WO2019022466A1 - Method for producing dog skin glue solution coating agent - Google Patents

Method for producing dog skin glue solution coating agent Download PDF

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Publication number
WO2019022466A1
WO2019022466A1 PCT/KR2018/008341 KR2018008341W WO2019022466A1 WO 2019022466 A1 WO2019022466 A1 WO 2019022466A1 KR 2018008341 W KR2018008341 W KR 2018008341W WO 2019022466 A1 WO2019022466 A1 WO 2019022466A1
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Prior art keywords
extract
preparing
pigment
heating
coating
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PCT/KR2018/008341
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French (fr)
Korean (ko)
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채미영
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채미영
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Priority to CN201880054180.8A priority Critical patent/CN111051451A/en
Publication of WO2019022466A1 publication Critical patent/WO2019022466A1/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09HPREPARATION OF GLUE OR GELATINE
    • C09H3/00Isolation of glue or gelatine from raw materials, e.g. by extracting, by heating
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09HPREPARATION OF GLUE OR GELATINE
    • C09H9/00Drying of glue or gelatine

Definitions

  • the present invention relates to a method for preparing a microporous coating which can be used as various types of coating agents depending on the presence or absence of a wet environment.
  • Glue is a substance that solidifies the liquid of orphans, tendons, intestines, bones, etc. of the animal and is mainly used as a hemostatic agent, a medicinal capsule, a protective colloid, a painting agent, or an adhesive, and a plant glue and an animal glue.
  • Pigments are also powdery colorants that do not dissolve in water and most organic solvents. It mixes with a vehicle to make printing inks, paints, etc., to color on the surface of an object, or directly to rubber synthetic resin or the like.
  • the pigment can not be adhered with a particulate powder by itself, it is mixed with vegetable, animal glue and the like.
  • animal glues become aged and weakly weakened, and they are damaged due to inflow of water and the like, and are easily destroyed by small force.
  • Jeongbun Hokbun
  • Jeongbun can be used in the most diverse range because it is an additive for pigments which is white and transparent and has poor performance and function. Therefore, we will focus on the following method of making a teaching material for teaching materials.
  • stone of different kinds and colors of rock can be made to look like a stone by using an ultra-fine artificial coating as an inorganic binder, or it can be used as an improvement agent (monolayer) for monochromatic paints. Accordingly, it is an object of the present invention to provide a gypsum coating composition suitable for the base material of molded artwork using inorganic pigments.
  • the present invention provides a method of manufacturing a hair dryer, Preparing a first extract by adding the dried canopy to water and heating the mixture; Adding the open skin remaining in the first extract to water and preparing a second extract by heating; Preparing a solid glue by mixing the first extract and the second extract and then heating to concentrate and dry the mixture; Heating the solid glue with hot water to prepare a liquid gauze professor; And mixing the pigment and the pigment of the goggukha, which is heated by the hot water, to dissolve the pigment to prepare a gypsophila coating; And a method for manufacturing the same.
  • the present invention provides a gum tragacanth coating composition, which is produced according to the above-mentioned production method.
  • the present invention it is possible to use various kinds of coating agents according to the pigment capable of decomposing the photocatalyst.
  • coating agents according to the pigment capable of decomposing the photocatalyst.
  • [Kaegyoung Professor + Jungmin] has the best performance and function.
  • White gogyeongja professor coating is a photocatalytic nanocomposite, and is a naturally active substance of the jungbu and taekwaji professor, showing various effective performance and functions. After the drying, the finishing coat of the gyeongjiae coating material is covered with white so that it can be used regardless of the type and color of the rock.
  • White gogyeongja professor coatings such as the grave of Koguryo mural grains, if you create a wet environment, the natural calcium carbonate is created and turned into a transparent coating.
  • Transparent color is a coating material that can reveal all the color and background material of stone. Therefore, there is an effect that can be used as a coating material of the stone base from the grave of the mortar mortar of Koguryo.
  • the pigments with poor photocatalytic activity and poor adsorption can be used as an improving agent for monochromatic paints (compounding agent) by blending [Kaohsiung Co., Ltd.
  • the nanocomposite, "Kagakuya Professor + Jungwon" greatly improves the poor properties of the other pigments and strengthens the bond.
  • FIG. 1 is a flow chart schematically showing a method for producing a dog hair cosmetic coating agent having the best performance and function among the dog hair cosmetic coating agents of the present invention.
  • the coating composition of the present invention can be used as a white or transparent multifunctional nanocomposite by drying under dry or wet conditions, and can be preserved in a formative art cultural material using an inorganic material.
  • the present invention relates to a method for producing a hair follicle, Preparing a first extract by adding the dried canopy to water and heating the mixture; Adding the open skin remaining in the first extract to water and preparing a second extract by heating; Preparing a solid glue by mixing the first extract and the second extract and then heating to concentrate and dry the mixture; Heating the solid glue with hot water to prepare a liquid gauze professor; And mixing the pigment and the pigment of the goggukha, which is heated by the hot water, to dissolve the pigment to prepare a gypsophila coating; And a method for manufacturing the same.
  • the drying step may be, but not limited to, drying for 6 months after removing fine hairs and foreign matter.
