WO2018162208A3 - Particles for fluidised bed reaction methods and fluidised bed reaction methods - Google Patents

Particles for fluidised bed reaction methods and fluidised bed reaction methods Download PDF

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Publication number
WO2018162208A3
WO2018162208A3 PCT/EP2018/053872 EP2018053872W WO2018162208A3 WO 2018162208 A3 WO2018162208 A3 WO 2018162208A3 EP 2018053872 W EP2018053872 W EP 2018053872W WO 2018162208 A3 WO2018162208 A3 WO 2018162208A3
Authority
WO
WIPO (PCT)
Prior art keywords
fluidised bed
bed reaction
reaction methods
particles
methods
Prior art date
Application number
PCT/EP2018/053872
Other languages
French (fr)
Other versions
WO2018162208A2 (en
Inventor
Bartlomiej PRUSISZ
Original Assignee
Sibelco Nederland N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sibelco Nederland N.V. filed Critical Sibelco Nederland N.V.
Priority to EP18708923.0A priority Critical patent/EP3592459A2/en
Publication of WO2018162208A2 publication Critical patent/WO2018162208A2/en
Publication of WO2018162208A3 publication Critical patent/WO2018162208A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6522—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836—Heating and cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C1/00—Combustion apparatus specially adapted for combustion of two or more kinds of fuel simultaneously or alternately, at least one kind of fuel being either a fluid fuel or a solid fuel suspended in a carrier gas or air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/01—Fluidised bed combustion apparatus in a fluidised bed of catalytic particles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B15/00—Fluidised-bed furnaces; Other furnaces using or treating finely-divided materials in dispersion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1853—Steam reforming, i.e. injection of steam only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The present invention relates to particles for fluidised bed reaction methods and fluidised bed reaction methods. The particles comprise a bed material and a catalyst. The fluidised bed reaction method may be the oxidation of a fuel.
PCT/EP2018/053872 2017-03-06 2018-02-16 Bed materials for fluidised bed reaction methods and fluidised bed reaction methods WO2018162208A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP18708923.0A EP3592459A2 (en) 2017-03-06 2018-02-16 Particles for fluidised bed reaction methods and fluidised bed reaction methods

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1703550.2 2017-03-06
GB1703550.2A GB2560317A (en) 2017-03-06 2017-03-06 Bed materials for fluidised bed reaction methods and fluidised bed reaction methods

Publications (2)

Publication Number Publication Date
WO2018162208A2 WO2018162208A2 (en) 2018-09-13
WO2018162208A3 true WO2018162208A3 (en) 2019-08-22

Family

ID=58543952

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2018/053872 WO2018162208A2 (en) 2017-03-06 2018-02-16 Bed materials for fluidised bed reaction methods and fluidised bed reaction methods

Country Status (3)

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EP (1) EP3592459A2 (en)
GB (1) GB2560317A (en)
WO (1) WO2018162208A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108913260B (en) * 2018-07-06 2022-06-14 合肥市晶谷农业科技开发有限公司 Biomass fuel particle
CN109764331B (en) * 2019-01-10 2021-01-01 嘉兴圣斯顿金属制品有限公司 Biomass energy powder burner capable of efficiently burning
EP4139418A1 (en) * 2020-04-20 2023-03-01 Teknologian Tutkimuskeskus VTT OY Method and apparatus for producing hydrocarbons and use
CN112354516B (en) * 2020-10-26 2021-10-29 哈尔滨工业大学 Method for preparing magnetic sludge-based biochar material from sludge and application of magnetic sludge-based biochar material
MX2024001262A (en) * 2021-07-26 2024-02-14 The Trustees For The Time Being Of The Kmn Fulfilment Trust Fuel composition for combustion.
CN115337874A (en) * 2022-09-15 2022-11-15 南京理工大学 Membrane-breaking reaction method for metal fuel particle fluidized bed

Citations (11)

