WO2018124976A1 - Polyester laminate tube for container - Google Patents

Polyester laminate tube for container Download PDF

Info

Publication number
WO2018124976A1
WO2018124976A1 PCT/TH2017/000024 TH2017000024W WO2018124976A1 WO 2018124976 A1 WO2018124976 A1 WO 2018124976A1 TH 2017000024 W TH2017000024 W TH 2017000024W WO 2018124976 A1 WO2018124976 A1 WO 2018124976A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
film
polyethylene
laminate according
microns
Prior art date
Application number
PCT/TH2017/000024
Other languages
French (fr)
Inventor
Sumet LIMATIBUL
Original Assignee
Kimpai Lamitube Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from TH1601007772A external-priority patent/TH166248A/en
Application filed by Kimpai Lamitube Co., Ltd. filed Critical Kimpai Lamitube Co., Ltd.
Priority to EP17887948.2A priority Critical patent/EP3562670A4/en
Priority to CN201780028243.8A priority patent/CN109070562B/en
Priority to US16/315,815 priority patent/US11702262B2/en
Publication of WO2018124976A1 publication Critical patent/WO2018124976A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a general shape other than plane
    • B32B1/08—Tubular products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/05—5 or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/31—Heat sealable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/414—Translucent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/538—Roughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546—Flexural strength; Flexion stiffness
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
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    • B32—LAYERED PRODUCTS
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584—Scratch resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7244—Oxygen barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7246—Water vapor barrier
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    • B32B2439/00—Containers; Receptacles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/40—Closed containers
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    • B32B2553/00—Packaging equipment or accessories not otherwise provided for