  • the preparation of the first extract may be carried out by adding 30 to 40 g of the dried skin to 1 L of water, followed by heating for 120 to 150 minutes, but the present invention is not limited thereto.
  • the step of preparing the second extract may include re-heating the open skin remaining in the first extract to water for 120 to 150 minutes, but the present invention is not limited thereto.
  • the preparation of the solid glue may include, but is not limited to, mixing the first extract and the second extract, followed by heating for 90 to 120 minutes to concentrate the mixture.
  • the method for preparing the above-mentioned dog coating material is as follows.
  • the mixing ratio of the pigment and the professor Kang Ji - hyun heated by the bath is different according to the pigment. Among them, the ratio of [weight ratio [1: 3]] of [Kae Kwang Jae professor] and [Jung min] is not revealed in the granite minerals of granite. Therefore, when preservation treatment is carried out, stone artifacts can be blended from [1: 3] to [1: 5] depending on the degree of weathering. [1: 5] is a blending ratio suitable for the case where the weathering degree is high, and [1: 3] is not weathered. As a result of the experiment, it is recommended to follow this standard. Further, the mixing ratio of the above weight ratios [1: 3] to [1: 5] is changed into a whitish transparent coating agent when a wet environment such as a Koguryo mural tomb is formed.
  • the pigment may be, but is not limited to, a regent (jeongbun).
  • the pigment may have an average diameter of 0.5 to 150 mu m, but is not limited thereto.
  • the present invention provides a gum tragacanth coating composition, which is produced according to the above-mentioned production method.
  • Example 1 Preparation of a white opaque coating film
  • Example 2 30 to 40 g of a short-lid drained in 1 L of water was added and heated at a low temperature for 2 hours and 30 minutes to prepare a first extract.
  • Example 3 After the first extraction process, the remaining skin was put into 1 liter of water and heated at a low temperature for 2 hours and 30 minutes to prepare a second extract.
  • Example 4 The first extract and the second extract were mixed and then heated at a low temperature for 2 hours to concentrate the mixture. The concentrate was poured into a mold to solidify into a solid glue.
  • the solid glue prepared in ⁇ Example 1> was heated to prepare a gyohwaja professor in a liquid state dissolved at a temperature of 60 ° C or lower in a hot water bath. It is good enough to warm up the above-mentioned professor. If it exceeds 60 ° C, the adhesive strength of the glue may drop rapidly.
  • a white whitening resin coating composition was prepared under the same conditions as in Example 2 except that the weight ratio of the starch to the weight ratio of [1: 3] was changed.
  • a white whitening resin coating composition was prepared under the same conditions as in Example 2 except that the weight ratio of [1: 4] was adjusted to the ratio of [1: 4].
  • the whitening coating composition of the present invention as white and transparent coatings depending on the presence or absence of the wet environment. That is, the white paints of Examples 2 to 4 were changed into white nano thin film coatings during the drying process, and in Experiment 2, the relative humidity, condensation, and capillary phenomena To a thin film coating of transparent calcium carbonate.
  • microcapsules prepared according to Examples 2 to 4 are multifunctional photocatalyst nanocomposites, and thus are inorganic binders, strengthening agents, and nano thin film coating agents for stone cultural properties excellent in photocatalytic ability and adsorptivity.
  • the nanocomposite gyogyuja professor coating greatly improves the poor properties of the other pigments and strengthens the bonding.
  • the pigment having poor photocatalytic activity and poor adsorption can be used as an improving agent for monochromatic paints, or as an extender, by blending [Kaohsiung Co., Ltd.
  • the nanocomposite, [Kogyoung Ahn Professor + Jeongdong] greatly improves the poor properties of the other pigments and strengthens the bond.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)

Abstract

Provided is a method for producing a dog skin glue solution coating agent comprising the steps of: drying dog skin after fine hair and foreign substances are removed therefrom; preparing a first extract; preparing a second extract; preparing solid glue by mixing and heating the first extract and second extract, and then concentrating and drying the mixture; preparing a liquid dog skin glue solution by heating the solid glue in a double-boiler; and producing a dog skin glue solution coating agent by mixing the dog skin glue solution, which has been heated in a double-boiler, with a pigment, and then dissolving the pigment.

Description

개가죽 아교수 코팅제 제조방법How to make a coating agent
본 발명은 습식환경의 조성 유무에 따라 다양한 형태의 코팅제로 사용할 수 있는 개가죽 아교수 코팅제 제조방법에 관한 것이다.The present invention relates to a method for preparing a microporous coating which can be used as various types of coating agents depending on the presence or absence of a wet environment.
아교는 동물의 가죽, 힘줄, 창자, 뼈 등을 고아 그 액체를 고형화한 물질로서, 지혈제, 약용 캅셀, 보호콜로이드, 회화용, 또는 접착제로 주로 이용되며, 식물성 아교와 동물성 아교 등이 있다.Glue is a substance that solidifies the liquid of orphans, tendons, intestines, bones, etc. of the animal and is mainly used as a hemostatic agent, a medicinal capsule, a protective colloid, a painting agent, or an adhesive, and a plant glue and an animal glue.
