WO2019010901A1 - Energy-saving and environmentally friendly combustion additive - Google Patents

Energy-saving and environmentally friendly combustion additive Download PDF

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Publication number
WO2019010901A1
WO2019010901A1 PCT/CN2017/113896 CN2017113896W WO2019010901A1 WO 2019010901 A1 WO2019010901 A1 WO 2019010901A1 CN 2017113896 W CN2017113896 W CN 2017113896W WO 2019010901 A1 WO2019010901 A1 WO 2019010901A1
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Prior art keywords
parts
tailings
extract
saving
energy
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PCT/CN2017/113896
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French (fr)
Chinese (zh)
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孙建英
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孙建英
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/14—Organic compounds
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    • C10L1/226—Organic compounds containing nitrogen containing at least one nitrogen-to-nitrogen bond, e.g. azo compounds, azides, hydrazines
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
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    • C10L1/00—Liquid carbonaceous fuels
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    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1216—Inorganic compounds metal compounds, e.g. hydrides, carbides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
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    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
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    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C—CHEMISTRY; METALLURGY
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    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

Definitions

  • the invention belongs to the technical field of environmental protection engineering, and particularly relates to a combustion additive which not only improves fuel efficiency but also reduces harmful gas emissions.
  • Combustion additives In order to make up for the defects of gasoline in certain properties and give gasoline some new excellent characteristics, functional substances to be added in gasoline.
  • the mainstream of the addition is 1:1000, which has the functions of improving power, removing carbon deposits, cleaning oil passages, saving fuel and preventing rust.
  • Gasoline additives are mainly organic substances. Although current gasoline additives can improve power, remove carbon deposits, clean oil lines, save fuel, and prevent rust, the efficiency of fuel efficiency is relatively low, and the efficiency of reducing harmful gas emissions is relatively low.
  • Patent 201510987469.3 discloses a gasoline additive which is made up of the following parts by weight: 8-10 parts of isobutanol, 3-4 parts of sec-butyl acetate, 1.5-2 parts of secondary alcohol polyoxyethylene ether, propargyl alcohol 2 ⁇ 2.5 parts, 6-8 parts of caprylic acid glyceride, 2 to 2.5 parts of monododecyl phosphate triethanolamine, 1 to 1.5 parts of nano cerium oxide, 6 to 8 parts of diethylene glycol monobutyl ether, and isooctyl 1.5 to 2 parts of the alcohol phosphate and 2.5 to 3 parts of the t-butyl methyl ether.
  • the gasoline additive of the invention has synergistic effect among the components, and the active factor in the additive improves the chemical activity of the fuel, thereby improving the combustion performance of the fuel, greatly improving the dynamic performance of the engine, and greatly increasing the natural fuel consumption. reduce.
  • the above additive components are complicated and the production cost is high.
  • Patent 201511012643.9 methanol gasoline high-efficiency compound additive, made of the following parts by weight: 8-10 parts of diethanol formal, 5-7 parts of tert-butyl methyl ether, 1 ⁇ 1.5 parts of isooctanol phosphate, nano-ferric acid 1.5 to 2 parts of cobalt, 1.5 to 2 parts of n-heptane, 5 to 7 parts of propylene glycol butyl ether, 4 to 5 parts of cocoic acid diethanolamide, 1 to 1.5 parts of isotridecyl stearate, and lauroyl sarcosine 2 to 3 parts of sodium.
  • the patent has high production cost and low combustion efficiency.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 30-50 parts of triethanolamine, 40-80 parts of ethylene glycol tert-butyl ether, 3-8 parts of polyferric sulfate, tert-butanol 10 -20 parts, 10-20 parts of dipenta iron, 10-20 parts of diamyl oxalate, 10-15 parts of dregs extract, 3-8 parts of tailings, and 3-8 parts of sulfonated oil.
  • the preferred energy-saving and environmentally friendly combustion additive is prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and dipentaFe 15 Parts, 15 parts of diamyl oxalate, 12 parts of dregs extract, 5 parts of tailings, and 6 parts of sulfonated oil.