Definitions

  • a polyester film particularly a biaxially-oriented film composed of polyethylene terephthalate, has been widely used as a packaging material or as a base for a reprographic film, etc.
  • a PET film is the use for laminating with other polymers, paper or foil.
  • the PET film is often coated with polyethylene or an ethylene copolymer by extrusion coating in order to obtain heat-sealing capability, adhesion to another material such as aluminium foil, additional bulk (thickness) or stiffness, or in order to achieve properties that are not possible to obtain with the PET film alone.
  • the surface of the PET film is not very receptive to the extrusion coating with other polymers.
  • Solvent-based polyurethane adhesives and polyethyleneimine primers are commonly used in order to solve this problem.
  • the PET film subjected to treating or priming for the extrusion coating without additional priming or corona treatment is preferable for a converter in order to laminate with other polymers.
  • a sheet material mainly uses for manufacturing a laminated tube container comprised of a plastic film in a tube body in order to prevent the contents from deterioration due to oxidation caused by oxygen coming from the outside of the laminated tube container.
  • a material with excellent oxygen barrier property, water-vapor barrier property, etc. is exemplified as a barrier film laminated together with a polyethylene layer or another sealant layer.
  • Aluminium foil is the most widely used material because of its very high gas barrier properties. However, the aluminium foil is inevitably opaque, so that it is not possible to see through the aluminium barrier laminate tube right to the contents inside. Hence, there is an increasing demand for the laminated tube container with high transparency.
  • PET laminates have been found to be useful in manufacturing of various designs of the packaging, and the following patents describe the types of laminate compositions that have been successfully used in the packaging of consumer goods.
  • US Patent No. 5,612,106 discloses a laminated tube container having the body comprising a substrate, a silicon oxide deposited layer, a heat buffer layer, and an extruded coating layer of a thermoadhesive resin.
  • the heat buffer layer such as PET, etc., prevents cracks from being generated in the silicon oxide deposited layer by the heat coming when the extruded coating layer of the thermoadhesive resin is laminated.
  • the heat buffer layer is preferably formed by dry lamination or non-solvent lamination which requires no heating.
  • An anchor coat layer may optionally be provided between the heat buffer layer and the extruded coating layer of the thermoadhesive resin so that the adhesion strength between these layers can be improved.
  • US Patent No. 5,942,320 discloses a barrier composite film comprising a base film, an anchor coat layer containing a silane coupling agent and a barrier resin such as a vinylidene chloride-series copolymer, an ethylene-vinyl alcohol copolymer, or etc., wherein the layers are formed on at least one side of the base film in the order of reference.
  • the anchor coat layer can be made of a chlorine-containing resin, a polyisocyanate compound, and a saturated polyester resin having a glass transition temperature of -10°C to 20°C.
  • a heat-sealing layer may be formed on the surface of the coating layer or the other side of the base film. This composite film provided with the inorganic layer can avoid losses of its adhesive properties and barrier properties even under severe conditions such as retort treatment.
  • PCT Patent application No. PCT/D O 1/00289 discloses a plastic laminate consisting of at least one plastic web and at least two plastic films disposed on each side of the plastic web and preferably connected to a web bond, wherein the laminate is pliable, and wherein respective melting points of the plastic films are approximately the same.
  • US Patent No. 10/493,088 discloses a composite film structure comprising a six-layered film.
  • An outer layer is a non-melting layer such as oriented polyester.
  • a second layer is linear low density polyethylene (LLDPE).
  • a fourth layer is an EVOH layer sandwiched with an adhesive (third) layer.
  • a fifth layer is a sealant layer. This composite film is useful for manu&cturing pouches using rotary thermic sealing.
  • US Patent No. 6,896,754 B2 discloses a wrapping clean film comprising at least two layers of thermoplastic resin films.
  • the wrapping clean film is formed by dry-laminating co-extruded films composed of at least two layers of thermoplastic films on both front and rear surfaces of a heat-resisting substrate.
  • the present invention relates to a polyester film laminated with other polymers to form a sheet.
  • a laminated tube for liquid and paste products such as toothpastes, lotions, and the like can be manufactured from said sheet.
  • the present invention also relates to a laminated tube container having a body made of a sheet material comprising an outer polyethylene film, a polyester film, and an inner polyethylene film, which is formed into a laminated tube.
  • This laminate tube can be used for storing paste products such as lotions, creams, toothpastes, and the like.
  • This invention aims to provide a laminated tube container having gas barrier properties as well as a scratch resistance.
  • the laminated tube for a packaging is commonly decorated by surface printing such as letterpress printing, flexographic printing, UV offset printing, etc. Direct or reverse printing on PET is also possible for the laminated rube.
  • the printed PET film is further laminated with other plastic film in order to form a laminated sheet. This method is used for improved protection of the printing ink.
  • the present invention uses both direct/reverse printing on the PET film and the surface printing of anti-scratch varnish on the PET laminate sheet.
  • a laminate having a structure comprising:
  • a first layer which is an outer polyethylene film
  • a second layer which is an adhesive agent layer
  • a third layer which is a polyester film
  • a fourth layer which is an adhesive agent layer
  • a fifth layer which is a composite polyethylene film
  • composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
  • a layer of the polyester film is adhesive-laminated by using an adhesive agent on the top and/or bottom of the polyester film.
  • the type of the adhesive agent used in this process i s usually made of a two-component polyurethane.
  • the adhesive used in the adhesive-lamination can be a polyester- or polyether-based polyurethane resin.
