, imazamox ammonium, imazapic, imazapic ammo- nium, imazapyr, imazapyr ammonium, imazaquin, imazethapyr, imazethapyr ammonium, cloransulam, diclosulam, flumetsulam and thiencarbazone.
  • preferred mixtures of the present invention are mixtures of L-glufosinate-ammonium or L- glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and an ALS inhibitor selected from the group consisting of chlorimuron, chlorimuron-ethyl, flazasulfuron, iodosulfuron, iodosulfuron-methyl-sodium, mesosulfuron, metsulfuron, metsulfuron-methyl, nicosulfuron, sul- fometuron, sulfometuron-methyl, tritosulfuron, imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr, imazapyr ammonium, imazethapyr, imazethapyr ammonium, flo- rasulam, penoxsulam, pyroxsulam, bispyribac
  • the mixtures of the present invention are mixtures of L- glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and an ALS inhibitor selected from the group consisting of chlorimuron, foramsulfuron, halosulfuron, iodosulfuron, prosulfuron, rimsulfuron, thifensulfuron, imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr, imazapyr ammonium, imazaquin, ima- zethapyr, imazethapyr ammonium, cloransulam, diclosulam, flumetsulam and thiencarbazone.
  • an ALS inhibitor selected from the group consisting of chlorimuron, foramsulfuron, halosulfuron, iodosulfuron, prosulfuron, rimsul
  • the mixtures of the present invention are mixtures of L- glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and an ALS inhibitor selected from the group consisting of chlorimuron, foramsulfuron, halosulfuron, iodosulfuron, prosulfuron, rimsulfuron, thifensulfuron
  • the mixtures of the present invention are mixtures of L- glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and an ALS inhibitor selected from the group consisting of imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr, imazapyr ammonium, imazaquin, imazethapyr, imazethapyr ammonium.
  • an ALS inhibitor selected from the group consisting of imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr, imazapyr ammonium, imazaquin, imazethapyr, imazethapyr ammonium.
  • the mixtures of the present invention are mixtures of L- glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and an ALS inhibitor selected from the group consisting of cloransulam, diclosulam, and- flumetsulam.
  • the mixtures of the present invention are mixtures of L- glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and a ALS inhibitor which is thiencarbazone.
  • Even more preferred mixtures of the present invention are mixtures of L-glufosinate-ammonium or L-glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and an ALS inhibitor selected from the group consisting of foramsulfuron, halosulfuron, iodosulfuron, prosulfuron, rimsulfuron and flumetsulam.
  • More preferred mixtures of the present invention are mixtures of L-glufosinate-ammonium or L- glufosinate-sodium as L-glufosinate salts or L-glufosinate as free acid and an ALS inhibitor selected from the group consisting of chlorimuron, chlorimuron-ethyl, flazasulfuron, iodosulfuron, iodosulfuron-methyl-sodium, mesosulfuron, metsulfuron, metsulfuron-methyl, nicosulfuron, sulfometuron, sulfometuron-methyl, tritosulfuron, imazamox, imazamox ammonium, imazapic, imazapic ammonium, imazapyr, imazapyr ammonium, imazethapyr, imazethapyr ammonium, florasulam, penoxsulam, pyroxsulam, bispyribac and bis
  • inventive mixtures can further contain one or more insecticides, fungicides, herbicides.
  • Preferred mixtures are the mixtures comprising L-glufosinate or its salt as compound I and two or more compounds selected from the group of 11-13 (imazamox), 11-14 (imazapic), 11-15 (imazapyr) and 11-16 (imazethapyr).
  • T-10 -1 + I 1-13 (imazamox ammonium) + 11-15 (imazapyr ammonium)
  • T-1 1 -1 + I 1-13 (imazamox ammonium) + 11-16 (imazethapyr ammonium)
  • T-12 -1 + I 1-14 (imazapic ammonium) + 11-15 (imazapyr ammonium)
  • T-13 -2 + I 1-13 (imazamox ammonium) + 11-15 (imazapyr ammonium)
  • T-14 1-2 + 11-13 (imazamox ammonium) + 11-16 (imazethapyr ammonium)
  • T-15 1-2 + 11-14 (imazapic ammonium) + 11-15 (imazapyr ammonium)
  • T-16 1-3 + 11-13 (imazamox ammonium) + 11-15 (imazapyr ammonium)
  • T-17 1-3 + 11-13 (imazamox ammonium) + 11-16 (imazethapyr ammonium)
  • T-18 1-3 + 11-14 (imazapic ammonium) + 11-15 (imazapyr ammonium)
  • the inventive mixtures can be converted into customary types of agrochemical mixtures, e. g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof.
  • mixture types are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wetable powders or dusts (e.g. WP, SP, WS, DP, DS), pressings (e.g. BR, TB, DT), granules (e.g.
  • the mixtures are prepared in a known manner, such as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.
  • Suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.
  • Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions of medium to high boiling point, e.g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g. ethanol, propanol, butanol, benzylalcohol, cyclohexanol; glycols; DMSO; ketones, e.g. cyclohexanone; esters, e.g.
  • mineral oil fractions of medium to high boiling point e.g. kerosene, diesel oil
  • oils of vegetable or animal origin oils of vegetable or animal origin
  • aliphatic, cyclic and aromatic hydrocarbons e. g. toluene, paraffin, tetrahydronaphthalene, alkylated
  • lactates carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.
  • Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.
  • mineral earths e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide
  • polysaccharides e.g. cellulose, starch
  • fertilizers
  • Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon's, Vol.1 : Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).
  • Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof.
  • sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates.
  • Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters.
  • Examples of phosphates are phosphate esters.
  • Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.
  • Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof.
  • alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents.
  • Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide.
  • N-subsititued fatty acid amides are fatty acid glucamides or fatty acid alkanolamides.
  • esters are fatty acid esters, glycerol esters or monoglycerides.
  • sugar- based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or al- kylpolyglucosides.
  • polymeric surfactants are home- or copolymers of vinylpyrroli- done, vinylalcohols, or vinylacetate.
  • Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.
  • Suitable amphoteric surfactants are alkylbetains and imidazolines.
  • Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide.
  • Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or pol- yethyleneamines.
  • Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the inventive mixtures on the target.
  • examples are surfactants, mineral or vegetable oils, and other auxilaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.
  • Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), anorganic clays (organically modified or unmodified), polycarboxylates, and silicates.
  • Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.
  • Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
  • Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.
  • Suitable colorants are pigments of low water solubility and water- soluble dyes.
  • examples are inorganic colorants (e.g. iron oxide, titan oxide, iron hexacyanofer- rate) and organic colorants (e.g. alizarin-, azo- and phthalocyanine colorants).
  • Suitable tackifiers or binders are polyvinylpyrrolidone, polyvinylacetates, polyvinyl alcohols, pol- yacrylates, biological or synthetic waxes, and cellulose ethers.
