WO2019012381A1 - Mélanges comprenant un régulateur de croissance des plantes (pgr) et un inhibiteur de nitrification tel que l'acide 2-(3,4-diméthyl-1h-pyrazol-1-yl)succinique (dmpsa) ou le glycolate de 3,4-diméthylpyrazolium (dmpg) - Google Patents

Mélanges comprenant un régulateur de croissance des plantes (pgr) et un inhibiteur de nitrification tel que l'acide 2-(3,4-diméthyl-1h-pyrazol-1-yl)succinique (dmpsa) ou le glycolate de 3,4-diméthylpyrazolium (dmpg) Download PDF

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Publication number
WO2019012381A1
WO2019012381A1 PCT/IB2018/054951 IB2018054951W WO2019012381A1 WO 2019012381 A1 WO2019012381 A1 WO 2019012381A1 IB 2018054951 W IB2018054951 W IB 2018054951W WO 2019012381 A1 WO2019012381 A1 WO 2019012381A1
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WO
WIPO (PCT)
Prior art keywords
compound
plant
dimethyl
methyl
salt
Prior art date
Application number
PCT/IB2018/054951
Other languages
English (en)
Inventor
Barbara Nave
Gregor Pasda
Alexander Wissemeier
Maarten Staal
Karl-Heinrich Schneider
Markus Schmid
Wolfram Zerulla
Sascha Shuxia ZHU
Daniella LOHE
Original Assignee
Basf Se
Basf (China) Company Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Basf (China) Company Limited filed Critical Basf Se
Publication of WO2019012381A1 publication Critical patent/WO2019012381A1/fr

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Definitions

  • At least one active compound I selected from the group consisting of: a) 2-(3,4-dimethyl-1 H-pyrazol-1 -yl)succinic acid (referred to as “DMPSA1 " in the following) and/or 2-(4,5-dimethyl-1 H-pyrazol-1 -yl)succinic acid (referred to as “DMPSA2” in the following), and/or a derivative thereof, and/or a salt thereof, b) glycolic acid addition salt of 3,4-dimethyl pyrazole (3,4-dimethyl pyrazolium glycolate, referred to as "DMPG” in the following), and/or an isomer thereof, and/or a derivative thereof, c) citric acid addition salt of 3,4-dimethyl pyrazole (3,4-dimethyl pyrazolium citrate, referred to as "DMPC” in the following), and/or an isomer thereof, and/or a derivative thereof, d) lactic acid
  • DMPL mandelic acid addition salt of 3,4-dimethyl pyrazole (3,4-dimethyl pyrazolium mandelate, referred to as "DMPM” in the following), and/or an isomer thereof, and/or a derivative thereof, f) 1 ,2,4-triazole (referred to as contextTZ” in the following), and/or a derivative thereof, and/or a salt thereof, g) 4-Chloro-3-methylpyrazole (referred to as contextCIMP” in the following), and/or an isomer thereof, and/or a derivative thereof, and/or a salt thereof, h) N-((3(5)-methyl-1 H-pyrazole-1-yl)methyl)acetamide, and/or an isomer thereof, and/or a derivative thereof, and/or a salt thereof, i) N-((3(5)-methyl-1 H-pyrazole-1-
  • the scope of the present invention includes mixtures of the (R)- and (S)-isomers and the racemates of compounds I and/or II and/or III having one or more chiral centers.
  • atrope isomers of active compounds I and/or II and/or III may be present. They also form part of the subject matter of the invention.
  • the active compounds I and/or II and/or III of the present invention may be present in the form of their N-oxides.
  • N-oxide includes any compound of the present invention which has at least one tertiary nitrogen atom that is oxidized to an N-oxide moiety.
  • the mixtures or compositions according to the invention improve or regulate plant growth.
  • the compound I I (PGR) is chlormequat.
  • the compound I I (PGR) is chlormequat chloride.
  • the compound I (PGR) is mepiquat chloride.
  • the present invention relates to mixtures comprising at least one active compound I, wherein the active compound I is 2-(3,4-dimethyl-1 H-pyrazol-1 -yl)succinic acid (DMPSA1 ) and/or 2-(4,5-dimethyl-1 H-pyrazol-1 -yl)succinic acid (DMPSA2), and/or a derivative thereof, and/or a salt thereof, more preferably DMPSA1 and/or DMPSA2, most preferably DMPSA1.
  • the active compound I is 2-(3,4-dimethyl-1 H-pyrazol-1 -yl)succinic acid (DMPSA1 ) and/or 2-(4,5-dimethyl-1 H-pyrazol-1 -yl)succinic acid (DMPSA2), and/or a derivative thereof, and/or a salt thereof, more preferably DMPSA1 and/or DMPSA2, most preferably DMPSA1.
  • the present invention relates to mixtures comprising at least one active compound I, wherein the active compound I is a reaction adduct of dicyandiamide, urea and formaldehyde, preferably a reaction adduct of dicyandiamide, urea and formaldehyde as described in US 2016/0060184 A1.
  • mixtures wherein compound I is selected from the group consisting of compounds I.A to I.AU:

Abstract

La présente invention concerne des mélanges comprenant, en tant que constituants actifs, au moins un inhibiteur de nitrification spécifique (composé I) et au moins un régulateur de croissance des plantes (composé II); un procédé permettant d'améliorer l'effet d'inhibition de la nitrification, ou d'augmenter la santé d'une plante à l'aide de mélanges d'au moins un composé I et d'au moins un composé II; l'utilisation de mélanges comprenant les composés I et les composés II pour augmenter la santé d'une plante; des compositions agrochimiques comprenant ces mélanges; et un matériel de multiplication des plantes, comprenant ces mélanges ou ces compositions agrochimiques.
PCT/IB2018/054951 2017-07-10 2018-07-05 Mélanges comprenant un régulateur de croissance des plantes (pgr) et un inhibiteur de nitrification tel que l'acide 2-(3,4-diméthyl-1h-pyrazol-1-yl)succinique (dmpsa) ou le glycolate de 3,4-diméthylpyrazolium (dmpg) WO2019012381A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17180508 2017-07-10
EP17180508.8 2017-07-10

Publications (1)

Publication Number Publication Date
WO2019012381A1 true WO2019012381A1 (fr) 2019-01-17

Family

ID=59313114

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2018/054951 WO2019012381A1 (fr) 2017-07-10 2018-07-05 Mélanges comprenant un régulateur de croissance des plantes (pgr) et un inhibiteur de nitrification tel que l'acide 2-(3,4-diméthyl-1h-pyrazol-1-yl)succinique (dmpsa) ou le glycolate de 3,4-diméthylpyrazolium (dmpg)

Country Status (1)

Country Link
WO (1) WO2019012381A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110436997A (zh) * 2019-08-12 2019-11-12 深圳市芭田生态工程股份有限公司 复合肥料及其制备方法和应用
WO2021144193A3 (fr) * 2020-01-16 2021-08-26 Basf Se Mélanges comprenant un support solide comprenant un inhibiteur d'uréase et un autre support solide comprenant un inhibiteur de nitrification
CN113854317A (zh) * 2021-11-04 2021-12-31 中农新科(苏州)有机循环研究院有限公司 一种餐厨沼液浓缩液和芸苔素内酯混合的植物生长调节剂
US11307130B2 (en) 2017-11-06 2022-04-19 Basf Se Indicating soil additives for improving soil water infiltration and/or modulating soil water repellence
US11505511B2 (en) 2017-08-18 2022-11-22 Basf Se Process for preparing improved 3,4-dimethyl-1H-pyrazole phosphate formulations
GB2608360A (en) * 2021-06-22 2023-01-04 Yara Uk Ltd Particles coated with a composition comprising choline chloride
US11659837B2 (en) 2017-07-10 2023-05-30 Basf Se Mixtures comprising an urease inhibitor (UI) and a nitrification inhibitor such as 2-(3,4-dimethyl-1H-pyrazol-1-yl)succinic acid (DMPSA) or 3,4-dimethyl pyrazolium glycolate (DMPG)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757285A (zh) * 2012-06-19 2012-10-31 阜阳富瑞雪化工科技有限公司 一种肥料缓释增效剂及其制备方法
CN106068252A (zh) * 2013-12-13 2016-11-02 欧洲化学农业有限公司 含硝化抑制剂的肥料混合物
CN106083290A (zh) * 2016-05-27 2016-11-09 安徽帝元生物科技有限公司 一种肥效保持剂及其应用

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757285A (zh) * 2012-06-19 2012-10-31 阜阳富瑞雪化工科技有限公司 一种肥料缓释增效剂及其制备方法
CN106068252A (zh) * 2013-12-13 2016-11-02 欧洲化学农业有限公司 含硝化抑制剂的肥料混合物
CN106083290A (zh) * 2016-05-27 2016-11-09 安徽帝元生物科技有限公司 一种肥效保持剂及其应用

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11659837B2 (en) 2017-07-10 2023-05-30 Basf Se Mixtures comprising an urease inhibitor (UI) and a nitrification inhibitor such as 2-(3,4-dimethyl-1H-pyrazol-1-yl)succinic acid (DMPSA) or 3,4-dimethyl pyrazolium glycolate (DMPG)
US11505511B2 (en) 2017-08-18 2022-11-22 Basf Se Process for preparing improved 3,4-dimethyl-1H-pyrazole phosphate formulations
US11307130B2 (en) 2017-11-06 2022-04-19 Basf Se Indicating soil additives for improving soil water infiltration and/or modulating soil water repellence
CN110436997A (zh) * 2019-08-12 2019-11-12 深圳市芭田生态工程股份有限公司 复合肥料及其制备方法和应用
WO2021144193A3 (fr) * 2020-01-16 2021-08-26 Basf Se Mélanges comprenant un support solide comprenant un inhibiteur d'uréase et un autre support solide comprenant un inhibiteur de nitrification
GB2608360A (en) * 2021-06-22 2023-01-04 Yara Uk Ltd Particles coated with a composition comprising choline chloride
CN113854317A (zh) * 2021-11-04 2021-12-31 中农新科(苏州)有机循环研究院有限公司 一种餐厨沼液浓缩液和芸苔素内酯混合的植物生长调节剂

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