또한 안료는 물 및 대부분 유기용제에 녹지 않는 분말상의 착색제이다. 전색제에 섞어서 인쇄잉크, 그림물감 등을 만들어 물체 표면에 착색하거나, 고무 합성수지 등에 직접 섞어 착색한다.Pigments are also powdery colorants that do not dissolve in water and most organic solvents. It mixes with a vehicle to make printing inks, paints, etc., to color on the surface of an object, or directly to rubber synthetic resin or the like.
특히 안료는 미립자상의 분말로 스스로 고착할 수 없기 때문에 식물성, 동물성 아교 등과 혼합하여 사용한다.Particularly, since the pigment can not be adhered with a particulate powder by itself, it is mixed with vegetable, animal glue and the like.
다만, 동물성 아교는 시간이 지날수록 노화되어 단단하게 결합되어 있던 힘이 약해지고, 수분 등의 유입으로 인하여 훼손상태가 발생하며 작은 힘에도 쉽게 파괴되는 성질을 나타낸다.However, as time passes, animal glues become aged and weakly weakened, and they are damaged due to inflow of water and the like, and are easily destroyed by small force.
따라서 상기 문제점을 해결하기 위하여 동물성 아교와 안료의 최적의 혼합을 통해 암석과 벽화 무덤 등의 문화재 보존을 위해 사용될 수 있는 코팅제에 대한 연구 개발이 시급한 실정이다.Therefore, in order to solve the above problems, it is urgent to research and develop coating agents that can be used for preserving cultural properties such as rocks and murals through optimal blending of animal glue and pigment.
본 발명의 목적은 개가죽 아교수 코팅제를 제공하는데 있다. 개가죽 아교수는 안료에 따라 광촉매분해가 가능한 예들이 있다. 그 중 정분(丁粉, jeongbun=호분)은 백색과 투명색이 가능하고 성능과 기능이 부족한 안료의 개선제 증량제이므로 가장 다양하게 활용할 수 있다. 따라서 이하 개가죽 아교수 코팅제 제조방법은 [개가죽 아교수+정분]을 중심으로 살펴보고자 한다.It is an object of the present invention to provide a gum tragacanth coating. There are examples of photocatalytic decomposition according to pigment. Among them, Jeongbun (jeongbun = Hokbun) can be used in the most diverse range because it is an additive for pigments which is white and transparent and has poor performance and function. Therefore, we will focus on the following method of making a teaching material for teaching materials.
[개가죽 아교수+정분]은 습식환경의 조성 유무에 따라 백색 · 투명색 두 종류의 코팅제와 무기질바인더(충전제) · 단청 물감의 개선제(증량제)로 사용할 수 있다. 이들 물감의 주성분은 모두 동일하지만 유물 유적의 바탕재질에 따라 색차값 안료를 응용해서 적용시킬 수 있다. [개가죽 아교수+정분]은 상온에서는 백색의 나노 박막 코팅제이다. 하지만 고구려 벽화무덤과 같은 습식환경을 조성해 주면 백색이 투명색의 탄산칼슘 코팅제로 변한다. 또한 암석의 종류와 색이 다른 석재는 개가죽 아교수 코팅제를 무기질바인더로 사용해서 원석처럼 보이게 제조할 수도 있고, 단청 물감의 개선제(증량제)로도 사용할 수도 있다. 따라서 무기안료가 사용된 조형미술품들의 바탕재질에 맞는 개가죽 아교수 코팅제를 제공하는 데에 있다.It can be used as a coating agent for white and transparent colors, an inorganic binder (filler), and an improvement agent for monochromatic paints (extender) depending on the presence or absence of a wet environment. The main components of these paints are all the same, but the color difference value pigment can be applied by applying to the base material of the relics. [Kogakuya Professor + Jungmin] is a white nanotilm coating agent at room temperature. But if you create a wet environment like a grave of Koguryeo, white becomes a transparent calcium carbonate coating. In addition, stone of different kinds and colors of rock can be made to look like a stone by using an ultra-fine artificial coating as an inorganic binder, or it can be used as an improvement agent (monolayer) for monochromatic paints. Accordingly, it is an object of the present invention to provide a gypsum coating composition suitable for the base material of molded artwork using inorganic pigments.
상기 목적을 달성하기 위하여, 본 발명은 개가죽의 잔털과 이물질을 제거한 후 건조하는 단계; 물에 상기 건조된 개가죽을 투입한 후 가열하여 제1추출물을 준비하는 단계; 상기 제1추출물에 잔존하는 개가죽을 물에 투입한 후 가열하여 제2추출물을 준비하는 단계; 상기 제1추출물과 제2추출물을 혼합한 후 가열하여 혼합물을 농축시키고 건조하여 고체 아교를 준비하는 단계; 상기 고체 아교를 중탕으로 가열하여 액체 상태인 개가죽 아교수를 준비하는 단계; 및 상기 중탕으로 가열된 개가죽 아교수와 안료를 혼합한 후 안료를 용해시켜 개가죽 아교수 코팅제를 제조하는 단계; 를 포함하는, 개가죽 아교수 코팅제 제조방법을 제공한다.In order to accomplish the above object, the present invention provides a method of manufacturing a hair dryer, Preparing a first extract by adding the dried canopy to water and heating the mixture; Adding the open skin remaining in the first extract to water and preparing a second extract by heating; Preparing a solid glue by mixing the first extract and the second extract and then heating to concentrate and dry the mixture; Heating the solid glue with hot water to prepare a liquid gauze professor; And mixing the pigment and the pigment of the goggukha, which is heated by the hot water, to dissolve the pigment to prepare a gypsophila coating; And a method for manufacturing the same.