  • Water-soluble concentrates (SL, LS) 10-60 wt% of an inventive mixture and 5-15 wt% wetting agent (e.g. alcohol alkoxylates) are dissolved in water and/or in a water-soluble solvent (e.g. alcohols) ad 100 wt%.
  • the active substance dissolves upon dilution with water.
  • an inventive mixture and 1 -10 wt% dispersant e. g. polyvinylpyrrolidone
  • organic solvent e.g. cyclohexanone
  • emulsifiers e.g. calcium dodecylben- zenesulfonate and castor oil ethoxylate
  • water-insoluble organic solvent e.g. aromatic hydrocarbon
  • Emulsions (EW, EO, ES)
  • emulsifiers e.g. calcium dodecylbenzene- sulfonate and castor oil ethoxylate
  • water-insoluble organic solvent e.g. aromatic hydrocarbon
  • 20-60 wt% of an inventive mixture are comminuted with addition of 2-10 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate), 0.1 - 2 wt% thickener (e.g. xanthan gum) and water ad 100 wt% to give a fine active substance suspension. Dilution with water gives a stable suspension of the active substance.
  • dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
  • 0.1 - 2 wt% thickener e.g. xanthan gum
  • an inventive mixture 50-80 wt% of an inventive mixture are ground finely with addition of dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate) ad 100 wt% and prepared as water- dispersible or water-soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.
  • dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
  • 50-80 wt% of an inventive mixture are ground in a rotor-stator mill with addition of 1 -5 wt% dispersants (e.g. sodium lignosulfonate), 1 -3 wt% wetting agents (e.g. alcohol ethoxylate) and solid carrier (e.g. silica gel) ad 100 wt%. Dilution with water gives a stable dispersion or solution of the active substance.
  • dispersants e.g. sodium lignosulfonate
  • 1 -3 wt% wetting agents e.g. alcohol ethoxylate
  • solid carrier e.g. silica gel
  • an inventive mixture In an agitated ball mill, 5-25 wt% of an inventive mixture are comminuted with addition of 3-10 wt% dispersants (e.g. sodium lignosulfonate), 1 -5 wt% thickener (e.g. carboxymethylcellulose) and water ad 100 wt% to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance.
  • dispersants e.g. sodium lignosulfonate
  • 1 -5 wt% thickener e.g. carboxymethylcellulose
  • an inventive mixture 5-20 wt% are added to 5-30 wt% organic solvent blend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt% surfactant blend (e.g. alcohol ethoxylate and arylphenol ethoxylate), and water ad 100 %.
  • organic solvent blend e.g. fatty acid dimethylamide and cyclohexanone
  • surfactant blend e.g. alcohol ethoxylate and arylphenol ethoxylate
  • An oil phase comprising 5-50 wt% of an inventive mixture, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), 2-15 wt% acrylic monomers (e.g. methylmethacrylate, methacrylic acid and a di- or triacrylate) are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.
  • an oil phase comprising 5-50 wt% of an inventive mixture according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer (e.g.
  • diphenylmethene-4,4'- diisocyanatae are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol).
  • a protective colloid e.g. polyvinyl alcohol.
  • the addition of a polyamine results in the formation of pol- yurea microcapsules.
  • the monomers amount to 1-10 wt%. The wt% relate to the total CS mixture.
  • Dustable powders (DP, DS)
  • an inventive mixture are ground finely and mixed intimately with solid carrier (e.g. finely divided kaolin) ad 100 wt%.
  • solid carrier e.g. finely divided kaolin
  • an inventive mixture is ground finely and associated with solid carrier (e.g. silicate) ad 100 wt%.
  • solid carrier e.g. silicate
  • organic solvent e.g. aromatic hydrocarbon
  • the mixtures types i) to xiii) may optionally comprise further auxiliaries, such as 0.1 -1 wt% bactericides, 5-15 wt% anti-freezing agents, 0.1 -1 wt% anti-foaming agents, and 0.1 -1 wt% color- ants.
  • auxiliaries such as 0.1 -1 wt% bactericides, 5-15 wt% anti-freezing agents, 0.1 -1 wt% anti-foaming agents, and 0.1 -1 wt% color- ants.
  • the resulting agrochemical mixtures generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of active substance.
  • the active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
  • Solutions for seed treatment (LS), Suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds.
  • the mixtures in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40%, in the ready-to-use preparations. Application can be carried out before or during sowing.
  • inventive mixtures and mixtures thereof, respectively, on to plant propagation material especially seeds include dressing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material.
  • inventive mixtures or the mixtures thereof, respectively, are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
  • the invention also relates to an herbicidal formulation, which comprises a herbicidally active mixture as defined herein and at least one carrier material, including liquid and/or solid carrier materials.
  • oils, wetters, adjuvants, fertilizer, or micronutrients, and further pesticides may be added to the active substances or the inventive mixtures comprising them as premix or, if appropriate not until immediately prior to use (tank mix).
  • pesticides e.g. herbicides, insecticides, fungicides, growth regulators, safeners
  • These agents can be admixed with the inventive mixtures in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.
  • the user applies the mixture according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
  • the agrochemi- cal mixture is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical mixture according to the invention is thus obtained.
  • 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to- use spray liquor are applied per hectare of agricultural useful area.
  • the invention also relates to the use of a mixture as defined herein for controlling undesirable vegetation in burndown programs, in industrial vegetation management and forestry, in vegetable and perennial crops and in turf and lawn, wherein the inventive mixtures can be applied pre- or post-emergence, i.e. before, during and/or after emergence of the unde- sirable plants.
  • the inventive mixtures are applied to a locus where crops will be planted before planting or emergence of the crop.
  • the present invention also relates to a method for burndown treatment of undesirable vegetation in crops, comprising applying an inventive mixture to a locus where crops will be planted before planting (or seeding) or emergence of the crop.
  • the inventive mixture is applied undesirable vegetation or the locus thereof.
  • present invention therefore relates to a method for controlling undesirable vegetation, which method comprises applying an inventive mixture to a locus where undesirable vegetation is present or is expected to be present, wherein application can be done before, during and/or after, preferably during and/or after, the emergence of the undesirable vegetation
  • undesirable vegetation As used herein, the terms “undesirable vegetation”, “undesirable species”, “undesirable plants”, “harmful plants”, “undesirable weeds”, or “harmfull weeds” are synonyms.
  • locus means the area in which the vegetation or plants are growing or will grow, typically a field.
  • the inventive mixtures can be applied prior to seeding (planting) or after seeding (or planting) of the crop plants but before the emergence of the crop plants, in particular prior to seeding.
  • the inventive mixtures are preferably applied prior to seeding of the crop plants.
  • the inventive mixtures will generally be applied a date up to 9 month, frequently up to 6 months, preferably up to 4 months prior to planting the crop.