  • the dregs extract is one or a kind of extract of Polygonum cuspidatum slag extract, medicinal herb slag extract, peony slag extract, eucalyptus medicinal slag extract, dried tangerine peel residue, and white peony residue. the above.
  • the method for extracting the dregs extract is: drying the traditional Chinese medicine dregs, grinding into a powder, adding 0.5-1 part by weight of water, naturally fermenting for 3-8 days, and adding 3-5 times the parts by weight. The 70% ethanol aqueous solution was refluxed for 3 times, and the filtrate was combined and evaporated to dryness.
  • the tailings are one or more of molybdenum tailings, copper tailings, iron tailings, phosphorus tailings, aluminum tailings, tin tailings, and lead tailings.
  • the invention has the beneficial effects that the energy-saving and environment-friendly combustion additive of the invention can improve the combustion efficiency of the combustion product, reduce the content of the inhalable particulate matter in the combustion process of the combustion product, save energy and protect the environment, and can save the use amount of combustion products such as gasoline.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, 6 parts of sulfonated oil.
  • the method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 30 parts of triethanolamine, 40 parts of ethylene glycol tert-butyl ether, 3 parts of polyferric sulfate, 10 parts of t-butanol, and 10 parts of dipenta Parts, 10 parts of diamyl oxalate, 10 parts of medicinal herb residue extract, 3 parts of copper tailings, and 3 parts of sulfonated oil.
  • the method for extracting the medicinal herb residue is: drying the medicinal herb residue, grinding into a powder, adding 0.5 times by weight of water, naturally fermenting for 3 days, and adding 3 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 50 parts of triethanolamine, 80 parts of ethylene glycol tert-butyl ether, 8 parts of polyferric sulfate, 20 parts of t-butanol, and dipenta iron 20 Parts, 20 parts of diamyl oxalate, 15 parts of peony residue, 8 parts of iron tailings, 8 parts of sulfonated oil.
  • the method for extracting the cockroach residue is: drying the medicinal slag, grinding into a powder, and doubling The parts by weight of water were naturally fermented for 8 days, and further extracted 5 times by weight with a 70% aqueous solution of 70% ethanol, and the filtrate was combined and evaporated to dryness.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, 6 parts of sulfonated oil, 8 parts of pegmatite.
  • the method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, 6 parts of sulfonated oil, 8 parts of kimberlite.
  • the method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Ingredients: 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, and 6 parts of sulfonated oil.
  • the method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
  • An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 6 parts of sulfonated oil.
  • the method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
  • Examples 1-5 and NO X emissions effective composition of Comparative Example 2 is for reducing the embodiment, there is no significant difference between the control group and Comparative Example 1 92 gasoline, compared to Comparative Example 1 Example 1 , other conditions being equal, only Comparative Example 1 was added a small dipentyl oxalate, dipentyl oxalate demonstrated a reduced effect of NO X combustion of gasoline.
  • Example 4-5 like Example 1 ratio, further reducing the emissions of NO X, compared with Example 1, other conditions being equal, only Examples 4-5 were added to the multi-pegmatite, kimberlite proved pegmatite, kimberlite gasoline combustion with reduced NO X efficacy.
  • Example 1 The compositions of Examples 1-5 and Comparative Example 1 were effective for reducing CO emissions, and Comparative Example 2 was not significantly different from Control Group No. 92 gasoline, and Comparative Example 2 was the same as Example 1, except for the pair.
  • Proportion 2 added less molybdenum tailings, which proves that molybdenum tailings have the effect of reducing CO emissions from gasoline combustion.
  • the examples 4-5 have further reduced the CO emission.
  • the other conditions are the same. Only the examples 4-5 respectively add pegmatite and kimberlite. Prove that pegmatite, kimberlite has the effect of reducing CO emissions from gasoline combustion.
  • Example 2 As can be seen from Table 2, the fuel powers of the compositions of Examples 1-5 and Comparative Example 1 were all improved, and Comparative Example 2 was not significantly different from the control No. 92 gasoline, and Comparative Example 2 was compared with Example 1.
  • the other conditions are the same, only the molybdenum tailings are added to the proportion 2, which proves that the molybdenum tailings have the effect of improving fuel power.
  • the embodiment 4-5 has further improved the fuel power.