또한 본 발명은 상기 제조방법에 따라 제조된 것을 특징으로 하는, 개가죽 아교수 코팅제를 제공한다.In addition, the present invention provides a gum tragacanth coating composition, which is produced according to the above-mentioned production method.
본 발명에 따라 제조된 개가죽 아교수 코팅제는 광촉매분해가 가능한 안료에 따라 다양한 형태의 코팅제로 사용할 수 있다. 그 중 [개가죽 아교수+정분]은 가장 성능과 기능이 좋다. [개가죽 아교수+정분]은 무기재료가 사용된 조형미술문화재의 (1)백색 나노 박막 코팅제, (2)투명색의 탄산칼슘 코팅제, (3)무기질 바인더(충전제), 및 (4)단청 물감의 개선제(증량제)로 사용할 수 있다.According to the present invention, it is possible to use various kinds of coating agents according to the pigment capable of decomposing the photocatalyst. Among them, [Kaegyoung Professor + Jungmin] has the best performance and function. (1) white nanotilm coating agent, (2) transparent calcium carbonate coating agent, (3) inorganic binder (filler), and (4) monochromatic paint. It can be used as an improving agent (extender).
(1) 백색 나노 박막 코팅제(1) White nano thin film coating
백색의 개가죽 아교수 코팅제는 광촉매 나노 복합체이고 정분과 개가죽 아교수도 천연의 활성물질이어서 여러 가지 효과적인 성능과 기능들을 보인다. 건조 후의 개가죽 아교수 코팅제의 마감칠은 백색으로 가려지므로 암석의 종류나 색상에 구애받지 않고 사용할 수 있다.White gogyeongja professor coating is a photocatalytic nanocomposite, and is a naturally active substance of the jungbu and taekwaji professor, showing various effective performance and functions. After the drying, the finishing coat of the gyeongjiae coating material is covered with white so that it can be used regardless of the type and color of the rock.
(2) 투명색의 탄산칼슘 코팅제(2) Transparent calcium carbonate coating
백색의 개가죽 아교수 코팅제는 고구려 벽화무덤과 같은 습식환경을 조성해 주면 자연적으로 탄산칼슘이 생성되어 투명한 코팅제로 변한다. 투명색은 석조물의 색상이나 바탕재질까지 모두 그대로 드러나 보이는 코팅제이다. 그런즉 고구려 석회 모르타르 벽화무덤에서부터 석재바탕의 코팅제로 사용할 수 있는 효과가 있다.White gogyeongja professor coatings, such as the grave of Koguryo mural grains, if you create a wet environment, the natural calcium carbonate is created and turned into a transparent coating. Transparent color is a coating material that can reveal all the color and background material of stone. Therefore, there is an effect that can be used as a coating material of the stone base from the grave of the mortar mortar of Koguryo.
(3)무기질바인더(3) Inorganic binders
암석의 종류가 다르거나 색이 다른 석조물도 개가죽 아교수 코팅제를 무기질 바인더로 해서 원석처럼 보이게 할 수 있다. 즉, [개가죽 아교수+정분]에 원석과 동일한 색차값 대로 색맞춤 안료를 배합하면 원석처럼 보인다. 이 경우 나노 복합체인 [개가죽 아교수+정분]은 다른 안료의 부족한 성질을 크게 개선시켜서 결합 강화되므로 무기질 바인더(충전제)로 사용할 수 있는 효과가 있다.It is also possible to make stones with different colors or different kinds of rocks as gypsum as a mineral binder. In other words, if the color pigment is blended with the same color difference value as the gem stone, it looks like a stone. In this case, the nanocomposite [Kao Kyohei Professor + Jungminwon] has the effect of being able to be used as an inorganic binder (filler) because it greatly improves the insufficient properties of other pigments and strengthens the bond.
(4)단청 물감의 개선제(증량제)(4) Improvement agent for monochromatic paints (extender)
광촉매능과 흡착능이 좋지 못한 안료는 [개가죽 아교수+정분]을 배합해서 단청 물감의 개선제(증량제)로도 사용할 수 있다. 이 경우도 나노 복합체인 [개가죽 아교수+정분]은 다른 안료의 부족한 성질을 크게 개선시켜서 결합 강화시킨다. The pigments with poor photocatalytic activity and poor adsorption can be used as an improving agent for monochromatic paints (compounding agent) by blending [Kaohsiung Co., Ltd. In this case too, the nanocomposite, "Kagakuya Professor + Jungwon" greatly improves the poor properties of the other pigments and strengthens the bond.