  • the burndown application can be done at a date up to 1 day prior to emergence of the crop plant and is preferably done at a date prior to seeding/planting of the crop plant, preferably at a date of at least one day, preferably at least 2 days and in particular at least one 4 days prior to planting or from 6 months to 1 day prior emergence, in particular from 4 months to 2 days prior emergence and more preferably from 4 months to 4 days prior emergence. It is, of course, possible to repeat the burndown application once or more, e.g. once, twice, three times, four times or five times within that time frame. It is a particular benefit of the inventive mixtures that they have a very good post-emergence herbicide activity, i.e.
  • the inventive mixtures are applied post- emergence, i.e. during and/or after, the emergence of the undesirable plants. It is particularly advantageous to apply the inventive mixtures post emergent when the undesirable plant starts with leaf development up to flowering.
  • the inventive mixtures are particularly useful for controlling undesirable vegetation which has already developed to a state, which is difficult to control with conventional burndown mixtures, i.e. when the individual weed is taller than 10 cm (4 inches) or even taller than 15 cm (6 inches) and/or for heavy weed populations.
  • the inventive mixtures are preferably applied by foliar application.
  • spray shields may be used.
  • Application may be effected, for example, by usual spraying techniques with water as the carrier, using amounts of spray mixture of usually from 10 to 2000 l/ha, in particular 50 to 1000 l/ha.
  • the required application rate of the mixture of the pure active compounds depends on the density of the undesired vegetation, on the development stage of the plants, on the climatic conditions of the location where the mixture is used and on the application method.
  • the application rate of the mixture is from 55 to 6000 g/ha, preferably from 100 to 5000 g/ha, from 200 to 4000 g/ha, and more preferably from 300 to 3000 g/ha of active ingredient (a.i.).
  • the active compounds present in the inventive mixtures can be applied simultaneously or in succession, where undesirable vegetation may occur.
  • the individual compounds present in the inventive mixtures are formulated jointly or separately and applied jointly or separately, and, in the case of separate application, in which order the application takes place. It is only necessary, that the individual compounds present in the inventive mixtures are applied in a time frame, which allows simultaneous action of the active ingredients on the undesirable plants.
  • inventive mixtures have several advantages i.e. enhanced herbicide action in comparison if compared to mixtures of racemic glufosinate with an ALS inhibitor.
  • inventive mixtures show a persistant herbicidal activity, even under difficult weathering conditions, which allows a more flexible application in burndown applications and minimizes the risk of weeds escaping.
  • inventive mixtures show superior crop compatibility with certain conventional crop plants and with herbicide tolerant crop plants, i.e. their use in these crops leads to a reduced damage of the crop plants and/or does not result in increased damage of the crop plants.
  • inventive mixtures can also be applied after the emergence of the crop plants.
  • the inventive mixtures may also show an accelerated action on harmful plants, i.e. they may affect damage of the harmful plants more quickly if compared to mixtures of racemic glufosinate with at least one ALS inhibitor.
  • the inventive mixtures are suitable for controlling a large number of harmful plants in agricultural crops, including monocotyledonous weeds, in particular annual weeds such as gramineous weeds (grasses) including Echinochloa species such as barnyardgrass (Echinochloa crusgalli var.
  • Poa species such as Poa an- nua or Poa trivialis L, Puccinellia distans, Rottboellia cochinchinensis, Sclerochloa kengiana (Ohwi) Tzvel., Trichloris crinita, Urochloa or Brachiaria species such as Brachiaria decumbens, Brachiaria plantaginea, Brachiaria platyphylla, Urochloa panicoides, Urochloa ramosa and the like.
  • Both L-glufosinate alone as well as the inventive mixtures are also suitable for controlling a large number of dicotyledonous weeds, in particular broad leaf weeds including Polygonum species such as wild buckwheat (Polygonum convolvolus), Polygonum pensilvanicum, Polygonum persicaria or prostrate knotweed (Polygonum aviculare), Amaranthus species such as pig- weed (Amaranthus retroflexus), Palmer amaranth (Amaranthus palmeri), tall waterhemp (Amaranthus tuberculatus or Amaranthus rudis), redroot pigweed (Amaranthus retroflexus), green amaranth (Amaranthus hybridus), purple amaranth (Amaranthus lividus), prickly amaranth (Amaranthus spinosus) or Amaranthus quitensis, Chenopodium species such as common lambsquarters (Chenopodium album L), Chenopodium serotinum
  • Both L-glufosinate alone as well as the inventive mixtures are also suitable for controlling a large number of annual and perennial sedge weeds including Cyperus species such as purple nutsedge (Cyperus rotundus L.), yellow nutsedge (Cyperus esculentus L.), hime-kugu (Cyperus brevifolius H.), sedge weed (Cyperus microiria Steud), rice flatsedge (Cyperus iria L.), Cyperus difformis, Cyperus difformis L., Cyperus esculentus, Cyperus ferax, Cyperus flavus, Cyperus iria, Cyperus lanceolatus, Cyperus odoratus, Cyperus rotundus, Cyperus serotinus Rottb., Eleocharis acicularis, Eleocharis kuroguwai, Fimbristylis dichotoma, Fimbristylis
  • Both L-glufosinate alone as well as the inventive mixtures are also suitable for controlling weeds that are resistant to commonly used herbicides such as, for example, weeds that are resistant to glyphosate, weeds that are resistant to auxin inhibitor herbicides such as e. g. 2,4-D or dicam- ba, weeds that are resistant to photosynthesis inhibitors such as e. g. atrazine, weeds that are resistant to ALS inhibitors such as e. g. sulfonylureas, imidazolinones or triazolopyrimidines, weeds that are resistant to ACCase inhibitors such as e. g.
  • clodinafop clethodim or pinoxaden or weeds that are resistant to protoporphyrinogen-IX-oxidase inhibitors such as e. g. sulfentra- zone, flumioxazine, fomesafen or acifluorfen, for example the weeds that are listed in the Inter- national Survey of Resistant Weeds
  • Rapistrum rugosum Rorippa indica, Rotala indica, Rotala pusilla, Rumex dentatus, Sagittaria guayensis, Sagittaria pygmaea, Sagittaria trifolia
  • Schoenoplectus fluviatilis Schoenoplectus juncoides
  • Schoenoplectus wallichii Sida spinosa, Silene gallica, Sinapis alba, Sisymbrium thel- lungii, Sorghum bicolor
  • mice Micranthos, Cirsium arvense, Commelina diffusa, Echinochloa crus-pavonis, Soliva sessilis and Sphenoclea zeylanica, HPPD inhibitor resistant Amaranthus palmeri and Amaranthus rudis, PPO inhibitor resistant Acalypha australis, Amaranthus hybridus, Amaranthus palmeri, Amaranthus retroflexus, Amaranthus rudis, Ambrosia artemisifolia, Avena fatua, Conyza sumatrensis, Descurainia sophia, Euphorbia heterophylla and Senecio vernalis, carotenoid biosynthesis inhibitor resistant Hydrilla verticillata, Raphanus raphanistrum, Senecio vernalis and Sisymbrium orientale, VLCFA inhibitor resistant Alopecurus myosuroides, Avena fatua and Echinochloa crus-galli.