  • An amount of the coated adhesive is in the range from 2 to 10 g/m 2 and preferably from 1-8 g/m .
  • Suitable solvents include aromatic hydrocarbons, alcohols, acetates, esters, and halogen-containing hydrocarbons.
  • this adhesi ve- lam inated PET multilayered film is further laminated with a polyethylene film using molten LLDPE by means of co-extrusion lamination.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be a mono-layered film, a three-layered film, or a multi-layered film.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may have thicknesses in the range of 90-165 microns, 120-140 microns, and 45-65 microns, respectively.
  • the polyester film is a polyethylene terephthalate (PET) film, preferably a printed amorphous polyester (APET) or oriented polyester (BOPET) film, and may have a thickness in the range of 12- 20 microns.
  • PET polyethylene terephthalate
  • APET printed amorphous polyester
  • BOPET oriented polyester
  • the co-extruded polyethylene layer may be selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof, and may have a thickness in the range of 15-80 microns.
  • a laminate having a structure comprising:
  • a first layer which is an outer polyethylene film
  • a second layer which is an adhesive agent layer
  • a third layer which is a polyester film
  • a fourth layer which is an adhesive agent layer
  • a fifth layer which is a composite polyethylene film.
  • Said composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
  • Said composite polyethylene film may further comprise at least one composite EVOH layer, wherein the composite EVOH layer comprises EVOH sandwiched by tie layers.
  • Said composite polyethylene film has a structure such that the composite EVOH layer, on the tie layers on both sides, are sandwiched by layers, each of which is at least one co-extruded polyethylene layer, and the composite EVOH layer, on the co-extruded polyethylene layers on both sides, are further sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
  • the adhesive-laminated PET multi layered film is further laminated with a polyethylene film using a molten copolymer of ethylene and vinyl alcohol (EVOH), tie, LLDPE by means of co-extrusion lamination,
  • EVOH ethylene and vinyl alcohol
  • the co-extrusion lamination in this step is performed in the following order: LLDPE/tie/EVOH tie/LLDPE.
  • LLDPE low density polyethylene
  • LDPE low density polyethylene
  • the five-layered co-extrusion lamination is existed in terms of restorability. Thicknesses of the tie layers and the LLDPE layers on both sides can be the same or different, but for a good example, the thicknesses of the LLDPE layers and the tie layers are 15 and 10 micrometers, respectively.
  • the composite EVOH layer comprises EVOH sandwiched by tie layers, wherein the composite EVOH layer is sandwiched by layers, each of which is at least one co -extruded polyethylene layer, on the tie layers on both sides.
  • the co-extruded polyethylene layer on each side may have a thickness in the range of 15-30 microns
  • the EVOH may have a thickness in the range of 10-30 microns
  • the tie layer on each side may have a thickness in the range of 0-20 microns.
  • the tie layer in this invention utilizes anhy dride-modifi ed polyethylene resins, low density polyethylene resins or linear low density polyethylene resins containing anhydride.
  • the extruded LLDPE layer may be made of a polyethylene resin with a density of 0.85-0.92 g/cc.
  • the outer or inner polyethylene films may be a blown film having 1-3 layers or more.
  • the outer and inner polyethylene films are flexible and comprise mixture of polyethylene such as high density polyethylene (HDPE), linear low density polyethylene (LLDPE) or low density polyethylene (LDPE).
  • HDPE high density polyethylene
  • LLDPE linear low density polyethylene
  • LDPE low density polyethylene
  • Thicknesses of the inner PE film in the range of approximately 90-165 micrometers and the outer PE film in the range of approximately 45-70 micrometers are preferable.
  • the outer and inner films are often a multi-layered blown film such as a three-layered film in order to obtain multilayerd-film performances such as translucency, toughness, rigidity, and seal ability.
  • the inner film having a multi-layered blown film is often used for obtaining various characteristics such as toughness, heat seal performance.
  • the polyethylene terephthalate (PET) film can generally be an amorphous polyester (APET) or oriented polyester (BOPET) film.
  • a thickness of the base film can be in the range of 10-25 microns.
  • the EVOH in this invention utilizes an ethylene-vinyl alcohol copolymer having an ethylene content in the range from 27 to 48%.
  • a thickness of the extruded EVOH layer can be in the range of 5-30 microns.
  • the co-extruded polyethylene layer may be selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof, and may have a thickness in the range of 15-30 microns.
  • a laminate having a structure comprising:
  • a first layer which is an outer polyethylene film
  • a second layer which is an adhesive agent layer
  • a third layer which is a polyester film
  • a fourth layer which is an adhesive agent layer
  • a fifth layer which is a composite polyethylene film
  • the laminate may further comprise a composite polyester film having a structure as follows:
  • layer I which is a polyethylene film
  • layer II which is a co-extruded polyethylene layer
  • layer IV which is an adhesive agent layer
  • composite polyester film is disposed between the fourth layer and the fifth layer, such that layer I is adhered to the adhesive agent layer of the fourth layer.
  • Said composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film have thicknesses in the range of 90-165 microns, 120-140 microns, and 45-65 microns, respectively.
  • Said metalized polyester film may have a thickness in the range of 10-25 microns.
  • Said co- extruded polyethylene layer may have a thickness in the range of 15-80 microns.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be a mono-layered film, a three-layered film, or a multi-layered film.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
  • the adhesive agent may be a two-component polyurethane.
  • the polyester film may be a polyethylene terephthalate (PET) film, preferably an amorphous polyester (APET) or oriented polyester (BOPET) film.
  • the third layer that is the polyester film may have been printed.
  • the co-extruded polyethylene layer may be selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer, and mixture thereof, and may have a thickness in the range of 12- 20 microns.