이상 [개가죽 아교수+정분]은 무기재료가 사용된 조형미술문화재의 백색 나노박막 코팅제 · 투명색 탄산칼슘 코팅제 · 암석의 종류가 다르고 색이 있는 석조물의 무기질바인더(충전제) · 단청 물감의 개선제(증량제) 등으로 사용할 수 있다. 유물 유적에 사용된 예들을 구체적으로 열거해보면 고구려 벽화무덤(석회 몰탈-송산리 벽화무덤 · 석재바탕)을 비롯한 석조문화재(암각화 · 석굴벽화와 석굴조각-석굴암 · 석탑 · 전탑… 석빙고 등) · 소조상 · 궁궐 및 사찰벽화 · 실내장식 공예품 · 단청 안료의 개선제(증량제) · 도자기(또는 도토기)의 보존처리에도 활용할 수 있다. 뿐만 아니라 [개가죽 아교수+정분]은 원자수준의 광촉매 나노 복합체이고 자연 순환이 가능하므로 융복합 기술혁신이 중요한 4차 산업 및 환경 분야에서도 활용할 수 있어서 응용범위가 매우 넓다.[Kookjunga Professor + Jungbun] is a white nano thin film coating agent for plastic arts cultural materials using inorganic materials, a transparent calcium carbonate coating agent, an inorganic binder (filler) for different kinds of rocks and colored stones, an improvement agent for monochromatic paints ) Can be used. The examples used in the relics are as follows: Goguryeo mural tomb (lime mortar - Songsan mural tombstone, stone base), stone cultural assets (petroglyphs, stone mural paintings and cave sculptures - seokguram, stone pagoda, · It can be used for the preservation treatment of the palaces and temple mural · Interior decoration artifacts · Improvement agent of monochromatic pigment (extender) · Ceramics (or Tokigi). In addition, it is an atomic-level photocatalytic nanocomposite that can be natural circulated, so that it can be utilized in the 4th industry and environment field where fusion technology innovation is important.
도 1은 본 발명인 개가죽 아교수 코팅제 중 가장 성능과 기능이 좋은 개가죽 아교수 코팅제의 제조방법을 개략적으로 나타낸 순서도이다.FIG. 1 is a flow chart schematically showing a method for producing a dog hair cosmetic coating agent having the best performance and function among the dog hair cosmetic coating agents of the present invention.
이하, 본 발명인 개가죽 아교수 코팅제 제조방법을 보다 상세하게 설명한다.Hereinafter, a method for preparing a coating composition of the present invention will be described in more detail.
본 발명의 [개가죽 아교수+정분] 코팅제는 건식 또는 습식 조건 하에서 건조시킴으로써 백색 또는 투명색의 다기능성 나노 복합체로 이용할 수 있고, 이를 무기재료가 사용된 조형미술문화재에 보존처리할 수 있다.The coating composition of the present invention can be used as a white or transparent multifunctional nanocomposite by drying under dry or wet conditions, and can be preserved in a formative art cultural material using an inorganic material.
본 발명은 개가죽의 잔털과 이물질을 제거한 후 건조하는 단계; 물에 상기 건조된 개가죽을 투입한 후 가열하여 제1추출물을 준비하는 단계; 상기 제1추출물에 잔존하는 개가죽을 물에 투입한 후 가열하여 제2추출물을 준비하는 단계; 상기 제1추출물과 제2추출물을 혼합한 후 가열하여 혼합물을 농축시키고 건조하여 고체 아교를 준비하는 단계; 상기 고체 아교를 중탕으로 가열하여 액체 상태인 개가죽 아교수를 준비하는 단계; 및 상기 중탕으로 가열된 개가죽 아교수와 안료를 혼합한 후 안료를 용해시켜 개가죽 아교수 코팅제를 제조하는 단계; 를 포함하는, 개가죽 아교수 코팅제 제조방법을 제공한다.The present invention relates to a method for producing a hair follicle, Preparing a first extract by adding the dried canopy to water and heating the mixture; Adding the open skin remaining in the first extract to water and preparing a second extract by heating; Preparing a solid glue by mixing the first extract and the second extract and then heating to concentrate and dry the mixture; Heating the solid glue with hot water to prepare a liquid gauze professor; And mixing the pigment and the pigment of the goggukha, which is heated by the hot water, to dissolve the pigment to prepare a gypsophila coating; And a method for manufacturing the same.
상기 건조하는 단계는 개가죽의 잔털과 이물질을 제거한 후 6개월 동안 건조하는 것일 수 있으며, 이에 제한되는 것은 아니다.The drying step may be, but not limited to, drying for 6 months after removing fine hairs and foreign matter.
상기 제1추출물을 준비하는 단계는 물 1 ℓ에 상기 건조된 개가죽 30 내지 40 g을 투입한 후 120 내지 150분 동안 가열할 수 있으며, 이에 제한되는 것은 아니다.The preparation of the first extract may be carried out by adding 30 to 40 g of the dried skin to 1 L of water, followed by heating for 120 to 150 minutes, but the present invention is not limited thereto.
상기 제2추출물을 준비하는 단계는 제1추출물에 잔존하는 개가죽을 물에 투입한 후 120 내지 150분 동안 재가열할 수 있으며, 이에 제한되는 것은 아니다.The step of preparing the second extract may include re-heating the open skin remaining in the first extract to water for 120 to 150 minutes, but the present invention is not limited thereto.
상기 고체 아교를 준비하는 단계는 제1추출물과 제2추출물을 혼합한 후 90 내지 120분 동안 가열하여 혼합물을 농축시킬 수 있으며, 이에 제한되는 것은 아니다.The preparation of the solid glue may include, but is not limited to, mixing the first extract and the second extract, followed by heating for 90 to 120 minutes to concentrate the mixture.