  • the inventive mixtures are suitable for combating/controlling common harmful plants in fields, where useful plants shall be planted (i.e. in crops).
  • the inventive mixtures are generally suitable for burndown of undesired vegetation in fields of the following crops:
  • Grain crops including e.g.
  • cereals small grain crops such as wheat (Triticum aestivum) and wheat like crops such as durum (T. durum), einkorn (T. monococcum), emmer (T. dicoccon) and spelt (T. spelta), rye (Secale cereale), triticale (Tritiosecale), barley (Hordeum vul- gare);
  • sorghum e.g. Sorghum bicolour
  • rice (Oryza spp. such as Oryza sativa and Oryza glaberrima); and
  • Fabaceae including e.g. soybeans (Glycine max.), peanuts (Arachis hypo- gaea and pulse crops such as peas including Pisum sativum, pigeon pea and cowpea, beans including broad beans (Vicia faba), Vigna spp., and Phaseolus spp. and lentils (lens culinaris var.);
  • brassicaceae including e.g. canola (Brassica napus), oilseed rape (OSR, Brassica na- pus), cabbage (B. oleracea var.), mustard such as B. juncea, B. campestris, B. narinosa,
  • broadleaf crops including e.g. sunflower, cotton, flax, linseed, sugarbeet, potato and tomato;
  • TNV-crops trees, nuts and vine
  • grapes citrus, pomefruit, e.g. apple and pear, coffee, pistachio and oilpalm, stonefruit, e.g. peach, almond, walnut, olive, cherry, plum and apricot
  • pomefruit e.g. apple and pear
  • coffee pistachio and oilpalm
  • stonefruit e.g. peach, almond, walnut, olive, cherry, plum and apricot
  • peach almond, walnut, olive, cherry, plum and apricot
  • garden ornamentals such as roses, petunia, marigold and snapdragon.
  • the inventive mixtures are in particular suitable for burndown of undesired vegetation in fields of the following crop plants: small grain crops such as wheat, barley, rye, triticale and durum, rice, maize (corn), sugarcane, sorghum, soybean, pulse crops such as pea, bean and lentils, peanut, sunflower, sugarbeet, potato, cotton, brassica crops, such as oilseed rape, canola, mustard, cabbage and turnip, turf, pasture, rangeland, grapes, pomefruit, such as apple and pear, stonefruit, such as peach, almond, walnut, pecans, olive, cherry, plum and apricot, citrus, coffee, pistachio, garden ornamentals, such as roses, petunia, marigold, snap dragon, bulb ornamentals such as tulips and narcissus, conifers and deciduous trees such as pinus, fir, oak, maple, dogwood, ha
  • the inventive mixtures are most suitable for burndown of undesired vegetation in fields of the following crop plants: small grain crops such as wheat, barley, rye, triticale and durum, rice, maize, sugarcane, soybean, pulse crops such as pea, bean and lentils, peanut, sunflower, cotton, brassica crops, such as oilseed rape, canola, turf, pasture, rangeland, grapes, stonefruit, such as peach, almond, walnut, pecans, olive, cherry, plum and apricot, citrus and pistachio.
  • small grain crops such as wheat, barley, rye, triticale and durum
  • rice maize
  • sugarcane soybean
  • pulse crops such as pea, bean and lentils
  • peanut, sunflower, cotton, brassica crops such as oilseed rape, canola
  • turf pasture, rangeland, grapes, stonefruit, such as peach, almond, walnut, pecans, olive, cherry, plum and apricot, citrus and pistachio.
  • the invention furthermore relates to the use of a mixture as defined herein for controlling undesirable vegetation in crops in a burndown program, in industrial vegetation management and forestry, in vegetable and perennial crops and in turf and lawn, wherein the crop is produced by genetic engineering or by breeding, are resistant to one or more herbicides and/or pathogens such as plant-pathogenous fungi, and/or to attack by insects; preferably resistant to glufosinate.
  • crops as used herein includes also (crop) plants which have been modified by mutagenesis or genetic engineering in order to provide a new trait to a plant or to modify an already present trait.
  • Mutagenesis includes techniques of random mutagenesis using X-rays or mutagenic chemicals, but also techniques of targeted mutagenesis, in order to create mutations at a specific locus of a plant genome.
  • Targeted mutagenesis techniques frequently use oligonucleotides or proteins like CRISPR/Cas, zinc-finger nucleases, TALENs or meganucleases to achieve the targeting effect.
  • Genetic engineering usually uses recombinant DNA techniques to create modifications in a plant genome which under natural circumstances cannot readily be obtained by cross breeding, mutagenesis or natural recombination.
  • one or more genes are integrated into the genome of a plant in order to add a trait or improve a trait.
  • transgenic plants These integrated genes are also referred to as transgenes in the art, while plant comprising such transgenes are referred to as transgenic plants.
  • the process of plant transformation usually produces several transformation events, which differ in the genomic locus in which a transgene has been integrated. Plants comprising a specific transgene on a specific genomic locus are usually described as comprising a specific "event", which is referred to by a specific event name. Traits which have been introduced in plants or have been modified include in particular herbicide tolerance, insect re- sistance, increased yield and tolerance to abiotic conditions, like drought.
  • Herbicide tolerance has been created by using mutagenesis as well as using genetic engineer- ing. Plants which have been rendered tolerant to acetolactate synthase (ALS) inhibitor herbicides by conventional methods of mutagenesis and breeding comprise plant varieties commercially available under the name Clearfield ® . However, most of the herbicide tolerance traits have been created via the use of transgenes.
  • ALS acetolactate synthase
  • Herbicide tolerance has been created to glyphosate, glufosinate, 2,4-D, dicamba, oxynil herbicides, like bromoxynil and ioxynil, sulfonylurea herbicides, ALS inhibitor herbicides and 4- hydroxyphenyl pyruvate dioxygenase (HPPD) inhibitors, like isoxaflutole and mesotrione.
  • HPPD 4- hydroxyphenyl pyruvate dioxygenase
  • Transgenes which have been used to provide herbicide tolerance traits comprise: for tolerance to glyphosate: cp4 epsps, epsps grg23ace5, mepsps, 2mepsps, gat4601 , gat4621 and goxv247, for tolerance to glufosinate: pat and bar, for tolerance to 2,4-D: aad-1 and aad-12, for tolerance to dicamba: dmo, for tolerance to oxynil herbicies: bxn, for tolerance to sulfonylurea herbicides: zm-hra, csr1 -2, gm-hra, S4-HrA, for tolerance to ALS inhibitor herbicides: csr1 -2, for tolerance to HPPD inhibitor herbicides: hppdPF, W336 and avhppd-03.