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FR1377957A (en) * 1963-12-27 1964-11-06 Improvements in the catalytic treatment of hydrocarbons and new catalysts which can be used in particular for this treatment
US3915844A (en) * 1972-11-30 1975-10-28 Mitsui Shipbuilding Eng Method for treatment of heavy oils
US4085707A (en) * 1975-02-14 1978-04-25 Exxon Research & Engineering Co. Combustion or part-combustion in fluidized beds
US4221657A (en) * 1976-02-10 1980-09-09 Omnium D'assainissement Biological fermentation substrates
FR2459211A1 (en) * 1979-06-19 1981-01-09 Argiles Mineraux Fired clays doped with metals - used as catalyst supports and in biological water treatment
WO2001089687A1 (en) * 2000-05-22 2001-11-29 Universite Louis Pasteur Catalyst for fluidised bed carbonation of biomass, method for obtaining same and uses thereof
US20050255995A1 (en) * 2004-05-14 2005-11-17 Gas Technology Institute Method for producing catalytically-active materials
US20060039849A1 (en) * 2000-06-02 2006-02-23 Resasco Daniel E Process and apparatus for producing single-walled carbon nanotubes
WO2009050292A2 (en) * 2007-10-19 2009-04-23 Shell Internationale Research Maatschappij B.V. Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation
WO2013098195A1 (en) * 2011-12-28 2013-07-04 Bioecon International Holding N.V. Optimized catalyst for biomass pyrolysis
WO2017150830A1 (en) * 2016-03-04 2017-09-08 (주) 엘지화학 Ferrite-based catalyst composite, method for preparing same, and method for preparing butadiene

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US4229234A (en) * 1978-12-29 1980-10-21 Exxon Research & Engineering Co. Passivated, particulate high Curie temperature magnetic alloys
DE3175965D1 (en) * 1980-12-24 1987-04-16 Standard Oil Co Ohio Catalytic process for converting carbon monoxide to a high energy gas
US4740642A (en) * 1986-08-21 1988-04-26 The Bf Goodrich Company Catalyst and process for the fluid-bed oxychlorination of ethylene to EDC
CN102186955B (en) * 2008-09-26 2015-09-02 俄亥俄州立大学 Carbonaceous fuel is converted into carbon-free energy carrier
KR101297599B1 (en) * 2011-04-26 2013-08-19 한국화학연구원 Fischer-tropsch synthesis catalyst having improved heat transfer capability
CN104822451B (en) * 2012-12-04 2017-05-31 研究三角协会 Carbon monoxide-olefin polymeric and its purposes in catalysis biomass pyrolysis

Patent Citations (12)

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Publication number Priority date Publication date Assignee Title
FR1377957A (en) * 1963-12-27 1964-11-06 Improvements in the catalytic treatment of hydrocarbons and new catalysts which can be used in particular for this treatment
US3915844A (en) * 1972-11-30 1975-10-28 Mitsui Shipbuilding Eng Method for treatment of heavy oils
US4085707A (en) * 1975-02-14 1978-04-25 Exxon Research & Engineering Co. Combustion or part-combustion in fluidized beds
US4221657A (en) * 1976-02-10 1980-09-09 Omnium D'assainissement Biological fermentation substrates
FR2459211A1 (en) * 1979-06-19 1981-01-09 Argiles Mineraux Fired clays doped with metals - used as catalyst supports and in biological water treatment
WO2001089687A1 (en) * 2000-05-22 2001-11-29 Universite Louis Pasteur Catalyst for fluidised bed carbonation of biomass, method for obtaining same and uses thereof
US20060039849A1 (en) * 2000-06-02 2006-02-23 Resasco Daniel E Process and apparatus for producing single-walled carbon nanotubes
US20050255995A1 (en) * 2004-05-14 2005-11-17 Gas Technology Institute Method for producing catalytically-active materials
WO2009050292A2 (en) * 2007-10-19 2009-04-23 Shell Internationale Research Maatschappij B.V. Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation
WO2013098195A1 (en) * 2011-12-28 2013-07-04 Bioecon International Holding N.V. Optimized catalyst for biomass pyrolysis
WO2017150830A1 (en) * 2016-03-04 2017-09-08 (주) 엘지화학 Ferrite-based catalyst composite, method for preparing same, and method for preparing butadiene
EP3308854A1 (en) * 2016-03-04 2018-04-18 LG Chem, Ltd. Ferrite-based catalyst composite, method for preparing same, and method for preparing butadiene

Also Published As

Publication number Publication date
GB201703550D0 (en) 2017-04-19
EP3592459A2 (en) 2020-01-15
WO2018162208A2 (en) 2018-09-13
GB2560317A (en) 2018-09-12

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