상기 개가죽 아교수를 중탕할 때에는 따뜻하게 하는 정도가 좋다. 60℃ 이상을 넘으면 아교의 접착력이 급격히 떨어지는 원인이 되므로 상기 온도 범위 내에서 중탕으로 가열하는 것이 바람직하다.It is good enough to warm up the above-mentioned professor. If the temperature exceeds 60 ° C, the adhesion of the glue sharply deteriorates. Therefore, it is preferable to heat the mixture with the hot water within the above temperature range.
상기 개가죽 아교수 코팅제를 제조하는 방법은 다음과 같다. 중탕으로 가열된 개가죽 아교수와 안료의 배합비율은 안료에 따라 차이를 보인다. 그 중 [개가죽 아교수]와 [정분]은 중량비 [1 : 3]의 배합비율은 되어야 화강석의 조암광물 성분이 드러나지 않는다. 그런즉 보존처리를 할 경우 석조문화재는 풍화도의 차이에 따라 [1 : 3] ∼ [1 : 5]까지 배합할 수 있다. [1 : 5]는 풍화도가 높은 경우의 배합비율이라면 [1 : 3]은 거의 풍화되지 않은 경우에 적합한 배합비율이다. 실험 결과 이 기준에 반드시 준하는 것이 좋다. 또한, 상기 중량비 [1 : 3] ∼ [1 : 5]의 배합비율은 고구려 벽화무덤과 같은 습식환경이 조성되면 백색이 투명색의 코팅제로 변한다.The method for preparing the above-mentioned dog coating material is as follows. The mixing ratio of the pigment and the professor Kang Ji - hyun heated by the bath is different according to the pigment. Among them, the ratio of [weight ratio [1: 3]] of [Kae Kwang Jae professor] and [Jung min] is not revealed in the granite minerals of granite. Therefore, when preservation treatment is carried out, stone artifacts can be blended from [1: 3] to [1: 5] depending on the degree of weathering. [1: 5] is a blending ratio suitable for the case where the weathering degree is high, and [1: 3] is not weathered. As a result of the experiment, it is recommended to follow this standard. Further, the mixing ratio of the above weight ratios [1: 3] to [1: 5] is changed into a whitish transparent coating agent when a wet environment such as a Koguryo mural tomb is formed.
상기 안료는 정분(丁粉, jeongbun=호분)일 수 있으며, 이에 제한되는 것은 아니다.)The pigment may be, but is not limited to, a regent (jeongbun).
상기 안료는 평균 직경이 0.5 내지 150 ㎛일 수 있으며, 이에 제한되는 것은 아니다.The pigment may have an average diameter of 0.5 to 150 mu m, but is not limited thereto.
또한 본 발명은 상기 제조방법에 따라 제조된 것을 특징으로 하는, 개가죽 아교수 코팅제를 제공한다.In addition, the present invention provides a gum tragacanth coating composition, which is produced according to the above-mentioned production method.
이하, 하기 실시예에 의해 본 발명인 개가죽 아교수 코팅제 제조방법을 보다 상세하게 설명한다. 다만, 이러한 실시예에 의해 본 발명이 한정되는 것은 아니다.Hereinafter, the method for preparing a coating composition of the present invention will be described in more detail with reference to the following examples. However, the present invention is not limited by these examples.
<실시예 1> 백색의 개가죽 아교수 코팅제 제조Example 1: Preparation of a white opaque coating film
1. 고체 아교 제조1. Manufacture of solid glue
<실시예 1> 개를 도살한 후 사후강직이 나타날 때 개가죽에 남아있는 잔털과 이물질을 제거한 후 6개월 동안 건조시켜 말린다. <Example 1> When the posterior stiffness appears after slaughtering the dog, the remaining fine hair and foreign matter remaining in the dog's hide are removed and dried for 6 months.
<실시예 2> 물 1 ℓ에 건조된 개가죽 약 30 내지 40 g을 투입한 후 2시간 30분 동안 저온으로 가열하여 제1추출물을 준비하였다.Example 2 30 to 40 g of a short-lid drained in 1 L of water was added and heated at a low temperature for 2 hours and 30 minutes to prepare a first extract.
<실시예 3> 제1 추출과정 후 남은 개가죽을 물 1 ℓ에 투입한 후 2시간 30분 동안 저온으로 가열하여 제2추출물을 준비하였다.Example 3 After the first extraction process, the remaining skin was put into 1 liter of water and heated at a low temperature for 2 hours and 30 minutes to prepare a second extract.
<실시예 4> 제1추출물과 제2추출물을 혼합한 후 2시간 동안 저온으로 가열하여 혼합물을 농축시키고, 농축액을 틀에 부어서 고체 아교로 굳히는 단계를 수행하였다. Example 4 The first extract and the second extract were mixed and then heated at a low temperature for 2 hours to concentrate the mixture. The concentrate was poured into a mold to solidify into a solid glue.
2. 개가죽 아교수 코팅제 제조2. Manufacture of coating agent
<실시예 1>에서 제조된 고체 아교를 가열하여 60℃ 이하에서 중탕으로 용해된 액체 상태의 개가죽 아교수를 준비하였다. 상기 개가죽 아교수를 중탕할 때에는 따뜻하게 하는 정도가 좋다. 60℃ 이상을 넘으면 아교의 접착력이 급격히 떨어지는 원인이 된다.The solid glue prepared in <Example 1> was heated to prepare a gyohwaja professor in a liquid state dissolved at a temperature of 60 ° C or lower in a hot water bath. It is good enough to warm up the above-mentioned professor. If it exceeds 60 ° C, the adhesive strength of the glue may drop rapidly.