  • Transgenic corn events comprising herbicide tolerance genes are for example, but not exclud- ing others, DAS40278, MON801 , MON802, MON809, MON810, MON832, MON8741 1 ,
  • Transgenic soybean events comprising herbicide tolerance genes are for example, but not ex- eluding others, GTS 40-3-2, MON87705, MON87708, MON87712, MON87769, MON89788, A2704-12, A2704-21 , A5547-127, A5547-35, DP356043, DAS44406-6, DAS68416-4, DAS- 81419-2, GU262, SYHT0H2, W62, W98, FG72 and CV127.
  • Transgenic cotton events comprising herbicide tolerance genes are for example, but not excluding others, 19-51 a, 31707, 42317, 81910, 281 -24-236, 3006-210-23, BXN1021 1 , BXN 10215, BXN10222, BXN 10224, MON1445, MON1698, MON88701 , MON88913, GHB1 19, GHB614, LLCotton25, T303-3 and T304-40.
  • Transgenic canola events comprising herbicide tolerance genes are for example, but not excluding others, MON88302, HCR-1 , HCN10, HCN28, HCN92, MS1 , MS8, PHY14, PHY23, PHY35, PHY36, RF1 , RF2 and RF3.
  • Insect resistance has mainly been created by transferring bacterial genes for insecticidal proteins to plants.
  • Transgenes which have most frequently been used are toxin genes of Bacillus spec, and synthetic variants thereof, like cry1A, crylAb, cry1Ab-Ac, crylAc, cry1A.105, cry1 F, cry1 Fa2, cry2Ab2, cry2Ae, mcry3A, ecry3.1Ab, cry3Bb1 , cry34Ab1 , cry35Ab1 , cry9C, vip3A(a), vip3Aa20.
  • genes of plant origin have been transferred to other plants.
  • genes coding for protease inhibitors like CpTI and pinll.
  • a further approach uses transgenes in order to produce double stranded RNA in plants to target and downregulate insect genes.
  • An example for such a transgene is dvsnf7.
  • Transgenic corn events comprising genes for insecticidal proteins or double stranded RNA are for example, but not excluding others, Bt10, Bt1 1 , Bt176, MON801 , MON802, MON809,
  • Transgenic soybean events comprising genes for insecticidal proteins are for example, but not excluding others, MON87701 , MON87751 and DAS-81419.
  • Transgenic cotton events comprising genes for insecticidal proteins are for example, but not excluding others, SGK321 , MON531 , MON757, MON1076, MON15985, 31707, 31803, 31807, 31808, 42317, BNLA-601 , Eventl , COT67B, COT102, T303-3, T304-40, GFM Cry1A, GK12, MLS 9124, 281 -24-236, 3006-210-23, GHB1 19 and SGK321.
  • Increased yield has been created by increasing ear biomass using the transgene athb17, being present in corn event MON87403, or by enhancing photosynthesis using the transgene bbx32, being present in the soybean event MON87712.
  • Crops comprising a modified oil content have been created by using the transgenes: gm-fad2-1 , Pj.D6D, Nc.Fad3, fad2-1A and fatb1 -A. Soybean events comprising at least one of these genes are: 260-05, MON87705 and MON87769.
  • Tolerance to abiotic conditions, in particular to tolerance to drought, has been created by using the transgene cspB, comprised by the corn event MON87460 and by using the transgene Hahb- 4, comprised by soybean event IND-00410-5.
  • Traits are frequently combined by combining genes in a transformation event or by combining different events during the breeding process.
  • Preferred combination of traits are herbicide tolerance to different groups of herbicides, insect tolerance to different kind of insects, in particular tolerance to lepidopteran and coleopteran insects, herbicide tolerance with one or several types of insect resistance, herbicide tolerance with increased yield as well as a combination of herbicide tolerance and tolerance to abiotic conditions.
  • inventive mixtures on crops may result in effects which are specific to a crop com- prising a certain gene or event. These effects might involve changes in growth behavior or changed resistance to biotic or abiotic stress factors. Such effects may in particular comprise enhanced yield, enhanced resistance or tolerance to insects, nematodes, fungal, bacterial, mycoplasma, viral or viroid pathogens as well as early vigour, early or delayed ripening, cold or heat tolerance as well as changed amino acid or fatty acid spectrum or content.
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of ingredients or new ingredients, specifically to improve raw material produc- tion, e.g., potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
  • a modified amount of ingredients or new ingredients specifically to improve raw material produc- tion, e.g., potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
  • glufosinate tolerant crop plant is preferably selected grom the group consisting of rice, canola, soybean, corn and cotton plants.
  • Transgenic corn events comprising glufosinate tolerance genes are for example, but not excluding others, 5307 x MIR604 x Bt1 1 x TC1507 x GA21 x MIR162 (event code: SYN-05307-1 x SYN-IR604-5 x SYN-BT01 1 -1 x DAS-01507-1 x MON-00021 -9 x SYN-IR162-4, gene: pat, e.g. commercially available as Agrisure® DuracadeTM 5222), 59122 (event code: DAS-59122-7, gene: pat, e.g.
  • Bt10 Bt1 1 (X4334CBR, X4734CBR)
  • Bt1 1 X4334CBR, X4734CBR
  • Event code SYN-BT01 1 -1
  • gene: pat e.g. commercially available as AgrisureTM CB/LL
  • BT1 1 x 59122 x MIR604 x TC1507 x GA21 event code: SYN- BT01 1 -1 x DAS-59122-7 x SYN-IR604-5 x DAS-01507-1 x MON-00021 -9
  • gene: pat e.g.
  • Bt1 1 x GA21 (event code: SYN-BT01 1 -1 x MON- 00021 -9, gene: pat, e.g. commercially available as AgrisureTM GT/CB/LL), Bt1 1 x MIR162 (event code: SYN-BT01 1 -1 x SYN-IR162-4, gene: pat, e.g. commercially available as Agrisure® VipteraTM 2100), Bt1 1 x MIR162 x GA21 (event code: SYN-BT01 1 -1 x SYN-IR162-4 x MON-00021 -9, gene: pat, e.g.
  • BT1 1 x MIR162 x MIR604 (event code: SYN-BT01 1 -1 x SYN-IR162-4 x SYN-IR604-5, gene: pat, e.g. commercially available as Agrisure® VipteraTM 3100), Bt1 1 x MIR162 x MIR604 x GA21 (event code: SYN-BT01 1 -1 x SYN-IR162-4 x SYN-IR604-5 x MON-00021 -9, gene: pat, e.g.