  • the other conditions are the same. Only the examples 4-5 respectively add pegmatite, kimberlite, and prove that Wei Crystal rock, kimberlite has the effect of improving fuel power.
  • Comparative Example 1 was the same as Example 1 except for the comparative example. 1 Less diamyl oxalate was added to prove that diamyl oxalate has the effect of reducing fuel consumption rate. Compared with the first embodiment, the embodiment 4-5 further reduces the fuel consumption rate. Compared with the first embodiment, the other conditions are the same. Only the examples 4-5 respectively add pegmatite and kimberlite. Prove that pegmatite, kimberlite has the effect of reducing fuel consumption.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Disclosed is an energy-saving and environmentally friendly combustion additive, which is made of the following components in parts by weight: 30-50 parts of triethanolamine, 40-80 parts of ethylene glycol tert-butyl ether, 3-8 parts of polyferric sulfate, 10-20 parts of tert-butanol, 10-20 parts of ferrocene, 10-20 parts of dipentyl oxalate, 10-15 parts of a herb residue extract, 3-8 parts of a tailing, and 3-8 parts of sulfonated oil. The energy-saving and environmentally friendly combustion additive can improve the combustion efficiency of a comburent and reduce the content of inhalable particulates during the combustion process of the comburent, is energy-saving and environmentally friendly, and can reduce the usage amount of a comburent, such as gasoline.

Description

一种节能环保的燃烧添加剂Energy-saving and environmentally friendly combustion additive 技术领域Technical field
本发明属于环境保护工程技术领域，具体涉及一种既提高燃效又减少有害气体排放的燃烧添加剂。The invention belongs to the technical field of environmental protection engineering, and particularly relates to a combustion additive which not only improves fuel efficiency but also reduces harmful gas emissions.
背景技术Background technique
燃烧添加剂为了弥补汽油在某些性质上的缺陷并赋予汽油一些新的优良特性，在汽油中要加入的功能性物质。其添加量主流是以1：1000，具有提升动力、清除积炭、清洁油路、节省燃油、防锈等功效。汽油添加剂主要为有机物质，目前的汽油添加剂虽然能提升动力、清除积炭、清洁油路、节省燃油、防锈，但是，提升燃料效率的功效比较低，降低有害气体排放的效率比较低。Combustion additives In order to make up for the defects of gasoline in certain properties and give gasoline some new excellent characteristics, functional substances to be added in gasoline. The mainstream of the addition is 1:1000, which has the functions of improving power, removing carbon deposits, cleaning oil passages, saving fuel and preventing rust. Gasoline additives are mainly organic substances. Although current gasoline additives can improve power, remove carbon deposits, clean oil lines, save fuel, and prevent rust, the efficiency of fuel efficiency is relatively low, and the efficiency of reducing harmful gas emissions is relatively low.
专利201510987469.3公开了汽油添加剂，由以下重量份数的组分制成：异丁醇8～10份、醋酸仲丁酯3～4份、仲醇聚氧乙烯醚1.5～2份、丙炔醇2～2.5份、辛癸酸甘油酯6～8份、单十二烷基磷酸酯三乙醇胺2～2.5份、纳米氧化铈1～1.5份、二乙二醇单丁醚6～8份、异辛醇磷酸酯1.5～2份、叔丁基甲基醚2.5～3份。本发明汽油添加剂，各组分之间协同作用突出，添加剂中的活性因子，使燃油的化学活性提高，进而提高燃油的燃烧性能，使发动机的动力性能大幅度提高，自然耗油量也大为降低。但是，上述添加剂成分复杂，制备成本高。专利201511012643.9甲醇汽油高效复合添加剂，由以下重量份数的组分制成：二乙醇缩甲醛8～10份、叔丁基甲基醚5～7份、异辛醇磷酸酯1～1.5份、纳米铁酸钴1.5～2份、正庚烷1.5～2份、丙二醇丁醚5～7份、椰油酸二乙醇酰胺4～5份、硬脂酸异十三酯1～1.5份、月桂酰肌氨酸钠2～3份。该专利制备成本高，提高燃烧效率不高。 