  • a laminate having a structure comprising:
  • a first layer which is an outer polyethylene film
  • a second layer which is an adhesive agent layer
  • a third layer which is a polyester film
  • a fourth layer which is an adhesive agent layer
  • a fifth layer which is a composite polyethylene film.
  • Said composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
  • Said composite polyethylene film may further comprise at least one composite EVOH layer, wherein the composite EVOH layer comprises EVOH sandwiched by tie layers.
  • Said composite polyethylene film has a structure such that the composite EVOH layer, on the tie layers on both sides, are sandwiched by layers, each of which is at least one co-extruded polyethylene layer, and the composite EVOH layer, on the co-extruded polyethylene layers on both sides, are further sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
  • the laminate may further comprise a composite polyester film having a structure as follows:
  • layer I which is a polyethylene film
  • layer II which is a co-extruded polyethylene layer
  • layer IV which is an adhesive agent layer, wherein the composite polyester film is disposed between the fourth layer and the fifth layer .such that layer I is adhered to the adhesive agent layer of the fourth layer.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may have thicknesses in the range of 90-120 microns, 40-60 microns, and 40-60 microns, respectively.
  • the composite EVOH layer comprises EVOH with a thickness in the range of 10-30 microns, and the tie layer on each side having a thickness in the range of 10-20 microns.
  • the tie is selected from the group consisting of anhydride-modified polyethylene resins, low density polyethylene resins, and linear low density polyethylene resins containing anhydride.
  • the metalized polyester film has a thickness in the range of 10-25 microns.
  • the co-extruded polyethylene layer has a thickness in the range of 15-80 microns.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are a mono-layered, three-layered, or multi-layered film.
  • the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
  • the adhesive agent is a two-component polyurethane.
  • the polyester film is a polyethylene terephthalate (PET) film, preferably an amorphous polyester (APET) or oriented polyester (BOPET) film.
  • the third layer, that is the polyester film, has been printed.
  • the co- extruded polyethylene layer is selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof.
  • the polyester film has a thickness in the range of 12-20 microns.
  • the metalized polyester film is obtained by evaporating either a metal, a metal oxide, or an inorganic substance on a base film made of polyethylene terephthalate (PET) with a thickness in the range of 10-25 microns.
  • PET polyethylene terephthalate
  • aluminium, chrome, or aluminium oxide are utilized as the metal, the metal oxide or the inorganic material used for evaporation coating. They can be vapor-deposited on the base film via any available known methods, such as vacuum deposition, ion plating, sputtering, plasma deposition, and the like. Chemical treatment prior to the metallization can be provided for improved bonding or so called "metal adhesion" between the metal and the PET.
  • a direct/reverse printed polyester film having a thickness of 12 microns is utilized as a substrate in order to form a multi-layered plastic sheet.
  • This PET film was dry- laminated on one side with a polyethylene film (140 microns), and then further dry-laminated on the other side with an outer polyethylene film (70 microns).
  • Adhesive used in this process is a urethane-based adhesive agent. A coating weight of the adhesive is about 4-5 g/m 2 .
  • this laminated film is further laminated with an inner polyethylene film (110 microns) by extrusion laminating with a hot-melted LLDPE resin. Finally, conventional anti -scratch varnish is coated on the top of the laminated sheet.
  • a direct/reverse printed polyester film (BOPET) having a thickness of 12 microns ⁇ is utilized as a substrate in order to form a multi-layered plastic sheet.
  • This PET film was dry- laminated on one side with a polyethylene film (140 microns), and then further dry-laminated on the other side with an outer polyethylene film (70 microns).
  • Adhesive used in this process is a urethane-based adhesive agent. A coating weight of the adhesive is about 4-5 g/m .
  • this laminated film is further laminated with an inner polyethylene film (110 microns) by extrusion laminating with a hot-melted LLDPE resin, tie and EVOH. Finally, conventional anti-scratch varnish is coated on the top of the laminated sheet.
  • a direct/reverse printed polyester film having a thickness of 12 microns is utilized as a substrate in order to form a multi-layered plastic sheet.
  • This PET film was dry- laminated on one side with a polyethylene film (40 microns), and then further dry-laminated on the other side with an outer polyethylene film (55 microns).
  • Adhesive used in this process is a urethane-based adhesive agent. A coating weight of the adhesive is about 4-5 g/m 2 .
  • a metal ized polyester film (mPET, 12 microns) is used in order enhance a gloss effect of a printing decoration. This metalized polyester film is dry-laminated with a polyethylene film (40 microns).
  • this metalized polyester film is further laminated with an inner polyethylene film (90 microns) by extrusion-laminating with a hot-melted LLDPE resin, tie, and EVOH, and then the metalized polyester laminate part is further laminated with the polyester laminate part by extrusion-laminating with a hot-melted LLDPE resin. Finally, conventional anti-scratch varnish is coated on the top of the laminated sheet.
  • OTR oxyge transmission rate
  • KPL-PET-01 has a higher oxygen transmission rate (the lower barrier) than that of the
  • PET/EVOH laminated sheet This feature may become generally known through the barrier property of the PET film itself.
  • KPL-PET-01 may be useful for manufacturing a body of a translucent laminated tube.
  • KPL-PET-02 that has extrusion-laminating with EVOH exhibits a much higher barrier property (the lower OTR value) than that of KPL-PET-01.
  • KPL-PET-02 may be suitable for increasing barrier in order to use for sensitive paste products.
  • the OTR and WVTR are almost comparable to KPL-PET-02.
  • the metalized PET film is added in order to enhance a gloss effect of the laminate sheet.
  • the laminated tube is ideally suited for low-oxygen-sensitive packaging of liquid or paste products.