  • Agrisure® VipteraTM 31 1 1 , Agrisure® VipteraTM 4 Bt1 1 x MIR162 x TC1507 x GA21 (event code: SYN-BT01 1 -1 x SYN-IR162-4 x DAS-01507-1 x MON-00021 - 9, gene: pat, e.g. commercially available as AgrisureTM Viptera 3220), Bt1 1 x MIR604 (event code: SYN-BT01 1 -1 x SYN-IR604-5, gene: pat, e.g.
  • TC1507 x 59122 (event code: DAS-01507-1 x DAS- 59122-7, gene: pat, e.g. commercially available as Herculex XTRATM), TC1507 x 59122 x MON810 x NK603 (event code: DAS-01507-1 x DAS-59122-7 x MON-00810-6 x MON- 00603-6, gene: pat, e.g.
  • OptimumTM Intrasect XTRA TC1507 x 59122 x NK603 (event code: DAS-01507-1 x DAS-59122-7 x MON-00603-6, gene: pat, e.g. commercially available as Herculex XTRATM RR), TC1507 x MIR604 x NK603 (event code: DAS-01507-1 x SYN-IR604-5 x MON-00603-6, gene: pat, e.g.
  • TC1507 x MON810 x NK603 (event code: DAS-01507-1 x MON-00810- 6 x MON-00603-6, gene: pat, e.g. commercially available as OptimumTM Intrasect), TC1507 x NK603 (event code: DAS-01507-1 x MON-00603-6, gene: pat, e.g.
  • DAS40278 (event code: DAS-59122-7 x MON-88017-3 x DAS-40278-9, gene: pat), 59122 x NK603 x MIR604 (event code: DAS-59122-7 x MON-00603-6 x SYN-IR604-5, gene: pat), Bt1 1 x 5307 (event code: SYN-BT01 1-1 x SYN-05307-1 , gene: pat), Bt1 1 x 5307 x GA21 (event code: SYN-BT01 1-1 x SYN-05307-1 x MON-00021-9, gene: pat), Bt11 x MIR162 x 5307 (event code: SYN-BT011-1 x SYN-IR162-4 x SYN-05307-1 , gene: pat), Bt11 x MIR162 x 5307 x GA21 (event code: SYN-BT01 1-1 x S
  • MON87427 x TC1507 x MON88017 x 59122 (event code: MON-87427-7 x DAS-01507-1 x MON-88017-3 x DAS-59122-7, gene: pat)
  • MON89034 x 59122 x DAS40278 (event code: MON-89034-3 x DAS-59122-7 x DAS-40278-9, gene: pat)
  • MON89034 x 59122 x MON88017 x DAS40278 (event code: MON-89034-3 x DAS-59122-7 x MON-88017-3 x DAS-40278-9, gene: pat)
  • MON89034 x TC1507 x 59122 x DAS40278 (event code: MON-89034-3 x DAS- 01507-1 x DAS-59122-7 x DAS-40278-9, gene: pat)
  • Transgenic soybean events comprising glufosinate tolerance genes are for example, but not excluding others, A2704-12 (event code: ACS-GM005-3, gene: pat , e.g. commercially availa- ble as Liberty LinkTM soybean), A2704-21 (event code: ACS-GM004-2, gene: pat, e.g. commercially available as Liberty LinkTM soybean), A5547-127 (event code: ACS-GM006-4, gene: pat, e.g. commercially available as Liberty LinkTM soybean), A5547-35 (event code: ACS- GM008-6, gene: pat, e.g.
  • MON89788 (event code: DAS-68416-4 x MON-89788-1 , gene: pat), SYHT0H2 (event code: SYN-000H2-5, gene: pat), DAS81419 x DAS44406-6 (event code: DAS-81419-2 x DAS- 44406-6, gene: pat) and FG72 x A5547-127 (event code: MST-FG072-3 x ACS-GM006-4, gene: pat).
  • Transgenic cotton events comprising glufosinate tolerance genes are for example, but not ex- eluding others, 3006-210-23 x 281 -24-236 x MON1445 (event code: DAS-21023-5 x DAS- 24236-5 x MON-01445-2, gene: bar, e.g. commercially available as WideStrikeTM Roundup ReadyTM Cotton), 3006-210-23 x 281 -24-236 x MON88913 (event code: DAS-21023-5 x DAS- 24236-5 x MON-88913-8, gene: bar, e.g.
  • Transgenic canola events comprising glufosinate tolerance genes are for example, but not ex- eluding others, HCN10 (Topas 19/2) (event code: , gene: bar, e.g. commercially available as Liberty LinkTM IndependenceTM), HCN28 (T45) (event code: ACS-BN008-2, gene: pat, e.g. commercially available as InVigorTM Canola), HCN92 (Topas 19/2 (event code: ACS-BN007-1 , gene: bar, e.g. commercially available as Liberty LinkTM InnovatorTM), MS1 (B91 -4) (event code: ACS-BN004-7, gene: bar, e.g.
  • InVigorTM Canola commercially available as InVigorTM Canola
  • RF3 event code: ACS-BN003-6, gene: bar, e.g. commercially available as InVigorTM Canola
  • MS1 x MON88302 event code: ACS-BN004-7 x MON- 88302-9, gene: bar, e.g. commercially available as InVigorTM x TruFlexTM Roundup ReadyTM Canola
  • MS8 x MON88302 event code: ACS-BN005-8 x MON-88302-9, gene: bar, e.g.
  • InVigorTM x TruFlexTM Roundup ReadyTM Canola RF1 x MON88302 (event code: ACS-BN001 -4 x MON-88302-9, gene: bar, e.g. commercially available as InVigorTM x TruFlexTM Roundup ReadyTM Canola), RF2 x MON88302 (event code: ACS-BN002-5 x MON-88302-9, gene: bar, e.g. commercially available as InVigorTM x TruFlexTM Roundup
  • HCN28 x MON88302 (event code: ACS-BN008-2 x MON-88302-9, gene: pat, e.g. commercially available as InVigorTM x TruFlexTM Roundup ReadyTM Canola), HCN92 x MON88302 (event code: ACS-BN007-1 x MON-88302-9, gene: bar, e.g.
  • Transgenic rice events comprising glufosinate tolerance genes are for example, but not excluding others, LLRICE06 (event code: ACS-OS001 -4, e.g. commercially available as Liberty LinkTM rice), LLRICE601 (event code: BCS-OS003-7, e.g. commercially available as Liberty LinkTM rice) and LLRICE62 (event code: ACS-OS002-5, e.g. commercially available as Liberty LinkTM rice).
  • LLRICE06 event code: ACS-OS001 -4, e.g. commercially available as Liberty LinkTM rice
  • LLRICE601 event code: BCS-OS003-7, e.g. commercially available as Liberty LinkTM rice
  • LLRICE62 event code: ACS-OS002-5, e.g. commercially available as Liberty LinkTM rice.