Patent 201510987469.3 discloses a gasoline additive which is made up of the following parts by weight: 8-10 parts of isobutanol, 3-4 parts of sec-butyl acetate, 1.5-2 parts of secondary alcohol polyoxyethylene ether, propargyl alcohol 2 ～2.5 parts, 6-8 parts of caprylic acid glyceride, 2 to 2.5 parts of monododecyl phosphate triethanolamine, 1 to 1.5 parts of nano cerium oxide, 6 to 8 parts of diethylene glycol monobutyl ether, and isooctyl 1.5 to 2 parts of the alcohol phosphate and 2.5 to 3 parts of the t-butyl methyl ether. The gasoline additive of the invention has synergistic effect among the components, and the active factor in the additive improves the chemical activity of the fuel, thereby improving the combustion performance of the fuel, greatly improving the dynamic performance of the engine, and greatly increasing the natural fuel consumption. reduce. However, the above additive components are complicated and the production cost is high. Patent 201511012643.9 methanol gasoline high-efficiency compound additive, made of the following parts by weight: 8-10 parts of diethanol formal, 5-7 parts of tert-butyl methyl ether, 1~1.5 parts of isooctanol phosphate, nano-ferric acid 1.5 to 2 parts of cobalt, 1.5 to 2 parts of n-heptane, 5 to 7 parts of propylene glycol butyl ether, 4 to 5 parts of cocoic acid diethanolamide, 1 to 1.5 parts of isotridecyl stearate, and lauroyl sarcosine 2 to 3 parts of sodium. The patent has high production cost and low combustion efficiency.
发明内容Summary of the invention
本发明的目的在于提供一种节能环保的燃烧添加剂。It is an object of the present invention to provide an energy-saving and environmentally friendly combustion additive.
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺30-50份，乙二醇叔丁基醚40-80份，聚合硫酸铁3-8份，叔丁醇10-20份，二戊铁10-20份，草酸二戊酯10-20份，药渣提取物10-15份，尾矿3-8份，磺化油3-8份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 30-50 parts of triethanolamine, 40-80 parts of ethylene glycol tert-butyl ether, 3-8 parts of polyferric sulfate, tert-butanol 10 -20 parts, 10-20 parts of dipenta iron, 10-20 parts of diamyl oxalate, 10-15 parts of dregs extract, 3-8 parts of tailings, and 3-8 parts of sulfonated oil.
优选的节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺40份，乙二醇叔丁基醚60份，聚合硫酸铁6份，叔丁醇15份，二戊铁15份，草酸二戊酯15份，药渣提取物12份，尾矿5份，磺化油6份。The preferred energy-saving and environmentally friendly combustion additive is prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and dipentaFe 15 Parts, 15 parts of diamyl oxalate, 12 parts of dregs extract, 5 parts of tailings, and 6 parts of sulfonated oil.
所述药渣提取物为虎杖药渣提取物，甘草药渣提取物，蝉蜕药渣提取物，大蓟药渣提取物，陈皮药渣提取物，白芨药渣提取物中的一种或一种以上。The dregs extract is one or a kind of extract of Polygonum cuspidatum slag extract, medicinal herb slag extract, peony slag extract, eucalyptus medicinal slag extract, dried tangerine peel residue, and white peony residue. the above.
所述药渣提取物的提取方法为：将中药药渣晒干，磨成粉末，加0.5-1倍重量份数的水，自然发酵3-8天，再加3-5倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The method for extracting the dregs extract is: drying the traditional Chinese medicine dregs, grinding into a powder, adding 0.5-1 part by weight of water, naturally fermenting for 3-8 days, and adding 3-5 times the parts by weight. The 70% ethanol aqueous solution was refluxed for 3 times, and the filtrate was combined and evaporated to dryness.
所述尾矿为钼尾矿，铜尾矿，铁尾矿，磷尾矿，铝尾矿，锡尾矿，铅尾矿中的一种或一种以上。The tailings are one or more of molybdenum tailings, copper tailings, iron tailings, phosphorus tailings, aluminum tailings, tin tailings, and lead tailings.