Abstract

A polyester film laminated with other polymers to form a sheet. A laminated tube for liquid and paste products such as toothpastes, and the like can be manufactured from said sheet. The laminate comprises an outer polyethylene film, adhesive agent layers, a polyester film, and a composite polyethylene film comprising at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film and an inner polyethylene film.

Description

POLYESTER LAMINATE TUBE FOR CONTAINER
FIELD OF THE INVENTION
This present invention is in the field of materials science and relates to a polyester laminate tube for a packaging
BACKGROUND ART
A polyester film, particularly a biaxially-oriented film composed of polyethylene terephthalate, has been widely used as a packaging material or as a base for a reprographic film, etc. Common use of a PET film is the use for laminating with other polymers, paper or foil. The PET film is often coated with polyethylene or an ethylene copolymer by extrusion coating in order to obtain heat-sealing capability, adhesion to another material such as aluminium foil, additional bulk (thickness) or stiffness, or in order to achieve properties that are not possible to obtain with the PET film alone. Unfortunately, the surface of the PET film is not very receptive to the extrusion coating with other polymers. Solvent-based polyurethane adhesives and polyethyleneimine primers are commonly used in order to solve this problem. The PET film subjected to treating or priming for the extrusion coating without additional priming or corona treatment is preferable for a converter in order to laminate with other polymers.
A sheet material mainly uses for manufacturing a laminated tube container comprised of a plastic film in a tube body in order to prevent the contents from deterioration due to oxidation caused by oxygen coming from the outside of the laminated tube container. A material with excellent oxygen barrier property, water-vapor barrier property, etc. is exemplified as a barrier film laminated together with a polyethylene layer or another sealant layer. Aluminium foil is the most widely used material because of its very high gas barrier properties. However, the aluminium foil is inevitably opaque, so that it is not possible to see through the aluminium barrier laminate tube right to the contents inside. Hence, there is an increasing demand for the laminated tube container with high transparency.
A wide variety of PET laminates have been found to be useful in manufacturing of various designs of the packaging, and the following patents describe the types of laminate compositions that have been successfully used in the packaging of consumer goods.
US Patent No. 5,612,106 discloses a laminated tube container having the body comprising a substrate, a silicon oxide deposited layer, a heat buffer layer, and an extruded coating layer of a thermoadhesive resin. The heat buffer layer, such as PET, etc., prevents cracks from being generated in the silicon oxide deposited layer by the heat coming when the extruded coating layer of the thermoadhesive resin is laminated. The heat buffer layer is preferably formed by dry lamination or non-solvent lamination which requires no heating. An anchor coat layer may optionally be provided between the heat buffer layer and the extruded coating layer of the thermoadhesive resin so that the adhesion strength between these layers can be improved.
US Patent No. 5,942,320 discloses a barrier composite film comprising a base film, an anchor coat layer containing a silane coupling agent and a barrier resin such as a vinylidene chloride-series copolymer, an ethylene-vinyl alcohol copolymer, or etc., wherein the layers are formed on at least one side of the base film in the order of reference. The anchor coat layer can be made of a chlorine-containing resin, a polyisocyanate compound, and a saturated polyester resin having a glass transition temperature of -10°C to 20°C. A heat-sealing layer may be formed on the surface of the coating layer or the other side of the base film. This composite film provided with the inorganic layer can avoid losses of its adhesive properties and barrier properties even under severe conditions such as retort treatment.
PCT Patent application No. PCT/D O 1/00289 discloses a plastic laminate consisting of at least one plastic web and at least two plastic films disposed on each side of the plastic web and preferably connected to a web bond, wherein the laminate is pliable, and wherein respective melting points of the plastic films are approximately the same.
US Patent No. 10/493,088 discloses a composite film structure comprising a six-layered film. An outer layer is a non-melting layer such as oriented polyester. A second layer is linear low density polyethylene (LLDPE). A fourth layer is an EVOH layer sandwiched with an adhesive (third) layer. A fifth layer is a sealant layer. This composite film is useful for manu&cturing pouches using rotary thermic sealing.
US Patent No. 6,896,754 B2 discloses a wrapping clean film comprising at least two layers of thermoplastic resin films. The wrapping clean film is formed by dry-laminating co-extruded films composed of at least two layers of thermoplastic films on both front and rear surfaces of a heat-resisting substrate.
SUMMARY OF THE INVENTION
The present invention relates to a polyester film laminated with other polymers to form a sheet. A laminated tube for liquid and paste products such as toothpastes, lotions, and the like can be manufactured from said sheet. The present invention also relates to a laminated tube container having a body made of a sheet material comprising an outer polyethylene film, a polyester film, and an inner polyethylene film, which is formed into a laminated tube. This laminate tube can be used for storing paste products such as lotions, creams, toothpastes, and the like. DETAILED DESCRIPTION
This invention aims to provide a laminated tube container having gas barrier properties as well as a scratch resistance. The laminated tube for a packaging is commonly decorated by surface printing such as letterpress printing, flexographic printing, UV offset printing, etc. Direct or reverse printing on PET is also possible for the laminated rube. The printed PET film is further laminated with other plastic film in order to form a laminated sheet. This method is used for improved protection of the printing ink. However, the present invention uses both direct/reverse printing on the PET film and the surface printing of anti-scratch varnish on the PET laminate sheet.
In one embodiment of this invention, it relates to a laminate having a structure comprising:
a first layer which is an outer polyethylene film;
a second layer which is an adhesive agent layer;
a third layer which is a polyester film;
a fourth layer which is an adhesive agent layer; and
a fifth layer which is a composite polyethylene film,
wherein the composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