  • inventive mixtures can be applied in conventional manner by using techniques as skilled person is familiar with. Suitable techniques include spraying, atomizing, dusting, spreading or watering. The type of application depends on the intended purpose in a well known manner; in any case, they should ensure the finest possible distribution of the active ingredients according to the invention.
  • inventive mixtures are applied to locus mainly by spraying, in particular foliar spraying of an aqueous dilution of the active ingredients of the mixture.
  • Application can be carried out by customary spraying techniques using, for example, water as carrier and spray liquor rates of from about 10 to 2000 l/ha or 50 to 1000 l/ha (for example from 100 to 500 l/ha).
  • Application of the inventive mixtures by the low-volume and the ultra-low-volume method is possible, as is their application in the form of microgranules.
  • the required application rate of the mixture of the pure active compounds depends on the density of the undesired vegetation, on the development stage of the plants, on the climatic conditions of the location where the mixture is used and on the application method.
  • the rate of application of L-glufosinate is usually from 50 g/ha to 3000 g/ha and preferably in the range from 100 g/ha to 2000 g/ha or from 200 g/ha to 1500 g/ha of active substance (a.i.), and the rate of application of the ALS inhibitors is from 1 g/ha to 2000 g/ha and preferably in the range from 5 g/ha to 1500 g/ha, more preferably from 25 g/ha to 900 g/ha of active substance (a.i.).

Abstract

La présente invention concerne un mélange herbicide comprenant du L-glufosinate ou son sel et au moins un inhibiteur de ALS. L'invention concerne en outre un procédé de lutte contre la végétation indésirable dans des programmes de brûlage, dans la gestion de végétation industrielle et la sylviculture, dans des cultures végétales et pérennes et dans le gazon et la pelouse.
PCT/EP2018/070931 2017-08-09 2018-08-02 Mélanges herbicides comprenant du l-glufosinate ou son sel et au moins un inhibiteur de als WO2019030089A1 (fr)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11122807B2 (en) 2017-08-09 2021-09-21 Basf Se Herbicidal mixtures comprising L-glufosinate or its salt and a second herbicide
EP3932205A1 (fr) * 2020-07-03 2022-01-05 Belchim Crop Protection USA, LLC Compositions herbicides et procédés associés
US11350631B2 (en) 2017-08-09 2022-06-07 Basf Se Herbicidal mixtures comprising l-glufosinate or its salt and at least one VLCFA inhibitor
US11363818B2 (en) 2017-08-09 2022-06-21 Basf Se Herbicidal mixtures comprising L-glufosinate and their use in soybean cultures
CN115104623A (zh) * 2021-03-22 2022-09-27 江苏七洲绿色化工股份有限公司 除草组合物及其制备方法
US11477985B2 (en) 2017-08-09 2022-10-25 Basf Se Herbicidal mixtures comprising L-glufosinate or its salt and at least one photosynthesis inhibitor
US11589591B2 (en) 2017-08-09 2023-02-28 Basf Se Herbicidal mixtures comprising L-glufosinate and their use in corn cultures
US11666052B2 (en) 2017-08-09 2023-06-06 Basf Se Herbicidal mixtures comprising L-glufosinate or its salt and at least one bleacher herbicide
US11666053B2 (en) 2017-08-09 2023-06-06 Basf Se Herbicidal mixtures comprising L-glufosinate and their use in cotton cultures
WO2024069167A1 (fr) * 2022-09-29 2024-04-04 Upl Mauritius Limited Combinaison herbicide, composition et procédé de lutte contre les mauvaises herbes l'utilisant

Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4265654A (en) 1977-12-28 1981-05-05 Meiji Seika Kaisha Ltd. Herbicidal compositions
EP0127429A2 (fr) 1983-05-27 1984-12-05 Meiji Seika Kaisha Ltd. Procédé de préparation de dérivés optiquement actifs d'acide((amino-3-carboxy-3)-propyl-1)phosphinique
EP0256942A2 (fr) * 1986-08-08 1988-02-24 Meiji Seika Kaisha Ltd. Composition herbicide
DE3938564A1 (de) 1989-11-21 1991-05-23 Hoechst Ag Herbizide mittel
WO1992008353A1 (fr) 1990-11-13 1992-05-29 Hoechst Aktiengesellschaft Herbicides synergiques
US5530142A (en) 1988-05-27 1996-06-25 Hoechst Aktiengesellschaft Process for the preparation of phosphorus-containing L-amino acids and their esters and N-derivatives
DE19815820A1 (de) 1998-04-08 1999-10-14 Hoechst Schering Agrevo Gmbh Synergistische herbizide Mittel auf Basis von phosphorhaltigen Blattherbiziden, Imidazolinonen und Wuchsstoffherbiziden
US7105470B1 (en) * 1998-08-13 2006-09-12 Hoechst Schering Agrevo Gmbh Herbicidal compositions for tolerant or resistant soybean crops
WO2006104120A1 (fr) 2005-03-29 2006-10-05 Meiji Seika Kaisha Ltd. Procede de production de l'acide l-2-amino-4-(hydroxymethylphosphinyl)butanoique
WO2009141367A2 (fr) 2008-05-21 2009-11-26 Basf Se Composition herbicide comprenant du glyphosate, du glufosinate ou leurs sels
JP2010077047A (ja) * 2008-09-25 2010-04-08 Sumitomo Chemical Co Ltd ヤトロファが生育している場所の雑草を防除する方法。
US20110287932A1 (en) * 2010-05-21 2011-11-24 Bayer Cropscience Ag Herbicidal composition for tolerant or resistant cereal crops
US20110287934A1 (en) * 2010-05-21 2011-11-24 Bayer Cropscience Ag Herbicidal composition for tolerant or resistant rice crops
US20130023413A1 (en) * 2011-05-20 2013-01-24 Bayer Intellectual Property Gmbh Herbicidal compositions for tolerant or resistant soybean crops
US20130190179A1 (en) * 2010-10-15 2013-07-25 Bayer Intellectual Property Gmbh Use of als inhibitor herbicides for control of unwanted vegetation in als inhibitor herbicide tolerant beta vulgaris plants
WO2013154396A1 (fr) 2012-04-12 2013-10-17 Dongbu Farm Hannong Co., Ltd. Composition herbicide comprenant un composé uracile comme ingrédient actif
EP3028573A1 (fr) 2014-12-05 2016-06-08 Basf Se Utilisation d'un triazole fongicide sur des plantes transgéniques