<실시예 2> 백색의 개가죽 아교수 코팅제 제조<Example 2> Preparation of a white white coat
중탕으로 녹은 따뜻한 개가죽 아교수에 평균 직경이 0.5 내지 150 ㎛ 크기인 정분(丁粉, jeongbun=호분)을 [1 : 3]의 중량비로 혼합한 후 용해시킴으로써 개가죽 아교수 코팅제를 제조하였다. (1: 3) at a weight ratio of 0.5 to 150 ㎛ in average diameter and then dissolving the mixture in a weight ratio of 1: 3.
<실시예 3> 백색의 개가죽 아교수 코팅제 제조<Example 3> Preparation of whitish white gum acne coating agent
개가죽 아교수와 정분을 [1 : 3]의 중량비로 혼합한 것을 제외하고는, 상기 <실시예 2>와 동일한 조건으로 백색의 개가죽 아교수 코팅제를 제조하였다.A white whitening resin coating composition was prepared under the same conditions as in Example 2 except that the weight ratio of the starch to the weight ratio of [1: 3] was changed.
<실시예 4> 백색의 개가죽 아교수 코팅제 제조Example 4: Preparation of whitish white gum acne coating agent
개가죽 아교수와 정분을 [1 : 4]의 중량비로 혼합한 것을 제외하고는, 상기 <실시예 2>와 동일한 조건으로 백색의 개가죽 아교수 코팅제를 제조하였다.A white whitening resin coating composition was prepared under the same conditions as in Example 2 except that the weight ratio of [1: 4] was adjusted to the ratio of [1: 4].
위와 같이 본 발명에 의해 제조된 개가죽 아교수 코팅제는 성분은 같지만 습식환경의 조성 유무에 따라 백색과 투명색 두 종류의 코팅제로 사용할 수 있다. 즉, <실시예 2 ∼ 4>의 백색 물감은 건조과정에 백색 나노박막코팅제로 변하고, <실험예 2>의 경우는 무덤 내에서 발생하는 100%에 가까운 상대습도, 결로현상, 및 모세관현상들에 의해서 투명색의 탄산칼슘의 박막코팅제로 변한다.As described above, it is possible to use the whitening coating composition of the present invention as white and transparent coatings depending on the presence or absence of the wet environment. That is, the white paints of Examples 2 to 4 were changed into white nano thin film coatings during the drying process, and in Experiment 2, the relative humidity, condensation, and capillary phenomena To a thin film coating of transparent calcium carbonate.
<실험예 1> 백색 나노박막코팅제EXPERIMENTAL EXAMPLE 1 A white nano thin film coating
<실시예 2 ∼ 4> 에 의해 제조된 개가죽 아교수 코팅제는 다기능성 광촉매 나노 복합체이기 때문에 광촉매능과 흡착능이 우수한 석조문화재의 무기질바인더 · 강화제 · 나노박막코팅제이다. The microcapsules prepared according to Examples 2 to 4 are multifunctional photocatalyst nanocomposites, and thus are inorganic binders, strengthening agents, and nano thin film coating agents for stone cultural properties excellent in photocatalytic ability and adsorptivity.
<실험예 2> 투명색 탄산칼슘 박막코팅제EXPERIMENTAL EXAMPLE 2 Transparent calcium carbonate thin film coating agent
<실시예 2 ∼ 4> 에 의해 제조된 개가죽 아교수 코팅제는 고구려 벽화무덤과 같은 습식환경이 조성될 경우 탄산칼슘이 생성되어 투명색으로 변한다. When a wet environment such as a tomb of Koguryeo is formed, calcium carbonate is produced and turned into a transparent color.
<실험예 3> 무기질바인더 &Lt; Experimental Example 3 >
개가죽 아교수 코팅제에 원석과 동일한 주성분 안료와 색차값 대로 색맞춤 안료를 배합하면 원석처럼 결합 강화될 수 있다. 이 경우 나노 복합체인 개가죽 아교수 코팅제는 다른 안료의 부족한 성질을 크게 개선시켜서 결합이 강화된다. It can be combined and strengthened like a raw stone by mixing coloring pigments with the same principle component pigments as the gem stone in the goggyeo professor coating agent. In this case, the nanocomposite gyogyuja professor coating greatly improves the poor properties of the other pigments and strengthens the bonding.
<실험예 4> 단청 물감의 개선제(증량제)<Experimental Example 4> An agent for improving monochromatic paints (extender)
광촉매능과 흡착능이 좋지 못한 안료는 [개가죽 아교수+정분]을 배합해서 단청 물감의 개선제, 또는 증량제로 사용할 수 있다. 이 경우도 나노 복합체인 [개가죽 아교수+정분] 은 다른 안료의 부족한 성질을 크게 개선시켜서 결합 강화된다. The pigment having poor photocatalytic activity and poor adsorption can be used as an improving agent for monochromatic paints, or as an extender, by blending [Kaohsiung Co., Ltd. In this case too, the nanocomposite, [Kogyoung Ahn Professor + Jeongdong], greatly improves the poor properties of the other pigments and strengthens the bond.