本发明的有益效果：本发明的节能环保的燃烧添加剂，能够提高燃烧物的燃烧效率，降低燃烧物燃烧过程中可吸入颗粒物的含量，节能环保，能够节约燃烧物如汽油等的使用量。The invention has the beneficial effects that the energy-saving and environment-friendly combustion additive of the invention can improve the combustion efficiency of the combustion product, reduce the content of the inhalable particulate matter in the combustion process of the combustion product, save energy and protect the environment, and can save the use amount of combustion products such as gasoline.
具体实施方式Detailed ways
下面结合具体实施例对本发明做进一步说明。 The invention will be further described below in conjunction with specific embodiments.
实施例1Example 1
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺40份，乙二醇叔丁基醚60份，聚合硫酸铁6份，叔丁醇15份，二戊铁15份，草酸二戊酯15份，虎杖药渣提取物12份，钼尾矿5份，磺化油6份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, 6 parts of sulfonated oil.
所述虎杖药渣提取物的提取方法为：将虎杖药渣晒干，磨成粉末，加1倍重量份数的水，自然发酵6天，再加4倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
实施例2Example 2
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺30份，乙二醇叔丁基醚40份，聚合硫酸铁3份，叔丁醇10份，二戊铁10份，草酸二戊酯10份，甘草药渣提取物10份，铜尾矿3份，磺化油3份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 30 parts of triethanolamine, 40 parts of ethylene glycol tert-butyl ether, 3 parts of polyferric sulfate, 10 parts of t-butanol, and 10 parts of dipenta Parts, 10 parts of diamyl oxalate, 10 parts of medicinal herb residue extract, 3 parts of copper tailings, and 3 parts of sulfonated oil.
所述甘草药渣提取物的提取方法为：将甘草药渣晒干，磨成粉末，加0.5倍重量份数的水，自然发酵3天，再加3倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The method for extracting the medicinal herb residue is: drying the medicinal herb residue, grinding into a powder, adding 0.5 times by weight of water, naturally fermenting for 3 days, and adding 3 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
实施例3Example 3
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺50份，乙二醇叔丁基醚80份，聚合硫酸铁8份，叔丁醇20份，二戊铁20份，草酸二戊酯20份，蝉蜕药渣提取物15份，铁尾矿8份，磺化油8份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 50 parts of triethanolamine, 80 parts of ethylene glycol tert-butyl ether, 8 parts of polyferric sulfate, 20 parts of t-butanol, and dipenta iron 20 Parts, 20 parts of diamyl oxalate, 15 parts of peony residue, 8 parts of iron tailings, 8 parts of sulfonated oil.
所述蝉蜕药渣提取物的提取方法为：将蝉蜕药渣晒干，磨成粉末，加1倍 重量份数的水，自然发酵8天，再加5倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The method for extracting the cockroach residue is: drying the medicinal slag, grinding into a powder, and doubling The parts by weight of water were naturally fermented for 8 days, and further extracted 5 times by weight with a 70% aqueous solution of 70% ethanol, and the filtrate was combined and evaporated to dryness.
实施例4Example 4
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺40份，乙二醇叔丁基醚60份，聚合硫酸铁6份，叔丁醇15份，二戊铁15份，草酸二戊酯15份，虎杖药渣提取物12份，钼尾矿5份，磺化油6份，伟晶岩8份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, 6 parts of sulfonated oil, 8 parts of pegmatite.
所述虎杖药渣提取物的提取方法为：将虎杖药渣晒干，磨成粉末，加1倍重量份数的水，自然发酵6天，再加4倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
实施例5Example 5
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺40份，乙二醇叔丁基醚60份，聚合硫酸铁6份，叔丁醇15份，二戊铁15份，草酸二戊酯15份，虎杖药渣提取物12份，钼尾矿5份，磺化油6份，金伯利岩8份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, 6 parts of sulfonated oil, 8 parts of kimberlite.
所述虎杖药渣提取物的提取方法为：将虎杖药渣晒干，磨成粉末，加1倍重量份数的水，自然发酵6天，再加4倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。 The method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
对比例1Comparative example 1
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺40份，乙二醇叔丁基醚60份，聚合硫酸铁6份，叔丁醇15份，二戊铁15份，虎杖药渣提取物12份，钼尾矿5份，磺化油6份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Ingredients: 12 parts of Polygonum cuspidatum extract, 5 parts of molybdenum tailings, and 6 parts of sulfonated oil.