In this invention, a layer of the polyester film is adhesive-laminated by using an adhesive agent on the top and/or bottom of the polyester film. The type of the adhesive agent used in this process i s usually made of a two-component polyurethane.
The adhesive used in the adhesive-lamination can be a polyester- or polyether-based polyurethane resin. An amount of the coated adhesive is in the range from 2 to 10 g/m2 and preferably from 1-8 g/m . Suitable solvents include aromatic hydrocarbons, alcohols, acetates, esters, and halogen-containing hydrocarbons.
In this invention, this adhesi ve- lam inated PET multilayered film is further laminated with a polyethylene film using molten LLDPE by means of co-extrusion lamination. The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be a mono-layered film, a three-layered film, or a multi-layered film.
The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may have thicknesses in the range of 90-165 microns, 120-140 microns, and 45-65 microns, respectively.
The polyester film is a polyethylene terephthalate (PET) film, preferably a printed amorphous polyester (APET) or oriented polyester (BOPET) film, and may have a thickness in the range of 12- 20 microns.
The co-extruded polyethylene layer may be selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof, and may have a thickness in the range of 15-80 microns.
In another embodiment of this invention, it relates to a laminate having a structure comprising:
a first layer which is an outer polyethylene film;
a second layer which is an adhesive agent layer;
a third layer which is a polyester film;
a fourth layer which is an adhesive agent layer; and
a fifth layer which is a composite polyethylene film.
Said composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
Said composite polyethylene film may further comprise at least one composite EVOH layer, wherein the composite EVOH layer comprises EVOH sandwiched by tie layers. Said composite polyethylene film has a structure such that the composite EVOH layer, on the tie layers on both sides, are sandwiched by layers, each of which is at least one co-extruded polyethylene layer, and the composite EVOH layer, on the co-extruded polyethylene layers on both sides, are further sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
Alternatively, the adhesive-laminated PET multi layered film is further laminated with a polyethylene film using a molten copolymer of ethylene and vinyl alcohol (EVOH), tie, LLDPE by means of co-extrusion lamination, The co-extrusion lamination in this step is performed in the following order: LLDPE/tie/EVOH tie/LLDPE. While the LLDPE can be replaced with low density polyethylene (LDPE) or mixture of LLDPE and LDPE, the five-layered co-extrusion lamination is existed in terms of restorability. Thicknesses of the tie layers and the LLDPE layers on both sides can be the same or different, but for a good example, the thicknesses of the LLDPE layers and the tie layers are 15 and 10 micrometers, respectively.
The composite EVOH layer comprises EVOH sandwiched by tie layers, wherein the composite EVOH layer is sandwiched by layers, each of which is at least one co -extruded polyethylene layer, on the tie layers on both sides. The co-extruded polyethylene layer on each side may have a thickness in the range of 15-30 microns, the EVOH may have a thickness in the range of 10-30 microns, and the tie layer on each side may have a thickness in the range of 0-20 microns.
The tie layer in this invention utilizes anhy dride-modifi ed polyethylene resins, low density polyethylene resins or linear low density polyethylene resins containing anhydride.
The extruded LLDPE layer may be made of a polyethylene resin with a density of 0.85-0.92 g/cc.
The outer or inner polyethylene films may be a blown film having 1-3 layers or more. The outer and inner polyethylene films are flexible and comprise mixture of polyethylene such as high density polyethylene (HDPE), linear low density polyethylene (LLDPE) or low density polyethylene (LDPE).
Thicknesses of the inner PE film in the range of approximately 90-165 micrometers and the outer PE film in the range of approximately 45-70 micrometers are preferable. The outer and inner films are often a multi-layered blown film such as a three-layered film in order to obtain multilayerd-film performances such as translucency, toughness, rigidity, and seal ability. The inner film having a multi-layered blown film is often used for obtaining various characteristics such as toughness, heat seal performance.
The polyethylene terephthalate (PET) film can generally be an amorphous polyester (APET) or oriented polyester (BOPET) film. A thickness of the base film can be in the range of 10-25 microns. The EVOH in this invention utilizes an ethylene-vinyl alcohol copolymer having an ethylene content in the range from 27 to 48%. A thickness of the extruded EVOH layer can be in the range of 5-30 microns.
The co-extruded polyethylene layer may be selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof, and may have a thickness in the range of 15-30 microns.
In another embodiment of this invention, it relates to a laminate having a structure comprising:
a first layer which is an outer polyethylene film;
a second layer which is an adhesive agent layer;
a third layer which is a polyester film;
a fourth layer which is an adhesive agent layer; and
a fifth layer which is a composite polyethylene film,
wherein the laminate, as mentioned above, may further comprise a composite polyester film having a structure as follows:
layer I which is a polyethylene film;
layer II which is a co-extruded polyethylene layer;
layer III which is a metalized polyester film: and
layer IV which is an adhesive agent layer,
wherein the composite polyester film is disposed between the fourth layer and the fifth layer, such that layer I is adhered to the adhesive agent layer of the fourth layer.
Said composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film have thicknesses in the range of 90-165 microns, 120-140 microns, and 45-65 microns, respectively.
Said metalized polyester film may have a thickness in the range of 10-25 microns. Said co- extruded polyethylene layer may have a thickness in the range of 15-80 microns.
The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be a mono-layered film, a three-layered film, or a multi-layered film. The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may be selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
The adhesive agent may be a two-component polyurethane. The polyester film may be a polyethylene terephthalate (PET) film, preferably an amorphous polyester (APET) or oriented polyester (BOPET) film. The third layer that is the polyester film may have been printed. The co-extruded polyethylene layer may be selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer, and mixture thereof, and may have a thickness in the range of 12- 20 microns.
In another embodiment of this invention, it relates to a laminate having a structure comprising:
a first layer which is an outer polyethylene film;
a second layer which is an adhesive agent layer;
a third layer which is a polyester film;
a fourth layer which is an adhesive agent layer; and