WO2016113334A1 (fr) * 2015-01-15 2016-07-21 Basf Se Combinaison herbicide comprenant du saflufénacil et du glufosinate
WO2017011288A1 (fr) 2015-07-13 2017-01-19 E I Du Pont De Nemours And Company Éthers d'aryloxypyrimidinyle employés comme herbicides

Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4265654A (en) 1977-12-28 1981-05-05 Meiji Seika Kaisha Ltd. Herbicidal compositions
EP0127429A2 (fr) 1983-05-27 1984-12-05 Meiji Seika Kaisha Ltd. Procédé de préparation de dérivés optiquement actifs d'acide((amino-3-carboxy-3)-propyl-1)phosphinique
EP0256942A2 (fr) * 1986-08-08 1988-02-24 Meiji Seika Kaisha Ltd. Composition herbicide
US5530142A (en) 1988-05-27 1996-06-25 Hoechst Aktiengesellschaft Process for the preparation of phosphorus-containing L-amino acids and their esters and N-derivatives
DE3938564A1 (de) 1989-11-21 1991-05-23 Hoechst Ag Herbizide mittel
WO1992008353A1 (fr) 1990-11-13 1992-05-29 Hoechst Aktiengesellschaft Herbicides synergiques
DE19815820A1 (de) 1998-04-08 1999-10-14 Hoechst Schering Agrevo Gmbh Synergistische herbizide Mittel auf Basis von phosphorhaltigen Blattherbiziden, Imidazolinonen und Wuchsstoffherbiziden
US6436874B1 (en) * 1998-04-08 2002-08-20 Aventis Cropscience Gmbh Synergistic herbicidal agents based on leaf herbicides containing phosphorus, imidazolinones and hormone weed killers
US7105470B1 (en) * 1998-08-13 2006-09-12 Hoechst Schering Agrevo Gmbh Herbicidal compositions for tolerant or resistant soybean crops
WO2006104120A1 (fr) 2005-03-29 2006-10-05 Meiji Seika Kaisha Ltd. Procede de production de l'acide l-2-amino-4-(hydroxymethylphosphinyl)butanoique
WO2009141367A2 (fr) 2008-05-21 2009-11-26 Basf Se Composition herbicide comprenant du glyphosate, du glufosinate ou leurs sels
JP2010077047A (ja) * 2008-09-25 2010-04-08 Sumitomo Chemical Co Ltd ヤトロファが生育している場所の雑草を防除する方法。
US20110287932A1 (en) * 2010-05-21 2011-11-24 Bayer Cropscience Ag Herbicidal composition for tolerant or resistant cereal crops
US20110287934A1 (en) * 2010-05-21 2011-11-24 Bayer Cropscience Ag Herbicidal composition for tolerant or resistant rice crops
US20130190179A1 (en) * 2010-10-15 2013-07-25 Bayer Intellectual Property Gmbh Use of als inhibitor herbicides for control of unwanted vegetation in als inhibitor herbicide tolerant beta vulgaris plants
US20130023413A1 (en) * 2011-05-20 2013-01-24 Bayer Intellectual Property Gmbh Herbicidal compositions for tolerant or resistant soybean crops
WO2013154396A1 (fr) 2012-04-12 2013-10-17 Dongbu Farm Hannong Co., Ltd. Composition herbicide comprenant un composé uracile comme ingrédient actif
EP3028573A1 (fr) 2014-12-05 2016-06-08 Basf Se Utilisation d'un triazole fongicide sur des plantes transgéniques
WO2016113334A1 (fr) * 2015-01-15 2016-07-21 Basf Se Combinaison herbicide comprenant du saflufénacil et du glufosinate
WO2017011288A1 (fr) 2015-07-13 2017-01-19 E I Du Pont De Nemours And Company Éthers d'aryloxypyrimidinyle employés comme herbicides

Non-Patent Citations (10)

* Cited by examiner, † Cited by third party
Title
"McCutcheon's, Vol.1: Emulsifiers & Detergents", vol. 1, 2008, MCCUTCHEON'S DIRECTORIES
"Pesticide Manual", vol. 5.2, 2008
"Technical Monograph", May 2008, CROPLIFE INTERNATIONAL, article "Catalogue of pesticide formulation types and international coding system"
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; YAMATO, SEIJI ET AL: "Acetolactate synthase inhibitor for weed control around Jatropha", XP002774642, retrieved from STN Database accession no. 2010:433141 *
F. SCHWERDTLE ET AL., Z. PFLANZENKR. PFLANZENSCHUTZ, 1981, pages 431 - 440
J. CHEM. SOC. PER-KIN TRANS., vol. 1, 1992, pages 1525 - 1529
KNOWLES: "Agrow Reports DS243", 2005, T&F INFORMA, article "New developments in crop protection product formulation"
KNOWLES: "Agrow Reports DS256", 2006, T&F INFORMA, article "Adjuvants and additives"
MOLLET; GRUBEMANN: "Formulation technology", 2001, WILEY VCH
MONIKA RUHLAND ET AL: "Distribution and metabolism ofD/L-,L- andD-glufosinate in transgenic, glufosinate-tolerant crops of maize(Zea mays L sspmays) and oilseed rape(Brassica napus L varnapus)", PEST MANAGEMENT SCIENCE, vol. 60, no. 7, 14 June 2004 (2004-06-14), BOGNOR REGIS; GB, pages 691 - 696, XP055415713, ISSN: 1526-498X, DOI: 10.1002/ps.857 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11122807B2 (en) 2017-08-09 2021-09-21 Basf Se Herbicidal mixtures comprising L-glufosinate or its salt and a second herbicide
US11350631B2 (en) 2017-08-09 2022-06-07 Basf Se Herbicidal mixtures comprising l-glufosinate or its salt and at least one VLCFA inhibitor
US11363818B2 (en) 2017-08-09 2022-06-21 Basf Se Herbicidal mixtures comprising L-glufosinate and their use in soybean cultures
US11477985B2 (en) 2017-08-09 2022-10-25 Basf Se Herbicidal mixtures comprising L-glufosinate or its salt and at least one photosynthesis inhibitor
US11589591B2 (en) 2017-08-09 2023-02-28 Basf Se Herbicidal mixtures comprising L-glufosinate and their use in corn cultures
US11666052B2 (en) 2017-08-09 2023-06-06 Basf Se Herbicidal mixtures comprising L-glufosinate or its salt and at least one bleacher herbicide
US11666053B2 (en) 2017-08-09 2023-06-06 Basf Se Herbicidal mixtures comprising L-glufosinate and their use in cotton cultures
EP3932205A1 (fr) * 2020-07-03 2022-01-05 Belchim Crop Protection USA, LLC Compositions herbicides et procédés associés
CN115104623A (zh) * 2021-03-22 2022-09-27 江苏七洲绿色化工股份有限公司 除草组合物及其制备方法
WO2024069167A1 (fr) * 2022-09-29 2024-04-04 Upl Mauritius Limited Combinaison herbicide, composition et procédé de lutte contre les mauvaises herbes l'utilisant

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