所述虎杖药渣提取物的提取方法为：将虎杖药渣晒干，磨成粉末，加1倍重量份数的水，自然发酵6天，再加4倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
对比例2Comparative example 2
一种节能环保的燃烧添加剂，由如下重量份数的组分制成：三乙醇胺40份，乙二醇叔丁基醚60份，聚合硫酸铁6份，叔丁醇15份，二戊铁15份，草酸二戊酯15份，虎杖药渣提取物12份，磺化油6份。An energy-saving and environmentally friendly combustion additive prepared from the following parts by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, 15 parts of t-butanol, and 15 parts of dipenta Parts, 15 parts of diamyl oxalate, 12 parts of Polygonum cuspidatum extract, 6 parts of sulfonated oil.
所述虎杖药渣提取物的提取方法为：将虎杖药渣晒干，磨成粉末，加1倍重量份数的水，自然发酵6天，再加4倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The method for extracting the Polygonum cuspidatum medicinal residue is: drying the Polygonum cuspidatum medicinal residue, grinding into a powder, adding 1 part by weight of water, naturally fermenting for 6 days, and adding 4 times by weight of 70% ethanol aqueous solution to reflux. The mixture was extracted 3 times, and the filtrate was combined and evaporated to dryness.
发动机性能试验，试验装置:DDM16发动机测试系统、GWIOO电涡流水力测功机、FGA4500排气分析仪等。分别采用92号汽油和添加本发明实施例1-5，对比例1-2，添加量为650mg/L的92号汽油汽油，在转速2800r/min对发动机的排放和油耗、功率进行对比试验。实验结果见表1和表2。 Engine performance test, test equipment: DDM16 engine test system, GWIOO eddy current hydraulic dynamometer, FGA4500 exhaust analyzer. The No. 92 gasoline and the addition of the inventive examples 1-5, Comparative Example 1-2, the addition of 650 mg / L of 92 gasoline gasoline, the engine emissions and fuel consumption, power comparison test at 2800r / min. The experimental results are shown in Tables 1 and 2.
表1 转速2800r/min时排放对比数据Table 1 Comparison of emission data at 2800r/min
组别Group NOX(mg/m3)NO X (mg/m 3 ) HC(mg/m3)HC (mg/m 3 ) CO(％)CO(%)
92号汽油92 petrol 38.938.9 6.86.8 0.250.25
实施例1Example 1 30.830.8 5.95.9 0.210.21
实施例2Example 2 30.730.7 5.85.8 0.220.22
实施例3Example 3 30.930.9 5.85.8 0.210.21
实施例4Example 4 22.222.2 5.85.8 0.130.13
实施例5Example 5 22.322.3 5.95.9 0.120.12
对比例1Comparative example 1 38.938.9 5.95.9 0.210.21
对比例2Comparative example 2 30.830.8 6.06.0 0.260.26
由表1可以看出，实施例1-5及对比例2的组合物对于降低NOX的排放量有效，对比例1与对照组92号汽油没有显著差异，对比例1与实施例1相比，其他条件相同，仅仅是对比例1少加入了草酸二戊酯，证明草酸二戊酯具有降低汽油燃烧NOX的功效。实施例4-5与实施例1想比，有进一步降低了NOX的排放量，与实施例1相比，其他条件相同，仅仅是实施例4-5分别多加入了伟晶岩，金伯利岩，证明伟晶岩，金伯利岩具有降低汽油燃烧NOX的功效。实施例1-5及对比例1的组合物对于降低CO的排放量有效，对比例2与对照组92号汽油没有显著差异，对比例2与实施例1相比，其他条件相同，仅仅是对比例2少加入了钼尾矿，证明钼尾矿具有降低汽油燃烧排放CO的功效。实施例4-5与实施例1想比，有进一步降低了CO的排放量，与实施例1相比，其他条件相同，仅仅是实施例4-5分别多加入了伟晶岩，金伯利岩，证明伟晶岩，金伯利岩具有降低汽油燃烧排放CO的功效。 As can be seen from Table 1, Examples 1-5 and NO X emissions effective composition of Comparative Example 2 is for reducing the embodiment, there is no significant difference between the control group and Comparative Example 1 92 gasoline, compared to Comparative Example 1 Example 1 , other conditions being equal, only Comparative Example 1 was added a small dipentyl oxalate, dipentyl oxalate demonstrated a reduced effect of NO X combustion of gasoline. Example 4-5 like Example 1 ratio, further reducing the emissions of NO X, compared with Example 1, other conditions being equal, only Examples 4-5 were added to the multi-pegmatite, kimberlite proved pegmatite, kimberlite