a fifth layer which is a composite polyethylene film.
Said composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
Said composite polyethylene film may further comprise at least one composite EVOH layer, wherein the composite EVOH layer comprises EVOH sandwiched by tie layers. Said composite polyethylene film has a structure such that the composite EVOH layer, on the tie layers on both sides, are sandwiched by layers, each of which is at least one co-extruded polyethylene layer, and the composite EVOH layer, on the co-extruded polyethylene layers on both sides, are further sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
The laminate, as mentioned above, may further comprise a composite polyester film having a structure as follows:
layer I which is a polyethylene film;
layer II which is a co-extruded polyethylene layer;
layer III which is a metalized polyester film; and
layer IV which is an adhesive agent layer, wherein the composite polyester film is disposed between the fourth layer and the fifth layer .such that layer I is adhered to the adhesive agent layer of the fourth layer.
The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film may have thicknesses in the range of 90-120 microns, 40-60 microns, and 40-60 microns, respectively.
The composite EVOH layer comprises EVOH with a thickness in the range of 10-30 microns, and the tie layer on each side having a thickness in the range of 10-20 microns.
The tie is selected from the group consisting of anhydride-modified polyethylene resins, low density polyethylene resins, and linear low density polyethylene resins containing anhydride.
The metalized polyester film has a thickness in the range of 10-25 microns. The co-extruded polyethylene layer has a thickness in the range of 15-80 microns. The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are a mono-layered, three-layered, or multi-layered film.
The inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
The adhesive agent is a two-component polyurethane. The polyester film is a polyethylene terephthalate (PET) film, preferably an amorphous polyester (APET) or oriented polyester (BOPET) film. The third layer, that is the polyester film, has been printed. The co- extruded polyethylene layer is selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof. The polyester film has a thickness in the range of 12-20 microns.
The metalized polyester film is obtained by evaporating either a metal, a metal oxide, or an inorganic substance on a base film made of polyethylene terephthalate (PET) with a thickness in the range of 10-25 microns. Moreover, aluminium, chrome, or aluminium oxide are utilized as the metal, the metal oxide or the inorganic material used for evaporation coating. They can be vapor-deposited on the base film via any available known methods, such as vacuum deposition, ion plating, sputtering, plasma deposition, and the like. Chemical treatment prior to the metallization can be provided for improved bonding or so called "metal adhesion" between the metal and the PET.
The following part explains this invention in details by way of examples, however this invention is not considered to be limited only to these illustrative examples. EXAMPLE 1: KPL-PET-01 :
Outer PE Film 70/Dry/Printed PET 12/Dry/PE Film 140/LLex.65/Inner PE Film 110
A direct/reverse printed polyester film (BOPET) having a thickness of 12 microns is utilized as a substrate in order to form a multi-layered plastic sheet. This PET film was dry- laminated on one side with a polyethylene film (140 microns), and then further dry-laminated on the other side with an outer polyethylene film (70 microns). Adhesive used in this process is a urethane-based adhesive agent. A coating weight of the adhesive is about 4-5 g/m2. Afterwards, this laminated film is further laminated with an inner polyethylene film (110 microns) by extrusion laminating with a hot-melted LLDPE resin. Finally, conventional anti -scratch varnish is coated on the top of the laminated sheet.
EXAMPLE 2: KPL-PET-02:
Outer PE Film 70/Dry Printed PET 12/Dry/PE Film 140/LLex.l 5/Tie 10/EV 15/Tie 10/LLex.l 5/ Inner PE Film 110
A direct/reverse printed polyester film (BOPET) having a thickness of 12 microns · is utilized as a substrate in order to form a multi-layered plastic sheet. This PET film was dry- laminated on one side with a polyethylene film (140 microns), and then further dry-laminated on the other side with an outer polyethylene film (70 microns). Adhesive used in this process is a urethane-based adhesive agent. A coating weight of the adhesive is about 4-5 g/m . Afterwards, this laminated film is further laminated with an inner polyethylene film (110 microns) by extrusion laminating with a hot-melted LLDPE resin, tie and EVOH. Finally, conventional anti-scratch varnish is coated on the top of the laminated sheet.
EXAMPLE 3: KPL-PET-03:
Outer PE Film 55/Dry PET Film 12/Printing/Dry/PE Film 40/LLex.65/mPET Film 12/Dry/ PE Film 40/LLex.15/Tie 10/EVOH 15/Tie 10/LLex.l5/Irmer PE Film 90
A direct/reverse printed polyester film (BOPET) having a thickness of 12 microns is utilized as a substrate in order to form a multi-layered plastic sheet. This PET film was dry- laminated on one side with a polyethylene film (40 microns), and then further dry-laminated on the other side with an outer polyethylene film (55 microns). Adhesive used in this process is a urethane-based adhesive agent. A coating weight of the adhesive is about 4-5 g/m2. A metal ized polyester film (mPET, 12 microns) is used in order enhance a gloss effect of a printing decoration. This metalized polyester film is dry-laminated with a polyethylene film (40 microns). Afterwards, this metalized polyester film is further laminated with an inner polyethylene film (90 microns) by extrusion-laminating with a hot-melted LLDPE resin, tie, and EVOH, and then the metalized polyester laminate part is further laminated with the polyester laminate part by extrusion-laminating with a hot-melted LLDPE resin. Finally, conventional anti-scratch varnish is coated on the top of the laminated sheet.
Table 1
Figure imgf000011_0001
According to table 1 , oxyge transmission rate (OTR) and water vapor transmission rate
(WVTR) were evaluated in accordance with ASTM D3985 and ASTM F1249, respectively.
KPL-PET-01 has a higher oxygen transmission rate (the lower barrier) than that of the
PET/EVOH laminated sheet. This feature may become generally known through the barrier property of the PET film itself. KPL-PET-01 may be useful for manufacturing a body of a translucent laminated tube. KPL-PET-02 that has extrusion-laminating with EVOH exhibits a much higher barrier property (the lower OTR value) than that of KPL-PET-01. KPL-PET-02 may be suitable for increasing barrier in order to use for sensitive paste products. In the case of KPL- PET-03 , the OTR and WVTR are almost comparable to KPL-PET-02. The metalized PET film is added in order to enhance a gloss effect of the laminate sheet. The laminated tube is ideally suited for low-oxygen-sensitive packaging of liquid or paste products.