이상과 같이, 본 발명은 비록 한정된 실시예와 도면에 의해 설명되었으나, 이것에 의해 한정되지 않는다. 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 본 발명의 기술 사상과 아래에 기재될 청구범위의 균등 범위 내에서 다양한 변형이 가능함은 물론이다.As described above, although the present invention has been described with reference to the limited embodiments and drawings, it is not limited thereto. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the appended claims.

Claims (10)

  1. 개가죽의 잔털과 이물질을 제거한 후 건조하는 단계;Removing the fine hairs and foreign matter from the open skin and drying;
    물에 상기 건조된 개가죽을 투입한 후 가열하여 제1 추출과정을 통해 제1추출물을 준비하는 단계;Preparing a first extract through a first extraction process by adding the dried skin to water and heating the same;
    상기 제1 추출과정 후 잔존하는 개가죽을 물에 투입한 후 가열하여 제2 추출과정을 통해 제2추출물을 준비하는 단계;Preparing a second extract through a second extraction process by charging the open skin remaining after the first extraction process into water and heating the same;
    상기 제1추출물과 제2추출물을 혼합한 후 가열하여 혼합물을 농축시키고 건조하여 고체 아교를 준비하는 단계;Preparing a solid glue by mixing the first extract and the second extract and then heating to concentrate and dry the mixture;
    상기 고체 아교를 중탕으로 가열하여 액체 상태인 개가죽 아교수를 준비하는 단계; 및Heating the solid glue with hot water to prepare a liquid gauze professor; And
    상기 중탕으로 가열된 개가죽 아교수와 안료를 혼합한 후 안료를 용해시켜 개가죽 아교수 코팅제를 제조하는 단계;Mixing the pigment and the pigment, and dissolving the pigment in the mixture to prepare a cheek coating resin;
    를 포함하는, 개가죽 아교수 코팅제 제조방법.&Lt; / RTI &gt;
  2. 청구항 1에 있어서,The method according to claim 1,
    상기 건조하는 단계는,The drying may comprise:
    개가죽의 잔털과 이물질을 제거한 후 5 내지 7개월 동안 건조하는 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.The method according to any one of claims 1 to 5, further comprising removing the fine hairs and foreign matter from the skin and drying for 5 to 7 months.
  3. 청구항 1에 있어서,The method according to claim 1,
    상기 제1추출물을 준비하는 단계는,Wherein the step of preparing the first extract comprises:
    물 1 ℓ에 상기 건조된 개가죽 30 내지 40 g을 투입한 후 120 내지 150분 동안 가열하는 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.Wherein 30 to 40 g of the dried skins are added to 1 liter of water, and the mixture is heated for 120 to 150 minutes.
  4. 청구항 1에 있어서,The method according to claim 1,
    상기 제2추출물을 준비하는 단계는,Wherein preparing the second extract comprises:
    제1추출물에 잔존하는 개가죽을 물에 투입한 후 120 내지 150분 동안 재가열하는 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.The method according to claim 1, wherein the open skin remaining in the first extract is put into water and reheated for 120 to 150 minutes.
  5. 청구항 1에 있어서,The method according to claim 1,
    상기 고체 아교를 준비하는 단계는,The step of preparing the solid glue comprises:
    제1추출물과 제2추출물을 혼합한 후 90 내지 120분 동안 가열하여 혼합물을 농축시키는 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.Characterized in that the first extract and the second extract are mixed and then heated for 90 to 120 minutes to concentrate the mixture.
  6. 청구항 1에 있어서,The method according to claim 1,
    상기 개가죽 아교수를 준비하는 단계는,The step of preparing the above-
    고체 아교를 50 내지 60℃에서 중탕으로 가열하는 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.Characterized in that the solid glue is heated with hot water at 50 to 60 占 폚.
  7. 청구항 1에 있어서,The method according to claim 1,
    상기 개가죽 아교수 코팅제를 제조하는 단계는,The step of preparing the microcapsule coating composition comprises:
    중탕으로 가열된 개가죽 아교수와 안료를 1 : (1 ~ 3)의 중량비로 혼합한 후 안료를 용해시키는 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.A method for manufacturing a canopy coating material characterized in that a pigment is dissolved in a mixing ratio of 1: 1 (1 to 3) by weight of a tea gum and the pigment heated by a hot water bath.
  8. 청구항 1에 있어서,The method according to claim 1,
    상기 안료는,The above-
    정분(丁粉, jeongbun=호분)인 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.(Jeongbun = hog). &Lt; / RTI &gt;
  9. 청구항 1에 있어서,The method according to claim 1,
    상기 안료는,The above-
    평균 직경이 0.5 내지 150 ㎛인 것을 특징으로 하는, 개가죽 아교수 코팅제 제조방법.Wherein the average diameter is 0.5 to 150 mu m.
  10. 청구항 1 내지 청구항 10 중 어느 한 항에 따라 제조된 것을 특징으로 하는, 개가죽 아교수 코팅제.10. The coating composition according to any one of claims 1 to 10,
PCT/KR2018/008341 2017-07-26 2018-07-24 Method for producing dog skin glue solution coating agent WO2019022466A1 (en)

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