gasoline combustion with reduced NO X efficacy. The compositions of Examples 1-5 and Comparative Example 1 were effective for reducing CO emissions, and Comparative Example 2 was not significantly different from Control Group No. 92 gasoline, and Comparative Example 2 was the same as Example 1, except for the pair. Proportion 2 added less molybdenum tailings, which proves that molybdenum tailings have the effect of reducing CO emissions from gasoline combustion. Compared with the first embodiment, the examples 4-5 have further reduced the CO emission. Compared with the first embodiment, the other conditions are the same. Only the examples 4-5 respectively add pegmatite and kimberlite. Prove that pegmatite, kimberlite has the effect of reducing CO emissions from gasoline combustion.
表2 转速2800r/min时油耗功率对比数据Table 2 Comparison of fuel consumption power at 2800r/min
组别Group 功率(kW)Power (kW) 燃油消耗率(g/kW.h)Fuel consumption rate (g/kW.h)
92号汽油92 petrol 41.1341.13 234.2234.2
实施例1Example 1 43.2243.22 230.2230.2
实施例2Example 2 43.2143.21 230.1230.1
实施例3Example 3 43.2243.22 230.3230.3
实施例4Example 4 43.2043.20 227.2227.2
实施例5Example 5 43.2243.22 227.1227.1
对比例1Comparative example 1 43.2243.22 234.2234.2
对比例2Comparative example 2 41.1241.12 230.2230.2
由表2可以看出，实施例1-5及对比例1的组合物的燃油功率都有所提高，对比例2与对照组92号汽油没有显著差异，对比例2与实施例1相比，其他条件相同，仅仅是对比例2少加入了钼尾矿，证明钼尾矿具有提高燃油功率的功效。实施例4-5与实施例1想比，有进一步提高了燃油功率，与实施例1相比，其他条件相同，仅仅是实施例4-5分别多加入了伟晶岩，金伯利岩，证明伟晶岩，金伯利岩具有提高燃油功率的功效。实施例1-5及对比例2的组合物对于降低燃油消耗率有效，对比例1与对照组92号汽油没有显著差异，对比例1与实施例1相比，其他条件相同，仅仅是对比例1少加入了草酸二戊酯，证明草酸二戊酯具有降低燃油消耗率的功效。实施例4-5与实施例1想比，有进一步降低了降低燃油消耗率，与实施例1相比，其他条件相同，仅仅是实施例4-5分别多加入了伟晶岩，金伯利岩，证明伟晶岩，金伯利岩具有降低燃油消耗率的功效。 As can be seen from Table 2, the fuel powers of the compositions of Examples 1-5 and Comparative Example 1 were all improved, and Comparative Example 2 was not significantly different from the control No. 92 gasoline, and Comparative Example 2 was compared with Example 1. The other conditions are the same, only the molybdenum tailings are added to the proportion 2, which proves that the molybdenum tailings have the effect of improving fuel power. Compared with the first embodiment, the embodiment 4-5 has further improved the fuel power. Compared with the first embodiment, the other conditions are the same. Only the examples 4-5 respectively add pegmatite, kimberlite, and prove that Wei Crystal rock, kimberlite has the effect of improving fuel power. The compositions of Examples 1-5 and Comparative Example 2 were effective for reducing the fuel consumption rate, and Comparative Example 1 was not significantly different from the control No. 92 gasoline. Comparative Example 1 was the same as Example 1 except for the comparative example. 1 Less diamyl oxalate was added to prove that diamyl oxalate has the effect of reducing fuel consumption rate. Compared with the first embodiment, the embodiment 4-5 further reduces the fuel consumption rate. Compared with the first embodiment, the other conditions are the same. Only the examples 4-5 respectively add pegmatite and kimberlite. Prove that pegmatite, kimberlite has the effect of reducing fuel consumption.