Claims

1. A laminate having a layer structure as follows:
a first layer which is an outer polyethylene film;
a second layer which is an adhesive agent layer;
a third layer which is a polyester film;
a fourth layer which is an adhesive agent layer; and
a fifth layer which is a composite polyethylene film,
wherein the composite polyethylene film comprises at least one co-extruded polyethylene layer sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
2. The laminate according to claim 1 in which said composite polyethylene film further comprises at least one composite EVOH layer, wherein: the composite EVOH layer comprises EVOH sandwiched by tie layers; and said composite polyethylene film has a structure such that the composite EVOH layer, on the tie layers on both sides, are sandwiched by layers, each of which is at least one co-extruded polyethylene layer, and the composite EVOH layer, on the co- extruded polyethylene layers on both sides, are further sandwiched by at least one polyethylene film adhered to the adhesive agent layer and an inner polyethylene film.
3. The laminate according to claim 1 or 2, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are a mono- layered film, a three-layered film, or a multi-layered film.
4. The laminate according to any one of claims 1 -3, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
5. The laminate according to any one of claims 1-4, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film have thicknesses in the range of 90-165 microns, 120-140 microns, and 45-65 microns, respectively.
6. The laminate according to any one of previous claims, wherein the adhesive agent is a two-component polyurethane.
7. The laminate according to any one of previous claims, wherein the polyester film is a polyethylene terephthalate (PET) film, preferably an amorphous polyester (APET) or oriented polyester (BOPET) film.
8. The laminate according to any one of previous claims, wherein the polyester film has a thickness in the range of 12-20 microns.
9. The laminate according to any one of previous claims, wherein the polyester fi lm has been printed.
10. The laminate according to any one of previous claims, wherein the co-extruded polyethylene layer is selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof.
11. The laminate according to claim 1 , wherein the co-extruded polyethylene layer has a thickness in the range of 15-80 microns.
12. The laminate according to claim 2, wherein the co-extruded polyethylene layer on each side has a thickness in the range of 15-30 microns.
13. The laminate according to claim 12, wherein the composite EVOH layer comprises the EVOH having a thickness in the range of 10-30 microns, and the tie layer on each side has a thickness in the range of 10-20 microns.
14. The laminate according to claim 2 or 13, wherein the tie is selected from the group consisting of anhydride-modified polyethylene resins, low density polyethylene resins, and linear low density polyethylene resins containing anhydride.
15. The laminate according to claim 1 further comprising a composite polyester film having a structure as follows:
layer I which is a polyethylene film;
layer II which is a co-extruded polyethylene layer;
layer III which is a metalized polyester film; and
layer IV which is an adhesive agent layer,
wherein the composite polyester film is disposed between the fourth layer and the fifth layer, such that layer I is adhered to the adhesive agent layer of the fourth layer.
16. The laminate according to claim 2 further comprising a composite polyester film having a structure as follows:
layer I which is a polyethylene film;
layer II which is a co-extruded polyethylene layer;
layer III which is a metalized polyester film; and
layer IV which is an adhesive agent layer. wherein the composite polyester film is disposed between the fourth layer and the fifth layer, such that layer I is adhered to the adhesive agent layer of the fourth layer.
17. The laminate according to claim 15, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film have thicknesses in the range of 90-165 microns, 120-140 microns, and 45-65 microns, respectively.
18. The laminate according to claim 16, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film have thicknesses in the range of 90-120 microns, 40-60 microns, and 40-60 microns, respectively.
19. The laminate according to claim 16 or 18, wherein the composite EVOH layer comprises the EVOH having a thickness in the range of 10-30 microns, and the tie layer on each side has a thickness in the range of 10-20 microns.
20. The laminate according to any one of claims 16, 18 and 19, wherein the tie is selected from the group consisting of anhydride-modified polyethylene resins, low density polyethylene resins, and linear low density polyethylene resins containing anhydride.
21. The laminate according to any one of claims 15-20, wherein the metalized polyester film has a thickness in the range of 10-25 microns.
22. The laminate according to any one of claims 15-21, wherein the co-extruded polyethylene layer has a thickness in the range of 15-80 microns.
23. The laminate according to any one of claims 15-22, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are a mono-layered film, a three-layered film, or a multi-layered film.
24. The laminate according to any one of claims 15-23, wherein the inner polyethylene film, the polyethylene film adhered to said adhesive agent layer, and the outer polyethylene film are selected from the group consisting of LDPE, LLDPE, HDPE, and mixture thereof.
25. The laminate according to any one of claims 15-24, wherein the adhesive agent is a two-component polyurethane.
26. The laminate according to any one of claims 15-25, wherein the polyester film is a polyethylene terephthalate (PET) film, preferably an amorphous polyester (APET) or oriented polyester (BOPET) film.
27. The laminate according to any one of claims 15-26, wherein the third layer, that is polyester film, has been printed.
28. The laminate according to any one of claims 15-27, wherein the co-extruded polyethylene layer is selected from the group consisting of an extruded LLDPE layer, an extruded LDPE layer and mixture thereof.
29. The laminate according to any one of claims 15-28, wherein the polyester film has a thickness in the range of 12-20 microns.
30. A tube container manufactured from the laminate according to any one of claims 1-29.
PCT/TH2017/000024 2016-12-27 2017-03-22 Polyester laminate tube for container WO2018124976A1 (en)

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EP17887948.2A EP3562670A4 (en) 2016-12-27 2017-03-22 Polyester laminate tube for container
CN201780028243.8A CN109070562B (en) 2016-12-27 2017-03-22 Polyester laminated tube for container
US16/315,815 US11702262B2 (en) 2016-12-27 2017-03-22 Polyester laminate tube for container

Applications Claiming Priority (2)

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TH1601007772A TH166248A (en) 2016-12-27 Polyester laminate tubes for packaging
TH1601007772 2016-12-27

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CN109070562B (en) 2021-11-16
EP3562670A4 (en) 2020-08-12
US20190300252A1 (en) 2019-10-03
CN109070562A (en) 2018-12-21
US11702262B2 (en) 2023-07-18

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