Claims (5)

  1. 一种节能环保的燃烧添加剂，其特征在于，由如下重量份数的组分制成：三乙醇胺30-50份，乙二醇叔丁基醚40-80份，聚合硫酸铁3-8份，叔丁醇10-20份，二戊铁10-20份，草酸二戊酯10-20份，药渣提取物10-15份，尾矿3-8份，磺化油3-8份。An energy-saving and environment-friendly combustion additive, which is prepared by the following components by weight: 30-50 parts of triethanolamine, 40-80 parts of ethylene glycol tert-butyl ether, and 3-8 parts of polyferric sulfate. 10-20 parts of t-butanol, 10-20 parts of diferric iron, 10-20 parts of diamyl oxalate, 10-15 parts of dregs extract, 3-8 parts of tailings, and 3-8 parts of sulfonated oil.
  2. 根据权利要求1所述节能环保的燃烧添加剂，其特征在于，由如下重量份数的组分制成：三乙醇胺40份，乙二醇叔丁基醚60份，聚合硫酸铁6份，叔丁醇15份，二戊铁15份，草酸二戊酯15份，药渣提取物12份，尾矿5份，磺化油6份。The energy-saving and environmentally-friendly combustion additive according to claim 1, which is prepared from the following components by weight: 40 parts of triethanolamine, 60 parts of ethylene glycol tert-butyl ether, 6 parts of polyferric sulfate, and tert-butyl 15 parts of alcohol, 15 parts of dipenta iron, 15 parts of diamyl oxalate, 12 parts of dregs extract, 5 parts of tailings, and 6 parts of sulfonated oil.
  3. 根据权利要求1所述节能环保的燃烧添加剂，其特征在于，所述药渣提取物为虎杖药渣提取物，甘草药渣提取物，蝉蜕药渣提取物，大蓟药渣提取物，陈皮药渣提取物，白芨药渣提取物中的一种或一种以上。The energy-saving and environmentally-friendly combustion additive according to claim 1, wherein the dregs extract is a scorpion dregs extract, a medicinal herb slag extract, a peony extract, a scorpion slag extract, and a tangerine peel drug. One or more of the slag extract, the extract of the white peony residue.
  4. 根据权利要求1所述节能环保的燃烧添加剂，其特征在于，所述药渣提取物的提取方法为：将中药药渣晒干，磨成粉末，加0.5-1倍重量份数的水，自然发酵3-8天，再加3-5倍重量份数的70％乙醇水溶液回流提取3次，合并滤液，蒸干制成。The energy-saving and environment-friendly combustion additive according to claim 1, wherein the method for extracting the dregs extract is: drying the traditional Chinese medicine dregs, grinding into a powder, adding 0.5-1 part by weight of water, naturally The mixture was fermented for 3-8 days, and further added with 3-5 times by weight of a 70% aqueous solution of ethanol for 3 times, and the filtrate was combined and evaporated to dryness.
  5. 根据权利要求1所述节能环保的燃烧添加剂，其特征在于，所述尾矿为钼尾矿，铜尾矿，铁尾矿，磷尾矿，铝尾矿，锡尾矿，铅尾矿中的一种或一种以上。 The energy-saving and environmentally-friendly combustion additive according to claim 1, wherein the tailings are molybdenum tailings, copper tailings, iron tailings, phosphorus tailings, aluminum tailings, tin tailings, lead tailings One or more.
PCT/CN2017/113896 2017-07-10 2017-11-30 Energy-saving and environmentally friendly combustion additive WO2019010901A1 (en)

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EP1954788B1 (en) * 2005-11-18 2013-09-18 Ferox, Inc. Biphenyl carrier for ferrocene catalysts and methods of using the same
CN101190255A (en) * 2006-11-22 2008-06-04 中国科学院过程工程研究所 Kudzu root total flavone extracting after steam-explosion process
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